US446351A - Aluminum alloy - Google Patents
Aluminum alloy Download PDFInfo
- Publication number
- US446351A US446351A US446351DA US446351A US 446351 A US446351 A US 446351A US 446351D A US446351D A US 446351DA US 446351 A US446351 A US 446351A
- Authority
- US
- United States
- Prior art keywords
- aluminum
- manganese
- aluminum alloy
- alloy
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000838 Al alloy Inorganic materials 0.000 title description 4
- 229910052782 aluminium Inorganic materials 0.000 description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 229910052728 basic metal Inorganic materials 0.000 description 3
- 150000003818 basic metals Chemical class 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910000906 Bronze Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 241000722270 Regulus Species 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910001020 Au alloy Inorganic materials 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 241000408670 Hosea Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 229940096118 ella Drugs 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000003353 gold alloy Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- -1 manganese-aluminum Chemical compound 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Inorganic materials [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/01—Alloys based on copper with aluminium as the next major constituent
Definitions
- My invention relates to aluminum alloys, and is more particularly useful with reference to so-called aluminum bronzes, in which a small proportion of aluminum is'alloyed with copper to impart something of its desirable qualities, particularly untarnishability.
- Most alloys of this character require repeated fusions to render them homogeneous, and, moreover, they are usually (unless the proportion of aluminum is very small) hard and brittle and lacking in both strength and malleability, owing to the crystalline combination formed by the metals.
- My invention has for its object to improve the quality of thesealloys and is based upon the discovery that the addition of a small proportion of manganese improves the texture and qualities of the alloy.
- the addition of manganese alone imparts malleability and a suseeptibility, t .o an exceedingly brilliant surface luster, besides enhancing the untarnishability.
- the resulting regulus consists of aggregations or nodules of varying proportions of the metals, which are then-lixiviated in boiling water to remove the soluble salts, and, finally, remelted to obtain a regulus of uniform composition, which is then remelted with the required proportion of copper.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Investigating And Analyzing Materials By Characteristic Methods (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
- UNITED STATES PATENT OFFICE.
JOHN A. JEANQON, OF NEIVPORT, KENTUCKY.
ALUMINUM ALLOY.
SPECIFICATION forming part of Letters Patent No. 446,351, dated February 10,1891.
Application filed March 20, 1890. Serial No. 344,675. (Specimens) To all whom it may concern.-
Be it known that I, J OHN A. J EANooN, a citizen of the United States, residing at Newport, in the county of Campbell and State of Kentucky, have invented new and useful Improvements in Aluminum Alloys, of which the following is a specification.
My invention relates to aluminum alloys, and is more particularly useful with reference to so-called aluminum bronzes, in which a small proportion of aluminum is'alloyed with copper to impart something of its desirable qualities, particularly untarnishability. Most alloys of this character, however, require repeated fusions to render them homogeneous, and, moreover, they are usually (unless the proportion of aluminum is very small) hard and brittle and lacking in both strength and malleability, owing to the crystalline combination formed by the metals.
My invention has for its object to improve the quality of thesealloys and is based upon the discovery that the addition of a small proportion of manganese improves the texture and qualities of the alloy. The addition of manganese alone imparts malleability and a suseeptibility, t .o an exceedingly brilliant surface luster, besides enhancing the untarnishability.
The improvement is especially valuable, in that a practically new class of bronzes is obtained having a much wider range of useful application than heretofore.
A larger percentage of aluminum can be utilized than has been found practicable here-,
tofore, thereby enhancing the untarnishability of the alloy, besides attaining a marked improvement in texture, luster, and color.
By way of example and illustration I haveappended in tabulated form a list of constituents and proportions of two bronzes produced according to my invention, samples of the same being placed on file as exhibit specimens correspondingly numbered:
Constituents. &2??? gg g Aluminum, partsv 20 15 Manganese, parts 3 3 Copper, parts U 77 62 These specimens are sufiiciently ductile to be rolled, hammered, drawn, or out, and are suitable for all manufactures involvingthese processes. Both possess the brilliant color, luster, and texture of gold alloys with a surface sheen peculiar to themselves.
In carrying out my invention I first produce an alloy of aluminum with manganese. This alloy in determined proportions is afterward used as a basic metal and fused with the copper in the desired proportions of the two. The basic metal can of course be. prepared directly by fusion of the constituent metals themselves with fluxes of the alkaline chlorides,potassium, sodium, and calciumaccording to known practice.
In commercial practice, however, I employ a cheaper method, as follows: To produce the basic metal of the manganese-aluminum bronze, I place in a graphite crucible, say, fifteen pounds anhydrous potassium and calcium chloride, heat slightly, and stir in a quantity of commi-nuted carbon. To this I add fifteen pounds aluminum in small fragments and heat to cherry hardness, fusing the chlorides and softening the aluminum, and, lastly, add and stir in about fifteen pounds anhydrous mangenese chloride, cover the crucible tightly, and heat to whiteness. The resulting regulus consists of aggregations or nodules of varying proportions of the metals, which are then-lixiviated in boiling water to remove the soluble salts, and, finally, remelted to obtain a regulus of uniform composition, which is then remelted with the required proportion of copper. I employ a fairly pure commercial aluminum and make ent-y-five to eighty-five per cent. of copper,
no account of the slight impurities contained twelve to twenty-five per cent. of aluminum,
therein. There is, of course, some loss in the and two to five per cent. manganese, substan- 15 process, for which experience will suggest tially as set forth.
5 the proper allowance, but which I roughly In Witness whereof I have hereunto set my estimate at about one per cent. for aluminum hand in the presence of two subscribing witand eight to ten per cent. for manganese nesses.
chloride. 7
Iclaim as my invention and desire to secure JOHN JEANQON' 10 by Letters Patent of the United States- WVitnesses:
A bronze or alloy of copper, aluminum, and L. M. HOSEA,
manganese in about the proportions of sev- ELLA I-IosEA.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US446351A true US446351A (en) | 1891-02-10 |
Family
ID=2515242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US446351D Expired - Lifetime US446351A (en) | Aluminum alloy |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US446351A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4038068A (en) * | 1976-02-19 | 1977-07-26 | Olin Corporation | Method of melting copper alloys with a flux |
-
0
- US US446351D patent/US446351A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4038068A (en) * | 1976-02-19 | 1977-07-26 | Olin Corporation | Method of melting copper alloys with a flux |
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