TWI898351B - Method of forming semiconductor structure - Google Patents
Method of forming semiconductor structureInfo
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- TWI898351B TWI898351B TW112148151A TW112148151A TWI898351B TW I898351 B TWI898351 B TW I898351B TW 112148151 A TW112148151 A TW 112148151A TW 112148151 A TW112148151 A TW 112148151A TW I898351 B TWI898351 B TW I898351B
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Abstract
Description
本揭露是關於一種半導體結構與其製作方法。 This disclosure relates to a semiconductor structure and a method for manufacturing the same.
高效能、高功率、高密度以及高可靠度為電子裝置發展的趨勢。然而,隨著電子裝置的耗能越來越高,其所產生的熱能也對應增加。因此,如何增進電子裝置的散熱能力,便成為一個課題。 High performance, high power, high density, and high reliability are the development trends of electronic devices. However, as the energy consumption of electronic devices increases, the heat energy they generate also increases accordingly. Therefore, how to improve the heat dissipation capacity of electronic devices has become a topic of discussion.
根據本揭露的一實施方式,提供了一種半導體結構,包含半導體基板,以及設置在半導體基板的表面上的散熱元件。散熱元件包含凸出部,各凸出部包含第一段與第二段,其中第一段的尺寸不同於第二段的尺寸。 According to one embodiment of the present disclosure, a semiconductor structure is provided, comprising a semiconductor substrate and a heat sink disposed on a surface of the semiconductor substrate. The heat sink comprises protrusions, each of which comprises a first section and a second section, wherein the dimensions of the first section are different from the dimensions of the second section.
在一些實施例中,半導體結構更包含設置在半導體基板的表面上的內墊氧化矽層,以及設置在內墊氧化矽層上的種子層,其中凸出部的底部透過種子層相連。 In some embodiments, the semiconductor structure further includes an interpad silicon oxide layer disposed on a surface of the semiconductor substrate, and a seed layer disposed on the interpad silicon oxide layer, wherein the bottoms of the protrusions are connected through the seed layer.
在一些實施例中,凸出部直接設置在半導體基板的表面上,凸出部的底部彼此分離。 In some embodiments, the protrusions are directly disposed on the surface of the semiconductor substrate, and the bottoms of the protrusions are separated from each other.
在一些實施例中,凸出部的底部嵌入半導體基板的 表面。 In some embodiments, the bottom of the protrusion is embedded in the surface of the semiconductor substrate.
在一些實施例中,半導體結構更包含設置在半導體基板中的通孔,其中通孔連接至凸出部的一或多個。 In some embodiments, the semiconductor structure further includes a through-hole disposed in the semiconductor substrate, wherein the through-hole is connected to one or more of the protrusions.
根據本揭露的另一實施方式,提供了一種半導體結構,包含第一半導體基板、第二半導體基板,以及散熱元件。第一半導體基板包含正面與背面,第二半導體基板包含正面與背面,其中第二半導體基板的正面與第二半導體基板的正面接合。散熱元件設置在第一半導體基板的背面上,散熱元件包含凸出部,凸出部包含第一段與第二段,其中第一段的尺寸不同於第二段的尺寸。 According to another embodiment of the present disclosure, a semiconductor structure is provided, comprising a first semiconductor substrate, a second semiconductor substrate, and a heat sink. The first semiconductor substrate comprises a front surface and a back surface, and the second semiconductor substrate comprises a front surface and a back surface, wherein the front surface of the second semiconductor substrate is bonded to the front surface of the second semiconductor substrate. The heat sink is disposed on the back surface of the first semiconductor substrate and comprises a protrusion, the protrusion comprising a first section and a second section, wherein the dimensions of the first section are different from the dimensions of the second section.
在一些實施例中,第一半導體基板為CMOS基板且第二半導體基板為陣列基板,或者,第一半導體基板為陣列基板且第二半導體基板為CMOS基板。 In some embodiments, the first semiconductor substrate is a CMOS substrate and the second semiconductor substrate is an array substrate, or the first semiconductor substrate is an array substrate and the second semiconductor substrate is a CMOS substrate.
根據本揭露的另一實施方式,提供了一種半導體結構的製作方法,包含:形成犧牲層堆疊在半導體基板的一表面上,犧牲層堆疊包含交替且重複地排列的複數個第一犧牲層與複數個第二犧牲層,且第一犧牲層的材料不同於第二犧牲層的材料;執行非等向性蝕刻製程於犧牲層堆疊,以形成在犧牲層結構之間的溝槽,犧牲層結構包含第一犧牲層與第二犧牲層;執行等向性蝕刻製程於犧牲層結構,以在第一犧牲層與第二犧牲層之間形成空腔;以導熱材料填充溝槽與空腔;以及移除犧牲層結構,其中導熱材料所留下來的部分成為位在半導體基板的表面上的散熱元件中的凸出部。 According to another embodiment of the present disclosure, a method for manufacturing a semiconductor structure is provided, comprising: forming a sacrificial layer stack on a surface of a semiconductor substrate, wherein the sacrificial layer stack comprises a plurality of first sacrificial layers and a plurality of second sacrificial layers arranged alternately and repeatedly, and the material of the first sacrificial layers is different from the material of the second sacrificial layers; performing an anisotropic etching process on the sacrificial layer stack to form A trench is formed between a sacrificial layer structure, the sacrificial layer structure comprising a first sacrificial layer and a second sacrificial layer; an isotropic etching process is performed on the sacrificial layer structure to form a cavity between the first sacrificial layer and the second sacrificial layer; the trench and the cavity are filled with a thermally conductive material; and the sacrificial layer structure is removed, wherein the remaining portion of the thermally conductive material becomes a protrusion in a heat sink located on a surface of a semiconductor substrate.
在一些實施例中,犧牲層堆疊包含複數個第三犧牲層,且第三犧牲層的材料不同於第一犧牲層的材料,第三犧牲層的材料不同於第二犧牲層的材料。 In some embodiments, the sacrificial layer stack includes a plurality of third sacrificial layers, and the material of the third sacrificial layer is different from the material of the first sacrificial layer, and the material of the third sacrificial layer is different from the material of the second sacrificial layer.
在一些實施例中,半導體結構的製作方法更包含:形成內墊氧化矽層在半導體基板的表面上;以及形成種子層在內墊氧化矽層上,其中以導熱材料填充溝槽與空腔的步驟包含執行電鍍製程。 In some embodiments, the method for fabricating a semiconductor structure further includes: forming an inter-pad silicon oxide layer on a surface of a semiconductor substrate; and forming a seed layer on the inter-pad silicon oxide layer, wherein the step of filling the trenches and cavities with a thermally conductive material includes performing an electroplating process.
本揭露提供了一種半導體結構與其製作方法。半導體結構具有半導體基板以及設置在半導體基板上的散熱元件,其中散熱元件是由半導體製程所製作且具有多個凸出部。每個凸出部具有皺褶的側表面,藉以增加凸出部的表面積,進而提升散熱元件的散熱效率。 This disclosure provides a semiconductor structure and a method for manufacturing the same. The semiconductor structure comprises a semiconductor substrate and a heat sink disposed on the semiconductor substrate. The heat sink is fabricated using a semiconductor process and has a plurality of protrusions. Each protrusion has a corrugated side surface, thereby increasing the surface area of the protrusion and thereby improving the heat dissipation efficiency of the heat sink.
100:半導體結構 100:Semiconductor structure
110:半導體基板 110: Semiconductor substrate
110a:第一半導體基板 110a: First semiconductor substrate
110b:第二半導體基板 110b: Second semiconductor substrate
110c:晶圓 110c: Wafer
110d:晶片 110d: Chip
110e:第一晶片 110e: First chip
110f:第二晶片 110f: Second chip
120:內墊氧化矽層 120: Inner pad silicon oxide layer
130:種子層 130:Seed layer
140:犧牲層堆疊 140: Sacrificial Layer Stacking
142:第一犧牲層 142: The First Sacrificial Layer
144:第二犧牲層 144: Second Sacrificial Layer
146:犧牲層結構 146: Sacrificial Layer Structure
148:第三犧牲層 148: The Third Sacrificial Layer
150:溝槽 150: Groove
152:空腔 152: Cavity
154:凹陷部 154: Depression
160:導熱材料 160: Thermal conductive material
200:散熱元件 200: Heat dissipation element
210:凸出部 210: Protrusion
212:第一段 212: First paragraph
214:第二段 214: Second paragraph
216:第三段 216: Third paragraph
220:通孔 220: Through hole
222:黏著層 222: Adhesive layer
224:導體核 224: Conductor Core
230:連接墊 230:Connection pad
S10,S12,S14,S16,S18,S20,S22,S30,S32,S34,S36,S38,S40,S42,S44:步驟 S10, S12, S14, S16, S18, S20, S22, S30, S32, S34, S36, S38, S40, S42, S44: Steps
Lx:寬度 Lx: Width
Ly:長度 Ly: Length
H:高度 H: Height
S:間距 S: Spacing
FS:正面 FS: Front
BS:背面 BS: Back
為讓本揭露之目的、特徵、優點與實施例能更明顯易懂,所附圖式之詳細說明如下: To make the purpose, features, advantages and embodiments of this disclosure more clearly understood, the attached drawings are described in detail as follows:
第1圖為根據本揭露之半導體結構的一些實施例的立體視圖。 Figure 1 is a perspective view of some embodiments of the semiconductor structure according to the present disclosure.
第2圖為第1圖之半導體結構的上視圖。 Figure 2 is a top view of the semiconductor structure in Figure 1.
第3圖為第1圖之半導體結構的剖面圖。 Figure 3 is a cross-sectional view of the semiconductor structure in Figure 1.
第4圖至第10圖分別為本揭露之半導體結構的製作方法的一些實施例於不同階段的剖面圖。 Figures 4 to 10 are cross-sectional views of some embodiments of the semiconductor structure fabrication method disclosed herein at different stages.
第11圖至第15圖分別為本揭露之半導體結構的製作方法的一些實施例於不同階段的剖面圖。 Figures 11 to 15 are cross-sectional views of some embodiments of the semiconductor structure fabrication method disclosed herein at different stages.
第16圖至第18圖分別為本揭露之半導體結構的製作方法的一些實施例於不同階段的剖面圖。 Figures 16 to 18 are cross-sectional views of some embodiments of the semiconductor structure fabrication method disclosed herein at different stages.
第19A圖至第19E圖分別為根據本揭露的半導體結構中的散熱元件的凸出部之不同實施例的上視示意圖。 Figures 19A to 19E are schematic top views of different embodiments of the protrusions of the heat sink in the semiconductor structure according to the present disclosure.
第20A圖與第20B圖分別為根據本揭露的半導體結構中的散熱元件的凸出部之不同實施例的上視示意圖。 Figures 20A and 20B are schematic top views of different embodiments of the protrusions of the heat sink in the semiconductor structure according to the present disclosure.
第21圖為根據本揭露之半導體結構的一些實施例的剖面圖。 Figure 21 is a cross-sectional view of some embodiments of the semiconductor structure according to the present disclosure.
第22圖與第23圖分別為根據本揭露之半導體結構的不同實施例的剖面圖。 Figures 22 and 23 are cross-sectional views of different embodiments of the semiconductor structure according to the present disclosure.
第24圖為根據本揭露的半導體結構之一些實施例的上視示意圖。 Figure 24 is a schematic top view of some embodiments of the semiconductor structure according to the present disclosure.
第25圖為根據本揭露的半導體結構之一些實施例的上視示意圖。 Figure 25 is a schematic top view of some embodiments of the semiconductor structure according to the present disclosure.
以下將以圖式及詳細說明清楚說明本揭露之精神,任何所屬技術領域中具有通常知識者在瞭解本揭露之較佳實施例後,當可由本揭露所教示之技術,加以改變及修飾,其並不脫離本揭露之精神與範圍。 The following diagrams and detailed descriptions clearly illustrate the spirit of this disclosure. After understanding the preferred embodiments of this disclosure, anyone skilled in the art can make changes and modifications based on the techniques taught by this disclosure without departing from the spirit and scope of this disclosure.
參照第1圖至第3圖,其中第1圖為根據本揭露之半導體結構的一些實施例的立體視圖,第2圖為第1圖之半導體結構的上視圖,第3圖為第1圖之半導體結構的剖面圖。本揭露提供了一種具有散熱元件200的半導體結 構100。半導體結構100包含有半導體基板110、設置在半導體結構100之表面上的內墊氧化矽層120、以及設置在內墊氧化矽層120上的散熱元件200。散熱元件200為由導熱性佳的材料所製成,且散熱元件200為一體成形地製作而成。更具體地說,散熱元件200包含有多個凸出部210直立在內墊氧化矽層120上的種子層130上,其中內墊氧化矽層120在半導體結構100之表面上。每一個凸出部210皆具有皺褶狀的側表面,藉以增加凸出部210的表面積,進而提升散熱元件200的熱交換效率。 Referring to Figures 1 to 3 , Figure 1 is a perspective view of some embodiments of semiconductor structures according to the present disclosure, Figure 2 is a top view of the semiconductor structure in Figure 1 , and Figure 3 is a cross-sectional view of the semiconductor structure in Figure 1 . The present disclosure provides a semiconductor structure 100 having a heat sink 200 . The semiconductor structure 100 includes a semiconductor substrate 110 , an inter-pad silicon oxide layer 120 disposed on a surface of the semiconductor structure 100 , and a heat sink 200 disposed on the inter-pad silicon oxide layer 120 . The heat sink 200 is made of a material with high thermal conductivity and is integrally formed. More specifically, the heat sink 200 includes a plurality of protrusions 210 standing upright on the seed layer 130 on the inner pad silicon oxide layer 120, wherein the inner pad silicon oxide layer 120 is on the surface of the semiconductor structure 100. Each protrusion 210 has a corrugated side surface to increase the surface area of the protrusion 210, thereby improving the heat exchange efficiency of the heat sink 200.
在一些實施例中,半導體基板110可以為或是包含塊體(bulk)半導體基板(即塊體矽基板)、絕緣體上矽(silicon-on insulator,SOI)基板、或是其他適合的基板材料。在一些實施例中,半導體基板110可以包含有一或多個摻雜區。在一些實施例中,半導體基板110可包含有積體電路及/或半導體元件。在一些實施例中,半導體基板110可以為晶圓(wafer)或是晶片(chip)。 In some embodiments, the semiconductor substrate 110 may be or include a bulk semiconductor substrate (i.e., a bulk silicon substrate), a silicon-on-insulator (SOI) substrate, or other suitable substrate materials. In some embodiments, the semiconductor substrate 110 may include one or more doped regions. In some embodiments, the semiconductor substrate 110 may include integrated circuits and/or semiconductor devices. In some embodiments, the semiconductor substrate 110 may be a wafer or a chip.
在一些實施例中,散熱元件200是由一連串的半導體製程,包含沉積步驟、微影步驟、蝕刻步驟等製作而成的。在一些實施例中,每一個散熱元件200的凸出部210具有多個第一段212及多個第二段214,其中第一段212的尺寸為大於第二段214的尺寸。舉例而言,第一段212跟第二段214可以是矩形的,而第一段212的寬度或是長度(Lx或是Ly)為大於第二段214的寬度或是長度。 In some embodiments, the heat sink 200 is fabricated through a series of semiconductor processes, including deposition, lithography, and etching. In some embodiments, the protrusion 210 of each heat sink 200 includes multiple first segments 212 and multiple second segments 214, with the first segments 212 having larger dimensions than the second segments 214. For example, the first segments 212 and the second segments 214 may be rectangular, with the width or length (Lx or Ly) of the first segment 212 being larger than the width or length of the second segment 214.
在一些實施例中,為了提供更好的散熱效果但是不 額外增加散熱元件200的空間,每一個凸出部210的高度H為在100μm至5000μm的範圍之間,相鄰的凸出部210之間的間距S為在50μm至500μm的範圍之間,每一個凸出部210的寬度Lx或是長度Ly為在50μm至50mm的範圍之間。 In some embodiments, to provide better heat dissipation without increasing the space required for the heat sink 200, the height H of each protrusion 210 is in the range of 100 μm to 5000 μm, the spacing S between adjacent protrusions 210 is in the range of 50 μm to 500 μm, and the width Lx or length Ly of each protrusion 210 is in the range of 50 μm to 50 mm.
相鄰的凸出部210之間的間距S可以被視為流道以供介質通過而與散熱元件200之凸出部210的皺褶狀側表面進行熱交換。在一些實施例中,散熱元件200為氣冷式的散熱元件,而通過間距S的介質為空氣。在一些實施例中,散熱元件200為水冷式的散熱元件,而通過間距S的介質為流體。 The spacing S between adjacent protrusions 210 can be considered a flow channel for a medium to pass through and exchange heat with the corrugated side surfaces of the protrusions 210 of the heat sink 200. In some embodiments, the heat sink 200 is an air-cooled heat sink, and the medium passing through the spacing S is air. In some embodiments, the heat sink 200 is a water-cooled heat sink, and the medium passing through the spacing S is fluid.
參照第4圖至第10圖,其分別為本揭露之半導體結構的製作方法的一些實施例於不同階段的剖面圖。半導體結構的製作方法始於步驟S10,提供半導體基板110。半導體基板110可以為或是包含塊體半導體基板(即塊體矽基板)、絕緣體上矽基板、或是其他適合的基板材料。在一些實施例中,半導體基板110可以包含有一或多個摻雜區。在一些實施例中,半導體基板110可包含有積體電路及/或半導體元件。在一些實施例中,半導體基板110可以為晶圓或是晶片。在一些實施例中,可執行薄化製程於半導體基板110上,以減少半導體基板110的厚度。 Refer to Figures 4 to 10, which are cross-sectional views of some embodiments of the method for manufacturing a semiconductor structure disclosed herein at different stages. The method for manufacturing a semiconductor structure begins with step S10, providing a semiconductor substrate 110. The semiconductor substrate 110 may be or include a bulk semiconductor substrate (i.e., a bulk silicon substrate), a silicon-on-insulator substrate, or other suitable substrate materials. In some embodiments, the semiconductor substrate 110 may include one or more doped regions. In some embodiments, the semiconductor substrate 110 may include an integrated circuit and/or semiconductor elements. In some embodiments, the semiconductor substrate 110 may be a wafer or a chip. In some embodiments, a thinning process may be performed on the semiconductor substrate 110 to reduce the thickness of the semiconductor substrate 110.
在步驟S10中,內墊氧化矽層120被沉積在半導體基板110的表面上,接著,種子層130進一步沉積在內墊氧化矽層120上。在一些實施例中,內墊氧化矽層120 的材料為二氧化矽,種子層130的材料為金屬,如銅。內墊氧化矽層120可以做為毯覆層以防止種子層130中的銅擴散至半導體基板110中。在一些實施例中,種子層130可以是單層或是多層結構,且種子層130與半導體基板110之間具有良好的附著力。 In step S10, an inter-pad silicon oxide layer 120 is deposited on the surface of the semiconductor substrate 110. Then, a seed layer 130 is further deposited on the inter-pad silicon oxide layer 120. In some embodiments, the inter-pad silicon oxide layer 120 is made of silicon dioxide, and the seed layer 130 is made of a metal, such as copper. The inter-pad silicon oxide layer 120 serves as a blanket layer to prevent the copper in the seed layer 130 from diffusing into the semiconductor substrate 110. In some embodiments, the seed layer 130 can be a single layer or a multi-layer structure, and the seed layer 130 has good adhesion to the semiconductor substrate 110.
參照第5圖,在步驟S12中,犧牲層堆疊140被形成在種子層130上。犧牲層堆疊140包含有多個第一犧牲層142以及多個第二犧牲層144,其中第一犧牲層142以及第二犧牲層144為交替且重複的堆疊設置。在一些實施例中,第一犧牲層142以及第二犧牲層144可以由多個循環的沉積製程所形成,且第一犧牲層142與第二犧牲層144的厚度為在數十奈米至數十毫米之間。在一些實施例中,第一犧牲層142以及第二犧牲層144的厚度可以相同或是不同。 Referring to FIG. 5 , in step S12, a sacrificial layer stack 140 is formed on the seed layer 130. The sacrificial layer stack 140 includes a plurality of first sacrificial layers 142 and a plurality of second sacrificial layers 144, wherein the first sacrificial layers 142 and the second sacrificial layers 144 are alternately and repeatedly stacked. In some embodiments, the first sacrificial layers 142 and the second sacrificial layers 144 can be formed by multiple cycles of deposition processes, and the thickness of the first sacrificial layers 142 and the second sacrificial layers 144 ranges from tens of nanometers to tens of millimeters. In some embodiments, the thicknesses of the first sacrificial layer 142 and the second sacrificial layer 144 may be the same or different.
第一犧牲層142以及第二犧牲層144為由介電材料製成,且第一犧牲層142的材料不同於第二犧牲層144的材料,以在第一犧牲層142與第二犧牲層144之間提供足夠的蝕刻選擇比。舉例而言,第一犧牲層142的材料可以為氧化物,如二氧化矽,第二犧牲層144的材料可以為氮化物,如氮化矽。 The first sacrificial layer 142 and the second sacrificial layer 144 are made of a dielectric material. The material of the first sacrificial layer 142 is different from the material of the second sacrificial layer 144 to provide sufficient etching selectivity between the first sacrificial layer 142 and the second sacrificial layer 144. For example, the material of the first sacrificial layer 142 can be an oxide, such as silicon dioxide, and the material of the second sacrificial layer 144 can be a nitride, such as silicon nitride.
參照第6圖,在步驟S14中,執行非等向性蝕刻製程以圖案化犧牲層堆疊140。非等向性蝕刻製程為具有方向性的且其對第一犧牲層142與第二犧牲層144具有大致上相同的蝕刻速率。非等向性蝕刻製程停止於種子層 130。在一些實施例中,非等向性蝕刻製程移除掉一部分的犧牲層堆疊140,而犧牲層堆疊140被移除掉的部分可以是格柵狀或是線狀的,以在犧牲層堆疊140中形成格柵狀或是線狀的溝槽150。在執行完非等向性蝕刻製程之後,多個犧牲層結構146形成在種子層130上。溝槽150形成在犧牲層結構146之間。犧牲層結構146的第一犧牲層142與第二犧牲層144的側表面經由溝槽150暴露。 Referring to FIG. 6 , in step S14 , an anisotropic etching process is performed to pattern the sacrificial layer stack 140 . The anisotropic etching process is directional and has substantially the same etching rate for the first sacrificial layer 142 and the second sacrificial layer 144 . The anisotropic etching process stops at the seed layer 130 . In some embodiments, the anisotropic etching process removes a portion of the sacrificial layer stack 140 . The removed portion of the sacrificial layer stack 140 may be in a grid-like or linear pattern, thereby forming grid-like or linear trenches 150 in the sacrificial layer stack 140 . After the anisotropic etching process is performed, a plurality of sacrificial layer structures 146 are formed on the seed layer 130. Trenches 150 are formed between the sacrificial layer structures 146. The side surfaces of the first sacrificial layer 142 and the second sacrificial layer 144 of the sacrificial layer structures 146 are exposed through the trenches 150.
參照第7圖,在步驟S16中,執行等向性蝕刻製程。應用於等向性蝕刻製程中的蝕刻劑對於第一犧牲層142與第二犧牲層144之間是具有蝕刻選擇比的。舉例而言,在一些實施例中,等向性蝕刻製程中選用的蝕刻劑可以是熱磷酸,其對氮化矽的蝕刻速率遠大於對二氧化矽的蝕刻速率,故在執行等向性蝕刻製程之後,第二犧牲層144會相對於第一犧牲層142凹陷,而在第一犧牲層142與第二犧牲層144之間形成空腔152。 Referring to FIG. 7 , in step S16 , an isotropic etching process is performed. The etchant used in the isotropic etching process has an etching selectivity between the first sacrificial layer 142 and the second sacrificial layer 144 . For example, in some embodiments, the etchant used in the isotropic etching process may be hot phosphoric acid, which has a much higher etching rate for silicon nitride than for silicon dioxide. Therefore, after the isotropic etching process, the second sacrificial layer 144 is recessed relative to the first sacrificial layer 142 , forming a cavity 152 between the first and second sacrificial layers 142 , 144 .
在其他的一些實施例中,等向性蝕刻製程中選用的蝕刻劑可以是緩衝氧化物蝕刻劑(buffered oxide etchant,BOE),其對二氧化矽的蝕刻速率遠大於對氮化矽的蝕刻速率,故在執行等向性蝕刻製程之後,第一犧牲層142會相對於第二犧牲層144凹陷。 In some other embodiments, the etchant used in the isotropic etching process may be a buffered oxide etchant (BOE), which has a much higher etching rate for silicon dioxide than for silicon nitride. Therefore, after the isotropic etching process, the first sacrificial layer 142 is recessed relative to the second sacrificial layer 144.
較佳地,犧牲層結構146中最頂層的層為相對於其下方的層凹陷。舉例而言,若是犧牲層結構146中最頂層的層為第一犧牲層142(即二氧化矽層),則等向性蝕刻製程中選用的蝕刻劑為緩衝氧化物蝕刻劑。是犧牲層結構 146中最頂層的層為第二犧牲層144(即氮化矽),則等向性蝕刻製程中選用的蝕刻劑為熱磷酸。 Preferably, the topmost layer in the sacrificial structure 146 is recessed relative to the underlying layers. For example, if the topmost layer in the sacrificial structure 146 is the first sacrificial layer 142 (i.e., silicon dioxide), the etchant used in the isotropic etching process is a buffer oxide etchant. If the topmost layer in the sacrificial structure 146 is the second sacrificial layer 144 (i.e., silicon nitride), the etchant used in the isotropic etching process is hot phosphoric acid.
在執行等向性蝕刻製程之後,第一犧牲層142以及第二犧牲層144的側表面可以是平面、凸面或是凹面,視等向性蝕刻製程的條件而定。 After performing the isotropic etching process, the side surfaces of the first sacrificial layer 142 and the second sacrificial layer 144 can be flat, convex, or concave, depending on the conditions of the isotropic etching process.
參照第8圖,在步驟S18中,提供導熱材料160以填充於在犧牲層結構146之間的溝槽150(如第7圖所示)以及填充於在第一犧牲層142與第二犧牲層144之間的空腔152(如第7圖所示)。導熱材料160覆蓋犧牲層結構146的上表面。 Referring to FIG. 8 , in step S18 , a thermally conductive material 160 is provided to fill the trenches 150 (shown in FIG. 7 ) between the sacrificial layer structures 146 and the cavity 152 (shown in FIG. 7 ) between the first sacrificial layer 142 and the second sacrificial layer 144 . The thermally conductive material 160 covers the upper surface of the sacrificial layer structures 146 .
在一些實施例中,導熱材料160的材料為金屬。舉例而言,導熱材料160的材料可以包含銀、銅、金、鋁或是鎢。導熱材料160可以透過電鍍製程形成在種子層130上。 In some embodiments, the thermally conductive material 160 is made of metal. For example, the thermally conductive material 160 may include silver, copper, gold, aluminum, or tungsten. The thermally conductive material 160 may be formed on the seed layer 130 through an electroplating process.
參照第9圖,在步驟S20中,執行平坦化製程,如化學機械研磨製程,以移除一部分的導熱材料160。在執行完平坦化製程之後,犧牲層結構146的上表面會由導熱材料160暴露。 Referring to FIG. 9 , in step S20 , a planarization process, such as a chemical mechanical polishing process, is performed to remove a portion of the thermally conductive material 160 . After the planarization process is completed, the upper surface of the sacrificial layer structure 146 is exposed by the thermally conductive material 160 .
參照第10圖,在步驟S22中,執行移除製程,以移除犧牲層結構146(如第9圖所示),保留下來的導熱材料160(如第9圖所示)便成為散熱元件200的凸出部210。散熱元件200之凸出部210的底部為透過種子層130連接在一起。執行移除製程的步驟包含使用第一道等向性蝕刻製程移除第一犧牲層142,以及使用第二道等向 性蝕刻製程來移除第二犧牲層144。 Referring to FIG. 10 , in step S22 , a removal process is performed to remove the sacrificial layer structure 146 (shown in FIG. 9 ). The remaining thermally conductive material 160 (shown in FIG. 9 ) becomes the protrusion 210 of the heat sink 200 . The bottoms of the protrusions 210 of the heat sink 200 are connected together through the seed layer 130 . The removal process includes removing the first sacrificial layer 142 using a first isotropic etch process and removing the second sacrificial layer 144 using a second isotropic etch process.
每一個凸出部210包含有交替設置的第一段212與第二段214,其中第一段212的尺寸不同第二段214的尺寸。更具體地說,第一段212與第二段214為由經過等向性蝕刻的第一犧牲層142以及第二犧牲層144(如第7圖所示)的輪廓所定義。 Each protrusion 210 includes alternating first segments 212 and second segments 214, wherein the dimensions of the first segments 212 are different from the dimensions of the second segments 214. More specifically, the first segments 212 and the second segments 214 are defined by the contours of the isotropically etched first and second sacrificial layers 142 and 144 (as shown in FIG. 7 ).
在其他的一些實施例中,散熱元件200可以由不是金屬的導熱材料所製作而成,因此,內墊氧化矽層以及種子層便可以被省略。 In some other embodiments, the heat sink 200 can be made of a non-metallic thermally conductive material, and thus the inner pad silicon oxide layer and the seed layer can be omitted.
參照第11圖至第15圖,其分別為本揭露之半導體結構的製作方法的一些實施例於不同階段的剖面圖。如第11圖所示,半導體結構的製作方法始於步驟S30,其中犧牲層堆疊140為直接形成在半導體基板110上。犧牲層堆疊140包含有第一犧牲層142以及第二犧牲層144,第一犧牲層142以及第二犧牲層144為交替且重複的堆疊設置。第一犧牲層142的材料不同於第二犧牲層144的材料,以在第一犧牲層142與第二犧牲層144之間提供足夠的蝕刻選擇比。舉例而言,第一犧牲層142的材料可以為氧化物,如二氧化矽,第二犧牲層144的材料可以為氮化物,如氮化矽。 Referring to Figures 11 to 15 , they are cross-sectional views of various stages of some embodiments of the semiconductor structure fabrication method disclosed herein. As shown in Figure 11 , the semiconductor structure fabrication method begins with step S30, wherein a sacrificial layer stack 140 is formed directly on a semiconductor substrate 110. The sacrificial layer stack 140 includes a first sacrificial layer 142 and a second sacrificial layer 144, with the first sacrificial layer 142 and the second sacrificial layer 144 being stacked in an alternating and repeated arrangement. The material of the first sacrificial layer 142 is different from the material of the second sacrificial layer 144 to provide a sufficient etching selectivity between the first sacrificial layer 142 and the second sacrificial layer 144. For example, the material of the first sacrificial layer 142 can be an oxide, such as silicon dioxide, and the material of the second sacrificial layer 144 can be a nitride, such as silicon nitride.
參照第12圖,在步驟S32中,執行非等向性蝕刻製程以圖案化犧牲層堆疊140。以在執行完非等向性蝕刻製程之後,將溝槽150形成在犧牲層結構146之間。在一些實施例中,非等向性蝕刻製程停止於半導體基板110, 故在執行完非等向性蝕刻製程之後,會有多個凹陷部154形成在半導體基板110的上表面上。 Referring to FIG. 12 , in step S32 , an anisotropic etching process is performed to pattern the sacrificial layer stack 140 . After the anisotropic etching process is completed, trenches 150 are formed between the sacrificial layer structures 146 . In some embodiments, the anisotropic etching process stops at the semiconductor substrate 110 . Therefore, after the anisotropic etching process is completed, a plurality of recesses 154 are formed on the top surface of the semiconductor substrate 110 .
參照第13圖,在步驟S34中,執行等向性蝕刻製程。應用於等向性蝕刻製程中的蝕刻劑對於第一犧牲層142與第二犧牲層144之間是具有蝕刻選擇比的。舉例而言,在一些實施例中,等向性蝕刻製程中選用的蝕刻劑可以是熱磷酸,其對氮化矽的蝕刻速率遠大於對二氧化矽的蝕刻速率,故在執行等向性蝕刻製程之後,第二犧牲層144會相對於第一犧牲層142凹陷,而在第一犧牲層142與第二犧牲層144之間形成空腔152。 Referring to FIG. 13 , in step S34 , an isotropic etching process is performed. The etchant used in the isotropic etching process has an etching selectivity between the first sacrificial layer 142 and the second sacrificial layer 144 . For example, in some embodiments, the etchant used in the isotropic etching process may be hot phosphoric acid, which has a much higher etching rate for silicon nitride than for silicon dioxide. Therefore, after the isotropic etching process, the second sacrificial layer 144 is recessed relative to the first sacrificial layer 142 , forming a cavity 152 between the first and second sacrificial layers 142 , 144 .
在其他的一些實施例中,等向性蝕刻製程中選用的蝕刻劑可以是緩衝氧化物蝕刻劑,其對二氧化矽的蝕刻速率遠大於對氮化矽的蝕刻速率,故在執行等向性蝕刻製程之後,第一犧牲層142會相對於第二犧牲層144凹陷。 In some other embodiments, the etchant used in the isotropic etching process may be a buffered oxide etchant, which has a much higher etching rate for silicon dioxide than for silicon nitride. Therefore, after the isotropic etching process, the first sacrificial layer 142 is recessed relative to the second sacrificial layer 144.
參照第14圖,在步驟S36中,提供導熱材料160以填充於在犧牲層結構146之間的溝槽150(如第13圖所示)以及填充於在第一犧牲層142與第二犧牲層144之間的空腔152(如第13圖所示)。導熱材料160進一步填充於半導體基板110之上表面上的凹陷部154(如第13圖所示)。 Referring to FIG. 14 , in step S36 , a thermally conductive material 160 is provided to fill the trenches 150 between the sacrificial layer structures 146 (as shown in FIG. 13 ) and the cavities 152 between the first sacrificial layer 142 and the second sacrificial layer 144 (as shown in FIG. 13 ). The thermally conductive material 160 further fills the recess 154 on the top surface of the semiconductor substrate 110 (as shown in FIG. 13 ).
在一些實施例中,導熱材料160的材料可以為石墨片。在一些實施例中,導熱材料160的材料可以為相變化材料。在一些實施例中,導熱材料160的材料可以為金屬膏。在一些實施例中,導熱材料160的材料可以為散熱 墊或是散熱膏。在一些實施例中,導熱材料160的材料可以為氮化鋁。導熱材料160可以透過沉積、填充或是任何適合的製程形成。 In some embodiments, thermally conductive material 160 may be made of a graphite sheet. In some embodiments, thermally conductive material 160 may be made of a phase change material. In some embodiments, thermally conductive material 160 may be made of a metal paste. In some embodiments, thermally conductive material 160 may be made of a heat sink or thermal paste. In some embodiments, thermally conductive material 160 may be made of aluminum nitride. Thermally conductive material 160 may be formed by deposition, filling, or any other suitable process.
參照第15圖,在步驟S38中,執行平坦化製程以移除一部分的導熱材料160,使得犧牲層結構146(如第14圖所示)的上表面由導熱材料160暴露,接著執行移除製程,以移除犧牲層結構146。具有凸出部210的散熱元件200為直接形成在半導體基板110上。每一個凸出部210包含有交替設置的第一段212與第二段214,其中第一段212的尺寸不同第二段214的尺寸。凸出部210的底部為彼此分隔開來的,且凸出部210的底部嵌入半導體基板110。這些嵌入半導體基板110的凸出部210的底部可以在半導體基板110與凸出部210之間提供更多的接觸面積,進而增加半導體基板110與凸出部210之間的熱交換面積。 Referring to FIG. 15 , in step S38 , a planarization process is performed to remove a portion of the thermally conductive material 160 , exposing the upper surface of the sacrificial layer structure 146 (shown in FIG. 14 ) from the thermally conductive material 160 . A removal process is then performed to remove the sacrificial layer structure 146 . The heat sink 200 having protrusions 210 is formed directly on the semiconductor substrate 110 . Each protrusion 210 includes alternating first segments 212 and second segments 214 , wherein the dimensions of the first segments 212 are different from those of the second segments 214 . The bottoms of the protrusions 210 are separated from each other and embedded in the semiconductor substrate 110 . The bottoms of these protrusions 210 embedded in the semiconductor substrate 110 can provide more contact area between the semiconductor substrate 110 and the protrusions 210, thereby increasing the heat exchange area between the semiconductor substrate 110 and the protrusions 210.
在又其他的一些實施例中,透過改變犧牲層堆疊140的組成,散熱元件200之凸出部210的側表面可以變得更加不規則化。 In some other embodiments, by changing the composition of the sacrificial layer stack 140, the side surface of the protrusion 210 of the heat sink 200 can become more irregular.
參照第16圖至第18圖,其分別為本揭露之半導體結構的製作方法的一些實施例於不同階段的剖面圖。如第16圖所示,半導體結構的製作方法始於步驟S40,其中犧牲層堆疊140為直接形成在半導體基板110上或是在種子層130(若有的話)上。犧牲層堆疊140包含有多個第一犧牲層142、多個第二犧牲層144,以及多個第三犧牲 層148,儘管圖中僅繪示出一個第二犧牲層144與一個第三犧牲層148。第一犧牲層142、第二犧牲層144、第三犧牲層148分別由不同的材料所製作而成。舉例而言,第一犧牲層142、第二犧牲層144、第三犧牲層148的材料可以是SiO2、SiN、SiON、SiCN,或是其他足以提供合適的蝕刻選擇比的材料。 Referring to Figures 16 to 18 , which are cross-sectional views of various stages of a method for fabricating a semiconductor structure according to the present disclosure, as shown in Figure 16 , the method for fabricating a semiconductor structure begins with step S40 , wherein a sacrificial layer stack 140 is formed directly on the semiconductor substrate 110 or on the seed layer 130 (if any). The sacrificial layer stack 140 includes a plurality of first sacrificial layers 142 , a plurality of second sacrificial layers 144 , and a plurality of third sacrificial layers 148 , although only one second sacrificial layer 144 and one third sacrificial layer 148 are shown in the figure. The first sacrificial layer 142, the second sacrificial layer 144, and the third sacrificial layer 148 are made of different materials. For example, the first sacrificial layer 142, the second sacrificial layer 144, and the third sacrificial layer 148 can be made of SiO2 , SiN, SiON, SiCN, or other materials that can provide a suitable etching selectivity.
在一些實施例中,第一犧牲層142、第二犧牲層144、第三犧牲層148的數量以及順序可以根據需求變更,且第一犧牲層142、第二犧牲層144、第三犧牲層148的厚度也可以是具有差異的。因此,犧牲層堆疊140的變化方式可以被進一步增加。 In some embodiments, the number and order of the first sacrificial layer 142, the second sacrificial layer 144, and the third sacrificial layer 148 can be varied as needed, and the thicknesses of the first sacrificial layer 142, the second sacrificial layer 144, and the third sacrificial layer 148 can also vary. Thus, the variety of sacrificial layer stacks 140 can be further increased.
參照第17圖,在步驟S42中,經由一連串的非等向性蝕刻製程以及等向性蝕刻製程來將犧牲層堆疊140圖案化。由於犧牲層堆疊140中的第一犧牲層142、第二犧牲層144、第三犧牲層148的材料之間的蝕刻選擇比,犧牲層結構146的形狀可以更為不規則,而在犧牲層結構146的第一犧牲層142、第二犧牲層144、第三犧牲層148之間的空間也變得更不均勻。 Referring to FIG. 17 , in step S42 , the sacrificial layer stack 140 is patterned through a series of anisotropic and isotropic etching processes. Due to the etching selectivity between the materials of the first, second, and third sacrificial layers 142, 144, and 148 in the sacrificial layer stack 140, the shape of the sacrificial layer structure 146 can be more irregular, and the spacing between the first, second, and third sacrificial layers 142, 144, and 148 in the sacrificial layer structure 146 also becomes more non-uniform.
參照第18圖,在步驟S44中,由犧牲層結構146所定義出來的多個凸出部210為形成在半導體基板110上或是種子層130(若有的話)上。凸出部210包含有多個第一段212、多個第二段214,以及多個第三段216,儘管圖中僅繪示出一個第二段214與一個第三段216。第一段212、第二段214、第三段216的厚度及/或尺寸可以是 不同的。每個散熱元件200的凸出部210具有增加的側表面積,進而提升散熱元件200的散熱效率。 Referring to FIG. 18 , in step S44 , a plurality of protrusions 210 defined by the sacrificial layer structure 146 are formed on the semiconductor substrate 110 or the seed layer 130 (if any). The protrusions 210 include a plurality of first segments 212 , a plurality of second segments 214 , and a plurality of third segments 216 , although only one second segment 214 and one third segment 216 are shown. The thickness and/or dimensions of the first, second, and third segments 212 , 214 , 216 may vary. Each protrusion 210 of the heat sink 200 has an increased lateral surface area, thereby enhancing the heat dissipation efficiency of the heat sink 200 .
參照第19A圖至第19E圖,其分別為根據本揭露的半導體結構中的散熱元件的凸出部之不同實施例的上視示意圖。在一些實施例中,散熱元件200之凸出部210的上視剖面形狀不限定於矩形或是正方形。在一些實施例中,散熱元件200之凸出部210可以不對齊或是不對稱於散熱元件200的X軸方向或是Y軸方向。舉例而言,散熱元件200之凸出部210的上視剖面形狀可以是圓形(如第19A圖所示)、三角形(如第19B圖所示)、多邊形(如第19C圖所示)、平行四邊形(如第19D圖所示)、或是菱形(如第19E圖所示)。 Referring to Figures 19A to 19E , they are top views of various embodiments of the protrusion of the heat sink in the semiconductor structure according to the present disclosure. In some embodiments, the top cross-sectional shape of the protrusion 210 of the heat sink 200 is not limited to a rectangle or a square. In some embodiments, the protrusion 210 of the heat sink 200 may be misaligned or asymmetric with respect to the X-axis or Y-axis of the heat sink 200. For example, the top cross-sectional shape of the protrusion 210 of the heat sink 200 may be circular (as shown in Figure 19A ), triangular (as shown in Figure 19B ), polygonal (as shown in Figure 19C ), parallelogram (as shown in Figure 19D ), or rhombus (as shown in Figure 19E ).
參照第20A圖與第20B圖,其分別為根據本揭露的半導體結構中的散熱元件的凸出部之不同實施例的上視示意圖。在一些實施例中,散熱元件200之凸出部210的形狀可以是長條形(如第20A圖所示)或是鰭狀(如第20B圖所示)。 Referring to FIG. 20A and FIG. 20B , they are top views of different embodiments of the protrusion of a heat sink in a semiconductor structure according to the present disclosure. In some embodiments, the protrusion 210 of the heat sink 200 may be in the shape of an elongated strip (as shown in FIG. 20A ) or a fin (as shown in FIG. 20B ).
參照第21圖,其為根據本揭露之半導體結構的一些實施例的剖面圖。在一些實施例中,半導體結構100更包含有多個通孔(via)220,設置在半導體基板110之中且與散熱元件200連接。每個通孔220可以連接至一或多個散熱元件200之凸出部210。每個通孔220可以包含有導體核224以及設置在導體核224與半導體基板110之間的黏著層222。通孔220為虛設的通孔其不提供電性連 接或傳輸的作用。在半導體基板110中的通孔220可以提供額外的熱交換路徑,進而加強半導體結構100的散熱效率。 Refer to FIG. 21 , which is a cross-sectional view of some embodiments of a semiconductor structure according to the present disclosure. In some embodiments, the semiconductor structure 100 further includes a plurality of vias 220 disposed in the semiconductor substrate 110 and connected to the heat sink 200. Each via 220 can be connected to one or more protrusions 210 of the heat sink 200. Each via 220 can include a conductive core 224 and an adhesive layer 222 disposed between the conductive core 224 and the semiconductor substrate 110. The vias 220 are virtual vias that do not provide electrical connection or conduction. The vias 220 in the semiconductor substrate 110 can provide additional heat exchange paths, thereby enhancing the heat dissipation efficiency of the semiconductor structure 100.
參照第22圖與第23圖,其分別為根據本揭露之半導體結構的不同實施例的剖面圖。半導體結構100包含有第一半導體基板110a以及第二半導體基板110b,其中第一半導體基板110a的正面FS與第二半導體基板110b的正面FS接合。在一些實施例中,第一半導體基板110a可以是CMOS晶圓,其包含有多個CMOS元件,而第二半導體基板110b可以是陣列晶圓,其包含有階梯狀的連線結構。因此,半導體結構100又可以被稱為是CMOS接合陣列(CMOS bonding array,CbA)結構。 Referring to Figures 22 and 23 , which are cross-sectional views of different embodiments of semiconductor structures according to the present disclosure, the semiconductor structure 100 includes a first semiconductor substrate 110a and a second semiconductor substrate 110b , wherein the front surface FS of the first semiconductor substrate 110a is bonded to the front surface FS of the second semiconductor substrate 110b . In some embodiments, the first semiconductor substrate 110a may be a CMOS wafer containing multiple CMOS devices, while the second semiconductor substrate 110b may be an array wafer containing a staircase interconnect structure. Therefore, the semiconductor structure 100 may also be referred to as a CMOS bonding array (CbA) structure.
如第22圖所示,在一些實施例中,散熱元件200可以設置在第一半導體基板110a(即CMOS晶圓)的背面BS,而半導體結構100的連接墊230可以設置在第二半導體基板110b(即陣列晶圓)的背面BS。 As shown in FIG. 22 , in some embodiments, the heat sink 200 can be disposed on the back surface BS of the first semiconductor substrate 110 a (i.e., the CMOS wafer), while the connection pads 230 of the semiconductor structure 100 can be disposed on the back surface BS of the second semiconductor substrate 110 b (i.e., the array wafer).
如第23圖所示,在一些實施例中,散熱元件200可以設置在第二半導體基板110b(即陣列晶圓)的背面BS,而半導體結構100的連接墊230可以設置在第一半導體基板110a(即CMOS晶圓)的背面BS。 As shown in FIG. 23 , in some embodiments, the heat sink 200 can be disposed on the back surface BS of the second semiconductor substrate 110 b (i.e., the array wafer), while the connection pads 230 of the semiconductor structure 100 can be disposed on the back surface BS of the first semiconductor substrate 110 a (i.e., the CMOS wafer).
參照第24圖,其為根據本揭露的半導體結構之一些實施例的上視示意圖。在一些實施例中,半導體結構100可以是晶圓對晶片的結構,其包含有晶圓110c以及接合於晶圓110c的多個晶片110d,如前所述的散熱元件(圖 中未繪示)可以設置在晶圓110c或是晶片110d的半導體基板上。 Referring to FIG. 24 , which is a schematic top view of some embodiments of a semiconductor structure according to the present disclosure, in some embodiments, semiconductor structure 100 may be a wafer-to-die structure, comprising a wafer 110c and a plurality of dies 110d bonded to wafer 110c. The aforementioned heat sink (not shown) may be disposed on the semiconductor substrate of wafer 110c or dies 110d.
參照第25圖,其為根據本揭露的半導體結構之一些實施例的上視示意圖。在一些實施例中,半導體結構100可以是晶片對晶片的結構,其包含有第一晶片110e以及接合於第一晶片110e的第二晶片110f,如前所述的散熱元件(圖中未繪示)可以設置在第一晶片110e或是第二晶片110f的半導體基板上。 Referring to FIG. 25 , which is a schematic top view of some embodiments of a semiconductor structure according to the present disclosure, in some embodiments, the semiconductor structure 100 may be a chip-on-chip structure, comprising a first chip 110e and a second chip 110f bonded to the first chip 110e. The aforementioned heat sink (not shown) may be disposed on the semiconductor substrate of either the first chip 110e or the second chip 110f.
本揭露提供了一種半導體結構與其製作方法。半導體結構具有半導體基板以及設置在半導體基板上的散熱元件,其中散熱元件是由半導體製程所製作且具有多個凸出部。每個凸出部具有皺褶的側表面,藉以增加凸出部的表面積,進而提升散熱元件的散熱效率。 This disclosure provides a semiconductor structure and a method for manufacturing the same. The semiconductor structure comprises a semiconductor substrate and a heat sink disposed on the semiconductor substrate. The heat sink is fabricated using a semiconductor process and has a plurality of protrusions. Each protrusion has a corrugated side surface, thereby increasing the surface area of the protrusion and thereby improving the heat dissipation efficiency of the heat sink.
雖然本揭露已以實施例揭露如上,然其並非用以限定本揭露,任何熟習此技藝者,在不脫離本揭露之精神和範圍內,當可作各種之更動與潤飾,因此本揭露之保護範圍當視後附之申請專利範圍所界定者為準。 Although the present disclosure has been disclosed above through embodiments, they are not intended to limit the present disclosure. Anyone skilled in the art may make various modifications and improvements without departing from the spirit and scope of the present disclosure. Therefore, the scope of protection of the present disclosure shall be determined by the scope of the attached patent application.
100:半導體結構 110:半導體基板 120:內墊氧化矽層 130:種子層 200:散熱元件 210:凸出部 212:第一段 214:第二段 100: Semiconductor structure 110: Semiconductor substrate 120: Inter-pad silicon oxide layer 130: Seed layer 200: Heat sink 210: Protrusion 212: First section 214: Second section
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030205817A1 (en) * | 1999-07-31 | 2003-11-06 | Romankiw Lubomyr Taras | Process for making low dielectric constant hollow chip structures by removing sacrificial dielectric material after the chip is joined to a carrier |
| US7719816B2 (en) * | 2007-05-22 | 2010-05-18 | Centipede Systems, Inc. | Compliant thermal contactor |
| TW201417642A (en) * | 2012-10-26 | 2014-05-01 | 臻鼎科技股份有限公司 | Connecting substrate and laminated package structure |
| TW201605005A (en) * | 2014-04-23 | 2016-02-01 | 歐普提茲股份有限公司 | Chip level heat dissipation using silicon |
| TW202118020A (en) * | 2019-10-17 | 2021-05-01 | 大陸商長江存儲科技有限責任公司 | Semiconductor element array applying deep trench isolation structure at back side |
| TWI744830B (en) * | 2019-07-31 | 2021-11-01 | 台灣積體電路製造股份有限公司 | Stacking structure |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20030205817A1 (en) * | 1999-07-31 | 2003-11-06 | Romankiw Lubomyr Taras | Process for making low dielectric constant hollow chip structures by removing sacrificial dielectric material after the chip is joined to a carrier |
| US7719816B2 (en) * | 2007-05-22 | 2010-05-18 | Centipede Systems, Inc. | Compliant thermal contactor |
| TW201417642A (en) * | 2012-10-26 | 2014-05-01 | 臻鼎科技股份有限公司 | Connecting substrate and laminated package structure |
| TW201605005A (en) * | 2014-04-23 | 2016-02-01 | 歐普提茲股份有限公司 | Chip level heat dissipation using silicon |
| TWI744830B (en) * | 2019-07-31 | 2021-11-01 | 台灣積體電路製造股份有限公司 | Stacking structure |
| TW202118020A (en) * | 2019-10-17 | 2021-05-01 | 大陸商長江存儲科技有限責任公司 | Semiconductor element array applying deep trench isolation structure at back side |
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