TWI828551B - Thin film transistor - Google Patents
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- TWI828551B TWI828551B TW112107359A TW112107359A TWI828551B TW I828551 B TWI828551 B TW I828551B TW 112107359 A TW112107359 A TW 112107359A TW 112107359 A TW112107359 A TW 112107359A TW I828551 B TWI828551 B TW I828551B
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- 239000010409 thin film Substances 0.000 title claims abstract description 42
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 120
- 229910052751 metal Inorganic materials 0.000 claims abstract description 115
- 239000002184 metal Substances 0.000 claims abstract description 115
- 239000000758 substrate Substances 0.000 claims abstract description 18
- 238000009413 insulation Methods 0.000 claims description 52
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 11
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 11
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 11
- 239000013078 crystal Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims 1
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- 239000010410 layer Substances 0.000 description 151
- 238000000034 method Methods 0.000 description 24
- 229910021417 amorphous silicon Inorganic materials 0.000 description 18
- 238000005224 laser annealing Methods 0.000 description 18
- 239000000463 material Substances 0.000 description 11
- 239000004020 conductor Substances 0.000 description 8
- 230000005484 gravity Effects 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 239000004065 semiconductor Substances 0.000 description 6
- 239000011810 insulating material Substances 0.000 description 5
- 238000001953 recrystallisation Methods 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 238000004627 transmission electron microscopy Methods 0.000 description 4
- 230000001154 acute effect Effects 0.000 description 3
- 229910000449 hafnium oxide Inorganic materials 0.000 description 3
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 238000000059 patterning Methods 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910052779 Neodymium Inorganic materials 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- -1 aluminum tin oxide Chemical compound 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- JAONJTDQXUSBGG-UHFFFAOYSA-N dialuminum;dizinc;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Zn+2].[Zn+2] JAONJTDQXUSBGG-UHFFFAOYSA-N 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229920002120 photoresistant polymer Polymers 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
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- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 1
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- 238000007667 floating Methods 0.000 description 1
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- 238000000206 photolithography Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
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- Thin Film Transistor (AREA)
Abstract
Description
本發明是有關於一種薄膜電晶體。 The present invention relates to a thin film transistor.
隨著科技的進展,電子產品已經與我們的生活密不可分,而顯示器在其間扮演了相當重要的角色,不論是手機、平板電腦或是智慧型手錶,都藉由顯示器作為人機溝通的介面。在傳統的顯示裝置中,通常會包括非晶矽薄膜電晶體。然而,由於非晶矽薄膜電晶體的載子遷移率低,非晶矽薄膜電晶體顯示裝置難以取得輕薄、省電、高畫質的優點。 With the advancement of technology, electronic products have become inseparable from our lives, and displays play a very important role. Whether it is a mobile phone, a tablet computer, or a smart watch, the display serves as the interface for human-machine communication. In traditional display devices, amorphous silicon thin film transistors are usually included. However, due to the low carrier mobility of amorphous silicon thin film transistors, it is difficult for amorphous silicon thin film transistor display devices to achieve the advantages of thinness, power saving, and high image quality.
為了提升薄膜電晶體的載子遷移率,目前提出了一種低溫多晶矽(low temperature polysilicon,LTPS)薄膜電晶體。一般而言,低溫多晶矽製程大多利用準分子雷射退火(Excimer Laser Annealing,ELA)技術進行,亦即利用準分子雷射提供熱能以將非晶矽結構轉換為多晶矽結構。準分子雷射照射於沉積有非晶矽的基板上,以使非晶矽吸收能量並轉變成為多晶矽。 In order to improve the carrier mobility of thin film transistors, a low temperature polysilicon (LTPS) thin film transistor has been proposed. Generally speaking, low-temperature polycrystalline silicon processes are mostly carried out using Excimer Laser Annealing (ELA) technology, which uses excimer lasers to provide heat energy to convert the amorphous silicon structure into a polycrystalline silicon structure. The excimer laser is irradiated on the substrate on which amorphous silicon is deposited, so that the amorphous silicon absorbs energy and transforms into polycrystalline silicon.
本發明提供一種薄膜電晶體,可以解決多晶矽層的載子遷移率不足的問題。 The present invention provides a thin film transistor that can solve the problem of insufficient carrier mobility of a polycrystalline silicon layer.
本發明的至少一實施例提供一種薄膜電晶體。薄膜電晶體包括第一金屬圖案、絕緣結構、多晶矽層、源極以及汲極。第一金屬圖案位於基板之上。第一金屬圖案的至少一個側面與第一金屬圖案的底面之間的角度為10度至35度。絕緣結構共形地形成於第一金屬圖案上。多晶矽層共形地形成於絕緣結構上,且重疊於第一金屬圖案。多晶矽層包含晶粒長度大於400埃的晶粒。源極以及汲極電性連接至多晶矽層。 At least one embodiment of the present invention provides a thin film transistor. The thin film transistor includes a first metal pattern, an insulation structure, a polycrystalline silicon layer, a source electrode and a drain electrode. The first metal pattern is located on the substrate. The angle between at least one side surface of the first metal pattern and the bottom surface of the first metal pattern is 10 degrees to 35 degrees. The insulation structure is conformally formed on the first metal pattern. The polycrystalline silicon layer is conformally formed on the insulating structure and overlaps the first metal pattern. The polycrystalline silicon layer contains grains with grain lengths greater than 400 Angstroms. The source electrode and the drain electrode are electrically connected to the polycrystalline silicon layer.
本發明的至少一實施例提供一種薄膜電晶體。薄膜電晶體包括第一金屬圖案、絕緣結構、多晶矽層、源極以及汲極。第一金屬圖案位於基板之上。第一金屬圖案的剖面形狀包括至少一個三角形。絕緣結構形成於第一金屬圖案上。多晶矽層形成於絕緣結構上,且重疊於第一金屬圖案。多晶矽層包含晶粒長度大於400埃的晶粒。源極以及汲極電性連接至多晶矽層。 At least one embodiment of the present invention provides a thin film transistor. The thin film transistor includes a first metal pattern, an insulation structure, a polycrystalline silicon layer, a source electrode and a drain electrode. The first metal pattern is located on the substrate. The cross-sectional shape of the first metal pattern includes at least one triangle. An insulation structure is formed on the first metal pattern. A polycrystalline silicon layer is formed on the insulating structure and overlaps the first metal pattern. The polycrystalline silicon layer contains grains with grain lengths greater than 400 Angstroms. The source electrode and the drain electrode are electrically connected to the polycrystalline silicon layer.
100:第一導電層 100: First conductive layer
100’:第一導電材料層 100’: first conductive material layer
110:掃描線 110:Scan line
120,120A,120B:第一金屬圖案 120,120A,120B: First metal pattern
122:導電結構 122:Conductive structure
122a:第一側面 122a: first side
122b:第二側面 122b: Second side
122c:底面 122c: Bottom surface
122d:頂面 122d:Top surface
200,200A,200B:多晶矽層 200, 200A, 200B: polycrystalline silicon layer
200’:非晶矽層 200’: Amorphous silicon layer
210:通道區 210: Passage area
222:第一輕摻雜區 222: First lightly doped region
224:第二輕摻雜區 224: The second lightly doped region
232:第一重摻雜區 232: First heavily doped region
234:第二重摻雜區 234: The second heavily doped region
200a:第一傾斜部 200a: first inclined part
200b:第二傾斜部 200b: Second inclined part
200d:平台部 200d:Platform Department
300:第二導電層 300: Second conductive layer
310:資料線 310:Data line
320,320A,320B:源極 320, 320A, 320B: source
330,330A,330B:汲極 330,330A,330B: drain
400,410:畫素電極 400,410: Pixel electrode
420:轉接電極 420: Adapter electrode
430:共用電極 430: Common electrode
D1:第一方向 D1: first direction
h:厚度 h: Thickness
I1:第一絕緣結構 I1: First insulation structure
I1a:氧化矽層 I1a: silicon oxide layer
I1b:氮化矽層 I1b: silicon nitride layer
I2:第二絕緣結構 I2: Second insulation structure
I2a:閘極絕緣層 I2a: Gate insulation layer
I2b:層間介電層 I2b: interlayer dielectric layer
I3:第三絕緣結構 I3: The third insulation structure
I4:第四絕緣結構 I4: The fourth insulation structure
L,L’,L”:長度 L, L’, L”: length
ND:法線方向 ND: normal direction
P:間距 P: pitch
SB:基板 SB:Substrate
T1,T2:薄膜電晶體 T1, T2: thin film transistor
TG1:第一頂閘極 TG1: The first top gate
TG2:第二頂閘極 TG2: The second top gate
θ,θ1,θ2:角度 θ, θ1, θ2: angle
圖1A是依照本發明的一實施例的一種畫素結構的上視示意圖。 FIG. 1A is a schematic top view of a pixel structure according to an embodiment of the present invention.
圖1B是沿著圖1A的線A-A’的剖面示意圖。 Fig. 1B is a schematic cross-sectional view along line A-A' of Fig. 1A.
圖2A至圖2E是依照本發明的一實施例的一種多晶矽層的 製造方法的剖面示意圖。 2A to 2E are diagrams of a polycrystalline silicon layer according to an embodiment of the present invention. Schematic cross-section of the manufacturing method.
圖3是依照本發明的一實施例的一種畫素結構的剖面示意圖。 FIG. 3 is a schematic cross-sectional view of a pixel structure according to an embodiment of the present invention.
圖4是依照本發明的一實施例的一種畫素結構的剖面示意圖。 FIG. 4 is a schematic cross-sectional view of a pixel structure according to an embodiment of the present invention.
圖5是依照本發明的一實施例的一種畫素結構的剖面示意圖。 FIG. 5 is a schematic cross-sectional view of a pixel structure according to an embodiment of the present invention.
圖6是依照本發明的一實施例的一種多晶矽層的掃描式電子顯微鏡照片。 Figure 6 is a scanning electron microscope photograph of a polycrystalline silicon layer according to an embodiment of the present invention.
圖7A是依照本發明的一實施例的一種第一金屬圖案、第一絕緣結構以及多晶矽層的掃描式電子顯微鏡照片。 7A is a scanning electron microscope photograph of a first metal pattern, a first insulating structure and a polycrystalline silicon layer according to an embodiment of the present invention.
圖7B是依照本發明的一實施例的一種第一金屬圖案、第一絕緣結構以及多晶矽層的穿透式電子顯微鏡照片。 7B is a transmission electron microscope photograph of a first metal pattern, a first insulating structure and a polycrystalline silicon layer according to an embodiment of the present invention.
圖8A至圖8C分別是利用不同蝕刻參數所形成的第一金屬圖案的穿透式電子顯微鏡照片。 8A to 8C are transmission electron microscopy photos of the first metal pattern formed using different etching parameters.
圖9A至圖9E分別是利用不同能量的準分子雷射退火製程所形成的多晶矽層的穿透式電子顯微鏡照片。 Figures 9A to 9E are transmission electron microscopy photos of polycrystalline silicon layers formed using excimer laser annealing processes with different energies.
圖10是準分子雷射退火製程的能量與多晶矽層的晶粒長度的實驗數據圖。 Figure 10 is an experimental data diagram showing the energy of the excimer laser annealing process and the grain length of the polycrystalline silicon layer.
圖1A是依照本發明的一實施例的一種畫素結構的上視 示意圖。圖1B是沿著圖1A的線A-A’的剖面示意圖。請參考圖1A與圖1B,畫素結構包括薄膜電晶體T1以及畫素電極400。薄膜電晶體T1包括第一金屬圖案120、第一絕緣結構I1、多晶矽層200、源極320以及汲極330。 Figure 1A is a top view of a pixel structure according to an embodiment of the present invention. Schematic diagram. Fig. 1B is a schematic cross-sectional view along line A-A' of Fig. 1A. Referring to FIGS. 1A and 1B , the pixel structure includes a thin film transistor T1 and a pixel electrode 400 . The thin film transistor T1 includes a first metal pattern 120 , a first insulation structure I1 , a polycrystalline silicon layer 200 , a source electrode 320 and a drain electrode 330 .
基板SB之材質可為玻璃、石英、有機聚合物或不透光/反射材料(例如:導電材料、金屬、晶圓、陶瓷或其他可適用的材料)或是其他可適用的材料。若使用導電材料或金屬時,則在基板SB上覆蓋一層絕緣層(未繪示),以避免短路問題。 The material of the substrate SB can be glass, quartz, organic polymer, opaque/reflective material (such as conductive material, metal, wafer, ceramic or other applicable materials) or other applicable materials. If conductive materials or metals are used, an insulating layer (not shown) is covered on the substrate SB to avoid short circuit problems.
第一金屬圖案120位於基板SB之上。在本實施例中,第一金屬圖案120為薄膜電晶體T1的閘極,且第一金屬圖案120電性連接至掃描線110。在本實施例中,第一金屬圖案120直接連接掃描線110。第一金屬圖案120與掃描線110屬於相同的第一導電層100。在一些實施例中,第一導電層100的材料包括鉻、金、銀、銅、錫、鉛、鉿、鎢、鉬、釹、鈦、鉭、鋁、鋅、鎳等金屬、上述金屬的合金或上述金屬的堆疊層。在一些實施例中,第一金屬圖案120的厚度為100奈米至400奈米。 The first metal pattern 120 is located on the substrate SB. In this embodiment, the first metal pattern 120 is the gate of the thin film transistor T1 , and the first metal pattern 120 is electrically connected to the scan line 110 . In this embodiment, the first metal pattern 120 is directly connected to the scan line 110 . The first metal pattern 120 and the scan line 110 belong to the same first conductive layer 100 . In some embodiments, the material of the first conductive layer 100 includes chromium, gold, silver, copper, tin, lead, hafnium, tungsten, molybdenum, neodymium, titanium, tantalum, aluminum, zinc, nickel and other metals, and alloys of the above metals. or stacked layers of the above metals. In some embodiments, the thickness of the first metal pattern 120 is 100 nm to 400 nm.
第一金屬圖案120的至少一個側面與第一金屬圖案120的底面之間的角度為10度至35度。舉例來說,第一金屬圖案120包括多個導電結構122,每個導電結構122電性連接至同一條掃描線110。在本實施例中,多個導電結構122在第一方向D1上排列,且多個導電結構122在第一方向D1上具有間距P,其中間距P為0.8微米至3.5微米。 The angle between at least one side surface of the first metal pattern 120 and the bottom surface of the first metal pattern 120 is 10 degrees to 35 degrees. For example, the first metal pattern 120 includes a plurality of conductive structures 122, and each conductive structure 122 is electrically connected to the same scan line 110. In this embodiment, the plurality of conductive structures 122 are arranged in the first direction D1, and the plurality of conductive structures 122 have a pitch P in the first direction D1, where the pitch P is 0.8 microns to 3.5 microns.
第一金屬圖案120的剖面形狀包括至少一個三角形。在本實施例中,第一金屬圖案120的剖面形狀包括多個三角形。具體地說,第一金屬圖案120中的各導電結構122的剖面形狀包括三角形。各導電結構122包括第一側面122a、第二側面122b與底面122c,其中第一側面122a與底面122c之間的角度θ1以及第二側面122b與底面122c之間的角度θ2皆為10度至35度。須注意的是,第一側面122a與底面122c之間的角度θ1指的是第一側面122a的延伸方向與底面122c的延伸方向之間的角度,且第二側面122b與底面122c之間的角度θ2指的是第二側面122b的延伸方向與底面122c的延伸方向之間的角度。第一側面122a與底面122c之間以及第二側面122b與底面122c之間可以包括圓角或銳角。另外,第一側面122a與第二側面122b之間也可以包括圓角或銳角。在本實施例中,各導電結構122的剖面形狀包括等腰三角形,且第一側面122a的長度L等於第二側面122b的長度L。 The cross-sectional shape of the first metal pattern 120 includes at least one triangle. In this embodiment, the cross-sectional shape of the first metal pattern 120 includes a plurality of triangles. Specifically, the cross-sectional shape of each conductive structure 122 in the first metal pattern 120 includes a triangle. Each conductive structure 122 includes a first side surface 122a, a second side surface 122b and a bottom surface 122c, wherein the angle θ1 between the first side surface 122a and the bottom surface 122c and the angle θ2 between the second side surface 122b and the bottom surface 122c are both 10 degrees to 35 degrees. Spend. It should be noted that the angle θ1 between the first side surface 122a and the bottom surface 122c refers to the angle between the extension direction of the first side surface 122a and the extension direction of the bottom surface 122c, and the angle between the second side surface 122b and the bottom surface 122c. θ2 refers to the angle between the extending direction of the second side surface 122b and the extending direction of the bottom surface 122c. The first side surface 122a and the bottom surface 122c and the second side surface 122b and the bottom surface 122c may include rounded corners or acute corners. In addition, a rounded corner or an acute corner may also be included between the first side surface 122a and the second side surface 122b. In this embodiment, the cross-sectional shape of each conductive structure 122 includes an isosceles triangle, and the length L of the first side 122a is equal to the length L of the second side 122b.
第一絕緣結構I1形成於第一導電層100上。在一些實施例中,第一絕緣結構I1共形地形成於第一金屬圖案120上。第一絕緣結構I1在基板SB的頂面的法線方向ND上重疊於掃描線110與第一金屬圖案120。在一些實施例中,第一絕緣結構I1的材料包括氧化矽、氮化矽、氮氧化矽、氧化鋁、氧化鉿或其他絕緣材料。在一些實施例中,第一絕緣結構I1包括單層結構或多層結構,舉例來說,第一絕緣結構I1包括氮化矽與氧化矽的疊 層,其中氮化矽接觸第一金屬圖案120,且氧化矽接觸多晶矽層200。在一些實施例中,第一絕緣結構I1包括多層氮化矽與多層氧化矽,其中氮化矽與氧化矽的交替堆疊。在一些實施例中,第一絕緣結構I1的厚度為h,3000Åh8000Å。在一些實施例中,當厚度h大於5000Å時,第一絕緣結構I1在準分子雷射退火中對多晶矽層200的保溫效果較佳,藉此可以減少準分子雷射退火所需的能量。 The first insulation structure I1 is formed on the first conductive layer 100 . In some embodiments, the first insulation structure I1 is conformally formed on the first metal pattern 120 . The first insulation structure I1 overlaps the scanning line 110 and the first metal pattern 120 in the normal direction ND of the top surface of the substrate SB. In some embodiments, the material of the first insulating structure I1 includes silicon oxide, silicon nitride, silicon oxynitride, aluminum oxide, hafnium oxide or other insulating materials. In some embodiments, the first insulation structure I1 includes a single-layer structure or a multi-layer structure. For example, the first insulation structure I1 includes a stack of silicon nitride and silicon oxide, where the silicon nitride contacts the first metal pattern 120, And the silicon oxide contacts the polycrystalline silicon layer 200 . In some embodiments, the first insulating structure I1 includes multiple layers of silicon nitride and multiple layers of silicon oxide, wherein silicon nitride and silicon oxide are alternately stacked. In some embodiments, the thickness of the first insulating structure I1 is h, 3000 Å h 8000Å. In some embodiments, when the thickness h is greater than 5000 Å, the first insulating structure I1 has a better heat preservation effect on the polycrystalline silicon layer 200 during excimer laser annealing, thereby reducing the energy required for excimer laser annealing.
在本實施例中,由於第一金屬圖案120的至少一個側面與第一金屬圖案120的底面之間的角度為10度至35度,形成於第一金屬圖案120上的第一絕緣結構I1的頂面包括斜面。 In this embodiment, since the angle between at least one side surface of the first metal pattern 120 and the bottom surface of the first metal pattern 120 is 10 degrees to 35 degrees, the first insulation structure I1 formed on the first metal pattern 120 is The top surface includes a bevel.
多晶矽層200共形地形成於第一絕緣結構I1上,且在基板SB的頂面的法線方向ND上重疊於第一金屬圖案120。由於第一絕緣結構I1的頂面包括斜面,共形於第一絕緣結構I1的多晶矽層200包括共形於前述斜面的多個傾斜部。具體地說,多晶矽層200包括在法線方向ND上重疊於第一側面122a的多個第一傾斜部200a以及在法線方向ND上重疊於第二側面122b的多個第二傾斜部200b,第一傾斜部200a與第二傾斜部200b交替排列。 The polycrystalline silicon layer 200 is conformally formed on the first insulation structure I1 and overlaps the first metal pattern 120 in the normal direction ND of the top surface of the substrate SB. Since the top surface of the first insulation structure I1 includes a slope, the polycrystalline silicon layer 200 conforming to the first insulation structure I1 includes a plurality of slope portions conforming to the slope. Specifically, the polysilicon layer 200 includes a plurality of first inclined portions 200a overlapping the first side 122a in the normal direction ND and a plurality of second inclined portions 200b overlapping the second side 122b in the normal direction ND, The first inclined portions 200a and the second inclined portions 200b are alternately arranged.
在本實施例中,由於導電結構122在第一方向D1上具有間距P,第一傾斜部200a及第二傾斜部200b中的每一者的長度L’大於第一側面122a及第二側面122b中的每一者的長度L。 In this embodiment, since the conductive structure 122 has a pitch P in the first direction D1, the length L' of each of the first inclined portion 200a and the second inclined portion 200b is greater than the first side 122a and the second side 122b. The length L of each of them.
在本實施例中,多晶矽層200經摻雜而包括第一重摻雜區232、第二重摻雜區234、第一輕摻雜區222、第二輕摻雜區 224以及通道區210。通道區210位於第一輕摻雜區222與第二輕摻雜區224之間,第一輕摻雜區222位於通道區210與第一重摻雜區232,且第二輕摻雜區224位於通道區210與第二重摻雜區234之間。在本實施例中,第一輕摻雜區222與第二輕摻雜區224分別在法線方向ND上重疊於第一金屬圖案120最外側的兩個側面。舉例來說,第一輕摻雜區222在法線方向ND上重疊於最左邊的第一側面122a,且第二輕摻雜區224在法線方向ND上重疊於最右邊的第二側面122b。在本實施例中,部分通道區210在法線方向ND上重疊於兩個導電結構122之間的間隙。換句話說,部分通道區210在法線方向ND上不重疊於第一金屬圖案120。 In this embodiment, the polycrystalline silicon layer 200 is doped to include a first heavily doped region 232, a second heavily doped region 234, a first lightly doped region 222, and a second lightly doped region. 224 and channel area 210. The channel region 210 is located between the first lightly doped region 222 and the second lightly doped region 224 , the first lightly doped region 222 is located between the channel region 210 and the first heavily doped region 232 , and the second lightly doped region 224 Located between the channel region 210 and the second heavily doped region 234 . In this embodiment, the first lightly doped region 222 and the second lightly doped region 224 respectively overlap with the two outermost side surfaces of the first metal pattern 120 in the normal direction ND. For example, the first lightly doped region 222 overlaps the leftmost first side 122a in the normal direction ND, and the second lightly doped region 224 overlaps the rightmost second side 122b in the normal direction ND. . In this embodiment, the partial channel region 210 overlaps the gap between the two conductive structures 122 in the normal direction ND. In other words, the partial channel area 210 does not overlap the first metal pattern 120 in the normal direction ND.
在一些實施例中,多晶矽層200中的第一重摻雜區232、第二重摻雜區234、第一輕摻雜區222以及第二輕摻雜區224皆為N型半導體,其中第一重摻雜區232以及第二重摻雜區234的摻雜濃度大於第一輕摻雜區222以及第二輕摻雜區224的摻雜濃度。在其他實施例中,多晶矽層200中的第一重摻雜區232、第二重摻雜區234皆為P型半導體,且可以省略第一輕摻雜區222以及第二輕摻雜區224。 In some embodiments, the first heavily doped region 232, the second heavily doped region 234, the first lightly doped region 222 and the second lightly doped region 224 in the polycrystalline silicon layer 200 are all N-type semiconductors, wherein the The doping concentrations of the first heavily doped region 232 and the second heavily doped region 234 are greater than the doping concentrations of the first lightly doped region 222 and the second lightly doped region 224 . In other embodiments, the first heavily doped region 232 and the second heavily doped region 234 in the polycrystalline silicon layer 200 are both P-type semiconductors, and the first lightly doped region 222 and the second lightly doped region 224 can be omitted. .
在本實施例中,在利用準分子雷射退火技術形成多晶矽層200時,多晶矽層200中的晶粒會受重力拉長,因此,不需要使用大能量的準分子雷射就能獲得較長的晶粒。具體地說,透過第一金屬圖案120的設計,可以使位於其上方的多晶矽層200 (在執行準分子雷射退火製程前為非晶矽層)具有多個傾斜部,藉由傾斜部的設計,可以使非晶矽在再結晶時受重力拉伸,進而使再結晶後的晶粒具有較長的長度。在一些實施例中,多晶矽層200包含晶粒長度大於400埃的晶粒。舉例來說,多晶矽層200中的至少部分晶粒的晶粒長度大於500埃、大於600埃、大於700埃、大於800埃或大於900埃。藉由使多晶矽層200中包含晶粒長度大於400埃的晶粒,可以提升多晶矽層200的載子遷移率。 In this embodiment, when the excimer laser annealing technology is used to form the polycrystalline silicon layer 200, the crystal grains in the polycrystalline silicon layer 200 will be elongated by gravity. Therefore, it is not necessary to use a high-energy excimer laser to obtain a longer length. of grains. Specifically, through the design of the first metal pattern 120, the polycrystalline silicon layer 200 located above it can be (The amorphous silicon layer before performing the excimer laser annealing process) has multiple inclined parts. Through the design of the inclined parts, the amorphous silicon can be stretched by gravity during recrystallization, thereby making the crystalline layer after recrystallization Grain has a longer length. In some embodiments, polycrystalline silicon layer 200 contains grains with grain lengths greater than 400 Angstroms. For example, at least some of the grains in the polycrystalline silicon layer 200 have a grain length greater than 500 angstroms, greater than 600 angstroms, greater than 700 angstroms, greater than 800 angstroms, or greater than 900 angstroms. By allowing the polycrystalline silicon layer 200 to include grains with a grain length greater than 400 Angstroms, the carrier mobility of the polycrystalline silicon layer 200 can be improved.
第二絕緣結構I2位於多晶矽層200上。在一些實施例中,第二絕緣結構I2的材料包括氧化矽、氮化矽、氮氧化矽、氧化鋁、氧化鉿、有機絕緣材料或其他絕緣材料。在一些實施例中,第二絕緣結構I2包括單層結構或多層結構。 The second insulation structure I2 is located on the polysilicon layer 200 . In some embodiments, the material of the second insulation structure I2 includes silicon oxide, silicon nitride, silicon oxynitride, aluminum oxide, hafnium oxide, organic insulating materials or other insulating materials. In some embodiments, the second insulation structure I2 includes a single-layer structure or a multi-layer structure.
源極320以及汲極330位於第二絕緣結構I2上,且電性連接至多晶矽層200。在本實施例中,源極320以及汲極330填入第二絕緣結構I2中的通孔,並分別接觸多晶矽層200的第一重摻雜區232以及第二重摻雜區234。在本實施例中,源極320直接連接資料線310。資料線310、源極320與汲極330屬於相同的第二導電層300。在一些實施例中,第二導電層300的材料包括鉻、金、銀、銅、錫、鉛、鉿、鎢、鉬、釹、鈦、鉭、鋁、鋅、鎳等金屬、上述金屬的合金或上述金屬的堆疊層。 The source electrode 320 and the drain electrode 330 are located on the second insulation structure I2 and are electrically connected to the polycrystalline silicon layer 200 . In this embodiment, the source electrode 320 and the drain electrode 330 fill the through holes in the second insulation structure I2 and contact the first heavily doped region 232 and the second heavily doped region 234 of the polycrystalline silicon layer 200 respectively. In this embodiment, the source 320 is directly connected to the data line 310 . The data line 310, the source electrode 320 and the drain electrode 330 belong to the same second conductive layer 300. In some embodiments, the material of the second conductive layer 300 includes chromium, gold, silver, copper, tin, lead, hafnium, tungsten, molybdenum, neodymium, titanium, tantalum, aluminum, zinc, nickel and other metals, and alloys of the above metals. or stacked layers of the above metals.
第三絕緣結構I3位於第二導電層300上,且覆蓋資料線310、源極320與汲極330。在一些實施例中,第三絕緣結構I3 的材料包括氧化矽、氮化矽、氮氧化矽、氧化鋁、氧化鉿、有機絕緣材料或其他絕緣材料。在一些實施例中,第三絕緣結構I3包括單層結構或多層結構。 The third insulating structure I3 is located on the second conductive layer 300 and covers the data line 310, the source electrode 320 and the drain electrode 330. In some embodiments, the third insulating structure I3 The materials include silicon oxide, silicon nitride, silicon oxynitride, aluminum oxide, hafnium oxide, organic insulating materials or other insulating materials. In some embodiments, the third insulation structure I3 includes a single-layer structure or a multi-layer structure.
畫素電極400位於三絕緣結構I3上。畫素電極400填入第三絕緣結構I3中的通孔,並接觸汲極330。在一些實施例中,畫素電極400的材料包括銦錫氧化物、銦鋅氧化物、鋁錫氧化物、鋁鋅氧化物、銦鎵鋅氧化物、或是上述至少二者之堆疊層。 The pixel electrode 400 is located on the three-insulation structure I3. The pixel electrode 400 fills the through hole in the third insulation structure I3 and contacts the drain electrode 330 . In some embodiments, the material of the pixel electrode 400 includes indium tin oxide, indium zinc oxide, aluminum tin oxide, aluminum zinc oxide, indium gallium zinc oxide, or a stacked layer of at least two of the above.
圖2A至圖2E是依照本發明的一實施例的一種多晶矽層的製造方法的剖面示意圖。舉例來說,圖2A至圖2E是圖1A與圖1B中的多晶矽層200的製造方法的剖面示意圖。 2A to 2E are schematic cross-sectional views of a method for manufacturing a polycrystalline silicon layer according to an embodiment of the present invention. For example, FIGS. 2A to 2E are schematic cross-sectional views of the manufacturing method of the polycrystalline silicon layer 200 in FIGS. 1A and 1B .
請參考圖2A,形成第一導電材料層100’於基板SB之上。 Referring to FIG. 2A, a first conductive material layer 100' is formed on the substrate SB.
請參考圖2B,對第一導電材料層100’執行一次或多次的圖案化製程,以形成第一金屬圖案120於基板SB上。舉例來說,透過一次或多次的微影製程於第一導電材料層100’上形成光阻層,並利用光阻層為遮罩對第一導電材料層100’執行一次或多次蝕刻,以形成包括多個導電結構122的第一金屬圖案120。在一些實施例中,對第一導電材料層100’執行一次或多次的圖案化製程,以形成第一金屬圖案120以及掃描線(圖2B未繪出)於基板SB上。 Referring to FIG. 2B, one or more patterning processes are performed on the first conductive material layer 100' to form the first metal pattern 120 on the substrate SB. For example, a photoresist layer is formed on the first conductive material layer 100' through one or more photolithography processes, and one or more etchings are performed on the first conductive material layer 100' using the photoresist layer as a mask. To form a first metal pattern 120 including a plurality of conductive structures 122 . In some embodiments, one or more patterning processes are performed on the first conductive material layer 100' to form the first metal pattern 120 and scan lines (not shown in FIG. 2B) on the substrate SB.
請參考圖2C,形成第一絕緣結構I1於第一金屬圖案120上。 Referring to FIG. 2C , a first insulation structure I1 is formed on the first metal pattern 120 .
請參考圖2D,形成非晶矽層200’於第一絕緣結構I1上。 Referring to FIG. 2D, an amorphous silicon layer 200' is formed on the first insulation structure I1.
請參考圖2E,對非晶矽層200’執行圖案化製程,並從非晶矽層200’的正面透過準分子雷射退火製程以使非晶矽再結晶成為多晶矽。接著再利用一次或多次的摻雜製程摻雜前述多晶矽,以形成多晶矽層200。在一些實施例中,在執行摻雜製程前,於多晶矽上方形成罩幕,並藉由罩幕定義出多晶矽層200中欲進行摻雜製程的位置。在一些實施例中,在執行摻雜製程後,移除前述罩幕。 Referring to FIG. 2E, a patterning process is performed on the amorphous silicon layer 200', and an excimer laser annealing process is performed from the front side of the amorphous silicon layer 200' to recrystallize the amorphous silicon into polycrystalline silicon. Then, one or more doping processes are used to dope the polycrystalline silicon to form the polycrystalline silicon layer 200 . In some embodiments, before performing the doping process, a mask is formed over the polysilicon, and the mask defines the location in the polysilicon layer 200 where the doping process is to be performed. In some embodiments, after performing the doping process, the mask is removed.
在本實施例中,由於非晶矽層200’具有多個傾斜部,藉由傾斜部的設計,可以使非晶矽在再結晶時受重力拉伸,進而使再結晶後的晶粒具有較長的長度。 In this embodiment, since the amorphous silicon layer 200' has multiple inclined portions, through the design of the inclined portions, the amorphous silicon can be stretched by gravity during recrystallization, thereby making the recrystallized grains have a larger long length.
在一些實施例中,在多晶矽層200上形成第二絕緣結構、源極以及汲極,以獲得薄膜電晶體。 In some embodiments, a second insulating structure, a source electrode, and a drain electrode are formed on the polycrystalline silicon layer 200 to obtain a thin film transistor.
圖3是依照本發明的一實施例的一種畫素結構的剖面示意圖。在此必須說明的是,圖3的實施例沿用圖1A和圖1B的實施例的元件標號與部分內容,其中採用相同或近似的標號來表示相同或近似的元件,並且省略了相同技術內容的說明。關於省略部分的說明可參考前述實施例,在此不贅述。 FIG. 3 is a schematic cross-sectional view of a pixel structure according to an embodiment of the present invention. It must be noted here that the embodiment of FIG. 3 follows the component numbers and part of the content of the embodiment of FIG. 1A and FIG. 1B , where the same or similar numbers are used to represent the same or similar elements, and references with the same technical content are omitted. instruction. For descriptions of omitted parts, reference may be made to the foregoing embodiments and will not be described again here.
圖3的實施例與圖1A的實施例的主要差異在於:在圖3的實施例中,第一金屬圖案120的剖面形狀包括至少一個梯形。 The main difference between the embodiment of FIG. 3 and the embodiment of FIG. 1A is that in the embodiment of FIG. 3 , the cross-sectional shape of the first metal pattern 120 includes at least one trapezoid.
請參考圖3,在本實施例中,第一金屬圖案120的至少一個側面與第一金屬圖案120的底面之間的角度為10度至35度。舉例來說,第一金屬圖案120包括多個導電結構122,每個導電結構122電性連接至同一條掃描線110。在本實施例中,多個導電結構122在第一方向D1上排列,且多個導電結構122在第一方向D1上具有間距P,其中間距P為0.8微米至3.5微米。 Referring to FIG. 3 , in this embodiment, the angle between at least one side surface of the first metal pattern 120 and the bottom surface of the first metal pattern 120 is 10 degrees to 35 degrees. For example, the first metal pattern 120 includes a plurality of conductive structures 122, and each conductive structure 122 is electrically connected to the same scan line 110. In this embodiment, the plurality of conductive structures 122 are arranged in the first direction D1, and the plurality of conductive structures 122 have a pitch P in the first direction D1, where the pitch P is 0.8 microns to 3.5 microns.
第一金屬圖案120的剖面形狀包括至少一個梯形。在本實施例中,第一金屬圖案120的剖面形狀包括多個梯形。具體地說,第一金屬圖案120中的各導電結構122的剖面形狀包括梯形。各導電結構122包括第一側面122a、第二側面122b、底面122c與頂面122d,其中第一側面122a與底面122c之間的角度θ1以及第二側面122b與底面122c之間的角度θ2皆為10度至35度。須注意的是,第一側面122a與底面122c之間的角度θ1指的是第一側面122a的延伸方向與底面122c的延伸方向之間的角度,且第二側面122b與底面122c之間的角度θ2指的是第二側面122b的延伸方向與底面122c的延伸方向之間的角度。第一側面122a與底面122c之間以及第二側面122b與底面122c之間可以包括圓角或銳角。 The cross-sectional shape of the first metal pattern 120 includes at least one trapezoid. In this embodiment, the cross-sectional shape of the first metal pattern 120 includes a plurality of trapezoids. Specifically, the cross-sectional shape of each conductive structure 122 in the first metal pattern 120 includes a trapezoid. Each conductive structure 122 includes a first side surface 122a, a second side surface 122b, a bottom surface 122c and a top surface 122d, wherein the angle θ1 between the first side surface 122a and the bottom surface 122c and the angle θ2 between the second side surface 122b and the bottom surface 122c are both 10 degrees to 35 degrees. It should be noted that the angle θ1 between the first side surface 122a and the bottom surface 122c refers to the angle between the extension direction of the first side surface 122a and the extension direction of the bottom surface 122c, and the angle between the second side surface 122b and the bottom surface 122c. θ2 refers to the angle between the extending direction of the second side surface 122b and the extending direction of the bottom surface 122c. The first side surface 122a and the bottom surface 122c and the second side surface 122b and the bottom surface 122c may include rounded corners or acute corners.
第一絕緣結構I1共形地形成於第一金屬圖案120上。 The first insulation structure I1 is conformally formed on the first metal pattern 120 .
多晶矽層200共形地形成於第一絕緣結構I1上,且在基板SB的頂面的法線方向ND上重疊於第一金屬圖案120。由於第一絕緣結構I1的頂面包括斜面,共形於第一絕緣結構I1的多晶 矽層200包括共形於前述斜面的多個傾斜部。具體地說,多晶矽層200包括在法線方向ND上重疊於第一側面122a的多個第一傾斜部200a與在法線方向ND上重疊於第二側面122b的多個第二傾斜部200b,第一傾斜部200a與第二傾斜部200b交替排列。在本實施例中,多晶矽層200還包括在法線方向ND上重疊於頂面122d的多個平台部200d。各第一傾斜部200a與對應的第二傾斜部200b位於對應的平台部200d的兩側。在一些實施例中,各導電結構122的頂面122d的長度X1小於或等於0.5微米,藉此避免多晶矽層200中的平台部200d的長度X2過長。平台部200d的長度X2為0.1微米至1微米。 The polycrystalline silicon layer 200 is conformally formed on the first insulation structure I1 and overlaps the first metal pattern 120 in the normal direction ND of the top surface of the substrate SB. Since the top surface of the first insulating structure I1 includes a slope, the polycrystalline surface conformal to the first insulating structure I1 The silicon layer 200 includes a plurality of inclined portions conformable to the aforementioned inclined surfaces. Specifically, the polycrystalline silicon layer 200 includes a plurality of first inclined portions 200a overlapping the first side surface 122a in the normal direction ND and a plurality of second inclined portions 200b overlapping the second side surface 122b in the normal direction ND. The first inclined portions 200a and the second inclined portions 200b are alternately arranged. In this embodiment, the polycrystalline silicon layer 200 further includes a plurality of platform portions 200d overlapping the top surface 122d in the normal direction ND. Each first inclined portion 200a and the corresponding second inclined portion 200b are located on both sides of the corresponding platform portion 200d. In some embodiments, the length X1 of the top surface 122d of each conductive structure 122 is less than or equal to 0.5 microns, thereby preventing the length X2 of the platform portion 200d in the polycrystalline silicon layer 200 from being too long. The length X2 of the platform portion 200d is 0.1 micron to 1 micron.
在本實施例中,第一輕摻雜區222與第二輕摻雜區224分別在法線方向ND上重疊於第一金屬圖案120最外側的兩個側面。舉例來說,第一輕摻雜區222重疊於最左邊的第一側面122a,且第二輕摻雜區224重疊於最右邊的第二側面122b。在本實施例中,部分通道區210在法線方向ND上重疊於兩個導電結構122之間的間隙。換句話說,部分通道區210在法線方向ND上不重疊於第一金屬圖案120。 In this embodiment, the first lightly doped region 222 and the second lightly doped region 224 respectively overlap with the two outermost side surfaces of the first metal pattern 120 in the normal direction ND. For example, the first lightly doped region 222 overlaps the leftmost first side 122a, and the second lightly doped region 224 overlaps the rightmost second side 122b. In this embodiment, the partial channel region 210 overlaps the gap between the two conductive structures 122 in the normal direction ND. In other words, the partial channel area 210 does not overlap the first metal pattern 120 in the normal direction ND.
在一些實施例中,多晶矽層200中的第一重摻雜區232、第二重摻雜區234、第一輕摻雜區222以及第二輕摻雜區224皆為N型半導體,其中第一重摻雜區232以及第二重摻雜區234的摻雜濃度大於第一輕摻雜區222以及第二輕摻雜區224的摻雜濃度。在其他實施例中,多晶矽層200中的第一重摻雜區 232、第二重摻雜區234皆為P型半導體,且可以省略第一輕摻雜區222以及第二輕摻雜區224。 In some embodiments, the first heavily doped region 232, the second heavily doped region 234, the first lightly doped region 222 and the second lightly doped region 224 in the polycrystalline silicon layer 200 are all N-type semiconductors, wherein the The doping concentrations of the first heavily doped region 232 and the second heavily doped region 234 are greater than the doping concentrations of the first lightly doped region 222 and the second lightly doped region 224 . In other embodiments, the first heavily doped region in polysilicon layer 200 232. The second heavily doped region 234 is both a P-type semiconductor, and the first lightly doped region 222 and the second lightly doped region 224 can be omitted.
在本實施例中,在利用準分子雷射退火技術形成多晶矽層200時,多晶矽層200中的晶粒會受重力拉長,因此,不需要使用大能量的準分子雷射就能獲得較長的晶粒。具體地說,透過第一金屬圖案120的設計,可以使位於其上方的多晶矽層200(在執行準分子雷射退火製程前為非晶矽層)具有多個傾斜部,藉由傾斜部的設計,可以使非晶矽在再結晶時受重力拉伸,進而使再結晶後的晶粒具有較長的長度。在一些實施例中,多晶矽層200包含晶粒長度大於400埃的晶粒。舉例來說,多晶矽層200中的至少部分晶粒的晶粒長度大於500埃、大於600埃、大於700埃、大於800埃或大於900埃。藉由使多晶矽層200中包含晶粒長度大於400埃的晶粒,可以提升多晶矽層200的載子遷移率。 In this embodiment, when the excimer laser annealing technology is used to form the polycrystalline silicon layer 200, the crystal grains in the polycrystalline silicon layer 200 will be elongated by gravity. Therefore, it is not necessary to use a high-energy excimer laser to obtain a longer length. of grains. Specifically, through the design of the first metal pattern 120, the polycrystalline silicon layer 200 located above it (the amorphous silicon layer before the excimer laser annealing process is performed) can have multiple inclined portions. Through the design of the inclined portions, , which can cause amorphous silicon to be stretched by gravity during recrystallization, thereby making the recrystallized grains have a longer length. In some embodiments, polycrystalline silicon layer 200 contains grains with grain lengths greater than 400 Angstroms. For example, at least some of the grains in the polycrystalline silicon layer 200 have a grain length greater than 500 angstroms, greater than 600 angstroms, greater than 700 angstroms, greater than 800 angstroms, or greater than 900 angstroms. By allowing the polycrystalline silicon layer 200 to include grains with a grain length greater than 400 Angstroms, the carrier mobility of the polycrystalline silicon layer 200 can be improved.
圖4是依照本發明的一實施例的一種畫素結構的剖面示意圖。在此必須說明的是,圖4的實施例沿用圖1A和圖1B的實施例的元件標號與部分內容,其中採用相同或近似的標號來表示相同或近似的元件,並且省略了相同技術內容的說明。關於省略部分的說明可參考前述實施例,在此不贅述。 FIG. 4 is a schematic cross-sectional view of a pixel structure according to an embodiment of the present invention. It must be noted here that the embodiment of FIG. 4 follows the component numbers and part of the content of the embodiment of FIG. 1A and FIG. 1B , where the same or similar numbers are used to represent the same or similar elements, and references with the same technical content are omitted. instruction. For descriptions of omitted parts, reference may be made to the foregoing embodiments and will not be described again here.
請參考圖4,在本實施例中,畫素結構包括薄膜電晶體T1、薄膜電晶體T2、畫素電極410、轉接電極420以及共用電極430。 Please refer to FIG. 4 . In this embodiment, the pixel structure includes a thin film transistor T1 , a thin film transistor T2 , a pixel electrode 410 , a transfer electrode 420 and a common electrode 430 .
薄膜電晶體T1包括第一金屬圖案120A、第一絕緣結構I1、多晶矽層200A、源極320A以及汲極330A。薄膜電晶體T2包括第一金屬圖案120B、第一絕緣結構I1、多晶矽層200B、源極320B以及汲極330B。 The thin film transistor T1 includes a first metal pattern 120A, a first insulation structure I1, a polysilicon layer 200A, a source electrode 320A, and a drain electrode 330A. The thin film transistor T2 includes a first metal pattern 120B, a first insulation structure I1, a polysilicon layer 200B, a source electrode 320B and a drain electrode 330B.
第一金屬圖案120A以及第一金屬圖案120B各自包括多個導電結構122。在本實施例中,第一金屬圖案120A以及第一金屬圖案120B各自包括三個導電結構122。第一金屬圖案120A以及第一金屬圖案120B屬於相同膜層,舉例來說,第一金屬圖案120A以及第一金屬圖案120B皆屬於第一導電層。換句話說,第一金屬圖案120A以及第一金屬圖案120B是同時形成。 Each of the first metal pattern 120A and the first metal pattern 120B includes a plurality of conductive structures 122 . In this embodiment, the first metal pattern 120A and the first metal pattern 120B each include three conductive structures 122 . The first metal pattern 120A and the first metal pattern 120B belong to the same film layer. For example, the first metal pattern 120A and the first metal pattern 120B both belong to the first conductive layer. In other words, the first metal pattern 120A and the first metal pattern 120B are formed simultaneously.
第一絕緣結構I1共形地形成於第一金屬圖案120A以及第一金屬圖案120B。在本實施例中,薄膜電晶體T1以及薄膜電晶體T2共用第一絕緣結構I1。 The first insulation structure I1 is conformally formed on the first metal pattern 120A and the first metal pattern 120B. In this embodiment, the thin film transistor T1 and the thin film transistor T2 share the first insulation structure I1.
多晶矽層200A以及多晶矽層200B共形地形成於第一絕緣結構I1上,且在基板SB的頂面的法線方向ND上分別重疊於第一金屬圖案120A以及第一金屬圖案120B。由於第一絕緣結構I1的頂面包括斜面,共形於第一絕緣結構I1的多晶矽層200A以及多晶矽層200B包括共形於前述斜面的多個傾斜部。藉由傾斜部的設計,可以使非晶矽在再結晶時受重力拉伸,進而使再結晶後的晶粒具有較長的長度。在一些實施例中,多晶矽層200A以及多晶矽層200B包含晶粒長度大於400埃的晶粒。舉例來說,多晶矽層200A以及多晶矽層200B中的至少部分晶粒的晶粒長度 大於500埃、大於600埃、大於700埃、大於800埃或大於900埃。藉由使多晶矽層200A以及多晶矽層200B中包含晶粒長度大於400埃的晶粒,可以提升多晶矽層200A以及多晶矽層200B的載子遷移率。 The polycrystalline silicon layer 200A and the polycrystalline silicon layer 200B are conformally formed on the first insulation structure I1 and overlap with the first metal pattern 120A and the first metal pattern 120B respectively in the normal direction ND of the top surface of the substrate SB. Since the top surface of the first insulation structure I1 includes a slope, the polycrystalline silicon layer 200A and the polycrystalline silicon layer 200B conforming to the first insulation structure I1 include a plurality of slope portions conforming to the slope. Through the design of the inclined portion, the amorphous silicon can be stretched by gravity during recrystallization, thereby making the recrystallized grains have a longer length. In some embodiments, polycrystalline silicon layer 200A and polycrystalline silicon layer 200B include grains with grain lengths greater than 400 Angstroms. For example, the grain length of at least some of the grains in the polycrystalline silicon layer 200A and the polycrystalline silicon layer 200B is Greater than 500 Angstroms, greater than 600 Angstroms, greater than 700 Angstroms, greater than 800 Angstroms, or greater than 900 Angstroms. By allowing the polycrystalline silicon layer 200A and the polycrystalline silicon layer 200B to include grains with a grain length greater than 400 Angstroms, the carrier mobility of the polycrystalline silicon layer 200A and the polycrystalline silicon layer 200B can be improved.
在本實施例中,多晶矽層200A經摻雜而包括第一重摻雜區232、第二重摻雜區234、第一輕摻雜區222、第二輕摻雜區224以及通道區210。多晶矽層200B經摻雜而包括第一重摻雜區232、第二重摻雜區234以及通道區210。在本實施例中,多晶矽層200A中的第一重摻雜區232、第二重摻雜區234、第一輕摻雜區222以及第二輕摻雜區224皆為N型半導體,其中第一重摻雜區232以及第二重摻雜區234的摻雜濃度大於第一輕摻雜區222以及第二輕摻雜區224的摻雜濃度。在本實施例中,多晶矽層200B中的第一重摻雜區232、第二重摻雜區234皆為P型半導體。 In this embodiment, the polysilicon layer 200A is doped to include a first heavily doped region 232 , a second heavily doped region 234 , a first lightly doped region 222 , a second lightly doped region 224 and a channel region 210 . The polysilicon layer 200B is doped to include a first heavily doped region 232, a second heavily doped region 234, and a channel region 210. In this embodiment, the first heavily doped region 232, the second heavily doped region 234, the first lightly doped region 222 and the second lightly doped region 224 in the polycrystalline silicon layer 200A are all N-type semiconductors, wherein the The doping concentrations of the first heavily doped region 232 and the second heavily doped region 234 are greater than the doping concentrations of the first lightly doped region 222 and the second lightly doped region 224 . In this embodiment, the first heavily doped region 232 and the second heavily doped region 234 in the polycrystalline silicon layer 200B are both P-type semiconductors.
第二絕緣結構I2位於多晶矽層200A以及多晶矽層200B上。 The second insulation structure I2 is located on the polycrystalline silicon layer 200A and the polycrystalline silicon layer 200B.
源極320A、汲極330A、源極320B、汲極330B以及共用訊號線340位於第二絕緣結構I2上,其中源極320A以及汲極330A電性連接至多晶矽層200A,且源極320B以及汲極330B電性連接至多晶矽層200B。在本實施例中,源極320A以及汲極330A填入第二絕緣結構I2中的通孔,並分別接觸多晶矽層200A的第一重摻雜區232以及第二重摻雜區234。在本實施例中,源 極320B以及汲極330B填入第二絕緣結構I2中的通孔,並分別接觸多晶矽層200B的第一重摻雜區232以及第二重摻雜區234。 The source electrode 320A, the drain electrode 330A, the source electrode 320B, the drain electrode 330B and the common signal line 340 are located on the second insulating structure I2. The source electrode 320A and the drain electrode 330A are electrically connected to the polysilicon layer 200A, and the source electrode 320B and the drain electrode 330A are electrically connected to the polysilicon layer 200A. Pole 330B is electrically connected to polysilicon layer 200B. In this embodiment, the source electrode 320A and the drain electrode 330A fill the through holes in the second insulation structure I2 and contact the first heavily doped region 232 and the second heavily doped region 234 of the polycrystalline silicon layer 200A respectively. In this example, the source The electrode 320B and the drain electrode 330B fill the through holes in the second insulation structure I2 and contact the first heavily doped region 232 and the second heavily doped region 234 of the polycrystalline silicon layer 200B respectively.
源極320A、汲極330A、源極320B、汲極330B以及共用訊號線340屬於相同膜層,舉例來說,源極320A、汲極330A、源極320B、汲極330B以及共用訊號線340皆屬於第二導電層。換句話說,源極320A、汲極330A、源極320B、汲極330B以及共用訊號線340是同時形成。 The source electrode 320A, the drain electrode 330A, the source electrode 320B, the drain electrode 330B and the common signal line 340 belong to the same film layer. For example, the source electrode 320A, the drain electrode 330A, the source electrode 320B, the drain electrode 330B and the common signal line 340 are all Belongs to the second conductive layer. In other words, the source electrode 320A, the drain electrode 330A, the source electrode 320B, the drain electrode 330B and the common signal line 340 are formed at the same time.
第三絕緣結構I3位於源極320A、汲極330A、源極320B、汲極330B以及共用訊號線340上。 The third insulating structure I3 is located on the source electrode 320A, the drain electrode 330A, the source electrode 320B, the drain electrode 330B and the common signal line 340.
轉接電極420以及共用電極430位於三絕緣結構I3上。轉接電極420填入第三絕緣結構I3中的通孔,並接觸汲極330A。共用電極430填入第三絕緣結構I3中的通孔,並接觸共用訊號線340。在一些實施例中,轉接電極420以及共用電極430的材料包括銦錫氧化物、銦鋅氧化物、鋁錫氧化物、鋁鋅氧化物、銦鎵鋅氧化物、或是上述至少二者之堆疊層。 The transfer electrode 420 and the common electrode 430 are located on the three-insulation structure I3. The transfer electrode 420 fills the through hole in the third insulating structure I3 and contacts the drain electrode 330A. The common electrode 430 fills the through hole in the third insulation structure I3 and contacts the common signal line 340 . In some embodiments, the materials of the transfer electrode 420 and the common electrode 430 include indium tin oxide, indium zinc oxide, aluminum tin oxide, aluminum zinc oxide, indium gallium zinc oxide, or at least two of the above. Stack layers.
第四絕緣結構I4位於轉接電極420以及共用電極430上。 The fourth insulation structure I4 is located on the transfer electrode 420 and the common electrode 430 .
畫素電極410位於四絕緣結構I4上。畫素電極410填入第四絕緣結構I4中的通孔,並接觸轉接電極420。 The pixel electrode 410 is located on the four-insulation structure I4. The pixel electrode 410 fills the through hole in the fourth insulation structure I4 and contacts the transfer electrode 420.
圖5是依照本發明的一實施例的一種畫素結構的剖面示意圖。在此必須說明的是,圖5的實施例沿用圖5的實施例的元 件標號與部分內容,其中採用相同或近似的標號來表示相同或近似的元件,並且省略了相同技術內容的說明。關於省略部分的說明可參考前述實施例,在此不贅述。 FIG. 5 is a schematic cross-sectional view of a pixel structure according to an embodiment of the present invention. It must be noted here that the embodiment of Figure 5 follows the elements of the embodiment of Figure 5 Part numbers and part of the content, the same or similar numbers are used to represent the same or similar components, and the description of the same technical content is omitted. For descriptions of omitted parts, reference may be made to the foregoing embodiments and will not be described again here.
請參考圖5,在本實施例中,薄膜電晶體T1還包括第一頂閘極TG1。薄膜電晶體T2還包括第二頂閘極TG2。 Please refer to FIG. 5 . In this embodiment, the thin film transistor T1 further includes a first top gate TG1 . The thin film transistor T2 also includes a second top gate TG2.
在本實施例中,第二絕緣結構I2包括閘極絕緣層I2a以及層間介電層I2b。閘極絕緣層I2a位於多晶矽層200A以及多晶矽層200B上。 In this embodiment, the second insulation structure I2 includes a gate insulation layer I2a and an interlayer dielectric layer I2b. The gate insulating layer I2a is located on the polysilicon layer 200A and the polysilicon layer 200B.
第一頂閘極TG1以及第二頂閘極TG2位於閘極絕緣層I2a上,其中第一頂閘極TG1在法線方向ND上重疊於多晶矽層200A以及第一金屬圖案120A,且第二頂閘極TG2在法線方向ND上重疊於多晶矽層200B以及第二金屬圖案120B。 The first top gate TG1 and the second top gate TG2 are located on the gate insulating layer I2a, where the first top gate TG1 overlaps the polysilicon layer 200A and the first metal pattern 120A in the normal direction ND, and the second top gate TG1 The gate TG2 overlaps the polysilicon layer 200B and the second metal pattern 120B in the normal direction ND.
在一些實施例中,薄膜電晶體T1以及薄膜電晶體T2皆為雙閘極型薄膜電晶體,其中第一金屬圖案120A與第一頂閘極TG1彼此電性連接,且第二金屬圖案120B與第二頂閘極TG2彼此電性連接。在其他實施例中,薄膜電晶體T1以及薄膜電晶體T2皆為頂閘極型薄膜電晶體,其中第一金屬圖案120A與二金屬圖案120B皆為遮光結構。當第一金屬圖案120A與二金屬圖案120B為遮光結構時,第一金屬圖案120A與二金屬圖案120B可以為浮置結構。 In some embodiments, the thin film transistor T1 and the thin film transistor T2 are both dual-gate thin film transistors, in which the first metal pattern 120A and the first top gate TG1 are electrically connected to each other, and the second metal pattern 120B is electrically connected to each other. The second top gates TG2 are electrically connected to each other. In other embodiments, the thin film transistor T1 and the thin film transistor T2 are both top-gate thin film transistors, in which the first metal pattern 120A and the second metal pattern 120B are both light-shielding structures. When the first metal pattern 120A and the second metal pattern 120B are light-shielding structures, the first metal pattern 120A and the second metal pattern 120B may be a floating structure.
層間介電層I2b位於閘極絕緣層I2a、第一頂閘極TG1以及第二頂閘極TG2上。源極320A、汲極330A、源極320B、 汲極330B以及共用訊號線340位於層間介電層I2b上。 The interlayer dielectric layer I2b is located on the gate insulating layer I2a, the first top gate TG1 and the second top gate TG2. Source 320A, drain 330A, source 320B, The drain electrode 330B and the common signal line 340 are located on the interlayer dielectric layer I2b.
圖6是依照本發明的一實施例的一種多晶矽層的掃描式電子顯微鏡照片。舉例來說,在利用圖2A至圖2E的製程形成多晶矽層200之後,利用電子顯微鏡拍攝多晶矽層200的表面。由圖6可以得知,多晶矽層200包含晶粒長度L”大於400埃的晶粒。另外,在圖6中,以虛線示意出對應於導電結構之第一側面與第二側面的交界線的位置,由圖6可以得知,當導電結構的剖面形狀為三角形時,在對應第一側面與第二側面的交界線的位置,多晶矽層的晶粒的邊界會彼此連接成接近直線的一條線。 Figure 6 is a scanning electron microscope photograph of a polycrystalline silicon layer according to an embodiment of the present invention. For example, after the polycrystalline silicon layer 200 is formed using the process of FIGS. 2A to 2E , the surface of the polycrystalline silicon layer 200 is photographed using an electron microscope. It can be seen from FIG. 6 that the polycrystalline silicon layer 200 includes grains with a grain length L″ greater than 400 Angstroms. In addition, in FIG. 6 , a dotted line is used to illustrate the boundary line corresponding to the first side and the second side of the conductive structure. position, it can be known from Figure 6 that when the cross-sectional shape of the conductive structure is a triangle, at the position corresponding to the intersection line between the first side and the second side, the boundaries of the grains of the polycrystalline silicon layer will be connected to each other to form a nearly straight line. .
圖7A是依照本發明的一實施例的一種第一金屬圖案、第一絕緣結構以及多晶矽層的掃描式電子顯微鏡照片。圖7B是依照本發明的一實施例的一種第一金屬圖案、第一絕緣結構以及多晶矽層的穿透式電子顯微鏡照片。 7A is a scanning electron microscope photograph of a first metal pattern, a first insulating structure and a polycrystalline silicon layer according to an embodiment of the present invention. 7B is a transmission electron microscope photograph of a first metal pattern, a first insulating structure and a polycrystalline silicon layer according to an embodiment of the present invention.
請參考圖7A與圖7B,在本實施例中,第一金屬圖案僅包括單一個導電結構122,且導電結構122為三角形。此外,在本實施例中,第一絕緣結構I1包括位於導電結構122上的氧化矽層I1a以及位於氧化矽層I1a上的氮化矽層I1b。多晶矽層200位於氮化矽層I1b上。 Please refer to FIGS. 7A and 7B . In this embodiment, the first metal pattern only includes a single conductive structure 122 , and the conductive structure 122 is triangular. In addition, in this embodiment, the first insulating structure I1 includes a silicon oxide layer I1a located on the conductive structure 122 and a silicon nitride layer I1b located on the silicon oxide layer I1a. The polysilicon layer 200 is located on the silicon nitride layer I1b.
圖8A至圖8C分別是利用不同蝕刻參數所形成的第一金屬圖案的穿透式電子顯微鏡照片。由圖8A至圖8C可以得知,藉由調整蝕刻參數,可以改變第一金屬圖案120(或導電結構)的側面與底面之間的角度θ。當第一金屬圖案120(或導電結構) 的側面與底面之間的角度θ越緩,則第一金屬圖案120(或導電結構)的側面的長度越長。 8A to 8C are transmission electron microscopy photos of the first metal pattern formed using different etching parameters. It can be known from FIGS. 8A to 8C that by adjusting the etching parameters, the angle θ between the side surface and the bottom surface of the first metal pattern 120 (or conductive structure) can be changed. When the first metal pattern 120 (or conductive structure) The slower the angle θ between the side surface and the bottom surface, the longer the length of the side surface of the first metal pattern 120 (or the conductive structure).
圖9A至圖9E分別是利用不同能量的準分子雷射退火製程所形成的多晶矽層的穿透式電子顯微鏡照片。在圖9A至圖9E所示的多晶矽層下方,包括第一絕緣結構(請參考圖1B與其相關說明)以及剖面形狀為三角形的第一導電結構(請參考圖1B與其相關說明)。圖9A、圖9B、圖9C、圖9D以及圖9E所使用的準分子雷射退火製程的能量分別為400mJ/cm2、410mJ/cm2、420mJ/cm2、430mJ/cm2以及440mJ/cm2。圖10是準分子雷射退火製程的能量與多晶矽層的晶粒長度的實驗數據圖。由圖9A可以得知,透過本發明的第一金屬圖案的設計,只要將準分子雷射退火製程的能量調整至400mJ/cm2,就可以使多晶矽層包含晶粒長度大於400埃的晶粒。另外,由圖9A至9E以及圖10可以得知,當準分子雷射退火製程所用的能量越高,多晶矽層中的晶粒的晶粒長度越長。然而,當準分子雷射退火製程所用的能量太高,例如荼9E所示的高於440mJ/cm2,多晶矽層容易因為能量過高而受損。 Figures 9A to 9E are transmission electron microscopy photos of polycrystalline silicon layers formed using excimer laser annealing processes with different energies. Below the polycrystalline silicon layer shown in FIGS. 9A to 9E , there is a first insulating structure (please refer to FIG. 1B and its related description) and a first conductive structure with a triangular cross-sectional shape (please refer to FIG. 1B and its related description). The energies of the excimer laser annealing processes used in Figures 9A, 9B, 9C, 9D and 9E are 400mJ/cm 2 , 410mJ/cm 2 , 420mJ/cm 2 , 430mJ/cm 2 and 440mJ/cm respectively. 2 . Figure 10 is an experimental data diagram showing the energy of the excimer laser annealing process and the grain length of the polycrystalline silicon layer. It can be seen from Figure 9A that through the design of the first metal pattern of the present invention, as long as the energy of the excimer laser annealing process is adjusted to 400mJ/cm 2 , the polycrystalline silicon layer can contain grains with a grain length greater than 400 Angstroms. . In addition, it can be known from FIGS. 9A to 9E and FIG. 10 that the higher the energy used in the excimer laser annealing process, the longer the grain length of the grains in the polycrystalline silicon layer. However, when the energy used in the excimer laser annealing process is too high, such as higher than 440mJ/cm 2 as shown in Figure 9E, the polycrystalline silicon layer is easily damaged due to the high energy.
綜上所述,透過本發明的第一金屬圖案的設計,可以在準分子雷射退火製程中利用重力增加多晶矽層中的晶粒的晶粒長度,因此,不需要將準分子雷射退火製程的能量調到很高就可以獲得足夠長的晶粒長度,藉此提升多晶矽層中的載子遷移率。 In summary, through the design of the first metal pattern of the present invention, gravity can be used to increase the grain length of the crystal grains in the polycrystalline silicon layer during the excimer laser annealing process. Therefore, there is no need to use the excimer laser annealing process. By adjusting the energy to a high level, a sufficiently long grain length can be obtained, thereby increasing the carrier mobility in the polycrystalline silicon layer.
120:第一金屬圖案 120: First metal pattern
122:導電結構 122:Conductive structure
122a:第一側面 122a: first side
122b:第二側面 122b: Second side
122c:底面 122c: Bottom surface
200:多晶矽層 200:Polycrystalline silicon layer
210:通道區 210: Passage area
222:第一輕摻雜區 222: First lightly doped region
224:第二輕摻雜區 224: The second lightly doped region
232:第一重摻雜區 232: First heavily doped region
234:第二重摻雜區 234: The second heavily doped region
200a:第一傾斜部 200a: first inclined part
200b:第二傾斜部 200b: Second inclined part
320:源極 320:Source
330:汲極 330:Jiji
400:畫素電極 400: Pixel electrode
D1:第一方向 D1: first direction
h:厚度 h: Thickness
I1:第一絕緣結構 I1: First insulation structure
I2:第二絕緣結構 I2: Second insulation structure
I3:第三絕緣結構 I3: The third insulation structure
L,L’:長度 L, L’: length
ND:法線方向 ND: normal direction
P:間距 P: pitch
SB:基板 SB:Substrate
T1:薄膜電晶體 T1: thin film transistor
θ1,θ2:角度 θ1, θ2: angle
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| TW200722560A (en) * | 2005-12-12 | 2007-06-16 | Ind Tech Res Inst | Method of fabricating a poly-silicon thin film |
| US20070215887A1 (en) * | 2002-12-27 | 2007-09-20 | General Electric Company | Gallium nitride crystal and method of making same |
| CN104409517A (en) * | 2009-07-29 | 2015-03-11 | Nlt科技股份有限公司 | Thin film transistor substrate and thin film transistor used for the same |
| CN106663394A (en) * | 2014-07-23 | 2017-05-10 | 索尼公司 | Display device, method of manufacturing display device, and electronic apparatus |
| CN109285782A (en) * | 2018-10-15 | 2019-01-29 | 深圳市华星光电技术有限公司 | Thin film transistor structure and method of making the same |
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| US20070215887A1 (en) * | 2002-12-27 | 2007-09-20 | General Electric Company | Gallium nitride crystal and method of making same |
| TW200722560A (en) * | 2005-12-12 | 2007-06-16 | Ind Tech Res Inst | Method of fabricating a poly-silicon thin film |
| CN104409517A (en) * | 2009-07-29 | 2015-03-11 | Nlt科技股份有限公司 | Thin film transistor substrate and thin film transistor used for the same |
| CN106663394A (en) * | 2014-07-23 | 2017-05-10 | 索尼公司 | Display device, method of manufacturing display device, and electronic apparatus |
| CN109285782A (en) * | 2018-10-15 | 2019-01-29 | 深圳市华星光电技术有限公司 | Thin film transistor structure and method of making the same |
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