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TWI701815B - Memory device - Google Patents

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TWI701815B
TWI701815B TW108102916A TW108102916A TWI701815B TW I701815 B TWI701815 B TW I701815B TW 108102916 A TW108102916 A TW 108102916A TW 108102916 A TW108102916 A TW 108102916A TW I701815 B TWI701815 B TW I701815B
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layer
channel
channel structure
memory device
stacked
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TW108102916A
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Chinese (zh)
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TW202029476A (en
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胡志瑋
葉騰豪
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旺宏電子股份有限公司
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Abstract

A memory device is provided. The memory device comprises a stack structure and a channel structure. The stack structure is on a substrate and comprises gate electrodes and insulating films stacked alternately. The channel structure is electrically coupled to the gate electrodes, and is on sidewall surfaces of the gate electrodes. The channel structure comprises a first channel structure and a second channel structure. The second channel structure is on an upper surface of the first channel structure. The first channel structure and/or the second channel structure has a ring shape.

Description

記憶體裝置 Memory device

本發明是有關於一種記憶體裝置。 The present invention relates to a memory device.

隨著積體電路中元件的關鍵尺寸逐漸縮小至製程技術所能感知的極限,設計者已經開始尋找可達到更大記憶體密度的技術,藉以達到較低的位元成本(costs per bit)。目前正被關注的技術包括反及閘記憶體(NAND memory)及其製造方法。 As the critical size of components in integrated circuits gradually shrinks to the perceptible limit of the process technology, designers have begun to look for technologies that can achieve greater memory density, thereby achieving lower costs per bit. Technologies that are currently being watched include NAND memory and its manufacturing method.

本發明係有關於一種記憶體裝置。 The invention relates to a memory device.

根據本發明之一方面,提出一種記憶體裝置,其包括記憶體裝置包括堆疊結構及通道結構。堆疊結構位於基底上。堆疊結構包括交錯堆疊的閘電極與絕緣膜。通道結構電性耦接閘電極,並位在閘電極的側表面上。通道結構包括第一通道結構及第二通道結構。第二通道結構位在第一通道結構的上表面上。第一通道結構及/或第二通道結構為環形狀。 According to one aspect of the present invention, a memory device is provided, which includes a memory device including a stacked structure and a channel structure. The stacked structure is located on the substrate. The stacked structure includes gate electrodes and insulating films stacked alternately. The channel structure is electrically coupled to the gate electrode and is located on the side surface of the gate electrode. The channel structure includes a first channel structure and a second channel structure. The second channel structure is located on the upper surface of the first channel structure. The first channel structure and/or the second channel structure have a ring shape.

為了對本發明之上述及其他方面有更佳的瞭解,下文特舉實施例,並配合所附圖式詳細說明如下: In order to have a better understanding of the above and other aspects of the present invention, the following specific examples are given in conjunction with the accompanying drawings to describe in detail as follows:

102:基底 102: Base

104、204:絕緣膜 104, 204: insulating film

106、206:蝕刻終止層 106, 206: etching stop layer

109:底導電層 109: bottom conductive layer

109S1:側表面 109S1: side surface

109S2:上表面 109S2: upper surface

110:第一溝槽 110: The first groove

111:導電層 111: conductive layer

111S:側表面 111S: side surface

112:電荷儲存層 112: charge storage layer

112A:上表面 112A: upper surface

112B:側表面 112B: side surface

112S:上表面 112S: upper surface

114:絕緣層 114: insulating layer

114S:上表面 114S: upper surface

116:凹口 116: Notch

210:第二溝槽 210: second groove

216:凹口 216: Notch

217:頂部導電層 217: Top conductive layer

217S:側表面 217S: side surface

218:閘介電層 218: Gate Dielectric Layer

220:絕緣材料 220: insulating material

300、304:導電柱 300, 304: conductive pillar

302:導電層 302: conductive layer

320開孔 320 opening

322:絕緣牆 322: Insulated Wall

BL:位元線 BL: bit line

CL1:第一通道結構 CL1: The first channel structure

CL1B:第一底通道層 CL1B: The first bottom channel layer

CL1R:第一環形通道層 CL1R: The first ring channel layer

CL1S1:上表面 CL1S1: Upper surface

CL1S2:上表面 CL1S2: upper surface

CL1S3:上表面 CL1S3: Upper surface

CL2、CL4:連接層 CL2, CL4: connection layer

CL2S:上表面 CL2S: upper surface

CL3:第二通道結構 CL3: Second channel structure

CL31:第一通道層 CL31: The first channel layer

CL32:第二通道層 CL32: Second channel layer

CL32B:第二底通道層 CL32B: second bottom channel layer

CL32R:第二環形通道層 CL32R: The second ring channel layer

CSL:共同源極線 CSL: Common Source Line

D1:第一方向 D1: First direction

D2:第二方向 D2: second direction

D3:第三方向 D3: Third party

GSL:接地選擇線 GSL: Ground selection line

IG:底反轉閘電極 IG: bottom inversion gate electrode

K:堆疊結構 K: Stacked structure

K1:第一堆疊層 K1: The first stacked layer

K1S:上表面 K1S: upper surface

K2:第二堆疊層 K2: second stacked layer

K2S:上表面 K2S: upper surface

N1:第一距離 N1: first distance

N2:第二距離 N2: second distance

P1、P2、P3、P4、P5、P6、P7:剖面 P1, P2, P3, P4, P5, P6, P7: profile

WL:字元線 WL: Character line

SSL:串列選擇線 SSL: Serial selection line

第1圖至第20圖繪示根據一實施例的記憶體裝置的製造方法。 FIG. 1 to FIG. 20 illustrate a method of manufacturing a memory device according to an embodiment.

以下係以一些實施例做說明。須注意的是,本揭露並非顯示出所有可能的實施例,未於本揭露提出的其他實施態樣也可能可以應用。再者,圖式上的尺寸比例並非按照實際產品等比例繪製。因此,說明書和圖示內容僅作敘述實施例之用,而非作為限縮本揭露保護範圍之用。另外,實施例中之敘述,例如細部結構、製程步驟和材料應用等等,僅為舉例說明之用,並非對本揭露欲保護之範圍做限縮。實施例之步驟和結構各之細節可在不脫離本揭露之精神和範圍內根據實際應用製程之需要而加以變化與修飾。以下是以相同/類似的符號表示相同/類似的元件做說明。 Some examples are described below. It should be noted that this disclosure does not show all possible embodiments, and other implementation aspects not mentioned in this disclosure may also be applicable. Furthermore, the size ratios in the drawings are not drawn in proportion to the actual products. Therefore, the contents of the description and illustrations are only used to describe the embodiments, rather than to limit the protection scope of this disclosure. In addition, the descriptions in the embodiments, such as detailed structure, process steps, material applications, etc., are for illustrative purposes only, and are not intended to limit the scope of the disclosure. The details of the steps and structures of the embodiments can be changed and modified according to the needs of the actual application process without departing from the spirit and scope of the present disclosure. In the following description, the same/similar symbols represent the same/similar elements.

第1圖至第20圖繪示根據一實施例的記憶體裝置的製造方法。 FIG. 1 to FIG. 20 illustrate a method of manufacturing a memory device according to an embodiment.

請參照第1圖,可在基底102上交錯堆疊導電層與絕緣膜以形成第一堆疊層K1。一實施例中,基底102可包括矽基底,第一堆疊層K1可形成在矽基底上的絕緣層上,絕緣層例如包括氧化矽等材料。導電層包括最底的底導電層109及其上方的其它導電層111。底導電層109與導電層111可包括導電材料,例如導體材料或半導體材料。半導體材料包括多晶矽,例如經摻 雜的多晶矽。絕緣膜可包括絕緣膜104及蝕刻終止層106,蝕刻終止層106可形成在最頂端的絕緣膜104上。一實施例中,絕緣膜104可包括氧化物例如氧化矽,蝕刻終止層106可包括氮化物例如氮化矽。 Referring to FIG. 1, conductive layers and insulating films can be alternately stacked on the substrate 102 to form a first stacked layer K1. In an embodiment, the substrate 102 may include a silicon substrate, and the first stacked layer K1 may be formed on an insulating layer on the silicon substrate. The insulating layer may include materials such as silicon oxide. The conductive layer includes the bottom conductive layer 109 and other conductive layers 111 above it. The bottom conductive layer 109 and the conductive layer 111 may include conductive materials, such as conductive materials or semiconductor materials. Semiconductor materials include polysilicon, such as doped Miscellaneous polysilicon. The insulating film may include an insulating film 104 and an etch stop layer 106, and the etch stop layer 106 may be formed on the topmost insulating film 104. In one embodiment, the insulating film 104 may include oxide such as silicon oxide, and the etch stop layer 106 may include nitride such as silicon nitride.

請參照第2圖,可進行圖案化製程以在第一堆疊層K1中形成第一溝槽110。第一溝槽110可露出第一堆疊層K1的側表面,包括導電層111的側表面111S,及底導電層109的側表面109S1,並可露出底導電層109的上表面109S2。形成電荷儲存層112在第一溝槽110中。電荷儲存層112可形成在第一溝槽110露出的第一堆疊層K1的側表面及底導電層109的上表面109S2上,及第一堆疊層K1的上表面K1S上。第一通道結構CL1可形成在第一溝槽110所露出之電荷儲存層112的上表面112A及側表面112B上。位在第一堆疊層K1(包括導電層111的側表面111S及底導電層109的側表面109S1及上表面109S2)與第一通道結構CL1之間的電荷儲存層112可具有ONO結構、ONONO結構、ONONONO結構、或氮氧化矽/氮化矽/氧化物結構。第一通道結構CL1可包括半導體材料,包括經摻雜的半導體材料或未經摻雜的半導體材料。一實施例中,第一通道結構CL1的材料包括多晶矽,例如經摻雜的多晶矽或未經摻雜的多晶矽。 Referring to FIG. 2, a patterning process can be performed to form the first trench 110 in the first stacked layer K1. The first trench 110 may expose the side surface of the first stacked layer K1, including the side surface 111S of the conductive layer 111 and the side surface 109S1 of the bottom conductive layer 109, and may expose the upper surface 109S2 of the bottom conductive layer 109. A charge storage layer 112 is formed in the first trench 110. The charge storage layer 112 may be formed on the side surface of the first stacked layer K1 exposed by the first trench 110 and the upper surface 109S2 of the bottom conductive layer 109, and on the upper surface K1S of the first stacked layer K1. The first channel structure CL1 may be formed on the upper surface 112A and the side surface 112B of the charge storage layer 112 exposed by the first trench 110. The charge storage layer 112 located between the first stacked layer K1 (including the side surface 111S of the conductive layer 111 and the side surface 109S1 and the upper surface 109S2 of the bottom conductive layer 109) and the first channel structure CL1 may have an ONO structure or an ONONO structure , ONONONO structure, or silicon oxynitride/silicon nitride/oxide structure. The first channel structure CL1 may include a semiconductor material, including a doped semiconductor material or an undoped semiconductor material. In one embodiment, the material of the first channel structure CL1 includes polysilicon, such as doped polysilicon or undoped polysilicon.

第2A圖繪示沿第2圖所示之結構沿橫剖面P1的上視示意圖。如第2A圖中所示,第一溝槽110中的電荷儲存層112及第一通道結構CL1具有環形狀,其中環狀包括圓形或橢圓,第 一通道結構CL1例如為中空環狀、實心環狀、半中空環狀或實心半環狀。第2圖可為沿第2A圖所示之結構沿AB線的縱剖面示意圖。 FIG. 2A is a schematic top view of the structure shown in FIG. 2 along the cross section P1. As shown in Figure 2A, the charge storage layer 112 and the first channel structure CL1 in the first trench 110 have a ring shape, wherein the ring shape includes a circle or an ellipse. A channel structure CL1 is, for example, a hollow ring, a solid ring, a semi-hollow ring, or a solid half ring. Figure 2 may be a schematic longitudinal cross-sectional view of the structure shown in Figure 2A along the line AB.

請參照第3圖,可形成絕緣層114填充第一溝槽110,並於第一通道結構CL1的上表面CL1S1上。絕緣層114形成在第一溝槽110露出的第一通道結構CL1上。一實施例中,絕緣層114的材料包括氧化物例如氧化矽。 Referring to FIG. 3, an insulating layer 114 can be formed to fill the first trench 110 and on the upper surface CL1S1 of the first channel structure CL1. The insulating layer 114 is formed on the first channel structure CL1 exposed by the first trench 110. In one embodiment, the material of the insulating layer 114 includes oxide such as silicon oxide.

請參照第4圖,可利用回蝕刻製程移除電荷儲存層112、第一通道結構CL1及絕緣層114位在第一堆疊層K1上方的部分。一實施例中,回蝕刻製程可包括化學機械研磨方法或其它合適的蝕刻方法。此回蝕刻製程可使得結構具有一平坦的上表面。 Referring to FIG. 4, the charge storage layer 112, the first channel structure CL1, and the insulating layer 114 above the first stacked layer K1 can be removed by an etch-back process. In an embodiment, the etch-back process may include a chemical mechanical polishing method or other suitable etching methods. This etch-back process can make the structure have a flat upper surface.

請參照第5圖,可從移除電荷儲存層112、第一通道結構CL1及絕緣層114的上部分以形成從第一堆疊層K1之上表面K1S下凹的凹口116。凹口116露出電荷儲存層112的上表面112S、第一通道結構CL1的上表面CL1S2及絕緣層114的上表面114S。一實施例中,可利用具有蝕刻選擇性的蝕刻製程,以蝕刻終止層106作為蝕刻遮罩進行此移除步驟。此例中,凹口116可實質上對齊第一溝槽110。例如凹口116在第一方向D1上的尺寸可實質上等於第一溝槽110在第一方向D1上的尺寸。凹口116在第二方向D2上的尺寸可實質上等於第一溝槽110在第二方向D2上的尺寸。另一實施例中,可對第4圖所示的結構進行 圖案化製程以形成凹口116。此例中,凹口116的尺寸/形狀可不同於第一溝槽110。 Referring to FIG. 5, the charge storage layer 112, the first channel structure CL1, and the upper portion of the insulating layer 114 can be removed from the upper portion to form a recess 116 recessed from the upper surface K1S of the first stacked layer K1. The recess 116 exposes the upper surface 112S of the charge storage layer 112, the upper surface CL1S2 of the first channel structure CL1, and the upper surface 114S of the insulating layer 114. In one embodiment, an etching process with etching selectivity can be used to perform this removal step using the etching stop layer 106 as an etching mask. In this example, the notch 116 can be substantially aligned with the first groove 110. For example, the size of the notch 116 in the first direction D1 may be substantially equal to the size of the first groove 110 in the first direction D1. The size of the notch 116 in the second direction D2 may be substantially equal to the size of the first groove 110 in the second direction D2. In another embodiment, the structure shown in Figure 4 can be The patterning process is used to form the recess 116. In this example, the size/shape of the recess 116 may be different from the first groove 110.

請參照第6圖,可形成連接層CL2填充凹口116,並位在電荷儲存層112的上表面112S、第一通道結構CL1露出的上表面CL1S2及絕緣層114的上表面114S上,並位在絕緣膜104及蝕刻終止層106的側表面上,與第一堆疊層K1之上表面K1S上。連接層CL2的材料可相同或不同於第一通道結構CL1的材料。連接層CL2的材料可包括導電材料或半導體材料。半導體材料可包括多晶矽材料。一實施例中,連接層CL2的材料包括經摻雜的半導體材料,例如摻雜的多晶矽材料,例如N型摻雜的多晶矽材料,其導電性可大於未摻雜的多晶矽材料。 Referring to FIG. 6, a connecting layer CL2 can be formed to fill the recess 116 and located on the upper surface 112S of the charge storage layer 112, the exposed upper surface CL1S2 of the first channel structure CL1, and the upper surface 114S of the insulating layer 114, and are aligned On the side surfaces of the insulating film 104 and the etching stop layer 106, and on the upper surface K1S of the first stacked layer K1. The material of the connection layer CL2 may be the same or different from the material of the first channel structure CL1. The material of the connection layer CL2 may include a conductive material or a semiconductor material. The semiconductor material may include polysilicon material. In one embodiment, the material of the connection layer CL2 includes a doped semiconductor material, such as a doped polysilicon material, such as an N-doped polysilicon material, and its conductivity may be greater than that of an undoped polysilicon material.

請參照第7圖,可利用回蝕刻製程移除連接層CL2位在第一堆疊層K1上方的部分。一實施例中,回蝕刻製程可包括化學機械研磨方法或其它合適的蝕刻方法。此回蝕刻製程可使得結構具有一平坦的上表面。 Referring to FIG. 7, an etch-back process can be used to remove the portion of the connecting layer CL2 located above the first stacked layer K1. In an embodiment, the etch-back process may include a chemical mechanical polishing method or other suitable etching methods. This etch-back process can make the structure have a flat upper surface.

第7A圖繪示沿第7圖所示之結構沿橫剖面P2的上視示意圖。如第7A圖中所示,凹口116中的連接層CL2具有實心的橢圓形狀。第7圖可為沿第7A圖所示之結構沿AB線的縱剖面示意圖,類似的概念不再重複贅述。 FIG. 7A is a schematic top view of the structure shown in FIG. 7 along the cross section P2. As shown in FIG. 7A, the connection layer CL2 in the recess 116 has a solid oval shape. Figure 7 may be a schematic longitudinal cross-sectional view of the structure shown in Figure 7A along the line AB, and similar concepts will not be repeated.

請參照第8圖,堆疊結構K包括第一堆疊層K1及第二堆疊層K2。在第一堆疊層K1及連接層CL2上形成頂部導電層217與絕緣膜204以形成第二堆疊層K2。頂部導電層217可 包括導電材料,例如導體材料或半導體材料。半導體材料包括多晶矽,例如經摻雜的多晶矽。蝕刻終止層206可形成在最頂的絕緣膜204上方。一實施例中,絕緣膜204可包括氧化物例如氧化矽。蝕刻終止層206可包括氮化物例如氮化矽。 Referring to FIG. 8, the stacked structure K includes a first stacked layer K1 and a second stacked layer K2. A top conductive layer 217 and an insulating film 204 are formed on the first stacked layer K1 and the connection layer CL2 to form a second stacked layer K2. The top conductive layer 217 can be Including conductive materials, such as conductive materials or semiconductor materials. The semiconductor material includes polysilicon, such as doped polysilicon. The etch stop layer 206 may be formed on the topmost insulating film 204. In one embodiment, the insulating film 204 may include oxide such as silicon oxide. The etch stop layer 206 may include nitride such as silicon nitride.

請參照第9圖,可進行圖案化製程以在包括頂部導電層217的第二堆疊層K2中形成第二溝槽210。圖案化製程包括蝕刻製程。用以形成第二溝槽210的蝕刻製程可利用連接層CL2作為蝕刻停止層。第二溝槽210可露出第二堆疊層K2的側表面(包括頂部導電層217的側表面217S,也包括絕緣膜204及蝕刻終止層206的側表面)及連接層CL2的上表面CL2S。連接層CL2的上表面CL2S可實質上對齊第一堆疊層K1的上表面K1S。一實施例中,蝕刻製程可移除連接層CL2的上部分,使得剩餘之連接層CL2的上表面CL2S低於第一堆疊層K1的上表面K1S。頂部導電層217可包括半導體材料,包括多晶矽,例如未摻雜的多晶矽。。 Referring to FIG. 9, a patterning process may be performed to form a second trench 210 in the second stacked layer K2 including the top conductive layer 217. The patterning process includes an etching process. The etching process for forming the second trench 210 may use the connection layer CL2 as an etching stop layer. The second trench 210 can expose the side surface of the second stacked layer K2 (including the side surface 217S of the top conductive layer 217 and the side surfaces of the insulating film 204 and the etching stop layer 206) and the upper surface CL2S of the connection layer CL2. The upper surface CL2S of the connection layer CL2 may be substantially aligned with the upper surface K1S of the first stacked layer K1. In one embodiment, the etching process can remove the upper part of the connecting layer CL2, so that the upper surface CL2S of the remaining connecting layer CL2 is lower than the upper surface K1S of the first stacked layer K1. The top conductive layer 217 may include a semiconductor material, including polysilicon, such as undoped polysilicon. .

請參照第10圖,形成閘介電層218在第二溝槽210中。閘介電層218可形成在第二堆疊層K2的側表面與上表面K2S上,及連接層CL2的上表面CL2S上。閘介電層218也可形成在蝕刻終止層106的側表面上。第一通道層CL31可形成在第二溝槽210中的閘介電層218上及第二堆疊層K2之上表面K2S上的閘介電層218上。第一通道層CL31形成在閘介電層218的側表面及上表面上。第一通道層CL31的材料可包括半導體材料。半 導體材料可包括多晶矽材料,例如未摻雜的多晶矽。一實施例中,閘介電層218為閘氧化物介電層,並鄰接第二堆疊層K2的側表面(包括頂部導電層217的側表面217S)及第一通道層CL31之間。閘氧化物介電層可包括氧化矽等。於較佳實施例中,閘介電層218僅包括單層氧化矽,換句話說閘介電層218不為複合層例如氧化矽層與氮化矽複合層。 Referring to FIG. 10, a gate dielectric layer 218 is formed in the second trench 210. The gate dielectric layer 218 may be formed on the side surface and the upper surface K2S of the second stacked layer K2, and on the upper surface CL2S of the connection layer CL2. The gate dielectric layer 218 may also be formed on the side surface of the etch stop layer 106. The first channel layer CL31 may be formed on the gate dielectric layer 218 in the second trench 210 and on the gate dielectric layer 218 on the upper surface K2S of the second stacked layer K2. The first channel layer CL31 is formed on the side surface and the upper surface of the gate dielectric layer 218. The material of the first channel layer CL31 may include a semiconductor material. half The conductive material may include polysilicon material, such as undoped polysilicon. In one embodiment, the gate dielectric layer 218 is a gate oxide dielectric layer and is adjacent to the side surface of the second stacked layer K2 (including the side surface 217S of the top conductive layer 217) and the first channel layer CL31. The gate oxide dielectric layer may include silicon oxide or the like. In a preferred embodiment, the gate dielectric layer 218 only includes a single layer of silicon oxide. In other words, the gate dielectric layer 218 is not a composite layer such as a silicon oxide layer and a silicon nitride composite layer.

請參照第11圖,可利用蝕刻製程移除位於連接層CL2的上表面CL2S及第二堆疊層K2的上表面K2S上的部分第一通道層CL31及閘介電層218,以露出連接層CL2,並同時留下位在第二堆疊層K2的側表面上另一部分的第一通道層CL31及閘介電層218。可利用非等向性蝕刻進行此移除步驟。一實施例中,蝕刻方法可包括電漿蝕刻製程,且保留在閘介電層218的側表面上的第一通道層CL31能避免閘介電層218受到蝕刻製程的損壞。蝕刻製程可停止在連接層CL2。 Referring to FIG. 11, an etching process can be used to remove part of the first channel layer CL31 and the gate dielectric layer 218 on the upper surface CL2S of the connecting layer CL2 and the upper surface K2S of the second stacked layer K2 to expose the connecting layer CL2 , While leaving the other part of the first channel layer CL31 and the gate dielectric layer 218 on the side surface of the second stacked layer K2. Anisotropic etching can be used for this removal step. In one embodiment, the etching method may include a plasma etching process, and the first channel layer CL31 remaining on the side surface of the gate dielectric layer 218 can prevent the gate dielectric layer 218 from being damaged by the etching process. The etching process can stop at the connection layer CL2.

請參照第12圖,第二通道層CL32可形成在第二堆疊層K2、閘介電層218、連接層CL2及第一通道層CL31上。第二通道層CL32形成在閘介電層218的側表面及連接層CL2的上表面上。第二通道層CL32的材料可包括半導體材料。半導體材料可包括多晶矽材料,例如未摻雜的多晶矽。 Referring to FIG. 12, the second channel layer CL32 can be formed on the second stack layer K2, the gate dielectric layer 218, the connection layer CL2, and the first channel layer CL31. The second channel layer CL32 is formed on the side surface of the gate dielectric layer 218 and the upper surface of the connection layer CL2. The material of the second channel layer CL32 may include a semiconductor material. The semiconductor material may include polysilicon material, such as undoped polysilicon.

請參照第13圖,形成絕緣材料220在第二通道層CL32上。一實施例中,絕緣材料220可包括氧化物例如氧化矽。 Referring to FIG. 13, an insulating material 220 is formed on the second channel layer CL32. In an embodiment, the insulating material 220 may include oxide such as silicon oxide.

請參照第14圖,移除部分絕緣材料220與位在第二 堆疊層K2之上表面K2S上方的部分第二通道層CL32,使絕緣材料220的頂表面與表面K2S切齊。可利用回蝕刻製程進行移除步驟。回蝕刻製程可包括化學機械研磨方法。 Please refer to Figure 14, remove part of the insulating material 220 and position the second A part of the second channel layer CL32 above the upper surface K2S of the stacked layer K2 makes the top surface of the insulating material 220 aligned with the surface K2S. An etch-back process can be used for the removal step. The etch-back process may include a chemical mechanical polishing method.

請參照第15圖,可從移除閘介電層218、第一通道層CL31、第二通道層CL32及絕緣材料220的上部分以形成從第二堆疊層K2之上表面K2S下凹的凹口216。凹口216可露出閘介電層218、第一通道層CL31、第二通道層CL32及絕緣材料220的上表面,並露出最頂端的絕緣膜204與蝕刻終止層206的側表面。第二通道結構CL3包括半導體材料,例如經摻雜的半導體材料或未經摻雜的半導體材料。一實施例中,第二通道結構CL3的材料包括多晶矽,例如經摻雜的多晶矽或未經摻雜的多晶矽。第二通道結構CL3包括第一通道層CL31及第二通道層CL32。第二通道結構CL3包括半導體材料,例如經摻雜的半導體材料或未經摻雜的半導體材料。一實施例中,第二通道結構CL3的材料包括多晶矽,例如經摻雜的多晶矽或未經摻雜的多晶矽。一實施例中,可利用具有蝕刻選擇性的蝕刻製程,以蝕刻終止層206作為蝕刻遮罩進行此移除步驟。此例中,凹口216可實質上對齊第一溝槽110/凹口116。例如凹口216在第一方向D1上的尺寸可實質上等於第一溝槽110/凹口116在第一方向D1上的尺寸。凹口216在第二方向D2上的尺寸可實質上等於第一溝槽110/凹口116在第二方向D2上的尺寸。另一實施例中,可對第14圖所示的結構進行圖案化製程以形成凹口216。此例中,凹口216的尺 寸/形狀可不同於第一溝槽110/凹口116。 Referring to FIG. 15, the upper portion of the gate dielectric layer 218, the first channel layer CL31, the second channel layer CL32, and the insulating material 220 can be removed from the upper portion of the insulating material 220 to form a concave recessed from the upper surface K2S of the second stacked layer K2.口216. The notch 216 can expose the upper surface of the gate dielectric layer 218, the first channel layer CL31, the second channel layer CL32 and the insulating material 220, and expose the side surfaces of the topmost insulating film 204 and the etching stop layer 206. The second channel structure CL3 includes a semiconductor material, such as a doped semiconductor material or an undoped semiconductor material. In one embodiment, the material of the second channel structure CL3 includes polysilicon, such as doped polysilicon or undoped polysilicon. The second channel structure CL3 includes a first channel layer CL31 and a second channel layer CL32. The second channel structure CL3 includes a semiconductor material, such as a doped semiconductor material or an undoped semiconductor material. In one embodiment, the material of the second channel structure CL3 includes polysilicon, such as doped polysilicon or undoped polysilicon. In one embodiment, an etching process with etching selectivity can be used to perform this removal step using the etching stop layer 206 as an etching mask. In this example, the notch 216 can be substantially aligned with the first groove 110/the notch 116. For example, the size of the notch 216 in the first direction D1 may be substantially equal to the size of the first groove 110/the notch 116 in the first direction D1. The size of the notch 216 in the second direction D2 may be substantially equal to the size of the first groove 110/the notch 116 in the second direction D2. In another embodiment, a patterning process can be performed on the structure shown in FIG. 14 to form the notch 216. In this example, the ruler of notch 216 The size/shape may be different from the first groove 110/notch 116.

第15A圖繪示沿第15圖所示之結構沿橫剖面P3的上視示意圖。第15B圖繪示沿第15圖所示之結構沿橫剖面P4的上視示意圖。如第15A圖及第15B圖中所示,留下的閘介電層218及第一通道層CL31具有環形狀,舉例而言為橢圓環形狀(中空)或橢圓實心狀。第二通道層CL32可具有杯子形狀,包括如第15A圖所示具有實心橢圓形狀的杯底部分,及如第15B圖所示具有環形狀如橢圓環形狀的杯壁部分。杯壁部分鄰接在杯底部分上。 FIG. 15A is a schematic top view of the structure shown in FIG. 15 along cross section P3. FIG. 15B is a schematic top view of the structure shown in FIG. 15 along cross section P4. As shown in FIGS. 15A and 15B, the remaining gate dielectric layer 218 and the first channel layer CL31 have a ring shape, for example, an elliptical ring shape (hollow) or an elliptical solid shape. The second channel layer CL32 may have a cup shape, including a cup bottom portion having a solid oval shape as shown in FIG. 15A, and a cup wall portion having a ring shape such as an elliptical ring shape as shown in FIG. 15B. The wall part of the cup abuts on the bottom part of the cup.

請參照第16圖,可形成連接層CL4以填充凹口216,並位在第二堆疊層K2的上表面K2S上。連接層CL4的材料可包括導電材料例如導體材料或半導體材料。半導體材料可包括多晶矽材料,例如N型摻雜的多晶矽。一實施例中,連接層CL4的材料可相同於連接層CL2,例如皆為摻雜的多晶矽。一實施例中,連接層CL4的主體材料可相同於第一通道結構CL1及第二通道結構CL2,差異在於第一通道結構CL1及第二通道結構CL2使用未摻雜的多晶矽。 Referring to FIG. 16, a connecting layer CL4 may be formed to fill the recess 216 and located on the upper surface K2S of the second stacked layer K2. The material of the connection layer CL4 may include a conductive material such as a conductive material or a semiconductor material. The semiconductor material may include polysilicon material, such as N-type doped polysilicon. In one embodiment, the material of the connection layer CL4 may be the same as that of the connection layer CL2, for example, both are doped polysilicon. In one embodiment, the main body material of the connection layer CL4 can be the same as the first channel structure CL1 and the second channel structure CL2. The difference is that the first channel structure CL1 and the second channel structure CL2 use undoped polysilicon.

請參照第17圖,可利用回蝕刻製程移除連接層CL4位在第二堆疊層K2上方的部分。一實施例中,回蝕刻製程可包括化學機械研磨方法或其它合適的蝕刻方法。此回蝕刻製程可使得結構具有一平坦的上表面。 Referring to FIG. 17, an etch-back process can be used to remove the portion of the connection layer CL4 located above the second stacked layer K2. In an embodiment, the etch-back process may include a chemical mechanical polishing method or other suitable etching methods. This etch-back process can make the structure have a flat upper surface.

第17A圖繪示沿第17圖所示之結構沿橫剖面P5的 上視示意圖。如第17A圖中所示,凹口216中的連接層CL4具有實心的橢圓形狀。 Figure 17A shows the cross-section P5 along the structure shown in Figure 17 Top view schematic. As shown in FIG. 17A, the connection layer CL4 in the recess 216 has a solid oval shape.

請參照第18圖,進行一圖案化製程以形成開孔320,從而堆疊結構K分割為兩分開的堆疊部分。開孔320將第一通道結構CL1、連接層CL2、第二通道結構CL3及連接層CL4分割為互相分開的兩個部分。詳細而言,開孔320將橢圓形狀的結構分割為兩個半環狀的結構(C型)。用以形成開孔320的圖案化製程亦同時將第一堆疊層K1的導電層(包括底導電層109及導電層111)及頂部導電層217圖案化成為閘電極。閘電極包括底導電層109經圖案化後所形成的底部電極,其可做為底反轉閘電極IG。閘電極也包括導電層111經圖案化後所形成的中間電極,其可做為字元線WL。此外,閘電極也包括頂部導電層217經圖案化後所形成的頂部電極,其可做為選擇線,選擇線包括互相分開的串列選擇線SSL及接地選擇線GSL。一實施例中,鄰接串列選擇線SSL/接地選擇線GSL的閘介電層218為單層結構的氧化矽膜,例如單層氧化矽膜,因此在進行記憶體抹除步驟時,能避免電荷儲存在閘介電層218中而干擾串列選擇線SSL/接地選擇線GSL的問題。 Referring to FIG. 18, a patterning process is performed to form the opening 320, so that the stacked structure K is divided into two separate stacked parts. The opening 320 divides the first channel structure CL1, the connection layer CL2, the second channel structure CL3, and the connection layer CL4 into two separate parts. In detail, the opening 320 divides the elliptical structure into two semi-annular structures (C-shaped). The patterning process used to form the opening 320 also simultaneously pattern the conductive layer (including the bottom conductive layer 109 and the conductive layer 111) and the top conductive layer 217 of the first stacked layer K1 into gate electrodes. The gate electrode includes a bottom electrode formed by patterning the bottom conductive layer 109, which can be used as a bottom inversion gate electrode IG. The gate electrode also includes an intermediate electrode formed by patterning the conductive layer 111, which can be used as a word line WL. In addition, the gate electrode also includes a top electrode formed by patterning the top conductive layer 217, which can be used as a selection line. The selection line includes a serial selection line SSL and a ground selection line GSL which are separated from each other. In one embodiment, the gate dielectric layer 218 adjacent to the serial select line SSL/ground select line GSL is a single-layer silicon oxide film, such as a single-layer silicon oxide film, so that it can be avoided during the memory erasing step. The charge is stored in the gate dielectric layer 218 and interferes with the problem of the serial selection line SSL/ground selection line GSL.

通道結構電性耦接閘電極,並位在閘電極的側表面上。通道結構包括第一通道結構CL1、及第二通道結構CL3。第二通道結構CL3位在第一通道結構CL1的上表面上。連接層CL2位於第一通道結構LL1及第二通道結構CL3之間。舉例來說, 連接層CL2鄰接在第一通道結構CL1的第一環形通道層CL1R及第二通道結構CL3的第二底通道層CL32B之間。第一通道結構CL1及/或第二通道結構CL3為環形狀。 The channel structure is electrically coupled to the gate electrode and is located on the side surface of the gate electrode. The channel structure includes a first channel structure CL1 and a second channel structure CL3. The second channel structure CL3 is located on the upper surface of the first channel structure CL1. The connection layer CL2 is located between the first channel structure LL1 and the second channel structure CL3. for example, The connecting layer CL2 is adjacent to the first annular channel layer CL1R of the first channel structure CL1 and the second bottom channel layer CL32B of the second channel structure CL3. The first channel structure CL1 and/or the second channel structure CL3 have a ring shape.

電荷儲存層112位在堆疊結構K的一部分內表面及第一通道結構CL1之間。部分的電荷儲存層112位於底反轉閘電極IG(底部電極)與字元線WL(中間電極)對應的側表面。閘介電層218位在堆疊結構K的另一部分內表面及第二通道結構CL3之間。部分的閘介電層218位於串列選擇線SSL/接地選擇線GSL(頂部電極)對應的側表面。蝕刻終止層106夾設在串列選擇線SSL/接地選擇線GSL(頂部電極)與字元線WL(中間電極)的至少一個之間。 The charge storage layer 112 is located between a portion of the inner surface of the stack structure K and the first channel structure CL1. Part of the charge storage layer 112 is located on the side surface of the bottom inversion gate electrode IG (bottom electrode) corresponding to the word line WL (middle electrode). The gate dielectric layer 218 is located between another part of the inner surface of the stacked structure K and the second channel structure CL3. Part of the gate dielectric layer 218 is located on the side surface corresponding to the serial selection line SSL/ground selection line GSL (top electrode). The etch stop layer 106 is sandwiched between at least one of the series selection line SSL/ground selection line GSL (top electrode) and the word line WL (middle electrode).

第18A圖繪示沿第18圖所示之結構沿橫剖面P1的上視示意圖。第18B圖繪示沿第18圖所示之結構沿橫剖面P6的上視示意圖。第18C圖繪示沿第18圖所示之結構沿橫剖面P7的上視示意圖。請參照第18圖、第18A圖、第18B圖及第18C圖,第一通道結構CL1包括一第一底通道層CL1B及二第一環形通道層CL1R。第一環形通道層CL1R彼此分開且鄰接在第一底通道層CL1B的兩端上。第一底通道層CL1B位在底反轉閘電極IG的上表面109S2及側表面109S1上。第一環形通道層CL1R鄰接在第一底通道層CL1B上,並藉由開孔320互相分開。第一環形通道層CL1R的高度(或第三方向D3的尺寸)可由開孔320的深度定義。第一底通道層CL1B可定義為第一通道結構CL1位 在開孔320之底表面下方的部分。一實施例中,第一底通道層CL1B未被開孔320分開而維持橢圓形狀的杯底部分。另一實施例中,開孔320可將第一底通道層CL1B分開。第一環形通道層CL1R較佳為垂直第一底通道層CL1B。第一方向D1、第二方向D2及第三方向D3可彼此不同。第一方向D1、第二方向D2及第三方向D3可實質上互相垂直。舉例來說,第一方向D1可為X方向,第二方向D2可為Y方向,第三方向D3可為Z方向。 FIG. 18A is a schematic top view of the structure shown in FIG. 18 along the cross section P1. FIG. 18B is a schematic top view of the structure shown in FIG. 18 along cross section P6. FIG. 18C is a schematic top view of the structure shown in FIG. 18 along cross section P7. Referring to FIG. 18, FIG. 18A, FIG. 18B, and FIG. 18C, the first channel structure CL1 includes a first bottom channel layer CL1B and two first annular channel layers CL1R. The first annular channel layers CL1R are separated from each other and adjacent to both ends of the first bottom channel layer CL1B. The first bottom channel layer CL1B is located on the upper surface 109S2 and the side surface 109S1 of the bottom inversion gate electrode IG. The first annular channel layer CL1R is adjacent to the first bottom channel layer CL1B and separated from each other by the opening 320. The height (or the size of the third direction D3) of the first annular channel layer CL1R can be defined by the depth of the opening 320. The first bottom channel layer CL1B can be defined as the first channel structure CL1 bit The part below the bottom surface of the opening 320. In one embodiment, the first bottom channel layer CL1B is not divided by the opening 320 and maintains an oval-shaped bottom portion of the cup. In another embodiment, the opening 320 may separate the first bottom channel layer CL1B. The first annular channel layer CL1R is preferably perpendicular to the first bottom channel layer CL1B. The first direction D1, the second direction D2, and the third direction D3 may be different from each other. The first direction D1, the second direction D2, and the third direction D3 may be substantially perpendicular to each other. For example, the first direction D1 may be the X direction, the second direction D2 may be the Y direction, and the third direction D3 may be the Z direction.

第18D圖繪示沿第18圖所示之結構沿橫剖面P2的上視示意圖。請參照第18圖及第18D圖,兩個藉由開孔320分開的連接層CL2分別在第一通道結構CL1之互相分開的第一環形通道層CL1R上表面CL1S2上。互相分開的兩個連接層CL2皆具有實心半環形狀,且平側表面是互相面對。 FIG. 18D is a schematic top view of the structure shown in FIG. 18 along the cross section P2. Referring to FIGS. 18 and 18D, two connection layers CL2 separated by the opening 320 are respectively on the upper surface CL1S2 of the first annular channel layer CL1R separated from each other of the first channel structure CL1. The two connecting layers CL2 separated from each other have a solid half-ring shape, and the flat side surfaces face each other.

第18E圖繪示沿第18圖所示之結構沿橫剖面P3的上視示意圖。第18F圖繪示沿第18圖所示之結構沿橫剖面P4的上視示意圖。請參照第18圖、第18E圖及第18F圖,第一通道層CL31具有環形狀。第二通道層CL32可包括二第二底通道層CL32B及二個第二環形通道層CL32R。二個第二底通道層CL32B彼此分開。第二底通道層CL32B為實心半環狀,例如實心半橢圓狀。二個第二環形通道層CL32R分別鄰接在二第二底通道層CL32B相互遠離的兩端上。第一通道層CL31位於第二通道層CL32與堆疊結構K之間。第二環形通道層CL32R為中空半環形狀,例如中空半橢圓狀。 FIG. 18E is a schematic top view of the structure shown in FIG. 18 along the cross section P3. FIG. 18F is a schematic top view of the structure shown in FIG. 18 along cross section P4. Referring to FIG. 18, FIG. 18E, and FIG. 18F, the first channel layer CL31 has a ring shape. The second channel layer CL32 may include two second bottom channel layers CL32B and two second ring-shaped channel layers CL32R. The two second bottom channel layers CL32B are separated from each other. The second bottom channel layer CL32B has a solid semi-circular shape, such as a solid semi-elliptical shape. The two second annular channel layers CL32R are respectively adjacent to the two second bottom channel layers CL32B at opposite ends of each other. The first channel layer CL31 is located between the second channel layer CL32 and the stacked structure K. The second annular channel layer CL32R has a hollow semi-ring shape, for example, a hollow semi-elliptical shape.

第18G圖繪示沿第18圖所示之結構沿橫剖面P5的上視示意圖。請參照第18圖及第18G圖,藉由開孔320分開的兩個連接層CL4是位在第二通道結構CL3的第二環形通道層CL32R的上表面上。連接層CL4具有半圓形狀,且平側表面是互相面對。 Fig. 18G is a schematic top view of the structure shown in Fig. 18 along cross section P5. Referring to FIGS. 18 and 18G, the two connection layers CL4 separated by the opening 320 are located on the upper surface of the second annular channel layer CL32R of the second channel structure CL3. The connection layer CL4 has a semicircular shape, and the flat side surfaces face each other.

於一實施例中,連接層CL2在第一方向D1上的徑向厚度是大於第一環形通道層CL1R在第一方向D1上的徑向厚度,並大於第二環形通道層CL32R在第一方向D1上的徑向厚度。 In one embodiment, the radial thickness of the connecting layer CL2 in the first direction D1 is greater than the radial thickness of the first annular channel layer CL1R in the first direction D1, and greater than the radial thickness of the second annular channel layer CL32R in the first direction D1. Radial thickness in direction D1.

請參照第19圖,利用絕緣牆322以填充開孔320。一實施例中,絕緣牆322可包括氧化物例如氧化矽。 Please refer to FIG. 19, the insulating wall 322 is used to fill the opening 320. In one embodiment, the insulating wall 322 may include oxide such as silicon oxide.

請參照第20圖,位元線BL及共同源極線CSL可形成在堆疊結構K的上方,且位元線BL藉由導電柱300、304與導電層302與通道結構電性連接,共同源極線CSL藉由導電柱300與通道結構電性連接,從而形成NAND記憶體串列。然導電柱300、304與導電層302可依照實際需求設置,本發明並不以此為限。NAND記憶體串列的記憶胞定義在第一通道結構CL1及用字元線WL之間。二個第一環形通道層CL1R具有一第一距離N1。二個第二環形通道層CL32R具有一第二距離N2。第一距離N1大於第二距離N2。 Referring to FIG. 20, the bit line BL and the common source line CSL can be formed above the stacked structure K, and the bit line BL is electrically connected to the channel structure through the conductive pillars 300, 304 and the conductive layer 302, and the common source The pole line CSL is electrically connected to the channel structure through the conductive pillar 300 to form a NAND memory series. However, the conductive pillars 300 and 304 and the conductive layer 302 can be arranged according to actual requirements, and the present invention is not limited thereto. The memory cells of the NAND memory string are defined between the first channel structure CL1 and the word line WL. The two first annular channel layers CL1R have a first distance N1. The two second annular channel layers CL32R have a second distance N2. The first distance N1 is greater than the second distance N2.

綜上所述,雖然本發明已以實施例揭露如上,然其並非用以限定本發明。本發明所屬技術領域中具有通常知識者, 在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定者為準。 In summary, although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention. Those who have general knowledge in the technical field of the present invention, Various changes and modifications can be made without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention shall be subject to those defined by the attached patent application scope.

300、304:導電柱 300, 304: conductive pillar

302:導電層 302: conductive layer

CL1:第一通道結構 CL1: The first channel structure

CL2:連接層 CL2: Connection layer

CL3:第二通道結構 CL3: Second channel structure

CL31:第一通道層 CL31: The first channel layer

CL32:第二通道層 CL32: Second channel layer

CL4:第三通道結構 CL4: Third channel structure

CSL:共同源極線 CSL: Common Source Line

D1:第一方向 D1: First direction

D2:第二方向 D2: second direction

D3:第三方向 D3: Third party

GSL:接地選擇線 GSL: Ground selection line

IG:底反轉閘電極 IG: bottom inversion gate electrode

K:堆疊結構 K: Stacked structure

K1:第一堆疊層 K1: The first stacked layer

K2:第二堆疊層 K2: second stacked layer

N1:第一距離 N1: first distance

N2:第二距離 N2: second distance

WL:字元線 WL: Character line

SSL:串列選擇線 SSL: Serial selection line

Claims (9)

一種記憶體裝置,包括:一堆疊結構,位於一基底上,並包括交錯堆疊的數個閘電極與數個絕緣膜;及一通道結構,電性耦接該些閘電極,並位在該些閘電極的側表面上,其中該通道結構包括:一第一通道結構,包括一第一底通道層及二個第一環形通道層,該二個第一環形通道層彼此分開且鄰接在該第一底通道層兩端上;及一第二通道結構,位在該第一通道結構的一上表面上,其中該第一通道結構及/或該第二通道結構為環形。 A memory device includes: a stacked structure on a substrate and including a plurality of gate electrodes and a plurality of insulating films stacked alternately; and a channel structure electrically coupled to the gate electrodes and located on the On the side surface of the gate electrode, the channel structure includes: a first channel structure, including a first bottom channel layer and two first ring-shaped channel layers, the two first ring-shaped channel layers are separated from each other and adjacent to each other On both ends of the first bottom channel layer; and a second channel structure located on an upper surface of the first channel structure, wherein the first channel structure and/or the second channel structure are ring-shaped. 如申請專利範圍第1項所述之記憶體裝置,其中該第二通道結構包括:一第一通道層;及一第二通道層,且該第二通道層包括:二第二底通道層,該二第二底通道層彼此分開;及二個第二環形通道層,分別鄰接在該二第二底通道層相互遠離的兩端上,且該第一通道層位於該第二通道層與該堆疊結構之間。 As for the memory device described in claim 1, wherein the second channel structure includes: a first channel layer; and a second channel layer, and the second channel layer includes: two second bottom channel layers, The two second bottom channel layers are separated from each other; and two second ring-shaped channel layers are respectively adjacent to the two second bottom channel layers at opposite ends of each other, and the first channel layer is located between the second channel layer and the Between stacked structures. 如申請專利範圍第2項所述之記憶體裝置,其中該二第一環形形通道層具有一第一距離,該二第二環形形通道層具有一第二距離,其中該第一距離大於該第二距離。 As for the memory device described in claim 2, wherein the two first annular channel layers have a first distance, and the two second annular channel layers have a second distance, wherein the first distance is greater than The second distance. 如申請專利範圍第2項所述之記憶體裝置,其中該第一通道層、該二第二環形通道層為中空環狀,該二第二底通道層為實心半橢圓狀。 As for the memory device described in item 2 of the scope of patent application, the first channel layer and the two second annular channel layers are hollow ring-shaped, and the two second bottom channel layers are solid semi-elliptical. 如申請專利範圍第1項所述之記憶體裝置,更包括一連接層,位於該第一通道結構及該第二通道結構之間。 The memory device described in item 1 of the scope of the patent application further includes a connecting layer located between the first channel structure and the second channel structure. 如申請專利範圍第5項所述之記憶體裝置,其中該第一通道結構與該第二通道結構的材料包括經摻雜的半導體材料或未經摻雜的半導體材料,該連接層的材料包括經摻雜的半導體材料。 The memory device according to claim 5, wherein the material of the first channel structure and the second channel structure includes a doped semiconductor material or an undoped semiconductor material, and the material of the connection layer includes Doped semiconductor material. 如申請專利範圍第1項所述之記憶體裝置,更包括:一電荷儲存層,位在該堆疊結構的一部分內表面及該第一通道結構之間;及一閘介電層,位在該堆疊結構的另一部分內表面及該第二通道結構之間。 The memory device described in claim 1 further includes: a charge storage layer located between a portion of the inner surface of the stacked structure and the first channel structure; and a gate dielectric layer located on the Between another part of the inner surface of the stacked structure and the second channel structure. 如申請專利範圍第7項所述之記憶體裝置,其中該些閘電極包括一底部電極、一複數個中間電極及一頂部電極之堆疊,且部分的該電荷儲存層位於該底部電極與該些中 間電極對應的側表面,部分的該閘介電層位於該頂部電極對應的側表面。 As for the memory device described in claim 7, wherein the gate electrodes include a stack of a bottom electrode, a plurality of middle electrodes, and a top electrode, and part of the charge storage layer is located between the bottom electrode and the in Part of the gate dielectric layer is located on the side surface corresponding to the top electrode. 如申請專利範圍第7項所述之記憶體裝置,其中更包括一蝕刻終止層,夾設在該頂部電極與該些中間電極的至少一個之間。 The memory device described in claim 7 further includes an etching stop layer sandwiched between the top electrode and at least one of the middle electrodes.
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