TWI762872B - Sputtering apparatus - Google Patents
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- TWI762872B TWI762872B TW109105168A TW109105168A TWI762872B TW I762872 B TWI762872 B TW I762872B TW 109105168 A TW109105168 A TW 109105168A TW 109105168 A TW109105168 A TW 109105168A TW I762872 B TWI762872 B TW I762872B
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- 238000004544 sputter deposition Methods 0.000 title claims abstract description 42
- 239000000758 substrate Substances 0.000 claims abstract description 114
- 239000010409 thin film Substances 0.000 claims abstract description 27
- 230000002093 peripheral effect Effects 0.000 claims description 23
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 7
- 229910052750 molybdenum Inorganic materials 0.000 claims description 7
- 239000011733 molybdenum Substances 0.000 claims description 7
- 230000004907 flux Effects 0.000 claims description 4
- 238000009826 distribution Methods 0.000 abstract description 18
- 239000002002 slurry Substances 0.000 abstract 1
- 210000002381 plasma Anatomy 0.000 description 51
- 239000010408 film Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 4
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001755 magnetron sputter deposition Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/3407—Cathode assembly for sputtering apparatus, e.g. Target
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/56—Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/34—Gas-filled discharge tubes operating with cathodic sputtering
- H01J37/3411—Constructional aspects of the reactor
- H01J37/3414—Targets
- H01J37/3423—Shape
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/34—Gas-filled discharge tubes operating with cathodic sputtering
- H01J37/3411—Constructional aspects of the reactor
- H01J37/345—Magnet arrangements in particular for cathodic sputtering apparatus
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Analytical Chemistry (AREA)
- Physical Vapour Deposition (AREA)
Abstract
本發明的課題是在於使薄膜的面內的特性分佈形成均一之濺射裝置的開閉作業容易。其解決手段是在以標靶側真空槽(11a)及基板側真空槽(11b)所構成的真空槽(11)之中,使電極板(28a)、(28b)的重量支撐於標靶側真空槽(11a),將電極板(28a)、(28b)配置於標靶(13)的短邊上而縮短標靶(13)與接地電位之間的距離,在基板(16)上使電漿形成均一。由於基板側真空槽(11b)的內部被輕量化,因此在使基板側真空槽(11b)移動而開閉真空槽(11)時,開閉作業變容易。An object of the present invention is to facilitate the opening and closing operation of a sputtering apparatus that makes the in-plane characteristic distribution of the thin film uniform. The solution is to support the weight of the electrode plates (28a) and (28b) on the target side in the vacuum chamber (11) composed of the target side vacuum chamber (11a) and the substrate side vacuum chamber (11b). In a vacuum chamber (11a), electrode plates (28a) and (28b) are arranged on the short sides of the target (13) to shorten the distance between the target (13) and the ground potential, and the electric The slurry is uniform. Since the inside of the substrate side vacuum chamber (11b) is reduced in weight, when the substrate side vacuum chamber (11b) is moved to open and close the vacuum chamber (11), the opening and closing operation is facilitated.
Description
本發明是有關濺射技術,特別是有關使金屬薄膜的面內的特性分佈形成均一的濺射技術。 The present invention relates to a sputtering technique, and particularly to a sputtering technique for uniformizing the in-plane characteristic distribution of a metal thin film.
根據濺射方法的薄膜形成是廣泛被使用的技術,近年來為了在大型基板形成薄膜,而被要求在大面積基板形成特性分佈均一的薄膜之技術。 Thin film formation by sputtering is a widely used technique, and in recent years, in order to form a thin film on a large substrate, a technique for forming a thin film with uniform characteristic distribution on a large area substrate is required.
圖9(平面圖與E-E線、F-F線截斷剖面圖)的電漿裝置102是在陰極電極112的表面配置有標靶(target)113,在背面設有外周磁石125及內側磁石126會被配置於軛(yoke)127的複數的磁石裝置1151~1154,一旦標靶113被濺射,則在與標靶113對面而被配置於基板配置部114上的基板116的表面形成薄膜。
In the
在基板116的外周上是配置有陽極電極117,被形成於標靶113表面的電漿會形成均一。
The
然而,隨著基板116更大型化,標靶113或磁
石裝置1151~1154跟著大型化時,在接近基板116的短邊的領域及其間的中央的部分是所被形成的薄膜的特性的差會變大。
However, when the size of the
若短邊部分的薄膜的電阻值與中央部分的薄膜的電阻值為大不同,則被形成於基板表面的發光層的發光分佈會不同,成為不均一的明亮度的畫面。 If the resistance value of the thin film in the short side portion is significantly different from that in the central portion, the light emission distribution of the light emitting layer formed on the surface of the substrate will be different, resulting in a screen with non-uniform brightness.
在下述專利文獻是記載大型基板對應的磁控濺射裝置,其配置與可移動的磁控電漿連動的接地電位電極來謀求膜質或膜厚的均一化。 The following patent documents describe a magnetron sputtering apparatus corresponding to a large-sized substrate, in which a ground potential electrode coupled with a movable magnetron plasma is arranged to achieve uniformity of film quality and film thickness.
[專利文獻1] [Patent Document 1]
日本特開平07-331433號公報 Japanese Patent Application Laid-Open No. 07-331433
本發明是為了解決上述以往技術的不合適而創作者,其目的是在於使被形成於大型基板表面的薄膜的特性分佈形成均一,特別是在於縮小接近細長的磁控磁石的端部的基板的緣附近的領域的薄膜特性與基板的中央附近的領域的薄膜特性的差。 The present invention was made in order to solve the above-mentioned inadequacy of the prior art, and its object is to make the characteristic distribution of the thin film formed on the surface of the large substrate uniform, and in particular, to reduce the size of the substrate near the end of the elongated magnetron magnet. The difference between the thin film properties of the region near the edge and the thin film properties of the region near the center of the substrate.
又,本發明的目的是在於減輕基板側真空槽的重量,使能以容易的作業進行真空槽的開閉。 Another object of the present invention is to reduce the weight of the vacuum chamber on the substrate side, and to enable opening and closing of the vacuum chamber with an easy operation.
為了解決上述課題,本發明的濺射裝置,係具有:真空槽;標靶,其係被配置於前述真空槽的內部;陰極電極,其係被配置於前述標靶的背面側,被連接至濺射電源;複數的磁石裝置,其係被配置於前述陰極電極的背面側;基板配置部,其係配置基板;及環形形狀的陽極電極,其係被連接至接地電位,覆蓋前述基板的外周上,在各前述磁石裝置係設有細長的環形形狀的外周磁石及被配置於其內側的內側磁石,在前述標靶的表面係被形成於前述外周磁石與其內側的前述內側磁石之間的磁束洩漏,前述標靶濺射而在前述基板表面形成薄膜,其特徵為:前述外周磁石與其內側的前述內側磁石係被分離,前述外周磁石與其內側的前述內側磁石之間的領域的電漿領域係被設為細長的環形形狀,前述電漿領域的兩端與前述基板的表面所位置的平面之間,係配置有被連接至接地電位的電極板, 前述電極板的表面與前述標靶的表面之間的TB距離比前述陽極電極的表面與前述標靶的表面之間的TA距離更短,在前述標靶的沿著前述電漿領域的兩端而位置的二邊上,係配置有前述電極板。 In order to solve the above-mentioned problems, a sputtering apparatus of the present invention includes: a vacuum chamber; a target arranged inside the vacuum chamber; and a cathode electrode arranged on the back side of the target and connected to the A sputtering power supply; a plurality of magnet devices arranged on the back side of the cathode electrode; a substrate arrangement part for arranging the substrate; and a ring-shaped anode electrode connected to a ground potential and covering the outer periphery of the substrate In the above, each of the magnet devices is provided with an elongated annular outer peripheral magnet and an inner magnet arranged on the inner side thereof, and on the surface of the target is a magnetic flux formed between the outer peripheral magnet and the inner magnet on the inner side. Leakage, the target is sputtered to form a thin film on the surface of the substrate, characterized in that the outer peripheral magnet and the inner magnet system on the inner side are separated, and the area between the outer peripheral magnet and the inner magnet system on the inner side is a plasma domain system. An electrode plate connected to the ground potential is arranged between the two ends of the plasma field and the plane where the surface of the substrate is located, which is formed into an elongated annular shape. The TB distance between the surface of the electrode plate and the surface of the target is shorter than the TA distance between the surface of the anode electrode and the surface of the target, at both ends of the target along the plasma field On the two sides of the position, the aforementioned electrode plates are arranged.
在本發明的濺射裝置中,前述真空槽,係設為可分離成:在內部配置有前述標靶的標靶側真空槽、及在內部配置有前述陽極電極的基板側真空槽,在前述標靶側真空槽與前述基板側真空槽緊貼而連接的狀態中,前述標靶與前述陽極電極係被配置成鉛直,前述電極板的重量係藉由述標靶側真空槽所支撐。 In the sputtering apparatus of the present invention, the vacuum chamber is separable into a target-side vacuum chamber in which the target is arranged, and a substrate-side vacuum chamber in which the anode electrode is arranged, wherein the In a state where the target-side vacuum chamber and the substrate-side vacuum chamber are in close contact with each other, the target and the anode electrode are arranged vertically, and the weight of the electrode plate is supported by the target-side vacuum chamber.
在使前述標靶側真空槽與前述基板側真空槽離時,前述標靶側真空槽為靜止的狀態,前述基板側真空槽設為移動。 When the target-side vacuum chamber is separated from the substrate-side vacuum chamber, the target-side vacuum chamber is in a stationary state, and the substrate-side vacuum chamber is moved.
在本發明的濺射裝置中,前述電極板的表面與前述標靶的表面之間的距離,係比前述標靶的表面與被配置於前述基板配置部的前述基板的表面之間的TS距離的10%大,比90%小。
In the sputtering apparatus of the present invention, the distance between the surface of the electrode plate and the surface of the target is greater than the TS distance between the surface of the target and the surface of the substrate arranged in the
在本發明的濺射裝置中,前述標靶為平板狀的金屬鉬板,前述薄膜為金屬鉬薄膜。 In the sputtering apparatus of the present invention, the target is a flat metal molybdenum plate, and the thin film is a metal molybdenum thin film.
基板表面之中,接近細長的磁控磁石的端部的區域與基板的中央的區域之間的薄膜特性的差變小,其 結果,有關形成於長方形基板的薄膜的特性,短邊附近的領域的特性與被夾於該領域的中央附近的領域的特性會形成均一。 Among the surfaces of the substrate, the difference in thin film properties between the region near the end of the elongated magnetron and the region in the center of the substrate becomes smaller, and the As a result, regarding the properties of the thin film formed on the rectangular substrate, the properties of the region near the short sides and the properties of the region sandwiched near the center of the region are uniform.
由於電極板與支撐構件被支撐於標靶側真空槽,基板側真空槽的內部被輕量化,因此在使基板側真空槽移動而開閉真空槽時,開閉作業變容易。 Since the electrode plate and the support member are supported by the target-side vacuum chamber, the inside of the substrate-side vacuum chamber is reduced in weight. Therefore, when the substrate-side vacuum chamber is moved to open and close the vacuum chamber, the opening and closing operation is facilitated.
2:濺射裝置 2: Sputtering device
10:電漿領域 10: Plasma Field
11:真空槽 11: Vacuum tank
11a:標靶側真空槽 11a: Target side vacuum tank
11b:基板側真空槽 11b: Substrate side vacuum tank
13:標靶 13: Target
14:基板配置部 14: Substrate configuration section
151~154:磁石裝置 15 1 ~15 4 : Magnet device
16:基板 16: Substrate
17:陽極電極 17: Anode electrode
28a,28b:電極板 28a, 28b: Electrode plate
22:濺射電源 22: Sputtering power supply
[圖1]是本發明的濺射裝置。 [ Fig. 1 ] is a sputtering apparatus of the present invention.
[圖2]是用以說明本發明的濺射裝置的內部構造的平面圖及其A-A線截斷剖面圖與B-B線截斷剖面圖。 2 is a plan view for explaining the internal structure of the sputtering apparatus of the present invention, and a cross-sectional view taken along line A-A and a cross-sectional view taken along line B-B.
[圖3]是用以說明被用在本發明的磁石裝置的平面圖及C-C線截斷剖面圖與D-D線截斷剖面圖。 3 is a plan view, a cross-sectional view taken along the line C-C, and a cross-sectional view taken along the line D-D for explaining the magnet device used in the present invention.
[圖4](a)~(c)是用以說明該磁石裝置的動作的剖面圖。 [ Fig. 4] (a) to (c) are cross-sectional views for explaining the operation of the magnet device.
[圖5]是用以說明本發明的其他的例子的圖。 [ Fig. 5] Fig. 5 is a diagram for explaining another example of the present invention.
[圖6]是本發明的濺射裝置的概略立體圖。 6 is a schematic perspective view of the sputtering apparatus of the present invention.
[圖7]是用以比較基板的溫度分佈的條線圖表。 [ Fig. 7 ] A bar graph for comparing temperature distributions of substrates.
[圖8]是電極板被安裝於陽極電極的濺射裝置。 8 is a sputtering apparatus in which an electrode plate is attached to an anode electrode.
[圖9]是用以說明以往技術的濺射裝置的圖。 [ Fig. 9] Fig. 9 is a diagram illustrating a conventional sputtering apparatus.
圖1的符號2是本發明的濺射裝置,具有真空槽11。圖2是比後述的陽極電極17的外周更內側的部分的
平面圖,及其A-A線截斷剖面圖與B-B線截斷剖面圖。
The code|
在真空槽11的內部是配置有長方形形狀的標靶13,在該標靶13的背面側是配置有陰極電極12。
Inside the
陰極電極12的表面是被接觸於標靶13的背面。
The surface of the
在陰極電極12的背面側是配置有磁石盒51,在磁石盒51的內部是配置有複數個(在此是4個)的磁石裝置151~154。磁石裝置151~154是被稱為磁控磁石。
A
被配置於陰極電極12的背面側的磁石裝置151~154是基本上同形狀,同大小,在圖3顯示1個的磁石裝置151~154的平面圖及其C-C線截斷剖面圖與D-D線截斷剖面圖。
The magnet devices 15 1 to 15 4 arranged on the back side of the
磁石裝置151~154是具有:環形形狀的外周磁石25,及被配置於外周磁石25之中的直線形形狀的內側磁石26,外周磁石25與內側磁石26是分別被設為細長,各磁石裝置151~154是被設為細長,各具有長度方向。
The magnet devices 15 1 to 15 4 have a ring-shaped
在此,各磁石裝置151~154的外周磁石25與標靶13的背面之間的距離是被設為相等,且各磁石裝置151~154的內側磁石26與標靶13的背面之間的距離也被設為相等,但本發明不限於此,為了使膜厚的分佈或膜質的分佈形成均一,亦可磁石裝置151~154與標靶13的背面之間的距離為彼此相異,或磁石裝置151~154與標靶13的背面之間為非平行配置。
Here, the distances between the outer
又,在此,各磁石裝置151~154的外周磁石
25與標靶13的背面之間的距離及內側磁石26與標靶13的背面之間的距離也被設為相等,但在各磁石裝置151~154之中,亦可含有內側磁石26與標靶13的背面之間的距離為相異的磁石裝置151~154,或外周磁石25與標靶13的背面之間的距離為相異的磁石裝置151~154。
Here, the distance between the outer
外周磁石25的二個的磁極之中,一方的磁極會朝向陰極電極12而配置,另一方的磁極會朝向與陰極電極12相反側,與軛27的表面接觸而配置,且內側磁石26的二個的磁極之中,一方的磁極會朝向陰極電極12而配置,另一方的磁極會朝向與陰極電極12相反側,與軛27的表面接觸而配置。
Of the two magnetic poles of the outer
朝向外周磁石25的陰極電極12的磁極,及朝向內側磁石26的陰極電極12的磁極之中,任一一方的磁極為N極,另一方的磁極為S極,在朝向陰極電極12的磁極間所形成的磁束是被洩漏至標靶13的表面,被彎曲成拱形形狀,而使標靶13表面的電子密度增加。
Among the magnetic poles facing the
在真空槽11內之與標靶13的表面對面的位置是配置台54,在台54上是配置有基板配置部14。
A position in the
基板配置部14是長方形形狀,在基板配置部14上是配置有成膜對象的長方形的基板16。
The
基板16是比標靶13更小,以下,若以投影至基板配置部14上的基板16的表面所位置的平面時的位置關係來決定內側與外側,則基板16的外周是比標靶13的外周更配置於內側。
The
標靶13與基板16是被配置為標靶13的長邊與基板16的長邊是平行,標靶13的表面與基板16的表面也被配置為平行。
The
磁石裝置151~154的長度方向的長度是與標靶13的長度方的長度大致同長度,基板16的長邊是比標靶13的長度方向的長度更短,且基板16的長邊是比磁石裝置151~154的長度方向的長度更短。
The length of the magnet devices 15 1 to 15 4 in the longitudinal direction is substantially the same as the length of the
各磁石裝置151~154是在軛27的背面側接觸於移動板52的狀態下被配置於移動板52上。
Each of the magnet devices 15 1 to 15 4 is arranged on the moving
各磁石裝置151~154是長度方向彼此平行,與標靶13及基板16的長邊平行,在短邊所延伸的方向排成一列。
The longitudinal directions of the respective magnet devices 15 1 to 15 4 are parallel to each other, parallel to the long sides of the
在真空槽11的外部是配置有移動裝置53,一旦移動裝置53動作,則移動板52是在標靶13的背面側沿著標靶13的表面而移動,各磁石裝置151~154是與移動板52一起移動。
A moving
洩漏至標靶13的表面的磁束是與磁石裝置151~154的移動共同移動。
The magnetic flux leaking to the surface of the
在移動時,各磁石裝置151~154是在外周磁石25與標靶13的背面之間的距離無變化,維持一定距離。並且,在內側磁石26與標靶13的背面之間的距離無變化,維持一定距離。
During the movement, each of the magnet devices 15 1 to 15 4 maintains a constant distance without changing the distance between the outer
因此,各磁石裝置151~154是與移動板52的移動共同一起移動於與標靶13的背面平行的平面內。圖
4(a)是表示各磁石裝置151~154位於各磁石裝置151~154的各者所移動的範圍的中央的狀態,同圖(b)是表示位於圖面右端的狀態,同圖(c)是表示位於圖面左端的狀態,重複移動於同圖(b)的狀態與同圖(c)的狀態之間。
Therefore, each of the magnet devices 15 1 to 15 4 moves in a plane parallel to the back surface of the
其次,在基板16與標靶13之間是配置有被連接至接地電位的陽極電極17。
Next, between the
陽極電極17是四角環形形狀,在中央形成有開口19。陽極電極17的外周與內周是長方形形狀,陽極電極17的外周是位於比被配置於基板配置部14的基板16的外周更外側。
The
在此例中,陽極電極17的內周是位於比基板16的緣更接近基板16的中央的區域,陽極電極17的四角環形形狀的二個的長邊部分是被配置於基板16的長邊上,二個的短邊部分是被配置於基板16的短邊上,基板配置部14上的基板16的外周是藉由陽極電極17所覆蓋,在開口19的底面是比基板16的外周更內側的部分會露出。
In this example, the inner circumference of the
在真空槽11是連接有真空排氣裝置21及氣體導入裝置23,真空槽11是藉由真空排氣裝置21來真空排氣,在真空槽11的內部是形成真空環境。
A
在真空槽11的外部是設有被電性連接至陰極電極12的濺射電源22,從氣體導入裝置23導入濺射氣體至形成真空環境的真空槽11的內部,內部在預定壓力安定時,從濺射電源22施加濺射電壓至陰極電極12。
Outside the
標靶13是金屬被板狀地成形的平板狀標靶,
邊使磁石裝置151~154移動,邊在標靶13的表面附近形成濺射氣體的電漿。
The
電漿中的濺射氣體的正離子被加速,濺射氣體的粒子會射入至標靶13,標靶13被濺射,構成標靶13的物質的粒子會作為濺射粒子從標靶13的表面放出朝向基板16飛行,到達基板16的表面而使薄膜成長。
The positive ions of the sputtering gas in the plasma are accelerated, the particles of the sputtering gas will be injected into the
一旦在基板16的表面形成預定膜厚的薄膜,則基板配置部14與基板16被搬出至真空槽11的外部,配置有未成膜的基板16的基板配置部14會被搬入至真空槽11的內部。
Once a thin film of a predetermined thickness is formed on the surface of the
如此藉由本發明在基板16的表面形成薄膜,但在大型的基板16表面形成的金屬薄膜的電阻值是依基板16的位置而異。
In this way, the thin film is formed on the surface of the
電阻值的分佈是具有與電漿的強度分佈密接的關聯,若說明本濺射裝置2的電漿,則首先在位於各磁石裝置151~154的外周磁石25與內側磁石26之間的標靶13的表面形成大的強度的電漿的點具有磁控濺射的特徵。
The distribution of the resistance value has a close relationship with the intensity distribution of the plasma. When describing the plasma of the
各磁石裝置151~154的外周磁石25是為了擴大被濺射的標靶的面積,而被設為細長的環形形狀,由於內側磁石26是直線形形狀,因此外周磁石25與內側磁石26之間的間隙是形成細長的環形形狀。因為電漿是形成與間隙同形狀,所以被形成的強度大的電漿也按每個磁石裝置151~154形成環形形狀。
The outer
細長的環形形狀的電漿是端部比直線部分更 電漿強度大為人所知。特別是因為各磁石裝置151~154的端部被配置成一直線,所以複數的細長的環形形狀的電漿的端部會在被配置成一直線的狀態下彼此平行排列,環形形狀的電漿的端部被排列的部分的電漿強度會比環形形狀的電漿的長邊的部分的電漿強度更大。 The elongated annular shape of the plasma is known to have greater plasma intensity at the ends than in the straight portion. In particular, since the ends of the magnet devices 15 1 to 15 4 are arranged in a straight line, the ends of the plurality of elongated annular-shaped plasmas are aligned in parallel with each other in a state of being arranged in a straight line, and the annular-shaped plasmas are arranged in a straight line. The plasma intensity of the portion where the ends of the ring-shaped plasma are aligned will be greater than the plasma intensity of the portion of the long side of the plasma of the annular shape.
被排列的端部的電漿是在基板16的短邊的附近使薄膜成長,電漿的長邊部分是在基板16的長邊的附近使薄膜成長時,在基板16表面的中央的區域及短邊附近的區域以及長邊附近的區域,薄膜的特性會相異。
The plasma at the arranged end portion grows the thin film in the vicinity of the short side of the
與各磁石裝置151~154的端部被排列的領域平行地分別配置陽極電極17的短邊,在陽極電極17的二個的短邊部分上的比基板16的緣更外側是分別配置有電極板28a、28b。
The short sides of the
濺射前的未使用的標靶13是與陰極電極12、電極板28a、28b、及陽極電極17互相平行。
The
二個的電極板28a、28b是互相平行,比標靶13的短邊更長,分別具有與標靶13的短邊33a、33b平行、與陽極電極17的短邊平行、及與陰極電極12的短邊平行的二條的緣31a、31b、32a、32b。
The two
與標靶13的短邊33a、33b平行的各電極板28a、28b的二條的緣31a、31b、32a、32b之中,一方的緣31a、31b是位於比標靶13的短邊更外側,另一方的緣32a、32b是位於比短邊更接近標靶13的中心的地方。
Of the two
因此,標靶13的短邊33a、33b附近是藉由電
極板28a、28b從短邊33a、33b到內側僅一定距離覆蓋。
Therefore, the vicinity of the
陰極電極12是經由絕緣板24來固定於真空槽11的壁面,陰極電極12與真空槽11是藉由絕緣板24來絕緣。在真空槽11的壁面是設有環形形狀的防著環36,標靶13是被配置於防著環36的內側。標靶13的外周面與防著環36的內周面是隔開預定距離而配置。
The
防著環36之中,在側面與標靶13的短邊33a、33b所位置的側面對面的部分的表面上安裝有支撐體29a、29b,電極板28a、28b是被安裝於支撐體29a、29b。
電極板28a、28b、防著環36及支撐體29a、29b是具有導電性,電極板28a、28b是經由支撐體29a、29b來電性連接至防著環36。
The
真空槽11是被連接至接地電位,防著環36是接觸於真空槽11,被連接至接地電位,因此電極板28a、28b是被連接至接地電位。陽極電極17也被連接至接地電位。
The
若將各磁石裝置151~154的外周磁石25與位於其內側的內側磁石26之間的領域分別設為磁石裝置151~154的電漿領域10,則各磁石裝置151~154的外周磁石25的兩端是被彎曲成半圓形,隨之,電漿領域10的兩端也被彎曲成半圓形,其結果,外周磁石25與電漿領域10是分別形成跑道形形狀。
If the areas between the outer
各磁石裝置151~154的電漿領域10的長度方向的長度是相等,各電漿領域10是與陽極電極17所位置的
平面之間的距離相等,各電漿領域10的兩端的彎曲的部分之中的一方的端部的彎曲的部分是排列成橫一列,相反側的端部的彎曲的部分也排列成橫一列。
The lengths in the longitudinal direction of the
各電漿領域10的兩端的彎曲的部分之中,一方的端部,在排列成橫一列的彎曲的部分與基板16的表面所位置的平面之間是配置有一片的電極板28a,相反側的端部,在排列成橫一列的彎曲的部分與基板16的表面所位置的平面之間是配置有其他的一片的電極板28b。
Among the curved portions at both ends of each
標靶13的表面是在陽極電極17的長邊部分上與陽極電極17的長邊部分相向,在陽極電極17的短邊部分上與電極板28a、28b的表面相向。
The surface of the
若將標靶13表面與基板16表面之間的距離設為TS距離,將標靶13表面與陽極電極17的長邊部分的表面之間的距離設為TA距離,將標靶13的表面與電極板28a、28b的表面之間的距離設為TB距離,則其次的三式成立。
Assuming that the distance between the surface of the
TA<TS,TB<TS,TB<TA TA<TS, TB<TS, TB<TA
在基板16的長邊的正旁邊位置,最接近標靶13的接地電位的構件是陽極電極17之與標靶13對面的表面,在基板16的長邊的正旁邊位置,標靶13與最接近標靶13的接地電位的構件的表面之間是僅分離TA距離。
At the position directly next to the long side of the
在基板16的短邊的正旁邊位置,最接近標靶13的接地電位的構件是電極板28a、28b之與標靶13對面的表面,在基板16的短邊的正旁邊位置,標靶13與最接近標靶13的接地電位的構件的表面之間是僅分離TB距離。
At the position immediately beside the short side of the
因此,標靶13與最接近標靶13的接地電位的構件的表面之間的距離是基板16的短邊的正旁邊位置比長邊的正旁邊位置更短。
Therefore, the distance between the
特別是藉由電極板28a、28b,在比基板16的緣更外側,標靶13與接地電位之間的距離變短,電極板28a、28b會吸引比基板16的緣更內側的電漿,因此在比基板16的緣更外側,電極板28a、28b所位置的基板16的短邊的外側的電漿強度變強,其結果,接近基板16的短邊的基板16上的電漿強度變小。總而言之,無電極板28a、28b時,接近基板16上的電漿領域10的長度方向的兩端的部分的電漿是比基板16上的其他的部分的電漿更強度變大,但藉由設置電極板28a、28b,接近基板16上的電漿領域10的長度方向的兩端的部分的電漿強度變小,其結果,基板16上的電漿強度會被均一化,被形成的薄膜的特性分佈會被均一化。
In particular, by the
TB距離是若不比標靶13的表面與被配置於基板配置部14的基板16的表面之間的TS距離的10%大,則反而特性分佈惡化,若不比90%小,則效果變弱的情形被確認。
If the TB distance is not larger than 10% of the TS distance between the surface of the
在電漿領域10的兩端之彎曲的部分上設有電極板28a、28b,若與標靶13表面對面,則與接地電位的構件之間的距離是電極板28a、28b與標靶13之間最短。如上述般,電極板28a、28b上的電漿強度會增大。
電極板28a、28b是被配置於比基板16更外
側,基板16的外側的電漿強度增大的結果,基板16上之中,在電極板28a、28b接近的基板16的緣附近是電漿強度會減少,因此基板16上的電漿強度會被均一化,基板16的表面內的電阻值分佈會形成均一。
The
其次,若說明本發明的真空槽11,則本發明的真空槽11是以標靶側真空槽11a及基板側真空槽11b所構成。標靶側真空槽11a與基板側真空槽11b是緣部分可緊貼,在緊貼的狀態下形成氣密的真空槽。
Next, if the
在本發明中,陰極電極12、標靶13、防著環36及陽極電極17是形成鉛直,陰極電極12是經由鉛直的絕緣板24來安裝於標靶側真空槽11a的形成鉛直的壁面。防著環36是被安裝於同壁面。
In the present invention, the
標靶13是被設在陰極電極12之與接觸於絕緣板24的面相反側的面,而位於防著環36的內周。
The
電極板28a、28b也經由支撐體29a、29b與防著環36來被安裝於固定有陰極電極12、標靶13及防著環36的壁面。因此,電極板28a、28b的重量是藉由標靶側真空槽11a來支撐。
The
濺射時,標靶側真空槽11a與基板側真空槽11b是被氣密地連接,在基板側真空槽11b的內部是設有形成鉛直的陽極電極17,基板配置部14及被配置於基板配置部14的基板16會在形成鉛直的狀態下從真空槽11的外部搬入至內部,被配置於陽極電極17與基板側真空槽11b的形成鉛直的壁面之間。
During sputtering, the target-
維修時,真空槽11的內部為常壓,如圖6的概略立體圖般,標靶側真空槽11a與基板側真空槽11b會被分離。
During maintenance, the inside of the
圖6的符號55是台座,標靶側真空槽11a是被設在台座55,對於地面固定。因此,標靶側真空槽11a的重量是藉由台座55來支撐。
相對於此,基板側真空槽11b是未被固定於台座55,氣密地被安裝於標靶側真空槽11a。在圖6中,支撐體29a、29b是被省略。
On the other hand, the substrate-
此圖6是標靶側真空槽11a不使移動,使基板側真空槽11b移動來使標靶側真空槽11a與基板側真空槽11b分離的狀態,支撐體29a、29b與電極板28a、28b是重量會經由標靶側真空槽11a來被台座55支撐。
6 shows a state in which the target-
圖8是從真空槽11的壁面除去本發明的電極板28a、28b與支撐體29a、29b,藉由支撐體39a、39b來將電極板18a、18b設於陽極電極17上時的濺射裝置132。
8 shows the sputtering apparatus when
在本發明的濺射裝置2及此圖8的濺射裝置132的基板面內的複數的同地方測定溫度。將測定結果顯示於圖7的圖表。溫度分佈是可謂大致相同。
Temperatures were measured at plural same places in the substrate surface of the
並且,在本發明的濺射裝置2形成鉬薄膜時的薄膜電阻值Rs是0.0760Ω/□±18.7%,膜厚分佈是3915ű14.6%。
In addition, the sheet resistance value Rs when the molybdenum thin film was formed in the
在圖8的濺射裝置132是與0.0804Ω/□±18.2%同程度,膜厚分佈是3805ű14.1%,同等的特性。
In the
將膜厚分佈顯示下表。 The film thickness distribution is shown in the table below.
但,圖8的濺射裝置132的情況,電極板18a、18b與支撐體39a、39b是經由陽極電極17來被支撐於基板側真空槽,因此從標靶側真空槽分離的基板側真空槽
的內部的重量變大,標靶側真空槽與基板側真空槽之間的分離形成困難的作業。
However, in the case of the
另外,二個的支撐體29a、29b是分別為一片的板,但如圖5所示的濺射裝置3般,亦可分別以3個的支撐體29c、29d來支撐一片的電極板28a、28b。
In addition, the two
又,電漿領域10是只要為無端狀、環形形狀即可,外周磁石25的兩端為方形的情況或為橢圓形的情況也含在本發明。
In addition, the
又,不將各磁石裝置151~154的端部配置於同一直線上的情況,或不將各磁石裝置151~154的端部與陰極電極12的距離形成一定的情況也含在本發明。
In addition, the case where the ends of the magnet devices 15 1 to 15 4 are not arranged on the same straight line, or the case where the distance between the ends of the magnet devices 15 1 to 15 4 and the
另外,上述電極板28a、28b是位於陽極電極17的邊上,平行的二邊之中的一邊會比基板16的邊更外側,其他的一邊會位於比標靶13的邊更內側。
In addition, the
二個的電極板28a、28b是分別具有平行的二邊的形狀,電極板28a、28b是例如為長方形形狀。
The two
電漿領域10的兩端之中,電漿領域10的一方的端部之排成一列的彎曲的部分與基板16的表面所位置的平面之間配置有一片的電極板28a,電漿領域10的相反側的端部之配成一列的彎曲的部分與基板16的表面所位置的平面之間配置有其他的一片的電極板28b。
Among both ends of the
又,電極板28a、28b的二邊之中,離標靶13的中心遠的邊是亦可伸出至電漿領域10的彎曲的部分的外側,離標靶13的中心近的邊是亦可伸出至電漿領域10的彎
曲的部分的內側。又,亦可從雙方伸出。
In addition, among the two sides of the
另外,上述標靶13為金屬鉬,本發明是不限於金屬鉬,本發明的濺射裝置2是對於由金屬鈦、鉬合金、鋁、鋁合金、金屬鎢、純銅、銅合金、鉭等的金屬所成的標靶13可取得本發明的效果。
In addition, the above-mentioned
2:濺射裝置 2: Sputtering device
11:真空槽 11: Vacuum tank
11a:標靶側真空槽 11a: Target side vacuum tank
11b:基板側真空槽 11b: Substrate side vacuum tank
12:陰極電極 12: Cathode electrode
13:標靶 13: Target
14:基板配置部 14: Substrate configuration section
151~154:磁石裝置 15 1 ~15 4 : Magnet device
16:基板 16: Substrate
17:陽極電極 17: Anode electrode
19:開口 19: Opening
21:真空排氣裝置 21: Vacuum exhaust device
22:濺射電源 22: Sputtering power supply
23:氣體導入裝置 23: Gas introduction device
24:絕緣板 24: Insulation board
28a:電極板 28a: Electrode plate
29a:支撐體 29a: Support body
36:防著環 36: Anti-lock ring
51:磁石盒 51: Magnet Box
52:移動板 52: Mobile board
53:移動裝置 53: Mobile Devices
54:配置台 54: Configuration Desk
Claims (3)
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| JP2019118165A JP6982597B2 (en) | 2019-06-26 | 2019-06-26 | Sputtering equipment |
| JP2019-118165 | 2019-06-26 |
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| TW202100780A TW202100780A (en) | 2021-01-01 |
| TWI762872B true TWI762872B (en) | 2022-05-01 |
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| KR (1) | KR102478616B1 (en) |
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Citations (5)
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|---|---|---|---|---|
| JP2000248360A (en) * | 1999-03-01 | 2000-09-12 | Sharp Corp | Magnetron sputtering equipment |
| JP2000273628A (en) * | 1999-03-29 | 2000-10-03 | Matsushita Electric Ind Co Ltd | Sputtering method and apparatus |
| TW201315705A (en) * | 2011-09-06 | 2013-04-16 | 出光興產股份有限公司 | Sputter target |
| TW201812065A (en) * | 2016-06-21 | 2018-04-01 | 日商愛發科股份有限公司 | Target device, sputtering apparatus |
| TW201912827A (en) * | 2017-09-07 | 2019-04-01 | 日商愛發科股份有限公司 | Sputtering device |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07331433A (en) * | 1994-06-07 | 1995-12-19 | Hitachi Ltd | Sputtering device |
| JPH09111448A (en) * | 1995-10-16 | 1997-04-28 | Ulvac Japan Ltd | Sputtering device |
| JPH1192927A (en) * | 1997-09-17 | 1999-04-06 | Hitachi Ltd | Magnetron sputtering equipment |
| JP2001335930A (en) * | 2000-05-25 | 2001-12-07 | Matsushita Electric Ind Co Ltd | Thin film forming equipment |
| JP4246547B2 (en) * | 2003-05-23 | 2009-04-02 | 株式会社アルバック | Sputtering apparatus and sputtering method |
| JP4713853B2 (en) * | 2004-07-07 | 2011-06-29 | 株式会社アルバック | Magnetron cathode electrode and sputtering method using magnetron cathode electrode |
| JP5049561B2 (en) * | 2006-11-17 | 2012-10-17 | 株式会社アルバック | Magnetron sputtering electrode and sputtering apparatus provided with magnetron sputtering electrode |
| JP5286351B2 (en) * | 2008-03-17 | 2013-09-11 | 株式会社アルバック | Magnetron sputtering apparatus and magnetron sputtering method |
-
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000248360A (en) * | 1999-03-01 | 2000-09-12 | Sharp Corp | Magnetron sputtering equipment |
| JP2000273628A (en) * | 1999-03-29 | 2000-10-03 | Matsushita Electric Ind Co Ltd | Sputtering method and apparatus |
| TW201315705A (en) * | 2011-09-06 | 2013-04-16 | 出光興產股份有限公司 | Sputter target |
| TW201812065A (en) * | 2016-06-21 | 2018-04-01 | 日商愛發科股份有限公司 | Target device, sputtering apparatus |
| TW201912827A (en) * | 2017-09-07 | 2019-04-01 | 日商愛發科股份有限公司 | Sputtering device |
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| TW202100780A (en) | 2021-01-01 |
| JP6982597B2 (en) | 2021-12-17 |
| KR20210001904A (en) | 2021-01-06 |
| CN112144026B (en) | 2022-09-09 |
| KR102478616B1 (en) | 2022-12-16 |
| JP2021004390A (en) | 2021-01-14 |
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