US2414525A - Process of applying insulation - Google Patents

Description

Jan. 21, 1947. c. F. HILL ETAL PROCESS OF APPLYING INSULATION Filed Feb. 25,1944 2 Sheets-Sheet l Fa l T/uc/r Pesznous Chafing Nafer-ial flaking Ore/7 f'Yg .3.

flaking Oven I-ll llllll.

Z 77):11 impregnating Pesz'nbus Composition lNVENTORS Charles fi'l/t'll and Jan. 21, 1947.

c. F. HILL r-rrm. 2,414,525

PROCESS OF APPLYING INSULATION Filed Feb. 25, 1944 2 Sheets-Sheet 2 9- 3 Fig U.

l flaking Oren 66 Fig A4 fia/rz'rrg 0119/1 64 52 26 FZg./j.- E Baking Ore/1 5g 58;.C -Z 1 WITNESSES: INVENTORS Char/es l". f/z'll aha Patented Jan. 21, 1947 UNITED STATES PATENT OFFICE PROCESS OF APPLYING INSULATION Charles F. Hill,

Edgewood, and Newton 0.-

Foster, Wilkinsburg, Pa., asslgnors to Westinghouse Electric Corporation, East Pittsburgh. Pa., a corporation of Pennsylvania Application February 25, 1944, Serial No. 523,948

I with insulating resinous substances wherein the interstices of electrical members are substantially completely impregnated with a solid resinous composition and the exterior surface of the member carries a complete, resilient, weatherresisting coating of resinous material thereon.

An important problem in the manufacture of electrical apparatus is the application thereto of electrical insulation. The insulation serves not only to electrically insulate electrical conductors and other members from one another, but serves likewise to protect the apparatus from the undesirable eifects of weather, and moisture or water in particular. It is a well known phenomenon that insulations applied to electrical members when dry function satisfactorily but'when exposed to moisture absorb it gradually and lose their resistance properties. In many cases the insulating requirements for electrical members specify that immersion in water should have no significant adverse effects upon the operation thereof. Electrical members such as coils, transformers, motors, capacitors and similar devices are frequently located in exposed conditions where they may be subject to rainfall, inundation by water, various corrosive atmospheres, metallic dusts, and the like. It is particularly desirable that insulation applied to the apparatus should protect the conductors under these adverse conditions whereby normal functioning of the apparatus is maintained.

According to the present invention, electrical members are effectively encapsulated substantially completely with resinous insulating materials capable of withstanding a wide range of temperatures, various atmospheres and water. The encapsulation provides a flexible, weatherresisting exterior coating that will be unaffected by the normal operation of the apparatus and will withstand ordinary wear and tear without cracking, chipping or flaking off. The interior of the electrical member is completely impregnated to provide good electrical insulation, good thermal conductivity to remove heat developed during operation and protection against the elements and moisture.

Briefly, the process of encapsulation according to the present invention is based on the application to the outer surface of an electrical member a thin, non-porous coating of resinous material that closely follows the contours of the member and bridges gaps in the member to provide a complete cup-like shell which, when suitably hardened, will hold a thin, penetrating resin impregnating the interstices of the member whereby the latter resin may be polymerized to give a substantially solid impregnation. Subseimpregnate the interstices thereof, thereby maintaining high electrical insulating efiiciency under all conditions.

Other objects of the invention will, in part, be obvious and will, in part, appear hereinafter.

For a fuller understanding of the nature and objects of the invention reference should be had to the following figures of the drawings, in which Figures 1 to 8 illustrate one sequence of steps carrying out the invention and Figs. 9 to 15 illustrate a modified process.

Figure 1 is an elevational view, partly in section.

Fig. 2 is a View in elevation.

Fig. 3 is a schematic showing of a baking oven.

Fig. 4 is an elevational view, partly in section.

Fig. 5 is a schematic showing of a baking oven.

Fig. 6 is an elevational view, partly in section.

Fig. 7 is a schematic showing of a baking oven.

Fig. 8 is a view in elevation of a completed insulated member.

Fig. 9 is a view in elevation, partly in section.

Fig. 10 is a cross-sectional view of a partially treated coil and core.

Fig. 11 is a schematic view of an oven.

Fig. 12 is a view in elevation, partly in section.

Fig. 13 is a schematic view of a baking oven.

Fig. 14 is a view in elevation, partly in section.

Fig. 15 is a schematic view of a baking oven.

As shown in the processes of Figs. 1 to 8 and 9 to 15, respectively, the process of encapsulation comprises essentially the steps of applying an initial cup-like shell of a relatively thick resinous material to the exterior of the member being insulated, impregnating the member with a fluid 3 penetrating solventless type of resin composition, the shell serving to hold the penetrating resin in the member. hardening the resinous composition and completing the outer shell to cover the entire surface of the electrical member with the relatively thick resin.

In the preferred embodiment of the invention in carrying out the process of encapsulation, two distinct types of resinous insulating materials may be employed. In order to provide the outer shell about an electrical member, a relatively thick resinous material having thixotropic properties is desirable. The relatively thick resinous material should be capable of bridging small gaps, such, for example, as of the order of width without penetrating far into the fine interstices that may exist in normally wound coils and the like. Generally, the thick resinous material carries a filler composed of finely divided inorganic solid material in order to enable the building up of a relatively thick outer protective coating which may be from 5 mils to or more in thickness. A too-thick coating compared to the size of the member obviously may be subject to cracking due to thermal expansion of the various elements of the encased member and may lack a certain degree of required flexibility, In the case of relatively large members, such, for example, as large generator coils, such exterior coating of thick resin may be reinforced by means of tapes of inorganic fibrous material to provide for adequate mechanical characteristics.

For impregnating the interstices of the interior of the electrical member, a relatively thin, fluid resinous composition substantially free of solvents requiring evaporation during the process of hardening the resin is requisite. Such resinous compositions are commonly known as solventless compositions, though in fact a solvent composed of a reacting substance is present. The presence of any filler material is generally undesirable since the penetration of the resin into the interstice in the article being impregnated may be hindered. During hardening, the solventless resinous composition should give oil no moisture of condensation or other gaseous products, since these will tend to cause gas pockets and otherwise deleteriously affect th insulation of the member. In other words in preparing the composition, it should be kept in mind that it should be of such a nature that when polymerizing it does not produce moisture or other gaseous products. The composition should harden or polymerize without any significant change in volume over that occupied while in the liquid state. A volume shrinkage of up to 10% is not objectionable in the process of encapsulation.

A number of resinous materials have been discovered which may be employed with satisfactory results in the process of encapsulating electrical members. The following examples are typical of compositions which have been employed with good results to produce the outer coating.

Example No. I

A resin composed of:

Parts by weight Castor oil 100 Maleic anhydride was prepared by heating the mixture at 120 C. for several hours to produce a castor oil-maleate of a molasses-like consistency. About 60 parts by weight of the cooled castor oil-maleate was dissolved in 30 parts by weight of monomeric styrene plus 0.02% of hydroquinone to inhibit premature polymerization. A resinous solution of the consistency of thin oil was so produced. In order to enhance the thixotropic properties of the solution, 65 parts by weight of the solution was admixed in an evacuated flask with parts by weight of 325 mesh mica and 1% of benzoyl peroxide catalyst based on the weight of the resinous components. A thick, golden-brown resinous material was produced by the process The resinous material was applied by dipping small transformer assemblies therein. Although the material did not have a very high viscosity, it appeared to exhibit strong thixotropic proper-- ties, since, after baking for eight hours, each transformer assembly was found to be coated both on the sides and bottom with a uniform coating about 14 mils in thickness. Heat treatment converted the material into a thermoset solid body.

The resin shrunk slightly in volume upon .polymerizin-g to the solid state. Gaps in the coil mem her were completely bridged by the coating.

The castor-oil-maleate-styrene resin has an exceptionally fiat hardness-temperature curve. Durometer measurements of one sample at 28 C. gave values of while at C. the value was 70. This relatively small change in hardness over this temperature range is a particularly valuable feature.

Oils and many other petroleum products exert no solvent effect on this family of resins.

Example No. II

A resin composed of:

Parts by weight Linseed oil 61 Castor oil 15.8 Maleic anhydride 23.2

was produced by heating the mixture for eight hours at 175 C. to 200 C. 75 parts of this resin were dissolved in 25 parts of monomeric styrene and 0.03% hydroquinone inhibitor and 1% by weight of benzoyl peroxide catalyst was added.

When the resinous material is for coating or encapsulating some article such as a transformer, powdered mice. may be incorporated in the resin solution in an evacuated flask in the proportion of 35 parts of mica to 65 parts of the solution. In applying the resinous material a transformer unit was coated and baked 12 hours at C. The resulting coating was substantially uniform in thickness and bridged all the gaps in the transformer core and coils. The coating was softer and more flexible than that described in Example I but exhibited a tough, oxidized surface skin.

Example No. II!

A mixture of:

I Parts by weight Castor oil 20 Linseed nil 60 Peanut oil 20 Maleic anhydride 30 was heated at a temperature of C. for eight hours to a thick sirupy state. The reaction product was dissolved in 30 parts by weight of monostyrene to '70 parts by weight of the linseedpared to that produced on the linseed oil-castor oil resin of Example No. II. The proportion of peanut oil may be increased or decreased to meet requirements.

Drying oils' such as Perilla oil, soybean oil, cotton-seed oil, corn oil, cashew nut shell oil and the like may be used to replace all or part of the linseed oil of Example II. a The proportion of castor oil and linseed oil'or other drying oil may be modified to provide for diflerent degrees of oxidation of the outer surface depending on conditions to be met. Various non-drying oils may replace all or part of the peanut oil.

As described in the copending patent application of N. Foster entitled Synthetic resin compositions, filed November 7, 1941, Serial No. 418,153, tung and oiticica oils as well as alkyds may be combined with the castor oil-maleate or castor oil-maleate-drying oils as described herein to provide for different degrees of flexibility.

The resin of Examples I to III are specific to maleic anhydride as one of the reactants. How

ever fumaric acid, citraconic acid and mesaconic acid, maleic acid and other ethylene alpha-beta 'dicarboxylic acids and their anhydrides may remonostyrenes are equally effective for this purpose as are simple methyl substituted styrenes. Thus monomeric para-methyl-styrene will disreact to form resilient thermoset resinous solids therewith. Distyrene is also an example of other usable reacting solvents.

Other liquid monomeric vinyl compounds are capable of dissolving the castor oil-maleates and oil modified castor oil-maleates and polymerizing therewith. Examples of typical vinyl compounds suitable for this purpose are alpha methyl styrene, vinyl acetate, methyl vinyl ketone, acrylic nitrite, methyl methacrylate and allyl esters such as diallyl phthalate.

Various peroxides and ozonides may be em-- ployed as catalysts in lieu of benzoyl peroxide.

It has been found that a finely divided flakelike material such as mica flakes in an amount of from about to 50% by weight gives improved thioxtropic properties for the purpose of this application. However, other finely divided insulating inorganic materials such as powdered asbestos,

solve castor oil-maleates and subsequently cotransformer member I! composed of a magnetic core I! and a coil I4 is dipped into the thick resinous castor oil-maleate-styrene coating material I8 present in the tank l8 to cover a major proportion of the outside surface of the member. Since the coil H presents the more critical insulation problem, the thick resinous material is applied just short of the top of the coil l4. 1

When removed from the tank l8, the member III has the coating 20 of the resinous material over the lower portion thereof disposed as a thick imperforate layer closely conforming to the contour of the member. By reason of the thixotropic properties of the resin it the coating 20 will not drip to a great extent. When placed in the baking oven 22 of Fig. 3, the castor oil-maleatestyrene resin polymerizes into a thermoset infusible material. Thus an imperforate cup-like shell of resin is provided about the electrical member.

The electrical member I0 is then placed within the impregnating tank 24 which can be hermetically sealed by means of the cover 25 and all the air and moisture evacuated by the line 28. After being subjected to evacuation, the tank can be filled with the thin penetrating resinous composition 30 introduced into the tank 24 by means of the conduit 32. The thin resinous material, after it has risen past the top of the shellformed by the outer coating 20, will flow inside the cup-like shell and fill substantially all the interstices of the member Ill. The impregnated member ID is removed from the tank 24 and placed in the baking oven 34 where the resinous composition 3b is caused to polymerize into a solid thermoset impregnation without any gas pockets.

After baking, the coated and filled member I 0 in inverted and dipped into the thick resinous coating material it in tank 36 to a level whereby the newly applied coating overlaps the original coating 20. After baking in the oven 38, the com viously the coating 40 may be applied to the entire outer surface. Even the leads 42 are coated with the resinous material in such a manner that an airtight seal is produced.

silica, powdered glass and the like may be added in amounts of from 25% up to 50% and higher. In some cases conducting solid material in finely divided form, such as carbon or graphite may be incorporated in the outer coating material, to provide for reducing or preventing corona.

A number of solventless resinous compositions have been employed in impregnating electrical members after the exterior has been provided with a cup-like shell by mean or the relatively thick resin solutions in the three examples above given. The castoroil-maleates or the linseed-castor oilmaleates of Examples I and II are dissolved in larger proportions of monostyrene to produce sufficiently thin compositions. The proportion of 50 parts to 90 parts by weight of monostyrene and 1 from 50 parts to 10 parts of the castor oil-maleate will produce a suitably thin fluid solution. No filler is added since this would impair the penetrating qualities of the resinous composition.

Referring to Figs. 1 to 8 of the drawings, there is illustrated one mode of carrying forward the encapsulating. process. In Fig. 1, the electrical The completed units have been cut in two. Examination shows practically complete filling. Undoubtedly the encapsulating process described enables accommodation'of the various resins to one another and to the member so that-the slight shrinkage of the penetrating resin produces no apparent porosity internally. 1

Units such as the insulated electrical member ID shown in 'Fig. 8 have been subjected to a water test in which the entire unit has been immersed in saturated salt water at C. for two hours, transferred to a saturated salt solution of 0 C. for two hours and the immersion repeated four times for a total time of 20 hours. At the end of the treatment, the transformer exhibited a resistance of as much as 100,000

In such a case the applicationof the first coating of thick resinous material may be effected to take advantage of the impervious material applied thereto. As illustrated in Fig. 9, the magnetic coil 60 comprising a core 52, a coil (shown in Fig. and a cylindrical impervious insulating paper collar 56 about the coil is dipped in the thick resinous material H6 in the tank 60 just beyond the lower level of the collar 56. As shown in cross section in Fig. 10, the thick resinous material forms a coating 62 about one conductor 58 and overlaps the insulating paper covering 56, whereby a liquid tight cup is produced. After baking in an oven 66 to polymerize the resin 62, the magnetic coil 56 is placed in the impregnating tank 2% containing the thin penetrating resinous com postion 30 where it may be subjected to vacuum treatment to obtain a complete impregnation of the interstices of the coil 50. After baking in the oven 66, the impregnated magnetic coil 50 is inverted and dipped into the thick resinous composition H5 in the tank 36 to a level such that the original coating 62 is below the surface of the composition 16. After baking in the oven 68, a completely insulated and impregnated magnetic core is produced similar to that shown in Fig. 8.

It is highly economical to combine in the Y series of steps shown in Figs. 1 to 8 of the drawings, for example, the process of applying both the exterior protective coating 26-46 with the steps of applying the interior impregnating resin 30. Alternatively in some cases it may be desirable to apply to the exterior of electrical members a cup-like shell of a temporary surface coating having some of the properties of the thick resinous material. For example, cellulose acetate or other acyl cellulose ester in a relatively viscous state may be applied to the exterior of electrical members so thatan open-end cup-like shell is produced. Afterthe shell has been filled with the thin resinous composition and hardened, the cellulose acetate shell may be stripped from the exterior of the electrical member and the entire electrical member dipped in a thick resinous material to provide a permanent exterior weather-resisting protective coating of the type used in Fig. 1 of the drawings. Advantages arising from the use of cellulose acetate are that in some cases the thin impregnating composition having about 90% monostyrene solvent exerts a softening eifect on the outer shell even though polymerized to a thermoset state. Cellulose acetate is not as soluble in the monostyrene and therefore better resultsmay be obtained under these conditions.

Railway motor coils have been encapsulated by first dipping them in a thick resinous material such as that of Example I leaving only a small portion of the upper end of the coil uncoated. After a treatment to polymerize the surface coating of resinous material, the coil is impregnated with a thin resinous composition in a vacuum impregnating chamber and hardened by heat treatment. The final application of a cap to the exterior of the coil to provide a complete surface coating produces a completely insulated and practically solid resin filled coil.

It will be apparent that almost any type of electrical member may be practically solidly impregnated with the thin resinous composition by the process described herein. The solid solventless resinous composition applied as an impregnant provides for better conduction of heat than achieved in the prior art impregnating before polymerization. The insulation charac-.

teristics of the electrical members produced by the.practice of the present invention are un- I paralleled, both as to breakdown strength and resistance to the deleterious efiect of moisture and other materials to which electrical apparatus may be subjected. Even members sealed in a metal container filled with an insulating dielectric liquid have failed when subjected to conditions of use where the present invention has been satisfactorily employed for prolonged periods of time.

Various insulating varnishes, such, for exam-- ple, as are employed at the present time in coating electrical conductors, may be applied to the exterior of electrical members if prepared with a minimum of solvent and incorporating sumcient finely divided inorganic solids to attain suitable thixotropic properties to provide a coating of adequate thickness on the member. It may be necessary, however, with some coating compositions to apply a plurality of coatings before a suificiently thick and non-porous exterior layer is obtained. Polyvinyl acetals suitably thickened with finely divided mica are suitable as the exterior coating material. The reaction products of maleic anhydride and styrene in a viscous and thixotropic state have been employed for the same purpose. Alkyd resins alone or combined with the castor oil-maleate and dissolved in monostyrene can be used for both coating and impregnating members.

Both volatile solvents and copolymerizing solvents such as monostyrene, diallyl phthalate, methyl methacrylate and similar monomeric materials that are good solvents for a resin base may be employed for the purpose of providing the outer cup-like shell coating. Since the outer coating is not harmfully afiected thereby, the use of volatile solvents which do not take part in the reaction is permissible.

Since certain changes may be made in the above invention and difierent embodiments of the invention may be made without departing from the scope thereof, it is intended that all matter contained in the above described disclosure shall be interpreted as illustrative and not in a limiting sense.

We claim as our invention:

1. The process of encapsulating an electrical member which comprises, in combination, apply.. ing to a portion of the surface of the member a relatively thick resinous material which is too thick to penetrate far into the interstices of the member and is capable of bridging over surface discontinuities, the thick resinous material forming an exterior coating to provide an outer shell of cup-like form, treating the resinous exterior coating to harden it, applying a relatively thin and penetrating resinous composition to the electrical member to fill the cup-like form'and to impregnate the interstices of the electrical member, treating the member to harden the thin resinous composition to a nonfiowing state, inverting and dipping the member into the relatively thick res inous material to produce on the exterior of the member a coating overlapping and sealed to the original coating, and treating the member to harden the applied resinous material to a hard,

insoluble state.

2. The process of producing electrical insulation on members comprising, in combination, applying to the member a relatively thick resinous material to less than all of the outer surface of the member to provide a shell of the resinous material thereon, treating the resinous material to harden it, applying a relatively thin, fluid resinous composition substantially free of solvent requiring evaporation to fill th hardened shell and to impregnate the member, treating the relative- 1y thin resinous material to harden it, inverting the member and applying a relatively thick resinous material to the remainder of the outer surface of the member to completely enclose the outer surface, and hardening the resinous material.

3. The process of providing electrical insulation on members comprising, in combination, applying to the outer surface of the member a relatively thick thermosetting resinous material having good elasticity and weather-resisting properties, the resinous material being applied to nearly all of the outer surface to provide an open end shell of the resinous material, heat treating the resinous material to a hardened state, applying a relatively thin, thermosetting resinous composition characterized by good electrically insulating properties to fill the open end shell and to impregnate the member, heat treating the member to polymerize the thin resinous material to a thermoset state, applying to the outer surface a relatively thick thermosetting resin to form a complete shell and heat-treating the member to convert the resinous material to a hardened state. 4. In the process of providing an electrical member with insulation substantially completely impregnating the interstices thereof comprising,

in combination, applying to a major proportion of the outer surface of the member, a relatively thick, fiowable resinous material having the property of bridging surface gaps and incapable of penetrating appreciably into the fine interstices thereof, treating the resinous material to harden it to a nonfiowable state during subsequent treatment, the hardened resinous material forming an open-end, cup-like shell adherent to the outer surface of the member and substantially containing the member, introducing into the cup-like shell a relatively thin, fluid resinous composition substantially free of solvent requiring evaporation in hardening to a solid state, the thin resinous composition capable of impregnating fine interstices, and treating the member to harden the thin resinous composition to a solid state.

5. In the process of providing an electrical member with insulation substantially completely impregnating the interstices thereof comprising, in combination, applying to a major proportion of the outer surface of the member, a relatively thick, flowable resinous material having the property of bridging surface gaps and incapable of penetrating appreciably into the fine interstices thereof, treating the resinous material to harden it to a nonflowable state during subsequent treatment, the hardened resinous material forming an open-end, cup-like shell adherent to the outer surface of the member and substantially containing the member, subjecting the member to a vacuum, and introducing into the evacuated cup-like shell a relatively thin, fluid resinous composition substantially free of solvent requiring evaporation in hardening to a solid state, the thin resinous composition capable of impregnating fine interstices and treatin the member to harden the thin resinous composition to a solid state.

6. In the process of providing an electrical member with insulation substantially completely impregnating the interstices thereof comprising, in combination, applying to a major proportion of the outer surface of the member, a relatively thick, flowable resinous material having the property of bridging surface gaps and incapable of penetrating appreciably into the fine interstices thereof, treating the resinous material to harden it to a nonfiowable state during subsequent treatment, the hardened resinous material forming an open-end, cup-like shell substantially containing the member, introducing into the cuplike shell a relatively thin, fluid resinous composition substantially free of solvent requiring evaporation in hardening to a solid state, the thin resinous composition capable of impregnating fine interstices, treating the member to harden the thin resinous composition to a solid state, stripping the cup-like shell from the member and coating the entire outer surface of the member with a protective weather-resisting composition.

7. In the process of encapsulating an electrical member, the steps of treating the surface of the electrical member with a resinous composition to provide an incomplete envelope attached to the outer surface of the electrical member, impregnating the electrical member with a fluid insulating composition to fill the envelope, and to remove air and moisture and to fill the interstices in the electrical member and then applying a resinous composition to cover the surface of the member to provide for completely sealing the envelope.

CHARLES F. HILL. NEWTON C. FOSTER.

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