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TWI283655B - Method for producing microlens array by using flexible mold - Google Patents

Method for producing microlens array by using flexible mold Download PDF

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Publication number
TWI283655B
TWI283655B TW93127449A TW93127449A TWI283655B TW I283655 B TWI283655 B TW I283655B TW 93127449 A TW93127449 A TW 93127449A TW 93127449 A TW93127449 A TW 93127449A TW I283655 B TWI283655 B TW I283655B
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Taiwan
Prior art keywords
mold
flexible
microlens array
cavity
array
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TW93127449A
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Chinese (zh)
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TW200500305A (en
Inventor
Hsi-Haring Yang
Zueng-Jhe Li
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Univ Nat Chunghsing
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Publication of TWI283655B publication Critical patent/TWI283655B/en

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Abstract

A method for producing a microlens array by using a flexible mold comprises performing a pressure variation procedure on a flexible mold having a flexible membrane for forming an internal chamber to produce a deformation on the curvature of the membrane; and using a curable polymer material to replicate the shape thereof so that the flexible mold can produce a microlens array with a different radius of curvature and focal length by using a different pressure in order to endow the microlens array with focusing and photo-sensing functions. Since the formation process of the microlens array is free of thermal melting, the shape and the dimension of the microlens can be controlled stably. Furthermore, an electro-casting formation mold is used for mass-production, thereby achieving a low production device cost and a stable process.

Description

1283655 五、發明說明(1) 【發明所屬之技術領域】 本發明係有關—種應用撓 法,更詳而言之,4 仇八衩具I作破透鏡陣列之方 體之撓式模具,以壓;曰:3利用具有撓式薄膜與内腔 高分子固化材料形變,再運用 不同壓力控制製造出不同曲率半…過 凹透鏡陣列之方法。 ^、“、、之彳政凸透鏡或微 【先前技術】 不論是液晶顯示器(LCD)、行動電話 位助理(m),均需要更亮、更持久、更省幕體 的光源來強化顯不效果。而使用微透鏡陣列( array)技術時,已有研究指出可提升25%之1 ns 它也可應用於其他光學或軍事領域。 此外, 傳統之微透鏡陣列具有多種製造方法, 其中常見之一種,如我國專利公告號第5 1 9578號^「積^ 化微球透鏡光纖切換裝置之製造方法」發 利用微影與餘刻製程,在一基板上形成—透鏡u疋 厚=阻層,並利用光罩在厚膜光阻上定義 = 之成型區•,再將成型區域以外之透鏡承載層及厚 層蝕刻去除’以形成柱狀之微結構,再經過高溫埶處 使該柱狀微結構熔化,並藉由内聚力盥表面步力 η該等微凸圓柱可自動凝聚變成半球狀之微透鏡;=結1283655 V. INSTRUCTION DESCRIPTION OF THE INVENTION (1) Technical Field of the Invention The present invention relates to a method of applying a deflection method, and more specifically, a flexible mold of a square lens of a broken lens array. Pressure: 曰: 3 using a flexible film and a cavity polymer cured material deformation, and then using different pressure control to create a different curvature half ... over concave lens array method. ^, ",, 彳 凸 凸 或 或 or micro [previous technology] Whether it is liquid crystal display (LCD), mobile phone assistant (m), need brighter, more durable, more screen-like light source to enhance the display effect When microlens array technology is used, it has been pointed out that it can be improved by 25% ns. It can also be applied to other optical or military fields. In addition, conventional microlens arrays have various manufacturing methods, one of which is common. For example, in our Patent Publication No. 5 1 9578, "Manufacturing Method of Integrated Microsphere Lens Fiber Switching Device", using a lithography and a remnant process, a lens u 疋 thickness = a resist layer is formed on a substrate, and Using a mask to define the molding area on the thick film photoresist =, and then removing the lens carrier layer and the thick layer outside the molding area to form a columnar microstructure, and then passing the high temperature crucible to make the columnar microstructure Melting, and by cohesive force 盥 surface step force η, the micro-convex cylinders can be automatically condensed into hemispherical microlenses;

1283655 五、發明說明(2) 【發明内容】 隹驾决光阻熱嫁法之微透鏡曲率半徑雖可以藉由厚 2 2阻厚度及直徑控制’但是半球狀表面之控制不易精確 控制,因此整體之製程不穩定,故仍有極大改善之空間。 、本發明係提供一種應用撓式模具製作微透鏡陣列之方 法乃係利用一具有撓式薄膜及用以形成内腔體之撓式模 具,經由壓力變化使薄膜曲率產生形變,並運用可固化高 分子材料將其形狀翻製出來,使該撓式模具可配合不同壓 力控制製造出不同曲率半徑與焦距之微透鏡陣列,以達到 聚焦與感光之功用者。 本發明之應用撓式模具製作微透鏡陣列之方法,主要 係可用以解決習知製模方法複雜且單一鏡片高度受到限制 之缺點,其次,可使製程穩定,並精確製造不同曲率半徑 與焦距之微凸透鏡陣列或微凹透鏡陣列,最後,則是可再 翻製成模具組,使其適合大量生產。 【實施方式】 請參閱第一圖,係一薄膜結構受到均勻壓力差時產生 之結構變化示意圖’亦即,當該薄膜結構a内、外側分別 受到一均勻壓力P2與P1作用’且該P2大於p 1時,將使薄膜 結構a往外側方向變形呈微透鏡狀,此乃本發明形成微透 鏡陣列必需使用之基礎原理,特此敘明。 請參閱第二、三圖,本發明係為一種應用撓式模具製 12836551283655 V. DESCRIPTION OF THE INVENTION (2) [Summary of the Invention] The radius of curvature of the microlens can be controlled by the thickness of the thickness of the film and the diameter of the lens. However, the control of the hemispherical surface is difficult to accurately control, so the whole The process is unstable, so there is still room for improvement. The present invention provides a method for manufacturing a microlens array by using a flexural mold by using a flexible film having a flexible film and a flexible mold for forming an inner cavity, and deforming the curvature of the film by pressure change, and using a curable high The molecular material transforms its shape so that the flexural mold can be used with different pressure control to produce microlens arrays with different radii of curvature and focal length to achieve focus and sensitization. The method for manufacturing a microlens array by using a flexible mold of the present invention can be mainly used to solve the defects that the conventional molding method is complicated and the height of a single lens is limited, and secondly, the process can be stabilized, and different curvature radius and focal length can be accurately manufactured. A micro-convex lens array or a micro-concave lens array, and finally, can be re-formed into a mold set, making it suitable for mass production. [Embodiment] Please refer to the first figure, which is a schematic diagram of a structural change caused when a film structure is subjected to a uniform pressure difference, that is, when the film structure a is subjected to a uniform pressure P2 and P1 respectively and the P2 is larger than When p 1 , the film structure a is deformed in the outer direction to be in the form of a microlens, which is a basic principle that must be used in the formation of the microlens array of the present invention, and is hereby described. Please refer to the second and third figures, the invention is a method of applying a flexible mold 1283655

作微透鏡陣列之方法,其包括有下列步驟: (一) 撓式模具之製作 a、預先備置一矽晶圓基板1 1,並於基板Η上以 光阻塗佈、曝光以及顯影等黃光微影技術製作出丨〇〇 #爪厚 呈圓柱狀之SU-8光阻結構層丄2陣列,以形成一光阻模具 10; b 二將PDMS?K 合物 2〇 (係polydimethy —^。““聚 合物之簡稱)以600轉/分(rpm)塗佈於光阻模具丄〇之 結構層1 2上; c、 最後,以150。〇,15分鐘熱烤PDMS聚合物2 〇與 固化劑之混合物,使PDMS聚合物2 0固化; ” d、 將固化之PDMS聚合物2 0從光阻模具丄0上脫模 形成一撓式模具3 0,該撓式模具3 〇相對光阻模具丄〇 各光阻結構層1 2處係分別形成有一凹陷槽3 1 ,並於各 凹陷槽3 1之槽底部分別形成有一撓性之薄膜結構層3 2 ’之後’將撓式模具3 0之凹陷槽3 1方向,以3 〇瓦特的 氧電漿處理3 0秒’並將其接合於一玻璃基板4 〇上,使於 性模具3 0各薄膜結構層3 2下方之凹陷槽3 1可被密射 形成一内腔體33。 '于 (二) 微透鏡陣列之翻製 a、在撓式模具3 0之薄膜結構層3 2上塗佈可固化 回为子材料’本實施例係採用UV固化膠作為可固化$八子 材料’而使該撓式模具3 0上形成有一可固化高分^纟士構 層50,並將該撓式模具30、玻璃基板4〇及可固^言The method for making a microlens array comprises the following steps: (1) Fabrication of a flexural mold a, pre-preparing a wafer substrate 1 1, and applying yellow light lithography such as photoresist coating, exposure and development on the substrate The technique produces a SU2 array of SU-8 photoresist structure layers 爪2 with a thick claw shape to form a photoresist mold 10; b 2 PDMS?K compound 2 〇 (system polydimethy -^." The abbreviation of the polymer is applied to the structural layer 12 of the photoresist mold at 600 revolutions per minute (rpm); c, finally, at 150. 〇, 15 minutes hot-baked mixture of PDMS polymer 2 and curing agent to cure the PDMS polymer 20; "d, demold the cured PDMS polymer 20 from the photoresist mold 丄0 to form a flex mold 30, the flexural mold 3 〇 is opposite to the photoresist mold 丄〇 each photoresist structure layer 12 is formed with a recessed groove 3 1 , and a flexible film structure is formed at the bottom of each recessed groove 31 After layer 3 2 'after 'the direction of the recessed groove 3 1 of the flexible mold 30 is treated with 3 watts of oxygen plasma for 30 seconds' and bonded to a glass substrate 4 ,, so that the mold 3 0 The recessed groove 3 1 under each of the film structure layers 3 2 can be densely formed to form an inner cavity 33. '(2) The micro lens array is rotated a, and the film structure layer 3 2 of the flexible mold 30 is coated. The cloth can be cured back into a sub-material. In this embodiment, a UV-curable adhesive is used as the curable $eight material, and a curable high-divided gentleman layer 50 is formed on the flexural mold 30, and the flexible layer is formed. Mold 30, glass substrate 4 and can be fixed

1283655 五 發明說明(4) ^子結構層5 〇 一起放置於一環 ;6 0頂端以-可為壓力克等透“料^中,該環境腔 ”密封,並於環境腔體6 0内部連;明蓋6 1 二控制該環境腔體6 ◦内部:浦7 腔體3 3 :3ϊΠ60内部壓力大於撓式模具3 〇内 2便會ί = 該撓式模具3〇之薄膜結構層3 未固化:用向内凹陷形成一微凹狀,録佈其上 :反之Ζ固化尚分子結構層5 0隨其形狀變形呈外凸狀 壓力小於:ΐ閱第四圖,當環境腔體6 0内部形成負壓或 模且q ^ 70式模具3 〇内腔體3 3之内在壓力時,該撓式 之薄膜結構層3 2亦會受壓力差作用向外凸出形 凸狀,使塗佈其上未固化之可固化高分子結構層5 U Ρ通其形狀變形呈内凹狀; c、利用紫外線光源8 0由透明蓋6 1上方照射,使 其紫外光穿透壓克力透明蓋6 1後,得照射於可固化高分 子結構層5 〇之uv固化膠上,使之固化,之後,再將該固 化後之可固化高分子結構層5 〇 ’脫模,即可在其上由該 撓式模具3 0翻製形成微凹透鏡狀或板凸透鏡狀之微透鏡 陣列5 1 。 另’該微透鏡陣列5 1形成後,可再運用電鑄製程轉 換製作成金屬模具,以供射出成形及大量生產者。 關於本發明之實驗,其裝配方式如第三圖所示,並分 別在壓力差為10、20、30、40、50、60、70 KPa時依序進 行實驗,相關條件如第圖五所示,透過下列公式(1 )可算1283655 5 invention description (4) ^ substructure layer 5 〇 placed together in a ring; 6 0 top with - can be pressure gram through the "material ^, the environmental cavity" sealed, and connected inside the environmental cavity 60; Ming cover 6 1 2 control the environment cavity 6 ◦ inside: Pu 7 cavity 3 3 : 3 ϊΠ 60 internal pressure is greater than the flex mold 3 〇 2 will ί = the flexural mold 3 〇 film structure layer 3 uncured: A concave shape is formed by inward depression, and the upper surface is recorded: on the contrary, the solid molecular structure layer 50 is deformed by the shape of the convex structure, and the pressure is less than: the fourth picture is shown, when the environmental cavity 60 forms a negative inside. When the pressure or the mold and the q ^ 70 type mold 3 are within the internal pressure of the inner cavity 3 3 , the flexible film structural layer 32 is also convexly convex by the pressure difference, so that the coating is not applied thereto. The cured curable polymer structure layer 5 U is deformed in a concave shape; c. is irradiated by the ultraviolet light source 80 from above the transparent cover 61, so that the ultraviolet light penetrates the acrylic transparent cover 6 1 It is irradiated onto the uv curable adhesive of the curable polymer structure layer 5 to be cured, and then the cured high score can be cured. Structural layer 5 billion 'release, which can be in the microlens array or lenticular dimples lenticular plate 51 is formed of a flexible mold 30 of the turning system. Further, after the microlens array 51 is formed, it can be converted into a metal mold by electroforming process for injection molding and mass production. Regarding the experiment of the present invention, the assembly method is as shown in the third figure, and the experiments are sequentially performed at pressure differences of 10, 20, 30, 40, 50, 60, 70 KPa, respectively, and the relevant conditions are as shown in FIG. , can be calculated by the following formula (1)

第8頁 1283655 五、發明說明(5) 出透鏡高度h,之後,把每個微透鏡表面輪廓當作成圓球 表面’利用所量得之透鏡高度h與直徑d,以及光阻層本身 的折射率n(refractive index),並透過下列公式(2)及 (3)可算出透鏡曲率半徑rc (radius of curvature)及焦 距f(focus),如第五圖之數據資料 (1) (2) ΜPage 8 1283655 V. Description of the invention (5) The height h of the lens is taken out, after which the surface contour of each microlens is regarded as the surface of the sphere 'using the measured lens height h and diameter d, and the refractive index of the photoresist layer itself Rate n (refractive index), and through the following formulas (2) and (3), the radius of curvature of the lens rc (radius of curvature) and the focal length f (focus) can be calculated, as shown in the data of the fifth figure (1) (2)

Rc =- 2k 與Rc =- 2k and

Rc «-1 (3) 再者,將 1 ·本發 陣列或微凹透 半徑與焦距, 片高度受到限 2 ·本發 改變及控制薄 透鏡之形狀與 3 ·本發 設備,加上可 產设備成本低 本發明之優 明之撓式模 鏡陣列之功 故可有效解 制等缺點。 明之撓式模 膜結構層3 尺寸,故其 明無需複雜 以電鑄成形 與製程穩定 點及可達成功效歸納如下: 具3 0同時兼具有製作微凸透鏡 能,並可依需要控制不同之曲率 決習知製模方法複雜,且單一鏡 具30可藉由壓力差之設定,來 2之形狀與變形量,進而控制微 製,土於控制且相當穩定。 二叩貝之可程式控制裝置或生產 模具作為量產之製裎,以達到生 之特性。Rc «-1 (3) Furthermore, 1 · the array or the concave radius and focal length of the hair array, the height of the sheet is limited to 2 · The hair changes and controls the shape of the thin lens and 3 · The hair device, plus the available Low equipment cost The advantages of the flexible mirror array of the present invention can be effectively solved and the like. Ming's flexible film structure layer 3 size, so it does not need to be complicated by electroforming and process stability points and the achievable functions are summarized as follows: It has 30 0 and has the ability to make micro-convex lens, and can control different curvatures as needed. The method of ignoring the mold is complicated, and the single mirror 30 can control the microfabrication by controlling the microfabrication by the setting of the pressure difference, and the soil is controlled and quite stable. The second mussel's programmable control device or production mold is used as a mass production system to achieve the characteristics of life.

1283655 五、發明說明(6) 最後,值得再接的县 透鏡陣列5 i更包含有下列產業利=之技術所形成之微 元;光學鏡片。 3 ·承焦之微透鏡可用於 Ϊ知耗。 產精準模具之裝配。 予^了早糸統,應用於生 作方^對於生醫器材所需之内視鏡’提供微小鏡片之製 發光I率可提升有機二極體(〇LED)與無機二極體⑽)之 ” 6尤:,:提升平面顯示器背光模組之光源均句度與 宂度由尤,、疋王彩面板’包括PDA (個 機、車用螢幕及行動器儀表板等。 里為)手 綜上所述,本發明在同類產品中實有其極佳之進步實 用性,同時遍查國内外關於此類結構之技術資肖,文獻中 亦未發現有相同的構造存在在先,是以, 新型專利要件,爰依法提出申請。 ^ ^ 准,以上所述者,僅係本發明之一較佳可行實施例而 已,故舉凡應用本發明說明書及申請專利範圍所為之等效|籲 結構變化’理應包含在本發明之專利範圍内。 第10頁 1283655 圖式簡單說明 【圖式簡單說明】 第一圖為薄膜結構受到均勻壓力差時所產生之結構變 化示意圖。 第二圖係本發明撓式模具之製作流程圖。 第三圖係本發明微凹透鏡之成形示意圖。 第四圖係本發明微凸透鏡之成形示意圖。 第五圖係本發明在不同壓力差所產生之結果比較表。 【主要元件代表符號說明】 a 薄膜結構1283655 V. INSTRUCTIONS (6) Finally, the county lens array 5 i worthy of re-inclusion includes micro-forms formed by the following technologies: optical lenses. 3 • The micro-lens of the focus can be used for knowing. Production of precision mold assembly. To the early sputum, applied to the production side ^ for the endoscopes required for biomedical equipment 'providing a small lens, the luminous rate I can improve the organic diode (〇LED) and the inorganic diode (10) 6 Special::: The light source of the flat panel display backlight module is uniform and the degree is wide, and the 疋王彩面板' includes PDA (single machine, car screen and mobile instrument panel, etc.) As described above, the present invention has excellent advancement and practicability in the same kind of products, and at the same time, the technical knowledge of such structures is frequently investigated at home and abroad, and the same structure is not found in the literature. New patent requirements, 提出 apply in accordance with the law. ^ ^ Quasi, the above is only one of the preferred embodiments of the present invention, so the equivalent of the application of the present invention and the scope of the patent application It is intended to be included in the scope of the patent of the present invention. Page 10 1283655 Brief description of the drawing [Simple description of the drawing] The first figure is a schematic diagram of the structural change produced when the film structure is subjected to a uniform pressure difference. The second figure is the deflection of the present invention. Mold The third drawing is a schematic view of the forming of the micro concave lens of the present invention. The fourth drawing is a schematic view of the forming of the micro convex lens of the present invention. The fifth drawing is a comparison table of the results produced by the present invention under different pressure differences. Description] a film structure

10 光阻模具 11 矽晶圓基板 12 光阻結構層 2 0 PDMS聚合物 3 0 撓式模具 3 1 凹陷槽 3 2 薄膜結構層 3 3 内腔體 4 0 玻璃基板 5 0 可固化高分子結構層 5 0 ’可固化高分子結構層10 photoresist mold 11 矽 wafer substrate 12 photoresist structure layer 2 0 PDMS polymer 3 0 flexible mold 3 1 depressed groove 3 2 thin film structure layer 3 3 inner cavity 4 0 glass substrate 5 0 curable polymer structure layer 5 0 'curable polymer structural layer

5 1 微透鏡陣列 6 0 環境腔體 61 透明蓋 7 0 空氣壓力幫浦 80 紫外線光源5 1 Microlens array 6 0 Environmental chamber 61 Transparent cover 7 0 Air pressure pump 80 UV light source

第11頁Page 11

Claims (1)

丄283655丄283655 括有應用挽式棋具製作微透鏡陣列之方法 係包 以彈性體材料製作 成有撓式薄膜結構層陣列; b、將撓式模具接合於一基板上, 溥膜結構層陣列與基板間各形成有一 5 腔體; / ’該撓式模具上形 使撓式模具之撓式 預定腔體壓力之内 c、 在撓式模具之撓 子材料,以形成一可固化 力調控之環境腔體内,利 預定壓力差,使撓式模具 鏡形狀之變形,同時使可 d、 將成形後之高分 ,即可獲致微透鏡陣列。 2、依申請專利範圍 微透鏡陣列之方法,其中 材料。 性薄膜結構層上塗佈可固化高矣 尚分子結構層,並放置於一可屬 用環境腔體與模具内腔體間形成 之撓性薄膜結構層陣列產生微透 固化高分子結構層亦隨之成形; 子結構層固化,並將其脫模取出 第1項所述之應用撓式模具製作 該彈性體材料係採用PDMS高分子The method for manufacturing a microlens array by using a pull-type chess piece is formed by using an elastomer material to form an array of a flexible film structure layer; b. bonding the flexible mold to a substrate, forming an array between the enamel film structure layer and the substrate There is a 5 cavity; / 'the flexible mold is shaped to flex the predetermined cavity pressure of the mold, c, in the flexible mold of the flexible material to form a curable force regulating environment cavity, The microlens array can be obtained by predetermining the pressure difference and deforming the shape of the flexible mold mirror, and at the same time making it possible to obtain a high score after forming. 2. According to the method of applying for a patent range of microlens arrays, among which materials. The film structure layer is coated with a curable sorghum molecular structure layer and placed in an array of flexible film structure layers formed between the environment cavity and the cavity of the mold to form a micro-transparent cured polymer structure layer. Forming; substructure layer is solidified, and demolded to remove the application of the flexible mold described in item 1 to produce the elastomer material using PDMS polymer 3、 依申請專利範圍第1項所述之應用撓式模具製作 微透鏡陣列之方法,其中該撓式模具係以預先成型之光阻 模具脫模而成。 4、 依申請專利範圍第3項所述之應用撓式模具製作 微透鏡陣列之方法,其中該光阻模具係利用一基板上以黃 光微影技術製作出一預定高度呈圓柱狀之光阻層所形成, 而撓性模具係以PDMS聚合物以預定速度塗佈於光阻模具之3. A method of fabricating a microlens array using a flexural mold according to the first aspect of the patent application, wherein the flexural mold is demolded by a preformed photoresist mold. 4. A method for fabricating a microlens array using a flexural mold according to the third aspect of the patent application, wherein the photoresist mold is formed by using a yellow light lithography technique on a substrate to form a photoresist layer having a predetermined height and a cylindrical shape. Formed, and the flexible mold is coated with a PDMS polymer at a predetermined speed on the photoresist mold 第12頁 1283655 六、申請專利範圍 光阻層,並經適當時間與溫度之燒烤固化後脫模而成“ 料、涵依申請專利範圍第1項所述之應用撓式模具製作 朦、見列之方法’其中該高分子固化材料係採用UV固化 使其可利用紫外線光源照射產生固化者。 6、依申請專利範圍第1項所述之應用撓式模具製作 微透鏡陣列之方法,其中該環境腔體密封有一透明蓋,其 内部更連通有一空氣壓力幫浦,可藉以控制環境腔體之^ 部壓力。 7、依申請專利範圍第1項所述之應用撓式模具製作 微透鏡陣列之方法,其中該高分子結構層成形之壓力差範 圍為 1 0Okpa。Page 12 1283655 VI. Apply for the patented range of photoresist layer, and demolish it after curing at the appropriate time and temperature, and make the application of the flexible mold as described in item 1 of the patent application scope. The method of the invention wherein the polymer-cured material is UV-cured to be irradiated by an ultraviolet light source to produce a curing agent. 6. A method of manufacturing a microlens array using a flexural mold according to claim 1 of the patent application scope, wherein the environment The cavity seal has a transparent cover, and an air pressure pump is further connected therein to control the pressure of the environment cavity. 7. The method for manufacturing the microlens array by using the flex mold according to the first claim of the patent application scope The pressure difference in the formation of the polymer structural layer ranges from 10 kPa.
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