WO2000046492A1 - Black smoke/particulates controlling device for diesel engines and auxiliary device for exhaust gas reduction - Google Patents
Black smoke/particulates controlling device for diesel engines and auxiliary device for exhaust gas reduction Download PDFInfo
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- WO2000046492A1 WO2000046492A1 PCT/JP2000/000556 JP0000556W WO0046492A1 WO 2000046492 A1 WO2000046492 A1 WO 2000046492A1 JP 0000556 W JP0000556 W JP 0000556W WO 0046492 A1 WO0046492 A1 WO 0046492A1
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- Prior art keywords
- exhaust gas
- filter
- black smoke
- heat
- particulate matter
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
- F01N3/0226—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being fibrous
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/13—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories
- F02M26/22—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories with coolers in the recirculation passage
- F02M26/29—Constructional details of the coolers, e.g. pipes, plates, ribs, insulation or materials
- F02M26/32—Liquid-cooled heat exchangers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/13—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories
- F02M26/35—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories with means for cleaning or treating the recirculated gases, e.g. catalysts, condensate traps, particle filters or heaters
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2370/00—Selection of materials for exhaust purification
- F01N2370/22—Selection of materials for exhaust purification used in non-catalytic purification apparatus
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the present invention relates to a diesel engine exhaust purification device and an exhaust gas reduction auxiliary device, and particularly to exhaust (particulate) black smoke and particulate matter at a heat resistant temperature.
- a continuous fiber of 700-1000 ° C or continuous fiber of aluminum at 1400 ° C it collects sparks and coarse particles, and 0.03 micron particles are collected in the secondary filter. Repair is also possible.
- clean exhaust gas from diesel engines can be used to reduce harmful exhaust gas such as N02 by recirculating clean exhaust gas from the outlet. It relates to a reduction assisting device. Background art
- the particulate matter and black smoke removal device is a black filter collected by a ceramic filter, such as silicon carbide (Sic) or cordierite, made of a wall-honeycomb cylindrical shape.
- Smoke and particulate matter can be regenerated by operating the burner at a burner temperature of about 720 ° C for about 10 minutes to regenerate.
- Mic eight-cam-shaped cylindrical filter Air flows the particulate matter collected by the filter in the direction opposite to that of the exhaust gas, and the fine particles attached to the wall K are moved to the hopper by gravity. Dropping and incineration with an electric heater. Electric heater by collecting with a ceramic honeycomb filter. Incineration by burners is the mainstream.
- the configuration of the present invention does not use expensive ceramic filters and electric heating heaters, and the material of the filters includes an urban waste incinerator.
- High cost bag filter for dust collection with PTFE (Volatile Fluoroethylene) fiber filter which has been used for several decades, enables low cost.
- the membrane filter is a tough, supple, fine, continuous porous body made by advanced special processing technology. It has a surface filtration function and is hardly clogged.
- Traditional filter bags relied on dust primary deposition to deposit dust locally, but this primary adhesion could be an obscure cause. This reduced the function of the dust collector: in contrast, the membrane filter knuckle filtered the dust through the surface of the membrane that was laminated to the surface. It has a complete surface filtration function. In other words, there is no need for a primary adhesion layer that causes clogging.
- the filter bag has excellent characteristics such as low pressure loss and increased processing air volume.
- the technical challenge is to reduce the exhaust gas temperature to 260 ° C or less using a radiator.
- a radiator For this purpose, the use of a stand-alone mini-cyclone that also functions as a radiator, aluminum with good heat dissipation characteristics, etc., and installation of a membrane filter, heat sink, etc. on the side of the main unit, You can use the filter for a longer time.
- FIG. 1 is a partial filter cut-away front sectional view showing a device for purifying black smoke and particulate matter according to a first embodiment of the present invention.
- Figure 2 shows the finalizer unit.
- Figure 3 shows the black smoke, particulate matter purification device, and the outer structure.
- FIG. 4 is a side view of the membrane filter bag.
- Figure 5 shows a thin retainer c
- FIG. 6 is a front view of the thin retainer.
- FIG. 7 is a cross-sectional plan view of the apparatus for purifying black smoke and particulate matter.
- the exhaust gas is injected from the nozzle to directly regenerate the membrane filter bag.
- FIG. 8 is a side sectional view of FIG. 7 in the same manner.
- Figure 9 shows a box for collecting black smoke and particulate matter.
- Fig. 10 is a front sectional view of the dust collection box.
- Fig. 11 shows the structure of the valve.
- Fig. 12 shows a black smoke and particulate matter purification device, and a membrane filter. Vibration fine contact type
- FIG. 13 is a front cross-sectional view of the regeneration method.
- FIG. 13 is a plan cross-sectional view of FIG. Black smoke and particulate matter purification equipment
- FIG. 14 is a cross-sectional view showing the structure of the fine vibration contact type shown in FIG. BEST MODE FOR CARRYING OUT THE INVENTION
- FIG. 1 shows a structure of a first embodiment of a device for purifying diesel engine black smoke and particulate matter and an auxiliary device for reducing exhaust gas according to the present invention.
- the filter regeneration method used exhaust gas and air. This is a backwash method. When using the filter, the exhaust gas inlet of 13 and the valve of 15 are taken, and the flue of 16 enters the black smoke and particulate matter purifier through the flue of 16.
- the black smoke and particulate matter purifying apparatus of the present invention has three regeneration methods, and can be used in appropriate combination.
- Fig. 7 shows the second playback method.
- the nozzle injection regeneration system using exhaust gas shown in Fig. 8, and the order of regeneration is the same as the valve operation in the backwash system shown in Fig. 2.
- the black smoke and particulate matter purifying device of the nozzle injection regeneration system was injected from the nozzles of the 23 injection pipes when the filter was used, and the exhaust gas was 19, 5, 6, 7 , 8, and 9 are emitted.
- the exhaust gas is discharged from the exhaust outlet at 28 because the valve 25 in the dust collection box in Fig. 9 opens and the exhaust valve opens when the filter 8 is used. Go outside. Playback time is about 1-2 minutes. At this time, black smoke and particulate matter are also sent to the 27 heat-resistant dust collection pack. This heat-resistant dust-collecting pack should be replaced and used as needed.
- the dust-collecting box 24 can be dust-collected by an electric motor, and dust can be collected at any time. You can do this.
- the scraper of 32 shown in Fig. 12, Fig. 13, and Fig. 14 vibrates up and down to the membrane filter of 19.
- Regeneration is performed by making a slight contact, and the operation sequence of the valve during the regeneration uses exhaust gas and air. The same applies to the backwashing method and the exhaust injection regeneration method.
- on-road driving test as a result of conducting a driving test on December 30, 1998, January 3 and 4, and 2-ton track, good collection performance and feasibility were obtained. I was able to get the best playback function
- the size of the filter used was a flat hollow type with a width of 120 and a length of 300, and four filters were used. Approximately 5 hours operating time Engine rotation speed 700-3800
- the temperature of one room of the secondary filter was the highest at about 180 degrees.
- the gears are set to the engine speed of 3800 and the speed of 70 keys.
- the mouth of the secondary filter after running for 20 minutes
- the temperature of the primary filter room temperature 290 degrees was recorded, the configuration of the black smoke and particulate matter purification device is shown in Fig. 1 3 Fig. 1
- the hot gas filter collects sparks and coarse particles.
- This fiber uses fire-continuous fiber with a heat-resistant temperature of 700 or aluminum continuous fiber with a heat-resistant temperature of 1400 ° C to collect sparks and coarse particles.
- This thickness is on the order of 0.6 mm to 0.8 mm.
- there is a wire mesh such as SUS316, which also catches sparks and coarse particles.
- the above-mentioned PTFE (volume tetrafluoroethylene) fiber membrane filter has a heat resistant temperature of 260 ° C. Therefore, when the temperature is 260 ° C or more, the temperature sensor or speed Control the temperature with a sensor, etc. so that the temperature does not exceed 260 ° C. For example, stop using the filter at a set temperature of 230 ° C and use a normal muffler. Can be switched to.
- the above-mentioned operation of the switching valve can be performed by a motor, air cylinder, or electric cylinder, but it can also be performed by wire-type manual operation to save cost. You.
- the pressure sensor operates the switching valve when the filter becomes clogged.
- the vibration of the wiping mechanism utilizes the vibration of the car, and the wiping device removes the fine particles adhering to the filter surface by the vibration of the spring.
- a constant vibration type wiping-off mechanism is a camshaft that oscillates in a constant cycle in order to extend the life of the filter.
- Recirculating clean exhaust gas to the intake pipe of the engine can also be used to reduce nitrogen oxides.
- a heat-resistant packing such as expanded black smoke braided packing that has a heat-resistant temperature of 600.
- the performance of the filter for collecting black smoke and particulate matter is high, and by using aluminum for the main body, heat dissipation is improved and the weight is reduced Also, the cost is low.
- Separating the radiator with a part of the filter increases the degree of freedom of the mounting base and the size of the secondary filter. Therefore, vertical type and horizontal type in backwash type are also possible, making it possible to manufacture thin type-
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
- Processes For Solid Components From Exhaust (AREA)
- Filtering Materials (AREA)
Abstract
Description
明細書 ディ ーゼルエ ンジンの黒煙、 微粒子状物質浄化装置及び排ガス低減補助 Description Diesel engine black smoke and particulate matter purification equipment and exhaust gas reduction assistance
技術分野 Technical field
本発明は ディ ーゼルエ ン ジ ンの排気浄化装置、 及び排ガス低減補助 装置で、 特に排気 (微粒子) 黒煙、 微粒子状物質を耐熱温度 The present invention relates to a diesel engine exhaust purification device and an exhaust gas reduction auxiliary device, and particularly to exhaust (particulate) black smoke and particulate matter at a heat resistant temperature.
700 度 一 1000 度のシ リ カ連続繊維や、 1400 度のアル ミ ナ連続繊 維等を使用 して、 火の粉や粗い粒子を捕集、 2次フ ィ ルタ一に 0.03 ミ ク ロ ン粒子の補修も可能に した- ポ リ テ ト ラ フ ロ ロエチ レン(PTFE)繊維を 使用 して、 黒煙及び微粒子状物質を捕集 し、 それを振動式払い落と し機 構及び排気ガス, 及びエアーを活用 した逆洗式、 排気ガス使用 ノ ズル噴 射再生方式によ り 再生を可能に したものである。 更に出 口 よ り のク リ 一 ンな排ガス を再循環させる こ と によ り 、 N02等の有害排気ガス低減にも 役立てる こ と が可能な ディ ーゼルエンジンの黒煙、 微粒子状物質浄化 装置及び排ガス低減補助装置 に関する も のであ る。 背景技術 Using a continuous fiber of 700-1000 ° C or continuous fiber of aluminum at 1400 ° C, it collects sparks and coarse particles, and 0.03 micron particles are collected in the secondary filter. Repair is also possible.-Uses polytetrafluoroethylene (PTFE) fiber to collect black smoke and particulate matter, and then removes it with a vibration-type sweeping mechanism, exhaust gas, and air. Regeneration is made possible by a back-washing type using exhaust gas and a nozzle injection regeneration method using exhaust gas. In addition, clean exhaust gas from diesel engines can be used to reduce harmful exhaust gas such as N02 by recirculating clean exhaust gas from the outlet. It relates to a reduction assisting device. Background art
特開平 9- 25813 、 特開平 8- 281034 、 特開平 9-4436、 号等公報に 開示されるディ 一ゼルエ ンジンの排気浄化装置では Japanese Patent Application Laid-Open Nos. 9-25813, 9-281034, 9-4436, etc. disclose exhaust gas purifying apparatuses for diesel engines.
粒子状物質と 黒煙の除去装置はウォールフ ロ 一ハニカム形状を した円筒 形ででき てい る炭化珪素(Sic)やコ ージュ ライ ト 等のセ ラ ミ ッ ク フ ィ ル タ一で捕集 した黒煙及び粒子状物質を、 バーナー温度 720度く らいで再 生時間に約 10 分間バーナーを作動させ再生をする方式や、 同 じ く セラ ミ ッ ク 八 -カ ム形状円筒状フ ィ ルタ 一で捕集された粒子状物質をエアー を排気ガス と 逆方向の経路で流動 させ、 壁 Kに付着 した微粒子を重力に よ り ホ ッパーへ落下 し、 電気 ヒ 一タ ーで焼却する方法、 セ ラ ミ ッ ク ハニ カ ム フ ィ ルターで捕集を して電気 ヒ ーター。 バーナーで焼却させる方法 が主流になっている。 その他、 不織布状のセ ラ ミ ッ ク繊維材 (炭化珪素) に付着 した、 粒子状物質を燃焼させる金網 ヒ ーターを密着させた蛇腹型 の フ ィ ルタ 一等も出てい る。 The particulate matter and black smoke removal device is a black filter collected by a ceramic filter, such as silicon carbide (Sic) or cordierite, made of a wall-honeycomb cylindrical shape. Smoke and particulate matter can be regenerated by operating the burner at a burner temperature of about 720 ° C for about 10 minutes to regenerate. Mic eight-cam-shaped cylindrical filter Air flows the particulate matter collected by the filter in the direction opposite to that of the exhaust gas, and the fine particles attached to the wall K are moved to the hopper by gravity. Dropping and incineration with an electric heater. Electric heater by collecting with a ceramic honeycomb filter. Incineration by burners is the mainstream. In addition, there is a bellows-type filter with a wire mesh heater attached to a nonwoven ceramic fiber material (silicon carbide) that burns particulate matter.
し力、 し、 セラ ミ ッ ク フ ィ ルタ一式の価格は ¥ 450 万 と 高 コ ス トであ り 、 現状では横浜市営バスに 60 台納入されているが、 普及にはかな り の期 間を要する と 思われる。 The price of a set of ceramic filters is a high cost of ¥ 4.5 million, and currently 60 units are delivered to Yokohama municipal buses. It seems to be necessary.
環境庁が 98年 10月 2 日 に発表 した、 自動車 NOX法制定時の 「公約」 だった。 2 0 0 0 年度の基準達成が絶望的になった こ と が、 大気汚染調 査からわかった。 It was a “commitment” announced by the Environment Agency on October 2, 1998 when the automobile NOX law was enacted. The air pollution survey showed that the achievement of the standards for fiscal 2000 was hopeless.
環境庁によ る と 、 今 日 、 千葉、 祌奈川、 埼玉、 大阪、 兵庫の 6都府県 の幹線道路沿いに設置された 「 自動車排ガス測定局」 ( 172) での窒素酸 化物環境基準 (0.04pp m ― 0. 06pp m) 達成率は 34,3 %。 96 年度 と比 ベて横ばいだった。 全国的に見て も 、 自 動車局 (410) の窒素酸化物基 準達成率は 65. 7 %、 主にディ ーゼル車から排出 される粒子状物質(SPM) は、 同 32, 9% と いずれも低い値で推移 している。 ヨ ーロ ッパにおける粒 子状物質の排出ガス規制値ユー ロ 2 と 、 日本の平成 6 年の粒子状物質 (SPM)規制値を比較する と約 5 倍ほ ど厳しい規制 と なっている。 ァメ リ 力においても米環境保護局(EPA)は、 自動車な どのディ ーゼルエ ンジン の排ガス規制に乗 り 出す。 ディ 一ゼル排ガス中の微粒子が低濃度でも肺 がんを引 き起 こす危険性があ る と のデータ が健康影響調査で得られた 98年 5 月 の専門家会合を経て、規制內容を決定する基になる最終報告書 を 9 8 年夏にま と める。 日 本において も 、 国立環境研究所総合研究官、 嵯峨井勝氏によ って、 ディ ーゼル排気微粒子によ る健康被害が科学的に実証されている。 その 内容 と は、 ディ 一ゼル棑気微粒子が従来の喘息と は別の 「都市型喘息」を 起こす仕組みを実証、それが公害訴訟の流れに大き な変革を もた ら した。 以上のよ う な現状を考えてみる と 、 低コ ス ト な黒煙、 微粒子状物質除去 装置を早急に提供する必要がある。 発明の開示 According to the Environment Agency, today, the Nitrogen Oxide Environmental Standards (0.04 pp) at the “Automobile Exhaust Gas Monitoring Bureau” (172) installed along the main roads in six prefectures in Chiba, Kanagawa, Saitama, Osaka, and Hyogo prefectures m-0.06 pp m) The achievement rate is 34.3%. The level was flat compared to 1996. Looking at the whole country, the rate of achievement of the Nitrogen Oxide Standard of the Motor Vehicle Administration (410) was 65.7%, and the particulate matter (SPM) mainly emitted from diesel vehicles was 32,9%. All have been low. A comparison of the EU regulation value for particulate matter Euro 2 in Europe with the regulation value for particulate matter (SPM) in Japan in 1994 shows that the regulation is about five times as strict. In the United States, the U.S. Environmental Protection Agency (EPA) is embarking on emissions regulations for diesel engines such as automobiles. Decision on regulatory content after an expert meeting in May 1998 obtained data from a health impact study that found that even low concentrations of diesel exhaust gas could cause lung cancer. Final report to be compiled in the summer of 1998. In Japan as well, Dr. Masaru Sagai, Researcher, National Institute for Environmental Studies, has scientifically demonstrated the health hazards caused by diesel exhaust particulates. Its content demonstrated how diesel air particles can cause “urban asthma” that is different from conventional asthma, and this has led to a major change in the flow of pollution litigation. Considering the above situation, it is necessary to provide a low-cost black smoke and particulate matter removal device as soon as possible. Disclosure of the invention
上記 目 的を達成するために、 本発明の構成は高価なセラ ミ ッ ク フ ィ ル タ一及び電熱 ヒ ータ一を使用せず、 フ ィ ルタ一の素材には、 都市型ごみ 焼却炉の集塵用高温バグフ ィ ルタ 一で数 10年の実績がある、 PTFE (ボ リ テ ト ラ フ ロ ロエチ レン) 繊維メ ン レ ンフ ィ ルターを使用 して低コ ス ト を可能に します。 メ ンブレンフ ィ ルタ一は、 高度な特殊加工技術によ り 、 強靭かっ しなやかで微細な連続多孔体と したものです 表面ろ過機 能を持ち、 目詰ま り が しに く い構造である。 従来のフ ィ ルタ ーバ ッ グは、 ダス ト のろ過を內部に堆積する ダス ト の 1次付着層に依存 していま した しか し、 こ の 1 次付着層が 目 づま り の原因 と な り 、 集塵機の機能を低下 させていたのです: これに対 して、 当 メ ンブレンフ ィ ルタ一ノくッ グは、 表面にラ ミ ネ一 ト されたメ ンブ レンの表面でダス ト をろ過する と レ、 ぅ 完 全な表面ろ過機能を備えています。 つま り 、 目詰ま り の原因 と なる 1 次 付着層を必要と しないのです。 どのよ う な払い落と し機構を備えた集塵 機でも、 低い圧力損失、 処理風量の増加な どの優れた特性を持つフ ィ ル タ一バ ッ グであ り ます。 In order to achieve the above object, the configuration of the present invention does not use expensive ceramic filters and electric heating heaters, and the material of the filters includes an urban waste incinerator. High cost bag filter for dust collection with PTFE (Volatile Fluoroethylene) fiber filter, which has been used for several decades, enables low cost. . The membrane filter is a tough, supple, fine, continuous porous body made by advanced special processing technology. It has a surface filtration function and is hardly clogged. Traditional filter bags relied on dust primary deposition to deposit dust locally, but this primary adhesion could be an obscure cause. This reduced the function of the dust collector: in contrast, the membrane filter knuckle filtered the dust through the surface of the membrane that was laminated to the surface. It has a complete surface filtration function. In other words, there is no need for a primary adhesion layer that causes clogging. Regardless of the type of dust collector, the filter bag has excellent characteristics such as low pressure loss and increased processing air volume.
PTFE 100%であるため、 リ リ ース制、 耐熱性 ( - 240〜 + 260°C ) 耐薬品 性 (溶融アルカ リ 金属、 活性期のフ ッ素ガス以外にはおかされません) をすベて兼ね備えてお り ます。 フ イ ノレタ ーメ ーカ一によ る捕集効率試験によ る と 、 試験紛体 JI S 1 2種力 一ボンブラ ッ ク の捕集効率は 99. 99 %以上である しか し、 耐熱温度が 最高で 260;Cであ るため、 260 以下の条件の も と での使用制限が必要 になる。 Since it is 100% PTFE, it has a release system, heat resistance (-240 to + 260 ° C), and chemical resistance (it cannot be used except for molten alkali metal and active fluorine gas). It has all the features. According to the collection efficiency test by a final manufacturer, the collection efficiency of the test powder JIS 1 two-strength one-bon black was 99.99% or more, but the heat resistance temperature was lower. Since the maximum is 260 ; C, use under 260 or less is required.
こ の技術課題は排ガス温度を放熱器によ り 260度以下に下げる こ と であ る。 そのために独立型の放熱器兼用 ミ ニサイ ク ロ ン、 放熱特性 の良いアル ミ 等の使用、 本体の側面にメ ンブ レンフ ィ ルタ 一、 放熱板等 の取 り 付ける こ と によ り 、 フ ィ ルタ 一の使用 をよ り 長 く 使 う こ と が出来 る。 図面の簡単な説明 The technical challenge is to reduce the exhaust gas temperature to 260 ° C or less using a radiator. For this purpose, the use of a stand-alone mini-cyclone that also functions as a radiator, aluminum with good heat dissipation characteristics, etc., and installation of a membrane filter, heat sink, etc. on the side of the main unit, You can use the filter for a longer time. BRIEF DESCRIPTION OF THE FIGURES
第 1 図は、 本発明の第一の実施例に係わる、 黒煙、 微粒子状物質浄化装 置を示す、 一部フ ィ ルタ 一ュ - ッ ト正面断面図である。 FIG. 1 is a partial filter cut-away front sectional view showing a device for purifying black smoke and particulate matter according to a first embodiment of the present invention.
第 2図は、 フ イ ノレタ ーユニ ッ トである。 Figure 2 shows the finalizer unit.
第 3図は、 黒煙、 微粒子状物質浄化装置、 外側の構造である。 Figure 3 shows the black smoke, particulate matter purification device, and the outer structure.
第 4図は、 メ ンブ レ ンフ ィ ルタ 一バ ッ グの側面図である。 FIG. 4 is a side view of the membrane filter bag.
第 5 図は、 薄型 リ テ一ナ一である c Figure 5 shows a thin retainer c
第 6図は、 薄型 リ テーナ一の正面図である。 FIG. 6 is a front view of the thin retainer.
第 7 図は、 黒煙、 微粒子状物質浄化装置の平面の断面図である。 排気ガ ス をノ ズルから噴射 して、 直接メ ンブ レンフ ィ ルタ一バ ッ グを再生する ものである。 FIG. 7 is a cross-sectional plan view of the apparatus for purifying black smoke and particulate matter. The exhaust gas is injected from the nozzle to directly regenerate the membrane filter bag.
第 8 図は、 同 じ く 第 7 図の側面の断面図である。 FIG. 8 is a side sectional view of FIG. 7 in the same manner.
第 9 図は、 黒煙、 微粒子状物質の集塵ボ ッ ク スである。 Figure 9 shows a box for collecting black smoke and particulate matter.
第 1 0 図は、 集塵ボ ッ ク ス の正面断面図である Fig. 10 is a front sectional view of the dust collection box.
第 1 1 図は、 バルブの構造である。 Fig. 11 shows the structure of the valve.
第 1 2 図は、 黒煙、 微粒子状物質浄化装置で、 メ ンブ レンフ ィ ルタ 一バ ッ グに対 して、 振動微接触型 Fig. 12 shows a black smoke and particulate matter purification device, and a membrane filter. Vibration fine contact type
再生方式の正面断面図である - 第 1 3 図は、 第 1 2 図の平面断面図である。 黒煙、 微粒子状物質浄化装 置 FIG. 13 is a front cross-sectional view of the regeneration method. FIG. 13 is a plan cross-sectional view of FIG. Black smoke and particulate matter purification equipment
第 1 4 図は、 第 1 3 図の振動微接触型の構造を示 した、 断面図である。 発明を実施するための最良の形態 FIG. 14 is a cross-sectional view showing the structure of the fine vibration contact type shown in FIG. BEST MODE FOR CARRYING OUT THE INVENTION
本発明をよ り 詳細に説述するために、 添付の図面に したがつて これを 説明する。 図 1 は本発明に係わるディ ーゼルエ ンジ ンの黒煙、 微粒 子状物質浄化装置及び排ガス低減補助装置 の第一の実施例を示す構造 である。 フ ィ ルタ 一の再生方式は、 排気ガス及びエア一を使用 した。 逆 洗方式である。 フ ィ ルタ 一の使用時は、 1 3 の排気ガス入口から、 1 5 のバルブを と う り 、 1 6 の煙道から 、 黒煙、 微粒子状物質浄化装置に入 る。 In order to explain the present invention in more detail, this will be described with reference to the accompanying drawings. FIG. 1 shows a structure of a first embodiment of a device for purifying diesel engine black smoke and particulate matter and an auxiliary device for reducing exhaust gas according to the present invention. The filter regeneration method used exhaust gas and air. This is a backwash method. When using the filter, the exhaust gas inlet of 13 and the valve of 15 are taken, and the flue of 16 enters the black smoke and particulate matter purifier through the flue of 16.
6 の排気ガス集合ボ ッ ク ス よ り 、 7 の煙道を と う り 、 8 のフ ィ ルタ 一使 用時排出バルブを と う り 9 の フ ィ ルタ 一使用排時排気出 口 よ り排出 され る。 こ の際、 1 1 の通常走行使用時バルブは、 閉めてお く 。 こ のバルブ を開 く と 黒煙、 微粒子状物質浄化装置は使用 しない。 そ して、 1 7 の逆 洗時使用バルブも閉めている。 フィ ルタ一の再生は、 圧力セ ンサ一が 目 標値になる と 、 1 0 の黒煙、 微粒子状物質排出 口 よ り , 接続されている。 第 9 図の 2 5集塵ボ ッ ク スバルブを開き , 次に 8 , 1 5 のバルブを閉め る 1 7 の逆洗バルブを開 く と排気ガスは、 1 8, 7、 6 を と う り 5 の リ テ—ナ一から フ ィ ルタ ーを抜けて、 1 0 を と う り 第 1 0 図の 2 8排気 出 口 よ り 、 外に出て、 逆洗を行 う 、 約 1 — 2 分で終了する。 From the exhaust gas collecting box of 6, take the flue of 7, take the exhaust valve when using the filter of 8 and take the exhaust valve when using the filter of 9 from the exhaust outlet. Emitted. At this time, close the valve for normal use in 11. When this valve is opened, the black smoke and particulate matter purifier will not be used. Also, the valve used for backwashing in step 17 is also closed. When the pressure sensor reaches the target value, the filter is regenerated, and the filter is connected via the black smoke and particulate matter discharge port of 10. Open the 25 dust collection box valve in Fig. 9 and then close the 8 and 15 valves. When the 17 backwash valve is opened, the exhaust gas takes 18, 7 and 6. Pull out the filter from the retainer of No. 5, take 10 and go out through the 28 exhaust outlet of Fig. 10 to perform backwash. Finish in minutes.
本発明の黒煙、 微粒子状物質浄化装置は、 3 つの再生方式があ り 、 適宜 組合わせて、 使用する こ と が可能である。 2 つめの再生方式は、 第 7 図 と 第 8 図の排気ガス使用 ノ ズル噴射再生方式で, 再生の順序は, 第 丄 図 の逆洗方式と 同様なバルブの操作と なる。 ノ ズル噴射再生方式の黒煙、 微粒子状物質浄化装置はフ ィ ルタ 一使用時は、 2 3 の噴射パイ ブの ノ ズ ルよ り 噴射された, 排気ガスは 1 9 , 5 , 6 , 7, 8, 9 と排出 される。 2圧力セ ンサ一が、 目標値になる と 、 第 7 図のよ う に、 メ ンブ レ ンフ ィ ルタ ーの横に設置された、 2 3 の噴射パイ プの ノ ズルよ り , 噴射された 排気ガスは逆洗方式と 同様に、 第 9 図集塵ボ ッ ク ス の 2 5 のバルブが開 き 、 8 のフ ィ ルタ ー使用時排出バルブが開 く ため、 2 8 の排気出 口 よ り 外に出て行く 。 再生時間は約 1 — 2 分で完了する。 こ の際黒煙、 微粒子 状物質も 2 7 の耐熱型集塵パ ッ ク に送 り 込まれる。 こ の、 耐熱型集塵パ ッ ク は、 適宜交換して, 使用する 、 尚、 2 4 の集塵ボ ッ ク ス に電動モ一 ターによ る集塵も可能で、 随時集塵をする こ と が出来る。 The black smoke and particulate matter purifying apparatus of the present invention has three regeneration methods, and can be used in appropriate combination. Fig. 7 shows the second playback method. And the nozzle injection regeneration system using exhaust gas shown in Fig. 8, and the order of regeneration is the same as the valve operation in the backwash system shown in Fig. 2. The black smoke and particulate matter purifying device of the nozzle injection regeneration system was injected from the nozzles of the 23 injection pipes when the filter was used, and the exhaust gas was 19, 5, 6, 7 , 8, and 9 are emitted. (2) When the pressure sensor reaches the target value, as shown in Fig. 7, it is injected from the nozzle of the injection pipe (23) installed next to the membrane filter. As in the case of the backwashing method, the exhaust gas is discharged from the exhaust outlet at 28 because the valve 25 in the dust collection box in Fig. 9 opens and the exhaust valve opens when the filter 8 is used. Go outside. Playback time is about 1-2 minutes. At this time, black smoke and particulate matter are also sent to the 27 heat-resistant dust collection pack. This heat-resistant dust-collecting pack should be replaced and used as needed. The dust-collecting box 24 can be dust-collected by an electric motor, and dust can be collected at any time. You can do this.
第三の再生方式と して、 第 1 2 図, 第 1 3 図、 第 1 4 図によ る、 3 2 の 払い落と し器が、 上下に振動 して、 1 9 のメ ンブ レンフィ ルターに微接 触をする こ と によ り 、 再生を行 う 、 再生時のバルブの操作順序は、 排気 ガス及びエア一を使用 した。 逆洗方式と 、 排 ' 噴射再生 方式と も同様である。 路上走行テス ト においては、 98年 12月 30 日 、 1 月 3 日 、 4 日 、 2 ト ン ト ラ ッ ク によ る 、 走行テス ト を実施 した結果、 良 好な捕集性能と フ ィ ルタ 一の再生機能を得る こ と が出来た、 As a third regeneration method, the scraper of 32 shown in Fig. 12, Fig. 13, and Fig. 14 vibrates up and down to the membrane filter of 19. Regeneration is performed by making a slight contact, and the operation sequence of the valve during the regeneration uses exhaust gas and air. The same applies to the backwashing method and the exhaust injection regeneration method. In the on-road driving test, as a result of conducting a driving test on December 30, 1998, January 3 and 4, and 2-ton track, good collection performance and feasibility were obtained. I was able to get the best playback function
使用 したフ ィ ルタ ーのサイ ズは、 平板中空型 幅 120 長さ 300 のも のを、 4枚使用 運転時間約 5 時間 エ ンジン回転数 700- 3800 The size of the filter used was a flat hollow type with a width of 120 and a length of 300, and four filters were used. Approximately 5 hours operating time Engine rotation speed 700-3800
2次フ ィ ルタ 一室圧力 0. 15 キ ロ グラ ム、 使用ギア変速比 セカ ン ド サ ― ド使用 Secondary filter Single chamber pressure 0.15 Kilogram, gear ratio used Second side used
街中走行においては、 2 次フ ィ ルタ一室の温度は 180度 ぐ らいが最高で あった、 In city driving, the temperature of one room of the secondary filter was the highest at about 180 degrees.
高速走行においては、 ギアをサ一 ドでエ ンジン回転数 3800、 速度 7 0 キ 口 2 0 分走行後 2 次フ ィ ルタ 一室温度 2 2 6 度 1 次フ ィ ルタ 一室温度 2 9 0 度を記録 した、 黒煙、 微粒子状物質浄化装置 の構成は図 1 3 図 1 6 の入口管よ り 排気ガスが入る と 、 最初に高温ガス フ ィ ルタ 一で火の 粉や粗い粒子を捕集する。 こ の繊維は耐熱温度 700 の シ リ 力連続繊維 や、 耐熱温度 1 400°Cアル ミ ナ連続繊維等を使用 して、 火の粉や粗い粒子 を捕集する。 この厚みは、 0. 6 m m〜 0. 8 m m位である。 更に S U S 3 1 6等 の金網があ り 、 この金網も同 じ く 火の粉や粗い粒子を捕集する。 In high-speed driving, the gears are set to the engine speed of 3800 and the speed of 70 keys. The mouth of the secondary filter after running for 20 minutes The temperature of the secondary filter room temperature 2 266 degrees The temperature of the primary filter room temperature 290 degrees was recorded, the configuration of the black smoke and particulate matter purification device is shown in Fig. 1 3 Fig. 1 When the exhaust gas enters from the inlet pipe of No. 6, first the hot gas filter collects sparks and coarse particles. This fiber uses fire-continuous fiber with a heat-resistant temperature of 700 or aluminum continuous fiber with a heat-resistant temperature of 1400 ° C to collect sparks and coarse particles. This thickness is on the order of 0.6 mm to 0.8 mm. Furthermore, there is a wire mesh such as SUS316, which also catches sparks and coarse particles.
次にセラ ミ ッ ク断熱シ一 トで仕切 られた空間を Next, the space partitioned by the ceramic insulation sheet
通過する。 最後に PTFE (ポ リ テ ト ラ フ ロ ロエチ レン) 繊維メ ンブ レ ン フ ィ ルタ ー 1 9 を通過 してフィルタ一内部の平板 リ テ一ナ一 5 を通過 して排 気口 9 に出る。 pass. Finally, it passes through the PTFE (Polytetrafluoroethylene) fiber membrane filter 19, passes through the flat plate retainer 15 inside the filter 1, and exits to the exhaust port 9 .
前記の PTFE (ボ リ テ ト ラ フ ロ ロエチ レン) 繊維メ ンブ レンフ ィ ルタ一 フィ ルタ一は耐熱温度が 260 °Cである ため、 260°C以上の と き は、 温度 センサ一又はス ピー ドセ ンサ、 等で温度コ ン ト ロ ールを行い常に 260度 を以上にな らないよ う にする、 例えば設定温度 2 30度でフ ィ ルタ 一の使 用を止めて通常のマフ ラーに切換える こ と が出来る。 The above-mentioned PTFE (volume tetrafluoroethylene) fiber membrane filter has a heat resistant temperature of 260 ° C. Therefore, when the temperature is 260 ° C or more, the temperature sensor or speed Control the temperature with a sensor, etc. so that the temperature does not exceed 260 ° C. For example, stop using the filter at a set temperature of 230 ° C and use a normal muffler. Can be switched to.
上記の切換弁の操作は、 モーター、 エア一シ リ ンダー、 電気式シ リ ンダ で行 う こ と もでき るが、 コ ス ト を省 く ためワイ ヤ式の手動でも行 う こ と ができ る。 The above-mentioned operation of the switching valve can be performed by a motor, air cylinder, or electric cylinder, but it can also be performed by wire-type manual operation to save cost. You.
安全装置と して、 独立の 自動安全弁、 フ ィ ルターが 目詰ま り を起こ した 時に、 圧力センサ一が切換えバルブを作動 して As a safety device, an independent automatic safety valve, the pressure sensor operates the switching valve when the filter becomes clogged.
通常のマフラーで走行をする。 Drive with a normal muffler.
排ガス温度が 260 °C以上にな らないよ う 、排ガス浄化装置の放熱性を 良く するため、 大型 ト ラ ッ ク等 Large trucks, etc., to improve the heat dissipation of the exhaust gas purifier so that the exhaust gas temperature does not exceed 260 ° C
の取 り 付けスペースがある場合は、 ミ ニサイ ク ロ ンを使用する こ と によ り 放熱を促進出来また集塵も圧力損失を少な く 行える利点があ り ます: 放熱対策及び圧力上昇防止対策 と して第三図の 1 9 のメ ンブ レンフ ィ ルタ 一を外側に取 り 付け る こ と で、 放熱及び圧力 の上昇を防止する効果が有 り 、 排ガス浄化装置をアルミ 等の放熱性のよ い材料の使用で、 排ガス浄化装置内部の温度は、 通常の運転では、 2 6 0 °Cには上昇 しない こ と が、 確認された。 9 9 年 8 月 の走行テス ト は、 同 じ く 2 ト ン排気量 4000cc フ ィ ルタ 一サイ ズ高 さ 380長 さ 500 を、 4 枚使用 して、 2 0 0 0 キ ロ走行 して、 捕集 した、 黒煙、 微粒子状 物質は約 8 0 0 グラ ムになった = 9 9 年 9 月 の走行テス ト は 4 ト ン車で 6 8 0 キ ロ走行 して, 約 3 6 0 グラ ム捕集 した。 放熱対策 と して、 アル ミ 等の放熱特性の良い金属を使用する。 放熱フ ィ ンを本体、 マ フ ラーに取 り 付ける。 If there is space for installation, heat radiation can be promoted by using a mini cyclone, and dust collection reduces pressure loss. There is an advantage that can be done: As a measure against heat radiation and pressure rise, the effect of preventing heat radiation and pressure rise by installing the membrane filter shown in Fig. 19 on the outside. It was confirmed that the temperature inside the exhaust gas purification device did not rise to 260 ° C during normal operation by using a material with good heat dissipation such as aluminum for the exhaust gas purification device. . In the same way, the running test in August 2009 was conducted using the same two-ton displacement 4000cc filter, size 380, height 500 and length 500, and traveled 200 km. The collected black smoke and particulate matter amounted to about 800 grams. = In September 1997, the running test was about 360 grams on a 4-ton car running on a 68-kilo meter. Were collected. As a heat dissipation measure, use a metal with good heat dissipation properties, such as aluminum. Attach the heat radiation fin to the main unit and muffler.
オプシ ョ ンでは、 ヒ ー トノ イ ブも取 り 付け る。 Optionally, also install heat noise.
払い落と し機構の振動は車の振動を活用 して、 払い落と し器をスプ リ ン グによ る振動でフ ィ ルタ一の表面に付着 した微粒子を The vibration of the wiping mechanism utilizes the vibration of the car, and the wiping device removes the fine particles adhering to the filter surface by the vibration of the spring.
払い落とす常時振動 式払い落 と し機構 、 二番 目 の方式と して、 フ ィ ルターの寿命を延ばすために、 一定サイ クルで振動を起こす、 カムシャ フ 卜 A constant vibration type wiping-off mechanism. The second method is a camshaft that oscillates in a constant cycle in order to extend the life of the filter.
モーター駆動式、 三番 目 の方式と して、 フ ィ ルタ 一に無接触 な逆洗式 フ ィ ルタ 一再生式がある。 As a third type, a motor-driven type, there is a non-contact backwash type filter-regenerative type filter.
ク リ ー ンな排ガス をエ ンジンの吸気管に再循環させる こ と に よ り 、 窒素 酸化物の削減に活用する こ と も可能である。 第 1 1 図の 2 9 Recirculating clean exhaust gas to the intake pipe of the engine can also be used to reduce nitrogen oxides. Fig. 11 2 9
バルブの弁の材質は、 6 0 0 の耐熱温度をもつ膨張黒煙編組パ ッ キ ン 等耐熱パッ キ ンを使用する。 For the valve material, use a heat-resistant packing such as expanded black smoke braided packing that has a heat-resistant temperature of 600.
産業上の利用可能性 Industrial applicability
本発明によれば黒煙、微粒子状物質補集フィルタ-の性能が高 く 本体にアルミ を使用する事によ り 、 放熱性がよ く 軽量化がはかれる また、 コ ス ト も低く お さ え られる。 放熱器をフ ィ ル タ一部分と セパ レ一 卜 にする こ と に よ り 、 取 り 付けス ベー ス の 自 由度が広がる、 更に二次フ ィ ル タ 一 のサイ ズの大き さ も 自 由 に、 縦型、 及び逆洗式では 横型も可能であ り 、 薄型タイ ブ の製作も可能 と な り ます - According to the present invention, the performance of the filter for collecting black smoke and particulate matter is high, and by using aluminum for the main body, heat dissipation is improved and the weight is reduced Also, the cost is low. Separating the radiator with a part of the filter increases the degree of freedom of the mounting base and the size of the secondary filter. Therefore, vertical type and horizontal type in backwash type are also possible, making it possible to manufacture thin type-
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11/25500 | 1999-02-02 | ||
| JP2550099 | 1999-02-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2000046492A1 true WO2000046492A1 (en) | 2000-08-10 |
Family
ID=12167796
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2000/000556 Ceased WO2000046492A1 (en) | 1999-02-02 | 2000-02-02 | Black smoke/particulates controlling device for diesel engines and auxiliary device for exhaust gas reduction |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2000046492A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9051067B2 (en) | 2008-03-13 | 2015-06-09 | Nippon Shokubai Co., Ltd. | Method for producing particulate water-absorbing agent composed principally of water-absorbing resin |
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| JPH0797908A (en) * | 1993-08-03 | 1995-04-11 | Isuzu Ceramics Kenkyusho:Kk | Diesel particulate filter |
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| JPH09324620A (en) * | 1996-06-10 | 1997-12-16 | Toyota Central Res & Dev Lab Inc | Exhaust gas purification device for diesel engine |
| JP2843245B2 (en) * | 1993-03-10 | 1999-01-06 | 日野自動車工業株式会社 | Soot treatment device for dust collector |
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|---|---|---|---|---|
| WO1985004595A1 (en) * | 1984-04-07 | 1985-10-24 | Firma Herding Gmbh | Filter element for separating solid material particles from gas or liquid media |
| JPH0446165B2 (en) * | 1985-03-30 | 1992-07-29 | Sumitomo Metal Ind | |
| JPH0534733Y2 (en) * | 1987-12-24 | 1993-09-02 | ||
| JPH01174509U (en) * | 1988-05-31 | 1989-12-12 | ||
| JPH0352322U (en) * | 1989-09-28 | 1991-05-21 | ||
| JPH0417711A (en) * | 1990-05-09 | 1992-01-22 | Hino Motors Ltd | Intake and exhaust system of engine |
| JPH0493712U (en) * | 1991-01-10 | 1992-08-14 | ||
| JPH04243511A (en) * | 1991-01-28 | 1992-08-31 | Matsushita Electric Works Ltd | Dust collecting filter of dust collector |
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| JP2843245B2 (en) * | 1993-03-10 | 1999-01-06 | 日野自動車工業株式会社 | Soot treatment device for dust collector |
| JPH0797908A (en) * | 1993-08-03 | 1995-04-11 | Isuzu Ceramics Kenkyusho:Kk | Diesel particulate filter |
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| US9051067B2 (en) | 2008-03-13 | 2015-06-09 | Nippon Shokubai Co., Ltd. | Method for producing particulate water-absorbing agent composed principally of water-absorbing resin |
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