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WO1999064649A1 - Procede servant a fabriquer un non-tisse - Google Patents

Procede servant a fabriquer un non-tisse Download PDF

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Publication number
WO1999064649A1
WO1999064649A1 PCT/GB1999/001775 GB9901775W WO9964649A1 WO 1999064649 A1 WO1999064649 A1 WO 1999064649A1 GB 9901775 W GB9901775 W GB 9901775W WO 9964649 A1 WO9964649 A1 WO 9964649A1
Authority
WO
WIPO (PCT)
Prior art keywords
cellulose
fibre
web
fabric
fibres
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB1999/001775
Other languages
English (en)
Inventor
Stephen John Law
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lenzing Fibers Ltd
Original Assignee
Acordis Fibres Holdings Ltd
Tencel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Acordis Fibres Holdings Ltd, Tencel Ltd filed Critical Acordis Fibres Holdings Ltd
Priority to DE69911776T priority Critical patent/DE69911776T2/de
Priority to JP2000553637A priority patent/JP4373008B2/ja
Priority to BR9910862-3A priority patent/BR9910862A/pt
Priority to AU41582/99A priority patent/AU4158299A/en
Priority to EP99925203A priority patent/EP1093536B1/fr
Priority to CA002333882A priority patent/CA2333882A1/fr
Priority to AT99925203T priority patent/ATE251239T1/de
Publication of WO1999064649A1 publication Critical patent/WO1999064649A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425—Cellulose series
    • D04H1/4258—Regenerated cellulose series
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/06—Wet spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/02—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from solutions of cellulose in acids, bases or salts
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425—Cellulose series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/56—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in association with fibre formation, e.g. immediately following extrusion of staple fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/013—Regenerated cellulose series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/015—Natural yarns or filaments
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • D04H3/03—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments at random
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion

Definitions

  • This invention relates to a method of manufacture of a nonwoven fabric made from cellulose and in particular from a solution of cellulose.
  • Cellulose fibres and filaments may be produced by spinning a solution of cellulose in an amine oxide solvent which is then leached into water or a dilute solution of aqueous amine oxide, to produce cellulose filaments which can then be cut into staple fibres.
  • the process of extrusion and coagulation is referred to as solvent spinning, and the fibres of solvent-spun cellulose so produced are known under the generic name of lyocell.
  • the present applicant's international patent application PCT/GB97/03391 discloses a method of manufacture of a nonwoven cellulose fibre made from fibres formed by extruding a solution of cellulose through at least one spinning jet and subjecting the extrudate fibre to a high velocity gas flow, the fibres being collected on a surface on which the fibre is subsequently coagulated.
  • the fibres tend to bond together before coagulation forming a relatively dense nonwoven fabric which is highly bonded.
  • a highly bonded, high density fabric web is not desirable, for example for filtration materials, or for materials which require a high water holding capacity.
  • the present invention provides a method of manufacture of a nonwoven cellulose fabric having a high loft and a relatively low density. According to the present invention there is provided a method of manufacture of a non-woven cellulose fabric in which extrudate fibre produced from a spinning jet is subjected to a high velocity gas flow, and the fibre is passed through a vapour mist which at least partially coagulates the fibre prior to its collection as a fibre web.
  • the extruded fibre is attenuated by the gas flow and may be broken down into indefinite lengths.
  • the vapour mist may be formed from any suitable coagulant.
  • the mist is preferably an aqueous mist, although lower alkyl alcohols, for example, may also be used.
  • atomised water may be sprayed from a nozzle located below the spinning jet.
  • the cellulose solution is preferably a solution of cellulose in an amine oxide solvent, typically a tertiary N- amine oxide and in particular N-methylmorpholene-N-oxide
  • the cellulose solution may contain 4-22% by weight of cellulose, preferably 10-15%, having a degree of polymerisation of 200-5,000, and more typically 400-1,000.
  • the cellulose solution comprises 14% by weight of cellulose, 12% by weight water and 74% by weight of NMMO, the cellulose having a degree of polymerisation of about 600.
  • the attenuated fibre- forming microfibres or fibrils are collected and are then further coagulated (alternatively referred to as being "regenerated") by means of water, or a dilute aqueous solution of amine oxide containing up to 20% amine oxide in water.
  • the fibrils may be collected directly into a coagulation bath, or may be collected onto a surface and then further coagulated.
  • the gas preferably air or dry steam, is blown onto the extruded fibres at a velocity of between 200 m.s "1 (metres per second) and 500 m.s "1 and has a temperature of between 100°C and 155 °C, preferably about 145 °C for a cellulose concentration of 14-15%.
  • the gas velocity should be at least 50 times higher than the velocity of the extrudate fibre emerging from the spinning jet, and preferably between 1,000 and 20,000 times said velocity.
  • the air is directed onto the fibre extrudate at a bias angle, preferably of between 15° and 45° relative to the longitudinal axis of the extrudate, and more preferably about 30°.
  • the air jets may also be biased at a second skew angle relative to the spinning jet so that the air jet axes and fibre axis do not intersect, the air jets being tangential to the surface of the fibre extrudate.
  • the fibre collecting surface may be flexible, or resilient.
  • the fibre collection is made onto a bed of foam which is preferably soaked in water or aqueous NMMO solution.
  • the invention also provides a nonwoven lyocell fabric in which the fibres are bonded or entangled together without the use of a binder, the fabric having a density no greater than 175 g.d "3 , and/or a tensile extension to break of at least 7%.
  • Figure 1 is a schematic drawing of an embodiment of apparatus for the production of a nonwoven fabric according to the present invention
  • Figure 2 is a plan view of a spinning jet nozzle used in the apparatus of Figure 1;
  • Figure 3 is a side elevation of the nozzle shown in Figure 2, with internal passages ghosted; and Figure 4 is an axial cross-section through the nozzle shown in Figure 2 and Figure 3.
  • an extruder 10 having a nozzle 11 attached thereto.
  • the extruder is fed with a solution comprising 14% by weight cellulose, 12% by weight of water and 74% by weight of N-methylmorpholene-N- oxide (NMMO) .
  • NMMO N-methylmorpholene-N- oxide
  • the cellulose has an average degree of polymerisation of about 600.
  • the cellulose solution may be manufactured as is described in WO 94/28217.
  • the cellulose solution in the extruder is held at a temperature of between 95 and 110 °C, preferably 105 °C, and is forced through the nozzle to extrude as a continuous filament of cellulose dope.
  • the nozzle 11 is shown in Figures 2 and 3 and may be secured directly onto the extruder 10, or may be secured to an adapter (not shown) which in turn is secured to the extruder 10.
  • the nozzle 11 has a hollow screw threaded stud 13 on its back face 12 and a central passageway 14 which terminates in a jet aperture 15.
  • the jet has a diameter of between 0.2 and 0.3mm, and preferably about 0.27mm.
  • the cellulose dope is forced into the passageway 14 under pressure, and is extruded through the jet 15.
  • the nozzle 11 also has a plurality of gas outlet passageways 16, preferably three, spaced around the central passageway 14.
  • Each gas passageway 16 is inclined with respect to the jet axis, and they are circumferentially equally spaced around the jet 15 so that each gas stream exiting its respective passageway 16 has the same effect upon the extrudate filament.
  • the gas passageways 16 make a bias or convergence angle with the longitudinal axis of the jet of between 15° and 45°, and more preferably 30°.
  • the passageways 16 are also skewed so that the axes of the passageways 16 do not themselves converge.
  • the gas passageways are about 2.0 mm in diameter.
  • the back face 12 of the nozzle has an annular groove 17 therein which interconnects the ends of the three passageways 16.
  • the central passageway 14 is connected to the cellulose dope feed and the annular passageway 17 is connected to a gas supply, preferably compressed air.
  • compressed air is fed from a source (not shown) through a flow regulator valve 21, a flow meter 22, a heater 23 and a temperature sensor 24, to the air passageway 17 in the nozzle.
  • the sensor 24 may be connected to the air heater 23 for control of the air temperature.
  • the extrudate filaments emerging from the nozzle 11 are subjected to attenuation by high velocity air streams 25 emerging from the outlet passageways 16, and the filament is drawn and may be fractured and either blown directly into a coagulation bath 27 or, preferably, blown onto a support surface 26 situated about 30 cm from the nozzle 11.
  • the cellulose dope flow rate is preferably about 0.2 g.min "1 .
  • the support surface 26 is formed by the outer peripheral surface of a rotatable drum 28, which turns at about 10 revolutions per minute (rpm) to build up a layer of nonwoven fabric on the drum.
  • the extrudate filaments pass through a fine mist 30 of water vapour, generated by water sprayed from an air atomising nozzle 32 located about 10 cm below nozzle 11.
  • the surface of the drum may be covered in compliant material such as a layer of foam, preferably a 2mm thick layer of polyurethane foam having an average cell size of 50 ⁇ m.
  • compliant material such as a layer of foam, preferably a 2mm thick layer of polyurethane foam having an average cell size of 50 ⁇ m.
  • the foam may be soaked in water or an aqueous solution of NMMO.
  • the drum 28 is immersed in a coagulant bath 27 containing a suitable coagulant such as water or a dilute solution of amine oxide in water, to coagulate the nonwoven cellulose fabric on the drum.
  • a suitable coagulant such as water or a dilute solution of amine oxide in water
  • An air flow rate of 2.4 l.s "1 (litres/second) corresponds 15 approximately to air velocity of 250 m.s "1 .
  • Samples 3 and 4 were made in accordance with present inventions .
  • the thickness is normalised to a basis weight of 25 g.m "2 .
  • the foam serves two purposes, namely (a) nascent fibres striking a hard collector surface tend to fuse on impact - a compliant surface removes some of the impact energy and reduces bonding and (b) on compression of the foam at impact, coagulant contained in its pores is expressed to the surface and aids rapid regeneration.
  • Table 3 summarises the properties of the fabric webs formed on the drum 26.
  • sample 1 the surface of the drum is dry and the fabric is regenerated after build up on the drum.
  • Samples 3 and 4 collected on the drum after passing through the vapour mist, clearly had lower tensile strength but greater extension to break whilst still maintaining some integrity after the break point. These high loft material are suitable for use as filters and high absorbency materials.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Artificial Filaments (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Procédé servant à fabriquer un non-tissé à base de cellulose et consistant à produire des fibres par extrusion d'une solution de cellulose à travers au moins une filière de filage et à soumettre les fibres extrudées à un écoulement de gaz très rapide. La fibre traverse une brume de vapeur qui la coagule au moins partiellement avant d'être recueillie sous forme de voile. Ce procédé permet d'obtenir un non-tissé possédant un gonflant important et une densité relativement basse.
PCT/GB1999/001775 1998-06-05 1999-06-04 Procede servant a fabriquer un non-tisse Ceased WO1999064649A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE69911776T DE69911776T2 (de) 1998-06-05 1999-06-04 Vliesstoff und Verfahren zu seiner Herstellung
JP2000553637A JP4373008B2 (ja) 1998-06-05 1999-06-04 不織布の製造方法
BR9910862-3A BR9910862A (pt) 1998-06-05 1999-06-04 Processo para a fabricação de um pano não tecido de celulose, pano não tecido de lyocell, e, tela de pano não tecido de lyocell.
AU41582/99A AU4158299A (en) 1998-06-05 1999-06-04 Methods of manufacture of nonwoven fabric
EP99925203A EP1093536B1 (fr) 1998-06-05 1999-06-04 Non-Tisse et procede servant a le fabriquer
CA002333882A CA2333882A1 (fr) 1998-06-05 1999-06-04 Procede servant a fabriquer un non-tisse
AT99925203T ATE251239T1 (de) 1998-06-05 1999-06-04 Vliesstoff und verfahren zu seiner herstellung

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9812089A GB2337957A (en) 1998-06-05 1998-06-05 Method of manufacture of a nonwoven fabric
GB9812089.2 1998-06-05

Publications (1)

Publication Number Publication Date
WO1999064649A1 true WO1999064649A1 (fr) 1999-12-16

Family

ID=10833247

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1999/001775 Ceased WO1999064649A1 (fr) 1998-06-05 1999-06-04 Procede servant a fabriquer un non-tisse

Country Status (15)

Country Link
EP (1) EP1093536B1 (fr)
JP (1) JP4373008B2 (fr)
KR (1) KR100563788B1 (fr)
CN (1) CN1161502C (fr)
AT (1) ATE251239T1 (fr)
AU (1) AU4158299A (fr)
BR (1) BR9910862A (fr)
CA (1) CA2333882A1 (fr)
DE (1) DE69911776T2 (fr)
ES (1) ES2209444T3 (fr)
GB (1) GB2337957A (fr)
ID (1) ID27038A (fr)
TR (1) TR200003602T2 (fr)
TW (1) TW419543B (fr)
WO (1) WO1999064649A1 (fr)

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002052070A3 (fr) * 2000-12-22 2002-11-07 Lueder Gerking Procedes et dispositifs pour la production de filaments fins sensiblement continus
US7008889B2 (en) 2001-09-07 2006-03-07 Polymer Group, Inc. Imaged nonwoven fabric comprising lyocell fibers
WO2007124522A1 (fr) * 2006-04-28 2007-11-08 Lenzing Aktiengesellschaft Produit non-tisse obtenu par fusion-soufflage
JP2012046861A (ja) * 2000-05-11 2012-03-08 Weyerhaeuser Co Ｃｖ特性を強化したリヨセル繊維
US8282877B2 (en) 2006-04-28 2012-10-09 Lenzing Aktiengesellschaft Process of making a hydroentangled product from cellulose fibers
US9334592B2 (en) 2007-11-07 2016-05-10 Lenzing Aktiengesellschaft Process for the production of a hydroentangled product comprising cellulose fibers
EP3144376A1 (fr) 2015-09-16 2017-03-22 Lenzing Aktiengesellschaft Utilisation d'une fibre lyocell
WO2018071928A1 (fr) 2016-10-21 2018-04-26 Lenzing Ag Procédé et dispositif de formation de bandes cellulosiques directement formées
EP3385435A1 (fr) 2017-04-03 2018-10-10 Lenzing Aktiengesellschaft Tissu de fibres de cellulose non tissé ayant différents ensembles de pores
EP3385430A1 (fr) 2017-04-03 2018-10-10 Lenzing Aktiengesellschaft Tissu de fibres de cellulose non tissé humide optiquement transparent
EP3385431A1 (fr) 2017-04-03 2018-10-10 Lenzing Aktiengesellschaft Tissu de fibres de cellulose non tissé ayant des fibres fusionnées de façon homogène
EP3385425A1 (fr) 2017-04-03 2018-10-10 Lenzing Aktiengesellschaft Tissu de fibres de cellulose non tissé présentant une meilleure capacité d'absorption d'huile
EP3385434A1 (fr) 2017-04-03 2018-10-10 Lenzing Aktiengesellschaft Tissu de fibres de cellulose non tissé avec des fibres fusionnées
EP3385429A1 (fr) 2017-04-03 2018-10-10 Lenzing Aktiengesellschaft Tissu de fibres de cellulose non tissé ayant des particules de diffusion de rayonnement connectés aux fibres
EP3385428A1 (fr) 2017-04-03 2018-10-10 Lenzing Aktiengesellschaft Tissu de fibres de cellulose non tissé avec des fibres ayant une section transversale non circulaire
EP3385432A1 (fr) 2017-04-03 2018-10-10 Lenzing Aktiengesellschaft Tissu de fibres de cellulose non tissé ayant une très faible teneur en métaux lourds
EP3385426A1 (fr) 2017-04-03 2018-10-10 Lenzing Aktiengesellschaft Tissu de fibres de cellulose non tissé ayant une plus grande capacité de rétention d'eau et un faible poids de base
EP3385433A1 (fr) 2017-04-03 2018-10-10 Lenzing Aktiengesellschaft Tissu de fibres de cellulose non tissé avec capacité de drainage de liquide sur mesure
EP3385427A1 (fr) 2017-04-03 2018-10-10 Lenzing Aktiengesellschaft Tissu de fibres de cellulose non tissé avec répartition de diamètres de fibres
WO2018184046A1 (fr) 2017-04-03 2018-10-11 Lenzing Ag Matériau non tissé conçu pour être utilisé en tant que milieu filtrant
WO2018184045A1 (fr) 2017-04-03 2018-10-11 Lenzing Ag Bande non tissée conçue pour être utilisée en tant que milieu filtrant d'huile de cuisson à chaud
WO2018184051A1 (fr) 2017-04-03 2018-10-11 Lenzing Ag Matériau non tissé conçu pour être utilisé dans des structures de cœurs absorbants ayant des capacités d'acquisition/distribution intrinsèques
EP3604652A1 (fr) 2018-07-31 2020-02-05 Lenzing Aktiengesellschaft Non-tissé, utilisation du non-tissé et chiffon, toile de séchage ainsi que masque pour le visage comportant du non-tissé

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6210801B1 (en) 1996-08-23 2001-04-03 Weyerhaeuser Company Lyocell fibers, and compositions for making same
US6471727B2 (en) 1996-08-23 2002-10-29 Weyerhaeuser Company Lyocell fibers, and compositions for making the same
US6235392B1 (en) 1996-08-23 2001-05-22 Weyerhaeuser Company Lyocell fibers and process for their preparation
US6331354B1 (en) 1996-08-23 2001-12-18 Weyerhaeuser Company Alkaline pulp having low average degree of polymerization values and method of producing the same
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JP7102662B2 (ja) * 2017-04-03 2022-07-20 レンチング アクチエンゲゼルシャフト 多重接着技術で作られた連続フィラメントセルロース不織布
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WO2018184043A1 (fr) 2017-04-03 2018-10-11 Lenzing Ag Bande non tissée conçue pour être utilisée dans une lingette de salle blanche
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EP3636672A1 (fr) 2018-10-09 2020-04-15 Lenzing Aktiengesellschaft Marquage d'une matière cellulosique régénérée
CN109554828B (zh) * 2018-10-22 2021-06-22 复旦大学 一种超低定量再生纤维素纤维丝网的制备方法
EP3696317A1 (fr) 2019-02-15 2020-08-19 Lenzing Aktiengesellschaft Fibre teinte dans la masse et son procédé de fabrication
TWI770569B (zh) * 2020-07-29 2022-07-11 新麗企業股份有限公司 不織布製造設備及其製造方法
EP4163430A1 (fr) 2021-10-08 2023-04-12 Lenzing Aktiengesellschaft Couche non-tissée comprenant un réseau de fibres cellulosiques régénérées sensiblement continues
EP4215170A1 (fr) 2022-01-20 2023-07-26 Lenzing Aktiengesellschaft Couche non tissée comprenant un réseau de fibres cellulosiques régénérées sensiblement continues
EP4293148A1 (fr) 2022-06-15 2023-12-20 Lenzing Aktiengesellschaft Couche non tissée comprenant un réseau de fibres cellulosiques régénérées sensiblement continues

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JP2012046861A (ja) * 2000-05-11 2012-03-08 Weyerhaeuser Co Ｃｖ特性を強化したリヨセル繊維
WO2002052070A3 (fr) * 2000-12-22 2002-11-07 Lueder Gerking Procedes et dispositifs pour la production de filaments fins sensiblement continus
CN1322181C (zh) * 2000-12-22 2007-06-20 吕德·格金 制造基本连续不断的细丝的方法和装置
US7922943B2 (en) 2000-12-22 2011-04-12 Luder Gerking Method and device for producing substantially endless fine threads
US7008889B2 (en) 2001-09-07 2006-03-07 Polymer Group, Inc. Imaged nonwoven fabric comprising lyocell fibers
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US9334592B2 (en) 2007-11-07 2016-05-10 Lenzing Aktiengesellschaft Process for the production of a hydroentangled product comprising cellulose fibers
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WO2018071928A1 (fr) 2016-10-21 2018-04-26 Lenzing Ag Procédé et dispositif de formation de bandes cellulosiques directement formées
US11371173B2 (en) 2016-10-21 2022-06-28 Lenzing Ag Process and device for the formation of directly-formed cellulosic webs
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CA2333882A1 (fr) 1999-12-16
CN1304464A (zh) 2001-07-18
ID27038A (id) 2001-02-22
KR100563788B1 (ko) 2006-03-27
GB2337957A (en) 1999-12-08
CN1161502C (zh) 2004-08-11
ATE251239T1 (de) 2003-10-15
EP1093536A1 (fr) 2001-04-25
DE69911776D1 (de) 2003-11-06
GB9812089D0 (en) 1998-08-05
EP1093536B1 (fr) 2003-10-01
JP2002517630A (ja) 2002-06-18
JP4373008B2 (ja) 2009-11-25
TW419543B (en) 2001-01-21
ES2209444T3 (es) 2004-06-16
KR20010071345A (ko) 2001-07-28
TR200003602T2 (tr) 2001-04-20
AU4158299A (en) 1999-12-30
DE69911776T2 (de) 2004-08-19

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