TWI295852B - Semiconductor structure and fabricating method thereof - Google Patents
Semiconductor structure and fabricating method thereof Download PDFInfo
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- TWI295852B TWI295852B TW95112821A TW95112821A TWI295852B TW I295852 B TWI295852 B TW I295852B TW 95112821 A TW95112821 A TW 95112821A TW 95112821 A TW95112821 A TW 95112821A TW I295852 B TWI295852 B TW I295852B
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- 239000004065 semiconductor Substances 0.000 title claims description 55
- 238000000034 method Methods 0.000 title claims description 54
- 239000007789 gas Substances 0.000 claims description 63
- 239000000758 substrate Substances 0.000 claims description 49
- 229910052751 metal Inorganic materials 0.000 claims description 24
- 239000002184 metal Substances 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 22
- 229910021480 group 4 element Inorganic materials 0.000 claims description 21
- 239000013078 crystal Substances 0.000 claims description 19
- 229910052732 germanium Inorganic materials 0.000 claims description 19
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 19
- 229910001922 gold oxide Inorganic materials 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 9
- 239000004575 stone Substances 0.000 claims description 9
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 230000007547 defect Effects 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 4
- 238000001465 metallisation Methods 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- 239000004020 conductor Substances 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 2
- 229910052707 ruthenium Inorganic materials 0.000 claims 2
- KZNMRPQBBZBTSW-UHFFFAOYSA-N [Au]=O Chemical compound [Au]=O KZNMRPQBBZBTSW-UHFFFAOYSA-N 0.000 description 27
- 125000006850 spacer group Chemical group 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 9
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 8
- 238000002955 isolation Methods 0.000 description 8
- 229910044991 metal oxide Inorganic materials 0.000 description 7
- 150000004706 metal oxides Chemical class 0.000 description 7
- 238000005530 etching Methods 0.000 description 5
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 241000238631 Hexapoda Species 0.000 description 3
- 238000005468 ion implantation Methods 0.000 description 3
- 229920002120 photoresistant polymer Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 206010012735 Diarrhoea Diseases 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- 229910001257 Nb alloy Inorganic materials 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 238000002513 implantation Methods 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 241000287828 Gallus gallus Species 0.000 description 1
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 239000002320 enamel (paints) Substances 0.000 description 1
- VABNKPWLESVOJG-UHFFFAOYSA-N ethylboron Chemical compound [B]CC VABNKPWLESVOJG-UHFFFAOYSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000000752 ionisation method Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 229910003468 tantalcarbide Inorganic materials 0.000 description 1
Landscapes
- Insulated Gate Type Field-Effect Transistor (AREA)
- Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
Description
^9585^ 九、發明說明: 【發明所屬之技術領域】 本發明是有關於 別是有關於以摻雜之應二^體結構及其製作方法,且特 構及其製作方法。、义曰作為源/汲極的一種半導體結 【先前技術】 金氧半電晶體是目箭扣 極為重要的締。積體電路(VLSI如也)中 器、半導體記憶树了非常的廣泛’舉凡微處理 體作為其基本之構輕元辜辑科,均可讀氧半電晶 件效ί,ί:二:二=增加金氧半電晶體的元 會產生應變解導體;成開σ,然後將 M ^千令版材枓(如SiGe)填入開口中以作為源/ ' “提咼電子或電洞在通道中的移動率(mobility)。 圖1A〜1B為習知一種金氧半電晶體之製作流程剖面 圖。首先,請參照圖1A,提供基底1〇〇。基底 100中已形 :、井區101。然後,利用一般熟知的技術於井區101上 =成閑極結構102,其包括依序形成於基底1〇〇上的閘介 電層104與閘極106。接著,於閘極結構102的側壁上形 ,間隙壁108。隨後,以閘極結構102與間隙壁108為罩 幕進行韻刻製程,移除部分基底10〇而形成開口 11()。 接著,請參照圖1B,於開口 110中形成應變層112 以作為源/汲極,並使應變層112的表面高於基底1〇〇的表 面’其高出部分標號為113。之後,於閘極結構102與應 變層112上形成自行對準金屬矽化物層114。 1295 doc/e 、由於應變層112的表面高於基底1〇〇的表面,因此可 以減少或消除金屬矽化物層114所產生的應力影響。此 外,為了提高應變層112所受的應力,以P型金氧半電晶 體為例,可在開口 110中填入鍺濃度大於20%的矽鍺合金 :=將補合金層的厚度增加,亦即形成深度較深的開 曰然而,矽鍺合金層的厚度會與鍺的濃度成反比,也就 是說,錯的濃度愈高,則補合金層的厚度愈薄。此外, 鍺的濃度愈高,補合金層的晶格常數也會愈大,使得石夕 鍺合金層與基底的晶格尺寸差異愈A,而容易在錢合金 層與基底的接面之間產线陷,進而影響元件效能。另外, 在進行自行對準金屬魏物製程時,鍺也會進人金屬石夕化 物層中而降低其品質。 【發明内容】 A本發明的目的就是在提供一種半導體結構,其利用晶 格常數不-致的應變層作為源/汲極,以避免因應變層與基 底的晶格大小相差過乡,而在應變層與基底的接面產生缺 陷。 、 本發明的半導體結構包括一基底、第一導電型的第一 金^半電晶體與第二導電型的第二金氧半電晶體。基底中 2罘-?電型的第一井區與第二導電型的第二井區,其中 第-金氧半電晶體配置於第二井區上,且第二金氧半電晶 體配置於第-井區上。第—金氧半電晶體包括第一閑極結 構與第-導電型的第—應變層。其中,第—閘極結構配置 6 I295§^,oc/e 於第二井區上,且其兩側之第二井區中具有第一開口。第 一應變層配置於第一開口中,此第一應變層於鄰近第一開 口底部之部分的晶格常數與基底的晶格常數之間的差異小 於其遠離第一開口底部之部分的晶格常數與基底的晶格常 數之間的差異。 在本發明的較佳實施例中,前述第一應變層的晶格常 數呈梯度分佈。 在一些實施例中,上述第一導電型為P型,且第一應 變層於鄰近第一開口底部之部分的晶格常數小於遠離第一 開口底部之部分的晶格常數。此種第一應變層的材質例如 為石夕鍺合金。 在另一些實施例中,上述第一導電型為N型,且第一 應變層於鄰近第一開口底部之部分的晶格常數大於遠離第 一開口底部之部分的晶格常數。此種第一應變層的材質例 如為碳化石夕。 在本發明一實施例中,上述第二金氧半電晶體包括配 置於第一井區上的第二閘極結構,以及第二導電型的源/ 汲極區,其配置於第二閘極結構兩侧的第一井區中。此時 前述半導體結構可更包括配置於第一應變層上的矽層,以 及一金屬梦化物層,其配置於前述梦層、源/沒極區、第一 閘極結構與第二閘極結構上。 在另一實施例中,上述第二金氧半電晶體包括配置於 第一井區上的第二閘極結構,以及第二導電型的源/汲極 區,配置於第二閘極結構兩側的第一井區中的第二開口的 doc/e 此㈣料導赌射更包括配置於第-岸 層/以及一金屬鷄層,其配置於前述二 ’、區、罘一閘極結構與第二閘極結構上。 第一井區上=例中’上述第二金氧半電晶體包括配置於 層,其:己置於弟第二:二以及第二導電型的第二應變 ♦。『於閘極m構兩側第-井區中的第二門口 基底的數與 與汽:格常數二= 於鄰近第4=:tt為_時’第-應變層 口底部之部分的晶格常 】於,、延雜弟一開 底部之部分的晶格常數大於其以=第, 第-應變層二ίΤΓ第二導電型為p型時, 遠離第一開口底 =口底部之部分的晶格常數大於其 近第二Η口广都 刀的晶格常數’且第二應變層於鄰 部之“的曰&二Γ分的晶格常數小於其遠離第二開口底 是呈i 另外,第二應變層的晶格常數例如 一、/刀布。此實施例之半導體結構可更包括配置於第 應變層上的石夕層,以及一金屬石夕化物層,其配置 於石夕層與前述第-、第二閘極結構上。 ^明的半導體結構製作方法如下。首先提供一基 :北7中已形成第一導電型的第-井區與第二導電型的第 —井區’再於第二井區上形成第一閑極結構,然後移除第[9585] IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a doping structure and a method for fabricating the same, and a structure and a method of fabricating the same. , a kind of semiconductor junction as a source/dippole. [Prior Art] Gold-oxide semi-transistor is an extremely important link. The integrated circuit (VLSI) also has a very wide range of semiconductor memory trees. As a basic structure of the light element, all of them can read the oxygen half-electric crystal device. ί, 2:2 = Increasing the element of the gold-oxygen semi-transistor produces a strain-relieving conductor; forming an open σ, and then filling the M ^ 千 版 枓 (such as SiGe) into the opening as a source / ' "Improving electrons or holes in the channel Figure 1A to 1B are cross-sectional views showing a manufacturing process of a conventional gold oxide semi-electrode. First, referring to Fig. 1A, a substrate 1 is provided. The substrate 100 has been shaped: well 101 Then, using well-known techniques on the well region 101 = a dummy structure 102 comprising a gate dielectric layer 104 and a gate 106 sequentially formed on the substrate 1 . Next, at the gate structure 102 The side wall is shaped like a gap wall 108. Subsequently, the gate structure 102 and the spacer wall 108 are used as a mask to perform a rhyme process, and a part of the substrate 10 is removed to form an opening 11 (). Next, please refer to FIG. 1B, at the opening 110. The strained layer 112 is formed as a source/drain and the surface of the strained layer 112 is higher than the surface of the substrate 1' The upper portion is labeled 113. Thereafter, a self-aligned metal telluride layer 114 is formed on the gate structure 102 and the strained layer 112. 1295 doc/e, since the surface of the strained layer 112 is higher than the surface of the substrate 1〇〇, Therefore, the influence of the stress generated by the metal telluride layer 114 can be reduced or eliminated. Further, in order to increase the stress applied to the strained layer 112, a P-type gold-oxygen semi-transistor can be used as an example, and the opening 110 can be filled with a germanium concentration of more than 20 % niobium alloy: = increase the thickness of the alloy layer, that is, form a deeper opening. However, the thickness of the niobium alloy layer is inversely proportional to the concentration of niobium, that is, the higher the concentration of the fault, The thinner the thickness of the alloy layer is, the higher the concentration of bismuth is, the larger the lattice constant of the alloy layer will be, the more the lattice size difference between the alloy layer and the substrate is A, and it is easy to be in the alloy. The line is trapped between the layer and the substrate, which affects the efficiency of the device. In addition, when the self-aligned metal material process is performed, the crucible also enters the metal layer to reduce the quality. A The purpose of the invention is A semiconductor structure is provided which utilizes a strained layer having a lattice constant which is not a source/drain to avoid a defect in the lattice size of the strained layer and the substrate, and a defect in the junction between the strained layer and the substrate. The semiconductor structure of the present invention comprises a substrate, a first gold-type semi-electrode of a first conductivity type and a second MOS transistor of a second conductivity type. The first well region and the second type of the second-electrode type in the substrate a second conductivity type second well region, wherein the first-gold oxide semi-transistor is disposed on the second well region, and the second gold-oxygen semi-transistor is disposed on the first well region. a first pole structure and a first conductivity type first strain layer, wherein the first gate structure is configured to be 6 I295§^, oc/e on the second well region, and the second well region on both sides has the first An opening. The first strain layer is disposed in the first opening, and the difference between the lattice constant of the portion of the first strain layer adjacent to the bottom of the first opening and the lattice constant of the substrate is smaller than the lattice of the portion away from the bottom of the first opening The difference between the constant and the lattice constant of the substrate. In a preferred embodiment of the invention, the lattice constant of the first strained layer is a gradient distribution. In some embodiments, the first conductivity type is a P-type, and a lattice constant of a portion of the first strainer layer adjacent to a bottom portion of the first opening is smaller than a lattice constant of a portion distant from a bottom portion of the first opening. The material of the first strain layer is, for example, a stone alloy. In still other embodiments, the first conductivity type is N-type, and a lattice constant of a portion of the first strain layer adjacent to a bottom portion of the first opening is greater than a lattice constant of a portion away from a bottom portion of the first opening. The material of the first strain layer is, for example, carbon carbide. In an embodiment of the invention, the second MOS transistor includes a second gate structure disposed on the first well region, and a source/drain region of the second conductivity type disposed at the second gate In the first well area on both sides of the structure. The semiconductor structure may further include a germanium layer disposed on the first strain layer, and a metal dream layer disposed in the dream layer, the source/drain region, the first gate structure, and the second gate structure. on. In another embodiment, the second MOS transistor includes a second gate structure disposed on the first well region, and a source/drain region of the second conductivity type disposed in the second gate structure The doc/e of the second opening in the first well region of the side is further configured to be disposed on the first bank layer/and a metal chicken layer, and is disposed in the foregoing two ', region, and first gate structures. With the second gate structure. In the first well region, the second oxy-halide transistor includes a layer disposed on the second layer: the second strain of the second conductivity type. "The number of bases in the second doorway in the first-well area on both sides of the gate m-structure and the vapor: lattice constant two = near the fourth =: tt is _ 'the portion of the bottom of the first-strain layer格常】,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, The lattice constant is greater than the lattice constant of the second Η口广刀, and the lattice constant of the second strain layer at the adjacent portion is smaller than the bottom of the second opening. The lattice constant of the second strain layer is, for example, a/knife. The semiconductor structure of this embodiment may further include a layer disposed on the strained layer, and a metallization layer disposed on the layer And the foregoing first and second gate structures. The semiconductor structure is fabricated as follows. First, a base is provided: a first well region of the first conductivity type and a first well region of the second conductivity type have been formed in the north 7 'The first idle structure is formed on the second well area, and then the first
井區上3第二導電型的金氧半電晶體。 ^在—些實施例中,前述第-導電塑為P型,且第-Iv • ;^素的原子徑大_子徑,减第—錢層成為墨 層。3 second conductivity type gold oxide semi-transistors on the well region. In some embodiments, the first-conducting plastic is P-type, and the atomic diameter of the first -Iv is larger than the sub-path, and the first-thick layer is reduced to the ink layer.
A 一在一些實施例中,前述第一導電型為N型,且第_IV ^元素為原子徑小神原子徑的碳,以 張應變層。 又曰驭马 々在一實施例中,上述第一混合氣體可更包括第一摻雜 j體’使第-應變層可直接形成為第—導電型的膜層。第 。井區上的金氧半電晶體的形成方法,例如是先於第—井 _ 區上形成第二閘極結構,再於第二閘極結構兩侧的第_井 =中形成第二導電型的源/沒極區。此時,上述半導體結構 衣作方法更可包括於第一應變層上形成矽層,再於此 層、第-閘極結構、第二閘極結構與源/汲極 成 矽化物層等步驟。 乂孟屬 下。首先於第一井區上形成第二閘極結構, 結構兩側的第一井區中形成第二開口,然種 壁與下方的第一井區中形成一源/汲極區。说 在另-實施例中,前述金氧半電晶體的形成方法可如 構,再於第二閘極 然後於第二開口側 。此時,上述半導 體j製作方法更可包括於第一應變層上形成韻,再於 ^層、源級極區、第—閉極結構與第二間 成 金屬矽化物層等步驟。 倂工办珉 在又-實施例中,前述金氧半電晶體的形成方法可如 下。首先於第-井區上形成第二閘極結構,再移除第 極結構兩側之部分基底以形成第二開口,再提供第二^丄 氣體以進行屋晶製程,以於第二開口巾形成含树及第: iv族元素的第二應變層。其中,第二混合氣體包括前述^ 一氣,與含第二1V族元素之第三氣體,且第二混合氣體 中之第三氣體的含量隨時間而增加。當第一導電型為P 型、第二導電型為N型時,第一 IV族元素的原子徑二於 夕的原子L ,且苐一 IV族元素為原子徑小於石夕原子徑的 碳;,當第一導電型為、第二導電型為p型時,^一 IV族元素為原子徑小於矽原子徑的碳,且第二ιν族元素 的原子徑大於矽的原子徑。另外,上述第二混合氣體可更 包括第二摻雜氣體,使得第二應變層可以直接形成為第二 導電型的膜層。在此實施例中,前述半導體結構的製作方 法可更包括於第一、第二應變層上形成矽層,再於此矽層 及弟與弟一閘極結構上形成金屬石夕化物層的步驟。 本發明在形成作為金氧半電晶體之源/汲極的應變層 的磊晶製程中,令所通入之非矽IV族元素來源氣體與矽 來源氣體的比例隨時間而增加,以使所形成之應變層於鄰 近開口底部之部分的晶格常數與基底的晶格常數之間的差 異小於其遠離開口底部之部分的晶格常數與基底的晶格常 10 I295^oc/e 巧的差異’因此避免了習知因鄰近開口底部 ^曰曰格尺寸與基底的晶格尺寸之間差異過大^錢^ 與基底的接面產生缺陷的問題。此外,本發明先於應變層 士开/成矽層,再於矽層上形成金屬矽化物層,故可避免應 、交層中的特IV族元素進人金屬雜物層而降低其品質。 #為壌本發明之上述和其他目的、特徵和優點能更明顯 易懂,下文特舉實施例,並配合所附圖式詳細說明如下。 【實施方式】 ^ 在以下的各個實施例中,相同的構件將給予相同的標 號,且各個實施例中的半導體結構將搭配其製作方法來對 本發明做說明。 圖2為本發明一實施例的半導體結構之剖面示意 圖。此半導體結構包括基底2〇〇、第一導電型的金氧半電 晶體202、第二導電型的金氧半電晶體2〇4以及隔離結才I 2〇6。基底200中具有第一導電型的井區2〇8與第二導電型 的井區210。金氧半電晶體202配置於井區21〇上,包括 閘極結構212與第一導電型的應變層216,其中閘極結構 212包括配置於基底200上的閘極212a、閘極212a與基底 200之間的閘介電層212b,以及閘極212a與閘介電層212b 侧壁上的間隙壁212c。閘極結構212配置於210井區上, 且其兩侧之井區210中具有開口 214。閘極以仏的材質例 如為多晶矽或金屬,閘介電層212b的材質例如為氧化矽、 氮化矽或氮氧化矽,間隙壁212c的材質則例如為氮化矽。 第一導電型的應變層216配置於開口 214中以作為金 11 Ι295·一 氧半電晶體2〇2的源/、、芬托广 近開口 2H底部之一部分,此應變層加於鄰 之間的差異小於其遠與基底的晶格常數 度分佈。告第H間的差異,且其晶格常數例如呈梯 ,电型為P型時,應變層216為壓應變層, 200 ΓΧ214 林曰且小於其遠離開口 214底部之部分的晶 : —導電型型時,應變層216為張應變層, 底部之部分的晶格常數㈣等於基底 故〜日日0讀,且a於其遠離開口214底部之部分的晶 二。吊i:此外’金氧半電晶體逝還包括第一導電型的推 τ隹區217以及第一導電型的源/沒極延伸區训。摻雜區2U 配置於開口區214下方及周圍,作為金氧半電晶體202的 源/及極區的另部分。源/汲極延伸區219配置於間隙壁 212c下方的井區21〇中。 金氧半電晶體204配置於井區208上。隔離結構206 酉巨己置縣底2GG中以定義出元件的主動區,其例如為淺溝 渠隔離(shallow trench isolation,STI)結構或其他型式的元 件隔離結構。在本實施例中,金氧半電晶體2〇4包括閘極 結構218與第二導電型的應變層222。閘極結構218配置 於井區208上,且其兩侧之井區208中具有開口 22〇。閘 極結構218包括配置於基底200上的閘極218a、閘極218a 與基底200之間的閘介電層218b,以及閘極2i8a與閘介 電層218b侧壁上的間隙壁218c。閘極218a的材質例如為 12 1295^ doc/e 多晶,,金屬,閘介電層鳩的材質例如為氧切、氮化 矽或氮氧化矽,間隙壁218c的材質例如為氮化矽。 應變層222配置於開口 22〇中以作為金氧半電晶體 2〇4的源/汲極區的一部分。同樣地,應變層a:於鄰近開 口 220底部之部分的晶格常數與基底200的晶格常數之間 的差異小於其遠離開口 220底部之部分的晶格常數盥二 200的晶格常數之間的差異,且晶格常數例如呈梯^ 佈。不過,應變層222的晶格常數變化趨勢與應變層216 相反。亦即,當第一導電型為p型(即第二導電型為N型)、 應變層216為壓應變層時,應變層222為張應變層,其於 鄰近開口 220底部之部分的晶格常數小於等於基底2〇〇的 晶格常數,且大於其遠離開口 22〇底部之部分的晶格常 數。當第一導電型為N型(即第二導電型為p型)、應變層 216為張應變層時,應變層222為壓應變層,其於鄰近開 口 220底部之部分的晶格常數大於等於基底2〇〇的晶格常 數,且小於其遠離開口 220底部之部分的晶格常數。此外, 金氧半電晶體204還包括第二導電型的摻雜區223以及第 一導電型的源/>及極延伸區225,其中摻雜區223配置於開 口區220下方及侧壁,作為金氧半電晶體2〇4的源/汲極區 的另一部分。源/汲極延伸區225配置於間隙壁218c下方 的井區208中。 特別一提的是,在本實施例中,當第一導電型為p型、 第二導電型為N型時,具壓應變之應變層216的材質例如 為晶格常數大於純矽的矽鍺合金,而具張應變之應變層 13 I295§52f.doc/e 222的材質例如為晶格常數小於純石夕的碳化秒。反之,當 第一導電型為N型、第二導電型為P型時,應變層216 = 材質例如為碳化矽,而應變層222的材質例如為石夕鍺合金。A. In some embodiments, the first conductivity type is an N-type, and the _IV^ element is a carbon having a small atomic diameter and a tensile strain layer. Further, in an embodiment, the first mixed gas may further include a first doping body so that the first strained layer may be directly formed into a first conductive type film layer. First. The method for forming the gold oxide semi-transistor in the well region, for example, forms a second gate structure on the first well region, and forms a second conductivity type in the first well = on both sides of the second gate structure. Source / no pole area. In this case, the semiconductor structure coating method may further include the steps of forming a germanium layer on the first strain layer, and further forming a germanium layer on the first layer, the first gate structure, the second gate structure, and the source/drain. Yu Meng is under. First, a second gate structure is formed on the first well region, and a second opening is formed in the first well region on both sides of the structure, and a source/drain region is formed in the seed wall and the first well region below. In another embodiment, the method of forming the MOS transistor may be as follows, and then on the second gate and then on the second opening side. In this case, the method for fabricating the semiconductor j may further include forming a rhyme on the first strain layer, and further forming a layer, a source-level polar region, a first-closed-pole structure, and a second inter-metallization layer. In another embodiment, the method of forming the aforementioned gold oxide semi-electrode can be as follows. First, a second gate structure is formed on the first well region, and then a part of the base on both sides of the pole structure is removed to form a second opening, and a second gas is provided to perform the roofing process for the second opening towel. A second strained layer comprising a tree and a: iv group element is formed. Wherein, the second mixed gas comprises the foregoing gas and the third gas containing the second group 1V element, and the content of the third gas in the second mixed gas increases with time. When the first conductivity type is P type and the second conductivity type is N type, the atomic diameter of the first group IV element is equal to the atom L of the eve, and the group of the group IV is carbon having an atomic diameter smaller than the diameter of the stone atom; When the first conductivity type is and the second conductivity type is p type, the group IV element is carbon having an atomic diameter smaller than the 矽 atomic diameter, and the atomic diameter of the second ιν group element is larger than the atomic diameter of 矽. Further, the second mixed gas may further include a second doping gas so that the second strained layer can be directly formed into a film layer of the second conductivity type. In this embodiment, the method for fabricating the semiconductor structure further includes the steps of forming a germanium layer on the first and second strain layers, and forming a metallization layer on the germanium layer and the gate structure. . In the epitaxial process for forming a strained layer as a source/drain of a metal oxide semi-crystal, the ratio of the non-矽IV element source gas to the helium source gas is increased with time, so that The difference between the lattice constant of the strained layer formed at the portion near the bottom of the opening and the lattice constant of the substrate is smaller than the difference between the lattice constant of the portion away from the bottom of the opening and the lattice of the substrate often 10 I295^oc/e 'Therefore, it is avoided that the difference between the size of the grid at the bottom of the adjacent opening and the lattice size of the substrate is too large. In addition, the present invention precedes the strained layer to open/form the tantalum layer and then form the metal telluride layer on the tantalum layer, thereby preventing the special group IV elements in the intersecting layer from entering the metal impurity layer and reducing the quality. The above and other objects, features, and advantages of the present invention will become more apparent from the <RTIgt; [Embodiment] ^ In the following embodiments, the same members will be given the same reference numerals, and the semiconductor structures in the respective embodiments will be described in conjunction with the manufacturing method thereof. Fig. 2 is a schematic cross-sectional view showing a semiconductor structure in accordance with an embodiment of the present invention. The semiconductor structure includes a substrate 2, a first conductivity type MOS transistor 202, a second conductivity type MOS transistor 2 〇 4, and an isolation junction I 2 〇 6. The substrate 200 has a well region 2〇8 of a first conductivity type and a well region 210 of a second conductivity type. The MOS transistor 202 is disposed on the well region 21, and includes a gate structure 212 and a strain layer 216 of a first conductivity type. The gate structure 212 includes a gate 212a, a gate 212a and a substrate disposed on the substrate 200. A gate dielectric layer 212b between 200, and a spacer 212c on the sidewalls of the gate 212a and the gate dielectric layer 212b. The gate structure 212 is disposed on the 210 well region and has an opening 214 in the well region 210 on both sides. The material of the gate electrode is, for example, polysilicon or metal. The material of the gate dielectric layer 212b is, for example, hafnium oxide, tantalum nitride or hafnium oxynitride, and the material of the spacer 212c is, for example, tantalum nitride. The strain layer 216 of the first conductivity type is disposed in the opening 214 to serve as a source of gold 11 Ι 295 · an oxygen half transistor 2 〇 2, and a portion of the bottom of the Fenton wide opening 2H, which is applied between the adjacent layers The difference is less than the distribution of the lattice constants far from the substrate. The difference between the H and the lattice constant is, for example, a ladder. When the electric type is P type, the strain layer 216 is a compressive strain layer, and the crystal is 200 ΓΧ 214 and smaller than the portion away from the bottom of the opening 214: - Conductive type In the case of the type, the strained layer 216 is a tensile strained layer, and the lattice constant of the portion of the bottom portion (four) is equal to the base crystal, and the crystal of the portion is away from the bottom portion of the opening 214. Hang i: In addition, the 'gold-oxygen semiconductor half-transistor includes a push-type τ region 217 of the first conductivity type and a source/no-pole extension region of the first conductivity type. The doped region 2U is disposed under and around the open region 214 as a further portion of the source/drain region of the MOS transistor 202. The source/drain extension 219 is disposed in the well 21a below the spacer 212c. The gold oxide semi-transistor 204 is disposed on the well region 208. The isolation structure 206 is located in the bottom 2GG of the county to define the active area of the element, which is, for example, a shallow trench isolation (STI) structure or other type of element isolation structure. In the present embodiment, the MOS transistor 〇4 includes a gate structure 218 and a strain layer 222 of a second conductivity type. The gate structure 218 is disposed on the well region 208 with openings 22 in the well regions 208 on either side thereof. The gate structure 218 includes a gate 218a disposed on the substrate 200, a gate dielectric layer 218b between the gate 218a and the substrate 200, and a spacer 218c on the sidewalls of the gate 2i8a and the gate dielectric layer 218b. The material of the gate electrode 218a is, for example, 12 1295 ^ doc / e polycrystal, and the material of the metal or gate dielectric layer is, for example, oxygen-cut, tantalum nitride or hafnium oxynitride, and the material of the spacer 218c is, for example, tantalum nitride. The strained layer 222 is disposed in the opening 22A as part of the source/drain region of the MOS transistor 〇4. Similarly, the strain layer a: the difference between the lattice constant of the portion adjacent to the bottom of the opening 220 and the lattice constant of the substrate 200 is less than the lattice constant of the portion of the lattice constant 盥200 from the portion of the bottom portion of the opening 220. The difference, and the lattice constant is, for example, a ladder. However, the lattice constant of the strained layer 222 changes in a tendency opposite to the strained layer 216. That is, when the first conductivity type is p-type (ie, the second conductivity type is N-type) and the strain layer 216 is a compressive strain layer, the strain layer 222 is a tensile strain layer whose lattice is adjacent to the bottom portion of the opening 220. The constant is less than or equal to the lattice constant of the substrate 2〇〇 and is greater than the lattice constant of the portion away from the bottom of the opening 22〇. When the first conductivity type is N-type (ie, the second conductivity type is p-type) and the strain layer 216 is a tensile strain layer, the strain layer 222 is a compressive strain layer whose lattice constant is greater than or equal to a portion adjacent to the bottom of the opening 220. The lattice constant of the substrate 2〇〇 is smaller than the lattice constant of the portion away from the bottom of the opening 220. In addition, the MOS semiconductor 204 further includes a doping region 223 of a second conductivity type and a source/ gt; and a polarity extension region 225 of the first conductivity type, wherein the doping region 223 is disposed under the opening region 220 and the sidewall. As another part of the source/drain region of the metal oxide semi-transistor 2〇4. Source/drain extension 225 is disposed in well region 208 below spacer 218c. In particular, in the present embodiment, when the first conductivity type is p-type and the second conductivity type is N-type, the material of the compressive strain strain layer 216 is, for example, a lattice constant larger than a pure 矽. The alloy, and the strain-strained layer 13 I295 § 52f.doc/e 222 is, for example, a carbonization second having a lattice constant smaller than that of pure stone. On the other hand, when the first conductivity type is N type and the second conductivity type is P type, the strain layer 216 = material is, for example, tantalum carbide, and the strain layer 222 is made of, for example, a stone alloy.
此外’由於應變層216/222於鄰近開口 214/220底部 之部分的晶格常數與基底200的晶格常數之間的差異小於 遠離開口 214/220底部之部分的晶格常數與基底2〇〇的晶 格常數之間的差異,因此開口 214/22〇底部之應變層 216/222與基底200的接面較不會因為晶格尺寸差異過大 而產生缺陷,進而影響元件效能。Furthermore, the difference between the lattice constant of the portion of the strained layer 216/222 adjacent the opening 214/220 and the lattice constant of the substrate 200 is smaller than the lattice constant of the portion away from the bottom of the opening 214/220 and the substrate 2〇〇 The difference between the lattice constants, so that the interface between the strain layer 216/222 at the bottom of the opening 214/22〇 and the substrate 200 is less likely to cause defects due to excessive difference in lattice size, thereby affecting the device performance.
另外本赉明之半導體結構還可以於應變層216盘222 上配置對應導電型的矽層22如與224b,並於矽層22'知、 224b與閑極結構212、218上配置金屬石夕化物層。石夕層 224a、224b的厚度例如是介於1〇〇A〜5〇〇A之間。金屬矽 化物層226的材質例如為石夕化鎢、石夕化鈦、石夕化銘、石夕化 鉬、石夕化鎳、石夕偏巴或石夕化翻。再者,更可以於基底· 表面上配置接觸窗綱終止層通與鳩。接觸窗侧 =2卿,材質如為氮化石夕。接觸窗_止 二&與208b通可以作為對金氧半電晶體2〇2、2〇4提供 m力力的應力層,贿-步提高金氧半電晶 .以下將說明圖2中之半導體結構的製作流程的一例, =此+賴結構左右兩半結構相似,故以下先說明其左 半邊結構的製程。 〃 圖3A〜3C緣示金氧半電晶體2〇2之製作流程剖面 14 1295§^.—/e ,^首先’明茶如、11 3A,提供基底200,基底200中已形 一導電㈣賴(树示)、第二導的賴210與 ::„f 206 ’其中隔離結構206定義出元件的主動區。 f曰型的井區與第二導電型的井區21G的形成方法例 姑疋對基底2QG進行第—導電型與第二導電型的離子 二Γ程。隔離結構206的形成方法例如是淺溝渠隔離結 構衣程。接著,於井區210上形成閉極212a與閉介電層In addition, the semiconductor structure of the present invention can also be provided with the corresponding conductive type germanium layers 22 and 224b on the strain layer 216, and the metal layer can be disposed on the germanium layer 22', the 224b and the idler structures 212 and 218. . The thickness of the layer 224a, 224b is, for example, between 1 〇〇A and 5 〇〇A. The material of the metal telluride layer 226 is, for example, Shi Xihua Tungsten, Shi Xihua Titanium, Shi Xi Hua Ming, Shi Xihua Mo, Shi Xihua Nickel, Shi Xi Bi Ba or Shi Xi Hua. Furthermore, it is also possible to arrange the contact window termination layer and the crucible on the substrate and the surface. Contact window side = 2 Qing, the material is Nitride. The contact window _ 止 二 & 208b can be used as a stress layer for the metal oxide half crystal 2 〇 2, 2 〇 4 to provide m force, bribe-step to increase the gold-oxygen semi-electrode. The following will explain the Figure 2 An example of the fabrication process of the semiconductor structure is that the structure of the left and right halves of the structure is similar, so the process of the left half structure will be described below. 〃 Figures 3A to 3C show the production flow profile of the gold-oxygen semi-transistor 2〇2 14 1295§^.—/e, ^ first 'ming tea, 11 3A, providing the substrate 200, the substrate 200 has formed a conductive (four) Lai (tree), second guide Lai 210 and:: „f 206 ' where the isolation structure 206 defines the active area of the component. The formation method of the f曰 type well area and the second conductivity type well area 21G The substrate 2QG is subjected to a first conductivity type and a second conductivity type ionization process. The isolation structure 206 is formed by, for example, a shallow trench isolation structure process. Then, a closed pole 212a and a closed dielectric are formed on the well region 210. Floor
212b ’其方法例如枝於基底上依序形成料電材料層與212b' method, for example, forming a layer of material and material on the substrate sequentially
1極材料層’再以微雜刻法依序圖案化閘極材料層 介電材料層。 J …請繼續參照圖3A,於閘極212a兩側的井區21〇中形 成第型的摻雜區211,其例如是以閘極212a為罩幕 進仃離子植入製程,將第一導電型的摻質植入基底中 而形成。接著,再於閘極212a與閉介電層212b的側壁上 心成間隙壁212c。此處間極212a、間介電層212b與間隙 壁212c合稱為閘極結構212。The 1-pole material layer is then sequentially patterned in a micro-aliasing manner to form a gate material layer dielectric material layer. J ... please continue to refer to FIG. 3A, forming a first type doped region 211 in the well region 21 两侧 on both sides of the gate 212a, which is, for example, a gate 212a as a mask for the ion implantation process, and the first conductive A type of dopant is formed by implanting into the substrate. Next, a spacer 212c is formed on the sidewalls of the gate 212a and the closed dielectric layer 212b. Here, the interpole 212a, the inter-dielectric layer 212b, and the spacer 212c are collectively referred to as a gate structure 212.
然後,請參照圖3B,移除閘極結構212兩側之部分 基底200以形成開口 214,此時摻雜區211有部分被移除, 而形成源/汲極延伸區219。開口 214的形成方法例如是先 於,底200上形成圖案化光阻層(未繪示),此圖案化光阻 層暴露出閘極結構212與預定形成開口 214的區域。然後, 以閘極結構212與圖案化光阻層為罩幕進行蝕刻製程,以 移除部分的基底200。上述的蝕刻製程可以是等向性蝕刻 製程、非等向性蝕刻製程或斜向(tilted)蝕刻製程。開口 21< 15 ,doc/e 的深度例如是介於100A〜l_A之間,較佳是介於3〇〇a 〜500人之間。 隨後’靖錄圖3C,以閘極結構212為罩幕進行離 子植入製程,將第一導電型的摻質植入開口 214下方及側 壁的基底200中,以形成摻雜區217 ,苴是作為全'半♦ 晶體搬的源/沒極區的-部分。特別一提的是,上^白^ 子植入製程也可以改在形成開口 214之前進行,然後再移 除部分基底200以形成開口 214與摻雜區217,但開口 214 的珠度必須小於離子植入的深度。 請繼續參關3C,提供第_混合氣體以進行蠢晶製 程丄於開口 214中形成應變層216,其中第一混合氣體包 括含石夕之第-氣體與含第-IV族元素之第二氣體,且第 二二氣體、Ϊ之第二氣體的含量隨時間而增加。上述磊晶 二王歹1。為選擇性蟲晶成長製程,而第—氣體例如為石夕甲 =二扣燒。此外’第-混合氣體較佳更包括第一推雜 =八"以使應變層216直接形成為第一導電型的膜層,作 ^孟氧半黾晶體202的源/汲極區的另一部分。當第一導電 綠^ ’為產生較大的晶格常數以形成具壓應變的應 曰216’所選用的第一 IV族元素為原子徑大於矽原子徑 常數以^疋錯。第一導電型為Ν型時,為產生較小的晶格 乂形成具張應變的應變層216,所選用的第一 IV族元 為原子徑小於矽原子徑的碳。 、 202 ^卜’金氧半電晶體2〇4的製作方法與金氧半電晶體 ▽衣作方法大致相同,差異在於金氧半電晶體2〇2為 16 1295^,00/e 第一導電型,而金氧半電晶體204為第二導電型,且形成 應變層222所使用的為包括第一氣體與含第二IV族元素 之第三氣體的第二混合氣體。當然,第二混合氣體也可以 更包括第二摻雜氣體,以使應變層222直接形成為第二導 電型的膜層,作為金氧半電晶體204的源/汲極區的一部 分。為分別形成PMOS所需的壓應變層與NMOS所需的 張應變層,當第一導電型為P型、第二導電型為N型時, 第一 IV族元素的原子徑大於矽原子徑,以得較大的晶格 常數,而第二IV族元素為原子徑小於矽原子徑的碳,以 得較小的晶格常數。反之,當第一導電型為N型、第二導 電型為P型時,第一 IV族元素為原子徑小於矽原子徑的 碳,而第二IV族元素的原子徑大於矽原子徑。 特別一提的是,當上述第一導電型為P型、第二導電 型為N型時,第二氣體例如為鍺烷,且在磊晶製程中第一 混合氣體中的第二氣體的含量例如是隨時間由〇增加至 40%,而第一摻雜氣體例如為乙硼烷。第三氣體例如為曱 烷或乙烷,且在磊晶製程中第二混合氣體中的第三氣體的 含量例如是隨時間由0增加至20%,而第二摻雜氣體例如 為鱗化氮。 反之,當上述第一導電型為N型、第二導電型為P型 時,第二氣體例如為曱烷或乙烷,且在磊晶製程中第一混 合氣體中的第二氣體的含量例如是隨時間由〇增加至 20%,而第一摻雜氣體例如為磷化氳。第三氣體例如為鍺 烷,且在磊晶製程中第二混合氣體中的第三氣體的含量例 17 I295S52vf.d〇c/e 而第二摻雜氣體例如為乙硼 於分開製作5疋_’上述金氧半電晶體202、2G4並不限 金氧半ί晶體2、〇Ι2ί金氧半電晶體2Q2的製作過程與 白勺衣作過程整合’以簡化製程步驟。 性地於座^、孟氧半电晶體2〇2 (或2〇4)之後,還可以選擇 也:應受層216 (或222)上形成韻咖(或黑),如Then, referring to FIG. 3B, a portion of the substrate 200 on both sides of the gate structure 212 is removed to form an opening 214, at which time the doped region 211 is partially removed to form a source/drain extension 219. The opening 214 is formed, for example, by forming a patterned photoresist layer (not shown) on the bottom 200, the patterned photoresist layer exposing the gate structure 212 and the region where the opening 214 is intended to be formed. Then, an etching process is performed with the gate structure 212 and the patterned photoresist layer as a mask to remove a portion of the substrate 200. The etching process described above may be an isotropic etching process, an anisotropic etching process, or a tilting etching process. The depth of the opening 21 < 15 , doc / e is, for example, between 100A and l_A, preferably between 3〇〇a and 500. Subsequently, the image recording process is performed by using the gate structure 212 as a mask, and the dopant of the first conductivity type is implanted into the substrate 200 below the opening 214 and the sidewall to form a doping region 217. As the source of the full 'half ♦ crystal movement / the part of the non-polar zone. In particular, the upper implantation process may also be performed before the opening 214 is formed, and then a portion of the substrate 200 is removed to form the opening 214 and the doped region 217, but the opening 214 must have a smaller bead than the ion. The depth of implantation. Please continue to participate in 3C, providing a first mixed gas to perform a stupid process, forming a strained layer 216 in the opening 214, wherein the first mixed gas includes a first gas containing gas and a second gas containing a group IV element And the content of the second gas and the second gas of the crucible increases with time. The above-mentioned epi-crystals are two kings. For the selective insect crystal growth process, and the first gas is, for example, Shi Xijia = two buckle burn. In addition, the 'first-mixed gas preferably further includes the first push-type=eight" to make the strained layer 216 directly formed into the first conductive type film layer, and the source/drain region of the ? portion. The first group IV element selected for the first conductive green ^' to produce a larger lattice constant to form a compressive strain 216' has an atomic diameter larger than the 矽 atomic diameter constant. When the first conductivity type is a Ν type, a strain layer 216 having a strain is formed to produce a smaller lattice ,, and the selected first group IV is carbon having an atomic diameter smaller than the 矽 atomic diameter. The method for fabricating the 202 卜 'gold oxide semi-transistor 2 〇 4 is substantially the same as the method for galvanic semi-transistor enamel coating, the difference is that the gold-oxide semi-transistor 2 〇 2 is 16 1295 ^, 00 / e first conductive And the MOS transistor 204 is of a second conductivity type, and the second gas mixture comprising the first gas and the third gas containing the second group IV element is used to form the strain layer 222. Of course, the second mixed gas may further include a second doping gas so that the strained layer 222 is directly formed as a second conductive type film layer as a part of the source/drain regions of the MOS semiconductor 204. In order to form the strain strain layer required for the PMOS and the tensile strain layer required for the NMOS, when the first conductivity type is P type and the second conductivity type is N type, the atomic diameter of the first group IV element is larger than the germanium atom diameter. The larger lattice constant is obtained, and the second group IV element is carbon having an atomic diameter smaller than the 矽 atomic diameter to obtain a smaller lattice constant. On the other hand, when the first conductivity type is N type and the second conductivity type is P type, the first group IV element is carbon having an atomic diameter smaller than the 矽 atomic diameter, and the atomic diameter of the second group IV element is larger than the 矽 atom diameter. In particular, when the first conductivity type is a P type and the second conductivity type is an N type, the second gas is, for example, decane, and the content of the second gas in the first mixed gas in the epitaxial process For example, it increases from 〇 to 40% over time, and the first doping gas is, for example, diborane. The third gas is, for example, decane or ethane, and the content of the third gas in the second mixed gas in the epitaxial process is, for example, increased from 0 to 20% with time, and the second doping gas is, for example, scalar nitrogen. . On the other hand, when the first conductivity type is N-type and the second conductivity type is P-type, the second gas is, for example, decane or ethane, and the content of the second gas in the first mixed gas in the epitaxial process is, for example, It is increased from 〇 to 20% over time, and the first doping gas is, for example, bismuth phosphide. The third gas is, for example, decane, and the content of the third gas in the second mixed gas in the epitaxial process is as described in Example 17 I295S52vf.d〇c/e and the second doping gas is, for example, ethyl boron, separately produced 5疋_ 'The above-mentioned gold-oxygen semi-transistors 202, 2G4 are not limited to the gold oxide half crystal 2, the process of making 2Q2 gold oxide semi-transistor 2Q2 is integrated with the white coating process' to simplify the process steps. Sexually after the ^, Meng oxygen semi-transistor 2 〇 2 (or 2 〇 4), you can also choose: also should be formed on layer 216 (or 222) rhyme (or black), such as
圖所=。秒層224a (或224b)的形成方法例如是在蟲晶製 ^一中1形成應變層216 (或222)之後,停止供應第二(或 弟-)乳體,而_供應切之第—氣體及第Figure =. The formation method of the second layer 224a (or 224b) is, for example, after the formation of the strain layer 216 (or 222) in the insect crystal system 1 , the supply of the second (or brother-) milk body is stopped, and the first gas is supplied. And
雜氣體,直到石夕層池(或通娜成至所需厚度。在形成 石夕層224a與224b之後’更可以選擇性鱗砍層似心牝 與閘極結構212、218上形成金屬魏物層挪,如圖2所 示。金屬矽化物層226的形成方法例如為自行對準金屬石夕 化物(self-align siHcide,salidde)製程。在形成金屬矽化物 層226之後’更可於基底200上形成接觸窗彳終止層 228’如圖2所示。接觸窗蝕刻終止層228的形成方法例如 為化學氣相沈積法。 在上述C Μ 0 S結構中,除了可將同樣形咸晶格常數不 一致的應變層的第一導電型金氧半電晶體2〇2與第二導電 型金氧半電晶體204搭配之外,還可將第一導電型金氧= 電晶體202與其他結構的第二導電型金氧半電晶體搭二。 圖4為本發明另一實施例的半導體結構之剖面^示音 圖。在本實施例中,與第一導電型金氧半電晶體2〇2搭^己 18 I295§52f.d〇c/e j第―導私型金氧半電晶體204,配置於井區208上,包括 則迷之閘極結構218與第二導電型的源級極區227,其中 源/汲極區227配置於閘極結構218兩側的井區208中。、金 氧半電晶體2〇4,還包括第二導電型的源/汲極延伸區225, 其配置於間隙壁218C下方的井區2〇8中。 同樣地,本實施例之半導體結構也可以於應變層216 上配置石夕層224,並於石夕層224、閘極結構212、218與源/ _ /及極區227上配置金屬矽化物層226。其中,石夕層224的 厚度與金屬矽化物層226的材質例如為前述者。再者,更 可以於金屬石夕化物層226上方配置接觸窗_終止層施 與208b,其材質如為氮化矽。 關於金氧半電晶體202的形成方法已於先前之實施例 做!田迷,於此不再另做說明。在本實施例中,金氧半電晶 體綱,的形成方法例如是先於井區2〇8上形成閘極結構 218,再於閘極結構218兩側的井區2〇8中形成第二導電型 的源/汲極區227,其方法例如是離子植入法。 藝圖5為本發明又—實施例的半導體結構之剖面示意 圖^在本實施例中,與第一導電型金氧半電晶體202搭配 之f二導電型金氧半電晶體204,,亦配置於井區2〇8上,包 括前述之閘極結構218與第二導電型的源/汲極區229,其 中源/沒極區229配置於開口 231下方及侧壁之井區2〇8 中。金氧半電晶體204’’還包括第二導電型的源級極延伸 區225,其配置於間隙壁218c下方的井區2〇8中。 同樣地,本發明之半導體結構也可以於應變層216上 19 l295^2vf.doc/e 224,並於石夕層224、,結構212、218與源汲 t⑽上配置金屬魏物層226,其切層224的厚度 ”盃屬石夕化物層226的材質例如為前述者。再者,更可以 於金屬梦化物層226上方配置接觸窗钱刻終止層228a與 208b,其巾闕賴刻終止層鳩的厚度至少足以填滿開 口 23^’以對金氧半電晶體2(Η”之通道區提供足夠的應力 而提南其载子移動率。接觸窗侧終止層228a與208b的 材質例如為氮化石夕。 關於金氧半電晶體202的形成方法已於先前之實施例 做描述,於此不再另做說明。在本實施例中,金氧半電晶 體204”的形成方法例如是:先於井區规上形成閘極結= 218,再移除閘極結構218兩側之部分基底2〇〇,以形成開 口 231。然後,於開口 231下方及側壁之井區2〇8中形成 第二導電型的源/汲極區229,其方法例如是離子植入法。 值得一提的是,上述金氧半電晶體2〇4,或2〇4,,同樣 不限於與金氧半電晶體202分開製作,亦可將金氧半電晶 體202的製作方法與金氧半電晶體2〇4,或2〇4,,的製作方 法整合,以簡化製程步驟。 特別一提的是,在本發明之再一實施例中,還可以將 金氧半電晶體202與另一個與金氧半電晶體2〇2具有相似 結構但不同導電型態的金氧半電晶體(未繪示)搭配。二者 的差異在於:金氧半電晶體202中具有前述晶格常數不一 致的應變層216,其晶格常數例如呈梯度分佈;而此金氧 半電晶體中的應變層之晶格常數為定值。 20 doc/e I2958s^i^wf· f上所述,本發明在形成作為金氧半電晶體之源級極 的應文層的|晶製程中’令蟲晶用混合氣體中含有非石夕W 族元素之氣體的含量隨咖而增加,以使所形成之應變層 於鄰近開π底部之部分的晶格倾與基絲晶格常數之間 的呈異小於其遠離開σ底部之部分的晶格常數與基底的晶 格常數之_差異’而可避免目晶格尺寸差異過大造成應 變層與基底之_接面產生影響元件效能的缺陷。 此外本叙明先於應變層上形成石夕層,再於石夕層上形 成金屬魏物層,可避免前述特IV族元素在自行對準 至屬石夕化物製程中進入金屬石夕化物層而降低其品質。 雖然本發明已以貫施例揭露如上,然其並非用以限定 本發明、’任何熟習此技藝者,在不脫離本發明之精神和範 f内,當可作些許之更動與潤飾,因此本發明之保護範圍 畲視後附之申請專利範圍所界定者為準。 【圖式簡單說明】 圖1A〜1B為習知一種金氧半電晶體之製作流程剖面 圖。 圖2為本發明一實施例的半導體結構之剖面示意圖。 圖3A〜3C為金氧半電晶體202之製作流程剖面圖。 圖4為本發明另一實施例的半導體結構之剖面示意 圖。 圖5為本發明又一實施例的半導體結構之剖面示意 圖。 【主要元件符號說明】 21 ,doc/e 100、200 :基底 206 :隔離結構 102、212、218 :閘極結構 104、212b、218b :閘介電層 106、212a、218a :閘極 108、212c、218c :間隙壁 110、214、220、231 :開口 114、226 :金屬矽化物層 202、204、204’、204” :金氧半電晶體 1(U、208、210 :井區 211、217、223 :摻雜區 112、216、222 :應變層 219、225 :源/汲極延伸區 224a、224b :矽層 227、229 :源/汲極區 228a、228b :蝕刻終止層 22Miscellaneous gases, until the Shixi layer pool (or Tongna into the required thickness. After the formation of the Shihua layer 224a and 224b), the selective scale-like layering of the heart and the formation of metal structures on the gate structures 212, 218 The layer is moved as shown in Fig. 2. The method for forming the metal telluride layer 226 is, for example, a self-aligned siHdide (salidde) process. After forming the metal telluride layer 226, it is more suitable for the substrate 200. The contact window stop layer 228' is formed as shown in Fig. 2. The contact window etch stop layer 228 is formed by a chemical vapor deposition method, for example, in the above C Μ 0 S structure, except that the same salty lattice constant can be used. The first conductivity type MOS transistor 2〇2 of the inconsistent strain layer is combined with the second conductivity type MOS transistor 204, and the first conductivity type gold oxide=the transistor 202 and other structures may also be used. FIG. 4 is a cross-sectional view of a semiconductor structure according to another embodiment of the present invention. In this embodiment, a first conductivity type MOS transistor is used. ^已18 I295§52f.d〇c/ej first-guided private gold oxide semi-transistor 20 4, disposed on the well region 208, including the gate structure 218 and the source region pole region 227 of the second conductivity type, wherein the source/drain region 227 is disposed in the well region 208 on both sides of the gate structure 218. The metal oxide semiconductor transistor 2〇4 further includes a source/drain extension region 225 of a second conductivity type disposed in the well region 2〇8 below the spacer 218C. Similarly, the semiconductor structure of the embodiment is also A layer of diarrhea 224 may be disposed on the strained layer 216, and a metal telluride layer 226 may be disposed on the layer 224, the gate structures 212, 218, and the source/_/polar regions 227. The thickness of the layer 224 The material of the metal telluride layer 226 is, for example, the above. Further, a contact window-termination layer 208b may be disposed above the metal lithium layer 226, and the material thereof is tantalum nitride. The formation method of 202 has been made in the previous embodiment! Tian fans, no further explanation here. In the present embodiment, the formation method of the metal oxide semi-crystal crystal, for example, is formed on the well 2〇8. The gate structure 218 further forms a source/drain region 227 of the second conductivity type in the well region 2〇8 on both sides of the gate structure 218. The method is, for example, an ion implantation method. Figure 5 is a schematic cross-sectional view of a semiconductor structure according to still another embodiment of the present invention. In the present embodiment, the f-conducting gold type is matched with the first conductive type MOS transistor 202. The oxygen semiconductor transistor 204 is also disposed on the well region 2〇8, including the gate structure 218 and the source/drain region 229 of the second conductivity type, wherein the source/no-pole region 229 is disposed under the opening 231 and The well region 2 〇 8 of the sidewall. The MOS semi-transistor 204 ′′ further includes a source-level extension region 225 of the second conductivity type disposed in the well region 2〇8 below the spacer 218c. Similarly, the semiconductor structure of the present invention may also be disposed on the strained layer 216, and disposed on the shoal layer 224, the structures 212, 218, and the source 汲t(10). The thickness of the slice 224 "the material of the cup diarrhea layer 226 is, for example, the above. Further, the contact window stop layer 228a and 208b may be disposed above the metal dream layer 226, and the cover layer of the cover layer 228a and 208b may be disposed. The thickness of the crucible is at least sufficient to fill the opening 23^' to provide sufficient stress to the channel region of the MOS transistor 2 to increase the carrier mobility. The material of the contact window side termination layers 228a and 208b is, for example, The method for forming the gold oxide semi-transistor 202 has been described in the previous embodiments, and will not be further described herein. In the present embodiment, the method of forming the gold-oxide semi-transistor 204" is, for example: A gate junction = 218 is formed on the well region gauge, and then a portion of the substrate 2 两侧 on both sides of the gate structure 218 is removed to form an opening 231. Then, it is formed in the well region 2〇8 below the opening 231 and the sidewall. a source/drain region 229 of a second conductivity type, such as ion implantation It is worth mentioning that the above-mentioned gold-oxygen semiconductor transistor 2〇4, or 2〇4, is also not limited to being fabricated separately from the gold-oxygen semiconductor transistor 202, and the gold-oxygen semiconductor transistor 202 can also be fabricated. It is integrated with the manufacturing method of MOS semi-transistor 2〇4, or 2〇4, to simplify the process steps. In particular, in another embodiment of the present invention, a gold-oxygen semi-transistor can also be used. 202 is matched with another gold-oxygen semi-transistor (not shown) having a similar structure but different conductivity types to the gold-oxygen semi-transistor 2〇2. The difference between the two is that the metal oxide semiconductor crystal 202 has the foregoing crystal. The strain layer 216 whose lattice constant is inconsistent has a lattice constant such as a gradient distribution; and the lattice constant of the strain layer in the MOS semi-electrode is constant. 20 doc/e I2958s^i^wf·f The content of the gas containing the non-stone group W element in the mixed gas for the insect crystal in the crystal forming process of the source layer which is the source electrode of the metal oxide semi-crystal is increased with the coffee, so that The difference between the lattice tilt of the formed strain layer at the portion adjacent to the bottom of the π opening and the lattice constant of the base filament Less than the difference between the lattice constant of the portion far from the bottom of σ and the lattice constant of the substrate, it is possible to avoid the difference in the size of the mesh size of the mesh, which causes the defect of the interface between the strained layer and the substrate to affect the performance of the element. The formation of the layer of the stone layer on the strain layer and the formation of the metal layer on the layer of the stone layer can prevent the above-mentioned special group IV elements from entering the metal-stone layer in the process of self-alignment to the group of stone-like compounds. The present invention has been disclosed in the above-described embodiments, and is not intended to limit the invention, and any skilled person can make some modifications and refinements without departing from the spirit and scope of the present invention. The scope of the invention is defined by the scope of the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS Figs. 1A to 1B are cross-sectional views showing a manufacturing process of a conventional gold oxide semi-electrode. 2 is a cross-sectional view showing a semiconductor structure in accordance with an embodiment of the present invention. 3A to 3C are cross-sectional views showing the manufacturing process of the gold oxide semiconductor transistor 202. Figure 4 is a cross-sectional view showing a semiconductor structure in accordance with another embodiment of the present invention. Figure 5 is a cross-sectional view showing a semiconductor structure in accordance with still another embodiment of the present invention. [Main component symbol description] 21, doc/e 100, 200: substrate 206: isolation structure 102, 212, 218: gate structure 104, 212b, 218b: gate dielectric layer 106, 212a, 218a: gate 108, 212c 218c: spacers 110, 214, 220, 231: openings 114, 226: metal telluride layers 202, 204, 204', 204": MOS semi-transistor 1 (U, 208, 210: well 211, 217 223: doped regions 112, 216, 222: strained layers 219, 225: source/drain extensions 224a, 224b: germanium layers 227, 229: source/drain regions 228a, 228b: etch stop layer 22
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