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TWI556439B - Column iv transistors for pmos integration - Google Patents

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TWI556439B
TWI556439B TW101148097A TW101148097A TWI556439B TW I556439 B TWI556439 B TW I556439B TW 101148097 A TW101148097 A TW 101148097A TW 101148097 A TW101148097 A TW 101148097A TW I556439 B TWI556439 B TW I556439B
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source
layer
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liner
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TW201342614A (en
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葛蘭 葛雷斯
安拿 莫希
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英特爾股份有限公司
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Description

用於PMOS整合之第IV族電晶體 Group IV transistor for PMOS integration

本發明係關於用於PMOS整合之第IV族電晶體。 This invention relates to Group IV transistors for PMOS integration.

電路裝置(包括電晶體、二極體、電阻、電容、及形成於半導體基板上的其他被動或主動電子裝置)增加的效能一般為在設計、製造、及操作這些裝置的過程中所要考量的主要因素。舉例來說,在金屬氧化物半導體(MOS)電晶體半導體裝置(例如在互補式金屬氧化物半導體(CMOS)中所使用者)的設計及製造或形成過程中,通常欲最小化關聯於接觸(亦稱作外部電阻Rext)的寄生電阻。降低的Rext能使相同電晶體的設計有更高的電流。 The increased performance of circuit devices (including transistors, diodes, resistors, capacitors, and other passive or active electronic devices formed on a semiconductor substrate) is generally the primary consideration in the design, manufacture, and operation of such devices. factor. For example, in the design and fabrication or formation of metal oxide semiconductor (MOS) transistor semiconductor devices, such as those used in complementary metal oxide semiconductors (CMOS), it is often desirable to minimize the association with contact ( Also known as the parasitic resistance of the external resistor Rext). The reduced Rext enables a higher current for the design of the same transistor.

【發明內容及實施方式】 SUMMARY OF THE INVENTION AND EMBODIMENT

所揭露之技術係用以形成第IV族電晶體裝置,其具有高鍺濃度之源極/汲極區域,且相對傳統裝置表現出降低的寄生電阻。在某些範例具體實施例中,所產生之電晶體結構之源極/汲極區域之每一者包括薄的p型矽或鍺或矽鍺(SiGe)襯層,且源極/汲極材料的剩餘物為p型鍺或鍺合金,其包括例如鍺及錫,且具有至少80原子百分比的鍺含量(及20原子百分比或更低的其他成分,例如錫及/或其他適合的應變誘導物。在某些情況中,應變鬆弛的證據可於此富含鍺之層中觀察到,其包括錯位差排及 /或穿透差排。根據本發明,許多電晶體組態以及合適的製造程序將為顯而易見,其包括平面及非平面電晶體結構兩者(例如鰭式場效電晶體及奈米線電晶體)、以及應變及非應變通道結構。本發明技術特別適於實現p型MOS(PMOS)裝置,然而其他電晶體組態亦可受益。 The disclosed technology is used to form a Group IV transistor device having a source/drain region of high germanium concentration and exhibiting reduced parasitic resistance relative to conventional devices. In certain exemplary embodiments, each of the source/drain regions of the resulting transistor structure comprises a thin p-type germanium or germanium or germanium (SiGe) liner, and the source/drain material The remainder is a p-type tantalum or niobium alloy including, for example, tantalum and tin, and having a niobium content of at least 80 atomic percent (and other components of 20 atomic percent or less, such as tin and/or other suitable strain inducers) In some cases, evidence of strain relaxation can be observed in this layer rich in strontium, which includes misalignment and / or penetrate the difference row. Many transistor configurations and suitable fabrication procedures will be apparent in accordance with the present invention, including both planar and non-planar transistor structures (e.g., fin field effect transistors and nanowire transistors), as well as strained and unstrained channels. structure. The techniques of the present invention are particularly well suited for implementing p-type MOS (PMOS) devices, although other transistor configurations may also benefit.

概述 Overview

如前文所解釋,一般可藉由降低裝置外部電阻(Rext)而達成電晶體中增加的驅動電流。然而,PMOS電晶體效能為裝置內各種構件電阻的函數,如參照圖1所示。通道電阻R1可經由載子遷移率(其為通道內壓縮應變的函數)而調節。裝置的外部電阻Rext包括頂端電阻R2(頂端區域亦稱作源極/汲極延伸)、源極/汲極電阻R3、及接觸電阻R4(金屬至半導體)。所有這些分段電阻具有一材料構件(例如橫跨介面的能量屏障、載子濃度及遷移率)、幾何構件(例如長度、寬度等)、及動態電性負載構件(電流擁擠)。 As explained above, the increased drive current in the transistor can generally be achieved by lowering the external resistance (Rext) of the device. However, the PMOS transistor performance is a function of the resistance of the various components within the device, as shown in Figure 1. Channel resistance R1 can be adjusted via carrier mobility, which is a function of compressive strain within the channel. The external resistor Rext of the device includes a top resistor R2 (the top region is also referred to as a source/drain extension), a source/drain resistor R3, and a contact resistor R4 (metal to semiconductor). All of these segmented resistors have a material member (eg, energy barrier across the interface, carrier concentration and mobility), geometric components (eg, length, width, etc.), and dynamic electrical load members (current crowding).

因此,根據本發明某些具體實施例,以p型薄襯層及高含量的鍺(具有非常高的p型摻雜物濃度)來取代源極/汲極區域中的一般矽或SiGe合金材料係最小化外部電阻構件(R2、R3、及R4)。此外,藉由引入高度壓縮應變的材料,通道電洞遷移率係最大化或增加,因而降低通道電阻(R1)。降低的通道、頂端、源極/汲極及接觸電阻的靜影響為在一給定電壓下(相對臨界電壓Vt,即V- Vt)之改善的電晶體電流。 Thus, in accordance with certain embodiments of the present invention, a general germanium or SiGe alloy material in the source/drain region is replaced by a p-type thin liner and a high content of germanium (having a very high p-type dopant concentration). The external resistance members (R2, R3, and R4) are minimized. Furthermore, by introducing a highly compressive strained material, the channel hole mobility is maximized or increased, thereby reducing the channel resistance (R1). Reduced static channel, the top of the source / drain contact resistance and effect transistor current at a given voltage (relative to the threshold voltage V t, i.e., V- V t) of improvement.

在某些範例情況中,薄襯層為p型摻雜矽或鍺或SiGe合金,且一般小於總源極/汲極沉積層厚度的50%。剩餘的源極/汲極沉積層厚度一般大於總源極/汲極沉積層厚度的50%,且可例如為p型摻雜鍺或鍺合金,例如鍺:錫或鍺:錫:x(其中x例如為矽或其他微量的成分或基於製程/擴散的人為產物),具有至少80原子百分比的鍺及20原子百分比或更少的其他成分(例如錫及/或任何其他合適的應變誘導物及/或其他微量無意的成分)。在某些特殊的此類範例具體實施例中,源極/汲極襯層與高濃度鍺蓋層的厚度比為約1:5或更低(其中襯層構成總源極/汲極沉積層厚度之約20%或更低)。在某些此類範例情況中,襯層的厚度為一到數個單分子層。 In some exemplary cases, the thin liner is a p-type doped germanium or germanium or SiGe alloy and is typically less than 50% of the total source/drain deposited layer thickness. The remaining source/drain deposit layer thickness is typically greater than 50% of the total source/drain deposit thickness and may be, for example, a p-type doped germanium or tantalum alloy, such as germanium: tin or germanium: tin: x (where x such as ruthenium or other minor components or process/diffusion based artificial products) having at least 80 atomic percent bismuth and 20 atomic percent or less of other components (eg tin and/or any other suitable strain inducer and / or other traces of unintentional ingredients). In some particular such exemplary embodiments, the thickness ratio of the source/drain liner to the high concentration cap layer is about 1:5 or less (wherein the liner constitutes the total source/drain deposit) About 20% or less of the thickness). In some such example cases, the thickness of the liner is from one to several monolayers.

本技術可用以形成電晶體裝置於任何數量的裝置及系統。在某些具體實施例中,例如具有n型MOS(NMOS)及PMOS電晶體兩者的CMOS裝置,可由各種方式來達成選擇性。在一具體實施例中,舉例來說,在NMOS源極/汲極位置上的沉積可藉由在PMOS沉積過程中將NMOS區域屏蔽而避免。在其他具體實施例中,選擇性可包括自然選擇。舉例來說,雖然硼摻雜鍺生成於p型SiGe(或矽)源極/汲極上,但其並不生成於絕緣體表面(例如二氧化矽(SiO2)或氮化矽(SiN))上;其亦不生成於例如n型區域中的暴露重度磷摻雜矽上。 The present technology can be used to form a transistor device in any number of devices and systems. In some embodiments, such as CMOS devices having both n-type MOS (NMOS) and PMOS transistors, the selectivity can be achieved in a variety of ways. In one embodiment, for example, deposition at the NMOS source/drain locations can be avoided by shielding the NMOS regions during PMOS deposition. In other embodiments, the selectivity can include natural selection. For example, although boron-doped germanium is formed on the p-type SiGe (or germanium) source/drain, it is not formed on the surface of the insulator (for example, cerium oxide (SiO2) or tantalum nitride (SiN)); It is also not formed on exposed heavily phosphorus doped germanium, for example in an n-type region.

本文中所提供的技術可用以改善在任何數量的電晶體 結構及組態中的裝置電阻,其包括平面、平齊式或抬升式源極/汲極、非平面(例如奈米線電晶體及鰭式電晶體,例如雙閘極及三閘極電晶體結構)、以及應變及非應變通道結構。源極/汲極區域可為凹陷(例如使用蝕刻製程)或非凹陷(例如形成於基板的頂表面)。此外,電晶體裝置可選擇性地包括源極及汲極頂端區域,其係設計以例如降低電晶體的整體電阻,同時改善短通道效應(SCE),但此類頂端區域並非必需。電晶體裝置可更包括任何數量的閘極組態,例如多晶閘極、高k介電質金屬閘極、替換性金屬閘極(RMG)製程閘極、或任何其他閘極結構。任何數量的結構特徵可與本文所述的低電阻電晶體技術一同使用。 The techniques provided herein can be used to improve in any number of transistors Device resistance in structure and configuration, including planar, flush or raised source/drain, non-planar (eg, nanowire transistors and fin transistors, such as double gate and triple gate transistors) Structure), as well as strained and unstrained channel structures. The source/drain regions may be recessed (eg, using an etch process) or non-recessed (eg, formed on a top surface of the substrate). In addition, the transistor device can optionally include source and drain top regions designed to, for example, reduce the overall resistance of the transistor while improving short channel effects (SCE), but such tip regions are not required. The transistor device can further include any number of gate configurations, such as poly gates, high-k dielectric metal gates, replacement metal gate (RMG) process gates, or any other gate structure. Any number of structural features can be used with the low resistance transistor technology described herein.

根據某些具體實施例,垂直於閘極線或二次離子質譜儀(SIMS)輪廓的穿透式電子顯微鏡(TEM)橫截面可用以顯示結構中的鍺濃度,因為矽及SiGe的磊晶合金的輪廓可容易地與高鍺濃度輪廓區別。在某些此類含矽基板的情況中,藉由捨棄用以維持應變(無差排)源極/汲極區域的一般需求,源極/汲極填充材料及矽通道之間的晶格維度不匹配對純鍺而言可增加至少2X,鍺-錫合金可增加更多。在差排出現於富含鍺之蓋層的情況中,雖然不是100%的應變都能夠轉移至通道,但後沉積熱處理可用以提供明確的電晶體效能(在給定V-Vt處的電流)增益,即使是鬆弛薄膜(如本文所述),其係相對應變SiGe控制。將理解到,鬆弛一般係表示薄膜可能具有錯位差排, 但也可指包括差排形成及傳播的可塑鬆弛機制。彈性鬆弛的程序在非平面組態(例如FinFET(如三閘極)及奈米結構中變得可能,其中應變材料並未完全受到基板的限制。因此,平面內晶格常數具有更大的彈性來擴張或縮小,而不受基板的影響,且此程序不需錯位差排的形成及傳播。在本文中,鬆弛一詞係用於可塑鬆弛的意義上而非用於彈性鬆弛的意義上。使用錫或其他合適應變誘導物以形成本文所述之高濃度鍺蓋層的合金可選擇性地用以增加通道區域中的應變,藉此透過圖1中電阻R1的降低而更降低整體的裝置電阻。將理解到,雖然無缺陷的純鍺為理想的,但對例如矽基板或甚至具有50原子百分比鍺之SiGe基板上的沉積通常難以無缺陷地成長。然而,意外地,若比較一般完全應變SiGe層與具有某些缺陷(例如具有錯位及/或穿透差排)之此類富含鍺層的效能,則有缺陷的富含鍺層將表現較佳。將理解到,此結果一般並不直觀,因為其違背了傳統對薄膜的了解。無論如何,雖然本發明的某些具體實施例可能包括缺少晶格特徵(例如錯位差排、穿透差排及雙晶(缺陷係源於橫跨雙晶平面之晶格方位中的改變))的富含鍺蓋層,但其他具體實施例可包括具有一或多個此類特徵的富含鍺蓋層。 According to some embodiments, a transmissive electron microscope (TEM) cross section perpendicular to the gate line or secondary ion mass spectrometer (SIMS) profile can be used to show the germanium concentration in the structure because of the epitaxial alloy of germanium and SiGe. The contour can be easily distinguished from the sorghum concentration profile. In some such germanium-containing substrates, the lattice dimension between the source/drain fill material and the germanium channel is eliminated by discarding the general requirements for maintaining strain (no-difference) source/drain regions. The mismatch can increase at least 2X for pure tantalum and the tantalum-tin alloy can add more. In the case where the difference occurs in the ruthenium-rich cap layer, although not 100% of the strain can be transferred to the channel, the post-deposition heat treatment can be used to provide a clear transistor performance (current at a given VV t ) gain. Even a relaxed film (as described herein) is controlled relative to strained SiGe. It will be understood that relaxation generally means that the film may have a misalignment, but may also refer to a plastic relaxation mechanism that includes the formation and propagation of the difference. Elastic relaxation procedures are made possible in non-planar configurations such as FinFETs (eg, three-gate) and nanostructures, where the strained material is not completely limited by the substrate. Therefore, the in-plane lattice constant has greater flexibility. To expand or contract without being affected by the substrate, and the procedure does not require the formation and propagation of misalignment. In this paper, the term relaxation is used in the sense of plastic relaxation rather than in the sense of elastic relaxation. An alloy using tin or other suitable strain inducer to form the high concentration capping layer described herein can be selectively used to increase strain in the channel region, thereby reducing the overall device through the reduction of resistor R1 in FIG. It will be understood that although flawless pure germanium is desirable, deposition on a SiGe substrate such as a germanium substrate or even a 50 atomic percent germanium is generally difficult to grow without defects. However, unexpectedly, if relatively complete A strained SiGe layer with such a defect-rich layer with certain defects (eg, with misalignment and/or penetration difference) will perform better with a defective germanium-rich layer. It will be understood that this knot It is generally not intuitive as it is contrary to the traditional understanding of thin films. In any event, although certain embodiments of the invention may include the lack of lattice features (e.g., misalignment, penetration, and twins) The capping layer is derived from a change in the orientation of the lattice across the bimorph plane), but other embodiments may include a capping layer having one or more such features.

結構及方法學 Structure and methodology

圖2為根據本發明之一具體實施例之用以形成第IV族電晶體之方法。圖3A至3F根據本發明之各種具體實施例 描述實施圖2之方法所形成之範例結構。一或多個此類電晶體可形成於例如處理器、通訊晶片或記憶體晶片的製造中。此類積體電路可接著用於各種電子裝置及系統中。 2 is a diagram of a method for forming a Group IV transistor in accordance with an embodiment of the present invention. 3A to 3F in accordance with various embodiments of the present invention An example structure formed by implementing the method of FIG. 2 is described. One or more such transistors may be formed in the fabrication of, for example, a processor, a communication chip, or a memory chip. Such integrated circuits can then be used in a variety of electronic devices and systems.

範例方法包括形成一或多個閘極堆疊於半導體基板上,其中MOS裝置可形成於基板上(202)。MOS裝置可包含例如PMOS電晶體、或NMOS及PMOS電晶體兩者(例如CMOS裝置)。圖3A顯示所產生的一範例結構,其在此情況中包括形成於基板300上之PMOS電晶體。可看出閘極堆疊係形成於通道區域之上,且包括閘極介電層302、閘極電極304、及選擇性硬式遮罩306。間隙壁310係鄰接閘極堆疊而形成。 An exemplary method includes forming one or more gates stacked on a semiconductor substrate, wherein a MOS device can be formed on the substrate (202). The MOS device can include, for example, a PMOS transistor, or both NMOS and PMOS transistors (eg, CMOS devices). FIG. 3A shows an example structure produced which in this case includes a PMOS transistor formed on substrate 300. It can be seen that the gate stack is formed over the channel region and includes a gate dielectric layer 302, a gate electrode 304, and a selective hard mask 306. The spacers 310 are formed adjacent to the gate stack.

閘極介電質302可例如為任何適合的氧化物,例如二氧化矽(SiO2)或高k閘極介電質材料。舉例來說,高k閘極介電質材料的範例包括氧化鉿、氧化矽鉿、氧化鑭、氧化鋁鑭、氧化鋯、氧化矽鋯、氧化鉭、氧化鈦、氧化鈦鍶鋇、氧化鈦鋇、氧化鈦鍶、氧化釔、氧化鋁、氧化鉭鈧鉛、及鈮酸鋅鉛。在某些具體實施例中,當使用高k材料時,可在閘極介電層302上實行退火程序以改善其品質。在某些特定範例具體實施例中,高k閘極介電質302可具有範圍在5Å至100Å厚的厚度(例如10Å)。在其他具體實施例中,閘極介電質302可具有一單分子層氧化材料的厚度。一般來說,閘極介電質302的厚度應足以將閘極電極304與源極及汲極接觸電性地隔離。在某些具體實施例中,可於高k閘極介電質302上執行額外的程序,例如退 火程序,以改善高k材料的品質。 Gate dielectric 302 can be, for example, any suitable oxide such as hafnium oxide (SiO 2 ) or a high-k gate dielectric material. For example, examples of high-k gate dielectric materials include hafnium oxide, hafnium oxide, hafnium oxide, hafnium oxide, zirconium oxide, hafnium zirconium oxide, hafnium oxide, titanium oxide, titanium oxide, and titanium oxide. , titanium oxide bismuth, cerium oxide, aluminum oxide, bismuth oxide bismuth, and lead bismuth citrate. In some embodiments, when a high-k material is used, an annealing process can be performed on the gate dielectric layer 302 to improve its quality. In certain specific example embodiments, the high-k gate dielectric 302 can have a thickness ranging from 5 Å to 100 Å thick (eg, 10 Å). In other embodiments, the gate dielectric 302 can have a thickness of a monolayer oxide material. In general, the thickness of the gate dielectric 302 should be sufficient to electrically isolate the gate electrode 304 from the source and drain contacts. In some embodiments, additional procedures, such as annealing procedures, can be performed on the high-k gate dielectric 302 to improve the quality of the high-k material.

閘極電極304的材料可例如為多晶矽、氮化矽、碳化物、或金屬層(例如鎢、氮化鈦、鉭、氮化鉭),然而也可使用其他合適的閘極電極材料。在某些具體實施例中,閘極電極304材料可為稍後在替換性金屬閘極(RMG)製程移除的一犧牲層,其厚度在約10Å至500Å(例如100Å)的範圍。 The material of the gate electrode 304 can be, for example, polysilicon, tantalum nitride, carbide, or a metal layer (e.g., tungsten, titanium nitride, tantalum, tantalum nitride), although other suitable gate electrode materials can be used. In some embodiments, the gate electrode 304 material can be a sacrificial layer that is later removed in a replacement metal gate (RMG) process, having a thickness in the range of about 10 Å to 500 Å (eg, 100 Å).

選擇性閘極硬式遮罩層306可用以在製造過程中提供某些益處或使用,例如保護閘極電極304免於後續的蝕刻及/或佈植製程。硬式遮罩層306可使用一般的硬式遮罩材料形成,例如二氧化矽、氮化矽、及/或習知的絕緣體材料。 The selective gate hard mask layer 306 can be used to provide certain benefits or uses during the fabrication process, such as protecting the gate electrode 304 from subsequent etching and/or implantation processes. The hard mask layer 306 can be formed using a conventional hard mask material such as hafnium oxide, tantalum nitride, and/or conventional insulator materials.

閘極堆疊可由習知方式形成或使用任何合適的客製化技術形成(例如習知的圖案化製程以蝕刻除去部份的閘極電極及閘極介電質層,以形成圖2A所示的閘極堆疊)。閘極介電質302及閘極電極304材料之每一者可例如使用習知的沉積製程而形成,例如化學汽相沉積(CVD)、分子層沉積(ALD)、旋塗沉積(SOD)、或物理汽相沉積(PVD)。也可使用其他沉積技術,舉例來說,閘極介電質302及閘極電極304材料可為熱成長。根據本說明書內容可理解到,可使用任何數量的其他合適材料、幾何、或形成製程來實施本發明的具體實施例,以提供本文所述的低電阻電晶體裝置或結構。 The gate stack can be formed in a conventional manner or using any suitable customization technique (eg, a conventional patterning process to etch away portions of the gate electrode and gate dielectric layer to form the layer shown in FIG. 2A). Gate stack). Each of the gate dielectric 302 and gate electrode 304 materials can be formed, for example, using conventional deposition processes such as chemical vapor deposition (CVD), molecular layer deposition (ALD), spin-on deposition (SOD), Or physical vapor deposition (PVD). Other deposition techniques can also be used. For example, the gate dielectric 302 and gate electrode 304 materials can be thermally grown. It will be understood from the present disclosure that any number of other suitable materials, geometries, or forming processes can be used to practice embodiments of the present invention to provide a low resistance transistor device or structure as described herein.

間隙壁310可例如使用習知的材料而形成,例如氧化 矽、氮化矽、或其他合適的間隙壁材料。間隙壁310的寬度一般可基於所形成電晶體的設計需求而選擇。然而,根據某些具體實施例,間隙壁310的寬度並不受到源極及汲極頂端區域之形成所造成的設計限制,其假設在源極/汲極頂端區域有足夠高的p型摻雜鍺含量(例如摻雜硼的鍺)或SiGe合金襯層。 The spacers 310 can be formed, for example, using conventional materials, such as oxidation. Tantalum, tantalum nitride, or other suitable spacer material. The width of the spacers 310 can generally be selected based on the design requirements of the formed transistor. However, according to some embodiments, the width of the spacers 310 is not limited by the design of the source and drain top regions, which assumes a sufficiently high p-type doping in the source/drain tip regions. Niobium content (eg, boron doped germanium) or SiGe alloy liner.

可使用任何數量的合適基板來實施基板300,包括塊狀基板、絕緣層上半導體基板(XOI,其中X為半導體材料,例如矽、鍺、或富含鍺的矽)、及多層結構,包括在隨後閘極圖案化製程之前可形成鰭式或奈米線於其上的那些基板。在某些特定範例情況中,基板300為鍺或矽或SiGe塊狀基板、或是鍺或矽或SiGe於氧化物基板上。雖然本文描述了可形成基板300之材料的幾個範例,但可作為建立低電阻電晶體裝置於其上之基礎的其他合適材料也在所主張之本發明的精神及範疇。 The substrate 300 can be implemented using any number of suitable substrates, including a bulk substrate, an on-insulator semiconductor substrate (XOI, where X is a semiconductor material such as germanium, germanium, or germanium-rich germanium), and a multilayer structure, including Those substrates on which the fins or nanowires are formed can then be formed prior to the gate patterning process. In some specific example cases, substrate 300 is a tantalum or tantalum or SiGe bulk substrate, or tantalum or niobium or SiGe on an oxide substrate. Although several examples of materials from which substrate 300 can be formed are described herein, other suitable materials that can be used as a basis for establishing a low resistance transistor device are also within the spirit and scope of the claimed invention.

再參考圖3A,在形成一或多個閘極堆疊後,方法繼續某些選擇性的處理,在此範例具體實施例中包括蝕刻電晶體結構的源極/汲極區域(204),以及去除結構之任何NMOS源極/汲極區域的遮罩(若有的話)(206)。將理解到,源極/汲極區域不需為凹陷或以其他方式蝕刻。在此情況中,源極/汲極材料可形成於基板300上而不需任何蝕刻。根據某些具體實施例,雖然此非凹陷源極/汲極區域將不影響通道電阻,仍可實施具有薄襯層及高鍺含量蓋層的雙層源極/汲極結構,以提供低接觸電阻。更將理 解到,並非所有具體實施例都包括n型區域。在某些範例情況中,舉例來說,所製造的電路可僅包括PMOS裝置。在此類範例情況中,無n型源極/汲極區域要被去除遮罩。當出現n型區域,可使用任何適合的遮罩技術,以在p型處理過程中保護n型區域。 Referring again to FIG. 3A, after forming one or more gate stacks, the method continues with some optional processing, including in this exemplary embodiment a source/drain region (204) of the etched transistor structure, and removal A mask (if any) of any NMOS source/drain region of the structure (206). It will be appreciated that the source/drain regions need not be recessed or otherwise etched. In this case, the source/drain material can be formed on the substrate 300 without any etching. According to some embodiments, although the non-recessed source/drain regions will not affect the channel resistance, a dual layer source/drain structure with a thin liner and a high germanium cap layer can be implemented to provide low contact. resistance. More reasonable It is understood that not all embodiments include an n-type region. In some example cases, for example, the fabricated circuit may include only PMOS devices. In such an example case, no n-type source/drain regions are to be masked. When an n-type region is present, any suitable masking technique can be used to protect the n-type region during p-type processing.

在源極/汲極區域被蝕刻的範例具體實施例中,產生源極/汲極凹洞312/314,如圖3A所示。凹洞有效地定義源極/汲極區域的位置。可進一步看出,基板300不僅已被蝕刻而產生源極/汲極凹洞312/314,也產生了底切閘極介電質302之其個別的頂端區域312A/314A。凹洞312/314及其個別的頂端區域312A/314A可使用任何數量的合適製程而以習知方式形成。在某些範例情況中,這包括離子佈植以高度地摻雜鄰接閘極堆疊之部份的基板300,接著退火以驅使摻雜物更進入基板300,以改善預期源極/汲極區域的蝕刻速率。接著,可使用乾蝕刻製程來蝕刻基板300的摻雜區域,以形成凹洞312/314及其個別的頂端區域312A/314A。在完成乾蝕刻製程後,可例如使用濕蝕刻以清潔及進一步地蝕刻凹洞312/314及其個別的頂端區域312A/314A。此類濕蝕刻可使用習知或客製的濕蝕刻化學劑而實行,其可用以移除污染物,例如碳、氟、氟氯碳、及氧化物(例如氧化矽),以提供後續製程可實施於其上的乾淨表面。此外,假設一單晶矽表面,濕蝕刻也可用以沿<111>及<001>結晶面來移除薄的部份基板300,以提供平滑表面,其中高品質磊晶沉積可發生於其 上。在某些範例情況中,被蝕刻移除之薄的部份基板300可例如高達5奈米厚,且可移除殘留的污染物。濕蝕刻一般會造成凹洞312/314及其個別頂端區域312A/314A的邊緣沿著<111>及<001>結晶面。 In an exemplary embodiment where the source/drain regions are etched, source/drain recesses 312/314 are created, as shown in Figure 3A. The cavity effectively defines the location of the source/drain region. It can further be seen that the substrate 300 has not only been etched to create source/drain recesses 312/314, but also individual top end regions 312A/314A of the undercut gate dielectric 302. The dimples 312/314 and their individual top end regions 312A/314A can be formed in a conventional manner using any number of suitable processes. In some exemplary cases, this includes ion implantation to highly dope the substrate 300 adjacent the portion of the gate stack, followed by annealing to drive the dopant further into the substrate 300 to improve the desired source/drain region. Etching rate. Next, a dry etch process can be used to etch the doped regions of the substrate 300 to form the dimples 312/314 and their individual top regions 312A/314A. After the dry etch process is completed, the wet etch can be used, for example, to clean and further etch the recesses 312/314 and their individual top end regions 312A/314A. Such wet etching can be carried out using conventional or custom wet etching chemistries that can be used to remove contaminants such as carbon, fluorine, chlorofluorocarbons, and oxides (eg, cerium oxide) to provide subsequent processes. A clean surface applied to it. In addition, assuming a single crystal germanium surface, wet etching can also be used to remove the thin portion of the substrate 300 along the <111> and <001> crystal faces to provide a smooth surface in which high quality epitaxial deposition can occur. on. In some exemplary cases, the thin portion of the substrate 300 that is etched away may be, for example, up to 5 nanometers thick and may remove residual contaminants. Wet etching generally results in the edges of the recesses 312/314 and their individual tip regions 312A/314A along the <111> and <001> crystal faces.

進一步參考圖2,方法繼續沉積p型矽或鍺或SiGe襯層313/315於p型源極/汲極區域(208),且接著在襯層313/315之上沉積p型鍺或鍺合金於p型源極/汲極區域中(210)。這些沉積之每一者可例如使用選擇性磊晶沉積而實現,然而可使用任何合適的沉積製程。參考圖3B可看出,p型矽或鍺或SiGe襯層313/315係沉積於凹洞312/314及其個別頂端區域312A/314A中。此外,如圖3C所示,凹洞312/314及其個別頂端區域312A/314A係進一步地填充以提供p型鍺或鍺合金的厚蓋層318/320於p型襯層313/315之上。將理解到,p型摻雜物的範例包括例如硼、鎵、或任何其他合適的p型摻雜物,且所主張之本發明並不意欲受限於任何特定一種。 With further reference to FIG. 2, the method continues to deposit a p-type germanium or germanium or SiGe liner 313/315 in the p-type source/drain region (208), and then deposit a p-type germanium or germanium alloy over the liner 313/315. In the p-type source/drain region (210). Each of these deposits can be achieved, for example, using selective epitaxial deposition, although any suitable deposition process can be used. As can be seen with reference to Figure 3B, a p-type germanium or germanium or SiGe liner 313/315 is deposited in the recesses 312/314 and their individual tip regions 312A/314A. In addition, as shown in FIG. 3C, the recesses 312/314 and their individual top end regions 312A/314A are further filled to provide a p-type tantalum or niobium alloy thick cap layer 318/320 over the p-type liner 313/315. . It will be appreciated that examples of p-type dopants include, for example, boron, gallium, or any other suitable p-type dopant, and the claimed invention is not intended to be limited to any particular one.

根據基板300為矽或SiGe塊狀基板、或絕緣層上半導體基板(XOI,其中X為矽或SiGe)之某些特定範例具體實施例,源極及汲極凹洞312/314及其個別頂端區域312A/314A係以原位硼摻雜之矽或SiGe填充,藉以形成對應的襯層313/315,並接著以原位硼摻雜之鍺或富含鍺的合金進一步填充,以形成蓋層318/320。在基板300為鍺塊狀基板或絕緣層上鍺基板的其他範例具體實施例中,源極及汲極凹洞312/314及其個別頂端區域312A/314A可 以原位硼摻雜之富含鍺的合金(例如鍺:錫)填充,藉以形成對應的襯層313/315,並接著以原位硼摻雜之富含鍺合金進一步填充,以形成蓋層318/320。根據本說明書內容可理解到,襯層313/315及蓋層318/320的個別鍺或p型摻雜物濃度可根據例如以下因素而變化:基板300的組成、晶格匹配/相容性之漸次變化的使用、以及總源極/汲極沉積的整體理想厚度。根據本說明書內容可理解到,可實施許多材料系統及p型摻雜組態。 According to certain specific embodiments of the substrate 300 being a germanium or SiGe bulk substrate, or a semiconductor substrate on an insulating layer (XOI, where X is germanium or SiGe), the source and drain recesses 312/314 and their respective top ends The regions 312A/314A are filled with in-situ boron doped germanium or SiGe to form corresponding liners 313/315, and then further filled with in-situ boron doped germanium or germanium-rich alloys to form a cap layer. 318/320. In other exemplary embodiments in which the substrate 300 is a germanium-like substrate or a germanium-on-insulator substrate, the source and drain recesses 312/314 and their individual top regions 312A/314A may Filled with an in-situ boron doped yttrium-rich alloy (eg, yttrium: tin) to form a corresponding liner 313/315, and then further filled with an in-situ boron doped yttrium-rich alloy to form a cap layer 318/320. It will be understood from the present disclosure that the individual germanium or p-type dopant concentrations of the liners 313/315 and cap layers 318/320 can vary depending on, for example, the composition of the substrate 300, lattice matching/compatibility The use of gradual changes and the overall desired thickness of the total source/drain deposition. As can be appreciated from the description, many material systems and p-doped configurations can be implemented.

舉例來說,在具有矽或鍺或SiGe基板的某些範例具體實施例中,襯層313/315的鍺含量可在20原子百分比至100原子百分比的範圍中,且硼濃度在1E20cm-3至2E21cm-3的範圍中。根據某些具體實施例,為避免晶格與底下的含矽基板不匹配,襯層313/315的鍺濃度可漸次變化。舉例來說,在一此類具體實施例中,襯層313/315可為一漸次變化的硼摻雜SiGe層,其具有從相容於底下矽或SiGe基板300之一基準濃度漸次變化至100原子百分比(或接近100原子百分比,例如超過90原子百分比或95原子百分比或98原子百分比)的鍺濃度。在一特定的此類具體實施例中,鍺濃度的範圍從40原子百分比或更低到超過98原子百分比。襯層313/315內的硼濃度可例如固定在一高位準或者可漸次變化。舉例來說,襯層313/315內的硼濃度可從等於或相容於底下基板300之一基準濃度漸次變化到一理想高濃度(例如,超過1E20cm-3、2E20cm-3、或5E20cm-3)而。在某些此類具體實施例中 ,硼摻雜鍺蓋層318/320具有超過1E20cm-3(例如超過2E20cm-3或2E21cm-3或更高)的硼濃度。此蓋層318/320中的硼濃度可以類似於參照襯層313/315所描述的方式漸次變化。更一般地來說,硼濃度可依需要調整,以提供所需的傳導率等級,其可根據本說明書內容而理解。舉例來說,蓋層318/320的鍺濃度可固定於100原子百分比。或者,根據本說明書內容可理解到,蓋層318/320的鍺濃度可從低至高濃度(例如從20原子百分比至100原子百分比)漸次變化,以考量到襯層313/315與蓋層318/320之理想峰值鍺濃度之間的晶格不匹配。在其他具體實施例中,蓋層318/320可由鍺合金來實施,其中混合物可例如為高達80原子百分比的鍺以及高達20原子百分比的合金材料(其在某些具體實施例中為錫)。需注意,將理解到,錫濃度(或其他合金材料)也可漸次變化。在一此情況中,當蓋層318/320中的錫濃度範圍在3至8原子百分比,通道應變將增加(蓋層318/320之平衡原子百分比實質為鍺及任何梯度材料)。儘管鬆弛,晶格常數仍舊相對為大,且能夠施予足夠的應變於鄰接的通道。其他合適的錫濃度為顯而易見,其他合適的應變誘導物亦是。 For example, in certain exemplary embodiments having a ruthenium or iridium or SiGe substrate, the ruthenium content of the liner layer 313/315 can range from 20 atomic percent to 100 atomic percent, and the boron concentration can range from 1E20 cm -3 to In the range of 2E21cm -3 . According to certain embodiments, the germanium concentration of the liners 313/315 may be gradually changed to avoid mismatching of the crystal lattice with the underlying germanium-containing substrate. For example, in one such embodiment, the liner 313/315 can be a progressively varying boron-doped SiGe layer having a gradual change from one of the baseline concentrations compatible with the underlying germanium or SiGe substrate 300 to 100. A concentration of germanium (or close to 100 atomic percent, such as more than 90 atomic percent or 95 atomic percent or 98 atomic percent). In a particular such embodiment, the cerium concentration ranges from 40 atomic percent or less to over 98 atomic percent. The concentration of boron in the liners 313/315 can be fixed, for example, at a high level or can be varied gradually. For example, the concentration of boron in the liner 313/315 can be gradually changed from a reference concentration equal to or compatible with one of the underlying substrates 300 to a desired high concentration (eg, over 1E20 cm -3 , 2E20 cm -3 , or 5E20 cm -3 ) )and. In certain such embodiments, the boron-doped capping layer 318/320 has a boron concentration in excess of 1E20 cm" 3 (eg, in excess of 2E20 cm" 3 or 2E21 cm" 3 or higher). The boron concentration in this cap layer 318/320 can be varied progressively in a manner similar to that described with reference to liner 313/315. More generally, the boron concentration can be adjusted as needed to provide the desired conductivity level, which can be understood in light of the present disclosure. For example, the germanium concentration of the cap layer 318/320 can be fixed at 100 atomic percent. Alternatively, it will be understood from the present disclosure that the germanium concentration of the cap layer 318/320 can be gradually changed from low to high concentrations (eg, from 20 atomic percent to 100 atomic percent) to account for the liner 313/315 and the cap layer 318/ The lattice of the ideal peak 锗 concentration of 320 does not match. In other embodiments, the cap layer 318/320 can be implemented from a tantalum alloy, wherein the mixture can be, for example, up to 80 atomic percent of tantalum and up to 20 atomic percent of alloy material (which in some embodiments is tin). It should be noted that it will be appreciated that the tin concentration (or other alloy material) may also vary gradually. In this case, when the tin concentration in the cap layer 318/320 ranges from 3 to 8 atomic percent, the channel strain will increase (the equilibrium atomic percentage of the cap layer 318/320 is substantially 锗 and any gradient material). Despite the relaxation, the lattice constant is still relatively large and can impart sufficient strain to adjacent channels. Other suitable tin concentrations are readily apparent, as are other suitable strain inducers.

需注意,使用純鍺基板下,襯層313/315可由鍺來實現且不需漸次變化。在某些此類情況中,襯層313/315的鍺濃度可為固定(例如100原子百分比)且蓋層318/320可由鍺合金(例如鍺:錫、或前述之其他合適的鍺合金)來實現。如前文所解釋,蓋層318/320中的鍺濃度(或錫 或其他合金材料濃度)可漸次變化以產生理想的通道應變。在某些此類的情況中,需進一步注意,鍺襯層313/315可有效地與鍺合金蓋層318/320整合或可為源極/汲極區域沉積之一無法偵測的組件。 It should be noted that under a pure tantalum substrate, the liners 313/315 can be realized by tantalum without gradual changes. In some such cases, the germanium concentration of the liners 313/315 can be fixed (eg, 100 atomic percent) and the cap layer 318/320 can be made of a tantalum alloy (eg, tin: tin, or other suitable tantalum alloys as previously described). achieve. As explained above, the germanium concentration in the cap layer 318/320 (or tin) Or other alloy material concentrations) can be gradually varied to produce the desired channel strain. In some such cases, it is further noted that the tantalum liner 313/315 can be effectively integrated with the tantalum alloy cap layer 318/320 or can be an undetectable component of the source/drain region deposition.

有關漸次變化,需注意到本文中所使用的相容性並不需要在濃度等級上重疊(舉例來說,底下基板300的鍺濃度可為0至20原子百分比,且襯層313/315的初始鍺濃度可為30至40原子百分比)。此外,如本文所使用,有關濃度等級的「固定」一詞意指相對不變的濃度等級(例如層中最低濃度等級為在該層內之最高濃度等級的10%)。在更一般的意義上,固定的濃度等級係意指缺乏故意的漸次變化濃度等級。 Regarding the gradual change, it is noted that the compatibility used herein does not need to overlap at the concentration level (for example, the ruthenium concentration of the bottom substrate 300 may be 0 to 20 atomic percent, and the initial of the liner 313/315 The cerium concentration can be from 30 to 40 atomic percent). Moreover, as used herein, the term "fixed" with respect to a concentration level means a relatively constant concentration level (eg, the lowest concentration level in the layer is 10% of the highest concentration level within the layer). In a more general sense, a fixed concentration level means a lack of intentional gradual change in concentration levels.

襯層313/315及蓋層318/320的厚度也可隨以下因素而變化:基板300的組成、晶格匹配/相容性之漸次變化的使用、以及總源極/汲極沉積的整體理想厚度。一般來說,在襯層313/315組態為具有漸次變化的鍺含量以提供與不具有或具有低鍺含量之基板300的相容性的情況下,襯層313/315可較厚。在其他情況中,當基板300為鍺基板或者含有相對高濃度的鍺,襯層313/315不需漸次變化,因此可相對較薄(例如一至數個單分子層)。在其他情況中,當基板300不含或具有相對低的鍺含量,襯層313/315可由相對薄的矽層或低鍺含量材料層來實施,且蓋層318/320的鍺含量可依相容性所需而漸次變化。在任何此類情況中,襯層313/315一般構成少於50%的總源極/ 汲極沉積層厚度,且剩餘的源極/汲極沉積層厚度一般大於50%的總源極/汲極沉積層厚度。根據某些此類範例具體實施例,當襯層313/315未漸次變化,襯層313/315對蓋層318/320的厚度比為約2:5或更低(即襯層構成總源極/汲極沉積層厚度的約40%或更低)。在某些特定的此類具體實施例中,襯層313/315對蓋層318/320的厚度比為約1:5或更低(即襯層構成總源極/汲極沉積層厚度的約20%或更低)。在一此類特定範例情況中,襯層313/315的厚度在1至數個單分子層到約10奈米的範圍中,且總源極/汲極沉積層厚度在50至500奈米的範圍。根據本說明內容可清楚有許多源極/汲極襯層及蓋層幾何及材料組態。 The thickness of liners 313/315 and cap layer 318/320 may also vary depending on the composition of substrate 300, the gradual change in lattice matching/compatibility, and the overall ideality of total source/drain deposition. thickness. In general, the liners 313/315 may be thicker where the liners 313/315 are configured to have a gradually varying tantalum content to provide compatibility with the substrate 300 that does not have or have a low tantalum content. In other cases, when the substrate 300 is a tantalum substrate or contains a relatively high concentration of tantalum, the liners 313/315 need not be gradually changed, and thus may be relatively thin (e.g., one to several monolayers). In other cases, when the substrate 300 does not contain or has a relatively low germanium content, the liners 313/315 may be implemented from a relatively thin layer of tantalum or low tantalum content material, and the tantalum content of the cap layer 318/320 may be phase dependent. Capacitive needs and gradually change. In any such case, the liners 313/315 generally constitute less than 50% of the total source / The thickness of the drain layer is reduced, and the thickness of the remaining source/drain layer is generally greater than 50% of the total source/drain thickness. According to certain such exemplary embodiments, when the liners 313/315 are not progressively changed, the thickness ratio of the liners 313/315 to the cap layer 318/320 is about 2:5 or less (ie, the liner constitutes the total source) / The thickness of the drain layer is about 40% or less). In certain particular such embodiments, the thickness ratio of the liner layer 313/315 to the cap layer 318/320 is about 1:5 or less (ie, the thickness of the liner constitutes the total source/drain deposition layer thickness). 20% or less). In one such particular example case, the thickness of the liner 313/315 is in the range of 1 to several monolayers to about 10 nanometers, and the total source/drain deposition layer thickness is between 50 and 500 nanometers. range. It is clear from this description that there are many source/drain lining and cap geometries and material configurations.

根據本說明書內容將理解到,本發明具體實施例可實施任何數量的其他電晶體特徵。舉例來說,通道可為應變或非應變,且源極/汲極區域可包括或不包括形成於對應源極/汲極區域及通道區域之間的頂端區域。從這個意義來說,不論電晶體結構具有應變或非應變通道、或具有源極/汲極頂端區域或不具源極/汲極頂端區域,都與本發明各種具體實施例不特別相關,且所主張之本發明並不意欲受限於任何特定之此類結構特徵。相反地,任何數量的電晶體結構及種類,特別是那些具有p型或n型及p型兩者之源極/汲極電晶體區域的結構,將從使用具有本文所述之襯層及高鍺濃度蓋層之雙層源極/汲極組態而受益。 It will be understood from the description herein that embodiments of the invention may implement any number of other transistor features. For example, the channel can be strained or unstrained, and the source/drain regions can include or exclude top regions formed between the corresponding source/drain regions and the channel regions. In this sense, regardless of whether the transistor structure has strained or unstrained channels, or has a source/drain top region or no source/drain top region, it is not particularly relevant to various embodiments of the present invention, and The invention claimed is not intended to be limited to any particular such structural feature. Conversely, any number of transistor structures and types, particularly those having a source/dip transistor region of either p-type or n-type and p-type, will have the lining and height described herein. Benefit from the double layer source/dip configuration of the germanium concentration cap.

可使用CVD製程或其他合適的沉積技術來進行沉積 (208及210)。舉例來說,208及210的沉積可於CVD反應器、LPCVD反應器、或超高真空CVD(UHVCVD)中實行。在某些範例情況中,反應器溫度可例如落於600℃至800℃之間,且反應器壓力可例如落於1至760托耳之間。載子氣體可例如包括氫或氦,其具有適當的流速,例如在10至50 SLM之間。在某些特定具體實施例中,可使用鍺源前驅物氣體(例如在H2中稀釋的GeH4(舉例來說,GeH4可稀釋為1-20%))來實行沉積。舉例來說,稀釋的GeH4可在1%濃度及流速範圍在50至300 SCCM之間使用。針對硼的原位摻雜,可使用稀釋的B2H6(例如B2H6可在H2中稀釋為1-20%)。舉例來說,稀釋的B2H6可在3%濃度及流速範圍在10至100 SCCM之間使用。在某些範例情況中,可加入蝕刻劑,以增加沉積的選擇性。舉例來說,可加入流速範圍在例如50至300 SCCM之間的HCI或Cl2Deposition (208 and 210) can be performed using a CVD process or other suitable deposition technique. For example, the deposition of 208 and 210 can be performed in a CVD reactor, an LPCVD reactor, or ultra high vacuum CVD (UHVCVD). In certain exemplary cases, the reactor temperature may, for example, fall between 600 °C and 800 °C, and the reactor pressure may, for example, fall between 1 and 760 Torr. The carrier gas may, for example, comprise hydrogen or helium with a suitable flow rate, for example between 10 and 50 SLM. Embodiment may be used germanium source precursor gas (e.g., diluted in 2 H GeH 4 (for example, GeH 4 may be diluted to 20%)) is deposited to implement in certain specific embodiments. For example, dilute GeH 4 may be used between 50 and 300 SCCM and the flow rate at a 1% concentration range. For in situ doping of boron, diluted B 2 H 6 can be used (eg, B 2 H 6 can be diluted to 1-20% in H 2 ). For example, the diluted B 2 H 6 may be used between 10 and 100 SCCM of 3% concentration and flow rate range. In some exemplary cases, an etchant may be added to increase the selectivity of the deposition. For example, HCI or Cl 2 having a flow rate ranging, for example, between 50 and 300 SCCM can be added.

根據本說明書內容,源極/汲極雙層結構上的各種變化將為顯而易見。舉例來說,在某些具體實施例中,襯層313/315係由磊晶沉積的硼摻雜SiGe所實施,其可為一或多層且具有範圍在30至70原子百分比或更高的鍺濃度。如前文所解釋,此SiGe襯層的鍺濃度可為固定或漸次變化,以從基準(接近基板300)增加至高位準(例如超過50原子百分比,接近蓋層318/320之鍺濃度的基準濃度,鍺持續漸次變化至100原子百分比)。在某些此類具體實施例中的硼濃度可超過1E20 cm-3,例如高於5E20 cm-3或 2E21 cm-3,且亦可漸次變化以從接近基板300的基準增加至高位準(例如超過1E20 cm-3或2E20 cm-3或3E20 cm-3等,接近蓋層318/320)。在硼摻雜SiGe襯層313/315的鍺濃度為固定的具體實施例中,可使用薄的漸次變化緩衝以較佳地連接襯層313/315與硼摻雜蓋層318/320。需注意,此緩衝可為一中間層或整合至蓋層318/320的成分中。為了此揭露的目的,此緩衝可視為蓋層318/320的部份。根據某些特定範例具體實施例,硼摻雜SiGe沉積層(或層的集合)313/315的厚度可例如在數單分子層至50奈米的範圍,而層(或層的集合)318/320可具有範圍在例如51至500奈米的厚度,然而其他具體實施例可具有其他的襯層及蓋層厚度,其根據本說明書內容將為顯而易見的。在某些具體實施例中,需注意到凹洞312/314可在循環的沉積-蝕刻製程過程中產生於間隙壁底下,且這些凹洞312/314也可由磊晶蓋層回填(其可例如具有與硼摻雜鍺蓋層318/320相同的成分)。 Various variations in the source/drain double layer structure will be apparent from the description herein. For example, in some embodiments, the liners 313/315 are implemented by epitaxially deposited boron-doped SiGe, which may be one or more layers and have a range of 30 to 70 atomic percent or greater. concentration. As explained above, the germanium concentration of the SiGe liner can be fixed or gradually varied to increase from the reference (close to substrate 300) to a high level (eg, over 50 atomic percent, close to the reference concentration of the germanium concentration of cap layer 318/320). , 锗 continues to gradually change to 100 atomic percent). The boron concentration in certain such embodiments may exceed 1E20 cm -3 , such as above 5E20 cm -3 or 2E21 cm -3 , and may also gradually change to increase from a baseline close to substrate 300 to a high level (eg, More than 1E20 cm -3 or 2E20 cm -3 or 3E20 cm -3, etc., close to the cover layer 318/320). In a particular embodiment where the germanium concentration of the boron-doped SiGe liner 313/315 is fixed, a thin incremental change buffer can be used to better connect the liner 313/315 with the boron doped cap layer 318/320. It should be noted that this buffer can be an intermediate layer or integrated into the composition of the cap layer 318/320. For the purposes of this disclosure, this cushioning can be considered as part of the cover layer 318/320. According to certain specific example embodiments, the thickness of the boron-doped SiGe deposition layer (or collection of layers) 313/315 may range, for example, from a few monolayers to 50 nanometers, while the layers (or collections of layers) 318/ 320 may have a thickness ranging, for example, from 51 to 500 nanometers, although other embodiments may have other liners and cover thicknesses, as will be apparent from the description herein. In some embodiments, it is noted that the cavities 31 / 314 may be created under the spacer during the cyclic deposition-etch process, and the recesses 31 / 314 may also be backfilled by the epitaxial cap layer (which may for example It has the same composition as the boron-doped capping layer 318/320).

鑒於本說明書內容將更理解到,高鍺濃度(例如超過50原子百分比且高達純鍺)及高硼濃度(例如超過1E20cm-3)的組合(如本文所討論)可用以主要地實現在PMOS電晶體裝置中之源極及汲極區域(圖1中的R3)以及其個別的頂端區域(圖1中的R2)中較高的傳導率。此外,如前文所解釋,因為相對於低鍺成分層,硼擴散在高鍺成分層中係足夠地被抑制,儘管在沉積應力源薄膜中的高摻雜濃度,當相較於具有相同p型摻雜物種類及摻雜 等級之較低鍺成分層,可以後續的熱退火實現較少不利的SCE退化。在接觸表面的較高鍺濃度(其造成圖1中的較低接觸電阻R4)也致能了阻障高度降低。在某些範例具體實施例中,可使用超過80原子百分比以及高達純鍺(100原子百分比)的鍺濃度來達成此益處。然而,需注意到純鍺並非必須。舉例來說,某些具體實施例可具有超過90或95原子百分比(但不是純的)的鍺濃度。 As will become more fully understood in the present specification, combinations of sorghum concentrations (eg, over 50 atomic percent and up to pure ruthenium) and high boron concentrations (eg, over 1E20 cm -3 ) (as discussed herein) can be used primarily to achieve PMOS power. The higher conductivity in the source and drain regions (R3 in Figure 1) and their individual tip regions (R2 in Figure 1) in the crystal device. Further, as explained above, since boron diffusion is sufficiently suppressed in the sorghum composition layer with respect to the low bismuth composition layer, although the high doping concentration in the deposition stressor film is compared with having the same p type The lower dopant composition of the dopant species and doping level allows for subsequent thermal annealing to achieve less adverse SCE degradation. The higher germanium concentration at the contact surface, which causes the lower contact resistance R4 in Figure 1, also enables the barrier height to decrease. In certain exemplary embodiments, this benefit can be achieved using a cerium concentration of more than 80 atomic percent and up to pure cerium (100 atomic percent). However, it is important to note that pure cockroaches are not required. For example, certain embodiments may have a cerium concentration of more than 90 or 95 atomic percent (but not pure).

參考圖3C可進一步看出,在相對靠近通道區域中形成源極/汲極頂端318A/320A亦施予較大的流體靜力應力於通道上。此應力增加通道內的應變,藉此而增加通道中的遷移率並增加驅動電流。在含矽基板的情況中,此應力可進一步藉由增加源極/汲極頂端318A/320A的鍺濃度而放大,而在鍺基板的情況中可藉由增加錫濃度而放大。這是對擴散為基礎的製程的改善,其中頂端區域一般不包括應變於通道區域上。 As can be further seen with reference to Figure 3C, the formation of source/drain terminals 318A/320A in relatively close channel regions also imparts greater hydrostatic stress on the channels. This stress increases the strain in the channel, thereby increasing the mobility in the channel and increasing the drive current. In the case of a germanium-containing substrate, this stress can be further amplified by increasing the germanium concentration of the source/drain tip 318A/320A, and in the case of a germanium substrate by increasing the tin concentration. This is an improvement to the diffusion-based process where the tip region generally does not include strain on the channel region.

一旦根據本發明具體實施例填充源極及汲極區域,可實行各種習知的MOS製程以完成MOS電晶體的製造,例如替代性閘極氧化物製程、替代性金屬閘極製程、退火、及矽化金屬沉積製程,其可進一步更改電晶體及/或提供必需的電性互連。舉例來說,在源極/汲極區域與其個別頂端的磊晶沉積後,進一步參考圖2,方法可繼續從n型區域移除任何遮罩並依所需處理這些區域(若可應用,例如在CMOS製程)(212),且沉積絕緣體於電晶體之上(214),且接著以一般的做法平面化該絕緣體層。絕緣 體層可使用習知適用於積體電路結構之絕緣體層的材料,例如低k介電質(絕緣體)材料。此絕緣體材料包括例如氧化物(如二氧化矽(SiO2)及碳摻雜氧化物(CDO))、氮化矽、有機聚合物(例如八氟環丁烷、聚四氟乙烯)、氟矽玻璃(FSG)、及有機矽酸鹽(例如半矽氧烷、矽氧烷、或有機矽酸鹽玻璃)。在某些範例組態中,絕緣體層可包括細孔或其他孔洞,以進一步降低其介電質常數。圖3D描述沉積絕緣體層322並接著將其平面化至硬式遮罩306的一範例。 Once the source and drain regions are filled in accordance with embodiments of the present invention, various conventional MOS processes can be implemented to complete the fabrication of MOS transistors, such as alternative gate oxide processes, alternative metal gate processes, annealing, and A deuterated metal deposition process that can further modify the transistor and/or provide the necessary electrical interconnections. For example, after epitaxial deposition of the source/drain regions and their individual tips, with further reference to Figure 2, the method can continue to remove any mask from the n-type region and process the regions as needed (if applicable, for example In a CMOS process (212), an insulator is deposited over the transistor (214), and then the insulator layer is planarized in a conventional manner. insulation As the bulk layer, a material suitable for an insulator layer of an integrated circuit structure, such as a low-k dielectric (insulator) material, can be used. The insulator material includes, for example, oxides (such as cerium oxide (SiO2) and carbon-doped oxide (CDO)), tantalum nitride, organic polymers (such as octafluorocyclobutane, polytetrafluoroethylene), fluorocarbon glass. (FSG), and organic bismuth salts (such as hemioxanes, decanes, or organosilicate glasses). In some example configurations, the insulator layer may include pores or other holes to further reduce its dielectric constant. FIG. 3D depicts an example of depositing an insulator layer 322 and then planarizing it to a hard mask 306.

參考圖3D'可進一步看出,本發明的某些具體實施例使用一替代性金屬閘極製程,且方法可包括使用習知的蝕刻製程移除閘極堆疊(包括高k閘極介電質層302、犧牲閘極電極304、及硬式遮罩層306)。在另一實施中,僅移除犧牲閘極304。若移除閘極介電質302,則方法可包括沉積新的閘極介電質層至溝渠開口。在此可使用任何合適的高k介電質材料(如前文所描述),例如氧化鉿。也可使用相同的沉積製程。可使用閘極介電質302的取代,以例如解決在乾式及濕式蝕刻製程的應用過程中發生在最初閘極介電質層的任何損壞,及/或以高k或其他理想的閘極介電質材料來取代低k或犧牲介電質材料。方法接著可繼續沉積金屬閘極電極層至溝渠中及閘極介電質層之上。可使用習知的金屬沉積製程以形成金屬閘極電極層,例如CVD、ALD、PVD、無電電鍍、或電鍍。金屬閘極電極層可包括例如p型功函數金屬,例如釕、鈀、鈷、鎳、 及導電金屬氧化物(例如氧化釕)。在某些範例組態中,可沉積二或更多金屬閘極電極層。舉例來說,可沉積功函數金屬,接著沉積合適的金屬閘極電極填充金屬,例如鋁。圖3D'描述根據本發明一具體實施例之一範例高k閘極介電質層324以及金屬閘極電極326,其已沉積至溝渠開口中。需注意,若需要的話,此RMG程序可在製程中的不同時間點實行。 Referring further to FIG. 3D', it can be further seen that certain embodiments of the present invention use an alternative metal gate process, and the method can include removing the gate stack (including high-k gate dielectrics using conventional etching processes). Layer 302, sacrificial gate electrode 304, and hard mask layer 306). In another implementation, only the sacrificial gate 304 is removed. If the gate dielectric 302 is removed, the method can include depositing a new gate dielectric layer to the trench opening. Any suitable high-k dielectric material (as described above), such as yttrium oxide, can be used herein. The same deposition process can also be used. Substitute of gate dielectric 302 can be used to address, for example, any damage to the initial gate dielectric layer during dry and wet etch processes, and/or to high k or other desirable gates Dielectric materials replace low-k or sacrificial dielectric materials. The method can then continue to deposit a metal gate electrode layer into the trench and over the gate dielectric layer. Conventional metal deposition processes can be used to form metal gate electrode layers, such as CVD, ALD, PVD, electroless plating, or electroplating. The metal gate electrode layer may include, for example, a p-type work function metal such as germanium, palladium, cobalt, nickel, And a conductive metal oxide (such as yttrium oxide). In some example configurations, two or more metal gate electrode layers can be deposited. For example, a work function metal can be deposited followed by a suitable metal gate electrode fill metal, such as aluminum. FIG. 3D' depicts an example high-k gate dielectric layer 324 and metal gate electrode 326 that have been deposited into the trench opening, in accordance with an embodiment of the present invention. It should be noted that this RMG program can be implemented at different points in the process, if desired.

進一步參考圖2,在形成絕緣體層322後(及任何所需的預先接觸形成RMG製程),方法繼續蝕刻以形成源極/汲極接觸溝渠(216)。可使用任何合適的乾式及/或濕式蝕刻製程。圖3E顯示根據一範例具體實施例之在完成蝕刻後的源極/汲極接觸溝渠。 With further reference to FIG. 2, after forming the insulator layer 322 (and any desired pre-contact formation of the RMG process), the method continues etching to form the source/drain contact trench (216). Any suitable dry and/or wet etch process can be used. FIG. 3E shows source/drain contact trenches after etching is completed, according to an exemplary embodiment.

接著,方法繼續沉積接觸電阻降低金屬及退火(218),接著沉積源極/汲極接觸插塞(220)。圖3F顯示接觸電阻降低金屬325,其在某些具體實施例中包括銀、鎳、鋁、鈦、金、金-鍺、鎳-鉑、或鎳-鋁、及/或其他此類電阻降低金屬或合金。圖3F更顯示接觸插塞金屬329,其在某些具體實施例中包括鋁或鎢,然而可使用任何合適的導電接觸金屬或合金,例如銀、鎳-鉑或鎳-鋁或鎳及鋁的其他合金、或鈦,其使用習知的沉積製程。源極/汲極接觸的金屬化可例如使用鍺化製程(一般來說,接觸金屬的沉積及後續的退火)。舉例來說,可使用具有鎳、鋁、鎳-鉑或鎳-鋁或鎳及鋁的其他合金、或鈦的鍺化(包含或不包含鍺預非晶佈植)來形成低電阻鍺化物。硼 摻雜鍺蓋層318/320允許金屬-鍺化物形成(例如鎳-鍺)。鍺化物允許比傳統金屬-矽化物系統明顯較低的蕭特基-阻障高度及改善的接觸電阻。舉例來說,傳統的電晶體一般使用源極/汲極SiGe磊晶製程,其鍺濃度的範圍在30至40原子百分比。此傳統的系統展現約140歐姆-微米的Rext值,受限於磊晶/矽化物介面電阻,其為高且可能阻礙未來的閘極節距縮放。本發明的某些具體實施例允許PMOS裝置中Rext的顯著改善(例如2x或更佳的改善,例如約70歐姆-微米或更低的Rext),其可較佳地支援PMOS裝置縮放。因此,相較於傳統的電晶體,具有組態為如本文所述之雙層源極/汲極結構之源極/汲極的電晶體可展現相對較低的Rext值。 Next, the method continues to deposit the contact resistance reducing metal and anneal (218), followed by deposition of the source/drain contact plug (220). 3F shows contact resistance reducing metal 325, which in some embodiments includes silver, nickel, aluminum, titanium, gold, gold-bismuth, nickel-platinum, or nickel-aluminum, and/or other such resistance reducing metals Or alloy. Figure 3F further shows contact plug metal 329, which in some embodiments includes aluminum or tungsten, although any suitable conductive contact metal or alloy may be used, such as silver, nickel-platinum or nickel-aluminum or nickel and aluminum. Other alloys, or titanium, use conventional deposition processes. The metallization of the source/drain contact can be performed, for example, using a deuteration process (generally, deposition of contact metal and subsequent annealing). For example, other alloys having nickel, aluminum, nickel-platinum or nickel-aluminum or nickel and aluminum, or titanium deuteration (with or without yttrium pre-amorphous implants) can be used to form low resistance tellurides. boron The doped capping layer 318/320 allows metal-deuterated formation (eg, nickel-rhenium). Telluride allows a significantly lower Schottky-block height and improved contact resistance than conventional metal-telluride systems. For example, conventional transistors typically use a source/drain SiGe epitaxial process with a germanium concentration ranging from 30 to 40 atomic percent. This conventional system exhibits a Rext value of approximately 140 ohm-micron, limited by epitaxial/deuterated interface resistance, which is high and may hinder future gate pitch scaling. Certain embodiments of the present invention allow for a significant improvement in Rext in a PMOS device (e.g., a 2x or better improvement, such as Rext of about 70 ohm-micron or lower), which preferably supports PMOS device scaling. Thus, a transistor having a source/drain configured as a dual layer source/drain structure as described herein can exhibit a relatively low Rext value compared to conventional transistors.

非平面組態 Non-planar configuration

非平面架構可例如使用鰭式電晶體或奈米線組態而實施。FinFET為圍繞一半導體材料薄條(一般稱作鰭)而建立的電晶體。電晶體包括標準場效電晶體(FET)節點,包括閘極、閘極介電質、源極區域、及汲極區域。裝置的傳導通道位在閘極介電質底下、鰭的外側之上/之內。特別地,電流沿鰭的兩側壁(垂直基板平面之側)流動,也沿鰭的頂部(平行基板平面之側)流動。因為此組態的傳導通道主要位在沿鰭的三個不同的外部、平面區域,此一FinFET設計有時稱作三閘極FinFET。其他類型的FinFET組態也可使用,例如所謂的雙閘極FinFETs, 其中傳導通道主要僅位於沿鰭的兩側壁(沒有沿著鰭的頂部)。 The non-planar architecture can be implemented, for example, using a fin transistor or nanowire configuration. A FinFET is a transistor that is built around a thin strip of semiconductor material, commonly referred to as a fin. The transistor includes a standard field effect transistor (FET) node including a gate, a gate dielectric, a source region, and a drain region. The conduction path of the device is located below/under the outside of the gate dielectric. In particular, current flows along both sidewalls of the fin (the side of the vertical substrate plane) and also along the top of the fin (the side parallel to the plane of the substrate). Because this configured conduction channel is primarily located in three different external, planar regions along the fin, this FinFET design is sometimes referred to as a three-gate FinFET. Other types of FinFET configurations are also available, such as the so-called double gate FinFETs, Wherein the conduction channels are mainly located only along the two sidewalls of the fin (not along the top of the fin).

圖4A至4G之每一者顯示根據本發明一具體實施例形成之FinFET電晶體結構的透視圖。將理解到,前文有關圖2至圖3F的討論同樣可用於此處。可看出,圖4A所示之範例非平面組態係以鰭式結構來實施,包括基板400,其具有半導體本體或鰭410從基板400延伸通過淺溝渠隔離(STI)層420。基板可例如為矽、鍺、或SiGe。 4A through 4G each show a perspective view of a FinFET transistor structure formed in accordance with an embodiment of the present invention. It will be appreciated that the foregoing discussion of Figures 2 through 3F is equally applicable here. It can be seen that the example non-planar configuration illustrated in FIG. 4A is implemented in a fin structure including a substrate 400 having a semiconductor body or fin 410 extending from the substrate 400 through a shallow trench isolation (STI) layer 420. The substrate can be, for example, tantalum, niobium, or SiGe.

圖4B顯示形成於鰭410之三個表面之上的閘極電極440,以形成三個閘極(因此為三閘極裝置)。閘極介電質材料430係形成於鰭410與閘極電極440之間,且硬式遮罩450係形成於閘極電極440的頂部。圖4C描述在沉積絕緣材料及後續蝕刻(其留下絕緣體材料之覆層於所有垂直表面上,以形成間隙壁460)後所產生的結構。 FIG. 4B shows the gate electrode 440 formed over the three surfaces of the fin 410 to form three gates (and thus a three-gate device). A gate dielectric material 430 is formed between the fin 410 and the gate electrode 440, and a hard mask 450 is formed on top of the gate electrode 440. Figure 4C depicts the resulting structure after deposition of an insulating material and subsequent etching that leaves a coating of the insulating material on all vertical surfaces to form spacers 460.

圖4D描述在額外蝕刻處理後所產生的結構,其從鰭410的側壁消除了多餘的絕緣/間隙壁材料,而僅留下間隙壁460在閘極電極440的相對側壁。圖4E描述在凹槽蝕刻後所產生的結構,其移除了基板400之源極/汲極區域中的鰭410,從而形成凹槽470。需注意,其他具體實施例可無凹槽(例如源極/汲極區域與STI層420對齊)。 4D depicts a structure created after an additional etch process that eliminates excess insulation/gap material from the sidewalls of fin 410 leaving only spacer 460 at the opposite sidewalls of gate electrode 440. 4E depicts a structure created after trench etch that removes fins 410 in the source/drain regions of substrate 400, thereby forming recesses 470. It should be noted that other embodiments may have no grooves (eg, source/drain regions are aligned with STI layer 420).

圖4F描述在磊晶襯層480生長後所產生的結構,其可為薄、p型並含相當大部份的矽(例如矽或具有70原子百分比矽的SiGe)、或為純鍺(例如鍺的分隔層、或整合 至或包含於蓋層318/320的成分中之不可偵測層)。圖4G描述在成長磊晶源極/汲極蓋層490後所產生的結構,其可為p型且主要包含鍺,但可包含少於20原子百分比的錫或其他合適的合金材料,如前文所解釋。根據本說明書內容將可理解到,可使用習知的製程及形成技術以製造本文所述之具有雙層源極/汲極結構FinFET電晶體結構。 Figure 4F depicts the structure produced after epitaxial liner 480 growth, which may be thin, p-type and contain a significant portion of germanium (e.g., germanium or SiGe with 70 atomic percent germanium), or pure germanium (e.g.,分隔 separate layer, or integration To or included in the undetectable layer of the composition of the cap layer 318/320). Figure 4G depicts the structure produced after growing the epitaxial source/drain cap layer 490, which may be p-type and mainly contains germanium, but may contain less than 20 atomic percent tin or other suitable alloy material, as previously described Explained. It will be appreciated from the teachings herein that conventional process and formation techniques can be used to fabricate the dual layer source/drain structure FinFET transistor structures described herein.

將進一步理解到,需注意,所示三閘極組態的替代物為雙閘極架構,其包括介電質/隔離層於鰭410的頂部。更需注意,構成圖4G所示之源極/汲極區域之襯層480及蓋層490的範例外形並不意欲限制所主張之本發明於任何特定的源極/汲極種類或形成製程,且根據本說明書內容,其他源極/汲極外形為顯而易知的(例如可實施圓形、方形或矩形源極/汲極區域)。 It will be further appreciated that it is noted that an alternative to the illustrated three gate configuration is a dual gate architecture that includes a dielectric/isolation layer on top of the fins 410. It is further noted that the exemplary shapes of the liner 480 and the cap layer 490 constituting the source/drain regions shown in FIG. 4G are not intended to limit the claimed invention to any particular source/drain type or formation process, And other source/drain profiles are readily apparent in light of this description (eg, circular, square or rectangular source/drain regions can be implemented).

圖5A顯示根據本發明一具體實施例而形成之奈米線電晶體結構的透視圖。奈米線電晶體(有時稱作環繞式閘極FET)係類似地組態為以鰭為基礎的電晶體,但使用奈米線來代替鰭,且閘極材料一般圍繞通道區域的所有側。根據特定的設計,某些奈米線電晶體具有例如四個等效閘極。圖5A描述具有兩個奈米線510的奈米線通道架構,然而其他具體實施例可具有任何數量的線。奈米線510可由例如p型矽或鍺或SiGe奈米線來實施。可看出,一奈米線510係形成或提供於基板400的凹陷處,且其他奈米線510係等效地漂浮在包含襯層580及蓋層590的源極/汲極材料雙層結構中。如同鰭式組態,需注意可由本文所 述之源極/汲極材料的雙層結構取代源極/汲極中的奈米線510(例如相對薄的矽或鍺或SiGe襯層以及相對厚的高濃度鍺蓋層)。或者,雙層結構可形成於最初所形成之奈米線510周圍,如圖所示(其中襯層580係形成於奈米線510周圍,且蓋層590接著形成於襯層580的周圍)。圖5B也描述具有多個奈米線510的奈米線組態,但在此範例中,根據本說明書內容可理解,在奈米線形成過程中,非活性材料511沒有從個別的奈米線之間移除,其可使用各種習知的技術來實行。因此,一奈米線510係形成於基板400的凹陷處,而另一奈米線510係等效地位於材料511的頂部。需注意,奈米線510通過通道而作用,但511材料則無。可看出,襯層580及蓋層590的雙層源極/汲極結構係圍繞奈米線510的所有其他暴露表面。 Figure 5A shows a perspective view of a nanowire transistor structure formed in accordance with an embodiment of the present invention. Nanowire transistors (sometimes referred to as wraparound gate FETs) are similarly configured as fin-based transistors, but using nanowires instead of fins, and the gate material generally surrounds all sides of the channel region. . Some nanowire transistors have, for example, four equivalent gates, depending on the particular design. FIG. 5A depicts a nanowire channel architecture having two nanowires 510, although other embodiments may have any number of wires. The nanowire 510 can be implemented by, for example, a p-type 矽 or 锗 or a SiGe nanowire. It can be seen that one nanowire 510 is formed or provided in the depression of the substrate 400, and the other nanowires 510 are equivalently floating on the double layer structure of the source/drain material including the liner 580 and the cap layer 590. in. Like the fin configuration, you need to pay attention to this article. The two-layer structure of the source/drain material replaces the nanowires 510 in the source/drain (eg, a relatively thin tantalum or niobium or SiGe liner and a relatively thick high concentration capping layer). Alternatively, a two-layer structure can be formed around the initially formed nanowire 510, as shown (where liner 580 is formed around nanowire 510 and cap layer 590 is then formed around liner 580). Figure 5B also depicts a nanowire configuration having a plurality of nanowires 510, but in this example, it will be understood from the description of the present specification that the inactive material 511 is not from individual nanowires during nanowire formation. Removed between, which can be implemented using a variety of conventional techniques. Thus, one nanowire 510 is formed in the recess of the substrate 400, while the other nanowire 510 is equivalently located on top of the material 511. It should be noted that the nanowire 510 acts through the channel, but the 511 material does not. It can be seen that the dual layer source/drain structure of liner 580 and cap layer 590 surrounds all other exposed surfaces of nanowire 510.

範例系統 Sample system

圖6描述一計算系統1000,其係以根據本發明範例具體實施例而組態之一或多個電晶體結構而實施。可看出,計算系統1000內含一主機板1002。主機板1002可包括一些組件,其包括但不限於處理器1004及至少一通訊晶片1006,其每一者可物理地及電性地耦合至主機板1002,或是整合於其中。將理解到,主機板1002可例如為任何印刷電路板,不論是主板、架設於主板上的子板、或僅系統1000的板等。根據其應用,計算系統1000可包括一或多個其他組件,其可或可不物理及電性地耦合至主機板 1002。這些其他組件可包括但不限於揮發性記憶體(如DRAM)、非揮發性記憶體(如ROM)、圖形處理器、數位信號處理器、密碼處理器、晶片組、天線、顯示器、觸控螢幕顯示器、觸控螢幕控制器、電池、音頻編解碼器、視頻編解碼器、功率放大器、全球定位系統(GPS)裝置、羅盤、加速度計、陀螺儀、揚聲器、相機、大量儲存裝置(如硬碟驅動、光碟(CD)、數位多功能光碟(DVD)等)。計算系統1000所包括的任何組件可包括一或更多本文所述的電晶體結構(例如具有雙層源極/汲極結構,其包含相對薄的p型矽或鍺或SiGe襯層及相對較厚的p型高鍺含量蓋層)。這些電晶體結構可用以例如實施機載處理器快取或記憶體陣列。在某些具體實施例中,多重函數可整合至一或多個晶片(例如,需注意通訊晶片1006可為處理器1004的部份或整合至處理器1004)。 FIG. 6 depicts a computing system 1000 implemented in accordance with one or more transistor structures configured in accordance with an exemplary embodiment of the present invention. It can be seen that computing system 1000 includes a motherboard 1002. The motherboard 1002 can include components including, but not limited to, a processor 1004 and at least one communication chip 1006, each of which can be physically and electrically coupled to the motherboard 1002 or integrated therein. It will be appreciated that the motherboard 1002 can be, for example, any printed circuit board, whether it be a motherboard, a daughter board that is mounted on a motherboard, or a board of system 1000 alone. Depending on its application, computing system 1000 can include one or more other components that may or may not be physically and electrically coupled to a motherboard 1002. These other components may include, but are not limited to, volatile memory (such as DRAM), non-volatile memory (such as ROM), graphics processor, digital signal processor, cryptographic processor, chipset, antenna, display, touch screen Display, touch screen controller, battery, audio codec, video codec, power amplifier, global positioning system (GPS) device, compass, accelerometer, gyroscope, speaker, camera, mass storage device (such as hard drive) Driver, CD (CD), digital versatile disc (DVD), etc.). Any of the components included in computing system 1000 can include one or more of the transistor structures described herein (eg, having a dual layer source/drain structure comprising relatively thin p-type germanium or germanium or SiGe liners and relatively relatively Thick p-type sorghum content cover). These transistor structures can be used, for example, to implement an onboard processor cache or memory array. In some embodiments, the multiple functions can be integrated into one or more of the wafers (eg, it is noted that the communication chip 1006 can be part of the processor 1004 or integrated into the processor 1004).

通訊晶片1006係致能往返計算系統1000之資料轉移的無線通訊。「無線」及其衍生物可用以描述電路、裝置、系統、方法、技術、通訊通道等,其可透過經由非固態媒體之調節電磁輻射的使用來通訊資料。此術語不表示相關裝置不含任何電線,然而其在某些具體實施例中可能不含。通訊晶片1006可實現任何數量的無線標準或協定,包括但不限於Wi-Fi(IEEE 802.11家族)、WiMAX(IEEE 802.16家族)、IEEE 802.20、長期進化(LTE)、Ev-DO、HSPA+、HSDPA+、HSUPA+、EDGE、 GSM、GPRS、CDMA、TDMA、DECT、藍牙、其衍生物、以及指定為3G、4G、5G或更高之任何其他無線協定。計算系統1000可包括複數個通訊晶片1006。舉例來說,第一通訊晶片1006可專用於較短範圍的無線通訊,例如Wi-Fi及藍芽,而第二通訊晶片1006可專用於較長範圍無線通訊,例如GPS、EDGE、GPRS、CDMA、WiMAX、LTE、Ev-DO及其他。 The communication chip 1006 is a wireless communication that enables data transfer to and from the computing system 1000. "Wireless" and its derivatives can be used to describe circuits, devices, systems, methods, techniques, communication channels, etc., which can communicate data by regulating the use of electromagnetic radiation via non-solid media. This term does not mean that the associated device does not contain any wires, however it may not be included in some embodiments. The communication chip 1006 can implement any number of wireless standards or protocols including, but not limited to, Wi-Fi (IEEE 802.11 family), WiMAX (IEEE 802.16 family), IEEE 802.20, Long Term Evolution (LTE), Ev-DO, HSPA+, HSDPA+, HSUPA+, EDGE, GSM, GPRS, CDMA, TDMA, DECT, Bluetooth, its derivatives, and any other wireless protocol designated as 3G, 4G, 5G or higher. Computing system 1000 can include a plurality of communication chips 1006. For example, the first communication chip 1006 can be dedicated to a shorter range of wireless communication, such as Wi-Fi and Bluetooth, and the second communication chip 1006 can be dedicated to longer-range wireless communication, such as GPS, EDGE, GPRS, CDMA. , WiMAX, LTE, Ev-DO and others.

計算系統1000的處理器1004包括封裝於處理器1004之內的積體電路晶粒。在本發明某些具體實施例中,處理器的積體電路晶粒包括內建記憶體電路,其以一或多個本文所述之電晶體結構(如PMOS或CMOS)所實施。「處理器」一詞可指任何裝置或一裝置的部份,其處理例如來自暫存器及/或記憶體的電子資料並轉換電子資料為可儲存於暫存器及/或記憶體的其他電子資料。 The processor 1004 of the computing system 1000 includes integrated circuit dies that are packaged within the processor 1004. In some embodiments of the invention, the integrated circuit die of the processor includes a built-in memory circuit implemented in one or more of the transistor structures (e.g., PMOS or CMOS) described herein. The term "processor" may refer to any device or part of a device that processes, for example, electronic data from a register and/or memory and converts the electronic data into other storage and/or memory. Electronic information.

通訊晶片1006也可包括封裝於通訊晶片1006內的積體電路晶粒。根據某些此類範例具體實施例,通訊晶片的積體電路晶粒包括以一或多個本文所述之電晶體結構所實施的一或多個電路(例如晶片上處理器或記憶體)。根據本說明書內容將理解到,需注意,多重標準無線能力可直接整合至處理器1004(例如任何晶片1006的功能係整合至處理器1004中,而非具有獨立的通訊晶片)。此外,需注意,處理器1004可為具有此無線能力的晶片組。簡言之,可使用任何數量的處理器1004及/或通訊晶片1006。同樣地,任一晶片或晶片組可具有多個功能整合於 其中。 The communication chip 1006 can also include integrated circuit dies that are packaged within the communication chip 1006. In accordance with certain such exemplary embodiments, the integrated circuit die of the communication chip includes one or more circuits (e.g., on-wafer processor or memory) implemented in one or more of the transistor structures described herein. It will be appreciated from the description that it is noted that multiple standard wireless capabilities may be directly integrated into processor 1004 (eg, the functionality of any of the wafers 1006 is integrated into processor 1004 rather than having separate communication chips). Additionally, it is noted that the processor 1004 can be a chipset having this wireless capability. In short, any number of processors 1004 and/or communication chips 1006 can be used. Similarly, any wafer or wafer set can have multiple functions integrated into among them.

在各種實施中,計算系統1000可為膝上型電腦、輕省筆電、筆記型電腦、智慧型手機、平板電腦、個人數位助理(PDA)、超行動PC、行動電話、桌上型電腦、伺服器、印表機、掃描器、監視器、機上盒、娛樂控制單元、數位相機、行動音樂播放器、或數位視頻記錄器。在進一步的實施中,系統1000可為處理資料或使用本文所述之低電阻電晶體裝置(如PMOS及CMOS電路)的任何其他電子裝置。 In various implementations, computing system 1000 can be a laptop, a laptop, a notebook, a smart phone, a tablet, a personal digital assistant (PDA), an ultra mobile PC, a mobile phone, a desktop computer, Servers, printers, scanners, monitors, set-top boxes, entertainment control units, digital cameras, mobile music players, or digital video recorders. In further implementations, system 1000 can be any other electronic device that processes data or uses low resistance transistor devices (such as PMOS and CMOS circuits) as described herein.

許多具體實施例將為明顯的,且本文所述的特徵可結合於任何數量的組態中。本發明一範例具體實施例提供一電晶體裝置。裝置包括具有通道區域的基板、在通道區域之上的閘極電極、及形成於基板之上或之中且鄰接通道區域的源極/汲極區域。源極及汲極區域之每一者具有一總厚度,其包含矽或鍺或矽鍺的一p型襯層以及具有鍺濃度超過80原子百分比的一p型蓋層,其中襯層小於總厚度的50%。在某些情況中,裝置為平面、FinFET、或奈米線PMOS電晶體之其中一者。在某些情況中,裝置更包括金屬-鍺化物源極/汲極接觸。在某些情況中,襯層厚度對蓋層厚度的厚度比為2:5或更低(襯層為總厚度的40%或更低)。在某些情況中,襯層厚度對蓋層厚度的厚度比為1:5或更低(襯層為總厚度的20%或更低)。在某些情況中,襯層之每一者具有範圍在約1單分子層至10奈米的一厚度,且蓋層之每一者具有範圍在約50奈米至500奈 米的一厚度。在某些情況中,襯層及/或蓋層之其中至少一者具有鍺及/或p型摻雜物之一漸次變化濃度之至少一者。舉例來說,在某些情況中,襯層之其中至少一者具有一鍺濃度,其從相容於基板之一基準濃度至超過50原子百分比之一高濃度而漸次變化。在一此類情況中,高濃度係超過90原子百分比。在某些情況中,襯層之其中至少一者具有一p型摻雜物濃度,其從相容於基板之一基準濃度至超過1E20cm-3之一高濃度而漸次變化。在一此類情況中,一或多個襯層之p型摻雜物為硼。在某些情況中,蓋層之其中至少一者具有超過95原子百分比之一鍺濃度。在某些情況中,蓋層之其中至少一者具有從相容於對應襯層之一基準濃度至超過80原子百分比之一高濃度而漸次變化的一鍺濃度。在某些情況中,蓋層之其中至少一者具有從相容於對應襯層之一基準濃度至超過1E20cm-3之一高濃度而漸次變化的一p型摻雜物濃度。在某些情況中,一或多個蓋層之p型摻雜物為硼。在某些情況中,蓋層之其中至少一者更包含錫。許多變化將為顯而易見的。舉例來說,在某些範例情況中,基板為含矽基板。在某些此類情況中,p型襯層包含矽或矽鍺。在其他範例情況中,基板為鍺基板。在某些此類情況中,p型襯層為p型鍺。在某些範例的此類情況中,每一襯層係包括在對應蓋層的成分中(使得不同及獨立的襯層可能無法與不同及獨立的蓋層區別)。在某些情況中,蓋層之其中至少一者更包含錯位差排及/或穿透差排及/或雙晶,而在其他情況 中,蓋層無錯位差排、穿透差排、及雙晶。本發明的另一具體實施例包括具有一印刷電路板的一電子裝置,其中印刷電路板具有包括此段落中各種不同定義之一或多個電晶體裝置的一積體電路。在一此類情況中,積體電路包含一通訊晶片及/或一處理器之其中至少一者。在某些情況中,電子裝置為一計算裝置。 Many specific embodiments will be apparent, and the features described herein can be combined in any number of configurations. An exemplary embodiment of the present invention provides an optoelectronic device. The device includes a substrate having a channel region, a gate electrode over the channel region, and a source/drain region formed on or in the substrate adjacent the channel region. Each of the source and drain regions has a total thickness comprising a p-type liner of tantalum or niobium or tantalum and a p-type cap layer having a tantalum concentration of more than 80 atomic percent, wherein the liner layer is less than the total thickness 50%. In some cases, the device is one of a planar, FinFET, or nanowire PMOS transistor. In some cases, the device further includes a metal-telluride source/drain contact. In some cases, the thickness ratio of the thickness of the liner to the thickness of the cover layer is 2:5 or less (the liner is 40% or less of the total thickness). In some cases, the thickness ratio of the thickness of the liner to the thickness of the cover layer is 1:5 or lower (the liner is 20% or less of the total thickness). In some cases, each of the liners has a thickness ranging from about 1 monolayer to 10 nanometers, and each of the cap layers has a thickness ranging from about 50 nanometers to 500 nanometers. In some cases, at least one of the liner and/or the cap layer has at least one of a progressively varying concentration of one of the erbium and/or p-type dopants. For example, in some cases, at least one of the liners has a germanium concentration that varies gradually from a reference concentration that is compatible with one of the substrates to a high concentration of more than 50 atomic percent. In one such case, the high concentration is greater than 90 atomic percent. In some cases, at least one of the liners has a p-type dopant concentration that varies from a reference concentration of one of the substrates to a high concentration of more than 1E20 cm -3 . In one such case, the p-type dopant of one or more of the liners is boron. In some cases, at least one of the cap layers has a concentration of more than 95 atomic percent. In some cases, at least one of the cap layers has a concentration that varies gradually from a reference concentration that is compatible with one of the corresponding liner layers to a high concentration that is greater than 80 atomic percent. In some cases, at least one of the cap layers has a p-type dopant concentration that varies gradually from a reference concentration that is compatible with one of the corresponding liners to a high concentration that exceeds 1E20 cm -3 . In some cases, the p-type dopant of one or more cap layers is boron. In some cases, at least one of the cap layers further comprises tin. Many changes will be obvious. For example, in some example cases, the substrate is a germanium containing substrate. In some such cases, the p-type liner comprises tantalum or niobium. In other example cases, the substrate is a germanium substrate. In some such cases, the p-type liner is p-type tantalum. In such instances of certain examples, each liner is included in the composition of the corresponding cover layer (so that different and separate liners may not be distinguishable from different and separate cover layers). In some cases, at least one of the cap layers further comprises a misalignment row and/or a penetrating row and/or a twin crystal, and in other cases, the cap layer has no misalignment, a penetrating row, and Double crystal. Another embodiment of the invention includes an electronic device having a printed circuit board having an integrated circuit including one or more of the various different definitions in this paragraph. In one such case, the integrated circuit includes at least one of a communication chip and/or a processor. In some cases, the electronic device is a computing device.

本發明的其他具體實施例提供一積體電路。電路包括一基板(如矽、SiGe、或鍺),其具有通道區域、於通道區域之上的閘極電極、形成於基板之上或之中且鄰接通道區域的源極/汲極區域、以及金屬鍺化物源極及汲極接觸。源極及汲極區域之每一者具有一總厚度,其包含矽或鍺或矽鍺的一p型襯層以及具有鍺濃度超過80原子百分比的一p型蓋層,其中襯層為總厚度的40%或更低。在某些情況中,襯層厚度對蓋層厚度的厚度比為1:5或更低。在某些情況中,蓋層之其中至少一者更包含錫。 Other embodiments of the present invention provide an integrated circuit. The circuit includes a substrate (such as germanium, SiGe, or germanium) having a channel region, a gate electrode over the channel region, a source/drain region formed on or in the substrate and adjacent to the channel region, and The metal telluride source is in contact with the drain. Each of the source and drain regions has a total thickness comprising a p-type liner of tantalum or niobium or tantalum and a p-type cap layer having a tantalum concentration of more than 80 atomic percent, wherein the liner is a total thickness 40% or less. In some cases, the thickness ratio of the thickness of the liner to the thickness of the cover layer is 1:5 or less. In some cases, at least one of the cap layers further comprises tin.

本發明的另一具體實施例提供用以形成電晶體裝置的一方法。方法包括提供具有一通道區域的一基板、提供在通道區域之上的一閘極電極、以及提供形成於基板之上或之中且鄰近通道區域的源極及汲極區域。源極及汲極區域之每一者具有一總厚度,其包含矽或鍺或矽鍺的一p型襯層以及具有鍺濃度超過80原子百分比的一p型蓋層,其中襯層小於總厚度的50%。在某些情況中,方法包括提供金屬鍺化物之源極及汲極接觸。在某些情況中,襯層厚度對蓋層厚度的厚度比為2:5或更低。在某些情況中,襯 層及/或蓋層之其中至少一者具有鍺及/或p型摻雜物之一漸次變化濃度之至少一者。在某些情況中,蓋層之其中至少一者更包含錫(或其他合適的應變誘導物)。 Another embodiment of the invention provides a method for forming an optoelectronic device. The method includes providing a substrate having a channel region, providing a gate electrode over the channel region, and providing source and drain regions formed on or in the substrate adjacent to the channel region. Each of the source and drain regions has a total thickness comprising a p-type liner of tantalum or niobium or tantalum and a p-type cap layer having a tantalum concentration of more than 80 atomic percent, wherein the liner layer is less than the total thickness 50%. In some cases, the method includes providing a source and a drain contact of the metal telluride. In some cases, the thickness ratio of the thickness of the liner to the thickness of the cover layer is 2:5 or less. In some cases, lining At least one of the layer and/or the cap layer has at least one of a progressively varying concentration of one of the germanium and/or p-type dopants. In some cases, at least one of the cap layers further comprises tin (or other suitable strain inducer).

前文中已提出本發明範例具體實施例的描述作為說明及描述目的。這並不意圖為詳盡的或限制本發明於所揭露的精確形式。根據本說明書內容,許多修改及變化是可能的。舉例來說,雖然本發明某些具體實施例利用鍺的原位硼摻雜,但其他具體實施例可使用本質鍺,其在沉積後係接著受到p型摻雜物佈植及退火製程以提供所需的p型摻雜濃度。此外,某些具體實施例可包括如本文所述而製造的源極及汲極區域,但仍使用傳統製程(例如佈植及退火)來形成源極及汲極區域的頂端。在此具體實施例中,頂端可具有比主要源極及汲極區域低的鍺及/或p型摻雜物濃度,其在某些應用中是可接受的。在其他具體實施例中,只有源極及汲極區域的頂端可組態為具有高鍺及p型摻雜物濃度,而源極及汲極區域的主要部份可具有傳統或較低的鍺/摻雜物濃度。本發明的範疇並不意欲受限於此詳細的說明內容,而是由後附之申請專利範圍所限制。 The foregoing description of the specific embodiments of the invention has been set forth This is not intended to be exhaustive or to limit the invention. Many modifications and variations are possible in light of the present disclosure. For example, while certain embodiments of the present invention utilize in situ boron doping of germanium, other embodiments may use an intrinsic germanium that is subsequently deposited by a p-type dopant implant and anneal process to provide The required p-type doping concentration. Moreover, certain embodiments may include source and drain regions fabricated as described herein, but still use conventional processes (eg, implant and anneal) to form the tips of the source and drain regions. In this particular embodiment, the tip can have a lower germanium and/or p-type dopant concentration than the main source and drain regions, which is acceptable in certain applications. In other embodiments, only the tops of the source and drain regions can be configured to have high germanium and p-type dopant concentrations, while the major portions of the source and drain regions can have conventional or lower germanium. / dopant concentration. The scope of the present invention is not intended to be limited to the details of the invention, but is limited by the scope of the appended claims.

300‧‧‧基板 300‧‧‧Substrate

302‧‧‧閘極介電層 302‧‧‧ gate dielectric layer

304‧‧‧閘極電極 304‧‧‧gate electrode

306‧‧‧選擇性硬式遮罩 306‧‧‧Selective hard mask

310‧‧‧間隙壁 310‧‧‧ spacer

312‧‧‧凹洞 312‧‧‧

312A‧‧‧頂端區域 312A‧‧‧top area

313‧‧‧襯層 313‧‧‧ lining

314‧‧‧凹洞 314‧‧‧Deep

314A‧‧‧頂端區域 314A‧‧‧Top area

315‧‧‧襯層 315‧‧‧ lining

318‧‧‧蓋層 318‧‧‧ cover

318A‧‧‧源極頂端 318A‧‧‧ source top

320‧‧‧蓋層 320‧‧‧ cover

320A‧‧‧汲極頂端 320A‧‧‧汲 pole top

322‧‧‧絕緣體層 322‧‧‧Insulator layer

324‧‧‧高k閘極介電質層 324‧‧‧High-k gate dielectric layer

325‧‧‧接觸電阻降低金屬 325‧‧‧Contact resistance reduction metal

326‧‧‧金屬閘極電極 326‧‧‧Metal gate electrode

329‧‧‧接觸插塞金屬 329‧‧‧Contact plug metal

400‧‧‧基板 400‧‧‧Substrate

410‧‧‧鰭 410‧‧‧Fins

420‧‧‧STI層 420‧‧‧STI layer

430‧‧‧閘極介電質材料 430‧‧‧Gate dielectric materials

440‧‧‧閘極電極 440‧‧‧gate electrode

450‧‧‧硬式遮罩 450‧‧‧hard mask

460‧‧‧間隙壁 460‧‧‧ spacer

470‧‧‧凹槽 470‧‧‧ Groove

480‧‧‧磊晶襯層 480‧‧‧ epitaxial lining

490‧‧‧磊晶源極/汲極蓋層 490‧‧‧ Epitaxial source/drain capping

510‧‧‧奈米線 510‧‧Neon line

511‧‧‧材料 511‧‧‧Materials

580‧‧‧襯層 580‧‧‧ lining

590‧‧‧蓋層 590‧‧‧ cover

1000‧‧‧計算系統 1000‧‧‧Computation System

1002‧‧‧主機板 1002‧‧‧ motherboard

1004‧‧‧處理器 1004‧‧‧ processor

1006‧‧‧通訊晶片 1006‧‧‧Communication chip

圖1示意地描述包括源極及汲極頂端區域之一典型MOS電晶體之電阻的構件;圖2為根據本發明之一具體實施例之用以形成第IV族電晶體之方法; 圖3A至3F根據本發明之各種具體實施例描述實施圖2之方法所形成之結構;圖4A至4G之每一者顯示根據本發明之一具體實施例所形成之FinFET電晶體結構的透視圖;圖5A及5B之每一者顯示根據本發明之一具體實施例所形成之奈米線電晶體結構的透視圖;以及圖6描述根據本發明之一具體實施例之以一或多個電晶體結構所實施之計算系統。 1 schematically depicts a component including the resistance of a typical MOS transistor of a source and drain top region; FIG. 2 is a diagram of a method for forming a Group IV transistor in accordance with an embodiment of the present invention; 3A through 3F depict structures formed by the method of FIG. 2 in accordance with various embodiments of the present invention; each of FIGS. 4A through 4G shows a perspective view of a FinFET transistor structure formed in accordance with an embodiment of the present invention. 5A and 5B each show a perspective view of a nanowire transistor structure formed in accordance with an embodiment of the present invention; and FIG. 6 depicts one or more electrodes in accordance with an embodiment of the present invention. A computing system implemented by a crystal structure.

應理解,圖式未必是以等比例繪出或是意圖限制本發明於所示的特定組態。舉例來說,雖然某些圖式一般係顯示直線、直角、及平滑表面,但鑒於真實世界對所使用之處理設備及技術的限制,電晶體結構的實際實作可能具有較不完美的直線及/或直角,且某些特徵可能具有表面拓撲或是不平滑。簡言之,圖式僅被提供來顯示範例結構。 It is to be understood that the drawings are not necessarily to the For example, although some drawings generally show straight lines, right angles, and smooth surfaces, in view of the real world limitations on the processing equipment and techniques used, the actual implementation of the transistor structure may have imperfect lines and / or right angle, and some features may have a surface topology or are not smooth. In short, the drawings are only provided to show example structures.

300‧‧‧基板 300‧‧‧Substrate

302‧‧‧閘極介電層 302‧‧‧ gate dielectric layer

304‧‧‧閘極電極 304‧‧‧gate electrode

306‧‧‧選擇性硬式遮罩 306‧‧‧Selective hard mask

313‧‧‧襯層 313‧‧‧ lining

315‧‧‧襯層 315‧‧‧ lining

318‧‧‧蓋層 318‧‧‧ cover

318A‧‧‧源極頂端 318A‧‧‧ source top

320‧‧‧蓋層 320‧‧‧ cover

320A‧‧‧汲極頂端 320A‧‧‧汲 pole top

322‧‧‧絕緣體層 322‧‧‧Insulator layer

325‧‧‧接觸電阻降低金屬 325‧‧‧Contact resistance reduction metal

329‧‧‧接觸插塞金屬 329‧‧‧Contact plug metal

Claims (25)

一種電晶體裝置,包含:一基板,具有一矽通道區域;一閘極電極,在該矽通道區域之上;以及源極及汲極區域,形成於該基板之上或之中且鄰近該矽通道區域,其中該源極及汲極區域之每一者:在該矽通道區域之一高度之上延伸;包括在該閘極電極之下延伸的頂端區域;及採用雙層結構,其具有一總厚度,該總厚度包含:矽或鍺或矽鍺的一p型襯層;以及具有鍺濃度超過80原子百分比的一p型蓋層,其中該襯層小於該總厚度的50%,且為在該閘極電極之下延伸的該頂端區域做內襯。 A transistor device comprising: a substrate having a channel region; a gate electrode over the channel region; and a source and drain region formed on or in the substrate adjacent to the substrate a channel region, wherein each of the source and drain regions extends over a height of one of the channel regions; includes a tip region extending below the gate electrode; and a two-layer structure having a a total thickness comprising: a p-type liner of ruthenium or osmium or iridium; and a p-type cap layer having a yttrium concentration of more than 80 atomic percent, wherein the lining layer is less than 50% of the total thickness, and The top end region extending below the gate electrode is lined. 如申請專利範圍第1項所述之裝置,其中該裝置為一平面、鰭式場效電晶體(FinFET)、或奈米線PMOS電晶體之其中一者。 The device of claim 1, wherein the device is one of a planar, fin field effect transistor (FinFET), or nanowire PMOS transistor. 如申請專利範圍第1項所述之裝置,更包含金屬鍺化物之源極及汲極接觸。 The device according to claim 1 further comprises a source of germanium metal and a drain contact. 如申請專利範圍第1項所述之裝置,其中襯層厚度對蓋層厚度的厚度比為2:5或更低。 The device of claim 1, wherein the thickness ratio of the thickness of the liner to the thickness of the cover layer is 2:5 or less. 如申請專利範圍第1項所述之裝置,其中襯層厚度對蓋層厚度的厚度比為1:5或更低。 The device of claim 1, wherein the thickness ratio of the thickness of the liner to the thickness of the cover layer is 1:5 or lower. 如申請專利範圍第1項所述之裝置,其中該等襯層之每一者具有範圍在約1單層(monolayer)至10奈米的 一厚度,且該等蓋層之每一者具有範圍在約50奈米至500奈米的一厚度。 The device of claim 1, wherein each of the lining layers has a range of from about 1 monolayer to 10 nm. A thickness, and each of the cap layers has a thickness ranging from about 50 nanometers to 500 nanometers. 如申請專利範圍第1項所述之裝置,其中該等襯層及/或蓋層之其中至少一者具有鍺及/或p型摻雜物之一漸次變化濃度之至少一者。 The device of claim 1, wherein at least one of the liners and/or cap layers has at least one of a progressively varying concentration of one of the erbium and/or p-type dopants. 如申請專利範圍第7項所述之裝置,其中該等襯層之其中至少一者具有一鍺濃度,該鍺濃度從相容於該基板之一基準濃度至超過50原子百分比之一高濃度而漸次變化。 The device of claim 7, wherein at least one of the underlayers has a germanium concentration ranging from a reference concentration of one of the substrates to a high concentration of more than 50 atomic percent. Gradually change. 如申請專利範圍第8項所述之裝置,其中該高濃度係超過90原子百分比。 The device of claim 8, wherein the high concentration is more than 90 atomic percent. 如申請專利範圍第7項所述之裝置,其中該等襯層之其中至少一者具有一p型摻雜物濃度,該p型摻雜物濃度從相容於該基板之一基準濃度至超過1E20cm-3之一高濃度而漸次變化。 The device of claim 7, wherein at least one of the lining layers has a p-type dopant concentration from a reference concentration of one of the substrates to a One of the 1E20cm -3 was highly concentrated and gradually changed. 如申請專利範圍第10項所述之裝置,其中該一或多個襯層之該p型摻雜物為硼。 The device of claim 10, wherein the p-type dopant of the one or more liners is boron. 如申請專利範圍第7項所述之裝置,其中該等蓋層之其中至少一者具有超過95原子百分比之一鍺濃度。 The device of claim 7, wherein at least one of the cap layers has a concentration of more than 95 atomic percent. 如申請專利範圍第7項所述之裝置,其中該等蓋層之其中至少一者具有從相容於該對應襯層之一基準濃度至超過80原子百分比之一高濃度而漸次變化的一鍺濃度。 The device of claim 7, wherein at least one of the cap layers has a gradual change from a reference concentration that is compatible with one of the corresponding lining layers to a high concentration of more than 80 atomic percent. concentration. 如申請專利範圍第7項所述之裝置,其中該等蓋 層之其中至少一者具有從相容於該對應襯層之一基準濃度至超過1E20cm-3之一高濃度而漸次變化的一p型摻雜物濃度。 The device of claim 7, wherein at least one of the cap layers has a p-gradient change from a reference concentration compatible with one of the corresponding liners to a high concentration exceeding one of 1E20 cm -3 Type dopant concentration. 如申請專利範圍第14項所述之裝置,其中該一或多個蓋層之該p型摻雜物為硼。 The device of claim 14, wherein the p-type dopant of the one or more cap layers is boron. 如申請專利範圍第1項所述之裝置,其中該等蓋層之其中至少一者更包含錫。 The device of claim 1, wherein at least one of the cap layers further comprises tin. 如申請專利範圍第1項所述之裝置,其中該等蓋層無錯位差排、穿透差排、及雙晶。 The device of claim 1, wherein the cap layers have no misalignment, a poor displacement row, and a twin crystal. 一種電子裝置,包含:一印刷電路板,具有包括前述申請專利範圍任一項所定義之一或多個電晶體裝置的一積體電路。 An electronic device comprising: a printed circuit board having an integrated circuit comprising one or more of the transistor devices as defined in any one of the preceding claims. 如申請專利範圍第18項所述之電子裝置,其中該積體電路包含一通訊晶片及/或一處理器之其中至少一者。 The electronic device of claim 18, wherein the integrated circuit comprises at least one of a communication chip and/or a processor. 如申請專利範圍第18項所述之電子裝置,其中該電子裝置為一計算裝置。 The electronic device of claim 18, wherein the electronic device is a computing device. 一種積體電路,包含:如申請專利範圍第1項所述之裝置,其中該襯層小於該總厚度的40%;以及金屬鍺化物之源極及汲極接觸;其中襯層厚度對蓋層厚度的厚度比為1:5或更低,且該等蓋層之其中至少一者更包含錫。 An integrated circuit comprising: the device of claim 1, wherein the underlayer is less than 40% of the total thickness; and the source and the drain of the metal telluride are contacted; wherein the thickness of the liner is opposite to the cap layer The thickness ratio of the thickness is 1:5 or less, and at least one of the cap layers further contains tin. 一種用以形成一電晶體裝置之方法,包含: 提供具有一矽通道區域的一基板;提供在該矽通道區域之上的一閘極電極;以及提供形成於該基板之上或之中且鄰近該矽通道區域的源極及汲極區域,其中該源極及汲極區域之每一者:在該矽通道區域之一高度之上延伸;包括在該閘極電極之下延伸的頂端區域;及採用雙層結構,其具有一總厚度,包含:矽或鍺或矽鍺的一p型襯層;以及具有鍺濃度超過80原子百分比的一p型蓋層,其中該襯層小於該總厚度的50%,且為在該閘極電極之下延伸的該頂端區域做內襯。 A method for forming a transistor device, comprising: Providing a substrate having a channel region; providing a gate electrode over the channel region; and providing source and drain regions formed on or in the substrate adjacent to the channel region, wherein Each of the source and drain regions: extending over a height of one of the channel regions; including a tip region extending below the gate electrode; and employing a two-layer structure having a total thickness, including a p-type liner of tantalum or niobium or tantalum; and a p-type cap layer having a tantalum concentration of more than 80 atomic percent, wherein the liner layer is less than 50% of the total thickness and is below the gate electrode The top end region of the extension is lined. 一種電晶體裝置,包含:一含矽基板,具有一通道區域;一閘極電極,在該通道區域之上;以及源極及汲極區域,形成於該基板之上或之中且鄰近該通道區域,其中該源極及汲極區域之每一者:在該通道區域之一高度之上延伸;包括在該閘極電極之下延伸的頂端區域;及採用雙層結構,其具有一總厚度,包含:矽或矽鍺的一p型襯層;以及具有鍺濃度超過80原子百分比的一p型蓋層,其中該襯層小於該總厚度的50%,且為在該閘極電極之下延伸的該頂端區域做內襯。 A transistor device comprising: a germanium-containing substrate having a channel region; a gate electrode over the channel region; and source and drain regions formed on or in the substrate adjacent to the channel a region, wherein each of the source and drain regions extends over a height of one of the channel regions; includes a top end region extending below the gate electrode; and has a two-layer structure having a total thickness a p-type liner comprising: tantalum or niobium; and a p-type cap layer having a niobium concentration of more than 80 atomic percent, wherein the liner layer is less than 50% of the total thickness and is below the gate electrode The top end region of the extension is lined. 一種電晶體裝置,包含: 一鍺基板,具有一通道區域;一閘極電極,在該通道區域之上;以及源極及汲極區域,形成於該基板之上或之中且鄰近該通道區域,其中該源極及汲極區域之每一者:在該通道區域之一高度之上延伸;包括在該閘極電極之下延伸的頂端區域;及採用雙層結構,其具有一總厚度,包含:鍺的一p型襯層;以及具有鍺濃度超過80原子百分比的一p型蓋層,其中該襯層小於該總厚度的50%,且為在該閘極電極之下延伸的該頂端區域做內襯。 A transistor device comprising: a substrate having a channel region; a gate electrode over the channel region; and a source and a drain region formed on or in the substrate adjacent to the channel region, wherein the source and the gate Each of the pole regions: extending over a height of one of the channel regions; includes a tip region extending below the gate electrode; and employing a two-layer structure having a total thickness comprising: a p-type of 锗a liner; and a p-type cap layer having a germanium concentration in excess of 80 atomic percent, wherein the liner is less than 50% of the total thickness and is lined with the top end region extending below the gate electrode. 如申請專利範圍第24項所述之裝置,其中每一襯層係包含於該對應蓋層之成分中。 The device of claim 24, wherein each of the lining layers is included in a composition of the corresponding cap layer.
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