US2045074A - Mercerizing liquors - Google Patents
Mercerizing liquors Download PDFInfo
- Publication number
- US2045074A US2045074A US740539A US74053934A US2045074A US 2045074 A US2045074 A US 2045074A US 740539 A US740539 A US 740539A US 74053934 A US74053934 A US 74053934A US 2045074 A US2045074 A US 2045074A
- Authority
- US
- United States
- Prior art keywords
- acid
- mercerizing
- wetting
- liquors
- cymene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009736 wetting Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000007792 addition Methods 0.000 description 4
- 150000003505 terpenes Chemical class 0.000 description 4
- 235000007586 terpenes Nutrition 0.000 description 4
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical class C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- IBDVYGIGYPWWBX-WCBMZHEXSA-N (1r,3s)-1-methyl-3-propan-2-ylcyclopentane-1-carboxylic acid Chemical compound CC(C)[C@H]1CC[C@@](C)(C(O)=O)C1 IBDVYGIGYPWWBX-WCBMZHEXSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- -1 camphor carboxylic acids Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- KTSCHRREMZDLIP-UHFFFAOYSA-N 2,6,6-trimethyloxane-2,5-dicarboxylic acid Chemical compound CC1(C)OC(C)(C(O)=O)CCC1C(O)=O KTSCHRREMZDLIP-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- GLVKGYRREXOCIB-UHFFFAOYSA-N Bornylene Natural products CC1CCC(C(C)(C)C)C=C1 GLVKGYRREXOCIB-UHFFFAOYSA-N 0.000 description 1
- LSPHULWDVZXLIL-UHFFFAOYSA-N Camphoric acid Natural products CC1(C)C(C(O)=O)CCC1(C)C(O)=O LSPHULWDVZXLIL-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241000022563 Rema Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- LSPHULWDVZXLIL-QUBYGPBYSA-N camphoric acid Chemical compound CC1(C)[C@H](C(O)=O)CC[C@]1(C)C(O)=O LSPHULWDVZXLIL-QUBYGPBYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 229930007927 cymene Natural products 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical compound NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/66—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with sulfamic acid or its salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01B—MACHINES OR ENGINES, IN GENERAL OR OF POSITIVE-DISPLACEMENT TYPE, e.g. STEAM ENGINES
- F01B25/00—Regulating, controlling or safety means
- F01B25/02—Regulating or controlling by varying working-fluid admission or exhaust, e.g. by varying pressure or quantity
- F01B25/14—Regulating or controlling by varying working-fluid admission or exhaust, e.g. by varying pressure or quantity peculiar to particular kinds of machines or engines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
- Y10S516/04—Protein or carboxylic compound containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
- Y10S516/05—Organic amine, amide, or n-base containing
Definitions
- the wetting and penetrati've capacity of alkaline baths for the treatment of textiles can be considerably increased by adding to the liquid cymene-sulph amide and a monoor di-carboxylic acid of the terpene or camphor series, together with a solvent distributor.
- the quantity of the added substances may amount to 5 20 grams per liter of liquor.
- a mercerizing liquor containing-additions in accordance with the present invention has a very 'high capacity for wetting and penetrating the textile material; the concentrated alkali 7 solution takes effect very rapidly and uniformly and raw cotton which has not been de-sized can be used withoutv any pre-treatment.
- This excellent wetting action, especially in the first fifteen seconds, is'possessed by neither of the classes of substances alone.
- the wetting action may be somewhat further increased, without detracting from the general properties, by the addition of a small proportion of a hydrocarbon of the benzene series particu- 10 larly cymene.
- solvent distributorthere may be used, for example, phenol, a cresol, a xylenol, a mixture of cresols, methyl alcohoLethyl alcohol a highly sulphonated oil or the like.
- carboxylic acids of the terpene and camphor series suitable for use in the invention there may be named in particular bornylene carboxylic acid, campholic' acid, isocampholic acid, fencholic acid, oxyfencholic acid, hydropinenic 0 acid, sabinenic acid, camphoric acid, cineolic acid and so on.
- bornylene carboxylic acid campholic' acid
- isocampholic acid fencholic acid
- oxyfencholic acid oxyfencholic acid
- hydropinenic 0 acid hydropinenic 0 acid
- sabinenic acid camphoric acid
- cineolic acid cineolic acid and so on.
- Example 1 To a caustic soda solution of 30 B. are added 30 Percent Fencholic acid 5 Cymene-sulphamide 10 35 Crude ores ol The mercerizing liquor thus prepared wetsraw cotton uniformly within'a few seconds, so that the mercerizing operation may be conducted with 40 great certainty and without the faulty results which would otherwise frequently occur.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment Of Fiber Materials (AREA)
Description
Patented June 23, 1936 UNITED STATES- PATENT OFFICE MERCERIZING LIQUORS Jacques Feldmann, Basel, Switzerland, assignor to the firm of J. R. Geigy A.
zerland" G., Basel, Swit- No Drawing. Application August 18, 1934, Serial No. 740,539. In Germany September 7, 1933 10 Claims.
proceeds only slowly and lacks uniformity. Many proposals have been made for overcoming this objection, either by pretreating the textile materials, for example, by Kier boiling, or by adding to the alkaline bath a substance which imparts to it a greater capacity for wetting the material.
The use of phenols and homologues thereof for this purpose has long been known, and it has since frequently been attempted to increase the insuflicient action of these compounds by suitable additions, such as soaps, Turkey red oils, alcohols, amines, ethers and so on.
According to this invention the wetting and penetrati've capacity of alkaline baths for the treatment of textiles can be considerably increased by adding to the liquid cymene-sulph amide and a monoor di-carboxylic acid of the terpene or camphor series, together with a solvent distributor. The quantity of the added substances may amount to 5 20 grams per liter of liquor.
The addition of aromatic sulphonic and carboxylic acids to alkaline liquors, even together with a solvent distributor, has the disadvantage, explicable by the law of mass action, that the salts of these acids which are formed are only sparingly soluble owing to the high concentration of the bath in alkali and are therefore in greater part precipitated. Cymene-sulphamide exhibits specific properties in concentrated solutions of alkalies,-and moreover, as a sulphamide it is far less dependent on the aforesaid influences which limit the'solubility. It acts as an excellent solvent distributor for the alkali salts of the 'carboxylic acid of the terpene and camphor series.
A mercerizing liquor containing-additions in accordance with the present invention has a very 'high capacity for wetting and penetrating the textile material; the concentrated alkali 7 solution takes effect very rapidly and uniformly and raw cotton which has not been de-sized can be used withoutv any pre-treatment. This excellent wetting action, especially in the first fifteen seconds, is'possessed by neither of the classes of substances alone. These are indeed good wetting agents when added separately to a mercerizing liquor together with a solvent distributor, but .the terpene and camphor carboxylic acids particularly have a tendency to precipitate,
per liter 15 grams of a mixture consisting of:
so that the wetting action is greatly reduced. Only by the combination of substances of the two chemical classes is it possible to attain the rema'rkable wetting actiontogether with the other favourable properties nowadays required of a 5 wetting agent for use in mercerizing baths.
The wetting action may be somewhat further increased, without detracting from the general properties, by the addition of a small proportion of a hydrocarbon of the benzene series particu- 10 larly cymene.
As solvent distributortheremay be used, for example, phenol, a cresol, a xylenol, a mixture of cresols, methyl alcohoLethyl alcohol a highly sulphonated oil or the like. 15
Among the carboxylic acids of the terpene and camphor series suitable for use in the invention there may be named in particular bornylene carboxylic acid, campholic' acid, isocampholic acid, fencholic acid, oxyfencholic acid, hydropinenic 0 acid, sabinenic acid, camphoric acid, cineolic acid and so on. The following examples illustrate the invention, but it will be understood that the proportions given therein may vary within wide limits:
Example 1 To a caustic soda solution of 30 B. are added 30 Percent Fencholic acid 5 Cymene-sulphamide 10 35 Crude ores ol The mercerizing liquor thus prepared wetsraw cotton uniformly within'a few seconds, so that the mercerizing operation may be conducted with 40 great certainty and without the faulty results which would otherwise frequently occur.
ample 1.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE439436X | 1933-09-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2045074A true US2045074A (en) | 1936-06-23 |
Family
ID=6507311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US740539A Expired - Lifetime US2045074A (en) | 1933-09-07 | 1934-08-18 | Mercerizing liquors |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US2045074A (en) |
| BE (1) | BE404899A (en) |
| ES (1) | ES135505A1 (en) |
| FR (2) | FR439436A (en) |
| GB (1) | GB439436A (en) |
| NL (1) | NL37755C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2481693A (en) * | 1944-04-29 | 1949-09-13 | Rayonier Inc | Raw cotton for conversion into rayon |
| FR2419312A1 (en) * | 1978-03-08 | 1979-10-05 | Teyssier Micheline | PERFUMED FLAME RETARDANT COMPOSITION |
-
0
- NL NL37755D patent/NL37755C/xx active
- BE BE404899D patent/BE404899A/xx unknown
-
1912
- 1912-01-27 FR FR439436A patent/FR439436A/en not_active Expired
-
1934
- 1934-08-18 US US740539A patent/US2045074A/en not_active Expired - Lifetime
- 1934-08-29 FR FR777800D patent/FR777800A/en not_active Expired
- 1934-09-01 ES ES0135505A patent/ES135505A1/en not_active Expired
- 1934-09-05 GB GB25580/34A patent/GB439436A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2481693A (en) * | 1944-04-29 | 1949-09-13 | Rayonier Inc | Raw cotton for conversion into rayon |
| FR2419312A1 (en) * | 1978-03-08 | 1979-10-05 | Teyssier Micheline | PERFUMED FLAME RETARDANT COMPOSITION |
Also Published As
| Publication number | Publication date |
|---|---|
| FR777800A (en) | 1935-02-28 |
| FR439436A (en) | 1912-06-13 |
| NL37755C (en) | |
| GB439436A (en) | 1935-12-06 |
| ES135505A1 (en) | 1934-11-01 |
| BE404899A (en) |
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