US20080311305A1

US20080311305A1 - Waterborne epoxy coating composition and method

Info

Publication number: US20080311305A1
Application number: US12/198,805
Authority: US
Inventors: Remi Briand; J. Alisa Duncan; Yves Floriot; Jennifer S. McGreal
Original assignee: Tnemec Co Inc
Current assignee: Tnemec Co Inc
Priority date: 2004-12-20
Filing date: 2008-08-26
Publication date: 2008-12-18
Also published as: US20060135656A1; WO2006068674A2; US7435449B2; CA2591169A1; WO2006068674A3; WO2006068674B1

Abstract

A waterborne coating composition comprising a waterborne epoxy coating with hydraulic cement, which is capable of a thin initial application. The coating composition may be made, stored and transported as a two-part composition, where each part is a pourable liquid. The waterborne epoxy composition cures under normal conditions and adheres to surfaces including masonry, concrete and metal.

Description

RELATED APPLICATIONS

The present application is a continuation and claims priority benefit of an earlier-filed application of the same title, Ser. No. 11/018,644, filed Dec. 20, 2004. The identified earlier-filed application is hereby incorporated by reference into the present application.

FIELD OF THE INVENTION

This invention relates to coating compositions and, more particularly, to waterborne epoxy coating compositions and methods for using such compositions.

BACKGROUND OF THE INVENTION

Epoxy coating compositions are used to treat surfaces to protect against corrosion and other forms of wear and tear caused by use and the environment. The types of surfaces treated include concrete, metal, and other surfaces. Effective coating compositions are prized not only for the quality of protection, but also for easy and efficient transportation, storage, and application. Thus, a good coating composition will not only protect the surface, but also be easy to apply and quick to cure.
The use of epoxy compositions containing volatile organic solvents has fallen out of favor even though these compositions provide exceptional anti-corrosion protection. The organic solvent based compositions are environmentally unfriendly and their use has been curtailed. Solvent free epoxy coatings often require sophisticated, non-standard equipment for application.
Other epoxy coating compositions provide good protection if applied at the recommended thickness. This recommended thickness requires multiple coats and each coat must be cured or set before another coat may be applied. Each additional coat requires additional labor, which increases the cost of application. Other coats may be applied at greater initial thickness, but require more time to set up. Coatings applied at greater initial thicknesses may also introduce flaws caused by voids from evaporation of volatile components during the curing process.
The combination of an epoxy resin and cement in a coating composition has been used previously to create cement compositions suitable for overlaying concrete. For example, prior products include cement based compositions with an epoxy used as “mortars,” “toppings,” or “overlays” to coat Portland cement concrete or metal surfaces. These compositions use a small portion of epoxy to enhance the cement composition and the final compositions are thick like cement and resembles cement. These are generally two-component compositions having a dry-mix component and a wet-mix component which are combined to form the final composition for application to surfaces in thick films, typically greater than about 20 mils. Other compositions have used an epoxy to bind a cement composition.

BRIEF SUMMARY OF THE INVENTION

There is, therefore, provided in the practice of the invention a novel waterborne fluid coating composition, which is epoxy based and includes hydraulic cement, for reduced initial thickness application, and which provides for a quicker application at a reduced cost. The waterborne epoxy coating composition broadly includes an epoxy resin, a hydraulic cement powder, a curing agent and water.
In one embodiment, the coating composition is prepared by mixing two pre-blended liquid components; one component containing a liquid epoxy resin and hydraulic cement powder; and the other component containing an amine-based curing agent and water. The first part may also include additives, such as a non-reactive diluent, a reactive diluent, an organosilicon adhesion promoter, a pigment, hollow spheres, or other materials. The second part may also include additives, such as a cement plasticizer, a non-reactive diluent, a water-based latex resin, a defoamer, a corrosion inhibitor, or other materials.
Accordingly, it is an object of the present invention to provide an improved two-part waterborne epoxy coating providing anti-corrosion protection.

DETAILED DESCRIPTION

The waterborne epoxy composition broadly includes an epoxy resin, cement powder, an amine-based curing agent, and water. The composition may be enhanced with additives, including a non-reactive diluent, a reactive diluent, an organosilicon adhesion promoter, a pigment, hollow spheres, a cement plasticizer, a water-based latex resin, a defoamer, a corrosion inhibitor, or other materials Each element of the general formula will be discussed in detail below, followed by several embodiments of the composition and the method of production and application.
In various embodiments of the invention, the epoxy resin is present in the composition in an amount of about 8.0% to about 23.0% by weight, preferably about 10.0% to about 21.0% by weight, and more preferably about 11.0% to about 19.0% by weight.
The epoxy resin may be liquid, solid or semi-solid. The epoxy resin functions as the curable component of one part of the two-part epoxy coating composition. In one embodiment, the epoxy resin may consist of any one of bisphenol A, bisphenol F, epoxy phenol novolac, epoxy cresol novolac, naphthalene epoxy, or tertiary butyl cathecol epoxy. Another epoxy may be used besides those listed here, although these are preferred. In exemplary embodiments, the epoxy resin is a liquid bisphenol A epoxy resin, including for example, liquid bisphenol A epoxy resin such as Huntsman GY6010, or a water-dispersed bisphenol A epoxy resin such as Resolution EPI-REZ 3510-W-60.
In various embodiments of the invention, hydraulic cement powder is present in the composition in an amount of about 20.0% to about 72.0% by weight, preferably about 28.0% to about 71.0% by weight, and more preferably about 30.0% to about 70.0% by weight.
The hydraulic cement powder may be any type of Portland cement and may also be any color. Portland cement comes in Types I, II, III, IV, and V. The possible colors include white, grey, etc. In another embodiment, the hydraulic cement powder is a mixture of 0.50 to 0.95 weight parts of Portland Cement and 0.05 to 0.50 weight parts pozzolan powder derived from a group comprising fly ash, steel slag, silica fume, or calcined kaolin clay.
In various embodiments of the invention, the curing agent is present in the composition in an amount of about 5.0% to about 21.0% by weight, preferably about 7.0% to about 19.0% by weight, and more preferably about 8.0% to about 18.0% by weight.
The curing agent may be a substantially solvent free, or a water dilutable polyamine having a plurality of N—H linkages capable of reacting with the epoxy resin. The amine-based curing agent may be a polyoxyalkylene polyamine, arylene polyamine, cyclo-aliphatic polyamine, Mannich base, or a blend of two or more of these polyamines. An example of a solvent free amine curing agent used in an embodiment is a polyoxypropylene polyamine such as Huntsman JEFFAMINE D-400. Examples of commercially available water-based amine curing agents useful in the invention include, for example, Cognis WATERPOXY 751, UCB BECKOPOX 613, Huntsman ARADUR 39, Bakelite RUETADUR VE-51, and Air Products ANQUAMINE 287. Preferably, the curing agent is a water soluble polyamine adduct containing a grafted internal reactive surfactant on the backbone, containing primary, secondary and tertiary amine functionality with some free monomeric polyamine, enabling the emulsification of liquid epoxy resin, without addition of external surfactant, and that is miscible with water in all proportions, such as Cognis WATERPOXY 751, as disclosed in U.S. Pat. No. 6,395,806.
The coating compositions of the invention are prepared from a desired amount of epoxy resin such that the weight ratio of epoxy resin to hydraulic cement is in the range of about 0.1:1 to about 1.2:1; the compositions further provide a ratio of about 0.8 to 1.3 equivalents of total epoxy groups to 1.0 equivalent of reactive curing agent amine groups; and 0.2 to 0.9 parts water to 1.0 part hydraulic cement.
A non-reactive diluent may be added to decrease the viscosity of the mixture. Any diluent that does not react with the other elements of the composition and decreases viscosity may be used. In one embodiment, the non-reactive diluent is benzyl alcohol, which not only reduces viscosity, but also speeds the epoxy/amine reaction and helps prevent freezing or crystallization of the coating composition. In another embodiment, the non-reactive diluent is an aromatic hydrocarbon resin, such as Rütgers NOVARES LS 500 for example, which not only reduces viscosity, but also has lower volatility. The non-reactive diluent may be included in either or both components of the composition.
The composition may further include a reactive diluent. The reactive diluent may be an aliphatic, cycloaliphatic, or aromatic epoxy functional diluent. The reactive diluent may be either monofunctional or multifunctional. In one embodiment, the reactive diluent is a C6 to C18 alkyl mono glycidyl ether, and is included at a ratio of about 8 to 26 parts per 100 parts of epoxy resin. One example of a commercial reactive diluent suitable for this composition is Air Products EPODIL 748.
The composition may further include an organosilicon adhesion promoter to enhance the adhesion of the cured composition to the surface being coated. The organosilicon adhesion promoter is included in a ratio of about 0.5 to 2 parts to 100 parts of epoxy resin. In one embodiment, the organosilicon adhesion promoter is γ-glycidoxypropyl-trimethoxy silane.
The composition may further include a water-based latex resin in a ratio of up to about 1.2 parts water-based latex resin to 1.0 part of hydraulic cement. Examples of useful water-based latex resins include, acrylic, styrene-acrylic, styrene butadiene rubber (SBR), polyvinyl acetate (PVA), and ethylene vinyl acetate (EVA) latexes. In one embodiment, the latex resin is an acrylic, styrene-acrylic, or styrene butadiene rubber (SBR) latex. Examples include Rohm & Haas RHOPLEX MC-1834, SYNTHOMER 29Y46 SBR, and Resolution IC-780.
The composition may further include a desired amount of pigment up to about 24.0% in order to achieve the desired coating color. In one embodiment the pigment is titanium dioxide. The pigment may be dispersed in either component of the two-part composition of the invention.
The composition may further include up to about 8.0%, preferably about 1.0% to about 8.0%, by weight hollow spheres as an inert filler. In one embodiment the hollow spheres are hollow micro-spheres having a particle diameter in the range of about 5 to 90 microns and are included in the hydraulic cement containing component of the two-part composition in a ratio of about 1 part hollow spheres to about 3 to 50 parts of hydraulic cement. Examples include 3M SCOTCHLITE K37 Glass Bubbles and CHL A-90 Hollow Ceramic Microspheres.
The composition may further include up to about 0.4% of a cement plasticizer, such as a lignosulfonate salt, for example Lignotech Norlig 24C; up to about 0.55% of a defoamer, such as a non-silicone defoamer, for example BYK-Chemie BYK-011, and/or a silicone defoamer, for example Tego FOAMEX 805; and up to about 2.4% of a corrosion inhibitor, such as Cortec MCI-2000 or W. R. Grace DCI S; all as set forth in the following examples and claims.
Thus, in various embodiments, the composition of the present invention includes some or all of the following components: about 0.06% to about 0.40% by weight of a concrete plasticizer; about 0.15% to about 0.55% by weight of a defoamer; and, about 0.01% to about 2.4% by weight of a corrosion inhibitor.
One embodiment of the waterborne epoxy coating composition is divided into two parts for easy storage and transportation. Part A of this formula is non-aqueous and includes liquid Bisphenol A epoxy resin, reactive diluent, organosilicon adhesion promoter, hydraulic cement, and hollow spheres. Part B is aqueous and includes water-based amine curing agent, water-based latex resin, and defoamer. The two parts are combined in a sprayer to mix the two parts together and then apply the coating composition to a surface, wherein the composition has a weight ratio of epoxy resin to hydraulic cement in the range of about 0.19:1 to about 0.6:1; a ratio of about 0.9 to 1.15 equivalents of total epoxy groups to 1.0 equivalent of reactive curing agent amine groups; and 0.3 to 0.6 parts total water to 1.0 part hydraulic cement.
Another embodiment comprises a non-aqueous Part A including liquid Bisphenol A epoxy resin, reactive diluent, organosilicon adhesion promoter, hydraulic cement, and hollow spheres; and an aqueous Part B including a water-based amine curing agent, water-based latex resin, and defoamer. The two parts are combined in a sprayer to mix the two parts together and then apply the coating composition to a surface, wherein the final composition has a weight ratio of epoxy resin to hydraulic cement is in the range of about 0.25:1 to about 0.5:1; a ratio of about 0.95 to 1.1 equivalents of total epoxy groups to 1.0 equivalent of reactive curing agent amine groups; and 0.4 to 0.6 parts total water to 1.0 part hydraulic cement. Each part is approximately equal in volume and additional water may be added after the two parts are mixed.
Various embodiments of the non-aqueous Part A of the two part composition of the invention broadly comprise some or all of the following components: epoxy resin in an amount of about 10% to about 42% by weight, preferably about 15% to about 33% by weight, and more preferably about 18% to about 27% by weight of said Part A; hydraulic cement powder in an amount of about 46% to about 90% by weight, preferably about 57% to about 84% by weight, and more preferably about 58% to about 80% by weight of said Part A; hollow spheres in an amount of about 1% to about 13% by weight of said Part A; mono glycidyl ether as reactive diluent in an amount of about 1.1% to about 4.8% by weight of said Part A; and an organosilicon adhesion promoter in an amount of about 0.1% to about 0.5% by weight, preferably about 0.2% to about 0.4% by weight of said Part A. Various embodiments of the aqueous Part B of the two part composition of the invention broadly comprise some or all of the following components: at least one curing agent, comprising a water soluble polyamine, in an amount of about 30% to about 60% by weight, preferably about 34% to about 52% by weight of said Part B; concrete plasticizer in an amount of about 0.2% to about 0.6% by weight of said Part B; water-based latex resin in an amount of about 30% to about 50% by weight of said Part B; defoamer in an amount of about 0.5% to about 1.0% by weight of said Part B; and corrosion inhibitor in an amount of about 0.04% to about 18.5% by weight of said Part B. Further exemplary embodiments are set forth in the following examples.
In an alternative embodiment the non-aqueous Part A includes a solvent-free amine curing agent, hydraulic cement and hollow spheres. Part B is aqueous and includes a water-dispersed epoxy resin, and may further contain a water-based latex resin, and defoamer. The two parts are combined in a sprayer to mix the two parts together and then apply the coating composition to a surface, wherein the composition has a weight ratio of epoxy resin to hydraulic cement in the range of about 0.1:1 to about 1.2:1; a ratio of about 0.8 to 1.3 equivalents of total epoxy groups to 1.0 equivalent of reactive curing agent amine groups; and 0.2 to 0.9 parts total water to 1.0 part hydraulic cement.
The embodiments of the waterborne epoxy coating composition may be applied with a brush, roller, or airless sprayer to produce cured coatings with a thickness from about 78% to about 95% of the single coat wet thickness. Exemplary embodiments of the composition applied by airless sprayer produce cured coatings with a thickness from about 90% to about 95% of the single coat wet thickness. Said cured coatings have a thickness of from approximately 2 mils to approximately 15 mils, preferably having a thickness of approximately 4 mils to approximately 12 mils, and more preferably having a thickness of approximately 6 mils to approximately 10 mils. The embodiments of the composition exhibit gel times from about 60 minutes to about 120 minutes and are dry to touch in less than 24 hours.
The embodiments of the composition are more specifically shown in the following examples, wherein it can be seen that the embodiments of the composition are prepared without the use of a separate emulsifier surfactant to stabilize either part of the two part composition or the final blended composition. It is further apparent from the foregoing detailed description and the component ranges from the following examples of embodiments of the composition of the invention that the composition has low volatile organic compound content, generally not more than about 3.3% by weight of the total composition, preferably not more than about 2.2% by weight of the total composition, and more preferably not more than about 2% by weight of total composition, as indicated by the non-reactive diluent (benzyl alcohol) content.


	Examples

1	2	3
Weight %	Weight %	Weight %

Part A Components

Epoxy Resin	Huntsman GY6010	22.29	20.35	23.26
Reactive Diluent	Air Products Epodil 748	2.50	2.29	2.61
Adhesion Promoter	OSi Silquest A-187	0.25	0.23	0.26
Portland Cement	Lehigh Type I	59.43	0	0
	Lefarge Fondu Type V	0	66.43	50.32
Pozzolan	Lefarge NewChem Slag	0	0	16.70
Titanium Dioxide	Huntsman TR-60	9.60	0	0
Hollow Spheres		2.50	7.59	3.27
Non-reactive Diluent	Benzyl Alcohol	3.42	3.12	3.57
Total Part A		100.00	100.00	100.00

Part B Components

Water-based amine curing	Cognis Waterpoxy 751	14.95	25.64	51.87
agent	Anquamine 287	35.33	10.85	0
Titanium Dioxide	Huntsman TR-60		27.82	0
Concrete Super Plasticizer	Lignotech Norlig 24C	0.57	0	0
Latex Emulsion	Synthomer 29Y46 SBR	48.61	0	0
	Rohm & Haas Rhoplex MC-	0	35.28	0
	1834
Non-reactive Diluent	Benzyl Alcohol	0.55	0.40	0
Deionized Water		0	0	29.95
Corrosion Inhibitor	W. R. Grace DCI S	0	0	18.18
Total Part B		100.00	100.00	100.00

Examples

4	5	6	7	8	9	10
Weight %	Weight %	Weight %	Weight %	Weight %	Weight %	Weight %

Part A Components
Epoxy Resin:	13.04	13.45	12.20	14.44	10.55	16.47	8.23
Huntsman GY6010
Reactive Diluent: Air	1.46	1.51	1.37	1.62	1.19	1.85	0.92
Products Epodil 748
Adhesion Promoter:	0.15	0.15	0.14	0.16	0.12	0.19	0.09
OSi Silquest A-187
Portland Cement:	35.82	37.44	38.90	34.12	43.08	26.68	42.67
Lefarge Secar 71 Type V
Pozzolan: Calcined	7.18	3.74	7.78	2.73	10.77	1.33	21.34
Kaolin Imerys
Metastar 450
Hollow Spheres: 3M	2.34	2.42	2.19	2.60	1.90	2.96	1.48
Scotchlite K37
Non-reactive Diluent:	2.00	2.07	1.87	2.22	1.62	2.53	1.26
Benzyl Alcohol
Sub-total	61.99	60.78	64.45	57.9057.89	69.23	52.01	75.99
Part B Components
Water-based amine	16.49	17.01	15.42	18.26	13.35	20.82	10.41
curing agent: Cognis
Waterpoxy 751
Deionized Water	4.74	4.90	4.44	5.26	3.84	5.99	3.00
Latex Emulsion:	16.27	16.78	15.22	18.02	13.17	20.54	10.27
Rohm & Haas
Rhoplex MC-1834
Non-reactive Diluent:	0.18	0.19	0.17	0.20	0.15	0.23	0.12
Benzyl Alcohol
Defoamer: BYK-	0.33	0.34	0.31	0.36	0.26	0.41	0.21
Chemie BYK-011
(non-silicone)
Sub-total	38.01	39.22	35.56	42.10	30.77	47.99	24.01

Examples

11	12	13	14	15	16	17
Weight %	Weight %	Weight %	Weight %	Weight %	Weight %	Weight %

Part A Components
Epoxy Resin: Huntsman	11.48	13.16	11.74	12.82	10.43	14.86	8.53
GY6010
Reactive Diluent: Air	1.29	1.48	1.32	1.44	1.17	1.67	0.96
Products Epodil 748
Adhesion Promoter: OSi	0.13	0.15	0.13	0.14	0.12	0.17	0.10
Silquest A-187
Portland Cement:	32.41	27.48	31.44	29.65	35.75	20.20	36.52
Lefarge Secar 71 Type V
Pozzolan: Fly Ash	6.71	2.75	6.29	2.37	8.94	1.01	18.26
Hollow Spheres: 3M	4.27	4.90	4.37	4.77	3.88	5.53	3.17
Scotchlite K37
Non-reactive Diluent:	1.76	2.02	1.80	1.97	1.60	2.28	1.31
Benzyl Alcohol
Sub-total	58.05	51.93	57.10	53.17	61.89	45.72	68.85
Part B Components
Water-based amine	14.52	16.64	14.85	16.21	13.19	18.79	10.78
curing agent: Cognis
Waterpoxy 751
Deionized Water	1.35	1.55	1.38	1.51	1.23	1.75	1.00
Titanium Dioxide:	11.3	12.95	11.55	12.61	10.26	14.62	8.39
Huntsman TR-60
Latex Emulsion: Rohm	14.33	16.42	14.65	16.00	13.02	18.54	10.64
& Haas Rhoplex MC-
1834
Non-reactive Diluent:	0.16	0.19	0.17	0.18	0.15	0.21	0.12
Benzyl Alcohol
Defoamer: BYK-	0.29	0.33	0.29	0.32	0.26	0.37	0.21
Chemie BYK-011 (non-
silicone)
Sub-total	41.95	48.07	42.90	46.83	38.11	54.28	31.15

Examples

18	19	20	21	22	23	24
Weight %	Weight %	Weight %	Weight %	Weight %	Weight %	Weight %

Part A Components
Epoxy Resin: Huntsman	13.20	13.85	12.62	14.81	10.99	16.76	8.73
GY6010
Reactive Diluent: Air	1.48	1.56	1.42	1.66	1.23	1.88	0.98
Products Epodil 748
Adhesion Promoter: OSi	0.15	0.16	0.14	0.17	0.12	0.19	0.10
Silquest A-187
Portland Cement:	34.91	35.51	37.07	32.24	41.32	25.01	41.05
Lefarge Fondu Type V
Pozzolan: Lefarge	7.00	3.55	7.41	2.58	10.33	1.25	20.53
NewChem Slag
Hollow Spheres: 3M	5.06	5.31	4.83	5.67	4.21	6.42	3.35
Scotchlite K37
Non-reactive Diluent:	2.03	2.13	1.94	2.27	1.69	2.57	1.34
Benzyl Alcohol
Sub-total	63.83	62.05	65.43	59.41	69.89	54.08	76.07
Part B Components
Water-based amine	16.07	16.86	15.36	18.03	13.38	20.40	10.63
curing agent: Cognis
Waterpoxy 751
Deionized Water	3.83	4.02	3.66	4.30	3.19	4.86	2.53
Latex Emulsion:	15.77	16.55	15.08	17.70	13.13	20.02	10.43
Synthomer 29Y46 SBR
Non-reactive Diluent:	0.18	0.19	0.17	0.20	0.15	0.23	0.12
Benzyl Alcohol
Defoamer: BYK-	0.32	0.33	0.30	0.36	0.27	0.40	0.21
Chemie BYK-011 (non-
silicone)
Sub-total	36.17	37.95	34.57	40.59	30.11	45.92	23.93

Examples

25	26	27	28	29	30	31
Weight %	Weight %	Weight %	Weight %	Weight %	Weight %	Weight %

Part A Components
Epoxy Resin: Huntsman	11.81	13.16	12.16	13.92	10.80	15.40	8.82
GY6010
Reactive Diluent: Air	1.33	1.48	1.37	1.56	1.21	1.73	0.99
Products Epodil 748
Adhesion Promoter: OSi	0.13	0.15	0.14	0.16	0.12	0.17	0.10
Silquest A-187
Portland Cement:	33.32	29.83	31.59	26.78	35.90	20.33	36.65
Lefarge Secar 71 White
Type V (Calcium
Aluminate)
Pozzolan: Silica Fume	6.66	2.98	6.32	2.14	8.97	1.02	18.32
Hollow Spheres: 3M	1.81	2.01	1.86	2.13	1.65	2.36	1.35
Scotchlite K37
Non-reactive Diluent:	1.81	2.02	1.87	2.14	1.66	2.37	1.35
Benzyl Alcohol
Sub-total	56.87	51.63	55.30	48.83	60.31	43.37	67.58
Part B Components
Water-based amine	14.93	17.07	15.77	18.05	14.00	19.98	11.44
curing agent: Cognis
Waterpoxy 751
Deionized Water	1.39	0.65	0.61	0.69	0.54	0.77	0.44
Titanium Dioxide:	11.62	13.28	12.27	14.05	10.90	15.55	8.90
Huntsman TR-60
Latex Emulsion: Rohm	14.73	16.84	15.56	17.81	13.82	19.72	11.29
& Haas Rhoplex MC-
1834
Non-reactive Diluent:	0.17	0.19	0.18	0.20	0.16	0.22	0.13
Benzyl Alcohol
Defoamer: BYK-Chemie	0.30	0.34	0.31	0.36	0.28	0.40	0.23
BYK-011 (non-silicone)
Sub-total	43.13	48.37	44.70	51.17	39.69	56.63	32.42

Examples

32	33	34	35	36	37	38
Weight %	Weight %	Weight %	Weight %	Weight %	Weight %	Weight %

Part A Components
Epoxy Resin: Huntsman	13.23	13.65	12.37	14.66	10.70	16.72	8.43
GY6010
Reactive Diluent: Air	1.49	1.53	1.39	1.65	1.20	1.88	0.95
Products Epodil 748
Adhesion Promoter: OSi	0.15	0.15	0.14	0.16	0.12	0.19	0.09
Silquest A-187
Portland Cement:	35.89	37.53	38.98	34.20	43.16	26.75	42.49
Federal Type I
Pozzolan: Calcined	7.20	3.75	7.80	2.74	10.79	1.34	21.25
Kaolin Imerys Metastar
450
Hollow Spheres: 3M	1.93	1.99	1.80	2.13	1.56	2.43	1.23
Scotchlite K37
Non-reactive Diluent:	2.03	2.10	1.90	2.25	1.64	2.57	1.29
Benzyl Alcohol
Sub-total	61.921	60.70	64.38	57.79	69.18	51.87	75.73
Part B Components
Water-based amine	16.52	17.05	15.45	18.31	13.37	20.88	10.53
curing agent: Cognis
Waterpoxy 751
Deionized Water	4.76	4.91	4.45	5.27	3.85	6.01	3.03
Latex Emulsion: Rohm	16.30	16.82	15.25	18.06	13.19	20.60	10.39
& Haas Rhoplex MC-
1834
Non-reactive Diluent:	0.18	0.19	0.17	0.20	0.15	0.23	0.12
Benzyl Alcohol
Defoamer: BYK-	0.33	0.34	0.31	0.36	0.27	0.41	0.21
Chemie BYK-011 (non-
silicone)
Sub-total	38.09	39.30	35.62	42.21	30.82	48.13	24.27

Examples

39	40	41	42	43	44	45
Weight %	Weight %	Weight %	Weight %	Weight %	Weight %	Weight %

Part A Components
Epoxy Resin: Huntsman	13.07	13.49	12.23	14.49	10.58	16.52	8.33
GY6010
Reactive Diluent: Air	1.47	1.52	1.37	1.63	1.19	1.86	0.94
Products Epodil 748
Adhesion Promoter: OSi	0.15	0.15	0.14	0.16	0.12	0.19	0.09
Silquest A-187
Portland Cement:	35.91	37.55	39.00	34.23	43.18	26.77	42.51
Federal Type I
Pozzolan: Lefarge	7.20	3.75	7.80	2.74	10.79	1.34	21.25
NewChem Slag
Hollow Spheres: 3M	2.08	2.14	1.94	2.30	1.68	2.63	1.32
Scotchlite K37
Non-reactive Diluent:	2.01	2.07	1.88	2.22	1.62	2.54	1.28
Benzyl Alcohol
Sub-total	61.89	60.68	64.36	57.77	69.16	51.83	75.72
Part B Components
Water-based amine	16.53	17.06	15.46	18.32	13.37	20.89	10.53
curing agent: Cognis
Waterpoxy 751
Deionized Water	4.76	4.91	4.45	5.27	3.85	6.01	3.03
Latex Emulsion: Rohm	16.31	16.83	15.25	18.07	13.20	20.61	10.39
& Haas Rhoplex MC-
1834
Non-reactive Diluent:	0.18	0.19	0.17	0.20	0.15	0.23	0.12
Benzyl Alcohol
Defoamer: BYK-	0.33	0.34	0.31	0.36	0.27	0.41	0.21
Chemie BYK-011 (non-
silicone)
Sub-total	38.11	39.32	35.64	42.23	30.84	48.17	24.28

Examples

46	47	48	49	50	51	52
Weight %	Weight %	Weight %	Weight %	Weight %	Weight %	Weight %

Part A Components
Epoxy Resin: Huntsman	13.11	13.53	12.26	14.53	10.60	16.58	8.34
GY6010
Reactive Diluent: Air	1.47	1.52	1.38	1.63	1.19	1.86	0.94
Products Epodil 748
Adhesion Promoter: OSi	0.15	0.15	0.14	0.16	0.12	0.19	0.09
Silquest A-187
Portland Cement:	36.02	37.66	39.10	34.33	43.28	26.86	42.58
Federal Type I
Pozzolan: Silica Fume	7.22	3.77	7.82	2.75	10.82	1.34	21.29
Hollow Spheres: 3M	1.80	1.86	1.68	2.00	1.46	2.28	1.15
Scotchlite K37
Non-reactive Diluent:	2.01	2.08	1.88	2.23	1.63	2.55	1.28
Benzyl Alcohol
Sub-total	61.78	60.56	64.26	57.64	69.09	51.66	75.68
Part B Components
Water-based amine	16.58	17.11	15.50	18.38	13.41	20.97	10.55
curing agent: Cognis
Waterpoxy 751
Deionized Water	4.77	4.92	4.46	5.29	3.86	6.03	3.04
Latex Emulsion: Rohm	16.36	16.88	15.29	18.13	13.23	20.69	10.41
& Haas Rhoplex MC-
1834
Non-reactive Diluent:	0.18	0.19	0.17	0.20	0.15	0.23	0.12
Benzyl Alcohol
Defoamer: BYK-	0.33	0.34	0.31	0.36	0.27	0.42	0.21
Chemie BYK-011 (non-
silicone)
Sub-total	38.22	39.44	35.74	42.36	30.91	48.34	24.32

Examples

53	54	55	56	57	58	59
Weight %	Weight %	Weight %	Weight %	Weight %	Weight %	Weight %

Part A Components
Epoxy Resin:	12.12	13.51	12.49	14.29	11.09	15.81	9.62
Huntsman GY6010
Reactive Diluent: Air	1.36	1.52	1.40	1.61	1.25	1.73	1.08
Products Epodil 748
Adhesion Promoter:	0.14	0.15	0.14	0.16	0.12	0.18	0.11
OSi Silquest A-187
Portland Cement: Type I	39.58	32.67	37.76	28.80	44.72	21.23	58.20
Hollow Spheres: 3M	2.28	2.54	2.35	2.68	2.08	2.97	1.81
Scotchlite K37
Non-reactive Diluent:	1.86	2.07	1.92	2.19	1.70	2.43	1.48
Benzyl Alcohol
Sub-total	57.34	52.46	56.06	49.73	60.97	44.39	72.29
Part B Components
Water-based amine	4.63	5.16	4.77	5.45	4.23	6.03	3.01
curing agent:
Anquamine 287
Water-based amine	10.93	12.18	11.26	12.89	10.00	14.26	7.10
curing agent:
Waterpoxy 751
Titanium Dioxide:	11.86	13.22	12.22	13.98	10.85	15.47	7.71
Huntsman TR-60
Latex Emulsion:	15.05	16.77	15.50	17.73	13.77	19.61	9.77
Synthomer 29Y46 SBR
Non-reactive Diluent:	0.17	0.19	0.18	0.20	0.16	0.22	0.11
Benzyl Alcohol
Corrosion Inhibitor:	0.02	0.02	0.02	0.02	0.02	0.02	0.01
Cortec MCI-2000
Sub-total	42.66	47.54	43.94	50.27	39.03	55.61	27.71

Further embodiments of the composition are described by the following untested examples. The following examples are provide by way of illustration not limitation, and the changes reflected are equally applicable to each of the compositions specifically described in Examples 1 through 59.


	Untested Examples

60	61	62	63	64
Weight %	Weight %	Weight %	Weight %	Weight %

Part A Components

Epoxy Resin	Huntsman GY6010	14.31	13.04	13.04	11.48	12.12
Reactive Diluent	Air Products Epodil	1.61	1.46	1.46	1.29	1.36
	748
Adhesion	OSi Silquest A-187	0.16	0.15	0.15	0.13	0.14
Promoter
Portland Cement	Type I	38.15	0	0	0	39.58
	Type V	0	35.82	35.82	32.41	0
Pozzolan	Calcined Kaolin	0	7.18	7.18	0	0
	Fly Ash	0	0	0	6.71	0
Titanium Dioxide	Huntsman TR-60	6.16	0	0	0	0
Hollow Spheres		1.61	2.34	2.34	4.27	2.28
Non-reactive	Rutgers Novares LS	2.20	2.00	2.00	1.76	1.86
Diluent	500
Sub-total		64.19	61.99	61.99	58.06	57.34

Part B Components

Water-based amine	Cognis Waterpoxy	5.35	16.49	16.49	14.52	10.93
curing agent	751
	Anquamine 287	12.65	0	0	0	4.63
Deionized Water			4.74	4.74	1.35	0
Titanium Dioxide	Huntsman TR-60	0	0	0	11.30	11.86
Concrete Super	Lignotech Norlig 24C	0.20	0	0	0	0
Plasticizer
Latex Emulsion	Synthomer 29Y46	17.41	0	0	0	15.05
	SBR
	Rohm & Haas	0	16.27	16.27	14.33	0
	Rhoplex MC-1834
Non-reactive	Benzyl Alcohol	0	0.18	0	0	0
Diluent	Rutgers Novares LS	0.2	0	0.18	0.16	0.17
	500
Defoamer	BYK-Chemie BYK-	0	0	0.16	0	0
	011 (non-silicone)
	Tego Foamex 805	0	0.33	0.17	0.29	0
	(silicone)
Corrosion Inhibitor	Cortec MCI-2000	0	0	0	0	0.02
Sub-total		35.81	38.01	38.01	41.94	42.66

	Untested Examples
	65
	Weight %

Part A Components

Liquid Amine Resin	Huntsman Jeffamine D-400	14.45
Portland Cement	Lehigh Type I	42.01
Hollow Spheres	Scotchlite K-37 Glass Bubbles	2.41
Sub-total		58.86

Part B Components

Water-dispersed Epoxy Resin	Resolution Epi-Rez 3510-W-60	41.14
Sub-total		41.14

Thus, in various embodiments, the composition of the present invention broadly comprises some or all of the following components: an epoxy resin of, in one embodiment, between 8.0% to 23.0% by weight, and, in another embodiment, between 10% to 42% by weight; a powdered hydraulic cement of, in one embodiment, between 20.0% to 72.0% by weight and, in another embodiment, between 46% to 90% by weight; water in an amount at least sufficient to react with the cement; a curing agent of, in one embodiment, between 5.0% to 21.0% by weight, and, in another embodiment, between 30% to 60%; a non-reactive diluent of between 0.1% to 3.3% by weight; a reactive diluent of, in one embodiment, between 0.8% to 2.6% by weight, and, in another embodiment, between 1.1% to 4.8% by weight; a pigment of between 6.0% to 24.0% by weight; an organosilicon adhesion promoter of, in one embodiment, between 0.08% to 0.26% by weight, and, in another embodiment, between 0.1% to 0.5%; a water-based latex resin of between 4.0% to 31.0% by weight; a plurality of hollow spheres of, in one embodiment, between 1.0% to 8.0% by weight, and, in another embodiment, between 1% to 13% by weight; a defoamer of between 0.5% to 1.0% by weight; a non-silicon defoamer of between 0.15% to 0.55% by weight; a silicone defoamer of between 0.15% to 0.55% by weight; a corrosion inhibitor of, in one embodiment, between 0.01% to 2.4% by weight, and, in another embodiment, of between 0.04% to 18.5% by weight; a concrete plasticizer of between 0.2% to 0.6% by weight; and/or a latex resin of between 30% to 50% by weight. Characterized another way, one embodiment of the composition of the present invention broadly comprises approximately 90 parts epoxy resin mixed with approximately 10 parts reactive diluent to produce a mixture, and approximately 1 part hydraulic cement powder mixed with approximately 0.11 to 1.5 parts of the aforementioned mixture, to ultimately produce the coating composition having between 0.80 to 1.30 equivalents of total epoxy groups to 1.00 equivalent of reactive amine groups. In various embodiments, the composition forms a coat having a thickness of approximately between 2 mils to 15 mils.
Any of the disclosed embodiments of the claimed composition may be used in a process to protectively coat a surface. The process involves preparing the composition according to the present invention, mixing the two parts with an appropriate amount of water, and applying the coating to the surface. The formula may be applied with a brush, roller or airless sprayer and will achieve a high build film in a single application, although multiple coats may be applied at the discretion of the user.
Thus, a waterborne epoxy composition is disclosed which utilizes hydraulic cement powder as an element of the epoxy composition to provide a desired initial application coat thickness with good fluidity and enhanced cure time while still providing protection against corrosion and other environmental threats. The coating composition also provides corrosion resistance equal to organic solvent based and solvent free coatings.
While preferred embodiments and particular applications of this invention have been shown and described, it is apparent to those skilled in the art that many other modifications and applications of this invention are possible, including using the teaching to develop coating compositions having three or more components, without departing from the inventive concepts herein. It is, therefore, to be understood that, within the scope of the appended claims, this invention may be practiced otherwise than as specifically described, and the invention is not to be restricted except in the spirit of the appended claims. Though some of the features of the invention may be claimed in dependency, each feature has merit if used independently.

Claims

1. (canceled)

2. A composition for use in coating surfaces with a thin coating, the composition comprising:

(a) a desired amount of at least one epoxy resin;

(b) a desired amount of at least one mono glycidyl ether reactive diluent;

(c) a desired amount of at least one powdered hydraulic cement;

(d) at least one curing agent comprising a water soluble polyamine composition capable of emulsifying the epoxy resin;

(e) water in an amount at least sufficient to react with the powdered hydraulic cement; and

(f) wherein the composition forms coatings having a thickness of from approximately 2 mils to approximately 15 mils.

3. The composition according to claim 2, wherein the epoxy resin is a liquid epoxy resin comprising approximately 11.0% to 19.0% by weight of the total composition.

4. The composition according to claim 3, wherein the liquid epoxy resin is a liquid bisphenol A epoxy resin.

5. The composition according to claim 2, wherein the powdered hydraulic cement is Portland Cement comprising approximately 30.0% to 70.0% by weight of the total composition.

6. The composition according to claim 2, wherein the powdered hydraulic cement is a mixture of approximately 0.50 to 0.95 weight parts of Portland Cement and approximately 0.05 to 0.50 weight parts pozzolan powder derived from a group comprising fly ash, steel slag, silica fume, or calcined kaolin clay.

7. The composition according to claim 2, wherein the curing agent is a polyamine having a plurality of N—H linkages capable of reacting with the epoxy resin comprising approximately 8.0% to 18.0% by weight of the total composition.

8. The composition according to claim 2, wherein the curing agent is a polyoxyalkylene polyamine.

9. The composition according to claim 2, wherein the curing agent is an arylene polyamine.

10. The composition according to claim 2, wherein the curing agent is a cyclo-aliphatic polyamine.

11. The composition according to claim 2, wherein the curing agent comprises a blend of a Mannich base with polyoxyalkylene polyamines, arylene polyamines, and cyclo-aliphatic polyamines.

12. The composition according to claim 2, wherein the curing agent comprises a blend of polyoxyalkylene polyamines, arylene polyamines, and cyclo-aliphatic polyamines.

13. The composition according to claim 2, wherein the composition further includes approximately 0.1% to 3.3% by weight of a non-reactive diluent.

14. The composition according to claim 13, wherein the non-reactive diluent is benzyl alcohol.

15. The composition according to claim 13, wherein the non-reactive diluent is an aromatic hydrocarbon resin.

16. The composition according to claim 2, wherein the mono glycidyl ether is present in an amount of approximately 0.8% to 2.6% by weight of the composition.

17. The composition according to claim 16, wherein the mono glycidyl ether is a C-6 to C-18 alkyl glycidyl ether.

18. The composition according to claim 16, wherein the mono glycidyl ether is a C-12 to C-14 alkyl glycidyl ether.

19. The composition according to claim 2, wherein the composition further includes approximately 6.0% to 24.0% by weight of a pigment.

20. The composition according to claim 19, wherein the pigment is titanium dioxide.

21. The composition according to claim 2, wherein the composition further includes approximately 0.08% to 0.26% by weight of an organosilicon adhesion promoter.

22. The composition according to claim 21, wherein the organosilicon adhesion promoter is γ-glycidoxypropyl-trimethoxy silane.

23. The composition according to claim 2, wherein the composition further includes approximately 4.0% to 31.0% by weight of a water-based latex resin.

24. The composition according to claim 23, wherein the water-based latex resin is a styrene-acrylic latex.

25. The composition according to claim 23, wherein the water-based latex resin is a styrene butadiene rubber latex.

26. The composition according to claim 23, wherein the water-based latex resin is an acrylic latex.

27. The composition according to claim 2, wherein the composition further includes hollow spheres in an amount of approximately 1.0% to 8.0% by weight of the composition.

28. The composition according to claim 2, wherein the composition further includes approximately 0.15% to 0.55% by weight of a non-silicone defoamer.

29. The composition according to claim 2, wherein the composition further includes approximately 0.15% to 0.55% by weight of a silicone defoamer.

30. The composition according to claim 2, wherein the composition further includes approximately 0.01% to 2.4% by weight of a corrosion inhibitor

31. The composition according to claim 2, wherein the composition forms coatings having a thickness of from approximately 4 mils to approximately 12 mils.

32. The composition according to claim 2, wherein the composition forms coatings having a thickness of from approximately 6 mils to approximately 10 mils.

33. A paint composition for use in coating surfaces, the composition comprising:

(a) approximately 10% to 42% by weight of an epoxy resin;

(b) approximately 46% to 90% by weight of hydraulic cement powder;

(c) approximately 30% to 60% by weight of a curing agent comprising a water soluble polyamine composition capable of emulsifying the epoxy resin;

(d) water in an amount at least sufficient to react with the hydraulic cement;

(e) wherein the volatile organic compound content of the coating composition is not more than approximately 3.3% by weight of the total composition; and

(f) wherein the coating composition forms coatings having a thickness of from approximately 2 mils to approximately 15 mils.

34. The composition according to claim 33, wherein the composition further includes a desired amount of an inert filler.

35. The composition according to claim 34, wherein the inert filler comprises hollow spheres in an amount of approximately 1.0% to 8.0% by weight of the total composition.

36. The composition according to claim 33, wherein the composition is applied to a surface using a brush, roller or airless sprayer to form a protective coating with a thickness of from approximately 6 mils to approximately 10 mils.

37. The composition according to claim 33, having a gel time of approximately 60 to 120 minutes.

38. The composition according to claim 33, having approximately 0.8 to 1.3 equivalents of total epoxy groups to 1.0 equivalent of reactive amine groups.

39. The composition according to claim 33, having approximately 0.2 to 0.9 parts water to 1.0 part of hydraulic cement.

40. A process for protecting a surface, the process comprising:

(a) applying a fluid protective coating composition to the surface, the coating composition comprising:

(i) a desired amount of at least one epoxy resin;

(ii) a desired amount of at least one mono glycidyl ether reactive diluent;

(iii) a desired amount of at least one powdered hydraulic cement;

(iv) at least one curing agent in an amount sufficient to react with the epoxy resin; and

(v) water in an amount at least sufficient to react with the powdered hydraulic cement; and

(b) permitting the coating composition to cure to form a protective coating with a thickness of from approximately 2 mils to approximately 15 mils.

41. The process according to claim 40, wherein the composition is applied to a surface using a brush, roller or airless sprayer to form a protective coating with a thickness of from approximately 4 mils to approximately 12 mils.

42. The process according to claim 40, wherein the composition is applied to a surface using a brush, roller or airless sprayer to form a protective coating with a thickness of from approximately 6 mils to approximately 10 mils.

43. The process according to claim 40, wherein the composition is applied in two coats.

44. The process according to claim 40, wherein the composition is applied in three coats.

45. The process according to claim 40, wherein the composition further includes:

(a) mixing approximately 90 parts epoxy resin with approximately 10 parts mono glycidyl ether reactive diluent;

(b) adding approximately 1 part hydraulic cement powder to approximately 0.11 to 1.15 part epoxy mixture; and

(c) adding approximately 1 part hollow spheres to approximately 3 to 50 parts of hydraulic cement powder to form a first component of said composition;

(d) separately mixing at least one curing agent, wherein the curing agent is a polyamine having a plurality of N—H linkages capable of reacting with the epoxy resin, with a desired amount of latex resin and water to form a second component of said composition; and

(e) combining the first component and the second component, in a ratio to provide a coating composition having approximately 0.8 to 1.3 equivalents of total epoxy groups to 1.0 equivalent of reactive amine groups, in a conventional airless sprayer.

46. The process according to claim 45, wherein the first component and the second component are combined in a ratio to provide a coating composition having approximately 0.9 to 1.1 equivalents of total epoxy groups to 1.0 equivalent of reactive amine groups.

47. The process according to claim 45, wherein the first component and the second component are combined in a ratio to provide a coating composition having approximately 0.2 to 0.9 parts water to 1.0 part of hydraulic cement.

48. The process according to claim 45, wherein the first component and the second component are combined in a ratio to provide a coating composition having approximately 0.4 to 0.6 parts water to 1.0 part of hydraulic cement.

49. A composition for use in coating surfaces with a thin coating, the composition comprising:

(a) a desired amount of at least one epoxy resin;

(b) a desired amount of at least one powdered hydraulic cement;

(c) a desired amount of at least one type of hollow spheres;

(d) at least one curing agent in an amount sufficient to react with the epoxy resin;

(e) water in an amount at least sufficient to react with the powdered hydraulic cement;

(f) wherein the composition does not include a separate emulsifier surfactant; and

(g) wherein the composition forms coatings having a thickness of from approximately 2 mils to approximately 15 mils.

50. A two-component composition for use in coating surfaces, the composition comprising:

(a) a first component including:

(i) approximately 10% to 42% by weight of an epoxy resin; and

(ii) approximately 46% to 90% by weight of hydraulic cement powder; and

(b) a second component including:

(i) approximately 30% to 60% by weight of a curing agent; and

(ii) water in an amount at least sufficient to react with the hydraulic cement; and

(c) the first component and second component being mixed to provide the coating composition having a gel time of approximately 60 minutes to approximately 120 minutes, wherein the coating composition forms coatings having a thickness of from approximately 2 mils to approximately 15 mils.

51. The composition according to claim 50, wherein the curing agent includes primary, secondary, and tertiary amine functionality.

52. The composition according to claim 50, wherein the curing agent is a diamine.

53. A two-component composition for use in coating surfaces, the composition comprising:

(a) an aqueous first component including:

(i) a desired amount of at least one water dispersed epoxy resin;

(ii) a desired amount of at least one latex resin;

(iii) a desired amount of water; and

(b) a non-aqueous second component including:

(i) a desired amount of at least one liquid amine curing agent, wherein the curing agent is a polyamine having a plurality of N—H linkages capable of reacting with the epoxy resin;

(ii) a desired amount of at least one hydraulic cement powder;

(iii) a desired amount of at least one type of hollow spheres; and

(c) the first component and second component being mixed in a ratio to provide a coating composition having 0.20 to 0.90 parts water to 1.00 part of hydraulic cement, wherein the coating composition forms coatings having a thickness of from approximately 2 mils to approximately 15 mils.