1359879 九、發明說明： 【發明所屬之技術領域】 本發明之實施例提供一種二氧化氯生產設備及其生產 方法。 【先前技術】 二氧化氯其性無色、無味、無毒、無腐#性，不易燃， 不揮發，且二氧化氯為一種強氧化劑，具有高效之滅菌、 消毒之作用。由於二氧化氯不與有機物結合產生氯化效應 生成三氯曱烷等致癌物質，為無毒、無刺激之消毒劑，能 夠安全地廣泛應用於各種領域中，如應用於養殖、公共環 境，或居家生活之消毒殺菌、除臭、防霉的作用，或於食 品加工作業中之脫色、除藻、消毒、滅菌、除臭、保鮮， 或去除毒害物質之作用，而二氧化氯消毒十分安全，無殘 留毒性，不會造成環境或人體上的毒害，其安全性是被世 界衛生組織（WHO)定為AI級的。 二氧化氯於國外廣泛應用於飲用水及環境用藥以及工 業污水中，近年來應用於冷卻循環系統及水產保鮮與水產 養殖等領域的使用，則越來越普遍。由於二氧化氯有許多 優越性，目前世界上有許多國家的自來水廠，皆採用二氧 化氯消毒，而且有迅速發展之趨勢，可助於人類飲用水品 質之提昇。在工業應用方面，二氧化氯不僅在空調及冷卻 水之殺菌、抑制藻類生長方面有顯著的成效，其對於冷卻 水的碳酸鈣等結垢物亦能夠達到抑制形成，可大幅達到節 5 省電力及減少清理與更換冷卻水，並且比其他的冷卻水處 理劑易於使用而不易衍生問題。而又因其強效之殺菌及氧 化能力，Cl〇2已被WHO列為A1級消毒劑應用於防疫工 作；歐美、曰本、澳洲皆已核可α〇2作為食品消毒添加 或保鮮劑。一氧化氯除在傳統工業水處理過程中提供具節 能、省水、低成本、無排玫等優良功效，其良好消毒劑特 性亦對於醫療用途與保健工業也可有廣泛地應用。 習知生產二氧化氣的方法有化學法及電解法。.化學法 主要係利用化學酸製法生產為主，如以亞氯酸鈉(NaC1〇3) 與鹽酸(HC1) ’或以亞氯酸鈉(NaC1〇3)與硫酸(H2S〇4)作為 原料反應生成，然而，為了要使反應完全，鹽酸或硫酸的 使用量必須超過理論值的數倍，且須同時注意反應物的濃 度不宜過高：操作必須非常小心，否則控管不慎，若反應 過於激烈，14樣的製借方法可能隨時有發生爆炸的風險。 而最為溫和的化學反應方法，係湘草酸與驗鈉作為反 應物生成二氧化氣氣體，但其缺點域本高。電解法目前 木用亞氯酸鹽電解氧化和氯酸鹽電解還廣法製備_二氧化 虱’而-般電解裝置大多應用在大型氯鹼工業之氣氣或氯 酸鹽的製造及造⑽之紙漿漂白上，極少用於二氧化氣的 生產’且體積都相當龐大，造價與運作費用非常昂貴，因 此難以推廣應用到—般中小型的使用場合。另，雖然此電 解法較化料製備的二氧化氯純度高，但其所 需之能耗較 大，且以亞級H氯料作為電解反應物之設備，其反 應原料並無法以-般的通路取m彡貞以特定之方式儲 存的轉㈣並料叙的 綜觀上述，因此有需要―、叙生活當中。 操作方便、安全、生 叹備工間小、運作成本低、 所設計的二氧化氯生產設=。’且反應原料簡單易得之概念 【發明内容】 應室本rrir;—產料，包含：—陽極反 極反應室外，該陰極槽包含至少=極=其位於該陽 室連接，其〜所管路 =陽極反應室^連通管“== 源流經該冷卻管路時對該陽接反應室進行冷卻.以及^ 氣管路，連接該陽極玄…兮…7部’以及-集 氣體產物。 方之該上盖板，用以收集—陽極 本發月也^供一種一氧化氣生產方法，包含下步驟： 使—水源流入一含有氯化鈉之反應原料之原料室中，該水 原與該3有氣化鈉之反應原料混合後，形成一含有氯化鈉 反2原料之水溶液；使該含有含有氯化鈉反應原料之水溶 液流至一陽極反應室及一陰極槽中，以平衡該陽極反應室 ’、該陰極槽間之壓差，其中該陽極反應室中設有至少一陽 極’該陰極槽中設有至少—陰極；使用至少—隔膜以隔離 1359879 該陽極及該陰極，其令該隔膜位於該陽極反應室之一侧邊 上，使該水源流經一冷卻管路，以對該陽極反應室進行冷 卻’其中該冷卻管路穿過該陽極反應室，·開啟與該陽極及 該陰極電性連接之一電源供應器，以進行電解，生產一含 有二氧化氯之陽極氣體產物；以及收集該含有二氧化 ，極f體產物，將該含有二氧化氯之陽極氣體產物溶於該 水源中，形成一二氧化氯溶液。 '【-實施方式】 本發明之實施例提供_種_ 氣生產方法。有關各實施例之==設借及二氣化 所詳述，並伴隨圖示加以說^式和使用方式係如下 用之相同的元件編號係表示相^ ’、圖式和說明書中使 中，為清楚和方便說明起見，S —以之70件。而在圖式 有不符實際之情形。而以下 關實％例之形狀和厚度或 裝置的各項元件或其整合加以^日述者係特別針對本發明之 上述元件並不特別限定於所說明，然而，值得注意的是， 此技藝之人士所得之的各種形$或榀述者，而是可以熟習 請參考第1廚’說明本發 備及其生產方法的示意圖。一 e列之一氧化氣生產設 應室.2,其具有至少一隔祺^心化氣生產設備包含陽極反 陽極反應室2之相對側邊上。N如一對隔膜4可分別位於 係由聚四氟乙烯（PTFE)、全，二具體實施例中，隔膜4 物、過氟化梭酸聚合物、=氣％酸樹脂、氟烯磺酸聚合 棉隔膜、.微孔性織布隔膜等材 1359879 料所組成。陽極反應室2中具有—陽極6,其固定於一位 於陽極反應室2上方之上蓋板8a。可使用一閉鎖裝置（未 顯示於圖中）以使陽極反應室2氣密完全。在一具體實施 例中，陽極6為板狀或網狀之結構，而在其他實施中，陽 不限定於上述結構。陽極6可為由鈦㈤網上批 銥㈤、釕（Ru)等貴重金屬而成之觸媒陽極卜 陰極槽ig，其中陽極反應室2與陰 槽10係藉由一連通管路18連接。連通管路18且有一互 ，用以連通或隔離陽極反應室2及陰極槽1〇。 二考第2圖’其顯示根據第1圖之實施例中，二氧化氯 生產設備之外觀示意圖，其中陰極槽1G上方具有—上蓋板 極包Λ—位於陽極反應室2上方之上蓋板8a，以及位於 1¼極反應室2外側之卜蓄4c。1« 内包含兩险極甘請參考第1圖’陰極槽10 ^ 八固疋於陽極反應室2外侧之上蓋板 實^、^陰極12及陽極6係藉由隔膜4所隔離。在一具體 12可以鈦金屬或136號以上之鋼板所組 成陰極槽1 〇之側壁麻《ώβ -ρ 一六 # 底 包含—排鹼閥50以避免陰極 槽10内鹼液濃度太高影響電解效率。 請參考第1圖及第2 R . 8為-可㈣型之上具體實施财，上蓋板 纲敫，151 板，其P迎陽極反應室2.之大小而作 二相對位二依,動力學調整陽# 6、陰極12，及隔膜 膜4之陽極反庫^得到較佳之反應環境。陽極6及包含隔 == 室2亦可隨其上方之上蓋板如抽離，因此 、速陽極6及包含隔膜4之陽極反應室2,同時 9 1359879 亦能更換並調整隔膜4之尺寸（面積）。二氧化氯生產設 備還包含一原料室30用以置放反應原料。原料室30可包 含一原料室上蓋板30a。陽極反應室2、上蓋板8、陰極槽 10或原料室30可以PVC或任何足以防止腐蝕之材質所組 成。原料室30係藉由一原料管路14與陽極反應室2連接， 而原料管路14係用以傳送一含有反應原料之水溶液至陽 極反應室2中。原料室30還與一進水管路34連接，其中 進水管路34係用以供應水源至原料室30中，當水源與置 於該原料室30中之反應原料混合後，能形成上述含有反應 原料之水溶液。 請參考第1圖，二氧化氯生產設備包含一穿過陽極反 應室2之冷卻管路20，當水源流經冷卻管路20時能對陽 極反應室2進行冷卻。請參考第3圖，其顯示根據第1圖 中，具有一 U狀結構冷卻管路20穿過陽極反應室2之剖 面圖。在其他實施例中，冷卻管路20可以是一直狀、U狀、 環狀，或曲狀之管路。請參考第1圖，一總水源管路36， 其與進水管路34及冷卻管路20藉由一切換調整閥38相連 接，而切換調整閥38係用以控制連通或隔離總水源管路 36及進水管路34，及用以控制連通或隔離總水源管路36 及冷卻管路20，以控制總水源管路36傳送水源至進水管 路34及冷卻管路20之一。 請參考第1圖，位於陽極反應室2上方之上蓋板8a與 一集氣管路24連接。集氣管路24係作收集陽極氣體產物 1359879 之用。集氣管路24及冷卻管路20以一垂直角度，藉由一 喷流器42與一產物管路40連接，其中噴流器42係用以藉 由水源之流動所產生集氣管路24向外之空氣負壓，將陽極 氣體產物溶於冷卻管路20之水源中，形成一產物溶液，經 產物管路40流出。請參考第2圖，位於陽極反應室2外側 之上蓋板8b可包含一陰極氣體溢散孔48，其可連接管線 以收集或排放陰極氣體產物。位於陽極反應室2上方之上 蓋板8a可具有一溫度計置入口（未顯示於圖中），用以置 放溫度計mm極反應室2之溫度。.位於陽極反應室 2上方之上蓋板8a可具有一洩壓口（未顯示於圖中）:當 管線發生阻塞時作為緊急洩壓用途。請參考U2圖，一^ ，供應器46分财陽極6及陰極12電性料^㈣電 解動力。 本發明實施例之二氧化氯生產方法包含將反應原料置 =原料室30卜在-具體實施财，反應原料係食鹽（氯 化納，NaC1)、海鹽、頁鹽、涵水或其他含有氯化鋼成份 =原料。原料室30可以反應原料填充致完全填滿狀態。利 =換調整閥料通進水管路34與總水源管路％，並隔 =冷卻管路20與總水源管路36，使水源自總水源管路％ 水管路34，而進人原料室3G中。水源流入原料室 溶解原料室3〇中之反應原料而形成含有反應原料 -ΙίΓ! °在""實施例中’上述含有反應原料之水溶液為 飽和水溶液。在一具體實施例中，含有 液為含有氯化納反應原料之水溶液。當含有: = 液路14流人陽極反應室2後，含有反應原料 祕W液U位於陽極反應室2兩侧之隔媒*進入陰極 、曰1〇 Ί水源經由隔膜4進人陰極槽1G之流速緩慢， ^避免隔膜4於陽極反應室2之單㈣力過大而造成破 -知可利用連通官路18所具有之互通切換閥28,連通陽 極反應室2及陰極槽1〇，使含有反應原料之水溶液快速自 陽極反應至2洲_至陰極槽1〇中，以平衡陽極反應室2與陰 鲁極=1G間H使陽極反應室2與陰極槽ig内之水位 平衡上升。在一實施例中，可將含有反應原料之水溶液加 至一溢流水位。 待含有反應原料之水.溶液流入陽極反應室2及陰極槽 10中後，切換上述切換調整閥38以隔離進水管路％與總 水源官路36，並連通冷卻管路2〇與總水源管路％，使水 源自總水源管路36流經冷卻管路2〇。由於當陽極反應室2 $之陽極6在進行電解反應時會放熱，故當水源流經冷卻 鲁 官路20時，經過陽極反應室2之冷卻管路20可對陽極反 應室2進行冷卻。冷卻管路20可以是一直狀、11狀、環狀， 或曲狀之管路。在一具體實施例中，冷卻管路20在經過陽 極反應室2之部份，如第3圖所示，其具有u狀結構。 接者開啟與陽極6及陰極12電性連接之電源供應琴 46’以進行電解。陽極6及陰極12隨著電解反應的進行^ 另J產生1%極氣體產物及陰極氣體產物。在一具體實施例 中，含有氯化鈉反應原料之水溶液於電解過程中產生次氣 酸（HOC1)、.次氯酸根（cl〇-)、氣酸根（CKV)、鹽酸 12 1359879 (HC1)等物種之連續化學反應，而產生二氧化氯（C102)， 並伴隨有臭氧（〇3)及過氧化氳（H2o2)及氫氣（H2)氯 氣（Cl2)之生成。其中二氧化氯（C102)、臭氧（03)及 氯氣（Cl2)為陽極氣體產物。可藉由與陽極室2上方之上 蓋板8連接的集氣管路24收集陽極氣體產物。藉由喷流器 42，以水源之流動所產生集氣管路24向外之空氣負壓，將 陽極氣體產物溶於冷卻管路20之水源中，形成產物溶液， 經產物管路44流出，其中集氣管路24及該冷卻管路20 係以一.垂直角度，藉由該喷流器42與該產物管路40連接。 於電解過程中，陽極反應室2内含有反應原料之水溶液中 的濃度會逐漸變低，此時進水管路34與總水源管路36雖 然係隔離的，然而於原料室30中具有較高濃度之含有反應 原料之水溶液，可藉由濃度梯度之效應，傳送原料至陽極 反應室2内，以使後續之電解反應具有良好之電解效率。 本發明之實施例所揭露之二氧化氣生產設備及其生產 方法中，二氧化氯生產設備包含上蓋板為一可調整型之上 蓋板，其隨陽極反應室之大小而作調整，因此能夠依據動 力學調整陽極、陰極，及隔膜之相對位置，以得到較佳之 反應環境。陽極及包含隔膜之陽極反應室亦可隨其上方之 上蓋板抽離，因此能夠快速更換陽極及包含隔膜之陽極反 應室，同時亦能更換並調整隔膜之尺寸。利用切換調整閥 連通進水管路與總水源管路，並隔離冷卻管路與總水源管 路，使水源自總水源管路流經進水管路，而進入原料室中。 待含有反應原料之水溶液流入陽極反應室及陰極槽中後， 13 1359879 切換上述切換調整閥以隔離進水管路與總水源管路，並連 通冷卻管路與總水源管路，使水源自總水源管路流經冷卻 管路。於電解過程中，可藉由與陽極室上方之上蓋板連接 的集氣管路收集陽極氣體產物。藉由喷流器，以水源之流 動所產生集氣管路向外之空氣負壓，將陽極氣體產物溶於 冷卻管路之水源中，形成產物溶液，經產物管路流出，其 中集氣管路及該冷卻管路係以一垂直角度，藉由該喷流器 與該產物管路連接。於電解過程中，陽極反應室内含有反 應原料之水溶液中的濃度會逐漸變低，此時進水管路與總 水源管路雖然係隔離的，然而於原料室中具有較高濃度之 含有反應原料之水溶液，可藉由濃度梯度之效應，傳送原 料至陽極反應室内，以使後續之電解反應具有良好之電解 效率。因此本發明實施例之水流管路設計為單組架構三迴 路設計，所有管線彼此串聯，藉由控制閥門之切換、質傳 效應及流體力學，不須任何電解電力以外之額外動力，並 可免除加裂機組散熱系統所衍生之用電耗損與風險，亦避 免氣態產品貯存與輸送的成本與危害。 雖然本發明已以電解設備電解含有含有氯化鈉之水溶 液，以得含有二氧化氯（Cl〇2)之產物溶液的較佳實施例 揭露如上，然其並非用以限定本發明，‘本發明實施例之二 氧化氯生產設備及其生產方法可用以生產其他物質，因此 任何熟悉此項技藝者，在不脫離本發明之精神和範圍内， 當可做些許更動與潤飾，因此本發明之保護範圍當視後附 之申請專利範圍所界定者為準。 14 1359879 【圖式簡單說明】 第1圖係顯示根據本發明實施例所述之二氧化氣生產 設備及其生產方法示意圖。 第2圖係顯示根據第1圖之實施例中，二氧化氯生產 設備及其生產方法之外觀示意圖。 第3圖係顯示根據第1圖中，具有一 U狀結構冷卻管 路穿過陽極反應室之剖面圖。 【主要元件符號說明】 2陽極反應室； 4隔膜； 6陽極； 8上蓋板； 8a上盖板， 8b上蓋板； 10陰極槽； 12陰極； 14原料管路； 18連通管路； 20冷卻管路；‘ 24集氣管路； 28互通切換閥； 30原料室； 30a原料室上蓋板； 15 1359879 34進水管路； 3 6總水源管路； 38切換調整閥； 40產物管路； 42噴流器； 46電源供應器； 48陰極氣體溢散孔； 50排鹼閥。1359879 IX. Description of the Invention: [Technical Field of the Invention] Embodiments of the present invention provide a chlorine dioxide production apparatus and a production method thereof. [Prior Art] Chlorine dioxide is colorless, odorless, non-toxic, non-corrosive, non-flammable, non-volatile, and chlorine dioxide is a strong oxidant, which has an efficient sterilization and disinfection effect. Since chlorine dioxide does not combine with organic substances to produce chlorination effects to form carcinogens such as triclosan, it is a non-toxic, non-irritating disinfectant that can be safely used in a wide range of fields, such as in aquaculture, public environments, or at home. Chlorine disinfection, disinfection, deodorization, anti-mildew, or decolorization, algae removal, disinfection, sterilization, deodorization, preservation, or removal of toxic substances in food processing operations, while chlorine dioxide disinfection is very safe, no Residual toxicity does not cause environmental or human toxicity, and its safety is determined by the World Health Organization (WHO) as AI grade. Chlorine dioxide is widely used in drinking water and environmental medicine as well as industrial sewage in foreign countries. In recent years, it has become more and more popular in the fields of cooling circulation systems, aquatic preservation and aquaculture. Due to the many advantages of chlorine dioxide, there are many countries in the world that use water chlorine disinfection, and there is a rapid development trend, which can help improve the quality of human drinking water. In industrial applications, chlorine dioxide not only has remarkable effects in the sterilization of air conditioners and cooling water, but also inhibits the growth of algae. It can also inhibit the formation of scales such as calcium carbonate in cooling water, which can greatly achieve the power saving of 5 provinces. And to reduce the cleaning and replacement of cooling water, and easier to use than other cooling water treatment agents are not easy to derive problems. Due to its potent bactericidal and oxidizing ability, Cl〇2 has been listed as an A1 disinfectant by WHO for epidemic prevention work; Europe, America, Sakamoto and Australia have approved α〇2 as a food disinfection additive or preservative. In addition to the excellent functions of energy saving, water saving, low cost and no arranging in the traditional industrial water treatment process, chlorine dioxide has good disinfectant properties and can be widely used in medical applications and health care industries. Conventional methods for producing dioxide gas include chemical methods and electrolysis methods. The chemical method is mainly produced by chemical acid production, such as sodium chlorite (NaC1〇3) and hydrochloric acid (HC1)' or sodium chlorite (NaC1〇3) and sulfuric acid (H2S〇4) as raw materials. The reaction is formed. However, in order to complete the reaction, the amount of hydrochloric acid or sulfuric acid used must exceed several times the theoretical value, and the concentration of the reactants should not be too high: the operation must be very careful, otherwise the control may be inadvertent if the reaction Too intense, 14 ways of borrowing may be at risk of explosion at any time. The most moderate chemical reaction method is the combination of oxalic acid and sodium as a reactant to generate a gas of dioxin, but its disadvantage is high. The electrolysis method currently uses chlorite electrolytic oxidation and chlorate electrolysis for the preparation of cerium oxide, and the electrolysis device is mostly used in the manufacture and manufacture of gas or chlorate in the large chlor-alkali industry (10). Bleaching, rarely used in the production of dioxide gas' and the volume is quite large, the cost and operation cost is very expensive, so it is difficult to promote the application to small and medium-sized applications. In addition, although the electrolysis method has higher purity of chlorine dioxide prepared by the chemical material, the energy consumption required by the electrolysis method is larger, and the sub-level H chlorine material is used as the equipment of the electrolysis reactant, and the reaction raw material cannot be used in general. The path is taken from the transfer (4) in a specific way, and it is necessary to look at the above. It is easy to operate, safe, and has a small preparation space, low operating cost, and designed chlorine dioxide production. 'And the concept of the reaction material is simple and easy to obtain [invention content] should be room rrir; - production material, including: - anode reverse polarity reaction outside, the cathode tank contains at least = pole = it is located in the solar chamber connection, its pipeline = anode reaction chamber ^ communication tube "= = the anode reaction chamber is cooled when the source flows through the cooling line. And the gas line is connected to the anode ... 7 ... 7 - and - collect gas products. The upper cover plate is used for collecting the anode and the anode is also supplied with a method for producing a gas monoxide, comprising the following steps: flowing the water source into a raw material chamber of the reaction raw material containing sodium chloride, the water source and the gas are 3 After mixing the raw materials of the sodium, an aqueous solution containing the sodium chloride counter 2 raw material is formed; and the aqueous solution containing the raw material containing the sodium chloride reaction is flowed into an anode reaction chamber and a cathode tank to balance the anode reaction chamber' a pressure difference between the cathode tanks, wherein the anode reaction chamber is provided with at least one anode, wherein the cathode tank is provided with at least a cathode; and at least a separator is used to isolate the anode and the cathode, which is disposed at the anode anode On one side of the reaction chamber, the water source is passed through a cooling line to cool the anode reaction chamber, wherein the cooling line passes through the anode reaction chamber, and the anode and the cathode are electrically connected. a power supply for performing electrolysis to produce an anode gas product containing chlorine dioxide; and collecting the product containing a dioxide, a polar body, and dissolving the chlorine gas-containing anode gas product in the water source to form A chlorine dioxide solution. '[Embodiment] The embodiment of the present invention provides a method for producing gas, which is described in detail in the respective examples of == lending and two gasification, and is illustrated with the accompanying drawings. The same component numbers as used below are used to indicate the phase, the schema and the description, for the sake of clarity and convenience of description, S - 70. In the case of the pattern is not realistic. In the following, the shape and thickness of the % example or the components of the device or the integration thereof are specifically described. The above-mentioned elements particularly for the present invention are not particularly limited to the description, however, it is worth noting that the art is people The various forms of $ or narration, but can be familiar with the reference to the first kitchen's description of the preparation and production methods. One of the columns of oxidation gas production equipment room. 2, which has at least A separator gas generating apparatus comprises the opposite sides of the anode counter anode reaction chamber 2. N, such as a pair of separators 4, may be respectively located in polytetrafluoroethylene (PTFE), all, A material, a perfluorinated fumaric acid polymer, a gas-% acid resin, a fluoroolefin sulfonated polymerized cotton membrane, a microporous woven fabric separator, etc. 1359879. The anode reaction chamber 2 has an anode 6 which is fixed. The upper cover 8a is located above the anode reaction chamber 2. A blocking device (not shown) may be used to completely seal the anode reaction chamber 2. In a specific embodiment, the anode 6 is a plate or a mesh. The structure of the shape, and in other implementations, the anode is not limited to the above structure. The anode 6 may be a catalyst anode cathode tank ig formed of a precious metal such as titanium (5), ruthenium (Ru), etc., wherein the anode reaction chamber 2 and the cathode tank 10 are connected by a communication line 18. The communication line 18 has a mutual phase for connecting or isolating the anode reaction chamber 2 and the cathode chamber 1〇. Figure 2 of the second test, which shows a schematic view of the appearance of the chlorine dioxide production equipment according to the embodiment of Fig. 1, wherein the cathode tank 1G has an upper cover pole package - a cover plate above the anode reaction chamber 2 8a, and 4c located outside the 11⁄4 pole reaction chamber 2. 1« contains two dangerous poles, please refer to Figure 1 'cathode tank 10 ^ eight solids on the outer side of the anode reaction chamber 2 cover plate ^, ^ cathode 12 and anode 6 are isolated by the diaphragm 4. In a specific 12 titanium metal or 136 or more steel plate composed of the cathode groove 1 〇 side wall hemp "ώβ -ρ一六# bottom contains - discharge alkali valve 50 to avoid too high concentration of alkali in the cathode tank 10 affects the electrolysis efficiency . Please refer to Figure 1 and 2R. 8 for the - (4) type, the implementation of the financial, upper cover, 151 plates, the P is the anode reaction chamber 2. The size is two relative position, the power Learn to adjust the anode #6, the cathode 12, and the anode of the diaphragm 4 to obtain a better reaction environment. The anode 6 and the chamber 2 including the partition == can also be separated from the upper cover plate, and therefore, the quick anode 6 and the anode reaction chamber 2 including the diaphragm 4, and the size of the diaphragm 4 can be replaced and adjusted by 9 1359879 ( area). The chlorine dioxide producing apparatus further includes a raw material chamber 30 for placing the reaction raw material. The material chamber 30 may include a raw material chamber upper cover 30a. The anode reaction chamber 2, the upper cover 8, the cathode tank 10 or the raw material chamber 30 may be formed of PVC or any material sufficient to prevent corrosion. The raw material chamber 30 is connected to the anode reaction chamber 2 by a raw material line 14 for transferring an aqueous solution containing the reaction raw material to the anode reaction chamber 2. The raw material chamber 30 is also connected to a water inlet line 34 for supplying a water source to the raw material chamber 30. When the water source is mixed with the reaction raw material placed in the raw material chamber 30, the above-mentioned reaction raw material can be formed. An aqueous solution. Referring to Figure 1, the chlorine dioxide production facility includes a cooling line 20 that passes through the anode reaction chamber 2 to cool the anode reaction chamber 2 as it flows through the cooling line 20. Referring to Fig. 3, there is shown a cross-sectional view of the cooling duct 20 having a U-shaped structure passing through the anode reaction chamber 2 according to Fig. 1. In other embodiments, the cooling line 20 can be a straight, U-shaped, annular, or curved conduit. Referring to FIG. 1, a total water source line 36 is connected to the water inlet line 34 and the cooling line 20 by a switching regulator valve 38, and the switching regulator valve 38 is used to control the communication or isolation of the total water source line. 36 and the water inlet line 34, and for controlling the communication or isolation of the total water source line 36 and the cooling line 20 to control the total water source line 36 to transfer the water source to one of the inlet line 34 and the cooling line 20. Referring to Fig. 1, the upper cover 8a is connected to a gas collection line 24 above the anode reaction chamber 2. The gas collection line 24 is used to collect the anode gas product 1359879. The gas collection line 24 and the cooling line 20 are connected to a product line 40 by a spout 42 at a vertical angle, wherein the spout 42 is used to generate the gas collection line 24 by the flow of the water source. Under negative air pressure, the anode gas product is dissolved in the water source of the cooling line 20 to form a product solution which flows out through the product line 40. Referring to Figure 2, the cover plate 8b above the anode reaction chamber 2 can include a cathode gas spill hole 48 that can be connected to the line to collect or discharge the cathode gas product. Located above the anode reaction chamber 2, the cover 8a may have a thermometer inlet (not shown) for accommodating the temperature of the thermometer mm chamber 2. The upper cover 8a above the anode reaction chamber 2 may have a pressure relief port (not shown) for use as an emergency relief when the line is blocked. Please refer to the U2 diagram, a ^, the supply 46 is divided into the anode 6 and the cathode 12 electrical material ^ (4) electrolytic power. The chlorine dioxide production method according to the embodiment of the present invention comprises: setting the reaction raw material = the raw material chamber 30 - in the specific implementation, the reaction raw material is the salt (NaCl), sea salt, sulphate, culvert or other chlorination Steel composition = raw material. The raw material chamber 30 can be filled with the reaction raw material to be completely filled. ==Change the regulating valve material to the water inlet line 34 and the total water source line %, and the partition = cooling line 20 and the total water source line 36, so that the water is sourced from the total water source line % water line 34, and enters the raw material room 3G. The water source flows into the raw material chamber, and the reaction raw material in the raw material chamber 3 is dissolved to form a reaction raw material. The aqueous solution containing the reaction raw material in the "" In one embodiment, the liquid is an aqueous solution containing a sodium chloride reaction material. When it contains: = the liquid path 14 flows into the human anode reaction chamber 2, the medium containing the reaction material secret liquid W on both sides of the anode reaction chamber 2 enters the cathode, and the water source enters the cathode tank 1G via the separator 4 The flow rate is slow, and the single (four) force of the diaphragm 4 in the anode reaction chamber 2 is prevented from being excessively large, so that the intervening switching valve 28 of the connecting official passage 18 can be utilized to connect the anode reaction chamber 2 and the cathode tank 1 to cause the reaction. The aqueous solution of the raw material is rapidly reacted from the anode to the second to the cathode tank to balance the water level in the anode reaction chamber 2 and the cathode tank ig by balancing the H between the anode reaction chamber 2 and the cathode and the anode. In one embodiment, the aqueous solution containing the reaction material can be added to an overflow level. After the water containing the reaction raw material flows into the anode reaction chamber 2 and the cathode tank 10, the switching regulator valve 38 is switched to isolate the water inlet pipe % from the total water source official road 36, and to communicate the cooling pipe 2 and the total water source pipe. The road % causes water to flow from the total water source line 36 through the cooling line 2 . Since the anode 6 of the anode reaction chamber 2 is exothermic when performing the electrolysis reaction, when the water source flows through the cooling Luguan Road 20, the anode reaction chamber 2 can be cooled by the cooling line 20 of the anode reaction chamber 2. The cooling line 20 can be a straight, elliptical, annular, or curved tube. In a specific embodiment, the cooling line 20 passes through a portion of the anode reaction chamber 2, as shown in Fig. 3, which has a u-like structure. The power supply is supplied to the power supply unit 46' electrically connected to the anode 6 and the cathode 12 for electrolysis. The anode 6 and the cathode 12 are subjected to an electrolysis reaction to produce a 1% polar gas product and a cathode gas product. In a specific embodiment, the aqueous solution containing the sodium chloride reaction raw material generates hypoxamic acid (HOC1), hypochlorite (cl〇-), oleate (CKV), hydrochloric acid 12 1359879 (HC1), etc. during electrolysis. The continuous chemical reaction of the species produces chlorine dioxide (C102) accompanied by the formation of ozone (〇3) and hydrogen peroxide (H2o2) and hydrogen (H2) chlorine (Cl2). Among them, chlorine dioxide (C102), ozone (03) and chlorine (Cl2) are anode gas products. The anode gas product can be collected by a gas collection line 24 connected to the upper cover 8 above the anode chamber 2. The anode gas product is dissolved in the water source of the cooling line 20 by the jet 42 to generate a product solution through the product line 44, wherein the anode gas product is dissolved in the water source of the cooling line 20 by the flow of the water source. The gas collection line 24 and the cooling line 20 are connected at a vertical angle to the product line 40 by the spout 42. During the electrolysis process, the concentration in the aqueous solution containing the reaction raw material in the anode reaction chamber 2 is gradually lowered. At this time, the water inlet pipe 34 and the total water source pipe 36 are isolated, but have a higher concentration in the raw material chamber 30. The aqueous solution containing the reaction raw material can transfer the raw material into the anode reaction chamber 2 by the effect of the concentration gradient, so that the subsequent electrolytic reaction has good electrolysis efficiency. In the chlorine dioxide production equipment and the production method thereof disclosed in the embodiments of the present invention, the chlorine dioxide production equipment includes an upper cover plate as an adjustable upper cover plate, which is adjusted according to the size of the anode reaction chamber, so The relative positions of the anode, the cathode, and the separator can be adjusted according to the kinetics to obtain a better reaction environment. The anode and the anode reaction chamber containing the separator can also be withdrawn from the upper cover plate, so that the anode and the anode reaction chamber containing the diaphragm can be quickly replaced, and the size of the diaphragm can be replaced and adjusted. The switching regulator valve is used to communicate the inlet pipe and the total water source pipe, and the cooling pipe and the total water source pipe are isolated, so that the water flows from the total water source pipe through the water inlet pipe and enters the raw material chamber. After the aqueous solution containing the reaction raw material flows into the anode reaction chamber and the cathode tank, 13 1359879 switches the above-mentioned switching regulating valve to isolate the inlet pipe and the total water source pipe, and connects the cooling pipe and the total water source pipe, so that the water is derived from the total The water source line flows through the cooling line. During the electrolysis process, the anode gas product can be collected by a gas collection line connected to the upper cover above the anode chamber. The anode gas product is dissolved in the water source of the cooling pipeline by the jet flow device, and the anode gas product is dissolved in the water source of the cooling pipeline to form a product solution, which flows out through the product pipeline, wherein the gas gathering pipeline and the gas pipeline The cooling line is connected to the product line by the jet at a vertical angle. During the electrolysis process, the concentration in the aqueous solution containing the reaction raw material in the anode reaction chamber will gradually become lower. At this time, although the inlet water pipeline and the total water source pipeline are isolated, the raw material chamber has a higher concentration of the reaction raw material. In the aqueous solution, the raw material can be transferred to the anode reaction chamber by the effect of the concentration gradient, so that the subsequent electrolytic reaction has good electrolysis efficiency. Therefore, the water flow pipeline of the embodiment of the invention is designed as a single-circuit three-loop design, and all the pipelines are connected in series with each other. By controlling the switching of the valve, the mass transfer effect and the fluid mechanics, no additional power other than electrolytic power is required, and the power can be eliminated. The power consumption and risk derived from the heat dissipation system of the cracking unit also avoid the cost and harm of storage and transportation of gaseous products. Although the present invention has been electrolyzed with an aqueous solution containing sodium chloride to obtain a product solution containing chlorine dioxide (Cl 2 ), as disclosed above, it is not intended to limit the invention, 'the invention The chlorine dioxide production equipment of the embodiment and the production method thereof can be used to produce other substances, and therefore, any one skilled in the art can make some modifications and retouchings without departing from the spirit and scope of the invention, and thus the protection of the present invention. The scope is subject to the definition of the scope of the patent application attached. 14 1359879 BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a view showing a gas dioxide production apparatus and a production method thereof according to an embodiment of the present invention. Fig. 2 is a view showing the appearance of a chlorine dioxide production apparatus and a production method thereof according to the embodiment of Fig. 1. Figure 3 is a cross-sectional view showing the cooling tube having a U-shaped structure passing through the anode reaction chamber according to Fig. 1. [Main component symbol description] 2 anode reaction chamber; 4 diaphragm; 6 anode; 8 upper cover; 8a upper cover, 8b upper cover; 10 cathode slot; 12 cathode; 14 raw material pipeline; Cooling line; '24 gas collecting line; 28 intercom switching valve; 30 raw material room; 30a raw material room upper cover; 15 1359879 34 water inlet pipe; 3 6 total water source pipeline; 38 switching adjustment valve; 40 product pipeline; 42 jets; 46 power supply; 48 cathode gas overflow holes; 50 rows of alkali valves.