US1990075A - Core and mold wash - Google Patents
Core and mold wash Download PDFInfo
- Publication number
- US1990075A US1990075A US656382A US65638233A US1990075A US 1990075 A US1990075 A US 1990075A US 656382 A US656382 A US 656382A US 65638233 A US65638233 A US 65638233A US 1990075 A US1990075 A US 1990075A
- Authority
- US
- United States
- Prior art keywords
- core
- cores
- wash
- mica
- castings
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 20
- 238000005266 casting Methods 0.000 description 15
- 239000010445 mica Substances 0.000 description 9
- 229910052618 mica group Inorganic materials 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 7
- 239000004927 clay Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 235000013379 molasses Nutrition 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- -1 glutrin Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052626 biotite Inorganic materials 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005058 metal casting Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910001737 paragonite Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052628 phlogopite Inorganic materials 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C3/00—Selection of compositions for coating the surfaces of moulds, cores, or patterns
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S106/00—Compositions: coating or plastic
- Y10S106/03—Mica
Definitions
- This invention relates to 'orcoatings for 'awlication' to foundry cores-"afidmolds-in j the casting of metals, wmchfr'quire a'high' particularly of "metals degree will be effective to prevent burning-in, erosion, or penetration of the metal into the sand or the f core or mold, or fusion to metal molds, gasificasurface, etc., all of which defective castings requiring tion, pitting of the result in rough and costlycleaning operations to'make them serviceable.
- the various refractory agents used heretofore include silica, graphite, magnesia, lime, aluminum oxide, fire clay, etc., and the binders such as oils, molasses, sodium silicate, starch, glutrin, pitch, resins, etc., but while most of these mixtures appear to be suitable for some particular use, they utterly fail in other situations, so that it may be said that no universal core wash has heretofore been developed nor has any practicable wash been developed which would stand up properly under the intense heat of steel casting without causing defects in the castings.
- the core wash which I have developed will stand all heats up to several thousand degrees, will permit of application of several coats and forced drying without cracking, develops no pinholes or rough spots on the castings, and always insures a smooth surfaced casting requiring the very minimum of cleaning operations to finish them, is an inexpensive mixture easily applied either by brush or spray, adheres either to sand or metal molds and cores, yet does not choke the necessary pores of fine sand cores and molds.
- the important ingredient in my compound is finely divided mica, though its combination with the other ingredients seems necessary to get the full benefits of the invention.
- the other ingredients in the formula as developed for highest heat resistance such as in steel founding) are talc, silica, and china clay (kaolin).
- the materials are all very finely ground, preferably to pass of my improved core and in the following descrip- Application-W11, Serial No. 658,382
- Chinaclay 2 I It is furnished in dry form to the foundryman' who simply mixes some of the powder with water to the consistency or cream "and applies it to the cores or molds by brushing, spraying or dipping.
- Theabove is thepreferred mixturefor use in. casting steel' where the temperatures to about 3000 F. as the coating producedby the wash has been found to resist directly applied heats as high as 6000 F. for considerable'periods oftimewithout developing faults.
- the powder is mixed with molasses water (about 1 part to 100 parts) and applied as mentioned.
- molasses water any other binder commonly used in the foundry may be used.
- the first formula given is self-bonding and after drying by the usual methods as by baking or torch will permit free handling of the cores and molds without danger of injury to the coated surfaces.
- the absence of any organic or oil binders is very important in steel castings as these are generally the cause of pinholes, blows and other surface defects.
- the second formula incorporating graphite will reduce the formation of oxides on the surface of the castings, but is subject to objectionable absorption in steel castings, sometimes giving rise to hard areas, whereas with the cores and mold coated with the first mixture the castings are as smooth as good iron castings and homogeneous in quality.
- wash is of proper consistency usually one coat will be found sufllcient, but another coat or iimnmatiy mixedin a mesh, orefiner, and the preferred two may be applied without danger of peeling, scaling, flaking, or cracking.
- sand cores protected with my improved wash will be found to collapse after casting and the sand to leave the casting easily without the aid of tools, with a result in smooth interior surfaces on the castings free from defects. The same result is secured on the exterior surfaces when the wash is applied to the molds.
- mica there are several varieties of mica such as muscovite, paragonite, lepidlite, zinnwaldite, biotite, and phlogopite, all of which when suflicient- 1y pure have been found to yield good results.
- the tale raises the heat resistance and also aids in proper mixing of the powders, and the silica seems also to combine its influence with that of the mica in raising the heat resistance of the mass, whereas the clay combines the properties of heat resistance with that of a binder able to withstand high temperatures.
- a coating for foundry cores containing finely divided mica, talc, silica and clay.
- a coating for foundry cores comprising substantially three parts 01' mica, one part of talc, one part of silica, and two parts of china. clay, all in finely divided condition intimately mixed together.
- a coating for foundry cores comprising substantially three parts of mica, one part of talc, one part of silica, and two parts of china clay, all in finely divided condition intimately mixed together and with enough water to make a paintlike mixture.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Mold Materials And Core Materials (AREA)
Description
' applied tothesurface of latented Feb. 5, 1935 PATENT OFFICE 001m AND BIOL'I) was]! Julius J. Calif asslgnorto 00-, San mm,-onm., a corporation-of Oflifomla This invention relates to 'orcoatings for 'awlication' to foundry cores-"afidmolds-in j the casting of metals, wmchfr'quire a'high' particularly of "metals degree will be effective to prevent burning-in, erosion, or penetration of the metal into the sand or the f core or mold, or fusion to metal molds, gasificasurface, etc., all of which defective castings requiring tion, pitting of the result in rough and costlycleaning operations to'make them serviceable.
Other advantages mold wash willappear tion;
As the fundamental requirements in a core wash for foundry use is a substance which can'be the core or mold which will resist the great heat of molten-metal, many attempts to produce satisfactory mixtures of finely ground refractory materials with water or other-liquid, together with a suitable binder, have been made. The various refractory agents used heretofore include silica, graphite, magnesia, lime, aluminum oxide, fire clay, etc., and the binders such as oils, molasses, sodium silicate, starch, glutrin, pitch, resins, etc., but while most of these mixtures appear to be suitable for some particular use, they utterly fail in other situations, so that it may be said that no universal core wash has heretofore been developed nor has any practicable wash been developed which would stand up properly under the intense heat of steel casting without causing defects in the castings.
The core wash which I have developed will stand all heats up to several thousand degrees, will permit of application of several coats and forced drying without cracking, develops no pinholes or rough spots on the castings, and always insures a smooth surfaced casting requiring the very minimum of cleaning operations to finish them, is an inexpensive mixture easily applied either by brush or spray, adheres either to sand or metal molds and cores, yet does not choke the necessary pores of fine sand cores and molds.
The important ingredient in my compound is finely divided mica, though its combination with the other ingredients seems necessary to get the full benefits of the invention. The other ingredients (in the formula as developed for highest heat resistance such as in steel founding) are talc, silica, and china clay (kaolin). The materials are all very finely ground, preferably to pass of my improved core and in the following descrip- Application-W11, Serial No. 658,382
, 4 cum. (on. zz- -rasy or heat temeit gihem, and the principal object ofthe invention is to provide a wash of the kind mentioned which time I a 250 proportions-are as follows:
1 mixing machine. Chinaclay 2 I It is furnished in dry form to the foundryman' who simply mixes some of the powder with water to the consistency or cream "and applies it to the cores or molds by brushing, spraying or dipping. Theabove is thepreferred mixturefor use in. casting steel' where the temperatures to about 3000 F. as the coating producedby the wash has been found to resist directly applied heats as high as 6000 F. for considerable'periods oftimewithout developing faults.
For usewith metals pouring at'lower temperatures, such ascast iron, brass, bronze, aluminum, aluminum alloys, and the non-ferrous metals generally, a modification of the compound has been found more suitable, and is as follows:
Parts g Mica 1 I J Silica 2 Intimately mixed as before. Graphite -1 The graphite to be crystalline or amorphous and of a high graphitic carbon content.
It will be noted that clay has been omitted in this mixture, as it would tend to choke the pores of the very fine sands used in some non-ferrous casting. In use the powder is mixed with molasses water (about 1 part to 100 parts) and applied as mentioned. In place of molasses water any other binder commonly used in the foundry may be used.
The first formula given is self-bonding and after drying by the usual methods as by baking or torch will permit free handling of the cores and molds without danger of injury to the coated surfaces. The absence of any organic or oil binders is very important in steel castings as these are generally the cause of pinholes, blows and other surface defects.
The second formula incorporating graphite will reduce the formation of oxides on the surface of the castings, but is subject to objectionable absorption in steel castings, sometimes giving rise to hard areas, whereas with the cores and mold coated with the first mixture the castings are as smooth as good iron castings and homogeneous in quality.
If the wash is of proper consistency usually one coat will be found sufllcient, but another coat or iimnmatiy mixedin a mesh, orefiner, and the preferred two may be applied without danger of peeling, scaling, flaking, or cracking. In all cases sand cores protected with my improved wash will be found to collapse after casting and the sand to leave the casting easily without the aid of tools, with a result in smooth interior surfaces on the castings free from defects. The same result is secured on the exterior surfaces when the wash is applied to the molds.
The micais chiefly responsible for the extraordinary results obtained with the compound and I believe it is due to the fact that this substance even though finely ground is of a scaly nature with the particles more or less in overlapping arrangement, but strange as it may seem the complete mixture appears considerably more resistant to extreme heats than any of the constituents alone.
There are several varieties of mica such as muscovite, paragonite, lepidlite, zinnwaldite, biotite, and phlogopite, all of which when suflicient- 1y pure have been found to yield good results.
The tale raises the heat resistance and also aids in proper mixing of the powders, and the silica seems also to combine its influence with that of the mica in raising the heat resistance of the mass, whereas the clay combines the properties of heat resistance with that of a binder able to withstand high temperatures.
It will be evident from a consideration of the invention, that once the formula is disclosed it is possible for anyone to vary its proportions, or incorporate other ingredients, and any such variations coming within the spirit of the invention are intended to be covered in my appended claims, and while I use the words coating for foundry cores" in my claims, this is descriptive merely and is intended to cover the mixture whether in the form of a liquid. paste or dry powder, also whether to be used on cores or molds of either sand or metal.
I therefore claim:-
1. A coating for foundry cores containing finely divided mica, talc, silica and clay.
2. A coating for foundry cores comprising substantially three parts 01' mica, one part of talc, one part of silica, and two parts of china. clay, all in finely divided condition intimately mixed together.
3. A coating for foundry cores comprising substantially three parts of mica, one part of talc, one part of silica, and two parts of china clay, all in finely divided condition intimately mixed together and with enough water to make a paintlike mixture.
4. A coating for foundry cores containing mica and clay, the mica being in prepondering amount and both ground to very fine condition adapted to mix with water to form a cream-like mixture for applying to the cores.
JULIUS J. HORAK.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US656382A US1990075A (en) | 1933-02-11 | 1933-02-11 | Core and mold wash |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US656382A US1990075A (en) | 1933-02-11 | 1933-02-11 | Core and mold wash |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1990075A true US1990075A (en) | 1935-02-05 |
Family
ID=24632792
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US656382A Expired - Lifetime US1990075A (en) | 1933-02-11 | 1933-02-11 | Core and mold wash |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1990075A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2442568A (en) * | 1945-12-08 | 1948-06-01 | Ford Motor Co | Core assembly |
| US2558411A (en) * | 1945-05-22 | 1951-06-26 | Battelle Development Corp | Ceramic coating composition, coated article, and method of making same |
| US2988454A (en) * | 1957-08-01 | 1961-06-13 | Surface Chemical Dev Corp | Mold coating |
| US3126294A (en) * | 1964-03-24 | Mold release material | ||
| US3214302A (en) * | 1961-02-22 | 1965-10-26 | Hooker Chemical Corp | Method for forming insulating coatings on metal surfaces |
| US3243397A (en) * | 1961-08-18 | 1966-03-29 | Gen Motors Corp | Mold and core coating composition from calcined hydrated aluminum silicate, mica, and bentonite |
| US3632961A (en) * | 1970-11-04 | 1972-01-04 | Us Navy | Silica-clay tooling material for welding and brazing operations |
| WO2019224070A1 (en) * | 2018-05-25 | 2019-11-28 | Ask Chemicals Gmbh | Sizing composition, method for coating a casting mould and use of the sizing composition for coating a casting mould |
-
1933
- 1933-02-11 US US656382A patent/US1990075A/en not_active Expired - Lifetime
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3126294A (en) * | 1964-03-24 | Mold release material | ||
| US2558411A (en) * | 1945-05-22 | 1951-06-26 | Battelle Development Corp | Ceramic coating composition, coated article, and method of making same |
| US2442568A (en) * | 1945-12-08 | 1948-06-01 | Ford Motor Co | Core assembly |
| US2988454A (en) * | 1957-08-01 | 1961-06-13 | Surface Chemical Dev Corp | Mold coating |
| US3214302A (en) * | 1961-02-22 | 1965-10-26 | Hooker Chemical Corp | Method for forming insulating coatings on metal surfaces |
| US3243397A (en) * | 1961-08-18 | 1966-03-29 | Gen Motors Corp | Mold and core coating composition from calcined hydrated aluminum silicate, mica, and bentonite |
| US3632961A (en) * | 1970-11-04 | 1972-01-04 | Us Navy | Silica-clay tooling material for welding and brazing operations |
| WO2019224070A1 (en) * | 2018-05-25 | 2019-11-28 | Ask Chemicals Gmbh | Sizing composition, method for coating a casting mould and use of the sizing composition for coating a casting mould |
| CN112334246A (en) * | 2018-05-25 | 2021-02-05 | Ask化学品股份有限公司 | Coating composition, method for coating casting moulds and use of said coating composition for coating casting moulds |
| EP4147804A1 (en) * | 2018-05-25 | 2023-03-15 | ASK Chemicals GmbH | Sizing composition, method for coating a casting mould and use of the sizing composition for coating a casting mould |
| CN112334246B (en) * | 2018-05-25 | 2023-04-28 | Ask化学品股份有限公司 | Coating composition, method for coating a casting mould, and use of said coating composition for coating a casting mould |
| EP3801949B1 (en) | 2018-05-25 | 2024-02-14 | ASK Chemicals GmbH | Coating composition, process for coating a casting mold and use of the coating composition for coating a casting mold |
| US12157163B2 (en) | 2018-05-25 | 2024-12-03 | Ask Chemicals Gmbh | Sizing composition, method for coating a casting mould and use of the sizing composition for coating a casting mould |
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