[go: up one dir, main page]

TWI541338B - 合成氣冷卻器系統及操作方法 - Google Patents

合成氣冷卻器系統及操作方法 Download PDF

Info

Publication number
TWI541338B
TWI541338B TW101112059A TW101112059A TWI541338B TW I541338 B TWI541338 B TW I541338B TW 101112059 A TW101112059 A TW 101112059A TW 101112059 A TW101112059 A TW 101112059A TW I541338 B TWI541338 B TW I541338B
Authority
TW
Taiwan
Prior art keywords
syngas
synthesis gas
gasification
injection port
blended
Prior art date
Application number
TW101112059A
Other languages
English (en)
Other versions
TW201247862A (en
Inventor
彼得 貝爾
尼可拉斯 范赫克
伯納德 戴斯凱爾斯
Original Assignee
億諾斯生物有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 億諾斯生物有限公司 filed Critical 億諾斯生物有限公司
Publication of TW201247862A publication Critical patent/TW201247862A/zh
Application granted granted Critical
Publication of TWI541338B publication Critical patent/TWI541338B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/723—Controlling or regulating the gasification process
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/726—Start-up
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/86—Other features combined with waste-heat boilers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
    • C10K3/003—Reducing the tar content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
    • C10K3/003—Reducing the tar content
    • C10K3/005—Reducing the tar content by partial oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
    • C10K3/003—Reducing the tar content
    • C10K3/008—Reducing the tar content by cracking
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22—STEAM GENERATION
    • F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00—Methods of steam generation characterised by form of heating method
    • F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • F22B1/1838—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0877—Methods of cooling by direct injection of fluid
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0888—Methods of cooling by evaporation of a fluid
    • C01B2203/0894—Generation of steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/09—Mechanical details of gasifiers not otherwise provided for, e.g. sealing means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/15—Details of feeding means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1606—Combustion processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Industrial Gases (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Treatment Of Sludge (AREA)
  • Catalysts (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Description

合成氣冷卻器系統及操作方法
本申請案主張美國臨時專利申請案號61/516,667、61/516,704及61/516,646之利益，其全部皆在2011年4月6日提出，其全部之全文於此以參考方式併入本文。
本發明提供一種用以冷卻合成氣的方法及系統。更特別的是，摻合合成氣與冷卻再循環的合成氣以提供一摻合的合成氣。隨後，將該摻合的合成氣傳遞至合成氣冷卻器。
發明背景
微生物可經由氣體基質之發酵從一氧化碳(CO)製造乙醇及其它化合物。經常以合成氣形式將CO提供至發酵作為氣體基質的部分。氣化含碳材料以製造包含一氧化碳及氫的發生爐氣或合成氣體或合成氣在技藝中熟知。典型來說，此氣化方法包括含碳材料之部分氧化或缺氧氧化，其中將次化學計量的氧量供應至該氣化方法以促進一氧化碳之製造。
藉由在技藝中所描述的氣化方法製造之合成氣可熱且需要在下游加工及隨後發酵前冷卻。包含在氣化裝置中所產生的一氧化碳之熱合成氣在熱交換器或該氣化裝置的下游廢熱鍋爐中冷卻，參見例如美國專利案號6,435,139；美國專利案號7,587,995及美國專利案號7,552,701。有效及控制合成氣之冷卻在減少積垢上重要。
發明概要
用以冷卻合成氣的方法及系統提供有效的合成氣冷卻及造成在合成氣冷卻設備中的積垢程度減低。在一個觀點中，用以冷卻合成氣的方法包括以有效提供一在合成氣冷卻器的注入口處具有溫度約600℉至約1400℉之摻合的合成氣之量摻合合成氣與冷卻再循環的合成氣。該摻合的合成氣在合成氣冷卻器之注入口前改變流動方向至少一次。
在另一個觀點中，該合成氣混合系統包括一具有直徑DH的氣化艙及一具有直徑DC的合成氣再循環注入口。該合成氣再循環注入口在該氣化艙的遠端處進入該氣化艙。該系統包括具有直徑DM的氣化排出口。該氣化排出口與該氣化艙的遠端連續及該氣化排出口包括在進入合成氣冷卻器前至少一次改變方向。
在另一個觀點中，用以冷卻合成氣的方法包括以有效提供一在合成氣冷卻器的注入口處具有溫度在範圍約600℉至約1400℉內之摻合的合成氣之量摻合合成氣與冷卻再循環的合成氣。將該冷卻再循環的合成氣經由具有直徑DC的合成氣再循環注入口供應至具有直徑DH的氣化艙遠端，及DC/DH係約0.25至約0.75。
圖式簡單說明
本方法之上述及其它觀點、數個觀點的特徵及優點將從下列圖形中更明瞭。
第1圖闡明一合成氣混合系統。
第2圖顯示出一合成氣混合系統的下視圖。
相應的參考符號遍及數個描繪圖指示出相應的構件。熟練的人士將察知在圖形中的元件係為了簡易及清楚地闡明，其不必呈比例繪製。例如，在圖形中，某些元件的尺寸可相對於其它元件過大以幫助改善了解本方法及裝置的多個觀點。同樣地，經常不描出在商業可行的觀點中有用或需要之常見但是充分了解的元件，以幫助不妨礙地觀看這些不同觀點。
詳細說明
下列描述不欲以限制性觀念採用，而是僅用於描述出範例性具體實例之一般原理的目的。本發明之範圍應該參照申請專利範圍而決定。
該合成氣冷卻方法及系統係在有效提供有效合成氣冷卻及減低設備積垢的溫度下操作。該系統之設計提供有效的合成氣混合。
定義
除非其它方面有所定義，否則遍及本揭示的此專利說明書所使用之下列用語皆如下所定義及可包括下列所定義的定義之單或複數形式：
修飾任何量的用語"約"指為在真實世界條件中(例如，在實驗室、中型試驗工廠或製造設施中)所遭遇到的量之變量。例如，在混合物中所使用的成份或度量之量或定量當由"約"所修飾時，其包括典型在製造工廠或實驗室 的實驗條件下測量時所使用的變量及關心程度。例如，產物組分的量當由"約"修飾時，其包括在工廠或實驗室的多重實驗批次間之變量及在分析方法中固有的變量。不論是否由"約"所修飾，該等量皆包括那些量的同等物。於本文所描述及由"約"所修飾的任何定量亦可使用在本揭示中，如未由"約"修飾的量般。
如於本文中所使用，"含碳材料"指為富碳材料，諸如煤及石化製品。但是，在此專利說明書中，含碳材料包括任何碳材料，不論是呈固體、液體、氣體或漿狀態。在可視為含碳材料的許多項目當中，本揭示考慮到：含碳材料、含碳液體產物、含碳工業再循環液體、含碳都市固體廢棄物(MSW或msw)、含碳城鎮廢棄物、含碳農業材料、含碳林業材料、含碳木質廢棄物、含碳建築材料、含碳植物材料、含碳工業廢棄物、含碳發酵廢棄物、含碳石化副產品、含碳醇生產副產品、含碳煤、輪胎、塑膠、廢塑料、焦爐焦油、纖維軟物質(fibersoft)、木質素、黑液、聚合物、廢棄聚合物、聚對酞酸乙二酯(PETA)、聚苯乙烯(PS)、污水淤泥、動物廢棄物、莊稼殘渣、能源作物、森林加工殘餘物、木材加工殘餘物、家畜廢棄物、家禽廢棄物、食物加工殘餘物、發酵過程廢棄物、乙醇副產品、穀渣、用過的微生物或其組合。
用語"纖維軟物質(fibersoft)"或"纖維軟物質(Fibersoft)"或"纖維軟物質(fibrosoft)"或"纖維軟物質(fibrousoft)"意謂著由於多種物質的軟化及濃縮所產生之 含碳材料型式；在實施例中，含碳材料係經由多種物質的蒸氣熱壓而製造。在另一個實施例中，該纖維軟物質可包括蒸氣熱壓產生自纖維糊狀材料的城市、工業、商業、醫療廢棄物。
用語"都市固體廢棄物"或"MSW"或"msw"意謂著包含家用、商業、工業及/或殘餘廢棄物的廢棄物。
用語"合成氣"或"合成氣體"意謂著合成氣體，其係一提供給包含不同量的一氧化碳及氫之氣體混合物的名稱。製造方法的實施例包括天然氣或烴之蒸氣重組以產生氫、煤之氣化及在某些型式的廢棄物轉能源氣化設施中。該名稱來自其作為在產生合成天然氣(SNG)時的中間物及用於製造氨或甲醇的用途。合成氣可燃燒及經常使用作為燃料來源或作為用於其它化學物質之製造的中間物。
在一個觀點中，含碳材料之氣化提供合成氣。氣化包括生物質在限制性供應氧下之部分燃燒。所產生的氣體包括CO及H2。在此觀點中，合成氣將包含至少約20莫耳%的CO，在一個觀點中，約20至約100莫耳%的CO，在另一個觀點中，約30至約90莫耳%的CO，在另一個觀點中，約40至約80莫耳%的CO，及在另一個觀點中，約50至約70莫耳%的CO。該合成氣將具有CO/CO2比率至少約0.75。序號61/516,667、61/516,704及61/516,646描述出合適的氣化方法及裝置之某些實施例(美國序號61/516,667、61/516,704及61/516,646，其全部皆在2011年4月6日提出，及其全部皆以參考之方式併入本文)。離開該氣化器的合成氣將具 有溫度高於約1400℉，及在另一個觀點中，至少約1400℉至約3500℉。該氣化方法對焦油之破壞有效。
合成氣冷卻系統
如顯示在第1圖中，該氣體混合系統包括氣化艙100。合成氣再循環注入口300進入該氣化艙的遠端或引出區段200。在此觀點中，該合成氣再循環注入口300在外圓周處進入該氣化艙100的遠端200。該氣化注入口300切線地進入該氣化艙的遠端200及可呈角度約15至約165°(顯示為θ)，在另一個觀點中，約30至約150°，在另一個觀點中，約45至約135°，在另一個觀點中，約60至約120°，在另一個觀點中，約75至約105°，及在另一個觀點中，約85至約95°。
離開氣化器100的熱合成氣經由合成氣再循環注入口300接觸再循環冷卻的合成氣。該再循環冷卻的合成氣在該熱合成氣離開氣化器後及在該摻合的合成氣經由氣化排出口400進入合成氣冷卻器(無顯示)前的位置處接觸該熱合成氣。該氣化排出口400可為導管或輸送管。在此觀點中，"再循環冷卻的合成氣"指為已經在合成氣冷卻器中冷卻至溫度約350℉至約450℉的合成氣。
該方法包括以約0.1至約20之比率摻合再循環冷卻的合成氣與熱合成氣。在其它觀點中，再循環冷卻的合成氣對熱合成氣之比率可包括約1至約15，約1至約10，約1至約5，約1至約4，約1至約3，約1至約2及約1至約1。
該摻合的合成氣具有溫度約1400℉或較低，在另一個觀點中，約600℉至約1400℉，在另一個觀點中，約750℉ 至約1400℉，在另一個觀點中，約600℉至約1400℉，在另一個觀點中，約750℉至約1200℉，在另一個觀點中，約750℉至約900℉，在另一個觀點中，約750℉至約825℉，及在另一個觀點中，約600℉至約900℉。在此觀點中，熱電耦測量在合成氣冷卻器500的注入口處溫度。該熱電耦可配置在穿越合成氣冷卻器500的注入口直徑之任何位置處。
如於本文中所使用，"平均溫度"指為使用已知方法來決定穿越直徑的多個溫度，然後以平均表示出那些多個溫度度量。在一個觀點中，可使用電腦模型來提供平均溫度。在其它觀點中，可使用配備用於此測量的溫度計、紅外線檢測及其類似物來進行多個溫度測量。
該合成氣冷卻器的溫度、流速及組態有效防止再循環冷卻的合成氣及摻合的合成氣流入氣化艙200中。在此觀點中，通過該合成氣冷卻器的流大於每秒約24公尺。
如進一步顯示在第1圖中，該氣化艙的遠端200與氣化排出口400連續。該氣化排出口400可在進入合成氣冷卻器前改變方向至少一次。如顯示在第1圖中，該氣化排出口400以90°改變方向一次。在此觀點中，該氣化排出口400可改變方向至少一次，且任何方向改變每個各自獨立地在角度約15至約165°。
如在第1圖中闡明，該氣化艙200具有直徑DH，該合成氣再循環注入口300具有直徑DC，及該氣化排出口400具有直徑DM。該合成氣再循環注入口300位於一離氣化排出口 400距離(L)處。測量比率可如下：DC/DH：約0.25至約0.75，在另一個觀點中，約0.35至約0.65，及在另一個觀點中，約0.45至約0.55；L/DH：約1至約10，在另一個觀點中，約3至約8，及在另一個觀點中，約4至約6；及DH/DM：約0.5至約2.0，在另一個觀點中，約0.75至約1.75，及在另一個觀點中，約1.0至約1.5。
在另一個觀點中，該合成氣再循環注入口300可具有直徑約32至約42英吋，在另一個觀點中，約34至約40英吋，及在另一個觀點中，約35至約38英吋。該氣化排出口400可具有直徑約40至約52英吋，在另一個觀點中，約43至約49英吋，及在另一個觀點中，約45至約47英吋。
第2圖闡明該合成氣冷卻系統的下視圖。在此觀點中，該合成氣再循環注入口300在該氣化艙的外圓周600處進入氣化艙100。
在另一個觀點中，該合成氣再循環注入口300在氣化艙100上之位置處進入氣化艙100及初始氣體混合發生在氣化艙100上之位置處。在此組態中，任何形成的沈積物可向下落回氣化艙100中。
實施例 實施例1：合成氣冷卻器注入口溫度在熱傳遞及積垢上的效應
使用描述在下列的溫度及流速操作具有於此所描述的設計之氣化器。積垢因數如指示出般決定。
在600℉注入口溫度下對合成氣冷卻器之積垢因數：
在600℉注入口處的平均積垢因數為0.019Btu/(平方呎小時℉)。
使用較低的合成氣冷卻器注入口溫度及描述在下列的流速操作具有於此所描述的設計之氣化器。積垢因數如指示出般決定。
在1300℉注入口溫度處對合成氣冷卻器之積垢因數：
在1300℉注入口處的平均積垢因數為0.078Btu/(平方呎小時℉)。
雖然已經藉由特定的具體實例、實施例及其應用描述出於此所揭示的本發明，可由熟習該項技術者向那裏製得許多改質及變化而沒有離開本發明在申請專利範圍中所提出之範圍。
100‧‧‧氣化艙
200‧‧‧遠端
300‧‧‧合成氣再循環注入口
400‧‧‧氣化排出口
500‧‧‧合成氣冷卻器
600‧‧‧外圓周
θ‧‧‧角度
DH‧‧‧氣化艙直徑
DM‧‧‧氣化排出口直徑
DC‧‧‧合成氣再循環注入口直徑
L‧‧‧距離
第1圖闡明一合成氣混合系統。
第2圖顯示出一合成氣混合系統的下視圖。
100‧‧‧氣化艙
200‧‧‧遠端
300‧‧‧合成氣再循環注入口
400‧‧‧氣化排出口
500‧‧‧合成氣冷卻器
θ‧‧‧角度
DH‧‧‧氣化艙直徑
DM‧‧‧氣化排出口直徑
DC‧‧‧合成氣再循環注入口直徑
L‧‧‧距離

Claims (25)

  1. 一種用以冷卻合成氣的方法，該方法包括：以有效在合成氣冷卻器的注入口處提供一溫度600℉至1400℉之摻合的合成氣的量來摻合合成氣與冷卻再循環的合成氣，其中該摻合的合成氣在該合成氣冷卻器之注入口前改變流動方向至少一次，其中將冷卻再循環的合成氣經由具有直徑DC的合成氣再循環注入口供應至具有直徑DH的氣化艙遠端，及其中將該摻合的合成氣供應至具有直徑DM的氣化排出口，該氣化排出口與該氣化艙之遠端連續。
  2. 如申請專利範圍第1項之方法，其中該冷卻再循環的合成氣具有溫度350℉至450℉。
  3. 如申請專利範圍第1項之方法，其中該冷卻再循環的合成氣以0.1至20之比率與合成氣摻合。
  4. 如申請專利範圍第1項之方法，其中該摻合的合成氣具有溫度600℉至900℉。
  5. 如申請專利範圍第4項之方法，其中該摻合的合成氣具有溫度750℉至825℉。
  6. 如申請專利範圍第1項之方法，其中該合成氣再循環注入口在該氣化艙的外圓周處切線地進入該氣化艙之遠端。
  7. 如申請專利範圍第1項之方法，其中該合成氣再循環注入口以15至165°的角度進入該氣化艙的遠端。
  8. 如申請專利範圍第1項之方法，其中L(合成氣再循環注入口離氣化器排出口的距離)/DH係1至10。
  9. 如申請專利範圍第1項之方法，其中DC/DH係0.25至0.75。
  10. 如申請專利範圍第1項之方法，其中DH/DM係0.5至2.0。
  11. 一種合成氣混合系統，其包含：一具有直徑DH的氣化艙；一具有直徑DC的合成氣再循環注入口，該合成氣再循環注入口在該氣化艙的遠端處進入該氣化艙；及一具有直徑DM的氣化排出口，該氣化排出口與該氣化艙的遠端連續，該氣化排出口包括在進入合成氣冷卻器前至少一次改變方向。
  12. 如申請專利範圍第11項之氣體混合系統，其中該合成氣再循環注入口在該氣化艙的外圓周處切線地進入該氣化艙之遠端。
  13. 如申請專利範圍第11項之氣體混合系統，其中該合成氣再循環注入口以15至165°的角度進入該氣化艙的遠端。
  14. 如申請專利範圍第11項之氣體混合系統，其中L(合成氣再循環注入口離氣化器排出口的距離)/DH係1至10。
  15. 如申請專利範圍第11項之氣體混合系統，其中DC/DH係0.25至0.75。
  16. 如申請專利範圍第11項之氣體混合系統，其中DH/DM係0.5至2.0。
  17. 一種用以冷卻合成氣的方法，該方法包括：以有效在合成氣冷卻器的注入口處提供一溫度600 ℉至1400℉之摻合的合成氣的量來摻合合成氣與冷卻再循環的合成氣，其中將冷卻再循環的合成氣經由具有直徑DC的合成氣再循環注入口供應至具有直徑DH的氣化艙之遠端，及DC/DH係0.25至0.75，其中該摻合的合成氣在該合成氣冷卻器之注入口前改變流動方向至少一次，及其中將該摻合的合成氣供應至具有直徑DM的氣化排出口，該氣化排出口與該氣化艙之遠端連續。
  18. 如申請專利範圍第17項之方法，其中該冷卻再循環的合成氣具有溫度350℉至450℉。
  19. 如申請專利範圍第17項之方法，其中冷卻再循環的合成氣以0.1至20之比率與合成氣摻合。
  20. 如申請專利範圍第17項之方法，其中該摻合的合成氣具有溫度600℉至900℉。
  21. 如申請專利範圍第20項之方法，其中該摻合的合成氣具有溫度750℉至825℉。
  22. 如申請專利範圍第17項之方法，其中該合成氣再循環注入口在該氣化艙的外圓周處切線地進入該氣化艙之遠端。
  23. 如申請專利範圍第17項之方法，其中該合成氣再循環注入口以15至165°的角度進入該氣化艙之遠端。
  24. 如申請專利範圍第19項之方法，其中L(合成氣再循環注入口離氣化器排出口的距離)/DH係1至10。
  25. 如申請專利範圍第19項之方法，其中DH/DM係0.5至2.0。
TW101112059A 2011-04-06 2012-04-05 合成氣冷卻器系統及操作方法 TWI541338B (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201161516646P 2011-04-06 2011-04-06
US201161516704P 2011-04-06 2011-04-06
US201161516667P 2011-04-06 2011-04-06
US13/324,299 US9028571B2 (en) 2011-04-06 2011-12-13 Syngas cooler system and method of operation

Publications (2)

Publication Number Publication Date
TW201247862A TW201247862A (en) 2012-12-01
TWI541338B true TWI541338B (zh) 2016-07-11

Family

ID=46965027

Family Applications (5)

Application Number Title Priority Date Filing Date
TW101112070A TWI537375B (zh) 2011-04-06 2012-04-05 用於氣化含碳材料以製造合成氣的裝置及方法
TW101112059A TWI541338B (zh) 2011-04-06 2012-04-05 合成氣冷卻器系統及操作方法
TW101112053A TWI586922B (zh) 2011-04-06 2012-04-05 用於由合成氣發酵法發電的系統
TW101112052A TWI541339B (zh) 2011-04-06 2012-04-05 用以自含碳材料製造合成氣之製程的操作方法
TW101112062A TWI541337B (zh) 2011-04-06 2012-04-05 用於移除來自合成氣之焦油的裝置及方法

Family Applications Before (1)

Application Number Title Priority Date Filing Date
TW101112070A TWI537375B (zh) 2011-04-06 2012-04-05 用於氣化含碳材料以製造合成氣的裝置及方法

Family Applications After (3)

Application Number Title Priority Date Filing Date
TW101112053A TWI586922B (zh) 2011-04-06 2012-04-05 用於由合成氣發酵法發電的系統
TW101112052A TWI541339B (zh) 2011-04-06 2012-04-05 用以自含碳材料製造合成氣之製程的操作方法
TW101112062A TWI541337B (zh) 2011-04-06 2012-04-05 用於移除來自合成氣之焦油的裝置及方法

Country Status (20)

Country Link
US (9) US20120255301A1 (zh)
EP (9) EP2694432B1 (zh)
JP (6) JP6415320B2 (zh)
KR (6) KR101959581B1 (zh)
CN (8) CN103874751B (zh)
AR (4) AR085932A1 (zh)
AU (4) AU2012375190B2 (zh)
BR (5) BR112013025720B1 (zh)
CA (5) CA2832554C (zh)
CR (4) CR20130573A (zh)
EA (4) EA027557B1 (zh)
ES (5) ES2686289T3 (zh)
MX (4) MX2013011570A (zh)
MY (5) MY166661A (zh)
NZ (1) NZ710264A (zh)
PL (5) PL2694432T3 (zh)
RU (1) RU2603663C2 (zh)
TW (5) TWI537375B (zh)
WO (5) WO2013147918A2 (zh)
ZA (5) ZA201308267B (zh)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012528925A (ja) 2009-06-02 2012-11-15 サーモケム リカバリー インターナショナル インコーポレイテッド 一体化された燃料電池発電システムを有するガス化装置
CN103347601B (zh) 2010-11-05 2015-04-22 国际热化学恢复股份有限公司 固体循环系统与捕捉和转化反应性固体的方法
US20120255301A1 (en) 2011-04-06 2012-10-11 Bell Peter S System for generating power from a syngas fermentation process
AU2012252412B2 (en) * 2011-05-11 2015-06-25 Shell Internationale Research Maatschappij B.V. Process for producing purified synthesis gas
US8673181B2 (en) * 2011-08-11 2014-03-18 Kellogg Brown & Root Llc Systems and methods for starting up a gasifier
CN103958398B (zh) 2011-09-27 2016-01-06 国际热化学恢复股份有限公司 合成气净化系统和方法
CA2867054A1 (en) * 2012-03-29 2013-10-03 Her Majesty The Queen In Right Of Canada As Represented By The Ministeof Natural Resources Supplemental burner for conversion of biomass and related solid fuel
JP6248495B2 (ja) * 2013-09-18 2017-12-20 株式会社Ihi ガス化ガス中のタールの改質装置
US9631151B2 (en) * 2014-09-04 2017-04-25 Ag Energy Solutions, Inc. Apparatuses, systems, tar crackers, and methods for gasifying having at least two modes of operation
FI126357B (en) 2014-11-14 2016-10-31 Teknologian Tutkimuskeskus Vtt Oy Method and apparatus for gasification of raw material and gaseous product
US10774267B2 (en) * 2014-11-21 2020-09-15 Kevin Phan Method and device for converting municipal waste into energy
CN104845677A (zh) * 2015-03-30 2015-08-19 天津渤化永利化工股份有限公司 一种降低煤气化炉过热段入口合成气温度的方法
GB2539447B (en) 2015-06-16 2017-07-05 Sage & Time Llp Converting a carbonaceous feedstock into a product gas e.g. methane gas
CA3001536A1 (en) 2015-12-28 2017-07-06 Riken Compositions for use in recovering or ameliorating deterioration of physiological functions due to aging
ES2940894T3 (es) 2016-02-16 2023-05-12 Thermochem Recovery Int Inc Sistema y método de generación de gas producto de energía integrada de dos etapas
EP3210939A1 (en) 2016-02-24 2017-08-30 Casale SA A reactor for oxidation of ammonia in the production of nitric acid
ES2923073T3 (es) 2016-03-25 2022-09-22 Thermochem Recovery Int Inc Sistema de generación de producto gaseoso integrada en energía de tres fases
ES2966552T3 (es) * 2016-06-03 2024-04-22 Wildfire Energy Pty Ltd Producción de un gas y métodos para ello
GB2551314B (en) * 2016-06-06 2021-03-17 Kew Tech Limited Equilibium approach reactor
US10364398B2 (en) 2016-08-30 2019-07-30 Thermochem Recovery International, Inc. Method of producing product gas from multiple carbonaceous feedstock streams mixed with a reduced-pressure mixing gas
US10197014B2 (en) 2016-08-30 2019-02-05 Thermochem Recovery International, Inc. Feed zone delivery system having carbonaceous feedstock density reduction and gas mixing
US10197015B2 (en) 2016-08-30 2019-02-05 Thermochem Recovery International, Inc. Feedstock delivery system having carbonaceous feedstock splitter and gas mixing
JP6822025B2 (ja) * 2016-09-12 2021-01-27 株式会社Ihi タール改質装置
US11203725B2 (en) * 2017-04-06 2021-12-21 LLT International (Ireland) Ltd. Systems and methods for gasification of carbonaceous materials
US10329506B2 (en) 2017-04-10 2019-06-25 Thermochem Recovery International, Inc. Gas-solids separation system having a partitioned solids transfer conduit
US10717102B2 (en) 2017-05-31 2020-07-21 Thermochem Recovery International, Inc. Pressure-based method and system for measuring the density and height of a fluidized bed
US9920926B1 (en) 2017-07-10 2018-03-20 Thermochem Recovery International, Inc. Pulse combustion heat exchanger system and method
GB2567229A (en) * 2017-10-07 2019-04-10 Narasimhamurthy Prakashkumar Set-up for continuous production of H2 , CO, granulated fertiliser slag from the molten slag and sequestering CO2 from the flue exhaust
CN111278953A (zh) * 2017-10-12 2020-06-12 丹麦技术大学 一种气化单元、生产产品气的方法和这种方法的应用
US10099200B1 (en) 2017-10-24 2018-10-16 Thermochem Recovery International, Inc. Liquid fuel production system having parallel product gas generation
US11597906B2 (en) 2018-05-21 2023-03-07 Jupeng Bio(Hk) Limited System for obtaining protein-rich nutrient supplements from bacterial fermentation process
MY199603A (en) * 2018-11-19 2023-11-08 Lanzatech Inc Integration of fermentation and gasification
CN109652127A (zh) * 2018-11-30 2019-04-19 浙江天禄环境科技有限公司 一种利用低阶煤中挥发分制备包含c1-c2的烃类的方法和系统
US11447576B2 (en) * 2019-02-04 2022-09-20 Eastman Chemical Company Cellulose ester compositions derived from recycled plastic content syngas
US11312914B2 (en) 2019-02-04 2022-04-26 Eastman Chemical Company Gasification of plastics and solid fossil fuels to produce organic compounds
WO2021032770A1 (en) * 2019-08-21 2021-02-25 Ags Energy (Ireland) Limited A gasification apparatus and method
WO2021041018A1 (en) 2019-08-26 2021-03-04 Eastman Chemical Company 2-ethylhexanoyl substituted cellulose esters
US11555157B2 (en) 2020-03-10 2023-01-17 Thermochem Recovery International, Inc. System and method for liquid fuel production from carbonaceous materials using recycled conditioned syngas
GB2593231B (en) 2020-03-17 2022-03-23 Velocys Tech Limited Process
US11466223B2 (en) 2020-09-04 2022-10-11 Thermochem Recovery International, Inc. Two-stage syngas production with separate char and product gas inputs into the second stage
WO2022235436A1 (en) * 2021-05-05 2022-11-10 Eastman Chemical Company Recycle content triacetin
US11827859B1 (en) 2022-05-03 2023-11-28 NuPhY, Inc. Biomass gasifier system with rotating distribution manifold
EP4619491A1 (en) * 2022-11-16 2025-09-24 Sungas Renewables, Inc. Increased processing flexibility in gasification
CN116396783A (zh) * 2023-03-30 2023-07-07 中国科学院广州能源研究所 一种介质阻挡放电等离子体部分氧化粗燃气中焦油的方法
WO2024237861A1 (en) 2023-05-17 2024-11-21 Actinon Pte. Ltd. Integrated synthesis gas cleaning and thermal decomposition reactor
WO2025176299A1 (de) * 2024-02-22 2025-08-28 Glock Technology Gmbh Vorrichtung und verfahren zum vergasen von biomasse

Family Cites Families (121)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2815007A (en) * 1951-12-12 1957-12-03 Babcock & Wilcox Co Synthesis gas generator
US3787192A (en) * 1972-03-02 1974-01-22 Mcdowell Wellman Eng Co Process for coal gasification
NL178134C (nl) * 1974-06-17 1986-02-03 Shell Int Research Werkwijze en inrichting voor het behandelen van een heet produktgas.
US3963457A (en) * 1974-11-08 1976-06-15 Koppers Company, Inc. Coal gasification process
US3980592A (en) 1974-12-23 1976-09-14 Texaco Development Corporation Recovery of particulate carbon from synthesis gas
US4072625A (en) 1975-03-03 1978-02-07 Imperial Chemical Industries Limited Steam-hydrocarbon process
US4017271A (en) 1975-06-19 1977-04-12 Rockwell International Corporation Process for production of synthesis gas
US4172425A (en) * 1977-10-31 1979-10-30 Consumat Systems, Inc. Incinerator with improved means for transferring burning waste through the combustion chamber
DE2836175A1 (de) * 1978-08-18 1980-02-28 Metallgesellschaft Ag Verfahren zum vergasen fester, feinkoerniger brennstoffe
US4270493A (en) * 1979-01-08 1981-06-02 Combustion Engineering, Inc. Steam generating heat exchanger
US4326856A (en) * 1979-05-30 1982-04-27 Texaco Development Corporation Production of cleaned and cooled synthesis gas
US4248604A (en) * 1979-07-13 1981-02-03 Texaco Inc. Gasification process
US4279622A (en) * 1979-07-13 1981-07-21 Texaco Inc. Gas-gas quench cooling and solids separation process
US4308034A (en) * 1980-05-19 1981-12-29 Hoang Dinh C Apparatus for incinerating and gasifying biomass material
US4490156A (en) * 1981-06-10 1984-12-25 Texaco Inc. Partial oxidation system
IN156182B (zh) * 1981-11-16 1985-06-01 Shell Int Research
US4461674A (en) * 1981-12-31 1984-07-24 Allis-Chalmers Corporation Apparatus for recovery of different weight fractions of oil from shale
US4497637A (en) * 1982-11-22 1985-02-05 Georgia Tech Research Institute Thermochemical conversion of biomass to syngas via an entrained pyrolysis/gasification process
JPS61250092A (ja) * 1985-04-30 1986-11-07 Ishikawajima Harima Heavy Ind Co Ltd 固体有機物のガス化方法
US4749383A (en) * 1986-06-04 1988-06-07 Mansfield Carbon Products Method for producing low and medium BTU gas from coal
US4823742A (en) * 1987-12-11 1989-04-25 Shell Oil Company Coal gasification process with inhibition of quench zone plugging
US4805561A (en) * 1987-12-11 1989-02-21 Shell Oil Company Coal gasification process with inhibition of quench zone plugging
US4805562A (en) * 1987-12-11 1989-02-21 Shell Oil Company Coal gasification process with inhibition of quench zone plugging
US4823741A (en) 1987-12-11 1989-04-25 Shell Oil Company Coal gasification process with inhibition of quench zone plugging
US4865625A (en) * 1988-05-02 1989-09-12 Battelle Memorial Institute Method of producing pyrolysis gases from carbon-containing materials
DE3816340A1 (de) * 1988-05-13 1989-11-23 Krupp Koppers Gmbh Verfahren und vorrichtung zum kuehlen eines heissen produktgases, das klebrige bzw. schmelzfluessige partikel enthaelt
US4859213A (en) * 1988-06-20 1989-08-22 Shell Oil Company Interchangeable quench gas injection ring
DK315289A (da) * 1988-06-30 1989-12-31 Shell Int Research Fremgangsmaade til omdannelse af forureninger i en raa hoejtrykssyntesegasstroem med hoej temperatur
JPH0816229B2 (ja) * 1988-10-18 1996-02-21 三菱重工業株式会社 ガス中のタールおよびアンモニアの分解装置
US4959080A (en) * 1989-06-29 1990-09-25 Shell Oil Company Process for gasification of coal utilizing reactor protected interally with slag coalescing materials
DE3929766A1 (de) * 1989-09-07 1991-03-14 Krupp Koppers Gmbh Anlage fuer die erzeugung eines produktgases aus einem feinteiligen kohlenstofftraeger
DE4035293C1 (zh) 1990-11-07 1992-01-02 Metallgesellschaft Ag, 6000 Frankfurt, De
AU1449992A (en) 1992-03-05 1993-10-05 Technische Universiteit Delft Method and apparatus for combusting a carbonaceous material
DE4310447A1 (de) * 1993-03-31 1994-10-06 Krupp Koppers Gmbh Verfahren zur Kühlung von durch Vergasung gewonnenem Rohgas
JP2544584B2 (ja) * 1994-04-11 1996-10-16 株式会社日立製作所 石炭ガス化炉及び石炭ガス化炉の使用方法
ZA969708B (en) * 1995-12-15 1997-06-20 Krupp Polysius Ag Prevention of snowmen and removal of lumps in clinker coolers
RU2117687C1 (ru) * 1996-12-20 1998-08-20 Акционерное общество открытого типа "Энергетический институт им.Г.М.Кржижановского" Установка для термической переработки твердых топлив
US5944034A (en) * 1997-03-13 1999-08-31 Mcnick Recycling, Inc. Apparatus and method for recycling oil laden waste materials
US6033447A (en) 1997-06-25 2000-03-07 Eastman Chemical Company Start-up process for a gasification reactor
US5984998A (en) 1997-11-14 1999-11-16 American Iron And Steel Institute Method and apparatus for off-gas composition sensing
JP4137266B2 (ja) * 1999-01-28 2008-08-20 新日本製鐵株式会社 還元鉄製造方法
DE19949142C1 (de) * 1999-10-12 2001-05-10 Thermoselect Ag Vaduz Verfahren und Vorrichtung zur Entsorgung und Nutzbarmachung von Abfallgütern
US7090707B1 (en) * 1999-11-02 2006-08-15 Barot Devendra T Combustion chamber design for a quench gasifier
CA2416500C (en) 2000-07-25 2010-07-13 Bioengineering Resources, Inc. Methods for increasing the production of ethanol from microbial fermentation
DE10062320A1 (de) 2000-12-14 2002-06-20 Borsig Gmbh Abhitzekessel zum Kühlen von heißem Synthesegas
US20030046868A1 (en) * 2001-03-12 2003-03-13 Lewis Frederic Michael Generation of an ultra-superheated steam composition and gasification therewith
JP2003161414A (ja) * 2001-11-27 2003-06-06 Mitsubishi Heavy Ind Ltd ストーカ式廃棄物ガス化焼却装置及び焼却方法
US7022992B2 (en) 2002-01-17 2006-04-04 American Air Liquide, Inc. Method and apparatus for real-time monitoring of furnace flue gases
JP3824267B2 (ja) * 2002-11-20 2006-09-20 日本碍子株式会社 廃棄物からの可燃性ガス回収装置
JP4255279B2 (ja) * 2002-12-27 2009-04-15 独立行政法人科学技術振興機構 固体燃料ガス化システム
JP2005060533A (ja) * 2003-08-12 2005-03-10 Chugai Ro Co Ltd バイオマスガス化システムの燃料ガス改質装置
US20050095183A1 (en) * 2003-11-05 2005-05-05 Biomass Energy Solutions, Inc. Process and apparatus for biomass gasification
EP1531147A1 (en) * 2003-11-06 2005-05-18 CASALE ChEMICALS S.A. Catalytic secondary reforming process and reactor for said process
JP4312632B2 (ja) * 2004-03-03 2009-08-12 中外炉工業株式会社 バイオマスガス化システムおよびその運転方法
KR100637340B1 (ko) 2004-04-09 2006-10-23 김현영 고온 개질기
JP2006028211A (ja) * 2004-07-12 2006-02-02 Kawasaki Heavy Ind Ltd 廃棄物ガス化装置
DE102004039076A1 (de) 2004-08-12 2006-02-23 Sms Demag Ag Berührungslose Abgasmessung mittels FTIR-Spektroskopie an metallurgischen Aggregaten
JP2006131820A (ja) * 2004-11-09 2006-05-25 Ishikawajima Harima Heavy Ind Co Ltd 流動層ガス化方法及び装置
FI20055237A7 (fi) 2005-05-18 2006-11-19 Foster Wheeler Energia Oy Menetelmä ja laitteisto hiilipitoisen materiaalin kaasuttamiseksi
CN100543116C (zh) * 2005-08-19 2009-09-23 中国科学院过程工程研究所 制备无焦油产品气的贫氧流化燃烧下吸式气化方法及装置
MY148126A (en) 2005-10-21 2013-02-28 Taylor Biomass Energy Llc Process and system for gasification with in-situ tar removal
US7587995B2 (en) 2005-11-03 2009-09-15 Babcock & Wilcox Power Generation Group, Inc. Radiant syngas cooler
JP4790412B2 (ja) 2005-12-28 2011-10-12 中外炉工業株式会社 バイオマスガス化装置
WO2007112101A2 (en) 2006-03-24 2007-10-04 Silvagas Corporation Biomass gasification system
NZ546496A (en) 2006-04-07 2008-09-26 Lanzatech New Zealand Ltd Gas treatment process
FI118647B (fi) * 2006-04-10 2008-01-31 Valtion Teknillinen Menetelmä tervamaisia epäpuhtauksia sisältävän kaasun reformoimiseksi
AU2007238126B2 (en) * 2006-04-11 2013-08-15 Thermo Technologies, Llc Methods and apparatus for solid carbonaceous materials synthesis gas generation
NZ573217A (en) 2006-05-05 2011-11-25 Plascoenergy Ip Holdings S L Bilbao Schaffhausen Branch A facility for conversion of carbonaceous feedstock into a reformulated syngas containing CO and H2
WO2007131241A2 (en) 2006-05-05 2007-11-15 Plasco Energy Group Inc. A horizontally-oriented gasifier with lateral transfer system
CN103395743A (zh) * 2006-05-05 2013-11-20 普拉斯科能源Ip控股公司毕尔巴鄂-沙夫豪森分公司 使用等离子体炬热的气体重整系统
EP2015859A4 (en) 2006-05-05 2010-09-29 Plascoenergy Ip Holdings Slb GAS CONDITIONING SYSTEM
US7552701B2 (en) 2006-05-16 2009-06-30 Shell Oil Company Boiler for making super heated steam and its use
US20080169449A1 (en) 2006-09-08 2008-07-17 Eltron Research Inc. Catalytic membrane reactor and method for production of synthesis gas
US8444725B2 (en) 2006-09-11 2013-05-21 Purdue Research Foundation System and process for producing synthetic liquid hydrocarbon
CN1931959B (zh) * 2006-09-28 2010-10-20 武汉凯迪工程技术研究总院有限公司 利用生物质制造合成气的复合循环式高温气化工艺方法
EP1918352B1 (en) 2006-11-01 2009-12-09 Shell Internationale Researchmaatschappij B.V. Solid carbonaceous feed to liquid process
AU2008215182B2 (en) 2007-02-16 2011-09-22 Corky's Carbon And Combustion Pty Ltd Drying and gasification process
JP5547659B2 (ja) * 2007-02-27 2014-07-16 プラスコエナジー アイピー ホールディングス、エス．エル．、ビルバオ、シャフハウゼン ブランチ 加工原料／チャー変換とガス改質を伴うガス化方式
CN101285004B (zh) * 2007-04-11 2010-12-15 中国科学院工程热物理研究所 一种多功能能源装置
JP5001355B2 (ja) * 2007-04-18 2012-08-15 優久雄 片山 コークス炉ガス用改質器
US20080280236A1 (en) 2007-05-08 2008-11-13 Wright Roger G Solid fuel compositions, processes for preparing solid fuel, and combustion processes
EP2162387A4 (en) * 2007-07-09 2012-08-22 Range Fuels Inc METHODS AND APPARATUS FOR PRODUCING SYNTHESIS GAS
US20090014689A1 (en) * 2007-07-09 2009-01-15 Range Fuels, Inc. Methods and apparatus for producing syngas and alcohols
US8142530B2 (en) 2007-07-09 2012-03-27 Range Fuels, Inc. Methods and apparatus for producing syngas and alcohols
US8153027B2 (en) 2007-07-09 2012-04-10 Range Fuels, Inc. Methods for producing syngas
US8236071B2 (en) 2007-08-15 2012-08-07 General Electric Company Methods and apparatus for cooling syngas within a gasifier system
US9074152B2 (en) 2007-09-12 2015-07-07 General Electric Company Plasma-assisted waste gasification system
BRPI0818094A2 (pt) 2007-10-09 2015-07-14 Rentech Inc Método para remover alcatrão de um gás, e, sistema e método de gaseificação de biomassa
US8328889B2 (en) * 2007-12-12 2012-12-11 Kellogg Brown & Root Llc Efficiency of gasification processes
US7923476B2 (en) 2007-12-13 2011-04-12 Gyco, Inc. Method and apparatus for reducing CO2 in a stream by conversion to a syngas for production of energy
US7932298B2 (en) 2007-12-13 2011-04-26 Gyco, Inc. Method and apparatus for reducing CO2 in a stream by conversion to a syngas for production of energy
DE102007062413B3 (de) * 2007-12-20 2009-09-10 Conera Process Solutions Gmbh Verfahren und Vorrichtung zur Wiederaufbereitung von CO2-haltigen Abgasen
JP5166910B2 (ja) 2008-01-29 2013-03-21 三菱重工業株式会社 石炭ガス化炉の起動方法および起動装置
US20110035990A1 (en) 2008-02-28 2011-02-17 Krones Ag Method and device for converting carbonaceous raw materials
US8697405B2 (en) 2008-03-11 2014-04-15 Ineos Usa Llc Process for the production of ethanol and butanol
DE102008027858A1 (de) 2008-06-11 2009-12-17 Jörg HO Verfahren und Vorrichtung zur Erzeugung eines teerfreien Brenngases
JP5282455B2 (ja) * 2008-06-17 2013-09-04 株式会社Ｉｈｉ ガス化ガスの改質方法及び装置
US8592190B2 (en) * 2009-06-11 2013-11-26 Ineos Bio Limited Methods for sequestering carbon dioxide into alcohols via gasification fermentation
MX2010014197A (es) * 2008-06-20 2011-03-21 Ineos Usa Llc Métodos para aislar dióxido de carbono en alcoholes por medio de gasificación y fermentación.
EP2303993A4 (en) 2008-06-25 2013-01-23 Nexterra Systems Corp Generating clean syngas from biomass
US20100044643A1 (en) 2008-08-22 2010-02-25 Hunton Energy Holdings, LLC Low NOx Gasification Startup System
EP2334764A2 (en) * 2008-10-08 2011-06-22 Shell Internationale Research Maatschappij B.V. Process to prepare a gas mixture of hydrogen and carbon monoxide
US8192647B2 (en) 2008-12-19 2012-06-05 Enerkem Inc. Production of synthesis gas through controlled oxidation of biomass
TW201026395A (en) * 2008-12-24 2010-07-16 Conocophillips Co Tar-free gasification system and process
US8357216B2 (en) * 2009-04-01 2013-01-22 Phillips 66 Company Two stage dry feed gasification system and process
WO2010118022A2 (en) 2009-04-06 2010-10-14 Rentech, Inc. System and method for conditioning biomass-derived synthesis gas
US20100270505A1 (en) * 2009-04-22 2010-10-28 Range Fuels, Inc. Integrated, high-efficiency processes for biomass conversion to synthesis gas
US20100294179A1 (en) * 2009-05-18 2010-11-25 Covanta Energy Corporation Gasification combustion system
JP5400505B2 (ja) * 2009-07-06 2014-01-29 バブコック日立株式会社 コークス炉ガスの無触媒改質方法及び改質装置
WO2011014713A1 (en) * 2009-07-29 2011-02-03 James Matthew Mason System and method for downdraft gasification
US8759047B2 (en) * 2009-09-16 2014-06-24 Coskata, Inc. Process for fermentation of syngas from indirect gasification
US8597934B2 (en) * 2009-10-30 2013-12-03 Coskata, Inc. Process for controlling sulfur in a fermentation syngas feed stream
EP2459681A4 (en) * 2010-03-01 2012-08-29 Plasco Energy Group Inc CARBON CONVERSION SYSTEM WITH INTEGRATED PROCESSING ZONES
US8580152B2 (en) 2010-04-13 2013-11-12 Ineos Usa Llc Methods for gasification of carbonaceous materials
US8999021B2 (en) 2010-04-13 2015-04-07 Ineos Usa Llc Methods for gasification of carbonaceous materials
US8585789B2 (en) 2010-04-13 2013-11-19 Ineos Usa Llc Methods for gasification of carbonaceous materials
US8691115B2 (en) * 2010-04-29 2014-04-08 Indiana University Research And Technology Corporation System and method for controlling char in biomass reactors
US8377154B2 (en) * 2010-05-18 2013-02-19 Kellogg Brown & Root Llc Gasification system and process for maximizing production of syngas and syngas-derived products
CN201713504U (zh) * 2010-05-24 2011-01-19 中国科学院广州能源研究所 一种生物质复合气化装置
CN101906339A (zh) * 2010-08-05 2010-12-08 中国石油大学(北京) 煤气化和甲烷化一体化生产代用天然气的工艺及装置
US20120255301A1 (en) 2011-04-06 2012-10-11 Bell Peter S System for generating power from a syngas fermentation process

Also Published As

Publication number Publication date
AR085864A1 (es) 2013-10-30
TW201245436A (en) 2012-11-16
MY166661A (en) 2018-07-18
MY188922A (en) 2022-01-13
ZA201308269B (en) 2017-06-28
ES2656948T3 (es) 2018-03-01
EA201370218A1 (ru) 2014-08-29
NZ617114A (en) 2015-12-24
CA2832434C (en) 2020-06-30
WO2012138766A2 (en) 2012-10-11
EP2694626A2 (en) 2014-02-12
PL2694624T3 (pl) 2019-07-31
ZA201308265B (en) 2016-08-31
JP2014514416A (ja) 2014-06-19
CA2832431C (en) 2019-04-23
CN105907423A (zh) 2016-08-31
BR112013025720B1 (pt) 2021-11-30
PL2694432T3 (pl) 2018-11-30
BR112013025724A2 (pt) 2018-07-24
EP2694623A1 (en) 2014-02-12
EA201370215A1 (ru) 2014-08-29
EP2694625B1 (en) 2017-11-15
EP3381997A1 (en) 2018-10-03
JP6415320B2 (ja) 2018-10-31
BR112013025718B1 (pt) 2019-12-10
EP3381997B1 (en) 2020-06-03
JP2014510189A (ja) 2014-04-24
KR101884494B1 (ko) 2018-08-01
TWI537375B (zh) 2016-06-11
ES2660963T3 (es) 2018-03-26
TWI541339B (zh) 2016-07-11
WO2012138751A1 (en) 2012-10-11
AR085863A1 (es) 2013-10-30
JP6483733B2 (ja) 2019-03-13
AR085932A1 (es) 2013-11-06
EA027587B1 (ru) 2017-08-31
EP2694625A1 (en) 2014-02-12
KR101882544B1 (ko) 2018-07-26
EP3453747A1 (en) 2019-03-13
ES2708221T3 (es) 2019-04-09
RU2013149044A (ru) 2015-05-20
EA029848B1 (ru) 2018-05-31
MX2013011567A (es) 2013-11-01
CA2832554C (en) 2019-02-26
EP3556828A1 (en) 2019-10-23
CR20130574A (es) 2014-03-19
US20120255301A1 (en) 2012-10-11
CN103874749B (zh) 2017-05-17
BR112013025724B1 (pt) 2019-04-09
CR20130575A (es) 2014-03-13
WO2013147918A3 (en) 2013-11-28
BR112013025727A2 (pt) 2018-05-02
BR112013025722B1 (pt) 2020-10-27
CN103874750B (zh) 2016-02-03
US9051523B2 (en) 2015-06-09
JP6127323B2 (ja) 2017-05-17
MX2013011708A (es) 2014-04-25
KR20140058420A (ko) 2014-05-14
MY172095A (en) 2019-11-13
BR112013025727B1 (pt) 2020-10-27
AU2012240302A1 (en) 2013-11-14
US20120256128A1 (en) 2012-10-11
KR20140058421A (ko) 2014-05-14
TW201248085A (en) 2012-12-01
CN108611124A (zh) 2018-10-02
US8894885B2 (en) 2014-11-25
PL2694625T3 (pl) 2018-04-30
CN103874750A (zh) 2014-06-18
KR102026047B1 (ko) 2019-09-27
KR20180088920A (ko) 2018-08-07
CA3035043A1 (en) 2013-03-07
EP3301143B1 (en) 2019-06-12
US20150232771A1 (en) 2015-08-20
AU2012375190B2 (en) 2015-09-03
TW201249979A (en) 2012-12-16
AU2012240219A1 (en) 2013-11-14
JP2014512435A (ja) 2014-05-22
EA201370216A1 (ru) 2014-08-29
PL3301143T3 (pl) 2019-12-31
NZ617148A (en) 2015-09-25
AR085866A1 (es) 2013-10-30
US20120256129A1 (en) 2012-10-11
US20120256131A1 (en) 2012-10-11
BR112013025718A2 (pt) 2018-06-19
JP6129818B2 (ja) 2017-05-17
AU2012302236B2 (en) 2016-11-03
EP2694432B1 (en) 2018-06-06
KR101959581B1 (ko) 2019-03-18
MY181501A (en) 2020-12-24
CA2832431A1 (en) 2013-03-07
NZ710264A (en) 2017-04-28
AU2012302236A1 (en) 2013-11-14
ES2686289T3 (es) 2018-10-17
AU2012240302B2 (en) 2017-04-13
TWI541337B (zh) 2016-07-11
WO2012138762A1 (en) 2012-10-11
EP2694432A2 (en) 2014-02-12
JP2017133013A (ja) 2017-08-03
AU2012375190A1 (en) 2013-11-14
US20150037229A1 (en) 2015-02-05
US10487280B2 (en) 2019-11-26
EA027586B1 (ru) 2017-08-31
EP3301143A1 (en) 2018-04-04
NZ617115A (en) 2015-09-25
MX2013011570A (es) 2014-03-05
WO2013147918A2 (en) 2013-10-03
TW201245435A (en) 2012-11-16
RU2603663C2 (ru) 2016-11-27
EA201370217A1 (ru) 2014-08-29
US20120256130A1 (en) 2012-10-11
BR112013025720A2 (pt) 2018-05-02
JP2017101252A (ja) 2017-06-08
US20140246626A1 (en) 2014-09-04
EP2694626B1 (en) 2018-06-13
CA3035043C (en) 2021-07-13
TWI586922B (zh) 2017-06-11
PL2694623T3 (pl) 2018-05-30
US9028571B2 (en) 2015-05-12
KR20140056165A (ko) 2014-05-09
EP2694623B1 (en) 2017-12-06
CA2832419C (en) 2021-05-04
KR101934688B1 (ko) 2019-01-03
CN104039935A (zh) 2014-09-10
EP2694624A1 (en) 2014-02-12
JP6102007B2 (ja) 2017-03-29
ZA201308266B (en) 2016-08-31
CR20130576A (es) 2014-03-13
CR20130573A (es) 2014-03-13
CA2832419A1 (en) 2012-10-11
NZ617028A (en) 2015-09-25
CN103874749A (zh) 2014-06-18
BR112013025722A2 (pt) 2018-04-24
CA2832554A1 (en) 2013-10-03
CN108611124B (zh) 2021-07-20
ES2740002T3 (es) 2020-02-05
EP2694624B1 (en) 2018-10-31
EA027557B1 (ru) 2017-08-31
KR101959702B1 (ko) 2019-03-18
MY195696A (en) 2023-02-05
CN103874751A (zh) 2014-06-18
US20200017784A1 (en) 2020-01-16
WO2012138766A3 (en) 2013-03-21
US9745529B2 (en) 2017-08-29
KR20140061312A (ko) 2014-05-21
CN103874751B (zh) 2016-06-22
ZA201308271B (en) 2020-05-27
MX2013011571A (es) 2014-01-17
CN107880943A (zh) 2018-04-06
MX354778B (es) 2018-03-21
ZA201308267B (en) 2016-08-31
CA2832434A1 (en) 2012-10-11
CN103958649A (zh) 2014-07-30
JP2014515774A (ja) 2014-07-03
TW201247862A (en) 2012-12-01
KR20190006025A (ko) 2019-01-16
US9045706B2 (en) 2015-06-02
JP6698561B2 (ja) 2020-05-27
AU2012240219B2 (en) 2016-07-28
WO2013032537A1 (en) 2013-03-07

Similar Documents

Publication Publication Date Title
TWI541338B (zh) 合成氣冷卻器系統及操作方法
WO2009093107A1 (en) Agitating pyrolysis and gasification reactor
US20150129178A1 (en) Process for processing inorganic matter containing residue
OV Agricultural residues gasification, dependency of main operational parameters of the process on feedstock characteristics.
NZ617148B2 (en) Syngas cooler system and method of operation
UA111933U (uk) Спосіб виробництва суміші генераторного газу і біогазу газогенераторною та біогазовою установками