TWI239976B - Fire-retarded polyamide composition - Google Patents
Fire-retarded polyamide composition Download PDFInfo
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- TWI239976B TWI239976B TW089102700A TW89102700A TWI239976B TW I239976 B TWI239976 B TW I239976B TW 089102700 A TW089102700 A TW 089102700A TW 89102700 A TW89102700 A TW 89102700A TW I239976 B TWI239976 B TW I239976B
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- 239000000203 mixture Substances 0.000 title claims abstract description 46
- 229920002647 polyamide Polymers 0.000 title abstract description 6
- 239000004952 Polyamide Substances 0.000 title abstract description 4
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000007974 melamines Chemical class 0.000 claims abstract description 9
- 229920000768 polyamine Polymers 0.000 claims description 12
- 229920000877 Melamine resin Polymers 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 239000003365 glass fiber Substances 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 229920000388 Polyphosphate Polymers 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 5
- 239000000806 elastomer Substances 0.000 claims description 5
- 230000009970 fire resistant effect Effects 0.000 claims description 5
- 239000001205 polyphosphate Substances 0.000 claims description 5
- 235000011176 polyphosphates Nutrition 0.000 claims description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 claims description 4
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 3
- 239000002557 mineral fiber Substances 0.000 claims description 3
- 239000012763 reinforcing filler Substances 0.000 claims description 3
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 2
- 235000021357 Behenic acid Nutrition 0.000 claims description 2
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 2
- 229940116226 behenic acid Drugs 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 claims 2
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 claims 1
- 239000004640 Melamine resin Substances 0.000 claims 1
- BLRHXYOZUHSROE-UHFFFAOYSA-N O=[Pt](=O)=O Chemical compound O=[Pt](=O)=O BLRHXYOZUHSROE-UHFFFAOYSA-N 0.000 claims 1
- 235000021314 Palmitic acid Nutrition 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 1
- 239000001361 adipic acid Substances 0.000 claims 1
- 235000011037 adipic acid Nutrition 0.000 claims 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims 1
- 235000011180 diphosphates Nutrition 0.000 claims 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims 1
- 150000004291 polyenes Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 3
- -1 dihydroxyphenol Chemical class 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 8
- 229920002292 Nylon 6 Polymers 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920006122 polyamide resin Polymers 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 102100025027 E3 ubiquitin-protein ligase TRIM69 Human genes 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 101000830203 Homo sapiens E3 ubiquitin-protein ligase TRIM69 Proteins 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004954 Polyphthalamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229960004365 benzoic acid Drugs 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 150000004074 biphenyls Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- ULFHSQLFQYTZLS-UHFFFAOYSA-N difluoroamine Chemical compound FNF ULFHSQLFQYTZLS-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- ZGHDMISTQPRNRG-UHFFFAOYSA-N dimolybdenum Chemical compound [Mo]#[Mo] ZGHDMISTQPRNRG-UHFFFAOYSA-N 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- OTLGFUHTYPXTTG-UHFFFAOYSA-M indium(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[In+3] OTLGFUHTYPXTTG-UHFFFAOYSA-M 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000962 poly(amidoamine) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920006375 polyphtalamide Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2255—Oxides; Hydroxides of metals of molybdenum
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Connector Housings Or Holding Contact Members (AREA)
- Materials For Medical Uses (AREA)
Description
1239976
五、發明說明（1) 本發明係關於一種防、火性聚醯胺組合物，尤其承關於— 種可以用於製造模製物件者。 、 、 . 本發明更尤其是關於一種聚醯胺之組合物是藉一種沒 、〜· 任何函素或石粦之防火系統防火。 基於聚醯胺樹脂之組合物是用於藉定屬名"模製”指稱之 多種形成方法製造物件。這些物件是用於多種技術範圍。 在其中’製造電或電子糸統方面之組件是一種主要主途其 需要特殊性質者。因此，這些組件必須具高機械性質且也 耐化學品，電絕緣之性質及，取重要者，防火性質。 研究基於聚醯胺樹脂之組合物之防火性質已有極長之時 _ 間。因此，使用之主要防火劑是紅磷及i化合物諸如二漠 酚，多溴聯苯，多溴聯酚鹽及溴化之聚苯乙烯。在以往二 十年間，已發現防火劑之新門類，例如，有機氮化合物於 · 三哄類，諸如三聚氰胺或其衍生物，諸如三聚氰胺氰尿酸 -酯，及更晚近磷酸§旨’多磷酸酯及三聚氰胺進磷酸酯。 防火劑之後者門類之優點是這些化合物不含函1素或自由 磷。此是因為含鹵素或紅磷之防火劑在該聚醯胺組合物之 燃燒期間能產生毒性氣體或蒸氣。獲得令人滿意之防火所 需之三聚氰胺化合物之量是非常高，尤其是在組合物含增 籲 強填料以纖維，形態諸如玻璃纖維，礦物纖維或熱穩定性 有機纖維之情況。這些組合物之成本，由於大量之三聚氰 胺化合物，使其從商業觀點使人興趣索然。此外，三聚氰 胺化合物之此高濃度有某些缺點，尤其是在該組合物之製 造期間，諸如產生該三聚氰胺化合物之蒸氣或，在模製物
第5頁 1239976
五、發明說明（2) 件間，諸如通氣管之阻塞及沉積形成於模型中。 铁而：Γ胺化合物之組合物可能有良好的防火性質， 電方面的抗電弧傳播。以使其用於製造 聚點’藉提供-種基於三 該系统有^杯 有較含量之三聚氰胺化合物， A t卜曰二的抗電弧傳播，例如，300伏特以上。 -=二1本發明提供一種基於聚醯胺之組合物其包含 糸 '、先，特徵在於此防火系統含一 物及三氧化鉬。 禋一小虱fe何生 根據本發明之另一柱 _ ^ ^ ^ ^ ^ 另特欲，二聚氟胺之重量濃度，對該基
Jo f!二舌之組合物之總重量，是介於1與30重量％，以介 於10與20重量％為佳。 ^ ^ ^ - 特政二虱化鉬之重量濃度，對該組 &物之、，.心重$，是低於15重量％，宜是低於或等於ι〇重量 90 〇 A 2 ί :::月之一種較可取的具體體系，該防火性組合物 ^ 早匆—型聚合物其能對衝擊強度有所貢獻。對可 以使用之彈性物之_别、、々右限也丨 14_ 頦1有限制。特定言之，可以使用供 曰加承^ fe之、衝擊強度之一切已知之彈性物。適當的彈性 物，例是乙烯-丙烯酸酯-順—丁烯二酸酐，乙烯—丙烯—順一 丁烯一S文酐，EPDMs(乙烯-丙烯〜二烯單體）選擇性愈一種 接枝順-丁烯二酸酐。彈性物之重量濃度以低 重 有利，宜是低於5%。
第6頁 1239976 得之聚醯胺，諸如PA-6,6， PA-6, 1 0，PA-6，12 ^ PA-12, 12，PA-4，6 及MXD - 6，或一種 芳二羧酸與一種直鏈或芳二胺聚縮合羧得之聚醯胺諸如聚 對酞醯胺，聚異酞醯胺及芳族聚醯胺，藉一種胺基酸與本 身，該胺基酸可能是藉一個内醯胺環之水解開啟產生，之 聚縮合獲得之聚醯胺，諸如，例如PA-6，PA-7，PA-1 1及 PA-12。本發明之方法也適合用於處理衍生自尤其是以上 之聚醯胺，或這些聚醯胺或共聚醯胺之摻合物。 較可取的聚醯胺是聚六伸曱基己二醯胺，聚己内醯胺， 物其 物基 例如 例， 酸， 以上 酸， 酸， 是被 表面 及與 種化合 該聚合 期間， 羧酸之 ，硬脂 子十個 ，戊二 及對酞 聚醯胺 此有高 速降低 統包 於其 物之 為適 ，掠 ，含 ，丁 ，異 合物 點滴 度非 含一 是與 方法 當的 櫚酸 碳原 二酸 酞酸 ，當 ，因 常急 五、發明說明（3) 根據本發明之另一特徵，該 含至少一個羧酸官能基及有低 體混合之溫度，特別是在製造 於介於喲2 0 0 °C與約3 5 0 °C之溫 可以提及者是單羧酸，諸如肉 二十二酸，苯甲酸，柳酸及， 之單羧酸，二羧酸諸如草酸， 己二酸，庚二酸，癸二酸，十 或多羧酸，諸如1，3, 5-苯三酸 火焰熔化鏈長度減低時，造成 面積/質量比。因此這些小點 它們接觸之元件不再能著火。 該單-，二-或多緩酸以是對 與3%之重量濃度存在為有利， 該聚酸胺是選自該組鱗其包 直鏈或環二胺聚縮合獲 防火系 蒸氣壓 該化合 度。作 豆蔻酸 一般上 丙二酸 二二酸 。此化 產生小 滴之溫 該聚醯胺樹脂以介於0 . 0 1 % 宜是介於0 . 0 5 %與1 %。 含藉一種直鏈二羧酸與一種
O:\62\62775.ptd 第7頁 1239976 五、發明說明（4) 或聚六伸曱基已二醯胺與聚己内醯胺之共聚物及摻合物。 、適合用於本發明之三聚氰胺衍生物或化合物是選自該組 =其包含二聚氰胺氰尿酸酯，描述於日本專利 53/51250 ，JP-A-54/118454及JP-A-54/16564中，及 j聚氛胺碌酸鲳及多磷酸酯，描述於專利W0 9 6 /0 9 344 取I & f是’用於製造根據本發明之組合物之化合物是三 f鼠胺多碟酸_。其重量濃度，對該組合物之總重量，以 氐於2 5%是有利，宜是低於20%。 群ί=發3f之另一特徵，該組合物含增強填料選自該組 二匕a玻螭纖維，礦物纖維，例如矽灰石，陶磁纖維， 嶺、：性有機纖維，諸如聚酞醯胺纖維，及礦物填料諸如高 重量濃度，對該組合物之總重量，以介於1% ”5〇/°疋有利，宜是介於15與50%。 本發明之組合物可乂各# 製造模f物件之2㊉用於基於聚醯胺之組合物供 以；加劑，因Λ，作為添加劑之例，可 料，著色劑及衝V;;:劑抗氧化劑’潤，^ 物，-化物，位阻是及：：胺驗金屬•化 該υ V穩定劑通常是苯并- 一朴 ^ 。 鞾得太瘀日日夕々入4开一圭，二本甲酮或HALS。 後付本^月之組合物是藉混合各 皁螺旋或雙螺旋擠出機中，於、、w f :、通㊉是在一台 樹脂於熔融狀態。一般上，_ P二=以保持該聚酿胺 上獲付之聚合物化合物是擠製為
1239976 五、發明說明（5) 棒狀其是切為小段以生成顆粒— 進行添加該防火系統或該添加 ，形態添加這些化合物或以=體中可以 —種聚醯胺樹脂，巾之母熔體之形能=:，绪如，例如 後得之顆粒是用作扁料彳丘靡 ^ μ 4' 口 中，諸如射出m用於製模製物件之方法 ”成型’擠出，擠出吹模方法。 子連接技卞=日月之組合物是尤其適合用於製造用；^電或電 連接技術方面之物件，諸如 、次電 或類似物之組件。 ㈣斷路益H ’連接器 法本發明之組合物之性質是對試驗片作測定，冑用以下方 序。此試驗是對厚 進行試驗。結果 二^趋：根據保險業實驗室UL-94試驗程 度3· 2公厘，1· 6公厘及〇· 8公厘之試驗片 是以以下評等表示：
Uc :不列等（微弱防火）； 聚醯胺點 V-2 :平均燃燒時間是25秒以下（自行滅火）， 滴點燃該棉； H :平均燃燒時間25秒以下（自行滅火），聚醯胺 不點燃該棉； ·、、’ V-0 :平均燃_燒時間5秒以下（自行滅火），該棉不點燃 二屬絲抵抗根據IEC 69 5-2 _1標準對厚度3. 〇公… 厘’ 1 · 6公厘及1公厘之試驗片作測定。 機械性質使用以下方法測定： 一抗張強度 根據ISO R 527標準於調節該試驗片於23
第9頁 1239976
°C及5 0 °C之相對濕度之後； -致斷伸長 根據ISO 527標準； -模量 根據ISO 527標準； -IZ0D衝擊強度 根據IS0 179/IelJ標準； - CHARPY單樑式衝擊試驗根據ISO 179/IeA標準· -抗電弧傳播 根據I EC 112標準。 ’ 實例說明 藉以次之例說明本發明，這些例只是作為指示及 制本發明之範圍。 ：、不限 精以一種二聚氣胺多填酸I旨’三氧化翻及玻璃纖 一種聚醯胺製造多種組合物。 、、、配混 在一台單-螺旋擠製機於溫度2 50 °c製造該組合物 ^ , w ° 吞亥矣且 合物是擠製為棒狀以藉切這些棒以生成顆粒。 " 使用之材料是·· 聚醯胺A :聚六伸甲基己二醯胺（PA-6, 6)，以商品名 nTecnonylon27 A 00"銷售 三聚氰胺化合物B ··三聚氰胺多磷酸酯，以商品名 "MELAPUR 200π 銷售 二氧化銦C:三氧銦 MFR，由 Clymax Molybdenum USA 銷 售 —· 玻璃纖維D :玻璃纖維，直徑1 〇微米，以截股狀以商品 名11 FV-R123” 銷售 彈性物 E :L0TADER 3210 由 Elf Atochem 銷售 彈性物F : EXXELOR VA 1801 由 Exxon Chemicals 銷售
第10頁 1239976 五、發明說明（7) 每一組合物之每一成分之重量濃度百分率及每一組合物 之機械及防火性質列於以下表中。
例 1 2 3 4 5 6 A 50 55 50 43 43 45 B 25 20 20 25 25 20 C 0 0 5 5 5 10 D 25 25 25 25 25 25 E 0、 〇 0 0 〇 0 F 0 0 0 ,〇 2 0 切口 Charpy 衝擊強度 kJ/m2 4.1 4.6 5.3 5.3 5.1 5.6 不切口 Charpy 衝擊強度 kJ/m2 32.9 40 42 40 41 13.7 抗張強度 133.5 140 156 149 154 102.7 致斷伸長，％ 1.9 2.3 1.7 1.6 1.7 0.9 模量，MPa 11258 10735 11930 11700 12150 13543 UL-94試驗 3.2/1.6/0.8 mm V0/V0/V1 vo/vo/ucf V0/V0/V1 V0/V0/VI V0/V0/VI V0/V0/V1 白熱金屬絲 試驗於 3/1.6/1 mm 960/960/ 960 960/960/ 960 960/960/ 960 960/960/ 960 960/960/ 960 960/960/ 960 抗電派傳播 試驗 <300 V 未測定 >400 V >400 V >350 V >400 V (*)uc :不列等 ' 這些試驗示…三氧化鉬之存在使可能降低三聚氰_胺之量同 時由仍維持令人滿意的防火性質及以獲得有良好抗電弧傳 播之組合物。
O:\62\62775.ptd 第11頁
Claims (1)
- 案號 89102700 Μ 月 曰 修正 六、申請專利範圍 1 . 一種防火性聚醯胺組合物，其包含一種防火系統，特 徵在於該防火系統含一種三聚氰胺衍生物及三氧化鉑， 其中對該組合物之總重量，三聚氰胺衍生物之重量濃 度是介於1與30重量％，且三氧化鉬之重量濃度是低於15重 量％ 〇 2 ·根據申請專利範圍第1項之組合物，特徵在於三氧化 鉬之重量濃度，對該組合物之總重量，是低於1 0重量％。 3 ·根據申請專利範圍第1項之組合物，特徵在於三聚氰 胺衍生物是選自包含三聚氰胺氰尿酸酯，三聚氰胺磷酸酯 及三聚氰胺多磷酸酯或焦磷酸酯之組群中。 4.根據申請專利範圍第3項之組合物，特徵在於該三聚 氰胺衍生物是三聚氰胺多磷酸酯。 5 ·根據申請專利範圍第4項之組合物，特徵在於該三聚 氰胺多填酸酯之重量濃度，對該組合物之總重量，是低於 2 5%。 6 .根據申請專利範圍第1項之組合物，特徵在於其包含 增強填料，其係選自包含玻璃纖維、礦物纖維及耐熱有機 纖維之組群中。 7 .根據申請專利範圍第1項之組合物，特徵在於其包含 一種彈性物。 8 .根據申請專利範圍第1項之組合物，特徵在於該防火 系統含一種單-，二-或多敌酸。 9 .根據申請專利範圍第8項之組合物，特徵在於該單-， 二-或多竣酸之重量濃度，對該三聚氰胺樹脂，是以介於O:\62\62775-930701.ptc 第13頁 1239976 _案號89102700 P年1月 日 修正_ 六、申請專利範圍 ο. α 1 %與3 %存在。 1 0 .根據申請專利範圍第8項之組合物，特徵在於該上述 之酸是選自包含肉豆蔻酸、棕櫊酸、硬脂酸、二十二酸、 苯曱酸、柳酸、草酸、丙二酸、丁二酸、戊二酸、己二 酸、庚二酸、癸二酸、十二二酸、異酞酸、對It酸及1，3， 5 -苯三酸之組群中。 1 1 . 一種藉模製或成型根據申請專利範圍第1至1 0項中任 一項之組合物而獲得之防火性模製物件。O:\62\62775-930701.ptc 第14頁
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| FR2810326B1 (fr) * | 2000-06-16 | 2006-08-04 | Rhodia Eng Plastics Srl | Polyamides modifies, compositions a base de ces polyamides, et leur procede de fabrication |
| US7799854B2 (en) * | 2004-04-01 | 2010-09-21 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic composition and articles comprising the same |
| US7417083B2 (en) * | 2004-04-01 | 2008-08-26 | Sabic Innovative Plastics Ip B.V. | Flame retardant composition |
| US7582692B2 (en) * | 2004-04-01 | 2009-09-01 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic composition and articles comprising the same |
| FR2872515B1 (fr) * | 2004-07-02 | 2006-10-13 | Arkema Sa | Compositions thermoplastiques ignifuges, leur procede de preparation |
| EP1683830A1 (en) * | 2005-01-12 | 2006-07-26 | DSM IP Assets B.V. | Heat stabilized moulding composition |
| EP1681313A1 (en) * | 2005-01-17 | 2006-07-19 | DSM IP Assets B.V. | Heat stabilized moulding composition |
| BR112013015087A2 (pt) * | 2010-12-16 | 2016-08-09 | Basf Se | composição de moldagem termoplástica, uso da composição de moldagem termoplástica e fibra, folha, ou peça moldada |
| EP3697838A2 (en) * | 2017-10-17 | 2020-08-26 | Celanese Sales Germany GmbH | Flame retardant polyamide composition |
| US11865394B2 (en) | 2017-12-03 | 2024-01-09 | Mighty Fire Breaker Llc | Environmentally-clean biodegradable water-based concentrates for producing fire inhibiting and fire extinguishing liquids for fighting class A and class B fires |
| US10260232B1 (en) | 2017-12-02 | 2019-04-16 | M-Fire Supression, Inc. | Methods of designing and constructing Class-A fire-protected multi-story wood-framed buildings |
| US20240157180A1 (en) | 2021-02-04 | 2024-05-16 | Mighty Fire Breaker Llc | Method of and kit for installing and operating a wildfire defense spraying system on a property parcel for proactively spraying environmentally-clean liquid fire inhibitor thereover to inhibit fire ignition and flame spread caused by wind-driven wildfire embers |
| US10653904B2 (en) | 2017-12-02 | 2020-05-19 | M-Fire Holdings, Llc | Methods of suppressing wild fires raging across regions of land in the direction of prevailing winds by forming anti-fire (AF) chemical fire-breaking systems using environmentally clean anti-fire (AF) liquid spray applied using GPS-tracking techniques |
| US10311444B1 (en) | 2017-12-02 | 2019-06-04 | M-Fire Suppression, Inc. | Method of providing class-A fire-protection to wood-framed buildings using on-site spraying of clean fire inhibiting chemical liquid on exposed interior wood surfaces of the wood-framed buildings, and mobile computing systems for uploading fire-protection certifications and status information to a central database and remote access thereof by firefighters on job site locations during fire outbreaks on construction sites |
| US11395931B2 (en) | 2017-12-02 | 2022-07-26 | Mighty Fire Breaker Llc | Method of and system network for managing the application of fire and smoke inhibiting compositions on ground surfaces before the incidence of wild-fires, and also thereafter, upon smoldering ambers and ashes to reduce smoke and suppress fire re-ignition |
| US11836807B2 (en) | 2017-12-02 | 2023-12-05 | Mighty Fire Breaker Llc | System, network and methods for estimating and recording quantities of carbon securely stored in class-A fire-protected wood-framed and mass-timber buildings on construction job-sites, and class-A fire-protected wood-framed and mass timber components in factory environments |
| US10814150B2 (en) | 2017-12-02 | 2020-10-27 | M-Fire Holdings Llc | Methods of and system networks for wireless management of GPS-tracked spraying systems deployed to spray property and ground surfaces with environmentally-clean wildfire inhibitor to protect and defend against wildfires |
| US10430757B2 (en) | 2017-12-02 | 2019-10-01 | N-Fire Suppression, Inc. | Mass timber building factory system for producing prefabricated class-A fire-protected mass timber building components for use in constructing prefabricated class-A fire-protected mass timber buildings |
| US10290004B1 (en) | 2017-12-02 | 2019-05-14 | M-Fire Suppression, Inc. | Supply chain management system for supplying clean fire inhibiting chemical (CFIC) totes to a network of wood-treating lumber and prefabrication panel factories and wood-framed building construction job sites |
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1999
- 1999-02-24 FR FR9902525A patent/FR2789996B1/fr not_active Expired - Fee Related
-
2000
- 2000-02-17 TW TW089102700A patent/TWI239976B/zh not_active IP Right Cessation
- 2000-02-22 ES ES00909230T patent/ES2182789T3/es not_active Expired - Lifetime
- 2000-02-22 WO PCT/EP2000/001436 patent/WO2000050505A1/fr not_active Ceased
- 2000-02-22 PT PT00909230T patent/PT1155070E/pt unknown
- 2000-02-22 BR BR0010203-2A patent/BR0010203A/pt not_active IP Right Cessation
- 2000-02-22 AT AT00909230T patent/ATE223941T1/de not_active IP Right Cessation
- 2000-02-22 DK DK00909230T patent/DK1155070T3/da active
- 2000-02-22 EP EP00909230A patent/EP1155070B1/fr not_active Expired - Lifetime
- 2000-02-22 CA CA002363651A patent/CA2363651C/fr not_active Expired - Fee Related
- 2000-02-22 AU AU31585/00A patent/AU3158500A/en not_active Abandoned
- 2000-02-22 DE DE60000446T patent/DE60000446T2/de not_active Expired - Fee Related
-
2001
- 2001-08-24 US US09/935,670 patent/US6608123B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO2000050505A1 (fr) | 2000-08-31 |
| FR2789996B1 (fr) | 2001-04-13 |
| BR0010203A (pt) | 2002-01-29 |
| US6608123B2 (en) | 2003-08-19 |
| CA2363651A1 (fr) | 2000-08-31 |
| EP1155070A1 (fr) | 2001-11-21 |
| AU3158500A (en) | 2000-09-14 |
| CA2363651C (fr) | 2004-06-22 |
| DE60000446T2 (de) | 2003-05-15 |
| US20020045688A1 (en) | 2002-04-18 |
| FR2789996A1 (fr) | 2000-08-25 |
| PT1155070E (pt) | 2003-03-31 |
| DE60000446D1 (de) | 2002-10-17 |
| ES2182789T3 (es) | 2003-03-16 |
| DK1155070T3 (da) | 2002-10-14 |
| ATE223941T1 (de) | 2002-09-15 |
| EP1155070B1 (fr) | 2002-09-11 |
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| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |