US10815147B2 - Substrate provided with a stack having thermal properties - Google Patents
Substrate provided with a stack having thermal properties Download PDFInfo
- Publication number
- US10815147B2 US10815147B2 US15/742,360 US201615742360A US10815147B2 US 10815147 B2 US10815147 B2 US 10815147B2 US 201615742360 A US201615742360 A US 201615742360A US 10815147 B2 US10815147 B2 US 10815147B2
- Authority
- US
- United States
- Prior art keywords
- layer
- dielectric
- functional
- thickness
- glazing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 35
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Classifications
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- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
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- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/0021—Reactive sputtering or evaporation
- C23C14/0036—Reactive sputtering
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0641—Nitrides
- C23C14/0652—Silicon nitride
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/083—Oxides of refractory metals or yttrium
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/086—Oxides of zinc, germanium, cadmium, indium, tin, thallium or bismuth
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/18—Metallic material, boron or silicon on other inorganic substrates
- C23C14/185—Metallic material, boron or silicon on other inorganic substrates by cathodic sputtering
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/3464—Sputtering using more than one target
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/28—Interference filters
- G02B5/281—Interference filters designed for the infrared light
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/416—Reflective
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
Definitions
- the invention relates to a material, such as a glazing, comprising a transparent substrate coated with a stack of thin layers comprising several functional layers that can influence solar radiation and/or infrared radiation.
- a material such as a glazing
- the invention also relates to glazings comprising these materials and also to the use of such materials for manufacturing thermal insulation and/or solar protection glazings.
- These glazings may be intended to equip both buildings and vehicles, for the purpose in particular of reducing the air-conditioning load and/or of preventing excessive overheating, which glazings are referred to as “solar control” glazings, and/or to reduce the amount of energy dissipated to the outside, which glazings are referred to as “low-emissivity” glazings, driven by the ever-increasing size of glazed surfaces in buildings and vehicle passenger compartments.
- the desired performance in terms of light transmission and solar factor may vary within a certain range.
- the light transmission must be low enough to eliminate glare and high enough so that the reduction in the amount of light penetrating inside the space delimited by said glazing does not make it necessary to use artificial light.
- glazings having a light transmission of the order of 50% and sufficiently low solar factor values.
- Glazings comprising transparent substrates coated with a stack of thin layers comprising three functional metallic layers, each positioned between two dielectric coatings, have been proposed in order to improve the solar protection while retaining a sufficient light transmission. These stacks are generally obtained by a series of depositions carried out by sputtering, optionally magnetron sputtering. These glazings are described as selective since they make it possible:
- the materials currently on the market that make it possible to obtain this shiny silver appearance in reflection on the external side comprise:
- the objective of the invention is to develop a material having both a shiny silver appearance and exceptional solar control properties. According to the invention, it is therefore sought to minimize the solar factor and to increase the selectivity, while keeping a light transmission suitable for allowing good insulation and good vision.
- the complexity of the stacks comprising three functional layers makes it difficult to improve these reflection properties without adversely affecting the solar control performance.
- the Applicant has surprisingly discovered that by optimizing the thicknesses of the three functional layers and by selecting a dielectric coating, located between the substrate and the first functional layer, that is relatively thick, a material capable of exhibiting the desired properties is obtained.
- the shiny silver appearance and a high reflection on the external side may in particular be obtained.
- the solution of the invention represents an excellent compromise between the optical performance, thermal performance, transparency and esthetic appearance.
- One subject of the invention is a material comprising a transparent substrate coated with a stack of thin layers successively comprising, starting from the substrate, an alternation of three silver-based functional metallic layers referred to, starting from the substrate, as first, second and third functional layers and of four dielectric coatings, referred to, starting from the substrate, as M1, M2, M3 and M4, each dielectric coating comprising at least one dielectric layer, so that each functional metallic layer is positioned between two dielectric coatings, characterized in that:
- the invention also relates to:
- the transparency of the glazing may be controlled so as to obtain T L values of the order of 50%, which range is very particularly suitable for glazings intended to be used in high-sunshine regions.
- T L values of the order of 50%, which range is very particularly suitable for glazings intended to be used in high-sunshine regions.
- the major advantage of the invention is that obtaining the satisfactory visual appearance with in particular specific colors in external reflection and sufficiently high external reflection values does not take place to the detriment of the solar protection performance.
- the refractive indices are measured at a wavelength of 550 nm.
- the light transmission T L and light reflection R L factors are measured under the illuminant D65 with a field of vision of 2°.
- a double glazing consisting of a 6 mm standard soda-lime glass substrate bearing the stack of thin layers, a 16 mm interlayer space filled with argon in a proportion of 90% and air in a proportion of 10% and another soda-lime glass substrate that is not coated and that has a thickness of 4 mm.
- the coated substrate is placed so that the stack of thin layers is on face 2 of the glazing.
- the external reflection Rext. is observed from the side of the substrate comprising the stack, whilst the reflection observed from the side of the substrate not comprising the stack is designated as the internal reflection.
- the light transmission (T L ) of standard soda-lime glass substrates, with no stack, is greater than 89%, preferably 90%.
- the thicknesses stated in the present document with no other specifications are physical, real or geometric thicknesses referred to as Ep and are expressed in nanometers (and not optical thicknesses).
- the optical thickness of the dielectric coating corresponds to the sum of the optical thicknesses of the various dielectric layers forming the dielectric coating.
- the substrate according to the invention is considered to be positioned horizontally.
- the stack of thin layers is deposited on top of the substrate.
- the meaning of the expressions “on top of” and “underneath” and “lower” and “upper” should be considered relative to this orientation.
- the expressions “on top of” and “underneath” do not necessarily mean that two layers and/or coatings are positioned in contact with one another. When it is specified that a layer is deposited “in contact” with another layer or with a coating, this means that there cannot be one (or more) layer(s) inserted between these two layers (or layer and coating).
- the labels “first”, “second”, “third” and “fourth” for the functional layers or the dielectric coatings are defined starting from the substrate bearing the stack and with reference to the layers or coatings having the same function.
- the functional layer closest to the substrate is the first functional layer
- the next one moving away from the substrate is the second functional layer, etc.
- the invention also relates to a glazing comprising a material according to the invention.
- the faces of a glazing are denoted starting from the outside of the building and by numbering the faces of the substrates from the outside towards the inside of the passenger compartment or room that it equips. This means that the incident solar light passes through the faces in the increasing order of their number.
- the stack is preferably positioned in the glazing so that the incident light coming from outside passes through the first dielectric coating before passing through the first functional metallic layer.
- the stack is not deposited on the face of the substrate that defines the external wall of the glazing but on the inner face of this substrate.
- the stack is therefore advantageously positioned on face 2, face 1 of the glazing being the outermost face of the glazing, as is customary.
- the relatively thick first dielectric coating (M1) is located between the outside and all the silver-based functional layers of the stack. Surprisingly, it appears that such a coating, placed at this location, makes it possible to obtain the combination of the desired properties and in particular a high reflection and a shiny silver appearance on the external side while maintaining the excellent energy performance and without requiring substantial modifications of the other parameters of the stack such as the nature, thickness and sequence of the layers forming it.
- the stack is deposited by magnetron sputtering.
- all the layers of the stack are deposited by magnetron sputtering.
- the invention also relates to the process for obtaining a material according to the invention, wherein the layers of the stack are deposited by magnetron sputtering.
- the silver-based functional metallic layers comprise at least 95.0%, preferably at least 96.5% and better still at least 98.0% by weight of silver relative to the weight of the functional layer.
- the silver-based functional metallic layer comprises less than 1.0% by weight of metals other than silver relative to the weight of the silver-based functional metallic layer.
- the functional metallic layers satisfy one or more of the following conditions:
- These thickness ranges for the functional metallic layers are the ranges for which the best results are obtained for a light transmission in double glazing of around 50%, a high light reflection and a low solar factor. A high selectivity is thus obtained.
- the glazing has a light transmission of less than 60.0% and/or a light reflection on the external side of greater than or equal to 20.0%.
- the stack may also comprise at least one blocking layer located in contact with a functional layer.
- the role of the blocking layers is conventionally to protect the functional layers from a possible degradation during the deposition of the upper antireflection coating and during an optional high-temperature heat treatment of the annealing, bending and/or tempering type.
- the blocking layers are selected from metallic layers based on a metal or on a metal alloy, metal nitride layers, metal oxide layers and metal oxynitride layers of one or more elements selected from titanium, nickel, chromium and niobium, such as Ti, TiN, TiOx, Nb, NbN, Ni, NiN, Cr, CrN, NiCr or NiCrN.
- these blocking layers When these blocking layers are deposited in metallic, nitride or oxynitride form, these layers may undergo a partial or complete oxidation depending on their thickness and the nature of the layers that surround them, for example, at the time of the deposition of the next layer or by oxidation in contact with the underlying layer.
- the blocking layer(s) satisfy one or more of the following conditions:
- the dielectric coatings satisfy one or more of the following conditions in terms of thicknesses:
- the dielectric coatings satisfy one or more of the following conditions:
- each dielectric coating consists only of one or more dielectric layers.
- the stacks of the invention may comprise dielectric layers having a barrier function.
- the term “dielectric layers having a barrier function” is understood to mean a layer made of a material capable of forming a barrier to the diffusion of oxygen and water at high temperature, originating from the ambient atmosphere or from the transparent substrate, toward the functional layer.
- the constituent materials of the dielectric layer having a barrier function thus must not undergo chemical or structural modification at high temperature which would result in a modification to their optical properties.
- the layer or layers having a barrier function are preferably also selected from a material capable of forming a barrier to the constituent material of the functional layer.
- the dielectric layers having a barrier function thus allow the stack to be subjected, without excessively significant optical change, to heat treatments of the annealing, tempering or bending type.
- the stacks of the invention may comprise dielectric layers having a stabilizing function.
- stabilizing means that the nature of the layer is selected so as to stabilize the interface between the functional layer and this layer. This stabilization results in the reinforcing of the adhesion of the functional layer to the layers which surround it and thus it will oppose the migration of its constituent material.
- the dielectric layer(s) having a stabilizing function may be directly in contact with a functional layer or separated by a blocking layer.
- the final dielectric layer of each dielectric coating located underneath a functional layer is a dielectric layer having a stabilizing function.
- a layer having a stabilizing function for example, based on zinc oxide underneath a functional layer, as it facilitates the adhesion and the crystallization of the silver-based functional layer and increases its quality and its stability at high temperature.
- a layer having a stabilizing function for example, based on zinc oxide on top of a functional layer, in order to increase the adhesion thereof and to optimally oppose the diffusion from the side of the stack opposite the substrate.
- the dielectric layer(s) having a stabilizing function may thus be on top of and/or underneath at least one functional layer or each functional layer, either directly in contact therewith or separated by a blocking layer.
- each dielectric layer having a barrier function is separated from a functional layer by at least one dielectric layer having a stabilizing function.
- This dielectric layer having a stabilizing function may have a thickness of at least 4 nm, in particular a thickness of between 4 and 10 nm and better still from 8 to 10 nm.
- the stack of thin layers may optionally comprise a protective layer.
- the protective layer is preferably the final layer of the stack, that is to say the layer furthest from the substrate coated with the stack.
- These upper protective layers are considered to be included in the fourth dielectric coating. These layers in general have a thickness of between 2 and 10 nm, preferably 2 and 5 nm.
- This protective layer may be selected from a layer of titanium, zirconium, hafnium, zinc and/or tin, this or these metals being in metallic, oxide or nitride form.
- the protective layer may for example be selected from a titanium oxide layer, a zinc tin oxide layer or a titanium zirconium oxide layer.
- One particularly advantageous embodiment relates to a substrate coated with a stack, defined starting from the transparent substrate, comprising:
- the transparent substrates according to the invention are preferably made of an inorganic rigid material, such as glass, or an organic material based on polymers (or made of polymer).
- the organic transparent substrates according to the invention may also be made of rigid or flexible polymers.
- Examples of polymers that are suitable according to the invention include, in particular:
- the substrate is preferably a sheet of glass or of glass-ceramic.
- the substrate is preferably transparent, colorless (it is then a clear or extra-clear glass) or colored, for example colored blue, grey or bronze.
- the glass is preferably of soda-lime-silica type, but it may also be made of glass of borosilicate or alumino-borosilicate type.
- the substrate advantageously has at least one dimension greater than or equal to 1 m, or even 2 m and even 3 m.
- the thickness of the substrate generally varies between 0.5 mm and 19 mm, preferably between 0.7 and 9 mm, in particular between 2 and 8 mm, or even between 4 and 6 mm.
- the substrate may be flat or curved, or even flexible.
- the material may undergo a high-temperature heat treatment such as an annealing, for example a flash annealing such as a laser or flame annealing, a tempering and/or a bending.
- a high-temperature heat treatment such as an annealing, for example a flash annealing such as a laser or flame annealing, a tempering and/or a bending.
- the temperature of the heat treatment is greater than 400° C., preferably greater than 450° C., and better still greater than 500° C.
- the substrate coated with the stack may therefore be curved and/or tempered.
- the glazing of the invention may be in the form of monolithic, laminated or multiple glazing, in particular double glazing or triple glazing.
- the stack is preferably deposited on face 2, that is to say that it is on the substrate that defines the external wall of the glazing and more specifically on the inner face of this substrate.
- a monolithic glazing comprises 2 faces; face 1 is on the outside of the building and therefore constitutes the external wall of the glazing, face 2 is on the inside of the building and therefore constitutes the internal wall of the glazing.
- a multiple glazing comprises at least two substrates kept at a distance so as to delimit a cavity filled by an insulating gas.
- the materials according to the invention are very particularly suitable when they are used in double glazings with enhanced thermal insulation (ETI).
- a double glazing comprises 4 faces; face 1 is outside of the building and therefore constitutes the external wall of the glazing, face 4 is inside the building and therefore constitutes the internal wall of the glazing, faces 2 and 3 being on the inside of the double glazing.
- a triple glazing comprises 6 faces; face 1 is outside of the building (external wall of the glazing), face 6 is inside the building (internal wall of the glazing) and faces 2 to 5 are on the inside of the triple glazing.
- a laminated glazing comprises at least one structure of first substrate/sheet(s)/second substrate type.
- the stack of thin layers is positioned on at least one of the faces of one of the substrates.
- the stack may be on the face of the second substrate not in contact with the, preferably polymer, sheet. This embodiment is advantageous when the laminated glazing is assembled as double glazing with a third substrate.
- the glazing according to the invention used as monolithic glazing or in a multiple glazing of double glazing type, has neutral, pleasant and subdued colors in external reflection, within the range of blues or blue-greens (values for dominant wavelength of the order of 470 to 500 nanometers). Furthermore, this visual appearance remains virtually unchanged irrespective of the angle of incidence with which the glazing is observed (normal incidence and under an angle). This means that an observer does not have the impression of a significant lack of uniformity in color or in appearance.
- color in the blue-green should be understood as meaning, within the meaning of the present invention, that, in the L*a*b* color measurement system, a* is between ⁇ 10.0 and 0.0, preferably between ⁇ 5.0 and 0.0, and b* is between ⁇ 10.0 and 0.0, preferably between ⁇ 5.0 and 0.0.
- the glazing of the invention has colors in reflection on the external side in the L*a*b* color measurement system:
- the glazing of the invention has colors in transmission in the L*a*b* color measurement system with a* between ⁇ 6.0 and 0.0, preferably between ⁇ 5.0 and 0.0.
- the glazing of the invention in the form of a double glazing comprising the stack positioned on face 2 makes it possible to achieve, in particular, the following performances:
- FIG. 1 illustrates a structure of a stack having three functional metallic layers 40 , 80 , 120 , this structure being deposited on a transparent glass substrate 10 .
- Each functional layer 40 , 80 , 120 is positioned between two dielectric coatings 20 , 60 , 100 , 140 such that:
- These dielectric coatings 20 , 60 , 100 , 140 each comprise at least one dielectric layer 24 , 28 ; 62 , 64 , 68 ; 102 , 104 , 108 ; 142 , 144 .
- the stack may also comprise:
- Stacks, defined below, of thin layers are deposited on substrates made of clear soda-lime glass with a thickness of 6 mm.
- Table 2 lists the materials and the physical thicknesses in nanometers (unless otherwise indicated) for each layer or coating that forms the stacks as a function of their position with respect to the substrate bearing the stack (final line at the bottom of the table).
- the “Ref.” numbers correspond to the references from FIG. 1 .
- Each dielectric coating 20 , 60 , 100 underneath a functional layer 40 , 80 , 120 comprises a final stabilizing layer 28 , 68 , 108 based on crystalline zinc oxide, and which is in contact with the functional layer 40 , 80 , 120 deposited immediately on top.
- Each dielectric coating 60 , 100 , 140 on top of a functional layer 40 , 80 , 120 comprises a first stabilizing layer 62 , 102 , 142 based on crystalline zinc oxide, and which is in contact with the functional layer 40 , 80 , 120 deposited immediately on top.
- Each dielectric coating 20 , 60 , 100 , 140 comprises a dielectric layer having a barrier function 24 , 64 , 104 , 144 , based on silica nitride, doped with aluminum, referred to here as Si 3 N 4 .
- Each functional metallic layer 40 , 80 , 120 is underneath and in contact with a blocking layer 50 , 90 and 130 .
- Each functional metallic layer 40 , 80 , 120 may be on top of a blocking layer 30 , 70 and 110 (not represented in FIG. 1 ).
- the stack also comprises a protective layer made of titanium zirconium oxide 160 (not represented in FIG. 1 ).
- Table 3 summarizes the characteristics linked to the thicknesses of the functional layers and of the dielectric coatings.
- Table 4 lists the main optical characteristics measured when the glazings are part of double glazing having a 6/16/4 structure: 6 mm glass/16 mm interlayer space 90% filled with argon/4 mm glass, the stack being positioned on face 2 (face 1 of the glazing being the outermost face of the glazing, as is customary).
- the colorimetric values at an angle a*g60° and b*g60° are measured on single glazing under an incidence of 60°. This takes into account the neutrality of the colors at an angle.
- a glazing comprising a stack having three functional metallic layers which has a shiny silver appearance in reflection on the external side, a light transmission of around 50%, a high selectivity, a high light reflection and a low solar factor.
- the examples according to the invention all have a pleasant and subdued color in transmission, preferably in the range of blues or blue-greens.
- the glazings according to the invention have both a solar factor of less than or equal to 25% and a selectivity of greater than 1.80. These glazings additionally have an external reflection of at least greater than 25%, or even less than 27.5%. These glazings also have neutral colors in transmission.
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- General Physics & Mathematics (AREA)
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1556483A FR3038598B1 (fr) | 2015-07-08 | 2015-07-08 | Substrat muni d'un empilement a proprietes thermiques |
| FR1556483 | 2015-07-08 | ||
| PCT/FR2016/051653 WO2017006030A1 (fr) | 2015-07-08 | 2016-06-30 | Substrat muni d'un empilement a proprietes thermiques |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20180194677A1 US20180194677A1 (en) | 2018-07-12 |
| US10815147B2 true US10815147B2 (en) | 2020-10-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US15/742,360 Active 2036-12-14 US10815147B2 (en) | 2015-07-08 | 2016-06-30 | Substrate provided with a stack having thermal properties |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10815147B2 (fr) |
| EP (1) | EP3319917B1 (fr) |
| JP (1) | JP2018519239A (fr) |
| KR (1) | KR102592541B1 (fr) |
| CN (1) | CN107810170A (fr) |
| BR (1) | BR112017027581B1 (fr) |
| CO (1) | CO2017013531A2 (fr) |
| FR (1) | FR3038598B1 (fr) |
| MX (1) | MX2017016712A (fr) |
| RU (1) | RU2708304C2 (fr) |
| WO (1) | WO2017006030A1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11208349B2 (en) * | 2018-03-08 | 2021-12-28 | Saint-Gobain Glass France | Material provided with a stack having thermal properties |
| US20240262740A1 (en) * | 2021-04-12 | 2024-08-08 | Saint-Gobain Glass France | Substrate provided with a stack having thermal properties |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10196735B2 (en) * | 2017-03-03 | 2019-02-05 | Guardian Glass, LLC | Coated article having low-E coating with IR reflecting layer(s) and doped titanium oxide dielectric layer(s) and method of making same |
| KR102082424B1 (ko) * | 2017-07-25 | 2020-02-27 | 주식회사 케이씨씨 | 저방사 유리 |
| WO2019050193A1 (fr) * | 2017-09-08 | 2019-03-14 | (주)엘지하우시스 | Matériau de construction fonctionnel pour porte et fenêtre |
| FR3072957B1 (fr) * | 2017-10-30 | 2019-10-18 | Saint-Gobain Glass France | Substrat muni d'un empilement a proprietes thermiques |
| FR3084356A1 (fr) * | 2018-07-26 | 2020-01-31 | Saint-Gobain Glass France | Materiau comprenant un substrat muni d'un empilement a proprietes thermiques. |
| FR3086285A1 (fr) * | 2018-09-20 | 2020-03-27 | Saint-Gobain Glass France | Materiau a proprietes optiques et esthetiques |
| KR102659107B1 (ko) * | 2018-12-31 | 2024-04-18 | 쌩-고벵 글래스 프랑스 | 다층 박막이 구비된 투명 기판 및 이를 포함하는 다중 글레이징 유닛 |
| JP7722925B2 (ja) | 2019-03-28 | 2025-08-13 | ビトロ フラット グラス エルエルシー | 低い可視光反射率を有するヘッドアップディスプレイのためのコーティング |
| BR112022015804A2 (pt) | 2020-02-14 | 2022-10-11 | Vitro Flat Glass Llc | Artigo revestido e método para a fabricação de um artigo revestido |
| EP4092571B1 (fr) | 2021-05-20 | 2025-08-06 | Litesentry LLC | Procédé pour classer les motifs de trempe de verres minéraux traités thermiquement et prédire leurs visibilité optique |
| CN114940589B (zh) * | 2022-06-30 | 2024-09-24 | 长兴旗滨节能玻璃有限公司 | 增透超保温玻璃 |
| EP4328570A1 (fr) | 2022-08-25 | 2024-02-28 | Saint-Gobain Glass France | Procédé de classification de motifs de trempe d'unités de vitrage isolant et de prédiction de la visibilité optique de celles-ci |
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- 2015-07-08 FR FR1556483A patent/FR3038598B1/fr not_active Expired - Fee Related
-
2016
- 2016-06-30 MX MX2017016712A patent/MX2017016712A/es unknown
- 2016-06-30 RU RU2018104698A patent/RU2708304C2/ru active
- 2016-06-30 US US15/742,360 patent/US10815147B2/en active Active
- 2016-06-30 CN CN201680039908.0A patent/CN107810170A/zh active Pending
- 2016-06-30 KR KR1020187000102A patent/KR102592541B1/ko active Active
- 2016-06-30 EP EP16742359.9A patent/EP3319917B1/fr active Active
- 2016-06-30 BR BR112017027581-3A patent/BR112017027581B1/pt not_active IP Right Cessation
- 2016-06-30 JP JP2018500304A patent/JP2018519239A/ja active Pending
- 2016-06-30 WO PCT/FR2016/051653 patent/WO2017006030A1/fr not_active Ceased
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2017
- 2017-12-27 CO CONC2017/0013531A patent/CO2017013531A2/es unknown
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| WO2011147864A1 (fr) | 2010-05-25 | 2011-12-01 | Agc Glass Europe | Vitrage de contrôle solaire à faible facteur solaire |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11208349B2 (en) * | 2018-03-08 | 2021-12-28 | Saint-Gobain Glass France | Material provided with a stack having thermal properties |
| US20240262740A1 (en) * | 2021-04-12 | 2024-08-08 | Saint-Gobain Glass France | Substrate provided with a stack having thermal properties |
| US12509390B2 (en) * | 2021-04-12 | 2025-12-30 | Saint-Gobain Glass France | Substrate provided with a stack having thermal properties |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017006030A1 (fr) | 2017-01-12 |
| KR20180028435A (ko) | 2018-03-16 |
| FR3038598B1 (fr) | 2017-07-21 |
| BR112017027581B1 (pt) | 2022-12-13 |
| MX2017016712A (es) | 2018-03-09 |
| RU2018104698A (ru) | 2019-08-08 |
| EP3319917A1 (fr) | 2018-05-16 |
| FR3038598A1 (fr) | 2017-01-13 |
| CO2017013531A2 (es) | 2018-03-20 |
| KR102592541B1 (ko) | 2023-10-23 |
| BR112017027581A2 (pt) | 2018-08-28 |
| EP3319917B1 (fr) | 2024-11-13 |
| US20180194677A1 (en) | 2018-07-12 |
| RU2708304C2 (ru) | 2019-12-05 |
| CN107810170A (zh) | 2018-03-16 |
| RU2018104698A3 (fr) | 2019-10-09 |
| JP2018519239A (ja) | 2018-07-19 |
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