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TWI758262B - System and method for making and applying a non-portland cement-based material - Google Patents

System and method for making and applying a non-portland cement-based material Download PDF

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Publication number
TWI758262B
TWI758262B TW105136165A TW105136165A TWI758262B TW I758262 B TWI758262 B TW I758262B TW 105136165 A TW105136165 A TW 105136165A TW 105136165 A TW105136165 A TW 105136165A TW I758262 B TWI758262 B TW I758262B
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Taiwan
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binder mixture
weight
portland cement
mixture
sulfate
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TW105136165A
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Chinese (zh)
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TW201817694A (en
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尤金 詹姆士 卡馬里
安卓亞斯 史墜爾
羅伯特 喬治 班斯
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美商英科技股份有限公司
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

A system and method for applying a construction material is provided. The method may include mixing blast furnace slag material, geopolymer material, alkali-based powder, and sand at a batching and mixing device to generate a non-Portland cement-based material. The method may also include transporting the non-Portland cement-based material from the mixing device, through a conduit to a nozzle and combining the transported non-Portland cement-based material with liquid at the nozzle to generate a partially liquefied non-Portland cement-based material. The method may further include pneumatically applying the partially liquefied non-Portland cement-based material to a surface.

Description

用於製作並施用非波特蘭水泥基材料之系統與方法System and method for making and applying non-Portland cement based materials

本發明係關於建構材料,且更具體言之,本發明係關於一種用於製作且施用建構材料之方法。The present invention relates to building materials, and more particularly, the present invention relates to a method for making and applying building materials.

下水道翻新及混凝土復原及建構之領域中之現存做法可涉及可氣動式地突出朝需要修復或建構之表面之噴漿混凝土之施用。此噴漿混凝土包含在鹼性混凝土中發現之材料,諸如砂、波特蘭水泥及液體。在一特定施工現場中,此噴漿混凝土可為一乾拌或一濕拌應用之形式。術語「乾拌」通常涉及將處於一乾式狀態之部分或全部材料氣動式地傳送通過一軟管至一噴嘴,其中在物質突出之前一操作者可控制在該噴嘴處將液體施加至乾拌。相比而言,術語「濕拌」通常涉及將包含液體之一先前混合之混凝土在突出之前傳送通過一軟管。 一些公司已嘗試改變噴漿混凝土之材料組成以獲得某些優勢。據此,一些做法可涉及無機聚合物之使用。然而,此等材料由於此等產物中固有之有機材料而通常遭受腐蝕。例如,Milliken®在其等產品之GeoSpray™及GeoSpray™ AMS線下製造各種產品。AMS產品可經施用作為GeoSpray™產品之一預先及/或後處理。GeoSpray係波特蘭水泥基且僅含有一小部分無機聚合物。此混合物不耐酸。AMS含有抵抗酸在波特蘭水泥基混凝土上之效應及與波特蘭水泥基材料發生之微生物引起之腐蝕之效應之有機物。Existing practice in the field of sewer renovation and concrete restoration and construction may involve the application of shotcrete that can be protruded pneumatically towards the surface in need of repair or construction. The shotcrete contains materials found in alkaline concrete, such as sand, Portland cement, and liquids. In a particular construction site, the shotcrete can be in the form of a dry mix or a wet mix application. The term "dry mix" generally refers to pneumatically conveying some or all of the material in a dry state through a hose to a nozzle where an operator can control the application of liquid to the dry mix before the material emerges. In contrast, the term "wet mix" generally involves conveying a previously mixed concrete containing a liquid through a hose prior to protruding. Some companies have attempted to alter the material composition of shotcrete to gain certain advantages. Accordingly, some practices may involve the use of inorganic polymers. However, these materials are often subject to corrosion due to the organic materials inherent in these products. For example, Milliken® manufactures various products under its GeoSpray™ and GeoSpray™ AMS lines. The AMS product can be pre- and/or post-treated by administration as one of the GeoSpray™ products. GeoSpray is Portland cement based and contains only a small fraction of inorganic polymers. This mixture is not acid resistant. AMS contains organics that resist the effects of acid on Portland cement-based concrete and the effects of microbial-induced corrosion that occurs with Portland cement-based materials.

在一第一實施方案中,提供一種用於施用一建構材料之方法。該方法可包含在一分批處理及混合裝置中混合高爐熔渣材料、無機聚合物材料、鹼基粉末及砂以產生一非波特蘭水泥基材料。該方法亦可包含:將該非波特蘭水泥基材料自該分批處理及混合裝置通過一導管輸送至一噴嘴;且將輸送之非波特蘭水泥基材料與液體在噴嘴處組合以產生一部分液化之非波特蘭水泥基材料。該方法可進一步包含將該部分液化之非波特蘭水泥基材料氣動式地施用至一表面。 可包含以下特徵之一或多者。在一些實施例中,無機聚合物材料係火山岩粉或浮石之至少一者。鹼基粉末可包含矽酸鹽。可將混合執行為一乾拌。非波特蘭水泥基材料可為無機的。可在一行動分批處理及混合車輛中執行混合。非波特蘭水泥基材料可包含黏土、片麻岩、花崗岩、流紋岩、安山岩、橄欖岩、鉀長石、鈉長石、浮石或沸石之至少一者。混合可包含在一可攜帶槍中混合,該可攜帶槍經構形以自分批處理及混合裝置接收非波特蘭水泥基材料。非波特蘭水泥基材料之成分可包含大約2500 cm2 /g至5000 cm2 /g之一布萊恩細度值(Blaine fineness value)。 在另一實施方案中,提供一種用於施用一建構材料之系統。該系統可包含經構形以分批處理且混合高爐熔渣材料、無機聚合物材料、鹼基粉末及砂以產生一非波特蘭水泥基材料之一分批處理及混合裝置。該系統亦可包含經構形以自分批處理及混合裝置輸送非波特蘭水泥基材料之一導管。該系統可進一步包含經構形以接收該非波特蘭水泥基材料且將輸送之非波特蘭水泥基材料與液體組合以產生一部分液化之非波特蘭水泥基材料之一噴嘴,其中該噴嘴進一步經構形以將部分液化之非波特蘭水泥基材料氣動式地施用至一表面。 可包含以下特徵之一或多者。在一些實施例中,無機聚合物材料可為火山岩粉或浮石之至少一者。鹼基粉末可包含矽酸鹽。可將混合執行為一乾拌。非波特蘭水泥基材料可為無機的。可在一行動分批處理及混合車輛中執行混合。非波特蘭水泥基材料可包含黏土、片麻岩、花崗岩、流紋岩、安山岩、橄欖岩、鉀長石、鈉長石、浮石或沸石之至少一者。混合可包含在一可攜帶槍中混合,該可攜帶槍經構形以自分批處理及混合裝置接收非波特蘭水泥基材料。非波特蘭水泥基材料之成分可包含大約2500 cm2 /g至5000 cm2 /g之一布萊恩細度值。 在另一實施方案中,提供一種非波特蘭水泥基建構材料。該非波特蘭水泥基建構材料包含高爐熔渣材料、火山岩粉、鹼基粉末及砂。在一些實施例中,該鹼基粉末可為矽酸鹽。 在隨附圖式及以下描述中闡述一或多個實施方案之細節。將自描述、圖式及申請專利範圍明白其他特徵及優勢。In a first embodiment, a method for applying a building material is provided. The method can include mixing blast furnace slag material, inorganic polymer material, base powder and sand in a batch processing and mixing apparatus to produce a non-Portland cement based material. The method may also include: delivering the non-Portland cement-based material from the batch processing and mixing device through a conduit to a nozzle; and combining the delivered non-Portland cement-based material with a liquid at the nozzle to produce a portion Liquefied non-Portland cement based material. The method may further comprise pneumatically applying the partially liquefied non-Portland cement based material to a surface. One or more of the following features may be included. In some embodiments, the inorganic polymeric material is at least one of volcanic rock dust or pumice. The base powder may contain silicates. Mixing can be performed as a dry mix. Non-Portland cement based materials may be inorganic. Blending can be performed in one-action batches and blended vehicles. The non-Portland cement-based material may comprise at least one of clay, gneiss, granite, rhyolite, andesite, peridotite, feldspar, albite, pumice, or zeolite. Mixing can include mixing in a portable gun configured to receive non-Portland cement based materials from the batch processing and mixing device. The composition of the non-Portland cement based material may comprise a Blaine fineness value of about 2500 cm 2 /g to 5000 cm 2 /g. In another embodiment, a system for applying a building material is provided. The system may include a batch processing and mixing apparatus configured to batch process and mix blast furnace slag material, inorganic polymer material, base powder and sand to produce a non-Portland cement based material. The system may also include a conduit configured to transport the non-Portland cement based material from the batch processing and mixing device. The system may further comprise a nozzle configured to receive the non-Portland cement-based material and combine the delivered non-Portland cement-based material with a liquid to produce a portion of the liquefied non-Portland cement-based material, wherein the nozzle It is further configured to pneumatically apply the partially liquefied non-Portland cement based material to a surface. One or more of the following features may be included. In some embodiments, the inorganic polymeric material may be at least one of volcanic rock dust or pumice. The base powder may contain silicates. Mixing can be performed as a dry mix. Non-Portland cement based materials may be inorganic. Blending can be performed in one-action batches and blended vehicles. The non-Portland cement-based material may comprise at least one of clay, gneiss, granite, rhyolite, andesite, peridotite, feldspar, albite, pumice, or zeolite. Mixing can include mixing in a portable gun configured to receive non-Portland cement based materials from the batch processing and mixing device. The composition of the non-Portland cement based material may contain a Blaine fineness value of about 2500 cm 2 /g to 5000 cm 2 /g. In another embodiment, a non-Portland cement based building material is provided. The non-Portland cement based construction material includes blast furnace slag material, volcanic rock powder, base powder and sand. In some embodiments, the base powder may be a silicate. The details of one or more implementations are set forth in the accompanying drawings and the description below. Other features and advantages will be apparent from the description, drawings and claims.

相關申請案之交叉參考 本申請案係2015年5月6日在美國專利及商標局申請之美國專利申請案第14/705,534號之一部份接續申請案。該案之全文以引用之方式併入本文中。 本發明之實施例係關於具有一鹼激發黏結劑(即,非波特蘭水泥基)之一建構材料及用於製作且施用該建構材料之一系統及方法。儘管在混凝土改造之背景內容中討論本文包含之諸多實例,但應注意本文描述之建構材料可在任何適合之應用中使用。部分此等應用可包含(但不限制於)下水道改造工程、經歷一酸侵蝕之任何混凝土結構等等。 參考圖1,其展示一行動分批處理及混合車輛100,行動分批處理及混合車輛100具有與其相關聯之數個容器、隔間及裝置。在一些實施例中,車輛100可包含可經構形以儲存砂或其他材料之第一容器102。儲存單元104可經構形以儲存水或其他液體。車輛100可進一步包含一分批處理及混合裝置106,裝置106可包含數個組件,部分組件可包含(但不限制於)第二容器108、可調整傳遞機構110及可攜帶槍212。如圖2中所展示,可攜帶槍212可經由導管或軟管216連接至噴嘴214。 在一些實施例中,行動分批處理及混合車輛100可經構形以分批處理、混合及施用一非波特蘭水泥基建構材料。此材料可在放置於第二容器108之前在車輛處(例如,在分批處理及混合裝置106內)進行分批處理及混合。可將此材料輸送至噴嘴214,在噴嘴214中此材料可在當需要建構或修復時施用至表面之前與儲存單元104中之液體混合。在下文中進一步詳細討論非波特蘭水泥基建構材料之特性。 在一些實施例中,相較於現存材料,本文描述之非波特蘭水泥基建構材料可具有更佳強度值、一高抵抗力且與無機及有機酸無反應且另外具有早期高強度值。非波特蘭水泥基建構材料可顯示對高溫之一改良之抵抗力以及顯著較高之強度及持久性性質。在一項實例中,非波特蘭水泥基建構材料可對強無機酸具有一絕佳抵抗力。此外,自非波特蘭水泥基建構材料產生之產品可具有絕佳壓縮強度及一十分低之熱導率。該材料可包含在一分批處理及混合裝置中之高爐熔渣材料、無機聚合物材料、鹼基粉末及砂之一乾拌(例如,一結合劑混合物)以產生非波特蘭水泥基材料。在一些實施例中,該結合劑混合物可用於產生該非波特蘭水泥基材料。 在一些實施例中,一結合劑混合物可包含4重量%至45重量%之火山岩、0重量%至40重量%之潛在水硬材料、選自群組:矽酸鈉、鹼金屬類氫氧化物、鹼金屬碳酸鹽及其等混合物之10重量%至45重量%之鹼性成分及20重量%至90重量%之粒料之一或多者。在一些實施例中,結合劑混合物可包含污染物形式之小於1重量%之一比例之硫酸鹽(SO4 2- )。在一些實施例中,結合劑混合物中可含有氧化鈣(CaO)形式之至多5重量%之一比例之鈣。 在一些實施例中,非波特蘭水泥基建構材料可包含各種類型之無機聚合物材料。無機聚合物材料可包含(但不限制於)火山岩。因而,術語「無機聚合物材料」及「火山岩」可在本發明之範疇內交替使用。此等無機聚合物材料之一部分可包含(但不限制於)可與強鹼反應且使得該摻合物與砂及/或粗砂混合之火山灰材料。火山灰或火山灰材料可為由二氧化矽、黏土、石灰岩、氧化鐵及鹼性物質組成之可通過熱效應獲得之合成或自然岩石。當與氫氧化鈣及水組合時,其等可形成結合劑。天然火山灰(pozzolana)可為岩漿岩,諸如凝灰岩或德國萊茵浮石凝灰岩,但亦可為含有一高比例之可溶性矽酸之沉積岩,且有時亦可為反應性氧化鋁(黏土)。在一些實施例中,火山灰可為一易於得到之原材料且可用作為非波特蘭水泥基建構材料中之火山岩或無機聚合物材料。然而,亦可使用如火山岩或一些其他物質之天然材料,若較少部分用作為十分精細之粉末(例如,此一火山岩粉)則可更期望使用此等天然材料。 在一些實施例中,非波特蘭水泥基建構材料可包含任何數目之火山灰材料,其一部分可包含(但不限制於)細磨黏土、片麻岩、花崗岩、流紋岩、安山岩、橄欖岩、鉀長石、鈉長石、浮石、沸石等等以及其等混合物。此等材料可以煅燒及/或非煅燒之一岩土形式使用。另外及/或替代地,含有充足反應性(例如,亞穩態玻璃) SiO2 及Al2 O3 量之所有原材料(包含(但不限制於)灰燼、火山灰、熔渣)亦可適合用於本發明之實施例。 在一些實施例中,非波特蘭水泥基建構材料可包含一潛在水硬材料。本文使用之一潛在水硬材料可包含(但不限制於)飛灰、高嶺土、浮石凝灰岩、粒狀熔渣(例如,高爐熔渣材料)及/或其等之一混合物。在一項實例中,可使用褐煤飛灰及無煙煤飛灰之形式之飛灰。在一些實施例中,火山灰材料可包含活性矽酸鹽,如熔渣砂或飛灰。在一些實施例中,磚灰(耐火黏土)或來自燃燒無煙煤或褐煤之植物之飛灰可被稱為合成火山灰。因而,本文使用之術語「飛灰」可係指一非天然或合成火山灰。在一些實施例中,可由二氧化矽與氧化鋁及氧化鈣之一有利比例引起飛灰之特定有利性質,此可區分此等物質。然而,且如將在下文更詳細地討論,飛灰可含有部分硫酸鹽及/或氧化鈣。因此,若將飛灰用於結合劑混合物中,則可使用含有具有一有利比例之指定物質之一種類型之飛灰。 在一些實施例中,非波特蘭水泥基建構材料可包含一鹼基粉末材料及/或各種混合液體。一些可能之混合液體可包含(但不限制於)鉀及鈉水玻璃、鹼金屬類氫氧化物等等。在一些實施例中,鹼或鹼性成分可為一水溶液矽酸鈉形式或一粉末矽酸鈉形式之矽酸鈉。在一些實施例中,可使用一噴霧乾燥矽酸鹽。當使用鹼金屬類氫氧化物或鹼金屬碳酸鹽時,此等材料可以其等液體形式或以一粉末或粒狀使用。 在一些實施例中,含有SiO2 /Al2 O3 之成分與鹼性混合液體之間之反應可導致具有一三維結構之矽鋁酸鹽。此等框架結構允許產生在其化合物中不含波特蘭水泥之一建構材料。 如以上所討論,結合劑混合物及/或結合劑混合物之成分可包含鈣。在一些實施例中,結合劑混合物可含有部分氧化鈣(CaO)形式之鈣。結合劑混合物及/或非波特蘭水泥基建構材料中之此等CaO部分可在與鹼水溶液及/或成分反應之後導致水化矽酸鈣,此可具有已知不利化學性質。此外,作為水泥基結晶結構之一成分之鈣離子通常顯示一非所要可溶性,此可隨著時間之推移導致水泥結構之一弱化。為此理由可使用一最少可能比例之鈣。利用可溶性矽酸形式之SiO2 、氧化鐵、鋁酸鹽形式之Al2 O3 及氧化鈣之本發明之實施例可經與水溶性矽酸鹽或強鹼一起實施,因此導致具有較少鈣或幾乎無鈣之一無機結合系統。 在一些實施例中,結合劑混合物中可含有氧化鈣(CaO)形式且具有至多5重量%之一比例之鈣。在一些實施例中,結合劑混合物中可含有氧化鈣形式且具有至多2重量%之一比例之鈣。另外及/或替代地,可含有氧化鈣形式且具有至多1重量%之一比例之鈣。 在一些實施例中,結合劑混合物中可含有污染物形式及/或具有小於1重量%之一比例之硫酸鹽(SO4 -2 )。以其鹽之形式出現之硫酸鹽係一與環境相關之物質。由農業施肥及廢料管理引起具有硫酸鹽之環境之增加之污染物。已證實硫酸鹽導致土地及地下水之酸化。由於硫酸鹽在水中之一通常較高之可溶性,所以其易於在地下水、滲漏及表面水流中輸送,最終增加廢料儲存設備中之含有硫酸鹽之材料之環境中之酸化效應。通過微生物程序將硫酸鹽分解為亞硫酸鹽,繼而可對動植物具有一負面效應。在一些實施例中,結合劑混合物中之硫酸鹽比例可盡可能地降低以至少避免此等負面效應。在一些實施例中,結合劑混合物中可含有污染物形式及/或具有小於0.5重量%之一比例之硫酸鹽(SO4 -2 )。在一項實施例中,可含有具有小於0.25重量%之一比例之硫酸鹽(SO4 -2 )。 在一些實施例中,非波特蘭水泥基建構材料可包含砂。然而,亦可使用其他粒料。例如,在一結合劑混合物中用作為一非水泥基混凝土之其他粒料可包含(但不限制於)砂礫、砂、玄武岩等等。亦可使用本發明之範疇內之用於非水泥基混凝土之其他材料。替代地且在各種應用中,亦可使用珍珠岩、膨脹葉岩、浮石或其等之一混合物。在一些實施例中,結合劑混合物可包含20重量%至70重量%之粒料。另外及/或替代地,20重量%至50重量%之粒料可包含於結合劑混合物中。在一項實施例中,20重量%至40重量%之粒料可包含於結合劑混合物中。 在一些實施例中,結合劑混合物亦可含有水。因此,在一項實施例中,可藉由由4重量%至45重量%之火山岩(例如,無機聚合物材料)、0重量%至40重量%之潛在水硬材料(例如,高爐熔渣材料)、10重量%至45重量%之鹼性成分(例如鹼)、20重量%至90重量%之粒料(例如砂)及/或水構成之一結合劑混合物展現對各種化學物質且尤其係對酸之一極高抵抗力。在一些實施例中,鹼性成分可包含矽酸鈉、鹼金屬類氫氧化物及/或鹼金屬碳酸鹽。另外及/或替代地,結合劑混合物可包含污染物形式及/或小於1重量%之一比例之硫酸鹽(SO4 2- )。在一些實施例中,結合劑混合物可包含氧化鈣(CaO)形式之至多5重量%之一比例之鈣。 在操作中,原料可粗略經分批處理及混合物(例如,全部或部分在車輛100中)且接著傳遞至可攜帶槍212。可經由壓縮空氣將非波特蘭水泥基建構材料攜帶通過導管216至噴嘴214。在一特定實施例中,矽酸鉀、固體含量48%、密度1,52 g/cm3、Wt SiO2:K2O 1,14及一些液體可經加入且將部分液化混合物氣動式地施用至受關注表面之前在噴嘴214內短時間(例如,小於1秒)粗略混合。 本文包含之實施例可包含含有以下之部分或全部之一混合物:熔渣(例如,非天然火山灰、基礎或潛在水硬材料)、飛灰(例如,非天然火山灰及配方中之選項)、無機聚合物(例如,天然火山灰及選項、地面火山材料/火山岩)、鹼/鹼性成分(例如,粉末或液體)、包含水(選項)及砂/粗砂或其他粒料之其他液體。以下提供特定混合物之實例,然而應注意,僅以實例方式包含本文提供之特定混合物。數個額外及替代實施例亦落於本發明之範疇內。 在一特定實例中,非波特蘭水泥基建構材料可包括以下混合物:

Figure 105136165-A0304-0001
表1 在一些實施例中,混合物之成分可包含大約2500 cm2 /g至5000 cm2 /g之一布萊恩細度值。該布萊恩值係用於水泥粉化程度之一標準量測。該布萊恩值經給出作為利用一布萊恩裝置在一實驗室中判定之一特定表面值(cm2 /g)。例如,標準波特蘭水泥(CEM I 32.5)具有3000至4500之一布萊恩值。在一些實施例中,結合劑混合物、火山岩及/或潛在水硬材料之成分可以具有大於3000之一布萊恩值之一細磨狀態使用。在一項實施例中,火山岩及/或潛在水硬材料可具有大於3500之一布萊恩值。細磨成分可導致一顯著改良之反應速度。細磨火山岩可更易處理且可進一步導致對成品中之各種不同化學物質(尤其係對酸)之一增加之抵抗力。 在另一實例中,非波特蘭水泥基建構材料可包括以下混合物:
Figure 105136165-A0304-0002
表2 在另一實例中,非波特蘭水泥基建構材料可包括以下混合物:
Figure 105136165-A0304-0003
表3 在一些實施例中,相較於一液壓硬化結合劑,可使用自4重量%至45重量%之火山岩、0重量% (或大於0重量%)至40重量%之潛在水硬材料、10重量%至45重量%之一鹼性成分及20重量%至90重量%之粒料之反應產生之一非波特蘭水泥基建構材料或結合劑混合物。在一些實施例中,鹼性成分可包含矽酸鈉、鹼金屬類氫氧化物及/或鹼金屬碳酸鹽。另外,結合劑混合物可包含污染物形式及/或小於1重量%之一比例之硫酸鹽(SO4 2- )。在一些實施例中,結合劑混合物中可含有氧化鈣(CaO)形式之至多5重量%之一比例之鈣。 非波特蘭水泥基建構材料之實施例產生一預料之外之結果,因為鹼性原料與岩石粉之反應時間足夠產生一黏性化合物。通過數個測試,發現此化合物極其牢固地黏著於一垂直表面上,建立一緊密結合且在3天內經硬化具有大約50 N/mm2 (8000 psi)之壓縮強度值。 在一些實施例中,結合劑混合物或非波特蘭水泥基建構材料可用於應用之不同技術領域中:乾砂漿、石膏及噴射混凝土 可藉由混合乾性成分產生乾砂漿及石膏混合物。為此目的,可使用噴霧乾燥反應性矽酸鹽或鹼金屬類氫氧化物。基於此情況,可針對其等用途將成品混合物生產作為噴射混凝土。發泡混凝土 商用發泡混凝土係具有300 kg/m3 至800 kg/m3 之一原密度之一基於礦質之蒸壓發泡大塊建構材料。發泡混凝土通常產自諸如石灰、無水石膏、水泥、水及矽砂之原材料且可組合支撐結構之性質與隔熱性。高度隔熱砌體建構可經產生具有整體單壁建構中之發泡混凝土。 在一些實施例中,一生產程序可包含磨碎一矽砂直至其在(例如)礫磨機中經磨細具有大於3000之布萊恩值。原料可經組合以形成(例如) 1:1:4之一比率之一砂漿混合物且同時加入水。在一些實施例中,一小部分鋁粉或糊漿可加入至完成之漿料中。可將砂漿混合物倒入其中金屬微粒鋁在鹼性砂漿漿料中形成氫氣之水槽內。可獲得使得逐漸硬化之砂漿發泡之氣泡。15至50分鐘後可獲得最終容積。此時,可獲得三米至八米長、一米至一點五米寬及50釐米至80釐米高之塊體。可使用金屬線將此等固體塊狀物或塊體切割至任何所要尺寸。在一些實施例中,此等塊體可在特殊蒸汽壓力鍋爐(例如,蒸壓釜)中以180° C至200° C之蒸汽溫度在其中該材料在6至12小時之後可含有其最終特性之10巴至12巴之一大氣下經固化。從化學角度來說,發泡混凝土可大部分對應於天然礦質雪矽鈣石,但其可為一合成材料。 除了低熱導率外,該建構材料可由其缺乏易燃性來區分,使得其可(例如)在歐洲消防分類A1中進行分類。現代發泡混凝土成分可含有生石灰、水泥、砂及水之一混合物。取決於烘乾密度及生石灰與水泥之比率,該成分可區分富含石灰及富含水泥之混合物。另外,可使用無水石膏或石膏形式之硫酸鹽載體改良壓縮強度及收縮性質,此係由於雪矽鈣石中之結晶「紙牌屋」結構之改良之生長。由於此等發現,在前數十年已證實加入無水石膏/石膏形式之硫酸鹽載體在生產中係有利的且因此係當前所有發泡混凝土組成物之一成分。 建構材料可通過在混合過程期間加入少量鋁粉而獲得一孔結構。在混合物中細分之鋁可在一鹼性媒介中反應,從而形成可使得原料混合物緩慢起泡之氫氣。此孔結構可留在產品中,即使係在實際熱液固化程序之後,且實質上可對最終產品之特性負責。 在一些實施例中,生產程序可分解為以下動作之一或多者: 1.磨碎矽砂且製備再循環泥漿 2.混合且倒入發泡混凝土泥漿 3.使得粗糙塊狀物或塊體膨脹、凝固且切割該等粗糙塊狀物或塊體 4.在熱液狀況下固化未切割塊體 5.打包且儲存成品 在混合發泡混凝土化合物且將其倒入鋼模具內之後,數個複雜化學反應可在凝固與熱液固化相之間發生。當加入水時,可在混合相期間開始生石灰之氫化。由於此係一放熱反應,所以可加熱發泡混凝土化合物且加速水泥物相之水化反應。因此,可在由氫的生長產生之膨脹期間發生發泡混凝土化合物之一連續硬化。為了獲得一同質孔結構,氣體生長可調整至膨脹發泡混凝土化合物之黏度曲線。若未能達成此步驟,則可在膨脹期間發生所謂之膨脹破裂之結構損壞,此在隨後之生產程序期間可係無法校正的。在數小時之一凝固時間段之後,未切割之塊體可藉由拉緊之金屬線切割成合適岩石構造。在切割程序期間產生之所有廢料可在組成中循環,使得在生產過程期間不存在廢料。 再循環能力之問題在未來至關重要。一方面,歐洲需求要求減少廢料,此伴隨垃圾場之關閉及對更多再循環之一增加之要求。另一方面,對於環境保護具有一增加之需求,諸如最低臨限值及關於地下水/替代建築材料/土壤保護之一覆面法規之框架中之替代建築材料法規之草案指南,此至少在一些情況中使得再循環市場上可用之建築材料變得更困難。可由900 mg/l與1650 mg/l之間之洗出液中之硫酸鹽濃度產生關於硫酸鹽之浸出規律。根據替代建築材料法規,用於洗出液中之基於礦質之替代建築材料之臨限值係250 mg/l硫酸鹽。在生產發泡混凝土中省略硫酸鹽載體及水泥可徹底減少洗出液中之上述硫酸鹽濃度且可能夠將發泡混凝土建構廢料用作為一基於礦質之替代建築材料。 在一些實施例中,使用根據本發明之非水泥基黏結劑可消除此缺點,且此外可具有一十分低之鈣含量。典型技術性質在其他方面可不受影響。預鑄混凝土 一預鑄混凝土部件或混凝土元件係由混凝土、鋼筋混凝土或預應力混凝土組成之一成分,其在一工廠中預先工業化製作且隨後(通常)使用一吊車將其置於最終位置中。廣泛使用且在各種建築技術中實施預鑄混凝土元件及鋼筋混凝土元件。用於開放渠道系統之預鑄元件之生產可用於本發明之一些實施例中。防火 在DIN 4102中列出用於混凝土元件及鋼筋混凝土元件之石膏成品(建築材料及建築元件與火之反應)。技術上適合用於防火之石膏係蛭石及珍珠岩絕緣石膏及根據DIN 18550, Part 2之石膏。 在一些實施例中,一噴射混合物可經供應作為具有一液壓硬化結合劑且在施用前不久與水混合之一乾砂漿——礦質纖維之一混合物,諸如玻璃絲、岩棉或礦物棉。關於防火之技術特性可與噴射石棉之技術特性相同。 在石膏成品中使用非水泥基結合劑可進一步改良防火性,因為一非水泥基結合劑可具有一更有利之膨脹行為且可展現高溫下之較低收縮性。 在本發明之一些實施例中,習知混合器不可用於生產結合劑混合物。在一些實施例中,將一所謂之黏土攪拌器或連續混合器用於生產一預先混合物且隨後將一加強混合器或行星式混合器用於在粒料中混合可導致可在模具中壓縮或圍封且可在一機械壓縮後生產所要產品之一無機材料。 以下提供之表4展示根據本發明之實施例之哪些混合及施用技術可導致用於結合劑混合物之應用之哪些領域。
Figure 105136165-A0304-0004
表4 在本發明之一些實施例中,提供一種用於生產一可模製混凝土化合物之方法。該方法可包含以下動作之一或多者: 該方法可包含供應含有4重量%至45重量%之火山岩、0重量%至40重量%之潛在水硬材料、10重量%至45重量%之一鹼性成分之一或多者之一結合劑混合物。在一項實例中,該鹼性成分或鹼可選自群組及/或可包含:矽酸鈉、鹼金屬類氫氧化物、鹼金屬碳酸鹽及其等混合物。在一些實施例中,結合劑混合物中可含有以結合劑混合物中之污染物之形式且具有小於1重量%之一比例之硫酸鹽(SO4 2- )。另外,結合劑混合物中可含有氧化鈣(CaO)形式之至多5重量%之一比例之鈣。該方法亦可包含使用一黏土攪拌器或連續混合器生產結合劑混合物之一預先混合物。在一些實施例中,該方法可進一步包含使用一強力混合器或行星式混合器將預先混合物與20重量%至90重量%之粒料混合以產生一可模製混凝土化合物。在一些實施例中,此可在1分鐘至5分鐘之一時間段內實施。在一項實施例中,此可在大約2分鐘之一時間段內實施。 該方法亦可包含通過壓縮或震動來壓縮可模製混凝土化合物以形成管道、預鑄混凝土元件、鐵枕、混凝土塊體、形成鋪地石、人行道板等等。 在本發明之一些實施例中,提供一種用於生產一可模製混凝土化合物之方法。該方法可包含以下展示之實施例之一或多者。 在一些實施例中,該方法可包含供應包含4重量%至45重量%之火山岩、0重量%至40重量%之潛在水硬材料、10重量%至45重量%之一鹼性成分之一或多者之一結合劑混合物。在一些實施例中,該鹼性成分可選自群組及/或可包含:矽酸鈉、鹼金屬類氫氧化物、鹼金屬碳酸鹽及其等混合物。在一項實例中,結合劑混合物可包含20重量%至90重量%之粒料。在一些實施例中,結合劑混合物中可含有污染物之形式且具有小於1重量%之一比例之硫酸鹽(SO4 2- )。另外,結合劑混合物中可含有氧化鈣(CaO)形式之至多5重量%之一比例之鈣。該方法亦可包含使用一乾式混合器產生一乾式混合物。該方法可進一步包含使用一強力混合器或行星式混合器混合與水產生之乾式混合物以產生一可模製混凝土化合物。 在本發明之一些實施例中,提供一種用於產生一可噴射混凝土化合物之方法。該方法可包含以下展示之實施例之一或多者。 在一些實施例中,該方法可包含供應包含4重量%至45重量%之火山岩、0重量%至40重量%之潛在水硬材料、10重量%至45重量%之一鹼性成分之一或多者之一結合劑混合物。在一些實施例中,該鹼性成分可選自群組及/或可包含:矽酸鈉、鹼金屬類氫氧化物、鹼金屬碳酸鹽及其等混合物。在一些實施例中,結合劑混合物可包含20重量%至90重量%之粒料。在一些實施例中,結合劑混合物中可含有污染物之形式且具有小於1重量%之一比例之硫酸鹽(SO4 2- )。另外,結合劑混合物中可含有氧化鈣(CaO)形式之至多5重量%之一比例之鈣。該方法亦可包含使用一乾式混合器產生一乾式混合物。在一些實施例中,該方法可進一步包含在一噴射槍中混合乾式混合物與水以用於產生且立即施用一可噴射混凝土化合物。 在一些實施例中,可針對不同應用領域製備結合劑混合物,包含(例如)以上表4中所列出。以下提供之實例1至5可繪示本發明之一或多個實施例。 實例1 在具有一擠出螺桿之一混合及捏合機器中,可組合且大力混合1份細磨火山岩(例如,布萊恩值3500)、0.15份飛灰及0.8份矽酸鈉直至獲得一同質可傾倒石膏。 此石膏可在一強力混合器(或行星式混合器)中與4份玄武岩及砂混合約2分鐘。藉此可獲得適合用於在生產混凝土塊體時施用為面混凝土之一土地潮濕無水泥混凝土。 混合物之硫酸鹽含量可達到0.16重量%且氧化鈣含量可為0.8重量%。 可通過(例如)在砌塊成型機器中實踐之壓縮及震動達成此一混合物之壓縮。 所得產品可由顯著較高抗酸性、更有利之機械強度性質及一顯著更強之彩色印刷區分。 當使用其他粒料混合物(諸如砂礫及砂)時,亦可產生混凝土管或特殊預鑄混凝土元件,此取決於一特定粒子尺寸分佈曲線。藉由控制水分含量及調適施用技術(例如,傾倒、離心分離等等),其他產品變動亦可行。 實例2 在一強力混合器中,可混合0.2份粒狀熔渣、1份細磨火山岩及3份砂。可將此乾式混合物置於一袋中。 在一施工現場中,可將依此方式產生之1份混合物在一路面混合物中與0.7份矽酸鈉混合且使其變為所要稠度。 混合物之硫酸鹽含量可高達0.19重量%且氧化鈣含量可為0.57重量%。 以此方式獲得之非水泥基砌塊及抹灰砂漿可以不同方式施用至待塗佈之一表面(例如,藉由習知抹灰、噴射等等)。 實例3 在一乾式混合器中可產生由1份火山灰(例如,大於3500之布萊恩值)、0.4份飛灰、1份珍珠岩及0.7份粉末矽酸鈉構成之一乾式混合物。 可通過與高剪力之強力混合而使得乾式混合物與水濕潤且倒入模具內而經壓縮。 濕潤混合物之硫酸鹽含量可高達0.32重量%且氧化鈣含量可為1.8重量%。 在基於以上實例之一實踐中,在一硬化相之後(在受到一延長時間段之焚燒後)獲得樣本且不顯示破裂或可見裂痕且在測試之後未展現減弱之機械強度性質。在遭受凍結溫度之後也不存在任何明顯損傷。 實例4 在一乾式混合器中,可產生由1份火山灰(例如,大於3500之布萊恩值)、0.4份粒狀熔渣、1份珍珠岩及0.7份粉末矽酸鈉構成之一乾式混合物。 可將乾式混合物連續施加至一噴射槍且可與水組合而產生一可噴射混凝土。可利用噴射技術使得管道及電纜穿墻、熱敏建築材料及表面無困難地經密封或塗佈具有抗熱性及防火非水泥基化合物。 可噴射混凝土之硫酸鹽含量可高達0.31重量%且氧化鈣含量可為1.29重量%。 實例5 為了生產一發泡混凝土,可在一商用混合器中集中地預先混合16.2份火山岩、3.35份飛灰、23份矽砂。此乾式混合物可在38° C之強剪力下增加至33份矽酸鈉,且可進一步在相同混合器中與0.43份鋁漿混合。 可將結合劑混合物倒入一特氟龍模具內且在該模具中加熱120分鐘至80° C。該混合物可變堅硬且同時急劇增加容積但仍然可切割。針對固化,可將該模具置於一固化腔室中且可在180° C之情況下在其內停留30分鐘。替代地,可在120° C之情況下使用一蒸壓釜。 可獲得具有可與根據典型方法獲得之一發泡混凝土比較之光學性質之一模製本體。與典型發泡混凝土不同,該材料可為抗酸的且具有0.21重量%之一硫酸鹽含量及0.6重量%之一氧化鈣含量。在一項實施例中,所得建構材料可具有一十分低之硫酸鹽及鈣含量。 本文使用之術語僅係為了描述特定實施例之目的且不意欲限制本發明。如本文所使用,除非本文另外明確指示,否則單數形式「一」(a、an)及「該」亦意欲包含複數形式。將進一步瞭解,術語「包括」(comprises及/或comprising)當在本說明書中使用時指定存在陳述之特徵、整數、步驟、操作、元件及/或組件,但不排除出現或增加一或多個其他特徵、整數、步驟、操作、元件、組件及/或其群組。 以下申請專利範圍中之所有裝置或步驟附加功能元件之對應結構、材料、動作及等效物意欲包含用於執行與特定提及之其他元件組合之功能之任何結構、材料或動作。本發明之描述係為了繪示及描述之目的呈現但不意欲具有窮舉性或將本發明限制於所揭示之形式。熟習技術者將明白在不違背本發明之範疇及精神之情況下之諸多修改及變動。實施例經選擇及描述以最佳地解釋本發明及實踐應用之原理,且使得一般技術者能夠了解本發明,因為具有各種修改之各種實施例適合設想之特定用途。 因為已詳細描述且參考本申請案之實施例來描述本申請案之發明內容,所以將明白在不違背隨附申請專利範圍中界定之本發明之範疇之情況下,修改及變動係可行的。 CROSS-REFERENCE TO RELATED APPLICATIONS This application is a continuation-in-part of US Patent Application Serial No. 14/705,534 filed in the US Patent and Trademark Office on May 6, 2015. The full text of the case is incorporated herein by reference. Embodiments of the present invention relate to a building material having an alkali-activated binder (ie, non-Portland cement based) and a system and method for making and applying the building material. While many of the examples contained herein are discussed in the context of concrete retrofits, it should be noted that the construction materials described herein may be used in any suitable application. Some of these applications may include, but are not limited to, sewer improvement projects, any concrete structure that has undergone an acid attack, and the like. Referring to Figure 1, a mobile batch processing and mixing vehicle 100 is shown having a number of containers, compartments and devices associated therewith. In some embodiments, the vehicle 100 may include a first container 102 that may be configured to store sand or other materials. The storage unit 104 may be configured to store water or other liquids. Vehicle 100 may further include a batch processing and mixing device 106 , which may include several components, some of which may include, but are not limited to, second container 108 , adjustable transfer mechanism 110 , and portable gun 212 . As shown in FIG. 2 , the portable gun 212 may be connected to the nozzle 214 via a conduit or hose 216 . In some embodiments, the mobile batch processing and mixing vehicle 100 may be configured to batch, mix and apply a non-Portland cement based construction material. This material may be batch processed and mixed at the vehicle (eg, within the batch processing and mixing device 106 ) prior to placement in the second container 108 . This material can be delivered to nozzle 214 where it can be mixed with the liquid in storage unit 104 before being applied to a surface when construction or repair is desired. The properties of non-Portland cement based construction materials are discussed in further detail below. In some embodiments, the non-Portland cement-based building materials described herein may have better strength values, a high resistance and non-reactivity with inorganic and organic acids, and in addition have early high strength values, compared to existing materials. Non-Portland cement based construction materials may exhibit improved resistance to high temperatures and significantly higher strength and durability properties. In one example, non-Portland cement based building materials can have an excellent resistance to strong inorganic acids. In addition, products derived from non-Portland cement based construction materials can have excellent compressive strength and a very low thermal conductivity. The material may comprise a dry mix (eg, a binder mix) of blast furnace slag material, inorganic polymer material, base powder, and sand in a batch processing and mixing apparatus to produce a non-Portland cement based material. In some embodiments, the binder mixture can be used to create the non-Portland cement based material. In some embodiments, a binder mixture may comprise 4-45 wt% volcanic rock, 0-40 wt% latent hydraulic material, selected from the group: sodium silicate, alkali metal hydroxides , alkali metal carbonates and mixtures thereof of 10% to 45% by weight of the alkaline component and 20% by weight to 90% by weight of the pellets one or more. In some embodiments, the binder mixture may include sulfate (SO 4 2− ) in a proportion of less than 1 wt % as a contaminant. In some embodiments, the binder mixture may contain calcium in a proportion of up to 5% by weight in the form of calcium oxide (CaO). In some embodiments, non-Portland cement based building materials may include various types of inorganic polymeric materials. Inorganic polymeric materials can include, but are not limited to, volcanic rocks. Thus, the terms "inorganic polymeric material" and "volcanic rock" may be used interchangeably within the scope of the present invention. A portion of these inorganic polymeric materials may include, but are not limited to, pozzolanic materials that can react with strong bases and allow the admixture to mix with sand and/or grit. The pozzolan or pozzolanic material may be a synthetic or natural rock composed of silica, clay, limestone, iron oxides and alkaline substances obtainable by thermal effects. When combined with calcium hydroxide and water, they can form a binding agent. Natural pozzolana can be magmatic rocks, such as tuff or Rhine pumice tuff, but can also be sedimentary rocks containing a high proportion of soluble silicic acid, and sometimes reactive alumina (clay). In some embodiments, pozzolan can be a readily available raw material and can be used as a volcanic rock or inorganic polymeric material in non-Portland cement based building materials. However, natural materials such as volcanic rock or some other substance may also be used, which may be more desirable if lesser fractions are used as very fine powders (eg, this volcanic rock powder). In some embodiments, non-Portland cement based building materials can include any number of pozzolanic materials, a portion of which can include, but is not limited to, finely ground clay, gneiss, granite, rhyolite, andesite, peridotite , potassium feldspar, albite, pumice, zeolite, etc. and mixtures thereof. These materials can be used in either calcined and/or non-calcined geotechnical forms. Additionally and/or alternatively, all raw materials (including, but not limited to, ash, pozzolan, slag) containing sufficient amounts of reactive (eg, metastable glass) SiO 2 and Al 2 O 3 may also be suitable for use in Embodiments of the present invention. In some embodiments, non-Portland cement based building materials may include a latent hydraulic material. A latent hydraulic material as used herein may include, but is not limited to, fly ash, kaolin, pumice tuff, granular slag (eg, blast furnace slag material), and/or a mixture thereof. In one example, fly ash in the form of lignite fly ash and anthracite fly ash may be used. In some embodiments, the pozzolanic material may comprise active silicates, such as slag sand or fly ash. In some embodiments, brick ash (refractory clay) or fly ash from plants that burn anthracite or lignite may be referred to as synthetic pozzolan. Thus, the term "fly ash" as used herein may refer to a non-natural or synthetic pozzolan. In some embodiments, certain advantageous properties of fly ash can be caused by a favorable ratio of silica to alumina and calcium oxide, which can differentiate these species. However, and as will be discussed in more detail below, the fly ash may contain some sulfate and/or calcium oxide. Thus, if fly ash is used in a binder mixture, one type of fly ash containing the specified substance in an advantageous ratio can be used. In some embodiments, non-Portland cement based building materials may include a base powder material and/or various mixed liquids. Some possible mixed liquids may include, but are not limited to, potassium and sodium water glasses, alkali metal hydroxides, and the like. In some embodiments, the base or alkaline component may be sodium silicate in the form of an aqueous sodium silicate solution or a powdered sodium silicate form. In some embodiments, a spray-dried silicate can be used. When alkali metal hydroxides or alkali metal carbonates are used, these materials can be used in their liquid form or in a powder or granular form. In some embodiments, the reaction between the SiO2 / Al2O3 - containing composition and the alkaline mixed liquid can result in aluminosilicates having a three-dimensional structure. These frame structures allow the creation of a construction material that does not contain Portland cement in its compound. As discussed above, the binder mixture and/or the ingredients of the binder mixture may include calcium. In some embodiments, the binder mixture may contain calcium in the form of partially calcium oxide (CaO). Such CaO moieties in the binder mixture and/or non-Portland cement based building materials can result in hydrated calcium silicate after reaction with the aqueous alkaline solution and/or ingredients, which can have known adverse chemical properties. Furthermore, calcium ions, which are a constituent of the cement-based crystalline structure, often exhibit an undesirable solubility, which can lead to a weakening of one of the cement structures over time. A minimum possible proportion of calcium can be used for this reason. Embodiments of the present invention utilizing SiO2 in the form of soluble silicate, iron oxide , Al2O3 in the form of aluminate, and calcium oxide can be implemented with water-soluble silicates or strong bases, thus resulting in less calcium Or an inorganic binding system with almost no calcium. In some embodiments, the binder mixture may contain calcium in the form of calcium oxide (CaO) in a proportion of up to 5% by weight. In some embodiments, the binder mixture may contain calcium in the form of calcium oxide in a proportion of up to 2% by weight. Additionally and/or alternatively, calcium may be contained in the form of calcium oxide and in a proportion of up to 1% by weight. In some embodiments, the binder mixture may contain sulfate ( SO4-2 ) in the form of contaminants and/or in a proportion of less than 1 wt%. Sulfate in the form of its salt is an environmentally relevant substance. Increased pollutants in sulfate-laden environments caused by agricultural fertilization and waste management. Sulfates have been shown to cause acidification of land and groundwater. Due to the generally higher solubility of sulfate in water, it is easily transported in groundwater, seepage and surface currents, ultimately increasing the acidification effect in the environment of sulfate-containing materials in waste storage facilities. Sulfate is broken down into sulfite by microbial processes, which in turn can have a negative effect on animals and plants. In some embodiments, the sulfate ratio in the binder mixture can be as low as possible to avoid at least these negative effects. In some embodiments, the binder mixture may contain sulfate (SO 4 -2 ) in the form of contaminants and/or in a proportion of less than 0.5% by weight. In one embodiment, sulfate (SO 4 -2 ) may be contained in a proportion of less than 0.25% by weight. In some embodiments, the non-Portland cement-based building material may comprise sand. However, other pellets can also be used. For example, other aggregates used as a non-cementitious concrete in a binder mixture may include, but are not limited to, gravel, sand, basalt, and the like. Other materials for non-cementitious concrete within the scope of the present invention may also be used. Alternatively and in various applications, a mixture of perlite, expanded leaf rock, pumice, or the like may also be used. In some embodiments, the binder mixture may comprise 20% to 70% by weight of the pellets. Additionally and/or alternatively, 20% to 50% by weight of the pellets may be included in the binder mixture. In one embodiment, 20% to 40% by weight of the pellets may be included in the binder mixture. In some embodiments, the binder mixture may also contain water. Thus, in one embodiment, volcanic rock (eg, inorganic polymer material) at 4-45 wt%, latent hydraulic material (eg, blast furnace slag material) at 0-40 wt% ), 10% to 45% by weight of alkaline components (such as alkalis), 20% to 90% by weight of pellets (such as sand) and/or water constitute a binder mixture that exhibits resistance to various chemicals and in particular Very high resistance to one of the acids. In some embodiments, the alkaline component may include sodium silicate, alkali metal hydroxides and/or alkali metal carbonates. Additionally and/or alternatively, the binder mixture may comprise sulfate (SO 4 2− ) in the form of contaminants and/or in a proportion of less than 1% by weight. In some embodiments, the binder mixture may include calcium in a proportion of up to 5% by weight in the form of calcium oxide (CaO). In operation, the raw materials may be roughly batched and mixed (eg, all or part of the vehicle 100 ) and then passed to the portable gun 212 . The non-Portland cement based building material may be carried through conduit 216 to nozzle 214 via compressed air. In a particular embodiment, potassium silicate, 48% solids, density 1,52 g/cm3, Wt SiO2:K2O 1,14 and some liquids may be added and the partially liquefied mixture applied pneumatically to the surface of interest Coarse mixing was previously performed within the nozzle 214 for a short period of time (eg, less than 1 second). Embodiments encompassed herein may include mixtures containing some or all of the following: slag (eg, non-natural pozzolans, base or latent hydraulic materials), fly ash (eg, non-natural pozzolans and options in formulations), inorganic Polymers (eg, natural pozzolans and options, ground volcanic materials/volcanic rocks), alkalis/alkaline ingredients (eg, powders or liquids), other liquids containing water (options) and sand/grit or other aggregates. Examples of specific mixtures are provided below, however it should be noted that the specific mixtures provided herein are included by way of example only. Several additional and alternative embodiments are also within the scope of the present invention. In a specific example, the non-Portland cement based construction material may include the following mixture:
Figure 105136165-A0304-0001
Table 1 In some embodiments, the ingredients of the mixture may comprise a Blaine fineness value of about 2500 cm 2 /g to 5000 cm 2 /g. The Blaine value is a standard measure for the degree of cement pulverization. The Bryan value is given as a specific surface value (cm 2 /g) determined in a laboratory using a Bryan device. For example, standard Portland cement (CEM I 32.5) has a Blaine value of one of 3000 to 4500. In some embodiments, the composition of the binder mixture, volcanic rock, and/or latent hydraulic material may be used in a finely ground state having a Blaine value greater than 3000. In one embodiment, the volcanic rock and/or latent hydraulic material may have a Blaine value greater than 3500. Finely ground ingredients can result in a significantly improved reaction rate. Finely ground volcanic rock can be more tractable and can further lead to increased resistance to one of a variety of different chemicals, especially acids, in the finished product. In another example, a non-Portland cement based building material may include the following mixture:
Figure 105136165-A0304-0002
Table 2 In another example, a non-Portland cement-based building material may include the following mixture:
Figure 105136165-A0304-0003
Table 3 In some embodiments, from 4 wt % to 45 wt % volcanic rock, 0 wt % (or greater than 0 wt %) to 40 wt % latent hydraulic material, The reaction of 10% to 45% by weight of an alkaline ingredient and 20% to 90% by weight of the pellets produces a non-Portland cement based building material or binder mixture. In some embodiments, the alkaline component may include sodium silicate, alkali metal hydroxides and/or alkali metal carbonates. In addition, the binder mixture may contain sulfate (SO 4 2− ) in the form of contaminants and/or in a proportion of less than 1% by weight. In some embodiments, the binder mixture may contain calcium in a proportion of up to 5% by weight in the form of calcium oxide (CaO). Examples of non-Portland cement based construction materials produced an unexpected result because the reaction time of the alkaline feedstock and rock dust was sufficient to produce a viscous compound. Through several tests, it was found that this compound adhered extremely strongly to a vertical surface, established a tight bond and hardened within 3 days with a compressive strength value of about 50 N/mm 2 (8000 psi). In some embodiments, binder mixtures or non-Portland cement based construction materials may be used in different technical fields of application: dry mortar, gypsum, and shotcrete . Dry mortar and gypsum mixtures may be produced by mixing dry ingredients. For this purpose, spray-dried reactive silicates or alkali metal hydroxides can be used. Based on this, the finished mixture can be produced as shotcrete for its use. Foamed Concrete Commercial foamed concrete is a mineral-based autoclaved foamed bulk building material with an original density of 300 kg/m 3 to 800 kg/m 3 . Foamed concrete is typically produced from raw materials such as lime, anhydrite, cement, water and silica sand and can combine the properties of the support structure with thermal insulation. Highly insulated masonry constructions can be produced with foamed concrete in a monolithic single wall construction. In some embodiments, a production process may include grinding a silica sand until it has a Blaine value greater than 3000 when ground in, for example, a pebble mill. The raw materials can be combined to form, for example, a mortar mixture in a ratio of 1:1:4 with the addition of water. In some embodiments, a small portion of aluminum powder or paste may be added to the finished paste. The mortar mixture can be poured into a sink in which metal particulate aluminum forms hydrogen gas in an alkaline mortar slurry. It is possible to obtain air bubbles that allow the foaming of the progressively hardened mortar. The final volume is obtained after 15 to 50 minutes. At this time, blocks of 3 to 8 meters long, 1 to 1.5 meters wide and 50 to 80 cm high can be obtained. These solid blocks or blocks can be cut to any desired size using wire. In some embodiments, the blocks can be in a special steam pressure boiler (eg, an autoclave) at a steam temperature of 180°C to 200°C where the material can contain its final properties after 6 to 12 hours Cured under one atmosphere of 10 to 12 bar. Chemically speaking, foamed concrete may largely correspond to the natural mineral tobermorite, but it may be a synthetic material. In addition to low thermal conductivity, the construction material can be distinguished by its lack of flammability, such that it can be classified, for example, in European fire classification A1. Modern foamed concrete compositions may contain a mixture of quicklime, cement, sand and water. Depending on the dry density and the ratio of quicklime to cement, this composition can differentiate between lime-rich and cement-rich mixtures. Additionally, anhydrite or sulfate carriers in the form of gypsum can be used to improve the compressive strength and shrinkage properties due to the improved growth of the crystalline "house of cards" structure in tobermorite. As a result of these discoveries, the addition of a sulfate carrier in the form of anhydrite/gypsum has proven advantageous in production in previous decades and is therefore an ingredient in all current foamed concrete compositions. The building material can obtain a pore structure by adding a small amount of aluminum powder during the mixing process. The finely divided aluminum in the mixture can be reacted in an alkaline medium to form hydrogen gas which can cause the starting mixture to bubble slowly. This pore structure can remain in the product, even after the actual hydrothermal curing process, and can be substantially responsible for the properties of the final product. In some embodiments, the production procedure can be broken down into one or more of the following actions: 1. Grind silica sand and prepare recycled mud 2. Mix and pour foamed concrete mud 3. Make coarse lumps or lumps Expand, set and cut the rough blocks or blocks 4. Cures the uncut blocks under hydrothermal conditions 5. Packs and stores the finished product After mixing the foamed concrete compound and pouring it into a steel mold, several Complex chemical reactions can occur between solidification and hydrothermal solidification phases. When water is added, the hydrogenation of the quicklime can begin during the mixing phase. Since this is an exothermic reaction, the foamed concrete compound can be heated and the hydration reaction of the cement phase can be accelerated. Thus, a continuous hardening of the foamed concrete compound can occur during the expansion caused by the growth of hydrogen. In order to obtain a homogeneous pore structure, the gas growth can be adjusted to the viscosity curve of the expanded foamed concrete compound. If this step is not achieved, structural damage called expansion rupture can occur during expansion, which can be uncorrectable during the subsequent production process. After a solidification period of several hours, the uncut block can be cut into suitable rock formations by tensioned wire. All scrap generated during the cutting procedure can be recycled in the composition so that no scrap is present during the production process. The issue of recycling capacity will be crucial in the future. On the one hand, European demand calls for a reduction in waste, which is accompanied by the closure of landfills and an increased demand for more recycling. On the other hand, there is an increased need for environmental protection, such as minimum threshold values and draft guidelines for alternative building material regulations in the framework of a cladding regulation on groundwater/alternative building materials/soil protection, which at least in some cases Makes it more difficult to recycle building materials available on the market. The leaching regime for sulfate can be derived from sulfate concentrations in the eluate between 900 mg/l and 1650 mg/l. According to the Alternative Building Materials Regulations, the threshold value for mineral-based alternative building materials used in the eluate is 250 mg/l sulphate. Omitting the sulfate carrier and cement in the production of foamed concrete can drastically reduce the above-mentioned sulfate concentration in the eluate and may enable the use of foamed concrete construction waste as a mineral-based alternative construction material. In some embodiments, the use of non-cementitious binders according to the present invention can eliminate this disadvantage, and in addition can have a very low calcium content. Typical technical properties are otherwise unaffected. Concrete A concrete part or concrete element is a composition consisting of concrete, reinforced concrete or prestressed concrete, which is pre-industrially produced in a factory and then (usually) placed in its final position using a crane. Concrete and reinforced concrete elements are widely used and implemented in various construction techniques. The production of PiXuan elements for open channel systems may be used in some embodiments of the present invention. Fire protection Listed in DIN 4102 are gypsum finished products for concrete and reinforced concrete elements (building materials and reaction of building elements with fire). Technically suitable gypsum for fire protection are vermiculite and perlite insulating gypsum and gypsum according to DIN 18550, Part 2. In some embodiments, a spray mix may be supplied as a dry mortar with a hydraulically hardening binder and mixed with water shortly before application - a mixture of mineral fibers, such as glass wool, rock wool, or mineral wool. The technical characteristics regarding fire protection can be the same as those for spraying asbestos. The use of non-cementitious binders in gypsum finished products can further improve fire resistance because a non-cementitious binder can have a more favorable expansion behavior and can exhibit lower shrinkage at high temperatures. In some embodiments of the present invention, conventional mixers cannot be used to produce binder mixtures. In some embodiments, the use of a so-called clay mixer or continuous mixer for producing a premix and subsequent use of an intensified mixer or planetary mixer for mixing in the pellets may result in compression or enclosure in a mold And one inorganic material of the desired product can be produced after a mechanical compression. Table 4, provided below, shows which mixing and application techniques according to embodiments of the present invention can lead to which areas of application for binder mixtures.
Figure 105136165-A0304-0004
Table 4 In some embodiments of the present invention, a method for producing a moldable concrete compound is provided. The method may include one or more of the following acts: The method may include supplying one of volcanic rock containing 4-45 wt%, 0-40 wt% latent hydraulic material, 10-45 wt% A binding agent mixture of one or more of the basic components. In one example, the alkaline component or base may be selected from the group and/or may include: sodium silicate, alkali metal hydroxides, alkali metal carbonates, and mixtures thereof. In some embodiments, the binder mixture may contain sulfate (SO 4 2− ) in the form of contaminants in the binder mixture in a proportion of less than 1 wt %. In addition, calcium in a proportion of up to 5% by weight in the form of calcium oxide (CaO) may be contained in the binder mixture. The method may also include using a clay mixer or continuous mixer to produce a premix of the binder mixture. In some embodiments, the method may further comprise mixing the premix with 20% to 90% by weight of the aggregates using an intensive mixer or planetary mixer to produce a moldable concrete compound. In some embodiments, this may be performed within a period of one minute to 5 minutes. In one embodiment, this may be performed within a time period of about 2 minutes. The method may also include compressing the moldable concrete compound by compression or vibration to form pipes, concrete elements, iron sleepers, concrete blocks, form pavers, sidewalk slabs, and the like. In some embodiments of the present invention, a method for producing a moldable concrete compound is provided. The method may include one or more of the embodiments presented below. In some embodiments, the method may include supplying one of volcanic rock comprising 4 to 45 wt%, 0 to 40 wt% latent hydraulic material, 10 to 45 wt% of an alkaline component, or One of more than one binder mixture. In some embodiments, the alkaline component may be selected from the group and/or may include: sodium silicate, alkali metal hydroxides, alkali metal carbonates, and mixtures thereof. In one example, the binder mixture may comprise 20% to 90% by weight of the pellets. In some embodiments, the binder mixture may contain sulfate (SO 4 2− ) in the form of contaminants with a proportion of less than 1 wt %. In addition, calcium in a proportion of up to 5% by weight in the form of calcium oxide (CaO) may be contained in the binder mixture. The method may also include using a dry mixer to produce a dry mix. The method may further comprise mixing the dry mixture with water using an intensive mixer or planetary mixer to produce a moldable concrete compound. In some embodiments of the present invention, a method for producing a sprayable concrete compound is provided. The method may include one or more of the embodiments presented below. In some embodiments, the method may include supplying one of volcanic rock comprising 4 to 45 wt%, 0 to 40 wt% latent hydraulic material, 10 to 45 wt% of an alkaline component, or One of more than one binder mixture. In some embodiments, the alkaline component may be selected from the group and/or may include: sodium silicate, alkali metal hydroxides, alkali metal carbonates, and mixtures thereof. In some embodiments, the binder mixture may comprise 20% to 90% by weight of the pellets. In some embodiments, the binder mixture may contain sulfate (SO 4 2− ) in the form of contaminants with a proportion of less than 1 wt %. In addition, calcium in a proportion of up to 5% by weight in the form of calcium oxide (CaO) may be contained in the binder mixture. The method may also include using a dry mixer to produce a dry mix. In some embodiments, the method may further comprise mixing the dry mixture with water in a spray gun for producing and immediately applying a sprayable concrete compound. In some embodiments, binder mixtures can be prepared for different application areas, including, for example, those listed in Table 4 above. Examples 1-5 provided below may illustrate one or more embodiments of the present invention. Example 1 In a mixing and kneading machine with an extrusion screw, 1 part finely ground volcanic rock (eg, Blaine number 3500), 0.15 parts fly ash, and 0.8 parts sodium silicate can be combined and vigorously mixed until a homogenous Pour the plaster. This gypsum can be mixed with 4 parts basalt and sand in an intensive mixer (or planetary mixer) for about 2 minutes. Thereby, a soil-moist cement-free concrete suitable for application as one of the face concretes in the production of concrete blocks can be obtained. The sulfate content of the mixture may reach 0.16% by weight and the calcium oxide content may be 0.8% by weight. Compression of such a mixture can be achieved, for example, by compression and vibration as practiced in block forming machines. The resulting products can be distinguished by significantly higher acid resistance, more favorable mechanical strength properties, and a significantly stronger color print. When other aggregate mixtures such as gravel and sand are used, concrete pipes or special concrete elements can also be produced, depending on a specific particle size distribution curve. Other product variations are also possible by controlling moisture levels and adapting application techniques (eg, pouring, centrifugation, etc.). Example 2 In an intensive mixer, 0.2 parts of granular slag, 1 part of finely ground volcanic rock and 3 parts of sand can be mixed. This dry mix can be placed in a bag. On a job site, 1 part of the mixture produced in this way can be mixed with 0.7 part of sodium silicate in a pavement mixture and brought to the desired consistency. The sulfate content of the mixture can be as high as 0.19 wt% and the calcium oxide content can be 0.57 wt%. The non-cementitious blocks and plastering mortars obtained in this way can be applied to a surface to be coated in different ways (eg by conventional plastering, spraying, etc.). Example 3 A dry mix consisting of 1 part pozzolan (eg, a Blaine value greater than 3500), 0.4 parts fly ash, 1 part perlite, and 0.7 parts powdered sodium silicate can be produced in a dry mixer. The dry mixture can be wetted with water and poured into molds for compression by vigorous mixing with high shear. The sulfate content of the wet mixture can be as high as 0.32 wt% and the calcium oxide content can be 1.8 wt%. In practice based on one of the above examples, samples were obtained after a hardened phase (after being subjected to incineration for an extended period of time) and showed no cracks or visible cracks and did not exhibit diminished mechanical strength properties after testing. Nor was there any visible damage after exposure to freezing temperatures. Example 4 In a dry mixer, a dry mixture consisting of 1 part pozzolan (eg, a Blaine value greater than 3500), 0.4 parts granular slag, 1 part perlite, and 0.7 parts powdered sodium silicate can be produced. The dry mix can be continuously applied to a spray gun and combined with water to create a sprayable concrete. Pipe and cable penetrations, heat-sensitive building materials and surfaces can be easily sealed or coated with heat-resistant and fire-resistant non-cementitious compounds using spray technology. The sulphate content of the sprayable concrete can be as high as 0.31 wt% and the calcium oxide content can be 1.29 wt%. Example 5 In order to produce a foamed concrete, 16.2 parts of volcanic rock, 3.35 parts of fly ash, 23 parts of silica sand can be premixed centrally in a commercial mixer. This dry mix can be increased to 33 parts sodium silicate under strong shear at 38°C and can be further mixed with 0.43 parts aluminum paste in the same mixer. The binder mixture can be poured into a Teflon mold and heated in the mold for 120 minutes to 80°C. The mixture can become firm and at the same time dramatically increase the volume while still being cuttable. For curing, the mold can be placed in a curing chamber and held therein for 30 minutes at 180°C. Alternatively, an autoclave can be used at 120°C. A moulded body can be obtained having optical properties comparable to a foamed concrete obtained according to a typical method. Unlike typical foamed concrete, the material can be acid resistant and has a sulfate content of 0.21 wt% and a calcium oxide content of 0.6 wt%. In one embodiment, the resulting build material may have a very low sulfate and calcium content. The terminology used herein is for the purpose of describing particular embodiments only and is not intended to limit the invention. As used herein, the singular forms "a" (a, an) and "the" are intended to include the plural forms as well, unless the context clearly dictates otherwise. It will be further understood that the terms "comprises" (comprises and/or comprising) when used in this specification designate the presence of stated features, integers, steps, operations, elements and/or components, but do not preclude the presence or addition of one or more Other features, integers, steps, operations, elements, components and/or groups thereof. The corresponding structures, materials, acts, and equivalents of all means or step additional function elements within the scope of the claims below are intended to include any structure, material, or act for performing the function in combination with other elements specifically mentioned. The description of the present invention is presented for purposes of illustration and description and is not intended to be exhaustive or to limit the invention to the form disclosed. Numerous modifications and variations will be apparent to those skilled in the art without departing from the scope and spirit of the invention. The embodiments were chosen and described in order to best explain the principles of the invention and its practical application, and to enable those of ordinary skill to understand the invention for various embodiments with various modifications as are suited to the particular use contemplated. Since the inventive content of this application has been described in detail and with reference to the embodiments of this application, it will be apparent that modifications and variations are possible without departing from the scope of the invention as defined in the appended claims.

100‧‧‧行動分批處理及混合車輛102‧‧‧第一容器104‧‧‧儲存單元106‧‧‧分批處理及混合裝置108‧‧‧第二容器110‧‧‧可調整傳遞機構212‧‧‧可攜帶槍214‧‧‧噴嘴216‧‧‧導管或軟管100‧‧‧Mobile batch processing and mixing vehicle 102‧‧‧First container 104‧‧‧Storage unit 106‧‧‧Batch processing and mixing device 108‧‧‧Second container 110‧‧‧Adjustable transfer mechanism 212 ‧‧‧Can carry gun 214‧‧‧Nozzle 216‧‧‧Catheter or hose

圖1係根據本發明之一實施例之經構形以分批處理、混合及施用一非水泥基材料之一行動系統之一側視圖; 圖2係根據本發明之一實施例之經構形以分批處理、混合及施用一非水泥基材料之一行動系統之一側視後視圖;且 圖3係描繪根據本發明之一實施例之符合一非水泥基施用程序之操作之一流程圖。 各種圖式中之相同參考符號可指示相同元件。Figure 1 is a side view of a motion system configured to batch, mix and apply a non-cementitious material according to an embodiment of the invention; Figure 2 is configured according to an embodiment of the invention A side rear view of an action system for batch processing, mixing and applying a non-cementitious material; and FIG. 3 is a flowchart depicting a flow chart of operations consistent with a non-cementitious application procedure according to an embodiment of the present invention . The same reference signs in the various figures may refer to the same elements.

Claims (11)

一種結合劑混合物,其包括:4重量%至45重量%之非浮石火山岩粉末;大於0重量%至40重量%之潛在水硬材料,其中該潛在水硬材料包含褐煤飛灰、無煙煤飛灰、高嶺土及浮石凝灰岩之一或多者且其中該火山岩具有大於3000之一布萊恩值,且其中該潛在水硬材料具有大於3000之一布萊恩值;10重量%至45重量%之一鹼性成分,其中該鹼性成分包含鹼金屬類氫氧化物及鹼金屬碳酸鹽之一或多者;20重量%至86重量%之粒料;小於1重量%之硫酸鹽,其中該硫酸鹽在該結合劑混合物中係為污染物之形式;及至多5重量%之鈣。 A binder mixture comprising: 4 wt% to 45 wt% non-pumice volcanic rock powder; greater than 0 wt% to 40 wt% latent hydraulic material, wherein the latent hydraulic material comprises lignite fly ash, anthracite fly ash, One or more of kaolin and pumice tuff and wherein the volcanic rock has a Blaine value greater than 3000, and wherein the latent hydraulic material has a Blaine value greater than 3000; 10% to 45% by weight of an alkaline component , wherein the alkaline component comprises one or more of alkali metal hydroxides and alkali metal carbonates; 20% to 86% by weight of pellets; less than 1% by weight sulfate, wherein the sulfate is in the combined in the form of contaminants in the agent mixture; and up to 5% by weight of calcium. 如請求項1之結合劑混合物,其中該結合劑混合物中之該硫酸鹽小於0.5重量%。 The binder mixture of claim 1, wherein the sulfate in the binder mixture is less than 0.5% by weight. 如請求項1之結合劑混合物,其中該結合劑混合物中之該鈣係氧化鈣之形式。 The binder mixture of claim 1, wherein the calcium in the binder mixture is in the form of calcium oxide. 如請求項1之結合劑混合物,其中該結合劑混合物中之該鈣為至多2重量%。 The binder mixture of claim 1, wherein the calcium in the binder mixture is at most 2% by weight. 如請求項1之結合劑混合物,其中該火山岩係火山灰。 The binder mixture of claim 1, wherein the volcanic rock is pozzolan. 如請求項1之結合劑混合物,其中該粒料包含砂礫、砂、玄武岩、珍珠岩及膨脹葉岩之一或多者。 The binder mixture of claim 1, wherein the pellets comprise one or more of gravel, sand, basalt, perlite, and expanded leaf rock. 如請求項1之結合劑混合物,其中該結合劑混合物中之該粒料係20重量%至70重量%。 The binder mixture of claim 1, wherein the pellets in the binder mixture are 20% to 70% by weight. 如請求項1之結合劑混合物,其中該結合劑混合物中之該粒料係20重量%至50重量%。 The binder mixture of claim 1, wherein the pellets in the binder mixture are 20% to 50% by weight. 如請求項1之結合劑混合物,其中該結合劑混合物中之該粒料係20重量%至40重量%。 The binder mixture of claim 1, wherein the pellets in the binder mixture are 20% to 40% by weight. 如請求項1之結合劑混合物,其進一步包括水。 The binder mixture of claim 1, further comprising water. 一種結合劑混合物,其包括:4重量%至45重量%之非浮石火山岩粉末;大於0重量%至40重量%之潛在水硬材料,其中該潛在水硬材料包含褐煤飛灰、無煙煤飛灰、高嶺土及浮石凝灰岩之一或多者且其中該火山岩具有大於3000之一布萊恩值,且其中該潛在水硬材料具有大於3000之一布萊恩值; 10重量%至45重量%之一鹼性成分,其中該鹼性成分包含粉末矽酸鈉及一噴霧乾燥矽酸鹽之一或多者且其中該鹼性成分包含鹼金屬類氫氧化物及鹼金屬碳酸鹽;20重量%至86重量%之粒料;小於1重量%之硫酸鹽,其中該硫酸鹽在該結合劑混合物中係為污染物之形式;及至多5重量%之鈣。 A binder mixture comprising: 4 wt% to 45 wt% non-pumice volcanic rock powder; greater than 0 wt% to 40 wt% latent hydraulic material, wherein the latent hydraulic material comprises lignite fly ash, anthracite fly ash, one or more of kaolin and pumice tuff and wherein the volcanic rock has a Blaine value greater than 3000, and wherein the latent hydraulic material has a Blaine value greater than 3000; 10% to 45% by weight of an alkaline component, wherein the alkaline component includes one or more of powdered sodium silicate and a spray-dried silicate, and wherein the alkaline component includes an alkali metal hydroxide and an alkali Metal carbonate; 20% to 86% by weight of pellets; less than 1% by weight of sulfate, wherein the sulfate is in the form of contaminants in the binder mixture; and up to 5% by weight of calcium.
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CN104016633A (en) * 2014-05-29 2014-09-03 安徽梦谷纤维材料科技有限公司 Exterior wall color surface decoration mortar and preparation method thereof

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US3107901A (en) * 1959-08-03 1963-10-22 Harold M Zimmerman Pre-mixed concrete system
CN102648167A (en) * 2009-11-26 2012-08-22 建筑研究和技术有限公司 Inorganic binder system for the production of chemically resistant construction chemistry products
CN104016633A (en) * 2014-05-29 2014-09-03 安徽梦谷纤维材料科技有限公司 Exterior wall color surface decoration mortar and preparation method thereof

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