TWI658585B - Semiconductor structures and fabrication method thereof - Google Patents
Semiconductor structures and fabrication method thereof Download PDFInfo
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- TWI658585B TWI658585B TW107111231A TW107111231A TWI658585B TW I658585 B TWI658585 B TW I658585B TW 107111231 A TW107111231 A TW 107111231A TW 107111231 A TW107111231 A TW 107111231A TW I658585 B TWI658585 B TW I658585B
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims description 36
- 238000004519 manufacturing process Methods 0.000 title claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 76
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 76
- 239000000758 substrate Substances 0.000 claims abstract description 71
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 26
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 26
- 238000005530 etching Methods 0.000 claims description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 16
- 238000002955 isolation Methods 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- 229910018503 SF6 Inorganic materials 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- SFZCNBIFKDRMGX-UHFFFAOYSA-N sulfur hexafluoride Chemical compound FS(F)(F)(F)(F)F SFZCNBIFKDRMGX-UHFFFAOYSA-N 0.000 claims description 8
- 229960000909 sulfur hexafluoride Drugs 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 description 10
- 229920002120 photoresistant polymer Polymers 0.000 description 7
- 238000002513 implantation Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
本揭露提供一種半導體結構,包括:一基板,包括一第一區域與一第二區域;一第一溝槽,形成於該基板中,位於該第一區域,由一第一突出結構所包圍;一第二溝槽,形成於該基板中,位於該第二區域,由一第二突出結構所包圍,其中該第二溝槽之深度大於該第一溝槽之深度;一第一氧化矽層,形成於該第一突出結構之頂部;一第二氧化矽層,形成於該第二突出結構之頂部;一第一介電層,形成於該第一氧化矽層上;以及一第二介電層,形成於該第二氧化矽層上,其中該第一介電層之厚度大於該第二介電層之厚度。 The present disclosure provides a semiconductor structure including: a substrate including a first region and a second region; a first trench formed in the substrate, located in the first region, and surrounded by a first protruding structure; A second trench is formed in the substrate, is located in the second region, and is surrounded by a second protruding structure, wherein the depth of the second trench is greater than the depth of the first trench; a first silicon oxide layer Formed on top of the first protruding structure; a second silicon oxide layer formed on top of the second protruding structure; a first dielectric layer formed on the first silicon oxide layer; and a second dielectric An electrical layer is formed on the second silicon oxide layer, wherein a thickness of the first dielectric layer is greater than a thickness of the second dielectric layer.
Description
本揭露係有關於一種半導體結構,特別是有關於一種在低壓區與高壓區具有不同厚度氮化矽層的半導體結構及其製造方法。 The disclosure relates to a semiconductor structure, and more particularly to a semiconductor structure having a silicon nitride layer with different thicknesses in a low-voltage region and a high-voltage region, and a method for manufacturing the same.
對於高壓(high voltage)元件來說,製作較深的溝槽是必要的,以有效提升其崩潰電壓。然而,對於低壓(low voltage)元件來說,由於低壓元件的接面較淺,若此時溝槽深度深,則後續在進行佈植製程時,勢必針對基板更深的位置進行佈植,然而,此種深度佈植的製程條件並不易控制,且由於深溝槽的填入製程並不易進行,須將低壓元件間的溝槽開口進一步擴大。種種顯示,單一深度的溝槽結構已不符合高、低壓元件整合製程的需求。然而,目前業界常使用製作不同深度溝槽的方法,均需配合多重的製程步驟(多次黃光、多次蝕刻)方能達成,相當耗費成本。 For high voltage devices, it is necessary to make deeper trenches to effectively increase their breakdown voltage. However, for low-voltage (low-voltage) components, because the interface of the low-voltage components is shallow, if the groove depth is deep at this time, the subsequent implantation process will necessarily be implanted for the deeper position of the substrate. However, The process conditions for such deep implantation are not easy to control, and because the deep trench filling process is not easy to perform, the trench openings between low-voltage components must be further enlarged. It has been shown that the single-depth trench structure no longer meets the requirements of high and low voltage component integration processes. However, currently the industry often uses methods for making trenches with different depths, which can only be achieved with multiple process steps (multiple yellow light and multiple etchings), which is quite costly.
因此,開發一種簡易的、且在低壓區與高壓區可同時具有不同深度溝槽的半導體結構及相關製造方法是眾所期待的。 Therefore, it is desirable to develop a simple semiconductor structure and related manufacturing method that can simultaneously have trenches with different depths in the low-voltage region and the high-voltage region.
根據本揭露之一實施例,提供一種半導體結構。 該半導體結構包括:一基板,包括一第一區域與一第二區域;一第一溝槽,形成於該基板中,位於該第一區域,由一第一突出結構所包圍;一第二溝槽,形成於該基板中,位於該第二區域,由一第二突出結構所包圍,其中該第二溝槽之深度大於該第一溝槽之深度;一第一氧化矽層,形成於該第一突出結構之頂部;一第二氧化矽層,形成於該第二突出結構之頂部;一第一介電層,形成於該第一氧化矽層上;以及一第二介電層,形成於該第二氧化矽層上,其中該第一介電層之厚度大於該第二介電層之厚度。 According to an embodiment of the present disclosure, a semiconductor structure is provided. The semiconductor structure includes: a substrate including a first region and a second region; a first trench formed in the substrate, located in the first region, surrounded by a first protruding structure; a second trench A trench is formed in the substrate, is located in the second region, and is surrounded by a second protruding structure, wherein the depth of the second trench is greater than the depth of the first trench; a first silicon oxide layer is formed on the substrate; On top of the first protruding structure; a second silicon oxide layer formed on top of the second protruding structure; a first dielectric layer formed on the first silicon oxide layer; and a second dielectric layer formed On the second silicon oxide layer, a thickness of the first dielectric layer is greater than a thickness of the second dielectric layer.
根據部分實施例,上述基板為一矽基板。 According to some embodiments, the substrate is a silicon substrate.
根據部分實施例,上述第一區域為低壓元件設置之區域,上述第二區域為高壓元件設置之區域。 According to some embodiments, the first region is a region where a low-voltage element is provided, and the second region is a region where a high-voltage element is provided.
根據部分實施例,上述第一溝槽為低壓元件間之電性隔離,上述第二溝槽為高壓元件間之電性隔離。 According to some embodiments, the first trench is an electrical isolation between low-voltage components, and the second trench is an electrical isolation between high-voltage components.
根據部分實施例,上述第一溝槽之深度與上述第二溝槽之深度之差異大體介於500埃至5,000埃。 According to some embodiments, the difference between the depth of the first trench and the depth of the second trench is generally between 500 angstroms and 5,000 angstroms.
根據部分實施例,上述第一介電層與上述第二介電層包括氮化矽或氧化矽。 According to some embodiments, the first dielectric layer and the second dielectric layer include silicon nitride or silicon oxide.
根據部分實施例,當上述第一介電層與上述第二介電層為氮化矽時,上述第一氧化矽層更包括延伸覆蓋上述第一突出結構之部分側壁,上述第二氧化矽層更包括延伸覆蓋上述第二突出結構之部分側壁。 According to some embodiments, when the first dielectric layer and the second dielectric layer are silicon nitride, the first silicon oxide layer further includes a portion of a sidewall extending to cover the first protruding structure, and the second silicon oxide layer It further includes a portion of the side wall extending to cover the second protruding structure.
根據部分實施例,上述第二突出結構之頂部與側壁之連接部分之曲率半徑大於上述第一突出結構之頂部與側 壁之連接部分之曲率半徑。 According to some embodiments, the radius of curvature of the connecting portion between the top of the second protruding structure and the side wall is greater than the top and side of the first protruding structure. The radius of curvature of the connecting part of the wall.
根據部分實施例,上述第一介電層之厚度與上述第二介電層之厚度之差異大體介於300埃至1,000埃。 According to some embodiments, the difference between the thickness of the first dielectric layer and the thickness of the second dielectric layer is generally between 300 angstroms and 1,000 angstroms.
根據本揭露之一實施例,提供一種半導體結構之製造方法。該製造方法包括:提供一基板,該基板包括一第一區域與一第二區域;形成一氧化矽層於該基板上;形成一介電層於該氧化矽層上,其中位於該基板之該第一區域之該介電層之厚度大於位於該基板之該第二區域之該介電層之厚度;以及實施一蝕刻製程,對該介電層進行蝕刻,穿過該氧化矽層至該基板,以於該基板之該第一區域中,形成一第一溝槽,由一第一突出結構所包圍,於該基板之該第二區域中,形成一第二溝槽,由一第二突出結構所包圍,其中該第二溝槽之深度大於該第一溝槽之深度,其中位於該第一突出結構之頂部之該氧化矽層定義為一第一氧化矽層,位於該第二突出結構之頂部之該氧化矽層定義為一第二氧化矽層。 According to an embodiment of the present disclosure, a method for manufacturing a semiconductor structure is provided. The manufacturing method includes: providing a substrate, the substrate including a first region and a second region; forming a silicon oxide layer on the substrate; forming a dielectric layer on the silicon oxide layer, wherein the silicon layer is located on the substrate; The thickness of the dielectric layer in the first region is greater than the thickness of the dielectric layer in the second region of the substrate; and an etching process is performed to etch the dielectric layer and pass through the silicon oxide layer to the substrate A first trench is formed in the first region of the substrate, and is surrounded by a first protruding structure; a second trench is formed in the second region of the substrate, and a second protrusion is formed Surrounded by a structure, wherein the depth of the second trench is greater than the depth of the first trench, wherein the silicon oxide layer on top of the first protruding structure is defined as a first silicon oxide layer located on the second protruding structure The silicon oxide layer on top of it is defined as a second silicon oxide layer.
根據部分實施例,上述蝕刻製程之蝕刻氣體包括六氟化硫、甲烷與氮氣之組合或六氟化硫、甲烷、氮氣與氧氣之組合。 According to some embodiments, the etching gas in the above-mentioned etching process includes sulfur hexafluoride, a combination of methane and nitrogen, or a combination of sulfur hexafluoride, methane, nitrogen, and oxygen.
根據部分實施例,上述介電層與上述基板之蝕刻選擇比大體介於1:4至1:10。 According to some embodiments, the etching selectivity ratio between the dielectric layer and the substrate is generally between 1: 4 and 1:10.
根據部分實施例,當上述介電層為氮化矽時,更包括實施一氧化製程,以使上述第一氧化矽層延伸覆蓋上述第一突出結構之部分側壁,使上述第二氧化矽層延伸覆蓋上述第二突出結構之部分側壁。 According to some embodiments, when the dielectric layer is silicon nitride, an oxidation process is further performed, so that the first silicon oxide layer extends to cover part of the sidewall of the first protruding structure, and the second silicon oxide layer extends. Covering part of the side wall of the second protruding structure.
本揭露在低壓區與高壓區製作出厚度不同的氮化矽層(即,於低壓區製作厚度較厚的氮化矽層、於高壓區製作厚度較薄的氮化矽層),後續再配合具備特定蝕刻條件(例如氮化矽層對矽基板的蝕刻選擇比)的單一蝕刻步驟,即能同時在低壓區獲得深度較淺的溝槽,又能在高壓區獲得深度較深的溝槽。 The present disclosure produces silicon nitride layers with different thicknesses in the low-voltage region and the high-voltage region (that is, a thicker silicon nitride layer in the low-voltage region and a thinner silicon nitride layer in the high-voltage region), and then cooperates with A single etching step with specific etching conditions (such as the silicon nitride layer-to-silicon substrate etching selection ratio) can simultaneously obtain shallower trenches in the low-voltage region and deeper trenches in the high-voltage region.
此外,在後續進行氧化製程時(可於化學機械研磨(CMP)製程之前或之後進行),由於低壓區的氮化矽層較厚,高壓區的氮化矽層較薄,使得低壓區溝槽的圓化效應(rounding effect)較不明顯,高壓區溝槽則呈現較明顯的圓化效應,而此不同程度的圓化效應,恰好分別對於低壓元件與高壓元件有著不同面向的貢獻。對於低壓元件來說,較低的圓化效應,可維持元件通道的有效寬度,得到高的飽和區汲極電流(saturation-region drain current,Idsat),而對於高壓元件來說,較高的圓化效應,則可提升相關結構於整片晶圓中的均勻性,增加元件匹配性。 In addition, during the subsequent oxidation process (can be performed before or after the chemical mechanical polishing (CMP) process), the silicon nitride layer in the low voltage region is thicker and the silicon nitride layer in the high voltage region is thinner, which makes the low voltage region trench The rounding effect is relatively insignificant, and the grooves in the high-voltage region show a more pronounced rounding effect. The different degrees of rounding effects have different contributions to the low-voltage and high-voltage components. For low-voltage components, the lower rounding effect can maintain the effective width of the element channel, and get a high saturation-region drain current (Idsat), while for high-voltage components, a higher roundness The effect can improve the uniformity of related structures in the whole wafer and increase the matching of components.
因此,本揭露在低壓區與高壓區製作出不同深度的溝槽的同時,又能提升低壓元件與高壓元件分別在結構及電性上的優勢。 Therefore, the present disclosure can simultaneously improve the structural and electrical advantages of low-voltage components and high-voltage components while making trenches of different depths in the low-voltage area and the high-voltage area.
為讓本發明之上述目的、特徵及優點能更明顯易懂,下文特舉一較佳實施例,並配合所附的圖式,作詳細說明如下。 In order to make the above-mentioned objects, features, and advantages of the present invention more comprehensible, a preferred embodiment is given below in conjunction with the accompanying drawings for detailed description as follows.
10‧‧‧半導體結構 10‧‧‧Semiconductor Structure
12‧‧‧基板 12‧‧‧ substrate
14‧‧‧第一溝槽 14‧‧‧first groove
16‧‧‧第一突出結構 16‧‧‧The first prominent structure
18‧‧‧第二溝槽 18‧‧‧Second Groove
20‧‧‧第二突出結構 20‧‧‧Second prominent structure
22‧‧‧第一氧化矽層 22‧‧‧ First silicon oxide layer
24‧‧‧第二氧化矽層 24‧‧‧Second silicon oxide layer
25‧‧‧氧化矽層 25‧‧‧Silicon oxide layer
26‧‧‧第一介電層 26‧‧‧First dielectric layer
28‧‧‧第二介電層 28‧‧‧Second dielectric layer
29‧‧‧介電層 29‧‧‧ Dielectric layer
30‧‧‧基板的第一區域 30‧‧‧ the first area of the substrate
32‧‧‧基板的第二區域 32‧‧‧ the second area of the substrate
34‧‧‧第一突出結構的頂部 34‧‧‧ the top of the first protruding structure
36‧‧‧第二突出結構的頂部 36‧‧‧ the top of the second protruding structure
38‧‧‧圖案化光阻層 38‧‧‧patterned photoresist layer
40‧‧‧第一突出結構的側壁 40‧‧‧ sidewall of the first protruding structure
42‧‧‧第二突出結構的側壁 42‧‧‧ the side wall of the second protruding structure
44‧‧‧第一突出結構的頂部與側壁的連接部分 44‧‧‧ the connection between the top of the first protruding structure and the side wall
46‧‧‧第二突出結構的頂部與側壁的連接部分 46‧‧‧ the connection between the top of the second protruding structure and the side wall
H1‧‧‧第一溝槽的深度 H1‧‧‧ Depth of the first groove
H2‧‧‧第二溝槽的深度 H2‧‧‧ Depth of second trench
R1‧‧‧第一突出結構的頂部與側壁的連接部分的曲率半徑 R1‧‧‧ the radius of curvature of the connecting portion between the top of the first protruding structure and the side wall
R2‧‧‧第二突出結構的頂部與側壁的連接部分的曲率半徑 R2 ‧‧‧ the radius of curvature of the connecting portion between the top of the second protruding structure and the side wall
T1‧‧‧第一介電層的厚度 T1‧‧‧Thickness of the first dielectric layer
T2‧‧‧第二介電層的厚度 T2‧‧‧thickness of the second dielectric layer
第1圖係根據本揭露之一實施例,一種半導體結構之剖面示意圖;第2A-2E圖係根據本揭露之一實施例,一種半導體結構製造方法之剖面示意圖。 FIG. 1 is a schematic cross-sectional view of a semiconductor structure according to an embodiment of the present disclosure; and FIGS. 2A-2E are cross-sectional schematic views of a method of manufacturing a semiconductor structure according to an embodiment of the present disclosure.
第3圖係根據本揭露之一實施例,一種半導體結構之剖面示意圖;第4A-4E圖係根據本揭露之一實施例,一種半導體結構製造方法之剖面示意圖。 FIG. 3 is a schematic cross-sectional view of a semiconductor structure according to an embodiment of the disclosure; and FIGS. 4A-4E are cross-sectional schematic views of a method of manufacturing a semiconductor structure according to an embodiment of the disclosure.
請參閱第1圖,根據本揭露的一實施例,提供一種半導體結構10。第1圖為半導體結構10的剖面示意圖。 Referring to FIG. 1, a semiconductor structure 10 is provided according to an embodiment of the disclosure. FIG. 1 is a schematic cross-sectional view of the semiconductor structure 10.
如第1圖所示,在本實施例中,半導體結構10包括基板12、第一溝槽14、第一突出結構16、第二溝槽18、第二突出結構20、第一氧化矽層22、第二氧化矽層24、第一介電層26、以及第二介電層28。基板12包括第一區域30與第二區域32。第一溝槽14形成於基板12中,位於第一區域30,由第一突出結構16所包圍。第二溝槽18形成於基板12中,位於第二區域32,由第二突出結構20所包圍。值得注意的是,第二溝槽18的深度H2大於第一溝槽14的深度H1。第一氧化矽層22形成於第一突出結構16的頂部34。第二氧化矽層24形成於第二突出結構20的頂部36。第一介電層26形成於第一氧化矽層22上。第二介電層28形成於第二氧化矽層24上。值得注意的是,第一介電層26的厚度T1大於第二介電層28的厚度T2。 As shown in FIG. 1, in this embodiment, the semiconductor structure 10 includes a substrate 12, a first trench 14, a first protruding structure 16, a second trench 18, a second protruding structure 20, and a first silicon oxide layer 22. , A second silicon oxide layer 24, a first dielectric layer 26, and a second dielectric layer 28. The substrate 12 includes a first region 30 and a second region 32. The first trench 14 is formed in the substrate 12, is located in the first region 30, and is surrounded by the first protruding structure 16. The second trench 18 is formed in the substrate 12, is located in the second region 32, and is surrounded by the second protruding structure 20. It is worth noting that the depth H2 of the second trench 18 is greater than the depth H1 of the first trench 14. The first silicon oxide layer 22 is formed on the top 34 of the first protruding structure 16. A second silicon oxide layer 24 is formed on the top 36 of the second protruding structure 20. A first dielectric layer 26 is formed on the first silicon oxide layer 22. A second dielectric layer 28 is formed on the second silicon oxide layer 24. It is worth noting that the thickness T1 of the first dielectric layer 26 is greater than the thickness T2 of the second dielectric layer 28.
在部分實施例中,基板12可為矽基板。 In some embodiments, the substrate 12 may be a silicon substrate.
在部分實施例中,第一區域30可為低壓(low voltage)元件設置的區域,第二區域32可為高壓(high voltage)元件設置的區域。 In some embodiments, the first region 30 may be a region provided with a low voltage element, and the second region 32 may be a region provided with a high voltage element.
在部分實施例中,第一溝槽14可為低壓元件間的電性隔離(electrical isolation),第二溝槽18可為高壓元件間的電性隔離。 In some embodiments, the first trench 14 may be electrical isolation between low-voltage components, and the second trench 18 may be electrical isolation between high-voltage components.
在部分實施例中,第一溝槽14的深度H1與第二溝槽18的深度H2的差異大體介於500埃至5,000埃。 In some embodiments, the difference between the depth H1 of the first trench 14 and the depth H2 of the second trench 18 is generally between 500 angstroms and 5,000 angstroms.
在部分實施例中,第一介電層26與第二介電層28可包括氮化矽或氧化矽。 In some embodiments, the first dielectric layer 26 and the second dielectric layer 28 may include silicon nitride or silicon oxide.
在本實施例中,第一介電層26與第二介電層28為氧化矽。 In this embodiment, the first dielectric layer 26 and the second dielectric layer 28 are silicon oxide.
在部分實施例中,第一介電層26的厚度T1與第二介電層28的厚度T2的差異大體介於300埃至1,000埃。 In some embodiments, the difference between the thickness T1 of the first dielectric layer 26 and the thickness T2 of the second dielectric layer 28 is generally between 300 angstroms and 1,000 angstroms.
請參閱第2A-2E圖,根據本揭露的一實施例,提供一種半導體結構10的製造方法。第2A-2E圖為半導體結構10製造方法的剖面示意圖。 Please refer to FIGS. 2A-2E. According to an embodiment of the present disclosure, a method for manufacturing a semiconductor structure 10 is provided. 2A-2E are schematic cross-sectional views of a method for manufacturing the semiconductor structure 10.
如第2A圖所示,提供基板12。基板12包括第一區域30與第二區域32。 As shown in FIG. 2A, a substrate 12 is provided. The substrate 12 includes a first region 30 and a second region 32.
在部分實施例中,基板12可為矽基板。 In some embodiments, the substrate 12 may be a silicon substrate.
在部分實施例中,第一區域30可為低壓元件設置的區域,第二區域32可為高壓元件設置的區域。 In some embodiments, the first region 30 may be a region where a low voltage element is provided, and the second region 32 may be a region where a high voltage element is provided.
之後,形成氧化矽層25於基板12上。 After that, a silicon oxide layer 25 is formed on the substrate 12.
之後,形成介電層29於氧化矽層25上。 Thereafter, a dielectric layer 29 is formed on the silicon oxide layer 25.
在部分實施例中,介電層29可包括氮化矽或氧化矽。 In some embodiments, the dielectric layer 29 may include silicon nitride or silicon oxide.
在本實施例中,介電層29為氧化矽。 In this embodiment, the dielectric layer 29 is silicon oxide.
之後,圖案化介電層29,以形成位於基板12的第一區域30的第一介電層26以及位於基板12的第二區域32的第二介電層28。值得注意的是,第一介電層26的厚度T1大於第二介電層28的厚度T2,如第2B圖所示。 Thereafter, the dielectric layer 29 is patterned to form a first dielectric layer 26 located in the first region 30 of the substrate 12 and a second dielectric layer 28 located in the second region 32 of the substrate 12. It is worth noting that the thickness T1 of the first dielectric layer 26 is greater than the thickness T2 of the second dielectric layer 28, as shown in FIG. 2B.
在部分實施例中,第一介電層26的厚度T1與第二介電層28的厚度T2的差異大體介於300埃至1,000埃。 In some embodiments, the difference between the thickness T1 of the first dielectric layer 26 and the thickness T2 of the second dielectric layer 28 is generally between 300 angstroms and 1,000 angstroms.
之後,形成圖案化光阻層38於第一介電層26與第二介電層28上,如第2C圖所示。 Thereafter, a patterned photoresist layer 38 is formed on the first dielectric layer 26 and the second dielectric layer 28, as shown in FIG. 2C.
之後,以圖案化光阻層38為罩幕,實施蝕刻製程,對第一介電層26與第二介電層28進行蝕刻,穿過氧化矽層25至基板12,以於基板12的第一區域30中,形成第一溝槽14,由第一突出結構16所包圍,於基板12的第二區域32中,形成第二溝槽18,由第二突出結構20所包圍。值得注意的是,第二溝槽18的深度H2大於第一溝槽14的深度H1。並將位於第一突出結構16的頂部34的氧化矽層定義為第一氧化矽層22,將位於第二突出結構20的頂部36的氧化矽層定義為第二氧化矽層24,如第2D圖所示。 After that, using the patterned photoresist layer 38 as a mask, an etching process is performed to etch the first dielectric layer 26 and the second dielectric layer 28, pass through the silicon oxide layer 25 to the substrate 12, and In a region 30, a first trench 14 is formed, surrounded by a first protruding structure 16, and in a second region 32 of the substrate 12, a second trench 18 is formed, surrounded by a second protruding structure 20. It is worth noting that the depth H2 of the second trench 18 is greater than the depth H1 of the first trench 14. The silicon oxide layer on the top 34 of the first protruding structure 16 is defined as the first silicon oxide layer 22, and the silicon oxide layer on the top 36 of the second protruding structure 20 is defined as the second silicon oxide layer 24, as in the 2D As shown.
在部分實施例中,上述蝕刻製程的蝕刻氣體可包括六氟化硫、甲烷與氮氣的組合或六氟化硫、甲烷、氮氣與氧氣的組合。 In some embodiments, the etching gas in the above-mentioned etching process may include sulfur hexafluoride, a combination of methane and nitrogen, or a combination of sulfur hexafluoride, methane, nitrogen, and oxygen.
在部分實施例中,第一介電層26與第二介電層28 對基板12的蝕刻選擇比大體介於1:4至1:10。 In some embodiments, the first dielectric layer 26 and the second dielectric layer 28 The etching selection ratio of the substrate 12 is generally between 1: 4 and 1:10.
在部分實施例中,第一溝槽14可為低壓元件間的電性隔離,第二溝槽18可為高壓元件間的電性隔離。 In some embodiments, the first trench 14 may be an electrical isolation between low-voltage components, and the second trench 18 may be an electrical isolation between high-voltage components.
在部分實施例中,第一溝槽14的深度H1與第二溝槽18的深度H2的差異大體介於500埃至5,000埃。 In some embodiments, the difference between the depth H1 of the first trench 14 and the depth H2 of the second trench 18 is generally between 500 angstroms and 5,000 angstroms.
之後,移除圖案化光阻層38,如第2E圖所示。至此,即完成本實施例半導體結構10的製作。 Thereafter, the patterned photoresist layer 38 is removed, as shown in FIG. 2E. So far, the fabrication of the semiconductor structure 10 of this embodiment is completed.
請參閱第3圖,根據本揭露的一實施例,提供一種半導體結構10。第3圖為半導體結構10的剖面示意圖。 Referring to FIG. 3, a semiconductor structure 10 is provided according to an embodiment of the present disclosure. FIG. 3 is a schematic cross-sectional view of the semiconductor structure 10.
如第3圖所示,在本實施例中,半導體結構10包括基板12、第一溝槽14、第一突出結構16、第二溝槽18、第二突出結構20、第一氧化矽層22、第二氧化矽層24、第一介電層26、以及第二介電層28。基板12包括第一區域30與第二區域32。第一溝槽14形成於基板12中,位於第一區域30,由第一突出結構16所包圍。第二溝槽18形成於基板12中,位於第二區域32,由第二突出結構20所包圍。值得注意的是,第二溝槽18的深度H2大於第一溝槽14的深度H1。第一氧化矽層22形成於第一突出結構16的頂部34。第二氧化矽層24形成於第二突出結構20的頂部36。第一介電層26形成於第一氧化矽層22上。第二介電層28形成於第二氧化矽層24上。值得注意的是,第一介電層26的厚度T1大於第二介電層28的厚度T2。 As shown in FIG. 3, in this embodiment, the semiconductor structure 10 includes a substrate 12, a first trench 14, a first protruding structure 16, a second trench 18, a second protruding structure 20, and a first silicon oxide layer 22. , A second silicon oxide layer 24, a first dielectric layer 26, and a second dielectric layer 28. The substrate 12 includes a first region 30 and a second region 32. The first trench 14 is formed in the substrate 12, is located in the first region 30, and is surrounded by the first protruding structure 16. The second trench 18 is formed in the substrate 12, is located in the second region 32, and is surrounded by the second protruding structure 20. It is worth noting that the depth H2 of the second trench 18 is greater than the depth H1 of the first trench 14. The first silicon oxide layer 22 is formed on the top 34 of the first protruding structure 16. A second silicon oxide layer 24 is formed on the top 36 of the second protruding structure 20. A first dielectric layer 26 is formed on the first silicon oxide layer 22. A second dielectric layer 28 is formed on the second silicon oxide layer 24. It is worth noting that the thickness T1 of the first dielectric layer 26 is greater than the thickness T2 of the second dielectric layer 28.
在部分實施例中,基板12可為矽基板。 In some embodiments, the substrate 12 may be a silicon substrate.
在部分實施例中,第一區域30可為低壓(low voltage)元件設置的區域,第二區域32可為高壓(high voltage) 元件設置的區域。 In some embodiments, the first region 30 may be a region provided by a low voltage element, and the second region 32 may be a high voltage region. The area where the component is set.
在部分實施例中,第一溝槽14可為低壓元件間的電性隔離(electrical isolation),第二溝槽18可為高壓元件間的電性隔離。 In some embodiments, the first trench 14 may be electrical isolation between low-voltage components, and the second trench 18 may be electrical isolation between high-voltage components.
在部分實施例中,第一溝槽14的深度H1與第二溝槽18的深度H2的差異大體介於500埃至5,000埃。 In some embodiments, the difference between the depth H1 of the first trench 14 and the depth H2 of the second trench 18 is generally between 500 angstroms and 5,000 angstroms.
在部分實施例中,第一介電層26與第二介電層28可包括氮化矽或氧化矽。 In some embodiments, the first dielectric layer 26 and the second dielectric layer 28 may include silicon nitride or silicon oxide.
在本實施例中,第一介電層26與第二介電層28為氮化矽。 In this embodiment, the first dielectric layer 26 and the second dielectric layer 28 are silicon nitride.
在本實施例中,第一氧化矽層22更包括延伸覆蓋第一突出結構16的一部分的側壁40,第二氧化矽層24更包括延伸覆蓋第二突出結構20的一部分的側壁42。值得注意的是,第二突出結構20的頂部36與側壁42的連接部分46的曲率半徑R2大於第一突出結構16的頂部34與側壁40的連接部分44的曲率半徑R1。 In this embodiment, the first silicon oxide layer 22 further includes a sidewall 40 extending to cover a portion of the first protruding structure 16, and the second silicon oxide layer 24 further includes a sidewall 42 extending to cover a portion of the second protruding structure 20. It is worth noting that the radius of curvature R2 of the connecting portion 46 between the top 36 of the second protruding structure 20 and the side wall 42 is greater than the radius of curvature R1 of the connecting portion 44 between the top 34 of the first protruding structure 16 and the side wall 40.
在部分實施例中,第一介電層26的厚度T1與第二介電層28的厚度T2的差異大體介於300埃至1,000埃。 In some embodiments, the difference between the thickness T1 of the first dielectric layer 26 and the thickness T2 of the second dielectric layer 28 is generally between 300 angstroms and 1,000 angstroms.
請參閱第4A-4E圖,根據本揭露的一實施例,提供一種半導體結構10的製造方法。第4A-4E圖為半導體結構10製造方法的剖面示意圖。 Please refer to FIGS. 4A-4E. According to an embodiment of the present disclosure, a method for manufacturing a semiconductor structure 10 is provided. 4A-4E are schematic cross-sectional views of a method for manufacturing the semiconductor structure 10.
如第4A圖所示,提供基板12。基板12包括第一區域30與第二區域32。 As shown in FIG. 4A, a substrate 12 is provided. The substrate 12 includes a first region 30 and a second region 32.
在部分實施例中,基板12可為矽基板。 In some embodiments, the substrate 12 may be a silicon substrate.
在部分實施例中,第一區域30可為低壓元件設置的區域,第二區域32可為高壓元件設置的區域。 In some embodiments, the first region 30 may be a region where a low voltage element is provided, and the second region 32 may be a region where a high voltage element is provided.
之後,形成氧化矽層25於基板12上。 After that, a silicon oxide layer 25 is formed on the substrate 12.
之後,形成介電層29於氧化矽層25上。 Thereafter, a dielectric layer 29 is formed on the silicon oxide layer 25.
在部分實施例中,介電層29可包括氮化矽或氧化矽。 In some embodiments, the dielectric layer 29 may include silicon nitride or silicon oxide.
在本實施例中,介電層29為氮化矽。 In this embodiment, the dielectric layer 29 is silicon nitride.
之後,圖案化介電層29,以形成位於基板12的第一區域30的第一介電層26以及位於基板12的第二區域32的第二介電層28。值得注意的是,第一介電層26的厚度T1大於第二介電層28的厚度T2,如第4B圖所示。 Thereafter, the dielectric layer 29 is patterned to form a first dielectric layer 26 located in the first region 30 of the substrate 12 and a second dielectric layer 28 located in the second region 32 of the substrate 12. It is worth noting that the thickness T1 of the first dielectric layer 26 is greater than the thickness T2 of the second dielectric layer 28, as shown in FIG. 4B.
在部分實施例中,第一介電層26的厚度T1與第二介電層28的厚度T2的差異大體介於300埃至1,000埃。 In some embodiments, the difference between the thickness T1 of the first dielectric layer 26 and the thickness T2 of the second dielectric layer 28 is generally between 300 angstroms and 1,000 angstroms.
之後,形成圖案化光阻層38於第一介電層26與第二介電層28上,如第4C圖所示。 Thereafter, a patterned photoresist layer 38 is formed on the first dielectric layer 26 and the second dielectric layer 28, as shown in FIG. 4C.
之後,以圖案化光阻層38為罩幕,實施蝕刻製程,對第一介電層26與第二介電層28進行蝕刻,穿過氧化矽層25至基板12,以於基板12的第一區域30中,形成第一溝槽14,由第一突出結構16所包圍,於基板12的第二區域32中,形成第二溝槽18,由第二突出結構20所包圍。值得注意的是,第二溝槽18的深度H2大於第一溝槽14的深度H1。並將位於第一突出結構16的頂部34的氧化矽層定義為第一氧化矽層22,將位於第二突出結構20的頂部36的氧化矽層定義為第二氧化矽層24,如第4D圖所示。 After that, using the patterned photoresist layer 38 as a mask, an etching process is performed to etch the first dielectric layer 26 and the second dielectric layer 28, pass through the silicon oxide layer 25 to the substrate 12, and In a region 30, a first trench 14 is formed, surrounded by a first protruding structure 16, and in a second region 32 of the substrate 12, a second trench 18 is formed, surrounded by a second protruding structure 20. It is worth noting that the depth H2 of the second trench 18 is greater than the depth H1 of the first trench 14. The silicon oxide layer on the top 34 of the first protruding structure 16 is defined as the first silicon oxide layer 22, and the silicon oxide layer on the top 36 of the second protruding structure 20 is defined as the second silicon oxide layer 24, as in the 4D As shown.
在部分實施例中,上述蝕刻製程的蝕刻氣體可包括六氟化硫、甲烷與氮氣的組合或六氟化硫、甲烷、氮氣與氧氣的組合。 In some embodiments, the etching gas in the above-mentioned etching process may include sulfur hexafluoride, a combination of methane and nitrogen, or a combination of sulfur hexafluoride, methane, nitrogen, and oxygen.
在部分實施例中,第一介電層26與第二介電層28對基板12的蝕刻選擇比大體介於1:4至1:10。 In some embodiments, the etching selectivity ratio of the first dielectric layer 26 and the second dielectric layer 28 to the substrate 12 is generally between 1: 4 and 1:10.
在部分實施例中,第一溝槽14可為低壓元件間的電性隔離,第二溝槽18可為高壓元件間的電性隔離。 In some embodiments, the first trench 14 may be an electrical isolation between low-voltage components, and the second trench 18 may be an electrical isolation between high-voltage components.
在部分實施例中,第一溝槽14的深度H1與第二溝槽18的深度H2的差異大體介於500埃至5,000埃。 In some embodiments, the difference between the depth H1 of the first trench 14 and the depth H2 of the second trench 18 is generally between 500 angstroms and 5,000 angstroms.
之後,移除圖案化光阻層38。 After that, the patterned photoresist layer 38 is removed.
在本實施例中,更包括實施氧化製程,以使第一氧化矽層22延伸覆蓋第一突出結構16的一部分的側壁40,使第二氧化矽層24延伸覆蓋第二突出結構20的一部分的側壁42。值得注意的是,第二突出結構20的頂部36與側壁42的連接部分46的曲率半徑R2大於第一突出結構16的頂部34與側壁40的連接部分44的曲率半徑R1,如第4E圖所示。至此,即完成本實施例半導體結構10的製作。 In this embodiment, an oxidation process is further performed, so that the first silicon oxide layer 22 extends to cover a side wall 40 of a portion of the first protruding structure 16, and the second silicon oxide layer 24 extends to cover a portion of the second protruding structure 20. Side wall 42. It is worth noting that the radius of curvature R2 of the connecting portion 46 between the top 36 of the second protruding structure 20 and the side wall 42 is greater than the radius of curvature R1 of the connecting portion 44 between the top 34 of the first protruding structure 16 and the side wall 40, as shown in FIG. 4E. Show. So far, the fabrication of the semiconductor structure 10 of this embodiment is completed.
本揭露在低壓區與高壓區製作出厚度不同的氮化矽層(即,於低壓區製作厚度較厚的氮化矽層、於高壓區製作厚度較薄的氮化矽層),後續再配合具備特定蝕刻條件(例如氮化矽層對矽基板的蝕刻選擇比)的單一蝕刻步驟,即能同時在低壓區獲得深度較淺的溝槽,又能在高壓區獲得深度較深的溝槽。 The present disclosure produces silicon nitride layers with different thicknesses in the low-voltage region and the high-voltage region (that is, a thicker silicon nitride layer in the low-voltage region and a thinner silicon nitride layer in the high-voltage region), and then cooperates with A single etching step with specific etching conditions (such as the silicon nitride layer-to-silicon substrate etching selection ratio) can simultaneously obtain shallower trenches in the low-voltage region and deeper trenches in the high-voltage region.
此外,在後續進行氧化製程時(可於化學機械研磨 (CMP)製程之前或之後進行),由於低壓區的氮化矽層較厚,高壓區的氮化矽層較薄,使得低壓區溝槽的圓化效應(rounding effect)較不明顯,高壓區溝槽則呈現較明顯的圓化效應,而此不同程度的圓化效應,恰好分別對於低壓元件與高壓元件有著不同面向的貢獻。對於低壓元件來說,較低的圓化效應,可維持元件通道的有效寬度,得到高的飽和區汲極電流(saturation-region drain current,Idsat),而對於高壓元件來說,較高的圓化效應,則可提升相關結構於整片晶圓中的均勻性,增加元件匹配性。 In addition, during subsequent oxidation processes (can be ground in CMP) (CMP process is performed before or after the process), because the silicon nitride layer in the low voltage region is thicker, and the silicon nitride layer in the high voltage region is thinner, the rounding effect of the trench in the low voltage region is less obvious, and the high voltage region The trench presents a more obvious rounding effect, and this different degree of rounding effect has exactly different contributions to the low-voltage component and the high-voltage component, respectively. For low-voltage components, the lower rounding effect can maintain the effective width of the element channel, and get a high saturation-region drain current (Idsat), while for high-voltage components, a higher roundness The effect can improve the uniformity of related structures in the whole wafer and increase the matching of components.
因此,本揭露在低壓區與高壓區製作出不同深度的溝槽的同時,又能提升低壓元件與高壓元件分別在結構及電性上的優勢。 Therefore, the present disclosure can simultaneously improve the structural and electrical advantages of low-voltage components and high-voltage components while making trenches of different depths in the low-voltage area and the high-voltage area.
雖然本發明已以數個較佳實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作任意之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 Although the present invention has been disclosed above with several preferred embodiments, it is not intended to limit the present invention. Any person with ordinary knowledge in the technical field can make any changes without departing from the spirit and scope of the present invention. And retouching, so the scope of protection of the present invention shall be determined by the scope of the attached patent application.
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| TW201118944A (en) * | 2009-11-13 | 2011-06-01 | Intersil Inc | A semiconductor process using mask openings of varying widths to form two or more device structures |
| TW201349310A (en) * | 2012-03-20 | 2013-12-01 | Taiwan Semiconductor Mfg | Semiconductor device and method of manufacturing same |
| TW201726316A (en) * | 2015-10-07 | 2017-08-01 | 3M新設資產公司 | Polishing pad and system and method of making and using same |
| TW201735260A (en) * | 2016-01-07 | 2017-10-01 | 瑞薩電子股份有限公司 | Semiconductor device and method of manufacturing same |
| TW201735178A (en) * | 2016-03-24 | 2017-10-01 | 台灣積體電路製造股份有限公司 | Method of forming a semiconductor device |
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2018
- 2018-03-30 TW TW107111231A patent/TWI658585B/en active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200529353A (en) * | 2004-02-26 | 2005-09-01 | Taiwan Semiconductor Mfg | Embedded semiconductor product with dual depth isolation regions |
| US20090302413A1 (en) * | 2008-06-05 | 2009-12-10 | Kang Dong-Woo | Semiconductor device and sti forming method therefor |
| TW201118944A (en) * | 2009-11-13 | 2011-06-01 | Intersil Inc | A semiconductor process using mask openings of varying widths to form two or more device structures |
| TW201349310A (en) * | 2012-03-20 | 2013-12-01 | Taiwan Semiconductor Mfg | Semiconductor device and method of manufacturing same |
| TW201726316A (en) * | 2015-10-07 | 2017-08-01 | 3M新設資產公司 | Polishing pad and system and method of making and using same |
| TW201735260A (en) * | 2016-01-07 | 2017-10-01 | 瑞薩電子股份有限公司 | Semiconductor device and method of manufacturing same |
| TW201735178A (en) * | 2016-03-24 | 2017-10-01 | 台灣積體電路製造股份有限公司 | Method of forming a semiconductor device |
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| TW201943070A (en) | 2019-11-01 |
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