TWI796371B - Active energy ray curable composition, cured product and film using same - Google Patents
Active energy ray curable composition, cured product and film using same Download PDFInfo
- Publication number
- TWI796371B TWI796371B TW107136353A TW107136353A TWI796371B TW I796371 B TWI796371 B TW I796371B TW 107136353 A TW107136353 A TW 107136353A TW 107136353 A TW107136353 A TW 107136353A TW I796371 B TWI796371 B TW I796371B
- Authority
- TW
- Taiwan
- Prior art keywords
- active energy
- energy ray
- meth
- acrylate
- curable composition
- Prior art date
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- 125000002723 alicyclic group Chemical group 0.000 claims abstract description 19
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- 150000003464 sulfur compounds Chemical class 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical compound CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- FCGQIZKUTMUWDC-UHFFFAOYSA-M trimethyl(propyl)azanium;bromide Chemical compound [Br-].CCC[N+](C)(C)C FCGQIZKUTMUWDC-UHFFFAOYSA-M 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- FEPMHVLSLDOMQC-UHFFFAOYSA-N virginiamycin-S1 Natural products CC1OC(=O)C(C=2C=CC=CC=2)NC(=O)C2CC(=O)CCN2C(=O)C(CC=2C=CC=CC=2)N(C)C(=O)C2CCCN2C(=O)C(CC)NC(=O)C1NC(=O)C1=NC=CC=C1O FEPMHVLSLDOMQC-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
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- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
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- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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Abstract
本發明提供一種活性能量線硬化性組合物及使用其的膜，所述活性能量線硬化性組合物的特徵在於含有：活性能量線硬化性化合物（A）、具有脂環結構及四級銨鹽的樹脂（B）、具有四級銨鹽且不具有脂環結構的化合物（C）及有機溶劑（D）。所述樹脂（B）與化合物（C）的質量比[（B）/（C）]優選為5/95～40/60的範圍內。所述樹脂（B）與化合物（C）的合計調配量相對於所述活性能量線硬化性化合物（A）100質量份而優選為1質量份～10質量份的範圍內。本發明所欲解決的課題在於提供可形成兼具優異的抗靜電性及耐滲出性的硬塗層的活性能量線硬化性組合物及使用其的膜。The present invention provides an active energy ray-curable composition characterized by containing an active energy ray-curable compound (A), having an alicyclic structure, and a quaternary ammonium salt, and a film using the same. Resin (B), compound (C) with quaternary ammonium salt and no alicyclic structure, and organic solvent (D). The mass ratio [(B)/(C)] of the resin (B) to the compound (C) is preferably within a range of 5/95 to 40/60. The total compounding amount of the resin (B) and the compound (C) is preferably within a range of 1 to 10 parts by mass relative to 100 parts by mass of the active energy ray-curable compound (A). The problem to be solved by the present invention is to provide an active energy ray curable composition capable of forming a hard coat layer having both excellent antistatic properties and bleeding resistance, and a film using the same.
Description
本發明關於一種活性能量線硬化性組合物及使用其的膜。The present invention relates to an active energy ray curable composition and a film using the same.
各種樹脂膜可用於液晶顯示器（Liquid crystal display，LCD）、有機電致發光顯示器（Organic Electroluminescent Display，OLED）、電漿顯示器（Plasma Diasplay Panel，PDP）等平板顯示器（Flat Panel Display，FPD）表面的防刮傷用膜、汽車的內外裝潢用裝飾膜（片）、窗用的低反射膜或熱射線截止膜等各種用途中。然而，由於樹脂膜表面柔軟且耐擦傷性低，因此為了彌補所述缺點，通常進行將包含紫外線（ultraviolet，UV）硬化性組合物等的硬塗劑塗敷於膜表面上並使其硬化而將硬塗層設置於膜表面上。若概述設置硬塗層的步驟，則為從卷成輥狀的膜坯材輸送至塗敷機，塗敷硬塗劑，利用紫外線照射進行硬化而形成硬塗層後，再次捲取成輥狀。Various resin films can be used on the surface of Flat Panel Display (FPD) such as Liquid crystal display (LCD), Organic Electroluminescent Display (OLED), Plasma Diasplay Panel (PDP), etc. Anti-scratch films, decorative films (sheets) for interior and exterior of automobiles, low-reflection films for windows, and heat ray cut-off films. However, since the surface of the resin film is soft and has low scratch resistance, in order to compensate for the disadvantages, a hard coating agent containing an ultraviolet (ultraviolet, UV) curable composition or the like is usually applied to the surface of the film and hardened. A hard coat layer is provided on the surface of the film. Outlining the steps of forming a hard coat layer, the film material rolled into a roll is transported to a coating machine, coated with a hard coat agent, hardened by ultraviolet radiation to form a hard coat layer, and wound up into a roll shape again. .
在所述捲取步驟中，藉由膜彼此的摩擦而在膜表面上產生靜電，因此再加工時，在將膜自輥抽出時會有膜彼此黏附的問題、或由於靜電而灰塵等變得容易附著於膜表面上的問題。另外，在將所述膜用於液晶顯示器等的情況下，也會有因產生的靜電而顯示器發生誤動作的問題。In the winding-up step, static electricity is generated on the surface of the film by friction between the films. Therefore, during reprocessing, when the film is pulled out from the roll, there is a problem that the films stick to each other, or dust, etc. become dirty due to static electricity. The problem of easy adhesion on the surface of the film. Moreover, when the said film is used for a liquid crystal display etc., there also exists a problem that a display malfunctions by the static electricity which generate|occur|produces.
為了抑制所述膜表面上產生靜電，通常進行在硬塗劑中調配抗靜電劑的手法。例如提出了將具有聚氧乙烯鏈與四級銨鹽的化合物作為抗靜電劑而調配於硬塗劑中的方法（例如，參照專利文獻1）。In order to suppress the generation of static electricity on the surface of the film, a method of blending an antistatic agent into the hard coating agent is generally performed. For example, a method of compounding a compound having a polyoxyethylene chain and a quaternary ammonium salt in a hard coating agent as an antistatic agent has been proposed (for example, refer to Patent Document 1).
另外，提出了將以具有四級銨鹽的聚合性單體作為原料的兩種共聚物作為抗靜電劑而調配於硬塗劑中的方法（例如，參照專利文獻2）。In addition, a method has been proposed in which two types of copolymers made of a polymerizable monomer having a quaternary ammonium salt as a raw material are mixed into a hard coating agent as an antistatic agent (for example, refer to Patent Document 2).
然而，調配了這些抗靜電劑的硬塗劑的抗靜電性能並不充分。進而，在調配大量的抗靜電劑的情況下，抗靜電性能提高，但有在濕熱條件下使用後發生抗靜電劑的滲出的問題。 [現有技術文獻] [專利文獻]However, the antistatic performance of the hard coating agent which mix|blended these antistatic agents is not sufficient. Furthermore, when a large amount of antistatic agent is blended, the antistatic performance is improved, but there is a problem that bleeding of the antistatic agent occurs after use under hot and humid conditions. [Prior Art Documents] [Patent Documents]
[專利文獻1]日本專利特開2004-143303號公報 [專利文獻2]日本專利特開2004-123924號公報[Patent Document 1] Japanese Patent Laid-Open No. 2004-143303 [Patent Document 2] Japanese Patent Laid-Open No. 2004-123924
[發明所欲解決之問題] 本發明所欲解決的課題在於提供可形成兼具優異的抗靜電性及耐滲出性的硬塗層的活性能量線硬化性組合物及使用其的膜。 [解決問題之手段][Problems to be Solved by the Invention] The problem to be solved by the present invention is to provide an active energy ray-curable composition capable of forming a hard coat layer having excellent antistatic properties and bleeding resistance, and a film using the same. [means to solve the problem]
本發明提供一種活性能量線硬化性組合物及使用其的膜，所述活性能量線硬化性組合物的特徵在於含有：活性能量線硬化性化合物（A）、具有脂環結構及四級銨鹽的樹脂（B）、具有四級銨鹽且不具有脂環結構的化合物（C）及有機溶劑（D）。 [發明的效果]The present invention provides an active energy ray-curable composition characterized by containing an active energy ray-curable compound (A), having an alicyclic structure, and a quaternary ammonium salt, and a film using the same. Resin (B), compound (C) with quaternary ammonium salt and no alicyclic structure, and organic solvent (D). [Effect of the invention]
本發明的活性能量線硬化性組合物藉由塗敷於膜表面上並進行硬化，可形成具有優異的抗靜電性及鉛筆硬度的硬塗層。因此，本發明的活性能量線硬化性組合物的硬化塗膜可抑制在膜表面上產生靜電。因而，可對各種膜賦予防止黏附、防止因靜電造成的灰塵等的附著等功能。因此，具有本發明的活性能量線硬化性組合物的硬化塗膜的膜由於在捲取成輥狀時、從輥抽出時均能避免黏附、灰塵等的附著等問題，因此可提供之後的操作性優異的膜。進而，本發明的活性能量線硬化性組合物的硬化塗膜具有優異的耐滲出性，即便在濕熱條件下使用後也不會發生抗靜電劑的滲出，抗靜電性的變化也少。The active energy ray-curable composition of the present invention can form a hard coat layer having excellent antistatic properties and pencil hardness by applying and curing the active energy ray-curable composition on a film surface. Therefore, the cured coating film of the active energy ray-curable composition of the present invention can suppress generation of static electricity on the film surface. Therefore, functions such as anti-adhesion and anti-adhesion of dust due to static electricity can be imparted to various films. Therefore, since the film having the cured coating film of the active energy ray-curable composition of the present invention can avoid problems such as sticking and adhesion of dust when being wound up into a roll and when it is drawn out from the roll, it can be used in subsequent operations. excellent film. Furthermore, the cured coating film of the active energy ray-curable composition of the present invention has excellent bleed-out resistance, does not bleed out the antistatic agent even after use under hot and humid conditions, and has little change in antistatic property.
另外，具有包含本發明的活性能量線硬化性組合物的硬化塗膜的硬塗層的膜可較佳地用作液晶顯示器（LCD）、有機EL顯示器（OLED）、電漿顯示器（PDP）等平板顯示器（FPD）中使用的光學膜。進而，由於在用於這些用途時也具有優異的抗靜電性，因此可抑制灰塵等的附著。進而，在將所述膜用於液晶顯示器等的情況下，也可防止因產生的靜電造成的顯示器的誤動作。In addition, a film having a hard coat layer comprising a cured coating film of the active energy ray-curable composition of the present invention can be preferably used as a liquid crystal display (LCD), an organic EL display (OLED), a plasma display (PDP), etc. Optical films used in flat panel displays (FPD). Furthermore, since it has excellent antistatic property even when it is used for these uses, adhesion of dust etc. can be suppressed. Furthermore, when the said film is used for a liquid crystal display etc., the malfunction of a display by the static electricity which generate|occur|produces can also be prevented.
本發明的活性能量線硬化性組合物含有：活性能量線硬化性化合物（A）、具有脂環結構及四級銨鹽的樹脂（B）、具有四級銨鹽且不具有脂環結構的化合物（C）及有機溶劑（D）。The active energy ray-curable composition of the present invention contains: an active energy ray-curable compound (A), a resin (B) having an alicyclic structure and a quaternary ammonium salt, and a compound having a quaternary ammonium salt and not having an alicyclic structure (C) and organic solvent (D).
作為所述活性能量線硬化性化合物（A），例如可使用多官能(甲基)丙烯酸酯、氨基甲酸酯(甲基)丙烯酸酯等。As the active energy ray-curing compound (A), for example, polyfunctional (meth)acrylates, urethane (meth)acrylates, and the like can be used.
作為所述多官能(甲基)丙烯酸酯，例如可列舉：1,4-丁二醇二(甲基)丙烯酸酯、3-甲基-1,5-戊二醇二(甲基)丙烯酸酯、1,6-己二醇二(甲基)丙烯酸酯、新戊二醇二(甲基)丙烯酸酯、2-甲基-1,8-辛二醇二(甲基)丙烯酸酯、2-丁基-2-乙基-1,3-丙二醇二(甲基)丙烯酸酯、三環癸烷二甲醇二(甲基)丙烯酸酯、乙二醇二(甲基)丙烯酸酯、二乙二醇二(甲基)丙烯酸酯、三乙二醇二(甲基)丙烯酸酯、二丙二醇二(甲基)丙烯酸酯、三丙二醇二(甲基)丙烯酸酯等二元醇的二(甲基)丙烯酸酯、聚乙二醇二(甲基)丙烯酸酯、聚丙二醇二(甲基)丙烯酸酯、三(2-羥基乙基)異三聚氰酸酯的二(甲基)丙烯酸酯、對1莫耳新戊二醇加成4莫耳以上的環氧乙烷或環氧丙烷而得的二醇的二(甲基)丙烯酸酯、對1莫耳雙酚A加成2莫耳的環氧乙烷或環氧丙烷而得的二醇的二(甲基)丙烯酸酯、三羥甲基丙烷三(甲基)丙烯酸酯、環氧乙烷改性三羥甲基丙烷三(甲基)丙烯酸酯、環氧丙烷改性三羥甲基丙烷三(甲基)丙烯酸酯、二-三羥甲基丙烷三(甲基)丙烯酸酯、二-三羥甲基丙烷四(甲基)丙烯酸酯、三(2-(甲基)丙烯醯氧基乙基)異三聚氰酸酯、甘油三(甲基)丙烯酸酯、季戊四醇三(甲基)丙烯酸酯、季戊四醇四(甲基)丙烯酸酯、二季戊四醇三(甲基)丙烯酸酯、二季戊四醇四(甲基)丙烯酸酯、二季戊四醇五(甲基)丙烯酸酯、二季戊四醇六(甲基)丙烯酸酯、三季戊四醇七(甲基)丙烯酸酯、三季戊四醇八(甲基)丙烯酸酯、聚季戊四醇聚(甲基)丙烯酸酯等。這些化合物可單獨使用，也可並用兩種以上。Examples of the polyfunctional (meth)acrylate include: 1,4-butanediol di(meth)acrylate, 3-methyl-1,5-pentanediol di(meth)acrylate , 1,6-hexanediol di(meth)acrylate, neopentyl glycol di(meth)acrylate, 2-methyl-1,8-octanediol di(meth)acrylate, 2- Butyl-2-ethyl-1,3-propanediol di(meth)acrylate, tricyclodecane dimethanol di(meth)acrylate, ethylene glycol di(meth)acrylate, diethylene glycol Di(meth)acrylic acid based on glycols such as di(meth)acrylate, triethylene glycol di(meth)acrylate, dipropylene glycol di(meth)acrylate, tripropylene glycol di(meth)acrylate, etc. ester, polyethylene glycol di(meth)acrylate, polypropylene glycol di(meth)acrylate, tris(2-hydroxyethyl)isocyanurate di(meth)acrylate, for 1 Mo Di(meth)acrylate of diol obtained by adding 4 moles or more of ethylene oxide or propylene oxide to neopentyl glycol, 2 moles of ethylene oxide added to 1 mole of bisphenol A Diol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, ethylene oxide modified trimethylolpropane tri(meth)acrylate , Propylene oxide modified trimethylolpropane tri(meth)acrylate, di-trimethylolpropane tri(meth)acrylate, di-trimethylolpropane tetra(meth)acrylate, three (2-(Meth)acryloxyethyl)isocyanurate, Glyceryl Tri(meth)acrylate, Pentaerythritol Tri(meth)acrylate, Pentaerythritol Tetra(meth)acrylate, Dipentaerythritol Tri(meth)acrylate, dipentaerythritol tetra(meth)acrylate, dipentaerythritol penta(meth)acrylate, dipentaerythritol hexa(meth)acrylate, tripentaerythritol hepta(meth)acrylate, tripentaerythritol Octa(meth)acrylate, polypentaerythritol poly(meth)acrylate, etc. These compounds may be used alone or in combination of two or more.
所述氨基甲酸酯(甲基)丙烯酸酯可使用聚異氰酸酯與具有羥基的(甲基)丙烯酸酯的反應物。As the urethane (meth)acrylate, a reactant of a polyisocyanate and a (meth)acrylate having a hydroxyl group can be used.
作為所述聚異氰酸酯，可列舉脂肪族聚異氰酸酯與芳香族聚異氰酸酯，但就可減少本發明的活性能量線硬化性組合物的硬化塗膜的著色的方面而言，優選為脂肪族聚異氰酸酯。Examples of the polyisocyanate include aliphatic polyisocyanate and aromatic polyisocyanate, but aliphatic polyisocyanate is preferred because it can reduce coloring of the cured coating film of the active energy ray-curable composition of the present invention.
所述脂肪族聚異氰酸酯是除了異氰酸酯基以外的部位為由脂肪族烴構成的化合物。作為所述脂肪族聚異氰酸酯的具體例，可列舉：六亞甲基二異氰酸酯、賴氨酸二異氰酸酯、賴氨酸三異氰酸酯等脂肪族聚異氰酸酯；降冰片烷二異氰酸酯、異佛爾酮二異氰酸酯、亞甲基雙(4-環己基異氰酸酯)、1,3-雙(異氰酸甲基)環己烷、2-甲基-1,3-二異氰酸環己烷、2-甲基-1,5-二異氰酸環己烷等脂環式聚異氰酸酯等。另外，將所述脂肪族聚異氰酸酯或脂環式聚異氰酸酯三聚化而成的三聚物也可用作所述脂肪族聚異氰酸酯。另外，這些脂肪族聚異氰酸酯可使用一種，也可並用兩種以上。The said aliphatic polyisocyanate is a compound which consists of an aliphatic hydrocarbon in the part other than an isocyanate group. Specific examples of the aliphatic polyisocyanate include: aliphatic polyisocyanates such as hexamethylene diisocyanate, lysine diisocyanate, and lysine triisocyanate; norbornane diisocyanate, isophorone diisocyanate, and the like; , Methylene bis(4-cyclohexyl isocyanate), 1,3-bis(isocyanatomethyl)cyclohexane, 2-methyl-1,3-diisocyanatocyclohexane, 2-methyl - Alicyclic polyisocyanates such as 1,5-diisocyanatocyclohexane, etc. Moreover, the trimer which trimerized the said aliphatic polyisocyanate or alicyclic polyisocyanate can also be used as the said aliphatic polyisocyanate. In addition, these aliphatic polyisocyanates may be used alone or in combination of two or more.
在所述脂肪族聚異氰酸酯中，為了提高塗膜的耐擦傷性，脂肪族聚異氰酸酯中優選為作為直鏈脂肪族烴的二異氰酸酯的六亞甲基二異氰酸酯、作為脂環式二異氰酸酯的降冰片烷二異氰酸酯、異佛爾酮二異氰酸酯。Among the aliphatic polyisocyanates, in order to improve the scratch resistance of the coating film, among the aliphatic polyisocyanates, hexamethylene diisocyanate which is a diisocyanate of linear aliphatic hydrocarbons, hexamethylene diisocyanate which is a diisocyanate of alicyclic diisocyanate, and Bornane diisocyanate, isophorone diisocyanate.
所述(甲基)丙烯酸酯為具有羥基與(甲基)丙烯醯基的化合物。作為所述(甲基)丙烯酸酯的具體例，可列舉：(甲基)丙烯酸2-羥基乙酯、(甲基)丙烯酸2-羥基丙酯、(甲基)丙烯酸2-羥基丁酯、(甲基)丙烯酸4-羥基丁酯、1,5-戊二醇單(甲基)丙烯酸酯、1,6-己二醇單(甲基)丙烯酸酯、新戊二醇單(甲基)丙烯酸酯、羥基特戊酸新戊二醇單(甲基)丙烯酸酯等二元醇的單(甲基)丙烯酸酯；三羥甲基丙烷二(甲基)丙烯酸酯、環氧乙烷（Ethylene Oxide，EO）改性三羥甲基丙烷(甲基)丙烯酸酯、環氧丙烷（Propylene Oxide，PO）改性三羥甲基丙烷二(甲基)丙烯酸酯、甘油二(甲基)丙烯酸酯、雙(2-(甲基)丙烯醯氧基乙基)羥基乙基異三聚氰酸酯等三元醇的單或二(甲基)丙烯酸酯、或者將這些醇性羥基的一部分利用ε-己內酯改性而成的具有羥基的單及二(甲基)丙烯酸酯；季戊四醇三(甲基)丙烯酸酯、二-三羥甲基丙烷三(甲基)丙烯酸酯、二季戊四醇五(甲基)丙烯酸酯等具有一官能的羥基與三官能以上的(甲基)丙烯醯基的化合物、或者將所述化合物進一步利用ε-己內酯改性而成的具有羥基的多官能(甲基)丙烯酸酯；二丙二醇單(甲基)丙烯酸酯、二乙二醇單(甲基)丙烯酸酯、聚丙二醇單(甲基)丙烯酸酯、聚乙二醇單(甲基)丙烯酸酯等具有氧化烯鏈的(甲基)丙烯酸酯；聚乙二醇-聚丙二醇單(甲基)丙烯酸酯、聚氧丁烯-聚氧丙烯單(甲基)丙烯酸酯等具有嵌段結構的氧化烯鏈的(甲基)丙烯酸酯；聚(乙二醇-四亞甲基二醇)單(甲基)丙烯酸酯、聚(丙二醇-四亞甲基二醇)單(甲基)丙烯酸酯等具有無規結構的氧化烯鏈的(甲基)丙烯酸酯等。這些(甲基)丙烯酸酯可使用一種，也可並用兩種以上。The (meth)acrylate is a compound having a hydroxyl group and a (meth)acryl group. Specific examples of the (meth)acrylates include: 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 2-hydroxybutyl (meth)acrylate, ( 4-Hydroxybutyl methacrylate, 1,5-pentanediol mono(meth)acrylate, 1,6-hexanediol mono(meth)acrylate, neopentyl glycol mono(meth)acrylate Mono(meth)acrylate esters of glycols such as hydroxypivalate neopentyl glycol mono(meth)acrylate; trimethylolpropane di(meth)acrylate, ethylene oxide (Ethylene Oxide) , EO) modified trimethylolpropane (meth)acrylate, propylene oxide (Propylene Oxide, PO) modified trimethylolpropane di(meth)acrylate, glycerol di(meth)acrylate, Mono- or di-(meth)acrylates of trihydric alcohols such as bis(2-(meth)acryloxyethyl)hydroxyethyl isocyanurate, or a part of these alcoholic hydroxyl groups using ε- Mono- and di(meth)acrylates with hydroxyl groups modified by caprolactone; pentaerythritol tri(meth)acrylate, di-trimethylolpropane tri(meth)acrylate, dipentaerythritol penta(meth)acrylate (meth)acrylic acid esters and other compounds having a monofunctional hydroxyl group and a trifunctional or more (meth)acryl group, or a multifunctional (meth)acryl group having a hydroxyl group obtained by further modifying the compound with ε-caprolactone ) acrylate; dipropylene glycol mono(meth)acrylate, diethylene glycol mono(meth)acrylate, polypropylene glycol mono(meth)acrylate, polyethylene glycol mono(meth)acrylate, etc. have oxidation Oxyalkylene chain (meth)acrylate; polyethylene glycol-polypropylene glycol mono(meth)acrylate, polyoxybutylene-polyoxypropylene mono(meth)acrylate, etc. have a block structure of oxyalkylene chain (meth)acrylate; poly(ethylene glycol-tetramethylene glycol) mono(meth)acrylate, poly(propylene glycol-tetramethylene glycol) mono(meth)acrylate, etc. have random Structured (meth)acrylates of oxyalkylene chains, etc. These (meth)acrylates may be used alone or in combination of two or more.
所述聚異氰酸酯與所述(甲基)丙烯酸酯的反應可利用常規方法的氨基甲酸酯化反應來進行。另外，為了促進氨基甲酸酯化反應的進行，優選為在氨基甲酸酯化催化劑的存在下進行氨基甲酸酯化反應。作為所述氨基甲酸酯化催化劑，例如可列舉：吡啶、吡咯、三乙胺、二乙胺、二丁胺等胺化合物；三苯基膦、三乙基膦等磷化合物；二月桂酸二丁基錫、三月桂酸辛基錫、二乙酸辛基錫、二乙酸二丁基錫、辛酸錫等有機錫化合物、辛酸鋅等有機鋅化合物等。The reaction between the polyisocyanate and the (meth)acrylate can be performed by a urethanization reaction of a conventional method. In addition, in order to promote the progress of the urethanization reaction, it is preferable to perform the urethanization reaction in the presence of a urethanization catalyst. As the urethanization catalyst, for example, amine compounds such as pyridine, pyrrole, triethylamine, diethylamine, and dibutylamine; phosphorus compounds such as triphenylphosphine and triethylphosphine; Organotin compounds such as butyltin, octyltin trilaurate, octyltin diacetate, dibutyltin diacetate, tin octoate, etc., organozinc compounds such as zinc octoate, etc.
再者，本發明中，所謂“(甲基)丙烯酸酯”是指丙烯酸酯與甲基丙烯酸酯中的一者或兩者，所謂“(甲基)丙烯醯基”是指丙烯醯基與甲基丙烯醯基中的一者或兩者。Furthermore, in the present invention, the so-called "(meth)acrylate" refers to one or both of acrylate and methacrylate, and the so-called "(meth)acryl" refers to acryl and methacrylate. One or both of the acryl groups.
作為所述活性能量線硬化性化合物（A），所述中，就可獲得更優異的抗靜電性及高硬度性的方面而言，優選為使用羥基價為40 mgKOH/g以下的化合物，更優選為使用二季戊四醇六丙烯酸酯及/或季戊四醇四丙烯酸酯。As the active energy ray-curable compound (A), among the above, it is preferable to use a compound having a hydroxyl value of 40 mgKOH/g or less in terms of obtaining more excellent antistatic properties and high hardness, and more preferably It is preferable to use dipentaerythritol hexaacrylate and/or pentaerythritol tetraacrylate.
所述樹脂（B）在獲得優異的抗靜電性的方面必須為具有四級銨鹽的樹脂。The resin (B) must be a resin having a quaternary ammonium salt in order to obtain excellent antistatic properties.
所述樹脂（B）在獲得優異的抗靜電性的方面必須具有脂環結構及四級銨鹽。The resin (B) must have an alicyclic structure and a quaternary ammonium salt in order to obtain excellent antistatic properties.
作為所述樹脂（B），具體而言例如可列舉具有脂環結構的聚合性單體（b1）、具有四級銨鹽的聚合性單體（b2）和可與所述（b1）及（b2）共聚的其他聚合性單體（b3）的共聚物。As the resin (B), specifically, for example, a polymerizable monomer (b1) having an alicyclic structure, a polymerizable monomer (b2) having a quaternary ammonium salt, and polymerizable monomers (b1) and ( b2) A copolymer of other polymerizable monomers (b3) to be copolymerized.
所述聚合性單體（b1）為具有脂環結構的聚合性單體。作為所述脂環結構，例如可列舉：環丙烷環、環丁烷環、環戊烷環、環己烷環、環庚烷環、環辛烷環、環壬烷環、環癸烷環等單環脂環結構；雙環十一烷環、十氫萘（decalin）環、三環[5.2.1.02,6 ]癸烷環、雙環[4.3.0]壬烷環、三環[5.3.1.1]十二烷環、螺[3.4]辛烷環等多環脂環結構等。另外，作為所述聚合性單體（b1）的具體例，可列舉：(甲基)丙烯酸環己酯、1,4-環己烷二甲醇單(甲基)丙烯酸酯、(甲基)丙烯酸異冰片酯、(甲基)丙烯酸二環戊烯酯、(甲基)丙烯酸二環戊烯氧基乙酯、(甲基)丙烯酸二環戊酯等。這些聚合性單體（b1）可使用一種，也可並用兩種以上。The polymerizable monomer (b1) is a polymerizable monomer having an alicyclic structure. Examples of the alicyclic structure include cyclopropane ring, cyclobutane ring, cyclopentane ring, cyclohexane ring, cycloheptane ring, cyclooctane ring, cyclononane ring, cyclodecane ring, etc. Monocyclic alicyclic structure; bicycloundecane ring, decalin ring, tricyclo[5.2.1.0 2,6 ]decane ring, bicyclo[4.3.0]nonane ring, tricyclo[5.3.1.1 ] dodecane ring, spiro [3.4] octane ring and other polycyclic alicyclic structures, etc. In addition, specific examples of the polymerizable monomer (b1) include cyclohexyl (meth)acrylate, 1,4-cyclohexanedimethanol mono(meth)acrylate, (meth)acrylic acid Isobornyl, dicyclopentenyl (meth)acrylate, dicyclopentenyloxyethyl (meth)acrylate, dicyclopentanyl (meth)acrylate, and the like. These polymerizable monomers (b1) may be used alone or in combination of two or more.
作為所述具有四級銨鹽的聚合性單體（b2），例如可列舉：2-[(甲基)丙烯醯氧基]乙基三甲基氯化銨、3-[(甲基)丙烯醯氧基]丙基三甲基氯化銨等反荷陰離子為氯離子者；2-[(甲基)丙烯醯氧基]乙基三甲基溴化銨、3-[(甲基)丙烯醯氧基]丙基三甲基溴化銨等反荷陰離子為溴離子者；2-[(甲基)丙烯醯氧基]乙基三甲基銨甲基苯基磺酸酯、2-[(甲基)丙烯醯氧基]乙基三甲基銨甲基磺酸酯、3-[(甲基)丙烯醯氧基]丙基三甲基銨甲基苯基磺酸酯、3-[(甲基)丙烯醯氧基]丙基三甲基銨甲基磺酸酯、2-[(甲基)丙烯醯氧基]乙基三甲基銨甲基硫酸酯、3-[(甲基)丙烯醯氧基]丙基三甲基銨甲基硫酸酯等反荷陰離子為非鹵素系者；二甲基氨基乙基(甲基)丙烯醯胺氯甲基四級鹽、二甲基氨基丙基(甲基)丙烯醯胺氯甲基四級鹽等。這些聚合性單體（b2）可使用一種，也可並用兩種以上。Examples of the polymerizable monomer (b2) having a quaternary ammonium salt include: 2-[(meth)acryloxy]ethyltrimethylammonium chloride, 3-[(meth)propylene Acryloxy]propyltrimethylammonium chloride and other counter anions are chloride ions; 2-[(meth)acryloxy]ethyltrimethylammonium bromide, 3-[(meth)propylene Acyloxy]propyltrimethylammonium bromide and other counter anions are bromide ions; 2-[(meth)acryloxy]ethyltrimethylammonium methylphenylsulfonate, 2-[ (Meth)acryloxy]ethyltrimethylammonium methylsulfonate, 3-[(meth)acryloxy]propyltrimethylammoniummethylphenylsulfonate, 3-[ (Meth)acryloxy]propyltrimethylammonium methylsulfonate, 2-[(meth)acryloxy]ethyltrimethylammonium methylsulfate, 3-[(methyl ) acryloxy] propyltrimethylammonium methylsulfate and other counter anions are non-halogen; dimethylaminoethyl (meth)acrylamide chloromethyl quaternary salt, dimethylamino Propyl (meth)acrylamide chloromethyl quaternary salt, etc. These polymerizable monomers (b2) may be used alone or in combination of two or more.
作為所述其他聚合性單體（b3），例如可列舉：(甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸正丙酯、(甲基)丙烯酸正丁酯、(甲基)丙烯酸異丁酯、(甲基)丙烯酸正戊酯、(甲基)丙烯酸正己酯、(甲基)丙烯酸正庚酯、(甲基)丙烯酸正辛酯、(甲基)丙烯酸2-乙基己酯、(甲基)丙烯酸壬酯、(甲基)丙烯酸癸酯、(甲基)丙烯酸十二烷基酯等(甲基)丙烯酸烷基酯；甲氧基聚乙二醇單(甲基)丙烯酸酯、辛氧基聚乙二醇·聚丙二醇單(甲基)丙烯酸酯、十二烷氧基聚乙二醇單(甲基)丙烯酸酯、十八烷氧基聚乙二醇單(甲基)丙烯酸酯、苯氧基聚乙二醇單(甲基)丙烯酸酯、苯氧基聚乙二醇·聚丙二醇單(甲基)丙烯酸酯、壬基苯氧基聚丙二醇單(甲基)丙烯酸酯、壬基苯氧基聚(乙二醇·丙二醇)單(甲基)丙烯酸酯等聚烷二醇的單(甲基)丙烯酸酯；(甲基)丙烯酸2-全氟己基乙酯等具有氟化烷基的(甲基)丙烯酸酯等。這些聚合性單體（b3）可使用一種，也可並用兩種以上。Examples of the other polymerizable monomer (b3) include methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, n-butyl (meth)acrylate, Isobutyl (meth)acrylate, n-pentyl (meth)acrylate, n-hexyl (meth)acrylate, n-heptyl (meth)acrylate, n-octyl (meth)acrylate, (meth)acrylate 2 - Alkyl (meth)acrylates such as ethylhexyl, nonyl (meth)acrylate, decyl (meth)acrylate, lauryl (meth)acrylate, etc.; methoxypolyethylene glycol mono (meth)acrylate, octyloxypolyethylene glycol polypropylene glycol mono(meth)acrylate, dodecyloxypolyethylene glycol mono(meth)acrylate, octadecyloxypolyethylene glycol Alcohol mono(meth)acrylate, Phenoxypolyethylene glycol mono(meth)acrylate, Phenoxypolyethylene glycol polypropylene glycol mono(meth)acrylate, Nonylphenoxypolypropylene glycol mono Mono(meth)acrylates of polyalkylene glycols such as (meth)acrylates, nonylphenoxy poly(ethylene glycol·propylene glycol) mono(meth)acrylates; (meth)acrylate 2-perfluoro A (meth)acrylate having a fluorinated alkyl group, such as hexyl ethyl ester, etc. These polymerizable monomers (b3) may be used alone or in combination of two or more.
作為所述聚合性單體（b3），就可獲得更優異的抗靜電性的方面而言，優選為使用具有氟化烷基的(甲基)丙烯酸酯及/或聚烷二醇的單(甲基)丙烯酸酯，另外作為所述聚烷二醇的單(甲基)丙烯酸酯，更優選為甲氧基聚乙二醇單(甲基)丙烯酸酯。As the polymerizable monomer (b3), it is preferable to use (meth)acrylate having a fluorinated alkyl group and/or mono( Meth)acrylate, in addition as the mono(meth)acrylate of polyalkylene glycol, is more preferably methoxypolyethylene glycol mono(meth)acrylate.
所述聚烷二醇的單(甲基)丙烯酸酯中，就可獲得更優異的抗靜電性的方面而言，優選為作為所述聚烷二醇的單(甲基)丙烯酸酯的原料的聚烷二醇的數量平均分子量為200～8,000的範圍者，更優選為300～6,000的範圍者，進而優選為400～4,000的範圍者，尤其優選為400～2,000的範圍者。Among the mono(meth)acrylates of polyalkylene glycol, it is preferable that the raw material of the mono(meth)acrylate of polyalkylene glycol is The number average molecular weight of the polyalkylene glycol is in the range of 200 to 8,000, more preferably in the range of 300 to 6,000, still more preferably in the range of 400 to 4,000, and especially preferably in the range of 400 to 2,000.
就可進一步提高本發明的活性能量線硬化性組合物的硬化塗膜的抗靜電性的方面而言，所述樹脂（B）的原料總量中的所述聚合性單體（b1）的比率優選為5質量%～55質量%的範圍內，更優選為10質量%～50質量%的範圍內，進而優選為12質量%～45質量%的範圍內。The ratio of the polymerizable monomer (b1) in the total amount of raw materials of the resin (B) is that the antistatic property of the cured coating film of the active energy ray-curable composition of the present invention can be further improved It is preferably in the range of 5% by mass to 55% by mass, more preferably in the range of 10% by mass to 50% by mass, and still more preferably in the range of 12% by mass to 45% by mass.
另外，就可進一步提高本發明的活性能量線硬化性組合物的硬化塗膜的抗靜電性的方面而言，所述樹脂（B）的原料總量中的所述聚合性單體（b2）的比率優選為30質量%～90質量%的範圍內，更優選為40質量%～80質量%的範圍內，進而優選為45質量%～70質量%的範圍內。In addition, the polymerizable monomer (b2) in the total amount of raw materials of the resin (B) can further improve the antistatic property of the cured coating film of the active energy ray-curable composition of the present invention. The ratio of is preferably in the range of 30% by mass to 90% by mass, more preferably in the range of 40% by mass to 80% by mass, and still more preferably in the range of 45% by mass to 70% by mass.
在使用所述聚烷二醇的單(甲基)丙烯酸酯作為所述聚合性單體（b3）的情況下，就可進一步提高本發明的活性能量線硬化性組合物的硬化塗膜的抗靜電性的方面而言，所述樹脂（B）的原料總量中的聚烷二醇的單(甲基)丙烯酸酯的比率優選為5質量%～60質量%的範圍內，更優選為10質量%～50質量%的範圍內，進而優選為20質量%～40質量%的範圍內。When the mono(meth)acrylate of polyalkylene glycol is used as the polymerizable monomer (b3), the resistance of the cured coating film of the active energy ray-curable composition of the present invention can be further improved. From the viewpoint of electrostatic properties, the ratio of mono(meth)acrylate of polyalkylene glycol in the total amount of raw materials of the resin (B) is preferably in the range of 5% by mass to 60% by mass, more preferably 10% by mass. It exists in the range of mass % - 50 mass %, More preferably, it exists in the range of 20 mass % - 40 mass %.
另外，在使用所述具有氟化烷基的(甲基)丙烯酸酯作為所述聚合性單體（b3）的情況下，就可進一步提高本發明的活性能量線硬化性組合物的硬化塗膜的抗靜電性的方面而言，所述樹脂（B）的原料總量中的具有氟化烷基的(甲基)丙烯酸酯的比率優選為0.1質量%～20質量%的範圍內，更優選為0.5質量%～10質量%的範圍內，進而優選為1質量%～5質量%的範圍內。In addition, when the (meth)acrylate having a fluorinated alkyl group is used as the polymerizable monomer (b3), the cured coating film of the active energy ray-curable composition of the present invention can be further improved. In terms of the antistatic property of the resin (B), the ratio of the (meth)acrylate having a fluorinated alkyl group in the total amount of raw materials of the resin (B) is preferably in the range of 0.1% by mass to 20% by mass, more preferably It exists in the range of 0.5 mass % - 10 mass %, More preferably, it exists in the range of 1 mass % - 5 mass %.
就可進一步提高本發明的活性能量線硬化性組合物的硬化塗膜的抗靜電性的方面而言，所述樹脂（B）的重量平均分子量優選為1,000～100,000的範圍內，更優選為2,000～50,000的範圍內，進而優選為3,000～30,000的範圍內。再者，本發明中的重量平均分子量是利用凝膠滲透色譜（Gel Permeation Chromatography，GPC）法測定的以聚苯乙烯換算計的值。The weight average molecular weight of the resin (B) is preferably in the range of 1,000 to 100,000, more preferably 2,000, from the viewpoint that the antistatic property of the cured coating film of the active energy ray-curable composition of the present invention can be further improved. It exists in the range of -50,000, More preferably, it exists in the range of 3,000-30,000. In addition, the weight average molecular weight in this invention is the value in terms of polystyrene measured by the gel permeation chromatography (Gel Permeation Chromatography, GPC) method.
就可進一步提高本發明的活性能量線硬化性組合物的硬化塗膜的抗靜電性及耐滲出性的方面而言，所述樹脂（B）的調配量相對於所述活性能量線硬化性化合物（A）100質量份而優選為0.1質量份～10質量份的範圍內，更優選為1.3質量份～5質量份的範圍內，進而優選為1.5質量份～2質量份的範圍內。In terms of further improving the antistatic properties and bleeding resistance of the cured coating film of the active energy ray-curable composition of the present invention, the compounded amount of the resin (B) relative to the active energy ray-curable compound (A) 100 parts by mass is preferably in the range of 0.1 to 10 parts by mass, more preferably in the range of 1.3 to 5 parts by mass, and still more preferably in the range of 1.5 to 2 parts by mass.
所述化合物（C）為具有四級銨鹽且不具有脂環結構的化合物。藉由並用所述化合物（C）與所述樹脂（B），即便在減少抗靜電劑（所述樹脂（B）及化合物（C））的使用量的情況下，也可顯現出硬化塗膜的優異的抗靜電性，也可抑制滲出。The compound (C) is a compound having a quaternary ammonium salt and not having an alicyclic structure. By using the above-mentioned compound (C) and the above-mentioned resin (B) together, even when the amount of the antistatic agent (the above-mentioned resin (B) and compound (C)) used is reduced, a cured coating film can be developed Excellent antistatic properties, also inhibit bleeding.
作為所述化合物（C），例如可使用可用作所述樹脂（B）的原料的所述具有四級銨鹽的聚合性單體（b2）、所述具有四級銨鹽的聚合性單體（b2）與所述其他聚合性單體（b3）的共聚物。As the compound (C), for example, the polymerizable monomer having a quaternary ammonium salt (b2), the polymerizable monomer having a quaternary ammonium salt, A copolymer of the body (b2) and the other polymerizable monomer (b3).
作為所述化合物（C）的重量平均分子量，就可獲得更優異的抗靜電性及耐滲出性的方面而言，優選為100～1,000的範圍內，更優選為130～500的範圍內，進而優選為150～300的範圍內。The weight average molecular weight of the compound (C) is preferably within a range of 100 to 1,000, more preferably within a range of 130 to 500, and furthermore excellent antistatic properties and bleeding resistance can be obtained. Preferably, it exists in the range of 150-300.
就提高耐滲出性的方面而言，進而優選為在所述化合物（C）中具有活性能量線硬化性官能基。From the viewpoint of improving bleeding resistance, it is more preferable to have an active energy ray-curable functional group in the compound (C).
作為所述化合物（C），所述中，就可獲得更優異的抗靜電性及耐滲出性的方面而言，優選為使用選自由2-[(甲基)丙烯醯氧基]乙基三甲基氯化銨、3-[(甲基)丙烯醯氧基]丙基三甲基氯化銨、二甲基氨基乙基(甲基)丙烯醯胺氯甲基四級鹽及二甲基氨基丙基(甲基)丙烯醯胺氯甲基四級鹽所組成的群組中的一種以上的化合物。As the compound (C), among the above, it is preferable to use a compound selected from the group consisting of 2-[(meth)acryloyloxy]ethyltrimonium trioxide in terms of obtaining more excellent antistatic properties and bleed resistance. Methylammonium chloride, 3-[(meth)acryloxy]propyltrimethylammonium chloride, dimethylaminoethyl(meth)acrylamide chloromethyl quaternary salt and dimethyl More than one compound in the group consisting of aminopropyl (meth)acrylamide chloromethyl quaternary salt.
就可進一步提高本發明的活性能量線硬化性組合物的硬化塗膜的抗靜電性及耐滲出性的方面而言，所述化合物（C）的調配量相對於所述活性能量線硬化性化合物（A）100質量份而優選為0.1質量份～15質量份的範圍內，更優選為1質量份～10質量份的範圍內，進而優選為3質量份～8質量份的範圍內。In terms of further improving the antistatic properties and bleeding resistance of the cured coating film of the active energy ray-curable composition of the present invention, the compounding amount of the compound (C) relative to the active energy ray-curable compound (A) 100 parts by mass is preferably in the range of 0.1 to 15 parts by mass, more preferably in the range of 1 to 10 parts by mass, and still more preferably in the range of 3 to 8 parts by mass.
作為所述樹脂（B）與所述化合物（C）的合計調配量，就可更進一步提高抗靜電性與耐滲出性的平衡，即便在濕熱條件下使用後抗靜電性的變化也少的方面而言，相對於所述活性能量線硬化性化合物（A）100質量份而優選為1質量份～10質量份的範圍內，更優選為3質量份～8質量份的範圍內。As the total compounding amount of the above-mentioned resin (B) and the above-mentioned compound (C), the balance between the antistatic property and the anti-bleeding property can be further improved, and there is little change in the antistatic property even after use under hot and humid conditions. Specifically, it is preferably in the range of 1 to 10 parts by mass, more preferably in the range of 3 to 8 parts by mass with respect to 100 parts by mass of the active energy ray-curing compound (A).
作為所述樹脂（B）與所述化合物（C）的質量比[（B）/（C）]，就可更進一步提高抗靜電性與耐滲出性的平衡且即便在濕熱條件下使用後抗靜電性的變化也少的方面而言，優選為5/95～40/60的範圍內，更優選為10/90～30/70的範圍內，進而優選為13/87～20/80的範圍內。As the mass ratio of the resin (B) to the compound (C) [(B)/(C)], it is possible to further improve the balance between the antistatic property and the anti-bleeding property, and the antistatic property can be resisted even after use under hot and humid conditions. In terms of little change in electrostatic properties, it is preferably in the range of 5/95 to 40/60, more preferably in the range of 10/90 to 30/70, and still more preferably in the range of 13/87 to 20/80 Inside.
所述有機溶劑（D）只要可溶解本發明的活性能量線硬化性組合物中的其他成分，則可無特別限制地使用。作為所述有機溶劑（D），例如可列舉：甲苯、二甲苯等芳香族烴；甲醇、乙醇、異丙醇、第三丁醇等醇類；乙酸乙酯、乙酸丁酯、丙二醇單甲醚乙酸酯等酯類；丙酮、甲基乙基酮、甲基異丁基酮、環己酮等酮類等。這些有機溶劑可單獨使用，也可並用兩種以上。The organic solvent (D) can be used without particular limitation as long as it can dissolve other components in the active energy ray-curable composition of the present invention. Examples of the organic solvent (D) include: aromatic hydrocarbons such as toluene and xylene; alcohols such as methanol, ethanol, isopropanol, and tertiary butanol; ethyl acetate, butyl acetate, and propylene glycol monomethyl ether. Acetate and other esters; acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone and other ketones, etc. These organic solvents may be used alone or in combination of two or more.
本發明的活性能量線硬化性組合物中的所述有機溶劑（D）的調配量優選為設為成為適合於後述的塗敷方法的黏度的量。It is preferable that the compounding quantity of the said organic solvent (D) in the active energy ray curable composition of this invention is set as the quantity which becomes the viscosity suitable for the coating method mentioned later.
另外，本發明的活性能量線硬化性組合物可藉由在塗敷於基材上後，照射活性能量線而製成硬化塗膜。所謂所述活性能量線是指紫外線、電子束、α射線、β射線、γ射線等電離射線。在照射紫外線作為活性能量線而製成硬化塗膜的情況下，優選為在本發明的活性能量線硬化性組合物中添加光聚合引發劑（E）來提高硬化性。另外，若需要則也可進一步添加光增感劑來提高硬化性。另一方面，在使用電子束、α射線、β射線、γ射線等電離射線的情況下，即便不使用光聚合引發劑（E）或光增感劑，也會快速地硬化，因此無需特別添加光聚合引發劑（E）或光增感劑。In addition, the active energy ray-curable composition of the present invention can be used as a cured coating film by irradiating active energy rays after coating on a substrate. The active energy rays refer to ionizing rays such as ultraviolet rays, electron beams, α rays, β rays, and γ rays. When irradiating ultraviolet rays as active energy rays to form a cured coating film, it is preferable to add a photopolymerization initiator (E) to the active energy ray-curable composition of the present invention to improve curability. In addition, if necessary, a photosensitizer may be further added to improve curability. On the other hand, when ionizing rays such as electron beams, α-rays, β-rays, and γ-rays are used, even without using a photopolymerization initiator (E) or a photosensitizer, it hardens quickly, so no special addition is required. A photopolymerization initiator (E) or a photosensitizer.
作為所述光聚合引發劑（E），例如可列舉：二乙氧基苯乙酮、2-羥基-2-甲基-1-苯基丙烷-1-酮、寡聚{2-羥基-2-甲基-1-[4-(1-甲基乙烯基)苯基]丙酮}、苯偶醯二甲基縮酮、1-(4-異丙基苯基)-2-羥基-2-甲基丙烷-1-酮、4-(2-羥基乙氧基)苯基-(2-羥基-2-丙基)酮、1-羥基環己基苯基酮、2-甲基-2-嗎啉基(4-硫甲基苯基)丙烷-1-酮、2-苄基-2-二甲基氨基-1-(4-嗎啉基苯基)-丁酮等苯乙酮系化合物；安息香、安息香甲醚、安息香異丙醚等安息香系化合物；2,4,6-三甲基安息香二苯基氧化膦、雙(2,4,6-三甲基安息香)-苯基氧化膦等醯基氧化膦系化合物；苯偶醯（聯苯甲醯）、甲基苯基乙醛酸酯、氧基苯基乙酸2-(2-羥基乙氧基)乙酯、氧基苯基乙酸2-(2-氧代-2-苯基乙醯氧基乙氧基)乙酯等苯偶醯系化合物；二苯甲酮、鄰苯甲醯基苯甲酸甲酯-4-苯基二苯甲酮、4,4'-二氯二苯甲酮、羥基二苯甲酮、4-苯甲醯基-4'-甲基-二苯基硫醚、丙烯酸化二苯甲酮、3,3',4,4'-四(第三丁基過氧基羰基)二苯甲酮、3,3'-二甲基-4-甲氧基二苯甲酮、2,4,6-三甲基二苯甲酮、4-甲基二苯甲酮等二苯甲酮系化合物；2-異丙基噻噸酮、2,4-二甲基噻噸酮、2,4-二乙基噻噸酮、2,4-二氯噻噸酮等噻噸酮系化合物；米其勒酮、4,4'-二乙基氨基二苯甲酮等氨基二苯甲酮系化合物；10-丁基-2-氯吖啶酮、2-乙基蒽醌、9,10-菲醌、樟腦醌、1-[4-(4-苯甲醯基苯基硫基)苯基]-2-甲基-2-(4-甲基苯基磺醯基)丙烷-1-酮等。這些光聚合引發劑（E）可使用一種，也可並用兩種以上。Examples of the photopolymerization initiator (E) include diethoxyacetophenone, 2-hydroxy-2-methyl-1-phenylpropane-1-one, oligo{2-hydroxy-2 -Methyl-1-[4-(1-methylvinyl)phenyl]acetone}, benzoyl dimethyl ketal, 1-(4-isopropylphenyl)-2-hydroxy-2- Methylpropan-1-one, 4-(2-hydroxyethoxy)phenyl-(2-hydroxy-2-propyl)ketone, 1-hydroxycyclohexylphenylketone, 2-methyl-2-mol Linyl (4-thiomethylphenyl) propan-1-one, 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)-butanone and other acetophenone compounds; Benzoin, benzoin methyl ether, benzoin isopropyl ether and other benzoin compounds; 2,4,6-trimethylbenzoin diphenylphosphine oxide, bis(2,4,6-trimethylbenzoin)-phenylphosphine oxide, etc. Acyl phosphine oxide compounds; benzoyl (diphenylformyl), methyl phenyl glyoxylate, 2-(2-hydroxyethoxy) ethyl oxyphenylacetate, 2-oxyphenylacetate -(2-oxo-2-phenylacetyloxyethoxy)ethyl ester and other benzoyl compounds; benzophenone, methyl o-benzoylbenzoate-4-phenylbenzoylbenzoate Ketone, 4,4'-Dichlorobenzophenone, Hydroxybenzophenone, 4-Benzyl-4'-methyl-diphenylsulfide, Acrylated Benzophenone, 3,3' ,4,4'-tetrakis(tert-butylperoxycarbonyl)benzophenone, 3,3'-dimethyl-4-methoxybenzophenone, 2,4,6-trimethyl Benzophenone compounds such as benzophenone and 4-methylbenzophenone; 2-isopropylthioxanthone, 2,4-dimethylthioxanthone, 2,4-diethylthioxanthone Thioxanthone-series compounds such as ketones and 2,4-dichlorothioxanthone; aminobenzophenone-series compounds such as Michelerone and 4,4'-diethylaminobenzophenone; 10-butyl- 2-chloroacridone, 2-ethylanthraquinone, 9,10-phenanthrenequinone, camphorquinone, 1-[4-(4-benzoylphenylthio)phenyl]-2-methyl- 2-(4-methylphenylsulfonyl)propan-1-one, etc. These photopolymerization initiators (E) may be used alone or in combination of two or more.
另外，作為所述光增感劑，例如可列舉：二乙醇胺、N-甲基二乙醇胺、三丁胺等三級胺化合物、鄰甲苯基硫脲等脲化合物、二乙基二硫代磷酸鈉、s-苄基異硫脲鎓-對甲苯磺酸酯等硫化合物等。In addition, examples of the photosensitizer include tertiary amine compounds such as diethanolamine, N-methyldiethanolamine, and tributylamine; urea compounds such as o-tolylthiourea; sodium diethyldithiophosphate; , S-benzylisothiouronium-p-toluenesulfonate and other sulfur compounds.
所述光聚合引發劑（E）及光增感劑的使用量相對於本發明的活性能量線硬化性組合物中的所述活性能量線硬化性化合物（A）100質量份而優選為分別為0.05質量份～20質量份，更優選為0.5質量份～10質量份。The photopolymerization initiator (E) and photosensitizer are preferably used in amounts of 100 parts by mass of the active energy ray-curable compound (A) in the active energy ray-curable composition of the present invention. 0.05 to 20 parts by mass, more preferably 0.5 to 10 parts by mass.
本發明的活性能量線硬化性組合物中可根據用途、要求特性而調配聚合抑制劑、表面調整劑、消泡劑、黏度調整劑、耐光穩定劑、耐候穩定劑、耐熱穩定劑、紫外線吸收劑、抗氧化劑、調平劑、有機顏料、無機顏料、顏料分散劑、矽珠、有機珠等添加劑；氧化矽、氧化鋁、氧化鈦、氧化鋯、五氧化銻等無機填充劑等來作為所述成分（A）～成分（E）以外的其他調配物。這些其他調配物可使用一種，也可並用兩種以上。In the active energy ray-curable composition of the present invention, polymerization inhibitors, surface modifiers, defoamers, viscosity modifiers, light-resistant stabilizers, weather-resistant stabilizers, heat-resistant stabilizers, and ultraviolet absorbers can be formulated according to the application and required characteristics. , antioxidants, leveling agents, organic pigments, inorganic pigments, pigment dispersants, silicon beads, organic beads and other additives; silicon oxide, aluminum oxide, titanium oxide, zirconium oxide, antimony pentoxide and other inorganic fillers are used as the Other formulations other than components (A) to (E). These other formulations may be used alone or in combination of two or more.
本發明的膜藉由如下方式獲得，即，將本發明的活性能量線硬化性組合物塗敷於膜基材的至少一面上，其後照射活性能量線而製成硬化塗膜。The film of the present invention is obtained by applying the active energy ray-curable composition of the present invention on at least one surface of a film substrate, and then irradiating active energy rays to form a cured coating film.
作為本發明的膜中使用的所述膜基材的材質，優選為透明性高的樹脂，例如可列舉：聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、聚萘二甲酸乙二酯等聚酯系樹脂；聚丙烯、聚乙烯、聚甲基戊烯-1等聚烯烴系樹脂；乙酸纖維素（二乙醯纖維素、三乙醯纖維素等）、乙酸丙酸纖維素、乙酸丁酸纖維素、乙酸丙酸丁酸纖維素、乙酸鄰苯二甲酸纖維素、硝酸纖維素等纖維素系樹脂；聚甲基丙烯酸甲酯等丙烯酸系樹脂；聚氯乙烯、聚偏二氯乙烯等氯乙烯系樹脂；聚乙烯醇；乙烯-乙酸乙烯酯共聚物；聚苯乙烯；聚醯胺；聚碳酸酯；聚碸；聚醚碸；聚醚醚酮；聚醯亞胺、聚醚醯亞胺等聚醯亞胺系樹脂；降冰片烯系樹脂（例如，日本瑞翁（ZEON）股份有限公司製造的“瑞諾（Zeonor）”）、改性降冰片烯系樹脂（例如，JSR股份有限公司製造的“阿特恩（Arton）”）、環狀烯烴共聚物（例如，三井化學股份有限公司製造的“阿派（Apel）”）等。進而，也可使用將兩種以上包含這些樹脂的基材貼合而成者。The material of the film substrate used in the film of the present invention is preferably a highly transparent resin, for example, polyethylene terephthalate, polybutylene terephthalate, polynaphthalate Polyester-based resins such as ethylene glycol; polyolefin-based resins such as polypropylene, polyethylene, and polymethylpentene-1; cellulose acetate (diacetyl cellulose, triacetyl cellulose, etc.), acetate propionate fiber Cellulose resins such as cellulose acetate butyrate, cellulose acetate propionate butyrate, cellulose acetate phthalate, and cellulose nitrate; acrylic resins such as polymethyl methacrylate; polyvinyl chloride, polyvinylidene Vinyl chloride resins such as ethylene dichloride; polyvinyl alcohol; ethylene-vinyl acetate copolymer; polystyrene; polyamide; polycarbonate; Polyimide-based resins such as polyetherimide; norbornene-based resins (for example, "Zeonor" manufactured by Japan Zeon Co., Ltd.), modified norbornene-based resins (for example, , "Arton" manufactured by JSR Co., Ltd.), cyclic olefin copolymers (for example, "Apel" manufactured by Mitsui Chemicals Co., Ltd.), and the like. Furthermore, what laminated|bonded the base material which consists of two or more types of these resins can also be used.
另外，所述膜基材可為膜狀也可為片狀，其厚度優選為20 μm～500 μm的範圍內。另外，在使用膜狀的基材膜的情況下，其厚度優選為20 μm～200 μm的範圍內，更優選為30 μm～150 μm的範圍內，進而優選為40 μm～130 μm的範圍內。藉由將膜基材的厚度設為所述範圍內，即便在利用本發明的活性能量線硬化性組合物而在膜的單面上設置硬塗層的情況下，也容易抑制捲曲。In addition, the film substrate may be in the form of a film or a sheet, and its thickness is preferably in the range of 20 μm to 500 μm. In addition, when a film-like base film is used, its thickness is preferably within a range of 20 μm to 200 μm, more preferably within a range of 30 μm to 150 μm, and still more preferably within a range of 40 μm to 130 μm. . By setting the thickness of the film substrate within the above range, curling can be easily suppressed even when a hard coat layer is provided on one surface of the film using the active energy ray-curable composition of the present invention.
作為將本發明的活性能量線硬化性組合物塗敷於所述膜基材上的方法，例如可列舉：模塗布、微凹版塗布、凹版塗布、輥塗布、缺角輪塗布、氣刀塗布、吻合式塗布、噴塗、浸漬塗布、旋塗、刷塗、利用絲網印刷的滿版塗布、線棒塗布、流塗等。Examples of methods for applying the active energy ray-curable composition of the present invention to the film substrate include die coating, microgravure coating, gravure coating, roll coating, chipping wheel coating, air knife coating, Dosing coating, spray coating, dip coating, spin coating, brush coating, solid coating by screen printing, wire bar coating, flow coating, etc.
關於本發明的活性能量線硬化性組合物中包含的有機溶媒，為了在將活性能量線硬化性組合物塗敷於基材膜上後且在照射活性能量線前揮發並且使所述樹脂（B）及化合物（C）偏析於塗膜表面上，優選為進行加熱或室溫乾燥。作為加熱乾燥的條件，只要為有機溶劑揮發的條件，則並無特別限定，但通常優選為在溫度50℃～100℃的範圍內、時間在0.5分鐘～10分鐘的範圍內進行加熱乾燥。Regarding the organic solvent contained in the active energy ray-curable composition of the present invention, the resin (B ) and compound (C) are segregated on the surface of the coating film, preferably by heating or drying at room temperature. The heat drying conditions are not particularly limited as long as the organic solvent volatilizes, but usually, heat drying is preferably performed at a temperature in the range of 50°C to 100°C and in a time range of 0.5 minutes to 10 minutes.
作為使本發明的活性能量線硬化性組合物硬化的活性能量線，如上所述為紫外線、電子束、α射線、β射線、γ射線等電離射線。此處，在使用紫外線作為活性能量線的情況下，作為照射所述紫外線的裝置，例如可列舉：低壓水銀燈、高壓水銀燈、超高壓水銀燈、金屬鹵化物燈、無電極燈（融合燈（fusion lamp））、化學燈、黑光燈、水銀-氙燈、短弧燈、氦·鎘雷射、氬雷射、太陽光、發光二極體（Light Emitting Diode，LED）燈等。The active energy rays that cure the active energy ray-curable composition of the present invention are ionizing rays such as ultraviolet rays, electron beams, α rays, β rays, and γ rays as described above. Here, when ultraviolet rays are used as the active energy rays, as a device for irradiating the ultraviolet rays, for example, low-pressure mercury lamps, high-pressure mercury lamps, ultra-high-pressure mercury lamps, metal halide lamps, electrodeless lamps (fusion lamps, etc.) )), chemical lamps, black light lamps, mercury-xenon lamps, short-arc lamps, helium-cadmium lasers, argon lasers, sunlight, light-emitting diode (Light Emitting Diode, LED) lamps, etc.
就使硬化塗膜的硬度充分且可抑制因塗膜的硬化收縮造成的膜的捲曲的方面而言，在所述膜基材上形成本發明的活性能量線硬化性組合物的硬化塗膜時的硬化塗膜的厚度優選為1 μm～30 μm的範圍內，更優選為3 μm～15 μm的範圍內，進而優選為4 μm～10 μm的範圍內。When forming the cured coating film of the active energy ray-curable composition of the present invention on the film base material, the hardness of the cured coating film is sufficient and the curling of the film due to the curing shrinkage of the coating film can be suppressed. The thickness of the cured coating film is preferably within a range of 1 μm to 30 μm, more preferably within a range of 3 μm to 15 μm, and still more preferably within a range of 4 μm to 10 μm.
以上，本發明的活性能量線硬化性組合物可形成具有優異的抗靜電性及耐滲出性的硬塗層。作為所述活性能量線硬化性組合物的硬化塗膜的表面電阻值，優選為1×107 Ω/□～9.99×109 Ω/□的範圍內，更優選為1×108 Ω/□～9.99×108 Ω/□的範圍內。再者，所述硬化塗膜的表面電阻值的測定方法記載於實施例中。 [實施例]As described above, the active energy ray-curable composition of the present invention can form a hard coat layer having excellent antistatic properties and bleeding resistance. The surface resistance value of the cured coating film of the active energy ray-curable composition is preferably in the range of 1×10 7 Ω/□ to 9.99×10 9 Ω/□, more preferably 1×10 8 Ω/□ to 9.99×10 8 Ω/□. In addition, the measuring method of the surface resistance value of the said cured coating film is described in an Example. [Example]
以下，利用實施例對本發明進行更具體的說明。Hereinafter, the present invention will be described more specifically using examples.
（製造例1：具有脂環結構及四級銨鹽的樹脂（B-1）的製造） 在具備攪拌裝置、回流冷卻管及氮氣導入管的燒瓶中導入氮氣，利用氮氣對燒瓶內的空氣進行置換。其後，在燒瓶中加入2-(甲基丙烯醯氧基)乙基三甲基氯化銨54.7質量份、甲基丙烯酸環己酯19.9質量份、甲氧基聚乙二醇甲基丙烯酸酯（日油股份有限公司製造的“布萊瑪（Blemmer）PME-1000”；重複單元數n≒23、分子量1,000）24.9質量份、甲基丙烯酸0.5質量份、甲醇50質量份及丙二醇單甲醚（Propylene Glycol Monomethyl Ether，PGME）10質量份。繼而，花30分鐘滴加利用PGME 2.4質量份溶解聚合引發劑（偶氮雙異丁腈）0.1質量份而得的溶液後，在65℃下反應3小時。繼而，加入甲醇並進行稀釋，而獲得具有脂環結構及四級銨鹽的樹脂（B-1）的45質量%溶液。所得的樹脂（B-1）的重量平均分子量為1萬。(Production Example 1: Production of a resin (B-1) having an alicyclic structure and a quaternary ammonium salt) Nitrogen gas was introduced into a flask equipped with a stirring device, a reflux cooling pipe, and a nitrogen gas introduction pipe, and the air in the flask was cooled with nitrogen gas. replacement. Thereafter, 54.7 parts by mass of 2-(methacryloxy)ethyltrimethylammonium chloride, 19.9 parts by mass of cyclohexyl methacrylate, methoxypolyethylene glycol methacrylate ("Blemmer PME-1000" manufactured by NOF Corporation; number of repeating units n≒23, molecular weight 1,000) 24.9 parts by mass, 0.5 parts by mass of methacrylic acid, 50 parts by mass of methanol, and propylene glycol monomethyl ether (Propylene Glycol Monomethyl Ether, PGME) 10 parts by mass. Then, after dripping the solution which melt|dissolved 0.1 mass part of polymerization initiators (azobisisobutyronitrile) with 2.4 mass parts of PGME over 30 minutes, it was made to react at 65 degreeC for 3 hours. Next, methanol was added and diluted to obtain a 45% by mass solution of a resin (B-1) having an alicyclic structure and a quaternary ammonium salt. The weight average molecular weight of the obtained resin (B-1) was 10,000.
（製造例2：具有脂環結構及四級銨鹽的樹脂（B-2）的製造） 在具備攪拌裝置、回流冷卻管及氮氣導入管的燒瓶中導入氮氣，利用氮氣對燒瓶內的空氣進行置換。其後，在燒瓶中加入2-(甲基丙烯醯氧基)乙基三甲基氯化銨53.7質量份、甲基丙烯酸環己酯29.3質量份、甲氧基聚乙二醇甲基丙烯酸酯（日油股份有限公司製造的“布萊瑪（Blemmer）PME-1000”；重複單元數n≒23、分子量1,000）14.6質量份、丙烯酸2-全氟己基乙酯1.9質量份、甲基丙烯酸0.5質量份、甲醇50質量份及丙二醇單甲醚10質量份。繼而，花30分鐘滴加利用丙二醇單甲醚2.4質量份溶解聚合引發劑（偶氮雙異丁腈）0.1質量份而得的溶液後，在65℃下反應3小時。繼而，加入甲醇並進行稀釋，而獲得具有脂環結構及四級銨鹽的樹脂（B-2）的45質量%溶液。所得的樹脂（B-2）的重量平均分子量為1萬。(Production Example 2: Production of a resin (B-2) having an alicyclic structure and a quaternary ammonium salt) Nitrogen gas was introduced into a flask equipped with a stirring device, a reflux cooling pipe, and a nitrogen gas introduction pipe, and the air in the flask was cooled with nitrogen gas. replacement. Thereafter, 53.7 parts by mass of 2-(methacryloxy)ethyltrimethylammonium chloride, 29.3 parts by mass of cyclohexyl methacrylate, methoxypolyethylene glycol methacrylate ("Blemmer PME-1000" manufactured by NOF Corporation; number of repeating units n≒23, molecular weight 1,000) 14.6 parts by mass, 1.9 parts by mass of 2-perfluorohexylethyl acrylate, 0.5 parts by mass of methacrylic acid parts by mass, 50 parts by mass of methanol, and 10 parts by mass of propylene glycol monomethyl ether. Then, after dripping the solution which melt|dissolved 0.1 mass part of polymerization initiators (azobisisobutyronitrile) with 2.4 mass parts of propylene glycol monomethyl ethers over 30 minutes, it was made to react at 65 degreeC for 3 hours. Next, methanol was added and diluted to obtain a 45% by mass solution of a resin (B-2) having an alicyclic structure and a quaternary ammonium salt. The obtained resin (B-2) had a weight average molecular weight of 10,000.
所述所得的樹脂（B-1）及樹脂（B-2）的重量平均分子量利用凝膠滲透色譜（GPC）法在下述條件下測定。The weight average molecular weights of the obtained resin (B-1) and resin (B-2) were measured by gel permeation chromatography (GPC) under the following conditions.
測定裝置：高速GPC裝置（東曹股份有限公司製造的“HLC-8220GPC”） 管柱：將東曹股份有限公司製造的下述管柱串聯連接而使用。 “TSKgel G5000”（7.8 mmI.D.×30 cm）×1支 “TSKgel G4000”（7.8 mmI.D.×30 cm）×1支 “TSKgel G3000”（7.8 mmI.D.×30 cm）×1支 “TSKgel G2000”（7.8 mmI.D.×30 cm）×1支 檢測器：RI（示差折射計） 管柱溫度：40℃ 溶離液：四氫呋喃（Tetrahydrofuran，THF） 流速：1.0 mL/分鐘 注入量：100 μL（試樣濃度0.4質量%的四氫呋喃溶液） 標準試樣：使用下述標準聚苯乙烯而製作標準曲線。Measuring device: High-speed GPC device ("HLC-8220GPC" manufactured by Tosoh Corporation) Column: The following columns manufactured by Tosoh Corporation were connected in series and used. "TSKgel G5000" (7.8 mmI.D. × 30 cm) × 1 "TSKgel G4000" (7.8 mmI.D. × 30 cm) × 1 "TSKgel G3000" (7.8 mmI.D. × 30 cm) × 1 "TSKgel G2000" (7.8 mmI.D.×30 cm)×1 detector: RI (differential refractometer) column temperature: 40°C eluent: tetrahydrofuran (Tetrahydrofuran, THF) flow rate: 1.0 mL/min injection volume : 100 μL (tetrahydrofuran solution with a sample concentration of 0.4% by mass) Standard sample: A calibration curve was prepared using the following standard polystyrene.
（標準聚苯乙烯） 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 A-500” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 A-1000” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 A-2500” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 A-5000” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 F-1” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 F-2” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 F-4” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 F-10” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 F-20” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 F-40” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 F-80” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 F-128” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 F-288” 東曹股份有限公司製造的“TSKgel 標準聚苯乙烯 F-550”(Standard polystyrene) "TSKgel Standard Polystyrene A-500" manufactured by Tosoh Corporation "TSKgel Standard Polystyrene A-1000" manufactured by Tosoh Corporation "TSKgel Standard Polystyrene A-1000" manufactured by Tosoh Corporation Polystyrene A-2500" "TSKgel Standard Polystyrene A-5000" manufactured by Tosoh Corporation "TSKgel Standard Polystyrene F-1" manufactured by Tosoh Corporation "TSKgel Standard Polystyrene F-1" manufactured by Tosoh Corporation Standard Polystyrene F-2" "TSKgel Standard Polystyrene F-4" manufactured by Tosoh Corporation "TSKgel Standard Polystyrene F-10" manufactured by Tosoh Corporation "TSKgel Standard Polystyrene F-10" manufactured by Tosoh Corporation "TSKgel Standard Polystyrene F-20" manufactured by Tosoh Corporation "TSKgel Standard Polystyrene F-40" manufactured by Tosoh Corporation "TSKgel Standard Polystyrene F-80" manufactured by Tosoh Corporation "TSKgel Standard Polystyrene F-128" "TSKgel Standard Polystyrene F-288" manufactured by Tosoh Corporation "TSKgel Standard Polystyrene F-550" manufactured by Tosoh Corporation
[羥基價的測定方法] 活性能量線硬化性組合物的羥基價是使用日本工業標準（Japanese Industrial Standards，JIS）-K0070中記載的羥基價測定方法，以如下方式測定。 在總量燒瓶100 ml中量取乙酸酐25 g，加入吡啶而使總量為100 ml，混合均勻並將所得的混合液秤量5 ml，在其中使活性能量線硬化性化合物溶解後，在100℃下使乙酸酐與活性能量線硬化性化合物中的羥基反應1小時。在放置冷卻後，加入水1 ml並攪拌混合，進而在100℃下攪拌10分鐘，將過剩的乙酸酐分解，在放置冷卻後利用乙醇5 ml清洗燒瓶等的壁。加入數滴酚酞溶液作為指示劑，利用0.5 mol/L氫氧化鉀乙醇溶液進行滴定（滴定量β ml）。同樣地進行不使用活性能量線硬化性化合物的空白測定並進行滴定（滴定量β0 ml）。羥基價根據下述式（1）求出。 羥基價（mgKOH/g）=（β0 -β）×f×28.05/S+D（1） 其中，f：0.5 mol/L氫氧化鉀乙醇溶液的因子 S：活性能量線硬化性化合物的實際採取重量（單位：g） D：酸價（mgKOH/g）[Method for Measuring Hydroxyl Value] The hydroxyl value of the active energy ray-curable composition was measured as follows using the method for measuring the hydroxyl value described in Japanese Industrial Standards (JIS)-K0070. Measure 25 g of acetic anhydride in a 100 ml total volume flask, add pyridine to make the total volume 100 ml, mix uniformly and weigh 5 ml of the resulting mixture, dissolve the active energy ray-curing compound therein, and Acetic anhydride was reacted with the hydroxyl group in the active energy ray-curable compound at °C for 1 hour. After standing to cool, add 1 ml of water and stir to mix, then stir at 100°C for 10 minutes to decompose excess acetic anhydride, and after standing to cool, wash the walls of the flask etc. with 5 ml of ethanol. Add a few drops of phenolphthalein solution as an indicator, and use 0.5 mol/L potassium hydroxide ethanol solution for titration (titration amount β ml). Similarly, a blank measurement not using the active energy ray-curing compound was performed and titrated (titration amount β 0 ml). The hydroxyl value was determined by the following formula (1). Hydroxyl value (mgKOH/g)=(β 0 -β)×f×28.05/S+D(1) Among them, f: factor S of 0.5 mol/L potassium hydroxide ethanol solution: actual value of active energy ray hardening compound Take weight (unit: g) D: acid value (mgKOH/g)
（實施例1） 將二季戊四醇六丙烯酸酯（以下，略記為“DPHA”）100質量份、製造例1中所得的樹脂（B-1）溶液2.22質量份（作為樹脂（B-1）1質量份）、二甲基氨基丙基丙烯醯胺氯甲基四級鹽（以下，略記為“C-1”）5質量份、光聚合引發劑（1-羥基環己基苯基酮）5質量份、溶劑（乙醇/正丙醇/甲醇=85.5/9.6/4.9（質量比））100質量份均勻混合，而獲得活性能量線硬化性組合物（1）。(Example 1) 100 parts by mass of dipentaerythritol hexaacrylate (hereinafter, abbreviated as "DPHA"), 2.22 parts by mass of the resin (B-1) solution obtained in Production Example 1 (as 1 mass part of resin (B-1) parts), dimethylaminopropylacrylamide chloromethyl quaternary salt (hereinafter, abbreviated as "C-1") 5 parts by mass, photopolymerization initiator (1-hydroxycyclohexyl phenyl ketone) 5 parts by mass 100 parts by mass of a solvent (ethanol/n-propanol/methanol=85.5/9.6/4.9 (mass ratio)) were uniformly mixed to obtain an active energy ray-curable composition (1).
（實施例2、比較例1～比較例3） 除了變更為表1所示的組成以外，與實施例1同樣地進行而獲得活性能量線硬化性組合物（2）、活性能量線硬化性組合物（R1）～活性能量線硬化性組合物（R3）。(Example 2, Comparative Example 1 to Comparative Example 3) Except changing to the composition shown in Table 1, it carried out similarly to Example 1, and obtained the active energy ray-curable composition (2), the active energy ray-curable composition A substance (R1) to an active energy ray-curable composition (R3).
[評價用樣品的製作] 利用棒塗機以成為膜厚5 μm的方式將活性能量線硬化性組合物塗敷於厚度60 μm的三乙醯纖維素（Triacetyl Cellulose，TAC）膜（富士膜股份有限公司製造）上，在60℃下乾燥1.5分鐘後，在空氣環境下使用紫外線照射裝置（愛古拉飛克斯（Eye Graphics）股份有限公司製造、高壓水銀燈），以照射光量3 kJ/m2 照射，而獲得具有硬化塗膜的TAC膜作為評價用樣品。 另外，將所述評價用樣品在溫度：65℃、濕度：95%的條件下放置300小時，而將其製成耐濕熱試驗後的評價用樣品。[Preparation of samples for evaluation] The active energy ray-curable composition was coated on a 60 μm thick triacetyl cellulose (TAC) film (Fuji Film Co., Ltd. Co., Ltd.), dry at 60°C for 1.5 minutes, and then use an ultraviolet irradiation device (manufactured by Eye Graphics Co., Ltd., high-pressure mercury lamp) in an air environment to irradiate with a light intensity of 3 kJ/m 2 irradiation to obtain a TAC film having a cured coating film as a sample for evaluation. Moreover, the said sample for evaluation was left to stand under the conditions of temperature: 65 degreeC, and humidity: 95% for 300 hours, and this was made into the sample for evaluation after the heat-and-moisture resistance test.
[表面電阻值的測定（抗靜電性的評價）] 關於所述所得的評價用樣品及耐久性試驗後的評價用樣品的硬化塗膜的表面，基於JIS試驗方法K6911-1995，使用高電阻率計（三菱化學分析技術（Mitsubishi Chemical Analytech）股份有限公司製造的“海麗塔（Hiresta）UP MCP-HT450”），以施加電壓500 V、測定時間10秒測定表面電阻值。[Measurement of surface resistance value (evaluation of antistatic property)] Regarding the surface of the cured coating film of the obtained evaluation sample and the evaluation sample after the durability test, a high resistivity was used based on JIS test method K6911-1995. Using a meter (“Hiresta UP MCP-HT450” manufactured by Mitsubishi Chemical Analytech Co., Ltd.), the surface resistance value was measured with an applied voltage of 500 V and a measurement time of 10 seconds.
[耐滲出性的評價方法] 關於所述所得的評價用樣品及耐久性試驗後的評價用樣品的硬化塗膜的表面，藉由目視觀察並以如下方式評價。 “○”：未確認到滲出物。 “×”：確認到滲出物。THE EVALUATION METHOD OF BLEED RESISTANCE About the surface of the cured coating film of the sample for evaluation obtained above and the sample for evaluation after a durability test, it evaluated as follows by visual observation. "○": Exudation was not confirmed. "x": Exudation was confirmed.
[鉛筆硬度的評價方法] 關於所述所得的評價用樣品及耐久性試驗後的評價用樣品的硬化塗膜的表面，基於JIS試驗方法K5600-5-4:1999，測定鉛筆硬度。THE EVALUATION METHOD OF THE PENCIL HARDNESS About the surface of the cured coating film of the obtained evaluation sample and the evaluation sample after a durability test, pencil hardness was measured based on JIS test method K5600-5-4:1999.
[表1]
表1中所示的略語表示下述化合物。 “PETA”：季戊四醇四丙烯酸酯 “（C-2）”：2-[甲基丙烯醯氧基]乙基三甲基氯化銨The abbreviations shown in Table 1 represent the following compounds. "PETA": Pentaerythritol tetraacrylate "(C-2)": 2-[methacryloxy]ethyltrimethylammonium chloride
可確認本發明的活性能量線硬化性組合物的硬化塗膜具有優異的鉛筆硬度，表面電阻值為10的8次方～9次方等級，抗靜電性也高。另外，即便在耐濕熱試驗後，表面電阻值的變化也少，也未確認到滲出物。It was confirmed that the cured coating film of the active energy ray-curable composition of the present invention has excellent pencil hardness, a surface resistance value of 10 to the 8th power to the 9th power level, and high antistatic properties. In addition, even after the heat-and-moisture resistance test, there was little change in the surface resistance value, and bleeding was not confirmed.
另一方面，比較例1為未調配樹脂（B）的形態，但表面電阻值為10的13次方等級，抗靜電性不良。On the other hand, in Comparative Example 1, the resin (B) was not prepared, but the surface resistance value was on the order of 10 to the 13th power, and the antistatic property was poor.
比較例2為未調配化合物（C）的形態，但表面電阻值為10的11次方等級，抗靜電性不良。In Comparative Example 2, the compound (C) was not prepared, but the surface resistance value was on the order of 10 to the 11th power, and the antistatic property was poor.
比較例3也為未調配化合物（C）的形態，表面電阻值雖良好，但明顯確認到耐濕熱試驗後的滲出物。In Comparative Example 3, the compound (C) was not prepared, and the surface resistance value was good, but bleeding after the heat and humidity resistance test was clearly observed.
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