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TWI232591B - Self-aligned Schottky barrier contact structure and its manufacturing methods - Google Patents

Self-aligned Schottky barrier contact structure and its manufacturing methods Download PDF

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Publication number
TWI232591B
TWI232591B TW93106587A TW93106587A TWI232591B TW I232591 B TWI232591 B TW I232591B TW 93106587 A TW93106587 A TW 93106587A TW 93106587 A TW93106587 A TW 93106587A TW I232591 B TWI232591 B TW I232591B
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layer
side wall
patent application
schottky barrier
dielectric
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TW93106587A
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TW200531290A (en
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Ching-Yuan Wu
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Silicon Based Tech Corp
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Abstract

A self-aligned Schottky barrier contact structure of the present invention comprises a diffusion guard ring being defined by a first sidewall dielectric spacer and a Schottky contact metal layer being formed on an exposed semiconductor surface surrounded by a second sidewall dielectric spacer, in which the first sidewall dielectric spacer being made of silicon dioxide is formed over an inner sidewall formed by a dielectric layer over a patterned field oxide layer and a thermal silicon dioxide layer on a portion of the diffusion guard ring or is formed over an inner sidewall formed by a composite dielectric layer over a patterned field oxide layer and on a portion of the diffusion guard ring. The self-aligned Schottky barrier contact structure of the present invention needs only two masking photoresist steps.

Description

1232591 五、發明說明(1) 【發明所屬之技術領域】 障(Schottky barrier)二極體 與一種自動對準蕭特基屏障接 本發明與一種蕭特基屏 及其製造方法有關,尤其是 觸結構及其製造方法有^。 術 技 前 先 金子器 觸載流 接數整 基多頻 特種高 蕭一個 個是一 一認或 含公體 包被極 少係二 至上換 體之交 極板速 二基高 障體個 屏導一 基半為 特個作 蕭一而 個於因 一成且 形體 層極 換設嗔 交要、 個主} 一其(IR 為,流 作電 於而漏 功計 向 極逆二、 障} B 屏(V 基壓 特電 蕭潰 種崩 一向 的逆 用於 之中 體集: 極均(IF 二題>^( 率問電 F V 壓 ^6-^9 向 'II 及 圖一顯示先前技術之另外一種蕭特基屏障接觸結構的 一個簡要剖面圖,其中一個P+擴散保護環丨05係透過形成 於兩個成形場氧化物層1 〇 2 a之間的一個擴散窗(未圖示)來 形成於一個η-/n+磊晶半導體基板1〇1/1〇〇之一個所設計的 表面部份之内;一個金屬矽化物層1 〇 3作為一個蕭特基接 觸金屬層係形成於該P +擴散保護環1 〇 5及經由一個成形步 階硼玻璃(BSG)層106a所包圍的一個暴露n — /n +磊晶半導體 基板101/100的表面之上;一個成形金屬層10“係形成於 該成形場氧化物層1 〇 2 a的一部份、該成形步階 <朋玻璃層1232591 V. Description of the invention (1) [Technical field to which the invention belongs] A Schottky barrier diode is connected to an auto-aligned Schottky barrier. The present invention relates to a Schottky screen and a manufacturing method thereof, particularly to The structure and its manufacturing method are ^. Before the technique, the gold device touches the current carrying number of the whole base and the multi-frequency special Gao Xiao. One by one is recognized or contains a public body cover and rarely is a two-to-up crossover plate speed. The basic half is a special one for Xiao Yi and Yu Yiyin because of 10% of the physical layer and poles, and the main body} one of them (IR is, the current working electricity is leaked to the pole inverse two, obstacles) B screen (V-base voltage special electricity Xiao Kuai has always been used in the reverse of the collection: extremely uniform (IF second question> ^ (rate question electric FV voltage ^ 6- ^ 9 to 'II and Figure 1 shows the other of the prior art A brief cross-sectional view of a Schottky barrier contact structure, in which a P + diffusion protection ring 05 is formed through a diffusion window (not shown) formed between two forming field oxide layers 102a. Within a designed surface portion of an η- / n + epitaxial semiconductor substrate 101/100; a metal silicide layer 103 is formed on the P + diffusion as a Schottky contact metal layer system. Guard ring 105 and an exposed n — / n + epitaxy surrounded by a shaped step boron glass (BSG) layer 106a On the surface of the semiconductor substrate 101/100; a forming metal layer 10 "is formed on a part of the forming field oxide layer 10a, and the forming step <

1232591 五、發明說明(2) 1 0 6 a及該金屬矽化物層1 0 3之上;以及一個背邊金屬層(未 圖示)作為一個歐姆接觸金屬層係形成於該η +半導體基板 1 0 0 之上。 因此,本發明的一個主要目的係提供一種蕭 特基屏障接觸結構及其製造方法來改進先前技術的缺點。 這裡可以清楚地看到,圖一所示之該蕭特基屏障二極 體的製造需要三個罩幕光阻步驟,其中一個第一罩幕光阻 步驟係用來定義該ρ +擴散保護環的一個擴散窗;一個第二 罩幕光阻步驟係用來去除該成形場氧化物層1 0 2 a (未圖示) 及該步階硼玻璃層1 0 6 a 的一部份來形成該金屬矽化物層 1 03 ;以及一個第三罩幕光阻步驟係用來形成該成形金屬 層1 0 4 a 。很明顯地,利用一種溼式蝕刻溶液(例如緩衝氫 氟酸)來同時去除該成形場氧化物層1 0 2 a 及該步階硼玻璃 層106 (未圖示)而不產生嚴重下部掏空(undercut)係相當 的困難。相似地,利用非等向乾式蝕刻法來同時去除該成 形場氧化物層1 0 2 a 及該步階硼玻璃層1 0 6 a 而不產生該p + 保護環及該暴露半導體基板1 0 1 / 1 0 0 的嚴重槽刻係相當 不容易。因此,利用溼式蝕刻法之該擴散窗的寬度必需保 持較大的尺寸(大於或等於1 0微米)而利用非等向乾式蝕刻 法之該P+擴散保護環105 的接面深度必需保持較深(大於 或等於2微米)。因而該蕭特基屏障二極體細胞元尺寸將變 大且對於一個指定的崩潰電壓而言,其雜散串聯電阻將增 力口0 因此,本發明的一個主要目的係提供一種自動對準蕭 特基屏障接觸結構具有一個最小化擴散保護環面積及一個1232591 V. Description of the invention (2) 1 0 6 a and the metal silicide layer 10 3; and a back metal layer (not shown) is formed on the η + semiconductor substrate 1 as an ohmic contact metal layer system. 0 0 above. Therefore, a main object of the present invention is to provide a Schottky barrier contact structure and a method of manufacturing the same to improve the disadvantages of the prior art. It can be clearly seen here that the fabrication of the Schottky barrier diode shown in Figure 1 requires three mask photoresist steps, one of which is the first mask photoresist step to define the ρ + diffusion protection ring. A diffusion window; a second mask photoresist step is used to remove the forming field oxide layer 1 0 2 a (not shown) and a part of the step boro glass layer 10 6 a to form the The metal silicide layer 103 and a third mask photoresist step are used to form the shaped metal layer 104a. Obviously, a wet etching solution (such as buffered hydrofluoric acid) is used to remove the forming field oxide layer 10 2 a and the step boron glass layer 106 (not shown) at the same time without serious undercutting. (Undercut) is quite difficult. Similarly, an anisotropic dry etching method is used to remove the forming field oxide layer 1 2 a and the step boro glass layer 1 0 6 a simultaneously without generating the p + guard ring and the exposed semiconductor substrate 1 0 1 The severe groove engraving of / 100 is not easy. Therefore, the width of the diffusion window using the wet etching method must be kept larger (10 micrometers or more) and the junction depth of the P + diffusion guard ring 105 using the non-isotropic dry etching method must be kept deep. (Greater than or equal to 2 microns). Therefore, the size of the Schottky barrier diode cell will become larger and its stray series resistance will increase to 0 for a specified breakdown voltage. Therefore, a main object of the present invention is to provide an automatic alignment Tactical barrier contact structure has a minimized diffusion guard ring area and a

1232591 五、發明說明(3) 最大化細胞元面積。 本發明的另一個目的係提供一種自動對準蕭特基屏障 接觸結構可以藉由最少的罩幕光阻步驟來製造。 本發明的一個進一步目的係提供種自動對準蕭特基屏 障接觸結構具有較佳的金屬步階覆蓋及一個已知崩潰電壓 下的較小串聯電阻。 【發明内容】 本發明揭示一種自動對準蕭特基屏障接觸結構及其製 造方法。該自動對準蕭特基屏障接觸結構至少包含一種第 一導電型的一個半導體基板具有一個淡摻雜磊晶半導體層 形成於一個高摻雜半導體基板之上;一種第二導電型的一 個擴散保護環藉由一個第一側邊牆介電墊層所定義的一個 離子佈植窗來形成,以及一個蕭特基接觸金屬層至少形成 於一個第二側邊牆介電墊層所包圍之一個暴露的半導體表 面之上。上述之第一側邊牆介電塾層係於一個介電層形成 於一個成形場氧化物層及一個熱二氧化矽層置於該擴散保 護環的一部份表面之上或係一個複合介電層置於一個成形 場氧化物層及該擴散保護環的一部份表面之上所形成的一 個外緣側邊牆之上。上述之離子佈植窗係形成於該介電層 或該複合介電層與該第一側邊牆介電墊層所包圍的一個罩 幕介電層之上。上述之第二側邊牆介電墊層由氮化矽或氧1232591 V. Description of the invention (3) Maximize the cell area. Another object of the present invention is to provide an auto-aligned Schottky barrier contact structure that can be fabricated with a minimum number of mask photoresist steps. A further object of the present invention is to provide an auto-aligned Schottky barrier contact structure with better metal step coverage and a smaller series resistance at a known breakdown voltage. SUMMARY OF THE INVENTION The present invention discloses an automatic alignment Schottky barrier contact structure and a manufacturing method thereof. The self-aligning Schottky barrier contact structure includes at least a semiconductor substrate of a first conductivity type having a lightly doped epitaxial semiconductor layer formed on a highly doped semiconductor substrate; a diffusion protection of a second conductivity type It is formed by an ion implanted window defined by a first side wall dielectric pad, and a Schottky contact metal layer is formed on at least one exposed surrounded by a second side wall dielectric pad. Semiconductor surface. The above-mentioned first side wall dielectric hafnium layer is formed by a dielectric layer formed on a forming field oxide layer and a thermal silicon dioxide layer on a part of the surface of the diffusion protection ring or a composite dielectric. The electric layer is placed on an outer side wall formed on a forming field oxide layer and a part of the surface of the diffusion protection ring. The above-mentioned ion implanted window is formed on a mask dielectric layer surrounded by the dielectric layer or the composite dielectric layer and the first side wall dielectric pad layer. The second side wall dielectric pad is made of silicon nitride or oxygen.

1232591 五、發明說明(4) 氮化矽所組成係形成於該成形場氧化物層的該内緣側邊牆 之上且置於該熱二氧化矽層之上或該第二側邊牆介電墊由 二氧化矽所組成係形成於該介電層或該複合介電層的一部 份表面之上。上述之擴散保護環至少包含一個中度摻雜擴 散保護環或一個高摻雜擴散保護環。上述之自動對準蕭特 基屏障接觸結構可以藉由二個罩幕光阻步驟來製造,而該 擴散保護環的寬度可以藉由該第一側邊牆介電墊層來控制 成很小。 【實施方式】 現請參見圖二A至圖二G,其中揭示製造本發明之一種 第一型自動對準蕭特基屏障接觸結構的製程步驟及其簡要 剖面圖。 圖二A顯示一個場氧化物層2 0 2係形成於一種第一導電 型的一個半導體基板201/200之上,其中上述之半導體基 板2 0 0 / 2 0 1至少包含一個淡摻雜磊晶半導體層201置於一個 高摻雜半導體基板2 0 0之上。該場氧化物層2 0 2係一個熱二 氧化石夕層藉由一個水蒸氣環境或一個溼氧環境來成長,一 個摻雜二氧化矽層藉由化學氣相堆積(C V D ) 法來堆積,及 一個CVD 二氧化石夕層形成於一個熱二氧化石夕層之上,其厚 度係介於6 0 0 0 埃和1 0 0 0 0埃之間。該淡摻雜磊晶矽層2 0 1 之内的摻雜質濃度係介於1 014/立方公分和1 017 /立方公分之1232591 V. Description of the invention (4) The silicon nitride composition is formed on the inner side wall of the forming field oxide layer and is placed on the thermal silicon dioxide layer or the second side wall. The electrical pad is composed of silicon dioxide and is formed on a part of the surface of the dielectric layer or the composite dielectric layer. The above-mentioned diffusion guard ring includes at least a moderately doped diffusion guard ring or a highly doped diffusion guard ring. The above-mentioned self-aligned Schottky barrier contact structure can be manufactured by two mask photoresist steps, and the width of the diffusion protection ring can be controlled to be small by the first side wall dielectric cushion layer. [Embodiment] Referring now to FIGS. 2A to 2G, the process steps for manufacturing a first type of self-aligning Schottky barrier contact structure of the present invention and a brief cross-sectional view thereof are disclosed. FIG. 2A shows that a field oxide layer 2 0 2 is formed on a semiconductor substrate 201/200 of a first conductivity type, wherein the semiconductor substrate 2 0 0/2 0 1 includes at least one lightly doped epitaxy. The semiconductor layer 201 is placed on a highly doped semiconductor substrate 2000. The field oxide layer 202 is a thermal dioxide layer grown by a water vapor environment or a wet oxygen environment, and a doped silicon dioxide layer is deposited by a chemical vapor deposition (CVD) method. And a CVD dioxide layer is formed on a thermal dioxide layer, and its thickness is between 60 Angstroms and 100 Angstroms. The dopant concentration within the lightly doped epitaxial silicon layer 2 0 1 is between 1 014 / cm 3 and 1 017 / cm 3

第10頁 1232591 五、發明說明(5) 間而磊晶層厚度係介於3微米和3 5微米之間,並依所指定 的崩潰電壓來決定。該高摻雜半導體基板2 0 0的摻雜質濃 度係介於1019/立方公分和5 X 102。/立方公分之間,而其厚 度係依照晶圓的尺寸大小來決定。該磊晶半導體基板2 0 1 / 2 0 0可以由其他半導體材料來取代,諸如砷化鎵(GaAs)或 碳化矽(SiC), 而該場氧化物層2 0 2可以是CVD法所堆積之 一個二氧化矽層。 圖二B顯示進行一個第一罩幕光阻(PR1)步驟(未圖示) 來定義一個主動區間(A A ),而該主動區之内的該場氧化物 層2 0 2係利用溼式蝕刻法或非等向乾式蝕刻法加予去除;然 後,去除該第一罩幕光阻(PR1)。 ’ 圖二C顯示一個熱二氧化矽層2 〇 3 係形成於一個暴露 ,半導體基板201/200之上,然後一個介電層204係形成於 f成形場氧化物層2 〇 2 a及該熱二氧化矽層2 0 3之上;接著, 2 0 4個、第一側邊踏介電塾層(S P a C 6 Γ ) 2 〇 $ a係形成於該介電層 面的一個内緣側邊牆之上且置於該介電層2 〇 4的一部份表 厚。該熱二氧化矽層2〇3係藉由乾氧氧化來形成且^ 矽ί,介於1〇〇埃和5 0 0埃之間。該介電層2 0 4係一個氮;[匕 於1"〇〇埃利用低壓氣相堆積法(LPCVD)來堆積,其厚度係介 氧化石夕%和5 〇〇埃之間。該第一側邊牆介電墊層20 5 a係由二 先堆積用低壓化學氣相(LPCVD)法來堆積,係 之上再二:::層:(未圖示)於所形成的結構表面 圖一 、之一乳化矽層205的一個厚度。 —,、、、不一個罩幕介電層2 0 6 a係填該第一侧邊牆介Page 10 1232591 V. Description of the invention (5) The thickness of the epitaxial layer is between 3 microns and 35 microns, and it is determined according to the specified breakdown voltage. The doped concentration of the highly doped semiconductor substrate 2000 is between 1019 / cm 3 and 5 × 102. / Cubic centimeter, and its thickness is determined according to the size of the wafer. The epitaxial semiconductor substrate 20 1/2 0 0 can be replaced by other semiconductor materials, such as gallium arsenide (GaAs) or silicon carbide (SiC), and the field oxide layer 202 can be deposited by a CVD method. A layer of silicon dioxide. FIG. 2B shows that a first mask photoresist (PR1) step (not shown) is performed to define an active region (AA), and the field oxide layer 2 0 2 in the active region uses wet etching. Removal is performed by a method or an anisotropic dry etching method; then, the first mask photoresist (PR1) is removed. '' Figure 2C shows that a thermal silicon dioxide layer 203 is formed on an exposed semiconductor substrate 201/200, and then a dielectric layer 204 is formed on the f-shaped field oxide layer 〇2a and the thermal Above the silicon dioxide layer 203; then, 204, the first side stepped on the dielectric hafnium layer (SP a C 6 Γ) 2 〇 $ a is formed on an inner edge side of the dielectric layer A portion of the surface thickness of the dielectric layer 204 above the wall. The thermal silicon dioxide layer 203 is formed by dry oxygen oxidation and the silicon is between 100 angstroms and 500 angstroms. The dielectric layer 204 is a nitrogen layer, and is deposited using a low pressure vapor deposition method (LPCVD) with a thickness of between about 100% and 500 angstroms. The first side wall dielectric pad layer 20 5 a is deposited by two low-pressure chemical vapor phase (LPCVD) deposition methods, and the second one is deposited on the structure: (layer) (not shown) on the formed structure. One of the surface figures I and E emulsifies a thickness of the silicon layer 205. — ,,,, and not a cover dielectric layer 2 0 6 a is filled with the first side wall dielectric

第11頁 1232591 五、發明說明(6) 電墊層205a所包圍的一個空隙。該罩幕介電層206a係一個 光阻層2 0 6 (未圖示),係將一個光阻層2 0 6塗於該半導體基 板201/200之上再回餘該光阻層206至一個所預定的'個各 度。這裡值得注意的是,其他流體材料亦可用來取代該光 阻層 206a,諸如(polyimide)。 圖二E 顯示該第一侧邊踏介電墊層2 0 5 a係利用緩衝氫 氟酸來加以去除;接著,以自動對準的方式進行離子佈植 並將一種第二導電型的1摻雜質跨過該介電層204置於該熱 二氧化矽層203於該半導體基板201/200的一個表面部份來 形成一個離子佈植層形2 〇 7。Page 11 1232591 V. Description of the invention (6) A gap surrounded by the electric cushion layer 205a. The mask dielectric layer 206a is a photoresist layer 206 (not shown), and a photoresist layer 206 is coated on the semiconductor substrate 201/200 and then the photoresist layer 206 is left to a The predetermined 'degrees. It is worth noting here that other fluid materials can be used to replace the photoresist layer 206a, such as (polyimide). FIG. 2E shows that the first side stepping dielectric pad layer 2 0 5 a is removed using buffered hydrofluoric acid; then, ion implantation is performed in an automatic alignment manner and a second conductivity type 1 is doped. Impurities are placed across the dielectric layer 204 on the thermal silicon dioxide layer 203 on a surface portion of the semiconductor substrate 201/200 to form an ion implanted layer shape 207.

圖一 F顯示該罩幕介電層2 〇 6 a係被去除,然後進行一 個雜質驅入製成來形成一個擴散保護環2 〇 7 a。這裡值得注 意=是’該擴散保護環2〇7a可以是中度(m〇derately)摻雜 或南(hea vi ly)摻雜且其接面深度係介於〇· 3微米和3微米 之間。 少 圖二/顯示該介電層2 係利用熱磷酸來加以去除;然Fig. 1F shows that the mask dielectric layer 2 06 a is removed, and then an impurity drive-in is performed to form a diffusion protection ring 2 07 a. It is worth noting here = Yes' The diffusion guard ring 207a can be moderately doped or hea vily doped and its junction depth is between 0.3 microns and 3 microns . Less Figure 2 / shows that the dielectric layer 2 is removed using hot phosphoric acid;

後’一個第二側邊牆介電墊層2 〇8a係形成於該成型場氧化 物層20 2 a的一個内緣側邊牆之上且置於該熱二氧化矽層 2 0 的一部份表面之上;該第二側邊牆介電墊層2 〇 8 &所包圍 的該熱二氧化矽層係利用濕式蝕刻法來加以去除;一個蕭 特基接觸金屬層2 0 9 a係形成於該第二側邊牆介電墊層2 〇 8 a 圍的一個暴露半導體表面之上;接著,一個成形金屬 層210a係形成於該成形場氧化物層2〇2a、該第二側邊牆介The rear side of a second side wall dielectric cushion layer 2 0a is formed on an inner edge side wall of the molding field oxide layer 20 2 a and is placed on a part of the thermal silicon dioxide layer 20. Over the surface; the thermal silicon dioxide layer surrounded by the second side wall dielectric pad layer 2 0 & is removed by wet etching; a Schottky contact metal layer 2 0 9 a Is formed on an exposed semiconductor surface surrounded by the second side wall dielectric pad layer 208a; then, a forming metal layer 210a is formed on the forming field oxide layer 202a, the second side Side wall

第12頁 1232591 五、發明說明(7) 電墊層208a及該蕭特基接觸金屬層209a之上,且藉由一個 第二罩幕光阻(PR 3 ) 步驟(未圖示)來形成。該第二側邊牆 介電墊層208a由氮化石夕或氧氮化石夕(oxynitride)所組成, 係先堆積一個氮化矽或氧氮化矽(未圖示)於一個所形成的 結構表面之上,再回蝕該堆積之氮化矽或氧氮化矽層2 0 8 的一個厚度。該蕭特基接觸金屬層209a至少包含一個金屬 矽化物層藉由一種習知自動對準矽化製程來形成。一個耐 高溫(refractroy)金屬層(未圖示)可以形成於所形成的結 構表面之上來取代該金屬矽化物層209a且與金屬層210來 同時成形。該成形金屬層2 1 0 a係一個銀(A g )、紹(A 1 )或金 (Au)置於一個障礙金屬(barrier metal)之上。 由圖二A至圖二G可以清楚的看到,本發明之第一型自 動對準蕭特基屏障接觸結構可以僅藉由二個罩幕光阻步驟 來製造,該擴散保護環2 0 7 a的寬度藉由該第一側邊牆介電 墊層2 0 5 a來定義係可以控制比一個所使用技術的最小線寬 還小。另外,該擴散保護環2 0 7 a具有一個淺接面及一個相 對低及斜坡雜質分佈可以消除接面曲率效應對崩潰電壓的 影響,而一個已知順向電流之下的順向電壓可以經由較小 的雜散串聯電阻來降低。 現請參見圖三A及圖三B,其中揭示製造本發明之一種 第二型自動對準蕭特基屏障接觸結構之接續圖二F的製程 步驟及其簡要剖面圖。 圖三A顯示一個第二側邊牆介電墊層2 0 8 a 係形成於該 介電層204之上且置於該介電層204 的一部份表面之上;該Page 12 1232591 V. Description of the invention (7) The electric pad layer 208a and the Schottky contact metal layer 209a are formed through a second mask photoresist (PR3) step (not shown). The second side wall dielectric pad layer 208a is composed of nitride nitride or oxynitride. A silicon nitride or silicon oxynitride (not shown) is first deposited on a structured surface. Then, a thickness of the stacked silicon nitride or silicon oxynitride layer 2 0 8 is etched back. The Schottky contact metal layer 209a includes at least one metal silicide layer formed by a conventional auto-aligned silicide process. A refractroy metal layer (not shown) may be formed on the surface of the formed structure to replace the metal silicide layer 209a and be formed simultaneously with the metal layer 210. The formed metal layer 2 1 0 a is made of silver (A g), sau (A 1) or gold (Au) on a barrier metal. It can be clearly seen from FIGS. 2A to 2G that the first type of self-aligning Schottky barrier contact structure of the present invention can be manufactured by only two mask photoresist steps. The diffusion protection ring 2 0 7 The width of a is defined by the first side wall dielectric pad 2 0 5 a, which can be controlled to be smaller than the minimum line width of a technology used. In addition, the diffusion guard ring 2 0 7 a has a shallow junction and a relatively low and slope impurity distribution to eliminate the impact of the curvature of the junction on the collapse voltage, and a forward voltage under a known forward current can be passed Smaller stray series resistance to reduce. Please refer to FIG. 3A and FIG. 3B, which illustrate the manufacturing steps and a schematic cross-sectional view of FIG. FIG. 3A shows that a second side wall dielectric cushion layer 2 0 8 a is formed on the dielectric layer 204 and is disposed on a part of the surface of the dielectric layer 204;

1232591 五、發明說明(8) 介電層2 0 4置於該成形場氧化物層2 0 2 a 之上及位於該第二 側邊牆介電墊層2 0 8 a所包圍的一個地區係藉由非等向乾式 蝕刻法或熱磷酸加予去除;接著,該第二側邊牆介電墊層 2 0 8 a所包圍的該熱二氧化矽層2 〇 3 係利用緩衝氫氟酸或稀 釋氫氟酸來加予去除。該第二側邊牆介電塾層2 0 8 a係由二 氧化矽所組成且利用LPCVD法來堆積。 圖三B顯示一個蕭特基屏障接觸金屬層2 0 9 a係形成於 該第二側邊牆介電墊層208a所包圍的一個暴露半導體表面 之上;然後,一個成形金屬層2 1 0a 係形成於該成形場氧化 物層202a的一部份表面、該介電層2〇4a的一部份表面、該 第二側邊牆介電墊層2 0 8 a及該蕭特基屏障接觸金屬層2 0 9 a 之上。該蕭特基屏障接觸金屬層2〇9a及該成形金屬層21〇a 係於圖二G所討論的一樣。比較圖二g及圖三B, 該第二型 自動對準蕭特基屏障接觸結構係予該第一型自動對準蕭特 基屏障接觸結構相似,因此其特色及優點係予該第一型自 動對準蕭特基屏障接觸結構所描述的一樣。 這裡值得注意的是,圖二C所示之該熱二氧化矽層可 以利用一個襯(1 i ne r )二氧化矽層(未圖示)形成於該成形 場氧化物層2 0 2 a及由該成形場氧化物層2 0 2 a所包圍之該暴 露半導體基板201/200之上。因此,圖二G所示之該第二側 邊牆介電層2 0 8 a置於該熱二氧化矽層2 〇 3 a之上可以利用該 第二側邊牆介電墊層2 0 8a襯(1 i ned)有一個襯二氧化矽層; 圖二B所示之該介電層204a形成於該成型場氧化物層2〇2a 的一個内緣側邊牆之上且置於該熱二氧化矽層2 〇 3 a之上可1232591 V. Description of the invention (8) A dielectric layer 2 0 4 is placed on the forming field oxide layer 2 0 2 a and is located in a region surrounded by the second side wall dielectric pad layer 2 8 a It is removed by non-isotropic dry etching or hot phosphoric acid. Next, the thermal silicon dioxide layer 2 0 3 surrounded by the second side wall dielectric pad 2 0 a is buffered hydrofluoric acid or Hydrofluoric acid was diluted to remove it. The second side wall dielectric hafnium layer 2 0 8 a is composed of silicon dioxide and is deposited by the LPCVD method. FIG. 3B shows that a Schottky barrier contact metal layer 209a is formed on an exposed semiconductor surface surrounded by the second side wall dielectric pad layer 208a; then, a shaped metal layer 210a system is formed. Formed on a portion of the surface of the forming field oxide layer 202a, a portion of the surface of the dielectric layer 204a, the second side wall dielectric pad layer 2 0a, and the Schottky barrier contact metal Layer 2 0 9 a. The Schottky barrier contact metal layer 209a and the formed metal layer 21a are as discussed in FIG. 2G. Comparing Figure 2g and Figure 3B, the second type of self-aligning Schottky barrier contact structure is similar to the first type of self-aligning Schottky barrier contact structure, so its features and advantages are similar to the first type. The auto-alignment Schottky barrier contact structure is as described. It is worth noting here that the thermal silicon dioxide layer shown in FIG. 2C can be formed on the forming field oxide layer 2 0 a with a liner (1 i ne r) silicon dioxide layer (not shown) and Above the exposed semiconductor substrate 201/200 surrounded by the field oxide layer 2 0 2 a. Therefore, the second side wall dielectric layer 2 0 8 a shown in FIG. 2G is placed on the thermal silicon dioxide layer 2 0 3 a to use the second side wall dielectric pad layer 2 8 a The liner (1 i ned) has a silicon dioxide liner; the dielectric layer 204a shown in FIG. 2B is formed on an inner edge side wall of the molding field oxide layer 202a and is placed on the heat Silicon dioxide layer

第14頁 1232591 五、發明說明(9) 以利用該介電層2 0 4 a襯有一個襯二氧化矽層來取代該襯氧 化矽層2 0 3。該襯二氧化矽層2 0 3 係由L P C V D或高溫氧化物 (Η T 0 )堆積法來形成。 基於此,本發明之該自動對準蕭特基屏障接觸結構的 特色及優點可以歸納如下: (a) 本發明之該自動對準蕭特基屏障接觸結構可以利 用兩個罩幕光阻步驟來製造。 (b ) 本發明之該自動對準蕭特基屏障接觸結構提供由 一個第一側邊牆介電墊層所定義的一個擴散保護環來縮小 由該擴散保護環所佔有之表面面積且因此提供最佳化的有 效表面面積來形成一個蕭特基屏障金屬接觸。 (c ) 本發明之該自動對準蕭特基屏障接觸結構提供一 個第二側邊牆介電墊層來改進金屬步階覆蓋。 (d) 本發明之該自動對準蕭特基屏障接觸結構提供一 個擴散保護環具有一個淺接面深度及一個相對低及斜坡摻 雜質分佈來消除接面曲率效應對崩潰電壓的影響且在一個 已知順向電流之下的順向電壓。 本發明雖特別以參考所附的例子或内涵來圖示及描述 ,但僅是代表陳述而非限制。再者,本發明不侷限於所列 之細節,對於熟知此種技術的人亦可瞭解,各種不同形狀 或細節的更動在不脫離本發明的真實精神和範缚下均可製 造,但亦屬本發明的範缚。Page 14 1232591 V. Description of the invention (9) The dielectric oxide layer 204 is lined with a silicon dioxide-lined silicon layer to replace the silicon oxide-lined silicon layer 203. The silicon dioxide-lined layer 203 is formed by a L P C V D or high temperature oxide (Η T 0) deposition method. Based on this, the features and advantages of the self-aligning Schottky barrier contact structure of the present invention can be summarized as follows: (a) The self-aligning Schottky barrier contact structure of the present invention can use two mask photoresist steps to Manufacturing. (b) The self-aligning Schottky barrier contact structure of the present invention provides a diffusion protection ring defined by a first side wall dielectric cushion to reduce the surface area occupied by the diffusion protection ring and thus provides Optimize the effective surface area to form a Schottky barrier metal contact. (c) The self-aligned Schottky barrier contact structure of the present invention provides a second side wall dielectric pad to improve metal step coverage. (d) The self-aligning Schottky barrier contact structure of the present invention provides a diffusion guard ring with a shallow junction depth and a relatively low and sloped dopant distribution to eliminate the impact of the junction curvature effect on the breakdown voltage and A forward voltage below a known forward current. Although the present invention is particularly illustrated and described with reference to the attached examples or connotations, it is only a representative statement and not a limitation. Furthermore, the present invention is not limited to the details listed, and those skilled in the art can also understand that changes of various shapes or details can be made without departing from the true spirit and scope of the present invention, but also belong to the present invention. Fans of invention.

第15頁 1232591 圖式簡單說明 圖一顯示先前技術之一種蕭特基屏障接觸結構具有一 個擴散保護環的一個簡要剖面圖。 圖二A至圖二G揭示製造本發明之一種第一型自動對準 蕭特基屏障接觸結構的製程步驟及其簡要剖面圖。 圖三A及圖三B揭示製造本發明之一種第二型自動對準 蕭特基屏障接觸結構之接續圖二F 的製程步驟及其簡要剖 面圖。 代表圖號說明: 200 而 摻 雜 半 導 體 基 板 20 1 202 場 氧 化 物 層 2 0 2a 203 軌 二 氧 化 矽 層 2 0 3a 204 介 電 層 2 0 4a 2 0 5 a 第 一 側 邊 牆 介 電 塾 層 2 0 6a 207 離 子 佈 植 區 2 0 7a 208 第 二 側 邊 牆 介 電 塾 層 2 0 9a 2 10 金 屬 層 210a 層 體層 導層碎 半物化 晶化氧層層 蟲氧二電電 雜場熱介介 摻形形形幕 淡成成成罩Page 15 1232591 Brief Description of Drawings Figure 1 shows a schematic cross-sectional view of a prior art Schottky barrier contact structure with a diffusion guard ring. Figures 2A to 2G disclose the manufacturing steps and a schematic cross-sectional view of the first type of self-aligning Schottky barrier contact structure of the present invention. Fig. 3A and Fig. 3B show the manufacturing steps and a schematic cross-sectional view of Fig. 2F, which are subsequent to Fig. 2F, for manufacturing a second type of self-aligning Schottky barrier contact structure of the present invention. Representative drawing number description: 200 and doped semiconductor substrate 20 1 202 field oxide layer 2 0 2a 203 track silicon dioxide layer 2 0 3a 204 dielectric layer 2 0 4a 2 0 5a 2 0 6a 207 Ion-implanted area 2 0 7a 208 Dielectric layer of the second side wall 2 0 9a 2 10 Metal layer 210a Layer body layer conductive layer Fractured semi-crystalline crystalline oxygen layer Insect oxygen secondary electric field hybrid Folded curtain into a mask

環 護 保 散 擴 P 層 屬 金 觸層 接屬 基金 特形 蕭成Environmental protection, protection and expansion, P layer, metal contact layer, fund connection, special shape, Xiao Cheng

第16頁Page 16

Claims (1)

1232591 六、申請專利範圍 1. 一種自動對準蕭特基屏障接觸結構,至少包含: 一種第一導電型的一個半導體基板,其中該半導體基 板至少包含一個淡摻雜磊晶半導體層形成於一個高摻雜半 導體基板之上; 一種第二導電型的一個擴散保護環透過由一個第一側 邊牆介電墊層所定義的一個離子佈植窗形成於該半導體基 板之一個所設計的表面部份之内,其中該第一側邊牆介電 墊層係形成於一個介電層置於一個成型場氧化物層及由該 成型場氧化物層所包圍之一個熱二氧化矽層置於該半導體 基板之上的一個内緣側邊牆之上; 一個蕭特基接觸金屬層至少形成於由一個第二側邊牆 介電墊層所包圍的該擴散保護環及該半導體基板之上擴; 以及 一個成形金屬層至少形成於該成形場氧化物層的一部 份表面、該第二側邊牆介電墊層及該蕭特基接觸金屬層之 上。 2 . 如申請專利範圍第1項所述之自動對準蕭特基屏障接觸 結構,其中上述之第一侧邊牆介電墊層由二氧化矽所組成 且利用低壓化學氣相堆積(LP CV D ) 法來製造而該介電層係 由氮化矽所組成且利用LPCVD法來堆積。 3. 如申請專利範圍第1項所述之自動對準蕭特基屏障接觸 結構,其中上述之第二側邊牆介電墊層由氮化矽或氧氮化1232591 VI. Scope of patent application 1. An auto-aligned Schottky barrier contact structure including at least: a semiconductor substrate of a first conductivity type, wherein the semiconductor substrate includes at least a lightly doped epitaxial semiconductor layer formed on a high Doped on a semiconductor substrate; a diffusion protection ring of a second conductivity type is formed on a designed surface portion of the semiconductor substrate through an ion implantation window defined by a first side wall dielectric pad Within the first side wall dielectric pad layer, a dielectric layer is formed on a molding field oxide layer, and a thermal silicon dioxide layer surrounded by the molding field oxide layer is disposed on the semiconductor. On an inner edge side wall above the substrate; a Schottky contact metal layer is formed on at least the diffusion protection ring and the semiconductor substrate surrounded by a second side wall dielectric cushion layer; and A forming metal layer is formed on at least a part of the surface of the forming field oxide layer, the second side wall dielectric pad layer, and the Schottky contact metal layer. 2. The self-aligning Schottky barrier contact structure described in item 1 of the scope of the patent application, wherein the first side wall dielectric pad is composed of silicon dioxide and uses low pressure chemical vapor deposition (LP CV D) and the dielectric layer is composed of silicon nitride and is deposited using the LPCVD method. 3. The self-aligned Schottky barrier contact structure described in item 1 of the scope of the patent application, wherein the second side wall dielectric pad layer is made of silicon nitride or oxynitride 第17頁 1232591 六、申請專利範圍 矽所組成且利用LPCVD 法來製造係形成於該成型氧化物層 的一個内緣側邊牆之上且置於該熱二氧化石夕層的一部份表 面之上。 4. 如申請專利範圍第1項所述之自動對準蕭特基屏障接觸 結構,其中上述之第二側邊牆介電墊層由二氧化矽所組成 且利用L P C V D 法來製造係形成於該介電層置於該成型場氧 化物層之上且置於該熱二氧化矽層的一個部份表面之上。 5. 如申請專利範圍第1項所述之自動對準蕭特基屏障接觸 結構,其中一個罩幕介電層至少包含一個罩幕光阻成或一 個(ρ ο 1 y n i d e )成係形成於由該第一側邊牆介電墊層所包圍 的該介電層之上以作為一個蝕刻罩幕來選擇性地去除該第 一側邊牆介電墊層以形成該離子佈植窗。 6. 如申請專利範圍第1項所述之自動對準蕭特基屏障接觸 結構,其中上述之擴散保護環至少包含一個中度摻雜擴散 保護環或一個高摻雜擴散保護環具有一個斜坡雜質分佈。 7. —種自動對準蕭特基屏障接觸結構,至少包含: 一種第一導電型的一個半導體基板,其中該半導體基 板至少包含一個淡摻雜磊晶半導體層形成於一個高摻雜半 導體基板之上; 一種第二導電型的一個擴散保護環透過由一個第一測Page 171232591 VI. Scope of Patent Application Silicon is formed by using LPCVD to form a part of the surface of an inner edge side wall of the forming oxide layer and placed on the thermal dioxide layer Above. 4. The self-aligning Schottky barrier contact structure described in item 1 of the scope of the patent application, wherein the second side wall dielectric pad layer is composed of silicon dioxide and is formed by using a LPCVD method. A dielectric layer is placed over the field oxide layer and over a portion of the surface of the thermal silicon dioxide layer. 5. The self-aligned Schottky barrier contact structure described in item 1 of the scope of patent application, wherein a mask dielectric layer includes at least one mask photoresist or one (ρ ο 1 ynide) system formed by The first side wall dielectric pad is surrounded by the dielectric layer as an etching mask to selectively remove the first side wall dielectric pad to form the ion implanted window. 6. The self-aligning Schottky barrier contact structure described in item 1 of the scope of the patent application, wherein the above-mentioned diffusion guard ring includes at least a moderately doped diffusion guard ring or a highly doped diffusion guard ring with a slope impurity distributed. 7. An auto-aligned Schottky barrier contact structure, comprising at least: a semiconductor substrate of a first conductivity type, wherein the semiconductor substrate comprises at least a lightly doped epitaxial semiconductor layer formed on a highly doped semiconductor substrate A diffusion protection ring of a second conductivity type is transmitted through a first measurement 第18頁 1232591 六、申請專利範圍 邊牆介電墊層所定義之一個離子佈植窗來形成於該半導體 基板的一個所設計的一個表面之内其中該第一側邊牆介電 層係形成於由一個複合介電層形成於一個成形場氧化物層 及由該成型場氧化物層所包圍的該半導體基板之上的一個 内緣側邊牆之上; 一個蕭特基接觸金屬層至少形成於由一個第二測邊牆 介電墊層所包圍的該擴散保護環及該半導體基板之上;以 及 一個成形金屬層形成於該成型場氧化物層的一部份表 面、該複合介電層的一部份表面、該第二側邊牆介電塾層 及該蕭特基接觸金屬層之上。 8. 如申請專利範圍第7項所述之自動對準蕭特基屏障接觸 結構,其中該複合介電層至少包含由LPCVD 法所堆積的一 個氮化矽層至於由L P C V D法或高溫氧化物(Η T 0 )堆積法所堆 積之一個襯二氧化矽層之上。 9. 如申請專利範圍第7項所述之自動對準蕭特基屏障接觸 結構,其中該第一側邊牆介電墊層由二氧化矽所組成且利 用LPC VD 法來堆積係在形成一個罩幕介電層置於該第一側 邊牆介電墊層所包圍之該複合介電層之上後來加以去除以 形成該離子佈植窗。 1 0 .如申請專利範圍第8項所述之自動對準蕭特基屏障接觸Page 181232591 6. Scope of patent application An ion-implanted window defined by a dielectric layer of a side wall is formed within a designed surface of the semiconductor substrate, wherein the first side wall dielectric layer is formed. A Schottky contact metal layer is formed on at least one inner dielectric sidewall formed by a composite dielectric layer on a forming field oxide layer and the semiconductor substrate surrounded by the forming field oxide layer; On the diffusion protection ring and the semiconductor substrate surrounded by a second side wall dielectric pad; and a forming metal layer is formed on a part of the surface of the forming field oxide layer and the composite dielectric layer A portion of the surface, the second side wall dielectric layer, and the Schottky contact metal layer. 8. The self-aligned Schottky barrier contact structure described in item 7 of the scope of the patent application, wherein the composite dielectric layer includes at least one silicon nitride layer deposited by the LPCVD method, and by the LPCVD method or a high temperature oxide ( Η T 0) stacked on a silicon dioxide-lined layer. 9. The self-aligning Schottky barrier contact structure as described in item 7 of the scope of patent application, wherein the first side wall dielectric cushion layer is composed of silicon dioxide and is stacked using the LPC VD method to form a The mask dielectric layer is placed on the composite dielectric layer surrounded by the first side wall dielectric cushion layer and then removed to form the ion implanted window. 10. Automatic alignment of Schottky barrier contacts as described in item 8 of the patent application 第19頁 1232591 六、申請專利範圍 結構,其中上述之罩幕介電層至少包含一個光阻層或一個 (ρ ο 1 y i m i d e ) 層係在透過該離子佈植窗進行離子佈植之後 來加以去除。 1 1 .如申請專利範圍第7項所述之自動對準蕭特基屏障接觸 結構,其中上述之第二側邊牆介電墊層由二氧化矽所組成 且利用LPCVD 來製造係形成於該複合介電層的一個内緣側 邊牆之上且置於該複合介電層的一部份表面之上。 1 2.如申請專利範圍第7項所述之自動對準蕭特基屏障接觸 結構,其中該第二側邊牆介電墊層由氮化矽或氧氮化矽所 組成且利用LPCVD 法來堆積係形成於一個襯二氧化矽層形 成於該成型場氧化物層之上且置於該擴散保護環的一部份 表面之上的該襯二氧化矽層的一部份表面之上的一個内緣 側邊牆之上。 1 3 ·如申請專利範圍第7項所述之自動對準蕭特基屏障接觸 結構,其中上述之蕭特基接觸金屬層至少包含一個耐高溫 金屬層或一個金屬矽化物層藉由一種自動對準矽化製程來 形成。 1 4 ·如申請專利範圍第7項所述之自動對準蕭特基屏障接觸 結構,其中上述之成型場氧化物層至少包含一個熱二氧化 矽層藉由熱氧化該半導體基板於一個蒸氣或濕氧環境下來Page 19, 1232591 6. The scope of the patent application, wherein the above-mentioned mask dielectric layer includes at least one photoresist layer or one (ρ ο 1 yimide) layer after being ion-implanted through the ion-implanted window to be removed. . 1 1. The self-aligning Schottky barrier contact structure as described in item 7 of the scope of the patent application, wherein the second side wall dielectric pad is composed of silicon dioxide and is formed by using LPCVD An inner edge side wall of the composite dielectric layer is placed on a part of the surface of the composite dielectric layer. 1 2. The self-aligning Schottky barrier contact structure described in item 7 of the scope of patent application, wherein the second side wall dielectric pad layer is composed of silicon nitride or silicon oxynitride and is obtained by LPCVD method. A stacking system is formed on a silicon dioxide-lined silicon dioxide-lined layer formed on a portion of the surface of the silicon dioxide-lined layer formed on the molding field oxide layer and on a portion of the surface of the diffusion protection ring. Inside edge side wall. 1 3 · The self-aligning Schottky barrier contact structure described in item 7 of the scope of patent application, wherein the Schottky contact metal layer includes at least one high-temperature-resistant metal layer or a metal silicide layer by an automatic alignment Quasi-silicidation process to form. 1 4 · The self-aligning Schottky barrier contact structure described in item 7 of the scope of the patent application, wherein the above-mentioned field oxide layer includes at least one thermal silicon dioxide layer by thermally oxidizing the semiconductor substrate in a vapor or Wet oxygen down 第20頁 1232591 六、申請專利範圍 成長、一個摻雜二氧化矽層藉由化學氣相堆積(CVD) 法來 堆積或一個摻雜CVD 二氧化矽層置於一個熱二氧化矽層之 1 5 . —種自動對準蕭特基屏障接觸結構,至少包含: 一種第一導電型的一個半導體基板,其中該半導體基 板至少包含一個淡摻雜磊晶半導體層形成於一個高摻雜半 導體基板之上, 一種第二導電型的一個擴散保護環透過由一個第一側 邊牆介電墊層所定義的一個離子佈植窗來形成於該半導體 基板的一個所設計的表面部份之内,其中該第一側邊牆介 電塾層由二氧化石夕所組成係形成於一個二氧化石夕層或一個 複合介電層形成於一個成型場氧化物層及置於由該成形場 氧化物層所包圍之一個熱二氧化矽層或該半導體基板之上 的一個内緣側邊牆之上及一個罩幕介電層係形成於由該第 一側邊牆介電墊層所包圍之該氮化矽層該複合介電層之上 來形成藉由去除該第一側邊牆介電墊層以形成該離子佈植 窗; 一個蕭特基接觸金屬層至少形成於由一個第二側邊牆 介電墊層所包圍的一個暴露半導體表面之上,其中該第二 側邊牆介電墊層由氮化矽或氧氮化矽所組成係形成於該成 形場氧化物層的一個内緣側邊牆之上且置於該熱二氧化矽 層的一個側邊表面之上或由二氧化矽所組成係形成於該氮 化矽層或該複合介電層的一個内緣側邊牆之上且置於該氮Page 20 1232591 6. The scope of the patent application grows, a doped silicon dioxide layer is deposited by chemical vapor deposition (CVD) or a doped CVD silicon dioxide layer is placed on a thermal silicon dioxide layer. A self-aligning Schottky barrier contact structure, including at least: a semiconductor substrate of a first conductivity type, wherein the semiconductor substrate includes at least a lightly doped epitaxial semiconductor layer formed on a highly doped semiconductor substrate A diffusion protection ring of a second conductivity type is formed in a designed surface portion of the semiconductor substrate through an ion implantation window defined by a first side wall dielectric pad. The dielectric layer on the first side wall is composed of dioxide, formed on a stone dioxide layer or a composite dielectric layer, formed on a forming field oxide layer, and placed on the forming field oxide layer. A surrounding thermal silicon dioxide layer or an inner edge side wall over the semiconductor substrate and a mask dielectric layer are formed surrounded by the first side wall dielectric pad layer. The silicon nitride layer is formed on the composite dielectric layer by removing the first side wall dielectric pad layer to form the ion implanted window; a Schottky contact metal layer is formed at least on a second side edge Above an exposed semiconductor surface surrounded by a wall dielectric pad, wherein the second side wall dielectric pad is composed of silicon nitride or silicon oxynitride and is formed on an inner edge of the forming field oxide layer Above the side wall and placed on a side surface of the thermal silicon dioxide layer or composed of silicon dioxide is formed on an inner edge side wall of the silicon nitride layer or the composite dielectric layer. On the nitrogen 第21頁 1232591 六、申請專利範圍 化矽層或該複合介電層的一部份表面之上;以及 一個成形金屬層至少形成於該成形場氧化物層的一部 份表面、該第二側邊牆介電墊層及該蕭特基接觸金屬層之 上。 16. 如申請專利範圍第1 5項所述之自動對準蕭特基屏障接 觸結構,其中上述之罩幕介電層至少包含一個光阻層或一 個(polyimide) 層且透過藉由去除該第一側邊踏介電塾層 所形成的該離子佈植窗來進行離子佈植之後來加以去除而 該複合介電層至少包含一個氮化矽層至於一個襯二氧化矽 層之上。 17. 如申請專利範圍第1 5項所述之自動對準蕭特基屏障接 觸結構,其中該擴散保護環至少包含一個中度摻雜擴散保 護環或一個高摻雜擴散保護環具有一個斜坡摻雜質分佈。 18. 如申請專利範圍第1 5項所述之自動對準蕭特基屏障接 觸結構,其中該蕭特基接觸金屬層至少包含一個耐高溫金 屬層或一個金屬石夕化物層藉由一種自動對準石夕化製程來形 成。 19. 如申請專利範圍第1 5項所述之自動對準蕭特基屏障接 觸結構,其中該成型金屬層至少包含一個銀(Ag)、鋁(A1 ) 或金(Au)層形成於一個障礙金屬層之上且利用一個第二罩Page 211232591 6. Patent application scope: Silicon layer or a part of the surface of the composite dielectric layer; and a forming metal layer is formed on at least a part of the surface of the forming field oxide layer and the second side A dielectric layer on the sidewall and the Schottky contact metal layer. 16. The self-aligning Schottky barrier contact structure described in item 15 of the scope of patent application, wherein the mask dielectric layer includes at least one photoresist layer or one (polyimide) layer and the first layer is removed by removing The ion implantation window formed on the dielectric layer on one side is removed after ion implantation, and the composite dielectric layer includes at least a silicon nitride layer on a silicon dioxide-lined layer. 17. The self-aligning Schottky barrier contact structure described in item 15 of the scope of patent application, wherein the diffusion guard ring includes at least a moderately doped diffusion guard ring or a highly doped diffusion guard ring with a ramp doping Impurity distribution. 18. The self-aligning Schottky barrier contact structure as described in item 15 of the scope of patent application, wherein the Schottky contact metal layer includes at least one high-temperature-resistant metal layer or a metal oxide layer by an automatic alignment It is formed by a quasi-shixi chemical process. 19. The self-aligning Schottky barrier contact structure described in item 15 of the scope of patent application, wherein the formed metal layer comprises at least one silver (Ag), aluminum (A1) or gold (Au) layer formed on an obstacle Over the metal layer with a second cover 第22頁 1232591 六、申請專利範圍 幕光阻步驟來成形。 20. 如申請專利範圍第1 5項所述之自動對準蕭特基屏障接 觸結構,其中該成型場養化物層至少包含一個熱二氧化矽 層藉由熱氧化該半導體基板於一個水蒸氣或濕氧環境來成 長、一個摻雜二氧化矽層藉由CVD法來堆積或一個摻雜CVD 二氧化石夕層置於一個熱二氧化石夕層之上且藉由一個第一罩 幕光阻步驟來成形。Page 22 1232591 VI. Scope of Patent Application Curtain photoresist step to shape. 20. The self-aligning Schottky barrier contact structure as described in item 15 of the patent application scope, wherein the molding field nutrient layer includes at least one thermal silicon dioxide layer by thermally oxidizing the semiconductor substrate to a water vapor or To grow in a wet oxygen environment, a doped silicon dioxide layer is deposited by CVD or a doped CVD SiO2 layer is placed on top of a thermal SiO2 layer and is protected by a first mask Steps to shape. 第23頁Page 23
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CN110379860A (en) * 2019-07-12 2019-10-25 中国科学院合肥物质科学研究院 A method of realizing electric polarization rectifying effect

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110379860A (en) * 2019-07-12 2019-10-25 中国科学院合肥物质科学研究院 A method of realizing electric polarization rectifying effect

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