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WO1993021293A1 - Compositions aqueuses detergentes a usage personnel ou cosmetique comprenant des apports en huile vegetale - Google Patents

Compositions aqueuses detergentes a usage personnel ou cosmetique comprenant des apports en huile vegetale Download PDF

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Publication number
WO1993021293A1
WO1993021293A1 PCT/US1993/002570 US9302570W WO9321293A1 WO 1993021293 A1 WO1993021293 A1 WO 1993021293A1 US 9302570 W US9302570 W US 9302570W WO 9321293 A1 WO9321293 A1 WO 9321293A1
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WO
WIPO (PCT)
Prior art keywords
surfactant
composition according
vegetable oil
formula
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1993/002570
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English (en)
Inventor
Michel Joseph Giret
Anne Langlois
Roland Philip Duke
Emil Jedla
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
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Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of WO1993021293A1 publication Critical patent/WO1993021293A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/14—Liposomes; Vesicles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/08—Polycarboxylic acids containing no nitrogen or sulfur
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/18—Sulfonic acids or sulfuric acid esters; Salts thereof derived from amino alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/32—Protein hydrolysates; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Definitions

  • the present invention relates to aqueous compositions in the form of solutions or dispersions and which comprise a vegetable oil adduct.
  • it relates to detergent, personal cleansing or cosmetic compositions comprising the vegetable oil adduct in solution or dispersion form.
  • it relates to foam-producing personal cleansing compositions suitable for simultaneously cleansing and conditioning the skin and/or the hair and which may be used, for example, in the form of foam bath preparations, shower products, skin cleansers, hand, face and body cleansers, shampoos, etc.
  • compositions comprising an aqueous dispersion of the vegetable oil adduct and wherein the vegetable oil adduct is partly or wholly in the form of vesicles.
  • Such compositions are especially valuable for controlled delivery of water-soluble cosmetically-active and pharmaceutically-active ingredients.
  • Foaming cosmetic and detergent compositions must satisfy a number of criteria including cleansing power, foaming properties and mildness/low i ⁇ itancy with respect to the skin, hair and the ocular mucosae.
  • Ideal cosmetic cleansers should cleanse the skin or hair gently, without defatting and/or drying the hair and skin and without irritating the ocular mucosae or leaving skin taut after frequent use. Most lathering soaps, shower and bath products, shampoos and bars fail in this respect.
  • Vesicles can be described as water-encapsulating lipid spheres having a diameter usually of 100 nm or less and which comprise multimolecular lipid layers having a thickness generally of about 3 to 10 nm (see for example Bangham, Standish and Watkins, J. Mol. Biol. 13, 238 (1965)).
  • Vesicular structures having much larger size, for example up to 10,000 nm are also known in the art. Vesicles are known to be obtained from certain lipids which are capable of forming a mesomorphic (liquid crystalline) phase in an aqueous medium. Vesicle systems are valuable in their own right as vehicles for controlled delivery of water-soluble cosmetic or pharmaceutical ingredients to a target organ, for example the skin.
  • the present invention provides compositions comprising the vegetable oil adduct in vesicle form, as well as processes for the preparation thereof.
  • a detergent, personal cleansing or cosmetic composition comprising: a) one or more surfactants selected from anionic, nonionic, amphoteric,
  • N-surfactant a surfactant having a structure incorporating one or more amido, amino or ammonio moieties
  • N-surfactant an adduct prepared from vegetable oils containing non-conjugated
  • polyunsaturated fatty acid esters which are conjugated and elaidinized and then modified via Dies- Alder addition with a member of the group consisting of acrylic acid, fumaric acid and maleic anhydride; and c) water, and wherein the vegetable oil adduct is in the form of a solution or dispersion having an average particle size of less than 1000 nm.
  • the invention takes the form of a foam producing cleansing product suitable for personal cleansing of the skin or hair and which may be used as foam bath and shower products, skin cleansers and shampoos etc.
  • the invention relates to a foam-producing cleansing composition with superior lathering characteristics (creaminess, abundance, stability) combined with excellent mildness to the skin and hair, together with good stability, cleansing ability and conditioning performance.
  • the invention also relates to a wash and rinse-off personal cleansing product having the above lathering, mildness, rinsibility, stability and conditioning benefits.
  • compositions of the invention comprise as an essential ingredient a surfactant having a structure incorporating one or more amido, amino or ammonio moeities, such a surfactant being referred to herein as an N-surfactant.
  • Suitable N-surfactants can be selected generally from anionic, nonionic, amphoteric, zwitterionic and cationic surfactants and mixtures thereof; amphoteric surfactants are preferred however.
  • the level of N-surfactant is generally from about 0.1 % to about 30% preferably from about 1% to about 15%, and more preferably from about 3% to about 12% by weight of composition.
  • Amphoteric N-surfactants suitable for use in the compositions of the invention include:
  • R 1 is C 7 -C 22 alkyl or alkenyl
  • R 2 is hydrogen or CH 2 Z
  • each Z is independently CO 2 M or CH 2 CO 2 M
  • M is H, alkali metal, alkaline earth metal, ammonium or alkanolammonium; and/or ammonium derivatives of formula (III)
  • R 1 , R 2 and Z are as defined above;
  • Suitable amphoteric surfactants of type (a) are marketed under the trade name Miranol and are understood to comprise a complex mixture of species.
  • Miranols have been described as having the general formula II, although the CTFA Cosmetic Ingredient Dictionary, 3rd Edition indicates the non-cyclic structure III.
  • CTFA Cosmetic Ingredient Dictionary, 3rd Edition indicates the non-cyclic structure III.
  • Preferred for use herein, however, are the non-cyclic species.
  • amphoteric surfactants of type (a) include compounds of formula II and/or III in which R 1 is C 8 H 17 (especially iso-capryl), C 9 H 19 and
  • materials preferred for use in the present invention include cocoamphocarboxypropionate, cocoamphocarboxy propionic acid, and especially cocoamphoacetate and cocoamphodiacetate (otherwise referred to as cocoamphocarboxyglycinate).
  • Specific commercial products include those sold under the trade names of Empigen CDL60 and CDR 60 (Albright & Wilson), Miranol C2M Cone. N.P., Miranol C2M Cone.
  • Miranol C2M SF Miranol CM Special (Miranol, Inc.); Alkateric 2CIB (Alkaril Chemicals); Amphoterge W-2 (Lonza, Inc.); Monateric CDX-38, Monateric CSH-32 (Mona Industries); Rewoteric AM-2C (Rewo Chemical Group); and Schercotic MS-2 (Scher Chemicals).
  • amphoteric surfactants of this type are manufactured and sold in the form of electroneutral complexes with, for example, hydroxide counterions or with anionic sulfate or sulfonate surfactants, especially those of the sulfated C 8 -C 18 alcohol, C 8 -C 18 ethoxylated alcohol or C 8 -C 18 acyl glyceride types.
  • anionic sulfate or sulfonate surfactants especially those of the sulfated C 8 -C 18 alcohol, C 8 -C 18 ethoxylated alcohol or C 8 -C 18 acyl glyceride types.
  • compositions which are essentially free of (non-ethoxylated) sulfated alcohol surfactants are based herein on the uncompiexed forms of the surfactants, any anionic surfactant counterions being considered as part of the overall anionic surfactant component content.
  • amphoteric surfactants of type (b) include salts, especially the triethanolammonium salts and salts of N-lauryl-beta-amino propionic acid and N-lauryl-imino-dipropionic acid. Such materials are sold under the trade name Deriphat by General Mills and Mirataine by Miranol Inc. Amphoterics preferred for use herein, however, are those of formula II and/or III.
  • Anionic N-surfactants suitable for use in the compositions of the invention can be selected from methyl acyl taurates, fatty acyl glycinates, N-acyi glutamates, acyl sarcosinates, fatty acid/protein condensates and mixtures thereof.
  • Nonionic N-surfactants suitable for use in the composition of the invention can be selected from polyhydroxy fatty acid amide surfactants having the formula
  • R 8 (CO)N(R 9 )Z 2 wherein R 9 is H, C 1 -C 4 hydrocarbyl, 2-hydroxyethyl, 2-hydroxypropyl or a mixture thereof, R 8 is C 5 -C 31 hydrocarbyl and Z 2 is a
  • polyhydroxyhydrocarbyl having a linear chain with at least 3 hydroxyls directly connected to said chain, or an alkoxylated derivative thereof.
  • the preferred polyhydroxy fatty acid amide surfactants are those in which R 9 is C 1-4 alkyl, preferably methyl, and R 8 is C 7 -C 19 alkyl or alkenyl, more preferably straight-chain C 9 -C 17 alkyl or alkenyl, or mixture thereof; and Z 2 is a
  • Z 2 preferably will be derived from a reducing sugar in a reductive amination reaction; more preferably Z 2 is a giycityl.
  • Suitable reducing sugars include glucose, fructose, maltose, lactose, galactose, mannose, and xylose.
  • high dextrose corn syrup, high fructose com syrup, and high maltose corn syrup can be utilized as well as the individual sugars listed above. These corn syrups may yield a mix of sugar components for Z 2 .
  • Z 2 preferably will be selected from the group consisting of -CH 2 (CHOH) n -CH 2 OH,-CH(CH 2 OH)- (CHOH) n-1 -CH 2 OH, -CH 2 -(CHOH) 2 (CHOR')(CHOH)-CH 2 OH, where n is an integer from 3 to 5, inclusive, and R' is H or a cyclic or aliphatic monosaccharide, and alkoxylated derivatives thereof. Most preferred are glycityls wherein n is 4, particularly -CH 2 -(CHOH) 4 -CH 2 OH.
  • the most preferred polyhydroxy fatty acid amide has the formula
  • R 8 (CO)N(CH 3 )CH 2 (CHOH) 4 CH 2 OH wherein R 8 is a C11-C17 straight chain alkyl or alkenyl group.
  • Zwitterionic N-surfactants suitable for use in the compositions of the invention include alkyl betaines of the formula R 5 R 6 R 7 N + (CH 2 ) n M (VII) and amido betaines of the formula (VIII)
  • R5 is C 12 -C 22 alkyl or alkenyl
  • R 6 and R 7 are independently C 1 -C 3 alkyl or hydroxy alkyl
  • M is H, alkali metal, alkaline earth metal, ammonium or
  • alkanolammonium and n, m are each numbers from 1 to 4.
  • Preferred betaines include cocoamidopropyldimethylcarboxymethyl betaine and
  • compositions of the invention can also contain an auxiliary surfactant which is free of surfactant species having a structure incorporating amido, amino or ammonio moietes.
  • auxiliary surfactants are selected from anionic and nonionic surfactants and mixtures thereof.
  • the level of auxiliary surfactant is preferably in the range from about 0.1% to about 30%, more preferably from about 1% to about 15%, and especially from about 3% to about 12% by weight in the case of liquid compositions and from about 50% to about 90%, preferably from about 65% to about 85% by weight in the case of solid bar compositions.
  • the weight ratio of N-surfactant:auxiliary surfactant is generally from about 1:5 to about 20:1, preferably from about 1:2 to about 5:1, and especially from about 1: 1 to about 2: 1.
  • the total level of N-surfactant and auxiliary surfactants is generally about 0.5% to about 50%, preferably from about 5% to about 25% and especially from about 10% to about 20% by weight in the case of liquid compositions and from about 60% to about 95%, preferably from about 70% to about 90% by weight in the case of solid bar compositions.
  • Anionic auxiliary surfactants suitable for inclusion in the compositions of the invention can generally be described as mild synthetic detergent surfactants and include ethoxylated alkyl sulfates, alkyl glyceryi ether sulfonates, acyl isethionates, alkyl sulfosuccinates, alpha-sulfonated fatty acids, their salts and/or their esters, alkyl phosphate esters, ethoxylated alkyl phosphate esters, and mixtures thereof.
  • Alkyl and/or acyl chain lengths for these surfactants are C 8 -C 22, preferably C 10 -C 18 .
  • suitable anionic auxiliary surfactants also include soaps of C 8 -C 22 fatty acids.
  • Preferred for use herein from the viewpoint of optimum mildness and lathering characteristics are the salts of sulfuric acid esters of the reaction product of 1 mole of a higher fatty alcohol and from about 1 to about 12 moles of ethylene oxide, with sodium and magnesium being the preferred counterions.
  • Particularly preferred are the alkyl sulfates containing from about 2 to 4 moles of ethylene oxide, such as sodium laureth-2 sulfate, sodium laureth-3 sulfate and magnesium sodium laureth-3.6 sulfate.
  • the anionic surfactant contains at least about 50%, especially at least about 75% by weight of ethoxylated alkyl sulfate. Again, in preferred
  • the anionic surfactant counterions are selected from magnesium and mixtures of magnesium with one or more counterions selected from alkali metal, ammonium and alkanolammonium, this being preferred from the viewpoint of providing optimum lathering, mildness, emolliency, viscosity and stability.
  • Nonionic auxiliary surfactants suitable for inclusion in the compositions of the invention include alkylpolysaccharides having the general formula (VI)
  • RO(C n H 2n O) t Z x where Z is a moiety derived from glucose, fructose or galactose, R is C 8 -C 18 alkyl or alkenyl, n is 2 or 3, t is from 0 to 10 and x is from about 1 to 10, preferably from about 1.5 to 4.
  • alkylpolyglucosides having the formula VI wherein Z is a glucose residue, R is C 8 -C 18 alkyl or alkenyl, t is from 0 to
  • n is 2 or 3 preferably 2, and x is from about 1.5 to 4.
  • x and t are understood to be weight average values and saccharide substitution is preferably at the 1- position of the saccharide.
  • C 12 -C 14 alkyl polysaccharides are preferred from the viewpoint of lathering and C 8 -C 10 alkyl polysaccharides from the viewpoint of skin conditioning.
  • ROH long chain alcohol
  • ROH longer chain alcohol
  • the short chain alkylglucoside content of the final alkylpolyglucoside material should be less than 50%, preferably less than 10%, more preferably less than 5%, most preferably 0% of the
  • alkylpolyglucoside alkylpolyglucoside
  • the amount of unreacted alcohol (the free fatty alcohol content) in the desired alkylpolysaccharide surfactant is preferably less than about 2%, more preferably less than about 0.5% by weight of the total of the alkyl polysaccharide plus unreacted alcohol.
  • the amount of alkylmonosaccharide is about 20% to about 70%, preferably 30% to 60%, more preferably 30% to 50% by weight of the total of the
  • alkylpolysaccharide alkylpolysaccharide
  • nonionic auxiliary surfactants include polyethyleneglycol glyceryl fatty ester surfactants having the formula (IX)
  • n is from about 5 to about 200, preferably from about 20 to about 100, more preferably from about 30 to about 85, and wherein R comprises an aliphatic radical having from about 5 to 19 carbon atoms, preferably from about 9 to 17 carbon atoms, more preferably from about 11 to 17 carbon atoms, most preferably from about 11 to 14 carbon atoms.
  • Suitable glyceryi fatty ester surfactants include polyethyleneglycol derivatives of glyceryl cocoate, glyceryl caproate, glyceryl caprylate, glyceryl tallowate, glyceryl palmate, glyceryl stearate, glyceryl laurate, glyceryl oleate, glyceryl ricinoleate, and glyceryl fatty esters derived from triglycerides, such as palm oil, almond oil, and corn oil, preferably glyceryl tallowate and glyceryl cocoate.
  • Suitable surfactants of this class are commercially available from Sherex
  • Varonic LI 420 PEG 200 glyceryl tallowate
  • Varonic LI 63 and 67 PEG 30 and PEG 80 glyceryl cocoates
  • Crovol A-40 PEG 20 almond glyceride
  • Crovol A-70 PEG 60 almond glyceride
  • Crovol M-40 PEG 20 maize giyceride
  • Crovol M70 PEG 60 maize glyceride
  • Crovol PK-40 PEG 12 palm kernei glyceride
  • Crovol PK-70 PEG 45 palm kernel glyceride
  • monotallowate and cocoate fatty ester derivatives of polyethylene giycol, or mixtures thereof particularly materials such as PEG 82 glyceryl monotallowate and PEG 30 glyceryl cocoate, and mixtures thereof.
  • nonionic auxiliary surfactants herein include Cg-C[3 aliphatic alcohol ethoxylates generally containing an average of from 1.5 to 25, preferably from
  • the preferred alcohol chain length range is C9-C11 as it has been found that lathering performance is optimum for ethoxylates made from such alcohols. It is also desirable for lathering performance reasons that the hydrophilic-lipophilic balance (HLB) of the ethoxylated alcohol is in the range from 8.0 to 17.0, more preferably from 11.0 to 17.0 and most preferably from 11.0 to 15.0.
  • HLB hydrophilic-lipophilic balance
  • compositions of the invention also contain a vegetable oil adduct which preferably has the general formula (I):
  • R3 and R4 are independently selected from saturated and unsaturated C7-C22 hydrocarbyl, each Z ⁇ being CO2M and wherein
  • M is H, or a salt-forming cation, preferably alkali metal, ammonium or
  • alkanolammonium alkanolammonium
  • Materials of this kind can generally be described as adducts prepared from vegetable oils containing non-conjugated polyunsaturated fatty acid esters which are conjugated and elaidinized then modified by Dies-Alder addition with a member of the group consisting of acrylic acid, fumaric acid and maleic anhydride.
  • the adducts and their preparation are described in US-A-4740367, the adducts being marketed under the trade name Ceraphyl GA (Van Dyke).
  • the vegetable oil adduct preferably comprises from about 0.5% to about 25%, preferably from about 0.5% to about 15%, more preferably from about 1% to about 10% by weight of the compositions herein.
  • a preferred method of preparing adducts herein is to react two moles of vegetable oil with one mole of the dienophile in the presence of catalytic amounts of iodine, the conjugation and elaidinization agent. This produces a 50:50 blend of adduct together with disproportionated (conjugated) vegetable oil.
  • the vegetable oil adduct is present in the compositions of the invention in the form of a solution or dispersion having an average particle size of less than about 10,000 nm, preferably less than about 1,500 nm, more preferably less than about 1000 nm (measured for example by Quasi-Elastic Light Scattering (90° angle) using a Helium/Neon Laser, a Malvern goniometer with temperature control (25°C) and a Brookhaven BI2030AT digital correlator.
  • the particles are assumed to be spherical and the refractive index and viscosity of the continuous phase are assumed to be the same as for water.
  • particle size can be determined using quasi-elastic (dynamic) light scattering and electron microscopy (see M. S.
  • the average particle size of the disperse phase of vegetable oil adduct is at least about 1 and less than about 1000 nm, preferably from about 50 to about 500 nm. Smaller particles having an average particle size from about 1 nm to about 100 nm, preferably from about 3 nm to about 50 nm, are also suitable however.
  • the weight ratio of N-surfactant to vegetable oil adduct is preferably from about 10:1 to about 1:10, more preferably from about 5:1 to about 1:2.
  • the vegetable oil adduct disperse phase is partly or wholly in the form of unilamellar or multilamellar water-encapsulating vesicles. It is a feature of the invention that the vegetable oil adduct can be prepared in vesicle form following the process described in more detail herein. However, compositions wherein the vegetable oil adduct is at least partly in micellar solution or microemulsion form are also encompassed herein.
  • composition comprising an adduct prepared from vegetable oils containing non- conjugated polyunsaturated fatty acid esters which are conjugated and elaidinized and then modified via Dies- Alder addition with a member of the group consisting of acrylic acid, fumaric acid and maleic anhydride; and wherein the vegetable oil adduct is partly or wholly in the form of an aqueous dispersion of unilamellar or multilamellar waterencapsulating vesicles.
  • Such vesicular structures preferably display optical activity under polarized light.
  • compositions of the invention can be made by a process of pre-dissolving or pre-dispersing the vegetable oil adduct in the N-surfactant or portion thereof, followed by admixing with the remainder of the composition.
  • the vegetable oil adduct is pre-dissolved or pre-dispersed in the N-surfactant or portion thereof prior to admixture with the auxiliary surfactant.
  • compositions herein containing the vegetable oil adduct in vesicle form the vegetable oil adduct is admixed with an N-surfactant, a substoichiometric quantity of water or an aqueous phase is added thereto and thereafter the mixture so prepared is dispersed in a stoichiometric excess of water or an aqueous phase, optionally incorporating one or more auxiliary surfactants.
  • the aqueous phase which is encapsulated in the vesicles can include a wide variety of active substances.
  • pharmaceutically active substances or cosmetic substances can be employed.
  • Cosmetic substances can include, for instance, components generally employed for the care of the skin and hair, including polymeric skin conditioning agents, moisturizers, panthenol, humectants such as glycerine, sorbitol, pentaerythritol, inositol, pyrrolidone carboxylic acid and its salts; artificial tanning agents such as dihydoxy acetone, erythrulose, glyceraldehyde and gamma-dialdehydes such as tartaric aldehyde, optionally in the presence of dyes; water-soluble anit-solar agents; antiperspirants; deodorants; astringents; skin refreshing products, tonics; cicatrisive products; keratolytic products; depilatories; perfumed water; extract
  • active pharmaceutical substances include vitamins; hormones; enzymes, for example, superoxide dismutase; vaccines; anti-inflammatory agents, for example, hydrocortisone; antibiotics; and bactericides.
  • active substance eg. panthenol
  • the active substance is incorporated in the substoichiometric quantity of water or aqueous phase which is added to the vegetable oil adduct/N- surfactant mixture in the process described above.
  • compositions of the invention for use as personal cleansers preferably also contain from about 0.5% to about 6%, preferably from about 1.5% to about 5% by weight of saturated acyl fatty acids having a weight average chain length of from 10 to 16, preferably from 12 to 14 carbon atoms. Highly preferred is myristic acid.
  • the fatty acid is valuable both from the viewpoint of providing emolliency benefits and also for controlling the viscosity of the final composition.
  • compositions of the invention for use as personal cleansers preferably also contain a cationic or nonionic polymeric skin or hair conditioning agent at a level from about 0.01% to about 5%, preferably from about 0.04% to about 2% and especially from about 0.05% to about 1 %.
  • the polymer is found to be valuable for enhancing the creaminess and quality of the foam as well as providing a hair or skin conditioning utility.
  • Suitable polymers are high molecular weight materials (mass-average molecular weight determined, for instance, by light scattering, being generally from about 2,000 to about 3,000,000, preferably from about 5,000 to about 1,000,000).
  • Useful polymers are the cationic, nonionic, amphoteric, and anionic polymers useful in the cosmetic field. Preferred are cationic and nonionic polymers used in the cosmetic fields as hair or skin conditioning agents.
  • Representative classes of polymers include cationic and nonionic
  • polysaccharides cationic and nonionic homopolymers and copolymers derived from acrylic and/or methacrylic acid; cationic and nonionic cellulose resins; cationic copolymers of dimethyldiallylammonium chloride and acrylic acid; cationic
  • cationic polymers suitable for use herein include cationic guar gums such as hydroxypropyl trimethyl ammonium guar gum (d.s. of from 0.11 to 0.22) available commercially under the trade names Jaguar C-14-S(RTM) and Jaguar C-17(RTM) and also Jaguar C-16(RTM), which contains hydroxypropyl substituents (d.s. of from 0.8-1.1) in addition to the above-specified cationic groups, and quaternized cellulose ethers available commercially under the trade names Ucare Polymer JR and Celquat.
  • cationic guar gums such as hydroxypropyl trimethyl ammonium guar gum (d.s. of from 0.11 to 0.22) available commercially under the trade names Jaguar C-14-S(RTM) and Jaguar C-17(RTM) and also Jaguar C-16(RTM), which contains hydroxypropyl substituents (d.s. of from 0.8-1.1) in addition to the above-specified cationic groups, and qua
  • Suitable cationic polymers are homopolymers of dimethyldiallylammonium chloride available commercially under the trade name Merquat 100, copolymers of dimethyl aminoethylmethacrylate and acrylamide, copolymers of dimethyldiallylammonium chloride and acrylamide, available commercially under the trade names Merquat 550 and Merquat S, quaternized vinyl pyrrolidone acrylate or methacrylate copolymers of amino alcohol available commercially under the trade name Gafquat, and polyaikyleneimines such as
  • polyethylenimine and ethoxylated polyethylenimine are examples of polyethylenimine and ethoxylated polyethylenimine.
  • Anionic polymers suitable herein include hydrophobically-modified cross-linked polymers of acrylic acid having amphipathic properties as marketed by B F Goodrich under the trade name Pemulen TRI and Pemulen TR2; and the carboxyvinyl polymers sold by B F Goodrich under the trade mark Carbopol and which consist of polymers of acrylic acid cross-linked with polyallyl sucrose or polyallyl pentaeythritol, for example, Carbopol 934, 940 and 950.
  • the viscosity of the final composition (Brookfield RVT, Spindle 5, 50 rpm, 25°C) is preferably at least about 1,000 cps, more preferably from about 2000 to about 10,000 cps, especially from about 5,000 to about 7,000 cps.
  • compositions have non-Newtonian viscosity characteristics, however, with a viscosity (Brookfield RVT, Helipath, Spindle T-B, 5 rpm, 25°C, 1 min) in the range of from about 10,000 to about 40,000 cps, more preferably from about 20,000 to about 30,000 cps and a yield point of at least 50 dynes/cm ⁇ , preferably at least 100 dynes/cm ⁇ (Brookfield RVT, Spindle CP52, Plate Code A, 25 ⁇ C).
  • a viscosity Brookfield RVT, Helipath, Spindle T-B, 5 rpm, 25°C, 1 min
  • compositions of the invention can optionally include a hair or skin moisturizer.
  • the preferred level of moisturizer is from about 3% to about 40% by weight.
  • the moisturizer is nonexclusive and is selected from:
  • nonocclusive moisturizers are glycerine, polyethylene glycol, propylene glycol, sorbitol, polyethylene glycol and propylene glycol ethers of methyl glucose (e.g. methyl glucan-20), polyethylene glycol and propylene glycol ethers of lanolin alcohol (e.g. Solulan-75), sodium pyrrolidone carboxylic acid, lactic acid, urea, L-proline, guanidine, pyrrolidone, hydrolyzed protein and other collagen-derived proteins, aloe vera gel, acetamide MEA and mixtures thereof.
  • glycerine is highly preferred.
  • a further preferred component of the compositions of the invention is a watersoluble Ca 2+ /Mg 2+ sequesterant which is preferably added at a level of from about 0.1% to about 5% by weight to provide lather boosting advantages under hard water usage conditions.
  • Suitable sequesterants include polycarboxylates, amino
  • polycarboxylates such as ethylenediaminetetraacetic acid, diethylenetriamine pentaacetic acid, citric acid, gluconic acid, pyrophosphoric acid, etc. and their water-soluble salts.
  • compositions of the invention include proteins and polypeptides and derivatives thereof; water-soluble or solubilizable preservatives such as DMDM Hydantoin, Germall 115, methyl, ethyl, propyl and butyl esters of hydroxybenzoic acid, EDTA, Euxyl (RTM) K400, Bronopol (2-bromo-2-nitropropane-1,3-diol), sodium benzoate and 2- phenoxyethanol; other moisturizing agents such as hylaronic acid, chitin , and starch-grafted sodium polyacrylates such as Sanwet (RTM) IM-1000, IM-1500 and IM-2500 available from Celanese Superabsorbent Materials, Portsmith, VA, USA and described in US-A-4,076,663; solvents such as hexylene glycol and propylene glycol; low temperature phase modifiers such as ammonium ion sources (e.
  • pearlescers and opacifiers such as ethylene glycol distearate, TiO 2 and TiO 2 -coated mica; perfumes and perfume solubilizers etc.
  • Conventional nonionic emollient oils and waxes can be included as additional skin and hair conditioning agents at levels from about 0.5% to about 20%, preferably from about 0.5% to about 10%, more preferably from about 1% to about 6%.
  • Such materials include, for example, water-insoluble silicones inclusive of non-volatile polyalkyl and polyaryl siloxane gums and fluids, volatile cyclic and linear polyalkylsiloxanes, polyalkoxylated silicones, amino and quaternary ammonium modified silicones, rigid cross-linked and reinforced silicones and mixtures thereof, C 1 -C 24 esters of C 8 -C 30 fatty acids such as isopropyl myristate and cetyl ricinoleate, beeswax, saturated and unsaturated fatty alcohols such as behenyl alcohol, hydrocarbons such as mineral oils, petrolatum and squalene, fatty sorbitan esters (see US-A-3988255, Seiden, issued October 26 1976), lanolin and lanolin derivatives, animal and vegetable triglycerides such as almond oil, peanut oil, wheat germ oil, linseed oil, jojoba oil, oil of apricot pits, walnuts,
  • triisostearyltrimerate Of the above highly preferred are the vegetable triglyceride oils.
  • Water is also present at a level preferably of from about 45 % to about 99 % , more preferably at least about 60% by weight in the case of liquid compositions, and from about 5% to about 30% in the case of solid bar form compositions.
  • the pH of the compositions is preferably from about 4 to about 9, more preferably from about 4.5 to about 8.5, pH being controlled, for example, using a citrate buffer system.
  • compositions herein comprises:
  • step (f) admixing the premix of step (e) with a substoichiometric amount of water;
  • cocoamphoacetate (the amphoteric of formula I and/or IV in which R ⁇ is coconut alkyl, R2 is H, and Z is CO 2 Na) and 1.35% cocoamphodiacetate (the amphoteric of formula I and/or IV in which R 1 is coconut alkyl, R 2 is CH 2 CO 2 Na and Z is CC 2 Na).
  • Amphoteric 2 Sodium N-lauryl-beta-amino-propionate.
  • compositions in the form of shower foam products and which are representative of the present invention.
  • the compositions are made by the process set out hereinabove, the Ceraphyl GA being prepared in the form of a dispersion having an average particle size of less than 500 nm.
  • Amphoteric 1 and Amphoteric 2 are incorporated as part of the first surfactant phase and the remaining N-surfactants, if any, are incorporated as part of the second surfactant phase.
  • the products provide excellent in-use and efficacy benefits including cleansing, lathering, mildness and skin conditioning (hydration, suppleness etc.), rinsibility and stability.
  • a composition comprising vegetable oil adduct in vesicular form is prepared as follows: 60 parts of Ceraphyl GA are added to 30 parts of Amphoteric 1 and the mixture is stirred at ambient temperature. 5 parts of a 10% aqueous solution of D-panthenol is then added to form a white latex-like mixture. The latex is then admixed with 100 parts of 10% sodium lauryi sulfate solution. The resulting dispersion comprised spherical vesicular structures comprising internal droplets of water and D-panthenol.

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Abstract

Composition détergente à usage personnel ou cosmétique comprenant: a) un ou plusieurs tensioactifs sélectionnés à partir de tensioactifs anioniques, nonioniques, amphotériques, zwitterioniques et cationiques, ainsi que leurs mélanges et comprenant au moins un tensioactif dont la structure incorpore une ou plusieurs fractions amido, amino ou amonio (dénonmmées tensioactif N), b) un apport préparé à partir d'huiles végétales comprenant des esters d'acides gras non conjugés et polyinsaturés qui sont conjugés et élaïdinisés et ensuite modifiés par l'intermédiaire d'une addition de Dies-Alder par un élément du groupe constitué par de l'acide acrylique, de l'acide fumarique et de l'anhydride maléique; et c) de l'eau, dans laquelle l'apport en huile végétale se présente sous la forme d'une solution ou d'une dispersion dont la dimension moyenne de particule est inférieure à 1000 nm environ. Dans un mode de réalisation préféré, l'apport en huile végétale se présente sous forme vésiculaire et peut être chargée avec des ingrédients actifs cosmétiquement ou pharmaceutiquement.
PCT/US1993/002570 1992-04-09 1993-03-22 Compositions aqueuses detergentes a usage personnel ou cosmetique comprenant des apports en huile vegetale Ceased WO1993021293A1 (fr)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2290551A (en) * 1994-05-11 1996-01-03 Procter & Gamble Cleansing Compositions
WO1996002225A1 (fr) * 1994-07-19 1996-02-01 Unilever Plc Composition detergente
WO1996002620A1 (fr) * 1994-07-19 1996-02-01 Henkel Kommanditgesellschaft Auf Aktien Melanges detergents a pouvoir ameliore de lavage
WO1996002224A1 (fr) * 1994-07-19 1996-02-01 Unilever Plc Composition detergente
US5496488A (en) * 1992-07-07 1996-03-05 The Procter & Gamble Company Cleansing bar composition containing petrolatum having a specific size range
WO1997007195A1 (fr) * 1995-08-14 1997-02-27 The Procter & Gamble Company Preparation nettoyante et articles comprenant cette preparation
US5650384A (en) * 1993-06-18 1997-07-22 The Procter & Gamble Company Personal cleansing system comprising a polymeric diamond mesh bath sponge and a liquid cleanser with moisturizer
WO1998005294A1 (fr) * 1996-08-02 1998-02-12 Plum Kemi Produktion A/S Emulsion huile dans l'eau servant au nettoyage, a la protection ou a l'amelioration de l'etat de la peau humaine
WO1998027937A1 (fr) * 1996-12-20 1998-07-02 The Procter & Gamble Company Produit de nettoyage personnel conditionne
EP0828807A4 (fr) * 1995-05-27 1999-01-13 Procter & Gamble Composition nettoyante contenant des agents tensioactifs a base d'amide d'acide gras polyhydroxyle
WO1999002186A3 (fr) * 1997-07-09 1999-04-01 Lyfja Roun Hf The Icelandic Bi Systeme d'administration d'antigene comprenant des derives de monoglyceride ou de diglyceride en tant qu'adjuvants
EP0828808A4 (fr) * 1995-05-27 1999-08-25 Procter & Gamble Compositions nettoyantes liquides pour l'hygiene personnelle, contenant un polymere cationique comme agent de conditionnement de la peau
US5977039A (en) * 1994-04-21 1999-11-02 The Procter & Gamble Company Personal cleansing system comprising a personal cleansing implement and a liquid cleanser with moisturizer
US6613817B2 (en) * 1999-06-08 2003-09-02 Imperial Chemical Industries Plc Emulsions

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4196134A (en) * 1977-01-31 1980-04-01 Westvaco Corporation Vegetable oil adducts
US4578216A (en) * 1983-12-21 1986-03-25 Kao Corporation Shampoo composition containing amino acid-anionic and amphoteric surface active agents
US4654207A (en) * 1985-03-13 1987-03-31 Helene Curtis Industries, Inc. Pearlescent shampoo and method for preparation of same
EP0250181A2 (fr) * 1986-06-16 1987-12-23 Helene Curtis Industries, Inc. Compositions détergentes douces
US4740367A (en) * 1984-07-19 1988-04-26 Westvaco Corporation Vegetable oil adducts as emollients in skin and hair care products

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4196134A (en) * 1977-01-31 1980-04-01 Westvaco Corporation Vegetable oil adducts
US4578216A (en) * 1983-12-21 1986-03-25 Kao Corporation Shampoo composition containing amino acid-anionic and amphoteric surface active agents
US4740367A (en) * 1984-07-19 1988-04-26 Westvaco Corporation Vegetable oil adducts as emollients in skin and hair care products
US4654207A (en) * 1985-03-13 1987-03-31 Helene Curtis Industries, Inc. Pearlescent shampoo and method for preparation of same
EP0250181A2 (fr) * 1986-06-16 1987-12-23 Helene Curtis Industries, Inc. Compositions détergentes douces

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5496488A (en) * 1992-07-07 1996-03-05 The Procter & Gamble Company Cleansing bar composition containing petrolatum having a specific size range
US5650384A (en) * 1993-06-18 1997-07-22 The Procter & Gamble Company Personal cleansing system comprising a polymeric diamond mesh bath sponge and a liquid cleanser with moisturizer
US5935915A (en) * 1993-06-18 1999-08-10 The Procter & Gamble Company Personal cleansing system comprising a polymeric diamond-mesh bath sponge and a liquid cleanser with moisturizer
US6066607A (en) * 1993-06-18 2000-05-23 The Procter & Gamble Company Personal cleansing system comprising a polymeric diamond-mesh bath sponge and a liquid cleanser with moisturizer
US5977039A (en) * 1994-04-21 1999-11-02 The Procter & Gamble Company Personal cleansing system comprising a personal cleansing implement and a liquid cleanser with moisturizer
GB2290551B (en) * 1994-05-11 1998-06-10 Procter & Gamble Cleansing compositions
GB2290551A (en) * 1994-05-11 1996-01-03 Procter & Gamble Cleansing Compositions
US5661189A (en) * 1994-07-19 1997-08-26 Lever Brothers Company, Division Of Conopco, Inc. Detergent composition
WO1996002224A1 (fr) * 1994-07-19 1996-02-01 Unilever Plc Composition detergente
WO1996002620A1 (fr) * 1994-07-19 1996-02-01 Henkel Kommanditgesellschaft Auf Aktien Melanges detergents a pouvoir ameliore de lavage
WO1996002225A1 (fr) * 1994-07-19 1996-02-01 Unilever Plc Composition detergente
EP0828807A4 (fr) * 1995-05-27 1999-01-13 Procter & Gamble Composition nettoyante contenant des agents tensioactifs a base d'amide d'acide gras polyhydroxyle
EP0828808A4 (fr) * 1995-05-27 1999-08-25 Procter & Gamble Compositions nettoyantes liquides pour l'hygiene personnelle, contenant un polymere cationique comme agent de conditionnement de la peau
WO1997007195A1 (fr) * 1995-08-14 1997-02-27 The Procter & Gamble Company Preparation nettoyante et articles comprenant cette preparation
US6063746A (en) * 1995-08-14 2000-05-16 The Procter & Gamble Company Cleansing preparation
US6300301B1 (en) 1995-08-14 2001-10-09 The Procter & Gamble Company Cleansing preparation and articles comprising a cleansing preparation
WO1998005294A1 (fr) * 1996-08-02 1998-02-12 Plum Kemi Produktion A/S Emulsion huile dans l'eau servant au nettoyage, a la protection ou a l'amelioration de l'etat de la peau humaine
US6342208B1 (en) 1996-08-02 2002-01-29 Plum Kerni Produktion A/S Oil-in-water emulsion containing C10-C24 fatty acid derivatives for treating skin of mammals
WO1998027937A1 (fr) * 1996-12-20 1998-07-02 The Procter & Gamble Company Produit de nettoyage personnel conditionne
WO1999002186A3 (fr) * 1997-07-09 1999-04-01 Lyfja Roun Hf The Icelandic Bi Systeme d'administration d'antigene comprenant des derives de monoglyceride ou de diglyceride en tant qu'adjuvants
US6514503B1 (en) 1997-07-09 2003-02-04 Lyfjathoun Hf Antigen delivery system
US6613817B2 (en) * 1999-06-08 2003-09-02 Imperial Chemical Industries Plc Emulsions

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