TWI855411B - Method and system for measuring the depth of a damaged layer on a wafer surface - Google Patents
Method and system for measuring the depth of a damaged layer on a wafer surface Download PDFInfo
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- G01B21/00—Measuring arrangements or details thereof, where the measuring technique is not covered by the other groups of this subclass, unspecified or not relevant
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- G—PHYSICS
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- G01N1/00—Sampling; Preparing specimens for investigation
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Abstract
本發明屬於測量晶圓表面損傷層深度的方法和系統,該方法包括:步驟101:對待測晶圓反復進行多次將晶圓浸入腐蝕液中規定時間並從腐蝕液中拉起的提拉蝕刻操作,使得通過由腐蝕液蝕刻而在晶圓的表面上形成具有一系列臺階面的臺階形狀;步驟102:對該一系列臺階面依次進行損傷檢測,直至未檢測到損傷為止;步驟103:根據未檢測到損傷時已進行的提拉蝕刻操作的次數和晶圓在每次浸入腐蝕液中時被蝕刻剝離的厚度確定晶圓的表面損傷層的深度,其中,該厚度根據腐蝕液的腐蝕速率和規定時間計算獲得。The present invention relates to a method and system for measuring the depth of a damaged layer on a wafer surface. The method comprises: step 101: repeatedly performing a pull-up etching operation on a wafer to be tested, wherein the wafer is immersed in an etching solution for a predetermined time and then pulled out of the etching solution, so that a step shape having a series of step surfaces is formed on the surface of the wafer by etching with the etching solution; step 102: The series of terraces are sequentially inspected for damage until no damage is detected; step 103: determining the depth of the surface damage layer of the wafer according to the number of pull-up etching operations performed when no damage is detected and the thickness of the wafer etched away each time the wafer is immersed in the etching solution, wherein the thickness is calculated based on the etching rate of the etching solution and the specified time.
Description
本發明屬於晶圓加工製造技術領域,具體地,關於測量晶圓表面損傷層深度的方法及系統。The present invention belongs to the field of wafer processing and manufacturing technology, and specifically, relates to a method and system for measuring the depth of a damaged layer on a wafer surface.
在從拉制的單晶矽棒到晶圓的製造過程中,需要經過滾磨、切片、研磨、蝕刻、拋光等多道工序。在例如滾磨、切片、研磨的機械加工過程中,會不可避免地在晶圓表面引入機械損傷。表面機械損傷破壞了原有的單晶層,嚴重影響了矽片的品質。因此,需要在後續加工過程中通過例如蝕刻、拋光等流程去除掉損傷層。在去除晶圓表面的機械損傷層時,需要能夠準確測量出該損傷層的深度,以據此設定去除操作中相關的具體去除量。In the manufacturing process from pulled single crystal silicon rods to wafers, multiple processes such as rolling, slicing, grinding, etching, and polishing are required. In the mechanical processing processes such as rolling, slicing, and grinding, mechanical damage will inevitably be introduced on the surface of the wafer. The surface mechanical damage destroys the original single crystal layer and seriously affects the quality of the silicon wafer. Therefore, it is necessary to remove the damaged layer through processes such as etching and polishing in the subsequent processing. When removing the mechanically damaged layer on the surface of the wafer, it is necessary to be able to accurately measure the depth of the damaged layer in order to set the specific removal amount related to the removal operation accordingly.
相關技術中,損傷層深度測量技術分為直接測量和間接測量。直接測量指直接觀測晶片斷面上的損傷,但因損傷較淺,不易直接用顯微鏡觀察,通常是將晶片截斷後採用掃描式電子顯微鏡(Scanning Electron Microscope,SEM)/透射式電子顯微鏡(Transmission Electron Microscope,TEM)等高精度設備觀察斷面,但該方法的設備成本高昂且制樣複雜。Among the related technologies, damage layer depth measurement technology is divided into direct measurement and indirect measurement. Direct measurement refers to directly observing the damage on the chip cross section, but because the damage is shallow, it is not easy to observe directly with a microscope. Usually, the chip is cut and then a scanning electron microscope (SEM)/transmission electron microscope (TEM) and other high-precision equipment are used to observe the cross section, but the equipment cost of this method is high and the sample preparation is complicated.
角度拋光法是實驗室內常採用的間接測量方法。在該方法中,通過將垂直的損傷層磨拋出一個光滑的斜面實現了損傷層的放大,以匹配顯微鏡的測量精度。磨拋的斜面會再經過蝕刻而將損傷進一步放大並使用顯微鏡測量,之後再經幾何換算為實際損傷深度。Angle polishing is an indirect measurement method commonly used in laboratories. In this method, the vertical damage layer is polished into a smooth bevel to magnify the damage layer to match the measurement accuracy of the microscope. The polished bevel will be etched to further magnify the damage and measured with a microscope, and then converted to the actual damage depth through geometry.
但是,角度拋光法對樣品的處理與測量要求較高。首先,該方法需要將晶圓裂解後獲得小片方可進行處理,且小片磨拋後的蝕刻需要設計單獨的夾具與槽體;再者,樣品的處理需要將小片黏接至已知角度的斜面,再將斜面黏接在磨拋盤上,兩次黏接導致穩定性較差;而且,樣片進行角度拋光時要避免引入新的損傷,斜面最好磨出光滑的表面,斜面的光滑效果直接影響顯微鏡分辨;最後,斜面測量時損傷層與無損傷層的介面是通過肉眼判定的,這使測量結果受人員影響較大。However, the angle polishing method has high requirements for sample processing and measurement. First, the method requires the wafer to be split and small pieces to be obtained before processing, and the etching of the small pieces after polishing requires the design of separate fixtures and troughs; secondly, the sample processing requires the small piece to be glued to a bevel with a known angle, and then the bevel is glued to the polishing plate. The two glues lead to poor stability; moreover, when the sample is angle polished, it is necessary to avoid introducing new damage. It is best to grind the bevel to a smooth surface. The smoothness of the bevel directly affects the resolution of the microscope; finally, when measuring the bevel, the interface between the damaged layer and the undamaged layer is judged by the naked eye, which makes the measurement result greatly affected by personnel.
本部分提供了本發明的總體概要,而不是對本發明的全部範圍或所有特徵的全面公開。This section provides a general summary of the invention, and is not a comprehensive disclosure of its full scope or all of its features.
本發明的一個目的在於提供一種能夠使用完整晶圓來進行的測量晶圓表面損傷層深度的方法。An object of the present invention is to provide a method for measuring the depth of a damaged layer on a wafer surface using a complete wafer.
本發明的另一目的在於提供一種能夠直接測量晶圓表面損傷深度而無需通過幾何關係進行逆推的測量晶圓表面損傷層深度的方法。Another object of the present invention is to provide a method for measuring the depth of the damage layer on the wafer surface, which can directly measure the depth of the damage layer on the wafer surface without reverse deduction through geometric relationships.
本發明的又一目的在於提供一種能夠避免肉眼觀察引入的判斷誤差的測量晶圓表面損傷層深度的方法。Another object of the present invention is to provide a method for measuring the depth of a damaged layer on a wafer surface which can avoid judgment errors introduced by naked eye observation.
為了實現上述目的中的一個或多個,根據本發明的一方面,提供了一種測量晶圓表面損傷層深度的方法,其包括: 步驟101:對待測晶圓反復進行多次將晶圓浸入腐蝕液中規定時間並從腐蝕液中拉起的提拉蝕刻操作,使得通過由腐蝕液蝕刻而在晶圓的表面上形成具有一系列臺階面的臺階形狀; 步驟102:對該一系列臺階面依次進行損傷檢測,直至未檢測到損傷為止; 步驟103:根據未檢測到損傷時已進行的提拉蝕刻操作的次數和晶圓在每次浸入腐蝕液中時被蝕刻剝離的厚度確定晶圓的表面損傷層的深度,其中,該厚度根據腐蝕液的腐蝕速率和規定時間計算獲得。 In order to achieve one or more of the above purposes, according to one aspect of the present invention, a method for measuring the depth of a damaged layer on a wafer surface is provided, which comprises: Step 101: repeatedly performing a pull-up etching operation on a wafer to be tested, wherein the wafer is immersed in an etching solution for a specified time and pulled out of the etching solution for multiple times, so that a step shape having a series of terraces is formed on the surface of the wafer by etching with the etching solution; Step 102: sequentially performing damage detection on the series of terraces until no damage is detected; Step 103: Determine the depth of the surface damage layer of the wafer based on the number of pull-up etching operations that have been performed when no damage is detected and the thickness of the wafer etched away each time it is immersed in the etching solution, wherein the thickness is calculated based on the etching rate of the etching solution and the specified time.
在上述測量晶圓表面損傷層深度的方法中,在步驟102中,如果該一系列臺階面中的最後一個臺階面仍被檢測出存在損傷,則可以重複步驟101和步驟102。In the above method for measuring the depth of the damage layer on the wafer surface, in step 102, if the last step in the series of steps is still detected to have damage, steps 101 and 102 may be repeated.
在上述測量晶圓表面損傷層深度的方法中,晶圓每次浸入腐蝕液中的規定時間可以是相等的。In the above method for measuring the depth of the damaged layer on the wafer surface, the prescribed time for each immersion of the wafer in the etching solution may be equal.
在上述測量晶圓表面損傷層深度的方法中,對該一系列臺階面依次進行損傷檢測可以包括對該一系列臺階面依次進行粗糙度檢測,並且未檢測到損傷通過檢測到粗糙度趨於不變來確定。In the above method for measuring the depth of the damage layer on the wafer surface, sequentially performing damage detection on the series of terraces may include sequentially performing roughness detection on the series of terraces, and no damage is detected, which is determined by detecting that the roughness tends to be constant.
在上述測量晶圓表面損傷層深度的方法中,對該一系列臺階面依次進行損傷檢測可以包括對該一系列臺階面依次進行X光繞射檢測,並且未檢測到損傷通過檢測到繞射鋒的半高寬趨於不變來確定。In the above method for measuring the depth of the damage layer on the wafer surface, sequentially performing damage detection on the series of steps may include sequentially performing X-ray diffraction detection on the series of steps, and no damage is detected by detecting that the half-height width of the diffraction front tends to be constant.
在上述測量晶圓表面損傷層深度的方法中,腐蝕液可以為由硝酸、氫氟酸、乙酸、蒸餾水按4:1:2:3的體積比混合而成的布萊特(Bright)腐蝕液。In the above method for measuring the depth of the damaged layer on the wafer surface, the etching solution may be a Bright etching solution prepared by mixing nitric acid, hydrofluoric acid, acetic acid, and distilled water in a volume ratio of 4:1:2:3.
在上述測量晶圓表面損傷層深度的方法中,規定時間可以設定為5s至10s。In the above method for measuring the depth of the damaged layer on the wafer surface, the specified time can be set to 5s to 10s.
在上述測量晶圓表面損傷層深度的方法中,腐蝕速率可以通過以下步驟確定: 步驟1:測量測試晶圓的初始厚度; 步驟2:將測試晶圓浸入腐蝕液中蝕刻特定時間並取出; 步驟3:對經過步驟2的測試晶圓的留存厚度進行測量;以及 步驟4:基於初始厚度與留存厚度之差以及該特定時間計算獲得腐蝕速率。 In the above method for measuring the depth of the damaged layer on the wafer surface, the corrosion rate can be determined by the following steps: Step 1: measuring the initial thickness of the test wafer; Step 2: immersing the test wafer in the etching solution for a specific time and taking it out; Step 3: measuring the remaining thickness of the test wafer after step 2; and Step 4: calculating the corrosion rate based on the difference between the initial thickness and the remaining thickness and the specific time.
根據本發明的另一方面,還提供了一種測量晶圓表面損傷層深度的系統,包括: 提拉單元,其用於對待測晶圓反復進行多次將晶圓浸入腐蝕液中規定時間並從腐蝕液中拉起的提拉蝕刻操作,使得通過由腐蝕液蝕刻而在晶圓的表面上形成具有一系列臺階面的臺階形狀; 檢測單元,其用於對該一系列臺階面依次進行損傷檢測,直至未檢測到損傷為止;以及 計算獲取單元,其用於根據未檢測到損傷時已進行的提拉蝕刻操作的次數和晶圓在每次浸入腐蝕液中時被蝕刻剝離的厚度確定晶圓的表面損傷層的深度,其中,該厚度由計算獲取單元根據腐蝕液的腐蝕速率和規定時間計算獲得。 According to another aspect of the present invention, a system for measuring the depth of a damaged layer on a wafer surface is provided, comprising: A pulling unit, which is used to repeatedly perform a pulling etching operation on a wafer to be tested, immersing the wafer in an etching solution for a specified time and pulling the wafer out of the etching solution, so that a step shape having a series of step surfaces is formed on the surface of the wafer by etching with the etching solution; A detection unit, which is used to perform damage detection on the series of step surfaces in sequence until no damage is detected; and The calculation acquisition unit is used to determine the depth of the surface damage layer of the wafer according to the number of pull-up etching operations that have been performed when no damage is detected and the thickness of the wafer etched and peeled off each time the wafer is immersed in the etching solution, wherein the thickness is calculated by the calculation acquisition unit according to the etching rate of the etching solution and the specified time.
在上述測量晶圓表面損傷層深度的系統中,還可以包括重複單元,其用於在檢測單元檢測出該一系列臺階面中的最後一個臺階面仍存在損傷時使提拉單元和檢測單元重複進行操作。The system for measuring the depth of the damaged layer on the surface of the wafer may further include a repeating unit for causing the pulling unit and the detecting unit to repeat the operation when the detecting unit detects that the last step in the series of steps still has damage.
本發明實施方式中,通過直接使用整片晶圓進行損傷層深度測量的方法,可以直接應用實驗室的屬於通用檢測設備的蝕刻機和料籃,避免了將晶圓裂解成小片後進行測量時需單獨設計的特製夾具和槽體,還避免了角度拋光時因黏接而導致的穩定性較差以及可能因拋光而在斜面上引入新的損傷從而影響測量結果的問題。另外,通過本方法中的將垂直損傷橫向分解來判定損傷程度隨深度的變化,使得能夠測試損傷層本身的深度,無需通過幾何關係進行逆推。此外,本方法中通過逐層剝離得到每個深度的損傷面即臺階面並利用例如粗糙度檢測/X光繞射檢測實現對臺階面的損傷存在與否的明確判定,因此避免了肉眼觀察可能引入的人員判斷誤差。In the embodiment of the present invention, by directly using the whole wafer to measure the depth of the damaged layer, the etcher and material basket of the laboratory, which are general testing equipment, can be directly applied, avoiding the need for a specially designed fixture and trough when the wafer is split into small pieces for measurement, and also avoiding the problem of poor stability caused by bonding during angle polishing and the possible introduction of new damage on the inclined surface due to polishing, thereby affecting the measurement results. In addition, by horizontally decomposing the vertical damage in this method to determine the change of the damage degree with the depth, the depth of the damaged layer itself can be tested without the need for reverse deduction through geometric relationships. In addition, in the present method, the damaged surface, i.e., the terrace, at each depth is obtained by peeling layer by layer, and roughness detection/X-ray diffraction detection, for example, is used to clearly determine whether the terrace is damaged, thereby avoiding human judgment errors that may be introduced by naked eye observation.
通過以下結合附圖對本發明的示例性實施方式的詳細說明,本發明的上述特徵和優點以及其他特徵和優點將更加清楚。The above features and advantages as well as other features and advantages of the present invention will become more apparent through the following detailed description of exemplary embodiments of the present invention in conjunction with the accompanying drawings.
為利 貴審查委員了解本發明之技術特徵、內容與優點及其所能達到之功效,茲將本發明配合附圖及附件,並以實施例之表達形式詳細說明如下,而其中所使用之圖式,其主旨僅為示意及輔助說明書之用,未必為本發明實施後之真實比例與精準配置,故不應就所附之圖式的比例與配置關係解讀、侷限本發明於實際實施上的申請範圍,合先敘明。In order to help you understand the technical features, contents and advantages of the present invention and the effects it can achieve, the present invention is described in detail as follows with the accompanying drawings and appendices in the form of embodiments. The drawings used therein are only for illustration and auxiliary description, and may not be the true proportions and precise configurations after the implementation of the present invention. Therefore, the proportions and configurations of the attached drawings should not be interpreted to limit the scope of application of the present invention in actual implementation.
在本發明實施例的描述中,需要理解的是,術語“長度”、“寬度”、“上”、“下”、“前”、“後”、“左”、“右”、“垂直”、“水平”、“頂”、“底”“內”、“外”等指示的方位或位置關係為基於附圖所示的方位或位置關係,僅是為了便於描述本發明實施例和簡化描述,而不是指示或暗示所指的裝置或元件必須具有特定的方位、以特定的方位構造和操作,因此不能理解為對本發明的限制。In the description of the embodiments of the present invention, it should be understood that the terms "length", "width", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inside", "outside", etc., indicating the orientation or position relationship, are based on the orientation or position relationship shown in the accompanying drawings, and are only for the convenience of describing the embodiments of the present invention and simplifying the description, and do not indicate or imply that the device or component referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be understood as a limitation on the present invention.
此外,術語“第一”、“第二”僅用於描述目的,而不能理解為指示或暗示相對重要性或者隱含指明所指示的技術特徵的數量。由此,限定有“第一”、“第二”的特徵可以明示或者隱含地包括一個或者更多個所述特徵。在本發明實施例的描述中,“多個”的含義是兩個或兩個以上,除非另有明確具體的限定。In addition, the terms "first" and "second" are used for descriptive purposes only and should not be understood as indicating or implying relative importance or implicitly indicating the number of the indicated technical features. Therefore, the features defined as "first" and "second" may explicitly or implicitly include one or more of the features. In the description of the embodiments of the present invention, the meaning of "plurality" is two or more, unless otherwise clearly and specifically defined.
下面參照附圖、借助於示例性實施方式對本發明進行詳細描述。要注意的是,對本發明的以下詳細描述僅僅是出於說明目的,而絕不是對本發明的限制。The present invention is described in detail below with reference to the accompanying drawings by means of exemplary embodiments. It should be noted that the following detailed description of the present invention is only for illustrative purposes and is by no means a limitation of the present invention.
目前經常採用的測量晶圓損傷層深度的方法包括角度拋光法,該方法需要將晶圓裂解成小的樣片來進行。角度拋光法通常包括以下步驟: 將晶圓裂解成多個尺寸較小的樣片; 利用例如樹脂膠將樣片黏接至已知角度的斜面,再將斜面黏接在磨拋盤上; 將樣片截面磨拋成一已知角度的斜面,以使晶圓表面的損傷層能夠在該已知角度的斜面上暴露出來; 使用特製的夾具夾持樣片並投入腐蝕液中進行蝕刻,以使損傷層在該已知角度的斜面上進一步放大顯現;以及 The commonly used methods for measuring the depth of the wafer damage layer include angle polishing, which requires the wafer to be split into small samples. The angle polishing method generally includes the following steps: Splitting the wafer into multiple smaller samples; Using, for example, resin glue to bond the sample to a bevel of known angle, and then bonding the bevel to a polishing disk; Polishing the sample cross section into a bevel of known angle so that the damage layer on the wafer surface can be exposed on the bevel of known angle; Using a special fixture to clamp the sample and put it into the etching solution for etching, so that the damage layer on the bevel of known angle can be further magnified and displayed; and
利用顯微鏡對黏接樣片的分界線或說介面進行觀測,依據分界線處裂紋的長度以及蝕坑的數量和分佈測量出該已知角度的斜面上的損傷的長度,並通過該長度與該已知角度的正弦值計算獲得損傷層的深度。The boundary line or interface of the bonded sample is observed under a microscope. The length of the crack at the boundary line and the number and distribution of the etch pits are used to measure the length of the damage on the slope of the known angle, and the depth of the damaged layer is calculated by the sine value of the length and the known angle.
然而,通過上述步驟可以看到,該方法需要對晶圓進行裂片處理以獲得較小樣片,且在對磨拋後的小片進行蝕刻時需要設計單獨的夾具與槽體;小片要被黏接至已知角度的斜面,且斜面要再黏接在磨拋盤上,兩次黏接導致穩定性較差;樣片進行角度拋光時要避免引入新的損傷,斜面最好磨出光滑的表面,斜面的光滑效果直接影響顯微鏡分辨;而且,斜面測量時損傷層與無損傷層的介面是通過肉眼判定的,這使測量結果受人員影響較大。However, it can be seen from the above steps that this method requires wafer splitting to obtain smaller samples, and a separate fixture and trough need to be designed when etching the polished small pieces; the small pieces need to be bonded to a bevel with a known angle, and the bevel needs to be bonded to the polishing plate, and the two bondings result in poor stability; when the sample is angle-polished, new damage should be avoided, and the bevel is preferably ground to a smooth surface, and the smoothness of the bevel directly affects the resolution of the microscope; moreover, when measuring the bevel, the interface between the damaged layer and the undamaged layer is judged by the naked eye, which makes the measurement result greatly affected by personnel.
為解決上述問題,本發明通過將在與晶圓表面垂直的方向上的損傷進行橫向分解並通過隨深度變化判斷損傷程度的變化來實現對損傷層深度的測量。具體而言,參照圖1,本發明實施方式提供了一種測量晶圓表面損傷層深度的方法,該方法包括: 步驟101:對待測晶圓100反復進行多次將晶圓100浸入腐蝕液中規定時間並從腐蝕液中拉起的提拉蝕刻操作,使得通過由腐蝕液蝕刻而在晶圓100的表面上形成具有一系列臺階面的臺階形狀; 步驟102:對該一系列臺階面依次進行損傷檢測,直至未檢測到損傷為止; 步驟103:根據未檢測到損傷時已進行的提拉蝕刻操作的次數和晶圓100在每次浸入腐蝕液中時被蝕刻剝離的厚度確定晶圓100的表面損傷層的深度,其中,該厚度根據腐蝕液的腐蝕速率和該規定時間計算獲得。 To solve the above problem, the present invention measures the depth of the damaged layer by laterally decomposing the damage in the direction perpendicular to the wafer surface and judging the change of the damage degree as the depth changes. Specifically, referring to FIG. 1 , the embodiment of the present invention provides a method for measuring the depth of a damaged layer on a wafer surface, the method comprising: Step 101: repeatedly performing a pull-up etching operation on a wafer 100 to be tested, immersing the wafer 100 in an etching solution for a specified time and pulling the wafer 100 out of the etching solution, so that a terrace shape having a series of terraces is formed on the surface of the wafer 100 by etching with the etching solution; Step 102: sequentially performing damage detection on the series of terraces until no damage is detected; Step 103: Determine the depth of the surface damage layer of the wafer 100 according to the number of pull-up etching operations that have been performed when no damage is detected and the thickness of the wafer 100 etched away each time it is immersed in the etching solution, wherein the thickness is calculated based on the etching rate of the etching solution and the specified time.
在該方法中,可以直接對整片晶圓進行損傷層深度測量,整片晶圓可以直接應用實驗室的屬於通用檢測設備的蝕刻機和料籃,通過蝕刻機機械臂的程式實現提拉蝕刻操作,而將晶圓裂解成小片後進行測量則需要單獨設計對小片進行蝕刻時要使用的特製夾具和槽體。此外,由於無需將晶圓裂解成小片,故不存在針對小片進行角度拋光時因兩次黏接而導致的穩定性較差的問題,也不存在由於角度拋光而在斜面上引入新的損傷從而影響測量結果的問題,由此節約了工序並因此降低了成本也提高了測量結果的準確度。In this method, the depth of the damaged layer can be directly measured for the whole wafer. The whole wafer can be directly applied to the laboratory's general testing equipment such as the etcher and the material basket. The pull-up etching operation can be realized through the program of the etcher robot arm. However, the measurement after the wafer is split into small pieces requires the design of a special fixture and trough for etching the small pieces. In addition, since there is no need to split the wafer into small pieces, there is no problem of poor stability caused by two bondings when performing angle polishing on the small pieces, and there is no problem of introducing new damage on the bevel due to angle polishing, thereby affecting the measurement results. This saves processes, reduces costs, and improves the accuracy of the measurement results.
參照圖2和圖3,對於步驟101,提拉蝕刻操作即為將晶圓100浸入腐蝕液中規定時間並從腐蝕液中拉起的操作,在該操作中,腐蝕液會對晶圓100的表面產生蝕刻,從而該表面會被剝離掉一定厚度,通過反復進行這種提拉蝕刻操作,就會在該表面上形成具有一系列臺階面的臺階形狀,如圖3中可以清楚地看到。通過這種方式,在與晶圓表面垂直的方向上的損傷層被橫向分解。Referring to FIG. 2 and FIG. 3 , for step 101, the pull-up etching operation is an operation of immersing the wafer 100 in an etching solution for a predetermined time and pulling it out of the etching solution. In this operation, the etching solution etches the surface of the wafer 100, so that the surface is peeled off by a certain thickness. By repeatedly performing this pull-up etching operation, a terrace shape with a series of terraces is formed on the surface, as can be clearly seen in FIG. In this way, the damaged layer in the direction perpendicular to the wafer surface is decomposed horizontally.
當形成一系列臺階面之後,可以進行步驟102,即對這些臺階面依次進行損傷檢測。需要注意的是,該損傷檢測僅為檢測在該臺階面處是否仍存在損傷。隨著腐蝕液的逐層蝕刻,晶圓表面損傷層會通過不斷進行的厚度剝離而被蝕刻完,即蝕刻進行到完美層,與此對應的,會出現檢測不到損傷。After a series of terraces are formed, step 102 can be performed, i.e., damage detection is performed on these terraces in sequence. It should be noted that the damage detection is only to detect whether there is still damage at the terrace. As the etching liquid etches layer by layer, the damaged layer on the wafer surface will be etched away through continuous thickness peeling, i.e., etching is performed to a perfect layer, and correspondingly, no damage will be detected.
在這種情況下,可以進行步驟103,即對檢測不到損傷時已進行的提拉蝕刻操作的次數n進行統計,並根據腐蝕液的腐蝕速率v和規定時間t計算獲得晶圓100在每次浸入腐蝕液中時被蝕刻剝離的厚度ΔL,並最終根據該次數和該厚度計算獲得晶圓的表面損傷層的深度H。In this case, step 103 can be performed, that is, the number n of pull-up etching operations that have been performed when no damage is detected is counted, and the thickness ΔL of the wafer 100 etched and peeled off each time it is immersed in the etching solution is calculated based on the corrosion rate v of the etching solution and the specified time t, and finally the depth H of the surface damage layer of the wafer is calculated based on the number of times and the thickness.
在上述方法中,通過將垂直損傷橫向分解來判定損傷程度隨深度的變化,測試的是損傷層本身的深度,無需通過幾何關係進行逆推,可以更加快速準確的獲得測量結果。In the above method, the change of damage degree with depth is determined by decomposing vertical damage horizontally. What is tested is the depth of the damaged layer itself. There is no need to reverse the geometric relationship, and the measurement result can be obtained more quickly and accurately.
可以設想的是,晶圓每次浸入腐蝕液中的規定時間t可以是相等的。It is conceivable that the prescribed time t for each immersion of the wafer in the etching solution may be equal.
厚度ΔL可以通過公式ΔL=v*t來計算,在晶圓每次浸入腐蝕液中的規定時間t相等的情況下,晶圓在每次浸入腐蝕液中時被蝕刻剝離的厚度ΔL也是相等的。在這種情況下,可以通過公式H=n*ΔL直接計算出晶圓的表面損傷層的深度H。The thickness ΔL can be calculated by the formula ΔL=v*t. When the specified time t of the wafer being immersed in the etching solution is equal each time, the thickness ΔL etched away from the wafer each time it is immersed in the etching solution is also equal. In this case, the depth H of the surface damage layer of the wafer can be directly calculated by the formula H=n*ΔL.
還可以設想的是,晶圓每次浸入腐蝕液中的規定時間t可以是不等的。例如,在剛開始進行的數次提拉蝕刻操作中,t可以相對較長,以使晶圓被腐蝕液通過蝕刻剝離更大的厚度以節省操作時間,而在之後的提拉蝕刻操作中,t可以相對較短,以使蝕刻以較小剝離量逐步逼近完美層,避免因規定時間t過長而在t未進行完時蝕刻就過早到達完美層而導致測量結果不夠準確。It is also conceivable that the prescribed time t for each immersion of the wafer in the etching solution may be different. For example, in the first few pull-up etching operations, t may be relatively long so that the wafer is etched away by the etching solution to a greater thickness to save operation time, while in subsequent pull-up etching operations, t may be relatively short so that the etching gradually approaches the perfect layer with a smaller amount of stripping, thereby avoiding the situation where the prescribed time t is too long and the etching reaches the perfect layer too early before t is completed, resulting in inaccurate measurement results.
在這種情況下,晶圓在每次浸入腐蝕液中時被蝕刻剝離的厚度ΔL也是不等的,需要根據檢測不到損傷時已進行的提拉蝕刻操作的次數n對這些不同的厚度ΔL進行加和來獲得晶圓的表面損傷層的深度H。In this case, the thickness ΔL etched away from the wafer each time it is immersed in the etching solution is also different. It is necessary to add these different thicknesses ΔL according to the number n of pull-up etching operations that have been performed when no damage is detected to obtain the depth H of the surface damage layer of the wafer.
可以理解的是,規定時間t不宜過大,以避免因t過長而在t未進行完時蝕刻就過早到達完美層而導致測量結果不夠準確,另一方面,規定時間t也不宜過短,以免到達完美層前進行的提拉蝕刻操作的次數過多,導致整個過程的耗時過長。通常,規定時間t可以設定為數秒。It is understandable that the specified time t should not be too long, so as to avoid the etching reaching the perfect layer too early before t is completed, resulting in inaccurate measurement results. On the other hand, the specified time t should not be too short, so as to avoid too many pull-up etching operations before reaching the perfect layer, resulting in the entire process taking too long. Usually, the specified time t can be set to a few seconds.
需要注意的是,步驟101中的提拉蝕刻操作的次數可以根據腐蝕液的腐蝕速率、估計的損傷層深度和設定的規定時間來進行大致設定,以使通過設定次數的提拉蝕刻操作可以使蝕刻到達完美層。It should be noted that the number of pull-up etching operations in step 101 can be roughly set according to the corrosion rate of the etching solution, the estimated depth of the damaged layer and the set prescribed time, so that the etching can reach a perfect layer through the set number of pull-up etching operations.
根據本發明的實施方式,在步驟102中,如果該一系列臺階面中的最後一個臺階面仍被檢測出存在損傷,則可以重複步驟101和步驟102。According to an embodiment of the present invention, in step 102, if the last step in the series of steps is still detected to be damaged, steps 101 and 102 may be repeated.
具體而言,當對該一系列臺階面依次進行損傷檢測直至最後一個臺階面的時候仍檢測出存在損傷時,需要重複進行步驟101,即將晶圓再次反復進行多次提拉蝕刻操作,以繼續形成新的多個臺階面,之後,再進行步驟102,即對新的多個臺階面依次進行損傷檢測,直至未檢測到損傷為止。該過程可以在最後一個臺階面仍未檢測出存在損傷時,反復進行。Specifically, when damage is still detected on the last step after the series of steps are tested for damage in sequence, step 101 needs to be repeated, i.e., the wafer is repeatedly subjected to multiple pull-up and etching operations to continue to form multiple new steps, and then step 102 is performed, i.e., the multiple new steps are tested for damage in sequence until no damage is detected. This process can be repeated until damage is still not detected on the last step.
下面結合圖4至圖7對針對臺階面進行損傷檢測的示例性實現方式進行詳細說明。An exemplary implementation of damage detection for a step is described in detail below with reference to FIGS. 4 to 7 .
根據本發明的一種實施方式,參照圖4和圖5,對該一系列臺階面依次進行損傷檢測包括對該一系列臺階面依次進行粗糙度檢測,並且未檢測到損傷通過檢測到粗糙度趨於不變來確定。According to an embodiment of the present invention, referring to FIG. 4 and FIG. 5 , the damage detection of the series of terraces includes sequentially performing roughness detection on the series of terraces, and no damage is detected, which is determined by detecting that the roughness tends to be constant.
具體而言,可以通過對每個臺階面處的粗糙度進行檢測來實現對該臺階面處是否存在損傷的檢測。對於該粗糙度檢測過程,在將經過多次提拉蝕刻操作後的晶圓放置在測試平臺上後,如圖4中所示,可以使粗糙度檢測儀、具體地粗糙度檢測儀的粗糙度探頭11移動,以對承載在處於固定位置的承載基座10上的晶圓100的該一系列臺階面的粗糙度依次進行檢測。Specifically, the roughness of each terrace can be detected to detect whether there is damage on the terrace. For the roughness detection process, after the wafer after multiple pull-up and etching operations is placed on the test platform, as shown in FIG4 , the roughness detector, specifically the roughness probe 11 of the roughness detector, can be moved to sequentially detect the roughness of the series of terraces of the wafer 100 supported on the supporting base 10 at a fixed position.
替代性地,還可以使用於承載晶圓100的承載基座10移動,以使得處於固定位置的粗糙度檢測儀、具體地粗糙度檢測儀的粗糙度探頭11對晶圓100的表面的該一系列臺階面的粗糙度依次進行檢測。Alternatively, the supporting base 10 for supporting the wafer 100 may be moved so that the roughness detector at a fixed position, specifically the roughness probe 11 of the roughness detector, sequentially detects the roughness of the series of terraces on the surface of the wafer 100 .
圖5示出了檢測到的各個粗糙度值與提拉蝕刻操作的次數的關係曲線。隨著提拉蝕刻操作次數的增多,蝕刻剝離後形成的臺階面也逐漸逼近完美層,使得在該臺階面處檢測到的粗糙度也逐漸接近完美層的粗糙度,當粗糙度值趨於不變時,圖5中的曲線也從曲率不斷變化變成趨近於水平直線,則判定蝕刻已到達完美層,也就是說未檢測到損傷。此時已進行的提拉蝕刻操作的次數即為未檢測到損傷時已進行的提拉蝕刻操作的次數。FIG5 shows the relationship curve between each detected roughness value and the number of pull-up etching operations. As the number of pull-up etching operations increases, the terrace formed after etching and peeling gradually approaches the perfect layer, so that the roughness detected at the terrace gradually approaches the roughness of the perfect layer. When the roughness value tends to remain constant, the curve in FIG5 also changes from a continuously changing curvature to a straight line that tends to be close to a horizontal line, and it is determined that the etching has reached the perfect layer, that is, no damage is detected. At this time, the number of pull-up etching operations that have been performed is the number of pull-up etching operations that have been performed when no damage is detected.
根據本發明的另一實施方式,參照圖6和圖7,對該一系列臺階面依次進行損傷檢測包括對該一系列臺階面依次進行X光繞射檢測,並且未檢測到損傷通過檢測到繞射鋒的半高寬趨於不變來確定。According to another embodiment of the present invention, referring to FIG. 6 and FIG. 7 , performing damage detection on the series of terraces in sequence includes performing X-ray diffraction detection on the series of terraces in sequence, and no damage is detected by detecting that the half-height width of the diffraction front tends to be constant.
具體而言,可以通過在每個臺階面處進行X光繞射檢測來實現對該臺階面處是否存在損傷的檢測。對於X光繞射檢測過程,在將經過多次提拉蝕刻操作後的晶圓放置在測試平臺上後,如圖6中所示,可以使用於承載晶圓100的承載基座10移動,以使得處於固定位置的X光繞射儀12對在晶圓100的表面上形成的該一系列臺階面依次進行X光繞射檢測。如圖6所示,X光從X光繞射儀出射,在臺階面處繞射後,由X光繞射儀進行接收。Specifically, the detection of whether there is damage at each step can be achieved by performing X-ray diffraction detection at the step. For the X-ray diffraction detection process, after placing the wafer after multiple pull-up and etching operations on the test platform, as shown in FIG6 , the support base 10 for supporting the wafer 100 can be moved so that the X-ray diffraction instrument 12 in a fixed position sequentially performs X-ray diffraction detection on the series of steps formed on the surface of the wafer 100. As shown in FIG6 , X-rays are emitted from the X-ray diffraction instrument, diffracted at the step, and then received by the X-ray diffraction instrument.
同樣,替代性地,還可以使X光繞射儀12移動,以對承載在處於固定位置的承載基座10上的晶圓100的該一系列臺階面依次進行X光繞射檢測。Likewise, alternatively, the X-ray diffraction device 12 may be moved to sequentially perform X-ray diffraction inspection on the series of steps of the wafer 100 supported on the support base 10 at a fixed position.
圖7示出了檢測到的各個繞射峰的半高寬與提拉蝕刻操作的次數的關係曲線。隨著提拉蝕刻操作次數的增多,蝕刻剝離後形成的臺階面也逐漸逼近完美層,使得在該臺階面處檢測到的繞射峰也逐漸接近完美層的繞射峰,當晶圓表面存在嚴重損傷時,幾乎不存在晶體特性,故繞射曲線的半高寬非常大,隨著蝕刻不斷進行,損傷層的繞射曲線的半高寬會逐漸減小,當繞射峰的半高寬趨於不變時,圖7中的曲線也從曲率不斷變化變成趨近於水平直線,則判定蝕刻已到達完美層,也就是說未檢測到損傷。此時已進行的提拉蝕刻操作的次數即為未檢測到損傷時已進行的提拉蝕刻操作的次數。Figure 7 shows the relationship between the half-height width of each detected diffraction peak and the number of pull-etching operations. As the number of pull-etching operations increases, the terrace formed after etching and stripping gradually approaches the perfect layer, so that the diffraction peak detected at the terrace gradually approaches the diffraction peak of the perfect layer. When there is severe damage on the wafer surface, there is almost no crystal property, so the half-height width of the diffraction curve is The width is very large. As the etching continues, the half-height width of the diffraction curve of the damaged layer will gradually decrease. When the half-height width of the diffraction peak tends to be constant, the curve in Figure 7 also changes from a constantly changing curvature to a nearly horizontal straight line, and it is determined that the etching has reached a perfect layer, that is, no damage is detected. The number of pull-up etching operations that have been performed at this time is the number of pull-up etching operations that have been performed when no damage is detected.
本方法中通過逐層剝離得到每個深度的損傷面即臺階面並利用例如粗糙度檢測/X光繞射檢測實現對臺階面的損傷存在與否的明確判定,因此避免了肉眼觀察可能引入的人員判斷誤差。In this method, the damaged surface, i.e., the terrace surface, at each depth is obtained by peeling layer by layer, and roughness detection/X-ray diffraction detection, for example, is used to clearly determine whether the terrace surface is damaged, thereby avoiding human judgment errors that may be introduced by naked eye observation.
還可以設想採用其他相關技術中的檢測方式來實現對臺階面處是否存在損傷的檢測。It is also conceivable to use detection methods in other related technologies to detect whether there is damage on the platform step.
根據本發明的實施方式,腐蝕液可以為布萊特(Bright)腐蝕液,其中,布萊特腐蝕液是半導體企業減薄常用的包括硝酸、氫氟酸與乙酸的一種混酸。作為示例,本實施方式中的布萊特腐蝕液可以由硝酸、氫氟酸、乙酸、蒸餾水按4:1:2:3的體積比混合而成。According to the implementation of the present invention, the etching solution can be a Bright etching solution, wherein Bright etching solution is a mixed acid including nitric acid, hydrofluoric acid and acetic acid commonly used for thinning in semiconductor enterprises. As an example, the Bright etching solution in this implementation can be a mixture of nitric acid, hydrofluoric acid, acetic acid and distilled water in a volume ratio of 4:1:2:3.
腐蝕液可以包括在晶圓減薄中經常使用的酸性腐蝕液如硝酸、冰乙酸與氫氟酸,以及鹼性腐蝕如KOH溶液。作為另一示例,腐蝕液還可以是由氫氟酸、硝酸、硫酸和磷酸按1:6:1:2的體積比混合而成的混酸。The etching solution may include acid etching solutions commonly used in wafer thinning, such as nitric acid, glacial acetic acid, and hydrofluoric acid, and alkaline etching solutions such as KOH solution. As another example, the etching solution may also be a mixed acid formed by mixing hydrofluoric acid, nitric acid, sulfuric acid, and phosphoric acid in a volume ratio of 1:6:1:2.
在採用由硝酸、氫氟酸、乙酸、蒸餾水按4:1:2:3的體積比混合而成的布萊特腐蝕液的情況下,腐蝕速率為6um/min,即0.1um/s。由於晶圓表面的損傷深度一般處於5 um至20 um的範圍,因此,晶圓每次浸入腐蝕液中的時間即規定時間t可設定為5s至10s。When using Bright etching solution made of nitric acid, hydrofluoric acid, acetic acid and distilled water in a volume ratio of 4:1:2:3, the etching rate is 6um/min, or 0.1um/s. Since the damage depth on the wafer surface is generally in the range of 5um to 20um, the time that the wafer is immersed in the etching solution each time, i.e., the specified time t, can be set to 5s to 10s.
該規定時間可根據晶圓的類型來設定為不同的,例如,當晶圓為線切割之後獲得的晶圓時,由於其表面損傷較大,單次的規定時間可設定為10s,對應的提拉蝕刻操作的次數可設定為大約25次;而當晶圓為精磨之後獲得的晶圓時,由於其表面損傷較小,單次的規定時間可設定為2s或5s,對應的提拉蝕刻操作的次數可分別設定為大約10次或25次。The specified time can be set differently according to the type of wafer. For example, when the wafer is obtained after wire cutting, due to the large damage on its surface, the single specified time can be set to 10s, and the corresponding number of pull-up etching operations can be set to about 25 times; and when the wafer is obtained after fine grinding, due to the small damage on its surface, the single specified time can be set to 2s or 5s, and the corresponding number of pull-up etching operations can be set to about 10 times or 25 times respectively.
在本發明的實施方式中,腐蝕液的腐蝕速率可以通過以下步驟確定: 步驟1:測量測試晶圓的初始厚度; 步驟2:將測試晶圓浸入該腐蝕液中蝕刻特定時間並取出; 步驟3:對經過步驟2的測試晶圓的留存厚度進行測量;以及 步驟4:基於初始厚度與留存厚度之差以及特定時間計算獲得腐蝕速率。 In an embodiment of the present invention, the corrosion rate of the etching solution can be determined by the following steps: Step 1: measuring the initial thickness of the test wafer; Step 2: immersing the test wafer in the etching solution for etching for a specific time and taking it out; Step 3: measuring the remaining thickness of the test wafer after step 2; and Step 4: calculating the corrosion rate based on the difference between the initial thickness and the remaining thickness and the specific time.
具體而言,例如,可以選用整張晶圓作為測試晶圓,首先測量該測試晶圓的初始厚度d0,將其投入腐蝕液中蝕刻時間t後整體取出,然後對此時的厚度即留存厚度進行測量為d1,由此,腐蝕速率可以根據v=(d1-d0)/t計算得出。例如,對於上述由硝酸、氫氟酸、乙酸、蒸餾水按4:1:2:3的體積比混合而成的布萊特腐蝕液,經測試和計算,其腐蝕速率為6um/min。Specifically, for example, a whole wafer can be selected as a test wafer, and the initial thickness d0 of the test wafer is first measured, and the wafer is put into the etching solution for etching time t and then taken out as a whole, and then the thickness at this time, i.e., the retained thickness, is measured as d1, and thus, the corrosion rate can be calculated according to v=(d1-d0)/t. For example, for the above-mentioned Bright etching solution composed of nitric acid, hydrofluoric acid, acetic acid, and distilled water in a volume ratio of 4:1:2:3, after testing and calculation, its corrosion rate is 6um/min.
根據本發明的另一方面,還提供了一種測量晶圓表面損傷層深度的系統,其包括: 提拉單元,其用於對待測晶圓反復進行多次將晶圓浸入腐蝕液中規定時間並從腐蝕液中拉起的提拉蝕刻操作,使得通過由腐蝕液蝕刻而在晶圓的表面上形成具有一系列臺階面的臺階形狀; 檢測單元,其用於對該一系列臺階面依次進行損傷檢測,直至未檢測到損傷為止;以及 計算獲取單元,其用於根據未檢測到損傷時已進行的提拉蝕刻操作的次數和晶圓在每次浸入腐蝕液中時被蝕刻剝離的厚度確定晶圓的表面損傷層的深度,其中,該厚度由計算獲取單元根據腐蝕液的腐蝕速率和規定時間計算獲得。 According to another aspect of the present invention, a system for measuring the depth of a damaged layer on a wafer surface is provided, which includes: A pulling unit, which is used to repeatedly perform a pulling etching operation on a wafer to be tested, immersing the wafer in an etching solution for a specified time and pulling it out of the etching solution for multiple times, so that a step shape having a series of step surfaces is formed on the surface of the wafer by etching with the etching solution; A detection unit, which is used to perform damage detection on the series of step surfaces in sequence until no damage is detected; and The calculation acquisition unit is used to determine the depth of the surface damage layer of the wafer according to the number of pull-up etching operations that have been performed when no damage is detected and the thickness of the wafer etched and peeled off each time the wafer is immersed in the etching solution, wherein the thickness is calculated by the calculation acquisition unit according to the etching rate of the etching solution and the specified time.
根據本發明的實施方式,該測量晶圓表面損傷層深度的系統還可以包括重複單元,其用於在檢測單元檢測出該一系列臺階面中的最後一個臺階面仍存在損傷時使提拉單元和檢測單元重複進行操作。According to an embodiment of the present invention, the system for measuring the depth of the damaged layer on the wafer surface may further include a repeating unit, which is used to cause the pulling unit and the detection unit to repeatedly operate when the detection unit detects that the last step in the series of steps still has damage.
根據本發明的實施方式,該檢測單元可以包括粗糙度檢測儀或X光繞射儀。According to an embodiment of the present invention, the detection unit may include a roughness detector or an X-ray diffractometer.
根據本發明的實施方式,該提拉單元可以包括放置待測晶圓的料籃和用於對料籃進行提拉操作的機械臂。According to an embodiment of the present invention, the lifting unit may include a basket for placing the wafer to be tested and a robot arm for lifting the basket.
以上僅為本發明之較佳實施例,並非用來限定本發明之實施範圍,如果不脫離本發明之精神和範圍,對本發明進行修改或者等同替換,均應涵蓋在本發明申請專利範圍的保護範圍當中。The above are only preferred embodiments of the present invention and are not intended to limit the scope of implementation of the present invention. If the present invention is modified or replaced by something equivalent without departing from the spirit and scope of the present invention, it should be included in the protection scope of the patent application of the present invention.
100:晶圓 10:承載基座 11:粗糙度探頭 12:X光繞射儀 101-103:步驟 100: Wafer 10: Carrier base 11: Roughness probe 12: X-ray diffractometer 101-103: Steps
圖1為根據本發明的實施方式的測量晶圓表面損傷層深度的方法的示意性流程圖; 圖2以正視圖示意性地示出了利用根據本發明的實施方式的測量晶圓表面損傷層深度的方法對待測晶圓進行多次提拉蝕刻操作後所獲得的晶圓; 圖3以側視截面圖示意性地示出了圖2中的晶圓的一系列臺階面; 圖4示意性地示出了利用粗糙度檢測來實現對臺階面的損傷檢測的操作過程; 圖5以曲線圖示意性地示出了檢測到的粗糙度值與拉起次數的關係; 圖6示意性地示出了利用X光繞射檢測來實現對臺階面的損傷檢測的操作過程; 圖7以曲線圖示意性地示出了檢測到的繞射峰的半高寬與拉起次數的關係。 FIG1 is a schematic flow chart of a method for measuring the depth of a wafer surface damage layer according to an embodiment of the present invention; FIG2 schematically shows in a front view a wafer obtained by performing multiple pull-up and etching operations on a wafer to be tested using the method for measuring the depth of a wafer surface damage layer according to an embodiment of the present invention; FIG3 schematically shows in a side cross-sectional view a series of terraces of the wafer in FIG2; FIG4 schematically shows the operation process of using roughness detection to realize damage detection of terraces; FIG5 schematically shows in a curve diagram the relationship between the detected roughness value and the number of pull-ups; FIG6 schematically shows the operation process of using X-ray diffraction detection to realize damage detection of terraces; Figure 7 schematically shows the relationship between the half-width of the detected diffraction peak and the number of pull-ups in a curve diagram.
101-103:步驟 101-103: Steps
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