TWI375821B - - Google Patents

Description

1375821 IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to a method for adjusting a squeegee of an oxime release liner, an adhesive layer on a release treatment surface of a lindenone release liner, and an optical layer of a rigid layer The constitution layer and the method for producing the same, and the adhesive-attached optical member, the step of using the above-mentioned adhesive layer for an optical member: a liquid crystal two-input organic electroluminescence (EL) display device, and a PDP (four) image_4.光学 The optical member is, for example, a polarizing plate, a phase difference plate, an optical compensation film, a brightness enhancement film, and the like. [Prior Art] An optical member such as a liquid crystal display device, for example, a polarizing plate or a phase difference plate, is attached to a liquid crystal element using an adhesive. Usually, it is an adhesive optical member in which an adhesive layer is laminated on an optical member. Since the optical member has a large degree of expansion and contraction under the condition of heating or humidification, it is easy to cause lifting or peeling after the attachment. Therefore, the adhesive for optical members is required to have a long-term response under heating or humidification conditions. Further, an adhesive optical member such as a crucible is usually formed integrally with a release liner to which an anthrone is removed, and exhibits smoothness. The release liner of the adhesive optical member is used for precision coating on a ruthenium (polyethylene terephthalate) film because it is excellent in transparency, heat resistance, smoothness, and appearance defects. A release liner formed by a ketone. The 嗣 嗣 嗣 塾 塾 可 于 于 于 于 于 于 于 不需要 不需要 不需要 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 Too small, there is a problem that the release liner is lifted or peeled off during the manufacturing process of the optical member such as punching, so the peeling force must be appropriate. In the method of adjusting the above-mentioned peeling force to an appropriate size, for example, a method of changing the amount of use of the anthrone component has been proposed (for example, refer to Patent Document No. 2 and Patent Document 2). However, if a peeling force is adjusted by using, for example, a heavy release agent or the like in the fluorenone component, the heavy release agent may be transferred onto the adhesive face to cause a decrease in adhesive properties. Further, it is known that when the anthrone release liner is wound around the original sheet, the heavy release agent is transferred to the back surface, which causes a defect when the release liner is peeled off. [Patent Document 1] Japanese Laid-Open Patent Publication No. 2000-199199. SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to provide a method for adjusting the peeling force of an anthrone release liner. The peeling force of the brewing j release liner can be easily adjusted without using an anthrone component such as a heavy release agent. Further, an object of the present invention is to provide a viscous (four) layer for an optical member and a method for producing the same, which are excellent in durability and have a peeling force. Further, an adhesive optical member having the above-described adhesive layer and an image display device using the adhesive optical member are provided. As a result of an effort to achieve the above object, the present invention has found that the above method can achieve the above object of the peeling force adjustment method of the anthrone release liner and complete the present invention. That is, the method for adjusting the peeling force of the anthrone release liner of the present invention comprises: a process of providing an adhesive composition layer containing a base polymer and a peroxide on a release treatment surface of the anthrone release liner; A process in which one or both of the foregoing peroxides are heated and decomposed. Further, a method for producing an anthranone release liner adhesive layer of the present invention, which is a method for producing an adhesive layer comprising a base polymer and a peroxidation provided on a release treatment surface of an anthrone release liner Adhesive composition • The process of the layer and includes a process for adjusting the peel force of the anthrone release liner. According to the method for adjusting the peeling force of the fluorenone release liner of the present invention, as shown in the results of the examples, the base polymer and the peroxide adhesive composition layer are provided by using the release treatment surface contained in the fluorenone release liner. The peeling force of the fluorenone release liner can be easily adjusted by the process and the peeling force adjustment method of the fluorenone release liner which partially or completely heat-decomposes one of the above-mentioned peroxides. The detailed reason for the peeling force of the liner can be easily adjusted by the above adjustment method. Although the detailed reason for the peeling force of the liner is not clear, it is presumed that the thermal radical decomposition of the peroxide in the adhesive composition generates active radicals, so that the anthrone molecule Dehydrogenation occurs in the process, resulting in denaturation of the oxime surface. In the method for adjusting the peeling force of the above-mentioned anthrone release liner, it is preferred that the above-mentioned adhesive composition lg is heated and decomposed. The peel force can be adjusted by adjusting the amount of peroxide to exhibit an appropriate peel force. The method for producing the ketone ketone release liner adhesive layer of the present invention comprises the process of providing a base polymer and an adhesive composition layer of the over 8 7 582821 = compound on the release treatment surface of the fluorenone release liner. The adhesive layer manufacturing method, the sister contains a process for adjusting the peeling force of the anthrone release liner. By using the "manufacturing", an adhesive layer for an optical member excellent in durability and having a peeling force can be obtained. In the method for producing the pressure-sensitive adhesive layer, the base polymer of the pressure-sensitive adhesive composition preferably contains (meth)acrylic acid in an amount of 80 parts by weight or more per 100 parts by weight of the monomer. Dilute acid polymer. By using the dot composition, an adhesive layer for an optical member excellent in durability and having a moderate peeling force can be obtained. Further, in the method for producing the above-mentioned pressure-sensitive adhesive layer, 1 part by weight of the adhesive composition may contain 1 part by weight of the money coupling agent G.G. By using the adhesive composition, an adhesive layer for an optical member excellent in durability and having a moderate peeling force can be obtained. On the other hand, the method for producing an anthraquinone release liner adhesive sheet of the present invention comprises a process for providing an adhesive composition layer containing a base polymer and a peroxide on a peeling treatment surface of a Shi Xigang release liner. It is characterized in that the peeling force of the Shi Xiying release liner is adjusted to a range of 〇1 to 〇4ν/5〇_ by a process of thermally decomposing part or all of the peroxide. By using this production method, it is possible to obtain an anthraquinone release liner-adhesive sheet which is excellent in durability and has a moderate peeling force. Further, the adhesive layer for an optical member of the present invention is produced in accordance with the above method. Since the pressure-sensitive adhesive layer of the present invention can function as described above, it is possible to obtain an adhesive sheet for an optical member which is excellent in durability and has a moderate peeling force by using the pressure-sensitive adhesive layer of the present invention. Therefore, it is particularly suitable for the 8 8 1375821 peeling type adhesive layer β. The optical member used in the present invention is formed by forming a release sheet on the adhesive layer. According to the light of the present invention, the second film is used for the purpose of exhibiting the above-mentioned effects, and the optical member for the optical member having excellent long-term durability and moderate peeling force is attached to the sword optical member. For ··· is in Guangcheng. The optical member (4) is formed of the adhesive layer. The adhesive member-attached optical member of the present invention has an adhesive layer capable of exhibiting an effect, and thus can be an adhesive-attached optical member excellent in durability and having a peeling force. The display device of the device is used for the liquid-day display device, the organic electroluminescence (EL) display device, and the ρε:: stored in the high-temperature and high-humidity state without using the above-mentioned adhesive optical member. Bubbles, when you can use them, then the force is also "large, can be; easily under the _. [Embodiment] Hereinafter, embodiments of the present invention will be described in detail. The release treatment surface of the release ketone release liner of the ketone release liner of the present invention contains .... It is included in the process of setting up the layer of the adhesive layer of the base polymer and peroxide, and the process of decomposing all the other parts of the peroxide. Invention#Reagent composition layer< In the process, the dispersing solvent of the composition of the agent is applied, and the coating is applied to the hot melt coating. However, in order to improve the coating, it is preferred to use a dispersing solvent. The dispersion solvent is not particularly limited. For example, an organic solvent such as toluene, B =, an alcohol or an organic compound, water or the like can be suitably used. It may be applied directly to the solvent used in the polymerization, or may be appropriately added. Each of the agents such as 5H may be used singly or in combination of two or more. For example, "Adhesive Handbook (2nd Edition), 174th Stomach, Adhesive Tape Industry Association" '1995.10.12' shows the use of a condensation reaction type ketone stripping agent (for example, 'generally has a hydroxyl group at both ends Polydimethyl methoxy oxime as a base polymer, polymethyl hydride dioxime as a cross-linking agent, kicking oxime as a catalyst, and addition reaction type ketone stripping agent (for example, Generally, a part of the methyl group in the polydimethyl oxalate which has a trans-group is substituted into a base-based polymer, and a polymethyl-methadiene is used as a cross-linking agent to a platinum system. The catalyst is a catalyst and an addition reaction type ketone stripper. However, the present invention is not particularly limited, and any release liner of a release agent may be used. The peroxide of the present invention can be used as long as it can generate active radicals by heating and react with the ketone of the release liner, but it is preferable to use the one-minute half-life temperature as the ribs. It is better to use a peroxide having a one-minute half-life temperature of 90 to 140 〇c. If the one-minute half-life temperature is too low, the reaction may be carried out during the storage before the coating is dried, so that the viscosity becomes high and it is impossible to coat. On the other hand, the temperature of the right 1 knives and half mourning period is too high.] As the temperature during the cross-linking reaction changes, the side b may undergo side reactions, or many unreacted peroxides remain.

JOZI cross-linking has been going on, so it is not good. The index of decomposition rate is the half-life of the b-b substance, which is the time when the peroxide is half-life at any time. The half-life time, the temperature of the solution, or the catalogue of each quotient at any temperature, for example, is described in the 曰本 = machine peroxide catalogue version 9 (_3 years.... The invention can be used Oxide, peroxydicarbonic acid (1 minute Feng & (2 ethylhexyl) knives hand temperature: 9 〇.6t), bis (4_second butyl Cyclohexyl) peroxydicarbonate Eight pull ·, Le Yi Ding § 曰 U minutes half-life temperature: 92 rc), two second butyl peroxydicarbonate n eight, one (knife clock half-life temperature: 92.4 ° c), the third Ding Oxygen neodecanoate (1 minute I 吝 1 knives clock + mourning temperature: 1 〇 3.5. 〇, third hexyl peroxydimethyl acetate vinegar · _ a 'half-agricultural temperature: 1 〇 9.1I3c ), tert-butyl peroxy: methyl acetate vinegar (1 minute half-life temperature: 11 〇 rc), dilaurin-based peroxide boring knife clock half-life temperature: 116 4. 〇, di-n-octyl peroxide peroxide 0 minute half-life temperature: ethylhexanoic acid S (1 minute half-life temperature: 124 3. 〇, bis (4 methyl benzoyl) peroxide (1 minute half-life temperature) : 128.2t), benzoyl hydrazine peroxide (1 minute half-life temperature: 13 〇〇. 〇, t-butyl peroxyisobutyrate vinegar 0 minute half-life temperature: 136.rc), 1,1. (Third hexyl peroxide) Cyclohexane (1 minute half-life temperature: 149.2. Hydrazine, etc. Among them, since the crosslinking reaction efficiency is particularly excellent, it is preferred to use bis(4·t-butylcyclohexyl)peroxy-one. Carbonate (1 minute half-life temperature: 92.1. (:), dilauroyl peroxide (1 minute half-life temperature: 116.4. 〇, benzophenone peroxide) 1 minute half-life temperature: 13 〇.〇° c) The above-mentioned peroxide may be used singly or in combination of two or more kinds. 1375821 The adhesive composition of the present invention is applied to a peeling treatment and dried, and a layer having an adhesive composition is formed. Moreover, the adhesive composition layer formed on other substrates may also be used. In the peeling force adjustment method of the present invention, in addition to adjusting the amount of peroxide, the decomposition treatment temperature and the decomposition treatment time are also important factors. In the present invention, the amount of peroxide decomposition, the aforementioned adhesive composition Ig, preferably adjusted to 1~2"m〇b is preferably 2~16"mob to 2~12" and preferably. If the decomposition amount of peroxide is lower, the peeling force will become too small, If it is higher than 2" mol, the peeling force may become too large, so it is not good. = The peroxide is more than 2 parts by weight of the adhesive composition (10 parts by weight). If it is lower than .2, the peeling force of the heavy separator may become too small. On the other hand, if it is higher than 2 parts, the peeling force will be too large, or the adhesive layer will be too large. In the middle of the night, the peroxide changes the adhesion characteristics with time. Regarding the decomposition treatment temperature and decomposition treatment time of the peroxide, the :2 can adjust the decomposition amount of the peroxide to the composition of the adhesive. The object lg is preferably // _ more preferably 2 to 12 卜,疋 'If the temperature is 1 70 〇C to process the temperature, you can use the dry 昧i, but the b can cause side reactions. Decompose 捍 鲑 鲑 step, time, dish, or can be 4 knives after drying Treatment. 虚理味p bow ^ Α π, β, can consider the productivity or workability setting, the hanging is 0 · 2 ~ 2 0 minutes; t die, π knife ring around ' 又. 5~10 minutes or so Preferably, the adhesive composition used may have a mouth-and-stick viscosity in the above composition, and the helmet is particularly limited, preferably (meth)acrylic acid 12 1375821 糸 polymer is used as the base polymer. Adhesive composition The (meth)acrylic acid can be used as the monomer component of the base polymer, and an ester formed with an alcohol having 12 or less carbon atoms can be used. In particular, a (fluorenyl) acrylic monomer having an alkyl group having 4 to 12 carbon atoms is preferred. The (meth)acrylic monomer may, for example, be methyl (meth)acrylate, ethyl (meth)acrylate, propyl (mercapto)acrylate, (mercapto)acrylic acid, n-butyl ester, Tert-butyl (meth)acrylate, isobutyl (meth)acrylate, amyl (meth)acrylate, hexyl (meth)acrylate, 2-ethyl hexyl (meth)acrylate, (A) Base n-octyl acrylate, isooctyl (meth)acrylate, n-decyl (meth)acrylate, isodecyl (decyl) acrylate, n-decyl (meth) acrylate, (methyl) propyl Isodecyl diester, (decyl) n-dodecyl acrylate. These bismuth acrylate monomers may be used singly or in combination of two or more. In the present invention, '(meth)acrylic acid-based polymer means an acrylic polymer and/or a mercaptoacrylic polymer, and (mercapto)acrylate means acrylate and/or methacrylate. . The (meth)acrylic polymer is preferably a (mercapto)acrylic polymer having 80 parts by weight of (meth)acrylic acid vinegar, based on 1 part by weight of the monomer component. In the (meth)acrylic acid polymer, the ratio of the alkyl (meth)acrylate is preferably 8 parts by weight or more (for example, about 80 to 99.8% by weight) based on 100 parts by weight of the monomer component. It is better to use 85 heavy U 々 v L system. If it is less than 80 parts by weight, stress relaxation is lacking, which is not preferable. In the present invention, a functional group-containing monomer having a functional group such as a trans group may be used. The kind of the functional group can be appropriately selected. 13 1375821 Specific examples of the above-mentioned functional group-containing monomer include, for example, (mercapto) acridine, itaconic acid, maleic acid, crotonic acid, maleic acid liver, 2-(indenyl) propylene oxide a fluorenyl-containing monomer such as ethyl succinic acid or 2-(methyl) propylene oxyethyl phthalic acid or an anhydride thereof; (meth) acrylamide, N,N-dimethyl(methyl) propyl Thin amine, N-hydroxydecyl (decyl) acrylamide, N-decyloxymethyl (decyl) propylene. · Amine, N-butoxymethyl (decyl) acrylamide, etc. Amidoxime-containing monomer; (methyl)-* 2-hydroxyethyl acrylate, 2-hydroxypropyl (meth) acrylate, 3-methyl propyl acrylate, (meth) propyl Dilute acid 2-butyl butyl ketone, (mercapto) propylene > acid 3-hydroxybutyl ester, (meth)acrylic acid 4-hydroxybutyl ester, polyethylene glycol mono (meth) acrylate, etc. An amine-containing monomer such as (fluorenyl) bis-decylamino acrylate, tert-butylaminoethyl (meth) acrylate; (meth) propyl propyl acrylate Monomer of propyl; (fluorenyl)propionitrile, (hexyl) acrylonitrile Morpholine, N- · 2 · ρ-vinyl pyrrolidone and the like. The functional group-containing monomer may be used singly or in combination, and the content of the monomer having a fluorenyl group is 100 parts by weight of the monomer component of the (fluorenyl) acrylic polymer, preferably 0 01. 2 parts by weight, and more preferably in parts by weight. If the content of the monomer having a functional group is less than 001 parts by weight, the crosslinking is insufficiently formed, and the durability is deteriorated, which is not preferable. On the other hand, if the monomer content of the yam-containing yam is more than 20 parts by weight, the adhesion to the liquid crystal element or the like may become too large or too good. The (fluorenyl) acrylic polymer used in the present invention has a weight average molecular weight of 10 to 5,000,000, preferably 20 to 4,000,000, more preferably 30 to 3,000,000. If the weight average molecular weight is less than 100,000, the cohesive force of the adhesive composition is 纥, and it is easy to produce a slag. On the other hand, if the weight average molecular weight exceeds 50,000, 1375821 1 », the fluidity of the polymer is lowered to make the affinity to the polarizing plate insufficient, and the peeling tendency is left between the adhesive composition layer of the optical member or the like. air. In the present invention, the weight average molecular weight is measured by GPC (gel permeatiation chromatography). The glass transition temperature (Tg) of the above (fluorenyl) acrylic polymer is 'below (usually _100 ° C or more), preferably -10 ° C or less. If the glass transition temperature is higher than 〇 ° C, the polymer does not easily flow, so that the affinity for the polarizing plate is insufficient, and the air is left between the polarizing plate and the adhesive composition layer of the surface protective film. The Tg of the (fluorenyl) acrylic polymer can be adjusted within the above range by appropriately changing the monomer component or composition ratio used. The glass transition temperature (Τ§) in the present invention means a one measured by a dynamic viscoelastic device. The polymerization method of the (meth)acrylic polymer used in the present invention is not particularly limited, and for example, a known method such as solution polymerization, emulsion polymerization, bulk polymerization, or suspension polymerization can be used. The obtained polymer may be either a random polymer or a block polymer. For example, when solution polymerization is used, a monomer polymerization agent may be added to a polymerization initiator such as azo-butyronitrile, and a polymerization solvent such as ethyl acetate may be used as a polymerization solvent. Nitrogen gas flow was carried out at 5 〇 to 70. (: The reaction is carried out for 8 to 30 hours to obtain a predetermined (meth)acrylic polymer. In the present invention, the '(meth)acrylic polymer can be used as a polymerization initiator in the polymerization. During the polymerization, the peroxide may remain in the adhesive composition layer without being reacted, but the residual peroxide may be used to adjust the peeling force of the release liner. Alternatively, the unreacted k oxide may be used. The residual amount is quantified, and a peroxide is added to a predetermined amount of peroxide as needed. 8 15 1375821 The 'decane coupling agent is not particularly limited in the invention, and a conventional one can be suitably used. For example, '3·epoxypropoxy group Propyltrimethoxydecane, 3-glycidoxypropyltriethoxydecane' 3_glycidoxypropylmercaptodiethoxydecane, 2-(3,4-epoxycyclohexyl Ethyl tridecyloxydecane-containing epoxy-containing decane coupling agent; 3-aminopropyltrimethoxy decane, N 2•(aminoethyl)_3_aminopropylmethyldimethoxy decane , an amine-containing decane coupling agent such as 3_triethoxydecyl _n (1,3_: decylbutylene) propylamine, 3 (meth)acrylic acid-containing decane coupling agent such as propylene oxypropyltrimethoxy decane, 3-mercapto propylene oxypropyltriethoxy decane, etc.; 3 · isocyanate propyl triethoxy decane, etc. The decane coupling agent containing an isocyanate group, etc. In the present invention, the decane coupling agent is preferably used in an amount of 100 parts by weight based on 100 parts by weight of the (meth)acrylic polymer. When the amount of the compounding is increased, the adhesion to the liquid crystal element is increased, and the removability is deteriorated. If the amount is too small, the sealing property may be lowered. The adhesive composition of the present invention It is excellent in heat resistance by appropriately mixing the (fluorenyl) acrylic polymer. The crosslinking agent used in the present invention is, for example, an 'isocyanate compound, an epoxy compound, a melamine resin, or a nitrogen heterocycle. Propane derivatives, metal chelating compounds, etc. Among them, it is mainly from the viewpoint of obtaining an appropriate cohesive force, particularly using an isocyanate compound or an epoxy compound. Especially when manufacturing a polymer, Xiao acrylic 2_ When a hydroxyl group-containing monomer such as hydroxyethyl ester is copolymerized to introduce a hydroxyl group into a polymer, it is preferred to use isocyanate S as a cross-linking compound which can be used alone or in combination. 13?582l isocyanate compound, For example, lower aliphatic polyisocyanates such as butyl diisocyanate and hexamethylene diisocyanate, fats such as cyclopentamethylene diisocyanate, cyclohexyl diisocyanate, and isophorone diisocyanate may be mentioned. Aromatic diisocyanates such as cycloisocyanates, 2,4-toluene diisocyanate, 4,4,-diphenylmethane diisocyanate, xylene diisocyanate, trimethylolpropane/nonylphenyl diisocyanate Ternary adduct (trade name: Coronette L, manufactured by Japan Polyurethane Industry Co., Ltd.), trimethyl methacrylate, and methyl monoisocyanate binary adduct (trade name Krone Isocyanate adducts such as trimeric isocyanate of hexamethylene diisocyanate (trade name: Coronette HX, manufactured by Japan Polyaminophthalate Co., Ltd.), etc. Alcohol Isocyanate adducts. These compounds may be used singly or in combination. The oxo compound may, for example, be N, N, N, N, _ tetraepoxypropyl _m·

Toluene-amine (trade name: TETRAD_X, manufactured by Mitsubishi Gas Chemical Co., Ltd.) or H-bis(N,N-monopropyloxypropylaminomethyl)cyclohexane (trade name, manufactured by Diman Gas Chemical Co., Ltd.). These compounds may be used singly or in combination. The melamine resin may, for example, be hexamethylene methyl melamine or the like. The miscellaneous propylene propylene derivative is exemplified by a commercially available product name (mutual pharmaceutical company). The name is TAZM (manufactured by Mutual Pharmaceutical Co., Ltd.), and the trade name is taz〇 (1). These compounds may be used singly or in combination. The metal component of the metal composition may, for example, be iron, tin, titanium or titanium, and the chelating agent may be, for example, acetylene, methyl acetoxyacetate or lactic acid. These compounds may be used alone or in combination. 17 ^75821 The content of the crosslinking agent used in the present invention is usually about 0.01 to 5 parts by weight based on 100 parts by weight of the above (fluorenyl) acrylic polymer, and it is preferred to adjust the amount of the crosslinking agent to be a crosslinking agent. The gel component after crosslinking is in an amount of from 45 to 95% by weight, more preferably from 5 to 85% by weight. If the gel fraction is less than 45 deg/hr, a problem such as bubbles may occur in the heating test, and the cohesive force of the adhesive composition becomes small, causing the occurrence of slag. On the other hand, if the gel fraction is more than 95% by weight, the cohesive force of the adhesive composition becomes large, and the subsequent property is deteriorated. In the present invention, the 'gel fraction' indicates the degree of crosslinking, which is the ratio of the portion to be crosslinked by the adhesive. The gel fraction measurement method described above is as follows. The adhesive layer immediately after the cross-linking treatment was weighed and found to have a weight fraction (Wi)g. Next, it was coated on a microporous tetrafluoroethylene film (coated film weight Wdg), and ethyl acetate was about 25 at 50 mi. (: After soaking for 2 days, the soluble component was extracted and removed. Then, the pressure-sensitive adhesive layer was taken out from ethyl acetate at 11 Torr. The mash was dried for 1 hour, and the dried weight Ws (g) was measured. The gel fraction (% by weight) of the adhesive layer was determined according to the following formula, and after the coating, after storage for 1 week at room temperature, the gel fraction was measured. Gel fraction (% by weight) = (\^3-\¥2/\^)\100 The adhesive composition of the present invention contains the above (meth)acrylic polymer as a base polymer. In the adhesive layer of the present invention, in addition to the above components Various tackifiers such as phenol resin, terpene-phenol resin, terpene resin, xylene resin, rosin resin, hydrogenated rosin resin, etc.; inorganic fillers such as calcium carbonate and carbon 18 1375821 black; lubricants, Anti-aging agent, colorant, pigment and other powder surfactant, plasticizer, defoamer, light stabilizer, thixotropic agent, ultraviolet absorber, low molecular weight polymer, surface lubricant, leveling agent, antioxidant, Polymerization stopper, heat stabilizer, hydrolysis resistance a stabilizer such as a stabilizer; a metal powder, a granule, a substance, etc. These components may be used singly or in combination of two or more. The thickness of the adhesive layer of the present invention is preferably 2# after drying. m~500 hearts, and 5"m~1〇〇//m is better. If it is thinner, the adhesion to the optical member will be insufficient, and if it exceeds 5〇〇_, the adhesion is saturated and uneconomical. And the adhesion of the adhesive will cause agglutination damage, making the separation difficult.

The adhesive layer of the present invention is formed on the release-treated crepe-removing lining to form the adhesive composition of the present invention. When the adhesive layer is formed, it is described that the solvent is volatilized after the application of the adhesive composition solution, and the adhesive layer obtained by volatilizing the solvent from the adhesive composition is transferred to the release-treated substrate. Or the like, or, by a roll coater such as a reverse cloth machine or a gravure coater, a curtain coater, a lip coater (Up one), a die coater, a roll brush, or the like The adhesive composition is applied by an air knife coating method or the like to form an adhesive layer m to be cooked to adjust the movement of the adhesive layer component after coating or to adjust the crosslinking reaction. X. When the adhesive composition is applied to the oxime release liner, a solvent other than the one or more polymerization solvents may be further added to the composition in order to uniformly coat the release-treated substrate. The release liner which has been subjected to the release treatment may, for example, be an anthrone release liner which is subjected to a bismuth release treatment on a PET film. 1375821 The adhesive sheet of the present invention is formed on a single side or both sides of various support bodies formed of a plastic film such as a polyester film or a porous material such as paper or non-woven fabric, and usually has a thickness of 2 for the adhesive layer. 〜5〇〇^m, preferably 5~100" m or so, and the form is sheet or tape. The support for the adhesive sheet is preferably a resin film having heat sealability, solvent resistance and flexibility. If the support has flexibility, it can be applied by roll coating, curtain coating, lip coating, die coating, 35 brushing, spray coating, air knife coating, etc. by reverse phase coating or gravure coating. The method of applying the adhesive composition can be wound into a roll shape. It is not limited to a tree which is formed as a support and has a sheet shape or a film shape as long as it can form a sheet or a film, and can be, for example, agglomerated. Ethylene, polypropylene, poly-1 - butyl, poly- 4-methyl ketone, 咕 _, T-l-pentene, ethylene propylene copolymer, ethylene 1-butadiene copolymer, It has been said that there are 7 kinds of polyolefin films such as ethylene vinyl acetate copolymer, ethylene·ethyl acrylate copolymer, ethylene·ethylene 醆^ G lung private copolymer; poly-p-ethylene glycol vinegar, poly 26-cage-field 5 6 polyester phthalate, polybutylene terephthalate and other polyester 脬. The lack of this μ axis film, polyacrylate 臈, polystyrene film, nylon 6, nylon 6, 6, some aromatic polyamines and other polyamine membranes; polyethylene film, polyethylene film, polycarbonate film; poly-ethylene resin and other gas-containing resin, polyimine, nylon, cellulose Wait. Further, in order to improve the adhesion between the adhesive layer and the support film, corona treatment can be performed on the surface of the support film. The thickness of the film is also 5 5 如 为 5 5 5 5 5 5 ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ 通常 ^ ^ 通常 ^ ^ ^ 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述20 1375821 The adhesive composition is applied to a release-treated crepe release liner, and after drying, the peroxide is subjected to a heat decomposition treatment process. The above is the optical member of the present invention. For the optical member such as a polarizing plate, the surface of the optical member such as a polarizing plate is formed by the above-mentioned method; ^ &>&& + κ for the adhesive layer, ί = = (four) agent layer. If the surface is exposed, etc. In general, the sheet optical member to be subjected to the separation treatment can be used as a user who forms an image display device such as a liquid crystal display device, and the type of the optical member is not particularly limited. The optical member is, for example, a polarizing plate or the like, and is used for a polarizing element single. The polarizing element having a transparent protective film on the surface or both sides is not particularly limited, and various types can be used. The polarizing element has a 'polyethylene glycol film, a part of a brewed polyethylene medium', and a polyethylene copolymer. Hydrophilic polymer film such as partial chemical film , Adsorption dish or dichroic stalk 雔Α # /z_ Alcohol α η f for uniaxial stretching, polyethylene film: "7 々 々 or polyvinyl chloride dehydrochlorination treatment, etc. Among the β and β, it is preferably a dichroic-based film and a dichroic material polarizing element such as ruthenium. The thickness of the polarizing elements is not particularly limited, and the general size is 5 to 8 〇々m 〇 = B A polarizing element in which a dilute alcohol film is uniaxially stretched after being dyed by the gorge. A/fine is prepared by immersing the polyethylene glycol in an aqueous solution of moth to be dyed, and then stretching it to a ratio of 5%. It may be immersed in boric acid or may be used as needed. An aqueous solution of zinc sulphate, == Aihua, etc., as needed, before the dyeing, the alcohol film is immersed in water for cleaning. By washing the polyethylene glycol with water, 21 can clean the polyether alcohol amine polyethylene The film is swollen to prevent or stain the dirt 5 or the anti-adhesive agent, and it can also be carried out, and it can also be dyed while the effect of the effect of the product. The stretching can be carried out after the dyeing of the eucalyptus or the moth-removing water. Stretch and then take the dyeing. r Seek in water/stretching liquid or in water bath. Formed before the value of the original value - 70 pieces of soap noodles or double The transparent protective film material 枓 preferably has transparency, mechanical orientation, good strength, thermal stability, moisture barrier property, etc., for example, poly-p-phenylene glycol vinegar or poly 2,6 First-class S-series polymer, cellulose-based polymer such as diethyl cellulose or broth cellulose, acrylic polymer such as methyl acetonate, polystyrene or acrylonitrile - a styrene copolymer such as a styrene copolymer 树脂 resin, a polycarbonate-based polymer, etc. Further, a polymer of the transparent protective film is exemplified by a polyethylene, a polypropylene, a ring system or a norbornene thin structure. Polyesters such as polystyrene's ethylene-acrylic copolymer, polyfluorene-based polyvinyl chloride-based poly-δ, polyamide or aromatic polyamine, amide-based polymers, brewed imine polymers, milled polymers, Jujunfeng polymer, polyetheretherketone polymer, polyphenylene sulfide polymer, vinyl alcohol polymer, ethylene gas polymer, ethylene butyral polymer, aryl ester polymer, poly A formaldehyde-based polymer, an epoxy-based polymer, or a blend of the foregoing polymers. The transparent protective film may be a thermosetting type or an ultraviolet curing type resin cured layer such as an acrylic 'amino phthalate type, an acryl amide type, an epoxy type or an enamel type. Further, the polymer film described in JP-A-2001-343529 (W001/37007) is, for example, a thermoplastic having a (Α) side chain having a substituted and/or unsubstituted quinone imine group. Resin and (Β) side chain 22 8 1375821 Resin composition of substituted and/or unsubstituted phenyl and nitrile-based thermoplastic resins. Specific examples include a film comprising a resin composition of an alternating copolymer of isobutylene and N-methylmaleimide and a copolymer of propionitrile and stupid ethylene. A film composed of a mixed extrusion of a resin composition can be used. The thickness of the protective film can be appropriately determined, and is generally about 1 to 500 " m based on strength, workability, and thin layer. Especially think that .. better, better than 5~200 y m.

It is preferable that the protective film is not colored as much as possible. Therefore, a preferred protective film is Rth-[(nx+ny)/2-nz] ·(wherein, 叮 is the principal refractive index of the film plane, nz is the refractive index in the film thickness direction, and the d4 film thickness is) The phase difference value in the film thickness direction is set to be 9 〇ηΠ1 to +7511〇1. By using a protective film having a thickness direction retardation value (Rth) of from ?9 nm to +75 nm, the polarizing plate coloring (optical coloring) due to the protective film can be roughly removed. The thickness direction retardation value (8) is more preferably -80 nm to +60 nm, and more preferably 7 〇ηηι to +45ηιη. The protective film is preferably a cellulose-based polymer such as triethylsulfonyl cellulose from the viewpoints of polarizing properties, durability, and the like. In particular, it is better to use a diethyl hydrazine-based cellulose film. Further, when a protective film is provided on both sides of the polarizing element, a protective film formed of the same polymer material may be used on the front and back sides, or a protective film composed of a different polymer material may be used. The polarizing element and the protective film are usually adhered to each other through a water-angle adhesive. The water-based adhesive agent may, for example, beocyanate-based adhesive: polyethylene (iv) adhesive, bright (iv) adhesive, ethylene-based latex, polyurethane, water-based polyester, and the like. The surface of the light element can be prevented or spread or anti-glare treatment depending on the purpose. The transparent protective film is not subjected to a hard coat layer or a reflection preventing treatment or adhesion. 23 1375821 Hard: Layer: To prevent the surface of the polarizing plate from being damaged, for example, it may be cured or smoothed by a suitable ultraviolet curing resin such as acryl (four). The hardened film is attached to the surface of the transparent protective film. Anti-reflection treatment The external light is reflected on the surface of the polarizing plate for the purpose of implementation. The method of forming an anti-reflection film or the like to achieve the H-attachment prevention treatment is performed for the purpose of preventing adhesion to an adjacent layer. 2, in order to prevent external light from being reflected on the surface of the polarizing plate and obstructing the polarizing plate, firstly for the purpose of visual observation, etc. (4), for example, a sand method or a "roughening method such as a processing method or a method of blending transparent particles" In the field method, a fine concavo-convex structure is formed on the surface of the transparent protective film. As the fine particles for forming the fine concavo-convex structure, it is possible to control, for example, the average particle diameter of the ruthenium oxide, the oxidation, the oxidation, the oxidation, and the oxidation. Tin, indium oxide, and oxidized m materials are transparent particles such as organic fine particles composed of fine particles, parent or uncrosslinked polymers. The amount of fine particles used to form the surface fine concavo-convex structure is usually used to form a surface. The transparency of the fine concavo-convex structure is preferably 100 parts by weight, preferably 2 to 5 parts by weight, and is preferably 5 to 25 parts by weight. The anti-glare layer may also function to diffuse polarized light and transmit light to increase the diffusion of the viewing angle. Layer (viewing angle expansion function). The anti-reflection layer, adhesion prevention layer, diffusion layer or anti-glare layer may be used as other optical layers in addition to the transparent protective layer. It is provided separately from the transparent protective layer. The optical member of the present invention is, for example, a reflective plate or a semi-transmissive plate, a phase difference plate (including a 1/2 or 1/4 wavelength plate), a viewing angle compensation film, a brightness enhancement film, or the like. The display device is used to form an optical layer to be used. These may be used alone as the optical member of the present invention, or may be laminated on the polarizing plate in actual use. In particular, 'better in the polarized light a reflective polarizing plate or a semi-transmissive polarizing plate formed by further laminating a reflecting plate or a semi-transmissive reflecting plate, an elliptically polarizing plate or a circular polarizing plate formed by further laminating a phase difference plate on the polarizing plate, and a polarizing plate a polarizing plate having a wide viewing angle compensation film for further accumulating the viewing angle compensation film or a polarizing plate further laminated on the polarizing plate. The reflective polarizing plate is provided with a reflective layer on the polarizing plate, and is formed to be from the visual side (display) The liquid crystal display device of the display type is reflected by the incident light of the side, and the light source such as the built-in backlight can be omitted, and the liquid crystal display device can be easily made thinner. The formation of the light plate may be performed by a suitable method such as a transparent protective layer or the like, and a reflective layer made of a metal or the like may be provided on one surface of the polarizing plate, etc. Specific examples of the reflective polarizing plate include a transparent protective film (for example). Depending on the surface, a reflective metal or a vapor-deposited film such as aluminum may be provided on one surface to form a reflective layer, etc. Further, the transparent protective layer may be made to contain fine particles. The surface has a fine concavo-convex structure, and a reflective layer having a fine concavo-convex structure is provided thereon. The reflective layer of the fine concavo-convex structure can prevent directionality and flickering from being caused by irregular reflection and diffusion of human light. The case of light and dark markings is its advantage. It also contains the 'particles of the 5th layer of the moon, which can be diffused when the incident light and its reflected light penetrate.' It can further suppress the shading of light and dark, which is also its advantage. The formation of the reflective layer of the fine concavo-convex structure reflecting the fine concavo-convex structure of the transparent protective layer can be performed by, for example, vacuum steaming, ion implantation, 8 25 1375821 sputtering An appropriate method such as a vapor deposition method or a plating method, such as a method, is carried out by directly attaching a metal to the surface of the transparent layer. In addition to being directly attached to the transparent protective layer of the polarizing plate, a reflecting plate formed by providing a reflecting layer on a suitable film having the transparent film as a structure may be used. Further, since the reflective layer is usually made of a metal, the reflective surface is covered with a transparent protective layer or a polarizing plate, and the like; the soil; the reflectance due to vaporization is prevented from being lowered, and the initial reflectance is long. It is better to continue the point of view, or to avoid the need to set a separate protective layer. Further, the semi-transmissive polarizing plate can be obtained by providing a semi-transmissive reflective layer such as a semi-lens or the like which reflects the light and penetrates the light through the reflective layer. It is provided inside the liquid crystal element, and can be used to form a liquid crystal display device of the type that reflects the incident light from the visual side (display side) and displays the image when the liquid crystal display device or the like is used in a relatively bright environment. In a relatively dark environment, the image is displayed using a built-in light source such as a backlight embedded inside the semi-transmissive polarizing plate. That is, the semi-transmissive polarizing plate can be used to reduce the energy used by the moonlight-specific light source in a bright environment, and a liquid crystal display device of a type having a built-in light source can be used in a relatively dark environment. Next, an elliptical polarizing plate or a circular polarizing plate formed by further laminating a phase difference plate on a polarizing plate will be described. In the case where the linearly polarized light is converted into elliptically polarized or circularly polarized light, or the elliptically polarized or circularly polarized light is converted into linearly polarized light, or the linearly polarized light direction is changed, a phase difference plate or the like is required, in particular, as a linear polarized light is converted into a circle. A polarizing plate or a phase difference plate that converts circularly polarized light into linearly polarized light 26 8 1375821 can be a so-called quarter-wave plate (also referred to as a λ/4 plate). The ι/2 wavelength plate (also known as the "2 plate) is usually used to change the direction of polarization of linearly polarized light. The elliptically polarizing plate can compensate (prevent) the color (blue or yellow) generated by the birefringence of the liquid crystal layer of the super twisted nematic (STN) type liquid crystal display device, and can be effectively used for black and white display without coloring. Occasionally. Further, it is preferable to control the three-dimensional refractive index to compensate (prevent) the coloring which occurs when the screen of the liquid crystal display device is viewed from the oblique direction. The circularly polarizing plate' can be effectively used, for example, in the case of image hue adjustment of a reflective liquid crystal display device in which the image is a color display, and also has a function of preventing reflection. The retardation plate ′ is, for example, a birefringent film obtained by uniaxially or biaxially stretching a polymer material, an alignment film of a liquid crystal polymer, and an alignment layer supporting a liquid crystal polymer. The thickness of the phase difference plate is not particularly limited 'generally about 20 to 150 private m.

, South molecular materials, for example: polyethylene glycol, polyethylene condensed chain, polymethyl vinyl ether, polyhydroxyethyl acrylate, hydroxyethyl cellulose, propyl travidine f-based cellulose , polycarbonate, polypropyl vinegar, poly maple, poly pair: diacid glycol vinegar 'poly 2,6-diformate glycol vinegar 'poly _, ..., polybenzophenone, poly propyl hydrazine 1 ethyl alcohol, polyamine, polyimine, polysulfide, polygas B, cellulose polymer, or the like, various copolymers, graft copolymers, blends Things and so on. These polymer materials are oriented to form an oriented material (stretched film) by stretching. The liquid crystal polymer may, for example, be a polymer in which a total of 27 JOZ linear linear radicals (liquid crystal cells) imparting liquid crystal alignment properties are introduced to a main chain or a side chain of a polymer. Wait. The ruthenium/column of the main chain type liquid crystal polymer is, for example, a nematic alignment liquid crystal polymer, a disk type polymer, and a cholesterol type in which a liquid crystal group is bonded to a spacer which imparts buckling property. Gathering people. Specific examples of the side chain type liquid crystal polymer include: polymethylene oxide, polyacrylic acid, and methyl methacrylate The liquid crystal base composed of the α" unit of the "substituent substitution" which is replaced by the alignment of the nematic alignment imparted by the spacer of the atomic weight of the bond. These liquid crystal polymers are formed, for example, by The surface of the film of polyacrylonitrile or polyvinyl alcohol on the glass is subjected to a heat treatment by a rubbing treatment agent or an oxygen-cut oblique steaming bond, and the solution of the liquid crystal polymer is expanded to perform heat treatment. 0' phase difference plate may be used for compensating for coloring or viewing angles due to, for example, various wavelength plates or liquid crystal layers, and may have an appropriate phase difference depending on the intended use. At least two kinds of phase difference plates are laminated to control optical characteristics such as phase difference, etc. Further, the elliptical gj polarizing plate and the reflective elliptically polarizing plate are polarized plates, reflective polarizing plates, and phase difference plates. Combination of layers The elliptically polarizing plate or the like can be formed by sequentially inserting a (reflective) polarizing plate and a phase difference plate in order to advance the entangled layer in the manufacturing process of the liquid crystal display device, but as described above. In general, it is an optical film such as a circular polarizing plate, and it is excellent in quality stability and laminating workability, and thus it is possible to improve the manufacturing efficiency of a liquid crystal display device, etc. 〃 1375821

The viewing angle compensation is used to make the screen of the liquid crystal display device relatively clear when viewed from the direction of the vertical direction: the film for the purpose of expanding the viewing angle. As such a viewing angle compensation, the difference plate is composed of, for example, a retardation film, an alignment film such as a liquid crystal polymer, or an alignment layer which supports a liquid crystal polymer or the like on a transparent substrate. A general phase difference plate is a polymer film which is uniaxially stretched and refracted in the direction of the surface thereof, and is used as a phase plate as a viewing angle compensation film for biaxial stretching in the plane direction. a polymer film having birefringence, or a polymer film having a refractive index in a thickness direction and a birefringent polymer film or a tilt alignment film, which is subjected to uniaxial stretching in the plane direction and also in the thickness direction. Stretching the film in two directions. As the oblique alignment film, for example, a heat shrinkable film is applied to the polymer film, and the polymer is subjected to a stretching treatment and/or shrinkage treatment under the action of heating to generate a shrinking force, or the liquid crystal is compounded. To the aligners and so on. The raw material polymer of the phase difference plate may be the same as the polymer described in the phase difference plate of the other surface, and may be colored, etc., which are suitable for preventing changes in the viewing angle based on the phase difference caused by the liquid aa element, or Expand the purpose of visually good perspectives, etc. Moreover, in order to achieve a wide range of good visual field of view considerations, it is preferred to support the optically anisotropic layer with triethylenesulfonyl cellulose (the tilt of the alignment layer of the liquid crystal polymer, especially the liquid crystal polymer) An optically compensated phase difference plate formed by the alignment layer. A polarizing plate which is formed by a polarizing plate and a brightness enhancement film is usually used inside the liquid crystal element. The brightness enhancement film exhibits the following characteristics: When the natural light is incident on the backlight of the liquid crystal display device or the reflection from (4), the linear polarization of the predetermined polarization axis or the circular polarization of the predetermined direction can be reflected to make the other Therefore, the polarizing plate laminated with the brightness enhancement film and the polarizing plate can cause light from a light source such as a backlight to be incident to obtain a penetrating light of a predetermined polarization state, and prevent light penetration other than the predetermined polarization state. It is reflected that the light reflected by the brightness enhancement film surface is reversely incident on the brightness enhancement film through a reflection layer or the like provided on the rear side thereof, so that part or all of the light is in a predetermined polarization state. In order to increase the amount of light transmitted through the brightness enhancement film and to supply the polarized light that is hard to be absorbed by the polarizing film, the amount of light that can be used for liquid crystal image display or the like is increased to increase the brightness. In other words, when the brightness enhancement film is not used and light is incident through the polarizing film inside the liquid crystal element such as a backlight, most of the light whose polarization direction does not coincide with the polarization axis of the polarizing film is absorbed by the polarizing film. Will pass through the polarizing film. That is, although the characteristics of the polarizing film to be used differ depending on the characteristics of the polarizing film to be used, substantially 50% of the light is absorbed by the polarizing film, and this portion causes the amount of light available to the liquid crystal display device to be reduced, resulting in darkening of the image. The brightness enhancement film prevents the light in the polarization direction absorbed by the polarizing film from being incident on the polarizing film, and is reflected by the lifting film, and is then folded back through the reflective layer provided on the rear side thereof and then incident on the brightness increasing film, thus repeating In the case where the light that is reflected and folded back between the two is supplied to the polarizing film by the polarized light that can pass through the polarizing direction of the polarizing plate, the display of the image of the liquid crystal display device can be effectively used. Make the image brighter. A diffusion plate may be provided between the brightness enhancement film and the reflective layer or the like. The diffusing plate provided by the light-receiving state reflected by the lift-free film toward the reflective layer or the like diffuses the passing light uniformly and eliminates the polarized light. The state of 13 1375821 becomes a non-polarized state. That is, return to the original natural light bear. The light in the non-polarized state (that is, the natural light state) travels toward the reflective layer or the like, is reflected by the reflective layer, and is incident on the brightness enhancement film through the diffusion plate, and is thus repeated. By providing a diffusing plate for returning to the original natural light state, the brightness of the display screen can be maintained, and the unevenness of the display screen can be reduced, and a uniform bright face can be provided. It is generally believed that by providing a diffusing plate for returning to the original natural light state, the initial incident light can provide a uniform bright display screen with the repetition of the appropriate reflection and the function of the diffusing plate. . As the brightness enhancement film, for example, a multilayer film of a dielectric or a multilayer laminate of a film having a different refractive index anisotropy can be suitably used, and other light can be reflected by linear polarization of a predetermined polarization axis. The characteristic is that if the alignment film supporting the cholesteric liquid crystal polymer or the alignment liquid crystal layer is supported on the film substrate, it is shown that either the left-handed or the right-handed circle can be polarized and reflected, and other light can be transmitted. Characteristics, etc. • Therefore, the above-described brightness enhancement film of a type that allows a linear polarization of a predetermined polarization axis to penetrate, by causing the transmitted light to be aligned with the polarization axis and incident on the polarizing plate, can suppress the loss of absorption by the polarizing plate, and can be efficiently worn. through. On the other hand, a brightness enhancement film of a type that allows a circularly polarized light to penetrate like a cholesteric liquid crystal layer can also cause light to be incident on the polarizing film locally, but suppresses the absorption loss. It is preferable that the phase difference plate is linearly polarized and then incident on the polarizing plate. Further, by using a quarter-wave plate, circularly polarized light can be converted into linearly polarized light. The 31 1375821 phase difference plate ' having a quarter-wave plate function in a wide wavelength range such as the visible light region can be formed by, for example, a phase difference layer that functions as a 1/4 wavelength plate for monochromatic light having a wavelength of 550 nm, and displays other A phase difference layer of a phase difference characteristic (for example, a phase difference layer functioning as a 1/2 wavelength plate) is superposed. Therefore, the retardation plate disposed between the polarizing plate and the brightness enhancement film may be composed of one or at least two or more retardation layers. Further, the cholesteric liquid crystal layer can be obtained by reflecting a circularly polarized light in a wide wavelength range such as a visible light region by combining the reflection wavelengths and the overlapping structure of two or at least three layers. The wide wavelength range of Lu penetrates the circular polarization. Further, the polarizing plate may be formed by laminating a polarizing plate and two or more optical layers as in the above-described polarizing-separating polarizing plate. Therefore, a reflective elliptically polarizing plate or a semi-transmissive elliptically polarizing plate formed by combining the above-described reflective polarizing plate or semi-transmissive polarizing plate and retardation plate may be used. The optical member formed by laminating the optical layer on the polarizing plate can be formed by laminating one by one in the manufacturing process of a liquid crystal display device or the like, and the optical member can be laminated in advance to achieve quality stability and assembly workability. The aspect is superior, so that the process of the liquid crystal display device and the like can be improved, which is an advantage. For the implementation of the laminate, an appropriate bonding means such as an adhesive layer can be used. When the polarizing plate is bonded to another optical layer, the optical axis of the polarizing plate can be appropriately arranged at an appropriate angle depending on the phase difference characteristics of the desired object. The respective layers of the adhesive optical member or the adhesive layer of the present invention may be, for example, a salicylate-based compound, a benzophenone-based compound benzotriazole-based compound, a cyanoacrylate-based compound, a nickel-salted salt-based compound, or the like. The ultraviolet absorber is treated to have ultraviolet absorbing ability. ' 5 32 1375821 The adhesive optical member of the present invention can be applied to the formation of various image display devices such as liquid crystal display devices. The formation of the liquid crystal display device can be carried out by a conventional method. In other words, the liquid crystal display device is generally formed by appropriately assembling a constituent member such as a liquid crystal element, an adhesive optical member, and an optional illumination system, and is added to a driving circuit or the like. The present invention does not require the use of the optical or structural member of the present invention. It is specifically limited, and a conventional constitution can be used. The liquid crystal element C can be used in any form such as a TN type, an STN type, or a π type. A liquid crystal display device in which an adhesive optical member ® is disposed on one side or both sides of a liquid crystal element, or a liquid crystal display device using a backlight or a reflector in an illumination system. In this case, the optical member of the present invention may be provided on one side or both sides of the liquid crystal element. If optical members are provided on both sides, they may be the same optical member or different. When forming a liquid crystal display device, one or two or more appropriate members may be disposed at appropriate positions, for example, a diffusion plate, an anti-glare layer, an anti-reflection film, a protective plate, a prism column, a lens array, a light diffusion plate, and a backlight. Wait. g Next, there is an electroluminescent device (organic EL display device). In general, an organic EL display device sequentially forms a transparent electrode, an organic light-emitting layer, and a metal electrode on a transparent substrate to form an illuminant (organic electroluminescence). Here, the organic light-emitting layer is a laminate of various organic thin films. A laminate comprising a hole-embedded layer made of a triphenylamine derivative or the like and a light-emitting layer composed of a fluorescent organic solid such as ruthenium, a light-emitting layer, and a perylene derivative are known. The laminate of the electron-implanted layer, or the combination of the hole-implanted layer, the layer of the light-emitting layer and the electron-implanted layer, and the like.

33 (D 1375821 organic EL device is usually based on the following principle to emit light. That is, a voltage is applied to the transparent electrode and the gold > 1 electrode to implant the hole in the organic light-emitting layer and the recombination of the electron hole and the electron. The energy excites the fluorescent substance, and the excited fluorescent substance emits light when it returns to the ground state. This mechanism is combined with the general diode in the middle, and it can be inferred that the current and the luminous intensity are applied. The voltage display is accompanied by the rectification of the strong non-linearity. In the organic EL device, the electrode for deriving the light from the organic light-emitting layer to the side must be a transparent electrode, which is usually transparently conductive by indium tin oxide (ITO) or the like. The transparent electrode formed by the body is used as an anode. On the other hand, in order to make electron implantation easy to improve luminous efficiency, it is important that the cathode uses a substance having a small work function, and generally MgAg, Al-Li, or the like can be used. In the organic EL device having the above configuration, the organic light-emitting layer is usually formed by a film having a thickness as thin as lOnm. Therefore, the organic light-emitting layer and the transparent light are formed. Similarly, the light can be almost completely penetrated. Therefore, the light that is incident on the surface of the transparent substrate from the surface of the transparent substrate and that is reflected by the organic light-emitting layer and is reflected on the metal electrode is emitted to the surface side of the transparent substrate again. When viewed from the outside, the display surface of the organic EL device is mirror-finished. The organic EL emitter (the surface of the organic light-emitting layer that emits light by applying a transparent electrode and the metal electrode on the back side of the organic light-emitting layer) are organic. In the EL display device, for example, on the surface side of the transparent electrode, the J·@俗a JL polarizing plate is provided, and a phase difference plate is disposed between the transparent electrode and the polarizing plate. 0 34 5 1375821 The phase difference plate and the polarizing plate have The externally incident light that is reflected by the metal electrode is polarized. Therefore, the polarizing effect can be used to confirm the mirror surface of the metal electrode from the outside. This is the effect. In particular, it is composed of a quarter-wave plate. By adjusting the angle of the polarizing plate and the polarization direction of the retardation film to π/4, the mirror surface of the metal electrode can be completely covered. 》 • For external light incident on the organic EL display device, only the linearly polarized component of the polarizing plate can penetrate the linearly polarized light by the retardation film—which can be elliptically polarized, but when the retardation film is 1/4 wavelength When the angle between the plate and the polarizing plate and the retardation film is 7 Γ /4, it becomes circularly polarized. This circular polarized light usually penetrates the transparent substrate, the transparent electrode, and the organic film, and is reflected at the metal electrode. The penetrating film of the organic film, the transparent electrode, and the transparent earth plate is again linearly polarized. This linear polarized light cannot penetrate the polarizing plate because it is orthogonal to the polarizing direction of the polarizing plate. Thus, the mirror surface of the metal electrode can be completely completed. [Embodiment] The present invention will be specifically described by way of Examples and the like, but the present invention is not limited thereto. Further, the evaluation items in the examples were measured in the following manner. % of each case is a weight basis. <Measurement of Weight Average Molecular Weight of Acrylic Polymer> The weight average molecular weight of the produced polymer was measured by GPC (gel permeation chromatography).

Knife analysis device: manufactured by Dongsuo Co., Ltd., HLC-8120GPC 1375821 Pipe column: Sample pipe column: manufactured by Dongsuo Co., Ltd., G7000Hxl + GMHxl+GMHxl Flow: 0.8ml/miη Injection volume: ΙΟΟ " 1

Column temperature: 40 ° C . · Eluent: THF . · Injection sample concentration: 0.1% by weight Detector: Differential refractometer • Weight average molecular weight is determined in terms of styrene. <Measurement of peroxide decomposition amount> The amount of peroxide decomposition after thermal decomposition treatment was measured by HPLC (High Speed Liquid Chromatography). Each of the adhesive compositions before and after the decomposition treatment was taken out to about 2 g, soaked in 10 ml of ethyl acetate, and shake-extracted at 25 ° C, 120 rpm for 3 hours, and allowed to stand at room temperature for 3 days. Next, 10 ml of acetonitrile was added, and the mixture was shaken at 120 rpm for 30 minutes at 25 ° C with a shaking machine, and filtered through a filtration membrane (0.45 ® / m), and the obtained extract was injected into the HPLC for analysis. The decrease in the amount of peroxide before and after the decomposition treatment was used as the amount of decomposition of the peroxide. Analytical device: manufactured by Dongsuo Co., Ltd., HPL CCPM/UB8000 Pipe column: Sample column: MACHEREY-NAGEL company, NUCLEOSIL 7 C 1 8 (4.6mm0x25Omm) Flow rate: 1. Oml/min Column pressure: 41 kg/m2 36 1375821 Column temperature: 40 °C Ejection: water / acetonitrile = 30 / 70 Injection volume: 10 y 1 Injecting sample concentration: 〇.〇! Weight 〇 / 〇 detector: UV detector (230nm) < peeling Measurement of Peel Force of Pads> A release-coated photonic member having a width of 50 mm and a length of i〇〇mm was produced, and it was measured to peel off at a peeling speed of 3 minutes (peeling angle 1800) in a universal tensile tester. Peeling force of the release liner. The measurement was carried out under ambient conditions of 23 x 50% RH. If the peeling force is lower than 〇 iN / 5 〇 mm, since the peeling force is too small, problems such as peeling of the release liner are likely to occur in the process such as punching. On the other hand, if the peeling force is more than 〇.4N/5〇mm, since the peeling force is too large, the problem that the release liner is not easily peeled off is likely to occur in actual use. <Evaluation of Durability> The optical member (size 12 Å) produced was attached to an alkali-free glass substrate (manufactured by Corning Co., Ltd., trade name: Corning laci, 737, X350 mm, thickness: mm 7 mm), and a pressure cooker was used for 5 ( The pressure was treated for 30 minutes at TC and 5 MPa, and then stored in an environment of 6 〇C 90 XiRH for 500 hours, and then returned to room temperature to prepare a sample for evaluation. After the treatment, the adhesion state to the glass plate was confirmed, and the following criteria were used. Evaluation: The optical member did not undergo charm or peeling: the optical member was warped or peeled off: 实施 [Example 1] 95 parts by weight of butyl acrylate, 3.0 parts by weight of acrylic acid, and 0.10 parts by weight of 1,375,821 2-hydroxyethyl acrylate And 0.050 parts by weight of 2,2-azobisisobutyronitrile and 200 parts by weight of ethyl acetate were put into a four-necked flask equipped with a nitrogen gas introduction tube and a cooling tube, and were sufficiently substituted with nitrogen, and then stirred at 56° under a nitrogen gas stream. c Polymerization was carried out for 20 hours to obtain a solution of a high molecular weight acrylic acid polymer A having a weight average molecular weight of 1.57 million. The solution (solid content) of the acrylic polymer A was weighted by 1 ,, and one was added. The brewed base peroxide (1 minute half life: 13001) 〇.15

Isocyanate cross-linking composed of 0.080 parts by weight of 3-glycidoxypropyltrimethoxydecane as a decane coupling agent and toluene diisocyanate adduct of trihydroxymercaptopropane as a crosslinking agent The agent (Cornette l, manufactured by Nippon Polyurethane Co., Ltd.) was 0.60 parts by weight, and was sufficiently mixed to prepare an adhesive composition. 'σ The above-mentioned adhesive composition is applied to the separation of Shi Xiu's system. 38... Polyethylene terephthalate granulated film U-Ring Co., Ltd. mrF38 (addition reaction type linoleic acid)), the adhesive layer is dried m, and the thief (4) is used for 2 minutes and the peroxide is transferred to the polarizing plate, and the present invention is prepared. Sticky parts. Further, the adhesive ratio of the adhesive layer was 69% by weight. The decomposition amount of the peroxide of the optical structure of the agent is 丨 ""claw (1). . 'Adhesive Composition [Example 2] In addition to the 0.30 parts by weight of the bismuthyl decyl peroxide in Example 1, -15 parts by weight was modified to make adhesion. Agent optical member. The viscosity is the same as that of the first embodiment, and the peroxide composition of the adhesive composition ig is eight: the gel fraction is 82, and the amount of the solution is U.74/z 38 1375821 mol 〇 [Example 3] The polyethylene terephthalate film of Example 1 (manufactured by Mitsubishi Polyester Co., Ltd., MRF38 (addition reaction type Shishi Brewing)) was changed to poly(p-diethylene glycol) self-tanning film (two An adhesive optical member was produced in the same manner as in Example 1 except that MRN3 8 (condensation reaction type) was used. The gel fraction of the adhesive layer was 70% by weight, and the decomposition amount of the peroxide of the adhesive composition lg was 7.50 μmol. [Example 4] 1 part by weight of isooctyl acrylate, 1 part by weight of 2,2-hydroxyethyl acrylate, and 0.10 part by weight of 2,2-azobisisobutyronitrile were added to 2 5% of ethyl acetate. Into a four-necked flask equipped with a helium gas introduction tube and a cooling tube, after charging with a nitrogen gas, the mixture was stirred under a nitrogen gas stream for 12 hours at wc to obtain a high molecular weight acrylic polymer having a weight average molecular weight of 1.75 million. Solution B. Solution (solid content) of the above-mentioned propionic acid-based polymer B 1 〇〇 weight injury: addition of benzhydryl peroxide (1 minute half-life: 13 〇〇. 〇〇 15 parts by weight, as (4) coupling agent 3. Polyethylene isocyanate-based cross-linking agent composed of 3-methylglycolyl propyl sulfonium diisocyanate adduct as a crosslinking agent 0.10 parts by weight of Coronette l, manufactured by Sakamoto Polyurethane Co., Ltd., and sufficiently mixed to prepare an adhesive composition. The above adhesive composition was applied to the thickness of the ketone ketone peeling treatment. 38em polyethylene terephthalate film (manufactured by Mitsubishi Polyester Co., Ltd., 39 1375821 MRF38 (addition reaction type (4))), the wire coating layer is dried to a thickness of 25# m, and dried at 15G °C for 2 minutes. The adhesive layer was transferred to a polarizing plate to obtain an adhesive optical member of the present invention. The adhesive layer had a gel fraction of 79% by weight and the adhesive composition lg was The decomposition amount of the peroxide was 8.0 vmol. [Example 5] Except that the second of Example 4 An adhesive optical member was prepared in the same manner as in Example 4 except that 15 parts by weight of the methyl ketone peroxide oxime was changed to 0.30 parts by weight of the benzhydryl peroxide. The gel fraction of the adhesive layer was 8 3 . % by weight, the decomposition amount of the peroxide of the adhesive composition lg is 12 〇 " mol 〇 [Example 6] 70 parts by weight of 2-ethylhexyl acrylate, 29 parts by weight of butyl acrylate, and 1.0 part by weight of acrylic acid And 2,2_azobisisobutyronitrile 〇〇5 parts by weight and 200 parts by weight of ethyl acetate, put into a four-necked flask equipped with a nitrogen gas introduction tube and a cooling tube, and sufficiently substituted with nitrogen, and then under a nitrogen gas stream The mixture was polymerized at 56 C for 20 hours with stirring to obtain a solution of a high molecular weight acrylic polymer C having a weight average molecular weight of J 4.6 million. A solution (solid content) of the above acrylic polymer C was added in an amount of 1 part by weight of 'diphenyl hydrazine. Mercapto peroxide (丨 minute half-life: 13 〇〇 <>c) 〇 15 parts by weight, as a decane coupling agent, 0.10 parts by weight of 3-glycidoxypropyltrimethoxy decane, as cross-linking The trimethylolpropane of the agent is stupid a polyisocyanate crosslinking agent (Cornet L, 聚本聚 amino phthalate company) composed of a cyanate ester adduct, 〇. 6 〇 by weight, and uniformly mixed,

40 !375821 Make an adhesive composition. The above-mentioned adhesive composition is applied to a polyethylene terephthalate film (manufactured by Mitsubishi Polyacetate Co., Ltd., Coffee 38 (addition reaction type (4))), which is peeled off by Shi Xixi, to adhere After the agent layer is dried, the thickness is... ^1 thief (four) 2 points into the money oxide read processing, the adhesive layer is transferred to the polarizing plate, and the plastic medium is too M to make the adhesive optical member of the invention. The gel fraction of the adhesive layer was 6] % of the rest of the hand 61, and the decomposition amount of the peroxide of the adhesive composition lg was 9.0 # mol. [Example 7] Except that the benzophenone in Example 6 was prepared, the ruthenium compound was changed to 0. 15 parts by weight to be benzoyl peroxide 〇 · 3 〇 An adhesive optical member was produced in the same manner as in Example 1 except for the wound. The gel fraction of the adhesive layer was 74% by weight. The decomposition amount of the peroxide of the adhesive composition lg was η. " mol 〇 [Example 8] 2-ethylhexyl acrylate 7 〇 旦 重 、, 29 parts by weight of butyl acrylate, L0 parts by weight of acrylic acid, and 3 · propylene In an amount of 2.070 parts by weight of a reactive emulsifier, Akua 帛hs (manufactured by Daiichi Kogyo Co., Ltd.), 25 parts by weight of Knife Octop, and emulsified by a homogenizer to obtain an emulsified product. Next, in the four-necked flask with the gas introduction tube and the cooling tube, the gas is introduced into the four-necked flask of the gas introduction tube and the cooling tube, and then 30 parts by weight of water is added, and the initiator VA-057 (and The pure drug was introduced into a 0.10 part by weight, and the reaction system was maintained at 59 ° C. The above emulsion was added dropwise at 4 Torr, and the polymerization was carried out for 4.5 hours. After the completion of the reaction, ammonia was added to adjust the pH to 8 to obtain a solution of the emulsified acrylic acid 41 1375821-based polymer D. To the solution (solid content) of the acrylic polymer D, 1 part by weight, diphenylguanidino peroxide (1 minute half-life: 13 〇〇) 〇 15 parts by weight, as a decane coupling agent 3- Glycidoxypropyltrimethoxy decane 〇 丨〇 by weight, and thoroughly mixed uniformly to prepare an adhesive composition. The above-mentioned adhesive composition is applied to a polyethylene terephthalate film (MRF38 (addition reaction type fluorenone) manufactured by Mitsubishi Polyester Co., Ltd.) having a thickness of 38 by the ketone ketone peeling treatment. The adhesive layer was dried to a thickness of 25 Å at 15 (TC was dried for 2 minutes and subjected to peroxide decomposition treatment, and the adhesive layer was transferred to a polarizing plate to obtain an adhesive optical member of the present invention. The gel fraction of the adhesive layer was 72% by weight, and the decomposition amount of the peroxide of the adhesive composition ig was 12.4 # mol. [Example 9] A solution (solid content) of the above acrylic polymer A was 1 〇. 〇 by weight, adding bis(4-tert-butylcyclohexyl)peroxydicarbonate (1 minute half-life: 92.rC) 0.15 parts by weight, as a money coupling agent, 3 • glycidoxypropyltrimethoxy Based on the weight of the 〇 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The composition of the composition is coated on the polyethylene terephthalate having a thickness of 38 m by the ketone ketone stripping treatment. Ester film (MRF38 (addition reaction type (4)) made by Mitsubishi Polyester Co., Ltd.), the thickness of the adhesive layer was dried and dried at 15 G °C for 2 minutes and subjected to peroxide decomposition treatment to bond 42 1375821 * » The agent layer is transferred to the polarizing plate' to obtain the adhesive optical member of the present invention. The adhesive layer has a gel fraction of 81% by weight, and the adhesive composition ig has a decomposition amount of 8.0. μ mol. [Example 10] A solution of the above acrylic polymer A (solid content) 1 〇〇 weight injury 'addition of 1,1-one (second butylhexylperoxy) cyclohexane (1 minute and a half) Decay: period: 149.2°c) 0.30 parts by weight, 0.075 parts by weight of 3·glycidoxypropyltrimethoxydecane as a decane coupling agent, and triphenylmethyl propane as a crosslinking agent A polyisocyanate-based crosslinking agent (Cornet L, manufactured by Sakamoto Polyurethane Co., Ltd.) made of an isocyanate adduct is used in an amount of 6 parts by weight, and is sufficiently uniformly mixed to prepare an adhesive composition. The composition of the composition is coated on a poly(p-benzene) having a yield of 38/m by the decyl ketone stripping treatment. Ethylene glycol citrate film (MRF38 (addition reaction type fluorenone) manufactured by Mitsubishi Polyester Co., Ltd.), the adhesive layer was dried to a thickness of 25, dried at 150 ° C for 2 minutes and subjected to peroxide decomposition. The adhesive layer is transferred to a polarizing plate to obtain an optical component for an adhesive of the present invention. The gel fraction of the adhesive layer is 72% by volume, and the decomposition of the peroxide composed of the adhesive The amount was 5.0/zm〇i. [Comparative Example 1] An adhesive optical member was produced in the same manner as in Example 1 except that the addition of the benzoyl fluorenyl peroxide in Example 1 was changed to no addition. The gel fraction of the adhesive layer was 62%. [Comparative Example 2] Except that the benzophenone-based peroxide 〇1.1) in Example 1 was changed to 43 1375821, the dibenzoyl peroxide-based method was used to prepare an adhesive light-winding structure: 'The cohesive fraction of the core layer of the same agent as in Example 1 was m〇I. The amount of decomposition of the emulsion was 22.2 " [Comparative Example 3] In addition to the peroxygen addition of the dibenzoyl group in Example 3, the faint disc was carefully placed, and the heart was added? In the same manner as in Example 3, the gel fraction of the adhesive layer was 59%. Photonic member [Comparative Example 4] Except that the addition of L-methyl thiol peroxide in Example 4 was changed to not added, and the addition of the adhesive to Example 3 was carried out. The eight t 1 method is used to fabricate an adhesive optical member. The gel fraction of the beta layer was 75 〇/. . [Comparative Example 5] Except that in Example 4, -^田μ*, a methyl carbazyl peroxide 〇.15 diphenyl hydrazino peroxide 〇6 〇舌县八, 篁 篁 changed to a sample μ μ The adhesive optical member was prepared in the same manner as in Example 4 except that .6 parts by weight. The amount of decomposition of the peroxide of the gel component of the adhesive layer 1 § is 2 ·, [Comparative Example 6] Mm〇i. Adhesive optical member adhesion was carried out in the same manner as in Example 5 except that the addition of the second stupid styrene in the fifth embodiment was changed to the addition of ruthenium-based peroxide in Example 5. The gel fraction of the agent layer was 6%. . [Comparative Example 7] Except for the second embodiment of the present invention, the second embodiment of the present invention is as follows: The adhesive member 78% 'adhesive composition 1 [Comparative Example 8] optical member was prepared in the same manner as 1375811. The gel fraction of the adhesive layer is the decomposition amount of peroxide of I 21 m〇i. The gel fraction of the adhesive layer was 63%. [Comparative Example 9] The addition of a non-T酝丞 虱 虱 改为 改为 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' Condensation fraction of the adhesive layer of the adhesive optical member ju〇/_ „ Except that 15 parts by weight of the dibenzoyl peroxide peroxide in Example 8 was changed to 0.60 parts by weight of the benzoyl peroxide. The adhesive optical member was produced in the same manner as in Example 8. The gel fraction of the adhesive layer was that the decomposition amount of the peroxide of the adhesive composition 1 was 23 to _. [Comparative Example 10] An adhesive optical member was prepared in the same manner as in Example 2 except that the addition of the benzoyl fluorenyl peroxide in Example 2 was changed, and the adhesive layer t gel fraction A 82 %, the decomposition amount of the peroxide of the composition 16ig was 23.1 μmol. [Comparative Example 11] The same procedure as in Example 8 was carried out except that the addition of the decane coupling agent in Example 8 was changed to not added. Adhesive optical member. The gel fraction of the adhesive layer is 78%, and the decomposition amount of the peroxide of the adhesive composition lg 12.4 /Z mol. [Comparative Example 12] In addition to the use of 2,2,-azobisisobutyronitrile (1,2,-azobisisobutyronitrile) in the 015 parts by weight of the benzhydryl peroxide in Example 1, An adhesive optical member was prepared in the same manner as in Example 2 except that the starting amount was 1,375,821, 0.30 parts by weight. The adhesive layer had a gel fraction of 72%. According to the above method, the adhesive was prepared. The optical member was subjected to the above evaluation. The results obtained are shown in Table 1. 1 [Table 1]

Acrylic polymer type ketone release treatment type peroxide (except S) release liner peeling force [n/50mm] decane coupling agent durability compound type compound compounding amount [% by weight] peroxide decomposition amount [/ Zmol/g] Example 1 A Addition P 0.15 7.6 0.25 Organic Example 2 A Addition P 0.30 11.7 0.32 Organic Example 3 A Condensation P 0.15 7.5 0.21 Organic Example 4 B Addition P 0.15 8.0 0.18 Example 5 B addition molding P 0.30 12.0 0.34 〇 Example 6 C addition molding P 0.15 9.0 0.18 〇 Example 7 C addition molding P 0.30 13.0 0.28 〇 Example 8 D addition molding P 0.15 12.4 0.18 〇 Example 9 A addition molding Q 0.15 8.0 0.19 〇 Example 10 A addition molding R 0.30 5.0 0.15 〇Comparative example 1 A addition molding - - - 0.05 〇Comparative example 2 A addition molding P 0.60 22.2 0.66 〇Comparative example 3 A condensed type - - - 0.05 〇 Comparative Example 4 B Addition - - - 0.06 〇Comparative Example 5 B Addition P 0.60 24.0 0.66 〇Comparative Example 6 C Addition - - - 0.07 〇Comparative Example 7 C plus Molding P 0.60 21.0 0.61 〇Comparative Example 8 D Addition - - - 0.06 〇Comparative Example 9 D Addition molding P 0.60 23.1 0.63 〇Comparative Example 10 A Addition molding P 0.30 11.7 0.32 - X Comparative Example 11 D Addition molding P 0.30 12.4 0.18 - X Comparative Example 12 A Addition molding S (azo system) 0.30 0 0.05 The compound type (peroxide and azo compound) in Table 1 is as follows.

a) peroxide P 8 1375821

b) peroxide Q bis(4-tert-butylcyclohexyl)peroxydicarboxylate

c) peroxide R

1,1-di(Third-hexyl peroxy)cyclohexane • Sentence azo compound S lr / 2,2'·Azobisisobutyronitrile As shown in the results of Table 1 above, according to the production method of the present invention, In the process of forming an adhesive layer on the fluorenone® release liner, which is included in the process of decomposing peroxide on the release liner (Example iMO), in all the examples, durability can be obtained and can be obtained. The adhesive layer for an optical member which easily adjusts the peeling force of the fluorenone release liner, and the optical member for attaching the adhesive (refer to FIG. 1). On the other hand, in the process of decomposing the peroxide on the release liner (Comparative Examples 1, 3 to 4, 6, 8, 12), although the durability is good, the release liner of either of the release liners The force is relatively small. 1N/5〇mm is small, and then the force is not sufficient. On the other hand, in the case where the peroxide decomposition amount is higher than 20/zm 〇 1 (Comparative Examples 2, 5, 7, and 9), although the durability is excellent, the peeling force of any of the peeling profiles is 0.4 N/50 mm. It is too large to make the peeling force too large. On the other hand, in the case where the Shishiyuan coupling agent was not contained (Comparative Example 1~u), although it had an appropriate peeling force, the durability was not good. Therefore, it has been confirmed that the pressure-sensitive adhesive layer of the present invention can produce an adhesive layer for an optical member which is excellent in durability and has an appropriate peeling force, and an optical member for attaching the adhesive.

47 1375821 [Simple description of the drawing] Fig. 1, the relationship between the amount of decomposition of peroxide and the peeling force in the examples and the like * [Description of main component symbols] im- * None 48

Claims (1)

1375821 X. Patent application scope: 1. The method for adjusting the peeling force of the ketone ketone release liner, comprising: δ on the release treatment surface of the fluorenone release liner, and the (meth)acrylic acid as the basic poly 5 The first process of the viscous (iv) composition layer of the polymer SA oxide and the thermal decomposition after the first process are performed to adjust the lithography. Part of or some of the 5 halo peroxides 2. If the mj range 帛i item ♦ _ peeling the lining peeling force adjustment method', wherein the adhesive group lg is heated to decompose the peroxide by 1 to 20 /z mo 1 . 3. A method for producing an adhesive layer for a lining ketone release liner comprising a (meth) propylene (tetra) polymer as a base polymer disposed on a release treatment surface of a lintelone release liner The first process of the oxide composition layer of the oxide includes a second process of thermally or decomposing one or all of the peroxide after the first process to adjust the peeling force of the anthrone release liner. 4. The method for producing an adhesive layer of an ketone release liner according to item 3 of the patent application, wherein the base polymer of the adhesive composition contains (fluorenyl) in 100 parts by weight of the monomer component. The alkyl acrylate is 8 parts by weight or more of the (meth)acrylic polymer. 5. The method for producing an adhesive layer of an ketone release liner according to Items 3 and 4 of the patent application, wherein the adhesive composition is 1 part by weight, 49 1375821, 101, i. Contains 0.01 to 1 part by weight of the dreaming coupling agent. ---- 6. - A method for manufacturing a viscous enamel core sheet with an ketone ketone release liner, which comprises a detachment treatment surface of an oxime ketone release liner, which is provided as a base polymer. a first process of forming a layer of (meth)acrylic acid-based t-compound and a peroxide, and the peroxide is carried out after the first process The second process of partially or completely decomposing heat is to adjust the peeling force of the peeling lining to a range of 0.1 to 0.4 N/50 mm. 7. The optical adhesive layer of the ketone ketone release liner is manufactured by the method of any one of the third to fifth aspects of the patent application. 8. An adhesive sheet for an optical member with an anthrone release liner, which has an anthraquinone release liner produced by the method of any one of the third to fifth items of the patent application scope. The optical member of the pad is an adhesive layer. The structural member is attached to the optical component of the optical anthraquinone 9 of the optical article 7. The adhesive member layer of the optical member for forming the release liner of the patent application range is formed on one side or both sides of the adhesive member optical member with the ketone release liner. Composition. 50