TWI620333B - Schottky diode and method for manufacturing the same - Google Patents
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Abstract
本發明實施例提供之肖特基二極體,包括:第一導電型態之井區;第二導電型態之輕掺雜區,位於井區上,且第一導電型態與第二導電型態相反;第二導電型態之重掺雜區,位於井區上;閘極結構,位於部份輕掺雜區上,且閘極結構具有閘極與閘極介電層,其中閘極結構未覆蓋的輕掺雜區與重掺雜區分別位於閘極結構的相反兩側;第一接點,電性連接重掺雜區與第一電極;第二接點,電性連接閘極與第二電極;以及第三接點,電性連接輕掺雜區與第二電極。 The Schottky diode of the embodiment of the present invention includes: a well region of a first conductivity type; a lightly doped region of a second conductivity type, located on the well region, and the first conductivity type and the second conductivity The opposite type; the heavily doped region of the second conductivity type is located on the well region; the gate structure is located on a portion of the lightly doped region, and the gate structure has a gate and a gate dielectric layer, wherein the gate The lightly doped region and the heavily doped region not covered by the structure are respectively located on opposite sides of the gate structure; the first contact is electrically connected to the heavily doped region and the first electrode; the second contact is electrically connected to the gate And the second electrode; and the third contact, electrically connecting the lightly doped region and the second electrode.
Description
本發明係關於肖特基二極體,更特別關於其結構與其形成方法。 The present invention relates to Schottky diodes, and more particularly to the structure and method of forming the same.
金屬與輕摻雜的半導體材料接觸會產生類似於PN接面的接觸結構(肖特基接觸),可用於製作肖特基二極體。外加正向電壓時,肖特基二極體處於導通狀態,電流流過肖特基二極體。外加反向電壓時,肖特基二極體處於關斷狀態。在理想情況下,反向電流為0。實際上,肖特基二極體不是理想裝置,會流過少量的反向漏電流。反向漏電流會影響電路的性能,降低電路的效率。為了降低反向漏電流,需降低輕掺雜的半導體材料之掺雜濃度,但這會讓肖特基二極體的啟動速度降低。 Contact of the metal with the lightly doped semiconductor material produces a contact structure (Schottky contact) similar to the PN junction and can be used to fabricate Schottky diodes. When a forward voltage is applied, the Schottky diode is in a conducting state, and current flows through the Schottky diode. When a reverse voltage is applied, the Schottky diode is turned off. In the ideal case, the reverse current is zero. In fact, the Schottky diode is not an ideal device and will have a small amount of reverse leakage current. Reverse leakage current can affect the performance of the circuit and reduce the efficiency of the circuit. In order to reduce the reverse leakage current, it is necessary to reduce the doping concentration of the lightly doped semiconductor material, but this will lower the startup speed of the Schottky diode.
綜上所述,目前需要新的肖特基二極體,在降低其反向漏電流時仍能兼顧其啟動速度。 In summary, a new Schottky diode is needed now, and its startup speed can be balanced while reducing its reverse leakage current.
本發明一實施例提供之肖特基二極體,包括:第一導電型態之井區;第二導電型態之輕掺雜區,位於井區上,且第一導電型態與第二導電型態相反;第二導電型態之重掺雜 區,位於井區上;閘極結構,位於部份輕掺雜區上,且閘極結構具有閘極與閘極介電層,其中閘極結構未覆蓋的輕掺雜區與重掺雜區分別位於閘極結構的相反兩側;第一接點,電性連接重掺雜區與第一電極;第二接點,電性連接閘極與第二電極;以及第三接點,電性連接輕掺雜區與第二電極。 A Schottky diode according to an embodiment of the present invention includes: a well region of a first conductivity type; a lightly doped region of a second conductivity type, located on the well region, and the first conductivity type and the second conductivity type The conductivity type is opposite; the second conductivity type is heavily doped The region is located on the well region; the gate structure is located on a portion of the lightly doped region, and the gate structure has a gate and a gate dielectric layer, wherein the lightly doped region and the heavily doped region are not covered by the gate structure Respectively located on opposite sides of the gate structure; the first contact electrically connecting the heavily doped region with the first electrode; the second contact electrically connecting the gate and the second electrode; and the third contact, electrical The lightly doped region and the second electrode are connected.
本發明一實施例提供之肖特基二極體的形成方法,包括:形成第一導電型態之井區;形成第二導電型態之輕掺雜區於井區上,且第一導電型態與第二導電型態相反;形成閘極結構於部份輕掺雜區上,且閘極結構具有閘極與閘極介電層;形成第二導電型態之重掺雜區於部份輕掺雜區與其下之井區中,其中閘極結構未覆蓋的輕掺雜區與重掺雜區分別位於閘極結構的相反兩側;形成第一接點,以電性連接重掺雜區與第一電極;形成第二接點,以電性連接閘極與第二電極;以及形成第三接點,以電性連接輕掺雜區與第二電極。 A method for forming a Schottky diode according to an embodiment of the present invention includes: forming a well region of a first conductivity type; forming a lightly doped region of a second conductivity type on the well region, and the first conductivity type The state is opposite to the second conductivity type; the gate structure is formed on a portion of the lightly doped region, and the gate structure has a gate and a gate dielectric layer; and the heavily doped region of the second conductivity type is formed in the portion In the lightly doped region and the well region below, the lightly doped region and the heavily doped region which are not covered by the gate structure are respectively located on opposite sides of the gate structure; the first contact is formed to be electrically doped heavily doped And a first electrode is formed to electrically connect the gate and the second electrode; and a third contact is formed to electrically connect the lightly doped region and the second electrode.
100‧‧‧基板 100‧‧‧Substrate
101‧‧‧隔離結構 101‧‧‧Isolation structure
103‧‧‧井區 103‧‧‧ Well Area
105‧‧‧輕掺雜區 105‧‧‧Lightly doped area
107‧‧‧閘極結構 107‧‧‧ gate structure
107A‧‧‧閘極介電層 107A‧‧‧gate dielectric layer
107B‧‧‧閘極 107B‧‧‧ gate
109‧‧‧中掺雜區 109‧‧‧Doped area
111、116‧‧‧光阻層 111, 116‧‧‧ photoresist layer
113‧‧‧間隔物 113‧‧‧ spacers
115‧‧‧重掺雜區 115‧‧‧ heavily doped area
117‧‧‧層間介電層 117‧‧‧Interlayer dielectric layer
119A、119B、119C‧‧‧接點 119A, 119B, 119C‧‧‧ contacts
第1A至1H圖係本發明一實施例中,肖特基二極體之製程剖視圖。 1A to 1H are cross-sectional views showing a process of a Schottky diode in an embodiment of the present invention.
第1A至1H圖係本發明一實施例中,肖特基二極體之製程剖視圖。如第1A圖所示,提供第一導電型態的基板100。在本發明一實施例中,基板100可為矽晶圓或絕緣層上矽(SOI)晶圓,且第一導電型態為p型。 1A to 1H are cross-sectional views showing a process of a Schottky diode in an embodiment of the present invention. As shown in FIG. 1A, a substrate 100 of a first conductivity type is provided. In an embodiment of the invention, the substrate 100 may be a germanium wafer or a germanium-on-insulator (SOI) wafer, and the first conductivity type is p-type.
接著如第1B圖所示,形成隔離結構101以定義肖特 基二極體(Schottky diode)區於隔離結構101之間。第1B圖所示之隔離結構101為局部氧化矽(LOCOS),其形成方法包括但不限於:沉積遮罩層如氮化矽層於基板100上、以微影及蝕刻製程圖案化遮罩層以露出部份基板100、熱氧化露出的部份基板100以形成氧化矽層、及移除圖案化的遮罩層。上述形成的氧化矽層即LOCOS。在其他實施例中,隔離結構101為淺溝槽隔離(STI)或中溝槽隔離(MTI),其形成方法包括但不限於:形成遮罩層於基板100上、以微影及蝕刻製程圖案化遮罩層以露出部份基板、蝕刻露出的部份基板100以形成溝槽、將隔離材料如氧化矽填入溝槽中、以及移除圖案化的遮罩層。 Next, as shown in section in FIG. 1B, a spacer structure 101 to define the Schottky diode (Schottky diode) in the region between the isolation structure 101. The isolation structure 101 shown in FIG. 1B is a partial ruthenium oxide (LOCOS), and the formation method thereof includes, but is not limited to, depositing a mask layer such as a tantalum nitride layer on the substrate 100, and patterning the mask layer by a lithography and etching process. A portion of the substrate 100 is exposed to thermally oxidize the exposed portion of the substrate 100 to form a hafnium oxide layer, and the patterned mask layer is removed. The yttrium oxide layer formed above is LOCOS. In other embodiments, the isolation structure 101 is shallow trench isolation (STI) or medium trench isolation (MTI), and the formation method thereof includes, but is not limited to, forming a mask layer on the substrate 100, and patterning by lithography and etching process. The mask layer exposes a portion of the substrate, etches the exposed portion of the substrate 100 to form trenches, fills the spacer material, such as yttrium oxide, into the trench, and removes the patterned mask layer.
接著如第1C圖所示,形成第一導電型態的井區103於肖特基二極體區中。在一實施例中,井區103為p型,其形成方法可為佈植p型掺質如硼。 Next, as shown in FIG. 1C, the well region 103 of the first conductivity type is formed in the Schottky diode region. In one embodiment, the well region 103 is p-type and can be formed by implanting a p-type dopant such as boron.
接著如第1D圖所示,形成第二導電型態之輕掺雜區105於肖特基二極體區的表面。第二導電型態與第一導電型態相反。在一實施例中,輕掺雜區105為n型,其形成方法可為佈植n型掺質如磷或砷。在一實施例中,輕掺雜區105的掺雜濃度介於5.0E11至1.0E13之間。 Next, as shown in FIG. 1D, a lightly doped region 105 of a second conductivity type is formed on the surface of the Schottky diode region. The second conductivity type is opposite to the first conductivity type. In one embodiment, the lightly doped region 105 is n-type and can be formed by implanting an n-type dopant such as phosphorus or arsenic. In one embodiment, the doped concentration of the lightly doped region 105 is between 5.0E11 and 1.0E13.
接著如第1E圖所示,形成閘極結構107於部份的輕掺雜區105上。在第1E圖中,閘極結構107位於肖特基二極體區的中央,但實際上可偏向任一側而不限於圖示的中央位置。閘極結構107的形成方法包含但不限於:依序沉積閘極介電層與閘極層後,以微影及蝕刻製程圖案化閘極介電層與閘極層,以定義閘極結構107之閘極介電層107A與閘極107B。上述閘極介 電層107A可為氧化矽,而閘極107B可為n型掺雜或未掺雜之多晶矽。當閘極107B為n型掺雜之多晶矽時,可在沉積閘極層時臨場佈植n型掺質。 Next, as shown in FIG. 1E, a gate structure 107 is formed on a portion of the lightly doped region 105. In Fig. 1E, the gate structure 107 is located at the center of the Schottky diode region, but may be biased to either side without being limited to the central position shown. The method for forming the gate structure 107 includes, but is not limited to, sequentially depositing a gate dielectric layer and a gate layer, and patterning the gate dielectric layer and the gate layer by a lithography and etching process to define the gate structure 107. The gate dielectric layer 107A and the gate 107B. The above gate Electrical layer 107A can be yttrium oxide and gate 107B can be n-type doped or undoped polysilicon. When the gate 107B is an n-type doped polysilicon, the n-type dopant can be implanted on site when the gate layer is deposited.
接著如第1F圖所示,形成第二導電型態之中掺雜區109於閘極結構107的一側。在一實施例中,中掺雜區109為n型,其形成方法包含但不限於:形成光阻層111於閘極結構107與輕掺雜區105上、微影圖案化光阻層111以露出閘極結構107一側之輕掺雜區105(而不露出閘極結構107另一側之輕掺雜區105)、以及佈植n型掺質如磷或砷至露出的輕掺雜區105與其下之井區103中。如第1F圖所示,中掺雜區109與輕掺雜區105的交界對準閘極結構107的側壁邊緣。在本發明一實施例中,中掺雜區109的掺雜濃度大於輕掺雜區105的掺雜濃度。舉例來說,中掺雜區109的掺雜濃度介於1.0E13~1.0E15之間。 Next, as shown in FIG. 1F, a doped region 109 in the second conductivity type is formed on one side of the gate structure 107. In one embodiment, the intermediate doping region 109 is n-type, and the forming method thereof includes, but is not limited to, forming the photoresist layer 111 on the gate structure 107 and the lightly doped region 105, and patterning the photoresist layer 111 with Exposing the lightly doped region 105 on one side of the gate structure 107 (without exposing the lightly doped region 105 on the other side of the gate structure 107), and implanting an n-type dopant such as phosphorus or arsenic to the exposed lightly doped region 105 is in the well area 103 below it. As shown in FIG. 1F, the boundary between the medium doped region 109 and the lightly doped region 105 is aligned with the sidewall edge of the gate structure 107. In an embodiment of the invention, the doping concentration of the medium doped region 109 is greater than the doping concentration of the lightly doped region 105. For example, the doping concentration of the medium doped region 109 is between 1.0E13 and 1.0E15.
接著如第1G圖所示,移除光阻層111後,形成間隔物113於閘極結構107的側壁上以覆蓋部份中掺雜區109。移除光阻層111的方法可為乾式灰化、濕式剝除、或上述之組合。在本發明一實施例中,間隔物113的形成方法包含但不限於:形成間隔物層於中掺雜區109、閘極結構107、與輕掺雜區105上,再進行非等向蝕刻以移除部份的間隔物層,以保留間隔物113於閘極結構107的側壁上。在本發明一實施例中,間隔物113可為氧化矽、氮化矽、氮氧化矽、或上述之多層結構。接著形成光阻層116保護輕掺雜區105,再形成第二導電型態之重掺雜區115於露出的部份中掺雜區109中。在一實施例中,重掺雜區115為n型,其形成方法包含但不限於:佈植n型掺質如磷或砷 至露出的中掺雜區109中。如第1G圖所示,重掺雜區115與中掺雜區109的交界對準間隔物113的邊緣。在本發明一實施例中,重掺雜區115的掺雜濃度大於中掺雜區109的掺雜濃度。舉例來說,重掺雜區115的掺雜濃度介於5.0E14~7.0E15之間。 Next, as shown in FIG. 1G, after the photoresist layer 111 is removed, a spacer 113 is formed on the sidewall of the gate structure 107 to cover the partially doped region 109. The method of removing the photoresist layer 111 may be dry ashing, wet stripping, or a combination thereof. In an embodiment of the invention, the method for forming the spacers 113 includes, but is not limited to, forming a spacer layer on the middle doped region 109, the gate structure 107, and the lightly doped region 105, and then performing anisotropic etching. A portion of the spacer layer is removed to retain spacers 113 on the sidewalls of the gate structure 107. In an embodiment of the invention, the spacer 113 may be tantalum oxide, tantalum nitride, hafnium oxynitride, or a multilayer structure as described above. A photoresist layer 116 is then formed to protect the lightly doped region 105, and a heavily doped region 115 of the second conductivity type is formed in the exposed portion of the doped region 109. In an embodiment, the heavily doped region 115 is n-type, and the formation method thereof includes, but is not limited to, implanting an n-type dopant such as phosphorus or arsenic. To the exposed medium doped region 109. As shown in FIG. 1G, the boundary between the heavily doped region 115 and the medium doped region 109 is aligned with the edge of the spacer 113. In an embodiment of the invention, the doping concentration of the heavily doped region 115 is greater than the doping concentration of the medium doped region 109. For example, the heavily doped region 115 has a doping concentration between 5.0E14 and 7.0E15.
接著如第1H圖所示,移除光阻層116後,形成層間介電層117於重掺雜區115上,並形成接點119A、119B、與119C以各自接觸重掺雜區115、閘極107B、與輕掺雜區105。移除光阻層116的方法可為乾式灰化、濕式剝除、或上述之組合。接點119A連接至第一電極(如陰極),且接點119B與119C連接至第二電極(如陽極)。至此即完成肖特基二極體。在本發明一實施例中,接點119A、119B、與119C的形成方法包含但不限於:形成遮罩層於層間介電層117上,以微影與蝕刻製程圖案化遮罩層並露出部份層間介電層117,蝕刻移除露出的層間介電層117以形成穿孔露出部份的重掺雜區115、閘極107B、與輕掺雜區105,最後將導電材料填入穿孔中以形成接點119A、119B、與119C。上述導電材料可為金屬如鎢、銅、銀、金、類似物、或上述之合金,其形成方法可為濺鍍法、電鍍法、或任何合適方法。 Then, as shown in FIG. 1H, after the photoresist layer 116 is removed, the interlayer dielectric layer 117 is formed on the heavily doped region 115, and the contacts 119A, 119B, and 119C are formed to contact the heavily doped region 115 and the gate respectively. The pole 107B and the lightly doped region 105. The method of removing the photoresist layer 116 may be dry ashing, wet stripping, or a combination thereof. Contact 119A is connected to a first electrode (such as a cathode), and contacts 119B and 119C are connected to a second electrode (such as an anode). This completes the Schottky diode. In an embodiment of the invention, the forming methods of the contacts 119A, 119B, and 119C include, but are not limited to, forming a mask layer on the interlayer dielectric layer 117, and patterning the mask layer by the lithography and etching process and exposing the mask layer. The interlayer dielectric layer 117 is etched to remove the exposed interlayer dielectric layer 117 to form the heavily doped region 115 of the via exposed portion, the gate 107B, and the lightly doped region 105, and finally the conductive material is filled into the via hole. Contacts 119A, 119B, and 119C are formed. The above conductive material may be a metal such as tungsten, copper, silver, gold, the like, or an alloy thereof, which may be formed by sputtering, electroplating, or any suitable method.
由於第二電極同時電性連接至閘極107B與輕掺雜區105,經由接點119B施加至閘極107B的電壓可開啟閘極結構107下方之輕掺雜區105(如通道),而經由接點119C施加至輕掺雜區105的電壓能更快通過閘極結構下方之輕掺雜區105,即縮短肖特基二極體所需的作動時間。另一方面,上述結構可採用較低掺雜濃度之輕掺雜區105以避免反向漏電流的問題,而閘 極結構107可避免降低輕掺雜區105之濃度所造成的問題(如肖特基二極體的作動時間拉長)。簡言之,上述肖特基二極體同時兼具快速啟動與低漏電流的優點。 Since the second electrode is electrically connected to the gate 107B and the lightly doped region 105 at the same time, the voltage applied to the gate 107B via the contact 119B can turn on the lightly doped region 105 (eg, the channel) under the gate structure 107, via The voltage applied to the lightly doped region 105 by the contact 119C can pass faster through the lightly doped region 105 under the gate structure, i.e., the actuation time required to shorten the Schottky diode. On the other hand, the above structure can adopt a lightly doped region 105 of a lower doping concentration to avoid the problem of reverse leakage current, and the gate The pole structure 107 avoids problems caused by reducing the concentration of the lightly doped region 105 (e.g., the actuation time of the Schottky diode is elongated). In short, the above Schottky diodes have the advantages of both fast start and low leakage current.
如第1H圖所示,閘極結構107未覆蓋的輕掺雜區105與重掺雜區115分別位於閘極結構107的相反兩側以達上述優點。另一方面,閘極結構107與輕掺雜區105的重疊長度介於0.3μm~1.0μm之間。若上述重疊長度過長,可能增加肖特基二極體的啟動時間。若上述重疊長度過短,可能產生漏電流的問題。 As shown in FIG. 1H, the lightly doped region 105 and the heavily doped region 115 which are not covered by the gate structure 107 are respectively located on opposite sides of the gate structure 107 to achieve the above advantages. On the other hand, the overlap length of the gate structure 107 and the lightly doped region 105 is between 0.3 μm and 1.0 μm. If the overlap length is too long, it may increase the start-up time of the Schottky diode. If the above overlap length is too short, a problem of leakage current may occur.
在上述實施例中,基板100與井區103為p型,輕掺雜區105、中掺雜區109、與重掺雜區115為n型,第一電極為陰極,而第二電極為陽極。在另一實施例中,基板100與井區103為n型,輕掺雜區105、中掺雜區109、與重掺雜區115為p型。第一電極為陰極,而第二電極為陽極。 In the above embodiment, the substrate 100 and the well region 103 are p-type, the lightly doped region 105, the medium doped region 109, and the heavily doped region 115 are n-type, the first electrode is a cathode, and the second electrode is an anode. . In another embodiment, the substrate 100 and the well region 103 are n-type, and the lightly doped region 105, the middle doped region 109, and the heavily doped region 115 are p-type. The first electrode is a cathode and the second electrode is an anode.
雖然本發明已以數個實施例揭露如上,然其並非用以限定本發明,任何本技術領域中具有通常知識者在不脫離本發明之精神和範圍內,當可作任意之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 While the invention has been described above in terms of several embodiments, it is not intended to limit the invention, and any one of ordinary skill in the art can make any changes and modifications without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.
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|---|---|---|---|---|
| US5818084A (en) * | 1996-05-15 | 1998-10-06 | Siliconix Incorporated | Pseudo-Schottky diode |
| TW201114032A (en) * | 2009-10-02 | 2011-04-16 | United Microelectronics Corp | Manufacturing method of lateral diffusion metal oxide semiconductor device |
| TW201126715A (en) * | 2010-01-29 | 2011-08-01 | Richtek Technology Corp | High voltage metal oxide semiconductor device and method for making same |
| US20120223383A1 (en) * | 2008-12-30 | 2012-09-06 | Vanguard International Semiconductor Corporation | Semiconductor structure and fabrication method thereof |
| TW201238049A (en) * | 2011-03-08 | 2012-09-16 | Vanguard Int Semiconduct Corp | High voltage semiconductor device and method for manufacturing the same |
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|---|---|---|---|---|
| US5818084A (en) * | 1996-05-15 | 1998-10-06 | Siliconix Incorporated | Pseudo-Schottky diode |
| US20120223383A1 (en) * | 2008-12-30 | 2012-09-06 | Vanguard International Semiconductor Corporation | Semiconductor structure and fabrication method thereof |
| TW201114032A (en) * | 2009-10-02 | 2011-04-16 | United Microelectronics Corp | Manufacturing method of lateral diffusion metal oxide semiconductor device |
| TW201126715A (en) * | 2010-01-29 | 2011-08-01 | Richtek Technology Corp | High voltage metal oxide semiconductor device and method for making same |
| TW201238049A (en) * | 2011-03-08 | 2012-09-16 | Vanguard Int Semiconduct Corp | High voltage semiconductor device and method for manufacturing the same |
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