1230582 A7 B7 五、發明説明（1 ) (請先閲讀背面之注意事項再填寫本頁) 本發明有關農業用劑之漂浮型調合物，更明確地說， 即所謂「大型（jumbo)調合物」，其特徵係不需要任何機 械即可將活性成份施用於稻田，此係藉由投下農業用劑本 身，或是事先包裝於水溶性袋中所製備的農業用劑。 這幾年來，因爲農業工作者人口逐年減少，農業工作 者平均年齡較高，以及務農轉變成副業之故，對於不使用 任何機械以及不必在稻田中行走之需要較少人力的噴灑方 法需求很高。另一方面，因爲社會高度關切農業用劑的環 境影響，所以極需要可以實際容易施用適當數量農業用劑 之農業用劑與噴灑技術，以減少農業用劑自噴灑之田地流 出，亦減少對於噴灑者的不良影響。 在這種情況下，因爲容易噴灑適當用量、於施用時天 候的影響小，農業用劑自噴灑區流出之風險低之’故，近來 所謂「大型（jumbo)調合物」——其特徵係不需要使用任何 機械即可將活性成份施用於稻田，此係藉由投下特定數量 之數個1 0克農業用劑本身，或是投下事先包裝於水溶性 袋內所製備的農業用劑——的發展變得相當受好評。 經濟部智慧財產局員工消費合作社印製 因爲大型（jumbo)調合物之產物可以局部噴灑於稻田 ，所以該產物於稻田中之良好擴散對於功效安定性以及減 少對於稻子的植物毒性而言極爲重要。此外，需要減少活 性成份與輔助用劑對於欲施用農作物以及對於環境的任何 不當影響。此外，以相當低的價格供應安定產物實際上很 重要。 有關大型（jumbo)調合物產物形式，日本專利特許公 氏張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ~ -4- 1230582 A7 _ B7 五、發明説明（2 ) 開公報第 H6- 192004、H6-2] 1 604 與 H 1 1 240803 號中已公 (請先閱讀背面之注意事項再填寫本頁) 告有關形成泡沬調合物，其係藉由結合固態酸與碳酸鹽或 重碳酸鹽，於農業用劑投入水中時所產生的二氧化碳氣體 ，將該農業用劑的活性成份懸浮於水中。此種形成泡沬大 型（jumbo)調合物對於藉由產生二氧化碳氣體在水中擴散 活性成份的擴散作用有特定影響。不過，因爲活性成份局 部殘留在形成泡沬大型（jumbo)調合物已沉入稻田上層土 壤處之故，其對於欲施用之農作物或是之後栽種的農作物 造成植物毒性的風險高。 還有另外實際缺點。換言之，因爲貯存期間該調合產 物中只要包含少量水就很容易引發中和反應，以及該中和 作用所產生的水會刺激此種中和反應，所以該外安裝材料 會被磨穿，而且於實際施用時不再發泡。 經濟部智慧財產局員工消費合作社印製 曰本專利特許公開公報第H1 1- 1402號中，揭示一種 調合物，其特徵係以貯存於包含農業用劑活性成份之顆粒 當中的空氣漂浮至水表面，並於沉入上層土壤之後，隨著 水溶性載體溶解於水中而分散於稻田中，此種調合物的優 點係即使不包裝於水溶性袋中，其散播性亦較小，這是因 爲該產物本身重量重所致。不過，在土壤吸收性高之農業 用劑情況當中，一部分活性成份會殘留在沉入處，因此很 難充分均勻分散。此外，還有許多技術問題。例如，該製 備方法需要特殊技術、水溶性載體會腐蝕用以調合之機器 、需要敏感地控制裝置製備設備室的溫度的濕氣，避免水 溶性載體潮解。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -5- 1230582 A7 B7___ 五、發明説明（3 ) (請先閲讀背面之注意事項再填寫本頁) 在大型（jumbo)調合物當中’ 「漂浮型調合物」之特 徵係於該活性成份分散並溶解於表面水之後’使該活性成 份到達該農作物，並具有下列優良特性。換言之’漂浮型 調合物可以使該活性成份漂浮在遠離上層土壤的水面上’ 其中該上層土壤具有對於所施用農業用劑吸收力強的不良 特性。該活性成份可以迅速分散於水中’藉由水的對流以 及重力，均勻溶解於水中，因此該上層土壤表面仍然保持 均勻狀態。 經濟部智慧財產局員工消費合作社印製 在曰本專利特許公開公報第H8-99803、H 1 0-265302 與H 1 0-287505號中，已揭示使用藉由捏合的粒化方法製 備漂浮型調合物之製備實例。藉由捏合之粒化方法通常用 以製備農業用劑，不過，因爲該方法複雜度以及需要乾燥 處理之故，其成本相當高。以該捏合方法，使用內部具有 大孔的大型顆粒製備漂浮型調合物的情況下，存在一些實 際問題，諸如此等顆粒通過篩網期間毀壞該篩網的風險或 是需要大量水以供捏合。一般來說，使用捏合方法可於存 在黏合劑之下壓製粉末材料，以形成顆粒，因此在使用內 部具有大孔之大型顆粒時，存在毀壞該顆粒結構之風險， 因此會喪失漂浮能力。此外，因乾燥期間所產生的熱，存 在某些實際風險，例如農業用劑的某些活性成份會分解， 產生惡臭，並且喪失界面活性劑之功能。在日本專利特許 公開公報第H 1 1-315004與H6-336403號，以及日本專利 公告弟H3-76281號當中，已揭7^ —些藉由塗覆作用或是 吸收作用，自孔狀物質製備漂浮型調合物之技術。此等方 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ' -- -6 - 1230582 A7 ______B7 五、發明説明（4 ) (請先閲讀背面之注意事項再填寫本頁) 法可以解決捏合方法中所述之缺點。不過，該應用實例中 所述之載體漂浮能力非常高，因此即使噴灑該調配產物後 該活性成份已釋放到水中，該載體留在稻田中的時間很長 。因此，存在因風吹而聚集該載體處附近，該農作物生長 受到抑制的缺點，而且自施用的稻田流出之風險高。 經濟部智慧財產局員工消費合作社印製 在日本專利特許公開公報第H 1 0- 1 09905號中，已揭 示一種可施用於水面上之漂浮型調合物，其係由陰離子界 面活性劑與無機或有機載體組成，而且平均粒徑小於50 微米。在日本專利特許公開公報第H8-99804號中，已揭 示一種可施用於水面上之漂浮型擴散調合物。此種調合物 之特徵係將農業用劑之活性成份保留在水漂浮顆粒架構中 ，以及結合水面擴散劑與分子結構中包含至少一個葡萄糖 殘基之乳化分散劑。在日本專利特許公開公報第H5- 1 557-9號中，已揭示一種可施用於水面上之漂浮型調合物，其 結合陰離子界面活性劑與無機或有機載體，而且平均粒徑 小於50微米。在此等公報當中，提及一些技術的應用實 例，藉由此等技術可以克服上述之技術問題。換言之，可 以達到貯存問題較少、製造機器的損壞較少，而且成本相 當低。此外，似乎可以包含某些技術，以製備因載體殘留 在水面上所致之植物毒性較小以及流出稻田風險低的漂浮 型調合物。 另一方面，平均粒徑小於1 〇〇微米的顆粒具有減少於 釋放活性成份之後該載體殘留在水面的優點。不過，與粗 顆粒相較，每單位重量的面積非常大，因此有形成顆粒黏 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 1230582 A7 _B7_ 五、發明説明（5 ) (請先閲讀背面之注意事項再填寫本頁) 合的傾向。結果，噴灑在稻田水面上之調配產物會長時間 停留在同一處而不會擴散開，妨礙活性成份釋放與均勻分 佈。因此，農業用劑的功效變得不足，而且造成植物毒性 與局部殘留物。 本發明目的在於提供下列調合物。於噴灑之後，該活 性成份可以充分釋放，而且該載體在相當短時間內下沉， 農業用劑可以抵抗顆粒間的內聚力，而在稻田的水面上擴 散開，因此該活性成份迅速釋放於水中。更明確地說，本 發明目的在於提供下列水漂浮型調合物。使用適用之農業 用劑設備，可以簡易方法以及較低廉成本製造彼，其於噴 灑之後具有優越效果，而且對於農作物以及環境的影響較 少，該載體可於相當短時間內下沉。此外，本發明目的在 於提供不必使用機械即可容易噴灑之農業用劑，其係以水 溶性材料（諸如聚乙烯醇膜）包裝上述漂浮型調合物達成此 目的。 經濟部智慧財產局員工消費合作社印製 本發明人觀察到該農業用劑之下列特性，其包含一種 活性成份、平均粒徑在10至100微米範圍內之孔狀載體 、界面活性劑、黏合劑與高吸水性聚合物。將該農業用劑 調合物噴灑於稻田的水面之後，該活性成份迅速分散，並 因顆粒間放大距離的刺激擴散而溶解於水中，該放大距離 係由高吸水性聚合物因吸收水而潤脹所致。 換言之，本發明有關農業化學物質的調合物其特徵係 包含活性成份、平均粒徑在10至100微米範圍內之孔狀 載體、界面活性劑、黏合劑以及高吸水性聚合物。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -8- 1230582 A7 ____ B7 五、發明説明（7 ) 直接施用於稻田中不需要任何機械之形式、功效高、節省 人力，而且對於噴灑者以及環境的不良影響較少。 (請先閲讀背面之注意事項再填寫本頁) 本發明中’欲使用之農業用劑的活性成份沒有特殊限 制，可提出例如除草劑、殺蟲劑或殺菌劑，諸如阿尼洛弗 (Anilofos)、亞速隆（Ethoxysulfuron)、本弗瑞殺特 (Benfuresate)、戴木隆（Daimuron)、樂滅草（Oxadiazon)、 歐撒狄亞基（Oxadiargyl)、本坐芬那（Benzofenap)、克普草 (Clomeprop)、拜芬諾（Biphenox)、撲拉克（Prochloraze)、 依普冬（Iprodion)、弗塞提（Fossetyl)、芬普尼（Fipronil)、 依西普羅（Ethiprole)、提歐卡（Thiocarb)、安殺番 (Endosulfan)、NAC、繁米松（Vamidothion)與矽護芬 (Silafluofen)。本發明欲使用之農業用劑不受限於此等產 物，而且可以使用此等產物作爲單一組份使用或是使用兩 種以上產物之混合物。 經濟部智慧財產局員工消費合作社印製 至於本發明中欲使用之孔狀載體，可提出平均粒徑在 1 0至1 00微米範圍內之下列物質，例如浮石、藉由燃燒 粉碎的浮石粉末、藉由燃燒粉碎的火山灰、藉由燃燒粉碎 的珠光石粉末、矽藻土、蛭石、發泡玻璃、處理成防水的 有機或無機粒子、植物來源粉末以及廢紙所製的粒子等等 。本發明欲使用之孔狀載體不受限於此等產物，而且可以 使用此等產物作爲單一組份使用或是使用兩種以上產物之 混合物。不過，使用藉由燃燒粉碎的火山灰爲佳，因爲其 密度低之故，所以少量添加即可提供漂浮能力。 至於界面活性劑，可以提出例如脂肪酸皂、油之硫酸 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -10- 1230582 A7 B7 五、發明説明（13) 對照實例2 將應用實例1中該藉由燃燒粉碎之火山灰的平均粒徑 自80改成600微米’以應用實例1所述之相同方法製得 一種漂浮型調合物，作爲對照調合物2。 試驗實例1 於硬質氯乙烯製成’兩端均封閉’深度1 6 c m、高度 12 cm，長度400 cm的水管中’添加水至深度6 cm(水容 量爲3 8 · 4公升）。將一份〇. 2 1 g實驗實例1所製備之調合 物包裝於一個袋中，該袋係由2 c m X 3 c m的聚乙烯醇膜 (Solublon PT40 微米，由 Aicello Chemical Co，m Ltd·所製） 製成，並投於距該水管末端1 〇 cm處。然後定時於投入處 、距投入處1.5 m、3 · 0 m與3 · 8 m處取得水的樣本’用於 分析農業用劑含量。同時’以肉眼觀察分析投入該水管中 之調合物消失。分析與觀察結果示於表1。 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -16 - 1230582 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明（14) 定時分析之水中的農業用劑活性成份濃度(ppm) ----- 時間 化合物 投入位 置 0 m 與投入> 1.5 m 位置距1 3 m 1 3.8m 觀察水面 1.5 h Oxad. 0.15 0.14 0.14 0.11 有點 Benz. 0.42 0.39 0.34 0.33 殘留 Ethox. 0.037 0.038 0.037 0,037 載體 5 h Oxad. 0.14 0.14 0.14 0.12 幾乎不 Benz. 0.33 0.27 0.30 0.31 殘留 Ethox. 0.037 0.037 0.37 0.037 載體 24 h Oxad. 0.13 0.14 0.14 0.12 完全不 Benz. 0.10 0.10 0.09 0.10 殘留 Ethox. 0.037 0.036 0.035 0.037 載體 〇xad.=歐撒狄可羅美豐（Oxadichlomefone) Benz.=本坐芬那（Benzofenap)1230582 A7 B7 V. Description of the invention (1) (Please read the precautions on the back before filling this page) The floating blend of the agricultural agent of the present invention, more specifically, the so-called "jumbo blend" Its characteristic is that the active ingredients can be applied to the paddy field without any machinery. This is an agricultural agent prepared by dropping the agricultural agent itself or packaging it in a water-soluble bag in advance. In the past few years, because the population of agricultural workers has been decreasing year by year, the average age of agricultural workers has been higher, and farming has turned into a sideline, there is a high demand for spraying methods that require less manpower without using any machinery and walking in rice fields. . On the other hand, because the society is highly concerned about the environmental impact of agricultural agents, there is a great need for agricultural agents and spraying techniques that can easily and practically apply the appropriate amount of agricultural agents to reduce the outflow of agricultural agents from the spraying fields and reduce Adverse effects of people. In this case, because it is easy to spray the appropriate amount, the weather effect at the time of application is small, and the risk of agricultural agents flowing out of the spraying area is low. Therefore, the so-called "jumbo blend"-its characteristics are not The active ingredients need to be applied to the paddy field using any machinery. This is done by dropping a specific amount of 10 grams of the agricultural agent itself, or by dropping the agricultural agent prepared in advance in a water-soluble bag. Development has become quite well received. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Because the product of the jumbo blend can be locally sprayed on the paddy field, the good diffusion of the product in the paddy field is very important for the stability of efficacy and reduction of phytotoxicity of rice. In addition, there is a need to reduce any undue influence of active ingredients and adjuvants on the crop to be applied and on the environment. In addition, it is actually important to supply stable products at fairly low prices. Regarding the product form of large (jumbo) blends, the Japanese Patent Chartered Duke scale applies the Chinese National Standard (CNS) A4 specification (210X297 mm) ~ -4- 1230582 A7 _ B7 V. Description of the invention (2) Kazakhstan's bulletin No. H6 -192004, H6-2] Nos. 1 604 and H 1 1 240803 have been published (please read the precautions on the back before filling this page) to report the formation of foam blends, which are obtained by combining solid acid with carbonate or The bicarbonate is a carbon dioxide gas generated when an agricultural agent is put into water, and the active ingredient of the agricultural agent is suspended in water. This jumbo-forming blend has a specific effect on the diffusion of active ingredients by generating carbon dioxide gas diffusion in water. However, because the active ingredient remains locally in the jumbo-forming blend that has sunk into the upper soil of the paddy field, it poses a high risk of phytotoxicity to crops to be applied or crops planted later. There are other practical disadvantages. In other words, as long as the blended product contains a small amount of water during storage, the neutralization reaction can be easily triggered, and the water generated by the neutralization can stimulate such a neutralization reaction, the external installation material will be worn through, and No more foaming during actual application. Printed in Japanese Patent Laid-Open Publication No. H1 1-1402 by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs discloses a blend that is characterized by floating on the water surface with air stored in particles containing active ingredients of agricultural agents After being sunk into the upper soil, it is dispersed in the paddy field as the water-soluble carrier dissolves in water. The advantage of this blend is that even if it is not packaged in a water-soluble bag, its dispersibility is relatively small. The weight of the product itself is caused. However, in the case of agricultural agents with high soil absorptivity, some of the active ingredients remain in the sinks, so it is difficult to fully and uniformly disperse them. In addition, there are many technical issues. For example, this preparation method requires special technology, the water-soluble carrier will corrode the machine used for blending, and moisture that sensitively controls the temperature of the device preparation equipment room to avoid deliquescent of the water-soluble carrier. This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) -5- 1230582 A7 B7___ V. Invention Description (3) (Please read the notes on the back before filling this page) In large (jumbo) blends Among them, the "" floating blend "is characterized in that after the active ingredient is dispersed and dissolved in surface water," the active ingredient reaches the crop and has the following excellent characteristics. In other words, the 'floating blend can cause the active ingredient to float on a water surface far from the upper soil', wherein the upper soil has a bad characteristic of being highly absorbent for the agricultural agent applied. The active ingredient can be quickly dispersed in water ', and is uniformly dissolved in water by convection of water and gravity, so the surface of the upper soil layer remains in a uniform state. Printed by the Consumers' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs in Japanese Patent Laid-Open Publication Nos. H8-99803, H 1 0-265302, and H 1 0-287505, it has been disclosed that a floating type blend is prepared by a kneading granulation method Examples of preparations. The method of granulation by kneading is usually used to prepare agricultural agents, but because of the complexity of the method and the need for drying treatment, its cost is quite high. With this kneading method, in the case of preparing a floating blend using large particles having large pores inside, there are some practical problems, such as the risk of damaging the screen during the passage of the particles through the screen or the need for a large amount of water for kneading. In general, the kneading method can be used to press powder materials under the presence of a binder to form granules. Therefore, when using large particles with large pores inside, there is a risk of destroying the structure of the particles, and therefore the floating ability will be lost. In addition, due to the heat generated during drying, there are some practical risks, such as that certain active ingredients of agricultural agents will decompose, produce a foul odor, and lose the function of the surfactant. In Japanese Patent Laid-Open Publication Nos. H 1 1-315004 and H6-336403, and Japanese Patent Publication No. H3-76281, 7 ^ have been disclosed. Some are prepared from porous materials by coating or absorption. Technology of floating blends. These paper sizes are applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) '--6-1230582 A7 ______B7 V. Description of the invention (4) (Please read the precautions on the back before filling this page) The disadvantages described in the kneading method can be solved. However, the carrier described in this application example has a very high floating capacity, so even if the active ingredient has been released into water after spraying the formulated product, the carrier remains in the rice field for a long time. Therefore, there are disadvantages that the vicinity of the carrier is gathered by wind, the growth of the crop is suppressed, and the risk of outflow from the applied paddy field is high. Printed in Japanese Patent Laid-Open Publication No. H 1 0-1 09905 by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, a floating blend that can be applied to the water surface is disclosed, which is composed of an anionic surfactant and an inorganic or Organic vehicle composition and average particle size of less than 50 microns. In Japanese Patent Laid-Open Publication No. H8-99804, a floating-type diffusion blend that can be applied to a water surface has been disclosed. The characteristics of this blend are that the active ingredients of the agricultural agent are kept in the water floating particle structure, and the emulsifying and dispersing agent that combines the water surface diffusing agent with the molecular structure containing at least one glucose residue. In Japanese Patent Laid-Open Publication No. H5- 1 557-9, a floating type blend that can be applied to the water surface is disclosed, which combines an anionic surfactant with an inorganic or organic carrier and has an average particle size of less than 50 microns. In these bulletins, some application examples of the technology are mentioned, by which the above technical problems can be overcome. In other words, less storage problems, less damage to manufacturing machines, and relatively low costs can be achieved. In addition, it seems that certain techniques can be included to prepare floating blends with less phytotoxicity due to carrier residues on the water surface and a low risk of flowing out of the rice field. On the other hand, particles with an average particle size of less than 100 microns have the advantage that the carrier remains on the water surface after the active ingredient is released. However, compared with coarse particles, the area per unit weight is very large, so there are particles that form particles. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1230582 A7 _B7_ V. Description of the invention (5) (Please read the notes on the back before filling out this page.) As a result, the formulated product sprayed on the water surface of the rice field will stay in the same place for a long time without spreading out, hindering the release and uniform distribution of the active ingredients. As a result, the efficacy of agricultural agents becomes insufficient and causes phytotoxicity and local residues. The object of the present invention is to provide the following blends. After spraying, the active ingredient can be fully released, and the carrier sinks in a relatively short time. The agricultural agent can resist the cohesive force between the particles and spread on the water surface of the rice field, so the active ingredient is quickly released into the water. More specifically, the present invention aims to provide the following water-floating blends. The use of suitable agricultural agent equipment can be used to make the method easily and at low cost. It has superior effects after spraying, and has less impact on crops and the environment. The carrier can sink in a relatively short time. Furthermore, the object of the present invention is to provide an agricultural agent that can be easily sprayed without using a machine, and this object is achieved by packaging the above-mentioned floating blend with a water-soluble material such as a polyvinyl alcohol film. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the inventor observed the following characteristics of the agricultural agent, which contains an active ingredient, a pore-shaped carrier with an average particle size in the range of 10 to 100 microns, a surfactant, and an adhesive With super absorbent polymer. After spraying the agricultural agent blend on the water surface of the rice field, the active ingredient was rapidly dispersed and dissolved in water due to the stimulus diffusion of the enlarged distance between the particles, which was swelling by the superabsorbent polymer due to water absorption. Caused by. In other words, the blend of agrochemicals according to the present invention is characterized by including an active ingredient, a pore-shaped carrier having an average particle diameter in the range of 10 to 100 m, a surfactant, a binder, and a super absorbent polymer. This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) -8- 1230582 A7 ____ B7 V. Description of the invention (7) Direct application to rice fields does not require any form of machinery, high efficiency, saving manpower, and It has less adverse effects on sprayers and the environment. (Please read the notes on the back before filling this page) There are no special restrictions on the active ingredients of the agricultural agents to be used in the present invention. For example, herbicides, pesticides or fungicides such as Anilofos ), Ethoxysulfuron, Benfuresate, Daimuron, Oxadiazon, Oxadiargyl, Benzofenap, Kempo (Clomeprop), Biphenox, Prochloraze, Iprodion, Fossetyl, Fipronil, Ethiprole, Thiocarb ), Endosulfan, NAC, Vamidothion and Silafluofen. The agricultural agent to be used in the present invention is not limited to these products, and these products can be used as a single component or a mixture of two or more products. The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs has printed the pore-shaped carrier to be used in the present invention, and can propose the following substances with an average particle size in the range of 10 to 100 microns, such as pumice, pumice powder crushed by combustion, Volcanic ash crushed by burning, pearlite powder crushed by burning, diatomaceous earth, vermiculite, foamed glass, organic or inorganic particles processed into waterproof, plant-derived powder, particles made from waste paper, and so on. The porous support to be used in the present invention is not limited to these products, and these products can be used as a single component or a mixture of two or more products. However, it is better to use volcanic ash which is pulverized by combustion. Because of its low density, a small amount of addition can provide floating ability. As for the surfactant, for example, the sulfuric acid of fatty acid soap and oil can be proposed. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -10- 1230582 A7 B7 V. Description of the invention (13) Comparative example 2 Application example The average particle size of the volcanic ash pulverized by combustion was changed from 80 to 600 μm in 1 to prepare a floating blend as the control blend 2 in the same manner as described in Application Example 1. Test Example 1 A water pipe made of rigid vinyl chloride with both ends closed at a depth of 16 cm, a height of 12 cm, and a length of 400 cm was added with water to a depth of 6 cm (a water capacity of 3 8 · 4 liters). A portion of 0.21 g of the blend prepared in Experimental Example 1 was packed in a bag made of a 2 cm X 3 cm polyvinyl alcohol film (Solublon PT 40 micron, manufactured by Aicello Chemical Co, m Ltd. (Made), and put it 10cm away from the end of the water pipe. Samples of water were taken regularly at the input, 1.5 m, 3.0 m, and 3.0 m from the input, for analysis of the agricultural agent content. At the same time, the blend put into the water pipe disappeared by visual analysis. The analysis and observation results are shown in Table 1. (Please read the notes on the back before filling out this page) The paper size printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) -16-1230582 employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperative A7 B7 V. Description of the invention (14) Concentration of active ingredients of agricultural agents in water (ppm) ----- Time compound input position 0 m and input > 1.5 m Position distance 1 3 m 1 3.8m Observation of water 1.5 h Oxad. 0.15 0.14 0.14 0.11 A little Benz. 0.42 0.39 0.34 0.33 Residual Ethox. 0.037 0.038 0.037 0,037 Carrier 5 h Oxad. 0.14 0.14 0.14 0.12 Hardly Benz. 0.33 0.27 0.30 0.31 Residual Ethox. 0.037 0.037 0.37 0.037 Carrier 24 h Oxad. 0.13 0.14 0.14 0.12 Not at all Benz. 0.10 0.10 0.09 0.10 Residual Ethox. 0.037 0.036 0.035 0.037 Carrier 〇xad. = Oxadichlomefone Benz. = Benzofenap
Ethox.=亞速隆（Ethoxysulfuron) PVA袋於投入之後破裂，細微顆粒擴散在水面上，而 且該活性成份於投入3分鐘內完全擴散在水面上。已觀察 到水管底部沒有顆粒殘留。所有載體沉入水中，而且於投 入5小時之後，沒有任何東西在水面上。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） I ----- —Γ---------I- ^ I I----— (請先閱讀背面之注意事項再填寫本頁) -17- 1230582 A7 B7 五、發明説明（15) 試驗實例2 (請先閱讀背面之注意事項再填寫本頁) 以試驗實例1所述相同方式，試驗應用實例2中製得 的調配產物。分析與觀察結果示於表2。 表2 :定時分析之水中的農業用劑活性成份濃度（ppm) 時間 化合物 投入位 與投入位置距離 觀察水面 置 0 m 1.5m 3 m 3.8m 1.5 h Oxad. 0.15 0.14 0.14 0.11 有點 Benz . 0.42 0.39 0.34 0.33 殘留 E thox. 0.037 0.038 0.037 0.037 載體 5 h Oxad. 0.14 0.14 0.14 0.12 幾乎不 Benz . 0.33 0.27 0.30 0.31 殘留 E thox. 0.037 0.037 0.37 0.037 載體 24 h Oxad. 0.13 0.14 0.14 0.12 完全不 Benz. 0.10 0.10 0.09 0.10 殘留 E thox. 0.037 0.036 0.035 0.037 載體 經濟部智慧財產局員工消費合作社印製 試驗實例2所獲的的結果幾乎與試驗實例1相同。換 言之，PV A袋於投入之後破裂，細微顆粒擴散在水面上， 而且該活性成份於投入3分鐘內完全擴散在水面上。已觀 察到水管底部沒有顆粒殘留。所有載體沉入水中，而且於 I紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 一 一 -18- 1230582 A7Ethox. = Ethoxysulfuron PVA bag ruptured after being charged, fine particles diffused on the water surface, and the active ingredient completely diffused on the water surface within 3 minutes after the input. No particles have been observed at the bottom of the water pipe. All carriers were submerged in the water and nothing was on the water surface after 5 hours of infusion. This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) I ----- —Γ --------- I- ^ I I ----— (Please read the Note this page, please fill in this page) -17- 1230582 A7 B7 V. Description of invention (15) Test example 2 (Please read the notes on the back before filling this page) In the same way as in test example 1, test application example 2 The resulting blended product. The analysis and observation results are shown in Table 2. Table 2: Active ingredient concentration (ppm) of agricultural agents in water for time analysis. Observation of the distance between the input position and the input position of the compound. The water surface is set to 0 m 1.5m 3 m 3.8m 1.5 h Oxad. 0.15 0.14 0.14 0.11 a bit Benz. 0.42 0.39 0.34 0.33 Residual E thox. 0.037 0.038 0.037 0.037 Carrier 5 h Oxad. 0.14 0.14 0.14 0.12 Hardly Benz. 0.33 0.27 0.30 0.31 Residual E thox. 0.037 0.037 0.37 0.037 Carrier 24 h Oxad. 0.13 0.14 0.14 0.12 No Benz. 0.10 0.10 0.09 0.10 Residual E thox. 0.037 0.036 0.035 0.037 The test result 2 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Carrier Economy is almost the same as the test example 1. In other words, the PV A bag was ruptured after being put in, the fine particles were diffused on the water surface, and the active ingredient was completely diffused on the water surface within 3 minutes of being put in. No particles were observed at the bottom of the water pipe. All carriers are submerged in water, and the Chinese paper standard (CNS) A4 (210X297 mm) is applied to the I paper size. 1-1 -18- 1230582 A7
7 B 五、發明説明（16) 投入5小時之後，沒有任何東西在水面上。 (請先聞讀背面之注意事項再填寫本頁) 試驗實例3 以試驗實例1所述相同方式，試驗應用實例3中製得 的調配產物。分析與觀察結果示於表3。 表3 ··定時分析之水中的農業用劑活性成份濃度（ppm) 時間 化合物 投入位 與投入位置距離 觀察水面 置 0 m 1.5 m 3 m 3.8m 1.5 h Oxad. 0.17 0.15 0.14 0.12 有點 Benz. 0.29 0.25 0.24 0.24 殘留 E thox. 0.039 0.039 0.036 0.036 載體 5 h Oxad. 0.16 0.15 0.14 0.13 幾乎不 Benz. 0.28 0.27 0.20 0.21 殘留 E thox. 0.037 0.037 0.37 0.037 載體 24 h Oxad. 0.13 0.13 0.12 0.12 完全不 Benz . 0.1 1 0.11 0.11 0.10 殘留 Ethox. 0.036 0.037 0.036 0.036 載體 經濟部智慧財產局員工消費合作社印製 驗實例3所獲的的結果幾乎與試驗實例1相同。換言 之’ PVA袋於投入之後破裂，細微顆粒擴散在水面上，而 本紙張尺度適用中國國家標準（CNS ) A4規格（21 O X 297公釐） -19- 1230582 A7 ___ B7 五、發明説明（17 ) 且該活性成份於投入3分鐘內完全擴散在水面上。已觀察 到水管底部沒有顆粒殘留。所有載體沉入水中，而且於投 入5小時之後，沒有任何東西在水面上。 試驗實例4 除了劑量爲0.32 g之外，以試驗實例1所述相同方 式，試驗應用實例4中製得的調配產物。分析與觀察結^ 示於表.4。 (請先閱讀背面之注意事項存填寫本貢) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -20 - 1230582 A7 B7 五、發明説明（18) ΓΕ^:定時分析之水中的農業用劑活性成份濃度（ppm) 時間 化合物 投入位 與投入位置距離 觀察水面 置 0 m 1.5 m 3 m 3.8m 1.5 h Anil. 0.71 0.71 0.66 0.65 有點 Benf. 0.63 0.64 0.57 0.55 殘留 E thox. 0.039 0.037 0.032 0.030 載體 Daim. 0.69 0.64 0.5 5 0.51 5 h Anil. 0.68 0.66 0.66 0.65 幾乎不 Benf. 0.59 0.60 0.58 0.55 殘留 E thox. 0.033 0.034 0.033 0.032 載體 Daim. 0.55 0.54 0.49 0.51 24 h Anil. 0.66 0.67 0.65 0.64 完全不 Benf. 0.58 0.57 0.55 0.54 殘留 E thox. 0.033 0.033 0.032 0.032 載體 Daim. 0.52 0.50 0.50 0.49 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製7 B V. Description of the invention (16) After putting in for 5 hours, nothing is on the water. (Please read the notes on the reverse side before filling out this page) Test Example 3 In the same manner as in Test Example 1, test the compounded product prepared in Application Example 3. The analysis and observation results are shown in Table 3. Table 3 · Concentration of active ingredients of agricultural agents in water at timed analysis (ppm) Time observation of the input position and distance of the input position of the water surface 0 m 1.5 m 3 m 3.8 m 1.5 h Oxad. 0.17 0.15 0.14 0.12 A bit Benz. 0.29 0.25 0.24 0.24 Residual E thox. 0.039 0.039 0.036 0.036 Carrier 5 h Oxad. 0.16 0.15 0.14 0.13 Hardly Benz. 0.28 0.27 0.20 0.21 Residual E thox. 0.037 0.037 0.37 0.037 Carrier 24 h Oxad. 0.13 0.13 0.12 0.12 Not Benz. 0.1 1 0.11 0.11 0.10 Residual Ethox. 0.036 0.037 0.036 0.036 The results obtained by the Consumer Co-operative Society of the Intellectual Property Bureau of the Ministry of Carrier Economy printed test example 3 were almost the same as the test example 1. In other words, the PVA bag ruptured after being put in, and fine particles diffused on the water surface, and this paper size applies the Chinese National Standard (CNS) A4 specification (21 OX 297 mm) -19- 1230582 A7 ___ B7 V. Description of the invention (17) And the active ingredient completely diffused on the water surface within 3 minutes after being put in. No particles have been observed at the bottom of the water pipe. All carriers were submerged in the water and nothing was on the water surface after 5 hours of infusion. Test Example 4 The formulated product prepared in Example 4 was tested in the same manner as described in Test Example 1 except that the dosage was 0.32 g. The analysis and observation results are shown in Table 4. (Please read the precautions on the back and fill in this tribute first.) Printed on the paper by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the paper size is applicable to China National Standard (CNS) A4 (210X297 mm) -20-1230582 A7 B7 V. Description of the invention (18) ΓΕ ^: The concentration of active ingredients in agricultural water (ppm) in timed analysis. Time to observe the distance between the input position and the input position of the water surface 0 m 1.5 m 3 m 3.8 m 1.5 h Anil. 0.71 0.71 0.66 0.65 A bit Benf. 0.63 0.64 0.57 0.55 residual E thox. 0.039 0.037 0.032 0.030 carrier Daim. 0.69 0.64 0.5 5 0.51 5 h Anil. 0.68 0.66 0.66 0.65 hardly Benf. 0.59 0.60 0.58 0.55 residual E thox. 0.033 0.034 0.033 0.032 carrier Daim. 0.55 0.54 0.49 0.51 24 h Anil. 0.66 0.67 0.65 0.64 No Benf. 0.58 0.57 0.55 0.54 Residual E thox. 0.033 0.033 0.032 0.032 Carrier Daim. 0.52 0.50 0.50 0.49 (Please read the precautions on the back before filling this page) Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Employee Consumer Cooperative
Anil.=阿尼洛弗（Anilofos)Anil. = Anilofos
Benf.=本弗瑞殺特（Benfuresate)Benf. = Benfuresate
Ethox.=亞速隆（Ethoxysulfuron)Ethox. = Ethoxysulfuron
Daim.=戴木隆（Daimuron) 驗實例4所獲的的結果幾乎與試驗實例1相同。換言 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -21 - A7 B7 1230582 、發明説明（19) 之，PVA袋於投入之後破裂，細微顆粒擴散在水面上，而 旦該活性成份於投入3分鐘內完全擴散在水面上。已觀察 到水管底部沒有顆粒殘留。所有載體沉入水中，而且於投 入5小時之後，沒有任何東西在水面上。 試驗實例5 以試驗實例1所述相同方式，試驗對照實例1中製得 的調配產物。分析與觀察結果示於表5。 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 表5 :定時分析之水中的農業用劑活性成份濃度（ppm) 時間 化合物 投入位 置 0 m 與投入1 1.5 m i立置距廣 3 m 1 3.8m 觀察水面 1.5 h Anil. 1.21 1.07 0.53 0.11 有點 Benf. 1.91 1.56 0.43 0.22 殘留 E thox. 0.080 0.070 0.029 0.012 載體 5 h Anil. 0.93 0.87 0.64 0.14 幾乎不 Benf. 0.88 0.74 0.46 0.36 殘留 Ethox. 0.057 0.044 0.033 0.023 載體 24 h Anil. 0.83 0.83 0.66 0.14 完全不 Benf. 0.79 0.71 0.55 0.41 殘留 E thox. 0.041 0.042 0.037 0.026 載體 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） -22- 1230582 A7 B7 五、發明説明（20 ) 與應用實例1相較，對照實例1的調配產物（其中省 略高吸水性聚合物）顯示固體物質殘留在水面上的結果較 差，而且活性成份分散結果不佳。換言之，PVA袋於投入 之後破裂，該顆粒在水面上有些擴散，但是整個實驗期間 ，殘留某些固體物質。此外，幾乎沒有顆粒沉入水管底部 試驗實例6 以對照實例1所述相同方式，試驗對照實例2中製得 的調配產物。分析與觀察結果示於表6。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNs ) A4規格（210X297公釐） -23- 1230582 A7 B7 五、發明説明（21 ) 定時分析之水中的農業用劑活性成份濃度（ppm) 時間 化合物 投入位 置 0 m 與投入-1.5 m 位置距1 3 m 誰 3.8 m 觀察水面 Anil. 0.80 0.79 0.76 0.69 有點 --—> Benf. 0.68 0.68 0.67 0.61 殘留 —~~~--- E thox. 0.040 0.09 0.039 0.032 載體 5J^ Anil. 0.76 0.74 0.72 0.70 幾乎不 Benf. 0.68 0.68 0.65 0.62 殘留 E thox. 0.038 0.038 0.036 0.035 載體 24 h Anil. 0.72 0.71 0.70 0.69 完全不 Benf. 0.66 0.65 0.66 0.63 殘留 E thox. 0.037 0.037 0.036 0.036 載體 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 PVA袋於投入之後破裂，於投入3分鐘內細微顆粒完 全擴散在整個水面上。幾乎沒有觀察到顆粒殘留在水管底 部，不過，整個實驗期間，有些載體殘留物留在水面上。 製備實例2之調配產物（其中藉由燃燒粉碎之火山灰的平 均粒徑以600微米代替應用實例1之80微米）顯示出該調 合物在水面上之良好擴散性以及活性成份於水中之良好分 散作用，但是在24小時之後仍有載體殘留物。 如上述，由本發明製備之農業用劑漂浮型調合物可以 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -24- 1230582 A7 B7 五、發明説明（22 ) 完全釋放，並且使該活性成份分散至稻田中，提供均勻效 果，而且八會對於農作物造成不良影響。 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -25-Daim. = Daimuron The results obtained in Test Example 4 are almost the same as those in Test Example 1. In other words, the paper size is in accordance with the Chinese National Standard (CNS) A4 (210X297 mm) -21-A7 B7 1230582 and the description of the invention (19). After the PVA bag is broken, fine particles diffuse on the water surface, and the activity The ingredients completely spread on the water within 3 minutes of being put in. No particles have been observed at the bottom of the water pipe. All carriers were submerged in the water and nothing was on the water surface after 5 hours of infusion. Test Example 5 In the same manner as described in Test Example 1, the compounded product prepared in Comparative Example 1 was tested. The analysis and observation results are shown in Table 5. (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Table 5: Active ingredient concentration in agricultural water (ppm) in timed analysis Time input position 0 m and input 1 1.5 Wide standing distance 3 m 1 3.8 m Observing the water 1.5 h Anil. 1.21 1.07 0.53 0.11 A bit Benf. 1.91 1.56 0.43 0.22 Residual E thox. 0.080 0.070 0.029 0.012 Carrier 5 h Anil. 0.93 0.87 0.64 0.14 Hardly Benf. 0.88 0.74 0.46 0.36 Residual Ethox. 0.057 0.044 0.033 0.023 Carrier 24 h Anil. 0.83 0.83 0.66 0.14 None at all Benf. 0.79 0.71 0.55 0.41 Residual E thox. 0.041 0.042 0.037 0.026 Carrier This paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) -22- 1230582 A7 B7 V. Description of the invention (20) Compared with the application example 1, the preparation product of the comparative example 1 (where the super absorbent polymer is omitted) shows that the result of the solid substance remaining on the water surface is poor, Moreover, the dispersion of the active ingredients is not good. In other words, the PVA bag ruptured after being put in, and the particles diffused slightly on the water surface, but some solid matter remained throughout the experiment. In addition, almost no particles sink into the bottom of the water pipe. Test Example 6 In the same manner as described in Comparative Example 1, the prepared product prepared in Comparative Example 2 was tested. The analysis and observation results are shown in Table 6. (Please read the notes on the back before filling out this page) The paper size printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs applies to Chinese national standards (CNs) A4 specifications (210X297 mm) -23- 1230582 A7 B7 V. Description of the invention (21) Concentration of active ingredients of agricultural agents in water in timed analysis (ppm) Time compound input position 0 m and input -1.5 m Position distance 1 3 m Who is 3.8 m Observing the water surface Anil. 0.80 0.79 0.76 0.69 A little --- > Benf. 0.68 0.68 0.67 0.61 Residue ~~~~ --- E thox. 0.040 0.09 0.039 0.032 Carrier 5J ^ Anil. 0.76 0.74 0.72 0.70 Hardly Benf. 0.68 0.68 0.65 0.62 Carrier E thox. 0.038 0.038 0.036 0.035 Carrier 24 h Anil 0.72 0.71 0.70 0.69 No Benf at all. 0.66 0.65 0.66 0.63 Residual E thox. 0.037 0.037 0.036 0.036 Carrier (Please read the precautions on the back before filling out this page) The PVA bag printed by the staff consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs after the investment Ruptured, fine particles completely diffused across the water surface within 3 minutes of being put in. Few particles were observed at the bottom of the water pipe, however, some carrier residues remained on the water surface throughout the experiment. The blended product of Preparation Example 2 (in which the average particle size of volcanic ash crushed by combustion was replaced by 600 μm with 80 μm in Application Example 1) showed good diffusion of the blend on the water surface and good dispersion of the active ingredient in water , But there is still carrier residue after 24 hours. As mentioned above, the agricultural agent floating blend prepared by the present invention can be applied to the Chinese paper standard (CNS) A4 (210X297 mm) at this paper size. -24-1230582 A7 B7 V. The invention description (22) is completely released, and The active ingredient is dispersed in the paddy field to provide a uniform effect, and the eight will cause adverse effects on the crops. (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -25-