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TWI762872B - Sputtering apparatus - Google Patents

Sputtering apparatus Download PDF

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TWI762872B
TWI762872B TW109105168A TW109105168A TWI762872B TW I762872 B TWI762872 B TW I762872B TW 109105168 A TW109105168 A TW 109105168A TW 109105168 A TW109105168 A TW 109105168A TW I762872 B TWI762872 B TW I762872B
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target
substrate
vacuum chamber
magnet
electrode
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TW109105168A
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Chinese (zh)
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TW202100780A (en
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大久保裕夫
小林大士
小野貴裕
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日商愛發科股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/35Sputtering by application of a magnetic field, e.g. magnetron sputtering
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3407Cathode assembly for sputtering apparatus, e.g. Target
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/56Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3411Constructional aspects of the reactor
    • H01J37/3414Targets
    • H01J37/3423Shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3411Constructional aspects of the reactor
    • H01J37/345Magnet arrangements in particular for cathodic sputtering apparatus

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Analytical Chemistry (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

本發明的課題是在於使薄膜的面內的特性分佈形成均一之濺射裝置的開閉作業容易。其解決手段是在以標靶側真空槽(11a)及基板側真空槽(11b)所構成的真空槽(11)之中,使電極板(28a)、(28b)的重量支撐於標靶側真空槽(11a),將電極板(28a)、(28b)配置於標靶(13)的短邊上而縮短標靶(13)與接地電位之間的距離,在基板(16)上使電漿形成均一。由於基板側真空槽(11b)的內部被輕量化,因此在使基板側真空槽(11b)移動而開閉真空槽(11)時,開閉作業變容易。An object of the present invention is to facilitate the opening and closing operation of a sputtering apparatus that makes the in-plane characteristic distribution of the thin film uniform. The solution is to support the weight of the electrode plates (28a) and (28b) on the target side in the vacuum chamber (11) composed of the target side vacuum chamber (11a) and the substrate side vacuum chamber (11b). In a vacuum chamber (11a), electrode plates (28a) and (28b) are arranged on the short sides of the target (13) to shorten the distance between the target (13) and the ground potential, and the electric The slurry is uniform. Since the inside of the substrate side vacuum chamber (11b) is reduced in weight, when the substrate side vacuum chamber (11b) is moved to open and close the vacuum chamber (11), the opening and closing operation is facilitated.

Description

濺射裝置Sputtering device

本發明是有關濺射技術,特別是有關使金屬薄膜的面內的特性分佈形成均一的濺射技術。 The present invention relates to a sputtering technique, and particularly to a sputtering technique for uniformizing the in-plane characteristic distribution of a metal thin film.

根據濺射方法的薄膜形成是廣泛被使用的技術,近年來為了在大型基板形成薄膜,而被要求在大面積基板形成特性分佈均一的薄膜之技術。 Thin film formation by sputtering is a widely used technique, and in recent years, in order to form a thin film on a large substrate, a technique for forming a thin film with uniform characteristic distribution on a large area substrate is required.

圖9(平面圖與E-E線、F-F線截斷剖面圖)的電漿裝置102是在陰極電極112的表面配置有標靶(target)113,在背面設有外周磁石125及內側磁石126會被配置於軛(yoke)127的複數的磁石裝置1151~1154,一旦標靶113被濺射,則在與標靶113對面而被配置於基板配置部114上的基板116的表面形成薄膜。 In the plasma device 102 of FIG. 9 (a plan view and a cross-sectional view taken along lines EE and FF), a target 113 is arranged on the front surface of the cathode electrode 112 , and an outer peripheral magnet 125 and an inner magnet 126 are arranged on the back surface. When the target 113 is sputtered, the plural magnet devices 115 1 to 115 4 of the yoke 127 form a thin film on the surface of the substrate 116 arranged on the substrate arrangement portion 114 opposite to the target 113 .

在基板116的外周上是配置有陽極電極117,被形成於標靶113表面的電漿會形成均一。 The anode electrode 117 is arranged on the outer periphery of the substrate 116, and the plasma formed on the surface of the target 113 is uniform.

然而,隨著基板116更大型化,標靶113或磁 石裝置1151~1154跟著大型化時,在接近基板116的短邊的領域及其間的中央的部分是所被形成的薄膜的特性的差會變大。 However, when the size of the target 113 or the magnet devices 115 1 to 115 4 increases as the size of the substrate 116 increases, the area close to the short sides of the substrate 116 and the central portion therebetween are characteristics of the thin film to be formed. The difference will get bigger.

若短邊部分的薄膜的電阻值與中央部分的薄膜的電阻值為大不同,則被形成於基板表面的發光層的發光分佈會不同,成為不均一的明亮度的畫面。 If the resistance value of the thin film in the short side portion is significantly different from that in the central portion, the light emission distribution of the light emitting layer formed on the surface of the substrate will be different, resulting in a screen with non-uniform brightness.

在下述專利文獻是記載大型基板對應的磁控濺射裝置,其配置與可移動的磁控電漿連動的接地電位電極來謀求膜質或膜厚的均一化。 The following patent documents describe a magnetron sputtering apparatus corresponding to a large-sized substrate, in which a ground potential electrode coupled with a movable magnetron plasma is arranged to achieve uniformity of film quality and film thickness.

[先前技術文獻] [Prior Art Literature] [專利文獻] [Patent Literature]

[專利文獻1] [Patent Document 1]

日本特開平07-331433號公報 Japanese Patent Application Laid-Open No. 07-331433

本發明是為了解決上述以往技術的不合適而創作者,其目的是在於使被形成於大型基板表面的薄膜的特性分佈形成均一,特別是在於縮小接近細長的磁控磁石的端部的基板的緣附近的領域的薄膜特性與基板的中央附近的領域的薄膜特性的差。 The present invention was made in order to solve the above-mentioned inadequacy of the prior art, and its object is to make the characteristic distribution of the thin film formed on the surface of the large substrate uniform, and in particular, to reduce the size of the substrate near the end of the elongated magnetron magnet. The difference between the thin film properties of the region near the edge and the thin film properties of the region near the center of the substrate.

又,本發明的目的是在於減輕基板側真空槽的重量,使能以容易的作業進行真空槽的開閉。 Another object of the present invention is to reduce the weight of the vacuum chamber on the substrate side, and to enable opening and closing of the vacuum chamber with an easy operation.

為了解決上述課題,本發明的濺射裝置,係具有:真空槽;標靶,其係被配置於前述真空槽的內部;陰極電極,其係被配置於前述標靶的背面側,被連接至濺射電源;複數的磁石裝置,其係被配置於前述陰極電極的背面側;基板配置部,其係配置基板;及環形形狀的陽極電極,其係被連接至接地電位,覆蓋前述基板的外周上,在各前述磁石裝置係設有細長的環形形狀的外周磁石及被配置於其內側的內側磁石,在前述標靶的表面係被形成於前述外周磁石與其內側的前述內側磁石之間的磁束洩漏,前述標靶濺射而在前述基板表面形成薄膜,其特徵為:前述外周磁石與其內側的前述內側磁石係被分離,前述外周磁石與其內側的前述內側磁石之間的領域的電漿領域係被設為細長的環形形狀,前述電漿領域的兩端與前述基板的表面所位置的平面之間,係配置有被連接至接地電位的電極板, 前述電極板的表面與前述標靶的表面之間的TB距離比前述陽極電極的表面與前述標靶的表面之間的TA距離更短,在前述標靶的沿著前述電漿領域的兩端而位置的二邊上,係配置有前述電極板。 In order to solve the above-mentioned problems, a sputtering apparatus of the present invention includes: a vacuum chamber; a target arranged inside the vacuum chamber; and a cathode electrode arranged on the back side of the target and connected to the A sputtering power supply; a plurality of magnet devices arranged on the back side of the cathode electrode; a substrate arrangement part for arranging the substrate; and a ring-shaped anode electrode connected to a ground potential and covering the outer periphery of the substrate In the above, each of the magnet devices is provided with an elongated annular outer peripheral magnet and an inner magnet arranged on the inner side thereof, and on the surface of the target is a magnetic flux formed between the outer peripheral magnet and the inner magnet on the inner side. Leakage, the target is sputtered to form a thin film on the surface of the substrate, characterized in that the outer peripheral magnet and the inner magnet system on the inner side are separated, and the area between the outer peripheral magnet and the inner magnet system on the inner side is a plasma domain system. An electrode plate connected to the ground potential is arranged between the two ends of the plasma field and the plane where the surface of the substrate is located, which is formed into an elongated annular shape. The TB distance between the surface of the electrode plate and the surface of the target is shorter than the TA distance between the surface of the anode electrode and the surface of the target, at both ends of the target along the plasma field On the two sides of the position, the aforementioned electrode plates are arranged.

在本發明的濺射裝置中,前述真空槽,係設為可分離成:在內部配置有前述標靶的標靶側真空槽、及在內部配置有前述陽極電極的基板側真空槽,在前述標靶側真空槽與前述基板側真空槽緊貼而連接的狀態中,前述標靶與前述陽極電極係被配置成鉛直,前述電極板的重量係藉由述標靶側真空槽所支撐。 In the sputtering apparatus of the present invention, the vacuum chamber is separable into a target-side vacuum chamber in which the target is arranged, and a substrate-side vacuum chamber in which the anode electrode is arranged, wherein the In a state where the target-side vacuum chamber and the substrate-side vacuum chamber are in close contact with each other, the target and the anode electrode are arranged vertically, and the weight of the electrode plate is supported by the target-side vacuum chamber.

在使前述標靶側真空槽與前述基板側真空槽離時,前述標靶側真空槽為靜止的狀態,前述基板側真空槽設為移動。 When the target-side vacuum chamber is separated from the substrate-side vacuum chamber, the target-side vacuum chamber is in a stationary state, and the substrate-side vacuum chamber is moved.

在本發明的濺射裝置中,前述電極板的表面與前述標靶的表面之間的距離,係比前述標靶的表面與被配置於前述基板配置部的前述基板的表面之間的TS距離的10%大,比90%小。 In the sputtering apparatus of the present invention, the distance between the surface of the electrode plate and the surface of the target is greater than the TS distance between the surface of the target and the surface of the substrate arranged in the substrate arrangement portion 10% larger than 90%.

在本發明的濺射裝置中,前述標靶為平板狀的金屬鉬板,前述薄膜為金屬鉬薄膜。 In the sputtering apparatus of the present invention, the target is a flat metal molybdenum plate, and the thin film is a metal molybdenum thin film.

基板表面之中,接近細長的磁控磁石的端部的區域與基板的中央的區域之間的薄膜特性的差變小,其 結果,有關形成於長方形基板的薄膜的特性,短邊附近的領域的特性與被夾於該領域的中央附近的領域的特性會形成均一。 Among the surfaces of the substrate, the difference in thin film properties between the region near the end of the elongated magnetron and the region in the center of the substrate becomes smaller, and the As a result, regarding the properties of the thin film formed on the rectangular substrate, the properties of the region near the short sides and the properties of the region sandwiched near the center of the region are uniform.

由於電極板與支撐構件被支撐於標靶側真空槽,基板側真空槽的內部被輕量化,因此在使基板側真空槽移動而開閉真空槽時,開閉作業變容易。 Since the electrode plate and the support member are supported by the target-side vacuum chamber, the inside of the substrate-side vacuum chamber is reduced in weight. Therefore, when the substrate-side vacuum chamber is moved to open and close the vacuum chamber, the opening and closing operation is facilitated.

2:濺射裝置 2: Sputtering device

10:電漿領域 10: Plasma Field

11:真空槽 11: Vacuum tank

11a:標靶側真空槽 11a: Target side vacuum tank

11b:基板側真空槽 11b: Substrate side vacuum tank

13:標靶 13: Target

14:基板配置部 14: Substrate configuration section

151~154:磁石裝置 15 1 ~15 4 : Magnet device

16:基板 16: Substrate

17:陽極電極 17: Anode electrode

28a,28b:電極板 28a, 28b: Electrode plate

22:濺射電源 22: Sputtering power supply

[圖1]是本發明的濺射裝置。 [ Fig. 1 ] is a sputtering apparatus of the present invention.

[圖2]是用以說明本發明的濺射裝置的內部構造的平面圖及其A-A線截斷剖面圖與B-B線截斷剖面圖。 2 is a plan view for explaining the internal structure of the sputtering apparatus of the present invention, and a cross-sectional view taken along line A-A and a cross-sectional view taken along line B-B.

[圖3]是用以說明被用在本發明的磁石裝置的平面圖及C-C線截斷剖面圖與D-D線截斷剖面圖。 3 is a plan view, a cross-sectional view taken along the line C-C, and a cross-sectional view taken along the line D-D for explaining the magnet device used in the present invention.

[圖4](a)~(c)是用以說明該磁石裝置的動作的剖面圖。 [ Fig. 4] (a) to (c) are cross-sectional views for explaining the operation of the magnet device.

[圖5]是用以說明本發明的其他的例子的圖。 [ Fig. 5] Fig. 5 is a diagram for explaining another example of the present invention.

[圖6]是本發明的濺射裝置的概略立體圖。 6 is a schematic perspective view of the sputtering apparatus of the present invention.

[圖7]是用以比較基板的溫度分佈的條線圖表。 [ Fig. 7 ] A bar graph for comparing temperature distributions of substrates.

[圖8]是電極板被安裝於陽極電極的濺射裝置。 8 is a sputtering apparatus in which an electrode plate is attached to an anode electrode.

[圖9]是用以說明以往技術的濺射裝置的圖。 [ Fig. 9] Fig. 9 is a diagram illustrating a conventional sputtering apparatus.

圖1的符號2是本發明的濺射裝置,具有真空槽11。圖2是比後述的陽極電極17的外周更內側的部分的 平面圖,及其A-A線截斷剖面圖與B-B線截斷剖面圖。 The code|symbol 2 of FIG. 1 is the sputtering apparatus of this invention, and has the vacuum chamber 11. As shown in FIG. FIG. 2 shows a portion inside the outer periphery of the anode electrode 17 to be described later. Plan view, and its A-A line truncated sectional view and B-B line truncated sectional view.

在真空槽11的內部是配置有長方形形狀的標靶13,在該標靶13的背面側是配置有陰極電極12。 Inside the vacuum chamber 11 , a rectangular target 13 is arranged, and a cathode electrode 12 is arranged on the back side of the target 13 .

陰極電極12的表面是被接觸於標靶13的背面。 The surface of the cathode electrode 12 is in contact with the back surface of the target 13 .

在陰極電極12的背面側是配置有磁石盒51,在磁石盒51的內部是配置有複數個(在此是4個)的磁石裝置151~154。磁石裝置151~154是被稱為磁控磁石。 A magnet case 51 is disposed on the back side of the cathode electrode 12 , and a plurality of (here, four) magnet devices 15 1 to 15 4 are disposed inside the magnet case 51 . The magnet devices 15 1 to 15 4 are called magnetron magnets.

被配置於陰極電極12的背面側的磁石裝置151~154是基本上同形狀,同大小,在圖3顯示1個的磁石裝置151~154的平面圖及其C-C線截斷剖面圖與D-D線截斷剖面圖。 The magnet devices 15 1 to 15 4 arranged on the back side of the cathode electrode 12 are basically of the same shape and size, and FIG. 3 shows a plan view of one magnet device 15 1 to 15 4 and a cross-sectional view taken along the line CC. Cutaway section of line DD.

磁石裝置151~154是具有:環形形狀的外周磁石25,及被配置於外周磁石25之中的直線形形狀的內側磁石26,外周磁石25與內側磁石26是分別被設為細長,各磁石裝置151~154是被設為細長,各具有長度方向。 The magnet devices 15 1 to 15 4 have a ring-shaped outer magnet 25 and a linear inner magnet 26 arranged in the outer magnet 25 . The magnet devices 15 1 to 15 4 are elongated and each has a longitudinal direction.

在此,各磁石裝置151~154的外周磁石25與標靶13的背面之間的距離是被設為相等,且各磁石裝置151~154的內側磁石26與標靶13的背面之間的距離也被設為相等,但本發明不限於此,為了使膜厚的分佈或膜質的分佈形成均一,亦可磁石裝置151~154與標靶13的背面之間的距離為彼此相異,或磁石裝置151~154與標靶13的背面之間為非平行配置。 Here, the distances between the outer peripheral magnets 25 of the respective magnet devices 15 1 to 15 4 and the back surface of the target 13 are set to be equal, and the inner magnets 26 of the respective magnet devices 15 1 to 15 4 and the back surface of the target 13 are set equal. The distances between them are also set to be equal, but the present invention is not limited to this. In order to make the distribution of the film thickness and the distribution of the film quality uniform, the distances between the magnet devices 15 1 to 15 4 and the back surface of the target 13 may be They are different from each other, or the magnet devices 15 1 to 15 4 and the back surface of the target 13 are arranged non-parallel.

又,在此,各磁石裝置151~154的外周磁石 25與標靶13的背面之間的距離及內側磁石26與標靶13的背面之間的距離也被設為相等,但在各磁石裝置151~154之中,亦可含有內側磁石26與標靶13的背面之間的距離為相異的磁石裝置151~154,或外周磁石25與標靶13的背面之間的距離為相異的磁石裝置151~154Here, the distance between the outer peripheral magnet 25 and the back surface of the target 13 and the distance between the inner magnet 26 and the back surface of the target 13 in each of the magnet devices 15 1 to 15 4 are also set to be equal. Among the magnet devices 15 1 to 15 4 , the magnet devices 15 1 to 15 4 in which the distances between the inner magnet 26 and the back surface of the target 13 are different, or between the outer peripheral magnet 25 and the back surface of the target 13 may be included. The distances are 15 1 ~15 4 for different magnet devices.

外周磁石25的二個的磁極之中,一方的磁極會朝向陰極電極12而配置,另一方的磁極會朝向與陰極電極12相反側,與軛27的表面接觸而配置,且內側磁石26的二個的磁極之中,一方的磁極會朝向陰極電極12而配置,另一方的磁極會朝向與陰極電極12相反側,與軛27的表面接觸而配置。 Of the two magnetic poles of the outer peripheral magnet 25, one magnetic pole is disposed toward the cathode electrode 12, and the other magnetic pole is disposed toward the opposite side of the cathode electrode 12 and is disposed in contact with the surface of the yoke 27, and the two magnetic poles of the inner magnet 26 are disposed. Among the magnetic poles, one magnetic pole is disposed toward the cathode electrode 12 , and the other magnetic pole is disposed toward the opposite side of the cathode electrode 12 and is disposed in contact with the surface of the yoke 27 .

朝向外周磁石25的陰極電極12的磁極,及朝向內側磁石26的陰極電極12的磁極之中,任一一方的磁極為N極,另一方的磁極為S極,在朝向陰極電極12的磁極間所形成的磁束是被洩漏至標靶13的表面,被彎曲成拱形形狀,而使標靶13表面的電子密度增加。 Among the magnetic poles facing the cathode electrode 12 of the outer peripheral magnet 25 and the magnetic poles facing the cathode electrode 12 of the inner magnet 26 , one of the magnetic poles is N pole, the other magnetic pole is S pole, and the magnetic pole facing the cathode electrode 12 The magnetic flux formed during this time is leaked to the surface of the target 13 and is bent into an arch shape, so that the electron density on the surface of the target 13 is increased.

在真空槽11內之與標靶13的表面對面的位置是配置台54,在台54上是配置有基板配置部14。 A position in the vacuum chamber 11 opposite to the surface of the target 13 is an arrangement stage 54 , and the substrate arrangement portion 14 is arranged on the stage 54 .

基板配置部14是長方形形狀,在基板配置部14上是配置有成膜對象的長方形的基板16。 The substrate placement portion 14 has a rectangular shape, and a rectangular substrate 16 to be deposited on the substrate placement portion 14 is placed.

基板16是比標靶13更小,以下,若以投影至基板配置部14上的基板16的表面所位置的平面時的位置關係來決定內側與外側,則基板16的外周是比標靶13的外周更配置於內側。 The substrate 16 is smaller than the target 13 . Hereinafter, if the inner side and the outer side are determined by the positional relationship when projected on the plane on which the surface of the substrate 16 is positioned on the substrate arrangement portion 14 , the outer periphery of the substrate 16 is smaller than the target 13 . The outer circumference of the is more arranged on the inner side.

標靶13與基板16是被配置為標靶13的長邊與基板16的長邊是平行,標靶13的表面與基板16的表面也被配置為平行。 The target 13 and the substrate 16 are arranged so that the long side of the target 13 and the long side of the substrate 16 are parallel, and the surface of the target 13 and the surface of the substrate 16 are also arranged parallel.

磁石裝置151~154的長度方向的長度是與標靶13的長度方的長度大致同長度,基板16的長邊是比標靶13的長度方向的長度更短,且基板16的長邊是比磁石裝置151~154的長度方向的長度更短。 The length of the magnet devices 15 1 to 15 4 in the longitudinal direction is substantially the same as the length of the target 13 in the longitudinal direction, the long side of the substrate 16 is shorter than the length of the target 13 in the longitudinal direction, and the long side of the substrate 16 It is shorter than the length in the longitudinal direction of the magnet devices 15 1 to 15 4 .

各磁石裝置151~154是在軛27的背面側接觸於移動板52的狀態下被配置於移動板52上。 Each of the magnet devices 15 1 to 15 4 is arranged on the moving plate 52 in a state where the back side of the yoke 27 is in contact with the moving plate 52 .

各磁石裝置151~154是長度方向彼此平行,與標靶13及基板16的長邊平行,在短邊所延伸的方向排成一列。 The longitudinal directions of the respective magnet devices 15 1 to 15 4 are parallel to each other, parallel to the long sides of the target 13 and the substrate 16 , and aligned in a line in the direction in which the short sides extend.

在真空槽11的外部是配置有移動裝置53,一旦移動裝置53動作,則移動板52是在標靶13的背面側沿著標靶13的表面而移動,各磁石裝置151~154是與移動板52一起移動。 A moving device 53 is arranged outside the vacuum chamber 11. When the moving device 53 operates, the moving plate 52 moves along the surface of the target 13 on the back side of the target 13. The magnet devices 15 1 to 15 4 are Moves together with the moving plate 52 .

洩漏至標靶13的表面的磁束是與磁石裝置151~154的移動共同移動。 The magnetic flux leaking to the surface of the target 13 moves together with the movement of the magnet devices 15 1 to 15 4 .

在移動時,各磁石裝置151~154是在外周磁石25與標靶13的背面之間的距離無變化,維持一定距離。並且,在內側磁石26與標靶13的背面之間的距離無變化,維持一定距離。 During the movement, each of the magnet devices 15 1 to 15 4 maintains a constant distance without changing the distance between the outer peripheral magnet 25 and the back surface of the target 13 . In addition, the distance between the inner magnet 26 and the back surface of the target 13 is not changed, and a constant distance is maintained.

因此,各磁石裝置151~154是與移動板52的移動共同一起移動於與標靶13的背面平行的平面內。圖 4(a)是表示各磁石裝置151~154位於各磁石裝置151~154的各者所移動的範圍的中央的狀態,同圖(b)是表示位於圖面右端的狀態,同圖(c)是表示位於圖面左端的狀態,重複移動於同圖(b)的狀態與同圖(c)的狀態之間。 Therefore, each of the magnet devices 15 1 to 15 4 moves in a plane parallel to the back surface of the target 13 together with the movement of the moving plate 52 . FIG. 4( a ) shows a state in which each of the magnet devices 15 1 to 15 4 is located in the center of the range in which each of the magnet devices 15 1 to 15 4 moves, and FIG. 4( b ) shows a state in which it is located at the right end of the drawing, The same figure (c) shows the state located at the left end of the drawing, and it repeatedly moves between the state of the same figure (b) and the state of the same figure (c).

其次,在基板16與標靶13之間是配置有被連接至接地電位的陽極電極17。 Next, between the substrate 16 and the target 13 is an anode electrode 17 connected to the ground potential.

陽極電極17是四角環形形狀,在中央形成有開口19。陽極電極17的外周與內周是長方形形狀,陽極電極17的外周是位於比被配置於基板配置部14的基板16的外周更外側。 The anode electrode 17 has a quadrangular ring shape, and an opening 19 is formed in the center. The outer periphery and the inner periphery of the anode electrode 17 are rectangular shapes, and the outer periphery of the anode electrode 17 is located outside the outer periphery of the substrate 16 arranged in the substrate arrangement portion 14 .

在此例中,陽極電極17的內周是位於比基板16的緣更接近基板16的中央的區域,陽極電極17的四角環形形狀的二個的長邊部分是被配置於基板16的長邊上,二個的短邊部分是被配置於基板16的短邊上,基板配置部14上的基板16的外周是藉由陽極電極17所覆蓋,在開口19的底面是比基板16的外周更內側的部分會露出。 In this example, the inner circumference of the anode electrode 17 is a region located closer to the center of the substrate 16 than the edge of the substrate 16 , and the two long sides of the square ring shape of the anode electrode 17 are arranged on the long sides of the substrate 16 . The two short side parts are arranged on the short side of the substrate 16, the outer periphery of the substrate 16 on the substrate arrangement portion 14 is covered by the anode electrode 17, and the bottom surface of the opening 19 is more than the outer periphery of the substrate 16. The inner part will be exposed.

在真空槽11是連接有真空排氣裝置21及氣體導入裝置23,真空槽11是藉由真空排氣裝置21來真空排氣,在真空槽11的內部是形成真空環境。 A vacuum exhaust device 21 and a gas introduction device 23 are connected to the vacuum chamber 11 , the vacuum chamber 11 is evacuated by the vacuum exhaust device 21 , and a vacuum environment is formed inside the vacuum chamber 11 .

在真空槽11的外部是設有被電性連接至陰極電極12的濺射電源22,從氣體導入裝置23導入濺射氣體至形成真空環境的真空槽11的內部,內部在預定壓力安定時,從濺射電源22施加濺射電壓至陰極電極12。 Outside the vacuum chamber 11 is provided a sputtering power source 22 electrically connected to the cathode electrode 12. The sputtering gas is introduced from the gas introduction device 23 to the interior of the vacuum chamber 11 forming a vacuum environment. A sputtering voltage is applied to the cathode electrode 12 from the sputtering power supply 22 .

標靶13是金屬被板狀地成形的平板狀標靶, 邊使磁石裝置151~154移動,邊在標靶13的表面附近形成濺射氣體的電漿。 The target 13 is a flat target in which a metal is formed in a plate shape, and while the magnet devices 15 1 to 15 4 are moved, a plasma of sputtering gas is formed in the vicinity of the surface of the target 13 .

電漿中的濺射氣體的正離子被加速,濺射氣體的粒子會射入至標靶13,標靶13被濺射,構成標靶13的物質的粒子會作為濺射粒子從標靶13的表面放出朝向基板16飛行,到達基板16的表面而使薄膜成長。 The positive ions of the sputtering gas in the plasma are accelerated, the particles of the sputtering gas will be injected into the target 13, the target 13 will be sputtered, and the particles of the substance constituting the target 13 will be sputtered from the target 13. The surface release of the film flies toward the substrate 16, reaches the surface of the substrate 16, and grows the thin film.

一旦在基板16的表面形成預定膜厚的薄膜,則基板配置部14與基板16被搬出至真空槽11的外部,配置有未成膜的基板16的基板配置部14會被搬入至真空槽11的內部。 Once a thin film of a predetermined thickness is formed on the surface of the substrate 16 , the substrate placement portion 14 and the substrate 16 are carried out to the outside of the vacuum chamber 11 , and the substrate placement portion 14 on which the substrate 16 not formed into a film is placed is loaded into the vacuum chamber 11 . internal.

如此藉由本發明在基板16的表面形成薄膜,但在大型的基板16表面形成的金屬薄膜的電阻值是依基板16的位置而異。 In this way, the thin film is formed on the surface of the substrate 16 according to the present invention, but the resistance value of the metal thin film formed on the surface of the large substrate 16 varies depending on the position of the substrate 16 .

電阻值的分佈是具有與電漿的強度分佈密接的關聯,若說明本濺射裝置2的電漿,則首先在位於各磁石裝置151~154的外周磁石25與內側磁石26之間的標靶13的表面形成大的強度的電漿的點具有磁控濺射的特徵。 The distribution of the resistance value has a close relationship with the intensity distribution of the plasma. When describing the plasma of the sputtering apparatus 2, first, the distribution between the outer magnets 25 and the inner magnets 26 of the magnet devices 15 1 to 15 4 is located between the outer magnets 25 and the inner magnets 26 The spot on the surface of the target 13 where the plasma of a large intensity is formed has the characteristics of magnetron sputtering.

各磁石裝置151~154的外周磁石25是為了擴大被濺射的標靶的面積,而被設為細長的環形形狀,由於內側磁石26是直線形形狀,因此外周磁石25與內側磁石26之間的間隙是形成細長的環形形狀。因為電漿是形成與間隙同形狀,所以被形成的強度大的電漿也按每個磁石裝置151~154形成環形形狀。 The outer peripheral magnet 25 of each of the magnet devices 15 1 to 15 4 is formed in an elongated annular shape in order to enlarge the area of the target to be sputtered, and since the inner magnet 26 has a linear shape, the outer peripheral magnet 25 and the inner magnet 26 The gap between is formed into an elongated annular shape. Since the plasma is formed in the same shape as the gap, the formed high-intensity plasma also has a ring shape for each of the magnet devices 15 1 to 15 4 .

細長的環形形狀的電漿是端部比直線部分更 電漿強度大為人所知。特別是因為各磁石裝置151~154的端部被配置成一直線,所以複數的細長的環形形狀的電漿的端部會在被配置成一直線的狀態下彼此平行排列,環形形狀的電漿的端部被排列的部分的電漿強度會比環形形狀的電漿的長邊的部分的電漿強度更大。 The elongated annular shape of the plasma is known to have greater plasma intensity at the ends than in the straight portion. In particular, since the ends of the magnet devices 15 1 to 15 4 are arranged in a straight line, the ends of the plurality of elongated annular-shaped plasmas are aligned in parallel with each other in a state of being arranged in a straight line, and the annular-shaped plasmas are arranged in a straight line. The plasma intensity of the portion where the ends of the ring-shaped plasma are aligned will be greater than the plasma intensity of the portion of the long side of the plasma of the annular shape.

被排列的端部的電漿是在基板16的短邊的附近使薄膜成長,電漿的長邊部分是在基板16的長邊的附近使薄膜成長時,在基板16表面的中央的區域及短邊附近的區域以及長邊附近的區域,薄膜的特性會相異。 The plasma at the arranged end portion grows the thin film in the vicinity of the short side of the substrate 16 , and the long side portion of the plasma grows the thin film in the vicinity of the long side of the substrate 16 , in the central region of the surface of the substrate 16 and the The area near the short side and the area near the long side have different properties of the film.

與各磁石裝置151~154的端部被排列的領域平行地分別配置陽極電極17的短邊,在陽極電極17的二個的短邊部分上的比基板16的緣更外側是分別配置有電極板28a、28b。 The short sides of the anode electrodes 17 are respectively arranged in parallel to the areas where the ends of the magnet devices 15 1 to 15 4 are arranged, and the two short sides of the anode electrodes 17 are respectively arranged outside the edge of the substrate 16 . There are electrode plates 28a, 28b.

濺射前的未使用的標靶13是與陰極電極12、電極板28a、28b、及陽極電極17互相平行。 The unused target 13 before sputtering is parallel to the cathode electrode 12 , the electrode plates 28 a and 28 b , and the anode electrode 17 .

二個的電極板28a、28b是互相平行,比標靶13的短邊更長,分別具有與標靶13的短邊33a、33b平行、與陽極電極17的短邊平行、及與陰極電極12的短邊平行的二條的緣31a、31b、32a、32b。 The two electrode plates 28a, 28b are parallel to each other and longer than the short side of the target 13, and are parallel to the short sides 33a, 33b of the target 13, parallel to the short side of the anode electrode 17, and the cathode electrode 12, respectively. The short sides of the two parallel edges 31a, 31b, 32a, 32b.

與標靶13的短邊33a、33b平行的各電極板28a、28b的二條的緣31a、31b、32a、32b之中,一方的緣31a、31b是位於比標靶13的短邊更外側,另一方的緣32a、32b是位於比短邊更接近標靶13的中心的地方。 Of the two edges 31a, 31b, 32a, 32b of the electrode plates 28a, 28b parallel to the short sides 33a, 33b of the target 13, one of the edges 31a, 31b is located outside the short sides of the target 13, The other edges 32a and 32b are located closer to the center of the target 13 than the short sides.

因此,標靶13的短邊33a、33b附近是藉由電 極板28a、28b從短邊33a、33b到內側僅一定距離覆蓋。 Therefore, the vicinity of the short sides 33a and 33b of the target 13 is The polar plates 28a, 28b cover only a certain distance from the short sides 33a, 33b to the inside.

陰極電極12是經由絕緣板24來固定於真空槽11的壁面,陰極電極12與真空槽11是藉由絕緣板24來絕緣。在真空槽11的壁面是設有環形形狀的防著環36,標靶13是被配置於防著環36的內側。標靶13的外周面與防著環36的內周面是隔開預定距離而配置。 The cathode electrode 12 is fixed to the wall surface of the vacuum chamber 11 through the insulating plate 24 , and the cathode electrode 12 and the vacuum chamber 11 are insulated by the insulating plate 24 . On the wall surface of the vacuum chamber 11 , a ring-shaped blocking ring 36 is provided, and the target 13 is arranged inside the blocking ring 36 . The outer peripheral surface of the target 13 and the inner peripheral surface of the stopper ring 36 are arranged to be separated by a predetermined distance.

防著環36之中,在側面與標靶13的短邊33a、33b所位置的側面對面的部分的表面上安裝有支撐體29a、29b,電極板28a、28b是被安裝於支撐體29a、29b。 Support bodies 29a and 29b are attached to the surface of the portion of the guard ring 36 where the side faces face the sides where the short sides 33a and 33b of the target 13 are located, and the electrode plates 28a and 28b are attached to the support bodies 29a and 29b. 29b.

電極板28a、28b、防著環36及支撐體29a、29b是具有導電性,電極板28a、28b是經由支撐體29a、29b來電性連接至防著環36。 The electrode plates 28a, 28b, the anti-stick ring 36, and the supports 29a, 29b are electrically conductive, and the electrode plates 28a, 28b are electrically connected to the anti-stick ring 36 via the supports 29a, 29b.

真空槽11是被連接至接地電位,防著環36是接觸於真空槽11,被連接至接地電位,因此電極板28a、28b是被連接至接地電位。陽極電極17也被連接至接地電位。 The vacuum chamber 11 is connected to the ground potential, the guard ring 36 is in contact with the vacuum chamber 11 and is connected to the ground potential, so the electrode plates 28a, 28b are connected to the ground potential. The anode electrode 17 is also connected to ground potential.

若將各磁石裝置151~154的外周磁石25與位於其內側的內側磁石26之間的領域分別設為磁石裝置151~154的電漿領域10,則各磁石裝置151~154的外周磁石25的兩端是被彎曲成半圓形,隨之,電漿領域10的兩端也被彎曲成半圓形,其結果,外周磁石25與電漿領域10是分別形成跑道形形狀。 If the areas between the outer peripheral magnets 25 of the magnet devices 15 1 to 15 4 and the inner magnets 26 located inside the magnet devices 15 1 to 15 4 are defined as the plasma areas 10 of the magnet devices 15 1 to 15 4, respectively, the magnet devices 15 1 to 15 Both ends of the outer peripheral magnet 25 of 4 are bent into a semicircle, and subsequently, both ends of the plasma field 10 are also bent into a semicircle. As a result, the outer peripheral magnet 25 and the plasma field 10 are respectively formed into racetrack shapes. shape.

各磁石裝置151~154的電漿領域10的長度方向的長度是相等,各電漿領域10是與陽極電極17所位置的 平面之間的距離相等,各電漿領域10的兩端的彎曲的部分之中的一方的端部的彎曲的部分是排列成橫一列,相反側的端部的彎曲的部分也排列成橫一列。 The lengths in the longitudinal direction of the plasma domains 10 of the respective magnet devices 15 1 to 15 4 are equal, the distances between the plasma domains 10 and the plane where the anode electrode 17 is located are equal, and both ends of the plasma domains 10 are curved. Among the parts, the curved parts of one end are arranged in a horizontal line, and the curved parts of the opposite end are also arranged in a horizontal line.

各電漿領域10的兩端的彎曲的部分之中,一方的端部,在排列成橫一列的彎曲的部分與基板16的表面所位置的平面之間是配置有一片的電極板28a,相反側的端部,在排列成橫一列的彎曲的部分與基板16的表面所位置的平面之間是配置有其他的一片的電極板28b。 Among the curved portions at both ends of each plasma domain 10 , one end portion is provided with a single electrode plate 28 a between the curved portions arranged in a horizontal row and the plane where the surface of the substrate 16 is located, and the opposite side is provided with one electrode plate 28 a. The other electrode plate 28b is arranged between the curved portion arranged in a horizontal row and the plane where the surface of the substrate 16 is located.

標靶13的表面是在陽極電極17的長邊部分上與陽極電極17的長邊部分相向,在陽極電極17的短邊部分上與電極板28a、28b的表面相向。 The surface of the target 13 faces the long-side portion of the anode electrode 17 on the long-side portion of the anode electrode 17 and faces the surfaces of the electrode plates 28 a and 28 b on the short-side portion of the anode electrode 17 .

若將標靶13表面與基板16表面之間的距離設為TS距離,將標靶13表面與陽極電極17的長邊部分的表面之間的距離設為TA距離,將標靶13的表面與電極板28a、28b的表面之間的距離設為TB距離,則其次的三式成立。 Assuming that the distance between the surface of the target 13 and the surface of the substrate 16 is the TS distance, the distance between the surface of the target 13 and the surface of the long side portion of the anode electrode 17 is the TA distance, and the surface of the target 13 is When the distance between the surfaces of the electrode plates 28a and 28b is the TB distance, the following three equations are established.

TA<TS,TB<TS,TB<TA TA<TS, TB<TS, TB<TA

在基板16的長邊的正旁邊位置,最接近標靶13的接地電位的構件是陽極電極17之與標靶13對面的表面,在基板16的長邊的正旁邊位置,標靶13與最接近標靶13的接地電位的構件的表面之間是僅分離TA距離。 At the position directly next to the long side of the substrate 16, the member closest to the ground potential of the target 13 is the surface of the anode electrode 17 opposite to the target 13, and at the position directly next to the long side of the substrate 16, the target 13 is closest to the target 13. The surfaces of the members close to the ground potential of the target 13 are separated only by the TA distance.

在基板16的短邊的正旁邊位置,最接近標靶13的接地電位的構件是電極板28a、28b之與標靶13對面的表面,在基板16的短邊的正旁邊位置,標靶13與最接近標靶13的接地電位的構件的表面之間是僅分離TB距離。 At the position immediately beside the short side of the substrate 16, the member closest to the ground potential of the target 13 is the surface of the electrode plates 28a, 28b opposite to the target 13, and at the position immediately beside the short side of the substrate 16, the target 13 The surface of the member closest to the ground potential of the target 13 is separated only by the TB distance.

因此,標靶13與最接近標靶13的接地電位的構件的表面之間的距離是基板16的短邊的正旁邊位置比長邊的正旁邊位置更短。 Therefore, the distance between the target 13 and the surface of the member closest to the ground potential of the target 13 is shorter than the position directly beside the short side of the substrate 16 than the position directly beside the long side.

特別是藉由電極板28a、28b,在比基板16的緣更外側,標靶13與接地電位之間的距離變短,電極板28a、28b會吸引比基板16的緣更內側的電漿,因此在比基板16的緣更外側,電極板28a、28b所位置的基板16的短邊的外側的電漿強度變強,其結果,接近基板16的短邊的基板16上的電漿強度變小。總而言之,無電極板28a、28b時,接近基板16上的電漿領域10的長度方向的兩端的部分的電漿是比基板16上的其他的部分的電漿更強度變大,但藉由設置電極板28a、28b,接近基板16上的電漿領域10的長度方向的兩端的部分的電漿強度變小,其結果,基板16上的電漿強度會被均一化,被形成的薄膜的特性分佈會被均一化。 In particular, by the electrode plates 28a, 28b, the distance between the target 13 and the ground potential is shortened on the outer side of the edge of the substrate 16, and the electrode plates 28a, 28b attract the plasma on the inner side of the edge of the substrate 16, Therefore, on the outer side of the edge of the substrate 16 , the plasma intensity on the outer side of the short side of the substrate 16 where the electrode plates 28 a and 28 b are located becomes stronger, and as a result, the plasma intensity on the substrate 16 near the short side of the substrate 16 becomes stronger. Small. In short, when the electrode plates 28a and 28b are not present, the plasma in the portion close to both ends in the longitudinal direction of the plasma field 10 on the substrate 16 is stronger than the plasma in other portions on the substrate 16, but by providing Electrode plates 28a and 28b have lower plasma intensity at the portions close to both ends of the plasma field 10 on the substrate 16 in the longitudinal direction. As a result, the plasma intensity on the substrate 16 is uniformized and the characteristics of the formed thin film are reduced. The distribution will be normalized.

TB距離是若不比標靶13的表面與被配置於基板配置部14的基板16的表面之間的TS距離的10%大,則反而特性分佈惡化,若不比90%小,則效果變弱的情形被確認。 If the TB distance is not larger than 10% of the TS distance between the surface of the target 13 and the surface of the substrate 16 arranged in the substrate arrangement portion 14, the characteristic distribution will be degraded on the contrary, and if it is not smaller than 90%, the effect will be weakened. The situation is confirmed.

在電漿領域10的兩端之彎曲的部分上設有電極板28a、28b,若與標靶13表面對面,則與接地電位的構件之間的距離是電極板28a、28b與標靶13之間最短。如上述般,電極板28a、28b上的電漿強度會增大。 Electrode plates 28 a and 28 b are provided on the curved portions of both ends of the plasma field 10 , and the distance between the electrode plates 28 a and 28 b and the target 13 is the distance between the electrode plates 28 a and 28 b and the target 13 when facing the surface of the target 13 . shortest. As described above, the plasma intensity on the electrode plates 28a, 28b increases.

電極板28a、28b是被配置於比基板16更外 側,基板16的外側的電漿強度增大的結果,基板16上之中,在電極板28a、28b接近的基板16的緣附近是電漿強度會減少,因此基板16上的電漿強度會被均一化,基板16的表面內的電阻值分佈會形成均一。 The electrode plates 28a and 28b are arranged outside the substrate 16 As a result of the increase in the plasma intensity on the outside of the substrate 16, the plasma intensity on the substrate 16 decreases in the vicinity of the edge of the substrate 16 where the electrode plates 28a and 28b are close, so that the plasma intensity on the substrate 16 decreases. By making it uniform, the distribution of the resistance value in the surface of the substrate 16 becomes uniform.

其次,若說明本發明的真空槽11,則本發明的真空槽11是以標靶側真空槽11a及基板側真空槽11b所構成。標靶側真空槽11a與基板側真空槽11b是緣部分可緊貼,在緊貼的狀態下形成氣密的真空槽。 Next, if the vacuum chamber 11 of this invention is demonstrated, the vacuum chamber 11 of this invention is comprised by the target side vacuum chamber 11a and the board|substrate side vacuum chamber 11b. The target-side vacuum chamber 11a and the substrate-side vacuum chamber 11b can be brought into close contact with each other at the edges, and in a state of close contact, an airtight vacuum chamber is formed.

在本發明中,陰極電極12、標靶13、防著環36及陽極電極17是形成鉛直,陰極電極12是經由鉛直的絕緣板24來安裝於標靶側真空槽11a的形成鉛直的壁面。防著環36是被安裝於同壁面。 In the present invention, the cathode electrode 12 , the target 13 , the guard ring 36 and the anode electrode 17 are formed vertically, and the cathode electrode 12 is attached to the vertical wall surface of the target side vacuum chamber 11 a via the vertical insulating plate 24 . The retaining ring 36 is attached to the same wall.

標靶13是被設在陰極電極12之與接觸於絕緣板24的面相反側的面,而位於防著環36的內周。 The target 13 is provided on the surface of the cathode electrode 12 on the opposite side to the surface in contact with the insulating plate 24 , and is located on the inner periphery of the guard ring 36 .

電極板28a、28b也經由支撐體29a、29b與防著環36來被安裝於固定有陰極電極12、標靶13及防著環36的壁面。因此,電極板28a、28b的重量是藉由標靶側真空槽11a來支撐。 The electrode plates 28 a and 28 b are also attached to the wall surface to which the cathode electrode 12 , the target 13 and the retaining ring 36 are fixed via the supports 29 a and 29 b and the retaining ring 36 . Therefore, the weight of the electrode plates 28a and 28b is supported by the target side vacuum tank 11a.

濺射時,標靶側真空槽11a與基板側真空槽11b是被氣密地連接,在基板側真空槽11b的內部是設有形成鉛直的陽極電極17,基板配置部14及被配置於基板配置部14的基板16會在形成鉛直的狀態下從真空槽11的外部搬入至內部,被配置於陽極電極17與基板側真空槽11b的形成鉛直的壁面之間。 During sputtering, the target-side vacuum chamber 11a and the substrate-side vacuum chamber 11b are air-tightly connected, and the substrate-side vacuum chamber 11b is provided with a vertical anode electrode 17, a substrate placement portion 14 and a substrate-side vacuum chamber 11b. The substrate 16 of the arrangement portion 14 is carried in from the outside to the inside of the vacuum chamber 11 in a vertical state, and is arranged between the anode electrode 17 and the vertical wall surface of the substrate-side vacuum chamber 11b.

維修時,真空槽11的內部為常壓,如圖6的概略立體圖般,標靶側真空槽11a與基板側真空槽11b會被分離。 During maintenance, the inside of the vacuum chamber 11 is at normal pressure, and the target side vacuum chamber 11 a and the substrate side vacuum chamber 11 b are separated as shown in the schematic perspective view of FIG. 6 .

圖6的符號55是台座,標靶側真空槽11a是被設在台座55,對於地面固定。因此,標靶側真空槽11a的重量是藉由台座55來支撐。 Reference numeral 55 in FIG. 6 is a pedestal, and the target-side vacuum chamber 11a is provided on the pedestal 55 and is fixed to the ground. Therefore, the weight of the target-side vacuum chamber 11 a is supported by the stand 55 .

相對於此,基板側真空槽11b是未被固定於台座55,氣密地被安裝於標靶側真空槽11a。在圖6中,支撐體29a、29b是被省略。 On the other hand, the substrate-side vacuum chamber 11b is not fixed to the pedestal 55, but is attached to the target-side vacuum chamber 11a in an airtight manner. In FIG. 6, the supports 29a, 29b are omitted.

此圖6是標靶側真空槽11a不使移動,使基板側真空槽11b移動來使標靶側真空槽11a與基板側真空槽11b分離的狀態,支撐體29a、29b與電極板28a、28b是重量會經由標靶側真空槽11a來被台座55支撐。 6 shows a state in which the target-side vacuum chamber 11a is not moved, the substrate-side vacuum chamber 11b is moved to separate the target-side vacuum chamber 11a from the substrate-side vacuum chamber 11b, supports 29a, 29b and electrode plates 28a, 28b The weight is supported by the pedestal 55 via the target side vacuum tank 11a.

圖8是從真空槽11的壁面除去本發明的電極板28a、28b與支撐體29a、29b,藉由支撐體39a、39b來將電極板18a、18b設於陽極電極17上時的濺射裝置132。 8 shows the sputtering apparatus when electrode plates 28a, 28b and supports 29a, 29b of the present invention are removed from the wall surface of the vacuum chamber 11, and the electrode plates 18a, 18b are provided on the anode electrode 17 by the supports 39a, 39b 132.

在本發明的濺射裝置2及此圖8的濺射裝置132的基板面內的複數的同地方測定溫度。將測定結果顯示於圖7的圖表。溫度分佈是可謂大致相同。 Temperatures were measured at plural same places in the substrate surface of the sputtering apparatus 2 of the present invention and the sputtering apparatus 132 of FIG. 8 . The measurement results are shown in the graph of FIG. 7 . The temperature distribution is roughly the same.

並且,在本發明的濺射裝置2形成鉬薄膜時的薄膜電阻值Rs是0.0760Ω/□±18.7%,膜厚分佈是3915ű14.6%。 In addition, the sheet resistance value Rs when the molybdenum thin film was formed in the sputtering apparatus 2 of the present invention was 0.0760Ω/□±18.7%, and the film thickness distribution was 3915ű14.6%.

在圖8的濺射裝置132是與0.0804Ω/□±18.2%同程度,膜厚分佈是3805ű14.1%,同等的特性。 In the sputtering apparatus 132 of FIG. 8 , it is about the same as 0.0804Ω/□±18.2%, and the film thickness distribution is 3805ű14.1%, which are equivalent characteristics.

將膜厚分佈顯示下表。 The film thickness distribution is shown in the table below.

Figure 109105168-A0305-02-0019-1
Figure 109105168-A0305-02-0019-1

Figure 109105168-A0305-02-0019-2
Figure 109105168-A0305-02-0019-2

但,圖8的濺射裝置132的情況,電極板18a、18b與支撐體39a、39b是經由陽極電極17來被支撐於基板側真空槽,因此從標靶側真空槽分離的基板側真空槽 的內部的重量變大,標靶側真空槽與基板側真空槽之間的分離形成困難的作業。 However, in the case of the sputtering apparatus 132 of FIG. 8, the electrode plates 18a, 18b and the supports 39a, 39b are supported by the substrate-side vacuum chamber via the anode electrode 17, so the substrate-side vacuum chamber is separated from the target-side vacuum chamber The weight of the interior becomes large, and the separation between the target-side vacuum chamber and the substrate-side vacuum chamber is difficult.

另外,二個的支撐體29a、29b是分別為一片的板,但如圖5所示的濺射裝置3般,亦可分別以3個的支撐體29c、29d來支撐一片的電極板28a、28b。 In addition, the two support bodies 29a, 29b are each a single plate, but as in the sputtering apparatus 3 shown in FIG. 28b.

又,電漿領域10是只要為無端狀、環形形狀即可,外周磁石25的兩端為方形的情況或為橢圓形的情況也含在本發明。 In addition, the plasma field 10 may have an endless or annular shape, and the case where both ends of the outer peripheral magnet 25 are square or elliptical is also included in the present invention.

又,不將各磁石裝置151~154的端部配置於同一直線上的情況,或不將各磁石裝置151~154的端部與陰極電極12的距離形成一定的情況也含在本發明。 In addition, the case where the ends of the magnet devices 15 1 to 15 4 are not arranged on the same straight line, or the case where the distance between the ends of the magnet devices 15 1 to 15 4 and the cathode electrode 12 is not constant is also included. this invention.

另外,上述電極板28a、28b是位於陽極電極17的邊上,平行的二邊之中的一邊會比基板16的邊更外側,其他的一邊會位於比標靶13的邊更內側。 In addition, the electrode plates 28 a and 28 b are located on the side of the anode electrode 17 , one of the two parallel sides is located outside the side of the substrate 16 , and the other side is located more inside than the side of the target 13 .

二個的電極板28a、28b是分別具有平行的二邊的形狀,電極板28a、28b是例如為長方形形狀。 The two electrode plates 28a and 28b have two parallel sides, respectively, and the electrode plates 28a and 28b have, for example, a rectangular shape.

電漿領域10的兩端之中,電漿領域10的一方的端部之排成一列的彎曲的部分與基板16的表面所位置的平面之間配置有一片的電極板28a,電漿領域10的相反側的端部之配成一列的彎曲的部分與基板16的表面所位置的平面之間配置有其他的一片的電極板28b。 Among both ends of the plasma field 10 , a single electrode plate 28 a is arranged between the curved portion lined up at one end of the plasma field 10 and the plane where the surface of the substrate 16 is located, and the plasma field 10 The other electrode plate 28b is arranged between the curved portion arranged in a line and the end portion on the opposite side of the substrate 16 and the plane where the surface of the substrate 16 is located.

又,電極板28a、28b的二邊之中,離標靶13的中心遠的邊是亦可伸出至電漿領域10的彎曲的部分的外側,離標靶13的中心近的邊是亦可伸出至電漿領域10的彎 曲的部分的內側。又,亦可從雙方伸出。 In addition, among the two sides of the electrode plates 28a and 28b, the side farther from the center of the target 13 may be extended to the outside of the curved portion of the plasma field 10, and the side near the center of the target 13 is also Bends that can extend into the plasma field 10 the inside of the curved part. Also, it may be extended from both sides.

另外,上述標靶13為金屬鉬,本發明是不限於金屬鉬,本發明的濺射裝置2是對於由金屬鈦、鉬合金、鋁、鋁合金、金屬鎢、純銅、銅合金、鉭等的金屬所成的標靶13可取得本發明的效果。 In addition, the above-mentioned target 13 is metal molybdenum, and the present invention is not limited to metal molybdenum. The sputtering device 2 of the present invention is suitable for metal titanium, molybdenum alloy, aluminum, aluminum alloy, metal tungsten, pure copper, copper alloy, tantalum, etc. The target 13 made of metal can achieve the effect of the present invention.

2:濺射裝置 2: Sputtering device

11:真空槽 11: Vacuum tank

11a:標靶側真空槽 11a: Target side vacuum tank

11b:基板側真空槽 11b: Substrate side vacuum tank

12:陰極電極 12: Cathode electrode

13:標靶 13: Target

14:基板配置部 14: Substrate configuration section

151~154:磁石裝置 15 1 ~15 4 : Magnet device

16:基板 16: Substrate

17:陽極電極 17: Anode electrode

19:開口 19: Opening

21:真空排氣裝置 21: Vacuum exhaust device

22:濺射電源 22: Sputtering power supply

23:氣體導入裝置 23: Gas introduction device

24:絕緣板 24: Insulation board

28a:電極板 28a: Electrode plate

29a:支撐體 29a: Support body

36:防著環 36: Anti-lock ring

51:磁石盒 51: Magnet Box

52:移動板 52: Mobile board

53:移動裝置 53: Mobile Devices

54:配置台 54: Configuration Desk

Claims (3)

一種濺射裝置,係具有:真空槽;標靶,其係被配置於前述真空槽的內部;陰極電極,其係被配置於前述標靶的背面側,被連接至濺射電源;複數的磁石裝置,其係被配置於前述陰極電極的背面側;基板配置部,其係配置基板;及環形形狀的陽極電極,其係被連接至接地電位,覆蓋前述基板的外周上,在各前述磁石裝置係設有細長的環形形狀的外周磁石及被配置於其內側的內側磁石,在前述標靶的表面係被形成於前述外周磁石與其內側的前述內側磁石之間的磁束洩漏,前述標靶濺射而在前述基板表面形成薄膜,其特徵為:前述外周磁石與其內側的前述內側磁石係被分離,前述外周磁石與其內側的前述內側磁石之間的領域的電漿領域係被設為細長的環形形狀,前述電漿領域的前述細長的環形形狀的短邊側的兩端與前述基板的表面所位置的平面之間,係配置有被連接至接地電位的電極板,前述電極板的表面與前述標靶的表面之間的TB距離 比前述陽極電極的表面與前述標靶的表面之間的TA距離更短,只在前述標靶的沿著前述電漿領域的前述短邊側的兩端而位置的二邊上,配置有前述電極板,前述真空槽,係設為可分離成:在內部配置有前述標靶的標靶側真空槽、及在內部配置有前述陽極電極的基板側真空槽,在前述標靶側真空槽與前述基板側真空槽緊貼而連接的狀態中,前述標靶與前述陽極電極係被配置成鉛直,前述電極板的重量係藉由前述標靶側真空槽所支撐,在使前述標靶側真空槽與前述基板側真空槽離時,前述標靶側真空槽為靜止的狀態,前述基板側真空槽設為移動。 A sputtering apparatus comprising: a vacuum chamber; a target arranged inside the vacuum chamber; a cathode electrode arranged on the back side of the target and connected to a sputtering power source; a plurality of magnets A device, which is arranged on the back side of the cathode electrode; a substrate arrangement part, which arranges the substrate; and a ring-shaped anode electrode, which is connected to the ground potential and covers the outer periphery of the substrate, in each of the magnet devices. An outer peripheral magnet of an elongated annular shape and an inner magnet arranged inside it are provided, and a magnetic flux leakage formed between the outer peripheral magnet and the inner magnet inside the target is formed on the surface of the target, and the target is sputtered. A thin film is formed on the surface of the substrate, characterized in that the outer peripheral magnet and the inner magnet on the inner side are separated, and the plasma area of the area between the outer peripheral magnet and the inner magnet on the inner side is formed into an elongated annular shape between the two ends of the short side of the elongated annular shape of the plasma field and the plane where the surface of the substrate is located, an electrode plate connected to the ground potential is arranged, and the surface of the electrode plate is connected to the mark. TB distance between target surfaces The TA distance between the surface of the anode electrode and the surface of the target is shorter than that of the target, and the target is arranged only on both sides of the target along the two ends of the short side of the plasma field. The electrode plate and the vacuum chamber are separable into a target-side vacuum chamber in which the target is arranged, and a substrate-side vacuum chamber in which the anode electrode is arranged, and the target-side vacuum chamber and the target-side vacuum chamber are arranged to be separated. In a state in which the substrate side vacuum tank is in close contact and connected, the target and the anode electrode are arranged vertically, the weight of the electrode plate is supported by the target side vacuum tank, and the target side is evacuated. When the tank is separated from the substrate-side vacuum tank, the target-side vacuum tank is in a stationary state, and the substrate-side vacuum tank is moved. 如請求項1之濺射裝置,其中,前述TB距離,係比前述標靶的表面與被配置於前述基板配置部的前述基板的表面之間的TS距離的10%大,比90%小。 The sputtering apparatus according to claim 1, wherein the TB distance is larger than 10% and smaller than 90% of the TS distance between the surface of the target and the surface of the substrate arranged in the substrate arrangement portion. 如請求項1或2項之濺射裝置,其中,前述標靶為平板狀的金屬鉬板,前述薄膜為金屬鉬薄膜。 The sputtering apparatus according to claim 1 or 2, wherein the target is a flat metal molybdenum plate, and the thin film is a metal molybdenum thin film.
TW109105168A 2019-06-26 2020-02-18 Sputtering apparatus TWI762872B (en)

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