TWI447861B - Semiconductor device and method of manufacturing same - Google Patents
Semiconductor device and method of manufacturing same Download PDFInfo
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Description
本發明係有關於半導體裝置及其製造方法,特別係有關於金屬氧化物半導體與記憶體及其製造方法。The present invention relates to a semiconductor device and a method of fabricating the same, and more particularly to a metal oxide semiconductor and a memory and a method of fabricating the same.
在半導體裝置中,舉例來說,會同時需要金屬氧化半導體與記憶體。半導體裝置中的金屬氧化半導體與記憶體一般係以分開的製程,分別形成在不同的基板上。於封裝過程中,利用打線將不同基板上的金屬氧化半導體與記憶體作電性連接。因此,半導體裝置的製程複雜且成本高。此外,金屬氧化半導體與記憶體之間電性連接的失誤率會比較高,且效果不佳。In a semiconductor device, for example, a metal oxide semiconductor and a memory are required at the same time. The metal oxide semiconductor and the memory in the semiconductor device are generally formed in separate processes and formed on different substrates. In the packaging process, the metal oxide semiconductor on different substrates is electrically connected to the memory by wire bonding. Therefore, the manufacturing process of the semiconductor device is complicated and costly. In addition, the error rate of electrical connection between the metal oxide semiconductor and the memory is relatively high, and the effect is not good.
本發明係有關於一種半導體裝置及其製造方法。相較於一般技術,實施例之半導體裝置的製造方法簡單且成本低。此外,舉例來說,記憶體與金屬氧化半導體之間可具有良好的電性連接。The present invention relates to a semiconductor device and a method of fabricating the same. The manufacturing method of the semiconductor device of the embodiment is simple and low in cost compared to the general technique. Further, for example, there may be a good electrical connection between the memory and the metal oxide semiconductor.
提供一種半導體裝置的製造方法。方法包括於基板上形成第一半導體元件與第二半導體元件。基板係單一。第一半導體元件係記憶體。第二半導體元件包括金屬氧化物半導體、電容或電阻。A method of fabricating a semiconductor device is provided. The method includes forming a first semiconductor component and a second semiconductor component on a substrate. The substrate is single. The first semiconductor element is a memory. The second semiconductor component includes a metal oxide semiconductor, a capacitor, or a resistor.
提供一種半導體裝置。半導體裝置包括基板、第一半導體元件與第二半導體元件。第一半導體元件係記憶體。第二半導體元件包括金屬氧化物半導體、電容或電阻。第一半導體元件與第二半導體元件係形成在單一基板上。A semiconductor device is provided. The semiconductor device includes a substrate, a first semiconductor element, and a second semiconductor element. The first semiconductor element is a memory. The second semiconductor component includes a metal oxide semiconductor, a capacitor, or a resistor. The first semiconductor element and the second semiconductor element are formed on a single substrate.
下文特舉較佳實施例,並配合所附圖式,作詳細說明如下:DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the preferred embodiment will be described in detail with reference to the accompanying drawings.
第1圖繪示根據一實施例之半導體裝置的剖面圖。請參照第1圖,基板2包括不同的第一基板區4與第二基板區6、第二基板區8、第二基板區10與第二基板區12。於實施例中,基板2係單一。此外,第一半導體元件配置在第一基板區4上。舉例來說,不同的第二半導體元件分別配置在第二基板區6、第二基板區8、第二基板區10與第二基板區12上。1 is a cross-sectional view of a semiconductor device in accordance with an embodiment. Referring to FIG. 1, the substrate 2 includes different first substrate regions 4 and second substrate regions 6, second substrate regions 8, second substrate regions 10, and second substrate regions 12. In the embodiment, the substrate 2 is single. Further, the first semiconductor element is disposed on the first substrate region 4. For example, different second semiconductor elements are disposed on the second substrate region 6, the second substrate region 8, the second substrate region 10, and the second substrate region 12, respectively.
請參照第1圖,第一基板區4上之第一半導體元件包括第三摻雜區14,配置於基板2中。第一摻雜區16配置於第三摻雜區14中。第二摻雜區18配置於第一摻雜區16中。舉例來說,包括第一介電層20與第二介電層22的介電結構24配置於第二摻雜區18之間的第一摻雜區16上,並延伸至第二摻雜區18上。第一電極層26配置於介電結構24上。配置袋摻雜區28。配置間隙壁30於介電結構24與第一電極層26的側壁上。舉例來說,基板2、第一摻雜區16與袋摻雜區28具有第一導電型例如P導電型。第三摻雜區14與第二摻雜區18具有相反於第一導電型的第二導電型例如N導電型。於實施例中,第一基板區4上的第一半導體元件係記憶體。舉例來說,第二摻雜區18係用作位元線。第一電極層26係用作字元線。Referring to FIG. 1 , the first semiconductor element on the first substrate region 4 includes a third doped region 14 disposed in the substrate 2 . The first doping region 16 is disposed in the third doping region 14. The second doping region 18 is disposed in the first doping region 16. For example, the dielectric structure 24 including the first dielectric layer 20 and the second dielectric layer 22 is disposed on the first doping region 16 between the second doping regions 18 and extends to the second doping region. 18 on. The first electrode layer 26 is disposed on the dielectric structure 24. The bag doped region 28 is configured. The spacers 30 are disposed on the sidewalls of the dielectric structure 24 and the first electrode layer 26. For example, the substrate 2, the first doped region 16, and the pouch doped region 28 have a first conductivity type such as a P conductivity type. The third doping region 14 and the second doping region 18 have a second conductivity type, such as an N conductivity type, opposite to the first conductivity type. In an embodiment, the first semiconductor component on the first substrate region 4 is a memory. For example, the second doped region 18 is used as a bit line. The first electrode layer 26 is used as a word line.
請參照第1圖,第二基板區6上之第二半導體元件包括介電元件32,配置於基板2上。第二電極層34配置於介電元件32上。第二介電層36配置於第二電極層34上。第一電極層38配置於第二介電層36上。第二電極層34、第二介電層36與第一電極層38可構成電容。間隙壁40可配置在第二電極層34的側壁上。間隙壁42配置在第二介電層36與第一電極層38的側壁上。第一電極層44配置於基板2未被第二電極層34覆蓋的部分上。於實施例中,第一電極層44係用作電阻。第二介電層46配置在介電元件32與第一電極層44之間。間隙壁48配置在第一電極層44與第二介電層46上。Referring to FIG. 1 , the second semiconductor component on the second substrate region 6 includes a dielectric component 32 disposed on the substrate 2 . The second electrode layer 34 is disposed on the dielectric element 32. The second dielectric layer 36 is disposed on the second electrode layer 34. The first electrode layer 38 is disposed on the second dielectric layer 36. The second electrode layer 34, the second dielectric layer 36, and the first electrode layer 38 may constitute a capacitor. The spacer 40 may be disposed on a sidewall of the second electrode layer 34. The spacer 42 is disposed on the sidewalls of the second dielectric layer 36 and the first electrode layer 38. The first electrode layer 44 is disposed on a portion of the substrate 2 that is not covered by the second electrode layer 34. In an embodiment, the first electrode layer 44 is used as a resistor. The second dielectric layer 46 is disposed between the dielectric element 32 and the first electrode layer 44. The spacers 48 are disposed on the first electrode layer 44 and the second dielectric layer 46.
請參照第1圖,第二基板區8上之第二半導體元件包括第三摻雜區50,配置於基板2中。第四摻雜區52配置在第三摻雜區50中。第二摻雜區54配置在第四摻雜區52中。摻雜區56配置在第三摻雜區50中。第二摻雜區58配置在摻雜區56中。閘結構60配置在第三摻雜區50與第四摻雜區52上。間隙壁62配置在閘結構60的側壁上。配置袋摻雜區64與袋摻雜區66。舉例來說,第四摻雜區52、袋摻雜區64、袋摻雜區66具有第一導電型例如P導電型。第三摻雜區50、第二摻雜區54、第二摻雜區58具有相反於第一導電型的第二導電型例如N導電型。摻雜區56可具有P導電型或N導電型。於實施例中,第二基板區8上的第二半導體元件係金屬氧化物半導體(MOS),例如85V橫向雙擴散金屬氧化物半導體(Lateral Double-diffused MOS;LDMOS)。Referring to FIG. 1 , the second semiconductor element on the second substrate region 8 includes a third doped region 50 disposed in the substrate 2 . The fourth doping region 52 is disposed in the third doping region 50. The second doping region 54 is disposed in the fourth doping region 52. The doped region 56 is disposed in the third doping region 50. The second doping region 58 is disposed in the doping region 56. The gate structure 60 is disposed on the third doping region 50 and the fourth doping region 52. The spacer 62 is disposed on the sidewall of the gate structure 60. The bag doped region 64 and the bag doped region 66 are configured. For example, the fourth doping region 52, the pocket doping region 64, and the pocket doping region 66 have a first conductivity type such as a P conductivity type. The third doping region 50, the second doping region 54, and the second doping region 58 have a second conductivity type, such as an N conductivity type, opposite to the first conductivity type. The doped region 56 may have a P conductive type or an N conductive type. In an embodiment, the second semiconductor component on the second substrate region 8 is a metal oxide semiconductor (MOS), such as a 85V lateral double-diffused metal oxide semiconductor (LDMOS).
請參照第1圖,第二基板區10上之第二半導體元件包括摻雜區68,配置在基板2中。摻雜區70配置在摻雜區68中。閘結構72配置在摻雜區68上。間隙壁74可配置在閘結構72的側壁上。也配置袋摻雜區76。第二基板區12上之第二半導體元件包括第二摻雜區78,配置在基板2中。閘結構80配置在第二摻雜區78之間的基板2上。配置袋摻雜區82。摻雜區68與摻雜區84可配置在摻雜區86上。舉例來說,摻雜區70與袋摻雜區82具有第一導電型例如P導電型。袋摻雜區68、袋摻雜區76、第二摻雜區78、摻雜區84與摻雜區86具有相反於第一導電型的第二導電型例如N導電型。於實施例中,形成在第二基板區10與第二基板區12上的第二半導體元件分別係相反型的MOS,例如低壓(LV)如5V的PMOS與LV如5V的NMOS。Referring to FIG. 1, the second semiconductor component on the second substrate region 10 includes a doped region 68 disposed in the substrate 2. Doped region 70 is disposed in doped region 68. The gate structure 72 is disposed on the doped region 68. The spacers 74 can be disposed on the sidewalls of the gate structure 72. A pocket doping region 76 is also provided. The second semiconductor component on the second substrate region 12 includes a second doped region 78 disposed in the substrate 2. The gate structure 80 is disposed on the substrate 2 between the second doping regions 78. A bag doped region 82 is configured. Doped region 68 and doped region 84 may be disposed on doped region 86. For example, doped region 70 and pocket doped region 82 have a first conductivity type, such as a P conductivity type. The bag doped region 68, the bag doped region 76, the second doped region 78, the doped region 84, and the doped region 86 have a second conductivity type, such as an N conductivity type, opposite to the first conductivity type. In an embodiment, the second semiconductor elements formed on the second substrate region 10 and the second substrate region 12 are respectively opposite MOSs, such as low voltage (LV) such as 5V PMOS and LV such as 5V NMOS.
第2圖至第20圖繪示根據一實施例之半導體裝置的製造方法。請參照第2圖,提供基板102。基板102包括第一基板區104與第二基板區106、第二基板區108、第二基板區110與第二基板區112。利用黃光微影製程於基板102上形成光阻層103。對光阻層103暴露的基板102佈植雜質例如銻(Sb)以在基板102中形成摻雜區186。請參照第3圖,移除光阻層103。可進行退火步驟以擴散摻雜區186。於一實施例中,在移除光阻層103與退火步驟之間可進行清洗步驟。2 to 20 illustrate a method of fabricating a semiconductor device in accordance with an embodiment. Referring to FIG. 2, a substrate 102 is provided. The substrate 102 includes a first substrate region 104 and a second substrate region 106, a second substrate region 108, a second substrate region 110, and a second substrate region 112. The photoresist layer 103 is formed on the substrate 102 by a yellow light lithography process. The substrate 102 exposed to the photoresist layer 103 is implanted with impurities such as antimony (Sb) to form doped regions 186 in the substrate 102. Referring to FIG. 3, the photoresist layer 103 is removed. An annealing step can be performed to diffuse the doped region 186. In one embodiment, a cleaning step can be performed between the removal of the photoresist layer 103 and the annealing step.
請參照第4圖,對基板102佈植雜質例如硼(boron)以使基板102在摻雜區186以外的區域造成相反的導電型。進行沉積或磊晶成長步驟以在基板102上形成薄膜。於一實施例中,在佈植步驟與薄膜形成步驟(例如磊晶或沉積步驟)之間,進行清洗步驟。Referring to FIG. 4, the substrate 102 is implanted with impurities such as boron to cause the substrate 102 to cause an opposite conductivity type in a region other than the doped region 186. A deposition or epitaxial growth step is performed to form a thin film on the substrate 102. In one embodiment, a cleaning step is performed between the implanting step and the film forming step (eg, epitaxial or deposition steps).
請參照第5圖,於基板102中形成第三摻雜區114與第三摻雜區150。於一實施例中,係對基板102的表面進行清洗步驟,然後在基板102的表面形成墊氧化層(pad oxide)。利用黃光微影製程在基板102上形成圖案化的光阻層。對圖案化的光阻層暴露的基板102佈植雜質例如磷(phosphorus)以在基板102中同時形成第三摻雜區114與第三摻雜區150。移除光阻層後可清洗基板102。進行退火步驟以擴散第三摻雜區114與第三摻雜區150。Referring to FIG. 5, a third doping region 114 and a third doping region 150 are formed in the substrate 102. In one embodiment, the surface of the substrate 102 is subjected to a cleaning step, and then a pad oxide is formed on the surface of the substrate 102. A patterned photoresist layer is formed on the substrate 102 using a yellow light lithography process. The substrate 102 exposed to the patterned photoresist layer is implanted with impurities such as phosphorousus to simultaneously form the third doping region 114 and the third doping region 150 in the substrate 102. The substrate 102 can be cleaned after the photoresist layer is removed. An annealing step is performed to diffuse the third doping region 114 and the third doping region 150.
請參照第6圖,於基板102中形成摻雜區168與摻雜區184。於第三摻雜區150中形成摻雜區107。於一實施例中,係對基板102的表面進行清洗步驟,然後在基板102的表面形成墊氧化層(pad oxide)。利用黃光微影製程在基板102上形成圖案化的光阻層。對圖案化的光阻層暴露的基板102與第三摻雜區150佈植雜質例如磷(phosphorus)以同時形成摻雜區168、摻雜區184與摻雜區107。然後移除光阻層。請參照第7圖,利用黃光微影製程於基板102上形成光阻層109。對光阻層109暴露的基板102佈植雜質例如硼(boron)以在基板102中形成摻雜區111、摻雜區113、摻雜區156與第一摻雜區116。然後移除光阻層109。Referring to FIG. 6, a doped region 168 and a doped region 184 are formed in the substrate 102. A doped region 107 is formed in the third doping region 150. In one embodiment, the surface of the substrate 102 is subjected to a cleaning step, and then a pad oxide is formed on the surface of the substrate 102. A patterned photoresist layer is formed on the substrate 102 using a yellow light lithography process. The substrate 102 exposed to the patterned photoresist layer and the third doped region 150 are implanted with impurities such as phosphorous to simultaneously form the doped region 168, the doped region 184, and the doped region 107. The photoresist layer is then removed. Referring to FIG. 7, a photoresist layer 109 is formed on the substrate 102 by a yellow lithography process. The substrate 102 exposed to the photoresist layer 109 is implanted with impurities such as boron to form a doping region 111, a doping region 113, a doping region 156, and a first doping region 116 in the substrate 102. The photoresist layer 109 is then removed.
請參照第8圖,擴散摻雜區111、摻雜區113、摻雜區156、第一摻雜區116、摻雜區184與摻雜區168。此外,在基板102上形成薄膜115。薄膜115可包括墊氧化層與墊氧化層上的氮化矽層。於一實施例中,在形成薄膜115之前清洗基板102的表面。然後進行退火步驟以擴散摻雜區111、摻雜區113、摻雜區156、第一摻雜區116、摻雜區184與摻雜區168。在清洗基板102的表面之後,形成墊氧化層,並在墊氧化層上沉積氮化矽層,以形成薄膜115。利用黃光微影製程形成圖案化的光阻層,蝕刻移除圖案化的光阻層所露出的薄膜115。然後移除圖案化的光阻層。Referring to FIG. 8 , the diffusion doping region 111 , the doping region 113 , the doping region 156 , the first doping region 116 , the doping region 184 , and the doping region 168 . Further, a film 115 is formed on the substrate 102. The film 115 may include a pad oxide layer and a tantalum nitride layer on the pad oxide layer. In one embodiment, the surface of the substrate 102 is cleaned prior to forming the film 115. An annealing step is then performed to diffuse the doped region 111, the doped region 113, the doped region 156, the first doped region 116, the doped region 184, and the doped region 168. After cleaning the surface of the substrate 102, a pad oxide layer is formed, and a tantalum nitride layer is deposited on the pad oxide layer to form a film 115. The patterned photoresist layer is formed by a yellow light lithography process, and the film 115 exposed by the patterned photoresist layer is removed by etching. The patterned photoresist layer is then removed.
請參照第9圖,在基板102中形成摻雜區117。於一實施例中,係利用黃光微影製程在基板102上形成圖案化的光阻層。對圖案化的光阻層暴露的基板102佈植雜質例如硼(boron)以形成摻雜區117。在佈植步驟之後,移除圖案化的光阻層。在薄膜115露出的基板102上形成如第10圖所示的介電元件132例如場氧化物,並移除薄膜115。於一實施例中,係在清洗基板102的表面之後形成介電元件132。在移除薄膜115之後,清洗基板102的表面,並在基板102上形成犧牲氧化層。在利用黃光微影製程形成光阻層119後,對光阻層119暴露的基板102佈植雜質例如硼(boron),以使摻雜區111具有足夠的P型雜質。於一實施例中,在此摻雜步驟之後,摻雜區168仍維持具有與摻雜區111相反的導電型,例如N導電型。移除光阻層119。Referring to FIG. 9, a doped region 117 is formed in the substrate 102. In one embodiment, a patterned photoresist layer is formed on the substrate 102 using a yellow light lithography process. The substrate 102 exposed to the patterned photoresist layer is implanted with impurities such as boron to form doped regions 117. After the implantation step, the patterned photoresist layer is removed. A dielectric member 132 such as a field oxide as shown in FIG. 10 is formed on the substrate 102 on which the film 115 is exposed, and the film 115 is removed. In one embodiment, the dielectric element 132 is formed after cleaning the surface of the substrate 102. After the film 115 is removed, the surface of the substrate 102 is cleaned and a sacrificial oxide layer is formed on the substrate 102. After the photoresist layer 119 is formed by the yellow light lithography process, the substrate 102 exposed to the photoresist layer 119 is implanted with impurities such as boron so that the doped region 111 has sufficient P-type impurities. In one embodiment, after this doping step, the doped region 168 still maintains a conductivity type opposite that of the doped region 111, such as an N conductivity type. The photoresist layer 119 is removed.
請參照第11圖,在基板102上形成第二電極層134、閘結構160、閘結構172與閘結構180。於一實施例中,係清洗基板102的表面之後,由下至上依序形成氧化層、多晶矽與金屬矽化物例如矽化鎢。然後蝕刻掉未被利用黃光微影製程形成之圖案化的光阻層所遮蔽的部分以形成如第11圖所示的第二電極層134、閘結構160、閘結構172與閘結構180。第二電極層134可包括多晶矽與金屬矽化物。第二電極層134與132之間亦可具有氧化層。移除圖案化的光阻層。Referring to FIG. 11, a second electrode layer 134, a gate structure 160, a gate structure 172, and a gate structure 180 are formed on the substrate 102. In one embodiment, after cleaning the surface of the substrate 102, an oxide layer, a polysilicon and a metal halide such as tungsten telluride are sequentially formed from bottom to top. The portion of the patterned photoresist layer that is not formed by the yellow lithography process is then etched away to form the second electrode layer 134, the gate structure 160, the gate structure 172, and the gate structure 180 as shown in FIG. The second electrode layer 134 may include polycrystalline germanium and metal germanide. The second electrode layers 134 and 132 may also have an oxide layer therebetween. The patterned photoresist layer is removed.
請參照第12圖,利用黃光微影製程於基板102上形成光阻層121。對光阻層121暴露的基板102佈植雜質例如硼(boron)以在150中形成摻雜區152。移除光阻層121。請參照第13圖,利用黃光微影製程於基板102上形成光阻層123。對光阻層123暴露的基板102佈植雜質例如磷(phosphorus)以同時在第一摻雜區116中形成摻雜區第二摻雜區118,在第四摻雜區152中形成摻雜區第二摻雜區154,在摻雜區156中形成摻雜區第二摻雜區158,並在摻雜區111中形成摻雜區第二摻雜區178。請參照第13圖,利用傾角(tilt)與旋轉(rotate)佈植的方式摻雜雜質例如硼以同時形成袋摻雜區128、袋摻雜區164、袋摻雜區166與袋摻雜區182。移除光阻層。Referring to FIG. 12, a photoresist layer 121 is formed on the substrate 102 by a yellow lithography process. The substrate 102 exposed to the photoresist layer 121 is implanted with impurities such as boron to form a doping region 152 in 150. The photoresist layer 121 is removed. Referring to FIG. 13, a photoresist layer 123 is formed on the substrate 102 by a yellow light lithography process. The substrate 102 exposed to the photoresist layer 123 is implanted with impurities such as phosphorous to simultaneously form a doped region second doped region 118 in the first doped region 116, and a doped region is formed in the fourth doped region 152. The second doped region 154 forms a doped region second doped region 158 in the doped region 156 and a doped region second doped region 178 in the doped region 111. Referring to FIG. 13, an impurity such as boron is doped by tilt and rotate implantation to simultaneously form the bag doped region 128, the bag doped region 164, the bag doped region 166, and the bag doped region. 182. Remove the photoresist layer.
請參照第14圖,於第一摻雜區116上形成第一介電層120。於一實施例中,第一介電層120的形成方法包括在基板102上共形地由下至上形成氧化層例如厚度約50埃與氮化矽層例如厚度約120埃。氧化層可以乾式法形成。在利用黃光微影製程形成光阻層125之後,蝕刻移除光阻層125所露出的氮化矽層與部分氧化層,舉例來說,留下厚度約20埃的氧化層。在形成氧化層之前,可以濕蝕刻的方式移除基板102上的氧化物。移除光阻層125。Referring to FIG. 14, a first dielectric layer 120 is formed on the first doping region 116. In one embodiment, the method of forming the first dielectric layer 120 includes conformally forming an oxide layer from bottom to top on the substrate 102, for example, having a thickness of about 50 angstroms and a tantalum nitride layer, for example, about 120 angstroms thick. The oxide layer can be formed by a dry process. After the photoresist layer 125 is formed by the yellow lithography process, the tantalum nitride layer and the partial oxide layer exposed by the photoresist layer 125 are removed by etching, for example, leaving an oxide layer having a thickness of about 20 angstroms. The oxide on the substrate 102 can be removed by wet etching prior to forming the oxide layer. The photoresist layer 125 is removed.
請參照第15圖,可在基板102上共形地形成第二介電層127與第一電極層129。可以熱氧化方式沉積第二介電層127。也可以濕式的方法形成第二介電層127。於一實施例中,第二介電層127的厚度約300埃。可以沉積的方式形成第一電極層129,包括多晶矽(polycide)。亦可對第一電極層129進行電阻佈植(HR-IMP)。第一電極層129的厚度可約為2000埃。Referring to FIG. 15, a second dielectric layer 127 and a first electrode layer 129 may be conformally formed on the substrate 102. The second dielectric layer 127 can be deposited by thermal oxidation. The second dielectric layer 127 can also be formed in a wet manner. In one embodiment, the second dielectric layer 127 has a thickness of about 300 angstroms. The first electrode layer 129 may be formed in a manner of deposition, including polycide. The first electrode layer 129 may also be subjected to resistance implantation (HR-IMP). The first electrode layer 129 may have a thickness of about 2000 angstroms.
請參照第16圖,利用黃光微影製程於基板102上形成光阻層131。對光阻層131暴露的基板129佈植雜質例如磷,劑量約E15/cm2。移除光阻層131。於一實施例中,在利用黃光微影製程於基板102上形成圖案化的光阻層之後,進行蝕刻步驟以移除圖案化的光阻層所露出的第二介電層127與第一電極層129,如第17圖所示,同時形成第二介電層122與第一電極層126、第二介電層146與第一電極層144,及第二介電層136與第一電極層138。舉例來說,可留下厚度約100埃的氧化層。在移除圖案化的光阻層之後,可進行金屬矽化物退火步驟。Referring to FIG. 16, a photoresist layer 131 is formed on the substrate 102 by a yellow lithography process. The substrate 129 exposed to the photoresist layer 131 is implanted with impurities such as phosphorus at a dose of about E15/cm2. The photoresist layer 131 is removed. In one embodiment, after the patterned photoresist layer is formed on the substrate 102 by the yellow lithography process, an etching step is performed to remove the second dielectric layer 127 and the first electrode layer exposed by the patterned photoresist layer. 129, as shown in FIG. 17, simultaneously forming the second dielectric layer 122 and the first electrode layer 126, the second dielectric layer 146 and the first electrode layer 144, and the second dielectric layer 136 and the first electrode layer 138 . For example, an oxide layer having a thickness of about 100 angstroms can be left. After removing the patterned photoresist layer, a metal telluride annealing step can be performed.
請參照第18圖,可同時形成間隙壁130、間隙壁133、間隙壁142、間隙壁148、間隙壁162與間隙壁174。此外,形成摻雜區170於摻雜區168中,並形成摻雜區137於第四摻雜區152與154中。間隙壁130、間隙壁133、間隙壁142、間隙壁148、間隙壁162與間隙壁174的形成方法可包括在基板102上沉積氧化層例如四乙基矽氧烷(Tetraethoxysilane;TEOS),然後利用蝕刻法移除部分的氧化層。摻雜區170與摻雜區137的形成方法包括利用黃光微影製程在基板102上形成光阻層135,然後對光阻層135暴露的基板102佈植雜質例如硼。請參照第18圖,利用傾角(tilt)與旋轉(rotate)佈植的方式摻雜雜質例如磷以形成袋摻雜區176。移除光阻層。Referring to FIG. 18, the spacer 130, the spacer 133, the spacer 142, the spacer 148, the spacer 162, and the spacer 174 can be simultaneously formed. In addition, doped regions 170 are formed in doped regions 168 and doped regions 137 are formed in fourth doped regions 152 and 154. The method of forming the spacer 130, the spacer 133, the spacer 142, the spacer 148, the spacer 162, and the spacer 174 may include depositing an oxide layer such as Tetraethoxysilane (TEOS) on the substrate 102, and then utilizing The etching removes a portion of the oxide layer. The method of forming the doped region 170 and the doped region 137 includes forming a photoresist layer 135 on the substrate 102 by a yellow photolithography process, and then implanting an impurity such as boron on the substrate 102 exposed to the photoresist layer 135. Referring to Fig. 18, an impurity such as phosphorus is doped by means of tilt and rotate implantation to form a bag doped region 176. Remove the photoresist layer.
請參照第19圖,在基板102上形成具有開口的層間介電質139。舉例來說,層間介電質139的形成方法包括沉積硼磷矽玻璃(BPSG)。在利用黃光微影製程形成圖案化的光阻層之後,利用蝕刻製程移除層間介電質139未被圖案化的光阻層遮蔽的部分,以形成開口。於一些實施例中,在沉積層間介電質139之前,可對基板102進行清洗步驟。在形成開口之後,移除圖案化的光阻層。請參考第20圖,形成導電插塞141於層間介電質139的開口中。也形成導電層143於層間介電質139上。導電插塞141包括金屬。於一實施例中,係在層間介電質139之開口的側壁上形成阻障層之後,進行快速熱退火步驟,然後以化學氣相沉積法在開口中填充金屬例如鎢以形成導電插塞141。Referring to FIG. 19, an interlayer dielectric 139 having an opening is formed on the substrate 102. For example, a method of forming interlayer dielectric 139 includes depositing borophosphon glass (BPSG). After the patterned photoresist layer is formed by the yellow lithography process, the portion of the interlayer dielectric 139 that is not shielded by the patterned photoresist layer is removed by an etching process to form an opening. In some embodiments, the substrate 102 can be subjected to a cleaning step prior to depositing the interlayer dielectric 139. After the opening is formed, the patterned photoresist layer is removed. Referring to FIG. 20, a conductive plug 141 is formed in the opening of the interlayer dielectric 139. A conductive layer 143 is also formed over the interlayer dielectric 139. The conductive plug 141 includes a metal. In one embodiment, after forming a barrier layer on the sidewall of the opening of the interlayer dielectric 139, a rapid thermal annealing step is performed, and then a metal such as tungsten is filled in the opening by chemical vapor deposition to form the conductive plug 141. .
於實施例中,為記憶體的第一半導體元件的製程係與用以形成第二半導體元件(包括金屬氧化半導體例如LDMOS、DMOS、CMOS或雙載子MOS)的雙載子-互補金氧半導體-雙重擴散金氧半導體(Bipolar-CMOS-DMOS;BCD)製程整合在一起成為一連續的流程。於其他實施例中,用以形成記憶體的製程亦可與邏輯製程整合在一起成為一連續的流程。第一半導體元件與第二半導體元件係形成在單一基板上。因此半導體裝置的製造成本低,且第一半導體元件與第二半導體元件之間可具有良好的電性連接。In an embodiment, the process of the first semiconductor component of the memory and the bi-carrier-complementary MOS semiconductor used to form the second semiconductor component (including a metal oxide semiconductor such as LDMOS, DMOS, CMOS or a bi-carrier MOS) - The Bipolar-CMOS-DMOS (BCD) process is integrated into a continuous process. In other embodiments, the process for forming a memory can also be integrated with a logic process to form a continuous process. The first semiconductor element and the second semiconductor element are formed on a single substrate. Therefore, the manufacturing cost of the semiconductor device is low, and a good electrical connection can be made between the first semiconductor element and the second semiconductor element.
第21圖繪示根據一實施例之半導體裝置及其製造方法。第21圖繪示之半導體裝置與第1圖繪示之半導體裝置的差異在於,第二電極層288係形成在第二摻雜區218之間的第一摻雜區216上。第一介電層220係形成在第二電極層288與第二介電層222之間。第二介電層222形成在第一介電層220的上表面上,且延伸至第一介電層220與第二電極層288的側壁上。於實施例中,第二電極層288可同時與第二電極層234、閘結構260、閘結構272與閘結構280一起形成。於一實施例中,形成在第一基板區204上的第一半導體元件係快閃記憶體。FIG. 21 illustrates a semiconductor device and a method of fabricating the same according to an embodiment. The difference between the semiconductor device shown in FIG. 21 and the semiconductor device shown in FIG. 1 is that the second electrode layer 288 is formed on the first doping region 216 between the second doping regions 218. The first dielectric layer 220 is formed between the second electrode layer 288 and the second dielectric layer 222. The second dielectric layer 222 is formed on the upper surface of the first dielectric layer 220 and extends to the sidewalls of the first dielectric layer 220 and the second electrode layer 288. In an embodiment, the second electrode layer 288 can be formed simultaneously with the second electrode layer 234, the gate structure 260, the gate structure 272, and the gate structure 280. In one embodiment, the first semiconductor component formed on the first substrate region 204 is a flash memory.
雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明,任何熟悉此項技藝者,在不脫離本發明之精神和範圍內,當可做些許更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。While the present invention has been described in its preferred embodiments, the present invention is not intended to limit the invention, and the present invention may be modified and modified without departing from the spirit and scope of the invention. The scope of protection is subject to the definition of the scope of the patent application.
2、102...基板2, 102. . . Substrate
4、104、204...第一基板區4, 104, 204. . . First substrate area
6、8、10、12、106、108、110、112...第二基板區6, 8, 10, 12, 106, 108, 110, 112. . . Second substrate area
14、50、114、150...第三摻雜區14, 50, 114, 150. . . Third doped region
16、116、216...第一摻雜區16, 116, 216. . . First doped region
18、54、58、78、118、154、158、178、218...第二摻雜區18, 54, 58, 78, 118, 154, 158, 178, 218. . . Second doped region
20、120、220...第一介電層20, 120, 220. . . First dielectric layer
22、36、46、122、127、136、146、222...第二介電層22, 36, 46, 122, 127, 136, 146, 222. . . Second dielectric layer
24...介電結構twenty four. . . Dielectric structure
26、38、44、126、129、138、144...第一電極層26, 38, 44, 126, 129, 138, 144. . . First electrode layer
28、64、66、76、82、128、164、166、176、182...袋摻雜區28, 64, 66, 76, 82, 128, 164, 166, 176, 182. . . Bag doping area
30、40、42、48、62、74、130、133、142、148、162、174...間隙壁30, 40, 42, 48, 62, 74, 130, 133, 142, 148, 162, 174. . . Clearance wall
32、132...介電元件32, 132. . . Dielectric element
34、134、234、288...第二電極層34, 134, 234, 288. . . Second electrode layer
52、152...第四摻雜區52, 152. . . Fourth doped region
56、68、70、84、86、107、111、113、117、137、156、168、170、184、186...摻雜區56, 68, 70, 84, 86, 107, 111, 113, 117, 137, 156, 168, 170, 184, 186. . . Doped region
60、72、80、160、172、180、260、272、280...閘結構60, 72, 80, 160, 172, 180, 260, 272, 280. . . Gate structure
103、109、119、121、123、125、131、135...光阻層103, 109, 119, 121, 123, 125, 131, 135. . . Photoresist layer
115...薄膜115. . . film
139...層間介電質139. . . Interlayer dielectric
141...導電插塞141. . . Conductive plug
143...導電層143. . . Conductive layer
第1圖繪示根據一實施例之半導體裝置的剖面圖。1 is a cross-sectional view of a semiconductor device in accordance with an embodiment.
第2圖至第20圖繪示根據一實施例之半導體裝置的製造方法。2 to 20 illustrate a method of fabricating a semiconductor device in accordance with an embodiment.
第21圖繪示根據一實施例之半導體裝置及其製造方法。FIG. 21 illustrates a semiconductor device and a method of fabricating the same according to an embodiment.
2...基板2. . . Substrate
4...第一基板區4. . . First substrate area
6、8、10、12...第二基板區6, 8, 10, 12. . . Second substrate area
14、50...第三摻雜區14, 50. . . Third doped region
16...第一摻雜區16. . . First doped region
18、54、58、78...第二摻雜區18, 54, 58, 78. . . Second doped region
20...第一介電層20. . . First dielectric layer
22、36、46...第二介電層22, 36, 46. . . Second dielectric layer
24...介電結構twenty four. . . Dielectric structure
26、38、44...第一電極層26, 38, 44. . . First electrode layer
28、64、66、76、82...袋摻雜區28, 64, 66, 76, 82. . . Bag doping area
30、40、42、48、62、74...間隙壁30, 40, 42, 48, 62, 74. . . Clearance wall
32...介電元件32. . . Dielectric element
34...第二電極層34. . . Second electrode layer
52...第四摻雜區52. . . Fourth doped region
56、68、70、84、86...摻雜區56, 68, 70, 84, 86. . . Doped region
60、72、80...閘結構60, 72, 80. . . Gate structure
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| TW200607082A (en) * | 2004-08-13 | 2006-02-16 | United Microelectronics Corp | Non-volatile memory cell and manufacturing method thereof |
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| TW413910B (en) * | 1999-06-22 | 2000-12-01 | Taiwan Semiconductor Mfg | Manufacturing method of split-gate type flash memory with capacitor |
| TW200607082A (en) * | 2004-08-13 | 2006-02-16 | United Microelectronics Corp | Non-volatile memory cell and manufacturing method thereof |
| TW201011910A (en) * | 2008-09-02 | 2010-03-16 | Dongbu Hitek Co Ltd | Poly-emitter type bipolar junction transistor, bipolar CMOS DMOS device, and manufacturing methods of poly-emitter type bipolar junction transistor and bipolar COMS DMOS device |
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