TWI328112B - - Google Patents
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- TWI328112B TWI328112B TW093122272A TW93122272A TWI328112B TW I328112 B TWI328112 B TW I328112B TW 093122272 A TW093122272 A TW 093122272A TW 93122272 A TW93122272 A TW 93122272A TW I328112 B TWI328112 B TW I328112B
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Links
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- 235000010339 sodium tetraborate Nutrition 0.000 description 1
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Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
- G01N21/88—Investigating the presence of flaws or contamination
- G01N21/89—Investigating the presence of flaws or contamination in moving material, e.g. running paper or textiles
- G01N21/8901—Optical details; Scanning details
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/21—Polarisation-affecting properties
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
- G01N21/88—Investigating the presence of flaws or contamination
- G01N21/95—Investigating the presence of flaws or contamination characterised by the material or shape of the object to be examined
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/59—Transmissivity
- G01N21/5907—Densitometers
- G01N2021/5957—Densitometers using an image detector type detector, e.g. CCD
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
- G01N35/00584—Control arrangements for automatic analysers
- G01N35/00722—Communications; Identification
- G01N35/00732—Identification of carriers, materials or components in automatic analysers
- G01N2035/00742—Type of codes
- G01N2035/00752—Type of codes bar codes
Landscapes
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Immunology (AREA)
- Physics & Mathematics (AREA)
- Pathology (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Polarising Elements (AREA)
- Investigating Materials By The Use Of Optical Means Adapted For Particular Applications (AREA)
- Liquid Crystal (AREA)
Description
1328112 九、發明說明: 【發明所屬之技術領域】 發明領域 本發明涉及記錄帶狀的薄片狀製品中存在的缺陷並在 5缺陷位置進行標記的薄片狀製品的檢查方法及檢查系統。 C先前技術3 發明背景 作為帶狀的薄片狀製品,例如有液晶顯示裝置中使用 的偏振片捲筒材。從帶狀的偏振片捲筒材開始至到對各個 10偏振片進行沖裁的程序按如下程序進行。首先,檢測出偏 振片捲请材的表面上存在的損傷等缺陷。當檢測出缺陷 時,對該缺陷位置進行標記,將偏振片捲筒材捲繞成捲筒 而進行保管。雖然根據來自用戶的規格,作為最終製品的 偏振片有各種大小’但是由於偏振片捲筒材可以共用,因 15此可以預先大量製造偏振片捲筒材,之後日後再根據需要 (根據來自各個用戶的訂購要求)從偏振片捲筒材中沖裁出 所需大小的偏振片製品。 還有,作為在缺陷位置進行標記的方法,例如已公布 在特開2002-303580號公報中(參照申請專利範圍、第1圖、 2〇第2圖)。該現有技術中,利用標記機構在檢測出缺陷的位 置加上損傷標記。具體來說,利用沿薄片狀製品的寬度方 向配置的多個加痕構件,加上損傷標記。 在獲得偏振片製品的情況下,將捲繞成捲筒的偏振片 捲筒材拉出’沖裁出所需大小的偏振片製品。在偏振片製 1328112 品上做有標記的製品由於不能作為最終製品,將被去除。 但是,在所述缺陷位置上進行標記的檢查方法有如下 的問題。即,如前所述,在標上標記後’雖然將薄片狀製 品捲繞起來形成為捲筒,但是當進行標記時,由於在進行 5 了標記的位置上會產生輕微的膨脹,因此當捲成捲筒時, 有可能在其他的正常的位置上產生新的缺陷。由於在這種 新產生的缺陷位置上沒有進行標記,因此有可能將存在缺 陷的製品提供給用戶。另外,由於產生了新的缺陷,因此 還會有材料利用率下降的問題。作為標記方法,除了如前 1〇 所述的加上損傷標記的方法以外,還有用油墨打印特定的 形狀的方法等,但是’由於利用油墨形成的標記也具有厚 度,因此在產生新的缺陷方面仍沒有改變。 C 明内容;J 癌·明概要 15 鑑於所述情況,本發明的目的在於,提供可以記錄帶 狀的薄片狀製品中存在的缺陷而且不會無益地擴大缺陷的 薄片狀製品的檢查方法及檢查系統。 為了解決所述問題’本發明的薄片狀製品的檢查方法 的特徵是,具有: 20 檢測出帶狀的薄片狀製品的缺陷的程序、 將所述被檢測出的缺陷的位置資訊記錄在薄片狀製品 的寬度方向端部的程序、 將記錄了所述位置資訊的帶狀的薄片狀製品捲繞成捲 筒的程序。 6 由這種構成所產生的薄片狀製品的檢查方法的作用、 效果如下。首先,檢測出帶狀的薄片狀製品的缺陷,將# 被檢測出的缺陷的位置資訊記錄在薄片狀製品的寬度方向 端部上。其後,捲繞帶狀的薄片狀製品而形成捲筒。這裡, 缺陷的位置資訊被記錄在薄片狀製品的寬度方向端部,而 該寬度方向端部是不作為製品使用的區域。所以,即使在 該寬度方向端部以任意的方式記錄位置資訊,並將薄片狀 製品捲繞成捲筒,也不會在作為最終製品使用的區域上產 生新的缺陷。其結果是’可以提供能夠記錄帶狀的薄片狀 製品上存在的缺陷而且不會無益地擴大缺陷的薄片狀製品 的檢查方法。 作為本發明的適宜的實施方式,可以舉出具有從所述 捲琦拉出帶狀的薄片狀製品的程序、檢測出記錄於薄片狀 製品的寬度方向端部的所述位置資訊的程序、根據所述被 檢測出的位置資訊來在缺陷位置上進行標記的程序、在進 行該標記後從帶狀的薄片狀製品沖裁出各個薄片狀製品的 程序的實施方式。 當採用該構成時,從捲筒上拉出帶狀的薄片狀製品, 並檢測出記錄於寬度方向端部的位置資訊。根據該被檢測 出的位置資訊’在缺陷位置上進行標記。然後,從帶狀的 薄片狀製品上沖裁出各個薄片狀製品。由於在進行了標記 後’能夠立即獲得各個薄片狀製品,因此不會因標記Z將 缺陷擴大。 作為本發明的其他的適宜的實施方式,可以舉出將缺 陷與寬度方向端部間的距離資訊作為所述位置資訊記錄的 實施方式。 薄片狀製品的缺陷雖然存在於寬度方向的某處,但是 位置資訊被記錄在寬度方向端部上。通過作為位置資訊記 錄缺陷與寬度方向端部間的距離資訊,可以报容易地確定 缺陷位置。 作為本發明的其他的適宜的實施方式,可以舉出以條 碼(bar code)的形式記錄魏位置f訊的實施方式。由於通 過用條碼進行記錄,可以在讀取條碼時制市售的條碼傳 感器,因此在成本方面是有利的。 作為本發明的又一個適宜的實施方式,可以舉出所述 位置資訊以條碼和數字兩種方式記錄祕與寬度方向端部 間的距離資訊的實施方式。 通過同時用數字和條碼記錄距離資訊,還可以容易地 用肉眼完成對缺陷位置的確認。 薄片狀製品的檢查系統 為了解決所述問題,本發明的 的特徵是,具備: Γ出帶狀的薄片狀製品的缺陷的缺陷撿測機構、 將所述破檢測出的缺陷的位置資 的寬度方向端部的缺陷記錄機構、 4片狀“ 筒的=錄了所述位置資訊的帶狀的薄片狀製品捲繞成捲 可以舉出如下的方 作為本發明的適宜的實施方式 式’即’具備: 1328112 從所述捲筒拉出帶狀的薄片狀製品的機構、 檢測出記錄於薄片狀製品的寬度方向端部的所述位置 資訊的位置資訊檢測機構、 根據所述被檢測出的位置資訊在缺陷位置進行標記的 5 標記機構、 在進行該標記後從帶狀的薄片狀製品上沖裁出各個薄 片狀製品的沖裁機構。 作為本發明的其他的實施方式,可以舉出所述位置資 訊以條碼的方式被記錄並且所述位置資訊檢測機構為條碼 10 閱讀器的實施方式。 這種檢查系統的作用、效果如同前述。 圖式簡單說明 第1圖是表示薄片狀製品的檢查系統的構成的示意圖 (條碼打印)。 15 第2圖是表示薄片狀製品的檢查系統的構成的示意圖 (條碼讀取)。 第3圖是表示系統的動作的流程圖。 第4(A)〜(E)圖是表示利用其他方式的缺陷記錄方法的 圖。 20 【實施方式】 較佳實施例之詳細說明 作為本系統中進行處理的薄片狀製品可以以偏振片捲 筒材為例進行說明。偏振片捲筒材被製成長的帶狀,從而 可以從薄膜狀的偏振片捲筒材沖裁出不同大小的偏振片。 9 132»112 偏振片捲筒材N可以通過在預先製造的PVA薄膜的正反兩 面上黏貼例如TAc薄膜而製得。有必要檢測出該被製成多 層構造的偏振片捲筒材N的表面朗部所存在的缺陷(損傷 或異物等)。 偏振片捲筒材N是利用包含如下程序的製造方法製造 的’即(A)對已實施了染色、交聯及拉伸處理的聚乙稀醇類 薄膜進订乾燥而獲得偏振鏡的程序,⑼在該偏振鏡的單側 或兩側黏貼保護層的程序,(c)在黏貼後進行加熱處理的程 序。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method and an inspection system for inspecting a sheet-like article which is recorded in a strip-shaped sheet-like article and which is marked at a defect position. C. Prior art 3 Background of the invention, as a strip-shaped sheet-like product, for example, a polarizing plate roll used in a liquid crystal display device is used. The procedure from the start of the strip-shaped polarizing plate roll to the punching of each of the 10 polarizing plates was carried out as follows. First, defects such as damage existing on the surface of the polarizing film roll are detected. When a defect is detected, the defect position is marked, and the polarizing plate roll is wound into a roll and stored. Although the polarizing plate as the final product has various sizes according to the specifications from the user, but since the polarizing plate roll can be shared, it is possible to mass-produce the polarizing plate roll in advance, and then, as needed, according to the needs (according to the respective users) Ordering Requirements) Blanking the desired size of the polarizer article from the polarizer roll. In addition, as a method of marking at a defect position, for example, JP-A-2002-303580 (refer to the patent application, the first drawing, the second drawing, the second drawing). In this prior art, a mark mechanism is used to add a damage mark at a position where a defect is detected. Specifically, a plurality of crease members disposed along the width direction of the sheet-like article are used, and a damage mark is added. In the case where a polarizing plate article is obtained, the polarizing plate roll wound into a roll is pulled out to punch out a polarizing plate article of a desired size. A marked article on polarizer 1328112 will be removed because it cannot be used as a final product. However, the method of inspecting the mark at the defect position has the following problems. That is, as described above, after the label is marked, 'when the sheet-like product is wound up to form a roll, when marking is performed, since a slight expansion occurs at the position where the mark is performed, when the mark is made, When rolling into a roll, it is possible to create new defects in other normal positions. Since no marking is made at this newly created defect location, it is possible to provide the defective product to the user. In addition, there are problems with material utilization degradation due to new defects. As a marking method, in addition to the method of adding a damage mark as described in the above, there is a method of printing a specific shape with ink, etc., but 'because the mark formed using the ink also has a thickness, in terms of generating new defects Still has not changed. In view of the above, it is an object of the present invention to provide an inspection method and inspection for a sheet-like product which can record defects existing in a strip-shaped sheet-like product without undesirably expanding defects. system. In order to solve the above problem, the inspection method of the sheet-like product of the present invention is characterized by having: 20 a program for detecting a defect of a strip-shaped sheet-like product, and recording position information of the detected defect in a sheet shape A program for the end portion in the width direction of the product, and a procedure for winding the strip-shaped sheet-like product in which the position information is recorded into a roll. The function and effect of the inspection method of the sheet-like product produced by such a configuration are as follows. First, the defect of the strip-shaped sheet-like product is detected, and the position information of the detected defect is recorded on the end portion in the width direction of the sheet-like product. Thereafter, a strip-shaped sheet-like product is wound to form a roll. Here, the positional information of the defect is recorded in the width direction end portion of the sheet-like article, and the width direction end portion is a region which is not used as a product. Therefore, even if the position information is recorded in an arbitrary manner at the end portion in the width direction, and the sheet-like product is wound into a roll, no new defects are produced in the area used as the final product. As a result, it is possible to provide a method of inspecting a sheet-like article capable of recording defects existing in a strip-shaped sheet-like product without undesirably expanding the defect. A preferred embodiment of the present invention includes a program for pulling out a strip-shaped sheet-like product from the roll, and a program for detecting the position information recorded at an end portion in the width direction of the sheet-like product, The program for marking the detected position information at the defect position, and the embodiment of the program for punching out each sheet-like product from the strip-shaped sheet product after the mark is performed. According to this configuration, the strip-shaped sheet-like product is pulled out from the reel, and the positional information recorded at the end portion in the width direction is detected. The mark is marked on the defect position based on the detected position information. Then, each of the sheet-like articles is punched out from the strip-shaped sheet-like product. Since each of the sheet-like articles can be obtained immediately after the marking is performed, the defects are not enlarged by the mark Z. As another preferable embodiment of the present invention, an embodiment in which the distance information between the defect and the end portion in the width direction is recorded as the position information can be cited. Although the defect of the sheet-like product exists somewhere in the width direction, the positional information is recorded on the end portion in the width direction. By recording the distance information between the defect and the end portion in the width direction as the position information, it is possible to easily determine the defect position. As another suitable embodiment of the present invention, an embodiment in which the Wei position information is recorded in the form of a bar code can be cited. Since the bar code sensor is commercially available when the bar code is read by recording with the bar code, it is advantageous in terms of cost. As still another preferred embodiment of the present invention, an embodiment in which the position information records distance information between the secret end and the end in the width direction in the form of bar code and number can be cited. By simultaneously recording distance information using numbers and bar codes, it is also easy to confirm the position of the defect with the naked eye. In order to solve the above problem, the present invention is characterized in that the present invention is characterized in that the present invention is characterized in that it includes a defect detecting means for picking up a defect of a strip-shaped sheet-like product, and a width of a position of the defect detected by the broken product. The defect recording mechanism at the direction end portion, and the four-sheet-shaped "cylinder-shaped sheet-like product in which the position information is recorded are wound into a roll, and the following is a preferred embodiment of the present invention. The device includes: 1328112 a mechanism for pulling out a strip-shaped sheet product from the reel, and a position information detecting mechanism for detecting the position information recorded at an end portion of the sheet-like product in the width direction, according to the detected position A five-marking mechanism for marking the defective position, and a punching mechanism for punching out each of the sheet-like products from the strip-shaped sheet-like product after the marking is performed. As another embodiment of the present invention, the above-mentioned The location information is recorded in the form of a barcode and the location information detecting mechanism is an implementation of the barcode 10 reader. The function and effect of the inspection system are as BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing a configuration of an inspection system for a sheet-like product (bar code printing). 15 Fig. 2 is a schematic view showing the configuration of an inspection system for a sheet-like product (bar code reading). The figure is a flowchart showing the operation of the system. The fourth (A) to (E) diagrams are diagrams showing the defect recording method by another method. 20 [Embodiment] The detailed description of the preferred embodiment is performed as the system. The sheet-like product can be exemplified by a polarizing plate roll. The polarizing plate roll is formed into a long strip shape, so that polarizing plates of different sizes can be punched out from the film-shaped polarizing plate roll. »112 The polarizing plate roll N can be obtained by adhering, for example, a TAc film on the front and back sides of a pre-manufactured PVA film. It is necessary to detect the surface lands of the polarizing plate roll N which is formed into a multilayer structure. Defects (damage, foreign matter, etc.) The polarizer roll N is manufactured by a manufacturing method including the following procedure: that is, (A) is a polyethylene glycol which has been subjected to dyeing, crosslinking, and stretching treatment. film Dried to obtain a polarizer set program, ⑼ adhesive protective layer of the polarizer side or both sides procedures, (c) heat-treating program after adhesive.
ιυ 15 20 /畔頸缚膜的染色、交聯、拉伸等各處理不需 :別:行’也可以同時進行,另外,各處理的順序也可 而且’作為聚乙烯醇類薄膜,也可以使用實 =聚乙稀醇類薄膜。-般來說,將聚乙稀醇 相制在或雙色性色素的溶 或雙色性色素而染色後,在便之及附 的溶液中以3倍〜7俨的拉絲玄在含有硼酸或硼砂 後’再在含有蝴酸或财等的溶谁的’讀中進订拉 之後再進行乾燥,可提㈣的取㈣34行拉伸(二級拉伸 因此特別理想。 改善偏光度特性 作為所述聚乙烯醇類聚合物 乙稀醋聚合後進行了皂化處理的 w舉出在使醋 了少量的不飽和紐、不飽和卿2醋酸乙稀上共 共聚的單體的材料等。聚6 讀子性單體等可 聚合物的平均聚合度Ιυ 15 20 / neck neck film dyeing, cross-linking, stretching and other treatments do not need: Do not: line ' can also be carried out at the same time, in addition, the order of each treatment can also be 'as a polyvinyl alcohol film, can also A real = polyethylene glycol film was used. In general, after the polyethylene glycol phase is dyed in a dichroic dye or a dichroic dye, it is dyed in a solution of 3 times to 7 Torr in a solution containing boric acid or borax. 'Re-drying after reading in the 'in the middle of the inclusion of the acid or the like, and extracting (4) 34 lines of stretching (secondary stretching is particularly desirable. Improving the polarization characteristics as the poly The vinyl alcohol polymer is saponified after being polymerized with ethylene vinegar, and the material of the monomer copolymerized with a small amount of unsaturated ketone and unsaturated ethyl acetate is used. Poly 6 readability Average polymerizability of monomers such as monomers
10 _、特別限制’可以使用任意聚合度的材料,但是優選 2 ’更優選2_〜涵。另外,聚乙稀醇類聚合物 -優選在85mol%以上,更優選98〜1〇〇咖1%。 不限=製造的偏振鏡的厚度雖然、—般為5〜⑽,但是並 有特又於此’料,關於調整偏振鏡的厚度的方法,也沒 、1道定,可以使用拉幅機、滾筒拉伸或壓通常的 万法。10 _, particularly limited 'A material of any degree of polymerization may be used, but 2' is more preferably 2_~ han. Further, the polyethylene polymer-based polymer is preferably at least 85 mol%, more preferably from 98 to 1%. Not limited to the thickness of the manufactured polarizer, although it is generally 5~(10), but there is a special reason for this. Regarding the method of adjusting the thickness of the polarizer, there is no one, and the tenter can be used. The drum is stretched or pressed in the usual way.
另,$振鏡與作為保護層的透明保護膜的黏接處理沒有特 ⑺別^定,例如可以借助由乙稀醇類聚合物製成的黏接劑或 至^由蝴酸或辦、戊二酿或三聚氰胺、草酸等乙稀醇類 聚合物的水溶性交聯劑製成的黏接劑等進行。該黏接層作 為水溶液的塗佈乾燥層等而形成,在調製該水溶液時,可 以根據需要配合其他的添加劑或酸等催化劑。In addition, the adhesion treatment of the galvanometer and the transparent protective film as a protective layer is not particularly limited, for example, by means of an adhesive made of a glycol polymer or to a sulphuric acid or a pentane An adhesive made of a water-soluble crosslinking agent of a second alcoholic polymer such as melamine or oxalic acid is used. The adhesive layer is formed as a coating dry layer of an aqueous solution or the like, and when the aqueous solution is prepared, other additives or a catalyst such as an acid may be blended as needed.
作為a又於偏振鏡的車側或兩侧的保護膜,可以使用適 15宜的透明薄膜。其中,優選使用由透明性或機械強度、熱 穩定性或水分屏蔽性等優良的聚合物製成的薄膜。作為該 聚合物,可以舉出如三乙酸纖維素等乙酸酯類樹脂,聚碳 醆酯類樹脂、聚芳酯、聚對苯二曱酸乙二醇酯等聚酯類樹 知,聚亞胺類樹脂、聚楓類樹脂、聚謎礙類樹脂、聚苯乙 〇烯類樹脂、聚乙烯、聚丙烯等聚烯烴類樹脂、聚乙烯醇類 樹脂、聚氯乙稀類樹脂、聚降冰片烯類樹脂、聚甲基丙烯 酸甲酯類樹脂、液晶聚合物等。薄膜也可以用澆注法、壓 延法、擠出法中的任意方法製造。 另外’可以舉出特開2001-343529號公報(W001/37007) 11 1328112 中5己述的聚合物薄膜,例如含有(A)在側鏈上具有取代或/ 和未取代亞氨基的熱塑性樹脂、和(B)在側鏈上具有取代或 /和未取代苯基及腈基的熱塑性樹脂的樹脂組合物。作為具 體例,可以舉出含有由異丁烯和N-曱基馬來酸酐縮亞胺構 5成的交替共聚物和丙烯腈、苯乙烯共聚物的樹脂組合物的 薄膜。作為薄膜可以使用由樹脂組合物的混含擠出品等製 成的薄膜《這些薄膜由於相位差小、光彈性係數小,因此 可以消除由偏振片的變形造成的不均等問題,另外由於透 濕度小’因而在加濕耐久性方面也很優良。 10 此外’保護膜最好沒有著色。所以,優選使用以Rth = [(nx+ny)/2-nz].d (其中’ nx、ny為薄膜平面内的主折射率, nz為薄膜厚度方向的折射率,d為薄膜厚度)表示的薄膜厚 度方向的相位差值為-90nm〜+75mn的保護膜。通過使用該 厚度方向的相位差值(Rth)為-90nm〜+75nm的保護膜,可以 15基本上消除由保護膜引起的偏振片的著色(光學著色)。厚度 方向的相位差值(Rth)更優選為_8〇nm〜+60nm,特別優選 -70nm〜+45nm。 從偏光特性或耐久性等方面考慮,優選如三乙酸纖維 素等乙酸醋類樹脂,特別優選對表面用鹼進行了皂化處理 20的三乙酸纖維素薄膜。而且,當在偏光薄膜的兩側設置透 明保護膜時,也可以在其正反兩面使用由不同的聚合物製 成的透明保護膜。 保護膜的厚度雖然為任意值,但是一般來說,出於偏 振片的薄型化等目的,設為5〇〇μιη以下,優選1〜3〇〇μιη, 12 1328112 特別優選5〜200μιη。而且,當在偏光薄膜的兩側設置透明 保護膜時,也可以在其正反兩面使用由不同的聚合物製成 的透明保護膜。 只要不損害本發明的目的,透明保護膜也可以是實施 5 了硬膜(hard-coat)處理或防反射處理、以擴散或防止黏附或 者抗眩光等為目的的處理的材料。硬膜處理是為了防止對 偏振片表面的損傷等而實施的,例如可以利用在透明保護 膜的表面附加由矽類等適宜的紫外線固化型樹脂形成的、 具有良好的硬度和光滑性等的硬化保護膜的方式等來形 10 成。 另一方面,防止反射處理是為了防止偏振片表面上的 外來光的反射而實施的,可以通過形成以往的防止反射膜 等來實現目的。另外,防止黏附處理是為了防止與相鄰層 的黏合而實施的,抗眩光處理是為了防止因外來光在偏振 15 片的表面反射而阻礙對偏振片透過光的識別等而實施的, 例如可以通過利用喷砂方式或壓花加工方式等的粗糙化方 式或透明微粒的配合方式等適宜的方式,在透明保護膜的 表面附加微細凹凸構造來形成。 作為所述透明微粒,例如可以舉出平均粒徑為0.5〜 20 20μπι的氧化矽或氧化鋁、氧化鈦或氧化鍅、氧化錫或氧化 銦、氧化鎘或氧化銻等,也可以使用具有導電性的無機微 粒,另外,也可以使用由交聯或未交聯的聚合物粒狀物等 構成的有機類微粒。透明微粒的使用量一般為,每100質量 份透明樹脂,使用2〜70質量份,特別優選5〜50質量份。 13 328112 男外,作為配合透明微粒的抗眩光層,可以採用透明 係護廣本身’或者可以在透明保護層表面作為塗佈層等設 爹。批眩光層也可以兼當用於擴散偏振片透過光而擴大視 角的擴散層(視角補償功能等)。而且,所述的防止反射層或 5防止黏附層、擴散層或抗眩光層等也可以作為由設置了這 竣層的薄片等構成的光學層,與透明保護層分開設置。 本發明的薄片狀製品在實際使用時,可·以將各種光學 層層燊而作為光學膜使用。對於該光學層,沒有特別限定, 例如$以舉出在未黏接所述透明保護膜的偏振鏡的面(未 〇 設裏所述黏接劑塗佈層的面)上,實施硬膜處理或防止反射 處理、以擴散或防止黏附或抗眩光為目的的表面處理,或 者層疊以視角補償等為目的的取向液晶層的方法。另外, 還玎以舉出黏貼1層或2層以上反射片或半透過片、相位差 板(包括1/2或1/4等波長片(λ片)/視角補償薄膜等用於液晶 15 顯示裝置等的形成中的光學薄膜的方法。特別是,如果薄 片狀製品是偏振片,則適合用作層疊反射片或半透過反射 片而形成的反射型偏振片或半透過型偏振片、層疊相位差 板而形成的橢圓偏振片或圓偏振片、層疊視角補償層或視 角補償薄膜而形成的廣角偏振片、或者層疊亮度改善用薄 20 膜而形成的偏振片。 反射型偏振片是在偏振片上設置了反射層的構件,是 用於形成通過使來自識認側(顯示側)的入射光反射而進行 顯示的類型的液晶顯示裝置等的構件,可以省略背光燈等 光源的内置,因而具有容易實現液晶顯示裝置的薄型化等 14 1328112 優點。反射型偏振片的形成可以利用根據需要隔著透明保 護詹等在偏振片的單面上附設由金屬等製成的反射層的方 式等適宜的方式來進行。 作為反射型偏振片的具體例,可以舉出在根據需要進 5 行了消光(matte)處理的透明保護膜的單面上,附設由鋁等 反射性金屬製成的箔或蒸鍍膜而形成反射層的偏振片。另 外,還可以舉出通過使所述透明保護膜含有微粒而形成表 面微細凹凸構造,而在其上具有微細凹凸構造的反射層的 偏振片。所述的微細凹凸構造的反射層具有如下優點,即, 10 可以利用漫反射使入射光擴散而防止方向性或外觀發亮, 並且可以抑制明暗的不均。另外,含有微粒的透明保護膜 還具有如下的優點,即,在入射光及其反射光透過它時被 擴散,從而可以進一步抑制明暗不均。形成反映了透明保 護膜的表面微細凹凸構造的微細凹凸構造的反射層時,可 15利用如下方法等完成,例如利用真空蒸鍍方式、離子鍍方 式、濺射方式等蒸鍍方式或鍍膜方式等適宜的方式,在透 明保護層的表面直接附設金屬。 反射片也可以不採用直接附加在所述偏振片的透明保 護膜上的方式’而作成在以該透明薄膜為基準的適宜的薄 20膜上設置反射層而形成的反射薄片等使用。而且,由於反 射層通常由金屬製成,因此從防止因氧化而造成的反射率 的下降、進而長期維持初期反射率的觀點或避免另外附設 保護層的觀點等出發,更優選在該反射面被透明保護膜或 偏振片等所覆蓋的狀態下使用的方式。 15 1328112 還有’在上述中,半透過型偏振片可以通過作成用反 射層反射光的同時使光透過的半透半反鏡等半透過型的反 射層而獲得。半透過型偏振片通常被設於液晶單元的背面 側,可以形成如下類型的液晶顯示裝置等,即,在比較明 5 亮的環境中使用液晶顯示裝置等的情況下,反射來自於識 認側(顯示側)的入射光而顯示圖像,在比較暗的環境中,使 用内置於半透過型偏振片的背面的背光燈等内置光源來顯 示圖像。即’半透過型偏振片在如下類型的液晶顯示裝置 等的形成中十分有用,即,在明亮的環境下可以節約使用 10 背光燈等光源的能量,在比較暗的環境下也可以使用内置 光源的類型的液晶顯示裝置的形成中非常有用。 下面對偏振片上還層疊相位差板而構成的橢圓偏振片 或圓偏振片進行說明。在將直線偏振光改變為橢圓偏振光 或圓偏振光’或者將橢圓偏振光或圓偏振光改變為直線偏 15振光,或者改變直線偏振光的偏振方向的情況下,可以使 用相位差板。特別是,作為將直線偏振光改變為圓偏振光 或將圓偏振光改變為直線偏振光的相位差板,可使用所謂 的1/4波長片(也稱為λ/4板)。1/2波長板(也稱為λ/2板)通常用 於改變直線偏振光的偏振方向的情況。 20 橢圓偏振片可以有效地用於以下情形,即補償(防止) 超扭曲向列相(STN)型液晶顯示裝置的液晶層因雙折射而 產生的著色(藍或黃),從而進行所述沒有著色的白黑顯示的 情形。另外,控制三維折射率的偏振片還可以補償(防止) 從斜向觀察液晶顯示裝置的畫面時產生的著色,因而十分 16 1328112 理想。圓偏振光片可以有效地用於對以彩色顯示圖像的反 射型液晶顯示裝置的圖像的色調進行調整的情形,而且還 具有防止反射的功能。 作為相位差板,可以舉出對高分子材料進行單向或雙 5 向拉伸處理而形成的雙折射性薄膜、液晶聚合物的取向 膜、用薄膜支撐液晶聚合物的取向層的構件等。拉伸處理 例如可以利用滾筒拉伸法、沿長間隙拉伸法、拉幅機拉伸 法、管式拉伸法等進行。拉伸倍率在單向拉伸的情況下, 一般為1.1〜3倍左右。對相位差板的厚度也沒有特別限 10 定,一般為 10〜200μηι,優選20〜ΙΟΟμιη。 作為所述高分子材料,例如可以舉出聚乙烯醇、聚乙 烯醇縮丁醛、聚甲基乙烯醚、聚羥基乙基丙烯酸酯、羥乙 基纖維素、羥丙基纖維素、甲基纖維素、聚碳酸酯、聚芳 酯、聚颯、聚對苯二甲酸乙二醇酯、聚萘二甲酸乙二醇酯、 15 聚醚颯、聚苯硫醚、聚苯醚、聚烯丙基颯、聚乙烯醇、聚 醯胺、聚醯亞胺、聚烯烴、聚氯乙稀、纖維素類聚合物或 它們的二元類、三元類各種共聚物、接枝共聚物、混聚物 等。這些高分子材料可通過拉伸等而成為取向物(拉伸薄 膜)。 20 作為所述液晶聚合物,例如可以舉出在聚合物的主鏈 或側鏈上導入了賦予液晶取向性的共軛性的直線狀原子團 (mesogene)的主鏈型或側鏈型各種聚合物。作為主鏈型液晶 性聚合物的具體例,可以舉出具有在賦予彎曲性的間隔部 上結合了上述直線狀原子團的構造的聚合物,例如向列取 17 向性的聚麵液晶性聚合物、圓盤狀聚合物或膽㈣型聚 合物等。作為側鏈型液晶性聚合物的具體例,可以舉出如 下的化合物等’即’將聚錢院、聚丙烯賴、聚甲基丙 歸曰或挈丙一酸酯為主鍵骨架,作為側鍵隔著由共報性 的原子團構成的間隔部而具有由賦予向列取向性的對位取 代環狀化合物單元構成的上述直線原子團部。這些液晶聚 合物通過以下方法進行處理,即,在對於形成在玻璃板上 的聚酿亞胺或聚乙烯醇等薄膜的表面進行摩擦處理後的材 料、斜向条鑛了氧化矽的材料等的取向處理面上,鋪展液 晶性聚合物的溶液而進行熱處理。 相位差板可以是例如各種波長板或用於補償由液晶層 的雙折射造成的著色或視角等的材科等具有對應於使用目 的的適宜的相位差的材料,也可以是層疊2種以上的相位差 板而控制了相位差等光學特性的材料。 補償視角薄膜是從不垂直於晝面的稍微傾斜的方向觀 察液晶顯示晝面的情況下也使圖像看起來比較清晰的、用 於擴大視角的薄膜。作為此種視角補償相位差板 ,例如由 在相位差薄膜、液晶聚合物等的取向薄膜或透明基材上支 撐了液晶聚合物等取向層的材料等構成。通常作為相位差 板使用的是沿其面方向被實施了單向拉伸的、雙折射聚合 物薄膜,與此相對,作為被用作視角補償薄臈的相位差板, 可以使用沿其面方向被實施了雙向拉伸的具有雙折射的聚 合物薄膜、沿其面方向被單向拉伸並且沿其厚度方向也被 拉伸了的控制厚度方向的折射率的具有雙折射的聚合物或 像傾斜取向膜等雙向拉伸賴等。作為傾斜取向膜,例如 可以舉財聚合㈣膜上黏接純賴後在因加熱形成的 收縮力的作用下,對聚合物薄膜進行了拉伸處理或/和收縮 處理的材料、使液晶聚合物傾斜取向而成的材料等。作為 相位差板的轉料聚合物可制與上述的相位差板中說明 2聚合物相同的聚合物’可以使肋防止基於由液晶單元 造成的相位差而形成的識認角的變化所帶來的著色等或擴 大識認度良好的視角等為目的的適宜的聚合物。 另外,從實現識認度良好的寬視角的觀點出發,可以 優選使用用三乙酸纖維素薄膜支樓由液晶聚合物的取向 層、特別是圓盤狀液晶聚合物的傾斜取向層構成的光學各 向異性層的光學補償相位差板。 將偏振片和亮度改善薄膜貼合在一起而成的偏振片通 *被设於液晶單元的背面一侧。亮度改善薄膜是顯示如下 特性的薄臈,即,當因液晶顯示裝置等的背光燈或來自背 面側的反射等,有自然光入射時,反射特定偏光軸的直線 偏振光或特定方向的圓偏振光,而使其他光透過。因此將 冗度改善薄膜與偏振片層疊而成的偏振片可使來自背光燈 等光源的光入射,而獲得特定偏振光狀態的透過光,同時, 所述特定偏振光狀態以外的光不能透過,被予以反射。借 助设於其後側的反射層等再次反轉在該亮度改善薄膜面上 反射的光’使之再次入射到亮度改善薄膜上,使其一部分 或全部作為特定偏振光狀態的光透過,從而増加透露亮度 改善薄膜的光’同時向偏光鏡提供難以吸收的偏振光,從 1328112 而增大能夠在液晶顯示圖像的顯示等中利用的光量,並由 此可以提高亮度。即,在不使用亮度改善薄膜而用背光燈 等從液晶單元的背面側穿過偏光鏡而使光入射的情況下, 具有與偏光鏡的偏光軸不一致的偏光方向的光基本上被偏 5光鏡所吸收,因而無法透過偏光鏡。即,雖然會因所使用 的偏光鏡的特性而不同,但是大約5〇%的光會被偏光鏡吸 收掉’因此’液晶圖像顯示等中能夠利用的光量將減少, 導致圖像變暗。由於亮度改善薄膜反覆進行如下操作,即, 使具有能夠被偏光鏡吸收的偏光方向的光不是入射到偏光 10鏡上,而是使該類光在亮度改善薄膜上發生反射,進而借 助設於其後側的反射層等完成反轉,使光再次入射到亮度 改善薄膜上’這樣,亮度改善薄膜只使在這兩者間反射並 反轉的光中的、其偏光方向變為能夠通過偏光鏡的偏光方 向的偏振光透過,同時將其提供給偏光鏡,因此可以在液 15晶顯示裝置的圖像的顯示中有效地使用背光燈的光,從而 可以使畫面明亮》 也可以在亮度改善薄膜和所述反射層等之間設置擴散 板。由亮度改善薄膜反射的偏振光狀態的光朝向所述反射 層等,所設置的擴散板可將通過的光均勻地擴散,同時消 20除偏振光狀態而成為非偏振光狀態。即,擴散板使偏振光 恢復到原來的自然光狀態。反覆進行如下的作業,即,將 該非偏振光狀態即自然光狀態的光射向反射層等,經過反 射層等而反射後,再次通過擴散板而又入射到亮度改善薄 膜上。通過在亮度改善薄膜和所述反射層之間設置使偏振 20 1328112 光恢復到原來的自然光狀態的擴散板,可以在維持顯示畫 面的亮度的同時,減少顯示晝面的亮度的不均,從而可以 提供均勻並且明亮的晝面。通過設置該擴散板,可適當增 加初次入射光的重複反射次數,並利用擴散板的擴散功 5能’可以提供均勻的明亮的顯示晝面。 作為所述亮度改善薄膜,例如可以使用:電介質的多 層薄膜或折射率各向異性不同的薄膜多層疊層體之類的顯 示出使特定偏光轴的直線偏振光透過而反射其他光的特性 的薄膜、膽留醇型液晶聚合物的取向膜或在薄膜基材上支 10樓了該取向液晶層的薄膜之類的顯示出將左旋或右旋中的 任一種圓偏振光反射而使其他光透過的特性的薄膜等適宜 的薄膜。 因此’通過利用使所述的特定偏光軸的直線偏振光透 過的類型的亮度改善薄膜,使該透過光直接沿著與偏光軸 15 致的方向入射到偏振片上,可以在抑制由偏振片造成的 吸收損失的同時,使之有效地透過。另一方面,利用膽留 醇型液晶層之類的使圓偏振光透過的類型的亮度改善薄 膜,雖然可以直接使光入射到偏光鏡上,但是,從抑制吸 收損失這-點考慮,最好借助相位差板對該圓偏振光 直線偏振光化,再入射到偏振片上。而且,通過使用⑽ 長片作為助位差板,可以將圓偏振光魏為直線偏振光皮 在可見光區域等較寬波長範圍中能起到1/4波長片^ 用的相位差板’例如可以利用以下方式獲得,即將4 於波長55Gnm的淺色光能起到1/4波長片相的相位差2 21 1328112 10 15 20 顯示其他的相位差特性的相位差層例如能起到Μ波長片 作用的相位差層重疊的方式裳 度改善薄膜之間的相位差置於偏振片和亮 差層構成。 了以疋由丨切層以上的相位 還有,就膽留醇型液晶層而言,也可以組合不同反射 波長的材料,構成重疊2層^ ^如 次3層以上的配置構造,由此獲 付在可見光區域等較寬的範圍内反射圓偏振光的構件從 而可以基於此而獲得較寬波長範圍的透過圓偏振光。 另外,本發明的薄片狀製品(例如偏振片)如同所述偏振 光分離型偏振片,可以由層疊了偏振片和2層或3層以上的 光學層的構件構成。所以,也可以是組合所述反射型偏振 片或半透過型偏振片和相位差板而成的反射逛橢圓偏振片 或半透過型橢圓偏振片等β 在偏振片上層疊了所述光學層的光學膜<以利用在液 晶顯示裝置等的製造過程中依次獨立層燊的方式來形成, 但是預先經層疊而成為光學膜的偏振片在質景的穩疋性或 組裝操作等方面優良,因此具有可改善浪晶蔡負不裝置等的 製造程序的優點。在層疊中可以使用黏换劑廣等適且的黏 ^ ^ β硌,它們的光學 接手段。在黏接所述偏振片和其他光學詹时 μ的犯置角度。 軸可以根據目標相位差特性等而採用適赏的 1达冰中,也可以設 本發明的偏振片或所述的疊層光學構1 瘅。對於該黏接 置用於與液晶單元等其他構件黏接的黏换席 > ,,ϋ相同的適宜的 層沒有特別限定,可以用丙烯酸類等與以^ 黏接劑來形成《從防止由吸濕造成的# ?包現象或'jAs a protective film on the vehicle side or both sides of the polarizer, a suitable transparent film can be used. Among them, a film made of a polymer excellent in transparency, mechanical strength, thermal stability or moisture barrier property is preferably used. Examples of the polymer include an acetate resin such as cellulose triacetate, a polyester such as a polycarboester resin, a polyarylate or a polyethylene terephthalate, and a polyimine. Resin, poly-Maple resin, poly-mystery resin, polystyrene resin, polyolefin resin such as polyethylene, polypropylene, polyvinyl alcohol resin, polyvinyl chloride resin, polynorbornene Resin, polymethyl methacrylate resin, liquid crystal polymer, and the like. The film can also be produced by any of a casting method, a calendering method, and an extrusion method. Further, the polymer film described in JP-A-2001-343529 (W001/37007) 11 1328112, for example, contains (A) a thermoplastic resin having a substituted or/and an unsubstituted imino group in a side chain, And (B) a resin composition having a thermoplastic resin having a substituted or/and unsubstituted phenyl group and a nitrile group in a side chain. Specific examples thereof include a film comprising a resin composition of an alternating copolymer of isobutylene and N-fluorenyl maleic anhydride, and an acrylonitrile or styrene copolymer. As the film, a film made of a mixed product of a resin composition or the like can be used. "These films have a small phase difference and a small photoelastic coefficient, so that the unevenness caused by the deformation of the polarizing plate can be eliminated, and the moisture permeability is small. 'Therefore, it is also excellent in humidifying durability. 10 In addition, the protective film is preferably not colored. Therefore, it is preferable to use Rth = [(nx+ny)/2-nz].d (where 'nx, ny is the principal refractive index in the plane of the film, nz is the refractive index in the film thickness direction, and d is the film thickness) The phase difference in the film thickness direction is a protective film of -90 nm to +75 nm. By using the protective film having a retardation value (Rth) in the thickness direction of -90 nm to +75 nm, the coloring (optical coloring) of the polarizing plate caused by the protective film can be substantially eliminated. The retardation value (Rth) in the thickness direction is more preferably from _8 〇 nm to +60 nm, and particularly preferably from -70 nm to +45 nm. From the viewpoints of polarizing characteristics, durability, and the like, an acetic acid-based resin such as triacetate or the like, and a cellulose triacetate film which has been subjected to saponification treatment with a base on the surface 20 is particularly preferable. Further, when a transparent protective film is provided on both sides of the polarizing film, a transparent protective film made of a different polymer may be used on both the front and back sides. Though the thickness of the protective film is an arbitrary value, it is generally 5 μm or less, preferably 1 to 3 μm, and 12 1328112 is particularly preferably 5 to 200 μm for the purpose of thinning the polarizing plate. Further, when a transparent protective film is provided on both sides of the polarizing film, a transparent protective film made of a different polymer may be used on both the front and back sides. The transparent protective film may be a material which is subjected to a treatment for hard-coating treatment or anti-reflection treatment, for diffusion or prevention of adhesion or anti-glare, etc., as long as the object of the present invention is not impaired. The hard coat treatment is carried out in order to prevent damage to the surface of the polarizing plate, and for example, it is possible to use a suitable ultraviolet curable resin such as a hydrazine or the like to be cured on the surface of the transparent protective film, and to have good hardness and smoothness. The form of the protective film is formed into a shape of 10%. On the other hand, the anti-reflection treatment is carried out in order to prevent reflection of external light on the surface of the polarizing plate, and the object can be achieved by forming a conventional anti-reflection film or the like. Further, the adhesion prevention process is performed to prevent adhesion to an adjacent layer, and the anti-glare treatment is performed to prevent external light from being reflected on the surface of the polarization 15 sheet, thereby preventing recognition of light transmitted through the polarizing plate, and the like. The fine concavo-convex structure is formed on the surface of the transparent protective film by a suitable method such as a roughening method such as a sand blasting method or an embossing method or a method of blending transparent fine particles. Examples of the transparent fine particles include cerium oxide or aluminum oxide having an average particle diameter of 0.5 to 20 20 μm, titanium oxide or cerium oxide, tin oxide or indium oxide, cadmium oxide or cerium oxide, and conductivity can also be used. The inorganic fine particles may be organic fine particles composed of crosslinked or uncrosslinked polymer particles or the like. The amount of the transparent fine particles used is usually 2 to 70 parts by mass, particularly preferably 5 to 50 parts by mass, per 100 parts by mass of the transparent resin. 13 328112 For men, as an anti-glare layer with transparent particles, it is possible to use a transparent protective tape itself or to use a coating layer on the surface of a transparent protective layer. The batch glare layer can also serve as a diffusion layer (viewing angle compensation function, etc.) for diffusing the polarizing plate to transmit light and widening the viewing angle. Further, the anti-reflection layer or the anti-reflection layer, the diffusion layer, the anti-glare layer or the like may be provided as an optical layer composed of a sheet or the like provided with the enamel layer, and provided separately from the transparent protective layer. When the sheet-like product of the present invention is actually used, it is possible to use various optical layers as an optical film. The optical layer is not particularly limited, and for example, a hard coat treatment is performed on a surface of a polarizer to which the transparent protective film is not bonded (a surface on which the adhesive coating layer is not provided) Or a method of preventing reflection treatment, surface treatment for diffusion or prevention of adhesion or anti-glare, or laminating a liquid crystal layer for the purpose of viewing angle compensation or the like. In addition, it is also possible to use one or two or more reflective sheets or semi-transmissive sheets, and a phase difference plate (including a 1/2 or 1/4 wavelength plate (λ piece)/viewing angle compensation film for liquid crystal display 15 A method of forming an optical film in a device or the like. In particular, if the sheet-like article is a polarizing plate, it is suitably used as a reflective polarizing plate or a semi-transmissive polarizing plate formed by laminating a reflective sheet or a semi-transmitting reflecting sheet, and laminating a phase. An elliptically polarizing plate or a circularly polarizing plate formed by a difference plate, a wide-angle polarizing plate formed by laminating a viewing angle compensation layer or a viewing angle compensation film, or a polarizing plate formed by laminating a thin film for brightness improvement. The reflective polarizing plate is on a polarizing plate. The member in which the reflective layer is provided is a member for forming a liquid crystal display device or the like which is displayed by reflecting incident light from the recognition side (display side), and the light source such as a backlight can be omitted, so that it is easy to be used. The advantage of the thinning of the liquid crystal display device is 14 1328112. The formation of the reflective polarizing plate can be performed on one side of the polarizing plate by transparent protection or the like as needed. A method of forming a reflective layer made of a metal or the like is carried out in an appropriate manner. As a specific example of the reflective polarizing plate, a single surface of a transparent protective film which is subjected to matte treatment as needed is exemplified. A polarizing plate in which a reflective layer is formed by a foil or a vapor-deposited film made of a reflective metal such as aluminum, and a fine fine concavo-convex structure is formed on the transparent protective film by forming fine particles. The polarizing plate of the reflective layer of the fine concavo-convex structure. The reflective layer of the fine concavo-convex structure has the advantage that the diffused reflection can diffuse the incident light to prevent directionality or appearance, and can suppress unevenness of light and dark. Further, the transparent protective film containing fine particles has an advantage of being diffused when incident light and reflected light thereof are transmitted therethrough, thereby further suppressing unevenness in light and darkness, and forming a fine uneven structure reflecting the surface of the transparent protective film. In the case of the reflective layer of the fine concavo-convex structure, the film 15 can be completed by the following method, for example, by vacuum deposition, ion plating, or sputtering. In a suitable manner such as a vapor deposition method or a plating method, a metal is directly attached to the surface of the transparent protective layer. The reflective sheet may be formed in a transparent manner without being directly attached to the transparent protective film of the polarizing film. A reflective sheet formed by providing a reflective layer on a suitable thin film based on a film, etc., is used. Since the reflective layer is usually made of metal, the reflectance is prevented from being lowered by oxidation, and the initial reflection is maintained for a long period of time. From the viewpoint of the rate or the viewpoint of avoiding the additional protective layer, it is more preferable to use the reflective surface in a state covered with a transparent protective film, a polarizing plate, or the like. 15 1328112 There is also 'in the above, semi-transmissive polarization. The sheet can be obtained by forming a semi-transmissive reflective layer such as a half mirror which transmits light while reflecting light by a reflective layer. The semi-transmissive polarizing plate is usually provided on the back side of the liquid crystal cell, and can be formed into the following types. In the case of using a liquid crystal display device or the like in a relatively bright environment, the reflection is from a liquid crystal display device or the like. An image is displayed by recognizing the incident light on the side (display side), and an image is displayed using a built-in light source such as a backlight built in the back surface of the transflective polarizer in a relatively dark environment. That is, the semi-transmissive polarizing plate is useful in the formation of a liquid crystal display device or the like of the following types, that is, in a bright environment, energy of a light source such as a backlight such as 10 backlights can be saved, and a built-in light source can be used in a relatively dark environment. Very useful in the formation of liquid crystal display devices of the type. Next, an elliptically polarizing plate or a circularly polarizing plate in which a retardation plate is further laminated on a polarizing plate will be described. In the case where the linearly polarized light is changed to elliptically polarized light or circularly polarized light 'or the elliptically polarized light or the circularly polarized light is changed to the linearly polarized light, or the polarization direction of the linearly polarized light is changed, a phase difference plate can be used. In particular, as a phase difference plate which changes linearly polarized light into circularly polarized light or circularly polarized light into linearly polarized light, a so-called quarter-wavelength plate (also referred to as a λ/4 plate) can be used. A 1/2 wavelength plate (also called a λ/2 plate) is generally used to change the polarization direction of linearly polarized light. 20 The elliptically polarizing plate can be effectively used in the case of compensating (preventing) the coloring (blue or yellow) of the liquid crystal layer of the super twisted nematic nematic (STN) type liquid crystal display device due to birefringence, thereby performing the above-mentioned The situation of white and black coloring is shown. In addition, the polarizing plate for controlling the three-dimensional refractive index can also compensate (prevent) the coloring which occurs when the screen of the liquid crystal display device is viewed obliquely, and thus is ideally 16 1328112. The circularly polarizing plate can be effectively used for adjusting the color tone of an image of a reflective liquid crystal display device which displays an image in color, and also has a function of preventing reflection. Examples of the retardation film include a birefringent film formed by uniaxially or biaxially stretching a polymer material, an oriented film of a liquid crystal polymer, and a member for supporting an alignment layer of a liquid crystal polymer with a film. The stretching treatment can be carried out, for example, by a drum stretching method, a long gap stretching method, a tenter stretching method, a tubular stretching method, or the like. In the case of uniaxial stretching, the stretching ratio is generally about 1.1 to 3 times. The thickness of the phase difference plate is also not particularly limited, and is generally 10 to 200 μm, preferably 20 to ΙΟΟμιη. Examples of the polymer material include polyvinyl alcohol, polyvinyl butyral, polymethyl vinyl ether, polyhydroxyethyl acrylate, hydroxyethyl cellulose, hydroxypropyl cellulose, and methyl fiber. , polycarbonate, polyarylate, polyfluorene, polyethylene terephthalate, polyethylene naphthalate, 15 polyether oxime, polyphenylene sulfide, polyphenylene ether, polyallyl飒, polyvinyl alcohol, polyamine, polyimine, polyolefin, polyvinyl chloride, cellulose polymer or their binary, ternary various copolymers, graft copolymers, mixed polymers Wait. These polymer materials can be oriented (stretched film) by stretching or the like. In the above-mentioned liquid crystal polymer, for example, a main chain type or a side chain type polymer in which a conjugated linear atomic group (mesogene) which imparts liquid crystal alignment properties is introduced into a main chain or a side chain of a polymer is exemplified. . Specific examples of the main chain type liquid crystal polymer include a polymer having a structure in which the linear atomic group is bonded to a spacer portion imparting flexibility, and for example, a 17-direction polymerized liquid crystal polymer. , disc-shaped polymer or bile (tetra) type polymer. Specific examples of the side chain type liquid crystalline polymer include the following compounds, that is, 'there is a side bond skeleton of a polyphenol, a polypropylene ray, a polymethyl propyl hydrazine or a bismuth acrylate. The key has a linear atomic group portion composed of a para-substituted cyclic compound unit imparting nematic orientation, via a spacer formed of a reproducible atomic group. These liquid crystal polymers are treated by a method of rubbing a surface of a film such as polyacrylonitrile or polyvinyl alcohol formed on a glass plate, or a material of obliquely strontium oxide, or the like. On the orientation-treated surface, a solution of the liquid crystalline polymer is spread and heat-treated. The retardation plate may be, for example, a material having various wavelength plates or a material for compensating for coloring or viewing angle due to birefringence of the liquid crystal layer, or the like having a suitable phase difference corresponding to the purpose of use, or may be laminated in two or more layers. A phase difference plate controls a material having optical characteristics such as a phase difference. The compensating viewing angle film is a film for enlarging the viewing angle while observing the liquid crystal display face from a direction slightly inclined to the facet. The viewing angle compensation retardation plate is made of, for example, a material which supports an alignment layer such as a liquid crystal polymer on an oriented film such as a retardation film or a liquid crystal polymer, or a transparent substrate. Generally, a birefringent polymer film which is uniaxially stretched in the plane direction thereof is used as the phase difference plate, and a phase difference plate which is used as a viewing angle compensation film can be used as the phase difference plate. a birefringent polymer film which is subjected to biaxial stretching, a birefringent polymer or a tilt like a refractive index in the thickness direction which is uniaxially stretched in the plane direction thereof and which is also stretched in the thickness direction thereof Oriented film or the like biaxially stretched. As the oblique alignment film, for example, a material which is subjected to a stretching treatment or/and a shrinkage treatment of a polymer film under the action of a shrinkage force by heating after bonding a pure ray on a film, and a liquid crystal polymer can be used. A material that is oriented obliquely. The transfer polymer as the phase difference plate can be made of the same polymer as described in the above-mentioned retardation plate, and the rib can prevent the rib from being changed based on the change in the recognition angle formed by the phase difference caused by the liquid crystal cell. A suitable polymer for the purpose of coloring, etc., or expanding the visibility of a good visibility. Further, from the viewpoint of realizing a wide viewing angle with good visibility, it is preferable to use an optical layer composed of an alignment layer of a liquid crystal polymer, particularly an inclined alignment layer of a discotic liquid crystal polymer, using a cellulose triacetate film branch. The optically retarded phase difference plate of the anisotropic layer. The polarizing plate through which the polarizing plate and the brightness improving film are bonded together is provided on the back side of the liquid crystal cell. The brightness-improving film is a thin film that exhibits a characteristic that reflects a linearly polarized light of a specific polarization axis or a circularly polarized light of a specific direction when natural light is incident due to a backlight of a liquid crystal display device or the like, reflection from the back side, or the like. And let other light pass through. Therefore, the polarizing plate in which the redundancy improving film and the polarizing plate are laminated can cause light from a light source such as a backlight to be incident to obtain transmitted light of a specific polarization state, and light other than the specific polarized light state is not transmitted. Be reflected. Re-inverting the light reflected on the surface of the brightness improving film by a reflective layer or the like provided on the rear side thereof to be incident on the brightness improving film again, and partially or completely transmitting light as a specific polarized light state, thereby adding The light of the brightness-improving film is revealed, and polarized light that is hard to absorb is supplied to the polarizing mirror, and the amount of light that can be used for display of a liquid crystal display image or the like is increased from 1328112, and thus the brightness can be improved. In other words, when the light is incident from the back side of the liquid crystal cell without using the brightness improving film, the light having the polarizing direction that does not coincide with the polarizing axis of the polarizer is substantially biased by the light. The mirror absorbs and cannot pass through the polarizer. That is, although it differs depending on the characteristics of the polarizer used, about 5% of the light is absorbed by the polarizer. Therefore, the amount of light that can be utilized in liquid crystal image display or the like is reduced, resulting in darkening of the image. The brightness improving film is repeatedly operated such that light having a polarization direction that can be absorbed by the polarizer is not incident on the mirror of the polarized light 10, but is caused to be reflected on the brightness improving film, and further The reflection layer on the rear side or the like is reversed to cause the light to be incident on the brightness improving film again. Thus, the brightness improving film only changes the polarization direction of the light reflected and inverted between the two to pass through the polarizer. The polarized light in the polarized direction is transmitted while being supplied to the polarizing mirror, so that the backlight light can be effectively used in the display of the image of the liquid 15-crystal display device, so that the screen can be made brighter, and the brightness improving film can also be used. A diffusion plate is provided between the reflective layer and the like. The light in the polarized state reflected by the brightness improving film faces the reflecting layer or the like, and the diffusing plate is provided to uniformly diffuse the passing light while eliminating the polarized light state to become an unpolarized state. That is, the diffusing plate restores the polarized light to the original natural light state. The operation of the non-polarized light state, that is, the natural light state, is directed to the reflective layer or the like, reflected by the reflective layer or the like, and then incident on the brightness improving film again through the diffusion plate. By providing a diffusing plate between the brightness improving film and the reflective layer to restore the polarization of the polarization 20 1328112 to the original natural light state, it is possible to reduce the brightness of the display screen while reducing the unevenness of the brightness of the display surface. Provides a uniform and bright face. By providing the diffusing plate, it is possible to appropriately increase the number of repeated reflections of the primary incident light, and to provide a uniform bright display pupil by the diffusion work of the diffusing plate. As the brightness improving film, for example, a film which exhibits characteristics of transmitting linearly polarized light of a specific polarization axis and reflecting other light, such as a multilayer film of a dielectric material or a film multilayer laminated body having different refractive index anisotropy, can be used. An alignment film of a cholesteric liquid crystal polymer or a film having a liquid crystal layer of 10 or more on the film substrate, which exhibits reflection of any of left-handed or right-handed circularly polarized light to transmit other light. A suitable film such as a film of properties. Therefore, by using the brightness improving film of the type that transmits the linearly polarized light of the specific polarizing axis, the transmitted light is incident on the polarizing plate directly in the direction opposite to the polarization axis 15, and the suppression by the polarizing plate can be suppressed. While absorbing the loss, it is effectively transmitted. On the other hand, a brightness improving film of a type that transmits circularly polarized light such as a cholesteric liquid crystal layer can directly cause light to be incident on the polarizer, but it is preferable from the viewpoint of suppressing absorption loss. The circularly polarized light is linearly polarized by means of a phase difference plate, and is incident on the polarizing plate. Moreover, by using the (10) long film as the helper plate, it is possible to use a circularly polarized light as a linearly polarized light film which can function as a quarter-wavelength plate in a wide wavelength range such as a visible light region. It is obtained by using a light-colored light having a wavelength of 55 Gnm to have a phase difference of a quarter-wavelength phase. 2 21 1328112 10 15 20 A phase difference layer exhibiting other phase difference characteristics can function, for example, as a wavelength plate. The manner in which the phase difference layers overlap is formed by the polarizing plate and the difference layer. In addition, in the case of the cholesteric liquid crystal layer, it is also possible to combine materials having different reflection wavelengths to form an arrangement structure in which two layers are superposed, such as three or more layers. A member that reflects circularly polarized light in a wide range such as a visible light region can be used to obtain transmitted circularly polarized light of a wide wavelength range based thereon. Further, the sheet-like product (e.g., polarizing plate) of the present invention may be composed of a member in which a polarizing plate and two or more optical layers are laminated, as in the polarizing-separating polarizing plate. Therefore, it is also possible to combine the reflective polarizing plate or the semi-transmissive polarizing plate and the retardation plate to form a reflection elliptically polarizing plate or a semi-transmissive elliptically polarizing plate, and the like. The optical layer is laminated on the polarizing plate. The film is formed by sequentially laminating layers in a manufacturing process of a liquid crystal display device or the like. However, the polarizing plate which is laminated in advance to form an optical film is excellent in stability of a texture, assembly operation, and the like, and thus has It can improve the advantages of the manufacturing process such as the failure of the device. In the lamination, it is possible to use a wide range of viscous adhesives, and their optical means. The angle of the μ when the polarizer and other opticals are bonded. The shaft may be used in a suitable amount of ice according to the target phase difference characteristic or the like, or the polarizing plate of the present invention or the laminated optical structure may be provided. The adhesive layer which is used for bonding to other members such as a liquid crystal cell is not particularly limited, and may be formed of an acrylic or the like by an adhesive. #包包现象 or 'j caused by moisture absorption
22 1328112 象、防止由熱膨脹差等造成的光學特性的降低或液晶單元 的翹曲以及形成高質量並且耐久性優良的圖像顯示裝置的 性質等方面考慮,優選吸濕率低並且耐熱性優良的黏接 層。另外,可以採用通過含有微粒而顯示出光擴散性的黏 5 接層等。黏接層根據需要設置在所需要的面上即可,例如, 對由偏光鏡和保護膜構成的偏振片來說’根據需要在保護 膜的單面或雙面上設置黏接層即可。 對於所述黏接層的暴露面,為了在提供於實用之前防 止其被污染,可以臨時黏貼隔膜而將其覆蓋。這樣,就可 10 以防止其在通常的處理狀態下與黏接層接觸。作為隔膜, 除了所述厚度條件以外,例如可以使用如下的與以往相同 的適宜的材料,即,根據需要用矽類或長鏈烷基類、氟類 或硫化鉬等適宜的剝離劑對塑料薄膜、橡膠薄片、紙、布、 無紡布、網狀物、發泡薄片或金屬箔、它們的層壓體等適 15 宜的薄片體進行了塗覆處理的材料。 還有,在本發明中,在形成上述的偏振片的偏光鏡或 透明保護膜或光學膜等中,另外在黏接層等各層中,也可 以利用例如用水楊酸酯類化合物或苯並苯酚類化合物、苯 並三唑類化合物或氰基丙烯酸酯類化合物、鎳絡合鹽類化 20 合物等紫外線吸收劑進行處理的方式,來使之具有紫外線 吸收能力等。 本發明的薄片狀製品可適用於液晶顯示裝置、有機EL 顯示裝置、PDP等圖像顯示裝置的形成中。 本發明的偏振片或光學膜可適用於液晶顯示裝置等各 23 1328112 種裝置的形成等中。液晶顯示裝置的形成可以按照以往的 方式進行。即,一般來說,液晶顯示裝置可通過適宜地組 合液晶單元和偏振片和光學膜以及根據需要而加入的照明 系統等構成部件並裝入驅動電路而形成,但是,本發明中, 5 除了使用本發明的偏振片或光學膜這一點以外,並沒有特 別限定,可以按照以往的方式進行。對於液晶單元而言, 也可以使用例如TN型或STN型、π型等任意類型的液晶單 元。 可以形成在液晶單元的單側或雙側配置了偏振片或光 10 學膜的液晶顯示裝置、在照明系統中使用了背光燈或反射 片的裝置等適宜的液晶顯示裝置。此時,本發明的偏振片 或光學膜可以設置在液晶單元的單側或雙側上。當將偏振 片或光學膜設置在雙側時,它們既可以是相同的材科,也 可以是不同的材料。另外,在形成液晶顯示裝置時,可以 15 在適宜的位置上配置1層或2層以上例如擴散板、抗眩光 層、防止反射膜、保護板、棱鏡陣列、透鏡陣列薄片、光 擴散板、背光燈等適宜的部件。 下面對有機電致發光裝置(有機EL裝置)進行說明。一 般來說,有機EL裝置中在透明基板上依次層疊透明電極、 20 有機發光層和金屬電極而形成發光體(有機電致發光體)。這 裡,有機發光層是各種有機薄膜的疊層體,已知有:例如 由三苯基胺衍生物等構成的空穴注入層利由蔥等螢光性的 有機固體構成的發光層的疊層體、或此種發光層和由二萘 嵌苯衍生物等構成的電子注入層的疊層體、或者具有這些 24 1328112 空六注入層、發光層及電子注入層的疊層體等各種組合。 有機EL顯示裝置根據如下的原理進行發光,即,通過 在透明電極和金屬電極上加上電壓,向有機發光層中注入 空穴和電子’由這些空穴和電子的復合而產生的能量激發 5螢光物質’被激發的螢光物質回到基態時,就會放射出光。 中間的復合機理與一般的二極管相同,由此也可以推測 出’電"IL和發光強度相對於外加電壓顯示出伴隨整流性的 較強的非線性。 在有機EL顯示裝置中,為了取出有機發光層中產生的 10光’至少一方的電極必須是透明的’通常將由氧化銦錫(IT〇) 等透明導電體製成的透明電極作為陽極使用。另一方面, 為了谷易進行電子的注入而提高發光效率,在陰極中使用 功函數較小的物質是十分重要的,通常使用Mg_Ag、Al-Li 等金屬電極。 15 在具有此種構成的有機EL顯示裝置中,有機發光層由 厚度為10nm左右的極薄的膜構成。所以,有機發光層也與 透明電極一樣,使光基本上完全地透過。其結果是,在不 發光時從透明基板的表面入射並透過透明電極和有機發光 層而在金屬電極反射的光會再次向透明基板的表面側射 2〇 出,因此’當從外部進行識認時,有機EL裝置的顯示面如 同鏡面。 在包括如下所述的有機電致發光體的有機EL顯示裝置 中’可以在透明電極的表面側設置偏振片,同時在這些透 明電極和偏振片之間設置相位差板,上述有機電致發光體 25 132811222 1328112 It is preferable to prevent a decrease in optical characteristics caused by a difference in thermal expansion or the like, or warpage of a liquid crystal cell, and properties of an image display device which is excellent in quality and excellent in durability, and is preferably low in moisture absorption rate and excellent in heat resistance. Adhesive layer. Further, an adhesive layer or the like which exhibits light diffusibility by containing fine particles can be used. The adhesive layer may be provided on a desired surface as needed. For example, for a polarizing plate composed of a polarizer and a protective film, an adhesive layer may be provided on one or both sides of the protective film as needed. For the exposed face of the adhesive layer, in order to prevent contamination of the exposed face before it is provided for practical use, the separator may be temporarily adhered to cover it. Thus, it is possible to prevent it from coming into contact with the adhesive layer under normal processing conditions. As the separator, in addition to the above-described thickness conditions, for example, the following suitable materials can be used, that is, a suitable release agent for a plastic film such as a hydrazine or a long-chain alkyl group, a fluorine group or a molybdenum sulfide, as needed. A material which is coated with a suitable sheet such as a rubber sheet, a paper, a cloth, a nonwoven fabric, a mesh, a foamed sheet or a metal foil, or a laminate thereof. Further, in the present invention, in the polarizing plate, the transparent protective film, the optical film or the like which forms the polarizing plate described above, in each layer such as the adhesive layer, for example, a salicylate compound or a benzophenol may be used. A UV absorber such as a compound, a benzotriazole compound, a cyanoacrylate compound or a nickel complex salt compound 20 is treated to have an ultraviolet absorbing ability or the like. The sheet-like product of the present invention can be suitably used in the formation of an image display device such as a liquid crystal display device, an organic EL display device, or a PDP. The polarizing plate or the optical film of the present invention can be suitably used for formation of a device such as a liquid crystal display device of 23 1328112 or the like. The formation of the liquid crystal display device can be carried out in a conventional manner. In other words, the liquid crystal display device can be formed by suitably combining a liquid crystal cell, a polarizing plate and an optical film, and a lighting system added as needed, and incorporating the driving circuit, but in the present invention, 5 The polarizing plate or the optical film of the present invention is not particularly limited, and can be carried out in a conventional manner. For the liquid crystal cell, any type of liquid crystal cell such as a TN type, an STN type, or a π type can also be used. A suitable liquid crystal display device such as a liquid crystal display device in which a polarizing plate or an optical film is disposed on one side or both sides of a liquid crystal cell, or a device in which a backlight or a reflective sheet is used in an illumination system can be formed. At this time, the polarizing plate or optical film of the present invention may be disposed on one side or both sides of the liquid crystal cell. When the polarizer or the optical film is disposed on both sides, they may be the same material or different materials. Further, when forming a liquid crystal display device, one or two or more layers such as a diffusion plate, an anti-glare layer, a reflection preventing film, a protective plate, a prism array, a lens array sheet, a light diffusing plate, and a backlight may be disposed at a suitable position. Suitable parts such as lights. Next, an organic electroluminescence device (organic EL device) will be described. In the organic EL device, a transparent electrode, a 20 organic light-emitting layer, and a metal electrode are sequentially laminated on a transparent substrate to form an illuminant (organic electroluminescence). Here, the organic light-emitting layer is a laminate of various organic thin films, and for example, a laminar injection layer made of a triphenylamine derivative or the like is known to be a laminate of a light-emitting layer composed of a fluorescent organic solid such as onion. A laminate of the light-emitting layer and the electron injecting layer composed of a perylene derivative or the like, or a combination of the 24 1328112 empty six-injection layer, the light-emitting layer, and the electron injecting layer. The organic EL display device emits light according to the principle that a hole is applied to the organic light-emitting layer by applying a voltage to the transparent electrode and the metal electrode, and energy generated by the recombination of the holes and electrons is excited. When the fluorescent substance that is excited by the fluorescent substance returns to the ground state, it emits light. The intermediate composite mechanism is the same as that of a general diode, and it can also be inferred that the 'electricity' and the luminous intensity show a strong nonlinearity with respect to the rectifying property with respect to the applied voltage. In the organic EL display device, in order to take out at least one of the electrodes generated in the organic light-emitting layer, at least one of the electrodes must be transparent. A transparent electrode made of a transparent conductor such as indium tin oxide (IT〇) is usually used as an anode. On the other hand, in order to facilitate electron injection in the valley, it is important to use a material having a small work function in the cathode, and a metal electrode such as Mg_Ag or Al-Li is usually used. In the organic EL display device having such a configuration, the organic light-emitting layer is formed of an extremely thin film having a thickness of about 10 nm. Therefore, the organic light-emitting layer also transmits light substantially completely like the transparent electrode. As a result, when the light is incident from the surface of the transparent substrate and the transparent electrode and the organic light-emitting layer are not emitted, the light reflected on the metal electrode is again emitted to the surface side of the transparent substrate, so that the identification is performed from the outside. At the time, the display surface of the organic EL device is like a mirror surface. In an organic EL display device including an organic electroluminescence body as described below, a polarizing plate may be disposed on the surface side of the transparent electrode, and a phase difference plate may be disposed between the transparent electrode and the polarizing plate, and the above organic electroluminescent body 25 1328112
中’在通過施加電壓而進行發光的有機發光層的表面側設 有透明電極,同時在有機發光層的背面侧設有金屬電極。X 由於相位差板及偏振片具有使從外部入射並在金屬電 極反射來的光成為偏振光的作用,因此利用該偏振光作用 5具有使得從外部無法識認出金屬電極的鏡面的效果。特別 是’採用1/4波長片構成相位差板,並且將偏振片和相位差 板的偏振光方向的夾角調整為7^4時,可以完全遮蔽金屬電 極的鏡面。 即,入射於該有機EL顯示裝置的外部光因偏振片的存 鲁 10在而只有直線偏振光成分透過。該直線偏振光一般會被相 位差板轉換成橢圓偏振光,而當相位差板為丨/4波長片並且 偏振片和相位差板的偏光方向的夾角為π/4時,就會成為圓 偏振光。 該圓偏振光透過透明基板、透明電極、有機薄膜,在 15 金屬電極上反射’再次透過有機薄膜、透明電極、透明基 板’由相位差板再次轉換成直線偏振光。由於該直線偏振 光與偏振片的偏振光方向正交,因此無法透過偏振片。其 結果是,可以將金屬電極的鏡面完全地遮蔽。 本發明的薄片狀製品(例如偏振片)可以適用於液晶顯 20 示裝置等各種裝置的形成等中。液晶顯示裝置可以形成為 將本發明的薄片狀製品(例如偏振片)配置在液晶單元的單 側或雙側而成的透過型或反射型或者透過、反射兩用型的 具有與以往相同的適宜的構造的裝置。所以,形成液晶顯 示裝置的液晶單元可以是任意的,例如也可以使用以薄膜 26 1328112 晶體管型為代表的單純矩陣驅動型的液晶單元等適宜類麼 的液晶單元。 另外,在液晶單元的兩側設置偏振片或光學部件時, 這些既可以是相同的構件,也可以是互不相同的構件。進 5而,在形成液晶顯示裝置時,可以在適當的位置上設置!層 或2層以上的棱鏡陣列薄片或透鏡陣列薄片、光擴散板或背 光燈等適宜的部件。 <檢查系統的構成> 下面根據附圖對本發明的薄片狀製品的檢查系統的適 10宜的實施方式進行說明。第1圖是表示薄片狀製品的檢查系 統當中的打印條碼的機構的圖。第2圖是表示檢查系統當中 的讀取條碼並進行標記的機構的圖。 為了檢測出偏振片捲筒材N的表面缺陷,配置有第丨攝 影機列1和第2攝影機列2。在第丨攝影機列丨中,沿著偏振片 15捲筒材N的寬度方向設有3台CCD攝影機h,在第项影機列 2中’同樣沿著寬度方向設有6台咖攝影機2卜第2攝影機 列2被配置在第i攝影機歹㈣下流側,為了可靠地進行缺陷 檢測,採用2列排列。 由把些第1、第2攝影機列1、2取得的圖像被送至圖像 20處理部3,使用圖像處埋技術檢測出存在於偏振片捲筒材N 的表面或内部的缺陷。圖像處理部3可以由圖像處理程序等 軟件構成。當然也可以用硬件構成圖像處理部3。利用圖像 處理部3判斷是否為缺陷的同時還求出缺陷位置。如上所 述’第1、第2攝影機列1、2及圖像處理部3可以發揮能檢測 27 可以採用公知的 出帶狀薄片狀製品的缺陷的缺陷檢測機構的功能。另外 利用圖像處理程序進行時的缺陷判定算法 算法》In the middle, a transparent electrode is provided on the surface side of the organic light-emitting layer that emits light by applying a voltage, and a metal electrode is provided on the back side of the organic light-emitting layer. X Since the retardation plate and the polarizing plate have a function of causing the light incident from the outside and reflected by the metal electrode to become polarized light, the polarizing action 5 has an effect of making the mirror surface of the metal electrode unrecognizable from the outside. In particular, when the retardation plate is formed by a quarter-wavelength plate and the angle between the polarization directions of the polarizing plate and the phase difference plate is adjusted to 7^4, the mirror surface of the metal electrode can be completely shielded. In other words, the external light incident on the organic EL display device is transmitted by the linearly polarized light component due to the presence of the polarizing plate. The linearly polarized light is generally converted into elliptically polarized light by the phase difference plate, and becomes circularly polarized when the phase difference plate is a 丨/4 wavelength plate and the angle of polarization of the polarizing plate and the phase difference plate is π/4. Light. The circularly polarized light is transmitted through the transparent substrate, the transparent electrode, and the organic thin film, and is reflected on the 15 metal electrode by 're-transmission of the organic thin film, the transparent electrode, and the transparent substrate' to be converted into linearly polarized light by the phase difference plate. Since the linearly polarized light is orthogonal to the polarization direction of the polarizing plate, the polarizing plate cannot be transmitted. As a result, the mirror surface of the metal electrode can be completely shielded. The sheet-like product (e.g., polarizing plate) of the present invention can be suitably used in the formation of various devices such as a liquid crystal display device. The liquid crystal display device can be formed such that the sheet-like product (for example, a polarizing plate) of the present invention is disposed on one side or both sides of the liquid crystal cell, and is transparent or reflective or transmissive or reflective. Construction of the device. Therefore, the liquid crystal cell forming the liquid crystal display device may be any. For example, a liquid crystal cell such as a simple matrix drive type liquid crystal cell typified by a thin film 26 1328112 transistor type may be used. Further, when a polarizing plate or an optical member is provided on both sides of the liquid crystal cell, these may be the same member or different members. In addition, when forming a liquid crystal display device, it can be set at an appropriate position! A suitable component such as a layer or two or more prism array sheets or lens array sheets, a light diffusing plate or a backlight. <Configuration of Inspection System> An appropriate embodiment of the inspection system for the sheet-like product of the present invention will be described below with reference to the drawings. Fig. 1 is a view showing a mechanism for printing a barcode in an inspection system of a sheet-like product. Fig. 2 is a view showing a mechanism for reading and marking a bar code in an inspection system. In order to detect the surface defect of the polarizing plate roll N, the second camera column 1 and the second camera column 2 are disposed. In the second camera train, three CCD cameras h are provided along the width direction of the roll material N of the polarizing plate 15, and in the second camera line 2, six coffee machine cameras are also provided along the width direction. The second camera row 2 is disposed on the downstream side of the i-th camera (four), and is arranged in two rows in order to reliably perform defect detection. The images obtained by the first and second camera rows 1 and 2 are sent to the image processing unit 3, and the defects existing on the surface or inside of the polarizing film roll N are detected using the image embedding technique. The image processing unit 3 can be constituted by software such as an image processing program. Of course, the image processing unit 3 can also be configured by hardware. The image processing unit 3 determines whether or not it is a defect and also determines the defect position. As described above, the first and second camera rows 1 and 2 and the image processing unit 3 can function as a defect detecting mechanism capable of detecting 27 defects in which a known strip-shaped sheet-like product can be used. In addition, the defect determination algorithm when using image processing program
打印機6(相當於缺陷記錄機構)是喷墨打印機,當由圖 5像處埋部3處理後發現存在缺陷時,在偏振片捲筒材N的寬 度方向端部(薄片面上)打印條。而且,打印辦也可以 使用噴墨式以外的設備。打印機驅動部5根據來自系統控制 部4的指命對打印機6進行驅動。即,當由圖像處理部3進行 處理而檢測出缺陷時,將該缺陷的位置資訊以條碼的形狀 !〇 進行打印(記錄)。The printer 6 (corresponding to the defect recording mechanism) is an ink jet printer. When a defect is found by the image-embedded portion 3 of Fig. 5, the strip is printed on the end portion (sheet surface) in the width direction of the polarizing plate roll material N. Moreover, the printing office can also use equipment other than inkjet. The printer driver unit 5 drives the printer 6 based on the command from the system control unit 4. That is, when the image processing unit 3 performs processing to detect a defect, the position information of the defect is printed (recorded) in the shape of a bar code !
第1圖中,以K表示缺陷,利用條碼錄相對寬度方 向端部到缺陷位置的距離L的資訊。雖然將條碼B放大顯 示,但是在條碼B的下側還以數值(0815)打印有距離資訊。 該數值是以mm單位表示的距離L值。第丨圖中,雖然將缺陷 15 κ畫得較大,但是,實際中大多是無法用肉眼確認的大小的 缺陷。通過將條碼B和數字一起打印,可以用肉眼確認缺陷 位置。條碼B被打印在寬度方向端部,但是就輸送方向上的 條碼B的打印位置而言,其打印位置在輸送方向上的相位與 缺陷位置相同。所以,如果從條碼B的打印前端位置沿寬度 20 方向查找’就可以發現存在於所記錄的距離位置上的缺陷。 打印了條碼B的偏振片捲筒材N被捲繞成捲筒1〇的形 態而保管。條碼B的打印是在寬度方向端部進行,被打印在 最終不作為製品使用的位置上。所以,即使將打印了條碼B 的偏振片捲筒材N捲繞成捲筒10,也不會因條碼B打印位置 28 1328112 的膨脹而將缺陷擴大至其他的正常的區域。 偏振片捲筒材N的輸送利用輸送滾筒進行,可沿著輸送 路控在適宜的位置上配置輸送滾筒。利用該輸送滾筒等, 可以構成將偏振片捲筒材N捲繞成捲筒1〇的機構。另外,還 5設有連動於偏振片捲筒材N的輸送的回轉式編碼器(未圖 示)’從而可以使得由各攝影機列1、2獲取圖像的時間和由 打印機6打印條碼的時間同步。 下面利用第2圖對讀取條碼的系統的構成進行說明。利 用輸送滾筒11等拉出機構,從捲筒1〇依次將偏振片捲筒材N 10拉出。條碼閱讀器7(相當於位置資訊檢測機構)讀取打印在 偏振片捲筒材N的寬度方向端部的條碼3。被條碼閱讀器7 讀取的條碼信號被送至條碼解析部12。標識器8 (相當於標 記機構)根據記錄在條碼B上的位置資訊,在缺陷位置進行 ‘ 。沿著偏振片捲筒材^^的寬度方向配置有多個標識器 15 8 ’僅使與缺陷位置對應的標識器8動作。標識器驅動部9根 據系統控制部4的指令,驅動位於被選擇的位置的標識器 8使之進行標記。標記M是對缺陷位置K進行的處理,就 私°己馗的形狀而言,只要是用肉眼可以識別的形狀,無論 疋心樣的形狀、大小都可以採用。標記除了利用油墨進行 的打印以外,也可以利用由切割器加上傷痕標記的方法等 適宜的標記方法進行。 雖然在第2圖中沒有表示,但是在捲筒材的相反一側的 端°卩上還設置有一組條碼閱讀器。這是因為,當該捲筒材 在途中被翻捲奇數次時,條碼就會被移動至相反一側。而 29 1328112 ^ ’此時’由於缺㈣是存在於條碼的前端 =度方向的位置上,因此應預先 = 的量後進行標記。 冗长度 在標識器8的下流側,設有夫_ _ & 1 從㈣翔沖裁裝置(機構), ίο 15In Fig. 1, the defect is represented by K, and the information of the distance L from the end portion of the width direction to the defect position is recorded by the bar code. Although the bar code B is enlarged, the distance information is printed on the lower side of the bar code B by the value (0815). This value is the distance L value expressed in mm units. In the figure, although the defect 15 κ is drawn to be large, in reality, it is often a defect of a size that cannot be confirmed with the naked eye. By printing the barcode B together with the number, the defect position can be confirmed with the naked eye. The bar code B is printed at the end in the width direction, but in terms of the printing position of the bar code B in the conveying direction, the phase of the printing position in the conveying direction is the same as the position of the defect. Therefore, if a defect is searched from the print leading end position of the bar code B in the width 20 direction, the defect existing at the recorded distance position can be found. The polarizing plate roll material N on which the barcode B is printed is wound into a roll 1 而 and stored. The printing of the barcode B is performed at the end in the width direction and is printed at a position which is not used as a product at the end. Therefore, even if the polarizing plate roll N on which the barcode B is printed is wound into the reel 10, the defect is not expanded to other normal areas due to the expansion of the bar code B printing position 28 1328112. The transport of the polarizer web N is carried out by means of a transport roller, and the transport roller can be disposed at a suitable position along the transport path. By means of the transport roller or the like, a mechanism for winding the polarizing plate roll N into a roll 1 can be configured. Further, a rotary encoder (not shown) that is linked to the conveyance of the polarizing plate roll N is provided to allow the time for acquiring images from the respective camera rows 1, 2 and the time for printing the barcode by the printer 6. Synchronize. Next, the configuration of a system for reading a barcode will be described using FIG. The polarizing plate roll N 10 is sequentially pulled out from the roll 1 by using a pulling mechanism such as the conveying roller 11. The bar code reader 7 (corresponding to the position information detecting means) reads the bar code 3 printed on the end portion in the width direction of the polarizing plate roll N. The barcode signal read by the barcode reader 7 is sent to the barcode analyzing unit 12. The marker 8 (equivalent to the marking mechanism) performs ‘ at the defect position based on the position information recorded on the barcode B. A plurality of markers 15 8 ' are disposed along the width direction of the polarizing plate roll member to operate only the marker 8 corresponding to the defect position. The marker drive unit 9 drives the marker 8 at the selected position to mark it according to an instruction from the system control unit 4. The mark M is a process for the defect position K, and as long as it is a shape recognizable by the naked eye, it can be used regardless of the shape and size of the heart. In addition to the printing by the ink, the marking may be carried out by a suitable marking method such as a method of adding a scar to the cutter. Although not shown in Fig. 2, a set of bar code readers is also provided on the opposite side of the web. This is because when the web is rolled an odd number of times on the way, the barcode is moved to the opposite side. And 29 1328112 ^ 'At this time' because the lack of (four) is in the position of the front end of the bar code = degree direction, it should be marked with the amount of = before. Length of redundancy On the downstream side of the marker 8, there is a _ _ & 1 from (four) xiang punching device (institution), ίο 15
從帶狀的偏振片捲筒上沖裁出具有最終製品的形離的 各個偏振片2(^在被沖裁出的偏振片辦中,對於打二了 標記Μ的部分於無法作為製品使用,因此在檢查程序 中去除。通過改變沖裁裝置的沖裁模,可以沖裁各種大小 的偏振片2G。即’可以從相同的偏振片捲筒材ν獲得各種大 小的偏振片20。所以,如第丄圖中說明所*,在預先對偏振 片捲筒材N進行檢查後,就可以捲繞成捲筒1Q而進行保管。 本發明採用如下的構成,即,利用與偏振片捲筒_ 的輸送動作連動的回轉式編碼器,使得由條碼閱讀器7讀取 條碼的時間和由標識器8進行標記的時間同步。 <系統的動作>Each of the polarizing plates 2 having the final product is punched out from the strip-shaped polarizing plate roll (^ in the punched polarizing plate, and the portion marked with the mark is not used as a product, Therefore, it is removed in the inspection program. By changing the punching die of the punching device, the polarizing plates 2G of various sizes can be punched out. That is, 'the polarizing plates 20 of various sizes can be obtained from the same polarizing plate roll cylinder ν. In the drawing, the polarizing plate roll material N is inspected in advance, and then it can be wound into a roll 1Q for storage. The present invention adopts a configuration in which the polarizing plate roll is used. The rotary encoder that conveys the motion linkage causes the time at which the barcode reading by the barcode reader 7 is synchronized with the time marked by the marker 8. <Action of the system>
下面利用第3圖的流程圖對第卜2圖所示的系統的動作 進行說明。首先,通過在PVA薄片的兩面上黏貼TAC膜,連 續製造出偏振片捲筒材(#1)。偏振片捲筒材N被沿著輸送路 徑配置的輸送滚筒以一定速度輸送。利用第丨攝影機列1和 2〇第2攝影機列2獲得偏振片捲筒材N的圖像,發送至圓像處理 部3(#3)。圖像處理部3對所獲得的圖像數據進行圖像處理和 解析,判定疋否存在缺陷(#5)。當檢測出缺陷時,驅動打印 機6,進行條碼的打印(#7、9、11)。另外,在打印條碼^的 同時,還打印數字。在進行了條碼β的打印後,將偏振片捲 30 筒材N捲繞成捲筒10而進行保管(#13)。 當從偏振片捲筒材N上沖裁作為製品的偏振片時,以如 下的順序進行。首先,從捲筒1〇依次拉出並輸送偏振片捲 琦材N。利用條碼閱讀器7檢測是否打印有條碼Β(#π)。當 檢測出打印有條碼時,對其進行讀取,將條碼信號送至條 碼解析部12(#19)。條碼解析部12解析條碼,讀取缺陷位置。 使對應於該缺陷位置的標識器8動作,在缺陷位置進行標記 (#23)。當通過標識器8的位置後,利用沖裁裝置沖裁出各個 偏振片20(#25)。被沖裁的偏振片20當中,將進行了標記的 部分從生產線上除去。 對於從生產線上去除不良的偏振片2〇的時間,可以適 宜地設定。例如’在將各個偏振片2〇取出的位置上也設置 條碼閱讀器,當檢測出條碼時,利用蜂鳴器或LEd進行顯 示’使機器暫時停止。LED可沿寬度方向並列配置多個, 並只點亮存在缺陷的位置上的LEd。操作者僅將位於LED 點亮的位置上的偏振片取出,再次起動機器。這樣就可以 僅使正常的偏振片流向下一程序。 此外’也可以採用利用機器只將不良的偏振片向生產 線外自動地排出的結構。另外,也可以在帶有缺陷的情況 下,對該偏振片下進行沖裁裝置的沖裁操作。 <與其他的方式的比較> 將本發明的缺陷記錄方法與其他的方法進行比較。第4 圖是對其他的方法進行簡單說明的圖。是使由CCd攝影 機檢測出的缺陷位置在紙上以地圖形式顯示的方法。(B)是 1328112 將缺陷的位置資訊記錄在紙或柔性盤等記錄裝置上的方 法。(C)是在偏振片捲筒材的端部黏貼標籤的方法。(D)是在 偏振片捲筒材的缺陷位置黏貼標籤的方法。(E)是對偏振片 捲筒材的缺陷位置進行標記的方法。而且,所述的任意一 5種方法在記錄了缺陷資訊後,都將偏振片捲筒材捲繞成捲 筒而保管。將評價結果表示在表1中。 [表1] 評價項目 本發明 (A) (B) (C) (D) (E) 因打痕造成的對合 格品部分的損傷 〇 〇 〇 〇 X X 因過度檢測造成的 材料利用率降低 〇 〇 〇 〇 〇 X 標記位置精度 〇 X X □ 〇 〇 機械故障/維護 〇 〇 〇 X X 〇Next, the operation of the system shown in Fig. 2 will be described using the flowchart of Fig. 3. First, a polarizing plate roll (#1) was continuously produced by adhering a TAC film on both sides of a PVA sheet. The polarizing plate roll N is conveyed at a constant speed by a transport roller disposed along the transport path. An image of the polarizing plate roll material N is obtained by the second camera line 1 and the second camera line 2, and is sent to the circular image processing unit 3 (#3). The image processing unit 3 performs image processing and analysis on the obtained image data, and determines whether or not there is a defect (#5). When a defect is detected, the printer 6 is driven to perform bar code printing (#7, 9, 11). In addition, the number is printed while the barcode is printed. After the printing of the barcode β is performed, the polarizer roll 30 is wound into a roll 10 and stored (#13). When the polarizing plate as a product is punched from the polarizing plate roll N, it is carried out in the following order. First, the polarizing plate roll material N is sequentially pulled out from the roll 1 。. The bar code reader 7 is used to detect whether or not a bar code Β (#π) is printed. When it is detected that a bar code is printed, it is read, and the bar code signal is sent to the bar code analyzing section 12 (#19). The barcode analyzing unit 12 analyzes the barcode and reads the defective position. The marker 8 corresponding to the defect position is operated and marked at the defect position (#23). After passing the position of the marker 8, each of the polarizing plates 20 (#25) is punched out by a punching device. Among the punched polarizing plates 20, the marked portions are removed from the production line. The time for removing the defective polarizing plate 2 from the production line can be appropriately set. For example, a bar code reader is also provided at a position where each of the polarizing plates 2 is taken out, and when a bar code is detected, display is performed by a buzzer or LEd' to temporarily stop the machine. The LEDs can be arranged in parallel along the width direction and only illuminate the LEd at the location where the defect exists. The operator only takes out the polarizing plate located at the position where the LED is lit and starts the machine again. This allows only the normal polarizer to flow to the next program. Further, it is also possible to employ a structure in which only a defective polarizing plate is automatically discharged to the outside of the production line by the machine. Alternatively, the punching operation of the punching device may be performed on the polarizing plate in the case of a defect. <Comparison with other methods> The defect recording method of the present invention is compared with other methods. Figure 4 is a diagram for a brief description of other methods. This is a method of displaying the defect position detected by the CCd camera on a paper in the form of a map. (B) is 1328112 A method of recording the position information of a defect on a recording device such as a paper or a flexible disk. (C) is a method of attaching a label to the end of a polarizing plate roll. (D) is a method of attaching a label to a defect position of a polarizing plate roll. (E) is a method of marking the defect position of the polarizing plate roll. Further, in any of the above five methods, after the defect information is recorded, the polarizing plate roll is wound into a roll and stored. The evaluation results are shown in Table 1. [Table 1] Evaluation item The present invention (A) (B) (C) (D) (E) Damage to the part of the qualified product due to the flaw 〇〇〇〇 XX The material utilization rate due to over-detection is lowered 〇〇 〇〇〇X mark position accuracy 〇 XX □ 〇〇 mechanical failure / maintenance 〇〇〇 〇 〇
由表1可見,本發明的方法優於其它方法。方法(A)在 10作為其他的介質的紙上以地圖形式表示,很難知道缺陷位 置位於何處。方法(B)也是如此。另外,當記錄在與偏振片 捲筒材不同的介質上時,很容易產生誤差(輸送方向的誤 差)。這是因為,偏振片捲筒材在被輸送期間,很容易發生 拉伸等。所以’在被記錄的缺陷位置的精度方面就會有問 15 題。方法(c)無法知道缺陷存在於寬度方向上的哪個位置 上。另外,有可能產生標籤的黏貼錯誤《方法(D)在捲繞成 捲筒後,會在正常區域上產生打痕。方法(E)也是如此。本 發明的方法在全部的評價項目中都是優。 <其他的實施方式> 32 1328112As can be seen from Table 1, the method of the present invention is superior to other methods. The method (A) is represented as a map on paper 10 as another medium, and it is difficult to know where the defect is located. The same is true for method (B). Further, when recorded on a medium different from that of the polarizing plate, it is easy to cause an error (error in the conveying direction). This is because the polarizing plate roll is easily stretched or the like during being conveyed. So there are 15 questions about the accuracy of the recorded defect location. The method (c) cannot know where the defect exists in the width direction. In addition, there is a possibility that the label is pasted incorrectly. "Method (D), after being wound into a roll, will cause scratches on the normal area. The same is true for method (E). The method of the present invention is excellent in all evaluation items. <Other Embodiments> 32 1328112
(1) 本實施方式中,雖然將用於獲取偏振片捲筒材的圖 像的攝影機列設為2列,但是並不限定於此,既可以是1列, 也可以是3列以上。另外,還可以適當設定沿寬度方向配置 的CCD攝影機的台數。另外,缺陷檢測機構也可以不是CCD 5 攝影機,可以採用其他類型的傳感器。由CCD攝影機拍攝 的圖像既可以是反射光圖像,也可以是透射光圖像。當採 用透射光圖像時,在薄片的背面側配置光源,在薄片的表 面側配置CCD攝影機。 (2) 本實施方式中,雖然用條碼記錄位置資訊,但是並 10 不限定於此。也可以用條碼以外的形態進行打印。當以條 碼進行記錄時,也可以不進行數字的打印。條碼也可以不 是1維的,而採用2維條碼。另外,作為記錄在條碼中的資 訊,也可以不僅記錄位置資訊,還組合記錄製造年月曰等 其他的任意資訊。當用距離資訊進行記錄時,距離的單位 15 也可以使用mm以外的單位。 (3) 本實施方式中,雖然作為薄片狀製品的例子舉出了 偏振片,但是,並不限定於此。 【圖式簡單說明】 第1圖是表示薄片狀製品的檢查系統的構成的示意圖 20 (條碼打印)。 第2圖是表示薄片狀製品的檢查系統的構成的示意圖 (條碼讀取)。 第3圖是表示系統的動作的流程圖。 第4(A)〜(E)圖是表示利用其他方式的缺陷記錄方法的 33 1328112 圖。 【主要元件符號說明】 1...第1攝影機列 9...標識器驅動部 la...CCD攝影機 10...捲筒 2...第2攝影機列 11...輸送滚筒 2a...CCD攝影機 12...條碼解析部 3…圖像處理部 20...偏振片 4...系統控制部 B...條碼 5...打印機驅動部 K...缺陷 6...打印機 M...標記 7...條碼閱讀器 N...偏振片捲筒材 8...標識器 34(1) In the present embodiment, the number of camera rows for acquiring the image of the polarizing plate roll is two rows. However, the number of the cameras is not limited thereto, and may be one column or three columns or more. Further, the number of CCD cameras arranged in the width direction can be appropriately set. In addition, the defect detecting mechanism may not be a CCD 5 camera, and other types of sensors may be employed. The image taken by the CCD camera can be either a reflected light image or a transmitted light image. When a transmitted light image is used, a light source is disposed on the back side of the sheet, and a CCD camera is disposed on the surface side of the sheet. (2) In the present embodiment, the position information is recorded by the bar code, but the number 10 is not limited thereto. It is also possible to print in a form other than a barcode. When recording in a barcode, it is also possible to print without numbers. Barcodes can also be 1D, but 2D barcodes. In addition, as the information recorded in the barcode, it is also possible to record not only the location information but also any other information such as the manufacturing year and month. When recording with distance information, the unit of distance 15 can also use units other than mm. (3) In the present embodiment, a polarizing plate is exemplified as a sheet-like product, but the invention is not limited thereto. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing the configuration of an inspection system for a sheet-like product 20 (barcode printing). Fig. 2 is a schematic view showing the configuration of an inspection system for a sheet-like product (bar code reading). Fig. 3 is a flow chart showing the operation of the system. Figures 4(A) to (E) are diagrams showing 33 1328112 using other methods of defect recording. [Description of main component symbols] 1...first camera column 9...marker drive unit la...CCD camera 10...roll 2...second camera column 11...transport roller 2a. .. CCD camera 12...bar code analysis unit 3...image processing unit 20...polarizer 4...system control unit B...bar code 5...printer drive unit K...defect 6.. .Printer M...Marker 7...Barcode Reader N...Polarizer Roller Cartridge 8...Marker 34
Claims (1)
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| JP2003202349 | 2003-07-28 |
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| TW200510710A TW200510710A (en) | 2005-03-16 |
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| TW093122272A TW200510710A (en) | 2003-07-28 | 2004-07-26 | Inspection method for sheet-shaped product and inspection system |
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| KR (1) | KR20050013491A (en) |
| CN (1) | CN100476414C (en) |
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| JP2007093411A (en) * | 2005-09-29 | 2007-04-12 | Olympus Corp | Substrate inspection apparatus |
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| KR101471500B1 (en) * | 2007-02-21 | 2014-12-11 | 무사시 엔지니어링 가부시키가이샤 | A method and apparatus for controlling application of ink-jet head |
| KR100899558B1 (en) * | 2007-05-03 | 2009-05-27 | 에버테크노 주식회사 | Marking Control Method of Polarizing Film Inspection System |
| CN101413903B (en) * | 2007-10-19 | 2011-05-18 | 欣竑科技有限公司 | Abnormal detection method of conduction tape of electronic component tape punching machine |
| DK2291101T3 (en) | 2008-06-26 | 2013-06-17 | Kingsdown Inc | METHODS AND APPARATUS FOR COMFORT / SUPPORT ANALYSIS OF A SLEEP SUPPORT ELEMENT |
| CN101368974B (en) * | 2008-09-28 | 2011-11-30 | 张德丰 | Method for printing defect on workpiece |
| JP2010262265A (en) * | 2009-04-10 | 2010-11-18 | Nitto Denko Corp | Optical film roll substrate and method of manufacturing image display device using the same |
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| JP6182806B2 (en) * | 2013-06-04 | 2017-08-23 | 住友化学株式会社 | Defect inspection system and film manufacturing apparatus |
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| JP2017075936A (en) * | 2015-10-15 | 2017-04-20 | 住友化学株式会社 | Optical film manufacturing apparatus and manufacturing method |
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| CN107064175B (en) * | 2017-06-14 | 2019-11-01 | 福州东旭光电科技有限公司 | Off-line type glass substrate conveying device and glass substrate defect detecting device |
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| CN109540797B (en) * | 2018-12-21 | 2021-12-10 | 东华大学 | Reflection type measuring device and method for fiber bundle arrangement uniformity and fracture morphology |
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-
2004
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| CN1576828A (en) | 2005-02-09 |
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