[go: up one dir, main page]

TWI277832B - Colored photosensitive resin composition - Google Patents

Colored photosensitive resin composition Download PDF

Info

Publication number
TWI277832B
TWI277832B TW092123123A TW92123123A TWI277832B TW I277832 B TWI277832 B TW I277832B TW 092123123 A TW092123123 A TW 092123123A TW 92123123 A TW92123123 A TW 92123123A TW I277832 B TWI277832 B TW I277832B
Authority
TW
Taiwan
Prior art keywords
photosensitive resin
resin composition
acid
colored photosensitive
pigment
Prior art date
Application number
TW092123123A
Other languages
Chinese (zh)
Other versions
TW200407674A (en
Inventor
Koji Ichikawa
Toshiya Inoue
Original Assignee
Sumitomo Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co
Publication of TW200407674A publication Critical patent/TW200407674A/en
Application granted granted Critical
Publication of TWI277832B publication Critical patent/TWI277832B/en

Links

Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
    • G03F7/033—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders the binders being polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B11/00—Diaryl- or thriarylmethane dyes
    • C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
    • C09B11/10—Amino derivatives of triarylmethanes
    • C09B11/24—Phthaleins containing amino groups ; Phthalanes; Fluoranes; Phthalides; Rhodamine dyes; Phthaleins having heterocyclic aryl rings; Lactone or lactame forms of triarylmethane dyes
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/22—Absorbing filters
    • G02B5/223—Absorbing filters containing organic substances, e.g. dyes, inks or pigments
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0005—Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor
    • G03F7/0007—Filters, e.g. additive colour filters; Components for display devices
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Optics & Photonics (AREA)
  • Materials For Photolithography (AREA)
  • Optical Filters (AREA)
  • Liquid Crystal (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Disclosed is a colored photosensitive resin composition containing (A) a coloring agent, (B) a binder resin, (C) a photopolymerizable compound, (D) a photopolymerization initiator, (E) a solvent, and (F) at least one surfactant selected from the group consisting of a silicon-containing surfactant, a fluorine-containing surfactant, and a silicon-containing surfactant having fluorine atoms; wherein component (F) is in an amount of 0.0005 weight parts to 0.14 weight parts based on 100 weight parts of the total amount of components (A), (B), (C), (D), and (E). In a 30 mL (height 65 mm and diameter 33 mm) of clean glass cylindrical brown bottle equipped with an octagon rotator (length 20 mm and diameter 6.5 mm), 15 mL of colored photosensitive resin composition is stirred with an octagon rotator at 700 rpm for 60 seconds, and laid aside for 600 seconds to defoam. Disclosed is also a method for producing, formulating, and patterning the colored photosensitive resin composition. When the colored photosensitive resin composition is patterned, a color filter can be produced therefrom, which can be used in a liquid crystal display device.

Description

1277832 玫、發明說明： 【發明所屬之技術領域】 本發明係關於著色感光性樹脂組成物。 【先前技術】 著色感光性樹脂組成物係含有著色劑的感光性樹脂 、、且成物’乃作為供形成構成彩色濾光片之著色圖案用的有 一/料在此所渭「彩色濾光片」係指供使用於將液晶顯 不I置的顯示圖像彩色化、或供將利用固體攝影元件所拍 攝至:的圖像予以彩色化之用的光學元件。所謂「著色圖案」 係指如紅、綠、藍等的顏色圖像、黑矩陣等，有線狀、或 鑲嵌（馬賽克）狀。 習知在晶圓等被塗布基板上採用著色感光性樹脂組 成物形成膜方面，有採用在被塗布基板中央處附近從塗布 裝置的喷嘴滴下著色感光性樹脂組成物之後，再使上述基 板依數百至數千rpm速度進行旋轉，使溶劑與過剩滴於基 板上的著色感光性樹脂組成物彈飛出去的旋塗機，而獲得 平坦的塗布膜。但是，纟此種塗布裝置中，從預先貯備著 色感光性樹脂組成物的槽中，通過配管等導向於喷嘴，通 常在噴嘴之前面設置去除粒子等之用的過濾器，在著色感 光性樹脂組成物通過此過濾器之際，將發生泡沫現象。此 泡沫若直接混入著色感光性樹脂組成物中，將由喷嘴帶到 基板等處，而造成發生紋斑等現象的原因。此外，在噴嘴 邛刀中，若於著色感光性樹脂組成物中混入空氣時，則在 經塗布後的膜中亦曾發生紋斑現象。 314979(修正本) 6 1277832 此外，塗布裝置若採用旋塗機的話，過剩滴於基板上 的著色感光性樹脂組成物將被彈飛掉，並未形成著色感光 性樹脂層，因為是被丟棄而造成浪費，因而為防止此現象， 便有開發減少對基板上的滴下量，且具狹縫狀噴嘴的省液 塗布機。 再者，為形成τν用等的彩色濾光 的玻璃等大面積基板上進行塗布的現象已有增加，但是頗 難使該等大面積基板依安定的高速度進行旋轉，因而為在 不致使基板旋轉的情況下進行大面積塗布，便有開發且狹 縫狀噴嘴的無旋轉塗布機等省液塗布機。相關上述省液塗 布機，譬如在日本專利特開2001-62370號公報中便有記 載。在具狹縫狀噴嘴的塗布機中，當從狹縫將著色感光性 樹脂組成物給予基板上之際，相較於普通喷嘴之下，具有 較容易混入空氣，@較容易發生氣泡的問題點。此外，、在 、!布：純’狹縫部分中將殘留著含氣泡的著色感光性樹 月二門：’由於此氣泡的緣故，4下次塗布時便會產生紋 、 匕見象田添加均塗劑等高分子添加劑、界面 活性劑之時，將有更明顯發生的傾向。 再者’即便將習知旋塗機 Λ .. 取彳土化者色感光性樹脂 η右 塗布機之其中1種的無旋轉塗布機 中，仍有頗難獲得平扫性 符“微 Μ业” 向。此理由乃因為旋塗機對 塗布狀恐的平坦性並非如 2 土機對 平坦性，且大部分溶劑將經旋轉㈣=而獲得某種程度 等而去除溶劑的過程中，在所二 =除’因此在經加熱 在所化成層内部中被去除溶劑的 314979(修正本) 7 1277832 去除量較少，因t 在無旋轉塗布機Γ 地損及平坦性之緣故。反之， 塗布狀態便、因為並未經由旋轉去除溶劑，因此由 溶劑去除旦二的平坦性’而且就經加熱等而去除的 所m里’相較於旋塗機之下顯然偏多，因此亦將從 以，\习二内部去除溶劑，結果便有平坦性惡化的傾向。所 為文良著色感光性樹脂組成物的塗布性方面， 有採用均塗劑等高分子添加劑的方法。 【發明内容】 # 么月之目的在於提供一種即便採用省液塗布機之 際’仍具優越塗布性的著色感光性樹脂組成物。 有鐘於斯，I發明者便#對上述待解決課題經深入鑽 研的結果，發現藉由特定之具消泡性著色感光性樹脂組成 物便可解決上述課題，遂完成本發明。 換句話說，本發明乃相關下述發明。 &lt; 1 &gt; 一種著色感光性樹脂組成物，係含有（A)著色 劑、（B)黏結樹脂、（C)光聚合性化合物、（D)光聚合起始劑、 (E)溶劑、以及（F)由矽酮系界面活性劑、氟系界面活性劑、 與具氟原子的石夕朗I系界面活性劑所構成組群中至少選擇1 種的界面活性劑； 其中，相對於除（F)成分以外之其餘成分總計每1〇〇重 量份，（F)成分係含有0.0005重量份至〇14重量份； 在具備八角轉子（全長20mm、直徑6.5mm)之容量 30mL(高度65mm、直徑33mm)的潔淨玻璃製圓筒狀褐色瓶 中，將1 5mL著色感光性樹脂組成物利用八角轉子以旋轉 8 314979(修正本) 1277832 數7〇〇rpm進行60秒鐘攪拌之後，再經靜置600秒時，便 呈消泡狀態者。 &lt; 2 &gt;如 &lt; 丨 &gt; 所述之著色感光性樹脂組成物，其中， 依著色感光性樹脂組成物之固形分中的質量分率計，（B) 黏結聚合物之含量為5至4〇%。 &lt; 3 &gt; —種著色感光性樹脂組成物之製造方法，係在 合（A)著色劑、（B)黏結樹脂、（C)光聚合性化合物、（D)光 來合起始劑、及斤）溶劑的混合物中，將由矽酮系界面 活性劑、氟系界面活性劑、與具氟原子的矽酮系界面活性 劑所構成組群中至少選擇丨種的界面活性劑，依相對於除 (F)成分以外之其餘成分總計每100重量份，添加0.0005 重里伤至0.14重量份者。 &lt; 4 &gt; 一種著色感光性樹脂組成物之調整方法，係在 將（A)著色劑、（B)黏結聚合物、光聚合性化合物、（〇) 光水合起始劑、（E)溶劑、以及由矽酮系界面活性劑、 氟系界面活性劑、與具氟原子的矽酮系界面活性劑所構成 組群中選擇至少1種的界面活性劑進行混合時， 依除（F)成分以外之其餘成分總計每1〇〇重量份，將（f) 成分的添加量，調整為〇·〇〇〇5重量份至〇14重量份的範 圍，使之在具備八角轉子（全長2〇mm、直徑6」mm)之容量 3OmL(间度65mm、直控33mm)的潔淨玻璃製圓筒狀褐色瓶 中將1 5mL著色感光性樹脂組成物利用八角轉子以旋轉 數700rpm進行60秒鐘攪拌後，再經靜置6〇〇秒後，便呈 消泡狀態。 314979(修正本） 9 I277832 &lt; 5 &gt; —種著色感光性樹脂組成物塗布層之形成方 去，係將如&lt; 1 &gt;或&lt; 2 &gt;所述之著色感光性樹脂組成物， 才木用無旋轉塗布機（spinless c〇ater)進行塗布，而在基板上 形成由著色感光性樹脂組成物所構成的層。 &lt; 6 &gt; —種圖案之形成方法，係將如〈丨〉或〈2 &gt;所 述之著色感光性樹脂組成物，塗布於基板上，再從所塗布 的著色感光性樹脂組成物層中去除揮發成分，經由光罩對 上述層進行曝光，顯影為圖案者。 &lt;7&gt;—種彩色濾光片，係含有依如&lt;6&gt;所述之方法 所形成的圖案。 &lt; 8 &gt;種液晶顯示裝置，係安裝著如&lt; 7 &gt;所述之彩 色濾光片（color filter)者。 【實施方式】 本發明的著色感光性樹脂組成物中所採用的（A)著色 劑’可為屬於有機物的有機顏料，亦可為屬於無機物的無 機顏料。其中，就從耐熱性、發色性優越的觀點而言，最 好採用有機顏料。 有機顏料與無機顏料，具體而言可舉例如··在色彩浐 南（The Society of Dyers and Colourists 公司八—、士、 、 Α㈠發行）中被歸 類為顏料（Pigment)的化合物。具體而言， J舉例如：C. I. 顏料黃1、C.I.顏料黃3、C丄顏料黃12、CI顏料黃13、 C.I.顏料黃Μ、C.I.顏料黃15、C.L顏料黃16 ' c丨顏料普 顏料黃53、c.i.顏料黃μ、c.][•顏料黃86 二 .. l ·1 ·顏料育9 3、 314979(修正本) 10 1277832 C.I.顏料黃94、C.I.顏料黃109、C.I.顏料黃110、C.I.顏料 黃117、C.I·顏料黃125、C.I.顏料黃128、C.I·顏料黃137、 C.I.顏料黃138、C.I.顏料黃139、C.I.顏料黃147、C.I·顏 料黃148、C.I.顏料黃150、C.I.顏料黃153、C.I.顏料黃154、 C.I.顏料黃166、C.I.顏料黃173、C.I.顏料黃194、C.I·顏 料黃2 1 4等黃色顏料； C.I.顏料橙13、CJ.顏料橙31、C.I.顏料橙36、C.I. 顏料橙38、C.I.顏料橙40、C.I.顏料橙42、C.I.顏料橙43、 C.I.顏料橙51、C.I.顏料橙55、C.I.顏料橙59、C.I.顏料橙 61、C.I.顏料橙 64、C.I.顏料橙 65、C.I.顏料橙 71、C.I· 顏料橙73等橙色顏料； C.I.顏料紅9、C.I.顏料紅97、C.I.顏料紅 105、C.I. 顏料紅122、C.I.顏料紅123、C.I.顏料紅144、C.I.顏料紅 149、C.I.顏料紅 166、C.I.顏料紅 168、C.I.顏料紅 176、 C.I.顏料紅177、C.I.顏料紅180、C.I.顏料紅192、C.I.顏 料紅209、C.I.顏料紅215、C.I·顏料紅216、C.I.顏料紅224、 C.I.顏料紅242、C.I.顏料紅254、C.I.顏料紅264、C.I.顏 料紅、C.I.顏料紅265等紅色顏料； C.I.顏料藍15、C.I.顏料藍15 ·· 3、C.I·顏料藍15 ·· 4、 C.I·顏料藍15 : 6、C.I·顏料藍60等藍色顏料； C.I.顏料紫1、C.I·顏料紫19、C.I.顏料紫23、C.I.顏 料紫29、C.I.顏料紫32、C.I·顏料紫36、C.I·顏料紫38等 紫色顏料； C.I·顏料綠7、C.I·顏料綠36等綠色顏料； 11 314979(修正本） 1277832 C.1.顏料棕23、C.I.顏料棕25等棕色顏料； Η·1.顏料黑7等黑色顏料。最好含有從 =^138、叫_139、^顏料黃1^顏 科、.工 177、C丄顏料紅 2〇9 ^ C.I.顏料K 15. 6 s 、种、254 C丄顏料紫23、 顏料者。 及C.I.顏料綠36中至少選擇其中1種 使用！1有機顏料與無機顏料可各自單獨使用，亦可混合 /上’譬如在形成紅色圖像時，最好含有C I || 顏料黃139,而在形成綠色圖像時，最好 至少、異摆1錄彔36、C I.顏料黃150、C.1·顏料黃138中 ^ = 種之顏料，在形成藍色圖像時，最好含有C I. 顏料藍15 : 6。 β … 2顏料中’有機顏料亦可施行如··松香處理、採用 “生基或驗性基之顏料衍生物等的表面處理、利用 合物等對顏料表面施行接枝處理、利用硫酸微粒 水等立1 匕處理、或利用供去除雜質用的有機溶劑或 、利用離子性雜質的離子交換法等施行 去除處理等等處理。 上述（Α)著色劑之使用量係當將著色感光性樹脂組成 句中的固形分設定4 _ f量份之時，通常在8質量份至 6〇質量份’最好為15質量份至55質量份，尤以25質量 :至5〇質量份以下為佳。若顏料含量在8質量份至60質 ϊ份’在當作彩色濾光片使用時的顏色濃度將充足，且因 為在組成物中含有需要量的黏結樹脂，因此可形成機械強 12 314979(修正本) 1277832 度足夠的圖案’所以屬於 「著色竭j W &amp; 狀况此外，本發明中所謂 餘成分的總計。 、口形为」係指除溶劑外之其 劑的= =著色感光性樹脂組成物’最好屬於著色 藉由蔣I 。因為將顏料設定為均勾粒徑的話， 劑且施分之外的界面活性劑當作顏料分散 態的顏料分:；。獲得顏料在溶液中呈均勻分散狀 類、2顏料分散劑可舉例如：聚醋類、聚環氧乙烯烷醚 ?衣氧乙烯烷基苯基醚類、聚乙二醇二酯類、山梨糖 類酐：肪酸醋类員、脂肪酸改質聚醋類、三級胺改質聚胺酯 、、來乙烯亞胺類等界面活性劑等等。該等可單獨使用1 種或組合使用2種以上。 相對方；著色劑每丨質量份，通常顏料分散劑的使用量 在1質量份以下，最好在〇 〇5質量份至〇·5質量份。若相 2於著色劑每1質量份上述顏料分散劑的使用量，通常設 义在1質量份以下時，便具有可獲得均勻粒徑顏料的傾 向’乃屬較佳狀況。 本發明所採用的（Β)黏結聚合物，可使用丙烯酸系共聚 物’譬如含羧基之單體、及和能與其進行共聚合之其他單 體的共聚物等。 δ緩基之早體可舉例如：不飽和單緩酸、不飽和二魏 酸、不飽和三羧酸等等不飽和多元羧酸等的分子中至少具 有1個緩基的不飽和緩酸。在此，不飽和單魏酸可舉例如： 13 314979(修正本） 1277832 丙烯酸、甲基丙烯酸、巴豆酸、α -氣丙烯酸、肉桂酸等。 不飽和二羧酸可舉例如：順丁烯二酸、反丁烯二酸、衣康 酸、檸康酸、甲基富馬酸等。不飽和多元羧酸可為其酸酐， 具體而言，可為如：順丁稀二酸酐、衣康酸酐、檸康酸酐 等。此外，不飽和多元羧酸可為其單（2-甲基丙烯醯氧基烷 酯），譬如：琥站酸單（2-丙烯醯氧基乙酯）、琥珀酸單（2_ 甲基丙細贐氧基乙酯）、鄰苯二甲酸單（2-丙烯醯氧基乙 酯）、鄰苯二甲酸單（2-甲基丙稀醯氧基乙酯）等。不飽和多 元羧酸亦可為二末端為二羧基聚合物的單（甲基）丙烯酸 酯，可如ω -羧基聚己内酯單丙烯酸酯、ω -羧基聚己内酯 單甲基丙烯酸S旨等。該等含羧基的單體可單獨使用或混合 使用2種以上。 上述能與含魏基之單體共聚合的其他單體，可舉例 如··苯乙烯、α_甲基笨乙烯、鄰乙烯基甲苯、間乙烯基甲 笨、對乙烯基甲笨、對氯苯乙烯、鄰甲氧基苯乙烯、間甲 氧基苯乙烯、對甲氧基苯乙烯、鄰乙烯基苄基曱醚、間乙 烯基Τ基甲醚、對乙烯基苄基甲醚、鄰乙烯基苄基縮水甘 油醚、間乙烯基苄基縮水甘油醚、對乙烯基苄基縮水甘油 醚、茚等芳香族乙烯化合物； 丙浠酸甲酯、甲基丙烯酸甲酯、丙烯酸乙酯、甲基丙 烯酸乙酯、丙烯酸正丙酯、甲基丙烯酸正丙酯、丙烯酸異 丙酯、曱基丙烯酸異丙酯、丙烯酸正丁酯、甲基丙烯酸正 丁酯、丙烯酸異丁酯、曱基丙烯酸異丁酯、丙烯酸第二丁 酯、曱基丙烯酸第二丁酯、丙烯酸第三丁酯、曱基丙烯酸 14 314979(修正本） 1277832 第三丁 S旨' 丙烯酸2 -經乙醋、甲基丙稀酸2 -經乙、丙埽 酸2 -髮丙酉旨、曱基丙稀酸2 -經丙酷、丙稀酸3 -經丙酉旨、甲 基丙烯酸3-羥丙酯、丙烯酸2-羥丁酯、曱基丙烯酸2-羥丁 SI、丙烯酸3 -經丁 S旨、曱基丙稀酸3 -經丁醋、丙稀酸4 -羥丁酯、曱基丙烯酸4-羥丁酯、丙烯酸烯丙酯、甲基丙稀 酸烯丙酯、丙烯酸苄酯、甲基丙烯酸苄酯、丙烯酸環己酯、 甲基丙烯酸環己酯、丙烯酸苯酯、曱基丙烯酸苯酯、丙歸 酸2 -甲氧基乙g旨、甲基丙稀酸2 -甲氧基乙S旨、丙稀酸2、 苯氧基乙酯、曱基丙烯酸2-苯氧基乙酯、丙烯酸甲氧基二 甘醇酯、甲基丙烯酸甲氧基二甘醇酯、丙烯酸甲氧基三甘 醇酯、曱基丙烯酸曱氧基三甘醇酯、丙烯酸甲氧基丙二醇 酯、甲基丙烯酸甲氧基丙二醇酯、丙烯酸甲氧基二丙二醇 酯、甲基丙烯酸曱氧基二丙二醇酯、丙烯酸甲氧基異冰片 酯、曱基丙烯酸異冰片酯、丙烯酸二環戊二烯酯、甲基丙 烯酸二環戊二烯酯、丙烯酸2-羥基-3-苯氧基丙酯、曱基丙 烯酸2-羥基-3-苯氧基丙酯、丙三醇單丙烯酸酯、丙三醇單 甲基丙烯酸酯等不飽和羧酸酯類； 丙烯酸2-胺基乙酯、甲基丙烯酸2-胺基乙酯、丙烯酸 2-二曱胺基乙酯、甲基丙烯酸2-二甲胺基乙酯、丙烯酸2-胺基丙酯、甲基丙烯酸2-胺基丙酯、丙烯酸2-二甲胺基丙 酯、曱基丙烯酸2-二甲胺基丙酯、丙烯酸3-胺基丙酯、甲 基丙烯酸3-胺基丙酯、丙烯酸3-二甲胺基丙酯、甲基丙烯 酸3-二甲胺基丙酯等不飽和羧酸胺烷基酯類； 丙稀酸縮水甘油酯、甲基丙稀酸縮水甘油醋專不飽和 15 314979(修正本） 1277832 叛酸縮水甘油酯類； 醋酸乙烯、丙酸乙烯、丁酸乙烯、苯甲酸乙烯等羧酸 乙烯酯類； 乙烯甲醚、乙烯乙醚、烯丙基縮水甘油醚等不飽和醚 類； ’ 丙烯腈、甲基丙烯腈、α_氯丙烯腈、氰化亞乙烯等氰 化乙烯化合物； 丙稀酿胺、曱基丙烯醯胺、α_氯丙烯醯胺、Ν_八羥乙 基丙烯醯胺、Ν-2-羥乙基曱基丙烯醯胺等不飽和醯胺類； 順丁烯二醯亞胺、Ν-苯基順丁烯二醯亞胺、Ν_環己基 順丁沐一 &amp;&amp;亞胺寺不飽和酸亞胺類； 1，3-丁二烯、異戊二烯、氯丁二烯等脂肪族共軛二烯 類； 甲基丙烯酸甲酯、聚丙 、聚矽氧烷之聚合物分 聚本乙烯、聚丙稀酸甲酷、聚 烯酸正丁酯、聚甲基丙烯酸正丁酯 子鏈末端具有單丙烯醯氧基或單甲基丙稀醯氧基的巨單體 類等。該料體分別可單獨使用或混合使用2種以上。 上述共聚物中，含縣單體單位含量，依質量分率 計’通常為1〇至50質量％，最好為15至4〇質量％，特 ，乙25至40質s %為佳。上述含缓基單體單位含量若設 定為1 0至5 0質量％瞎，射θ5〜 、+絲員衫液的溶解性較佳，在顯影 時具有正確地形成圖㈣傾向，屬較佳狀況。 314979(修正本） 16 1277832 物、（曱基）丙烯酸/(曱基）丙烯酸2-羥乙酯/(甲基）丙烯酸苄 酯共聚物、（甲基）丙烯酸/(甲基）丙烯酸甲酯/聚苯乙烯巨單 體共聚物、（甲基）丙烯酸/(曱基）丙烯酸曱酯/聚（甲基）丙烯 酸甲酯巨單體共聚物、（曱基）丙烯酸从曱基）丙烯酸苄酯/聚 苯乙烯巨單體共聚物、（甲基）丙烯酸/(甲基）丙烯酸苄酯/聚 (曱基）丙烯酸甲酯巨單體共聚物、（曱基）丙烯酸/(曱基）丙 烯酸2-羥乙酯/(甲基）丙烯酸苄酯/聚苯乙烯巨單體共聚 物、（曱基）丙烯酸/(甲基）丙烯酸2-羥乙酯/(甲基）丙烯酸苄 酯/聚（甲基）丙烯酸甲酯巨單體共聚物、（曱基）丙烯酸/苯乙 烯/(甲基）丙烯酸T酯/N-苯基順丁烯二醯亞胺共聚物、（甲 基）丙烯酸/琥珀酸單（2-丙烯醯氧基乙酯）/苯乙浠/(甲基）丙 烯酸苄酯/N-苯基順丁烯二醯亞胺共聚物、（甲基）丙烯酸/ 琥轴酸單（2-丙烯醯氧基乙酯）/苯乙烯/(曱基）丙烯酸烯丙 酯/N-苯基順丁烯二醯亞胺共聚物、（甲基）丙烯酸/(甲基）丙 烯酸T酯/N-苯基順丁烯二醯亞胺/苯乙烯/丙三醇單（甲基） 丙烯酸酯共聚物等。另外，所謂「（甲基）丙浠酸酯」係指 丙烯酸酯、或甲基丙烯酸酯。 其中，最好為（甲基）丙烯酸/(甲基）丙烯酸苄酯共聚 物、（甲基）丙烯酸/(甲基）丙烯酸苄酯/苯乙烯共聚物、（甲 基）丙烯酸/(甲基）丙烯酸甲酯共聚物、（甲基）丙烯酸/(甲基） 丙烯酸甲酯/苯乙烯共聚物等。 上述丙烯酸系聚合物的聚苯乙烯換算重量平均分子 量（以聚苯乙烯為標準品，利用凝膠滲透層析儀所求得 值），通常為5,000至50,000，最好為8,000至40,000範圍 17 314979(修正本) 1277832 内’特別以1〇,00…5，_為佳 50,000的話，便且有涂 子里為5,〇00至 光部分對顯影液的溶解,&amp; &quot;未曝 較佳狀況。 _^土且解像度提昇的傾向，乃屬 酸值通常為50至15〇，爭拉也α 至135 μ + 取好為60至1切，特別以80 為仏。右上述酸值在50至150的話，對顯影 解性將提昇，未曝光部 ' 、心 化顯影時將有殘留曝光部 “感度 較佳狀況。在此之酸值係針膜率的傾向，屬於 需要气气化钿 ’、、“共聚物ig進行中和時所 而要風乳化鉀Ϊ (mg)的測量值， 液進行滴定而進行求取。“可㈣聽化鉀水溶[Technical Field of the Invention] The present invention relates to a coloring photosensitive resin composition. [Prior Art] The coloring photosensitive resin composition is a photosensitive resin containing a coloring agent, and the product 'is used as a coloring pattern for forming a coloring pattern constituting a color filter. It is an optical element for coloring a display image in which liquid crystal display is not set, or for coloring an image captured by a solid-state imaging device. The "coloring pattern" refers to a color image such as red, green, or blue, a black matrix, or the like, and is linear or mosaic (mosaic). In order to form a film by using a colored photosensitive resin composition on a substrate to be coated such as a wafer, it is preferable to drop the colored photosensitive resin composition from the nozzle of the coating device in the vicinity of the center of the substrate to be coated, and then to apply the substrate to the substrate. The coating was carried out at a speed of several hundred to several rpm to obtain a flat coating film by blowing a solvent and a coloring photosensitive resin composition which was excessively dropped on the substrate. However, in the above-mentioned coating apparatus, a nozzle for removing a particle or the like is provided in a groove in which a coloring photosensitive resin composition is stored in advance, and a filter for removing particles or the like is provided in front of the nozzle, and the photosensitive resin is colored. As the object passes through the filter, a foaming phenomenon will occur. When the foam is directly mixed into the coloring photosensitive resin composition, it is carried by the nozzle to the substrate or the like, causing a phenomenon such as smear. Further, in the nozzle trowel, when air is mixed in the colored photosensitive resin composition, smear phenomenon also occurs in the coated film. 314979 (Revised) 6 1277832 In addition, if a coating machine is used as a spin coater, the colored photosensitive resin composition which is excessively dropped on the substrate will be flung off, and the colored photosensitive resin layer is not formed because it is discarded. In order to prevent this, it is possible to develop a liquid-saving coater that reduces the amount of dripping on the substrate and has a slit-like nozzle. Further, the phenomenon of coating on a large-area substrate such as glass for color filter of τν or the like has been increased. However, it is difficult to rotate the large-area substrates at a high speed, so that the substrate is not caused. In the case of large-area coating in the case of rotation, there is a liquid-saving coater such as a spin coater which develops a slit nozzle. The above-mentioned liquid-saving coating machine is described in Japanese Patent Laid-Open Publication No. 2001-62370. In the coater having the slit nozzle, when the colored photosensitive resin composition is applied to the substrate from the slit, it is easier to mix air than the ordinary nozzle, and the problem of bubble generation is more likely to occur. . In addition, in, cloth: pure 'slit part will remain with the bubble-colored coloring tree 2: 'Because of this bubble, 4 will be produced when the next coating, 匕 see Xiangtian added When a polymer additive such as a coating agent or a surfactant is used, there is a tendency that it is more likely to occur. Furthermore, even if it is a conventional spin coating machine, it is difficult to obtain a plain sweeping character "micro-small industry" in one of the non-rotating coaters of the earth-based coloring photosensitive resin η right coating machine. . The reason for this is that the flatness of the spin coater for the coating is not as good as the flatness of the machine, and most of the solvent will be rotated (four) = to obtain a certain degree and the like to remove the solvent, in the second = 'Therefore, the amount of removal of 314979 (Revised) 7 1277832, which was removed by heating in the interior of the chemical layer, was less, because t was not damaged by flatness in the spin coater. On the other hand, since the coating state is not removed by the rotation of the solvent, the flatness of the denier is removed by the solvent, and the m-removed by heating or the like is apparently more than that under the spin coater. The solvent will be removed from the inside of the kitchen, and as a result, the flatness tends to deteriorate. In view of the coatability of the composition of the photosensitive resin composition, there is a method of using a polymer additive such as a leveling agent. SUMMARY OF THE INVENTION The purpose of the month is to provide a colored photosensitive resin composition which is excellent in coating properties even when a liquid-absorbent coater is used. As a result of intensive studies on the above-mentioned problems to be solved, it has been found that the above problems can be solved by a specific antifoaming coloring photosensitive resin composition, and the present invention has been completed. In other words, the present invention relates to the following invention. &lt; 1 &gt; A colored photosensitive resin composition comprising (A) a colorant, (B) a binder resin, (C) a photopolymerizable compound, (D) a photopolymerization initiator, (E) a solvent, and (F) at least one surfactant selected from the group consisting of an anthrone-based surfactant, a fluorine-based surfactant, and a Shishalang I-based surfactant having a fluorine atom; wherein, (F) component contains 0.0005 parts by weight to 〇 14 parts by weight of the remaining components other than the F) component; 30 mL of the octagonal rotor (full length 20 mm, diameter 6.5 mm) (height 65 mm, diameter) In a clean glass cylindrical brown bottle of 33 mm), 15 mL of the colored photosensitive resin composition was stirred by an octagonal rotor by rotating 8 314 979 (revision) 1277832 at 7 rpm for 60 seconds, and then allowed to stand. At 600 seconds, it is in a defoaming state. (2) The colored photosensitive resin composition according to the above, wherein (B) the content of the binder polymer is 5, based on the mass fraction in the solid content of the coloring photosensitive resin composition. Up to 4〇%. &lt; 3 &gt; — A method for producing a colored photosensitive resin composition, which comprises a (A) colorant, (B) a binder resin, (C) a photopolymerizable compound, (D) a photopolymerization initiator, In the mixture of the solvent and the solvent, at least a surfactant selected from the group consisting of an anthrone-based surfactant, a fluorine-based surfactant, and an anthrone-based surfactant having a fluorine atom is used. The total amount of the components other than the component (F) is 0.0001 parts by weight to 0.14 parts by weight per 100 parts by weight. &lt; 4 &gt; A method for adjusting a coloring photosensitive resin composition, which comprises (A) a coloring agent, (B) a binding polymer, a photopolymerizable compound, (〇) a photo-hydration initiator, and (E) a solvent And when at least one type of surfactant is selected from the group consisting of an anthrone-based surfactant, a fluorine-based surfactant, and an anthrone-based surfactant having a fluorine atom, the component (F) is removed. In addition to the total amount of the other components, the amount of the component (f) is adjusted to a range of 5 parts by weight to 14 parts by weight, so that it has an octagonal rotor (full length 2 〇 mm) In a clean glass cylindrical brown bottle having a capacity of 3" mL (a diameter of 65 mm and a direct control of 33 mm) in a diameter of 6 mm), 15 mL of the colored photosensitive resin composition was stirred by an octagonal rotor at 700 rpm for 60 seconds. After standing for 6 seconds, it will be defoamed. 314979 (Revised) 9 I277832 &lt; 5 &gt; - The coloring photosensitive resin composition as described in &lt;1&gt; or &lt;2&gt; The wood is coated with a spinless coating machine to form a layer composed of a colored photosensitive resin composition on the substrate. &lt; 6 &gt; A method of forming a pattern by applying a colored photosensitive resin composition as described in <丨> or <2> to a substrate, and then forming a layer of the colored photosensitive resin layer to be applied The volatile component is removed, and the layer is exposed through a photomask to be developed into a pattern. &lt;7&gt; A color filter comprising a pattern formed by the method according to &lt;6&gt;. &lt;8&gt; A liquid crystal display device is a color filter as described in &lt;7&gt;. [Embodiment] The (A) colorant used in the colored photosensitive resin composition of the present invention may be an organic pigment belonging to an organic substance or an inorganic pigment belonging to an inorganic substance. Among them, organic pigments are preferred from the viewpoint of superior heat resistance and color developability. The organic pigment and the inorganic pigment may, for example, be classified as a pigment (Pigment) in Color Society (issued by The Society of Dyers and Colourists, Inc.). Specifically, J. For example: CI Pigment Yellow 1, CI Pigment Yellow 3, C丄 Pigment Yellow 12, CI Pigment Yellow 13, CI Pigment Astragalus, CI Pigment Yellow 15, CL Pigment Yellow 16 'c丨 Pigment Pigment Yellow 53, ci pigment yellow μ, c.] [• pigment yellow 86 II.. l · 1 · pigment breeding 9 3, 314979 (amendment) 10 1277832 CI pigment yellow 94, CI pigment yellow 109, CI pigment yellow 110, CI Pigment Yellow 117, CI·Pigment Yellow 125, CI Pigment Yellow 128, CI·Pigment Yellow 137, CI Pigment Yellow 138, CI Pigment Yellow 139, CI Pigment Yellow 147, CI·Pigment Yellow 148, CI Pigment Yellow 150, CI Pigment Yellow 153, yellow pigments such as CI Pigment Yellow 154, CI Pigment Yellow 166, CI Pigment Yellow 173, CI Pigment Yellow 194, CI·Pigment Yellow 2 1 4; CI Pigment Orange 13, CJ. Pigment Orange 31, CI Pigment Orange 36, CI Pigment Orange 38, CI Pigment Orange 40, CI Pigment Orange 42, CI Pigment Orange 43, CI Pigment Orange 51, CI Pigment Orange 55, CI Pigment Orange 59, CI Pigment Orange 61, CI Pigment Orange 64, CI Pigment Orange 65, CI Orange pigments such as Pigment Orange 71, CI·Pigment Orange 73; CI Pigment Red 9, CI Pigment Red 97, CI Pigment Red 105, CI Red 122, CI Pigment Red 123, CI Pigment Red 144, CI Pigment Red 149, CI Pigment Red 166, CI Pigment Red 168, CI Pigment Red 176, CI Pigment Red 177, CI Pigment Red 180, CI Pigment Red 192, CI Red pigments such as Pigment Red 209, CI Pigment Red 215, CI·Pigment Red 216, CI Pigment Red 224, CI Pigment Red 242, CI Pigment Red 254, CI Pigment Red 264, CI Pigment Red, CI Pigment Red 265, etc. CI Pigment Blue 15. CI Pigment Blue 15 ·· 3, CI·Pigment Blue 15 ·· 4, CI·Pigment Blue 15 : 6. Blue pigment such as CI·Pigment Blue 60; CI Pigment Violet 1, CI·Pigment Violet 19, CI Pigment Purple pigments such as Violet 23, CI Pigment Violet 29, CI Pigment Violet 32, CI·Pigment Violet 36, CI·Pigment Violet 38; Green pigments such as CI·Pigment Green 7, CI·Pigment Green 36; 11 314979 (Revised) 1277832 C.1. Pigment brown 23, CI pigment brown 25 and other brown pigments; Η·1. Pigment black 7 and other black pigments. It is best to contain from = ^ 138, called _139, ^ Pigment Yellow 1 ^ Yanke, . 177, C 丄 Pigment Red 2 〇 9 ^ CI Pigment K 15. 6 s, species, 254 C 丄 Pigment Violet 23, Pigment By. And at least one of C.I. Pigment Green 36 is used! 1 organic pigments and inorganic pigments may be used alone or in combination/upper. For example, when forming a red image, it is preferable to contain CI || pigment yellow 139, and when forming a green image, it is preferable to at least Recording 36, C I. Pigment Yellow 150, C.1·Pigment Yellow 138, the pigment of the species, when forming a blue image, preferably contains C I. Pigment Blue 15: 6. In the β 2 pigment, the 'organic pigment can also be treated with rosin as a rosin, surface treatment with a pigment derivative such as a bio-based or an experimental group, graft treatment of the surface of the pigment with a compound or the like, and use of sulfuric acid particulate water. The treatment is carried out by using an organic solvent for removing impurities or an ion exchange method using ionic impurities, etc. The removal amount of the above-mentioned (Α) coloring agent is composed of a colored photosensitive resin. When the solid content in the sentence is set to 4 _f parts, it is usually 8 parts by mass to 6 parts by mass 'preferably 15 parts by mass to 55 parts by mass, particularly preferably 25 parts by mass to 5 parts by mass or less. If the pigment content is from 8 parts by mass to 60 parts by mass, the color concentration will be sufficient when used as a color filter, and since the required amount of binder resin is contained in the composition, a mechanical strength of 12 314979 can be formed (corrected) This is a sufficient pattern of 1277832 degrees, so it belongs to "coloring exhausted j W &amp; condition, in addition, the total amount of the remaining components in the present invention. The mouth shape is" means the agent other than the solvent = = coloring photosensitive resin composition Object Preferably it belongs colored by Jiang I. Since the pigment is set to a uniform particle size, the surfactant other than the agent is used as a pigment in a pigment dispersion state:; The pigment is uniformly dispersed in the solution, and the pigment dispersant may be, for example, a polyacetate, a polyethylene oxide alkyl ether, an oxyethylene alkyl phenyl ether, a polyethylene glycol diester, or a sorbose. Anhydride: a fatty acid vinegar, a fatty acid modified polyacetate, a tertiary amine modified polyurethane, a surfactant such as ethyleneimine, and the like. These may be used alone or in combination of two or more. The amount of the pigment dispersant used is usually 1 part by mass or less, preferably 5 parts by mass to 〇 5 parts by mass per part by mass of the colorant. When the amount of the pigment dispersant used per 1 part by mass of the colorant is usually 1 part by mass or less, it is preferable to have a tendency to obtain a pigment having a uniform particle size. As the (Β) binder polymer to be used in the present invention, an acrylic copolymer such as a carboxyl group-containing monomer and a copolymer of another monomer copolymerizable therewith can be used. The early form of the δ retardation group may, for example, be an unsaturated buffer acid having at least one slow group in a molecule such as an unsaturated monobasic acid, an unsaturated dicarboxylic acid or an unsaturated tricarboxylic acid. Here, as the unsaturated monowei acid, for example, 13 314979 (amendment) 1277832 acrylic acid, methacrylic acid, crotonic acid, α-gas acrylic acid, cinnamic acid or the like can be mentioned. The unsaturated dicarboxylic acid may, for example, be maleic acid, fumaric acid, itaconic acid, citraconic acid or methyl fumaric acid. The unsaturated polycarboxylic acid may be an acid anhydride thereof, and specifically, for example, cis-succinic anhydride, itaconic anhydride, citraconic anhydride or the like. Further, the unsaturated polycarboxylic acid may be a mono(2-methylpropenyloxyalkyl ester) such as a succinic acid mono(2-propenyloxyethyl ester) or a succinic acid mono(2-methylpropanyl fine).赆 methoxyethyl ester), phthalic acid mono(2-propenyl methoxyethyl ester), phthalic acid mono (2-methyl propyl methoxyethyl ester), and the like. The unsaturated polycarboxylic acid may also be a mono(meth)acrylate having a dicarboxyl polymer at the two ends, and may be, for example, ω-carboxypolycaprolactone monoacrylate, ω-carboxypolycaprolactone monomethacrylic acid Wait. These carboxyl group-containing monomers may be used singly or in combination of two or more. The other monomer capable of copolymerizing with the Wei group-containing monomer may, for example, be styrene, α-methyl styrene, o-vinyltoluene, m-vinyl phenyl, p-vinyl phenyl, p-chloro Styrene, o-methoxystyrene, m-methoxystyrene, p-methoxystyrene, o-vinylbenzyl oxime ether, m-vinyl decyl methyl ether, p-vinylbenzyl methyl ether, o-ethylene Alkyl benzyl glycidyl ether, m-vinylbenzyl glycidyl ether, p-vinylbenzyl glycidyl ether, an aromatic vinyl compound such as hydrazine; methyl propyl acrylate, methyl methacrylate, ethyl acrylate, methyl Ethyl acrylate, n-propyl acrylate, n-propyl methacrylate, isopropyl acrylate, isopropyl methacrylate, n-butyl acrylate, n-butyl methacrylate, isobutyl acrylate, isobutyl methacrylate Ester, second butyl acrylate, second butyl methacrylate, third butyl acrylate, methacrylic acid 14 314979 (amendment) 1277832 third butyl s 'acrylic acid 2 - acetonitrile, methyl acrylate 2 - by B, propionate 2 - hairpin, thiol propylene 2 - by propylene, acrylic acid 3 - by propyl acetate, 3-hydroxypropyl methacrylate, 2-hydroxybutyl acrylate, 2-hydroxybutyric acid hydrazide, acrylic acid 3-- Acrylic acid 3 - butyl vinegar, 4-hydroxybutyl acrylate, 4-hydroxybutyl methacrylate, allyl acrylate, allyl methacrylate, benzyl acrylate, benzyl methacrylate Ester, cyclohexyl acrylate, cyclohexyl methacrylate, phenyl acrylate, phenyl methacrylate, 2-methoxy ethoxylate, methyl methacrylate 2-methoxy ethane Acrylic acid 2, phenoxyethyl ester, 2-phenoxyethyl methacrylate, methoxy diglycol acrylate, methoxy diglycol methacrylate, methoxy triethylene glycol acrylate , decyl methoxy ethoxylated triethylene glycol acrylate, methoxy propylene glycol acrylate, methoxy propylene glycol methacrylate, methoxy dipropylene glycol acrylate, decyloxy dipropylene glycol methacrylate, methoxy acrylate Isobornyl ester, isobornyl methacrylate, dicyclopentadienyl acrylate, dicyclopentadienyl methacrylate, 2-hydroxy acrylate Unsaturated carboxylic acid esters such as 3-phenoxypropyl ester, 2-hydroxy-3-phenoxypropyl methacrylate, glycerol monoacrylate, glycerol monomethacrylate; 2-amine acrylate Ethyl ethyl ester, 2-aminoethyl methacrylate, 2-diguanylaminoethyl acrylate, 2-dimethylaminoethyl methacrylate, 2-aminopropyl acrylate, 2-amine methacrylate Propyl propyl ester, 2-dimethylaminopropyl acrylate, 2-dimethylaminopropyl methacrylate, 3-aminopropyl acrylate, 3-aminopropyl methacrylate, 3-dimethylamine acrylate Alkyl propyl esters of unsaturated carboxylic acids such as propyl propyl ester and 3-dimethylaminopropyl methacrylate; glycidyl acrylate, glycidyl methacrylate monounsaturated 15 314979 (amendment) 1277832 deglycoglycidyl esters; vinyl acetates such as vinyl acetate, ethylene propionate, ethylene butyrate, ethylene benzoate; unsaturated ethers such as vinyl methyl ether, ethylene ether, allyl glycidyl ether; 'propylene A vinyl cyanide compound such as nitrile, methacrylonitrile, α-chloroacrylonitrile or vinyl cyanide; acrylamide, mercapto acrylamide, α_ Unsaturated guanamines such as chloropropene decylamine, hydrazine _ octahydroxyethyl acrylamide, hydrazine-2-hydroxyethyl decyl acrylamide; maleimide, fluorenyl-phenyl-butene醯iamine, Ν_cyclohexyl cis-butan- &amp;&amp; imine temple unsaturated acid imines; 1,3-butadiene, isoprene, chloroprene and other aliphatic conjugated dienes Class; Methyl methacrylate, polyacrylic acid, polyoxyalkylene polymer polymerized with ethylene, polyacrylic acid methyl, n-butyl polyacrylate, polybutyl methacrylate sub-chain end with monopropylene oxide A macromonomer or a monomethyl propyl decyloxy group. These materials may be used alone or in combination of two or more. In the above copolymer, the content of the monomer unit per unit is usually from 1 to 50% by mass, preferably from 15 to 4% by mass, particularly preferably from 25 to 40% by mass, based on the mass fraction. When the content of the slow-containing monomer unit is set to 10 to 50% by mass, the solubility of the θ5~ and + silk fabrics is preferred, and the tendency to form the pattern (4) correctly during development is preferred. . 314979(Revised) 16 1277832, 2-hydroxyethyl (meth)acrylate/benzyl (meth)acrylate copolymer, (meth)acrylic acid/methyl (meth)acrylate/(meth)acrylic acid/(meth)acrylate/ Polystyrene macromonomer copolymer, (meth)acrylic acid/(mercapto)acrylic acid acrylate/poly(methyl) methacrylate macromonomer copolymer, (mercapto)acrylic acid benzyl (meth) acrylate/ Polystyrene macromonomer copolymer, (meth)acrylic acid/benzyl (meth)acrylate/poly(methyl methacrylate) macromonomer copolymer, (mercapto)acrylic acid/(mercapto)acrylic acid 2- Hydroxyethyl ester / benzyl (meth) acrylate / polystyrene macromonomer copolymer, (mercapto) acrylic acid / 2-hydroxyethyl (meth) acrylate / benzyl (meth) acrylate / poly (methyl Methyl acrylate macromonomer copolymer, (mercapto)acrylic acid/styrene/(meth)acrylic acid T ester/N-phenyl maleimide copolymer, (meth)acrylic acid/succinic acid single (2-propenyloxyethyl ester) / phenethyl hydrazine / benzyl (meth) acrylate / N-phenyl maleimide copolymer, (meth) acrylic acid / Succinic acid mono(2-propenyloxyethyl ester) / styrene / (mercapto) acrylic acid allyl ester / N-phenyl maleimide copolymer, (meth) acrylic acid / (methyl ) Acrylic acid T ester / N-phenyl maleimide / styrene / glycerol mono (meth) acrylate copolymer. Further, "(meth)propionate" means acrylate or methacrylate. Among them, preferred are (meth)acrylic acid/benzyl (meth)acrylate copolymer, (meth)acrylic acid/benzyl (meth)acrylate/styrene copolymer, (meth)acrylic acid/(methyl) A methyl acrylate copolymer, a (meth)acrylic acid/methyl (meth) acrylate/styrene copolymer, or the like. The polystyrene-equivalent weight average molecular weight of the above acrylic polymer (determined by a gel permeation chromatograph based on polystyrene), usually from 5,000 to 50,000, preferably from 8,000 to 40,000, 17 314,979 (Revised) 1277832 'Specially 1〇, 00...5, _ is 50,000, then there is 5 in the coating, 〇00 to the light part of the developer, &amp;&quot; situation. _^ soil and the tendency to increase the resolution is usually 50 to 15 酸, and the ratio of α to 135 μ + is preferably 60 to 1 cut, especially 80. When the acid value of the right side is from 50 to 150, the development property will be improved, and the unexposed portion will be formed in the unexposed portion and the residual exposure portion will be better. The acid value is the tendency of the needle ratio. It is necessary to measure the gas emulsified potassium Ϊ (mg) when the copolymer ig is neutralized, and the liquid is titrated and obtained. "Can (4) Hearing potassium water soluble

上述黏結聚合物係相#4. ^ I 固形份，依質量分“ Λ/ t光性樹脂組成物的 貝里刀旱口十，通常在5質量％至4〇質量％， 好在1 0質量％至35質量％， 旦 、 圍者為於。4 、 貝里〇/〇至26質量〇/〇範 ”、、土。右U黏結聚合物含量在5質量％至4〇質量0/〇 的話’便可形成圖案，而右 、 屬較佳狀況。 有^知像度及殘膜率之傾向， 本發明中所採用的（c)光聚合性化合物，係藉由光的照 射，並利用從光聚合起始劑所產生的活性自由基、酸等， 而可進行聚合的化合物，譬如具聚合性碳_碳不飽 合物等。 上述光聚合性化合物最好為3官能基以 光聚合性化合物。3官能美以μ μ夕— 基 j g此基以上的多官能基光聚合性化合 物可舉例如：季戍四醇三丙稀酸醋、季戊四醇三甲基丙烯 314979(修正本） 18 1277832 季戊四醇四丙烯酸酽 ^ -金# 歸 §曰、季戊四醇四甲基丙稀酸酯、 一半戊四醇五丙烯酸 _ 季戊四酶丄一李戊四醇五甲基丙婦酸醋、二 …酸酿、季戊四醇六甲 上 述先聚合性化合物分別 其使用旦佑-么、 早獨使用或組合使用2種以上， ”里、者色感光性樹脂組成物的質量分率計，通常在 以貝15\至45 f ，最好為1G質量％至35質量％，特別 以1 5質量。至2 6皙吾〇/从M m 儿人t 貝里/°的乾圍者為佳。若上述光聚合性 s里在5 1 1%至45質量％以下的話，硬化將充分 地進行且殘膜率將提昇，圖案不易發生底切現象而呈現密 接性佳的傾向，故屬較佳狀況。 本毛明中所採用的（D)光聚合起始劑，最好至少含1 種苯乙酮系化合物。 苯乙酮系化合物可舉例如：二乙氧基苯乙酮、&quot;基 -2-嗎啉代小（4_甲基硫代苯）丙烷小酮、2_經基冬甲基_卜 苯基丙烷-1-酮、苄基二甲基酮縮醇、2_羥基_2_曱基 -l-[4-(2-經基乙氧基）苯基]丙烷_丨_酮、經基環己基笨 酮、2-經基_2_甲基小[4_(1_甲基乙烯基）苯基]丙烧小晒之 寡聚物等’最好為2-甲基_2_嗎卩林代+(4_甲基硫代苯）丙院 -1 -酮等。 再者，亦可組合使用複數苯乙酮系及其他光聚合起始 劑。苯乙酮系以外的光聚合起始劑，可舉例如：藉由光之 照射而產生活性自由基的活性自由基產生劑、增感劑等。 活性自由基產生劑可舉例如：苯偶因系化合物、二苯甲酮 系化合物、噻噸酮系化合物、三嗪系化合物等。 314979(修正本) 19 1277832 苯偶 τ ·，，η -尽 偶因乙醚、苯偶因異丙醚、笨偶因異丁醚等 .. 亦田备彳I-人/Ur» ^咖 因系化合物可舉例如：苯偶 # /田m w π 馬因甲_、茉 本偶口異丙醚、1值 / ’、 J % 令 〇 苯甲酮糸化合物可舉例如· _ 4笨m 甲，、鄰笨醯基苯 曱酸曱酯、4-本暴一本曱_、4-笨醯_4，_甲其一 * 物 筮二丁甘 本基硫化 '甲Vi 化幾基)二苯甲酮、2,4,6- 曱基二苯甲酮寺。 噻噸S同系化合物可舉例如：2_異丙基噻噸a同、4·異丙 基噻噸酮、2,4_二乙基噻噸類1、2,4_二氣噻噸 /、 丙氧基噻噸®同等。 氣 三嗪系化合物可舉例如：2,4_雙（三氣甲基）·6·(4_甲氧 基苯基）-1，3,5·三嗪、2,4_雙（三氣甲基甲氧基^ 基）-1，3,5-—秦2’4雙（二氯甲基）-6-(4-甲氧基笨乙烯 基）-1，3,5-三嗪、2,仁雙（三氯甲基&gt;6·[2_(5•甲基呋喃基） 乙烯基]-1，3,5-三嗪、2,4-雙（三氯甲基）_6_[2_(呋喃_2_基）乙 烯基]-1，3,5-三嗪、2,4-雙（三氣甲基）-6-[2_(4_二乙胺基_2_ 甲基苯基）乙烯基]-1，3,5-三嗪、2,4-雙（三氯甲 基）-6-[2-(3,4-二甲氧基苯基）乙烯基扒^^三嗪等。 活性自由基產生劑可採用如·· 2,4,6-三甲基笨甲醯基 二苯基膦氧化物^’-雙丨鄰氯苯基^^””-四苯基-〗，]，· 聯一 π米嗤、〗〇 - 丁基-2 -氯π丫 υ定酮、2 -乙基蒽醒、聯苯酿、9，1 〇 _ 菲醌、莰醌、苯基乙醛酸甲酯、鈦烯化合物等。 酸產生劑可舉例如· 4_羥基苯基二$基鎏鹽對$苯石黃 酸鹽、4-备基苯基二甲基鎏鹽六氟銻鹽、乙醯氧基苯基 二甲基鎏鹽對$苯磺酸鹽、4_乙醯氧基苯基基·苄基鎏 20 314979(修正本） !277832 鹽六氟銻鹽、三苯基鎏鹽對曱苯磺酸鹽、三苯基鎏鹽六氟 銻鹽、二苯基碘鍚鹽對甲苯磺酸鹽、二苯基碘鏺鹽六氟銻 鹽寺鍚鹽類、或硝基苄甲苯磺酸鹽類、苯偶因甲笨碏酸_ 類等。 義 再者’活性自由基產生劑亦可為在上述化合物中，與 活性自由基同時產生酸的化合物，譬如三嗪系光聚合起始 劑便亦可使用為酸產生劑。 (D)光聚合起始劑含量係相對於黏結聚合物與（c) 光聚合性化合物總計量丨〇〇重量份，通常在〇 ·丨重量份至 25重里份，最好為1質量％至15重量份。若光聚合起始 刈各里在0· 1重量份至25重量份的話，將有高感度化且縮 紐曝光時間而提昇生產性，此外亦不致感度過高而造成解 像度不佳的傾向，故屬較佳狀況。 在本發明中，亦採用（G)光聚合起始助劑。光聚合起始 助別有組合搭配光聚合起始劑使用的情況，乃為促進依光 聚合起始劑而開始進行聚合之光聚合性化合物的聚合而所 採用化合物。光聚合起始助劑可舉例如：胺系化合物、垸 氧基蒽系化合物、噻噸酮系化合物等。 fee系化合物可舉例如：三乙醇胺、甲基二乙醇胺、三 異丙醇胺、4-二曱胺基苯曱酸甲酯、4-二曱胺苯甲酸乙酯、 4·二甲胺苯曱酸異戊酯、苯甲酸2-二曱胺乙酯、仁二曱胺 笨曱酸2-乙基己酯、N，N-二甲基對曱苯胺、4,4，-雙（二甲胺 基）二笨曱酮（俗稱「米希勒酮（Michler，s ketone)」）、4,4，-雙（二乙胺基）二笨甲酮、4,4’-雙（乙曱胺基）二苯曱酮等，其 21 314979(修正本） 1277832 中最好為4,4’-雙(二乙胺基)二笨甲鲷。 烷氧基蒽系化合物可舉例如 K 910 - Ψ Ά Μ. ，1(K 二甲乳基恩、2-乙 14，1〇-—曱氧基恩、9，1〇_二 匕氣基恩、9 -乙某-9 10 - r 氧基蒽等。 -d 9，1〇-_乙 噻噸酮系化合物可舉例如· 盆_ e m 。， ^異丙基噻噸酮、4-昱丙 基唾噸酮、2,4-二乙基噻噸a同、2 &amp; 一 、丙 ’ D舉11頓嗣、1 -顧_ 4石 氧基噻噸酮等。 土貝1虱4丙 光聚合起始劑單獨使用或組 ^ . S5... 複數種使用均無妨。此 卜，光起始助劑亦可使用市 十…， 便用市售者，市售的光聚合起始 诏可舉例如.商品名「eab_f 等。 AB t」（保土谷化學工業（股）製） 本發明的著色感光性樹脂組成物中，光聚合起始劑與 光聚合起始助劑的組合，可舉例如下述組合：二乙氧基笨 乙酮/4,4雙（一乙胺基）二笨曱酮、2_甲基冬嗎啉代·ι_(4· 甲基硫代苯基）丙烷-；!_酮/4,4，_雙（二乙胺基）二苯曱酮、孓 罗二基2-曱基_1_笨基丙烷酮/4,4，_雙（二乙胺基）二笨甲 酮、Τ基二甲酮縮醇/4,4，-雙（二乙胺基）二苯曱酮、2_羥基 -2-曱基-l-[4-(2-羥基乙氧基）苯基]丙烷-^酮以/^雙（二乙 月女基）二笨甲嗣、1-羥基環己基苯酮/4,4，-雙（二乙胺基）二笨 甲酮、2-羥基_2_甲基曱基乙烯基）苯基]丙烷酮 的寡聚物/4,4、雙（二乙胺基）二苯曱酮、2-苄基-2-二甲胺基 -1-(4-嗎啉代笨基）丁烷-丨酮/4，4’_雙（二乙胺基）二苯曱酮 等，最好的組合為2-曱基-2-嗎啉代-1-(4-甲基硫代苯基） 丙烷-1-酮/4,4，-雙（二乙胺基）二苯甲酮。 22 314979(修正本） 1277832 當採用該等光聚合起始助劑曰、 聚合起始劑每1莫I，、s a ^ -、使用量為光 莫耳至5莫耳。 吊在1〇莫耳以下，最好為〇.〇】 本發明所刼用的(E)溶劑可舉例如：醚 類、酮類、醇類、酯類、醯胺類等。 、方曰夫 醚類可舉例如.·四％ 、、 7 -醢炅夫南、四氫咄喃、】，4_二噁烷、 乙一私早甲醚、乙二醇單 、_ 一口口 丁絲 一 7 _〜 —、、乙一酵單丙醚、乙二醇單 二醇”醚、二乙二醇單乙醚、二乙1單丁 醚、二乙二醇二甲醚、二乙二妒 乙一 ％早丁 一 —知—乙醚、二乙二醇二丙醚、 :一而一丁峻、丙二醇單甲峻醋酸酯、丙二醇單乙醚醋 醇單丙喊醋酸sl、甲基纖維素醋酸醋、乙基纖 維：旨、乙基卡必醇醋酸酿、丁基卡必醇醋酸醋、丙 一醇甲喊S日酸醋、甲氧基丁基醋酸S旨、甲氧基戊基醋酸酯、 茴香醚、苯乙醚、甲基茴香醚等。 芳香族烴類可舉例如：苯、甲苯、二甲苯 等。 一 酉同*員可舉例如：丙酮、2-丁酮、2_戊酮、3_戊酮、4_ 戊酮驭曱基-2-戊S同、環戊酮、環己酮等。 醇頒可舉例如：甲醇、乙醇、丙醇、丁醇、己醇、環 己醇、乙二醇、丙三醇等。 酉曰類可舉例如··醋酸乙酯、醋酸正丁酯、醋酸異丁酯、 蟻I戊知、醋酸異戊酯、醋酸異丁酯、丙酸丁酯、丁酸異 丙s曰 丁酸乙酯、丁酸丁酯、烷基酯類、乳酸曱酯、乳酸 乙知基醋酸曱酯、羥基醋酸乙酯、羥基醋酸丁酯、甲 23 314979(修正本) 1277832 氧基醋酸曱酯、甲氧基醋酸乙酯、甲氧基醋酸丁酯、乙氧 基醋酸甲酯、乙氧基醋酸乙酯、3 -羥基丙酸甲酯、3 -羥基 丙酸乙酯、3 -曱氧基丙酸甲酯、3 -甲氧基丙酸乙酯、3 -乙 氧基丙酸甲酯、3 -乙氧基丙酸乙酯、2_羥基丙酸甲酯、2_ 羥基丙酸乙酯、2-羥基丙酸丙酯、2-曱氧基丙酸甲酯、2-甲氧基丙酸乙S旨、2 -曱氧基丙酸丙S旨、2 -乙氧基丙酸甲S曰、 2 -乙氧基丙酸乙酉旨、2 -經基-2,甲基丙酸甲醋、2 -經基-2-甲 基丙酸乙酯、2-曱氧基_2_甲基丙酸甲酯、2_乙氧基_2·甲基 丙酸乙S旨、丙顚]酸甲醋、丙酮酸乙g旨、丙酮酸丙醋、乙醢 醋酸甲酯、乙醯醋酸乙酯、2-氧代丁酸甲酯、2-氧代丁酸 乙酯、3 -曱氧基丁基醋酸酯、3 -甲基-3 -曱氧基二丁基醋酸 酯、r - 丁内酯等。 醯胺基可例舉如：N，N-二甲基曱醯胺、N，N-二曱酸乙 酸胺等其它溶劑可例舉如：N-甲基吡咯烷酮、二曱基亞楓 等。 上述溶劑中，最好採用3_乙氧基丙酸乙酯、丙二醇單 曱_1醋酸西旨。 上述溶劑分別可單獨使用或組合使用2種以上。 (E)溶劑在本發明的著色感光性樹脂組成物中之含 里，以質量分率計，通常在70質量。/。至95質量％，最好 為75質量％至90質量％的程度。若將溶劑含量設定在上 述範圍内的話，塗布時的平坦性將變佳，且因為可形成色 濃度充分、顯示特性佳的彩色濾光片，故屬較佳狀況。 本發明的著色感光性樹脂組成物中，界面活性劑係由 24 314979(修正本) l277832 夕西π不界面活性劑、氟系界面活性 -11¾ έ X ^ ^ kiL ^ … 及含氟原子的矽 J不界面活性劑所構成組群中， ^ 活性劑（以下介士 r 擇其中1種的界面 生片丨（以下亦有稱「（F)成分」的情況 的石夕綱系界面活性劑。 取好為含I原子 含氟原子的矽酮系界面活性劑可舉例 結盘ϋ石声灰击A A田^ •具石夕氧烧鍵 克（纟主冊商押立巧、 了舉例如··美佳發 兄卜主冊商払，音譯）R08、同扯2〇、同F47s门 F44竹 I α 士、， Μ75、同 F477、同 (大日本油墨化學工举（股）|y、辇 冊A挪u 系（又）衣）寺取好為美佳發克（註 冊商標，音譯）F475。 矽酮系界面活性劑可舉例如： α ★， ’礼沉鍵結的界面活 性別。具體而言，可舉 牛J 仏田子吾矽（商品名，音 #)DC3PA、同 SH7PA、同 DC11PA、同 SH2ipa、同随觀、 同29SHPA、同SH3GpA、聚醚改f石夕油⑽彻（商品名： 德雷镇石夕康（股）製）；ΚΡ321、κρ322、κρ323、Km#、 6 ΚΡ340 、ΚΡ341(信越矽康公司製）；TSF4〇〇、 TSF401 &gt; TSF41〇' TSF4300. TSF4440, TSF4445&gt; TSF-4446 ^ TSF4452 ' TSF44460(吉伊東芝矽康（股）製）等。 氟系界面活性劑可舉例如：具敦碳鏈的界面活性劑。 具體而言，可舉例如：福羅納德（註冊商標，音譯）fc43〇、 同FCM3U住友斯里艾姆（股）製）；美佳發克（註冊商標，音 §睪）F142D 同 F171、同 F172、同 Fl73、同 F177、同 F183、 同R30(大曰本油墨化學工業（股）製）；艾福德布.（註冊商 標，音澤）EF301、同EF3〇3、同肛⑸、同新秋田 化成（股）製）’桑福龍（註冊商標，音譯）S381、同S382、同 25 314979(修正本) 1277832 SCI 01、同SCI 〇5(旭石肖子（股）製）；E5844[(股）大金精細化 學研究所製];31^-1 000、3]\/1-1100(均為商品名：3]^&lt;：1^11^ 公司製）等。 該等界面活性劑可單獨使用或組合使用2種以上。 相對於除（F)成分外的著色感光性樹脂組成物丨〇〇 f 量份，（F)成分的使用量在0.0005重量份至〇·14重量份， 最好在0.001重量份至0.12重量份的範圍内。若界面活性 劑含量設定在0.0005重量份至0.14重量份的話，便具有 平坦性變佳的傾向，故屬較佳狀況。 本發明的著色感光性樹脂組成物，亦可含有除（Β)黏結 聚合物以外的高分子化合物、填充劑、密接促進劑、抗氧 化劑、紫外線吸收劑、抗凝聚劑、有機酸、有機胺化合物、 硬化劑等添加劑。 除（Β)黏結聚合物以外的高分子化合物，可舉例如：聚 乙稀醇、聚丙烯酸、聚乙二醇單烷基醚、聚氟化烷基丙烯 酸酯等。 填充劑可舉例如：玻璃、氧化鋁等微粒子。 密接促進劑可舉例如：乙烯基三甲氧基矽烷、乙烯基 一乙氧基矽烷、乙烯基三（2-曱氧基乙氧基）矽烷、Ν-(2-胺 ^ 胺基丙基甲基二甲氧基矽烧、Ν-(2-胺基乙 土 -胺基丙基三曱氧基矽烷、3 -胺基丙基三乙氧基矽烷、 ^ 、乳丙氧基丙基三曱氧基矽烷、3-環氧丙氧基甲基二甲 乳基石夕燒、2-(3,4-環氧基環己基）乙基三甲氧基矽烷、3_氣 基甲基二甲氧基矽烷、3 -氯丙基三甲氧基矽烷、3 -甲基 26 314979(修正本） 1277832 丙稀酿氧基丙基三甲氧基矽烷、3·巯基丙基三甲氧基矽烷 等。 抗氧化劑可舉例如：4,4，-硫代雙（6-第三丁基-3 -甲基苯 西刀）、2,6 - 一弟二丁基-4-甲基苯齡等。 紫外線吸收劑可舉例如：2_(2-羥基-3_第三丁基_5-甲 基笨基）-5-氣苯并三唑等笨并三唑系；2_羥基辛氧基二 笨曱酮等二苯曱,酮系；2,4_二第三丁基苯基_3,5_二第三丁 基-4-羥基苯甲酸酯等笨曱酸酯系；2_(4,6_二苯基，弘三 嗪_2-基）-5 -己氧基苯酚等三嗪系等。 抗凝聚劑可舉例如··聚丙烯酸鈉等。 有機酸可舉例如：蟻酸、醋酸、丙酸、丁酸、吉草酸、 三甲基乙酸、己酸、二乙基醋酸、庚酸、辛酸等脂肪族單 羧酸類；草酸、丙二酸、琥珀酸、戊二酸、己二酸、庚二 酉夂、辛二酸、壬二酸、癸二酸、巴西二酸、甲基丙二酸、 乙基丙一酸、一曱基丙二酸、曱基琥珀酸、四曱基琥珀酸、 %己烷二羧酸、衣康酸、檸康酸、順丁烯二酸、反丁烯二 酉欠、曱基富馬酸等脂肪族二羧酸類；均丙三甲酸、烏頭酸、 才早腦酸等脂肪族三羧酸類；苯曱酸、甲笨酸、枯茗酸、2,3_ 一曱基苯基酸、二曱基苯曱酸等芳香族單羧酸類；酞酸、 間笨一曱I、對苯二甲酸等芳香族二羧酸類；偏苯三酸、 句笨一曱g夂、偏笨四甲酸、均苯四曱酸等芳香族聚羧酸類 等等。 、 有機胺化合物可舉例如：正丙胺、異丙胺、正丁胺、 丁胺、第一丁胺、第二丁胺、正戊胺、正己胺、正庚胺、 27 314979(修正本） 1277832 正辛胺、正壬胺、正癸胺、 r ^ m 41 . 正十一烷胺、正十二烷胺等單 烷暴胺頬；環己胺、2 基環己胺、等m 展己月安、3_甲基環己胺、4·甲 胺、乙λ/衣元基知類；甲乙胺、二乙胺、甲基正丙 土正丙胺、二正丙脸、一 丁胺、二第二丁^ . 一異丙胺、二正丁胺、二異 二烷基胺，女：一弟三丁胺、二正戊胺、二正己胺等 胺類.一=，甲基5哀己胺、乙基環己胺等單烷基單環烷基 月女颂，一％己胺等二環烷基 _ 二Γ跄 土妝頭，一曱乙胺、甲基二乙胺、 一乙胺、二$基正丙胺、二 乙其- 一乙基正丙胺、甲基二正丙胺、 乙暴一正丙胺、三正丙 二 胺、二 一 一丙胺、三正丁胺、三異丁 烧美脸+.s. 一弟—丁胺、三正戊胺、三正己胺等三 烷基胺頌，二甲基環己胺、_ 基胺類.审装 一乙基裱己胺等二烷基單環烷 基-严卜# 基—裱己胺、三環己胺等單烷 基一％烷基胺類；2_胺基乙醇 ^ . 4 A 1 , •胺基-1-丙醇、1-胺基-2_ 吁月女基-1-丁醇、5_胺基 烷醇胺翻, -戍醇、6-胺基_1_己醇等單 女類、4 -胺基-1 _環己醇箄置 二正 ：已知寺早裱烷醇胺類；二乙醇胺、 醇胺、—異丙醇胺、二正 n： u J醇月女、二異丁醇胳、- 正戍释胺、二正己醇胺等二院 ^ 一 二環烷舻…相 類’一（4-¾己醇）胺等 衣垸酉“女類’·三乙醇胺、三 正丁醇胺、三里丁幢π-内％胺、二異丙醇胺、三 醇胺類· - U &gt; 月 二正己醇胺等三烷 、，一（扣％己醇）胺等三環烷 烷二醇、2脸 · a , 胺基-1，2-丙 ^ 女基“，3-丙烷二醇、4-胺其彳， 胺基]，3-丁燒二醇…甲胺美〗：基-1，2-丁院二醇、4_ 基十2-丙〜， 以·丙烧二醇、3-二乙胺 , 甲胺基―1，3-丙烷二醇、2_二乙月^其 ，丙垸二醇等胺基鏈烷二醇類； 女土 314979(修正本) 28 1277832 4-胺基-1，2-環己烷二醇、4·胺基-1，3β環己统二醇等胺 基環烷二醇類；卜胺基環戊顏1甲醇、心胺基環戊酮甲醇等 含胺基之環烷酮甲醇類；1 —胺基環己銅甲醇、心胺基環己 iq曱醇、4 -二甲基胺基環戊烧甲醇、4 -二乙基胺基環戊烧 曱醇、4-二甲基胺基環己烷甲醇、心二乙基胺基環己烷甲 醇等含胺基之環鏈炫甲醇類；yS _丙胺酸、2 -胺基丁酸、3 -胺基丁酸、4-胺基丁酸、2_胺基異乙酸、3-胺基異乙酸、 2-胺基吉草酸、5-胺基吉草酸、5-胺基己酸、1-胺基環丙烷 羧酸、1-胺基環己烷羧酸、4-胺基環己烷羧酸等胺基羧酸 類；苯胺、鄰甲基苯胺、間甲基苯胺、對甲基笨胺、對乙 基苯胺、對正丙基苯胺、對異丙基苯胺、對正丁基苯胺、 對第三丁基苯胺、1-萘胺、2_萘胺、N，N-二甲基苯胺、N，N_ 二乙基苯胺、對甲基-N，N-二曱基苯胺等芳香族胺類；鄰胺 基苄醇、間胺基T醇、對胺基苄醇、對二甲胺基苄醇、對 二乙胺基苄醇等胺基苄醇類；鄰胺基苯酚、間胺基苯盼、 對胺基苯酚、對二甲胺基苯酚、對二乙胺基笨酚等胺基苯 齡類；間胺基苯甲酸、對胺基苯甲酸、對二曱胺基笨甲酸、 對二乙胺基苯曱酸等胺基苯甲酸類等等。 硬化劑可舉例如：經加熱而與黏結聚合物中的緩基進 行反應俾可交聯黏結聚合物的化合物。此外，其亦可單獨 聚合而獲得使著色圖案硬化的化合物。上述化合物可舉例 如·壞氧化合物、氧雜環丁烷化合物等。 環氧化合物可舉例如：聯笨盼A系環氧樹脂、氫化聯 m系環氧樹脂、聯苯紛F系環氧樹脂、氫化聯笨盼ρ 314979(修正本) 29 !277832 不％虱樹脂、酚醛清漆 m &gt; η- ι-- 衣虱树月曰、其他芳香族系環氧樹 月曰月曰裱族糸裱虱樹脂、雜严戶_ 月匕、…U 2 L — / 雜衣％乳树月日、縮水甘油酉旨系樹 月曰、縮水甘油胺系樹脂、 r ^ ^ ^ ^ 衣虱化油寺裱氧樹脂或該等環氧 树月曰的溴化衍生物、夢 ^ ^ 々虱柄'脂及其溴化衍生物之外的脂肪 、、月曰％私或芳香族的環氧 俨气儿t 衣乳化&amp;物、丁二烯的（共）聚物之 衣乳化物、異戊二烯的 ^ t b、）♦物之壞氧化物、（曱基）丙醯 酉夂^水甘油g旨的（j£彳取4 醋等等。 。、)1物之環氧化物、異氰酸三縮水甘油 =雜環丁，可舉例如：碳酸醋雙(氧雜環丁烧)、笨二 /又(乳雜壞丁烷)、己二酸酯雙(氧雜環丁烷卜對苯二甲 西夂醋雙（氧雜環y燒）、環己燒二㈣雙（氧雜環丁烧）等。 本發明之著色感光性樹脂組成物作為含有環氧化合 :物氧料丁烧化合物等之硬化劑時，亦可含有二 。之％氧基 '乳雜環丁院化合物之氧雜環丁㈣架進行 開《合而得之化合物。上述化合物可舉例如：多元缓酸 類、多元羧酸酐類、酸產生劑等。 多元幾酸類可舉例如··駄酸、3,心二甲基駄酸、間苯 :甲酸：_苯二甲酸、均苯四甲酸、偏苯三酸、1，4,5,8_ 奈基四鲮酸、3,3·，4,4,_二苯甲酮四羧酸等芳香族多元羧酸 ^琥珀駄、戊二酸、己二酸、〗，2,3,4-丁烷四羧酸、順丁 稀=酉义反丁烯二酸、衣康酸等脂肪族多元羧酸類；六氬 鄰苯一甲酸、3,仁二甲基四氫鄰苯二甲酸、六氫間苯二甲 酸、、六氫對苯二甲酸、u，心環戊垸三㈣、u，心環己燒 三羧酸、環戊烷四羧酸、〗，2,4,5_環己烷四羧酸等脂環族多 30 314979(修正本) 1277832 元叛酸類等等。 多元鲮酸酐類可舉例如· 苯三酸酐、3,3，，4,4，-二# •酞酸酐、均笨四曱酸哥、偏 酸酐類；I康酸酐、球？同四綾酸二酐等芳香族多元羧 酸酐、均丙三甲酸酐二久酐、榉康酸酐、十二烯醇琥珀 欠針順丁烯二醅醉,?, 二酐等脂肪族多元鲮酸酐類；一 ，丁烷四羧酸 氫歌S請、1，2,4-環戊γ ' '、氣歌&amp;酐、3,4·二甲基四 環戊烷四鲮酸二酐、！ ？ 4 &lt; ，2,4衣己烷二竣酸酐、 稀-π二緩酸野、内亞η燒四酐、5-降冰片 類；乙二醇雙(偏苯三酸：：本酐：脂壞族多元羧酸酐 羧酸酐類等等。 f油三偏苯三酸肝等含醋基之 羧酸酐類亦可採用市隹 ^ ^ ^ ^ ϋ的j衣虱树舳硬化劑。上述環氧 心更化劑，可舉例如：商品名「雅德佳哈德納EH·」 (旭電化工業（股）fj彳、商σ )%)商叩名「理佳德ΗΗ」（商品名，音 譯）（新日本理化（股）製）、商品名「廳··」（新日本理 製）等。. 上述硬化劑可分別單獨使用或組合使用2種以上。 本發明著色感光性樹脂組成物係含有上述（A)著色 剤、（B)黏結樹脂、光聚合性化合物、（D)光聚合起始劑、 (E)洛劑及（F)界面活性劑，且（F)界面活性劑含有除界面活 性劑外之其餘成分總計每100重量份，在0.0005重量份至 〇· 1 4重s份的組成物，而且將丨5mL的著色感光性樹脂組 成物’在具備八角轉子（全長20mm、直徑6.5mm)之容量 3OmL(高度65mm、直徑33mm)的潔淨玻璃製圓筒狀褐色瓶 31 314979(修正本) 1277832 中，利用八角轉子以旋轉數700rpm進行6〇秒鐘攪拌之 後’再經靜置6 0 0秒時，便呈消泡狀態的組成物。 在此為確認上述消泡狀態而所採用容量％Ml(言产 65mm、直徑33mm)的潔淨玻璃製圓筒狀褐色瓶，可採:二 合此規定，且開口部可密栓的普通取樣瓶，譬如圓形輕= 規格瓶（型號：3126-02、相互理化學破璃製作所製）。此^里 八角轉子（全長2〇mm、直徑6.5mm)，具體而言可舉例如： 八角轉子[商品名、型號：7_216·02、氟樹脂製（亞曰王（股） 製）]。另外’在將該八角轉子與著色感光性樹脂組成^ 1 5mL —齊填充於上述玻璃製圓筒狀褐色瓶中之後，在為 使八角轉子產生70〇rpm的旋轉，通常可採用電磁攪拌器^ 具體而言可舉例如：MAGNETIC STIRER Is 3g(池田科。技 股份有限公司製）。 在八角轉子旋轉數700rPm下進行60秒中攪拌及其後 =600秒靜置，均在常溫（通常15至3〇。〇下進行。在:所 謂「消泡狀態」係指組成物中，纟組成物的液表面與空間 部瓶壁等處實質未發現氣泡的狀態。 著色感光性樹脂組成物在上述條件下是否已呈消泡 狀心可藉由執行上述消泡狀態確認而進行確認。藉由將 各成分混合既定量而調製成組成物，進行上述消泡狀態的 確認。若經此確認而判斷未呈消泡狀態時，便譬如減少 成分在組成物中的含有比率，或將⑻成分從氟系界面活性 ，改變為具氣原子的石夕酮系界面活性劑、或者改變為石夕酮 糸界面活性劑’’然後再執行上述消泡狀態的確認。然後， 314979(修正本) 32 1277832 便可形成本發 藉由直到變成消泡狀能為μ仏 狀心馮止均重複此動作 明的著色感光性樹脂組成物。 採用本發明的著$ #本 、 邑戊先性树月曰組成物而形成圖案的 方法’具體而言，孽如將太欲 、 S如知本發明的著色感光性樹脂組成物 塗布於基板上，再從所涂束从贫 厅土布的者色感光性樹脂組成物層中 去除溶劑等揮發成分，祐P5装止 驭刀亚隔者先罩對經去除揮發成分的層 進行曝光並顯影的方法。 基板可舉例如：玻璃基板、矽基板、聚碳酸酯基板、 聚醋基板、芳香族㈣胺基板、Μ㈣亞胺基板、㈣ 亞胺基板、Α1基板、GaAs基板等表面平坦的基板。該等 基板亦可轭行如矽烷偶合劑等藥物的藥物處理、電漿處 理離子鍵處理、錢錢處理、氣相反應處理、真空蒸It處 j等前處理。當基板採用矽基板等時，亦可在上述矽基板 等表面上形成電荷耦合元件（CCD)、薄膜電晶體（tft)等。 將著色感光性樹脂組成物塗布於上述基板上時，僅要 採用習知的旋塗機、省液塗布機（其中，尤以無旋轉塗布機 為佳）塗布於基板等之上，接著再對溶劑等揮發成分進行加 熱而使揮發即可。依此的話，便可在基板等之上形成平坦 陸佳之由著色感光性樹脂組成物固形份所構成的層。 其次’對由著色感光性樹脂組成物固形份所構成層（以 下有將此稱為「著色感光性樹脂組成物固形份層」的情況） 進行曝光。在曝光方面僅要譬如隔著光罩照射光線的話便 可。光線通常可採用通稱g線（波長436nm)、i線（波長365nm) 的紫外線等。光線乃隔著光罩進行照射，在此所謂「光罩 33 314979(修正本) 1277832 乃譬如在玻璃板表面上所設置遮蔽光線的遮光層。在玻璃 板中未設置遮光層的部分乃為光線穿透的透光部，利用依 照此透光部圖案的圖案使著色感光性樹脂組成物層進行曝 光，便產生未被光線照射到的未照射區域、與精光線照射 到的照射區域。照射區域中的光線照射量乃隨黏結聚合物 的重量平均分子量、單量體比、含量、光聚合性化合物種 類或含量、光聚合起始劑種類或含量、光聚合起始助劑種 類或含量等因素而適當選擇。 經曝光後，再進行顯影。在顯影方面，僅要譬如使曝 光後的著色感光性樹脂組成物層與顯影液進行接觸的話便 可，具體而言，僅要將表面上已形成著色感光性樹脂組成 物層之狀態的基板，浸潰於顯影液中的話便可。顯影液可 舉例如：碳酸鈉、碳酸鉀、氫氧化鈉、氫氧化鉀、'氫氧四 曱基銨等鹼性化合物水溶液等。經由顯影’在著色感光性 樹脂組成物層中未被光線照射到的未照射區域 除。此外，光線照射區域則仍維持原樣以構成圖案γ 經顯影後，通常再經由水洗、乾燥，便可獲得標的圖 案。亦可在乾燥後，再施行加熱。藉由加熱圖案而硬化， 便具有提昇機械強度的傾向，當著色感光性樹脂組成物採 用含硬化劑的情況時’便可更加提昇機械強度。加熱溫度 通常在180°C以上’最好在200t以上，通常在25〇t以下夂。 依此的話’便可在已形成著色圖案的基板上，更含有 不同顏色之著色劑’而形成由經著色上不同顏色之著色感 光性樹脂組成物所構成的層，再對該層進行曝光之後，藉 314979(修正本) 34 1277832 由顯影，便可形成著色圖案。甚至採用經著色上不同顏色 的著色感光性樹月旨組成物並重複上述操作，便可依序形成 著色圖案，可製造標的彩色滤光片。換句話說，通常彩色 濾光片係將黑矩陣、與紅、綠及藍三原色著色圖案配置於 基板上，但是亦可藉由採用含有相當某顏色著色劑的本發 明著色感光性樹脂組成物，纟重複上述操作，而獲得此顏 色的黑矩陣或著色圖案，相關其他顏色，亦是採用含有相 當所需顏色著色劑的本發明著色感光性樹脂組成物並施行 同樣的操作μ更可將黑矩陣與三原色著色圖案配置於基板 上。此外’基板上-經配置某顏色之著色圖案或黑矩陣之 後，當處理其他顏色之著色感光性樹脂組成物的情況時， 便將該某顏色的著色感光性樹脂組成物進行塗布，經乾燥 後，通#對該某顏色之著色圖案或黑矩陣未配置的位置， 施行圖案化曝光，便可在經曝光的位置處配置著該其他顏 色的著色圖案或黑矩陣。當然，亦可黑矩陣及三原色中， 僅任1種、2種或3種採用本發明的著色感光性樹脂組成 物。另外，屬於遮光層的黑矩陣乃因為由如鉻層等所形成， 因而在此情況下，當然在黑矩陣的形成上並不需要採用本 發明的著色感光性樹脂組成物。 依此而所獲得的彩色濾光片乃含有圖案，藉由將上述 衫色慮光片組裝於液晶顯示裝置中，便可獲得頗佳的液晶 顯示裝置。 在上述中，雖針對本發明的實施形態進行說明，惟上 述所揭示的本發明實施形態，充其量僅止於例式而已，本 35 314979(修正本) 1277832 發：的範圍並非限定於該等實施形態。本發明的範圍乃依 :明專利範圍所示，甚至包含中請專利範圍中所記载的均 :/函義與範圍内之所有改變。以下，#由實施例更加詳細 說明本發明，惟本發明並不僅限於該等實施例。 本實施例中所採用的成分乃如下示，以下有簡略 的情況。 θ 又不 (A-1)著色劑：C.I.顏料紅254 ^ (A_2)著色劑：c.I.顏料黃139 (B) 黏結聚合物··甲基丙烯酸與甲基丙烯酸苄酯之共聚 物[曱基丙烯酸單位與曱基丙烯酸苄酯單位之比，依物質量 比（莫耳比）計，為27 : 73，酸值83，聚笨乙烯換算重量平 均分子量為1 8,〇〇〇] 相關黏結聚合物之重量平均分子量的測量，採用Gpc 法依下述條件而實施。The above-mentioned bonded polymer system phase #4. ^ I solid content, according to the mass "Λ / t light resin composition of the Baili knife dry mouth ten, usually in the range of 5 mass% to 4 mass%, preferably 10 mass % to 35 mass%, Dan, and the surrounding are. 4, Berry 〇 / 〇 to 26 mass 〇 / 〇 Fan",, soil. When the content of the right U-bonded polymer is from 5% by mass to 4% by mass, the pattern can be formed, and the right side is preferred. The photopolymerizable compound used in the present invention is a photopolymerizable compound used in the present invention, which is irradiated with light, and uses active radicals, acids, etc. generated from a photopolymerization initiator. And a compound which can be polymerized, such as a polymerizable carbon-carbon unsaturated. The photopolymerizable compound is preferably a trifunctional group to be a photopolymerizable compound. Examples of the polyfunctional photopolymerizable compound having a trifunctional or higher functional group include, for example, quaternary tetral triacetate, pentaerythritol trimethyl propylene 314979 (amendment) 18 1277832 pentaerythritol tetraacrylic acid酽^-金# 曰曰, pentaerythritol tetramethyl acrylate, pentaerythritol penta acrylate _ pentaerythritol 丄 李 李 李 醇 醇 李 李 李 李 李 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸Each of the above-mentioned polymerizable compounds is used alone or in combination of two or more kinds, and the mass fraction of the photosensitive resin composition is usually 15 to 45 f. It is preferably from 1 G% by mass to 35% by mass, especially from 15 masses to 26 皙 〇 / from M m 儿人贝里/°的干围者. If the above photopolymerization s is in 5 1 When it is 1% to 45% by mass or less, the hardening is sufficiently performed, and the residual film ratio is increased, and the pattern is less likely to cause undercutting and tends to have good adhesion, which is preferable. (D) light used in the present invention. The polymerization initiator preferably contains at least one acetophenone compound. The compound may, for example, be diethoxyacetophenone, &quot;yl-2-morpholino small (4-methylthiobenzene)propane ketone, 2 _ ketomethyl-p-phenylpropane- 1-ketone, benzyldimethylketal, 2-hydroxy-2-indolyl-l-[4-(2-carbylethoxy)phenyl]propane-nonanone, stupid base Ketone, 2-carbyl-2-methyl-[4_(1-methylvinyl)phenyl]propanone-based oligo-oligomer, etc. 'preferably 2-methyl_2_?卩林代+ (4-methylthiobenzene) propyl 1-ketone, etc. Further, a plurality of acetophenone-based and other photopolymerization initiators may be used in combination, and a photopolymerization initiator other than acetophenone may be used. For example, an active radical generator which generates an active radical by irradiation of light, a sensitizer, etc. Examples of the active radical generator include a benzoin-based compound, a benzophenone-based compound, and a thioxanthone. a compound, a triazine-based compound, etc. 314979 (amendment) 19 1277832 Benzene τ ·,, η - acetonyl ether, benzoin isopropyl ether, styrene, isobutyl ether, etc.. -People/Ur» ^Caine compounds can be exemplified by: Benzene # / 田mw π Maine _, 茉本偶口口isopropyl ether, 1 value / ', J % 〇 benzophenone oxime compound can be mentioned, for example, _ 4 stupid m A, 邻 醯 醯 醯 曱 曱 、 、, 4-本曱_, 4-醯醯_4,_甲甲一* 筮 丁 甘 本 本 硫化 ' 甲 甲 ' 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲 甲Examples of the S homologous compound include: 2-isopropyl thioxan a, 4 isopropyl thioxanthone, 2,4-diethyl thioxene 1, 2, 4-diox thioxantane, and propoxygen Keithene® is equivalent. The gas triazine-based compound may, for example, be 2,4_bis(trimethylmethyl)·6·(4-methoxyphenyl)-1,3,5·triazine, 2,4_bis (trigas) Methylmethoxy)-1,3,5--Qin 2'4 bis(dichloromethyl)-6-(4-methoxy stupidyl)-1,3,5-triazine, 2, Renshuang (trichloromethyl)&gt;6.[2_(5•methylfuranyl)vinyl]-1,3,5-triazine, 2,4-bis(trichloromethyl)_6_[2_ (furo-2-yl)vinyl]-1,3,5-triazine, 2,4-bis(trimethylmethyl)-6-[2_(4-diethylamino-2-phenylphenyl) Vinyl]-1,3,5-triazine, 2,4-bis(trichloromethyl)-6-[2-(3,4-dimethoxyphenyl)ethenyl]triazine, etc. The living radical generating agent may be, for example, 2,4,6-trimethyl benzoyl decyl diphenylphosphine oxide ^ '-bis fluorenyl phenyl phenyl ^ ^ "" - tetraphenyl - 〗 ],·联一π米嗤,〗 〇-butyl-2 -chloroπ丫υ 丫υ ketone, 2-ethyl oxime, biphenyl brewing, 9,1 〇 醌 醌, 莰醌, phenyl acetaldehyde The acid methyl ester, the titanium olefin compound, etc. The acid generator may, for example, be a 4-hydroxyphenyl bis-base sulfonium salt to a benzoate, a 4-predyl phenyl dimethyl sulfonium salt hexafluoroantimonate. , ethoxylated phenyl dimethyl sulfonium salt to $ benzene sulfonate, 4 ethoxylated phenyl benzyl hydrazine 20 314979 (amendment) ! 277832 salt hexafluoroantimony salt, triphenyl sulfonium Salt-p-toluenesulfonate, triphenylsulfonium salt hexafluoroantimony salt, diphenyliodonium salt p-toluenesulfonate, diphenyliodonium salt hexafluoroantimonate salt, or nitrobenzyltoluene a sulfonate, a benzoin, a benzoic acid, etc. The active radical generator may also be a compound which simultaneously generates an acid with an active radical in the above compound, such as a triazine photopolymerization. The initiator can also be used as an acid generator. (D) The photopolymerization initiator content is based on the total weight of the binder polymer and (c) photopolymerizable compound, usually in parts by weight. 25 parts by weight, preferably 1% by mass to 15 parts by weight. If the photopolymerization starting point is from 0.1 part by weight to 25 parts by weight, it will have high sensitivity and shrinkage exposure time to improve productivity. In addition, it is not preferred that the sensitivity is too high and the resolution is poor, so in the present invention, (G) photopolymerization is also employed. In the case where the photopolymerization initiator is used in combination with a photopolymerization initiator, it is a compound which promotes polymerization of a photopolymerizable compound which starts polymerization by a photopolymerization initiator. Examples of the starter auxiliary agent include an amine compound, a decyloxy compound, and a thioxanthone compound. Examples of the fee compound include triethanolamine, methyldiethanolamine, triisopropanolamine, and 4-dioxime. Methyl aminobenzoate, ethyl 4-diguanamine benzoate, isoamyl dimethyl imidate, 2-diguanamine ethyl benzoate, 2-diamine amide Hexyl hexyl ester, N,N-dimethyl-p-anilide, 4,4,-bis(dimethylamino) dioxin (commonly known as "Michler, s ketone"), 4, 4 , - bis (diethylamino) dimercapto ketone, 4,4 '- bis (acetamido) dibenzophenone, etc., 21 314 979 (amendment) 1277832 is best 4, 4 '- double (Diethylamino) dimethane. The alkoxy oxime-based compound may, for example, be K 910 - Ψ Ά Μ., 1 (K dimethyl ketone, 2-ethyl 14,1 〇-- oxime, 9,1 〇 匕 匕 基 基, 9-B -9 10 - r oxindole, etc. -d 9,1 〇--ethylthioxanthone-based compound, for example, · basin_em., ^isopropyl thioxanthone, 4-pyrene Sodium ketone, 2,4-diethyl thioxan a, 2 &amp; I, C' D 11 11 嗣, 1 - Gu _ 4 stone oxythioxanthone, etc. The polymerization initiator can be used alone or in groups. S5... It can be used in a plurality of kinds. For this, the photoinitiator can also be used in the market..., commercially available, commercially available photopolymerization initiator For example, the product name "eab_f, etc. AB t" (manufactured by Hodogaya Chemical Industry Co., Ltd.) In the coloring photosensitive resin composition of the present invention, a combination of a photopolymerization initiator and a photopolymerization initiation aid can be exemplified. The combination is as follows: diethoxy acetophenone / 4,4 bis (monoethyl amide ) dinonanone, 2 - methyl winter morpholino ι - (4 · methyl thiophenyl) propane -; !_ketone/4,4,_bis(diethylamino)benzophenone, indole 2-yl 2-mercapto-1_phenylpropane Ketone/4,4,_bis(diethylamino)dimercapto ketone, mercapto dimethyl ketal/4,4,-bis(diethylamino)benzophenone, 2-hydroxy-2- Mercapto-l-[4-(2-hydroxyethoxy)phenyl]propane- ketone as /^ double (dimenthyl), dipyridamyl, 1-hydroxycyclohexyl benzophenone / 4,4 ,-bis(diethylamino)dimercapto ketone, 2-hydroxy-2-methylnonylvinyl)phenyl]propanone oligomer/4,4, bis(diethylamino)diphenyl Anthrone, 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)butane-anthone/4,4'-bis(diethylamino)dibenzophenone, etc. The most preferred combination is 2-mercapto-2-morpholino-1-(4-methylthiophenyl)propan-1-one/4,4,-bis(diethylamino)benzophenone . 22 314979 (amendment) 1277832 When such photopolymerization initiation aids are used, the polymerization initiator is used every 1 mol, s a ^ -, and the amount used is light molar to 5 mol. The solvent (E) to be used in the present invention may, for example, be an ether, a ketone, an alcohol, an ester or a guanamine. And the scorpion ethers can be exemplified by, for example, four%, 7-suffrane, tetrahydrofuran, 4, dioxane, ethyl succinyl ether, ethylene glycol, _ squirrel丝一7 _~ —,, B-yield monopropyl ether, ethylene glycol monoglycol ether, diethylene glycol monoethyl ether, diethylene monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol %早丁一—知—Ethyl ether, diethylene glycol dipropyl ether,: one-to-one, propylene glycol monomethyl acetate, propylene glycol monoethyl ether acetate, single propane acetate, methyl cellulose acetate, vinegar, Base fiber: purpose, ethyl carbitol acetic acid brewing, butyl carbitol acetic acid vinegar, propanol A shouting S-cured vinegar, methoxybutyl acetate S, methoxypentyl acetate, anisole Examples of the aromatic hydrocarbons include benzene, toluene, and xylene. For example, acetone, 2-butanone, 2-pentanone, and 3-pentane can be mentioned. Ketone, 4-pentanone oxime-2-pentene S, cyclopentanone, cyclohexanone, etc. The alcohol may, for example, be methanol, ethanol, propanol, butanol, hexanol, cyclohexanol, ethylene glycol. , glycerol, etc. Examples of the hydrazine include ethyl acetate, n-butyl acetate, isobutyl acetate, ant I, isoamyl acetate, isobutyl acetate, butyl propionate, and isopropyl succinate. Ester, butyl butyrate, alkyl esters, decyl lactate, decyl acetate, hydroxyethyl acetate, butyl hydroxyacetate, A 23 314979 (amendment) 1277832 decyl oxyacetate, methoxy Ethyl acetate, butyl methoxyacetate, methyl ethoxyacetate, ethyl ethoxyacetate, methyl 3-hydroxypropionate, ethyl 3-hydroxypropionate, 3-methoxypropionic acid Ester, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, methyl 2-hydroxypropionate, ethyl 2-hydroxypropionate, 2-hydroxyl Propyl propionate, methyl 2-methoxypropionate, ethyl 2-methoxypropionate, 2-propoxypropionic acid propane S, 2-ethoxypropionic acid methyl sulfonium, 2- Ethyl ethoxypropionate, 2-carbyl-2, methyl methacrylate, ethyl 2-pyridyl-2-methylpropionate, methyl 2-decoxy-2-methylpropanoate , 2_ethoxy 2, methyl propionic acid, B, K, acetonitrile, acetic acid, pyruvate, pyruvate Vinegar, ethyl acetate, ethyl acetate, ethyl 2-oxobutanoate, ethyl 2-oxobutanoate, 3-methoxybutyl acetate, 3-methyl-3-anthracene Oxydibutyl acetate, r-butyrolactone, etc. The guanamine group may, for example, be N,N-dimethylguanamine or N,N-dicarboxylic acid amine acetate, and the like. : N-methylpyrrolidone, diterpene sulfoxide, etc. Among the above solvents, ethyl 3-ethoxypropionate and propylene glycol monoterpene-1-acetate are preferably used. The above solvents may be used singly or in combination. (E) The solvent is contained in the coloring photosensitive resin composition of the present invention, and is usually 70% by mass. /. It is up to 95% by mass, preferably from 75% by mass to 90% by mass. When the solvent content is set within the above range, the flatness at the time of coating is improved, and a color filter having a sufficient color density and excellent display characteristics can be formed, which is preferable. In the colored photosensitive resin composition of the present invention, the surfactant is composed of 24 314979 (amendment) l277832 xixi π non-surfactant, fluorine-based interfacial activity -113⁄4 έ X ^ ^ kiL ^ ... and fluorine atom-containing ruthenium In the group in which J is not a surfactant, ^ the active agent (the following is the interface of the one of the interface) (the following is also called "(F) component"). Take an anthrone-based surfactant which contains a fluorine atom of I atom. For example, it can be used as a smear of smear. Send brothers, the main volume of the book, transliteration) R08, the same as 2, the same F47s door F44 bamboo I α,, Μ75, with F477, the same (big Japanese ink chemical workers (shares) | y, A A u Department (also) clothing) Temple is taken as Meijia Fake (registered trademark, transliteration) F475. The ketone-based surfactants can be, for example: α ★, 'The interface activity of the stagnation bond. Specifically,牛牛J 仏田子吾矽 (commodity name, sound #) DC3PA, with SH7PA, with DC11PA, with SH2ipa, with the same view, with 29SHPA, with SH3GpA, polyether modified f Shixi oil (10) Che (trade name: Delei Town Shi Xikang (share) system); ΚΡ321, κρ322, κρ323, Km#, 6 ΚΡ 340, ΚΡ 341 (Shin-Etsukura Co., Ltd.) ;TSF4〇〇, TSF401 &gt; TSF41〇' TSF4300. TSF4440, TSF4445&gt; TSF-4446 ^ TSF4452 'TSF44460 (made by Gyoshi Toshiba Co., Ltd.), etc. Fluoro-based surfactants include, for example, a carbon chain Specific surfactants, for example, Frodon (registered trademark, transliteration) fc43〇, with FCM3U Sumitomo Seri Aim (share) system; Meijia Fake (registered trademark, sound § 睪) F142D with F171, with F172, with Fl73, with F177, with F183, with R30 (made by Otsuka Ink Chemical Industry Co., Ltd.); Aifubu. (registered trademark, Yinze) EF301, with EF3〇3, Tong An (5), Tongxin Akita Chemicals Co., Ltd.) Sang Fulong (registered trademark, transliteration) S381, same as S382, same as 25 314979 (amendment) 1277832 SCI 01, same as SCI 〇5 (Xu Shi Xiaozi (share) System); E5844 [(share) Daikin Fine Chemical Research Institute]; 31^-1 000, 3]\/1-1100 (all goods : 3] ^ &lt;: 1 ^ 11 ^ Co., Ltd.). These surfactants may be used alone or in combination of two or more. The component (F) is used in an amount of 0.0005 parts by weight to 〇·14 parts by weight, preferably 0.001 parts by weight to 0.12 parts by weight, based on the parts of the colored photosensitive resin composition excluding the component (F). In the range. When the content of the surfactant is set to 0.0005 part by weight to 0.14 part by weight, the flatness tends to be improved, which is preferable. The colored photosensitive resin composition of the present invention may further contain a polymer compound other than the (Β) binder polymer, a filler, a adhesion promoter, an antioxidant, an ultraviolet absorber, an anti-agglomerating agent, an organic acid, and an organic amine compound. , additives such as hardeners. The polymer compound other than the (Β) binder polymer may, for example, be polyethylene glycol, polyacrylic acid, polyethylene glycol monoalkyl ether or polyfluorinated alkyl acrylate. The filler may, for example, be fine particles such as glass or alumina. Examples of the adhesion promoter include vinyl trimethoxy decane, vinyl monoethoxy decane, vinyl tris(2-decyloxyethoxy) decane, and fluorenyl-(2-amine^aminopropylmethyl). Dimethoxy oxime, Ν-(2-aminoethyl-aminopropyltrimethoxy decane, 3-aminopropyltriethoxy decane, ^, lactopropyloxytrioxane Base decane, 3-glycidoxymethyl dimethyl ketone, 2-(3,4-epoxycyclohexyl)ethyltrimethoxydecane, 3-methoxymethyldimethoxydecane , 3-chloropropyltrimethoxydecane, 3-methyl 26 314979 (amendment) 1277832 acryloxypropyltrimethoxydecane, 3·mercaptopropyltrimethoxydecane, etc. The antioxidant may, for example : 4,4,-thiobis(6-tert-butyl-3-methylbenzenesulfonate), 2,6-di-dibutyl-4-methylbenzene, etc. Examples of the ultraviolet absorber include : 2_(2-hydroxy-3_t-butyl-5-methylphenyl)-5-gas benzotriazole and other stupid triazoles; 2_hydroxyoctyloxy bicinchone and the like , ketone system; 2,4_di-t-butylphenyl-3,5-di-t-butyl-4-hydroxybenzoate a triazine or the like such as 2_(4,6-diphenyl, giotriazine-2-yl)-5-hexyloxyphenol, etc. The anti-agglomeration agent may, for example, be sodium polyacrylate or the like. Such as: formic acid, acetic acid, propionic acid, butyric acid, oxalic acid, trimethylacetic acid, hexanoic acid, diethyl acetic acid, heptanoic acid, octanoic acid and other aliphatic monocarboxylic acids; oxalic acid, malonic acid, succinic acid, pentane Acid, adipic acid, gypsum, suberic acid, azelaic acid, sebacic acid, malic acid, methylmalonic acid, ethylpropionic acid, monomethylmalonic acid, mercapto succinic acid , tetradecyl succinic acid, % hexane dicarboxylic acid, itaconic acid, citraconic acid, maleic acid, antibutene dioxime, decyl fumaric acid and other aliphatic dicarboxylic acids; Aliphatic tricarboxylic acids such as formic acid, aconitic acid, and early brain acid; aromatic monocarboxylic acids such as benzoic acid, benzoic acid, cumanoic acid, 2,3-monophenylene acid, and dimercaptobenzoic acid An aromatic dicarboxylic acid such as citric acid, stupid I, terephthalic acid, aromatic polycarboxylic acid such as trimellitic acid, stupid monoterpene, tetrazoic acid, pyromellitic acid, etc. Etc., organic The compound may, for example, be n-propylamine, isopropylamine, n-butylamine, butylamine, first butylamine, second butylamine, n-pentylamine, n-hexylamine, n-heptylamine, 27 314979 (amendment) 1277832 n-octylamine, N-decylamine, n-decylamine, r ^ m 41 . monodecylamine, n-decylamine, n-decylamine, cyclohexylamine, cyclohexylamine, m-cyclohexylamine, etc. Methylcyclohexylamine, 4·methylamine, B λ/衣元基知; methyl ethylamine, diethylamine, methyl n-propenyl n-propylamine, di-n-propyl face, monobutylamine, and second second. Monoisopropylamine, di-n-butylamine, diisodialkylamine, female: an amine such as tributylamine, di-n-pentylamine, di-n-hexylamine, etc. A =, methyl 5 succinylamine, ethyl cyclohexyl A monoalkyl monocycloalkylalkylamine, such as an amine, a dicycloalkyl group such as a hexylamine, a dioxane makeup head, an ethylamine, a methyldiethylamine, a monoethylamine, a di-n-propylamine , diethylidene-ethyl-ethyl-propylamine, methyldi-n-propylamine, acetaminophen-n-propylamine, tri-n-propylenediamine, di-propylamine, tri-n-butylamine, tri-isobutyl-burning face +.s. a trialkylamine such as butylamine, tri-n-pentylamine or tri-n-hexylamine , dimethylcyclohexylamine, _ group amines. Review of monoalkyl monocycloalkyl groups such as monoethylhexylamine - succinyl mono-alkyl mono-alkane such as monohexylamine or tricyclohexylamine Amines; 2_Aminoethanol^. 4 A 1 , • Amino-1-propanol, 1-amino-2_ 月月女-1-butanol, 5-aminoalkanolamine, - Single females such as sterol and 6-amino-1-hexanol, 4-amino-1 _cyclohexanol 二 two positive: known as early stanolamines; diethanolamine, alcoholamines, Propylamine, di-n-n: u J-alcoholic, diisobutanol, - ruthenium, di-n-hexanolamine, etc. II dioxin 舻 相 phase one '4 (4-3⁄4 hexanol) Amines, etc. "female", triethanolamine, tri-n-butanolamine, riidine, π-endoamine, diisopropanolamine, triolamine, - U &gt; dioxin, hexanol a tricycloalkanediol such as trioxane, a (deductible % hexanol)amine, 2 face a, amino-1,2-propanyl-female ", 3-propane diol, 4-amine oxime, Amino], 3-butane diol...Methylamine: ketone-1,2-butanol diol, 4- kee-10-2-propyl, propylene glycol, 3-diethylamine, methylamine Base 1,3-propane Alkyl alkanediols such as alcohol, 2_diethylamine, propylene glycol, etc.; female soil 314979 (amendment) 28 1277832 4-amino-1,2-cyclohexanediol, 4·amine Aminocycloalkanediols such as keto-1,3βcyclohexyl diol; amine group-containing cycloalkanone methanols such as aminocyclopentanone 1 methanol, heart amine cyclopentanone methanol; Cyclohexylmethanol, heart amine cyclohexanol, 4-dimethylaminocyclopentanol, 4-diethylaminocyclopentanol, 4-dimethylaminocyclohexane methanol , an amine group-containing cycloalkane, such as diethylaminocyclohexane methanol; yS-alanine, 2-aminobutyric acid, 3-aminobutyric acid, 4-aminobutyric acid, 2_ Aminoisoacetic acid, 3-aminoisoacetic acid, 2-amino oxalic acid, 5-amino oxalic acid, 5-aminohexanoic acid, 1-aminocyclopropanecarboxylic acid, 1-aminocyclohexanecarboxylate An amine carboxylic acid such as an acid or 4-aminocyclohexanecarboxylic acid; aniline, o-methylaniline, m-methylaniline, p-methylamine, p-ethylaniline, p-propylaniline, p-isopropyl Aniline, p-n-butylaniline, p-tert-butylaniline, 1-naphthylamine, 2-naphthylamine, N,N-dimethylaniline, N , N_diethylaniline, p-methyl-N,N-didecylphenylamine and other aromatic amines; o-aminobenzyl alcohol, m-amino-alcohol, p-aminobenzyl alcohol, p-dimethylaminobenzyl alcohol Aminobenzyl alcohols such as p-diethylaminobenzyl alcohol; amino-based phenols such as o-aminophenol, m-aminophen, p-aminophenol, p-dimethylaminophenol, p-diethylaminophenol Classes; m-aminobenzoic acid, p-aminobenzoic acid, p-diamine-based benzoic acid, p-diethylaminobenzoic acid, and the like. The hardener may, for example, be a compound which is heated to react with a retarding group in the binder polymer to crosslink the binder polymer. Further, it may be polymerized separately to obtain a compound which hardens the colored pattern. The above compound may, for example, be an aerobic compound, an oxetane compound or the like. Examples of the epoxy compound include a combination of an A-type epoxy resin, a hydrogenated m-type epoxy resin, a biphenyl-based F-based epoxy resin, and a hydrogenation-linked ρ 314979 (Revised) 29 !277832 , phenolic varnish m &gt; η- ι-- 虱 虱 曰, other aromatic epoxy tree 曰 曰 曰裱 曰裱 、 、 、 、 、 、 _ _ _ _ _ _ ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... % 乳月月日, 缩 酉 酉 酉 酉 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰 曰^ 々虱 之外 ' 脂 fat and other brominated derivatives other than fat, 曰 曰 % % private or aromatic 俨 俨 t 乳化 乳化 乳化 & 、 、 、 、 、 、 、 、 、 、 、 , the isoprene of the isoprene, the bad oxide of the substance, the (indenyl) propyl hydrazine, the glycerin g (j), the vinegar, etc. Compound, isocyanuric acid triglycidyl = heterocyclic butyl, and examples thereof include: carbonated bis (oxetane), stupid / acetonide (milk-butane), adipate bis (oxetane) Alkane-p-xylylene vinegar double (oxygen) When the colored photosensitive resin composition of the present invention contains a curing agent such as an epoxidized product: an oxy-compound or a compound, it may be used as a curing agent such as a heterocyclic y-pyroxene or a cyclohexane-sintered bis(tetrahydrocarbazone). The oxetane (IV) containing the oxy-heterocyclic compound of the hydroxy group is prepared as a compound. The above compound may, for example, be a polybasic acid, a polycarboxylic acid anhydride or an acid generator. Examples of the polybasic acid include, for example, citric acid, 3, cardiodimethyl phthalic acid, m-benzene: formic acid: phthalic acid, pyromellitic acid, trimellitic acid, 1,4,5,8-nylene Aromatic polycarboxylic acids such as capric acid, 3,3·, 4,4,_benzophenone tetracarboxylic acid, amber, glutaric acid, adipic acid, and 2,3,4-butane tetracarboxylate Acid, cis-butadiene = aliphatic polycarboxylic acid such as succinic acid, itaconic acid; hexa-argon o-benzoic acid, 3, lenyltetrahydrophthalic acid, hexahydroisophthalic acid , hexahydroterephthalic acid, u, heart cyclopentane tris(4), u, heart-ring hexacarboxylic acid, cyclopentane tetracarboxylic acid, 〗 2, 4,5-cyclohexane tetracarboxylic acid, etc. Alicyclic group more than 30 314979 (amendment) 127783 2 yuan retinoids, etc. Polyhydric phthalic anhydrides such as, for example, trimellitic anhydride, 3,3,,4,4,-di# • phthalic anhydride, tetrazoic acid, partial acid anhydride; Aromatic polycarboxylic acid anhydride such as tetradecanoic acid dianhydride, acrylic acid anhydride icosonic anhydride, citric anhydride, dodecenyl succinyl sulphonate, dianhydride, etc. Anhydrides; one, butane tetracarboxylic acid hydrogen S, 1,2,4-cyclopenta γ ' ', gas song &amp; anhydride, 3,4 · dimethyl tetracyclopentane tetraphthalic acid dianhydride,! 4 &lt; , 2, 4 hexane hexane phthalic anhydride, dilute π bis-acid acid field, endia η pyrrolic anhydride, 5-norborns; ethylene glycol bis ( trimellitic acid:: phthalic anhydride: Aliphatic polycarboxylic acid anhydride carboxylic anhydrides and the like. The carboxylic acid anhydrides such as f oil trimellitic acid liver and the like which are vinegar-containing may also be used as the hardening agent of the 虱^^^^. For example, the brand name "Yarda Hadna EH" (Asahi Kasei Industry Co., Ltd. fj彳, 商σ)%) is the name of the trade name "Rika De" (trade name) , transliteration) (New Japan Physical and Chemical (stock) system), trade name "hall · ·" (New Japan). The above curing agents may be used alone or in combination of two or more. The colored photosensitive resin composition of the present invention contains the above (A) colored enamel, (B) a binder resin, a photopolymerizable compound, (D) a photopolymerization initiator, (E) a catalyzer, and (F) a surfactant. And (F) the surfactant contains a total of 0.0005 parts by weight to 〇·14 s by weight of the composition per 100 parts by weight of the remaining components except the surfactant, and 丨 5 mL of the colored photosensitive resin composition' In a clean glass cylindrical brown bottle 31 314979 (Revised) 1277832 having an octagonal rotor (20 mm in total length and 6.5 mm in diameter) and a capacity of 3OmL (height 65 mm, diameter: 33 mm), the octagonal rotor is rotated at 700 rpm using an octagonal rotor. After stirring for a second, when it was left to stand for 60 seconds, it was in a defoamed state. Here, in order to confirm the above-described defoaming state, a clean glass cylindrical brown bottle having a capacity of M1 (a product of 65 mm and a diameter of 33 mm) can be used, and an ordinary sampling bottle in which the opening portion can be tightly closed can be used. For example, round light = size bottle (model: 3126-02, made by mutual chemical chemistry). In this case, an octagonal rotor (a total length of 2 mm and a diameter of 6.5 mm) may be used, for example, an octagonal rotor [trade name, model number: 7_216·02, fluororesin (manufactured by Aachen)). In addition, after the octagonal rotor and the colored photosensitive resin composition are filled in the glass cylindrical brown bottle, the electromagnetic stirrer can be usually used to make the octagonal rotor rotate at 70 rpm. Specifically, for example, MAGNETIC STIRER Is 3g (manufactured by Ikeda Kogyo Co., Ltd.). Stirring in 60 seconds at an octagonal rotor rotation number of 700 rPm and then standing still after 600 seconds, all at room temperature (usually 15 to 3 Torr. Under the squat. In the so-called "defoaming state" means the composition, 纟A state in which no bubbles are substantially found on the liquid surface of the composition and the wall of the space portion, etc. Whether or not the colored photosensitive resin composition has been defoamed under the above conditions can be confirmed by performing the above-described defoaming state confirmation. The components are mixed and quantified to prepare a composition, and the defoaming state is confirmed. If it is determined by the confirmation that the defoaming state is not obtained, for example, the content ratio of the component in the composition is reduced, or the component (8) is From the fluorine-based interfacial activity, it is changed to a gas atom-containing alkaloid surfactant, or it is changed to a linaloquinone surfactant, and then the above-described defoaming state is confirmed. Then, 314979 (amendment) 32 1277832 It is possible to form a colored photosensitive resin composition which can repeat this action for the purpose of the defoaming state until the defoaming state is completed. The present invention uses the ##本, 邑戊先性树月曰group A method of forming a pattern by forming a product, specifically, for example, applying a colored photosensitive resin composition of the present invention to a substrate, and then applying a photosensitive resin from the poorly coated soil. In the composition layer, a volatile component such as a solvent is removed, and a layer in which the volatile component is removed is exposed and developed by a P5. The substrate may be, for example, a glass substrate, a germanium substrate, or a polycarbonate substrate. a flat surface substrate such as a polyester substrate, an aromatic (tetra) amine substrate, a ruthenium (iv) imine substrate, a (iv) imine substrate, a ruthenium substrate, or a GaAs substrate. The substrates may also be conjugated with a drug such as a decane coupling agent for treatment and electricity. The slurry is treated with an ion bond treatment, a money treatment, a gas phase reaction treatment, a vacuum evaporation treatment, etc. When the substrate is made of a tantalum substrate or the like, a charge coupled device (CCD) or a film may be formed on the surface of the tantalum substrate or the like. A crystal (tft), etc. When the colored photosensitive resin composition is applied onto the above substrate, it is only required to be coated by a conventional spin coater or a liquid-saving coater (especially, preferably without a spin coater). On the substrate or the like, a volatile component such as a solvent is heated and volatilized. In this case, a layer composed of a solid component of the colored photosensitive resin composition can be formed on the substrate or the like. Next, the layer formed of the solid portion of the colored photosensitive resin composition (hereinafter referred to as "the coloring photosensitive resin composition solid portion layer") is exposed. In terms of exposure, it is only necessary to irradiate through the mask. Light can be used. Light can be generally called g-line (wavelength 436nm), i-line (wavelength 365nm) ultraviolet light, etc. Light is irradiated through the reticle. Here, "Photomask 33 314979 (Revised) 1277832 For example, a light-shielding layer for shielding light is provided on the surface of the glass plate. The portion where the light-shielding layer is not provided in the glass plate is a light-transmissive light-transmitting portion, and the colored photosensitive resin composition is made by using a pattern according to the pattern of the light-transmitting portion. When the layer is exposed to light, an unirradiated area that is not irradiated with light and an irradiation area that is irradiated with the fine light are generated. The amount of light irradiation in the irradiation area is the weight average molecular weight, the monomer ratio, the content, the type or content of the photopolymerizable compound, the type or content of the photopolymerization initiator, and the type or content of the photopolymerization initiator. Choose the appropriate factors. After exposure, development is carried out. In the development, it is only necessary to bring the colored photosensitive resin composition layer after exposure to contact with the developer, and specifically, only the substrate on the surface in which the photosensitive resin composition layer is formed is colored. It can be immersed in the developer. The developing solution may, for example, be an aqueous solution of an alkaline compound such as sodium carbonate, potassium carbonate, sodium hydroxide, potassium hydroxide or 'hydrogen tetradecyl ammonium. The unexposed area which is not irradiated with light in the colored photosensitive resin composition layer is removed by development. In addition, the light-irradiated area remains as it is to form the pattern γ. After development, it is usually washed by water and dried to obtain the target pattern. It can also be heated after drying. When it is hardened by heating the pattern, it tends to increase the mechanical strength, and when the colored photosensitive resin composition is used in the case of containing a hardener, the mechanical strength can be further improved. The heating temperature is usually above 180 ° C, preferably at least 200 t, usually below 25 Torr. According to this, it is possible to form a layer composed of a colored photosensitive resin composition of different colors on a substrate on which a colored pattern is formed, and further containing a coloring agent of a different color, and then exposing the layer. By 314979 (amendment) 34 1277832 By developing, a colored pattern can be formed. Even by using the colored photosensitive tree composition colored in different colors and repeating the above operation, a colored pattern can be sequentially formed, and a target color filter can be manufactured. In other words, in general, the color filter has a black matrix and a red, green, and blue primary coloring pattern disposed on the substrate, but it is also possible to use the colored photosensitive resin composition of the present invention containing a coloring agent of a certain color.纟 repeating the above operation to obtain a black matrix or a colored pattern of the color, and other related colors, also using the colored photosensitive resin composition of the present invention containing a colorant of a desired color and performing the same operation. The color pattern with the three primary colors is disposed on the substrate. Further, after the coloring pattern or the black matrix of a certain color is disposed on the substrate, when the colored photosensitive resin composition of the other color is processed, the colored photosensitive resin composition of a certain color is applied and dried. The patterning exposure is performed on the color pattern of a certain color or the position where the black matrix is not disposed, and the color pattern or the black matrix of the other color can be disposed at the exposed position. Of course, any one, two or three of the black matrix and the three primary colors may be used as the coloring photosensitive resin composition of the present invention. Further, since the black matrix belonging to the light shielding layer is formed of, for example, a chromium layer or the like, in this case, of course, the coloring photosensitive resin composition of the present invention is not required to be formed on the black matrix. The color filter obtained in this manner contains a pattern, and a liquid crystal display device can be obtained by assembling the above-mentioned shirt color light-receiving sheet into a liquid crystal display device. In the above, the embodiments of the present invention have been described. However, the embodiments of the present invention disclosed above are merely examples, and the scope of the present invention is not limited to such implementations. form. The scope of the present invention is defined by the scope of the claims, and all of the changes in the scope of the claims and the scope of the invention are included. Hereinafter, the present invention will be described in more detail by way of examples, but the invention is not limited to the examples. The components used in the present embodiment are as follows, and the following is a brief case. θ No (A-1) Colorant: CI Pigment Red 254 ^ (A_2) Colorant: cI Pigment Yellow 139 (B) Adhesive Polymer··Copolymer of methacrylic acid and benzyl methacrylate [Mercaptoacrylic acid The ratio of the unit to the benzyl methacrylate unit is 27:73, the acid value is 83, and the weight average molecular weight of the polystyrene is 18, 〇〇〇] related binding polymer The measurement of the weight average molecular weight was carried out by the Gpc method under the following conditions.

裝置：HLC-8120GPC(東蘇（公司名，音譯）（股）製） 柱體：TSK-GELG2000HXL 柱體溫度：40°C 溶劑：THF 聚苯乙烯標準品：聚苯乙烯（東蘇（公司名，音譯）（股） 製、Mw : 9100)Device: HLC-8120GPC (made by Dongsu (company name, transliteration))) Column: TSK-GELG2000HXL Column temperature: 40 °C Solvent: THF Polystyrene Standard: Polystyrene (Dongsu (company name) , transliteration) (share) system, Mw: 9100)

流速：l.Oml/min 注入量：5Ομί 檢測器：RI (C) 光聚合性化合物：二季戊四醇六丙烯酸酯 36 314979(修正本） 1277832 (D-1)光聚合起始劑：2•甲基_2_嗎啉代小(4•甲基硫代 苯）丙烧-1 -酉同 (D-2)光聚合起始劑：2,‘雙（三氣甲基）_6_胡椒基 -1，3,5-三嗪 一 ’、 (G-1)光聚合起始助劑：2，扣二乙基噻噸_ (E-1)溶劑··丙二醇單甲醚醋酸酿 (E-2)溶劑：3-乙氧基丙酸乙鴨 實施例1 [者色感光性樹脂組成物之調製] 4·〇7〇重量份 〇·955重量份 1 ·5〇7重量份 3 · 2 2 9重量份 3·947重量份 〇·43 1重量份 〇·431重量份 〇·43ΐ重量份 76.502重量份 8 · 5 0 〇重量份 (A-1) (A-2) 聚醋糸顏料分散劑 (B) (C) (D-1) (D-2) (G-1) (E-1) (E-2) 將上述進行混合而獲得混合物1。在混合物1中混合 入（F)界面活性劑的美佳發克（註冊商標，音譯）F475(大曰本 油墨化學工業（股）製、含全氟烷基之矽酮寡聚物）〇〇1〇重 量份’而獲得著色感光性樹脂組成物1。Flow rate: l.Oml/min Injection amount: 5 Ομί Detector: RI (C) Photopolymerizable compound: dipentaerythritol hexaacrylate 36 314979 (amendment) 1277832 (D-1) photopolymerization initiator: 2•methyl _2_morpholino small (4•methylthiobenzene)propanone-1 - bis (D-2) photopolymerization initiator: 2, 'bis (trimethyl)methyl-6_piperidin-1 , 3,5-triazine-', (G-1) photopolymerization initiation aid: 2, deducted diethylthiophene _ (E-1) solvent · propylene glycol monomethyl ether acetate (E-2) Solvent: 3-Ethoxypropionic acid ethyl duck Example 1 [Preparation of composition of photosensitive resin composition] 4·〇7〇 parts by weight 955·955 parts by weight 1 ·5〇7 parts by weight 3 · 2 2 9 weight 3,947 parts by weight 〇·43 1 part by weight 〇·431 parts by weight 〇·43 ΐ parts by weight 76.502 parts by weight 8 · 5 0 〇 parts by weight (A-1) (A-2) Polyacetate pigment dispersant (B (C) (D-1) (D-2) (G-1) (E-1) (E-2) Mix the above to obtain the mixture 1. Mikafa (registered trademark, transliteration) F475 (manufactured by Otsuka Ink Chemical Industry Co., Ltd., perfluoroalkyl-containing fluorenone oligomer) 混合1 mixed with (F) surfactant in mixture 1. The coloring photosensitive resin composition 1 was obtained by the weight part.

314979(修正本） 37 1277832 斤在容量30mL(高度65mm、直徑33mm)的潔淨破璃製 圓筒狀褐色瓶中，填充入上述著色感光性樹脂組成物314979 (Revised) 37 1277832 jin filled in the above-mentioned colored photosensitive resin composition in a clean glass-filled cylindrical brown bottle having a capacity of 30 mL (height 65 mm, diameter: 33 mm)

HmL，在此褐色瓶中裝入八角轉子（全長2㈣功、直徑 6j.5mm)/ [商品名、型號· 7-216_〇2、氟樹脂製（亞日王（股） 製）]’採用電磁攪拌器[MAGNETIC STIRER IS 3G(池田科 技月又伤有限公司製）]，以7晰pm的速度進行M秒鐘檀掉 而起/包。所獲得著色感光性樹脂組成物的泡沫在4?〇秒内 消失。 “ 1 [利用無旋轉塗布機的評估] 將所獲知著色感光性樹脂組成物，經採用無旋轉塗布 機形成塗膜，而獲得平坦性佳且無紋斑的塗膜。 土 實施例2 』除將實施例！中之（F)成分的美佳發克（註冊商標，音 譯）F475(大曰本油墨化學工業（股）製）添加量，改為 重量份之外，其餘均如同實施例】，調製著色感光性樹脂 組成物。 [評估] 著色感光性樹脂組成物的泡沫在5〇〇秒内消失。 [利用無旋轉塗布機的評估] 將所獲得著色感光性樹脂組成物，經採用無旋轉塗布 機形成塗膜，而獲得平坦性佳且無紋斑的塗膜。 實施例3 除將實施例1中之（F)成分的美佳發克（註冊商標，音 譯）F475(大日本油墨化學工業（股）製）添加量，改為 314979(修正本) 38 1277832 重篁份之外，其餘均如同實施例丨，調製著色感光性樹脂 組成物。 [評估] 著色感光性樹脂組成物的泡沫在55〇秒内消失。 [利用無旋轉塗布機的評估] 將所獲得著色感光性樹脂組成物，經採用無旋轉塗布 機形成塗膜，而獲得平坦性佳且無紋斑的塗膜。土 實施例4 除將實施例i中之（F)成分的美佳發克（註冊商禪，立 譯^475(大曰本油墨化學工業（股）製）添加量，改為 重量份之外，其餘均如同實施例if周製著色感光 組成物。 对乃曰 [評估] 著色感光性樹脂組成物的泡沫在600秒内消失。 [利用無旋轉塗布機的評估] 將所獲付者色感光性樹脂組成物，經採用無旋轉 機形成塗膜’而獲得平坦性佳且無紋斑的塗膜。土 比較例1 除將實施例i中之⑺成分的美佳發克（註冊商標，立 =\75(大日本油墨化學工業（股）製）添加量，改為0‘ 組均如同實施例丨’調製著色感光性樹脂 [評估] 著色感光性樹脂組成物的料在_秒内消失。 314979(修正本) 39 1277832 [利用播疑轉塗布機的評估] 將所u于著色感光性樹脂組成物，經採用無旋轉塗布 機形成塗膜，而獲得平坦性不佳且有紋斑的塗膜。 比較例2 、 Λ除將實施例1中之（F)成分的美佳發克（註冊商標，音 。睪)=5(大日本油墨化學工業（股）製）添加量，改為 重量份之外’其餘均如同實施例】，調製著色感光性樹脂 組成物。 [評估] 著色感光性樹脂組成物的泡沫在1 2 〇 〇秒内消失。 [利用無旋轉塗布機的評估] 將所獲得著色感光性樹脂組成物，經採用無旋轉塗布 機幵^成塗膜’而獲得平坦性不佳且有紋斑的塗膜。 除無添加實施例1中之（F)成分的美佳發克（註冊商 标’音譯）F475(大日本油墨化學工業（股）製）之外，其餘均 士同貝施例1 ’調製著色感光性樹脂組成物。 [評估] 著色感光性樹脂組成物的泡沫在1 00秒内消失。 [利用無旋轉塗布機的評估] 將所獲得著色感光性樹脂組成物，經採用無旋轉塗布 機形成塗膜，而獲得平坦性不佳且有紋斑的塗膜。 除將實施例1中之（F)成分的美佳發克（註冊商標，音 40 314979(修正本) 1277832 譯州5(大日本油墨化學工業（股）製）〇 〇ι〇重量份，改為聚 商品名：德雷^康（股）製）〇〇〇5重 篁份之外，其餘均如同實施们，調製著色感光性樹脂組 [評估] 著色感光性樹脂組成物的泡沫在丨〇〇秒内消失。 [利用無旋轉塗布機的評估] 將所獲得著色感光性樹脂組成物，經採用無旋轉塗布 機形成塗膜’而獲得平坦性佳且無紋斑的塗膜。 實施例6 除將實施例1中之（F)成分的美佳發克（註冊商標，音 譯）F475(大日本油墨化學工業（股）製）〇〇1〇重量份，改為聚 醚改質矽油SH8400(商品名：德雷禧矽康（股）製）之外，其 餘均如同實施例1，調製著色感光性樹脂組成物。 [評估] 著色感光性樹脂組成物的泡沫在1 00秒内消失。 [利用無旋轉塗布機的評估] 將所獲得著色感光性樹脂組成物，經採用無旋轉塗布 機形成塗膜，而獲得平坦性佳且無紋斑的塗膜。 實施例7 除將實施例1中之（F)成分的美佳發克（註冊商標，音 譯）F475(大日本油墨化學工業（股）製）0·010重量份，改為聚 醚改質矽油SH8400(商品名：德雷禧矽康（股）製）0.050重 量份之外，其餘均如同實施例丨，調製著色感光性樹脂組 41 314979(修正本) 1277832 成物。 [評估] 著色感光性樹脂組成物的泡沫在i 〇〇秒内消失。 [利用無旋轉塗布機的評估] 將所狻得著色感光性樹脂組成物，經採用無旋轉塗布 機形成塗膜，而獲得平坦性佳且無紋斑的塗膜。 土 實施 除將實施例1中之（F)成分的美佳發克（註冊商標，音 譯）F475(大曰本油墨化學工業（股）製）〇 〇1〇重量份，改為聚 醚改貝矽油SH8400(商品名：德雷禧矽康（股）製）〇1⑼重 量份之外，其餘均如同實施例丨，調製著色感光性樹脂組 成物。 [評估] 著色感光性樹脂組成物的泡沫在i 〇5秒内消失。 [利用無旋轉塗布機的評估] 將所G彳于著色感光性樹脂組成物，經採用無旋轉塗布 機形成塗膜，而獲得平坦性佳且無紋斑的塗膜。 依…、本赉明之著色感光性樹脂組成物的話，即便採用 無旋轉塗布機等省液塗布機，將上述著色感光性樹脂組成 物塗布方、基板上，便可形成無產生紋斑，且膜厚面内均勻 性佳的彩色濾光片。 42 314979(修正本）HmL, the octagonal rotor (full length 2 (four) work, diameter 6j.5mm) / [trade name, model number 7-216_〇2, fluororesin (made by Yariwang Co., Ltd.)] The electromagnetic stirrer [MAGNETIC STIRER IS 3G (made by Ikeda Technology Co., Ltd.)], at a speed of 7 pm, was thrown off/packed for M seconds. The foam of the obtained colored photosensitive resin composition disappeared within 4 ? seconds. "1 [Evaluation by Rotor-Free Coating Machine] The obtained photosensitive resin composition was formed into a coating film by a spin coater to obtain a coating film having good flatness and no plaque. In the example, the amount of the (F) component of the Mejia Fake (registered trademark, transliteration) F475 (manufactured by Otsuka Ink Chemical Industry Co., Ltd.) is changed to the weight portion, and the rest is the same as the example] The photosensitive resin composition was colored. [Evaluation] The foam of the coloring photosensitive resin composition disappeared within 5 sec. [Evaluation by a spin coater] The obtained coloring photosensitive resin composition was subjected to spin coating. The coating film was formed to obtain a coating film having good flatness and no plaque. Example 3 In addition to the composition of the component (F) of Example 1, Mikake (registered trademark, transliteration) F475 (Daily Ink Chemical Industry Co., Ltd. The amount of the addition is changed to 314979 (Revised) 38 1277832 In addition to the retanning, the rest is the same as the Example 调制, and the coloring photosensitive resin composition is prepared. [Evaluation] The foam of the colored photosensitive resin composition is 55 〇. [Evaluation by Rotor-Free Coating Machine] The obtained coloring photosensitive resin composition was formed into a coating film by a spin coater to obtain a coating film having good flatness and no plaque. The addition amount of the (F) component of the component (F) in Example i (registered quotient, the translation of the 475 (manufactured by Otsuka Ink Chemical Industry Co., Ltd.)) was changed to the weight portion, and the rest was as in the example if The coloring photosensitive composition was prepared by a week. [Evaluation] The foam of the coloring photosensitive resin composition disappeared within 600 seconds. [Evaluation by a spin coater] The photosensitive resin composition obtained was used. The coating film was formed without a rotating machine to obtain a coating film having good flatness and no plaque. Soil Comparative Example 1 In addition to the composition of the component (7) in Example i (registered trademark, Li = \75 (Daily Ink Chemical Industry) The amount of addition was changed to 0' group as in Example 调制 'Preparation of coloring photosensitive resin [Evaluation] The material of the coloring photosensitive resin composition disappeared within _ seconds. 314979 (Revised) 39 1277832 [Usage Evaluation of the so-called transfer coating machine] u, the coloring photosensitive resin composition was formed into a coating film by a spin coater to obtain a coating film having poor flatness and streaking. Comparative Example 2, the component (F) of Example 1 was removed. Mejiafake (registered trademark, sound. 睪) = 5 (manufactured by Dainippon Ink Chemical Industry Co., Ltd.) was added in an amount other than the weight portion, and the rest were as in the examples, and a coloring photosensitive resin composition was prepared. Evaluation] The foam of the coloring photosensitive resin composition disappeared within 1 2 sec. [Evaluation by a spin coater] The obtained coloring photosensitive resin composition was formed into a coating film by using a spin coater. A coating film having poor flatness and streaking was obtained, except for the addition of the FF (registered trademark 'transliteration) F475 (manufactured by Dainippon Ink Chemical Industry Co., Ltd.) of the component (F) in Example 1. The rest of the same as the shell example 1 'modulation coloring photosensitive resin composition. [Evaluation] The foam of the colored photosensitive resin composition disappeared in 100 seconds. [Evaluation by Non-Rotary Coating Machine] The obtained coloring photosensitive resin composition was formed into a coating film by a spin coater to obtain a coating film having poor flatness and streaking. In addition to the (F) component of the (F) component of Example 1, the registered trademark, the sound 40 314979 (amendment) 1277832 translation state 5 (Daily Ink Chemical Industry Co., Ltd.) 〇〇ι〇 parts by weight, Poly product name: Delei (Kang) Co., Ltd.) 〇〇〇5 篁 篁 , , , 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制 调制Disappeared in seconds. [Evaluation by Non-Rotary Coating Machine] The obtained coloring photosensitive resin composition was formed into a coating film by a spin coater to obtain a coating film having good flatness and no plaque. Example 6 In addition to the propylene carbonate (registered trademark, transliteration) F475 (manufactured by Dainippon Ink Chemical Industry Co., Ltd.) of the component (F) in Example 1, 聚醚1 〇 by weight was changed to polyether modified eucalyptus oil. Other than the SH8400 (trade name: manufactured by Draycon), the coloring photosensitive resin composition was prepared as in Example 1. [Evaluation] The foam of the colored photosensitive resin composition disappeared in 100 seconds. [Evaluation by Rotor-Free Coating Machine] The obtained coloring photosensitive resin composition was formed into a coating film by a spin coater to obtain a coating film having good flatness and no plaque. Example 7 In addition to the 0. 010 parts by weight of the Fika (registered trademark, transliteration) F475 (manufactured by Dainippon Ink Chemicals Co., Ltd.) of the component (F) in Example 1, the polyether modified oyster sauce SH8400 was changed. (Product name: manufactured by Dresden Co., Ltd.), except for 0.050 parts by weight, the same was carried out as in Example 丨, and a coloring photosensitive resin group 41 314979 (amendment) 1277832 was prepared. [Evaluation] The foam of the colored photosensitive resin composition disappeared within i sec. [Evaluation by Rotor-Free Coating Machine] A colored photosensitive resin composition was obtained, and a coating film was formed by using a spin coater to obtain a coating film having good flatness and no plaque. In addition to the composition of the (F) component of Example 1, the F. (trademark, transliteration) F475 (manufactured by Otsuka Ink Chemical Industry Co., Ltd.) was changed to 1 part by weight to be changed to polyether modified beryllium oil. Other than the 1 (9) parts by weight of SH8400 (trade name: manufactured by Dresden Co., Ltd.), the coloring photosensitive resin composition was prepared as in the Example. [Evaluation] The foam of the colored photosensitive resin composition disappeared within 5 seconds of i 〇. [Evaluation by Non-Rotary Coating Machine] The coating film was formed by coating a coloring photosensitive resin composition with a spin coater to obtain a coating film having good flatness and no plaque. According to the color-sensitive resin composition of the present invention, even if the coloring photosensitive resin composition is coated on the substrate or the substrate by using a liquid-saving coating machine such as a spin coater, the film can be formed without a plaque. A color filter with good uniformity in a thick surface. 42 314979 (amendment)

Claims (1)

1277832 弟9 2 1 2 3 1 2 3號專利申請案 申請專利範圍修正本 (95年11月13日） 1 · 一種著色感光性树脂組成物’係含有（A)著色劑、（B)霉占 結樹脂、（C)光聚合性化合物、（D)光聚合起始劑、（幻 溶劑、以及（F)由石夕嗣系界面活性劑、氟系界面活性劑、 與具氟*原子的石夕嗣系界面活性劑所構成組群中選擇至 少1種的界面活性劑者， 其中，相對於除（F)成分以外之其餘成分的總計每 重里伤’（F)成分係含有0.0005重量份以上、ο 〗#重 量份以下； 在具備八角轉子（全長20mm、直徑6.5mm)之容量 3〇mL(高度65mm、直徑33mm)的潔淨玻璃製圓筒狀褐 色瓶中，將1 5mL著色感光性樹脂組成物利用八角轉子 以旋轉數700rpm進行60秒鐘攪拌之後，再經靜置6〇〇 秒時，便呈消泡狀態者。 I·. 〇申請專利範圍第1項之著色感光性樹脂組成物，其 中’依著色感光性樹脂組成物之固形分中的質量分率 &amp;外’（B)黏結聚合物之含量為5至40%。 種由著色感光性樹脂組成物所構成的層，係在基板 上將申請專利範圍第1或2項之著色感光性樹脂組成 扭用無旋轉塗布機（SpinleSs coator)進行塗布而形成 者。 種圖案’其特徵係將申請專利範圍第1或2項之著色 1 (修正本）314979 1277832 感光性樹脂組成物，塗布於基板上，再從所塗布的著色 感光性樹脂組成物層中去除揮發成分，經由光罩對上述 層進行曝光、顯影而形成者。 5. 6. 種彩色濾光片，其特徵係含有申請專利範圍第4項之 圖案。 、 一種液晶顯示裝置，其特徵係安裝有申請專利範圍第5 項之彩色濾光片（color filter)者。 2 (修正本）3149791277832 Brother 9 2 1 2 3 1 2 Patent Application Revision No. 3 (November 13, 1995) 1 · A colored photosensitive resin composition' contains (A) colorant, (B) mildew a knot resin, (C) a photopolymerizable compound, (D) a photopolymerization initiator, (a magic solvent, and (F) a stone interfacial surfactant, a fluorine-based surfactant, and a stone having a fluorine* atom When at least one type of surfactant is selected from the group consisting of the surfactants, the total amount of the component (F) is 0.0005 parts by weight or more based on the total amount of the components other than the component (F). ο 〗 〖# parts by weight; In a clean glass cylindrical brown bottle with an octagonal rotor (20 mm in length and 6.5 mm in diameter) with a capacity of 3 〇mL (height 65 mm, diameter 33 mm), 15 mL of colored photosensitive resin The composition was stirred in an octagonal rotor at a rotation number of 700 rpm for 60 seconds, and then left to stand for 6 seconds, and then defoamed. I·. 著 Patent Application No. 1 of the colored photosensitive resin composition , in which 'the color of the photosensitive resin composition The mass fraction of the fraction &amp; the outer (B) binder polymer content is 5 to 40%. The layer composed of the colored photosensitive resin composition is on the substrate and will be patented in the first or second paragraph. The colored photosensitive resin composition is formed by coating with a spin coater (SpinleSs coater). The pattern is characterized by the coloring of the first or second application of the patent range 1 (amendment) 314979 1277832 photosensitive resin composition The material is applied to a substrate, and the volatile component is removed from the applied colored photosensitive resin composition layer, and the layer is exposed and developed through a photomask. 5. 6. Color filter, characteristics thereof A pattern containing the fourth item of the patent application scope. A liquid crystal display device characterized in that a color filter of the fifth application patent is installed. 2 (Revised) 314979
TW092123123A 2002-08-26 2003-08-22 Colored photosensitive resin composition TWI277832B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2002244970A JP4269596B2 (en) 2002-08-26 2002-08-26 Colored photosensitive resin composition

Publications (2)

Publication Number Publication Date
TW200407674A TW200407674A (en) 2004-05-16
TWI277832B true TWI277832B (en) 2007-04-01

Family

ID=32053299

Family Applications (1)

Application Number Title Priority Date Filing Date
TW092123123A TWI277832B (en) 2002-08-26 2003-08-22 Colored photosensitive resin composition

Country Status (3)

Country Link
JP (1) JP4269596B2 (en)
KR (1) KR100999826B1 (en)
TW (1) TWI277832B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4502784B2 (en) * 2004-06-07 2010-07-14 富士フイルム株式会社 Color filter, color filter manufacturing method, and liquid crystal display device
JP4815952B2 (en) * 2005-08-26 2011-11-16 Ｊｓｒ株式会社 Polymer, radiation sensitive composition for color filter, color filter and color liquid crystal display panel
CN101379132B (en) * 2006-03-10 2011-07-27 三菱化学株式会社 Curable composition, color filter, and liquid crystal display device
KR101286705B1 (en) 2006-10-31 2013-07-16 삼성디스플레이 주식회사 Light source and lens for light source and backlight assembly having the same
WO2008096782A1 (en) * 2007-02-06 2008-08-14 Jsr Corporation Photosensitive resin composition, transfer film, and method of forming pattern
CN103489021A (en) 2007-09-25 2014-01-01 黑卡有限公司 Carbon transaction card
KR101658374B1 (en) * 2013-01-25 2016-09-22 롬엔드하스전자재료코리아유한회사 Colored photosensitive resin composition with dual property for column spacer and black matrix

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02804A (en) * 1987-12-18 1990-01-05 Fuji Photo Film Co Ltd Formation of multicolor pattern for color filter
JP3572731B2 (en) * 1995-07-26 2004-10-06 三菱化学株式会社 Color filter
JPH10293397A (en) * 1997-04-22 1998-11-04 Jsr Corp Radiation-sensitive composition for color filter
JP3684878B2 (en) * 1998-11-24 2005-08-17 東レ株式会社 Coating apparatus, coating member manufacturing method, and color filter manufacturing apparatus and manufacturing method
JP2000157907A (en) * 1998-11-25 2000-06-13 Canon Inc Single-wafer coating method, single-wafer coating apparatus, and color filter manufacturing method
JP2001195004A (en) * 2000-01-11 2001-07-19 Sony Corp Flat panel display, method of manufacturing the same, and color filter
JP4185245B2 (en) * 2000-12-26 2008-11-26 富士フイルム株式会社 Negative photosensitive thermosetting colored resin composition, transfer material using the same, and image forming method
JP2008209952A (en) * 2008-05-23 2008-09-11 Sumitomo Chemical Co Ltd Method for applying colored photosensitive resin composition

Also Published As

Publication number Publication date
JP2004085773A (en) 2004-03-18
KR20040030266A (en) 2004-04-09
KR100999826B1 (en) 2010-12-10
JP4269596B2 (en) 2009-05-27
TW200407674A (en) 2004-05-16

Similar Documents

Publication Publication Date Title
CN101617272B (en) Photosensitive resin composition for black matrix, black matrix prepared from the composition and liquid crystal display including the black matrix
JP2020144396A (en) Colored photosensitive resin composition suitable for both column spacers and black matrix
CN106019837B (en) Colored photosensitive resin composition, color filter, and image display device including the same
CN111399340B (en) Colored photosensitive resin composition, color filter comprising same, and display device
TWI264564B (en) Radiation sensitive composition for color filter, color filter, manufacturing method of liquid crystal color display, and forming method of colored layer of color filter
TWI670565B (en) A photosensitive resin composition, color filter and display device comprising the same
TWI516864B (en) Colored photosensitive resin composition
JP2022028693A (en) Method of preparing column spacer
TWI675254B (en) Blue photosensitive resin composition, blue color filter and display device having the same
TWI700551B (en) Colored photosensitive resin composition, color filter and image display device produced using the same
TW201531513A (en) Color photosensitive resin composition, color filter and display device comprising the same
KR101907220B1 (en) Photosensitive resin composition for black matrix, black matrix by the composition and display device including the black matrix
JP2014123116A (en) Photosensitive resin composition
TWI767904B (en) Colored photosensitive resin composition and color filter comprising the same
TWI277832B (en) Colored photosensitive resin composition
JP2003043685A (en) Color composition, and photosensitive color composition for color filter
CN101561631A (en) Coloring light-sensitive resin composition
CN104932196B (en) Colored photosensitive resin composition and colour filter comprising the composition
TW201736950A (en) Colored photosensitive resin composition and column spacer comprising the same
TW201807484A (en) A blue photosensitive resin composition, blue color filter and display device comprising the same
TWI313397B (en) Colored photosensitive resin composition
TWI361948B (en) Coloring photosensitive resin composition
JP2010085833A (en) Blue resist composition
TWI724045B (en) A blue photosensitive resin composition, blue color filter and display device comprising the same
JP3356749B2 (en) Photosensitive resin composition

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees