[go: up one dir, main page]

US20140193633A1 - Non-transparent art paper which prevents ink seepage - Google Patents

Non-transparent art paper which prevents ink seepage Download PDF

Info

Publication number
US20140193633A1
US20140193633A1 US13/919,355 US201313919355A US2014193633A1 US 20140193633 A1 US20140193633 A1 US 20140193633A1 US 201313919355 A US201313919355 A US 201313919355A US 2014193633 A1 US2014193633 A1 US 2014193633A1
Authority
US
United States
Prior art keywords
paper
sketch paper
sketch
styrene
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/919,355
Other languages
English (en)
Inventor
Ricardo MILLARES-NEYRA
Ricardo Millares-Sotres
Dalila Rivera-Carmona
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of US20140193633A1 publication Critical patent/US20140193633A1/en
Priority to US15/727,383 priority Critical patent/US10864703B2/en
Abandoned legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/002Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/002Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B29/005Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/06Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/12Coating on the layer surface on paper layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/28Multiple coating on one surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/028Paper layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/406Bright, glossy, shiny surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/41Opaque
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/728Hydrophilic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2554/00Paper of special types, e.g. banknotes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/256Heavy metal or aluminum or compound thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/258Alkali metal or alkaline earth metal or compound thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/259Silicic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31511Of epoxy ether
    • Y10T428/31515As intermediate layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31663As siloxane, silicone or silane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • Y10T428/3179Next to cellulosic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/3188Next to cellulosic
    • Y10T428/31895Paper or wood
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/3188Next to cellulosic
    • Y10T428/31895Paper or wood
    • Y10T428/31899Addition polymer of hydrocarbon[s] only
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/3188Next to cellulosic
    • Y10T428/31895Paper or wood
    • Y10T428/31899Addition polymer of hydrocarbon[s] only
    • Y10T428/31902Monoethylenically unsaturated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31971Of carbohydrate
    • Y10T428/31993Of paper

Definitions

  • the present invention refers to paper for sketches, art tracing, and graphic design applications, such paper being manufactured based on a lamination of at least two sheets of bond paper with at least one layer of intermediate emulsion with pigments which are non-transparent and waterproof to the passing of the ink.
  • the paper produced in this way is non-transparent and prevents the seepage of inks and liquid materials, favors the drying of the inks, averts the running of the inks and accepts without problem the application of dry materials for drawings and sketches.
  • pens with water-based ink, solvent base ink, gel inks, Chinese ink, oil-based ink and other black and varied-colored inks; water colors; inks for other drawing, sketching and writing instruments; ball-point pens; and dry materials such as carbon, charcoal, pastel colors, chalks, carbon pencil, graphite of different hardness, colored pencils, materials with a wax-base and other dry materials.
  • a sketch paper is described for art and design applications, which allows the use of drawing, design or painting materials without fluid materials or inks seeping through to the other side of the paper. It possesses an optimal texture for drawing with solid materials.
  • the paper is non-transparent, thus what is drawn on one side is not seen on the other side of the paper, allowing for the use of both sides of the paper.
  • the present disclosure describes both the sketch paper itself and methods for creating it.
  • the sketch paper of the present invention is suitable for drawing sketches with felt-tipped pens or markers, as well as water or solvent-based ink pens, gel inks, Chinese ink, oil-based inks, ball point pens, other inks, without the ink seeping through to the other side of the paper. It also prevents the image from being visible from one side of the paper to the other, i.e. the sketch paper is not transparent. With these properties sketches may be made on both sides of each sheet.
  • the sketch paper also facilitates drying of the ink due to its absorbent qualities. Due to its texture and surface finish it permits sketching with dry materials, including charcoal, pastel colors, chalks, graphite and colored pencils, materials with a wax base and other dry materials.
  • the sketch paper according to the present disclosure also permits the application of commonly-used fixatives for some dry materials. It possesses the novel property that liquid or dry materials are dried or cured and not transferred to adjacent papers.
  • the opacity of the sketch paper according to the present disclosure is generally between 88% and 99.5% TAPPI (Technical Association for the Pulp and Paper Industry) T-425 and, in certain embodiments, between 90% and 99.5% TAPPI T-425, and it has a minimum brightness of 90% TAPPI T-425.
  • TAPPI Technical Association for the Pulp and Paper Industry
  • the sketch paper according to the present disclosure may comprise at least two base sheets of bond paper, which may be laminated together.
  • the sketch paper may further comprise at least one intermediate layer of an emulsion containing non-transparent pigments, creating a waterproof barrier against migration of the inks and their solvents or vehicles.
  • a sketch paper according to the present disclosure may have a minimum brightness of 90 on the TAPPI scale of brightness; may be acid-free and sulfites free; may have a high virgin alpha-cellulose fiber content above or equivalent to 78%; may possess a Gurley Hill porosity of 20-10 Sec/100 cc air suitable for receiving all kinds of inks such as water-base, solvent-base, gel, oils, or having mixed diluents which may be applied with felt-tipped pens, markers, pens, paint brushes, brushes, stylographic pens or other sketching, writing, painting or drawing instruments, this porosity ensuring that these inks dry well without allowing the lines and figures made thereon to run or blur; which may have a suitable finish or texture to fully accept the application of dry drawing and art materials such as carbon, charcoal, pastel colors, chalks, carbon pencils, graphite of different hardness, colored pencils, materials based on waxes and other dry materials; and which may even accept renderings based on watercolor and gouache.
  • a sketch paper according to the present disclosure may achieve the unique result of allowing a suitable degree of ink absorption so as to provide fast and complete drying, preventing smears or running, while simultaneously providing a surface texture to which dry materials can be efficiently applied. This feature makes it novel as it facilitates the use of mixed techniques.
  • a sketch paper may comprise at least two base sheets of bond paper of the same type and same weight of 68 g/m 2 , which are laminated together.
  • a sketch paper according to this embodiment of the present disclosure may further comprise at least one intermediate layer inserted between the two base sheets.
  • such intermediate layer may be an aqueous emulsion of opacifier components, such aqueous emulsion comprising: at least one chemical opacifier compound selected from among the pigments of carbon black, rutile titanium dioxide, anatase titanium dioxide, calcium carbonate, kaolin with laminar structure, calcined kaolin, white polymers, organic pigments, inorganic pigments; one or more adhesives; at least one styrene emulsion selected from among butadiene, acrylic emulsion, acetylated starch, oxidized starch and other compounds such as low viscosity highly hydrolyzed polyvinyl alcohols; and one or more viscosity and surface tension control agents to provide stability to the selected emulsion, such as acrylic polymers and non-ionic surfactants, selected from among the materials commercially known as the surfynoles family
  • the sketch paper may further comprise one or more additional intermediate layers inserted between the two base sheets, such additional intermediate layers comprising one or more additional emulsions.
  • emulsion or emulsions may be applied by impregnating equipment, and their thicknesses may be calculated by the use of jets or sprinklers, bound rods, scrapers, air blades or any other suitable means used in the state of the art. It will be understood by one having ordinary skill in the art that reference is made to these methods only as a means to accomplish the methods according to the present disclosure and do not represent the invention itself.
  • the sketch paper may comprise one or more synthetic and/or natural resins which may be placed on the inside of each base sheet, i.e., the face of each base sheet which is to be laminated to the other base sheet, to prevent ink bleeding and to preserve fine lines and sketches in larger areas.
  • the sketch paper may further comprise one or more synthetic and/or natural resins placed on the outside face of each base sheet (to remain after lamination) to provide additional protection against ink bleeding and the blurring of fine lines, etc.
  • At least two sheets of greater weight may be used, such as 80 g/m 2 , 90 g/m 2 and up to 100 g/m 2 In still other embodiments, sheets of even higher weights may be used.
  • the two base sheets may have different finishes or textures on the outside face to optimize their application for dry drawing materials, which may be achieved by covering the outside faces of one or both of the base sheets with one or more kaolins, adhesives or other additives.
  • the two base sheets may be impregnated, prior to lamination, with a cationic wet strength additive together with carboxylated polyvinyl alcohols to provide a protective barrier.
  • Suitable cationic polymers include polymers of polyamine-epichlorohydrine resin.
  • Suitable commercially available resins include KYMENE 718 and POLYCUP LX manufactured by Hercules Inc, now part of Ashland Inc.
  • the sketch paper may further comprise an intermediate layer of paper placed between the two base sheets, wherein this intermediate paper layer may be coated on one or both sides by resins, and wherein at least one resin is selected from the group of polyolefins, polyethylene, polypropylene, styrene acrylic resins, polyester resins or other polymers as well as waxes and silicones.
  • resins such embodiments may be particularly useful for applications in which the user wishes to apply amounts of ink which would saturate, or almost saturate, the sketch paper with fluid water- or oil- or solvent-based inks
  • At least one of the base sheets is applied with an aqueous emulsion using any suitable system used in the art for impregnating or covering base papers such as, but not limited to, air blade or color-dispensing bound rod, calibrated spray jets, rotogravure roller, or scraper.
  • any suitable system used in the art for impregnating or covering base papers such as, but not limited to, air blade or color-dispensing bound rod, calibrated spray jets, rotogravure roller, or scraper.
  • Table I depicts exemplary implementations of the first three embodiments described above.
  • the aqueous emulsion was applied, and its thickness calibrated, using a color dispensing bound rod to give a dry thickness of between 3 and 8 grams per square meter (gsm) and, more specifically, of 4 to 5 g/m 2 .
  • the opacity of the sketch paper is achieved by using an aqueous emulsion with one or more white pigments having a high refraction index.
  • White pigments such as kaolins, calcined kaolins, calcium carbonate, synthetic polymers and titanium dioxide, due to their optic properties, are substances with a higher level of refraction (2.4, as a diamond). Even when pulverized or mixed with other loads, the average size of an 0.5 micron particle pigment provides a greater covering power and for this same reason is very opaque.
  • the calcined kaolins are also an alternative to provide opacity due to the laminar form of the particles and because of the small particle size of onlyl to 2 microns also contributes to ink absorption.
  • Table II shows exemplary implementations of the fourth embodiment according to the present disclosure, wherein the two base sheets may be impregnated, prior to lamination, with a solution of insolubilizing agents that absorb to the paper fibers, together with carboxylated polyvinyl alcohols to provide a protective barrier.
  • base sheets having a porosity of between 20 and 10 sec/100 ml Gurley Hill may be used with previous priming in the paper machine. This may provide sufficient absorption to be receptive to the inks or emulsions.
  • an aqueous emulsion containing white loads and an adhesive as described with respect to the embodiments shown in Table I, may be applied to the first base sheet by means of a rotogravure system.
  • An emulsion promoting adhesion may be applied to the second base sheet.
  • the two base sheets may be laminated together by means of a mechanism operated by steel cylinders.
  • Table III shows exemplary implementations of the fifth embodiment according to the present disclosure, wherein the sketch paper further comprises an intermediate layer of paper placed between the two base sheets, and wherein this intermediate paper layer is coated on one or both sides by resins.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)
  • Laminated Bodies (AREA)
US13/919,355 2013-01-10 2013-06-17 Non-transparent art paper which prevents ink seepage Abandoned US20140193633A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US15/727,383 US10864703B2 (en) 2013-01-10 2017-10-06 Non-transparent art paper which prevents seepage

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
MX2013000399A MX357920B (es) 2013-01-10 2013-01-10 Papel de arte no transparente para bocetos que impide que las tintas transminen.
MXMX/A/2013/000399 2013-01-10

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US15/727,383 Continuation US10864703B2 (en) 2013-01-10 2017-10-06 Non-transparent art paper which prevents seepage

Publications (1)

Publication Number Publication Date
US20140193633A1 true US20140193633A1 (en) 2014-07-10

Family

ID=51061165

Family Applications (2)

Application Number Title Priority Date Filing Date
US13/919,355 Abandoned US20140193633A1 (en) 2013-01-10 2013-06-17 Non-transparent art paper which prevents ink seepage
US15/727,383 Active 2033-12-27 US10864703B2 (en) 2013-01-10 2017-10-06 Non-transparent art paper which prevents seepage

Family Applications After (1)

Application Number Title Priority Date Filing Date
US15/727,383 Active 2033-12-27 US10864703B2 (en) 2013-01-10 2017-10-06 Non-transparent art paper which prevents seepage

Country Status (2)

Country Link
US (2) US20140193633A1 (es)
MX (1) MX357920B (es)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3028210A1 (fr) * 2014-11-07 2016-05-13 Canson Support plan a deux faces pour l'ecriture ou le dessin
FR3037275A1 (fr) * 2015-06-09 2016-12-16 Canson Support plan a deux faces pour l'ecriture ou le dessin a la main
CN109674375A (zh) * 2018-12-06 2019-04-26 何纲 一种带清凉提神效果的生活用纸
US10864703B2 (en) * 2013-01-10 2020-12-15 Ricardo MILLARES-NEYRA Non-transparent art paper which prevents seepage

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014186953A1 (en) * 2013-05-22 2014-11-27 Dow Global Technologies Llc Paper composition and process for making the same

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4731291A (en) * 1985-12-10 1988-03-15 Felix Schoeller, Jr. Gmbh & Co. Kg Water-resistant photographic paper support
US4734336A (en) * 1986-10-02 1988-03-29 Xerox Corporation Twin ply papers for ink jet processes
US5180624A (en) * 1987-09-21 1993-01-19 Jujo Paper Co., Ltd. Ink jet recording paper
US5401562A (en) * 1992-03-27 1995-03-28 Fuji Photo Film Co., Ltd. Paper material for photosensitive materials and method of producing the same
US5714270A (en) * 1996-03-04 1998-02-03 Xerox Corporation Multifunctional recording sheets
US6103308A (en) * 1998-04-23 2000-08-15 Gencorp Inc. Paper coating lubricant
US6224660B1 (en) * 1998-10-13 2001-05-01 Degussa-Huls Aktiengesellschaft Ink mixture
US6564199B1 (en) * 1999-04-01 2003-05-13 Imerys Pigments, Inc. Kaolin clay pigments, their preparation and use
US20050260428A1 (en) * 2004-05-24 2005-11-24 Song Jay C Gloss coated multifunctional printing paper
WO2011027752A1 (ja) * 2009-09-03 2011-03-10 日本製紙株式会社 感熱記録ラベル
US20110245369A1 (en) * 2008-12-16 2011-10-06 Dow Global Technologies Llc Coating composition, a process of producing a coating composition, a coated article, and a method of making such articles
US20120050440A1 (en) * 2010-08-31 2012-03-01 Fujifilm Corporation Inkjet recording medium

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1988179A (en) 1933-07-21 1935-01-15 Crown Willamette Paper Company Opaque paper
US4028173A (en) 1975-08-15 1977-06-07 P. H. Glatfelter Co. Methods of making combined titanium dioxide and calcium carbonate and opaque paper containing the resulting combination
US5654050A (en) 1996-01-30 1997-08-05 The United States Playing Card Company Laminated playing card
FR2835265B1 (fr) 2002-01-25 2004-07-02 Arjo Wiggins Papiers Couches Feuille couchee ultra opaque et son procede de fabrication
US7608338B2 (en) * 2002-06-13 2009-10-27 International Paper Company High brightness coating compositions and related products
US20050037158A1 (en) * 2003-08-12 2005-02-17 Yaoliang Hong Method of making glossy ink jet media using sub-micron silica coating and calendering process
MX357920B (es) * 2013-01-10 2018-07-31 Rivera Carmona Dalila Papel de arte no transparente para bocetos que impide que las tintas transminen.

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4731291A (en) * 1985-12-10 1988-03-15 Felix Schoeller, Jr. Gmbh & Co. Kg Water-resistant photographic paper support
US4734336A (en) * 1986-10-02 1988-03-29 Xerox Corporation Twin ply papers for ink jet processes
US5180624A (en) * 1987-09-21 1993-01-19 Jujo Paper Co., Ltd. Ink jet recording paper
US5401562A (en) * 1992-03-27 1995-03-28 Fuji Photo Film Co., Ltd. Paper material for photosensitive materials and method of producing the same
US5714270A (en) * 1996-03-04 1998-02-03 Xerox Corporation Multifunctional recording sheets
US6103308A (en) * 1998-04-23 2000-08-15 Gencorp Inc. Paper coating lubricant
US6224660B1 (en) * 1998-10-13 2001-05-01 Degussa-Huls Aktiengesellschaft Ink mixture
US6564199B1 (en) * 1999-04-01 2003-05-13 Imerys Pigments, Inc. Kaolin clay pigments, their preparation and use
US20050260428A1 (en) * 2004-05-24 2005-11-24 Song Jay C Gloss coated multifunctional printing paper
US20110245369A1 (en) * 2008-12-16 2011-10-06 Dow Global Technologies Llc Coating composition, a process of producing a coating composition, a coated article, and a method of making such articles
WO2011027752A1 (ja) * 2009-09-03 2011-03-10 日本製紙株式会社 感熱記録ラベル
US20120208698A1 (en) * 2009-09-03 2012-08-16 Nippon Paper Industries Co., Ltd Thermosensitive recording label
US20120050440A1 (en) * 2010-08-31 2012-03-01 Fujifilm Corporation Inkjet recording medium

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Encyclopedia of Surface and Colloid Science, 2nd Ed., P. Somasundara, ed., Taylor and Francis Group, 2006, pg. 4447. *
Helpful Fact About Paper, Xerox, Sept. 2004, pgs. 11, 49. *
Triton X-100 Technical Data Sheet, Dow Chemical Company *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10864703B2 (en) * 2013-01-10 2020-12-15 Ricardo MILLARES-NEYRA Non-transparent art paper which prevents seepage
FR3028210A1 (fr) * 2014-11-07 2016-05-13 Canson Support plan a deux faces pour l'ecriture ou le dessin
FR3037275A1 (fr) * 2015-06-09 2016-12-16 Canson Support plan a deux faces pour l'ecriture ou le dessin a la main
CN109674375A (zh) * 2018-12-06 2019-04-26 何纲 一种带清凉提神效果的生活用纸

Also Published As

Publication number Publication date
US20180029330A1 (en) 2018-02-01
US10864703B2 (en) 2020-12-15
MX357920B (es) 2018-07-31
MX2013000399A (es) 2014-07-16

Similar Documents

Publication Publication Date Title
US10864703B2 (en) Non-transparent art paper which prevents seepage
EP1820664B1 (en) Water-discoloring drawing toy set
WO2009087789A1 (ja) 水変色性布帛シート
US9630445B2 (en) Wipeable writing surface
JPS59114536A (ja) 写真用印画紙
JP4786564B2 (ja) 水変色性描画玩具及びそれを用いた水変色性描画玩具セット
JP2012206491A (ja) 水筆用紙
EP3606743A1 (en) Coating for recyclable paper
US20050170173A1 (en) Sheet for application of erasable print
US20070167324A1 (en) Erasable paper product
JP2007118198A (ja) 変色性積層体
CA2794365C (en) Paper product with bleed-through resistant and show-through resistant qualities
JP5751926B2 (ja) 水変色性積層体
JP6412792B2 (ja) 光輝性変色体及びそれを用いた光輝性変色体セット
JP5762726B2 (ja) 記録用紙、及び記録用紙の製造方法
JPH0455395B2 (es)
JP2010094971A (ja) 水変色性布帛及びそれを用いた水変色性描画玩具セット
JP2012061670A (ja) インクジェット用葉書
JP2001192617A (ja) 塗料及びその製造方法、並びに化粧紙
US20050100716A1 (en) Watercolor canvas
JP6615393B2 (ja) 変色体及びそれを用いた変色体セット
US20160130766A1 (en) Planar support with two faces for writing or drawing
JP2006346442A (ja) 水変色性パズル及びそれを用いた水変色性パズルセット
CN117488564A (zh) 一种纳米涂层儿童画布及其制备方法
JP2005326870A (ja) 変色性塗り絵及びそれを用いた変色性塗り絵セット

Legal Events

Date Code Title Description
STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION