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WO1996002224A1 - Composition detergente - Google Patents

Composition detergente Download PDF

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Publication number
WO1996002224A1
WO1996002224A1 PCT/GB1995/001687 GB9501687W WO9602224A1 WO 1996002224 A1 WO1996002224 A1 WO 1996002224A1 GB 9501687 W GB9501687 W GB 9501687W WO 9602224 A1 WO9602224 A1 WO 9602224A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
benefit agent
surface active
mixtures
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB1995/001687
Other languages
English (en)
Inventor
Margaret Jobling
Shiji Shen
Liang Sheng Tsaur
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever NV
Original Assignee
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever NV filed Critical Unilever NV
Priority to AU29856/95A priority Critical patent/AU2985695A/en
Priority to KR1019970700339A priority patent/KR970704418A/ko
Priority to BR9508782A priority patent/BR9508782A/pt
Priority to EP95925905A priority patent/EP0771186A1/fr
Priority to JP8504828A priority patent/JPH09512824A/ja
Publication of WO1996002224A1 publication Critical patent/WO1996002224A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Definitions

  • the present invention relates to detergent compositions suitable for the care and personal washing of the skin.
  • compositions which are formulated to give mild cleansing and conditioning of the skin.
  • WO 90/13283 discloses a composition comprising an acyl ester of an isethionic acid salt, a long chain fatty acid, a moisturiser component and, optionally, soap.
  • compositions such that they can deliver effective moisturising, conditioning or protection of the skin.
  • the maximum average droplet size of the silicone oil that can be used is 2 microns, if product stability is to be maintained.
  • particle by particle is meant a solid particle or liquid droplet, of benefit agents such as silicone oil can be incorporated into non-soap based compositions and stable compositions formed by the use of structurants .
  • an aqueous liquid cleansing and moisturising composition comprising:-
  • a surface active agent selected from anionic, non-Lome, zwitterionic, and cationic surface active agents; and mixtures thereof;
  • the viscosity quoted is the minimum viscosity required to suspend benefit agent having a weight average particle size of 50 microns such that the composition has a separation rate at 25°C of less than 1mm per year.
  • compositions comprising large particles of petrolatum are structured by the presence of at least 5wt% insoluble fatty acid soap.
  • insoluble fatty acid soap by which is meant the level of insoluble fatty acid soap is below 1 wt% based on the composition.
  • Suitable structurants are those materials which when added to a composition, will increase the zero shear rate viscosity. They include swelling clays, for example laponite; fatty acid and derivatives thereof, in particular fatty acid monoglyceride polyglycol ether; cross-linked polyacrylates such as Carbopol (TM) (polymers available from Goodrich); acrylates and copolymers thereof; polyvinylpyrrolidone and copolymers thereof; polyethylene i ines; salts such as sodium chloride and ammonium sulphate; sucrose esters; gellants; and mixtures thereof.
  • swelling clays for example laponite
  • fatty acid and derivatives thereof in particular fatty acid monoglyceride polyglycol ether
  • cross-linked polyacrylates such as Carbopol (TM) (polymers available from Goodrich); acrylates and copolymers thereof; polyvinylpyrrolidone and copolymers thereof; polyethylene i ines; salts such as sodium chloride
  • clays particularly preferred are synthetic hectorite (laponite) clay used in conjunction with an electrolyte salt capable of causing the clay to thicken so as to suspend the benefit agent.
  • electrolytes include alkali and alkaline earth salts such as halides, ammonium salts and sulphates.
  • Particularly preferred structurants include fatty acids and derivatives thereof and cross-linked polyacrylates.
  • composition comprises two or more benefit agents one of said benefit agents may also function as a structurant.
  • the surface active agent can be selected from any known surfactant suitable for topical application to the human body. Mild surfactants, i.e. surfactants which do not damage the stratum corneum, the outer layer of the skin, are particularly preferred.
  • One preferred anionic detergent is fatty acyl isethionate of formula:
  • R is an alkyl or alkenyl group of 7 to 21 carbon atoms and M is a solubilising cation such as sodium, potassium, ammonium or substituted ammonium.
  • M is a solubilising cation such as sodium, potassium, ammonium or substituted ammonium.
  • RCO groups Preferably at least three quarters of the RCO groups have 12 to 18 carbon atoms and may be derived from coconut, palm or coconut/palm blends.
  • R is an alkyl group of 8 to 22 carbon atoms
  • n ranges from 0.5 to 10, especially from 1.5 to 8
  • M is a solubilising cation as defined above.
  • anionic detergents include alkyl glyceryl ether sulphate, sulphosuccmates, taurates, sarcosinates, sulphoacetates, alkyl phosphate, alkyl phosphate esters and acyl lactates, alkyl glutamates and mixtures thereof.
  • Sulphoauccmates may be monoalkyl sulphosuccmates having the formula: R 5 0 2 CCH,CH(SO : M)CO ; M; and amido-MEA sulphosuccmates of the formula: R 5 CONHCH 2 CH 2 0 2 CCH 2 CH(SO,M)C0 2 M; wherein R 5 ranges from C 3 -C 20 alkyl, preferably C l2 -C lit alkyl, and M is a solubilising cation.
  • Sarcosinates are generally indicated by the formula: R 5 C0N(CH 3 )CH 2 C0 2 M, wherein R 5 ranges from C ⁇ -C 20 alkyl, preferably C 12 -C 15 alkyl and M is a solubilising cation.
  • Taurates are generally identified by the formula: R 5 C0NR 6 CH,CH 2 S0 3 M, wherein R 5 ranges from C 9 -C 20 alkyl, preferably C 12 -C 15 alkyl, R 6 ranges from C,-C 4 alkyl, and M is a solubilising cation.
  • Suitable nonionic surface active agents include alkyl polysaccharides, lactobiona ides, ethyleneglycol esters, glycerol monoethers, polyhydroxyamides (glucamide) , primary and secondary alcohol ethoxylates, especially the C B . 20 aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol.
  • the surface active agent is preferably present at a level of from 1 to 35 wt%, preferably 3 to 30 wt%.
  • R 1 is alkyl or alkenyl of 7 to 18 carbon atoms
  • R 2 and R 3 are each independently alkyl, hydroxyalkyl or carboxyalkyl of 1 to 3 carbon atoms
  • m is 2 to 4
  • n is 0 or 1;
  • X is alkylene of 1 to 3 carbon atoms optionally substituted with hydroxyl
  • Y is -C0 2 " or -S0 3 "
  • Zwitterionic detergents within the above general formula include simple betaines of formula:-
  • R 1 may, in particular, be a mixture of C 12 and C 14 alkyl groups derived from coconut so that at least half, preferably at least three quarters, of the group R 1 has 10 to 14 carbon atoms.
  • R 2 and R 3 are preferably methyl.
  • a further possibility is a sulphobetaine of formula:-
  • R 1 , R 2 and R 3 in these formulae are as defined previously.
  • the benefit agent may also function as a carrier to deliver efficacy agents to skin treated with the compositions of the invention.
  • This route is particularly useful for delivering efficacy agents which are difficult to deposit onto the skin or those which suffer detrimental interactions with other components in the composition.
  • the carrier is a often a silicone or hydrocarbon oil which is not solubilised/micellised by the surface active phase and in which the efficacy agent is relatively soluble.
  • efficacy agents include anti-viral agents; hydroxycaprylic acids; pyrrolidone; carboxylic acids; 2,4,4 ' -trichloro-2 ' -hydroxydiphenyl ether (Irgasan DP300); 3 , 4, 4 ' -trichlorocarbanilide; salicylic acid; benzoyl peroxide; perfumes; essential oils; germicides and insect repellants such as N,N-dimethyl m-toluamide (DEET) ; and mixtures thereof.
  • anti-viral agents include anti-viral agents; hydroxycaprylic acids; pyrrolidone; carboxylic acids; 2,4,4 ' -trichloro-2 ' -hydroxydiphenyl ether (Irgasan DP300); 3 , 4, 4 ' -trichlorocarbanilide; salicylic acid; benzoyl peroxide; perfumes; essential oils; germicides and insect repellants such as N,N-dimethyl
  • compositions of the invention may be formulated as products for washing the skin, for example bath or shower gels, hand washing compositions, facial .washing liquids; pre-and post- shaving products; rinse-off, wipe-off and leave-on skin care products.
  • compositions of the invention will generally be pourable liquids or semi-liquids for example pastes and will preferably have a viscosity in the range 1000 to 100,000 mPas measured at a shear rate of 10s "1 at 25°C in a Haake Rotoviscometer RV20.
  • compositions will exhibit a Newtonian viscosity at a shear stress of 0.01 Pa at 25°C of at least 5,000 Pas preferably greater than 10,000 Pas.
  • characteristic viscosity measurements may be determined exactly (as in the case of the non-zero shear viscosites) using, for example, a Carrimed CSL 100 low stress rheometer, or obtained from an extrapolation according to the Cross Model (see J of the Chemical Engineer, 1993, paper entitled “Rheology for the Chemical Engineer” by H Barnes) as in the case of the zero shear rate.
  • compositions according to the invention comprising:- a) structuring the base formulation comprising at least one surface active agent selected from anionic, nonionic, zwitterionic, and cationic surface active agents, and mixtures thereof with a structurant; and
  • Cross-linked polyacrylate was Carbopol ETD 2020 ex Goodrich.
  • Guar hydroxypropyl trimonium chloride was Jaguar C-13-S ex Meyhali.
  • Silicone oil emulsion was BC 92/057 ex Basildon.
  • Silicone oil was DC200, a polydimethylsiloxane ex Dow Corning with a viscosity of 60000 mPas.
  • the following method was used to determine the amount of benefit agent deposited onto full thickness porcine skin (5 x 15 cm) treated with compositions according to the invention.
  • the skin was prehydrated and then 0.5 ml of the product applied to it.
  • the product was lathered for 10 seconds and then rinsed for 10 seconds under running water.
  • a strip of adhesive tape was pressed onto the skin for 30 seconds by applying a constant load of lOOg.cm "2 .
  • the adhesive tape employed was J-Lar Superclear (TM) tape having a width of 2.5cm. In total ten strips of tape were applied to adjacent sites on the skin.
  • the amounts of silicon and skin adhering to the tape are determined by means of X-ray fluorescence spectroscopy.
  • the tape strips are placed in an X-ray fluorescence spectrometer with the adhesive side facing the beam of this machine.
  • a mask is applied over the tape to define a standardised area in the middle of the tape which is exposed to the X-ray beam.
  • the sample chamber of the machine is placed under vacuum before making measurements and the spectrometer is then used to measure the quantities of silicon and sulphur.
  • the sulphur is representative of the amount of skin which has transferred to the tape.
  • This level can be varied to obtain a pH for the composition of 5.3.
  • the base formulation was prepared by mixing sodium lauryl ether sulphate and betaine. Thereafter the remaining components were added with mixing.
  • Silicone oil was present at a level of 5 wt% based on the total composition.
  • One syringe was filled with the base formu- lation and the other with silicone oil.
  • the syringes were then inserted into the syringe pump and the infusion rate set at 5:95 oil:base.
  • the oil and base were forced through a static in-line mixer and a composition with oil particles of the required size obtained.
  • the size of the particles can be controlled by the diameter of the static mixer, the flow rate and length of the mixer tube. The size of the particles can be determined using a Malvern Mastersizer.
  • the composition was prepared by dispersing the polyacrylate in excess water. Thereafter sorbic acid and trisodium citrate dihydrate were added to the resulting polymer dispersion. The three surface active agents were mixed and the resulting mix added to the polymer dispersion. Thereafter minors were added. The viscosity of the resulting composition was measured at a shear rate of 10s "1 at 25°C and thickener added until the required viscosity obtained. The base formulation and silicone oil were infused using two Harvard 44 syringe pumps as described above. The viscosity of the final product was 5500 mPas.
  • the benefit agent used was silicone oil present in an amount of 5wt%.
  • the viscosity of the product according to the invention and of the comparison were, respectively, 4628 and 5500 mPas at 10s "1 and 25°C and 22783 and 12.16 mPas at 0.01 Pa and 25°C.
  • compositions were stored in sealed glass vessels and placed in a oven at 37°C.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Detergent Compositions (AREA)

Abstract

Une composition nettoyante et hydratante liquide et aqueuse comprend un agent tensioactif, un agent adoucissant pour la peau dont la granulométrie moyenne pondérale est comprise entre 50 et 500 microns, et un agent structurant. La composition est pratiquement exempte de savon renfermant des acides gras insolubles et a une viscosité d'au moins 5 000 Pas à une contrainte tangentielle de 0,01 Pa à 25 °C.
PCT/GB1995/001687 1994-07-19 1995-07-18 Composition detergente Ceased WO1996002224A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU29856/95A AU2985695A (en) 1994-07-19 1995-07-18 Detergent composition
KR1019970700339A KR970704418A (ko) 1994-07-19 1995-07-18 세제 조성물(Detergent Composition)
BR9508782A BR9508782A (pt) 1994-07-19 1995-07-18 Composição líquida de limpeza e umedecimento e processos para preparar a mesma e para depositar em agente beneficiador de um líquido aquoso de limpeza e umedecimento
EP95925905A EP0771186A1 (fr) 1994-07-19 1995-07-18 Composition detergente
JP8504828A JPH09512824A (ja) 1994-07-19 1995-07-18 洗浄剤組成物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9414575.2 1994-07-19
GB9414575A GB9414575D0 (en) 1994-07-19 1994-07-19 Detergent composition

Publications (1)

Publication Number Publication Date
WO1996002224A1 true WO1996002224A1 (fr) 1996-02-01

Family

ID=10758574

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1995/001687 Ceased WO1996002224A1 (fr) 1994-07-19 1995-07-18 Composition detergente

Country Status (9)

Country Link
EP (1) EP0771186A1 (fr)
JP (1) JPH09512824A (fr)
KR (1) KR970704418A (fr)
AU (1) AU2985695A (fr)
BR (1) BR9508782A (fr)
CA (1) CA2190739A1 (fr)
GB (1) GB9414575D0 (fr)
WO (1) WO1996002224A1 (fr)
ZA (1) ZA955973B (fr)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996029979A1 (fr) * 1995-03-29 1996-10-03 Unilever Plc Compositions nettoyantes liquides
WO1998011873A1 (fr) * 1996-09-23 1998-03-26 The Procter & Gamble Company Composition d'un nettoyant liquide d'hygiene personnelle contenant un agent d'hydratation de la peau lipophile compose de gouttelettes relativement grosses
WO1998011872A1 (fr) * 1996-09-23 1998-03-26 The Procter & Gamble Company Composition liquide d'hygiene personnelle contenant un agent hydratant pour la peau, lipophile et constitue de gouttelettes relativement grosses
US5804540A (en) * 1997-01-08 1998-09-08 Lever Brothers Company, Division Of Conopco, Inc. Personal wash liquid composition comprising low viscosity oils pre-thickened by non-antifoaming hydrophobic polymers
US6046145A (en) * 1996-03-14 2000-04-04 Johnson & Johnson Consumer Companies, Inc. Cleansing and moisturizing surfactant compositions
US6183766B1 (en) 1999-02-12 2001-02-06 The Procter & Gamble Company Skin sanitizing compositions
US6395690B1 (en) 2001-02-28 2002-05-28 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Process for making mild moisturizing liquids containing large oil droplet
EP0937495A3 (fr) * 1998-02-23 2002-07-10 Unilever Plc Mélanger de liquides immiscibles
US6423329B1 (en) 1999-02-12 2002-07-23 The Procter & Gamble Company Skin sanitizing compositions
WO2002067888A1 (fr) * 2001-02-28 2002-09-06 Unilever Plc Compositions d'hygiene personnelle renfermant une dispersion de particules dans de l'huile
EP1486195A3 (fr) * 2003-05-22 2004-12-22 Unilever Plc Composition d'hygiène corporel comprenant un agent bénéfique structéré prémélangé ou un agent véhiculant et aboutissant à un effet amèlioré du modifiant optique séparé de l'agent bénéfique structuré.
EP2114356A2 (fr) 2007-03-06 2009-11-11 Peter Greven Hautschutz GmbH & Co. KG Produit de nettoyage de la peau avec des particules comprenant de l'huile de ricin hydrogenée
US8029772B2 (en) 2001-12-21 2011-10-04 Rhodia Inc. Stable surfactant compositions for suspending components
US8828364B2 (en) 2007-03-23 2014-09-09 Rhodia Operations Structured surfactant compositions
US9216143B2 (en) 2008-08-07 2015-12-22 Conopco, Inc. Liquid personal cleansing composition

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9704643D0 (en) 1997-03-06 1997-04-23 Johnson & Johnson Chemical composition
US7875582B2 (en) * 2003-05-22 2011-01-25 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Nonbar personal product compositions comprising crystalline wax structured benefit agent premix or delivery vehicle

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0268982A2 (fr) * 1986-11-18 1988-06-01 Toray Silicone Company, Ltd. Compositions cosmétiques renfermant des microémulsions de diméthylpolysiloxane
EP0407042A2 (fr) * 1989-06-21 1991-01-09 Colgate-Palmolive Company Shampoing pour le soin des cheveux contenant un composé de type alcool à longue chaîne
EP0452202A1 (fr) * 1990-04-05 1991-10-16 L'oreal Composition cosmétique ou dermo-pharmaceutique aqueuse contenant en suspension des sphéroides hydratés d'une substance lipidique hydrophile
EP0485212A1 (fr) * 1990-11-07 1992-05-13 Unilever Plc Composition détergente
WO1993009761A1 (fr) * 1991-11-22 1993-05-27 Richardson-Vicks Inc. Compositions combinees de nettoyage et d'hydratation de la peau
EP0552024A2 (fr) * 1992-01-15 1993-07-21 Unilever Plc Composition cosmétique avec un dépôt d'agents cosmétiques amélioré
WO1993019149A1 (fr) * 1992-03-25 1993-09-30 The Procter & Gamble Company Compositions de nettoyage
WO1993021293A1 (fr) * 1992-04-09 1993-10-28 The Procter & Gamble Company Compositions aqueuses detergentes a usage personnel ou cosmetique comprenant des apports en huile vegetale
WO1994001084A2 (fr) * 1992-07-07 1994-01-20 The Procter & Gamble Company Produit de nettoyage liquide comprenant un hydratant
WO1994017166A1 (fr) * 1993-01-23 1994-08-04 The Procter & Gamble Company Compositions nettoyantes

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0268982A2 (fr) * 1986-11-18 1988-06-01 Toray Silicone Company, Ltd. Compositions cosmétiques renfermant des microémulsions de diméthylpolysiloxane
EP0407042A2 (fr) * 1989-06-21 1991-01-09 Colgate-Palmolive Company Shampoing pour le soin des cheveux contenant un composé de type alcool à longue chaîne
EP0413417A2 (fr) * 1989-06-21 1991-02-20 Colgate-Palmolive Company Shampooing conditionnant les cheveux
EP0452202A1 (fr) * 1990-04-05 1991-10-16 L'oreal Composition cosmétique ou dermo-pharmaceutique aqueuse contenant en suspension des sphéroides hydratés d'une substance lipidique hydrophile
EP0485212A1 (fr) * 1990-11-07 1992-05-13 Unilever Plc Composition détergente
WO1993009761A1 (fr) * 1991-11-22 1993-05-27 Richardson-Vicks Inc. Compositions combinees de nettoyage et d'hydratation de la peau
EP0552024A2 (fr) * 1992-01-15 1993-07-21 Unilever Plc Composition cosmétique avec un dépôt d'agents cosmétiques amélioré
WO1993019149A1 (fr) * 1992-03-25 1993-09-30 The Procter & Gamble Company Compositions de nettoyage
WO1993021293A1 (fr) * 1992-04-09 1993-10-28 The Procter & Gamble Company Compositions aqueuses detergentes a usage personnel ou cosmetique comprenant des apports en huile vegetale
WO1994001084A2 (fr) * 1992-07-07 1994-01-20 The Procter & Gamble Company Produit de nettoyage liquide comprenant un hydratant
WO1994017166A1 (fr) * 1993-01-23 1994-08-04 The Procter & Gamble Company Compositions nettoyantes

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996029979A1 (fr) * 1995-03-29 1996-10-03 Unilever Plc Compositions nettoyantes liquides
US6440907B1 (en) 1996-03-14 2002-08-27 Johnson & Johnson Consumer Companies, Inc. Cleansing and moisturizing surfactant compositions
US6046145A (en) * 1996-03-14 2000-04-04 Johnson & Johnson Consumer Companies, Inc. Cleansing and moisturizing surfactant compositions
WO1998011873A1 (fr) * 1996-09-23 1998-03-26 The Procter & Gamble Company Composition d'un nettoyant liquide d'hygiene personnelle contenant un agent d'hydratation de la peau lipophile compose de gouttelettes relativement grosses
WO1998011872A1 (fr) * 1996-09-23 1998-03-26 The Procter & Gamble Company Composition liquide d'hygiene personnelle contenant un agent hydratant pour la peau, lipophile et constitue de gouttelettes relativement grosses
US5854293A (en) * 1996-09-23 1998-12-29 The Procter & Gamble Company Liquid personal cleansing composition which contain a lipophilic skin moisturizing agent comprised of relatively large droplets
US6066608A (en) * 1996-09-23 2000-05-23 The Procter & Gamble Company Liquid personal cleansing composition which contain a lipophilic skin moisturing agent comprised of relatively large droplets
KR100314599B1 (ko) * 1996-09-23 2001-11-29 데이비드 엠 모이어 비교적 큰 소적으로 구성된 친유성 피부 보습제를 함유하는 개인용 액체 세정 조성물
US5804540A (en) * 1997-01-08 1998-09-08 Lever Brothers Company, Division Of Conopco, Inc. Personal wash liquid composition comprising low viscosity oils pre-thickened by non-antifoaming hydrophobic polymers
EP0937495A3 (fr) * 1998-02-23 2002-07-10 Unilever Plc Mélanger de liquides immiscibles
US6183766B1 (en) 1999-02-12 2001-02-06 The Procter & Gamble Company Skin sanitizing compositions
US6423329B1 (en) 1999-02-12 2002-07-23 The Procter & Gamble Company Skin sanitizing compositions
WO2002067892A3 (fr) * 2001-02-28 2002-12-19 Unilever Plc Procede de production de liquides hydratants doux contenant de grosses gouttelettes d'huile
US6395690B1 (en) 2001-02-28 2002-05-28 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Process for making mild moisturizing liquids containing large oil droplet
AU2002252997B2 (en) * 2001-02-28 2004-04-22 Unilever Plc Personal wash compositions containing particle-in-oil dispersion
AU2002250896B2 (en) * 2001-02-28 2004-05-06 Unilever Plc Process for making mild moisturizing liquids containing large oil droplet
WO2002067888A1 (fr) * 2001-02-28 2002-09-06 Unilever Plc Compositions d'hygiene personnelle renfermant une dispersion de particules dans de l'huile
RU2279272C2 (ru) * 2001-02-28 2006-07-10 Унилевер Нв Способ изготовления мягких увлажняющих жидкостей, содержащих большие капли масла
RU2282433C2 (ru) * 2001-02-28 2006-08-27 Унилевер Нв Моющие композиции для личного использования, содержащие дисперсию типа "частицы-в-масле"
KR100847606B1 (ko) * 2001-02-28 2008-07-21 유니레버 엔.브이. 큰 오일 액적을 함유하는 밀크 보습액의 제조 방법
CZ299677B6 (cs) * 2001-02-28 2008-10-15 Unilever N. V. Tekutý mycí prostredek
CZ306109B6 (cs) * 2001-02-28 2016-08-10 Unilever N.V. Způsob výroby mycího prostředku
US8029772B2 (en) 2001-12-21 2011-10-04 Rhodia Inc. Stable surfactant compositions for suspending components
EP1486195A3 (fr) * 2003-05-22 2004-12-22 Unilever Plc Composition d'hygiène corporel comprenant un agent bénéfique structéré prémélangé ou un agent véhiculant et aboutissant à un effet amèlioré du modifiant optique séparé de l'agent bénéfique structuré.
US8092787B2 (en) 2003-05-22 2012-01-10 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Personal product compositions comprising structured benefit agent premix or delivery vehicle and providing enhanced effect of optical modifier separate from structured benefit agent
EP2114356A2 (fr) 2007-03-06 2009-11-11 Peter Greven Hautschutz GmbH & Co. KG Produit de nettoyage de la peau avec des particules comprenant de l'huile de ricin hydrogenée
US8828364B2 (en) 2007-03-23 2014-09-09 Rhodia Operations Structured surfactant compositions
US9216143B2 (en) 2008-08-07 2015-12-22 Conopco, Inc. Liquid personal cleansing composition
US9931282B2 (en) 2008-08-07 2018-04-03 Conopco, Inc. Liquid personal cleansing composition

Also Published As

Publication number Publication date
ZA955973B (en) 1997-01-20
KR970704418A (ko) 1997-09-06
GB9414575D0 (en) 1994-09-07
BR9508782A (pt) 1997-11-25
JPH09512824A (ja) 1997-12-22
CA2190739A1 (fr) 1996-02-01
EP0771186A1 (fr) 1997-05-07
AU2985695A (en) 1996-02-16

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