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TWI667741B - Three dimensional memory device and method for fabricating the same - Google Patents

Three dimensional memory device and method for fabricating the same Download PDF

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TWI667741B
TWI667741B TW107136242A TW107136242A TWI667741B TW I667741 B TWI667741 B TW I667741B TW 107136242 A TW107136242 A TW 107136242A TW 107136242 A TW107136242 A TW 107136242A TW I667741 B TWI667741 B TW I667741B
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layer
trench
upper portion
stack structure
lower portion
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TW202017113A (en
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江昱維
陳介方
邱家榮
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旺宏電子股份有限公司
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Abstract

一種記憶體元件,包括基材、複數個導電層、複數個絕緣層、記憶層以及通道層。絕緣層和導電層交錯堆疊於基材上,形成一個多層堆疊結構,其中多層堆疊結構具有至少一條溝槽,穿過這些導電層和絕緣層。記憶層覆蓋多層堆疊結構,並且至少延伸至溝槽的側壁上。通道層覆蓋於記憶層上,其中通道層包括上方部、串列部和下方部。上方部鄰接溝槽的開口;下方部位於溝槽底部;串列部位於側壁之上,用以連接上方部和下方部,且具有實質小於上方部和下方部的離子摻雜濃度。 A memory component includes a substrate, a plurality of conductive layers, a plurality of insulating layers, a memory layer, and a channel layer. The insulating layer and the conductive layer are alternately stacked on the substrate to form a multilayer stacked structure, wherein the multilayer stacked structure has at least one trench passing through the conductive layer and the insulating layer. The memory layer covers the multilayer stack structure and extends at least to the sidewalls of the trench. The channel layer covers the memory layer, wherein the channel layer includes an upper portion, a tandem portion, and a lower portion. The upper portion abuts the opening of the trench; the lower portion is located at the bottom of the trench; the tandem portion is located above the sidewall for connecting the upper portion and the lower portion, and has an ion doping concentration substantially smaller than the upper portion and the lower portion.

Description

立體記憶體元件及其製作方法 Stereo memory element and manufacturing method thereof

本揭露書是有關於一種非揮發性記憶體(non-volatile memory)元件及其製作方法。特別是有關於一種立體的(Three-Dimension,3D)非揮發性記憶體元件及其製作方法。 The present disclosure relates to a non-volatile memory element and a method of fabricating the same. In particular, there is a three-dimensional (3D) non-volatile memory element and a method of fabricating the same.

非揮發性記憶體(Non-Volatile Memory,NVM)元件,例如快閃記憶體,具有在移除電源時亦不丟失儲存於記憶單元中之資訊的特性。已廣泛運用於用於可擕式音樂播放器、移動電話、數位相機等的固態大容量存儲應用。三維非揮發性記憶體元件,例如垂直通道式(Vertical-Channel,VC)立體NAND快閃記憶體元件,具有許多層堆疊結構,可達到更高的儲存容量,更具有優異的電子特性,例如具有良好的資料保存可靠性和操作速度。 Non-Volatile Memory (NVM) components, such as flash memory, have the property of not losing information stored in the memory unit when the power is removed. It has been widely used in solid-state mass storage applications for portable music players, mobile phones, digital cameras, and the like. Three-dimensional non-volatile memory components, such as vertical-channel (VC) stereo NAND flash memory components, have many layer stack structures for higher storage capacity and superior electronic characteristics, such as Good data retention reliability and speed of operation.

典型的垂直通道式立體非揮發性記憶體元件包括複數個彼此平行之絕緣層和導電層交錯堆疊而成的多層堆疊結構(multi-layer stacks)。多層堆疊結構包括至少一條溝槽,將多層疊結構區分為複數個脊狀多層疊層(ridge-shaped stacks),使每一脊 狀多層疊層都具有複數條由圖案化導電層所形成的導電條帶。三維非揮發性記憶體元件還包括記憶層和通道層。其中,記憶層位於溝槽的側壁上;通道層則覆蓋脊狀多層疊層和記憶層上,而在每一個導電條帶與記憶層和通道層三者重疊的位置,定義出複數個記憶胞。垂直排列的記憶胞,藉由通道層垂直串接,而形成記憶胞串列,並透過位於多層疊結構的金屬接觸結構電性連接至對應的位元線。 A typical vertical channel type stereoscopic non-volatile memory element includes a plurality of multi-layer stacks in which an insulating layer and a conductive layer which are parallel to each other are alternately stacked. The multi-layer stack structure includes at least one trench, and the multi-layer structure is divided into a plurality of ridge-shaped stacks to make each ridge The multilayer laminate has a plurality of conductive strips formed from patterned conductive layers. The three-dimensional non-volatile memory component also includes a memory layer and a channel layer. Wherein, the memory layer is located on the sidewall of the trench; the channel layer covers the ridge multilayer stack and the memory layer, and a plurality of memory cells are defined at a position where each of the conductive strips overlaps the memory layer and the channel layer. . The vertically aligned memory cells are formed by vertically connecting the channel layers in series to form a memory cell string and electrically connected to the corresponding bit line through the metal contact structure located in the multi-layer structure.

然而,隨著多層疊結構中絕緣層和導電層數量的增加,記憶胞串列中的記憶胞數量亦隨之增加。不僅操作時經由位元線輸入記憶體串列的電流必須增大,且由於形成溝槽的蝕刻步驟不易控制,使得溝槽底部的尺寸縮小,連帶縮減位於溝槽底部的之通道層的寬度,導致元件通道和位元線的阻值居高不下,嚴重影響垂直通道式立體非揮發性記憶體元件元件的操作品質及可靠度。 However, as the number of insulating layers and conductive layers in the multilayer structure increases, the number of memory cells in the memory cell series also increases. Not only the current input to the memory string via the bit line must be increased during operation, but also the size of the bottom of the trench is reduced by the etching step of forming the trench, and the width of the channel layer at the bottom of the trench is reduced. The resistance of the component channel and the bit line is high, which seriously affects the operation quality and reliability of the vertical channel type stereoscopic non-volatile memory component.

因此,有需要提供一種更先進的立體記憶體元件及其製作方法,以改善習知技術所面臨的問題。 Therefore, there is a need to provide a more advanced three-dimensional memory component and a method of fabricating the same to improve the problems faced by conventional techniques.

根據本說明書的一實施例,提供一種立體記憶體元件,其包括基材、複數個導電層、複數個絕緣層、記憶層以及通道層。絕緣層和導電層交錯堆疊於基材上,形成一個多層堆疊結構(multi-layer stack),其中多層堆疊結構具有至少一條溝槽,穿 過這些導電層和絕緣層。記憶層覆蓋多層堆疊結構,並且至少延伸至溝槽的一個側壁上。通道層覆蓋於記憶層上,其中通道層包括上方部、串列部和下方部。上方部鄰接溝槽的開口;下方部鄰接溝槽底部;串列部位於溝槽的側壁之上,用以連接上方部和下方部,且具有實質小於上方部和下方部的離子摻雜濃度。 According to an embodiment of the present specification, a stereo memory device is provided that includes a substrate, a plurality of conductive layers, a plurality of insulating layers, a memory layer, and a channel layer. The insulating layer and the conductive layer are alternately stacked on the substrate to form a multi-layer stack, wherein the multilayer stack structure has at least one trench, which is worn These conductive layers and insulating layers pass through. The memory layer covers the multilayer stack structure and extends over at least one sidewall of the trench. The channel layer covers the memory layer, wherein the channel layer includes an upper portion, a tandem portion, and a lower portion. The upper portion abuts the opening of the trench; the lower portion abuts the bottom of the trench; the tandem portion is located above the sidewall of the trench for connecting the upper portion and the lower portion, and has an ion doping concentration substantially smaller than the upper portion and the lower portion.

根據本說明書的另一實施例,提供一種立體記憶體元件的製作方法,包括下述步驟:首先,於基材上提供一個多層堆疊結構,此多層堆疊結構包括交錯堆疊的複數個絕緣層和複數個導電層。接著圖案化多層堆疊結構,藉以於多層堆疊結構中形成至少一條溝槽,穿過這些導電層和絕緣層。形成一記憶層,覆蓋多層堆疊結構,並且至少延伸至溝槽的一個側壁上。後續,形成通道層覆蓋記憶層。在以介電材料填充溝槽之前,對通道層進行一個離子摻雜製程,將複數個離子摻質植入通道層,並將通道層至少區隔成一個上方部、一個串列部和一個下方部。其中,上方部鄰接溝槽的開口;下方部鄰接溝槽底部;串列部位於溝槽的側壁之上,用以連接上方部和下方部;且串列部具有實質小於上方部和下方部的離子摻雜濃度。 According to another embodiment of the present specification, a method of fabricating a stereo memory device is provided, comprising the steps of: firstly providing a multi-layer stack structure on a substrate, the multi-layer stack structure comprising a plurality of insulating layers and a plurality of staggered stacks Conductive layers. The multilayer stack structure is then patterned, whereby at least one trench is formed in the multilayer stack structure, passing through the conductive layer and the insulating layer. A memory layer is formed covering the multilayer stack structure and extending over at least one sidewall of the trench. Subsequently, a channel layer is formed to cover the memory layer. Before filling the trench with a dielectric material, an ion doping process is performed on the channel layer, a plurality of ion dopants are implanted into the channel layer, and the channel layer is at least divided into an upper portion, a tandem portion and a lower portion. unit. Wherein the upper portion abuts the opening of the trench; the lower portion abuts the bottom of the trench; the tandem portion is located above the sidewall of the trench for connecting the upper portion and the lower portion; and the tandem portion has substantially smaller portions than the upper portion and the lower portion Ion doping concentration.

根據上述實施例,本發明是在提供一種立體記憶體元件及其製作方法。此一立體記憶體元件的製作方法,係在基材上提供一個圖案化的多層堆疊結構,並在多層堆疊結構的至少一條溝槽側壁上依序形成記憶層和通道層。在尚未以介電材料填充溝槽之前,先對通道層進行一個離子摻雜製程,將複數個離子摻 質植入通道層,使通道層位於溝槽側壁上的第一串列部所具有的離子摻雜濃度,實質小於通道層鄰接於溝槽開口的上方部和位於溝槽底部之下方部的離子摻雜濃度。 According to the above embodiment, the present invention provides a three-dimensional memory element and a method of fabricating the same. The method of fabricating the three-dimensional memory element provides a patterned multilayer stack structure on a substrate, and sequentially forms a memory layer and a channel layer on at least one trench sidewall of the multilayer stack structure. Before the trench is filled with the dielectric material, an ion doping process is performed on the channel layer to mix the plurality of ions Implanting the channel layer such that the first string portion of the channel layer on the sidewall of the trench has an ion doping concentration substantially smaller than the channel layer adjacent to the upper portion of the trench opening and the lower portion of the trench bottom portion Doping concentration.

由於,摻雜製程可以使位於溝槽底部之通道層的上方部和下方部具有帶電的離子摻質,可以有效降低通道層的阻值,改善立體記憶體元件因為多層疊結構中絕緣層和導電層數量的增加,造成通道寬度局部緊縮,所引發的通道電阻急遽升高的問題。 Since the doping process can have charged ion dopants in the upper and lower portions of the channel layer at the bottom of the trench, the resistance of the channel layer can be effectively reduced, and the three-dimensional memory device can be improved because of the insulating layer and the conductive layer in the multilayer structure. The increase in the number of layers causes a partial contraction of the width of the channel, causing a problem that the channel resistance is rapidly increased.

100、200‧‧‧立體記憶體元件 100, 200‧‧‧ stereo memory components

101、201‧‧‧基材 101, 201‧‧‧ substrate

101a‧‧‧介電隔離層 101a‧‧‧Dielectric isolation layer

104、204‧‧‧溝槽 104, 204‧‧‧ trench

104a、204a‧‧‧溝槽側壁 104a, 204a‧‧‧ trench sidewall

104b、204b‧‧‧溝槽開口 104b, 204b‧‧‧ trench opening

104c、204c‧‧‧溝槽底部 104c, 204c‧‧‧ trench bottom

109、209‧‧‧通道層 109, 209‧‧‧ channel layer

109a、209a‧‧‧上方部 109a, 209a‧‧‧ upper part

109c、209c‧‧‧串列 109c, 209c‧‧‧ series

109b、209c‧‧‧下方部 109b, 209c‧‧‧ lower part

110‧‧‧多層堆疊結構 110‧‧‧Multilayer stacking structure

111-115‧‧‧導電層 111-115‧‧‧ Conductive layer

111a‧‧‧導電層的頂面 111a‧‧‧Top surface of the conductive layer

120‧‧‧保護層 120‧‧‧Protective layer

128、228‧‧‧介電層 128, 228‧‧‧ dielectric layer

129A-129E、229A-229F‧‧‧接觸插塞 129A-129E, 229A-229F‧‧‧ contact plug

109a1-109a5、209a1-209a6‧‧‧銲墊 109a1-109a5, 209a1-209a6‧‧‧ solder pads

110a、110b、110c、210a、210b、210c‧‧‧脊狀多層疊層 110a, 110b, 110c, 210a, 210b, 210c‧‧‧ ridge multilayer laminate

121-125‧‧‧絕緣層 121-125‧‧‧Insulation

130、230‧‧‧離子摻雜製程 130, 230‧‧‧ ion doping process

131、1231‧‧‧記憶胞 131, 1231‧‧‧ memory cells

132、133、232‧‧‧記憶胞串列 132, 133, 232‧‧‧ memory cell series

134、135、136、137、234、235‧‧‧電晶體 134, 135, 136, 137, 234, 235‧‧‧ transistors

201a‧‧‧多晶矽層 201a‧‧‧Polysilicon layer

106、206‧‧‧記憶層 106, 206‧‧‧ memory layer

219a、219b‧‧‧通道膜 219a, 219b‧‧‧ channel membrane

為了對本發明之上述實施例及其他目的、特徵和優點能更明顯易懂,特舉數個較佳實施例,並配合所附圖式,作詳細說明如下:第1A圖至第1F圖係根據本發明的一實施例所繪示之作立體記憶體元件的一系列製程結構剖面示意圖;以及第2A圖至第2G圖係根據本發明的另一實施例所繪示之作立體記憶體元件的一系列製程結構剖面示意圖。 The above-described embodiments and other objects, features and advantages of the present invention will become more apparent and understood. A cross-sectional view of a series of process structures for a three-dimensional memory device according to an embodiment of the present invention; and FIGS. 2A to 2G are diagrams of a three-dimensional memory device according to another embodiment of the present invention. A schematic diagram of a series of process structures.

本發明提供一種立體記憶體元件及其製作方法,可 改善立體記憶體元件因為多層疊結構中絕緣層和導電層數量的增加,造成通道寬度緊縮,所引發的通道電阻急遽升高的問題。為了對本發明之上述實施例及其他目的、特徵和優點能更明顯易懂,下文特舉數立體記憶體元件及其製作方法作為較佳實施例,並配合所附圖式作詳細說明。 The invention provides a stereo memory component and a manufacturing method thereof, which can Improvement of the three-dimensional memory element due to an increase in the number of insulating layers and conductive layers in the multi-layered structure causes the channel width to be tightened, and the resulting channel resistance is rapidly increased. The above-described embodiments and other objects, features and advantages of the present invention will become more apparent and understood.

但必須注意的是,這些特定的實施案例與方法,並非用以限定本發明。本發明仍可採用其他特徵、元件、方法及參數來加以實施。較佳實施例的提出,僅係用以例示本發明的技術特徵,並非用以限定本發明的申請專利範圍。該技術領域中具有通常知識者,將可根據以下說明書的描述,在不脫離本發明的精神範圍內,作均等的修飾與變化。在不同實施例與圖式之中,相同的元件,將以相同的元件符號加以表示。 However, it must be noted that these specific embodiments and methods are not intended to limit the invention. The invention may be practiced with other features, elements, methods and parameters. The preferred embodiments are merely illustrative of the technical features of the present invention and are not intended to limit the scope of the invention. Equivalent modifications and variations will be made without departing from the spirit and scope of the invention. In the different embodiments and the drawings, the same elements will be denoted by the same reference numerals.

請參照第1A圖至第1F圖,第1A圖至第1F圖係根據本發明的一實施例所繪示之作立體記憶體元件100的一系列製程結構剖面示意圖。製作立體記憶體元件100的方法,包括下述步驟:首先提供一個基材101,並在基材101上形成多層堆疊結構110(如第1A圖所繪示)。在本發明的一些實施例中,基材101可以包括一個介電隔離層101a,多層堆疊結構110形成於介電隔離層101a上,並且與介電隔離層101a接觸。 Please refer to FIG. 1A to FIG. 1F. FIG. 1A to FIG. 1F are schematic cross-sectional views showing a series of process structures of the three-dimensional memory device 100 according to an embodiment of the invention. The method of fabricating the stereoscopic memory element 100 includes the steps of first providing a substrate 101 and forming a multilayer stack structure 110 on the substrate 101 (as depicted in FIG. 1A). In some embodiments of the present invention, the substrate 101 may include a dielectric isolation layer 101a formed on the dielectric isolation layer 101a and in contact with the dielectric isolation layer 101a.

多層堆疊結構110包括複數個導電層111-115以及複數個絕緣層121-125。其中,絕緣層121-125與導電層111-115係沿著第1A圖所繪示的Z軸方向,在基材101上彼此交錯堆疊, 並且相互平行。在本實施例之中,導電層111位於多層堆疊結構110的最底層,而絕緣層125位於多層堆疊結構110的頂層。 The multilayer stack structure 110 includes a plurality of conductive layers 111-115 and a plurality of insulating layers 121-125. The insulating layers 121-125 and the conductive layers 111-115 are staggered on the substrate 101 along the Z-axis direction depicted in FIG. 1A. And parallel to each other. In the present embodiment, the conductive layer 111 is located at the bottommost layer of the multilayer stack structure 110, and the insulating layer 125 is located at the top layer of the multilayer stack structure 110.

導電層111-115可以由金屬,例如金、銅、鋁,合金材料、金屬氧化物或其他合適的金屬材料所構成。此外,導電層111-115也可以由無摻雜的多晶或單晶半導體材料,例如多晶或單晶矽/鍺所構成。亦或由摻雜的半導體材質,例如摻雜磷(phosphorus,P)或砷(arsenic,As)的n型多晶矽,或摻雜硼(boron,B)的p型多晶矽,所構成。在本實施例中,導電層111-115係由無摻雜的多晶矽所構成。絕緣層121-125可以由介電材料,例如矽氧化物(oxide)、矽氮化物(nitride)、矽氮氧化物(oxynitride)、矽酸鹽(silicate)或其他材料,所構成。 The conductive layers 111-115 may be composed of a metal such as gold, copper, aluminum, an alloy material, a metal oxide or other suitable metal material. Furthermore, the conductive layers 111-115 may also be composed of an undoped polycrystalline or single crystal semiconductor material, such as polycrystalline or single crystal germanium/iridium. Alternatively, it may be composed of a doped semiconductor material such as an n-type polycrystalline germanium doped with phosphorus (Porus) or arsenic (As) or a p-type polycrystalline germanium doped with boron (boron, B). In the present embodiment, the conductive layers 111-115 are composed of undoped polysilicon. The insulating layers 121-125 may be composed of a dielectric material such as an oxide, a nitride, an oxynitride, a silicate or the like.

在本發明的一些實施例中,導電層111-115和絕緣層121-125可藉由,例如低壓化學氣相沉積(Low Pressure Chemical Vapor Deposition,LPCVD)製程,製作而成。絕緣層121-125的厚度可以實質介於30埃(angstrom,Å)到800埃之間。位於最底層的導電層111和最上層的導電層115具有比其他導電層112-114還厚的厚度。導電層112-114的厚度可以實質介於30埃到800埃之間。導電層111和115的厚度可以實質介於50埃到3000埃之間。但在其他實施例中,絕緣層和導電層的厚度並不以此為限。 In some embodiments of the present invention, the conductive layers 111-115 and the insulating layers 121-125 may be fabricated by, for example, a Low Pressure Chemical Vapor Deposition (LPCVD) process. The thickness of the insulating layers 121-125 may be substantially between 30 angstroms (Åstroms) and 800 angstroms. The conductive layer 111 at the bottommost layer and the conductive layer 115 at the uppermost layer have a thickness thicker than the other conductive layers 112-114. The thickness of the conductive layers 112-114 may be substantially between 30 angstroms and 800 angstroms. The thickness of the conductive layers 111 and 115 may be substantially between 50 angstroms and 3000 angstroms. However, in other embodiments, the thickness of the insulating layer and the conductive layer are not limited thereto.

接著,對多層堆疊結構110進行圖案化製程103以形成複數個脊狀多層疊層110a、110b和110c(如第1B圖所繪示)。 在本發明的一些實施例中,多層堆疊結構110的圖案化製程103,包括在多層堆疊結構110上形成硬罩幕層102,並圖案化硬罩幕層102。再以圖案化硬罩幕層102為蝕刻罩幕,藉由非等向蝕刻製程(anisotropic etching process),例如反應離子蝕刻(Reactive Ion Etching,RIE)製程,來移除一部份的多層堆疊結構110,藉以在多層堆疊結構110之中形成沿著Z軸方向延伸的溝槽104,將多層堆疊結構110分割成複數個沿著Y軸(垂直X軸)方向延伸的脊狀多層疊層,例如脊狀多層疊層110a、110b和110c,並將基材101中的一部分介電隔離層101a經由溝槽104曝露於外。其中,硬罩幕層102可以是一種形成於多層堆疊結構110的最頂層絕緣層125上的氮化矽層。 Next, the multi-layer stack structure 110 is patterned to form a plurality of ridge-like multilayer stacks 110a, 110b, and 110c (as shown in FIG. 1B). In some embodiments of the invention, the patterning process 103 of the multilayer stack structure 110 includes forming a hard mask layer 102 on the multilayer stack structure 110 and patterning the hard mask layer 102. Then, the patterned hard mask layer 102 is used as an etching mask, and a part of the multilayer stack structure is removed by an anisotropic etching process, such as a reactive ion etching (RIE) process. 110, by forming a trench 104 extending along the Z-axis direction among the multilayer stacked structures 110, dividing the multilayer stacked structure 110 into a plurality of ridge-shaped multilayer stacks extending along the Y-axis (vertical X-axis) direction, for example The ridge multilayer laminates 110a, 110b, and 110c expose a portion of the dielectric isolation layer 101a in the substrate 101 to the outside via the trenches 104. The hard mask layer 102 may be a tantalum nitride layer formed on the topmost insulating layer 125 of the multilayer stack structure 110.

然後,在多層堆疊結構110上形成記憶層106,使其覆蓋於脊狀多層疊層110a、110b和110c頂部並延伸進入溝槽104的底部104c(即被溝槽104暴露於外的一部分介電隔離層101a)和溝槽側壁104a上。再於脊狀多層疊層110a、110b和110c上進行共形沉積(conformal deposition),以形成通道層109,覆蓋於記憶層106上(如第1C圖所繪示)。 A memory layer 106 is then formed over the multilayer stack structure 110 to cover the top of the ridge multilayer stacks 110a, 110b, and 110c and extend into the bottom portion 104c of the trench 104 (i.e., a portion of the dielectric exposed by the trenches 104) The isolation layer 101a) and the trench sidewalls 104a. Conformal deposition is then performed on the ridge multilayer laminates 110a, 110b, and 110c to form a channel layer 109 overlying the memory layer 106 (as depicted in FIG. 1C).

在本發明的一些實施例中,記憶層106至少包含氧化矽(silicon oxide)層、氮化矽(silicon nitride)層和氧化矽層的複合層(即,ONO結構)。但記憶層106的結構並不以此為限。在本說明書的另一些實施例中,記憶層106的複合層還可以選自於由一矽氧化物-氮化矽-矽氧化物-氮化矽-矽氧化物 (oxide-nitride-oxide-nitride-oxide,ONONO)結構、一矽-矽氧化物-氮化矽-矽氧化物-矽(silicon-oxide-nitride-oxide-silicon,SONOS)結構、一能隙工程矽-矽氧化物-氮化矽-矽氧化物-矽(bandgap engineered silicon-oxide-nitride-oxide-silicon,BE-SONOS)結構、一氮化鉭-氧化鋁-氮化矽-矽氧化物-矽(tantalum nitride,aluminum oxide,silicon nitride,silicon oxide,silicon,TANOS)結構以及一金屬高介電係數能隙工程矽-矽氧化物-氮化矽-矽氧化物-矽(metal-high-k bandgap-engineered silicon-oxide-nitride-oxide-silicon,MA BE-SONOS)結構所組成之一族群。在本實施例中,記憶層106可以是藉由低壓化學氣相沉積製程所製作而成的ONO複合層,且厚度實質介於60埃至600埃之間。 In some embodiments of the invention, the memory layer 106 comprises at least a composite layer of a silicon oxide layer, a silicon nitride layer, and a hafnium oxide layer (ie, an ONO structure). However, the structure of the memory layer 106 is not limited thereto. In still other embodiments of the present specification, the composite layer of the memory layer 106 may also be selected from the group consisting of a tantalum oxide-cerium nitride-cerium oxide-cerium nitride-cerium oxide. (oxide-nitride-oxide-nitride-oxide, ONONO) structure, silicon-oxide-nitride-oxide-silicon (SONOS) structure, energy gap engineering Band-gap engineered silicon-oxide-nitride-oxide-silicon (BE-SONOS) structure, niobium nitride-alumina-tantalum nitride-rhenium oxide- Tantalum nitride (aluminum oxide, silicon nitride, silicon oxide, silicon, TANOS) structure and a metal high dielectric constant energy gap engineering 矽-矽 oxide-tantalum nitride-矽 oxide-矽 (metal-high-k Bandgap-engineered silicon-oxide-nitride-oxide-silicon, MA BE-SONOS) is a group of structures. In this embodiment, the memory layer 106 may be an ONO composite layer fabricated by a low pressure chemical vapor deposition process, and has a thickness substantially between 60 angstroms and 600 angstroms.

構成通道層109的材質可以包括半導體材質,例如摻雜有磷或砷的n型多晶矽(或n型磊晶單晶矽)、摻雜有硼的p型多晶矽(或p型磊晶單晶矽)、無摻雜的多晶矽、金屬矽化物(silicides),例如矽化鈦(TiSi)、矽化鈷(CoSi)或矽鍺(SiGe)、氧化物半導體(oxide semiconductors),例如氧化銦鋅(InZnO)或氧化銦鎵鋅(InGaZnO)或兩種或多種上述材質之組合物。在本實施例中,構成通道層109為無摻雜的多晶矽層,且其厚度實質介於30埃至500埃之間。 The material constituting the channel layer 109 may include a semiconductor material such as an n-type polycrystalline germanium doped with phosphorus or arsenic (or an n-type epitaxial single crystal germanium), and a p-type polycrystalline germanium doped with boron (or a p-type epitaxial single crystal germanium). , undoped polysilicon, metal silicides such as titanium telluride (TiSi), cobalt (CoSi) or germanium (SiGe), oxide semiconductors, such as indium zinc oxide (InZnO) or Indium gallium zinc oxide (InGaZnO) or a combination of two or more of the above materials. In the present embodiment, the channel layer 109 is formed as an undoped polysilicon layer, and its thickness is substantially between 30 angstroms and 500 angstroms.

之後,對通道層109進行一個離子摻雜製程130,將複數個離子摻質植入通道層109中,並將通道層至少區隔成一 個上方部109a、一個串列部109c和一個下方部109b(如第1D圖所繪示)。由於蝕刻製程的特性,使的所形成的溝槽104具有一個上寬下窄的外觀輪廓,因此離子摻雜製程130中大部分的摻雜離子,較有機會被植入通道層109鄰接於溝槽104開口104b的上方部109a以及位於溝槽104底部104c的下方部109b;而較無法摻雜位於溝槽104側壁104a上,用來連接上方部109a和下方部109b的串列部109c。因此,通道層109之串列部109c中的離子摻雜濃度,具有實質小於上方部109a和下方部109b的離子摻雜濃度。在本說明書的一些實施例中,下方部109b可以由溝槽底部104c向上延伸,但不會實質超過多層堆疊結構110的最底層之導電層111的頂面111a。 Thereafter, the channel layer 109 is subjected to an ion doping process 130, a plurality of ion dopants are implanted into the channel layer 109, and the channel layer is at least separated into one. An upper portion 109a, a tandem portion 109c and a lower portion 109b (as shown in FIG. 1D). Due to the characteristics of the etching process, the formed trenches 104 have an upper and lower narrow outline, so that most of the doping ions in the ion doping process 130 have a chance to be implanted into the channel layer 109 adjacent to the trench. The upper portion 109a of the opening 104b of the groove 104 and the lower portion 109b of the bottom portion 104c of the groove 104 are less capable of being doped with the tandem portion 109c for connecting the upper portion 109a and the lower portion 109b on the side wall 104a of the groove 104. Therefore, the ion doping concentration in the tandem portion 109c of the channel layer 109 has substantially smaller ion doping concentration than the upper portion 109a and the lower portion 109b. In some embodiments of the present specification, the lower portion 109b may extend upward from the trench bottom portion 104c, but does not substantially exceed the top surface 111a of the bottommost conductive layer 111 of the multilayer stack structure 110.

在本說明書的一些實施例中,在進行離子摻雜製程130之前,可選擇性地(optionally)於溝槽104的側壁104a和底部104c上形成一個保護層120(如第1D圖所繪示)。在本實施例中,保護層120,可以是藉由熱氧化製程或沉積製程所製作而成的二氧化矽層。其中,保護層120覆蓋於通道層109的上方部109a、下方部109b和串列部109c,用以調控,離子摻雜製程130摻雜離子的摻雜深度,並保護通道層109不會因離子轟擊受到損傷。 In some embodiments of the present specification, a protective layer 120 may be selectively formed on the sidewalls 104a and the bottom portion 104c of the trench 104 prior to performing the ion doping process 130 (as shown in FIG. 1D). . In this embodiment, the protective layer 120 may be a germanium dioxide layer formed by a thermal oxidation process or a deposition process. The protective layer 120 covers the upper portion 109a, the lower portion 109b and the tandem portion 109c of the channel layer 109 for regulating the doping depth of the doping ions of the ion doping process 130, and protecting the channel layer 109 from ions. The bombardment was damaged.

接著,形成介電層128填滿溝槽104並且覆蓋通道層109(如第1E圖所繪示)。在本說明書的一些實施例中,介電層128的形成,可以包括下述步驟:首先,以絕緣材料,例如矽氧化物,填滿溝槽104並覆蓋多層堆疊結構110。之後,再進行平 坦化步驟,例如化學機械研磨,移除位於多層堆疊結構110上方的一部分絕緣材料。 Next, a dielectric layer 128 is formed to fill the trenches 104 and cover the channel layer 109 (as depicted in FIG. 1E). In some embodiments of the present specification, the formation of the dielectric layer 128 may include the steps of first filling the trench 104 with an insulating material, such as tantalum oxide, and overlying the multilayer stack structure 110. After that, then flatten A canonization step, such as chemical mechanical polishing, removes a portion of the insulating material over the multilayer stack structure 110.

之後,再於每一個脊狀多層疊層110a、110b和110c上形成至少一個接觸插塞,分別穿過介電層128和保護層120,並與位於脊狀多層疊層110a、110b和110c上方的通道層109上方部109a接觸。例如,在本實施例中,接觸插塞129A和129B形成於脊狀多層疊層110a上;接觸插塞129C形成於脊狀多層疊層110b上;接觸插塞129D和129E形成於脊狀多層疊層110c上。 Thereafter, at least one contact plug is formed over each of the ridge multilayer laminates 110a, 110b, and 110c, respectively, through the dielectric layer 128 and the protective layer 120, and over the ridge multilayer laminates 110a, 110b, and 110c. The upper portion 109a of the channel layer 109 is in contact. For example, in the present embodiment, contact plugs 129A and 129B are formed on the ridge multilayer laminate 110a; contact plugs 129C are formed on the ridge multilayer laminate 110b; contact plugs 129D and 129E are formed in the ridge multilayer laminate On layer 110c.

接著,再進行一次蝕刻製程,移除位於脊狀多層疊層110a和110c頂部的一部分介電層128和一部分通道層109上方部109a,將位於脊狀多層疊層110a的通道層109上方部109a分別切割成彼此分離的第一銲墊109a1和第二銲墊109a2,進而將接觸插塞129A和129B電性隔離;以及將位於脊狀多層疊層110c的通道層109上方部109a分別切割成彼此分離的第四銲墊109a4和第五銲墊109a5,進而將接觸插塞129D和129E電性隔離。 Next, an etching process is performed to remove a portion of the dielectric layer 128 on the top of the ridge multilayer laminates 110a and 110c and a portion 109a above the channel layer 109, which will be located above the channel layer 109 of the ridge multilayer laminate 110a. The first pads 109a1 and the second pads 109a2 separated from each other are respectively cut, thereby electrically isolating the contact plugs 129A and 129B; and the upper portions 109a of the channel layer 109 located in the ridge multilayer laminate 110c are respectively cut into each other. The separated fourth pads 109a4 and fifth pads 109a5 further electrically isolate the contact plugs 129D and 129E.

在本實施例中,位於脊狀多層疊層110a頂部的接觸插塞129A和129B分別與第一銲墊109a1和第二銲墊109a2電性接觸;位於脊狀多層疊層110b頂部的接觸插塞129C與位於脊狀多層疊層110b頂部的通道層109上方部109a(以下稱為第三銲墊109a3)電性接觸;以及位於脊狀多層疊層110c頂部的接觸插塞129D和129E分別與第四銲墊109a4電和第五銲墊109a5性接 觸。 In the present embodiment, the contact plugs 129A and 129B on the top of the ridge multilayer laminate 110a are in electrical contact with the first pad 109a1 and the second pad 109a2, respectively; the contact plug on the top of the ridge multilayer laminate 110b. 129C is in electrical contact with the upper portion 109a (hereinafter referred to as the third pad 109a3) of the channel layer 109 at the top of the ridge multilayer laminate 110b; and the contact plugs 129D and 129E at the top of the ridge multilayer laminate 110c, respectively The four pads 109a4 are electrically connected to the fifth pad 109a5 touch.

第二銲墊109a2通過位於脊狀多層疊層110a和110b之間的一部分通道層109(包含下方部109b和串列部109c)與第三銲墊109a3導通,藉以構成一個U形通道,將形成在U形通道層109、記憶層106和導電層112-114交叉點上的複數個記憶胞131串接起來,在脊狀多層疊層110a和110b之間形成一個U形記憶胞串列132。同理,第四銲墊109a4通過位於脊狀多層疊層110b和110c之間的一部分通道層109(包含下方部109b和串列部109c)與位於脊狀多層疊層110b頂部的第三銲墊109a3導通,藉以在脊狀多層疊層110b和110c之間形成另一條U型記憶胞串列133。 The second pad 109a2 is electrically connected to the third pad 109a3 through a portion of the channel layer 109 (including the lower portion 109b and the tandem portion 109c) between the ridge multilayer laminates 110a and 110b, thereby forming a U-shaped channel, which will be formed. A plurality of memory cells 131 at the intersection of the U-shaped channel layer 109, the memory layer 106 and the conductive layers 112-114 are connected in series to form a U-shaped memory cell string 132 between the ridge multilayer laminates 110a and 110b. Similarly, the fourth pad 109a4 passes through a portion of the channel layer 109 (including the lower portion 109b and the tandem portion 109c) between the ridge multilayer laminates 110b and 110c and the third pad on the top of the ridge multilayer laminate 110b. 109a3 is turned on to form another U-shaped memory cell string 133 between the ridge-like multilayer stacks 110b and 110c.

在本實施例中,形成在脊狀多層疊層110a的通道層109、記憶層106和導電層115交叉點上的電晶體134,與複數個記憶胞131串接,可以作為U型記憶胞串列132的串列選擇線(String Select Line,SSL)開關。形成在脊狀多層疊層110b的通道層109、記憶層106和導電層115交叉點上的電晶體135,與複數個記憶胞131串接,可以作為U型記憶胞串列132的接地選擇線(Ground Select Line,GSL)開關。分別形成在脊狀多層疊層110a和110b的通道層109、記憶層106和導電層111交叉點上的電晶體136和137,與複數個記憶胞131串接,可以作為U型記憶胞串列132的反轉輔助閘極(Inversion Assist Gate,IG)開關。 In the present embodiment, the transistor 134 formed at the intersection of the channel layer 109 of the ridge multilayer laminate 110a, the memory layer 106 and the conductive layer 115 is connected in series with a plurality of memory cells 131, and can be used as a U-shaped memory cell string. Column 132's String Select Line (SSL) switch. The transistor 135 formed at the intersection of the channel layer 109 of the ridge multilayer laminate 110b, the memory layer 106 and the conductive layer 115 is connected in series with a plurality of memory cells 131 and can serve as a ground selection line for the U-shaped memory cell string 132. (Ground Select Line, GSL) switch. The transistors 136 and 137 formed at the intersections of the channel layer 109 of the ridge multilayer laminates 110a and 110b, the memory layer 106 and the conductive layer 111, respectively, are connected in series with a plurality of memory cells 131, and can be used as U-shaped memory cells. 132 Inversion Assist Gate (IG) switch.

後續,再經由一連串後段製程,將接觸插塞129B和129D分別連接至對應的位元線(未繪示),並將接觸插塞129C 連接至共同源極線(未繪示)完成立體記憶體元件100的製備(如第1F圖所繪示)。 Subsequently, through a series of back-end processes, the contact plugs 129B and 129D are respectively connected to corresponding bit lines (not shown), and the contact plugs 129C are connected. The connection to the common source line (not shown) completes the preparation of the stereo memory element 100 (as shown in FIG. 1F).

由於,如前所述,溝槽104具有上寬下窄的外觀輪廓,會緊縮位於U型記憶胞串列132和133位於溝槽底部104c的通道寬度,引發通道電阻急遽升高。藉由離子摻雜製程130,將具有帶電的離子摻質植入位於溝槽底部104c之通道層109的下方部109b,可以有效降低U型記憶胞串列132和133的通道電阻值。同樣的,被離子摻雜製程130植入帶電離子摻質的上方部109a,也可以進一步降低U型記憶胞串列132和133的整體通道阻值,具有改善立體記憶體元件100的操作品質和減少電力耗損的技術優勢。 Since, as previously mentioned, the trench 104 has an upper and lower narrow outline, it will tighten the channel width of the U-shaped memory cell strings 132 and 133 at the trench bottom 104c, causing the channel resistance to rise sharply. By implanting the charged ion dopant into the lower portion 109b of the channel layer 109 at the bottom 104b of the trench by the ion doping process 130, the channel resistance values of the U-type memory cell strings 132 and 133 can be effectively reduced. Similarly, the implantation of the ion doping process 130 into the upper portion 109a of the charged ion dopant can further reduce the overall channel resistance of the U-shaped memory cell strings 132 and 133, and improve the operational quality of the stereo memory device 100. The technical advantage of reducing power consumption.

但值得注意的是,雖然第1F圖所繪示的立體記憶體元件100是具有U型記憶胞串列結構的立體記憶體元件,但藉由前述實施例所述之離子摻雜製程130來降低立體記憶體元件100之記憶胞串列通道阻值的方法,並未限制僅適用於具有U型記憶胞串列結構的立體記憶體元件。例如,在本說明書的其他實施例中,此一方法也適合具有底部源極(bottom source)結構的立體記憶體元件中。 However, it should be noted that although the three-dimensional memory element 100 illustrated in FIG. 1F is a three-dimensional memory element having a U-shaped memory cell serial structure, it is reduced by the ion doping process 130 described in the foregoing embodiment. The method of the memory cell serial channel resistance of the stereo memory device 100 is not limited to the stereo memory element having the U-shaped memory cell string structure. For example, in other embodiments of the present specification, this method is also suitable for use in a stereo memory element having a bottom source structure.

請參照第2A圖至第2G圖,第2A圖至第2G圖係根據本發明的另一實施例所繪示之立體記憶體元件200的一系列製程結構剖面示意圖。製作立體記憶體元件200的方法,包括下述步驟:首先提供一個基材201並在基材201上形成多層堆疊結 構110(如第2A圖所繪示)。在本發明的一些實施例中,基材201可以包括是一種多晶矽層201a,多層堆疊結構110形成於多晶矽層201a上,並且於多晶矽層201a接觸。由於多層堆疊結構110的材質與製作程序以詳述如上,不在此贅述。 Please refer to FIG. 2A to FIG. 2G. FIG. 2A to FIG. 2G are schematic cross-sectional views showing a series of process structures of the three-dimensional memory device 200 according to another embodiment of the present invention. A method of fabricating a stereo memory device 200 includes the steps of first providing a substrate 201 and forming a multilayer stack on the substrate 201. Structure 110 (as shown in Figure 2A). In some embodiments of the present invention, the substrate 201 may include a polysilicon layer 201a formed on the polysilicon layer 201a and in contact with the polysilicon layer 201a. Since the materials and manufacturing procedures of the multilayer stack structure 110 are detailed as above, they are not described herein.

接著,對多層堆疊結構110進行圖案化製程203以形成複數個脊狀多層疊層210a、210b和210c(如第2B圖所繪示)。在本發明的一些實施例中,多層堆疊結構210的圖案化製程203,包括在多層堆疊結構110上形成硬罩幕層202,並圖案化硬罩幕層(未繪示)。再以圖案化硬罩幕層202為蝕刻罩幕,藉由非等向蝕刻製程,例如反應離子蝕刻製程,對多層堆疊結構110進行蝕刻,藉以在多層堆疊結構110之中形成沿著Z軸方向延伸的溝槽204,將多層堆疊結構110分割成複數個沿著Y軸方向延伸的脊狀多層疊層,例如脊狀多層疊層210a、210b和210c,並將基材201中的一部分多晶矽層201a經由溝槽204曝露於外。 Next, the multi-layer stack structure 110 is patterned to form a plurality of ridge-like multilayer stacks 210a, 210b, and 210c (as shown in FIG. 2B). In some embodiments of the invention, the patterning process 203 of the multilayer stack structure 210 includes forming a hard mask layer 202 on the multilayer stack structure 110 and patterning a hard mask layer (not shown). Then, the patterned hard mask layer 202 is used as an etching mask, and the multilayer stacked structure 110 is etched by an anisotropic etching process, such as a reactive ion etching process, thereby forming a Z-axis direction among the multilayer stacked structures 110. The extended trench 204 divides the multilayer stack structure 110 into a plurality of ridge multilayer stacks extending along the Y-axis direction, such as ridge-like multilayer stacks 210a, 210b, and 210c, and a portion of the polycrystalline germanium layer in the substrate 201. 201a is exposed outside via trench 204.

然後,於脊狀多層疊層210a、210b和210c上形成記憶層206,使其覆蓋於脊狀多層疊層210a、210b和210c頂部並延伸進入溝槽204的底部204c(即被溝槽204暴露於外的一部分多晶矽層201a)和溝槽側壁204a上。再於脊狀多層疊層210a、210b和210c上進行共形沉積,以形成第一通道膜219a,覆蓋於記憶層206上(如第2C圖所繪示)。 A memory layer 206 is then formed over the ridge multilayer stacks 210a, 210b, and 210c overlying the top of the ridge multilayer stacks 210a, 210b, and 210c and extending into the bottom 204c of the trench 204 (ie, exposed by the trench 204) A portion of the outer polysilicon layer 201a) and the trench sidewall 204a. Conformal deposition is then performed on the ridge multilayer stacks 210a, 210b, and 210c to form a first channel film 219a overlying the memory layer 206 (as depicted in Figure 2C).

接著,以蝕刻製程移除位於溝槽204底部的一部分第一通道膜219a和記憶層206將位於溝槽204底部的一部份多晶 矽層201a暴露於外。之後,再進行一次共形沉積,藉以在第一通道膜219a以及溝槽204的底部204c上形成第二通道膜219b,與第一通道膜219a整合成通道層209,並與位於溝槽204底部204c暴露的一部份多晶矽層201a導通(如第2D圖所繪示)。 Next, a portion of the first channel film 219a and the memory layer 206 located at the bottom of the trench 204 are removed by an etching process to be partially polycrystalline at the bottom of the trench 204. The ruthenium layer 201a is exposed to the outside. Thereafter, a conformal deposition is performed again to form a second channel film 219b on the first channel film 219a and the bottom 204c of the trench 204, integrated with the first channel film 219a into the channel layer 209, and at the bottom of the trench 204. A portion of the polysilicon layer 201a exposed by 204c is turned on (as shown in FIG. 2D).

進行一個離子摻雜製程230,將複數個離子摻質植入通道層209中(如第2E圖所繪示)。由於通道層209覆蓋於脊狀多層疊層210a、210b和210c頂部並延伸進入溝槽204的溝槽側壁204a和底部204c上,離子摻雜製程230中大部分的摻雜離子較有機會被植入通道層209鄰接於溝槽204開口204b的上方部209a以及鄰接於溝槽204底部204c的下方部209b;而較無法摻雜位於溝槽204側壁204a上,用來連接上方部209a和下方部209b的串列部209c。因此,通道層209之串列部209c中的離子摻雜濃度,具有實質小於上方部209a和下方部209b的離子摻雜濃度。在本說明書的一些實施例中,下方部209b可以由溝槽底部204c向上延伸,但不會實質超過多層堆疊結構110的最底層之導電層111的頂面111a。 An ion doping process 230 is performed to implant a plurality of ion dopants into the channel layer 209 (as depicted in FIG. 2E). Since the channel layer 209 covers the top of the ridge multilayer stacks 210a, 210b, and 210c and extends into the trench sidewalls 204a and 204c of the trenches 204, most of the dopant ions in the ion doping process 230 have a chance to be implanted. The inlet channel layer 209 is adjacent to the upper portion 209a of the opening 204b of the trench 204 and the lower portion 209b adjacent to the bottom 204c of the trench 204; and is less capable of being doped on the sidewall 204a of the trench 204 for connecting the upper portion 209a and the lower portion The string portion 209c of 209b. Therefore, the ion doping concentration in the tandem portion 209c of the channel layer 209 has substantially smaller ion doping concentration than the upper portion 209a and the lower portion 209b. In some embodiments of the present specification, the lower portion 209b may extend upward from the trench bottom 204c, but does not substantially exceed the top surface 111a of the bottommost conductive layer 111 of the multilayer stack structure 110.

之後,形成介電層228填滿溝槽204並且覆蓋通道層209(如第2F圖所繪示)。 Thereafter, a dielectric layer 228 is formed to fill the trench 204 and cover the channel layer 209 (as depicted in FIG. 2F).

接著,於每一個脊狀多層疊層210a、210b和210c上形成複數個接觸插塞229A-229F,分別穿過介電層228,並與位於脊狀多層疊層210a、210b和210c上方的通道層209上方部209a接觸。例如,在本實施例中,接觸插塞229A和229B形成 於脊狀多層疊層210a上;接觸插塞229C和229D形成於脊狀多層疊層210b上;接觸插塞229E和229F形成於脊狀多層疊層210c上。 Next, a plurality of contact plugs 229A-229F are formed on each of the ridge multilayer stacks 210a, 210b, and 210c, respectively, through the dielectric layer 228, and with channels above the ridge multilayer stacks 210a, 210b, and 210c. The upper portion 209a of the layer 209 is in contact. For example, in the present embodiment, the contact plugs 229A and 229B are formed. On the ridge multilayer laminate 210a; contact plugs 229C and 229D are formed on the ridge multilayer laminate 210b; contact plugs 229E and 229F are formed on the ridge multilayer laminate 210c.

然後,再進行一次蝕刻製程,移除位於同一個脊狀多層疊層頂部的一部分介電層228和一部分通道層209上方部209a,將位於同一個脊狀多層疊層的通道層209上方部209a分別切割成彼此分離的多個銲墊。進而將位於同一個脊狀多層疊層上方的多個接觸插塞電性隔離。例如,在本實施例中,上述蝕刻製程可以將位於脊狀多層疊層210a上的通道層209上方部209a分隔成第一銲墊209a1和第二銲墊209a2,藉以將接觸插塞229A和229B電性隔離。上述蝕刻製程可以將位於脊狀多層疊層210b上的通道層209上方部209a分隔成第三銲墊209a3和第四銲墊209a4,藉以將接觸插塞229C和229D電性隔離。上述蝕刻製程可以將位於脊狀多層疊層210c上的通道層209上方部209a分隔成第五銲墊209a5和第六銲墊209a6,藉以將接觸插塞229E和229F電性隔離。 Then, an etching process is performed to remove a portion of the dielectric layer 228 and a portion of the upper portion 209a of the channel layer 209 at the top of the same ridge multilayer stack, which will be located above the channel layer 209 of the same ridge multilayer stack. Cut into a plurality of pads separated from each other. Further, a plurality of contact plugs located above the same ridge multilayer stack are electrically isolated. For example, in the present embodiment, the etching process may divide the upper portion 209a of the channel layer 209 on the ridge multilayer laminate 210a into the first pad 209a1 and the second pad 209a2, thereby contacting the contacts 229A and 229B. Electrically isolated. The above etching process can divide the upper portion 209a of the channel layer 209 on the ridge multilayer laminate 210b into the third pad 209a3 and the fourth pad 209a4, thereby electrically isolating the contact plugs 229C and 229D. The etching process may divide the upper portion 209a of the channel layer 209 on the ridge multilayer laminate 210c into the fifth pad 209a5 and the sixth pad 209a6, thereby electrically isolating the contact plugs 229E and 229F.

位於脊狀多層疊層210a頂部的二個接觸插塞229A和229B,分別與第一銲墊209a1和第二銲墊209a2電性接觸。位於脊狀多層疊層210b頂部的二個接觸插塞229C和229D,分別與第三銲墊209a3和第四銲墊209a4電性接觸。位於脊狀多層疊層210c頂部的二個接觸插塞229E和229F,分別與第五銲墊209a5和第六銲墊209a6性接觸。第一銲墊209a1至第六銲墊209a6的 每一者,分別通過位於溝槽204側壁上的一部分通道層209(包含下方部209b和串列部209c),將形成在通道層209、記憶層206和導電層112-114交叉點上的複數個記憶胞231串接起來,形成一條平行Z軸的記憶胞串列232。其中,形成在脊狀多層疊層210a、210b和210c的通道層209、記憶層206和導電層115交叉點上的複數個電晶體234,分別與對應記憶胞串列232的複數個記憶胞231串接,可以分別作為對應記憶胞串列232的串列選擇線(SSL)開關。形成在脊狀多層疊層210a、210b和210c的通道層209、記憶層206和導電層111交叉點上的複數個電晶體235,分別與對應記憶胞串列232的複數個記憶胞231串接,可以分別作為對應記憶胞串列232的接地選擇線(GSL)開關。多晶矽層201a可以做為這些記憶胞串列232的底部共同源極線。 Two contact plugs 229A and 229B on the top of the ridge multilayer laminate 210a are in electrical contact with the first pad 209a1 and the second pad 209a2, respectively. Two contact plugs 229C and 229D on the top of the ridge multilayer laminate 210b are in electrical contact with the third pad 209a3 and the fourth pad 209a4, respectively. Two contact plugs 229E and 229F on the top of the ridge multilayer laminate 210c are in sexual contact with the fifth pad 209a5 and the sixth pad 209a6, respectively. First to sixth pads 209a1 to 209a6 Each of the plurality of channel layers 209 (including the lower portion 209b and the string portion 209c) on the sidewalls of the trenches 204, respectively, will form a plurality of intersections at the intersection of the channel layer 209, the memory layer 206, and the conductive layers 112-114. The memory cells 231 are connected in series to form a parallel string Z of memory cells 232. Wherein, a plurality of transistors 234 formed at intersections of the channel layer 209, the memory layer 206 and the conductive layer 115 of the ridge multilayer laminates 210a, 210b and 210c, and the plurality of memory cells 231 corresponding to the memory cell string 232, respectively The series connection can be used as a serial select line (SSL) switch corresponding to the memory cell string 232, respectively. A plurality of transistors 235 formed at intersections of the channel layer 209, the memory layer 206, and the conductive layer 111 of the ridge multilayer laminates 210a, 210b, and 210c are respectively connected in series with the plurality of memory cells 231 of the corresponding memory cell string 232. It can be used as a ground selection line (GSL) switch corresponding to the memory cell string 232, respectively. The polysilicon layer 201a can serve as the bottom common source line of these memory cell strings 232.

後續,再經由一連串後段製程(未繪示),將接觸插塞229A-229F分別連接至對應的位元線(未繪示),完成如第2G圖所繪示之立體記憶體元件200的製備。 Subsequently, through a series of back-end processes (not shown), the contact plugs 229A-229F are respectively connected to corresponding bit lines (not shown) to complete the preparation of the stereo memory device 200 as shown in FIG. 2G. .

藉由離子摻雜製程230將具有帶電的離子摻質植入通道層209的上方部209a和下方部209b,可以有效降低整體通道的電阻值,以改善立體記憶體元件200的操作品質同時減少電力耗損。 By implanting the charged ion dopant into the upper portion 209a and the lower portion 209b of the channel layer 209 by the ion doping process 230, the resistance value of the overall channel can be effectively reduced to improve the operational quality of the stereo memory device 200 while reducing power. Loss.

根據上述實施例,本發明是在提供一種立體記憶體元件及其製作方法。此一立體記憶體元件的製作方法,係在基材上提供一個圖案化的多層堆疊結構,並在多層堆疊結構的至少一 條溝槽側壁上依序形成記憶層和通道層。在尚未以介電材料填充溝槽之前,先對通道層進行一個離子摻雜製程,將複數個離子摻質植入通道層,使通道層位於溝槽側壁上的第一串列部所具有的離子摻雜濃度,實質小於通道層鄰接於溝槽開口的第一上方部和位於溝槽底部之下方部的離子摻雜濃度。 According to the above embodiment, the present invention provides a three-dimensional memory element and a method of fabricating the same. The method of fabricating the three-dimensional memory component provides a patterned multilayer stack structure on the substrate and at least one of the multilayer stack structures A memory layer and a channel layer are sequentially formed on the sidewalls of the trenches. Before the trench is filled with the dielectric material, an ion doping process is performed on the channel layer, and a plurality of ion dopants are implanted into the channel layer, so that the channel layer is located on the first series of the trench sidewalls. The ion doping concentration is substantially less than the ion doping concentration of the channel layer adjacent to the first upper portion of the trench opening and the lower portion of the trench bottom portion.

由於,摻雜製程可以使位於溝槽底部之通道層的下方部具有帶電的離子摻質,可以有效降低通道層的阻值,改善立體記憶體元件因為多層疊結構中絕緣層和導電層數量的增加,造成通道寬度局部緊縮,所引發的通道電阻急遽升高的問題。 Since the doping process can have charged ion dopants in the lower portion of the channel layer at the bottom of the trench, the resistance of the channel layer can be effectively reduced, and the number of insulating layers and conductive layers in the multilayer memory structure can be improved. The increase, causing the channel width to be partially tightened, causes the channel resistance to rise rapidly.

雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明。本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定者為準。 While the invention has been described above in the preferred embodiments, it is not intended to limit the invention. A person skilled in the art can make various changes and modifications without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.

Claims (10)

一種立體記憶體元件,包括:一基材;複數個導電層,位於該基材上;複數個絕緣層,位於該基材上,與該些導電層交錯堆疊形成一多層堆疊結構(multi-layer stacks),其中該多層堆疊結構具有至少一溝槽,穿過該些導電層和該些絕緣層;一記憶層,覆蓋該多層堆疊結構,並且至少延伸至該溝槽的一第一側壁上;以及一通道層,覆蓋於該記憶層上,其中該通道層包括一第一上方部、一第一串列部和一下方部,該第一上方部鄰接該溝槽的一開口;該下方部鄰接該溝槽底部;該第一串列部位於該第一側壁之上,用以連接該第一上方部和該下方部,且具有實質小於該第一上方部和該下方部的一離子摻雜濃度。 A three-dimensional memory component comprises: a substrate; a plurality of conductive layers on the substrate; a plurality of insulating layers on the substrate, and the conductive layers are alternately stacked to form a multi-layer stacked structure (multi- Layer stacks), wherein the multilayer stack structure has at least one trench passing through the conductive layers and the insulating layers; a memory layer covering the multilayer stack structure and extending at least to a first sidewall of the trench And a channel layer covering the memory layer, wherein the channel layer comprises a first upper portion, a first series portion and a lower portion, the first upper portion abutting an opening of the trench; the lower portion The portion is adjacent to the bottom of the trench; the first string portion is located above the first sidewall for connecting the first upper portion and the lower portion, and has an ion substantially smaller than the first upper portion and the lower portion Doping concentration. 如申請專利範圍第1項所述之立體記憶體元件,該通道層更包括:一第二上方部鄰接該溝槽的該開口,並與該第一上方部隔離;以及一第二串列部,位於該溝槽的一第二側壁上,該第二串列部的一端連接該第二上方部,該第二串列部的另一端藉由該下方部與該第一串列部連接,且該第二串列部具有實質小於該第二 上方部和該下方部的一離子摻雜濃度。 The three-dimensional memory component of claim 1, wherein the channel layer further comprises: a second upper portion adjacent to the opening of the trench and isolated from the first upper portion; and a second serial portion a second side wall of the trench is connected to the second upper portion, and the other end of the second string portion is connected to the first string portion by the lower portion. And the second serial portion has substantially less than the second An ion doping concentration of the upper portion and the lower portion. 如申請專利範圍第2項所述之立體記憶體元件,其中該基材包括一介電隔離層,與該多層堆疊結構接觸,且該溝槽底部位於該介電隔離層中。 The three-dimensional memory component of claim 2, wherein the substrate comprises a dielectric isolation layer in contact with the multilayer stack structure, and the trench bottom is located in the dielectric isolation layer. 如申請專利範圍第1項所述之立體記憶體元件,其中該基材包括一多晶矽層,與該多層堆疊結構接觸,且該溝槽底部位於該多晶矽層中。 The three-dimensional memory device of claim 1, wherein the substrate comprises a polysilicon layer in contact with the multilayer stack structure, and the bottom of the trench is located in the polysilicon layer. 如申請專利範圍第1項所述之立體記憶體元件,其中該下方部由該溝槽底部向上延伸,但未實質超過該些導電層之一最下層的一頂面。 The three-dimensional memory component of claim 1, wherein the lower portion extends upward from the bottom of the trench but does not substantially exceed a top surface of one of the lowermost layers of the conductive layers. 如申請專利範圍第1項所述之立體記憶體元件,更包括:一介電層,填充該溝槽,並覆蓋該通道層;以及一接觸插塞,穿過該介電層,並與該第一上方部接觸。 The three-dimensional memory device of claim 1, further comprising: a dielectric layer filling the trench and covering the channel layer; and a contact plug passing through the dielectric layer and The first upper portion is in contact. 一種立體記憶體元件的製作方法,包括:於一基材上形成一多層堆疊結構,該多層堆疊結構包括交錯堆疊的複數個絕緣層和複數個導電層; 圖案化該多層堆疊結構,藉以於該多層堆疊結構中形成至少一溝槽,穿過該些導電層和該些絕緣層;形成一記憶層,覆蓋該多層堆疊結構,並且至少延伸至該溝槽的一側壁上;形成一通道層,覆蓋該記憶層;以及在以一介電材料填充該溝槽之前,對該通道層進行一離子摻雜製程,將複數個離子摻質植入該通道層,並將該通道層至少區隔成一上方部、一串列部和一下方部;其中,該上方部鄰接該溝槽的一開口;該下方部位於該溝槽底部;該串列部位於該側壁之上,用以連接該上方部和該下方部;且該串列部具有實質小於該上方部和該下方部的一離子摻雜濃度。 A method for fabricating a three-dimensional memory device, comprising: forming a multi-layer stack structure on a substrate, the multi-layer stack structure comprising a plurality of insulating layers and a plurality of conductive layers staggered; Patterning the multi-layer stack structure, wherein at least one trench is formed in the multi-layer stack structure, passing through the conductive layers and the insulating layers; forming a memory layer covering the multi-layer stack structure and extending at least to the trench Forming a channel layer covering the memory layer; and performing an ion doping process on the channel layer before filling the trench with a dielectric material, implanting a plurality of ion dopants into the channel layer And the channel layer is at least divided into an upper portion, a series of portions and a lower portion; wherein the upper portion abuts an opening of the groove; the lower portion is located at the bottom of the groove; the string portion is located at the Above the sidewall, the upper portion and the lower portion are connected; and the series portion has an ion doping concentration substantially smaller than the upper portion and the lower portion. 如申請專利範圍第7項所述之立體記憶體元件的製作方法,還包括:形成一介電層填充該溝槽,並覆蓋該通道層;以及形成至少二個接觸插塞,穿過該介電層,並與該上方部接觸;以及進行一蝕刻製程,移除位於該多層堆疊結構之一頂部的一部分該介電層和一部分該通道層,以電性隔離該至少二個接觸插塞。 The method for fabricating a three-dimensional memory device according to claim 7, further comprising: forming a dielectric layer to fill the trench and covering the channel layer; and forming at least two contact plugs through the dielectric layer And electrically contacting the upper portion; and performing an etching process to remove a portion of the dielectric layer and a portion of the via layer on top of one of the multilayer stacked structures to electrically isolate the at least two contact plugs. 如申請專利範圍第7項所述之立體記憶體元件 的製作方法,其中該基材包括一介電隔離層,與該多層堆疊結構接觸,且該溝槽底部位於該介電隔離層中。 The three-dimensional memory component as described in claim 7 The method of fabricating, wherein the substrate comprises a dielectric isolation layer in contact with the multilayer stack structure, and the bottom of the trench is located in the dielectric isolation layer. 如申請專利範圍第7項所述之立體記憶體元件的製作方法,其中該基材包括一多晶矽層,與該多層堆疊結構接觸,且該溝槽底部係位於該多晶矽層中。 The method of fabricating a three-dimensional memory device according to claim 7, wherein the substrate comprises a polysilicon layer in contact with the multilayer stack structure, and the bottom of the trench is located in the polysilicon layer.
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