TWI481582B - A method of making mudstone red brick - Google Patents
A method of making mudstone red brick Download PDFInfo
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- TWI481582B TWI481582B TW102109241A TW102109241A TWI481582B TW I481582 B TWI481582 B TW I481582B TW 102109241 A TW102109241 A TW 102109241A TW 102109241 A TW102109241 A TW 102109241A TW I481582 B TWI481582 B TW I481582B
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- 239000011449 brick Substances 0.000 title claims description 54
- 238000004519 manufacturing process Methods 0.000 title claims description 18
- 239000000843 powder Substances 0.000 claims description 33
- 239000002699 waste material Substances 0.000 claims description 25
- 239000004973 liquid crystal related substance Substances 0.000 claims description 23
- 239000011521 glass Substances 0.000 claims description 21
- 238000005245 sintering Methods 0.000 claims description 13
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical group [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 12
- 230000004907 flux Effects 0.000 claims description 12
- 239000004088 foaming agent Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 6
- 239000004327 boric acid Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 125000005619 boric acid group Chemical group 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims 1
- 239000011734 sodium Substances 0.000 description 7
- 239000004927 clay Substances 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000004604 Blowing Agent Substances 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical group OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 230000005693 optoelectronics Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000004876 x-ray fluorescence Methods 0.000 description 2
- -1 ML stands for silt Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 238000009412 basement excavation Methods 0.000 description 1
- 238000009933 burial Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000010922 glass waste Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- Compositions Of Oxide Ceramics (AREA)
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Description
本發明是有關於一種磚及其製作方法，特別是指一種泥岩紅磚及其製作方法。 The invention relates to a brick and a manufacturing method thereof, in particular to a mudstone red brick and a manufacturing method thereof.
隨著經濟的蓬勃發展，事業廢棄物日益增加，也成為環境污染、影響氣候變遷的主因，因此保護環境的作法、永續經營的觀念也愈來愈被重視。 With the rapid development of the economy, the increasing amount of business waste has become the main cause of environmental pollution and affecting climate change. Therefore, the concept of environmental protection and sustainable management has become more and more important.
近年來國內代表性科技產業的其中之一就是光電產業，光電產業包括發光二極體(Light Emitting Diode,LED)製造業、液晶顯示器(Liquid Crystal Display,LCD)製造業…等，這類產業所產生之玻璃廢棄物當中，含有Ga、As、Si、P、Al、In…等成份，大多均屬於Ⅲ-V族元素，早期將此事業廢棄物是以固化中間處理及獨立掩埋最終處置。 In recent years, one of the representative technology industries in China is the optoelectronic industry. The optoelectronic industry includes Light Emitting Diode (LED) manufacturing, Liquid Crystal Display (LCD) manufacturing, etc. Among the glass wastes produced, most of them are components such as Ga, As, Si, P, Al, In, etc., which are classified as III-V elements. In the early stage, this commercial waste was disposed of by solidification intermediate treatment and independent burial.
由於上述成分之礦產來源已有枯竭之情形，加上此類元素資源具有特定之經濟價值，因此若能透過資源化之程序以回收有用資源，除可減少光電產業的廢棄物對環境的污染外，更能創造產業資源化之價值。 Since the mineral sources of the above components have been depleted and the resources of such elements have specific economic value, in addition to recycling the useful resources through the process of recycling, in addition to reducing the environmental pollution of the waste of the photovoltaic industry, It can create the value of industrial resources.
因此，本發明之目的，即在提供一種將廢液晶玻璃回收再利用而環保綠能的泥岩紅磚。 Accordingly, it is an object of the present invention to provide a mudstone red brick which is environmentally friendly and green energy by recycling waste liquid crystal glass.
於是本發明泥岩紅磚，以該泥岩紅磚整體總重量百分比為100%計，該泥岩紅磚包含：40wt%至60wt%的泥岩、26wt%至48wt%的廢液晶玻璃、1wt%至3wt%的助熔劑、1wt%至3wt%的發泡劑，及設定量的粉土。 Therefore, the mudstone red brick of the present invention is 100% of the total weight percentage of the mudstone red brick, and the mudstone red brick comprises: 40 wt% to 60 wt% of mudstone, 26 wt% to 48 wt% of waste liquid crystal glass, and 1 wt% to 3 wt%. a flux, 1 wt% to 3 wt% of a blowing agent, and a set amount of silt.
再者，本發明之另一目的，即在提供一種節省製作成本，且環保的泥岩紅磚的製造方法。 Furthermore, another object of the present invention is to provide a method for manufacturing a mudstone red brick which is environmentally friendly and which is environmentally friendly.
於是本發明泥岩紅磚的製造方法，包含以下步驟： Therefore, the method for manufacturing the mudstone red brick of the present invention comprises the following steps:
(a)將泥岩與廢液晶玻璃研磨成粉末。(b)調配一粉料並與水混拌成土團狀，以該粉料的總重量百分比為100%計，包括40wt%至60wt%的泥岩粉末、26wt%至48wt%的廢液晶玻璃粉末、1wt%至3wt%的助熔劑、1wt%至3wt%的發泡劑，及設定量的粉土。 (a) Grinding mudstone and waste liquid crystal glass into a powder. (b) compounding a powder and mixing it with water to form a dough, including 40% by weight to 60% by weight of mudstone powder, and 26% by weight to 48% by weight of waste liquid crystal glass powder, based on 100% by weight of the total weight of the powder. 1% to 3% by weight of flux, 1% to 3% by weight of blowing agent, and a set amount of silt.
(c)將土團狀的該粉料經壓製成形產出磚坯。(d)使該磚坯乾燥。(e)將乾燥後的磚坯燒結成紅磚，且最終燒結溫度為800℃~1000℃。 (c) The dough-like powder is subjected to press forming to produce a brick. (d) drying the slab. (e) The dried brick is sintered into a red brick, and the final sintering temperature is 800 ° C ~ 1000 ° C.
本發明之功效在於：使用廢液晶玻璃粉末及泥岩粉末製作泥岩紅磚，不僅節省礦材的採挖費用，也讓廢棄物量最小化與資源回收再利用量最大化，為永續經營且環保的泥岩紅磚的製作方法。 The effect of the invention is that the use of waste liquid crystal glass powder and mudstone powder to make mudstone red brick not only saves the mining cost of the mineral material, but also minimizes the amount of waste and maximizes the recycling of resources, and is a sustainable and environmentally friendly mudstone. How to make red bricks.
21‧‧‧步驟 21‧‧‧Steps
22‧‧‧步驟 22‧‧‧Steps
23‧‧‧步驟 23‧‧‧Steps
24‧‧‧步驟 24‧‧‧Steps
25‧‧‧步驟 25‧‧‧Steps
本發明之其他的特徵及功效，將於參照圖式的 實施方式中清楚地呈現，其中： Other features and effects of the present invention will be described with reference to the drawings. It is clearly presented in the embodiment, wherein:
圖1是一流程圖，說明本發明泥岩紅磚的製造方法的一較佳實施例。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a flow chart showing a preferred embodiment of a method of manufacturing a mudstone red brick of the present invention.
參閱圖1，本發明泥岩紅磚的製造方法之一較佳實施例，包含以下步驟： Referring to Figure 1, a preferred embodiment of a method for manufacturing a mudstone red brick of the present invention comprises the following steps:
步驟21，將泥岩與廢液晶玻璃研磨成粉末。 In step 21, the mudstone and the waste liquid crystal glass are ground into a powder.
由於台灣西南部地區之地質含有大量泥岩，每當大雨過後就有大量泥岩被沖刷而堆積於山腳下或河川下游處，泥岩含有很多膨脹性黏土，這些黏土的膠結力很弱，遇水則崩解分散，黏土的吸水膨脹性則造成旱季乾裂，雨季時雨水滲入較深處將黏土強度下降，而形成片狀、塊狀或泥流狀滑落，若以中度沖蝕(每年平均2~4mm/m2)而言，我國西南部泥岩區平均每年沖蝕量約為420萬立方公尺。因此泥岩不但易取得，成本低，且不需另外開挖以獲得黏土，而能達到廢物利用，節能減碳之功效。 Since the geology of southwestern Taiwan contains a lot of mudstone, a large amount of mudstone is washed away and piled up at the foot of the mountain or downstream of the river. After the heavy rain, the mudstone contains a lot of expansive clay. These clays have weak cementation and collapse when exposed to water. De-dispersion, the water-swelling property of clay causes dry cracking in the dry season. When the rainwater penetrates deeper in the rainy season, the strength of the clay decreases, and forms a flaky, massive or muddy flow. If it is moderately eroded (average 2~4mm per year) /m 2 ) In terms of average mud erosion in the southwestern part of China, the annual erosion amount is about 4.2 million cubic meters. Therefore, mudstone is not only easy to obtain, but also low in cost, and does not require additional excavation to obtain clay, but can achieve waste utilization, energy saving and carbon reduction.
本實施例使用的泥岩，經烘乾、研磨成粉末狀，其pH值為9，液限為40%，塑性指數為9%，屬於低塑性黏土(CL)，再由X光繞射分析(XRD)瞭解泥岩各個相位的組成生成物，其主要結晶形化合物為SiO2，次要結晶形化合物為Al2O3、Fe2O3、CaO、MgO、K2O、Na2O等，再由X光螢光分析(XRF)探討泥岩試樣中各元素含量，其中以C、O、Si、Al、Fe、Ca、K、Mg、Na等元素含量最高。 The mudstone used in this embodiment is dried and ground into a powder, and its pH value is 9, the liquid limit is 40%, the plasticity index is 9%, and it belongs to low plastic clay (CL), and then X-ray diffraction analysis ( XRD) Understand the composition of each phase of mudstone, the main crystalline compound is SiO 2 , and the secondary crystalline compounds are Al 2 O 3 , Fe 2 O 3 , CaO, MgO, K 2 O, Na 2 O, etc. X-ray fluorescence analysis (XRF) was used to investigate the content of various elements in mudstone samples, among which C, O, Si, Al, Fe, Ca, K, Mg, Na and other elements were the highest.
而步驟21中使用的廢液晶玻璃特別是指光電產 業在生產製造中切割後的下腳料、品質不良而淘汰的TFT廢液晶玻璃，廢液晶玻璃為非結晶形且活性很高的化合物組成，其化合物很類似SiO2、Al2O3、Fe2O3、CaO、MgO、K2O、Na2O等，由X光螢光分析(XRF)探討廢液晶玻璃試樣中各元素含量，其中以C、O、Si、Al、Fe、Ca、K、Mg、Na等元素含量最高。下表為本實施例中泥岩與廢液晶玻璃的成分列表。 The waste liquid crystal glass used in the step 21 is specifically a scrap waste liquid crystal glass which is cut after being cut in the production and manufacture of the photovoltaic industry, and the waste liquid crystal glass is amorphous and highly active. The compounds are very similar to SiO 2 , Al 2 O 3 , Fe 2 O 3 , CaO, MgO, K 2 O, Na 2 O, etc. The content of each element in the waste liquid crystal glass sample is investigated by X-ray fluorescence analysis (XRF). The content of elements such as C, O, Si, Al, Fe, Ca, K, Mg, Na is the highest. The following table is a list of the components of mudstone and waste liquid crystal glass in the present embodiment.
步驟22，調配一粉料並與水混拌成土團狀，以該粉料的總重量百分比為100%計，包括40wt%至60wt%的泥岩粉末、26wt%至48wt%的廢液晶玻璃粉末、1wt%至3wt%的助熔劑、1wt%至3wt%的發泡劑，及設定量的粉土。 Step 22, compounding a powder and mixing it with water to form a dough, comprising 40% by weight to 60% by weight of mudstone powder, and 26% by weight to 48% by weight of waste liquid crystal glass powder, based on 100% by weight of the total weight of the powder. 1% to 3% by weight of flux, 1% to 3% by weight of blowing agent, and a set amount of silt.
較佳地，以該粉料的總重量百分比為100%計，包括50wt%至60wt%的泥岩粉末、26wt%至38wt%的廢液晶玻璃粉末、1wt%至3wt%的助熔劑、1wt%至3wt%的發泡劑，及設定量的粉土。 Preferably, based on 100% by weight of the total powder, including 50% by weight to 60% by weight of mudstone powder, 26% by weight to 38% by weight of waste liquid crystal glass powder, 1% by weight to 3% by weight of flux, and 1% by weight to 3wt% foaming agent, and a set amount of silt.
而本實施例中，該助熔劑是選自於氧化鐵(Fe2O3)，或小蘇打(NaHCO3)，該發泡劑是選自於硼酸(H3BO3)，或碳酸鈉(Na2CO3)。 In this embodiment, the flux is selected from iron oxide (Fe 2 O 3 ) or baking soda (NaHCO 3 ), and the blowing agent is selected from boric acid (H 3 BO 3 ), or sodium carbonate ( Na 2 CO 3 ).
步驟23，將土團狀的該粉料倒入鋼製模型中，經壓坯機加壓而產出磚坯。 In step 23, the powder-like powder is poured into a steel mold and pressurized by a compactor to produce a brick.
步驟24，靜置該磚坯，採自然陰乾的方式，讓使該磚坯減少水分含量，而必需說明的是，除了自然陰乾的方式外，也可以利用將磚坯置入乾燥室而加快乾燥的速度。 In step 24, the brick is allowed to stand, and the natural dryness is adopted to reduce the moisture content of the brick. It must be noted that, in addition to the natural dry manner, the speed at which the brick can be placed in the drying chamber can be accelerated.
步驟25，將乾燥後的磚坯以漸進加熱方式燒結成紅磚，且最終燒結溫度為800℃~1000℃。 In step 25, the dried brick is sintered into a red brick by progressive heating, and the final sintering temperature is 800 ° C to 1000 ° C.
於本實施例中，是將粉土的重量百分比固定為10wt%，並搭配三種比例(40wt%、50wt%、60wt%)的泥岩粉末、三種比例(1wt%、2wt%、3wt%)的發泡劑、三種比例(1wt%、2wt%、3wt%)助熔劑，最後與26wt%至48wt%的廢液晶玻璃粉末調配、混拌產出磚坯，並在三種最終燒結溫度(800℃、900℃、1000℃)燒結製出泥岩紅磚，在上述各種成分的配合下約有60種的組合，並針對製得後的泥岩紅磚做抗壓強度與吸水率的測試，其結果分別如表二、三、四中所載，且製得的泥岩紅磚的實品照片如附件1。 In the present embodiment, the weight percentage of the silt is fixed to 10 wt%, and mixed with three proportions (40 wt%, 50 wt%, 60 wt%) of mudstone powder, three ratios (1 wt%, 2 wt%, 3 wt%) of hair. Foaming agent, three proportions (1wt%, 2wt%, 3wt%) flux, finally blended with 26wt% to 48wt% of waste liquid crystal glass powder, mixed to produce bricks, and at three final sintering temperatures (800 ° C, 900 ° C , 1000 ° C) sintering to produce mudstone red bricks, with the combination of the above various components, about 60 kinds of combinations, and test the compressive strength and water absorption rate of the prepared mudstone red bricks, the results are shown in Table 2 The actual photos of the mudstone red bricks, as contained in 3, 4, and 4, are attached as Annex 1.
在表二、三、四與附件1中，泥岩紅磚配比欄位是依廢液晶玻璃-泥岩-粉土-發泡劑-助熔劑的順序記載，其中TFT代表廢液晶玻璃粉末，M代表泥岩粉末，ML代表粉土，Na代表碳酸鈣(Na2CO3)，B代表硼酸(H3BO3)，Fe、NaH分別代表氧化鐵、小蘇打，而各成分後的數字代表各成分之重量百分比。 In Tables 2, 3, 4 and 1 of the table, the matching table of mudstone red bricks is recorded in the order of waste liquid crystal glass-mudstone-soil-foaming agent-fluxing agent, wherein TFT represents waste liquid crystal glass powder, and M represents Mudstone powder, ML stands for silt, Na stands for calcium carbonate (Na 2 CO 3 ), B stands for boric acid (H 3 BO 3 ), Fe and NaH represent iron oxide and baking soda, respectively, and the numbers after each component represent the components. Weight percentage.
在CNS 382的規範之下，普通磚依吸水率、抗壓強度分成三種，分別為： Under the specification of CNS 382, ordinary bricks are divided into three types according to water absorption rate and compressive strength, respectively:
1種磚：吸水率10%以下、抗壓強度300kgf/cm2以上。 1 type of brick: the water absorption rate is 10% or less, and the compressive strength is 300 kgf/cm 2 or more.
2種磚：吸水率13%以下、抗壓強度200kgf/cm2以上。 Two types of bricks: water absorption rate of 13% or less and compressive strength of 200 kgf/cm 2 or more.
3種磚：吸水率15%以下、抗壓強度150kgf/cm2以上。 3 kinds of bricks: water absorption rate of 15% or less, compressive strength of 150kgf/cm 2 or more.
而由表二、表三的實驗結果可知： From the experimental results in Table 2 and Table 3, we can see that:
1.在相同助熔劑1%與發泡劑1%的使用量下，泥岩添加量40%、50%至60%，在燒結溫度達1000℃時，燒結得到的泥岩紅磚符合3種磚的標準。 1. Under the same fluxing agent 1% and foaming agent 1%, the mudstone addition amount is 40%, 50% to 60%. When the sintering temperature reaches 1000 °C, the sintered mudstone red brick meets 3 kinds of bricks. standard.
2.在相同發泡劑3%、助熔劑1%的使用量下，泥岩添加量40%、50%至60%，在發泡劑為硼酸時，燒結溫度900℃燒結得到的泥岩紅磚即能符合3種磚的標準，而發泡劑為碳酸鈉時，燒結溫度需達1000℃得到的泥岩紅磚才能符合3種磚的標準。 2. In the same amount of foaming agent 3% and flux 1%, the amount of mudstone added is 40%, 50% to 60%. When the foaming agent is boric acid, the mudstone red brick obtained by sintering at 900 °C is It can meet the standards of 3 kinds of bricks, and when the foaming agent is sodium carbonate, the mudstone red brick obtained by sintering temperature up to 1000 °C can meet the standards of 3 kinds of bricks.
3.在發泡劑固定使用量為1%，而氧化鐵(助熔劑)的使用量由1%增加至3%，不論泥岩添加量為40%、50%或60%，燒結溫度達1000℃時得到的泥岩紅磚能夠符合3種磚的標準。 3. The amount of foaming agent used is 1%, and the amount of iron oxide (flux) is increased from 1% to 3%, regardless of the amount of mudstone added 40%, 50% or 60%, and the sintering temperature reaches 1000 °C. The mudstone red bricks obtained at the time can meet the standards of the three bricks.
4.發泡劑用硼酸、助熔劑用氧化鐵時，隨結燒溫度的提升、增加氧化鐵添加量或增加硼酸添加量，燒結後的泥岩紅磚在抗壓強度皆會提高。 4. When using iron oxide for boric acid and flux for the foaming agent, the compressive strength of the sintered mudstone red brick will increase as the sintering temperature increases, the amount of iron oxide added or the amount of boric acid added increases.
因此，本實施泥岩紅磚的製作方法製得泥岩紅磚確實能用做建築上的普通磚，而藉此回收、再利用光電產業的TFT廢液晶玻璃，及被沖涮的泥岩，是屬於環保、綠能的一種方法及紅磚，且在原物料的取得成本能降低，提高產品競爭力。 Therefore, the method for manufacturing the mudstone red brick can be used as a common brick in the building, and the TFT waste liquid crystal glass of the photovoltaic industry and the washed mudstone are recycled. A method of green energy and red brick, and the cost of obtaining raw materials can be reduced, and the competitiveness of products can be improved.
綜上所述，本發明利用廢液晶玻璃與泥岩，配合助熔劑、發泡劑之各種不同比例，將燒結溫度控制在1000℃上下製作而成泥岩紅磚，經實驗可知多能符合CNS的3種磚標準而在建築上應用，因此確實能夠有利將廢液晶玻璃與泥岩回收使用，不僅環保、綠能，節能減碳，且能大幅降低生產成本，故確實能達成本發明之目的。 In summary, the invention utilizes waste liquid crystal glass and mudstone, cooperates with different proportions of fluxing agent and foaming agent, and controls the sintering temperature to be 1000 ° C to make mudstone red brick. It can be seen that the experiment can meet the CNS 3 The brick type standard is applied to the building, so it is indeed advantageous to recycle the waste liquid crystal glass and the mud rock, which is not only environmentally friendly, green energy, energy saving and carbon reduction, but also can greatly reduce the production cost, so the object of the present invention can be achieved.
惟以上所述者，僅為本發明之較佳實施例而已，當不能以此限定本發明實施之範圍，即大凡依本發明申請專利範圍及專利說明書內容所作之簡單的等效變化與修飾，皆仍屬本發明專利涵蓋之範圍內。 The above is only the preferred embodiment of the present invention, and the scope of the present invention is not limited thereto, that is, the simple equivalent changes and modifications made by the patent application scope and patent specification content of the present invention, All remain within the scope of the invention patent.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| TW200402334A (en) * | 2003-07-11 | 2004-02-16 | Wen-Long Chyn | Method for processing and reducing waste glass materials into thermal insulation ceramic tiles |
| TW201131056A (en) * | 2010-03-10 | 2011-09-16 | Univ Nat Ilan | Method for manufacturing environmental friendly red bricks by sintering waste solar panel glass and the products thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200402334A (en) * | 2003-07-11 | 2004-02-16 | Wen-Long Chyn | Method for processing and reducing waste glass materials into thermal insulation ceramic tiles |
| TW201131056A (en) * | 2010-03-10 | 2011-09-16 | Univ Nat Ilan | Method for manufacturing environmental friendly red bricks by sintering waste solar panel glass and the products thereof |
Non-Patent Citations (1)
| Title |
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| 2012/10/03,簡聰有," 廢液晶玻璃添加泥岩燒製成輕質骨材及其工程性質之研究", 正修科技大學營建工程研究所碩士論文 * |
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