US20080038123A1 - Processing and/or operating machine comprising an ionic liquid as the operating liquid - Google Patents
Processing and/or operating machine comprising an ionic liquid as the operating liquid Download PDFInfo
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- US20080038123A1 US20080038123A1 US11/839,228 US83922807A US2008038123A1 US 20080038123 A1 US20080038123 A1 US 20080038123A1 US 83922807 A US83922807 A US 83922807A US 2008038123 A1 US2008038123 A1 US 2008038123A1
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- 239000002608 ionic liquid Substances 0.000 title claims abstract description 92
- 239000007788 liquid Substances 0.000 title claims abstract description 73
- 238000012545 processing Methods 0.000 title abstract description 13
- 239000012530 fluid Substances 0.000 claims abstract description 118
- 230000001050 lubricating effect Effects 0.000 claims abstract description 16
- 230000004888 barrier function Effects 0.000 claims abstract description 9
- 238000007789 sealing Methods 0.000 claims abstract description 8
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 74
- -1 pyrazolium cation Chemical class 0.000 claims description 57
- 125000004432 carbon atom Chemical group C* 0.000 claims description 36
- 239000007789 gas Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 28
- 125000005843 halogen group Chemical group 0.000 claims description 24
- 125000001072 heteroaryl group Chemical group 0.000 claims description 24
- 229910019142 PO4 Inorganic materials 0.000 claims description 20
- 125000003118 aryl group Chemical group 0.000 claims description 19
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims description 16
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 16
- 150000005840 aryl radicals Chemical class 0.000 claims description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 16
- 239000010452 phosphate Substances 0.000 claims description 16
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 claims description 16
- 229940124530 sulfonamide Drugs 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 13
- 125000002723 alicyclic group Chemical group 0.000 claims description 12
- 125000001931 aliphatic group Chemical group 0.000 claims description 12
- 125000005842 heteroatom Chemical group 0.000 claims description 12
- 150000003254 radicals Chemical class 0.000 claims description 12
- 229920006395 saturated elastomer Polymers 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 150000001450 anions Chemical class 0.000 claims description 11
- 150000001768 cations Chemical class 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 238000005260 corrosion Methods 0.000 claims description 6
- 230000007797 corrosion Effects 0.000 claims description 6
- 238000012546 transfer Methods 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- VRFOKYHDLYBVAL-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;ethyl sulfate Chemical compound CCOS([O-])(=O)=O.CCN1C=C[N+](C)=C1 VRFOKYHDLYBVAL-UHFFFAOYSA-M 0.000 claims description 4
- ZTLWMUBOQHZKNS-UHFFFAOYSA-M 1-ethyl-3-methylpyridin-1-ium;ethyl sulfate Chemical compound CCOS([O-])(=O)=O.CC[N+]1=CC=CC(C)=C1 ZTLWMUBOQHZKNS-UHFFFAOYSA-M 0.000 claims description 4
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 claims description 4
- PKXWFSLYBCTTSX-UHFFFAOYSA-N S(=O)(=O)=[N-].FC(F)F.FC(F)F.C(C)[N+]1=CN(C=C1)C Chemical compound S(=O)(=O)=[N-].FC(F)F.FC(F)F.C(C)[N+]1=CN(C=C1)C PKXWFSLYBCTTSX-UHFFFAOYSA-N 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 4
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 4
- 239000007866 anti-wear additive Substances 0.000 claims description 4
- 239000002518 antifoaming agent Substances 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- XSVRLIQTDQOQRI-UHFFFAOYSA-M butyl(trimethyl)phosphanium;dimethyl phosphate Chemical compound COP([O-])(=O)OC.CCCC[P+](C)(C)C XSVRLIQTDQOQRI-UHFFFAOYSA-M 0.000 claims description 4
- 230000000994 depressogenic effect Effects 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 150000002460 imidazoles Chemical class 0.000 claims description 4
- 239000003607 modifier Substances 0.000 claims description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims description 4
- 150000003217 pyrazoles Chemical class 0.000 claims description 4
- 150000003222 pyridines Chemical class 0.000 claims description 4
- 125000005497 tetraalkylphosphonium group Chemical group 0.000 claims description 4
- 150000003852 triazoles Chemical class 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 3
- 230000005540 biological transmission Effects 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 21
- 0 *n1ccn(C)c1 Chemical compound *n1ccn(C)c1 0.000 description 13
- 230000008901 benefit Effects 0.000 description 11
- 238000007906 compression Methods 0.000 description 10
- 239000000314 lubricant Substances 0.000 description 10
- 230000006835 compression Effects 0.000 description 9
- 238000005461 lubrication Methods 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 7
- 238000001704 evaporation Methods 0.000 description 6
- 235000002639 sodium chloride Nutrition 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 230000003466 anti-cipated effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229940077464 ammonium ion Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000010725 compressor oil Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000002173 cutting fluid Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012208 gear oil Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000010720 hydraulic oil Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 210000002445 nipple Anatomy 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 239000010723 turbine oil Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/56—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen
- C10M105/70—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen as ring hetero atom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/72—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing sulfur, selenium or tellurium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/74—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/78—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/023—Amines, e.g. polyalkylene polyamines; Quaternary amines used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/2203—Heterocyclic nitrogen compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
- C10M2215/2245—Imidazoles used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
- C10M2223/0603—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/077—Ionic Liquids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/44—Super vacuum or supercritical use
Definitions
- the invention relates to a processing and/or operating machine comprising an ionic liquid as the operating liquid.
- fluids preferably oils are used as lubricating fluid, sealing fluid, barrier fluid, pressure transfer fluid, i.e. quite generally as operating liquid, in the field of processing machines such as pumps, in particular vacuum pumps, rotary vane pumps, vane-cell pumps, piston pumps, diaphragm pumps etc., in compressors such as screw compressors etc. and in piston machines.
- processing machines such as pumps, in particular vacuum pumps, rotary vane pumps, vane-cell pumps, piston pumps, diaphragm pumps etc.
- compressors such as screw compressors etc. and in piston machines.
- vapour pressure of such fluids determines the minimum pressure in a processing machine, with, in the case of an evaporation of the fluid, this having to be eliminated from the process gas in a complex manner.
- Hydraulic diaphragm pumps are a typical example of the disadvantages described. As a result of their hermetic properties with a simultaneously high compressive rigidity and conveying accuracy, such hydraulic diaphragm pumps are preferably employed for critical conveying tasks such as conveying of toxic, environmentally relevant or hygiene fluids, for conveying at high pressures and for the precise dosage of any desired fluids.
- the hydraulic fluid which is used as a pressure transfer fluid from the piston to the diaphragm, represents a frequently limiting factor.
- mineral oil or synthetic oil e.g. polyglycol with a multiplicity of additives or special oil is used for this purpose.
- glycerine is also used in food technology or biotechnology.
- glycerine requires the application of inhibitors of biological decomposition. Nevertheless, decomposition cannot be prevented.
- the thermal limit in this case is merely 95° C.
- the viscosity is adjusted by mixing with water in a complex manner.
- a further typical example of the disadvantages described is presented by liquid ring vacuum pumps.
- the rotating fluid ring is required to seal the impeller chambers vis-à-vis each other and for transferring the necessary compression energy onto the gas.
- the vapour pressure of the ring liquid limits the minimum achievable intake pressure level. At this intake pressure, the impeller chambers fill completely with the evaporating operating liquid and the suction capacity of the liquid ring vacuum pump drops to zero.
- Operating liquids used in practice are preferably water with a vapour pressure at ambient temperature of approximately 23 mbar and oils with a vapour pressure of approximately 1 mbar thus permitting merely operation in the so-called coarse vacuum range.
- other compressors need to be consequently necessarily used for this purpose.
- these have disadvantages compared with the use of a liquid ring vacuum pump.
- their use for compressing hydrocarbons is possible only by taking great safety precautions since the compressors that can be used require an explosion-protected design.
- DE 10 2204 024 967 A1 discloses the use of ionic liquids as operating liquid (i.e. the fluid to be conveyed) for thermal absorption pumps, absorption refrigerating machines and thermal transformers.
- Gas conveying machines, hydraulic diaphragm pumps, liquid ring vacuum pumps and piston machines using ionic liquids as operating liquids are not disclosed in DE 10 2004 024 967 A1.
- the present invention is therefore based on the object of designing a processing and/or operating machine of the type appropriate for its kind which exhibits a fluid as operating liquid such that the disadvantages illustrated are avoided without loosing the advantages of the operating liquids previously employed.
- this invention relates to a device, in particular a pump, comprising an ionic liquid as operating liquid medium, in particular as separating fluid and/or hydraulic fluid.
- a second embodiment of the present invention consists of a hydraulic diaphragm pump which is characterized in that it comprises an ionic liquid as hydraulic fluid.
- a third embodiment of the present invention consists of a liquid ring vacuum pump which is characterized in that it comprises an ionic liquid as ring liquid. This extends the operating range of the pump into the fine vacuum range.
- a fourth embodiment of the present invention consists of a piston-containing machine which is characterized in that it is designed with a piston oscillating in a cylinder in the form of a fluid piston or a fluid master piston positioned in front which consists of an ionic liquid.
- a gas, a non-miscible fluid of low density or a fluid of high density can be conveyed.
- the invention moreover, relates to a process for operating the above-mentioned device by using ionic liquids as operating liquid medium.
- the invention provides a method of operating a machine comprising: including an ionic liquid as an operating fluid in the machine; and operating the machine.
- the invention also provides a method of equipping a machine comprising: including an ionic liquid in the machine as an operating fluid in the machine.
- operating fluid is meant a liquid employed by a machine to facilitate operation of a machine.
- the operating fluid can serve as a lubricant, barrier fluid, hydraulic fluid, ring liquid, fluid piston or any other such fluid. It should be understood that the scope of the invention is use of an ionic liquid as an operating fluid in a machine, wherein the ionic liquid is used other than solely as a heat transfer medium.
- FIG. 1 depicts an exemplary gas conveying machine of the invention comprising an ionic liquid.
- FIG. 2 depicts an exemplary hydraulic diaphragm pump of the invention comprising an ionic liquid.
- FIG. 3 depicts an exemplary liquid ring vacuum pump of the invention comprising an ionic liquid.
- FIG. 4 depicts an exemplary screw pump of the invention comprising an ionic liquid.
- the invention is based on the essential idea of designing a processing and/or operating machine in such a way that the operating medium provided therein, i.e. the operating liquid is an ionic liquid.
- Ionic liquids consist of ions, i.e. anions or cations and are consequently salts. In contrast to common salts, such as sodium chloride, however, they have a lower melting point and may be fluid even at room temperature. Thus, all salts which exist in the pure form as a fluid at below 100° are considered, by definition, to be ionic liquids.
- Ionic liquids may be referred to as liquid salts. They possess an extremely low vapour pressure (10 ⁇ 13 bar), have only a low gas solubility, are not combustible, are frequently physiologically safe and frequently thermally stable at up to more than 250° C. and suitable for lubrication.
- the list of advantages provided by ionic liquid is long. Consequently, ionic liquids represent an environmentally friendly and resources-conserving replacement for the fluids described so far.
- a machine or pump according to the invention will comprise ionic liquid as the working fluid or operating fluid.
- the ionic liquid can possess one or a combination of two, three, four or more of the following properties: 1) a vapor pressure of less than 10 ⁇ 3 mbar; 2) a melting point of less than 20° C.
- Additives can be used in combination with an ionic liquid according to the invention, such additives being those typically used in the oil and lubricant industry. Any zwitterionic or ionic commercial additive can be used. One or more additives can be used. Suitable additives include anti-wear additive, friction modifier, rust and corrosion inhibitor, antioxidant, dispersant, detergent, anti-foaming agent, pour point depressant and combinations thereof. Suitable additives are also disclosed in Patent No. [ADD] of Idemitsui, the disclosure of which is hereby incorporated by reference.
- the ionic liquid of the invention can be used in a variety of machinery and can be used as a substitute for engine oil, gear oil, hydraulic oil, cutting fluid (coolant), way lubricant, compressor oil, quenching and heat transfer oil, rust protection oil, transformer oil, turbine oil, chain lubricant, wire rope lubricant, bearing oil, sintered bearing oil, sealing oil.
- an ionic liquid as operating liquid in processing and/or operating machines, it is possible to advantageously influence the following parameters as desired: a) the lubricating effect; b) the compressive rigidity; c) the viscosity as a function of the temperature; d) the vapour pressure limit; e) the chemical inertness; f) the thermal inertness; g) the solubility behaviour; h) the physiological safety.
- Ionic liquids are therefore capable of avoiding the disadvantages described so far. Because of their extremely low vapour pressure of 10 ⁇ 13 bar (liquid salt), they are capable of reaching extremely low pressures in vacuum technology and consequently avoid contamination of the process gas both in vacuum pumps and in compressors.
- ionic liquids As a result of the use of ionic liquids, anticipated according to the invention, in process machines it is now also possible to operate the above-mentioned piston machines with a fluid piston consisting of an ionic liquid and to avoid the disadvantages described at the same time.
- the use of ionic liquids also provides the advantage that a reaction with the substance conveyed is impossible since it is inert to a large extent.
- liquid ring vacuum pumps as a result of the use, according to the invention, of ionic liquids as ring liquid, to employ these pumps also in the fine vacuum range.
- liquid ring vacuum pumps can be used instead of the previously used screw compressors, piston compressors, rotary vane cell compressors etc. and their great advantages regarding robustness, reliability and process safety can fully be exploited.
- a paddle wheel is arranged eccentrically in the case of a liquid ring vacuum pump in a cylindrical housing.
- the operating liquid present in the housing forms a co-rotating, concentrically formed fluid ring as a result of the rotation of the paddle wheel.
- the fluid ring closes off the gas volumes in the chambers.
- the paddles immerse, in the upper area, completely into the fluid ring such that the chamber volume is completely filled with operating liquid.
- the fluid ring detaches itself from the impeller hub and forms a crescent-shaped cavity.
- the gaseous fluid to be conveyed is sucked into the operating cavity by the control disc apertures arranged on the front surfaces on the impeller. Shortly before the gas-filled chamber volume reaches its maximum, the suction slit terminates and the chamber is sealed off by the control discs, the impeller paddles and the fluid. The fluid ring then migrates again towards the hub and compresses during this process the gas like a piston. As soon as the pressure slot apertures are reached, the compressed gas is pushed out.
- the operating liquid needs to fulfill above all three functions in liquid ring vacuum pumps, namely firstly the function of a moving piston with the operating pulses of suction, compaction and pushing out, secondly the sealing function to seal the scoop cavities from each other and thirdly the absorption of heat of compression.
- part of the operating liquid is continually expelled through the pressure slot, the same amount of fresh fluid being fed in via a fluid channel in the shaft hub of the pump. As a result of this ongoing recooling, a constant temperature of the operating liquid is reached.
- the vapour pressure of the operating liquid limits, the lowest possible suction level to be reached in the suction nipple of the pump. If the suction pressure drops to a value equal to or in the vicinity of the vapour pressure of the fluid, cavitation and consequently a complete drop in performance of the pump occur.
- liquid ring vacuum pumps enter an area of application which had previously been covered by rotary vane pumps and exterior vane pumps, eccentric piston pumps or injectors.
- liquid ring vacuum pumps can exhibit their pump-imminent advantages such as maximum reliability, quasi isothermic compression and absence of oil in the compression process in the now possible field of application of the fine vacuum (10 ⁇ 3 -10 ⁇ 1 mbar) and they open up, in this way, an entirely new way of process control and application possibilities.
- the ionic liquids used according to the invention as operating liquid are compounds composed of cations and anions.
- the ionic liquid can comprise one such compound or a mixture of two or more such compounds.
- a cation can be selected from the group consisting of:
- the anion can be selected from the group consisting of [PF 6 ] 31 , [BF 4 ] ⁇ , [CF 3 CO 2 ] ⁇ , [CF 3 SO 3 ] ⁇ , [(CF 3 SO 2 ) 2 N] ⁇ , [(CF 3 SO 2 )(CF 3 COO)N] ⁇ , [R 4 —SO 3 ] ⁇ , [R 4 —O—SO 3 ] ⁇ , [R 4 —COO] ⁇ , Cl ⁇ , Br ⁇ , I ⁇ , [NO 3 ] ⁇ , [N(CN) 2 ] ⁇ , [HSO 4 ⁇ or [R 4 R 5 PO 4 ] ⁇ , wherein:
- radicals R 4 and R 5 independently from each other are selected from the group consisting of:
- Exemplary ionic liquids that can be used according to the invention include, without limitation, 1-alkyl-3-alkyl-imidazolium tetrafluoroborate, 1-alkyl-3-alkyl-imidazolium hexafluorophosphate, 1-alkyl-3-alkyl-imidazolium alkyl sulfate, 1-alkyl-3-alkyl-imidazolium alkyl sulfonate, 1-alkyl-3-alkyl-imidazolium Trifluoralkyl sulfonate, 1-alkyl-3-alkyl-imidazolium bistrifluoromethane sulfonyl amide, 1-alkyl-3-alkyl-imidazolium dialkyl phosphate, tetraalkylphosphonium dialkyl phosphate, 1-alkyl-3-alkyl-pyridinium tetrafluoroborate, 1-alkyl-3-alkyl-pyridinium
- Combinations of two or more of the ionic liquids of the invention can be used.
- the alkyl moiety is independently substituted or unsubstituted at each occurrence in an ionic liquid.
- the alkyl component of the cation can be the same as or different than the alkyl component of the anion.
- a machine is made to include an ionic liquid of the invention.
- a gas conveying machine (gas pump) is made to include an ionic liquid as a lubricating fluid and a barrier fluid.
- a reciprocating gas compressor is a suitable example.
- Exemplary gas conveying machines suitable for use according to the invention are disclosed in U.S. Pat. Nos. 7,255,540, No. 7,114,493, No. 7,083,395, No. 6,951,025, No. 6,663,359, No. 6,422,027, No. 6,382,923, No. 6,311,519, No. 6,227,266, No. 6,200,116, No. 6,193,680, No. 5,800,146, No. 5,785,501, No. 5,730,286, No.
- a Hydraulic diaphragm pump is made to include an ionic liquid as the hydraulic fluid.
- Exemplary hydraulic diaphragm pumps suitable for use according to the invention are disclosed in U.S. Pat. Nos. 6,889,765, No. 6,884,045, No. 6,595,280, No. 6,464,474, No. 6,419,841, No. 6,251,293, No. 6,129,525, No. 6,105,829, No. 6,099,269, No. 6,071,089, No. 6,017,198, No. 5,934,886, No. 5,810,567, No. 5,782,315, No. 5,772,899, No. 5,707,219, No. 5,547,351, No.
- a liquid ring vacuum pump is made to include an ionic liquid as the ring liquid.
- Exemplary liquid ring vacuum pumps suitable for use according to the invention are disclosed in U.S. Pat. Nos. 6,585,492, No. 6,350,299, No. 6,315,524, No. 6,149,345, No. 6,128,901, No. 6,106,239, No. 6,033,462, No. 6,013,138, No. 5,946,767, No. 5,860,767, No. 5,803,713, No. 5,688,076, No. 5,586,836, No. 5,423,614, No. 5,366,348, No. 5,290,152, No. 5,246,348, No. 5,222,869, No. 5,151,010, No.
- a machine comprising a piston oscillating in a cylinder, in the form of a fluid piston or a fluid master piston arranged in front, is made to include an ionic liquid and, as a result of its oscillating movement, conveys a gas and/or non-miscible fluid of low density or a fluid of high density.
- Exemplary machines comprising a fluid piston or fluid master piston suitable for use according to the invention are disclosed in U.S. Pat. Nos. 7,162,944, No. 7,048,095, No. 6,945,889, No. 6,279,702, No. 3,067,726, No. 3,980,231, No. 5,395,201, No. 4,529,181 and No. 7,171,888 Canadian Patent No. 1,209,405, and PCT International Publications No. WO 1994/027852, No. WO 1994/023201, WO 1998/001405, and No. WO 2007/-40599, the entire disclosures of which are hereby incorporated by reference.
- a screw pump is made to include an ionic liquid according to the invention.
- Exemplary screw pumps suitable for use according to the invention are disclosed in U.S. Pat. Nos. 7,234,925, No. 7,232,297, No. 7,165,933, No. 7,131,827, No. 7,093,665, No. 7,080,798, No. 6,877,967, No. 6,854,955, No. 6,716,008, No. 6,688,499, No. 6,666,672, No. 6,600,000, No. 6,554,799, No. 6,544,015, No. 6,537,049, No. 6,497,563, No. 6,457,950, No. 6,447,275, No. 6,241,486, No. 6,227,829, No. 6,079,797, No.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Reciprocating Pumps (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005007100.7 | 2005-02-16 | ||
| DE102005007100A DE102005007100A1 (de) | 2005-02-16 | 2005-02-16 | Prozess- bzw. Arbeitsmaschine mit ionischer Flüssigkeit als Betriebsflüssigkeit |
| PCT/EP2006/050941 WO2006087333A1 (de) | 2005-02-16 | 2006-02-15 | Prozess- bzw. arbeitsmaschine mit ionischer flüssigkeit als betriebsflüssigkeit |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2006/050941 Continuation-In-Part WO2006087333A1 (de) | 2005-02-16 | 2006-02-15 | Prozess- bzw. arbeitsmaschine mit ionischer flüssigkeit als betriebsflüssigkeit |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20080038123A1 true US20080038123A1 (en) | 2008-02-14 |
Family
ID=36337376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/839,228 Abandoned US20080038123A1 (en) | 2005-02-16 | 2007-08-15 | Processing and/or operating machine comprising an ionic liquid as the operating liquid |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20080038123A1 (de) |
| EP (1) | EP1848789A1 (de) |
| JP (1) | JP2008530441A (de) |
| DE (1) | DE102005007100A1 (de) |
| WO (1) | WO2006087333A1 (de) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110023483A1 (en) * | 2009-07-31 | 2011-02-03 | Voith Patent Gmbh | Drive unit and method for its operation |
| US20110253929A1 (en) * | 2008-12-22 | 2011-10-20 | Basf Se | Mixtures of hydrophobic and hydrophilic ionic liquids and use thereof in liquid ring compressors |
| CN102732365A (zh) * | 2012-07-10 | 2012-10-17 | 广州市联诺化工科技有限公司 | 一种功能化离子液体辅助增效的水性环保切削液及其制备方法 |
| WO2014092953A1 (en) * | 2012-12-14 | 2014-06-19 | Exxonmobil Research And Engineering Company | Ionic liquids as lubricating oil base stocks, cobase stocks and multifunctional functional fluids |
| US20140171348A1 (en) * | 2012-12-14 | 2014-06-19 | Exxonmobil Research And Engineering Company | Ionic liquids as lubricating oil base stocks, cobase stocks and multifunctional functional fluids |
| US20140271257A1 (en) * | 2013-03-14 | 2014-09-18 | Oscomp Systems Inc. | Natural gas compressing and refueling system and method |
| US20160123636A1 (en) * | 2013-06-14 | 2016-05-05 | Siemens Aktiengesellschaft | Method for operating a heat pump and heat pump |
| US20170321142A1 (en) * | 2014-11-19 | 2017-11-09 | Nyco | Method for improving the coking resistance of a lubricating composition |
| US20180208869A1 (en) * | 2014-02-20 | 2018-07-26 | Ut-Battelle, Llc | Ionic liquids containing symmetric quaternary phosphonium cations and phosphorus-containing anions, and their use as lubricant additives |
| CN112375602A (zh) * | 2020-11-20 | 2021-02-19 | 常熟理工学院 | 一种离子液体基纳米流体切削液及其制备方法 |
| WO2023226344A1 (zh) * | 2022-05-26 | 2023-11-30 | 苏州金宏气体股份有限公司 | 离子液体组合物及其制备方法 |
| CN118994020A (zh) * | 2024-08-16 | 2024-11-22 | 中国科学院兰州化学物理研究所 | 氢压机用离子液体的合成及筛选方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2007106943A1 (en) | 2006-03-22 | 2007-09-27 | Ultraclean Fuel Pty Ltd | Process for removing sulphur from liquid hydrocarbons |
| EP2100124A1 (de) * | 2007-01-12 | 2009-09-16 | Friedrich-Alexander-Universität Erlangen-Nürnberg | Verfahren zur hochdruckpulsationsprüfung von maschinellen bauteilen |
| WO2008154997A1 (de) | 2007-06-20 | 2008-12-24 | KLüBER LUBRICATION MüNCHEN KG | Schmierfettzusammensetzung |
| EP2459579B1 (de) | 2009-07-31 | 2013-11-27 | Basf Se | Imidazolgruppenhaltige phosphinoboran-verbindungen und verfahren zur herstellung von imidazolgruppenhaltige phosphorverbindungen |
| JP5465485B2 (ja) * | 2009-08-11 | 2014-04-09 | 日本化学工業株式会社 | 潤滑油用添加剤、潤滑油組成物及びグリース組成物 |
| WO2011026822A2 (de) | 2009-09-03 | 2011-03-10 | Basf Se | Ionische flüssigkeiten mit verbesserter viskosität |
| DE102010022408B4 (de) * | 2010-06-01 | 2016-11-24 | Man Truck & Bus Ag | Verfahren und Vorrichtung zum Betrieb eines Dampfkreisprozesses mit geschmiertem Expander |
| US8703670B2 (en) | 2010-07-26 | 2014-04-22 | Basf Se | Ionic liquids having a content of ionic polymers |
| EP2598593B1 (de) | 2010-07-26 | 2014-04-23 | Basf Se | Verwendung von ionischen flüssigkeiten mit einem gehalt an ionischen polymeren |
| JP2012172030A (ja) * | 2011-02-21 | 2012-09-10 | Hitachi High-Technologies Corp | 真空装置及びそれに用いる潤滑油 |
| WO2013060579A1 (de) | 2011-10-25 | 2013-05-02 | Basf Se | Verwendung von fluessigen zusammensetzungen, welche imidazoliumsalze enthalten, als betriebsmittel |
| US9441169B2 (en) | 2013-03-15 | 2016-09-13 | Ultraclean Fuel Pty Ltd | Process for removing sulphur compounds from hydrocarbons |
| CA2906201C (en) | 2013-03-15 | 2022-05-31 | Ultraclean Fuel Pty Limited | Process for removing sulphur compounds from hydrocarbons |
| CN115605564A (zh) * | 2020-04-16 | 2023-01-13 | 道达尔能量联动技术公司(Fr) | 一种基于鏻的离子液体及其作为润滑剂添加剂的用途 |
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| US20080166243A1 (en) * | 2005-05-06 | 2008-07-10 | Michael Kotschan | Liquid for Compressing a Gaseous Medium and Use of the Same |
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| DE10316418A1 (de) * | 2003-04-10 | 2004-10-21 | Basf Ag | Verwendung einer ionischen Flüssigkeit |
| DE102004024967A1 (de) * | 2004-05-21 | 2005-12-08 | Basf Ag | Neue Absorptionsmedien für Absorptionswärmepumpen, Absorptionskältemaschinen und Wärmetransformatoren |
-
2005
- 2005-02-16 DE DE102005007100A patent/DE102005007100A1/de not_active Withdrawn
-
2006
- 2006-02-15 WO PCT/EP2006/050941 patent/WO2006087333A1/de not_active Ceased
- 2006-02-15 JP JP2007555599A patent/JP2008530441A/ja active Pending
- 2006-02-15 EP EP06708277A patent/EP1848789A1/de not_active Ceased
-
2007
- 2007-08-15 US US11/839,228 patent/US20080038123A1/en not_active Abandoned
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| US3999897A (en) * | 1973-03-22 | 1976-12-28 | Sulzer Brothers Limited | Pump supported by a fluid-isolated, liquid-lubricated thrust bearing |
| US5223164A (en) * | 1988-12-15 | 1993-06-29 | Idemitsu Kosan Co., Ltd. | Rust and corrosion preventive compositions |
| US5312459A (en) * | 1989-07-25 | 1994-05-17 | Sprugel Friedrich A | Additive for liquefied-gas fuels |
| US20020015884A1 (en) * | 2000-06-09 | 2002-02-07 | Merck Patent Gmbh | Ionic liquids II |
| US20070027038A1 (en) * | 2003-10-10 | 2007-02-01 | Idemitsu Losan Co., Ltd. | Lubricating oil |
| US20070269309A1 (en) * | 2004-09-17 | 2007-11-22 | Basf Aktiengesellschaft | Method for Operating a Liquid Ring Compressor |
| US20070258828A1 (en) * | 2004-09-24 | 2007-11-08 | Linde Aktiengesellschaft | Method and Device for Compressing a Gaseous Medium |
| US20080166243A1 (en) * | 2005-05-06 | 2008-07-10 | Michael Kotschan | Liquid for Compressing a Gaseous Medium and Use of the Same |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110253929A1 (en) * | 2008-12-22 | 2011-10-20 | Basf Se | Mixtures of hydrophobic and hydrophilic ionic liquids and use thereof in liquid ring compressors |
| US8991179B2 (en) * | 2009-07-31 | 2015-03-31 | Steamdrive Gmbh | Drive unit and method for its operation |
| US20110023483A1 (en) * | 2009-07-31 | 2011-02-03 | Voith Patent Gmbh | Drive unit and method for its operation |
| CN102732365A (zh) * | 2012-07-10 | 2012-10-17 | 广州市联诺化工科技有限公司 | 一种功能化离子液体辅助增效的水性环保切削液及其制备方法 |
| WO2014092953A1 (en) * | 2012-12-14 | 2014-06-19 | Exxonmobil Research And Engineering Company | Ionic liquids as lubricating oil base stocks, cobase stocks and multifunctional functional fluids |
| US20140171348A1 (en) * | 2012-12-14 | 2014-06-19 | Exxonmobil Research And Engineering Company | Ionic liquids as lubricating oil base stocks, cobase stocks and multifunctional functional fluids |
| US20160024414A1 (en) * | 2012-12-14 | 2016-01-28 | Exxonmobil Research And Engineering Company | Ionic liquids as lubricating oil base stocks, cobase stocks and multifunctional functional fluids |
| US20140271257A1 (en) * | 2013-03-14 | 2014-09-18 | Oscomp Systems Inc. | Natural gas compressing and refueling system and method |
| US20160123636A1 (en) * | 2013-06-14 | 2016-05-05 | Siemens Aktiengesellschaft | Method for operating a heat pump and heat pump |
| US20180208869A1 (en) * | 2014-02-20 | 2018-07-26 | Ut-Battelle, Llc | Ionic liquids containing symmetric quaternary phosphonium cations and phosphorus-containing anions, and their use as lubricant additives |
| US10435642B2 (en) * | 2014-02-20 | 2019-10-08 | Ut-Battelle, Llc. | Ionic liquids containing symmetric quaternary phosphonium cations and phosphorus-containing anions, and their use as lubricant additives |
| US20170321142A1 (en) * | 2014-11-19 | 2017-11-09 | Nyco | Method for improving the coking resistance of a lubricating composition |
| CN112375602A (zh) * | 2020-11-20 | 2021-02-19 | 常熟理工学院 | 一种离子液体基纳米流体切削液及其制备方法 |
| WO2023226344A1 (zh) * | 2022-05-26 | 2023-11-30 | 苏州金宏气体股份有限公司 | 离子液体组合物及其制备方法 |
| CN118994020A (zh) * | 2024-08-16 | 2024-11-22 | 中国科学院兰州化学物理研究所 | 氢压机用离子液体的合成及筛选方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102005007100A1 (de) | 2006-08-17 |
| EP1848789A1 (de) | 2007-10-31 |
| JP2008530441A (ja) | 2008-08-07 |
| WO2006087333A1 (de) | 2006-08-24 |
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