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US1990075A - Core and mold wash - Google Patents

Core and mold wash Download PDF

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Publication number
US1990075A
US1990075A US656382A US65638233A US1990075A US 1990075 A US1990075 A US 1990075A US 656382 A US656382 A US 656382A US 65638233 A US65638233 A US 65638233A US 1990075 A US1990075 A US 1990075A
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US
United States
Prior art keywords
core
cores
wash
mica
castings
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US656382A
Inventor
Julius J Herak
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QUANDT CHEMICAL CO
Original Assignee
QUANDT CHEMICAL CO
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QUANDT CHEMICAL CO filed Critical QUANDT CHEMICAL CO
Priority to US656382A priority Critical patent/US1990075A/en
Application granted granted Critical
Publication of US1990075A publication Critical patent/US1990075A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C3/00Selection of compositions for coating the surfaces of moulds, cores, or patterns
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S106/00Compositions: coating or plastic
    • Y10S106/03Mica

Definitions

  • This invention relates to 'orcoatings for 'awlication' to foundry cores-"afidmolds-in j the casting of metals, wmchfr'quire a'high' particularly of "metals degree will be effective to prevent burning-in, erosion, or penetration of the metal into the sand or the f core or mold, or fusion to metal molds, gasificasurface, etc., all of which defective castings requiring tion, pitting of the result in rough and costlycleaning operations to'make them serviceable.
  • the various refractory agents used heretofore include silica, graphite, magnesia, lime, aluminum oxide, fire clay, etc., and the binders such as oils, molasses, sodium silicate, starch, glutrin, pitch, resins, etc., but while most of these mixtures appear to be suitable for some particular use, they utterly fail in other situations, so that it may be said that no universal core wash has heretofore been developed nor has any practicable wash been developed which would stand up properly under the intense heat of steel casting without causing defects in the castings.
  • the core wash which I have developed will stand all heats up to several thousand degrees, will permit of application of several coats and forced drying without cracking, develops no pinholes or rough spots on the castings, and always insures a smooth surfaced casting requiring the very minimum of cleaning operations to finish them, is an inexpensive mixture easily applied either by brush or spray, adheres either to sand or metal molds and cores, yet does not choke the necessary pores of fine sand cores and molds.
  • the important ingredient in my compound is finely divided mica, though its combination with the other ingredients seems necessary to get the full benefits of the invention.
  • the other ingredients in the formula as developed for highest heat resistance such as in steel founding) are talc, silica, and china clay (kaolin).
  • the materials are all very finely ground, preferably to pass of my improved core and in the following descrip- Application-W11, Serial No. 658,382
  • Chinaclay 2 I It is furnished in dry form to the foundryman' who simply mixes some of the powder with water to the consistency or cream "and applies it to the cores or molds by brushing, spraying or dipping.
  • Theabove is thepreferred mixturefor use in. casting steel' where the temperatures to about 3000 F. as the coating producedby the wash has been found to resist directly applied heats as high as 6000 F. for considerable'periods oftimewithout developing faults.
  • the powder is mixed with molasses water (about 1 part to 100 parts) and applied as mentioned.
  • molasses water any other binder commonly used in the foundry may be used.
  • the first formula given is self-bonding and after drying by the usual methods as by baking or torch will permit free handling of the cores and molds without danger of injury to the coated surfaces.
  • the absence of any organic or oil binders is very important in steel castings as these are generally the cause of pinholes, blows and other surface defects.
  • the second formula incorporating graphite will reduce the formation of oxides on the surface of the castings, but is subject to objectionable absorption in steel castings, sometimes giving rise to hard areas, whereas with the cores and mold coated with the first mixture the castings are as smooth as good iron castings and homogeneous in quality.
  • wash is of proper consistency usually one coat will be found sufllcient, but another coat or iimnmatiy mixedin a mesh, orefiner, and the preferred two may be applied without danger of peeling, scaling, flaking, or cracking.
  • sand cores protected with my improved wash will be found to collapse after casting and the sand to leave the casting easily without the aid of tools, with a result in smooth interior surfaces on the castings free from defects. The same result is secured on the exterior surfaces when the wash is applied to the molds.
  • mica there are several varieties of mica such as muscovite, paragonite, lepidlite, zinnwaldite, biotite, and phlogopite, all of which when suflicient- 1y pure have been found to yield good results.
  • the tale raises the heat resistance and also aids in proper mixing of the powders, and the silica seems also to combine its influence with that of the mica in raising the heat resistance of the mass, whereas the clay combines the properties of heat resistance with that of a binder able to withstand high temperatures.
  • a coating for foundry cores containing finely divided mica, talc, silica and clay.
  • a coating for foundry cores comprising substantially three parts 01' mica, one part of talc, one part of silica, and two parts of china. clay, all in finely divided condition intimately mixed together.
  • a coating for foundry cores comprising substantially three parts of mica, one part of talc, one part of silica, and two parts of china clay, all in finely divided condition intimately mixed together and with enough water to make a paintlike mixture.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Mold Materials And Core Materials (AREA)

Description

' applied tothesurface of latented Feb. 5, 1935 PATENT OFFICE 001m AND BIOL'I) was]! Julius J. Calif asslgnorto 00-, San mm,-onm., a corporation-of Oflifomla This invention relates to 'orcoatings for 'awlication' to foundry cores-"afidmolds-in j the casting of metals, wmchfr'quire a'high' particularly of "metals degree will be effective to prevent burning-in, erosion, or penetration of the metal into the sand or the f core or mold, or fusion to metal molds, gasificasurface, etc., all of which defective castings requiring tion, pitting of the result in rough and costlycleaning operations to'make them serviceable.
Other advantages mold wash willappear tion;
As the fundamental requirements in a core wash for foundry use is a substance which can'be the core or mold which will resist the great heat of molten-metal, many attempts to produce satisfactory mixtures of finely ground refractory materials with water or other-liquid, together with a suitable binder, have been made. The various refractory agents used heretofore include silica, graphite, magnesia, lime, aluminum oxide, fire clay, etc., and the binders such as oils, molasses, sodium silicate, starch, glutrin, pitch, resins, etc., but while most of these mixtures appear to be suitable for some particular use, they utterly fail in other situations, so that it may be said that no universal core wash has heretofore been developed nor has any practicable wash been developed which would stand up properly under the intense heat of steel casting without causing defects in the castings.
The core wash which I have developed will stand all heats up to several thousand degrees, will permit of application of several coats and forced drying without cracking, develops no pinholes or rough spots on the castings, and always insures a smooth surfaced casting requiring the very minimum of cleaning operations to finish them, is an inexpensive mixture easily applied either by brush or spray, adheres either to sand or metal molds and cores, yet does not choke the necessary pores of fine sand cores and molds.
The important ingredient in my compound is finely divided mica, though its combination with the other ingredients seems necessary to get the full benefits of the invention. The other ingredients (in the formula as developed for highest heat resistance such as in steel founding) are talc, silica, and china clay (kaolin). The materials are all very finely ground, preferably to pass of my improved core and in the following descrip- Application-W11, Serial No. 658,382
, 4 cum. (on. zz- -rasy or heat temeit gihem, and the principal object ofthe invention is to provide a wash of the kind mentioned which time I a 250 proportions-are as follows:
1 mixing machine. Chinaclay 2 I It is furnished in dry form to the foundryman' who simply mixes some of the powder with water to the consistency or cream "and applies it to the cores or molds by brushing, spraying or dipping. Theabove is thepreferred mixturefor use in. casting steel' where the temperatures to about 3000 F. as the coating producedby the wash has been found to resist directly applied heats as high as 6000 F. for considerable'periods oftimewithout developing faults.
For usewith metals pouring at'lower temperatures, such ascast iron, brass, bronze, aluminum, aluminum alloys, and the non-ferrous metals generally, a modification of the compound has been found more suitable, and is as follows:
Parts g Mica 1 I J Silica 2 Intimately mixed as before. Graphite -1 The graphite to be crystalline or amorphous and of a high graphitic carbon content.
It will be noted that clay has been omitted in this mixture, as it would tend to choke the pores of the very fine sands used in some non-ferrous casting. In use the powder is mixed with molasses water (about 1 part to 100 parts) and applied as mentioned. In place of molasses water any other binder commonly used in the foundry may be used.
The first formula given is self-bonding and after drying by the usual methods as by baking or torch will permit free handling of the cores and molds without danger of injury to the coated surfaces. The absence of any organic or oil binders is very important in steel castings as these are generally the cause of pinholes, blows and other surface defects.
The second formula incorporating graphite will reduce the formation of oxides on the surface of the castings, but is subject to objectionable absorption in steel castings, sometimes giving rise to hard areas, whereas with the cores and mold coated with the first mixture the castings are as smooth as good iron castings and homogeneous in quality.
If the wash is of proper consistency usually one coat will be found sufllcient, but another coat or iimnmatiy mixedin a mesh, orefiner, and the preferred two may be applied without danger of peeling, scaling, flaking, or cracking. In all cases sand cores protected with my improved wash will be found to collapse after casting and the sand to leave the casting easily without the aid of tools, with a result in smooth interior surfaces on the castings free from defects. The same result is secured on the exterior surfaces when the wash is applied to the molds.
The micais chiefly responsible for the extraordinary results obtained with the compound and I believe it is due to the fact that this substance even though finely ground is of a scaly nature with the particles more or less in overlapping arrangement, but strange as it may seem the complete mixture appears considerably more resistant to extreme heats than any of the constituents alone.
There are several varieties of mica such as muscovite, paragonite, lepidlite, zinnwaldite, biotite, and phlogopite, all of which when suflicient- 1y pure have been found to yield good results.
The tale raises the heat resistance and also aids in proper mixing of the powders, and the silica seems also to combine its influence with that of the mica in raising the heat resistance of the mass, whereas the clay combines the properties of heat resistance with that of a binder able to withstand high temperatures.
It will be evident from a consideration of the invention, that once the formula is disclosed it is possible for anyone to vary its proportions, or incorporate other ingredients, and any such variations coming within the spirit of the invention are intended to be covered in my appended claims, and while I use the words coating for foundry cores" in my claims, this is descriptive merely and is intended to cover the mixture whether in the form of a liquid. paste or dry powder, also whether to be used on cores or molds of either sand or metal.
I therefore claim:-
1. A coating for foundry cores containing finely divided mica, talc, silica and clay.
2. A coating for foundry cores comprising substantially three parts 01' mica, one part of talc, one part of silica, and two parts of china. clay, all in finely divided condition intimately mixed together.
3. A coating for foundry cores comprising substantially three parts of mica, one part of talc, one part of silica, and two parts of china clay, all in finely divided condition intimately mixed together and with enough water to make a paintlike mixture.
4. A coating for foundry cores containing mica and clay, the mica being in prepondering amount and both ground to very fine condition adapted to mix with water to form a cream-like mixture for applying to the cores.
JULIUS J. HORAK.
US656382A 1933-02-11 1933-02-11 Core and mold wash Expired - Lifetime US1990075A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2442568A (en) * 1945-12-08 1948-06-01 Ford Motor Co Core assembly
US2558411A (en) * 1945-05-22 1951-06-26 Battelle Development Corp Ceramic coating composition, coated article, and method of making same
US2988454A (en) * 1957-08-01 1961-06-13 Surface Chemical Dev Corp Mold coating
US3126294A (en) * 1964-03-24 Mold release material
US3214302A (en) * 1961-02-22 1965-10-26 Hooker Chemical Corp Method for forming insulating coatings on metal surfaces
US3243397A (en) * 1961-08-18 1966-03-29 Gen Motors Corp Mold and core coating composition from calcined hydrated aluminum silicate, mica, and bentonite
US3632961A (en) * 1970-11-04 1972-01-04 Us Navy Silica-clay tooling material for welding and brazing operations
WO2019224070A1 (en) * 2018-05-25 2019-11-28 Ask Chemicals Gmbh Sizing composition, method for coating a casting mould and use of the sizing composition for coating a casting mould

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3126294A (en) * 1964-03-24 Mold release material
US2558411A (en) * 1945-05-22 1951-06-26 Battelle Development Corp Ceramic coating composition, coated article, and method of making same
US2442568A (en) * 1945-12-08 1948-06-01 Ford Motor Co Core assembly
US2988454A (en) * 1957-08-01 1961-06-13 Surface Chemical Dev Corp Mold coating
US3214302A (en) * 1961-02-22 1965-10-26 Hooker Chemical Corp Method for forming insulating coatings on metal surfaces
US3243397A (en) * 1961-08-18 1966-03-29 Gen Motors Corp Mold and core coating composition from calcined hydrated aluminum silicate, mica, and bentonite
US3632961A (en) * 1970-11-04 1972-01-04 Us Navy Silica-clay tooling material for welding and brazing operations
WO2019224070A1 (en) * 2018-05-25 2019-11-28 Ask Chemicals Gmbh Sizing composition, method for coating a casting mould and use of the sizing composition for coating a casting mould
CN112334246A (en) * 2018-05-25 2021-02-05 Ask化学品股份有限公司 Coating composition, method for coating casting moulds and use of said coating composition for coating casting moulds
EP4147804A1 (en) * 2018-05-25 2023-03-15 ASK Chemicals GmbH Sizing composition, method for coating a casting mould and use of the sizing composition for coating a casting mould
CN112334246B (en) * 2018-05-25 2023-04-28 Ask化学品股份有限公司 Coating composition, method for coating a casting mould, and use of said coating composition for coating a casting mould
EP3801949B1 (en) 2018-05-25 2024-02-14 ASK Chemicals GmbH Coating composition, process for coating a casting mold and use of the coating composition for coating a casting mold
US12157163B2 (en) 2018-05-25 2024-12-03 Ask Chemicals Gmbh Sizing composition, method for coating a casting mould and use of the sizing composition for coating a casting mould

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