US20110278162A1 - system for plating a conductive substrate, and a substrate holder for holding a conductive substrate during plating thereof - Google Patents
system for plating a conductive substrate, and a substrate holder for holding a conductive substrate during plating thereof Download PDFInfo
- Publication number
- US20110278162A1 US20110278162A1 US13/129,330 US200813129330A US2011278162A1 US 20110278162 A1 US20110278162 A1 US 20110278162A1 US 200813129330 A US200813129330 A US 200813129330A US 2011278162 A1 US2011278162 A1 US 2011278162A1
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- Prior art keywords
- substrate holder
- substrate
- contact
- conductive
- contact means
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/06—Suspending or supporting devices for articles to be coated
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/005—Contacting devices
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/001—Apparatus specially adapted for electrolytic coating of wafers, e.g. semiconductors or solar cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/002—Cell separation, e.g. membranes, diaphragms
Definitions
- the present invention relates to a substrate holder to be used in an electrolytic plating process. More specifically, the present invention relates to a substrate holder comprising a physically adaptable contact means arranged to provide electrical contact to cavities on the backside of an electrically conductive substrate attached to the substrate holder. A method for arranging a substrate in a substrate holder is also provided.
- Electroplating is used for microelectronics in a wide range of applications such as interconnects, components, waveguides, inductors, contact pads etc.
- a master electrode such as prepared by the present invention, is suitable for applications involving production of micro and nano structures in single or multiple layers, fabrication of PWB (printed wiring boards), PCB (printed circuit boards), MEMS (micro electro mechanical systems), IC (integrated circuit) interconnects, above IC interconnects, sensors, flat panel displays, magnetic and optical storage devices, solar cells and other electronic devices. It can also be used for different types of structures in conductive polymers, structures in semiconductors, structures in metals, and others are possible to produce using this master electrode. Even 3D-structures in silicon, such as by formation of porous silicon, are possible.
- Chemical vapour deposition and physical vapour deposition are processes that may also be used for metallization, but electroplating is often preferred since it is generally cheaper than other metallization processes and it can take place at ambient temperatures and at ambient pressures.
- Electroplating of a work piece takes place in a reactor containing an electrolyte.
- An anode carrying the metal to be plated, is connected to a positive voltage.
- the anode is inert and the metal to be plated comes from the ions in the electrolyte.
- the conductivity of the work piece such as a semiconductor substrate, is generally too low to allow the structures to be plated to be connected through the substrate to backside contacts. Therefore, the structures to be plated first have to be provided with a conductive layer, such as a seed layer. Leads connect the pattern to finger contacts on the front side. The finger contacts are in turn connected to a negative voltage.
- the electroplating step is an electrolytic process where the metal is transferred from the anode, or from the ions in the electrolyte, to the conductive pattern (cathode) by the electrolyte and the applied electric field between the anode and the conductive layer on the work piece, which forms the cathode.
- the work piece is usually made of a non-conductive material.
- the pattern to be plated is located on the front side, it is necessary to apply a voltage to the conductive layer on the front side. Additional leads and contact areas also have to be located on the front side since contacting the pattern directly with electrodes would disturb the plating process in those areas.
- the electrodes are fixed in a few locations close to the periphery of the substrate holder, only to ensure a peripheral contact with the conductive surface of the work piece intended to be plated, placing demands on the layout of the contact areas and leads of the work piece in order to ensure their correct placement in the corresponding locations on the backside of the work piece.
- the substrate holder according to U.S. Pat. No. 6,322,678 is useless for plating ECPR master electrodes, especially master electrodes having insulating material also on the side not intended for plating, since it cannot be assured that the electrodes contact conducting parts of the master electrode.
- the substrate also has to be carefully aligned with the substrate holder's electrodes.
- the electrodes are arranged, such that they are slidable through the substrate holder, thus failing to ensure isolation of the back side of the work piece from electrolyte.
- the present invention seeks to mitigate, alleviate or eliminate one or more of the above-identified deficiencies and to provide an improved substrate holder of the kind referred to.
- a system comprising (i) a conductive substrate, comprising a first and a second conductive side, wherein said first side of the conductive substrate is to be plated; and (ii) a substrate holder, comprising; an attachment means, for attaching the conductive substrate to the substrate holder, such that a first surface of the substrate holder faces the second side of the conductive substrate; and resilient contact means, attached to the first surface of the substrate holder, said resilient contact means being connectable to a first external potential; the second side of the conductive substrate being provided with an insulating material exposing the second side of the conductive substrate, such that at least one contact area is provided; wherein the resilient contact means is in contact with the exposed second side in at least one contact point in said at least one contact area.
- a substrate holder for holding a conductive substrate during plating thereof.
- the substrate holder comprises an attachment means, for attaching the conductive substrate to the substrate holder, such that a first surface of the substrate holder faces the second side of the conductive substrate; and resilient contact means, attached to the first surface of the substrate holder and connectable to at least one external potential.
- FIG. 1 is a cross-sectional view of an electroplating processing chamber
- FIGS. 2A-C illustrate exemplary designs of a conductive substrate for use in conjunction with the present invention
- FIGS. 3A , 3 B, and 4 illustrate embodiments of the substrate holder according to the present invention
- FIG. 5 illustrate loading/unloading embodiments of the substrate holder according to the present invention
- FIG. 6 illustrates aligning embodiments of the substrate holder according to the present invention
- FIG. 7 illustrates electrical contacting embodiments of the substrate holder according to the present invention
- FIG. 8 illustrates electrical contacting embodiments of the substrate holder according to the present invention
- FIG. 9 illustrates an electrical contacting embodiment of the substrate holder according to the present invention.
- FIGS. 10A and 10B illustrate details of an embodiment of the contact elements of the substrate holder according to the present invention
- FIGS. 11A and 11B illustrate details of embodiments of the contact elements of the substrate holder according to the present invention
- FIGS. 12A and 12B illustrate embodiments of the contact means of the substrate holder according to the present invention
- FIGS. 13A and 13B illustrate embodiments of the contact means of the substrate holder according to the present invention.
- FIGS. 14A and 14B illustrate embodiments of the contact means of the substrate holder according to the present invention.
- FIG. 1 illustrated is a cross-sectional overview of an electroplating processing apparatus 100 .
- the drawing is a sketch of the principles of operation of a plating process and is intended to illustrate the role of the substrate holder 101 in such a process.
- a conductive substrate 102 is attached to a substrate holder 101 .
- the conductive substrate 102 may be a wafer of conducting and/or semiconducting materials, for instance a metallic material, or of a doped semiconductor material, such as silicon.
- the conductive substrate 102 may be attached to the substrate holder 101 by an attachment means, sealing off the backside of the substrate from the electrolyte in the electroplating process.
- Such attachment means may for example be a clamping ring 104 .
- the clamping ring 104 may be made of a rigid non-conductive material, such as Teflon.
- said conductive substrate 102 comprises at least partly of a conducting silicon wafer.
- One or several layers or patterns of insulating material may then be arranged on the conductive substrate 102 .
- other conducting materials may be arranged on the conductive substrate 102 .
- one or several layers or patterns of insulating material may be combined with one or several layers or patterns of conducting material to pattern the conductive substrate 102 .
- the substrate holder 101 is made of an insulating material, such as PP (polypropylene), Teflon, or PEEK (polyetheretherketone), and in another embodiment of a conducting material, such as stainless steel.
- the substrate holder 101 is primarily of an insulating material but may comprise one or several conducting parts, different from the contact means described further in the present invention.
- the conductive substrate 102 is patterned with an electrically insulating layer 103 .
- the insulating layer 103 forms raised structures between which cavities are formed. In said cavities conductive surfaces are exposed onto which a metal may be deposited during the electroplating process.
- the bowl 105 is constructed with a reservoir 106 .
- the reservoir 106 is filled with an electrolyte.
- the electrolyte is pumped from an external reservoir (not shown), in a gentle flow, through an anode 107 .
- the anode 107 may be formed as a grating in order not to impede the flow of electrolyte, up towards the conductive substrate 102 , which is submerged below the surface of the electrolyte.
- the electrolyte is made to flow past the conductive surfaces in the cavities formed by the insulating layer 103 .
- a voltage is applied between the anode 107 , which may be single-pieced or segmented, and the backside of the conductive substrate 102 , which exposed conductive surface thereby forms the cathode in the process.
- the voltage may be applied between the anode 107 and the backside of the conductive substrate 102 via the substrate holder 101 , as will be further discussed below.
- Metal ions are released by the anode and are carried by the electrolyte and the applied electric field towards the exposed conductive surfaces where the metal ions are deposited as a plated metal layer.
- the anode is inert and the ions are provided only from the electrolyte. In this embodiment it is preferred to regularly replenish with a fresh ionic electrolyte.
- a permeable membrane (not shown) may be arranged in the bowl between the anode 107 and the substrate holder 101 in order to allow a process using two electrolytes, creating a first compartment in the bowl, wherein the substrate holder 101 is located, and a second compartment, wherein the anode 107 is located.
- the permeable membrane may be permeable to in-organic substances, such as to the metal ions resulting from the dissolution of metal at the anode 107 and water, but impermeable to organic substances, such as brighteners and suppressors.
- the second electrolyte may be injected above the membrane in the first compartment, i.e.
- the membrane may contain brighteners and suppressors. Since the brighteners and suppressors could degrade at the anode 107 it may be important that they are separated from the anode 107 by the membrane. Introducing the permeable membrane between the substrate holder 101 and the anode 107 solves the above-identified problem.
- the electrolyte is made to overflow the bowl 105 , as indicated by arrow 108 , into an external electrolyte-collecting sink 109 .
- the electrolyte may be returned to the external reservoir (not shown) to be recirculated into the process.
- the electrolyte may possibly first pass a control station and/or filter (not shown).
- the electrolyte may also be collected as waste liquid, which means that it will not be returned to the process.
- the process flow selected is chosen based on the requirements of the process in question.
- the substrate holder immerses the substrate in the electrolyte and a metal is deposited by electroplating in the cavities on the front side of the substrate, while keeping the backside sealed off from the electrolyte.
- the substrate holder 101 may be mounted to a piston 110 and an external process control apparatus (not shown). During the whole process the substrate holder 101 may be made to rotate in either direction around the z-axis, as indicated in the FIG. 1 . This ensures uniformity of the plating process with regard to variations in the electric field and in the flow of the electrolyte across the substrate.
- FIG. 1 shows the substrate holder 101 arranged horizontally, but it is equally possible to use the substrate holder 101 for an electroplating apparatus, such as a tilt plater.
- the substrate holder may for example be tilted in the interval of 30° to 60°, such as 45°, with respect to the z-axis.
- Another alternative is to use the substrate holder 101 for an electroplating apparatus, such as a rack plater.
- the substrate holder 101 is immersed substantially vertically in the electrolyte.
- the latter alternative may also allow for multiple substrate holders 101 to be used in parallel simultaneously in the same processing apparatus 100 .
- External conductors and/or air ducts represented by the dashed line 111 , supply power to the electrical contact means (not shown, but being comprised in the substrate holder 101 ) and gas pressure to the substrate holder 101 via the piston 110 , respectively. Due to the rotating movement of the piston, electrical contact to the at least one external power source may need, but not necessarily always, to be established through brush contacts, sliding contacts, or similar frictional contact means as deemed appropriate by a person skilled in the art.
- the purpose of said air ducts is to supply the substrate holder 101 with a gas pressure, e.g. for applications such as the attachment of a substrate 102 to the substrate holder 101 , for the loading/unloading of a substrate 102 into or out of the substrate holder 101 or for actuating the movement of the clamping ring 104 , etc.
- Conductors and/or air ducts 111 may be routed from the piston 110 to an external unit 112 that comprises a collection of devices, such as at least one device selected from the group comprising a power supply, a gas pump, a user interface, such as a computer by which an operator may control the different parts of the apparatus and/or the process.
- an external unit 112 that comprises a collection of devices, such as at least one device selected from the group comprising a power supply, a gas pump, a user interface, such as a computer by which an operator may control the different parts of the apparatus and/or the process.
- the insulating material 103 may be provided on a first portion of the side of the conductive substrate 102 facing the substrate holder.
- the backside insulating layer 103 A may be patterned to divide the backside into one or more contact areas 203 , at a second portion of said side of the conductive substrate 102 .
- the pattern on the backside is usually, but not necessarily always, in the shape of concentric circles or circle segments.
- the area in the middle, i.e. the center of the backside, is usually, but not necessarily always, left exposed to form one contact area.
- the whole backside is left exposed to form a single backside contact area 203 , as further described in relation to FIG. 2C .
- the patterned backside brings about the beneficial technical effect that master electrodes for ECPR, provided with pre-deposited material in cavities on the front side, may be connected to several voltages, from the different contact areas formed on the backside. This results in a possibility to control and assure an even distribution of plating efficiency over the entire master electrode. It is thus convenient to have also the backside patterned.
- the back side of the conductive substrate is provided with an insulating material forming at least one cavity exposing the front side of the conductive substrate, such that the at least one contact area is provided in said cavity.
- the first and the second portions of said back side of the conductive substrate are arranged such that said insulating material forms at least one cavity, wherein said at least one contact area 203 is provided in said cavity.
- At least one contact area 203 covers at least 50% of a diagonal of the backside of the conductive substrate 102 .
- at least 80%, such as at least 95%, of the diagonal of the backside of the conductive substrate 102 may be covered by contact areas 203 .
- this embodiment provides the technical effect that one specific backside pattern may interact with different configurations of contact means 304 , according to below.
- the resistivity of the conductive substrate 102 in a lateral direction may be large enough, or that the lateral spacing between contact areas of different potentials, or between cavities on the front side, may be large enough to yield different potentials in at least two points along a radius on the front side of the conductive substrate 102 .
- the front side insulating layer 103 B is patterned with the layout to be replicated when the substrate is used as a master electrode in an electrochemical pattern replication (ECPR) process.
- the cavities formed by the front side insulating layer 103 B are pre-arranged (in an earlier process) with one or more layers of a substantially inert (in said electrolyte) conductive material 201 , hereafter called electrode layer.
- the electrode layer may be of a material selected from the group comprising Au, Ti, TiW, Cr, Ni, Si, Pd, Pt, Rh, Co and/or alloys or heterogeneous mixtures thereof.
- a metal is deposited on said pre-arranged electrode layer 201 .
- a conductive substrate allows the use of an edge insulating layer 103 C, comprising at least one layer of at least one electrically insulating material, covering the edge of the conductive substrate 102 .
- the purpose of the edge insulating layer 103 C is to provide electrical insulation between the conductive substrate and a target wafer when said conductive substrate is used as a master electrode in an electrochemical pattern replication (ECPR) process.
- Another purpose of the edge insulating layer is to provide an air-tight seal together with the substrate holder 101 and to provide a surface that allows mechanical handling during the process, such as gripping by the substrate holder 101 or gripping by a robotic arm for loading or unloading of the wafer in the substrate holder 101 .
- the edge insulating layer 103 C is also used to form an air-tight seal together with a gasket when the substrate 102 is mounted on the substrate holder 101 during the process, in order to prevent the electrolyte from coming into contact with the backside of the substrate. It is preferable for the edge insulating layer 103 C to cover at least 1 to 10 mm from the edge of the substrate.
- edge insulating layer 103 C is during the use of the substrate 102 as a master electrode in a subsequent ECPR process.
- the edge insulating layer 103 C ensures that the substrate being patterned is not short-circuited along the edge.
- the whole backside is left exposed to form a single backside contact area 203 in a second portion of the side of the conductive substrate facing the substrate holder.
- the front side has been structured and an electrode layer 201 is arranged in the depressions.
- the sidewalls are covered by an insulating layer 103 B.
- the physically adaptable contact means may be any electrical contact means that is electrically insulated from the substrate holder 101 , except from any further described interconnections that are arranged to provide electrical contact between said electrical contact means 304 and any external power supply. Further interconnections may for example be leads passing through or around the substrate holder 101 .
- Such physically adaptable contact means may adapt to—and establish electrical contact with—a structured surface in a vertical direction, while at the same time covering a substantial surface area of a substrate in a lateral direction. Since a subsequent ECPR process requires a certain step height between the surface of the insulating layer (e.g.
- the contact means 304 may for example be physically adaptable by being resilient and attached to the surface of the substrate holder intended to face the backside of the substrate 102 .
- the electrical contact to the external power supply may be assured by leads passing through or around the substrate holder 101 .
- the leads may be integrated with the substrate holder 101 , such that the leads are not movable within the substrate holder. This ensures a good sealing effect between an inner space 306 and the environment surrounding the substrate holder.
- an operator of the present invention may be certain of making contact with any exposed contact areas 203 using the substrate holder 101 , equipped with the physically adaptable contact means 304 , illustrated by the arrows in FIGS. 3A and 3B .
- the arrows are only intended to show the principle of vertical adaptation and lateral coverage.
- the arrows of FIGS. 3A and 3B do not represent any physical device.
- the physically adaptable contact means may connect at the backside of the conductive substrate 102 to at least two contact areas 203 , or two contact points along a distance from the centre of the conductive substrate to the peripheral edge of the conductive substrate. These at least two contact areas 203 may be located along at least one radius. By contacting the backside of the substrate 102 in at least two contact areas 203 along at least one radius the current is distributed more evenly, which allows a higher rate of plating than only one contact area 203 along at least one radius.
- a first portion of the side of the conductive substrate facing the substrate holder is provided with an insulating material 103 A, 103 C, and a second portion of the side of the conductive substrate facing the substrate holder forms at least one contact area 203 ; wherein the resilient contact means 304 is in contact with at least one contact point in said at least one contact area.
- the arrangement of the contact means 304 is patterned, such that several contact points are provided on the front side of the conductive substrate.
- the conductive substrate 102 is normally secured to the substrate holder 101 with a clamping ring 302 .
- the clamping ring can be made of a rigid, insulating and inert material, such as PP (polypropylene), Teflon, PEEK (polyetheretherketone), or a metal or ceramic ring coated with mentioned insulated inert materials.
- PP polypropylene
- PEEK polyetheretherketone
- the clamping ring 302 is mounted by screwing it onto the substrate holder 101 by threaded surfaces on the vertical interface between the clamping ring 302 and the substrate holder 101 .
- the lower part of the clamping ring 302 may be provided with a slanting, low-profile structure 305 .
- the distance d should preferably be in the range of less than 10 mm, such as less than 5 mm, for instance less than 2 mm.
- the clamping ring 302 may have any suitable peripheral or circumferential form, as long as it is adapted for the substrate holder 101 and the substrate 102 , for which the clamping ring is intended.
- the peripheral or circumferential form may be circular, square, rectangular, or polygonal.
- gaskets 303 A-C may be provided. Furthermore, as disclosed above, the contact means 304 may be attached to the surface of the substrate holder 101 , with integrated leads in the substrate holder, said leads connecting the contact means and external power supply, to ensure that no electrolyte leaks to the backside of the substrate.
- the gaskets 303 A-C may be lip seals, double lip seals or o-rings. Gasket 303 A seals the inner space 306 between the substrate holder 101 and the conductive substrate 102 .
- the inner space 306 may be evacuated of air to a pressure ⁇ 1 atm through air ducts in the substrate holder 101 and in the piston 110 (not shown). The underpressure is established to secure the substrate 102 to the substrate holder 101 .
- the substrate 102 to the substrate holder 101 , by mechanically pressing the clamping ring 302 towards the substrate holder 101 .
- This may be accomplished by providing a screw vice action between the substrate holder 101 and the clamping ring 302 , for example by means of a screw/bolt configuration known to the skilled artisan.
- the screw/bolt configuration is then covered by an insulating material after arrangement, to escape electroplating on said configuration, when said configuration is of a conducting material.
- An additional pressure chamber may be provided in the bulk of the substrate holder 101 .
- the underpressure can be provided to the air ducts from an external source, such as a vacuum pump.
- a valve may be arranged between said external source and said air ducts.
- underpressure is continuously provided to the air ducts during processing, to ensure that a desirable underpressure is achieved, even if there are unexpected leaks through any valves or gaskets.
- said valve is open to provide underpressure when loading or unloading the substrate, but closed during the electroplating operation, which can reduce the risk of flowing electrolyte into the vacuum system, in the unexpected event of leaks.
- the underpressure may also be provided through a detachable connector.
- the substrate holder may comprise a check valve for ensuring that the underpressure is maintained.
- the outer space 307 is sealed off from the outside environment by gaskets 303 B and 303 C and from the inner space by gasket 303 A.
- the gas over or underpressure line may be provided with a ball bearing valve, whereby the substrate holder may be rotated without rotating the pressure supplying means.
- the outer space 307 may optionally be increased to a pressure >1 atm, e.g.
- Pressure sensors may also be arranged to monitor the pressures of the inner space 306 and the outer space 307 in order to provide a measured value to the external unit 112 and to warn an operator or to automatically initiate precautionary measures in the case of unforeseen pressure fluctuations. Measures may include automatic correction of the pressure or abortion or pausing of the process.
- the conductive substrate 102 may also be attached to the substrate holder 101 solely by the clamping ring 302 , as described above, in which case also the inner space 306 may be provided with an increased pressure, for instance by using nitrogen gas.
- the nozzles 308 of the air ducts may be shaped as grooves or holes in the front surface of the substrate holder 101 .
- the nozzles 308 may be laid out in patterns of concentric circles or radial lines, or a combination of both. Different pressures may be applied to different nozzles 308 or groups of nozzles 308 of different radial position, i.e. the applied pressure may be equal along concentric circles of the substrate holder 101 .
- FIG. 3B illustrated is a cross-section of an embodiment of present invention wherein the conductive substrate 102 is attached to the substrate holder 101 by underpressure alone.
- Gasket 303 A seals the inner space 306 from the electrolyte.
- an underpressure is established in the inner space 306 .
- the pressure is sufficiently small to bend the conductive substrate 102 towards the substrate holder 101 .
- Electrical contact may thereby be established with a contact means (not shown), such as a conductive plate that covers substantially the whole front side of the substrate holder 101 .
- a contact means such as a conductive plate that covers substantially the whole front side of the substrate holder 101 .
- the backside of the conductive substrate 102 may be left more or less completely exposed.
- underpressure in the inner space 306 may be used together with any contact means described in the present invention, in order to improve the electrical contact between the contact means and the conductive substrate 101 .
- FIG. 4 does not include the clamping ring 302 , but it is equally possible to bend the substrate 102 towards the substrate holder 101 while using the clamping ring 302 .
- FIG. 5 illustrated is a cross-section of another embodiment of the invention.
- the clamping ring 302 and substrate holder 101 may be linked to each other by guiding elements 501 , spaced along the periphery of the ring/holder.
- the clamping ring 302 may thus be lowered to a loading/unloading position or raised to a processing position by an actuator (not shown) such as a linear motor, stepper or rotational motor or by a pneumatic actuator.
- an actuator such as a linear motor, stepper or rotational motor or by a pneumatic actuator.
- the substrate 102 may be loaded/unloaded automatically by a robotic arm (not shown) or manually by an operator.
- a loading operation could be carried out by lifting the substrate 102 into contact with gasket 303 A where attachment is secured by an underpressure that is subsequently established according to the description of FIG. 3A . Dropping the substrate onto gasket 303 B and lifting it into contact with gasket 303 A may also be used to load a substrate 102 .
- the distance between at least two of the guiding elements 501 is greater than the diameter of the substrate 102 in order to facilitate the loading and unloading of the substrate 102 into or out of the substrate holder 101 .
- Another embodiment of the loading/unloading device may be in the form of pressure actuators 502 A and/or 502 B which may be connected to said at least one duct, the pressure actuators being able to hold a conductive substrate by underpressure, said pressure actuators being extendable and retractable to bring the conductive substrate into proximity of or away from the first surface of the substrate holder.
- the pressure actuator 502 A may for example be vacuum pins or vacuum pads, while pressure actuator 502 B for example may be a vacuum chuck.
- the pressure actuators 502 A and/or 502 B may thus be mounted in the front side of the substrate holder 101 .
- the actuators 502 A and/or 502 B are extended to hold the backside of the substrate 102 by vacuum suction.
- the actuators 502 A and/or 502 B are then retracted to bring the substrate 102 into contact with gasket 303 A.
- the actuators 502 A may be arranged in a circle with a maximum internal spacing of 120°, such as when having three actuator vacuum pins 502 A.
- the actuator 502 B such as a vacuum chuck, may be mounted in the center of the substrate holder 101 .
- the actuator 502 B has a diameter that is smaller than the conductive substrate 102 .
- the extension and retraction of the actuators 502 A and 502 B may be by pneumatic means, or by a linear motor, or stepper motor, or a rotational motor (not shown).
- an edge gripper (not shown), such as hooks or an edge grip ring (different from the clamping ring), may be used to grip the edge of the conductive substrate 102 and to pull it against the substrate holder 101 and the gasket 303 A.
- FIG. 6 illustrated is a cross-section of another embodiment of the invention.
- the substrate holder 101 and the clamping ring 302 are here designed with slanted guiding surfaces 601 A and 601 B, respectively.
- the guiding surfaces 601 A and 601 B are used to align the substrate 102 laterally and horizontally with respect to the substrate holder 101 during a loading operation.
- the substrate holder 101 and the clamping ring 302 may still be provided with gaskets 303 A and 303 B, respectively. For the sake of clarity, they have been left out of FIG. 6 .
- the clamping ring 302 depicted in FIG. 6 may for example be attached by screw-fit to the substrate holder 101 , as described above. However, it is equally possible to use the design with guiding elements 501 , as described in conjunction with FIG. 5 .
- physically adaptable contact means 701 means that the device comprises both contact elements 701 A and the interconnection structure 701 B.
- the physically adaptable contact means 701 is here laid out in a star-shaped pattern, with individual contact elements 701 A evenly spaced along interconnection structure 701 B.
- the pattern of the interconnection structure 701 B may be designed as concentric circles or a combination of concentric circles and a star. However, any shape that is able to cover a substantial part of the conductive substrate 102 is within the scope of the present invention.
- the contact elements 701 A are electrically connected in parallel with each other, through the interconnection structure 701 B.
- the contact elements 701 A are then electrically connected in parallel with each other, through the interconnection structure 701 B, to a common potential node 702 .
- the node 702 may, or may not be, located in the center of the substrate holder 101 .
- the node 702 is in turn connected through the piston 110 to at least one external potential (not shown) as described in conjunction with FIG. 1 .
- the potential of the contact elements 701 A it is preferable to keep the potential of the contact elements 701 A, at a certain radius from the center, at a certain level, e.g. to apply voltage in concentric equipotential circles.
- the contact elements 701 A may be designed in a number of different ways without departing from the concept of the invention. It is however preferred that the common and characterizing feature of all designs is that the contact elements 701 A should be flexible/resilient in a vertical direction. Thus enabling establishment of electrical contact with the backside of a conductive substrate 102 , regardless of the structural topography of the substrate surface. Different designs of the contact elements 701 A will be described more closely in conjunction with FIGS. 9 to 13 below.
- FIG. 8 illustrated is another exemplary embodiment of the invention, displaying the front side of the substrate holder 101 and the physically adaptable contact means 701 .
- the device of FIG. 8 differs from the device of 7 A only in that there is a larger contact element 701 C in the center. In all other respects the devices are the same and offer the same alternatives for configuration of electrical connections and layout of the physically adaptable contact means 701 .
- the contact elements 701 A is made of a conductive material and designed like a hook, which is resiliently flexible in a vertical direction.
- the contact element 701 A then makes electrical contact with the backside of the conductive substrate 102 .
- the contact element 701 A which is part of the physically adaptable contact means 701 is electrically connected in parallel to other similar contact elements 701 A through the interconnection structure 701 B, for example as disclosed in FIGS. 7A and 7B .
- the contact element 701 A may then be somewhat compressed, making physical contact with the backside insulating layer 103 A of the conductive substrate 102 .
- the physically adaptable contact means 901 is here laid out in a star-shaped pattern, with individual contact elements 901 A, in the form of a conductive resilient tube, connected to the interconnection structure 901 B.
- the tube may, for instance be made of conductive rubber.
- the pattern of the interconnection structure 901 B and contact elements 901 A may also be designed as concentric circles or a combination of concentric circles and a star. Any shape that is able to cover a substantial part of the conductive substrate 102 is within the scope of the present invention.
- the contact elements 901 A are electrically connected in parallel with each other, through the interconnection structure 901 B, to a common potential node 902 in the center of the substrate holder 101 .
- the node 902 is in turn connected through the piston 110 (not shown) to at least one external power source (not shown), as described in conjunction with FIG. 1 .
- the contact segments may then be connected individually or in groups of at least two contact segments, to different potentials in order to apply different potentials to different parts of the conductive substrate 102 . This may improve the voltage distribution in the conductive substrate which can lead to a more uniform rate of electroplating material on the conductive substrate.
- a more uniform plating rate allows plating more material into depressions of the conductive substrate 102 without overfilling certain areas.
- To avoid overfilling is crucial if the conductive substrate is to be used as a master electrode and is being put in contact with a target wafer substrate in a subsequent ElectroChemical Pattern Replication (ECPR) process, since overfilled material would short circuit the master electrode with said target substrate whereas no ECPR process could be performed. This is especially important when high rates are desirable.
- FIGS. 10A and 10B illustrate the flexibility of the physically adaptable contact means 901 .
- FIG. 10A illustrated is a detailed view of one of the contact elements 901 A, according to one embodiment.
- the depicted exemplary embodiment of contact element 901 A is made of a relatively soft, tube-shaped material, which may be conductive or whose surface may be coated with a conductive, flexible film 1001 .
- the inside 1002 of the contact element 901 A may be hollow or filled with another flexible material.
- FIG. 10A shows how the contact element 901 A makes electrical contact with the backside of the conductive substrate 102 .
- the contact element 901 A, which is part of the physically adaptable contact means 901 is electrically connected in parallel to other similar contact elements 901 A through the interconnection structure 701 B.
- a somewhat compressed contact element 901 A making physical contact with the backside insulating layer 103 A of the conductive substrate 102 .
- the contact element 901 A may in another embodiment be a spring of a conductive material.
- the spring may be laid out in a star pattern as depicted in FIG. 9 , but may also be laid out as concentric circles or as a combination of the two. Any other features of the device in FIG. 9 , 10 A and 10 B are also applicable to said spring.
- FIG. 11A illustrated is another view of an exemplary embodiment of a physically adaptable contact means 1101 .
- Contact elements 1101 A comprise micro bellows 1102 A, which may be inflated or deflated by an actuator such as an external pump unit or other pneumatic actuator (not shown), as required.
- the bellows 1102 A may, for instance, be deflated as the substrate is loaded into the substrate holder 101 and then inflated to establish electrical contact at the contact areas 203 .
- Air conduits 1103 are provided in the substrate holder 101 and connected to the external pneumatic actuator through at least one valve 1104 , via air ducts in the piston 110 (not shown).
- Overpressure or vacuum may in another embodiment be provided to the air conduits through a detachable connector.
- a check valve can be used to maintain the vacuum or pressure.
- the contact elements 1101 A are connected in parallel through the interconnection structure 1101 B. As described previously, in conjunction with FIGS. 7 to 10 , the contact elements 1101 A may also be connected individually or in groups in order to be able to apply different voltages to different contact elements 1101 A or to different groups of contact elements 1101 A.
- FIG. 11B illustrated is another detailed view of an exemplary embodiment of a physically adaptable contact means 1101 .
- the contact elements 1101 A are mounted on resilient springs 1102 B.
- the resilient springs 1102 B are, in a mechanically unstressed state, sufficiently extended to allow the contact elements 1101 A to reach contact areas 203 when a substrate 102 is loaded into the substrate holder 101 .
- the contact elements 1101 A are connected in parallel through the interconnection structure 1101 B.
- the contact elements 1101 A may also be connected individually or in groups in order to be able to apply different voltages to different contact elements 1101 A or to different groups of contact elements 1101 A.
- FIGS. 12A and 12B illustrated is another exemplary embodiment of the physically adaptable contact means 1201 .
- Contact elements 1201 A are mounted on a relatively soft, flexible resilient layer 1202 that is attached to the substrate holder 101 (not shown).
- the resilient layer 1202 is located proximally of the contact elements 1201 A, and the contact elements 1201 A is located distally of the resilient layer 1202 .
- the flexible resilient layer will adapt according to the pressure from the contact elements 1201 A.
- Contact elements 1201 A that make contact with the backside insulating layer 103 A pushed into the flexible resilient layer 1202 , as shown in FIG. 12B .
- Other contact elements 1201 A will reach into the cavities and make contact with the contact areas 203 .
- the contact elements 1201 A may be connected in parallel to a common voltage or may be connected individually, or in groups of at least two contact elements 1201 A, through the flexible resilient layer 1202 , via an interconnection structure (not shown), to at least one external voltage source (not shown).
- a flexible conductive film 1203 may be arranged between the contact elements 1201 A and the conductive substrate 102 , i.e. distally of the contact elements 1201 A.
- the flexible conductive film 1203 then acts as an interface between the contact elements 1201 A and the conductive substrate 102 .
- the conductive film may need to be divided into concentric circles that are electrically insulated from each other.
- the contact element 1301 A is formed as a conductive foil that comprises protruding structures 1303 .
- the structures may for instance be flexibly resilient point-like protrusions or elongated corrugations.
- Such flexible protruding structures may for instance be manufactured in a conductive foil by cutting, corrugating, lasercutting, punching, waterjet cutting or by grinding out the desired structures on the foil.
- the protrusions are either created directly by the shaping process or in a subsequent step where the shaped portions are deformed/bent to protrude from the flat foil.
- the protrusions 1303 that make physical contact with the backside insulating layer 103 A are resiliently deformed to allow other protrusions 1303 to reach into the cavities and establish electrical contact with the contact areas 203 .
- both the rigid conductive layer 1302 and the contact element 1301 A may be divided into concentric circles that are electrically insulated from each other.
- the resulting contact elements 1301 A may then be connected in parallel to a common voltage or may be connected individually, or in groups of at least two contact elements 1301 A, through the rigid conductive layer 1302 , via an interconnection structure (not shown), to at least one external voltage source (not shown).
- FIGS. 14A and 14B illustrated is another exemplary embodiment of the physically adaptable contact means 1401 .
- a relatively soft elastic layer 1402 is applied to the substrate holder 101 (not shown).
- the contact element 1401 A is formed as a flat, compliant and conductive foil, applied distally of said elastic layer 1402 .
- the elastic layer 1402 When the elastic layer 1402 is pressed against the conductive substrate 102 by the substrate holder 101 the elastic layer 1402 will resiliently deform to reach into the cavities formed by the backside insulating layer 103 A, thereby also pressing the compliant contact element 1401 A into electrical contact with the conductive substrate 102 .
- An interconnection structure (not shown) may be arranged on the substrate holder 101 and be connected to the contact element 1401 A through the elastic layer 1402 .
- contact element 1401 A may be divided into concentric circles that are electrically insulated from each other. The resulting contact elements 1401 A may then be connected in parallel to a common voltage or may be connected individually, or in groups of at least two contact elements 1401 A, through the elastic layer 1402 , via an interconnection structure (not shown), to at least one external voltage source (not shown).
- the contact element 1501 A is a thin electrically conductive foil that is fixed to the substrate holder 101 along the periphery by an airtight seal, such as an o-ring, lip-seal or a glued seal, or with a mechanical fixture, such as a clamping ring.
- An overpressure may be established in the volume enclosed between the contact element 1501 A and the substrate holder 101 via nozzles (not shown) in the substrate holder 101 , i.e. proximally of said contact element 1501 A.
- the contact element 1501 A is deformed to reach into the cavities formed by the back side insulating layer 103 A, thereby establishing electrical contact with the conductive substrate 102 .
- FIGS. 15C and 15D illustrated is an alternative embodiment of the device shown in FIGS. 15A and 15B .
- the contact element has been divided into concentric circles that are electrically insulated from each other.
- the resulting contact elements 1501 A may then be connected in parallel to a common voltage or may be connected individually, or in groups of at least two contact elements 1501 A, through the substrate holder 101 , via an interconnection structure (not shown), to at least one external voltage source (not shown), for instance connecting various voltages or currents to different individual or groups of contact elements.
- a trench 1503 may be formed between the circle segments and valves 1502 may be arranged in the trench in order to provide an under-pressure outside the volume enclosed between the contact elements 1501 A and the substrate holder 101 .
- the contacting parts 701 A, 901 A, 1001 , 1101 A, 1201 A, 1203 , 1301 A, 1401 A and 1501 A may be made of a durable, relatively flexible material of high electrical conductivity, that is resistant to chemicals and corrosion, such as a metal selected from Cu, Au, Pt, Pd, Ti or steel, or of metal alloys. They may also be coated with a metal layer or be made of an insulating material that is coated with a metal layer. The coating may be selected from durable and chemically resistant materials, such as Pt, Pd, Ir, Au or mixed conductive oxides.
- the interconnection structure 701 B, 901 B, 1101 B and any interconnection structure of FIGS. 12 , 13 , 14 and 15 may be provided with resistors, particularly variable resistors, and resistance meters, or any other means as deemed appropriate, in order to exercise control over the different voltages applied to different parts of the conductive substrate 102 while only using one external potential. Control of the variable resistors and the display of measured values are linked to the external unit 112 of FIG. 1 .
- interconnection structure 701 B, 901 B, 1101 B and any interconnection structure of FIGS. 12 , 13 , 14 and 15 may also be provided with switches to allow the electrical connection or disconnection of different parts of the contact means.
- Said at least one external power supply or voltage source may have multiple channels for supplying, and/or controlling, different potentials and/or currents to different individual contact means or groups of contact means.
- an additional insulating layer or film which may be patterned, between the substrate holder 101 and the conductive substrate 102 .
- the purpose of such an insulating layer or film is to cover certain exposed contact areas 203 should modifications to the backside insulating layer 103 A be required.
- Said insulating layer may be easily removable or exchangeable in order to easily modify the shape or size of exposed contact areas 203 for different applications, such as for different conductive substrates with different front or back side insulating pattern or conducting material.
- FIGS. 7 to 15 may comprise the air ducts and nozzles 308 , disclosed in FIGS. 1 and 3 to 6 , and the specification related thereto according to above.
- Such air ducts and nozzles may be located behind the layers disclosed in FIGS. 12 to 15 , if these different layers are permeable to air and/or other gases, such as nitrogen. If the layers disclosed in FIGS. 12 to 15 are not permeable to air and/or other gases, such as nitrogen, the different layers may be provided with locally situated channels through the layers, corresponding to the nozzles 308 in the front surface of the substrate holder 101 , whereby pressure or underpressure still may be provided in the inner space 306 , in accordance with the other embodiments described in connection to FIGS. 1 to 6 .
- FIGS. 7 to 15 may comprise the pressure actuators 502 A and 502 B, disclosed in FIG. 5 , and the specification related thereto according to above.
- Such pressure actuators 502 A and 502 B may then run in channels through layers disclosed in FIGS. 12 to 15 , whereby the actuators still may grip the substrate 102 , in accordance with the other embodiments described in connection to FIG. 5 .
- Substrate holders according to embodiments of the present invention may be used for the fabrication and preparation of a master electrode, i.e. an electrode in the form of a conductive substrate on which an insulating layer forms a pattern of cavities, in which cavities the conductive surface of the substrate is exposed.
- a master electrode i.e. an electrode in the form of a conductive substrate on which an insulating layer forms a pattern of cavities, in which cavities the conductive surface of the substrate is exposed.
- the substrate holder immerses the substrate in an electrolyte and a metal is deposited by electroplating in the cavities on the front side of the substrate, while keeping the backside sealed off from the electrolyte.
- ECPR electrochemical pattern replication
- the substrate holder according the invention greatly improves control over the deposition process by allowing the electrical contact means to physically adapt to any pattern layout of the substrate and by allowing exact control of the voltage applied to different parts of the substrate.
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Abstract
A system for plating a conductive substrate is provided. The system comprises a conductive substrate, comprising a first and a second conductive side, wherein said first side of the conductive substrate is to be plated. Furthermore, the system comprises a substrate holder with an attachment means, for attaching the conductive substrate to the substrate holder, such that a first surface of the substrate holder faces the second side of the conductive substrate. The substrate holder also comprises a resilient contact means, attached to the first surface of the substrate holder, said resilient contact means being connectable to a first external potential. The second side of the conductive substrate is provided with an insulating material exposing the second side of the conductive substrate, such that at least one contact area is provided, wherein the resilient contact means is in contact with the exposed second side in said at least one contact area. A substrate holder therefore is also provided.
Description
- The present invention relates to a substrate holder to be used in an electrolytic plating process. More specifically, the present invention relates to a substrate holder comprising a physically adaptable contact means arranged to provide electrical contact to cavities on the backside of an electrically conductive substrate attached to the substrate holder. A method for arranging a substrate in a substrate holder is also provided.
- Electroplating is used for microelectronics in a wide range of applications such as interconnects, components, waveguides, inductors, contact pads etc.
- A master electrode, such as prepared by the present invention, is suitable for applications involving production of micro and nano structures in single or multiple layers, fabrication of PWB (printed wiring boards), PCB (printed circuit boards), MEMS (micro electro mechanical systems), IC (integrated circuit) interconnects, above IC interconnects, sensors, flat panel displays, magnetic and optical storage devices, solar cells and other electronic devices. It can also be used for different types of structures in conductive polymers, structures in semiconductors, structures in metals, and others are possible to produce using this master electrode. Even 3D-structures in silicon, such as by formation of porous silicon, are possible.
- Chemical vapour deposition and physical vapour deposition are processes that may also be used for metallization, but electroplating is often preferred since it is generally cheaper than other metallization processes and it can take place at ambient temperatures and at ambient pressures.
- Electroplating of a work piece takes place in a reactor containing an electrolyte. An anode, carrying the metal to be plated, is connected to a positive voltage. In some cases, the anode is inert and the metal to be plated comes from the ions in the electrolyte. The conductivity of the work piece, such as a semiconductor substrate, is generally too low to allow the structures to be plated to be connected through the substrate to backside contacts. Therefore, the structures to be plated first have to be provided with a conductive layer, such as a seed layer. Leads connect the pattern to finger contacts on the front side. The finger contacts are in turn connected to a negative voltage. The electroplating step is an electrolytic process where the metal is transferred from the anode, or from the ions in the electrolyte, to the conductive pattern (cathode) by the electrolyte and the applied electric field between the anode and the conductive layer on the work piece, which forms the cathode.
- As stated above, the work piece is usually made of a non-conductive material. As the pattern to be plated is located on the front side, it is necessary to apply a voltage to the conductive layer on the front side. Additional leads and contact areas also have to be located on the front side since contacting the pattern directly with electrodes would disturb the plating process in those areas.
- The resulting setup has a number of disadvantages:
-
- Having contact areas on the front side occupies a lot of space that could otherwise be used for the pattern to be plated.
- The contact areas are restricted to the periphery of the work piece in order to occupy as little space as possible.
- The plating process takes place at an accelerated rate proximate the electrodes, resulting in non-uniformity of the metallization. Plating uniformity would be improved if any portion of the work piece could be contacted.
- The finger electrodes applied to the contact areas are submerged in the damaging, such as corrosive, environment of the electrolyte during the process, leading to degraded electrodes.
- Constructing durable electrodes requires complex designs and expensive materials.
- An alternative device and process is described in U.S. Pat. No. 6,322,678, wherein a substrate holder is constructed with electrodes that are applied to contact areas on the backside of a work piece, which contact areas are either connected to leads that reach around the edge of the work piece, or to conducting vias, leading through the substrate. However, U.S. Pat. No. 6,322,678 is still accompanied by the problem of leads and contact areas occupying space on the front side, since these leads and contact areas are impossible to coordinate with the intended plating. Also, the electrodes are fixed in a few locations close to the periphery of the substrate holder, only to ensure a peripheral contact with the conductive surface of the work piece intended to be plated, placing demands on the layout of the contact areas and leads of the work piece in order to ensure their correct placement in the corresponding locations on the backside of the work piece. Also, the substrate holder according to U.S. Pat. No. 6,322,678 is useless for plating ECPR master electrodes, especially master electrodes having insulating material also on the side not intended for plating, since it cannot be assured that the electrodes contact conducting parts of the master electrode. The substrate also has to be carefully aligned with the substrate holder's electrodes. Still further, the electrodes are arranged, such that they are slidable through the substrate holder, thus failing to ensure isolation of the back side of the work piece from electrolyte.
- Accordingly, the present invention seeks to mitigate, alleviate or eliminate one or more of the above-identified deficiencies and to provide an improved substrate holder of the kind referred to.
- For this purpose, in a first aspect, a system is provided. The system comprises (i) a conductive substrate, comprising a first and a second conductive side, wherein said first side of the conductive substrate is to be plated; and (ii) a substrate holder, comprising; an attachment means, for attaching the conductive substrate to the substrate holder, such that a first surface of the substrate holder faces the second side of the conductive substrate; and resilient contact means, attached to the first surface of the substrate holder, said resilient contact means being connectable to a first external potential; the second side of the conductive substrate being provided with an insulating material exposing the second side of the conductive substrate, such that at least one contact area is provided; wherein the resilient contact means is in contact with the exposed second side in at least one contact point in said at least one contact area.
- In another aspect a substrate holder for holding a conductive substrate during plating thereof is provided. The substrate holder comprises an attachment means, for attaching the conductive substrate to the substrate holder, such that a first surface of the substrate holder faces the second side of the conductive substrate; and resilient contact means, attached to the first surface of the substrate holder and connectable to at least one external potential.
- Advantageous features of the invention are defined in the dependent claims.
- These and other aspects, features and advantages of which the invention is capable of will be apparent and elucidated from the following description of embodiments of the present invention, reference being made to the accompanying drawings, in which
-
FIG. 1 is a cross-sectional view of an electroplating processing chamber; -
FIGS. 2A-C illustrate exemplary designs of a conductive substrate for use in conjunction with the present invention; -
FIGS. 3A , 3B, and 4 illustrate embodiments of the substrate holder according to the present invention; -
FIG. 5 illustrate loading/unloading embodiments of the substrate holder according to the present invention; -
FIG. 6 illustrates aligning embodiments of the substrate holder according to the present invention; -
FIG. 7 illustrates electrical contacting embodiments of the substrate holder according to the present invention; -
FIG. 8 illustrates electrical contacting embodiments of the substrate holder according to the present invention; -
FIG. 9 illustrates an electrical contacting embodiment of the substrate holder according to the present invention; -
FIGS. 10A and 10B illustrate details of an embodiment of the contact elements of the substrate holder according to the present invention; -
FIGS. 11A and 11B illustrate details of embodiments of the contact elements of the substrate holder according to the present invention; -
FIGS. 12A and 12B illustrate embodiments of the contact means of the substrate holder according to the present invention; -
FIGS. 13A and 13B illustrate embodiments of the contact means of the substrate holder according to the present invention; and -
FIGS. 14A and 14B illustrate embodiments of the contact means of the substrate holder according to the present invention. - Below, several embodiments of the invention will be described with references to the drawings. These embodiments are described in illustrating purpose in order to enable a skilled person to carry out the invention. However, such embodiments do not limit the invention, but other combinations of the different features are possible within the scope of the invention.
- Referring to
FIG. 1 , illustrated is a cross-sectional overview of anelectroplating processing apparatus 100. The drawing is a sketch of the principles of operation of a plating process and is intended to illustrate the role of thesubstrate holder 101 in such a process. - During an electroplating process according to an embodiment of the invention a
conductive substrate 102 is attached to asubstrate holder 101. Theconductive substrate 102 may be a wafer of conducting and/or semiconducting materials, for instance a metallic material, or of a doped semiconductor material, such as silicon. Theconductive substrate 102 may be attached to thesubstrate holder 101 by an attachment means, sealing off the backside of the substrate from the electrolyte in the electroplating process. Such attachment means may for example be a clampingring 104. Theclamping ring 104 may be made of a rigid non-conductive material, such as Teflon. - In one embodiment said
conductive substrate 102 comprises at least partly of a conducting silicon wafer. - One or several layers or patterns of insulating material may then be arranged on the
conductive substrate 102. Alternatively, other conducting materials may be arranged on theconductive substrate 102. Also, one or several layers or patterns of insulating material may be combined with one or several layers or patterns of conducting material to pattern theconductive substrate 102. - In one embodiment the
substrate holder 101 is made of an insulating material, such as PP (polypropylene), Teflon, or PEEK (polyetheretherketone), and in another embodiment of a conducting material, such as stainless steel. In a yet further embodiment, thesubstrate holder 101 is primarily of an insulating material but may comprise one or several conducting parts, different from the contact means described further in the present invention. Theconductive substrate 102 is patterned with an electrically insulatinglayer 103. The insulatinglayer 103 forms raised structures between which cavities are formed. In said cavities conductive surfaces are exposed onto which a metal may be deposited during the electroplating process. Thebowl 105 is constructed with areservoir 106. During the electroplating process thereservoir 106 is filled with an electrolyte. The electrolyte is pumped from an external reservoir (not shown), in a gentle flow, through ananode 107. Theanode 107 may be formed as a grating in order not to impede the flow of electrolyte, up towards theconductive substrate 102, which is submerged below the surface of the electrolyte. The electrolyte is made to flow past the conductive surfaces in the cavities formed by the insulatinglayer 103. A voltage is applied between theanode 107, which may be single-pieced or segmented, and the backside of theconductive substrate 102, which exposed conductive surface thereby forms the cathode in the process. The voltage may be applied between theanode 107 and the backside of theconductive substrate 102 via thesubstrate holder 101, as will be further discussed below. Metal ions are released by the anode and are carried by the electrolyte and the applied electric field towards the exposed conductive surfaces where the metal ions are deposited as a plated metal layer. - In another embodiment, the anode is inert and the ions are provided only from the electrolyte. In this embodiment it is preferred to regularly replenish with a fresh ionic electrolyte.
- According to another embodiment, a permeable membrane (not shown) may be arranged in the bowl between the
anode 107 and thesubstrate holder 101 in order to allow a process using two electrolytes, creating a first compartment in the bowl, wherein thesubstrate holder 101 is located, and a second compartment, wherein theanode 107 is located. The permeable membrane may be permeable to in-organic substances, such as to the metal ions resulting from the dissolution of metal at theanode 107 and water, but impermeable to organic substances, such as brighteners and suppressors. The second electrolyte may be injected above the membrane in the first compartment, i.e. on the side of the membrane where thesubstrate holder 101 is located, and may contain brighteners and suppressors. Since the brighteners and suppressors could degrade at theanode 107 it may be important that they are separated from theanode 107 by the membrane. Introducing the permeable membrane between thesubstrate holder 101 and theanode 107 solves the above-identified problem. - Having flowed past the substrate, the electrolyte is made to overflow the
bowl 105, as indicated byarrow 108, into an external electrolyte-collectingsink 109. From the sink, the electrolyte may be returned to the external reservoir (not shown) to be recirculated into the process. When recirculated, the electrolyte may possibly first pass a control station and/or filter (not shown). The electrolyte may also be collected as waste liquid, which means that it will not be returned to the process. The process flow selected is chosen based on the requirements of the process in question. - Thus, during the preparation of the master electrode, according to embodiments of the present invention, the substrate holder immerses the substrate in the electrolyte and a metal is deposited by electroplating in the cavities on the front side of the substrate, while keeping the backside sealed off from the electrolyte. According to one embodiment the
substrate holder 101 may be mounted to apiston 110 and an external process control apparatus (not shown). During the whole process thesubstrate holder 101 may be made to rotate in either direction around the z-axis, as indicated in theFIG. 1 . This ensures uniformity of the plating process with regard to variations in the electric field and in the flow of the electrolyte across the substrate. - The embodiment depicted in
FIG. 1 shows thesubstrate holder 101 arranged horizontally, but it is equally possible to use thesubstrate holder 101 for an electroplating apparatus, such as a tilt plater. In a tilt plater the substrate holder may for example be tilted in the interval of 30° to 60°, such as 45°, with respect to the z-axis. Another alternative is to use thesubstrate holder 101 for an electroplating apparatus, such as a rack plater. In a rack plater thesubstrate holder 101 is immersed substantially vertically in the electrolyte. The latter alternative may also allow formultiple substrate holders 101 to be used in parallel simultaneously in thesame processing apparatus 100. - External conductors and/or air ducts, represented by the dashed
line 111, supply power to the electrical contact means (not shown, but being comprised in the substrate holder 101) and gas pressure to thesubstrate holder 101 via thepiston 110, respectively. Due to the rotating movement of the piston, electrical contact to the at least one external power source may need, but not necessarily always, to be established through brush contacts, sliding contacts, or similar frictional contact means as deemed appropriate by a person skilled in the art. - The purpose of said air ducts is to supply the
substrate holder 101 with a gas pressure, e.g. for applications such as the attachment of asubstrate 102 to thesubstrate holder 101, for the loading/unloading of asubstrate 102 into or out of thesubstrate holder 101 or for actuating the movement of theclamping ring 104, etc. - Conductors and/or
air ducts 111 may be routed from thepiston 110 to anexternal unit 112 that comprises a collection of devices, such as at least one device selected from the group comprising a power supply, a gas pump, a user interface, such as a computer by which an operator may control the different parts of the apparatus and/or the process. - Referring to
FIG. 2A-B , illustrated are a number of exemplary embodiments of theconductive substrate 102 and the patterned insulatinglayer 103. The insulatingmaterial 103 may be provided on a first portion of the side of theconductive substrate 102 facing the substrate holder. Thus, thebackside insulating layer 103A may be patterned to divide the backside into one ormore contact areas 203, at a second portion of said side of theconductive substrate 102. The pattern on the backside is usually, but not necessarily always, in the shape of concentric circles or circle segments. The area in the middle, i.e. the center of the backside, is usually, but not necessarily always, left exposed to form one contact area. It is also within the scope of this embodiment that the whole backside is left exposed to form a singlebackside contact area 203, as further described in relation toFIG. 2C . The patterned backside brings about the beneficial technical effect that master electrodes for ECPR, provided with pre-deposited material in cavities on the front side, may be connected to several voltages, from the different contact areas formed on the backside. This results in a possibility to control and assure an even distribution of plating efficiency over the entire master electrode. It is thus convenient to have also the backside patterned. - In an embodiment, the back side of the conductive substrate is provided with an insulating material forming at least one cavity exposing the front side of the conductive substrate, such that the at least one contact area is provided in said cavity. Thus, the first and the second portions of said back side of the conductive substrate are arranged such that said insulating material forms at least one cavity, wherein said at least one
contact area 203 is provided in said cavity. - In one embodiment at least one
contact area 203 covers at least 50% of a diagonal of the backside of theconductive substrate 102. In this respect at least 80%, such as at least 95%, of the diagonal of the backside of theconductive substrate 102 may be covered bycontact areas 203. In this way an even distribution of voltages may be provided, ensuring an even plating height and plating speed on the front side. Also, this embodiment provides the technical effect that one specific backside pattern may interact with different configurations of contact means 304, according to below. - It is to be understood that the resistivity of the
conductive substrate 102 in a lateral direction may be large enough, or that the lateral spacing between contact areas of different potentials, or between cavities on the front side, may be large enough to yield different potentials in at least two points along a radius on the front side of theconductive substrate 102. - The front
side insulating layer 103B is patterned with the layout to be replicated when the substrate is used as a master electrode in an electrochemical pattern replication (ECPR) process. The cavities formed by the frontside insulating layer 103B are pre-arranged (in an earlier process) with one or more layers of a substantially inert (in said electrolyte)conductive material 201, hereafter called electrode layer. The electrode layer may be of a material selected from the group comprising Au, Ti, TiW, Cr, Ni, Si, Pd, Pt, Rh, Co and/or alloys or heterogeneous mixtures thereof. During the electrolytic process, represented by thearrows 202, a metal is deposited on saidpre-arranged electrode layer 201. - A conductive substrate allows the use of an
edge insulating layer 103C, comprising at least one layer of at least one electrically insulating material, covering the edge of theconductive substrate 102. The purpose of theedge insulating layer 103C is to provide electrical insulation between the conductive substrate and a target wafer when said conductive substrate is used as a master electrode in an electrochemical pattern replication (ECPR) process. Another purpose of the edge insulating layer is to provide an air-tight seal together with thesubstrate holder 101 and to provide a surface that allows mechanical handling during the process, such as gripping by thesubstrate holder 101 or gripping by a robotic arm for loading or unloading of the wafer in thesubstrate holder 101. Theedge insulating layer 103C is also used to form an air-tight seal together with a gasket when thesubstrate 102 is mounted on thesubstrate holder 101 during the process, in order to prevent the electrolyte from coming into contact with the backside of the substrate. It is preferable for theedge insulating layer 103C to cover at least 1 to 10 mm from the edge of the substrate. - Another advantage of the
edge insulating layer 103C is during the use of thesubstrate 102 as a master electrode in a subsequent ECPR process. When the master electrode is pressed to a substrate being patterned, theedge insulating layer 103C ensures that the substrate being patterned is not short-circuited along the edge. - Referring to
FIG. 2C , illustrated is another exemplary embodiment of theconductive substrate 102. In this embodiment the whole backside is left exposed to form a singlebackside contact area 203 in a second portion of the side of the conductive substrate facing the substrate holder. The front side has been structured and anelectrode layer 201 is arranged in the depressions. The sidewalls are covered by an insulatinglayer 103B. - Referring to
FIGS. 3A and 3B , illustrated are embodiments of thesubstrate holder 101 and the working principles of the physically adaptable contact means 304 according to the present invention. The physically adaptable contact means may be any electrical contact means that is electrically insulated from thesubstrate holder 101, except from any further described interconnections that are arranged to provide electrical contact between said electrical contact means 304 and any external power supply. Further interconnections may for example be leads passing through or around thesubstrate holder 101. Such physically adaptable contact means may adapt to—and establish electrical contact with—a structured surface in a vertical direction, while at the same time covering a substantial surface area of a substrate in a lateral direction. Since a subsequent ECPR process requires a certain step height between the surface of the insulating layer (e.g. such as theedge insulating layer 103C) and the bottom of the cavities, it also becomes necessary to be able to make good electrical contact to the backside of thesubstrate 102. This is ensured by the use of the physically adaptable contact means 304 of thesubstrate holder 101. The contact means 304 may for example be physically adaptable by being resilient and attached to the surface of the substrate holder intended to face the backside of thesubstrate 102. When the contact means 304 are resilient and attached to the surface of thesubstrate holder 101, the electrical contact to the external power supply may be assured by leads passing through or around thesubstrate holder 101. When the electrical contact to the external power supply is assured by leads passing through thesubstrate holder 101, the leads may be integrated with thesubstrate holder 101, such that the leads are not movable within the substrate holder. This ensures a good sealing effect between aninner space 306 and the environment surrounding the substrate holder. - Regardless of the layout or thickness of a pattern of the insulating
103A, 103C on the backside of thelayer substrate 102, an operator of the present invention may be certain of making contact with any exposedcontact areas 203 using thesubstrate holder 101, equipped with the physically adaptable contact means 304, illustrated by the arrows inFIGS. 3A and 3B . The arrows are only intended to show the principle of vertical adaptation and lateral coverage. The arrows ofFIGS. 3A and 3B do not represent any physical device. - Typically, if not the whole backside is to be contacted, the physically adaptable contact means may connect at the backside of the
conductive substrate 102 to at least twocontact areas 203, or two contact points along a distance from the centre of the conductive substrate to the peripheral edge of the conductive substrate. These at least twocontact areas 203 may be located along at least one radius. By contacting the backside of thesubstrate 102 in at least twocontact areas 203 along at least one radius the current is distributed more evenly, which allows a higher rate of plating than only onecontact area 203 along at least one radius. Thus, a first portion of the side of the conductive substrate facing the substrate holder is provided with an insulating 103A, 103C, and a second portion of the side of the conductive substrate facing the substrate holder forms at least onematerial contact area 203; wherein the resilient contact means 304 is in contact with at least one contact point in said at least one contact area. - In an embodiment the arrangement of the contact means 304 is patterned, such that several contact points are provided on the front side of the conductive substrate.
- Referring to
FIG. 3A , theconductive substrate 102 is normally secured to thesubstrate holder 101 with aclamping ring 302. The clamping ring can be made of a rigid, insulating and inert material, such as PP (polypropylene), Teflon, PEEK (polyetheretherketone), or a metal or ceramic ring coated with mentioned insulated inert materials. InFIG. 3A the clampingring 302 is mounted by screwing it onto thesubstrate holder 101 by threaded surfaces on the vertical interface between the clampingring 302 and thesubstrate holder 101. The lower part of theclamping ring 302 may be provided with a slanting, low-profile structure 305. This design brings about the technical effect that theclamping ring 302 will reduce the disturbance or hindering of the flow of the electrolyte in the vicinity of the front side of thesubstrate 102. The distance d should preferably be in the range of less than 10 mm, such as less than 5 mm, for instance less than 2 mm. - The
clamping ring 302 may have any suitable peripheral or circumferential form, as long as it is adapted for thesubstrate holder 101 and thesubstrate 102, for which the clamping ring is intended. Thus, the peripheral or circumferential form may be circular, square, rectangular, or polygonal. - In order to ensure that no electrolyte leaks to the backside of the substrate,
gaskets 303A-C may be provided. Furthermore, as disclosed above, the contact means 304 may be attached to the surface of thesubstrate holder 101, with integrated leads in the substrate holder, said leads connecting the contact means and external power supply, to ensure that no electrolyte leaks to the backside of the substrate. Thegaskets 303A-C may be lip seals, double lip seals or o-rings.Gasket 303A seals theinner space 306 between thesubstrate holder 101 and theconductive substrate 102. During or before/after operation theinner space 306 may be evacuated of air to a pressure <1 atm through air ducts in thesubstrate holder 101 and in the piston 110 (not shown). The underpressure is established to secure thesubstrate 102 to thesubstrate holder 101. - It is also feasible, according to another embodiment of the present invention, to secure the
substrate 102 to thesubstrate holder 101, by mechanically pressing theclamping ring 302 towards thesubstrate holder 101. This may be accomplished by providing a screw vice action between thesubstrate holder 101 and theclamping ring 302, for example by means of a screw/bolt configuration known to the skilled artisan. Preferably, the screw/bolt configuration is then covered by an insulating material after arrangement, to escape electroplating on said configuration, when said configuration is of a conducting material. - An additional pressure chamber (not shown) may be provided in the bulk of the
substrate holder 101. The purpose of this chamber, which is directly connected by ducts to theinner space 306, is to safeguard the attachment of thesubstrate 102 against unexpected pressure fluctuations, for instance due to leaks in the valves of the duct system (not shown). The underpressure can be provided to the air ducts from an external source, such as a vacuum pump. A valve may be arranged between said external source and said air ducts. In one embodiment, underpressure is continuously provided to the air ducts during processing, to ensure that a desirable underpressure is achieved, even if there are unexpected leaks through any valves or gaskets. In another embodiment, said valve is open to provide underpressure when loading or unloading the substrate, but closed during the electroplating operation, which can reduce the risk of flowing electrolyte into the vacuum system, in the unexpected event of leaks. The underpressure may also be provided through a detachable connector. In this case the substrate holder may comprise a check valve for ensuring that the underpressure is maintained. Theouter space 307 is sealed off from the outside environment by 303B and 303C and from the inner space bygaskets gasket 303A. In one embodiment the gas over or underpressure line may be provided with a ball bearing valve, whereby the substrate holder may be rotated without rotating the pressure supplying means. Theouter space 307 may optionally be increased to a pressure >1 atm, e.g. by introducing compressed air or preferably a substantially inert gas such as nitrogen gas, in order for theouter space 307 to act as an additional safeguard against the electrolyte leaking through 303B and 303C. Pressure sensors (not shown) may also be arranged to monitor the pressures of thegaskets inner space 306 and theouter space 307 in order to provide a measured value to theexternal unit 112 and to warn an operator or to automatically initiate precautionary measures in the case of unforeseen pressure fluctuations. Measures may include automatic correction of the pressure or abortion or pausing of the process. - The
conductive substrate 102 may also be attached to thesubstrate holder 101 solely by theclamping ring 302, as described above, in which case also theinner space 306 may be provided with an increased pressure, for instance by using nitrogen gas. - The
nozzles 308 of the air ducts may be shaped as grooves or holes in the front surface of thesubstrate holder 101. Thenozzles 308 may be laid out in patterns of concentric circles or radial lines, or a combination of both. Different pressures may be applied todifferent nozzles 308 or groups ofnozzles 308 of different radial position, i.e. the applied pressure may be equal along concentric circles of thesubstrate holder 101. - Referring to
FIG. 3B , illustrated is a cross-section of an embodiment of present invention wherein theconductive substrate 102 is attached to thesubstrate holder 101 by underpressure alone.Gasket 303A seals theinner space 306 from the electrolyte. - Referring to
FIG. 4 , illustrated is another embodiment of the invention wherein an underpressure is established in theinner space 306. The pressure is sufficiently small to bend theconductive substrate 102 towards thesubstrate holder 101. Electrical contact may thereby be established with a contact means (not shown), such as a conductive plate that covers substantially the whole front side of thesubstrate holder 101. In this embodiment the backside of theconductive substrate 102 may be left more or less completely exposed. In further embodiments, underpressure in theinner space 306 may be used together with any contact means described in the present invention, in order to improve the electrical contact between the contact means and theconductive substrate 101. -
FIG. 4 does not include theclamping ring 302, but it is equally possible to bend thesubstrate 102 towards thesubstrate holder 101 while using theclamping ring 302. - Referring to
FIG. 5 , illustrated is a cross-section of another embodiment of the invention. Instead of screwing theclamping ring 302 to thesubstrate holder 101, theclamping ring 302 andsubstrate holder 101 may be linked to each other by guidingelements 501, spaced along the periphery of the ring/holder. Theclamping ring 302 may thus be lowered to a loading/unloading position or raised to a processing position by an actuator (not shown) such as a linear motor, stepper or rotational motor or by a pneumatic actuator. In a loading/unloading position thesubstrate 102 may be loaded/unloaded automatically by a robotic arm (not shown) or manually by an operator. A loading operation could be carried out by lifting thesubstrate 102 into contact withgasket 303A where attachment is secured by an underpressure that is subsequently established according to the description ofFIG. 3A . Dropping the substrate ontogasket 303B and lifting it into contact withgasket 303A may also be used to load asubstrate 102. - It is preferred that the distance between at least two of the guiding
elements 501 is greater than the diameter of thesubstrate 102 in order to facilitate the loading and unloading of thesubstrate 102 into or out of thesubstrate holder 101. - Another embodiment of the loading/unloading device may be in the form of
pressure actuators 502A and/or 502B which may be connected to said at least one duct, the pressure actuators being able to hold a conductive substrate by underpressure, said pressure actuators being extendable and retractable to bring the conductive substrate into proximity of or away from the first surface of the substrate holder. Thepressure actuator 502A may for example be vacuum pins or vacuum pads, whilepressure actuator 502B for example may be a vacuum chuck. The pressure actuators 502A and/or 502B may thus be mounted in the front side of thesubstrate holder 101. When thesubstrate 102 is brought into proximity of thesubstrate holder 101, either manually or by a robotic arm, theactuators 502A and/or 502B are extended to hold the backside of thesubstrate 102 by vacuum suction. Theactuators 502A and/or 502B are then retracted to bring thesubstrate 102 into contact withgasket 303A. Theactuators 502A may be arranged in a circle with a maximum internal spacing of 120°, such as when having three actuator vacuum pins 502A. Theactuator 502B, such as a vacuum chuck, may be mounted in the center of thesubstrate holder 101. Theactuator 502B has a diameter that is smaller than theconductive substrate 102. The extension and retraction of the 502A and 502B may be by pneumatic means, or by a linear motor, or stepper motor, or a rotational motor (not shown).actuators - Instead of a
clamping ring 302, an edge gripper (not shown), such as hooks or an edge grip ring (different from the clamping ring), may be used to grip the edge of theconductive substrate 102 and to pull it against thesubstrate holder 101 and thegasket 303A. - Referring to
FIG. 6 , illustrated is a cross-section of another embodiment of the invention. Thesubstrate holder 101 and theclamping ring 302 are here designed with slanted guidingsurfaces 601A and 601B, respectively. The guiding surfaces 601A and 601B are used to align thesubstrate 102 laterally and horizontally with respect to thesubstrate holder 101 during a loading operation. Thesubstrate holder 101 and theclamping ring 302 may still be provided with 303A and 303B, respectively. For the sake of clarity, they have been left out ofgaskets FIG. 6 . - The
clamping ring 302 depicted inFIG. 6 may for example be attached by screw-fit to thesubstrate holder 101, as described above. However, it is equally possible to use the design with guidingelements 501, as described in conjunction withFIG. 5 . - When a
backside insulating layer 103A is used it may be necessary to align the pattern of thebackside insulating layer 103A with the contact means of thesubstrate holder 101 when loading thesubstrate 102 into thesubstrate holder 101. - Referring to
FIG. 7 , illustrated is an exemplary embodiment of the front side of thesubstrate holder 101, and the physically adaptable contact means 701. - In one embodiment physically adaptable contact means 701 means that the device comprises both
contact elements 701A and theinterconnection structure 701B. - The physically adaptable contact means 701 is here laid out in a star-shaped pattern, with
individual contact elements 701A evenly spaced alonginterconnection structure 701B. The pattern of theinterconnection structure 701B may be designed as concentric circles or a combination of concentric circles and a star. However, any shape that is able to cover a substantial part of theconductive substrate 102 is within the scope of the present invention. In the embodiment according toFIG. 7A thecontact elements 701A are electrically connected in parallel with each other, through theinterconnection structure 701B. Thecontact elements 701A are then electrically connected in parallel with each other, through theinterconnection structure 701B, to a commonpotential node 702. Thenode 702 may, or may not be, located in the center of thesubstrate holder 101. Thenode 702 is in turn connected through thepiston 110 to at least one external potential (not shown) as described in conjunction withFIG. 1 . It is equally possible to connect thecontact elements 701A individually, or in groups of at least twocontact elements 701A, to different potentials in order to apply different potentials to different parts of theconductive substrate 102. In such a case it may be necessary to route a number of conductors through thepiston 110 to at least one external power source to provide different potential todifferent contact elements 701A. Usually when applying different potentials to different parts of theconductive substrate 102 it is preferable to keep the potential of thecontact elements 701A, at a certain radius from the center, at a certain level, e.g. to apply voltage in concentric equipotential circles. - The
contact elements 701A may be designed in a number of different ways without departing from the concept of the invention. It is however preferred that the common and characterizing feature of all designs is that thecontact elements 701A should be flexible/resilient in a vertical direction. Thus enabling establishment of electrical contact with the backside of aconductive substrate 102, regardless of the structural topography of the substrate surface. Different designs of thecontact elements 701A will be described more closely in conjunction withFIGS. 9 to 13 below. - Referring to
FIG. 8 , illustrated is another exemplary embodiment of the invention, displaying the front side of thesubstrate holder 101 and the physically adaptable contact means 701. The device ofFIG. 8 differs from the device of 7A only in that there is alarger contact element 701C in the center. In all other respects the devices are the same and offer the same alternatives for configuration of electrical connections and layout of the physically adaptable contact means 701. - In one embodiment the
contact elements 701A is made of a conductive material and designed like a hook, which is resiliently flexible in a vertical direction. Thecontact element 701A then makes electrical contact with the backside of theconductive substrate 102. Thecontact element 701A, which is part of the physically adaptable contact means 701 is electrically connected in parallel to othersimilar contact elements 701A through theinterconnection structure 701B, for example as disclosed inFIGS. 7A and 7B . Thecontact element 701A may then be somewhat compressed, making physical contact with thebackside insulating layer 103A of theconductive substrate 102. - Referring to
FIG. 9 , illustrated is another exemplary embodiment of the front side of thesubstrate holder 101, and the physically adaptable contact means 901. The physically adaptable contact means 901 is here laid out in a star-shaped pattern, withindividual contact elements 901A, in the form of a conductive resilient tube, connected to theinterconnection structure 901B. The tube may, for instance be made of conductive rubber. The pattern of theinterconnection structure 901B andcontact elements 901A may also be designed as concentric circles or a combination of concentric circles and a star. Any shape that is able to cover a substantial part of theconductive substrate 102 is within the scope of the present invention. In this embodiment thecontact elements 901A are electrically connected in parallel with each other, through theinterconnection structure 901B, to a commonpotential node 902 in the center of thesubstrate holder 101. Thenode 902 is in turn connected through the piston 110 (not shown) to at least one external power source (not shown), as described in conjunction withFIG. 1 . It is equally possible to divide thecontact element 901A, along its length, into shorter, contact segments (not shown), electrically insulated from each other. The contact segments may then be connected individually or in groups of at least two contact segments, to different potentials in order to apply different potentials to different parts of theconductive substrate 102. This may improve the voltage distribution in the conductive substrate which can lead to a more uniform rate of electroplating material on the conductive substrate. A more uniform plating rate allows plating more material into depressions of theconductive substrate 102 without overfilling certain areas. To avoid overfilling is crucial if the conductive substrate is to be used as a master electrode and is being put in contact with a target wafer substrate in a subsequent ElectroChemical Pattern Replication (ECPR) process, since overfilled material would short circuit the master electrode with said target substrate whereas no ECPR process could be performed. This is especially important when high rates are desirable. In such a case it may be necessary to route multiple conductors through thepiston 110 to at least one external power source to provide different potentials to different segments. Usually, when applying different potentials to different parts of theconductive substrate 102 it is preferable to keep the potential of the contact segments, at a certain radius from the center, at a certain level, e.g. to apply voltage in concentric equipotential circles. -
FIGS. 10A and 10B illustrate the flexibility of the physically adaptable contact means 901. - Referring to
FIG. 10A , illustrated is a detailed view of one of thecontact elements 901A, according to one embodiment. The depicted exemplary embodiment ofcontact element 901A is made of a relatively soft, tube-shaped material, which may be conductive or whose surface may be coated with a conductive,flexible film 1001. The inside 1002 of thecontact element 901A may be hollow or filled with another flexible material.FIG. 10A shows how thecontact element 901A makes electrical contact with the backside of theconductive substrate 102. Thecontact element 901A, which is part of the physically adaptable contact means 901 is electrically connected in parallel to othersimilar contact elements 901A through theinterconnection structure 701B. - Referring to
FIG. 10B , illustrated is a somewhatcompressed contact element 901A, making physical contact with thebackside insulating layer 103A of theconductive substrate 102. - The
contact element 901A may in another embodiment be a spring of a conductive material. The spring may be laid out in a star pattern as depicted inFIG. 9 , but may also be laid out as concentric circles or as a combination of the two. Any other features of the device inFIG. 9 , 10A and 10B are also applicable to said spring. - Referring to
FIG. 11A , illustrated is another view of an exemplary embodiment of a physically adaptable contact means 1101.Contact elements 1101A comprisemicro bellows 1102A, which may be inflated or deflated by an actuator such as an external pump unit or other pneumatic actuator (not shown), as required. Thebellows 1102A may, for instance, be deflated as the substrate is loaded into thesubstrate holder 101 and then inflated to establish electrical contact at thecontact areas 203.Air conduits 1103 are provided in thesubstrate holder 101 and connected to the external pneumatic actuator through at least onevalve 1104, via air ducts in the piston 110 (not shown). - Overpressure or vacuum may in another embodiment be provided to the air conduits through a detachable connector. In this case a check valve can be used to maintain the vacuum or pressure.
- As shown in the figure, the
contact elements 1101A are connected in parallel through theinterconnection structure 1101B. As described previously, in conjunction withFIGS. 7 to 10 , thecontact elements 1101A may also be connected individually or in groups in order to be able to apply different voltages todifferent contact elements 1101A or to different groups ofcontact elements 1101A. - Instead of bellows it would be equally possible to mount the
contact elements 1101A on a member that is actuated by a linear motor, stepper motor, or rotational motor. - Referring to
FIG. 11B , illustrated is another detailed view of an exemplary embodiment of a physically adaptable contact means 1101. Here, thecontact elements 1101A are mounted onresilient springs 1102B. Theresilient springs 1102B are, in a mechanically unstressed state, sufficiently extended to allow thecontact elements 1101A to reachcontact areas 203 when asubstrate 102 is loaded into thesubstrate holder 101. As shown in the figure, thecontact elements 1101A are connected in parallel through theinterconnection structure 1101B. As described previously, in conjunction withFIGS. 7 to 10 , thecontact elements 1101A may also be connected individually or in groups in order to be able to apply different voltages todifferent contact elements 1101A or to different groups ofcontact elements 1101A. - Referring to
FIGS. 12A and 12B , illustrated is another exemplary embodiment of the physically adaptable contact means 1201.Contact elements 1201A are mounted on a relatively soft, flexibleresilient layer 1202 that is attached to the substrate holder 101 (not shown). Thus, theresilient layer 1202 is located proximally of thecontact elements 1201A, and thecontact elements 1201A is located distally of theresilient layer 1202. When asubstrate 102 is loaded into the substrate holder 101 (not shown) the flexible resilient layer will adapt according to the pressure from thecontact elements 1201A.Contact elements 1201A that make contact with thebackside insulating layer 103A pushed into the flexibleresilient layer 1202, as shown inFIG. 12B .Other contact elements 1201A will reach into the cavities and make contact with thecontact areas 203. - The
contact elements 1201A may be connected in parallel to a common voltage or may be connected individually, or in groups of at least twocontact elements 1201A, through the flexibleresilient layer 1202, via an interconnection structure (not shown), to at least one external voltage source (not shown). - In one embodiment a flexible
conductive film 1203 may be arranged between thecontact elements 1201A and theconductive substrate 102, i.e. distally of thecontact elements 1201A. The flexibleconductive film 1203 then acts as an interface between thecontact elements 1201A and theconductive substrate 102. In case different voltages are required at different parts of theconductive substrate 102, the conductive film may need to be divided into concentric circles that are electrically insulated from each other. - Referring to
FIGS. 13A and 13B , illustrated is another exemplary embodiment of the physically adaptable contact means 1301. A rigidconductive layer 1302 is applied to, and electrically connected with the substrate holder 101 (not shown). Thecontact element 1301A is formed as a conductive foil that comprises protrudingstructures 1303. The structures may for instance be flexibly resilient point-like protrusions or elongated corrugations. Such flexible protruding structures may for instance be manufactured in a conductive foil by cutting, corrugating, lasercutting, punching, waterjet cutting or by grinding out the desired structures on the foil. The protrusions are either created directly by the shaping process or in a subsequent step where the shaped portions are deformed/bent to protrude from the flat foil. - When the
contact element 1301A is pressed against asubstrate 102 that is loaded into the substrate holder 101 (not shown), theprotrusions 1303 that make physical contact with thebackside insulating layer 103A are resiliently deformed to allowother protrusions 1303 to reach into the cavities and establish electrical contact with thecontact areas 203. - In case different voltages are required at different parts of the
conductive substrate 102, both the rigidconductive layer 1302 and thecontact element 1301A may be divided into concentric circles that are electrically insulated from each other. The resultingcontact elements 1301A may then be connected in parallel to a common voltage or may be connected individually, or in groups of at least twocontact elements 1301A, through the rigidconductive layer 1302, via an interconnection structure (not shown), to at least one external voltage source (not shown). - Referring to
FIGS. 14A and 14B , illustrated is another exemplary embodiment of the physically adaptable contact means 1401. A relatively softelastic layer 1402 is applied to the substrate holder 101 (not shown). Thecontact element 1401A is formed as a flat, compliant and conductive foil, applied distally of saidelastic layer 1402. When theelastic layer 1402 is pressed against theconductive substrate 102 by thesubstrate holder 101 theelastic layer 1402 will resiliently deform to reach into the cavities formed by thebackside insulating layer 103A, thereby also pressing thecompliant contact element 1401A into electrical contact with theconductive substrate 102. - An interconnection structure (not shown) may be arranged on the
substrate holder 101 and be connected to thecontact element 1401A through theelastic layer 1402. - In case different voltages are required at different parts of the
conductive substrate 102,contact element 1401A may be divided into concentric circles that are electrically insulated from each other. The resultingcontact elements 1401A may then be connected in parallel to a common voltage or may be connected individually, or in groups of at least twocontact elements 1401A, through theelastic layer 1402, via an interconnection structure (not shown), to at least one external voltage source (not shown). - Referring now to
FIGS. 15A and 15B , illustrated is another exemplary embodiment of the physically adaptable contact means 1501. Thecontact element 1501A is a thin electrically conductive foil that is fixed to thesubstrate holder 101 along the periphery by an airtight seal, such as an o-ring, lip-seal or a glued seal, or with a mechanical fixture, such as a clamping ring. An overpressure may be established in the volume enclosed between thecontact element 1501A and thesubstrate holder 101 via nozzles (not shown) in thesubstrate holder 101, i.e. proximally of saidcontact element 1501A. When thesubstrate holder 101, together with thepressurized contact element 1501A, is subsequently pressed against theconductive substrate 102, thecontact element 1501A is deformed to reach into the cavities formed by the backside insulating layer 103A, thereby establishing electrical contact with theconductive substrate 102. - Referring now to
FIGS. 15C and 15D , illustrated is an alternative embodiment of the device shown inFIGS. 15A and 15B . Here, the contact element has been divided into concentric circles that are electrically insulated from each other. The resultingcontact elements 1501A may then be connected in parallel to a common voltage or may be connected individually, or in groups of at least twocontact elements 1501A, through thesubstrate holder 101, via an interconnection structure (not shown), to at least one external voltage source (not shown), for instance connecting various voltages or currents to different individual or groups of contact elements. Atrench 1503 may be formed between the circle segments andvalves 1502 may be arranged in the trench in order to provide an under-pressure outside the volume enclosed between thecontact elements 1501A and thesubstrate holder 101. Such an under-pressure may be in addition to the overpressure described above. The purpose of the under-pressure is to improve surface adaptability of thecontact element 1501A. The contacting 701A, 901A, 1001, 1101A, 1201A, 1203, 1301A, 1401A and 1501A may be made of a durable, relatively flexible material of high electrical conductivity, that is resistant to chemicals and corrosion, such as a metal selected from Cu, Au, Pt, Pd, Ti or steel, or of metal alloys. They may also be coated with a metal layer or be made of an insulating material that is coated with a metal layer. The coating may be selected from durable and chemically resistant materials, such as Pt, Pd, Ir, Au or mixed conductive oxides.parts - The
701B, 901B, 1101B and any interconnection structure ofinterconnection structure FIGS. 12 , 13, 14 and 15 (not shown) may be provided with resistors, particularly variable resistors, and resistance meters, or any other means as deemed appropriate, in order to exercise control over the different voltages applied to different parts of theconductive substrate 102 while only using one external potential. Control of the variable resistors and the display of measured values are linked to theexternal unit 112 ofFIG. 1 . - The
701B, 901B, 1101B and any interconnection structure ofinterconnection structure FIGS. 12 , 13, 14 and 15 (not shown) may also be provided with switches to allow the electrical connection or disconnection of different parts of the contact means. - Said at least one external power supply or voltage source may have multiple channels for supplying, and/or controlling, different potentials and/or currents to different individual contact means or groups of contact means.
- In any embodiment of the invention it is also possible to introduce an additional insulating layer or film, which may be patterned, between the
substrate holder 101 and theconductive substrate 102. The purpose of such an insulating layer or film is to cover certain exposedcontact areas 203 should modifications to thebackside insulating layer 103A be required. Said insulating layer may be easily removable or exchangeable in order to easily modify the shape or size of exposedcontact areas 203 for different applications, such as for different conductive substrates with different front or back side insulating pattern or conducting material. - The embodiments disclosed in
FIGS. 7 to 15 may comprise the air ducts andnozzles 308, disclosed inFIGS. 1 and 3 to 6, and the specification related thereto according to above. Such air ducts and nozzles may be located behind the layers disclosed inFIGS. 12 to 15 , if these different layers are permeable to air and/or other gases, such as nitrogen. If the layers disclosed inFIGS. 12 to 15 are not permeable to air and/or other gases, such as nitrogen, the different layers may be provided with locally situated channels through the layers, corresponding to thenozzles 308 in the front surface of thesubstrate holder 101, whereby pressure or underpressure still may be provided in theinner space 306, in accordance with the other embodiments described in connection toFIGS. 1 to 6 . - In the same way the embodiments disclosed in
FIGS. 7 to 15 may comprise the 502A and 502B, disclosed inpressure actuators FIG. 5 , and the specification related thereto according to above. 502A and 502B may then run in channels through layers disclosed inSuch pressure actuators FIGS. 12 to 15 , whereby the actuators still may grip thesubstrate 102, in accordance with the other embodiments described in connection toFIG. 5 . - Substrate holders according to embodiments of the present invention may be used for the fabrication and preparation of a master electrode, i.e. an electrode in the form of a conductive substrate on which an insulating layer forms a pattern of cavities, in which cavities the conductive surface of the substrate is exposed. During the preparation of the master electrode the substrate holder immerses the substrate in an electrolyte and a metal is deposited by electroplating in the cavities on the front side of the substrate, while keeping the backside sealed off from the electrolyte. In a subsequent electrochemical pattern replication (ECPR) process the substrate is used as a master electrode to fabricate electronic components, waveguides, etc.
- The substrate holder according the invention greatly improves control over the deposition process by allowing the electrical contact means to physically adapt to any pattern layout of the substrate and by allowing exact control of the voltage applied to different parts of the substrate.
- Although the present invention has been described above with reference to specific illustrative embodiments, it is not intended to be limited to the specific form set forth herein. Rather, the invention is limited only by the accompanying claims and other embodiments than the specific above are equally possible within the scope of these appended claims.
- In the claims, the term “comprises/comprising” does not exclude the presence of other elements or steps. Furthermore, although individually listed, a plurality of means, elements or method steps may be implemented by e.g. a single unit or processor. Additionally, although individual features may be included in different claims, these may possibly advantageously be combined, and the inclusion in different claims does not imply that a combination of features is not feasible and/or advantageous. In addition, singular references do not exclude a plurality. The terms “a”, “an”, “first”, “second” etc do not preclude a plurality. Reference signs in the claims are provided merely as a clarifying example and shall not be construed as limiting the scope of the claims in any way.
Claims (34)
1. A system for plating a conductive substrate, said system comprising:
(i) a conductive substrate, comprising a first and a second conductive side, wherein said first side of the conductive substrate is to be plated; and
(ii) a substrate holder, said substrate holder comprising:
an attachment means, for attaching the conductive substrate to the substrate holder, such that a first surface of the substrate holder faces the second side of the conductive substrate; and
a resilient contact means attached to the first surface of the substrate holder, said resilient contact means being connectable to a first external potential, wherein
a first portion of the second side of the conductive substrate is provided with an insulating material, and a second portion of the second side of the conductive substrate forms at least one contact area; wherein the resilient contact means is in contact with at least one contact point in said at least one contact area.
2. The system according to claim 1 , wherein the first and the second portions of said second side of the conductive substrate are arranged such that said insulating material forms at least one cavity, wherein said at least one contact area is provided in said cavity.
3. The system according claim 1 , wherein an edge insulating layer (103C), comprising at least one layer of at least one electrically insulating material, covers the edge of the conductive substrate (102).
4. The system according to claim 1 , wherein the at least one contact area covers at least 50% of a diagonal of said first side.
5. The system according to claim 1 , wherein the resilient contact means is in contact with said contact area in at least two contact points along a distance from the centre of the conductive substrate to the peripheral edge of the conductive substrate.
6. The system according to claim 1 or 5 , wherein at least one contact area is provided in the centre of the conductive substrate.
7. The system according to claim 1 , wherein the conductive substrate is sealingly attached to the substrate holder, such that electrolyte solution is prohibited from contacting the second side of the conductive substrate.
8. The system according to claim 1 , wherein the insulating material is patterned, such that several contact areas are provided on the second conductive side.
9. The system according to claim 8 , wherein the pattern is in the shape of concentric circles or circle segments.
10. The system according to claim 1 , wherein the arrangement of said contact means is patterned, such that several contact points are provided on the second conductive side.
11. The system according to claim 1 , wherein the attachment means comprises a clamping ring or edge gripper along the periphery of the substrate holder (101), or a pressure providing means and an airtight seal, said airtight seal being located along the periphery of the substrate holder (101).
12. The system according to claim 11 , wherein the clamping ring (302) or edge gripper and the substrate holder (101) are linked to each other by guiding elements (501), spaced along the periphery of the substrate holder (101), said guiding elements (501) being connected to an actuator, said actuator being adapted to lower to a loading/unloading position and/or raise to a processing position.
13. The system according to claim 1 , comprising at least two contact means, wherein a first resilient contact means is connectable to the first external potential, and a second resilient contact means is connectable to a second external potential.
14. A substrate holder for holding a conductive substrate during plating thereof, comprising
an attachment means, for attaching the conductive substrate to the substrate holder, such that a first surface of the substrate holder faces the second side of the conductive substrate; and resilient contact means, attached to the first surface of the substrate holder and connectable to at least one external potential.
15. The substrate holder according to claim 14 , wherein the arrangement of said contact means is patterned, such that several contact points are provided on the second side of the conductive substrate.
16. The substrate holder according to claim 14 , wherein the contact means comprises interconnection structure (701B), distributed on the first surface of the substrate holder, interconnecting resilient contact elements (701A).
17. The substrate holder according to claim 16 , wherein the distribution of the interconnection structure (701B) is in a shape selected from the group consisting of star shape, shape of concentric circles, or a combination of a shape of concentric circles and a star.
18. The substrate holder according to claim 16 , wherein the contact elements (701A) are electrically connected in parallel with each other, through the interconnection structure (701B), to a common potential node (702).
19. The substrate holder according to claim 16 , wherein the contact elements (701A) are flexible/resilient in a direction perpendicular to said first surface.
20. The substrate holder according to claim 14 , comprising at least one duct (111) supplying overpressure or underpressure to the contact means (304) or to the space in between the substrate holder (101) and the conductive substrate or to the space in between the contact means and the substrate holder (101).
21. The substrate holder according to claim 20 , wherein the contact means (304) is movable in the direction perpendicular to said first surface by means of gas pressure supplied in a bellows of said contact means.
22. The substrate holder according to claim 20 , comprising pressure actuators (502A, 502B), connected to said at least one duct, the pressure actuators being able to hold a conductive substrate by underpressure, said pressure actuators being extendable and retractable to bring the conductive substrate into proximity of or away from the first surface of the substrate holder.
23. The substrate holder according to claim 20 , comprising an additional pressure chamber, provided in the bulk of the substrate holder (101), and connected to said duct, said additional pressure chamber being in communication with the contact means (304) or with the space in between the substrate holder (101) and the conductive substrate or with the space in between the contact means and the substrate holder (101).
24. The substrate holder according to claim 14 , wherein the contact means (304) are mounted on a member that is actuated by a linear motor, stepper motor, or rotational motor, such that the contact means (304) is movable in the direction perpendicular to said first surface.
25. The substrate holder according to claim 14 , wherein the contact means (304) comprises hooks, loops, or tubes, flexible/resilient in a direction perpendicular to said first surface.
26. The substrate holder according to claim 14 , wherein the contact means (304) may be attached to the first surface of the substrate holder (101), with at least one integrated lead in the substrate holder (101), said at least one lead connecting the contact means and at least one external potential.
27. The substrate holder according to claim 14 , wherein the contact means (1201), comprises contact elements (1201A) mounted on a flexible resilient layer (1202) attached to the first surface of the substrate holder (101).
28. The substrate holder according to claim 27 , comprising a flexible conductive film (1203), arranged distally of the contact elements (1201A).
29. The substrate holder according to claim 14 , comprising a rigid conducting layer (1302) proximally of the contact means (1301A), said rigid conductive layer (1302) being electrically connected with the substrate holder 101, and wherein the contact means (1301A) is a conductive foil that comprises distally protruding conducting contact structures (1303).
30. The substrate holder according to claim 14 , comprising an elastic layer (1402) applied to the first surface of the substrate holder (101), wherein the contact element (1401A) is a compliant and conductive foil distally of said conductive elastic layer (1402).
31. The substrate holder according to claim 20 , wherein the contact means (1501A) is a thin electrically conductive foil, fixed to the first surface of the substrate holder (101) along the periphery of the substrate holder (101) by an airtight seal, said thin electrically conductive foil establishing a volume in between the first surface of the substrate holder and the thin electrically conductive foil, said volume being connected to at least one first duct.
32. The substrate holder according to claim 31 , wherein the contact means (1501) is divided into concentric circles, electrically insulated from each other.
33. The substrate holder according to claim 32 , wherein a trench (1503) formed between the circle segments, comprises valves (1502), arranged in the trench, said valves being connected to at least one second duct.
34. The substrate holder according to claim 16 , wherein the interconnection structure (701B, 901B, 1101B) is provided with at least one resistor.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2008/009658 WO2010054677A1 (en) | 2008-11-14 | 2008-11-14 | A system for plating a conductive substrate, and a substrate holder for holding a conductive substrate during plating thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20110278162A1 true US20110278162A1 (en) | 2011-11-17 |
Family
ID=40810546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/129,330 Abandoned US20110278162A1 (en) | 2008-11-14 | 2008-11-14 | system for plating a conductive substrate, and a substrate holder for holding a conductive substrate during plating thereof |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20110278162A1 (en) |
| EP (1) | EP2350357B1 (en) |
| JP (1) | JP5469178B2 (en) |
| KR (1) | KR20110088571A (en) |
| CN (1) | CN102257186B (en) |
| DK (1) | DK2350357T3 (en) |
| TW (1) | TWI468552B (en) |
| WO (1) | WO2010054677A1 (en) |
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| US20100288648A1 (en) * | 2009-05-15 | 2010-11-18 | Rolls-Royce Deutschland Ltd & Co Kg | Method and apparatus for etching the surfaces of integrally bladed rotors |
| US20150068918A1 (en) * | 2013-09-11 | 2015-03-12 | Infineon Technologies Ag | Wafer contacting device, and arrangement and method for electrochemical etching of a wafer |
| US20150147883A1 (en) * | 2013-11-22 | 2015-05-28 | Taiwan Semiconductor Manufacturing Company, Ltd. | Post-CMP Cleaning and Apparatus for Performing the Same |
| US20160108541A1 (en) * | 2010-09-23 | 2016-04-21 | Sunpower Corporation | Non-permeable substrate carrier for electroplating |
| US10793967B2 (en) | 2016-07-13 | 2020-10-06 | Ebara Corporation | Substrate holder and plating apparatus using the same |
| US10985006B2 (en) | 2018-03-20 | 2021-04-20 | Toshiba Memory Corporation | Electrolytic plating apparatus |
| US11015261B2 (en) | 2016-03-22 | 2021-05-25 | Ebara Corporation | Substrate holder and plating apparatus |
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| ES2592708T3 (en) * | 2010-07-15 | 2016-12-01 | Luxembourg Institute Of Science And Technology (List) | A contact sheet for the arrangement between a clamp and a master electrode in an ECPR process |
| KR101181983B1 (en) | 2010-08-04 | 2012-09-11 | 삼성전기주식회사 | Jig for electroplating of printed circuit board and method of electro plating using the same |
| JP5750327B2 (en) * | 2010-10-21 | 2015-07-22 | 株式会社荏原製作所 | Plating apparatus, plating processing method, and attitude changing method of substrate holder for plating apparatus |
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| EP3156523B1 (en) * | 2014-06-11 | 2019-03-27 | Shanghai Meishan Iron & steel Co., Ltd. | Continuous electroplating test device simulating different linear speeds of band steel |
| PT3034657T (en) * | 2014-12-19 | 2019-05-31 | Atotech Deutschland Gmbh | SUBSTRATE HOLDER FOR VERTICAL GALVANIC METAL DEPOSITION |
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| CN113882004B (en) * | 2021-10-28 | 2023-04-21 | 京东方科技集团股份有限公司 | Substrate carrier and electrochemical deposition apparatus |
| CN116555868A (en) * | 2023-04-13 | 2023-08-08 | 江西宇宙智能装备有限公司 | Fixture positioning mechanism and method thereof |
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| US20100288648A1 (en) * | 2009-05-15 | 2010-11-18 | Rolls-Royce Deutschland Ltd & Co Kg | Method and apparatus for etching the surfaces of integrally bladed rotors |
| US8980067B2 (en) * | 2009-05-15 | 2015-03-17 | Rolls-Royce Deutschland Ltd & Co Kg | Method and apparatus for etching the surfaces of integrally bladed rotors |
| US20160108541A1 (en) * | 2010-09-23 | 2016-04-21 | Sunpower Corporation | Non-permeable substrate carrier for electroplating |
| US20150068918A1 (en) * | 2013-09-11 | 2015-03-12 | Infineon Technologies Ag | Wafer contacting device, and arrangement and method for electrochemical etching of a wafer |
| US10373839B2 (en) * | 2013-09-11 | 2019-08-06 | Infineon Technologies Ag | Wafer contacting device, and arrangement and method for electrochemical etching of a wafer |
| DE102014113032B4 (en) * | 2013-09-11 | 2021-02-11 | Infineon Technologies Ag | Wafer contacting device and arrangement and method for electrochemical etching of a wafer |
| US20150147883A1 (en) * | 2013-11-22 | 2015-05-28 | Taiwan Semiconductor Manufacturing Company, Ltd. | Post-CMP Cleaning and Apparatus for Performing the Same |
| US11015261B2 (en) | 2016-03-22 | 2021-05-25 | Ebara Corporation | Substrate holder and plating apparatus |
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| US10985006B2 (en) | 2018-03-20 | 2021-04-20 | Toshiba Memory Corporation | Electrolytic plating apparatus |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201020344A (en) | 2010-06-01 |
| TWI468552B (en) | 2015-01-11 |
| EP2350357B1 (en) | 2019-08-21 |
| JP2012508814A (en) | 2012-04-12 |
| CN102257186B (en) | 2014-10-15 |
| JP5469178B2 (en) | 2014-04-09 |
| KR20110088571A (en) | 2011-08-03 |
| WO2010054677A1 (en) | 2010-05-20 |
| EP2350357A1 (en) | 2011-08-03 |
| CN102257186A (en) | 2011-11-23 |
| DK2350357T3 (en) | 2019-11-25 |
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