TWI850962B - Single chip integrating enhanced aluminum gallium nitride/gallium nitride high electron mobility transistor and low on-voltage diode using regrowth technology and its manufacturing method - Google Patents
Single chip integrating enhanced aluminum gallium nitride/gallium nitride high electron mobility transistor and low on-voltage diode using regrowth technology and its manufacturing method Download PDFInfo
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- 229910002601 GaN Inorganic materials 0.000 title claims abstract description 154
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 title claims abstract description 109
- RNQKDQAVIXDKAG-UHFFFAOYSA-N aluminum gallium Chemical compound [Al].[Ga] RNQKDQAVIXDKAG-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 238000005516 engineering process Methods 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 229910002704 AlGaN Inorganic materials 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 30
- 239000004065 semiconductor Substances 0.000 claims abstract description 25
- 238000005530 etching Methods 0.000 claims abstract description 24
- 230000004888 barrier function Effects 0.000 claims description 95
- 238000005253 cladding Methods 0.000 claims description 47
- 239000000463 material Substances 0.000 claims description 34
- 239000000758 substrate Substances 0.000 claims description 25
- 238000002161 passivation Methods 0.000 claims description 22
- 239000012212 insulator Substances 0.000 claims description 18
- 230000008929 regeneration Effects 0.000 claims description 15
- 238000011069 regeneration method Methods 0.000 claims description 15
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 10
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 229910052594 sapphire Inorganic materials 0.000 claims description 3
- 239000010980 sapphire Substances 0.000 claims description 3
- 238000010586 diagram Methods 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229920002120 photoresistant polymer Polymers 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 239000008186 active pharmaceutical agent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 239000003990 capacitor Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 238000001312 dry etching Methods 0.000 description 3
- 230000005684 electric field Effects 0.000 description 3
- 230000010354 integration Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 230000002860 competitive effect Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000001451 molecular beam epitaxy Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 230000005533 two-dimensional electron gas Effects 0.000 description 1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/02—Manufacture or treatment characterised by using material-based technologies
- H10D84/03—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology
- H10D84/038—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/80—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs
- H10D84/811—Combinations of field-effect devices and one or more diodes, capacitors or resistors
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Abstract
一種使用再生長技術整合增強型氮化鋁鎵/氮化鎵(AlGaN/GaN)高電子遷移率電晶體及低導通電壓二極體的單晶片與其製造方法,且單晶片可以用於直流轉直流(DC/DC)升壓轉換器中。進一步地,本發明主要是將原來的增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體的半導體結構進行蝕刻後,定義出電晶體區與二極體區,接著再進行蝕刻製程、再生長製程與電極佈局製程後,最後在電晶體區與二極體區分別形成增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體,以完成使用再生長技術整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體的單晶片之製作。A single chip and a manufacturing method thereof are provided for integrating an enhanced aluminum gallium nitride/gallium nitride (AlGaN/GaN) high electron mobility transistor and a low on-voltage diode using a regrowth technique. The single chip can be used in a DC/DC boost converter. Furthermore, the present invention mainly etches the original enhanced AlGaN/GaN high electron mobility transistor semiconductor structure to define the transistor region and the diode region, and then performs an etching process, a regrowth process and an electrode layout process, and finally forms an enhanced AlGaN/GaN high electron mobility transistor and a low on-voltage diode in the transistor region and the diode region respectively, so as to complete the production of a single chip integrating an enhanced AlGaN/GaN high electron mobility transistor and a low on-voltage diode using regrowth technology.
Description
本發明係關於一種使用再生長技術整合增強型氮化鋁鎵/氮化鎵(AlGaN/GaN)高電子遷移率電晶體及低導通電壓二極體的單晶片與其製造方法,且特別是一種用於直流轉直流(DC/DC)升壓轉換器之單晶片與其製造方法。The present invention relates to a single chip and a manufacturing method thereof that integrates an enhanced aluminum gallium nitride/gallium nitride (AlGaN/GaN) high electron mobility transistor and a low on-voltage diode using a regrowth technique, and in particular to a single chip and a manufacturing method thereof for a DC/DC boost converter.
直流轉直流升壓轉換器的電感主要做為用於將磁場和電能相互轉換的能量轉換元件。當直流轉直流升壓轉換器的功率開關導通時,電感將電能轉換為磁場能暫存起來。當功率開關截止時,電感將暫存的磁場能轉換為電場能,而這儲存的能量會在跟輸入電壓進行疊加後,經過直流轉直流升壓轉換器的二極體和電容的濾波後,便能得到直流電壓提供給負載。由於輸出電壓是輸入電壓和電感的磁碭能轉換為電能的疊加後所形成, 因此輸出電壓高於輸入電壓,即升壓過程的完成。The inductor of the DC-DC boost converter is mainly used as an energy conversion element for converting magnetic field and electrical energy to each other. When the power switch of the DC-DC boost converter is turned on, the inductor converts the electrical energy into magnetic field energy and stores it temporarily. When the power switch is turned off, the inductor converts the temporarily stored magnetic field energy into electric field energy, and this stored energy will be superimposed with the input voltage, and after filtering by the diode and capacitor of the DC-DC boost converter, a DC voltage can be obtained to provide to the load. Since the output voltage is formed by the superposition of the input voltage and the magnetic field energy of the inductor converted into electrical energy, the output voltage is higher than the input voltage, that is, the boost process is completed.
功率開關實際上是一種高功率電子元件,且目前製作高功率電子元件材料的選擇上,是以矽(Si)、碳化矽(SiC)與氮化鎵(GaN)三種材料為主。最早開發的元件是垂直式的矽基元件,也是目前市場上的主流。但由於矽材料有本質上散熱不佳、崩潰電場差與載子移動速率較慢等缺點,故無法應用於高電壓、高電流之高功率元件。除此之外,因垂直結構的矽基元件不易提升其操作頻率,故目前電力電子系統之直流轉直流轉換器的效率只侷限在80%左右。A power switch is actually a high-power electronic component, and the materials used to make high-power electronic components are mainly silicon (Si), silicon carbide (SiC) and gallium nitride (GaN). The earliest developed components were vertical silicon-based components, which are also the mainstream in the current market. However, due to the inherent disadvantages of silicon materials such as poor heat dissipation, poor collapse electric field and slow carrier movement rate, they cannot be used in high-voltage, high-current high-power components. In addition, because it is not easy to increase the operating frequency of vertically structured silicon-based components, the efficiency of DC-DC converters in current power electronics systems is limited to about 80%.
另一方面,碳化矽之量產的成熟度較高,且熱傳導係數與熔點等特性極佳,加上崩潰電場高,故碳化矽成為市場上功率元件選用的主要材料之一。然而,碳化矽缺乏高極化效應,故無法擁有高載子密度的二維電子氣,故其製作元件的方式會採用較接近矽基功率元件的方式,元件面積因此較大,加上碳化矽之材料成本昂貴,製作元件的成本極高,故碳化矽的功率元件較不具成本競爭力。On the other hand, the mass production maturity of silicon carbide is relatively high, and its thermal conductivity and melting point are excellent, and its collapse electric field is high, so silicon carbide has become one of the main materials used in power components on the market. However, silicon carbide lacks a high polarization effect, so it cannot have a two-dimensional electron gas with a high carrier density. Therefore, the method of manufacturing its components will adopt a method closer to silicon-based power components, so the component area is larger. In addition, the material cost of silicon carbide is expensive, and the cost of manufacturing components is extremely high, so silicon carbide power components are less cost competitive.
氮化鎵材料具有高抗熱、高崩潰電壓、高電子飽和速度與優秀極化效應產生的高載子密度等優勢,以其製成的元件的切換速率可提升至兆赫等級,且電力電子系統轉換及切換效率提升至95%以上。由於電流密度高,元件尺寸可大幅縮小,加上氮化鎵材料價格較碳化矽材料便宜許多,故目前氮化鎵材料相關的元件發展是目前市場上主要的發展方向。Gallium nitride materials have the advantages of high heat resistance, high breakdown voltage, high electron saturation speed and high carrier density generated by excellent polarization effect. The switching rate of components made of them can be increased to the megahertz level, and the conversion and switching efficiency of power electronic systems can be increased to more than 95%. Due to the high current density, the size of components can be greatly reduced. In addition, the price of gallium nitride materials is much cheaper than that of silicon carbide materials. Therefore, the development of components related to gallium nitride materials is currently the main development direction in the market.
舉例來說,氮化鎵高速場效電晶體的導通電阻只有傳統矽基板功率電晶體的百分之二,使其在未來高速、高功率的切換式電源供應器(switching power supply)應用上成為極佳的選擇,尤其適合像是在電力電子高溫、高功率的環境中,其寬能隙的物理特性以及更高的電子速度將會為此元件所製作出來之電力電子電路與系統更加可靠與有效率。For example, the on-resistance of gallium nitride high-speed field-effect transistors is only 2% of that of traditional silicon-based power transistors, making them an excellent choice for future high-speed, high-power switching power supply applications, especially in high-temperature, high-power environments such as power electronics. Their wide bandgap physical properties and higher electron speeds will make power electronics circuits and systems made with this component more reliable and efficient.
在直流轉直流升壓轉換器的應用中.由於傳統氮化鎵切換電晶體和高崩壓蕭特基二極體並不是製作於單一個晶片中,而是透過鎊線連作電性連接。然而,透過鎊線方法會使得轉換效率比較低,故實際得到的轉換效率應該會小於90%,且元件尺寸相對比較大。至於整合型單芯片在國內外之氮化鎵切換式電源供應器的文獻不多,相關研究也普遍存在元件為空乏型(depletion-mode)操作以及崩潰電壓小於200V等技術瓶頸,這樣的操作模式一直受到閘極負偏壓的限制,導致其整體電路面積偏大,降低其商業競爭力。In the application of DC-DC boost converters, the traditional gallium nitride switching transistors and high breakdown voltage Schottky diodes are not made in a single chip, but are electrically connected through a cadmium wire. However, the cadmium wire method will make the conversion efficiency lower, so the actual conversion efficiency should be less than 90%, and the device size is relatively large. As for the integrated single-chip gallium nitride switching power supply at home and abroad, there are not many literatures. Related research also generally has technical bottlenecks such as depletion-mode operation of the device and breakdown voltage less than 200V. This operating mode has always been limited by the negative bias of the gate, resulting in a large overall circuit area, reducing its commercial competitiveness.
基於本發明的至少一個目的,本發明提供一種使用再生長技術整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體的單晶片,其包括緩衝層、氮化鎵通道層、第一再生長阻障層、第一再生長p型覆蓋層、第一源極、第一汲極、閘極電極、原生阻障層、第二再生長阻障層、第二再生長p型覆蓋層、第二源極、第二汲極與陽極電極。氮化鎵通道層形成於緩衝層上,並具有溝槽以在溝槽兩側分別定義出電晶體區與二極體區。透過再生長製程(re-growth process),由氮化鋁鎵材料構成的第一再生長阻障層形成於氮化鎵通道層之上與位於電晶體區內。第一再生長p型覆蓋層、第一源極與第一汲極彼此絕緣,皆位於第一再生長阻障層之上,其中第一源極與第一汲極分別形成於第一再生長p型覆蓋層的兩側。閘極電極形成於第一再生長p型覆蓋層之上。由氮化鋁鎵材料構成的原生阻障層原生於氮化鎵通道層之上與位於二極體區內。透過再生長製程,由氮化鋁鎵材料構成的第二再生長阻障層形成於原生阻障層之上與位於二極體區內。第二再生長p型覆蓋層、第二源極與第二汲極彼此絕緣,皆位於第二再生長阻障層之上,其中第二源極與第二汲極分別形成於第二再生長p型覆蓋層的兩側。陽極電極形成於第一汲極、第二汲極與第二再生長p型覆蓋層之上。Based on at least one purpose of the present invention, the present invention provides a single chip integrating an enhanced aluminum gallium nitride/gallium nitride high electron mobility transistor and a low on-voltage diode using a regrowth technology, which includes a buffer layer, a gallium nitride channel layer, a first regrowth barrier layer, a first regrowth p-type cladding layer, a first source, a first drain, a gate electrode, a native barrier layer, a second regrowth barrier layer, a second regrowth p-type cladding layer, a second source, a second drain and an anode electrode. The gallium nitride channel layer is formed on the buffer layer and has a trench to define a transistor region and a diode region on both sides of the trench. Through the re-growth process, a first re-growth barrier layer composed of aluminum gallium nitride material is formed on the gallium nitride channel layer and in the transistor region. The first re-growth p-type cladding layer, the first source and the first drain are insulated from each other and are all located on the first re-growth barrier layer, wherein the first source and the first drain are formed on both sides of the first re-growth p-type cladding layer respectively. The gate electrode is formed on the first re-growth p-type cladding layer. The native barrier layer composed of aluminum gallium nitride material is natively formed on the gallium nitride channel layer and in the diode region. Through the regrowth process, a second regrowth barrier layer made of aluminum gallium nitride material is formed on the native barrier layer and in the diode region. The second regrowth p-type cladding layer, the second source and the second drain are insulated from each other and are all located on the second regrowth barrier layer, wherein the second source and the second drain are formed on both sides of the second regrowth p-type cladding layer respectively. The anode electrode is formed on the first drain, the second drain and the second regrowth p-type cladding layer.
基於本發明的另一個目的,本發明提供一種使用再生長技術整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體的單晶片之製造方法,且此製造方法具有以下步驟:提供具有氮化鋁鎵/氮化鎵高電子遷移率電晶體的半導體結構,對半導體結構進行高台蝕刻,並蝕刻至半導體結構之氮化鎵通道層的一部分,以形成溝槽,其中溝槽兩側定義出電晶體區與二極體區;對半導體結構的電晶體區進行蝕刻,並蝕刻至氮化鎵通道層;對半導體結構的二極體區進行蝕刻,並蝕刻至半導體結構的原生阻障層;進行再生長製程,以在電晶體區的氮化鎵通道層上依序形成第一再生長阻障層與第一再生長p型覆蓋層,以及在二極體區的原生阻障層上依序形成第二再生長阻障層與第二再生長p型覆蓋層;蝕刻第一再生長p型覆蓋層及第二再生長p型覆蓋層,以暴露第一再生長p型覆蓋層兩側的第一再生長阻障層,以及暴露第二再生長p型覆蓋層兩側的第二再生長阻障層;形成鈍化絕緣層覆蓋第一再生長阻障層、第一再生長p型覆蓋層、溝槽內的氮化鎵通道層、第二再生長阻障層與第二再生長p型覆蓋層,並對部分的鈍化絕緣層進行蝕刻至第一再生長阻障層及第二再生長阻障層,以定義出電晶體區與二極體區之每一者的源極區與汲極區;以及於電晶體區的源極區與汲極區分別形成第一源極與第一汲極,於二極體區的源極區與汲極區分別形成第二源極與第二汲極,形成閘極電極覆蓋第一再生長p型覆蓋層,以及形成陽極電極覆蓋第一汲極、第二汲極與第二再生長p型覆蓋層;其中原生阻障層、第一再生長阻障層與第一再生長p型覆蓋層由氮化鋁鎵材料構成。Based on another object of the present invention, the present invention provides a method for manufacturing a single chip integrating an enhanced aluminum gallium nitride/gallium nitride high electron mobility transistor and a low on-voltage diode using a regrowth technique, and the manufacturing method has the following steps: providing a semiconductor structure having an aluminum gallium nitride/gallium nitride high electron mobility transistor, performing a terrace etching on the semiconductor structure, and etching to a portion of the gallium nitride channel layer of the semiconductor structure to form a trench, wherein both sides of the trench define a transistor region and the diode region; etching the transistor region of the semiconductor structure and etching to the gallium nitride channel layer; etching the diode region of the semiconductor structure and etching to the native barrier layer of the semiconductor structure; performing a re-growth process to sequentially form a first re-growth barrier layer and a first re-growth p-type cap layer on the gallium nitride channel layer of the transistor region, and sequentially forming a second re-growth barrier layer and a second re-growth p-type cap layer on the native barrier layer of the diode region; etching the first re-growth p-type cap layer and A second regrown p-type cap layer is formed to expose the first regrown barrier layer on both sides of the first regrown p-type cap layer, and the second regrown barrier layer is exposed on both sides of the second regrown p-type cap layer; a passivated insulating layer is formed to cover the first regrown barrier layer, the first regrown p-type cap layer, the gallium nitride channel layer in the trench, the second regrown barrier layer and the second regrown p-type cap layer, and a portion of the passivated insulating layer is etched to the first regrown barrier layer and the second regrown barrier layer to define the transistor A source region and a drain region of each of the region and the diode region; and a first source and a first drain are formed in the source region and the drain region of the transistor region, respectively, and a second source and a second drain are formed in the source region and the drain region of the diode region, respectively, a gate electrode is formed to cover the first regenerated p-type cladding layer, and an anode electrode is formed to cover the first drain, the second drain and the second regenerated p-type cladding layer; wherein the native barrier layer, the first regenerated barrier layer and the first regenerated p-type cladding layer are composed of aluminum gallium nitride material.
簡言之,本發明提供一種使用再生長技術整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體的單晶片及其製造方法,其可以將優異的功率元件及整流器特性應用於直流轉直流轉換器中,並實現整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體與低導通電壓二極體於單晶片中的方案。整體來說,除了可以降低成本、減少晶片面積之外,更可以解決電路整合間封裝與不匹配之問題。再者,由於不用透過鎊線連接增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體與低導通電壓二極體,因此導線鍵合損耗的問題也可以獲得解決,故本發明的單晶片與製造方法非常具有研究與商業上的發展潛力。In short, the present invention provides a single chip and a manufacturing method thereof that integrates enhanced AlGaN/GaN high electron mobility transistors and low on-voltage diodes using regrowth technology, which can apply excellent power components and rectifier characteristics to DC-DC converters and realize the solution of integrating enhanced AlGaN/GaN high electron mobility transistors and low on-voltage diodes in a single chip. Overall, in addition to reducing costs and chip area, it can also solve the problems of packaging and mismatch between circuit integration. Furthermore, since the enhanced AlGaN/GaN high electron mobility transistor and the low on-voltage diode do not need to be connected through a nickel wire, the problem of wire bonding loss can also be solved. Therefore, the single chip and manufacturing method of the present invention have great research and commercial development potential.
為利 貴審查員瞭解本發明之技術特徵、內容與優點及其所能達成之功效,茲將本發明配合附圖,並以實施例之表達形式詳細說明如下,而其中所使用之圖式,其主旨僅為示意及輔助說明書之用,未必為本發明實施後之真實比例與精準配置,故不應就所附之圖式的比例與配置關係解讀、侷限本發明於實際實施上的權利範圍,合先敘明。In order to help the examiner understand the technical features, contents and advantages of the present invention and the effects that can be achieved, the present invention is described in detail as follows with the accompanying drawings and in the form of embodiments. The drawings used therein are only for illustration and auxiliary description, and may not be the true proportions and precise configurations after the implementation of the present invention. Therefore, it should not be interpreted based on the proportions and configurations of the attached drawings to limit the scope of rights of the present invention in actual implementation.
直流轉直流升壓轉換器廣泛地使用在電腦、通訊、軍事及航太等設備上,能提供穩定且高效的性能。本發明是在既有的氮化鋁鎵/氮化鎵高電子遷移率電晶體的半導體結構上透過磊晶結構設計、再成長的技術完成製作p型的增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體與低導通電壓二極體,且增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體與低導通電壓二極體被整合為單晶片。DC-to-DC boost converters are widely used in computers, communications, military and aerospace equipment, and can provide stable and efficient performance. The present invention is to manufacture p-type enhanced AlGaN/GaN high electron mobility transistors and low on-voltage diodes on the existing AlGaN/GaN high electron mobility transistor semiconductor structure through epitaxial structure design and re-growth technology, and the enhanced AlGaN/GaN high electron mobility transistor and low on-voltage diode are integrated into a single chip.
上述單晶片是將既有的氮化鋁鎵/氮化鎵高電子遷移率電晶體的半導體結構在定義的電晶體區的磊晶層中蝕刻至氮化鎵通道層,接著使用數位蝕刻(digital-etching)將定義的二極體區的磊晶層蝕刻至氮化鋁鎵/氮化鎵阻障層(即氮化鋁停止層及其之上的p型氮化鎵覆蓋層都被蝕刻去除),然後進行再生長製程,利用有機金屬化學氣相沉積法(MOCVD)在二極體區與電晶體區同時形成再生長氮化鋁鎵阻障層(其厚度例如為12奈米)及再生長p型氮化鎵覆蓋層(其厚度例如為60奈米),之後再經過源極、汲極跟電極的配置,以實現增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體與低導通電壓二極體的整合。The above-mentioned single chip is to etch the semiconductor structure of the existing AlGaN/GaN high electron mobility transistor in the epitaxial layer of the defined transistor area to the GaN channel layer, and then use digital etching to etch the epitaxial layer of the defined diode area to the AlGaN/GaN barrier layer (that is, the AlN stop layer and the p-type GaN capping layer thereon are etched away), and then proceed The regrowth process uses metal organic chemical vapor deposition (MOCVD) to simultaneously form a regrowth AlGaN barrier layer (whose thickness is, for example, 12 nanometers) and a regrowth p-type GaN cap layer (whose thickness is, for example, 60 nanometers) in the diode region and the transistor region, and then configures the source, drain and electrode to achieve the integration of the enhanced AlGaN/GaN high electron mobility transistor and the low on-voltage diode.
對於單晶片中的增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體來說,在再生長p型氮化鎵覆蓋層(作為p型閘極使用)下方形成有p-n接面空乏區,故能達成通道常關的特性,使得增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體具有低的導通電阻及好的可靠度,由於增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體是在順向電壓下操作,故可以達到避免負導通電壓與單一電壓供應。For the enhanced AlGaN/GaN high electron mobility transistor in a single chip, a p-n junction depletion region is formed under the regrown p-type GaN cap layer (used as a p-type gate), so that the channel normally-off characteristic can be achieved, making the enhanced AlGaN/GaN high electron mobility transistor have low on-resistance and good reliability. Since the enhanced AlGaN/GaN high electron mobility transistor operates under a forward voltage, it can avoid negative on-voltage and single voltage supply.
在二極體區中,再生長氮化鋁鎵阻障層與原生氮化鋁鎵阻障層的總厚度例如為18奈米,故可以使得其臨界電壓(threshold voltage)約在0V附近,再將閘極、汲極歐姆金屬做短路連接形成陽極(anode),即在二極體區中實現了低導通電壓二極體。電流藉由歐姆接觸導通即可降低低導通電壓二極體之導通電壓及切換之損耗,此外p型氮化鎵與氮化鋁鎵形成的p-n空乏區能關閉通道,故可以進而降低漏電流並提升元件的崩潰電壓。In the diode region, the total thickness of the regrown aluminum gallium nitride barrier layer and the native aluminum gallium nitride barrier layer is, for example, 18 nanometers, so that the critical voltage can be around 0V, and then the gate and drain ohmic metals are short-circuited to form an anode, that is, a low conduction voltage diode is realized in the diode region. The current conduction through the ohmic contact can reduce the conduction voltage and switching loss of the low conduction voltage diode. In addition, the p-n depletion region formed by p-type gallium nitride and aluminum gallium nitride can close the channel, so it can further reduce the leakage current and increase the breakdown voltage of the device.
在說明完本發明的概念後,接著以詳細的實施例說明本發明。首先,請參照圖7,圖7中下處的半導體結構,即為本發明最後所完成的使用再生長技術整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體的單晶片。單晶片包括基板11、緩衝層12、氮化鎵通道層13a、第一再生長阻障層15d、第一再生長p型覆蓋層16f、第一源極S1、第一汲極D1、閘極電極E2、原生阻障層14b、第二再生長阻障層15c、第二再生長p型覆蓋層16e、第二源極S2、第二汲極D2、陽極電極E1及複數個鈍化絕緣件M21~M27。After explaining the concept of the present invention, the present invention is described in detail with an embodiment. First, please refer to FIG. 7. The semiconductor structure at the bottom of FIG. 7 is the single chip of the present invention that integrates the enhanced AlGaN/GaN high electron mobility transistor and the low on-voltage diode using the regrowth technology. The single chip includes a substrate 11, a buffer layer 12, a gallium nitride channel layer 13a, a first re-growth barrier layer 15d, a first re-growth p-type cladding layer 16f, a first source S1, a first drain D1, a gate electrode E2, a native barrier layer 14b, a second re-growth barrier layer 15c, a second re-growth p-type cladding layer 16e, a second source S2, a second drain D2, an anode electrode E1 and a plurality of passivation insulators M21-M27.
緩衝層12形成於基板11之上,基板11為藍寶石基板、碳化矽基板或QST(Qromis Substrate Technology)基板,且本發明不以此為限制。在一些應用中,基板11可能在出廠時,被移除,即單晶片可以選擇性地不具有基板11。在氮化鎵通道層13a成長之前,會先以低溫成長一層緩衝層12,以藉此降低基板11與氮化鎵之晶格常數與熱膨脹係數差異所造成對結晶性的不良影響,進而改善其氮化鎵通道層13a的電性與光性。緩衝層12可以採用氮化鋁鎵材料,但本發明不以此為限制。The buffer layer 12 is formed on the substrate 11, and the substrate 11 is a sapphire substrate, a silicon carbide substrate or a QST (Qromis Substrate Technology) substrate, and the present invention is not limited thereto. In some applications, the substrate 11 may be removed when leaving the factory, that is, the single chip may selectively not have the substrate 11. Before the gallium nitride channel layer 13a is grown, a layer of buffer layer 12 is first grown at a low temperature to reduce the adverse effects on crystallinity caused by the difference in lattice constant and thermal expansion coefficient between the substrate 11 and gallium nitride, thereby improving the electrical and optical properties of the gallium nitride channel layer 13a. The buffer layer 12 can be made of aluminum gallium nitride material, but the present invention is not limited thereto.
氮化鎵通道層13a形成於緩衝層12上,並具有溝槽T01以在溝槽T01兩側分別定義出電晶體區R1與二極體區R2。透過再生長製程(re-growth process),由氮化鋁鎵材料構成的第一再生長阻障層15d形成於氮化鎵通道層13a之上與位於電晶體區R1內。透過鈍化絕緣件M22、M23,第一源極S1、第一再生長p型覆蓋層16f與第一汲極D1彼此絕緣,鈍化絕緣件M22、M23、第一源極S1、第一再生長p型覆蓋層16f與第一汲極D1皆位於第一再生長阻障層15d之上,鈍化絕緣件M21位於氮化鎵通道層13a之上,其中鈍化絕緣件M21位於第一源極S1的一側,第一源極S1與第一汲極D1分別形成於第一再生長p型覆蓋層16f的兩側,第一源極S1及第一再生長p型覆蓋層16f之間具有鈍化絕緣件M22,第一汲極D1及第一再生長p型覆蓋層16f之間具有鈍化絕緣件M23。閘極電極E2形成於第一再生長p型覆蓋層16f之上。The gallium nitride channel layer 13a is formed on the buffer layer 12 and has a trench T01 to define a transistor region R1 and a diode region R2 on both sides of the trench T01. Through a re-growth process, a first re-growth barrier layer 15d made of aluminum-gallium nitride material is formed on the gallium nitride channel layer 13a and located in the transistor region R1. The first source S1, the first regrown p-type cap layer 16f and the first drain D1 are insulated from each other by the passivation insulators M22 and M23. The passivation insulators M22, M23, the first source S1, the first regrown p-type cap layer 16f and the first drain D1 are all located on the first regrown barrier layer 15d. The passivation insulator M21 is located between the gallium nitride channel layer 13a. A passivation insulator M21 is formed on one side of the first source S1, the first source S1 and the first drain D1 are formed on both sides of the first regenerated p-type cladding layer 16f, a passivation insulator M22 is provided between the first source S1 and the first regenerated p-type cladding layer 16f, and a passivation insulator M23 is provided between the first drain D1 and the first regenerated p-type cladding layer 16f. A gate electrode E2 is formed on the first regenerated p-type cladding layer 16f.
由氮化鋁鎵材料構成的原生阻障層14原生於氮化鎵通道層13a之上與位於二極體區R2內。透過再生長製程,由氮化鋁鎵材料構成的第二再生長阻障層15c形成於原生阻障層14之上與位於二極體區R2內。透過鈍化絕緣件M25、M26,第二汲極D2、第二再生長p型覆蓋層16e與第二源極S2彼此絕緣,鈍化絕緣件M25、M26、第二汲極D2、第二再生長p型覆蓋層16e與第二源極S2皆位於第二再生長阻障層15c之上,鈍化絕緣件M27位於氮化鎵通道層13a之上,其中鈍化絕緣件M27位於第二源極S1的一側,第二汲極D2與第二源極S2分別形成於第二再生長p型覆蓋層16e的兩側,第二汲極D2與第二再生長p型覆蓋層16e之間具有鈍化絕緣件M25,第二源極S2與第二再生長p型覆蓋層16e之間具有鈍化絕緣件M26。鈍化絕緣件M24位於溝槽T01之內與位於氮化鎵通道層13a之上,鈍化絕緣件M24介於第一汲極D1與第二汲極D2之間。陽極電極E1形成於第一汲極D1、溝槽T01內的鈍化絕緣件M24、第二汲極D2與第二再生長p型覆蓋層16e之上。如此,便可以在電晶體區R1中形成p型的增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體。The native barrier layer 14 made of aluminum-gallium nitride material is natively formed on the gallium nitride channel layer 13a and located in the diode region R2. Through the regrowth process, a second regrowth barrier layer 15c made of aluminum-gallium nitride material is formed on the native barrier layer 14 and located in the diode region R2. The second drain D2, the second regrown p-type cap layer 16e and the second source S2 are insulated from each other by the passivation insulators M25 and M26. The passivation insulators M25, M26, the second drain D2, the second regrown p-type cap layer 16e and the second source S2 are all located on the second regrown barrier layer 15c. The passivation insulator M27 is located between the gallium nitride channel layer 13a. On, the passivation insulating member M27 is located on one side of the second source S1, the second drain D2 and the second source S2 are formed on both sides of the second regenerated p-type cladding layer 16e, respectively, there is a passivation insulating member M25 between the second drain D2 and the second regenerated p-type cladding layer 16e, and there is a passivation insulating member M26 between the second source S2 and the second regenerated p-type cladding layer 16e. The passivation insulating member M24 is located in the trench T01 and on the gallium nitride channel layer 13a, and the passivation insulating member M24 is between the first drain D1 and the second drain D2. The anode electrode E1 is formed on the first drain D1, the passivation insulator M24 in the trench T01, the second drain D2 and the second regrown p-type cladding layer 16e. Thus, a p-type enhanced AlGaN/GaN high electron mobility transistor can be formed in the transistor region R1.
第一再生長阻障層15d、原生阻障層14、第二再生長阻障層15c的採用同樣的氮化鋁鎵材料,其為Al xGa 1-xN,且x為0.13至0.25的任一數值。第一再生長p型覆蓋層16f與第二再生長p型覆蓋層16e之每一者的厚度為10至100奈米,原生阻障層14、第一再生長阻障層15d與第二再生長阻障層15c之每一者的厚度為1至20奈米,以及氮化鎵通道層的厚度為100至300奈米。第一再生長p型覆蓋層16f與第二再生長p型覆蓋層16f採用相同的材料,且此材料摻雜有濃度為1 10 17至1 10 21cm -3的鎂。如此,便可以在二極體區R2中形成低導通電壓二極體。較佳地,低導通電壓二極體的導通電壓大於0伏特且小於等於1伏特,甚至可以小於等於0.1伏特,但本發明不以此為限制。 The first regenerated growth barrier layer 15d, the native barrier layer 14, and the second regenerated growth barrier layer 15c use the same aluminum gallium nitride material, which is AlxGa1 -xN , and x is any value from 0.13 to 0.25. The thickness of each of the first regenerated growth p-type cladding layer 16f and the second regenerated growth p-type cladding layer 16e is 10 to 100 nanometers, the thickness of each of the native barrier layer 14, the first regenerated growth barrier layer 15d and the second regenerated growth barrier layer 15c is 1 to 20 nanometers, and the thickness of the gallium nitride channel layer is 100 to 300 nanometers. The first regenerated growth p-type cladding layer 16f and the second regenerated growth p-type cladding layer 16f use the same material, and this material is doped with a concentration of 1 10 17 to 1 10 21 cm -3 of magnesium. In this way, a low on-voltage diode can be formed in the diode region R2. Preferably, the on-voltage of the low on-voltage diode is greater than 0 volt and less than or equal to 1 volt, and can even be less than or equal to 0.1 volt, but the present invention is not limited thereto.
請參照圖9與圖10,增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體是常閉開關,必須施以大於1.7伏特的V GS電壓時,增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體才會導通,再者,在V GS電壓為0.8伏特且V DS電壓為8伏特時,導通電阻的電阻率為14.6歐姆•釐米,以及增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體在V GS電壓為0時,V DS電壓須被施以大於423伏特的電壓時,才會逆向導通。請參照圖11與圖12,低導通電壓二極體再施以趨近於0伏特的順向電壓(例如,0.1伏特)時,低導通電壓二極體便會導通,以及低導通電壓二極體在被施以大於606伏特的逆向電壓時,才會逆向導通。 Please refer to Figures 9 and 10. The enhanced AlGaN/GaN high electron mobility transistor is a normally closed switch. It must be applied with a V GS voltage greater than 1.7 volts for the enhanced AlGaN/GaN high electron mobility transistor to be turned on. Furthermore, when the V GS voltage is 0.8 volts and the V DS voltage is 8 volts, the resistivity of the on-resistance is 14.6 ohm•cm, and when the V GS voltage is 0, the enhanced AlGaN/GaN high electron mobility transistor must be applied with a V DS voltage greater than 423 volts for it to be reversely turned on. 11 and 12 , when a forward voltage close to 0V (eg, 0.1V) is applied to the low conduction voltage diode, the low conduction voltage diode will conduct, and when a reverse voltage greater than 606V is applied to the low conduction voltage diode, the low conduction voltage diode will conduct in the reverse direction.
請參照圖8,圖8是一種本發明實施例的直流轉直流升壓轉換器的示意電路圖。上述單晶片可以應用於直流轉直流升壓轉換器中,增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體21與低導通電壓二極體22被整合於上述單晶片中,並透過外接電感L電性連接直流轉直流升壓轉換器及外接電容C電性連接低導通電壓二極體22,即可以實現圖8的直流轉直流升壓轉換器。Please refer to FIG8 , which is a schematic circuit diagram of a DC-to-DC boost converter of an embodiment of the present invention. The above-mentioned single chip can be applied to the DC-to-DC boost converter, and the enhanced aluminum gallium nitride/gallium nitride high electron mobility transistor 21 and the low conduction voltage diode 22 are integrated in the above-mentioned single chip, and are electrically connected to the DC-to-DC boost converter through an external inductor L and an external capacitor C is electrically connected to the low conduction voltage diode 22, that is, the DC-to-DC boost converter of FIG8 can be realized.
在說明完本發明實施例的單晶片之細節與應用後,接著請參照圖1至圖7,以下將進一步地介紹上述單晶片的製造方法。在圖1中,提供具有氮化鋁鎵/氮化鎵高電子遷移率電晶體的半導體結構,對半導體結構進行高台蝕刻,並蝕刻至半導體結構之氮化鎵通道層13的一部分,以形成溝槽T01,其中溝槽T01兩側定義出電晶體區R1與二極體區R2。After explaining the details and applications of the single chip of the embodiment of the present invention, please refer to Figures 1 to 7 to further introduce the manufacturing method of the single chip. In Figure 1, a semiconductor structure with an aluminum gallium nitride/gallium nitride high electron mobility transistor is provided, and the semiconductor structure is subjected to high-table etching, and a portion of the gallium nitride channel layer 13 of the semiconductor structure is etched to form a trench T01, wherein the transistor region R1 and the diode region R2 are defined on both sides of the trench T01.
進一步地,提供的半導體結構是由基板11、緩衝層12、氮化鎵通道層13、阻障層14、蝕刻停止層15與p型氮化鎵覆蓋層16由下往上堆疊形成。p型氮化鎵覆蓋層16用於保護表面材料,其厚度為1至2奈米。蝕刻停止層15由氮化鋁材料構成,其厚度為1至2奈米,並作為高選擇比蝕刻停止層使用。阻障層14採用氮化鋁鎵材料,其為Al xGa 1-xN,且x為0.13至0.25的任一數值,其中阻障層14的厚度為1至20奈米,以及緩衝層12的厚度為1至10微米。 Furthermore, the semiconductor structure provided is formed by stacking a substrate 11, a buffer layer 12, a gallium nitride channel layer 13, a barrier layer 14, an etch stop layer 15 and a p-type gallium nitride cap layer 16 from bottom to top. The p-type gallium nitride cap layer 16 is used to protect the surface material and has a thickness of 1 to 2 nanometers. The etch stop layer 15 is made of aluminum nitride material and has a thickness of 1 to 2 nanometers and is used as a high selectivity etch stop layer. The barrier layer 14 is made of aluminum gallium nitride material, which is Al x Ga 1-x N, and x is any value from 0.13 to 0.25. The thickness of the barrier layer 14 is 1 to 20 nanometers, and the thickness of the buffer layer 12 is 1 to 10 micrometers.
氮化鎵通道層13在高台蝕刻後,溝槽T01的一部份深入氮化鎵通道層13,以形成氮化鎵通道層13a。在形成溝槽T01後,於電晶體區R1內,在氮化鎵通道層13a之上依序形成阻障層14a、蝕刻停止層15a與p型氮化鎵覆蓋層16a;以及,於二極體區R2內,在氮化鎵通道層13a之上依序形成原生阻障層14b、蝕刻停止層15b與p型氮化鎵覆蓋層16b。After the gallium nitride channel layer 13 is etched on the mesa, a portion of the trench T01 penetrates into the gallium nitride channel layer 13 to form a gallium nitride channel layer 13a. After the trench T01 is formed, a barrier layer 14a, an etch stop layer 15a, and a p-type gallium nitride capping layer 16a are sequentially formed on the gallium nitride channel layer 13a in the transistor region R1; and a native barrier layer 14b, an etch stop layer 15b, and a p-type gallium nitride capping layer 16b are sequentially formed on the gallium nitride channel layer 13a in the diode region R2.
接著,如圖2所示,於二極體區R2內之p型氮化鎵覆蓋層16b的上方設置光阻PR01,並進行乾蝕刻,以藉此對半導體結構的電晶體區R1進行蝕刻,並蝕刻至氮化鎵通道層13a,即透過乾蝕刻將阻障層14a、蝕刻停止層15a與p型氮化鎵覆蓋層16a移除。在進行完乾蝕刻後,將光阻PR01去除。Next, as shown in FIG. 2 , a photoresist PR01 is disposed above the p-type gallium nitride capping layer 16b in the diode region R2, and dry etching is performed to etch the transistor region R1 of the semiconductor structure and etch to the gallium nitride channel layer 13a, that is, the barrier layer 14a, the etching stop layer 15a and the p-type gallium nitride capping layer 16a are removed by dry etching. After the dry etching is completed, the photoresist PR01 is removed.
之後,如圖3所示,於電晶體區R1內的氮化鎵通道層13a之上放置光阻PR02,並且透過使用高選擇比材料的蝕刻停止層15b與數位蝕刻技術,對半導體結構的二極體區R2進行蝕刻,並蝕刻至半導體結構的原生阻障層14b,即透過數位蝕刻將蝕刻停止層15b與p型氮化鎵覆蓋層16b移除。在進行完數位蝕刻後,將光阻PR02去除。在此請注意,數位蝕刻非用於限制本發明,其他可以達到上述目的的蝕刻目的亦可以用於本發明。Afterwards, as shown in FIG. 3 , a photoresist PR02 is placed on the gallium nitride channel layer 13a in the transistor region R1, and the diode region R2 of the semiconductor structure is etched by using an etch stop layer 15b of a high selectivity material and digital etching technology, and the etching is performed to the native barrier layer 14b of the semiconductor structure, that is, the etch stop layer 15b and the p-type gallium nitride cap layer 16b are removed by digital etching. After the digital etching is completed, the photoresist PR02 is removed. Please note that digital etching is not used to limit the present invention, and other etching purposes that can achieve the above purpose can also be used in the present invention.
然後,如圖4所示,在氮化鎵通道層13a兩側設置遮罩件M01、M03,與在溝槽T01內的氮化鎵通道層13a之上設置遮罩件M02,並進行再生長製程,例如透過有機金屬化學氣相沉積法(MOCVD)或分子束磊晶法(MBE)的設備實現,以在電晶體區R1的氮化鎵通道層13a上依序形成第一再生長阻障層15d與第一再生長p型覆蓋層16d,以及在二極體區R2的原生阻障層14上依序形成第二再生長阻障層15c與第二再生長p型覆蓋層16c,並接著移除遮罩件M01~M03。Then, as shown in FIG. 4 , mask members M01 and M03 are disposed on both sides of the gallium nitride channel layer 13a, and a mask member M02 is disposed on the gallium nitride channel layer 13a in the trench T01, and a re-growth process is performed, for example, by using metal organic chemical vapor deposition (MOCVD) or molecular beam epitaxy (MBE) equipment, so as to sequentially form a first re-growth barrier layer 15d and a first re-growth p-type cap layer 16d on the gallium nitride channel layer 13a in the transistor region R1, and sequentially form a second re-growth barrier layer 15c and a second re-growth p-type cap layer 16c on the native barrier layer 14 in the diode region R2, and then remove the mask members M01 to M03.
第一再生長阻障層15d、原生阻障層14、第二再生長阻障層15c的採用同樣的氮化鋁鎵材料,其為Al xGa 1-xN,且x為0.13至0.25的任一數值。第一再生長p型覆蓋層16f與第二再生長p型覆蓋層16e之每一者的厚度為10至100奈米,以及第一再生長阻障層15d與第二再生長阻障層15c之每一者的厚度為1至20奈米。第一再生長p型覆蓋層16f與第二再生長p型覆蓋層16f採用相同的材料,且此材料摻雜有濃度為1 10 17至1 10 21cm -3的鎂。 The first regeneration barrier layer 15d, the native barrier layer 14, and the second regeneration barrier layer 15c use the same aluminum gallium nitride material, which is AlxGa1 -xN , and x is any value from 0.13 to 0.25. The thickness of each of the first regeneration p-type cladding layer 16f and the second regeneration p-type cladding layer 16e is 10 to 100 nanometers, and the thickness of each of the first regeneration barrier layer 15d and the second regeneration barrier layer 15c is 1 to 20 nanometers. The first regeneration p-type cladding layer 16f and the second regeneration p-type cladding layer 16f use the same material, and this material is doped with a concentration of 1 10 17 to 1 10 21 cm -3 of magnesium.
接著,如圖5所示,於電晶體區R1的第一再生長p型覆蓋層16d之上設置氮化矽材料的硬遮罩件M11,以定義出電晶體區R1內的閘極區,以及於二極體區R2的第二再生長p型覆蓋層16c之上設置氮化矽材料的硬遮罩件M12,以定義出電晶體區R1內的閘極區,並且進行蝕刻,如此第一再生長p型覆蓋層16d及第二再生長p型覆蓋層16c在被蝕刻後,會形成第一再生長p型覆蓋層16f及第二再生長p型覆蓋層16e,以暴露第一再生長p型覆蓋層16f兩側的第一再生長阻障層15d,以及暴露第二再生長p型覆蓋層16e兩側的第二再生長阻障層15c。在進行蝕刻後,硬遮罩件M11、M12會被移除。Next, as shown in FIG. 5 , a hard mask M11 of silicon nitride material is disposed on the first regrown p-type cladding layer 16d of the transistor region R1 to define the gate region in the transistor region R1, and a hard mask M12 of silicon nitride material is disposed on the second regrown p-type cladding layer 16c of the diode region R2 to define the gate region in the transistor region R1, and etching is performed. After the first regrown p-type cladding layer 16d and the second regrown p-type cladding layer 16c are etched, the first regrown p-type cladding layer 16f and the second regrown p-type cladding layer 16e are formed to expose the first regrown barrier layer 15d on both sides of the first regrown p-type cladding layer 16f and the second regrown barrier layer 15c on both sides of the second regrown p-type cladding layer 16e. After etching, the hard mask members M11 and M12 are removed.
之後,如圖6所示,形成氮化矽材料的鈍化絕緣層M2覆蓋第一再生長阻障層15d、第一再生長p型覆蓋層16f、溝槽T01內的氮化鎵通道層13a、第二再生長阻障層15c與第二再生長p型覆蓋層16e,並對部分的鈍化絕緣層M2進行蝕刻至第一再生長阻障層15d及第二再生長阻障層15c,以定義出電晶體區R1與二極體區R2之每一者的源極區與汲極區。在部分的鈍化絕緣層M2蝕刻完後,多個鈍化絕緣件M21~M27因此形成。Afterwards, as shown in FIG6 , a passivation insulating layer M2 of silicon nitride material is formed to cover the first regenerated growth barrier layer 15d, the first regenerated growth p-type cap layer 16f, the gallium nitride channel layer 13a in the trench T01, the second regenerated growth barrier layer 15c and the second regenerated growth p-type cap layer 16e, and a portion of the passivation insulating layer M2 is etched to the first regenerated growth barrier layer 15d and the second regenerated growth barrier layer 15c to define the source region and the drain region of each of the transistor region R1 and the diode region R2. After the portion of the passivation insulating layer M2 is etched, a plurality of passivation insulating members M21 to M27 are formed.
最後,如圖7所示,於電晶體區R1的源極區與汲極區分別形成第一源極S1與第一汲極D1,於二極體區R2的源極區與汲極區分別形成第二源極S2與第二汲極D2,然後,形成閘極電極E2覆蓋第一再生長p型覆蓋層16f,以及形成陽極電極E1覆蓋第一汲極D1、溝槽T01內的鈍化絕緣件M24、第二汲極D2與第二再生長p型覆蓋層16e。Finally, as shown in FIG. 7 , a first source S1 and a first drain D1 are formed in the source region and the drain region of the transistor region R1, respectively, and a second source S2 and a second drain D2 are formed in the source region and the drain region of the diode region R2, respectively. Then, a gate electrode E2 is formed to cover the first regrown p-type cover layer 16f, and an anode electrode E1 is formed to cover the first drain D1, the passivation insulator M24 in the trench T01, the second drain D2 and the second regrown p-type cover layer 16e.
由上述說明可知,本發明實施例提供一種使用再生長技術整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體的單晶片與其製造方法,其中單晶片特別適用於直流轉直流升壓轉換器之中。由於增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體是整合於單晶片中,因此不用透過鎊線連接增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體,故可以增加轉換效率與減少元件尺寸,再者二極體具有低導通電壓與高崩潰電壓,以及氮化鋁鎵/氮化鎵高電子遷移率電晶體是增強型,故整體面電路面積小,且具有商業競爭力。再者,整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體於單晶片中,更可以避免電路整合間封裝與不匹配之問題。As can be seen from the above description, the embodiment of the present invention provides a single chip and a manufacturing method thereof that integrates an enhanced aluminum gallium nitride/gallium nitride high electron mobility transistor and a low on-voltage diode using a regrowth technique, wherein the single chip is particularly suitable for use in a DC-to-DC boost converter. Since the enhanced AlGaN/GaN high electron mobility transistor and the low on-voltage diode are integrated in a single chip, there is no need to connect the enhanced AlGaN/GaN high electron mobility transistor and the low on-voltage diode through a copper wire, so the conversion efficiency can be increased and the device size can be reduced. Furthermore, the diode has a low on-voltage and a high breakdown voltage, and the AlGaN/GaN high electron mobility transistor is an enhanced type, so the overall surface area is small and commercially competitive. Furthermore, integrating enhanced AlGaN/GaN high electron mobility transistors and low on-voltage diodes into a single chip can avoid packaging and mismatch issues between circuit integration.
以上所述之實施例僅係為說明本發明之技術思想及特點,其目的在使熟習此項技藝之人士能夠瞭解本發明之內容並據以實施,當不能以之限定本發明之專利範圍,即大凡依本發明所揭示之精神所作之均等變化或修飾,仍應涵蓋在本發明之專利範圍內。The embodiments described above are only for illustrating the technical ideas and features of the present invention, and their purpose is to enable people familiar with this technology to understand the content of the present invention and implement it accordingly. They cannot be used to limit the patent scope of the present invention. In other words, all equivalent changes or modifications made according to the spirit disclosed by the present invention should still be included in the patent scope of the present invention.
11:基板 12:緩衝層 13、13a:氮化鎵通道層 14、14a、14b:阻障層 14b:原生阻障層 15a、15b:蝕刻停止層 15d:第一再生長阻障層 15c:第二再生長阻障層 16、16a 、16b:p型氮化鎵覆蓋層 16d、16f:第一再生長p型覆蓋層 16c、16e:第二再生長p型覆蓋層 21:增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體 22:低導通電壓二極體 S1:第一源極 S2:第二源極 D1:第一汲極 D2:第二汲極 E1:陽極電極 E2:閘極電極 M21~M27:鈍化絕緣件 T01:溝槽 R1:電晶體區 R2:二極體區 PR01、PR02:光阻 M01~M03:遮罩件 M11、M12:硬遮罩件 M2:鈍化絕緣層 L:電感 C:電容 11: Substrate 12: Buffer layer 13, 13a: GaN channel layer 14, 14a, 14b: Barrier layer 14b: Native barrier layer 15a, 15b: Etch stop layer 15d: First regrown barrier layer 15c: Second regrown barrier layer 16, 16a, 16b: P-type GaN cap layer 16d, 16f: First regrown p-type cap layer 16c, 16e: Second regrown p-type cap layer 21: Enhanced AlGaN/GaN high electron mobility transistor 22: Low on-voltage diode S1: First source S2: Second source D1: First drain D2: Second drain E1: Anode electrode E2: Gate electrode M21~M27: Passivated insulator T01: Trench R1: Transistor region R2: Diode region PR01, PR02: Photoresist M01~M03: Mask M11, M12: Hard mask M2: Passivated insulator L: Inductor C: Capacitor
提供的附圖用以使本發明所屬技術領域具有通常知識者可以進一步理解本發明,並且被併入與構成本發明之說明書的一部分。附圖示出了本發明的示範實施例,並且用以與本發明之說明書一起用於解釋本發明的原理。The accompanying drawings are provided to enable a person with ordinary knowledge in the art to which the present invention belongs to further understand the present invention, and are incorporated into and constitute a part of the specification of the present invention. The accompanying drawings show exemplary embodiments of the present invention, and are used together with the specification of the present invention to explain the principles of the present invention.
圖1~圖7分別是本發明實施例之使用再生長技術整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體的單晶片之製造方法的多個步驟的示意圖。FIG. 1 to FIG. 7 are schematic diagrams of multiple steps of a method for manufacturing a single chip integrating an enhanced AlGaN/GaN high electron mobility transistor and a low on-voltage diode using regrowth technology according to an embodiment of the present invention.
圖8是本發明實施例之使用再生長技術整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體的單晶片應用於直流轉直流升壓轉換器的示意圖。FIG8 is a schematic diagram of an embodiment of the present invention using a single chip integrating an enhanced AlGaN/GaN high electron mobility transistor and a low on-voltage diode using regrowth technology and applied to a DC-to-DC boost converter.
圖9與圖10分別是本發明實施例之使用再生長技術整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體的單晶片中之增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體的V GS、V DS電壓電流曲線示意圖與在V GS為0的V DS電壓電流曲線示意圖。 Figures 9 and 10 are respectively schematic diagrams of the V GS and V DS voltage-current curves of the enhanced AlGaN/GaN high electron mobility transistor in a single chip that integrates the enhanced AlGaN/GaN high electron mobility transistor and a low on-voltage diode using the regrowth technology in an embodiment of the present invention, and a schematic diagram of the V DS voltage-current curve when V GS is 0.
圖11與圖12分別是本發明實施例之使用再生長技術整合增強型氮化鋁鎵/氮化鎵高電子遷移率電晶體及低導通電壓二極體的單晶片中之低導通電壓二極體的順向電壓電流曲線示意圖與逆向電壓電流曲線示意圖。FIG. 11 and FIG. 12 are respectively schematic diagrams of the forward voltage-current curve and the reverse voltage-current curve of the low on-voltage diode in the single chip integrating the enhanced aluminum gallium nitride/gallium nitride high electron mobility transistor and the low on-voltage diode using the regrowth technology in an embodiment of the present invention.
11:基板 12:緩衝層 13a:氮化鎵通道層 14b:原生阻障層 15d:第一再生長阻障層 15c:第二再生長阻障層 16f:第一再生長p型覆蓋層 16e:第二再生長p型覆蓋層 S1:第一源極 S2:第二源極 D1:第一汲極 D2:第二汲極 E1:陽極電極 E2:閘極電極 M21~M27:鈍化絕緣件 T01:溝槽 R1:電晶體區 R2:二極體區 11: Substrate 12: Buffer layer 13a: GaN channel layer 14b: Native barrier layer 15d: First regrown barrier layer 15c: Second regrown barrier layer 16f: First regrown p-type cladding layer 16e: Second regrown p-type cladding layer S1: First source S2: Second source D1: First drain D2: Second drain E1: Anode electrode E2: Gate electrode M21~M27: Passivated insulator T01: Trench R1: Transistor region R2: Diode region
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