TWI465544B - Adhesive functional film - Google Patents

Description

Adhesive functional film

The present invention relates to a decorative film for applying a printing function to an adhesive functional film provided with an anthrone layer on a substrate, and for attaching or peeling a smooth surface several times. Further, the present invention relates to an adhesive functional film which is imparted with a function other than printing, such as ultraviolet blocking or infrared blocking. Further, the present invention relates to a sealing material, a cushioning material, and the like which are used in a wide range of fields in the industry.

The adhesive functional film provided with the fluorenone layer on the substrate is printed on the substrate, and the decorative film can be easily attached or peeled off several times on a smooth surface such as a window (Patent Literature) 2). In addition, various adhesive functional films are provided by imparting specific functions to the substrate and/or the laminate. A film provided with an fluorenone layer on the substrate or a film provided with a hard coat layer on the opposite surface of the fluorenone layer is attached to the liquid crystal screen to serve as a protective film for the screen.

For other applications, an adhesive functional film having an anthrone layer on a substrate is used as a sealing material, a cushioning material, and the like as an industrial material in various fields (Patent Document 2). However, the substrate containing the plastic has a low adhesion to the fluorenone layer, and there is a problem that peeling occurs at the interface between the substrate and the fluorenone layer during use. Therefore, the surface of the substrate is subjected to treatment with actinic rays such as corona discharge treatment, ultraviolet irradiation treatment, or plasma treatment. Further, there is provided a method of using an easy-adhesive film in which an adhesive layer containing a compound having improved adhesion is laminated on the surface of a substrate. However, if it is attached to the adherend, the following problems occur: the adhesion increases with time and the fluorenone layer adheres to the adherend, and if the adhesive functional film is to be peeled off, only the base is applied. The material is peeled off. Further, when direct sunlight is irradiated, the same problem is remarkably generated.

[Patent Document 1] Japanese Patent Publication No. 6-21711

[Patent Document 2] Japanese Patent Laid-Open No. Hei 10-95071

The present invention is an invention that solves the above problems. The present invention provides an adhesive functional film, and the adhesion between the substrate and the fluorenone layer does not decrease even when an adhesive functional film is used outdoors or indoors. Further, the present invention provides an adhesive functional film which does not adhere to the ketone layer and the adherend even when exposed to direct sunlight.

According to a first aspect of the invention, there is provided an adhesive functional film having an adhesive layer and an anthrone layer on at least one area of a substrate, and the resin contained in the adhesive layer is selected from the group consisting of an acid value of 7 to 110. A resin of a polyester resin.

According to a second aspect of the invention, the adhesive functional film according to the first aspect of the invention, wherein the carboxylic acid group is present in the polyester resin.

The adhesive functional film according to the first aspect of the invention, wherein the fluorenone layer contains at least one of the following fluorenone (1) to anthrone (4) and reacts with a hydroxyl group of the SiH group. a polyorganosiloxane obtained by crosslinking,

(1) an anthrone comprising a linear polyorganosiloxane having a vinyl group at both ends;

(2) an anthrone comprising a linear polyorganosiloxane having a vinyl group at both ends and a side chain;

(3) an anthrone comprising a branched polyorganosiloxane having a vinyl group at the end;

(4) An anthrone comprising a branched polyorganosiloxane having a vinyl group at the terminal and side chains.

The adhesive functional film according to the second aspect of the invention, wherein the fluorenone layer contains at least one of the following fluorenone (1) to anthrone (4) and reacts with a hydroxyl group of the SiH group. a polyorganosiloxane obtained by crosslinking,

(1) an anthrone comprising a linear polyorganosiloxane having a vinyl group at both ends;

(2) an anthrone comprising a linear polyorganosiloxane having a vinyl group at both ends and a side chain;

(3) an anthrone comprising a branched polyorganosiloxane having a vinyl group at the end;

(4) An anthrone comprising a branched polyorganosiloxane having a vinyl group at the terminal and side chains.

According to a fifth aspect of the invention, in the adhesive functional film according to the second aspect of the invention, the substrate and/or the laminate are provided with at least one specific function.

The above-mentioned laminate means an adhesive layer, an anthrone layer, and other functional layers and/or films and/or fabrics which are added as needed.

According to a sixth aspect of the invention, the adhesive functional film according to the third aspect of the present invention, wherein the substrate and/or the laminate are provided with at least one specific function.

The above-mentioned laminate means an adhesive layer, an anthrone layer, and other functional layers and/or films and/or fabrics which are added as needed.

According to a seventh aspect of the invention, in the adhesive functional film according to the fourth aspect of the invention, the substrate and/or the laminate are provided with at least one specific function.

The above-mentioned laminate means an adhesive layer, an anthrone layer, and other functional layers and/or films and/or fabrics which are added as needed.

[Effects of the Invention]

The printer of the adhesive functional film of the present invention can be attached to a smooth surface of a glazing or the like, and can be attached or peeled off several times. Since the adhesion between the substrate and the fluorenone layer is strong, the bonding place is not limited to the outdoor room, and even if it is peeled off from the adherend, there is no problem that only the fluorenone layer remains on the adherend.

In addition to the use of sealing materials or cushioning materials, the application of specific functions to the adhesive functional film can also be effectively used for ultraviolet cut-off film, infrared cut-off film, electromagnetic wave cut-off film, antistatic film, inkjet ink display. Various applications such as film and liquid crystal screen protection film.

The substrate used in the present invention is not particularly limited as long as it is a film containing various plastics. For example, a film containing a polyester, a polyamide, an acrylic resin or the like can be exemplified, but it is not limited to these films. In terms of handleability and adhesion to the ketone layer, a polyester film is preferably used. The thickness of the substrate is usually a thickness in the range of 4 μm to 400 μm.

An easily-adhesive polyester film obtained by treating the surface of the polyester film with actinic rays or a compound having improved adhesion to the surface layer of the polyester film can be used. Examples of the treatment method using actinic rays include corona discharge treatment, ultraviolet irradiation treatment, plasma treatment, and the like. Examples of the easily-adhesive component of the easy-adhesion laminated film include a polyurethane-based compound, a polyacryl-based compound, or a mixture thereof. Further, the surface of the easy-adhesion layer of the film in which the easy-adhesion layer is laminated may be treated by the actinic ray.

Even if the substrate for treating the actinic ray or the enamel layer is laminated after the layer is easily adhered to the substrate, the adhesion between the substrate and the fluorenone layer is insufficient. When the light resistance test is performed, peeling occurs. As a countermeasure against this, an adhesion improver is formulated into the anthrone layer. However, the adhesive layer of the present invention adheres the substrate to the fluorenone layer with a strong adhesive force even if the adhesiveness improver is not disposed in the fluorenone layer. That is, in the light resistance test, the anthrone layer does not peel off from the substrate.

As the adhesive layer, a resin selected from a polyester resin having an acid value of from 7 to 110 is used. Two or more types of polyester resins may be used in combination. When the acid value is less than the above range, the adhesion between the fluorenone layer and the adherend becomes too high over time, and it becomes difficult to peel off when the film of the present invention is peeled off from the adherend. A polyester resin having an acid value exceeding the above range is difficult to manufacture. A more preferable acid value is a polyester resin set in the range of 8 to 100.

Further, the polyester resin is preferably a water-soluble polyester resin or a water-dispersible polyester resin. The reason for this is that when the anti-motor property is imparted to the adhesive layer, the water-based adhesive layer coating liquid can make the coating liquid contain a lot of dispersibility in water and is more resistant than the organic solvent-based adhesive layer coating liquid. Antistatic agent with high electrostatic effect. For example, by containing 40 wt% to 70 wt% of an antistatic agent in the solid content of the adhesive layer, coating unevenness of the anthrone coating liquid applied to the adhesive layer can be prevented. In addition, when the ketone layer of the adhesive functional film of the present invention is adhered to the adherend and then peeled off, it is possible to prevent the occurrence of static electricity, that is, the so-called peeling electrification.

When the above resin is used, the acid group in the resin cross-links with the SiH group remaining in the fluorenone layer, and the amount of SiH groups remaining after the cross-linking reaction of the fluorenone itself can be reduced. As a result, it is possible to prevent an increase in the adhesion force caused by the reaction of the surface of the adherend, particularly the reaction between the glass surface and the fluorenone layer, at the time of adhesion. Examples of the acid group in the polyester resin include a carboxylic acid group, a sulfonic acid group, and a phosphoric acid group. The acid group is particularly preferably a carboxylic acid group.

The thickness of the adhesive layer is preferably in the range of 0.01 μm to 5 μm. More preferably, it is in the range of 0.1 μm to 3 μm. If the thickness of the adhesive layer is less than the above range, the fluorenone layer becomes easily detached from the substrate. When it exceeds the above range, the flexibility of the adhesive layer itself disappears and becomes a hard layer, and the adhesive strength of the adhesive layer to the substrate is lowered.

In the adhesive layer, a thermoplastic resin other than the above resin may be added in a range in which the effects of the present invention are not lowered. Examples of the thermoplastic resin include an acrylic resin, a polyamide resin, a xylene resin, an ethylene-vinyl acetate copolymer, an alkyd resin, and a urethane resin. One or more of these may be used.

As the anthrone used in the anthrone layer of the present invention, for example, an addition polymerization type anthrone polymer can be used. The addition polymerization type fluorenone resin is exemplified by polymerization by a platinum catalyst. As the properties of the anthrone layer suitable for the purpose of the present invention, it is required to have rubber-like flexibility, and the surface of the ketone layer is also convex and concave with respect to the surface of the adherend. Further, it is required to be easily peeled off with a small peeling force at the time of peeling.

As the anthrone of such a property, at least one anthrone selected from the group consisting of the following anthrone can be used for crosslinking: (1) a linear polyorganosiloxane having a vinyl group at both ends only An alkane ketone, (2) an anthrone comprising a linear polyorganosiloxane having a vinyl group at both ends and a side chain, and (3) a branched polyorganosiloxane having a vinyl group at the terminal only Anthrone, (4) an anthrone containing a branched polyorganosiloxane having a vinyl group at the terminal and side chains.

As one form of the fluorenone, a linear polyorganosiloxane having a vinyl group at both ends is a compound represented by the following formula (Chemical Formula 1).

(wherein R represents the following organic group, and n represents an integer)

(wherein R represents the following organic group, and m represents an integer)

The organic group (R) bonded to the ruthenium atom other than the vinyl group may be heterogeneous or the same species. Specific examples thereof include an alkyl group such as a methyl group, an ethyl group or a propyl group; and an aryl group such as a phenyl group or a tolyl group. Alternatively, a monovalent hydrocarbon group other than a part or all of a hydrogen atom to which a carbon atom of the group is bonded by a halogen atom, a cyano group or the like is used. R may be an organic group in which at least 50 mol% is a methyl group, and the diorganopolyoxyalkylene may be a single compound or a mixture of two or more kinds.

The anthrone having a linear polyorganosiloxane having a vinyl group at both ends and a side chain is a compound in which a part of R in the above formula (Chemical Formula 1) is a vinyl group. An anthrone including a branched polyorganosiloxane having a vinyl group at the terminal is a compound represented by the above formula (Chem. 2). The anthrone having a branched polyorganosiloxane having a vinyl group at the terminal and the side chain is a compound in which a part of R in the above formula (Chemical Formula 2) is a vinyl group.

Here, the crosslinking agent used for the crosslinking reaction may be a known crosslinking agent. An example of the crosslinking agent is an organic hydrogenated polyoxyalkylene. The organic hydrogenated polyoxyalkylene is one having at least three hydrogen atoms bonded to a halogen atom in one molecule. In terms of practical use, it is preferred that the two ≡SiH bonds in the molecule be 50% by weight of the total amount, and the remaining portion be at least three ≡SiH bonds in the molecule.

The platinum-based catalyst used for the crosslinking reaction may be a known platinum-based catalyst. Among them, chloroplatinic acid such as platinum dichloride acid or platinum tetrachloride, an alcohol compound of chloroplatinic acid, an aldehyde compound, or a chain salt of chloroplatinic acid and various olefins may be mentioned. The anthrone layer which has undergone the crosslinking reaction has a layer having flexibility such as an anthrone rubber, and this flexibility facilitates adhesion to the adherend.

The commercially available product of the anthrone material of the present invention may be in the form of a solventless type, a solvent type or an emulsion type, and any type may be used. Among them, the solvent-free type has advantages in terms of safety, hygiene, and air pollution because no solvent is used. In addition, the coating thickness of the anthrone layer must exceed 1.1 μm. Although it is set to a thickness of several millimeters, if it is a solvent type fluorenone or an emulsion type fluorenone, drying of the solvent at the time of application requires a lot of energy, and it becomes uneconomical. Therefore, the anthrone which is used in the present invention is preferably a solventless type of anthrone.

As described above, the adhesive layer of the present invention has a sufficiently high adhesive force to the adhesion of the fluorenone layer. If a higher adhesion is required, the anthrone layer can also contain a small amount of adhesion improver. The adhesion improving agent is preferably a compound containing a functional group reactive with a radical reaction. The compound may, for example, be an acrylic acid derivative, a methacrylic acid derivative or an allyl derivative. Among these derivatives, a compound having two or more, particularly three or more, unsaturated bonds is preferred. These compounds are compounds widely used as crosslinking agents for rubber, and examples thereof include acrylates or methacrylates of polyhydric alcohols, allyl esters of polycarboxylic acids, triallyl isocyanurates, and trienes. Cyanuric acid ester and the like.

In order to prevent the dirt or foreign matter on the surface of the fluorenone layer from adhering to or improve the processability of the adhesive functional film, the separator may be attached to the fluorenone layer. A resin film etc. are mentioned as a separator.

Usually, the thickness of the anthrone layer is preferably in the range of 1.1 μm to 3000 μm.

In the case of a decorative display film, it is preferably 1.1 μm to 50 μm. When the thickness of the fluorenone layer is less than 1.1 μm, it becomes difficult to adhere to the adherend, and the shear force in the direction of the adhesion surface of the adhesive functional film of the adherend becomes less than 1.0 N/cm. ² . When applied for a long time, the adhesive functional film may peel off. If the thickness of the fluorenone layer exceeds 50 μm, the amount of fluorenone used is increased, resulting in an increase in cost.

The thickness of the anthrone layer used for industrial applications such as sealing materials and cushioning materials is preferably from 30 μm to 500 μm. The adhesive functional film imparted with other specific functions is used to set the thickness of the anthrone layer in combination with the use thereof.

The application of the pressure-sensitive adhesive layer is carried out by dissolving and dispersing the above various polyester-based resins in an optimum solvent, and applying them to a substrate and drying them. As a coating method of the adhesive layer coating liquid and the ketone layer coating liquid, a multi-stage roll coater represented by a three-roll indirect gravure coater or a five-roll coater, direct gravure coating can be used. Cloth machine, bar coater, air knife coater, etc.

The material of the bonded body is usually glass, a resin plate, a metal plate, or a coated plate. The surface of the bonded body must be as smooth as possible. When the unevenness of the surface is large, it is difficult for the fluorenone layer to follow the unevenness, and it is impossible to adhere to each other.

Specific functions of the present invention mean ultraviolet blocking property, infrared blocking property, electromagnetic wave blocking property, antistatic property, electrical conductivity, deodorizing property, deodorizing property, antibacterial property, printability, ink receptivity, hydrophilicity, Anti-fog, water repellency, scratch resistance, thermal conductivity, etc.

The specific function described above is imparted by forming a functional layer by including a functionalizing agent in any one or more of the base material and the laminate.

Among the above functions, the ultraviolet blocking property is imparted by blending an inorganic or organic ultraviolet absorber with any of a substrate and a laminate, preferably a transparent substrate.

The infrared ray blocking property can be imparted by blending an inorganic or organic infrared absorbing agent into any of a transparent substrate and a laminate. Further, a film of a metal oxide may be formed on the surface of the substrate to impart infrared reflectance.

The electromagnetic wave blocking property can be imparted by disposing an inorganic or organic conductive agent or a magnetic material to any of the substrate and the laminate. Further, it can be provided by forming a thin film of a metal or a metal oxide on a substrate, and can be provided by laminating a metal-plated fabric on a substrate.

The antistatic property and the electrical conductivity can be imparted by disposing an antistatic agent or a conductive agent to any of the substrate and the laminate, preferably the substrate, and by forming a metal or a metal oxide on the substrate. The film is given.

The deodorizing property and the deodorizing property can be imparted by disposing an inorganic or organic deodorant or a deodorant to any of the substrate and the laminate, preferably the substrate.

The antibacterial property can be imparted by mixing an inorganic or organic antibacterial agent to any of the substrate and the laminate, preferably the substrate, and by laminating an active layer containing a photocatalyst such as titanium oxide on the substrate. Give.

The printability can be imparted by modifying the surface of the substrate to improve the adhesion of the printing ink or the carbon powder. Further, by forming a hydrophilic polymer layer or a hydrophilic polymer layer containing porous fine particles on the surface of the substrate, the inkjet ink can be improved in acceptability. The obtained functional film can be used as a poster and other advertising media on the wall or signboard of a building according to the printed or copied content, and can be attached as a meeting material or a method of contact and notification. Use it on a whiteboard or wall or signboard.

Hydrophilicity and antifogging property can be imparted by blending or laminating a hydrophilic agent or an antifogging agent on a substrate. Further, it can be imparted by a hydrophilic layer, an antifogging layer or a photocatalytic active layer on the surface layer of the substrate.

The water repellency can be imparted by forming a water-repellent layer containing a fluorine compound-containing monomer or a composite of a fluorine compound and a photocatalyst on the surface of the substrate.

Scratch resistance can be imparted by forming a hard coat layer containing an organic substance or an inorganic substance or a composite thereof on the surface of a substrate. The obtained functional film is used as a film for protecting the surface of a thin film switch, an anti-glare filter, a touch panel, or the like in a liquid crystal display unit or an input unit of a home appliance, an office automation (OA) machine, an information device, or the like. And sticking.

The thermal conductivity may be such that the laminate contains a thermally conductive filler. Examples of the thermally conductive filler include alumina, boron nitride, aluminum nitride, zinc oxide, aluminum oxide, tantalum carbide, quartz, and aluminum hydroxide.

In the present invention, the method of laminating the substrate and the adhesive layer and the laminate other than the fluorenone layer is arbitrary. That is, the film obtained by individually molding can be bonded by an adhesive or a binder or heat adhesion. It may be a method of direct integration by a coating method, a coating method, an extrusion lamination method, or the like. This direct integration approach is particularly good from an economic point of view.

[Example]

The invention will be more specifically illustrated by the following examples.

[Formation of ink imaging layer]

The following developer layer coating liquid was dispersed by a disperser to prepare a coating liquid. The coating liquid was applied onto one surface of a polyethylene terephthalate film having a thickness of 50 μm, and dried to form a developing layer for an ink jet printer having a thickness of 25 μm.

Imaging layer coating solution

Synthesis of amorphous ceria 4.2 parts by weight

Hydrophilic urethane resin 6.2 parts by weight

Polyacrylate aqueous solution (solid content: 30%) 1 part by weight

A dicyandiamide-based resin aqueous solution (solid content: 25%) 2 parts by weight

Water 37.6 parts by weight

Methanol 49 parts by weight

Total 100 parts by weight

[Synthesis of Resin of Adhesive Layer]

The method for synthesizing the resin contained in the adhesive layers of Examples 1 to 4 and Comparative Examples 1 to 2 is as follows.

The starting compounds shown in Tables 1 and 2 were added to the reaction vessel in the amounts shown in Tables 1 and 2 (moles). The esterification reaction was carried out for 3.5 hours under a nitrogen gas stream at a pressure of 0.3 MPaG and a temperature of 260 °C. To the obtained esterified product, antimony trioxide 2.5 × 10 ^-4 mol / acidic component 1 mol was added. The mixture was depressurized to 0.5 hPa, and subjected to a polycondensation reaction at 280 ° C for 3 hours to obtain a polyester. Then, the depolymerizing agents shown in Tables 1 and 2 were added to the polyester in the amounts shown in Table 1, Table 2 (molar amount). The depolymerization reaction was carried out at 250 ° C for 2 hours under normal pressure to obtain a polyester resin having the characteristics of Tables 1 and 2. Further, hot water at 90 ° C was added to prepare a polyester aqueous solution having a solid content of 20%.

The method for synthesizing the resin contained in the adhesive layers of Comparative Examples 3 to 4 is as follows.

The starting compounds shown in Table 3 were added to the reaction vessel in the amounts shown in Table 3 (moles), and azobisisobutyronitrile 5.0 × 10 ^-2 moles was added to the reaction vessel. The reaction was carried out at 115 ° C for 3 hours under a nitrogen gas stream. After the reaction was completed, dimethylethanolamine was used to neutralize the equivalent. Further, butyl cellosolve was added to obtain an acrylic copolymer solution having a solid content of 20% and having the characteristics of Table 2.

[Formation of Adhesive Layer]

The resin solutions of Examples 1 to 4 and Comparative Examples 1 to 4 were applied to the opposite surfaces of the above-mentioned substrate, and dried to form an adhesive layer having a thickness of 0.3 μm.

[Formation of an anthrone layer]

The following fluorenone coating liquid was applied to the adhesive layers of Examples 1 to 4 and Comparative Examples 1 to 4. Thereafter, the fluorenone was crosslinked by heating at 150 ° C for 100 seconds. An anthrone layer having a thickness of 25 μm was formed to prepare a film for inkjet recording.

Anthrone coating solution

100 parts by weight of a linear polyorganone (containing a crosslinking agent) having a vinyl group at both ends

(solvent-free type) (trade name "X-62-1347" manufactured by Shin-Etsu Chemical Co., Ltd.)

Platinum catalyst (trade name "CAT-PL-56" manufactured by Shin-Etsu Chemical Co., Ltd.) 2 parts by weight

The performance of each sample was evaluated according to the following evaluation method.

[Method for Measuring Acid Value of Resin]

A sample of 30 g was accurately weighed into a stoppered flask. (Sg)

A mixed solvent (toluene:methanol = 9:1 by volume) of 100 mL was added to dissolve the sample. A 1% phenolphthalein solution was added thereto as an indicator. The titration was carried out by using a 0.1 mol/L alcoholic potassium hydroxide solution as a point at which the red color remained for 30 seconds. (A mL)

The blank test was performed by the same operation. (B mL)

Acid value (mgKOH/g) = (A-B) × f × 56.1 / S

A in the above formula: the amount of 0.1 mol/L of the alcoholic potassium hydroxide solution required in the sample (mL)

B: The amount of 0.1 mol/L alcoholic potassium hydroxide solution required in the blank test (mL)

f: molar concentration of 0.1 mol/L alcoholic potassium hydroxide solution

S: sample extraction amount (g)

Evaluation method

Light resistance test

A sample obtained by cutting the film of each of the examples and the comparative examples into an appropriate size was prepared. The ketone layer of the cut sample was placed on the transparent glass. The carbon arc was irradiated for 100 hours in the carbon arc light resistance test on the glass side. The following samples of A and B were evaluated using this cut sample.

A. Adhesion evaluation of adhesive layer and anthrone layer

The edge portion of the sample was cut with a finger and the degree of peeling of the anthrone layer was evaluated on the basis of the following criteria. The evaluation results are shown in Table 1.

○: No peeling occurred at all.

△: Partially peeled off between the adhesive layer and the anthrone layer.

×: Completely peeled off.

B. Peel evaluation of the anthrone layer when the glass is attached

The polyethylene terephthalate film of the cut sample adhered to the glass was peeled off by 180° peeling, and the degree of peeling of the anthrone layer was evaluated for the glass based on the following criteria. The evaluation results are shown in Table 1.

○: The anthrone layer was completely peeled off from the glass.

△: The fluorenone layer was transferred and adhered to the glass due to agglomeration failure of a part of the fluorenone layer.

X: The fluorenone layer was transferred and adhered to the glass due to aggregation failure of the fluorenone layer on the entire surface of the affixing portion.

2. Image formation

In the samples of the above Examples 1 to 3 and Comparative Examples 1 to 5, in order to protect the surface, a transparent polyethylene terephthalate (PET) film having a thickness of 25 μm was attached as a separator. Combined with the fluorenone level. Each sample was cut into A4 size to prepare a sheet sample. A full-color image was formed on the imaging layer of the sheet sample using an inkjet printer PM-900C (dye-based ink) manufactured by Seiko Epson. A clear full color image is formed in any sheet sample.

Claims (7)

An adhesive functional film having an adhesive layer and an anthrone layer on at least one area of a substrate, and the resin contained in the adhesive layer is selected from the group consisting of polyesters having an acid value of 7 to 110 Resin. The adhesive functional film according to claim 1, wherein a carboxylic acid group is present in the polyester resin. The adhesive functional film according to claim 1, wherein the fluorenone layer comprises at least one of the following fluorenone (1) to anthrone (4) reacted with a hydroxyl group of the SiH group. a polyorganosiloxane obtained by crosslinking, (1) an anthrone having a linear polyorganosiloxane having a vinyl group at both ends; (2) a straight group having a vinyl group at both ends and a side chain a fluorenone of a chain polyorganosiloxane; (3) an fluorenone containing a branched polyorganosiloxane having a vinyl group at the terminal; (4) a branched polyorganic having a vinyl group at the terminal and the side chain Anthrone of a decane. The adhesive functional film according to claim 2, wherein the fluorenone layer comprises at least one of the following fluorenone (1) to anthrone (4) reacted with a hydroxyl group of the SiH group. a polyorganosiloxane obtained by crosslinking, (1) an anthrone having a linear polyorganosiloxane having a vinyl group at both ends; (2) a straight group having a vinyl group at both ends and a side chain a fluorenone of a chain polyorganosiloxane; (3) an fluorenone containing a branched polyorganosiloxane having a vinyl group at the terminal; (4) a branched polyorganic having a vinyl group at the terminal and the side chain Anthrone of a decane. The adhesive functional film according to claim 2, wherein the substrate and/or the laminate are provided with at least one specific function, and the laminate refers to an adhesive layer, an anthrone layer, and the like. Additional functional layers and/or films and/or fabrics as needed. The adhesive functional film according to claim 3, wherein the substrate and/or the laminate are provided with at least one specific function, and the laminate refers to an adhesive layer, an anthrone layer, and the like. Additional functional layers and/or films and/or fabrics as needed. The adhesive functional film according to Item 4, wherein the substrate and/or the laminate are provided with at least one specific function, and the laminate refers to an adhesive layer, an anthrone layer, and the like. Additional functional layers and/or films and/or fabrics as needed.