下面進一步詳細說明本發明。 本發明中，當記載為某一部件位於其他部件之“上”時，此不僅包括某一部件與其他部件接觸之情況，亦包括兩個部件之間設置有另一部件的情況。 本發明中，當記載某一部分“包括”某一構成要素時，在沒有明確相反之記載的情況下，表示並不排除其他構成要素，且可以進一步包括其他構成要素。 本發明提供著色感光性樹脂組合物及由其製造的彩色濾光片。著色感光性樹脂組合物
本發明之著色感光性樹脂組合物包含著色劑，該著色劑包含C.I.顏料綠59及C.I.顏料藍16。本發明之著色感光性樹脂組合物包含黏合劑樹脂、光聚合化合物、光聚合引發劑及溶劑，此外，亦可進一步包括此項技術常用之輔助成分，例如添加劑。著色劑
本發明之著色劑為了提供高色彩再現性的著色層而包含C.I.顏料綠59及C.I.顏料藍16。此外，本發明之著色劑包含C.I.顏料綠59及C.I.顏料藍16之外，亦可包含C.I.顏料綠58。 該著色劑藉由使用包含綠色顏料及藍色顏料之二元系混合顏料，不僅能夠實現綠色及藍色的寬色彩範圍，亦可呈現高亮度及高對比度或優異的著色力。此外，亦可呈現優異圖案形成性之優點。 在本發明中，該C.I.顏料綠59或C.I.顏料綠58主要起到使組合物呈現綠色之功能，C.I.顏料藍16起到使組合物呈現藍色之功能。 此時，C.I.顏料綠59相對於C.I.顏料藍16之重量比可配置為3:97至50:50，具體為5:95至15:75。 相對於該著色感光性樹脂組合物總固體成分，該著色劑組合物之含量可為10至60重量份，具體為20至60重量份；更具體為30至60重量份。該著色劑含量滿足上述範圍時，具有如下優點：即使形成薄膜，像素的色彩濃度亦充分，且能夠防止在顯影過程中非像素部的遺漏性降低的現象，因此有不易產生殘渣等優點。 在本發明中，該著色感光性樹脂組合物總固體成分或著色感光性樹脂組合物中的固體成分可以表示移除溶劑之成分的合計。 在上述著色劑包含顏料時，可藉由使著色劑含有顏料分散劑而進行分散處理，從而能夠獲得顏料在溶液中均勻分散狀態的顏料分散液。 該顏料分散劑可為例如陽離子類、陰離子類、非離子類、陽性、聚酯類、聚胺類及聚丙烯酸類等界面活性劑等，可以單獨使用或以兩種以上之組合使用。使用顏料分散劑時，相對於著色材料1重量份，其使用量較佳為低於1重量份，更佳為0.05至0.5重量份。顏料分散劑的使用量在上述範圍時，由於能夠獲得均勻分散狀態的顏料，因此較佳。 根據本發明之著色劑除了上述的顏料之外，在不超出本發明目的之範圍內，亦可包含此項技術使用的顏料及染料。 例如，該著色劑亦可包含C.I.顏料黃系列。該著色劑進一步包含C.I.顏料黃系列時，具有能夠實現更寬色彩範圍的優點。 本發明中可以進一步包含的顏料包括有機顏料及無機顏料。 該有機顏料可以使用用於印刷墨水、噴墨墨水等之各種顏料，具體地可以舉例為鐵酞菁(Phthalocyan)(水溶性偶氮顏料、不溶性偶氮顏料)、酞菁顏料、喹吖啶酮顏料、異吲哚啉酮顏料、異吲哚啉顏料、二萘嵌苯顏料、茈酮(perynone)顏料、二噁嗪顏料、蒽醌顏料、二蒽醌顏料、蒽并嘧啶(anthrapyrimidine)顏料、蒽嵌蒽醌(anthanthrone)顏料、陰丹酮(indanthrone)顏料、黃烷士酮(flavanthrone)顏料、皮蒽酮(pyranthrone)顏料或吡咯并吡咯二酮顏料等。 該無機顏料可為金屬氧化物或金屬錯合物等金屬化合物，具體可以舉例為鐵、鈷、鋁、鎘、錫、銅、鈦、鎂、鉻、鋅、銻等金屬的氧化物或複合金屬氧化物等。 具體而言，該有機顏料及無機顏料具體地可為在染料索引(英國染色工作者協會出版)中分類為顏料的化合物，更具體地，可為下列染料索引(C.I.)號的顏料，但不限於此。 根據本發明之顏料分散組合物中使用的顏料可為此項技術通常使用之有機顏料或無機顏料，其可單獨使用或兩種以上之組合使用。 該顏料根據需要進行如下處理：樹脂處理；利用導入酸性基團或鹼性基團之衍生物等的表面處理；利用高分子化合物等之顏料表面接枝處理；利用硫酸微粒化法等之微粒化處理或用於除去雜質之利用有機溶劑或水等的洗滌處理；藉由離子交換法等的離子型雜質的移除處理等。 該顏料的具體例有： C.I.顏料黃20、24、31、53、83、86、93、94、109、110、117、125、129、137、138、147、148、153、154、166、173、180及185； C.I.顏料橙13、31、36、38、40、42、43、51、55、59、61、64、65及71； C.I.顏料紅9、97、105、122、123、144、149、166、168、176、177、180、192、215、216、224、242、254、255及264； C.I.顏料紫14、19、23、32、33、36及38； C.I.顏料藍15(15:3、15:4、15:6等)、21、28、64及76； C.I.顏料綠10、15、25、36、47、62及63； C.I.顏料棕28。 該顏料較佳使用其粒徑均勻分散的顏料分散液。作為使顏料粒徑均勻分散的方法，可舉例藉由包含顏料分散劑而進行分散處理之方法等，藉由該方法能夠獲得顏料在溶液中均勻分散之狀態的顏料分散液。 對於本發明之著色感光性樹脂組合物，可採用顏料分散組合物之形態包含該顏料。 該顏料分散組合物包含顏料、分散劑、分散輔助劑，且為了儲藏穩定性及容易分散，可以進一步包含分散樹脂。 此外，相對於顏料分散組合物中固體成分總重量，該顏料之含量可在20至90重量份的範圍內，較佳在30至70重量份的範圍內。該顏料之含量不在上述範圍內時，黏度高、儲藏穩定性不佳、分散效率低，從而亦對對比度產生不良影響。 該染料只要對有機溶劑具有溶解性的染料即可不受限制地使用，較佳使用對有機溶劑具有溶解性的同時，能夠確保對鹼性顯影液具有溶解性、耐熱性及耐溶劑性等可靠性之染料。 該染料可以使用選自磺酸或羧酸等具有酸性基團之酸性染料、酸性染料及含氮化合物之鹽、酸性染料的磺胺類等及其衍生物中的染料，除此之外，亦可選擇偶氮類、氧雜蒽類、鈦箐類的酸性染料及其衍生物。 較佳地，該染料為在染料索引(英國染色工作者協會出版)中分類為顏料之化合物，或染色手冊(染色公司)中記載的習知染料。 該染料的具體例有： 作為C.I.溶劑染料有： C.I.溶劑黃4、14、15、21、23、24、38、62、63、68、82、94、98、99及162； C.I.溶劑紅8、45、49、122、125及130； C.I.溶劑橙2、7、11、15、26及56； C.I.溶劑藍35、37、59及67； C.I.溶劑綠1、3、4、5、7、28、29、32、33、34及35等綠色染料等。 此外，作為C.I.酸性染料有： C.I.酸性黃1、3、7、9、11、17、23、25、29、34、36、38、40、42、54、65、72、73、76、79、98、99、111、112、113、114、116、119、123、128、134、135、138、139、140、144、150、155、157、160、161、163、168、169、172、177、178、179、184、190、193、196、197、199、202、203、204、205、207、212、214、220、221、228、230、232、235、238、240、242、243及251； C.I.酸性紅1、4、8、14、17、18、26、27、29、31、34、35、37、42、44、50、51、52、57、66、73、80、87、88、91、92、94、97、103、111、114、129、133、134、138、143、145、150、151、158、176、182、183、198、206、211、215、216、217、227、228、249、252、257、258、260、261、266、268、270、274、277、280、281、195、308、312、315、316、339、341、345、346、349、382、383、394、401、412、417、418、422及426； C.I.酸性橙6、7、8、10、12、26、50、51、52、56、62、63、64、74、75、94、95、107、108、169及173； C.I.酸性藍1、7、9、15、18、23、25、27、29、40、42、45、51、62、70、74、80、83、86、87、90、92、96、103、112、113、120、129、138、147、150、158、171、182、192、210、242、243、256、259、267、278、280、285、290、296、315、324:1、335及340； C.I.酸性紫6B、7、9、17及19； C.I.酸性綠1、3、5、9、16、25、27、50、58、63、65、80、104、105、106及109等染料。 此外，作為C.I.直接顏料有： C.I.直接黃2、33、34、35、38、39、43、47、50、54、58、68、69、70、71、86、93、94、95、98、102、108、109、129、136、138及141； C.I.直接紅79、82、83、84、91、92、96、97、98、99、105、106、107、172、173、176、177、179、181、182、184、204、207、211、213、218、220、221、222、232、233、234、241、243、246及250； C.I.直接橙34、39、41、46、50、52、56、57、61、64、65、68、70、96、97、106及107； C.I.直接藍38、44、57、70、77、80、81、84、85、86、90、93、94、95、97、98、99、100、101、106、107、108、109、113、114、115、117、119、137、149、150、153、155、156、158、159、160、161、162、163、164、166、167、170、171、172、173、188、189、190、192、193、194、196、198、199、200、207、209、210、212、213、214、222、228、229、237、238、242、243、244、245、247、248、250、251、252、256、257、259、260、268、274、275及293； C.I.直接紫47、52、54、59、60、65、66、79、80、81、82、84、89、90、93、95、96、103及104； C.I.直接綠25、27、31、32、34、37、63、65、66、67、68、69、72、77、79及82等染料。 此外，作為C.I.媒介染料有： C.I.媒介黃5、8、10、16、20、26、30、31、33、42、43、45、56、61、62及65； C.I.媒介紅1、2、3、4、9、11、12、14、17、18、19、22、23、24、25、26、30、32、33、36、37、38、39、41、43、45、46、48、53、56、63、71、74、85、86、88、90、94及95； C.I.媒介橙3、4、5、8、12、13、14、20、21、23、24、28、29、32、34、35、36、37、42、43、47及48； C.I.媒介藍1、2、3、7、8、9、12、13、15、16、19、20、21、22、23、24、26、30、31、32、39、40、41、43、44、48、49、53、61、74、77、83及84； C.I.媒介紫1、2、4、5、7、14、22、24、30、31、32、37、40、41、44、45、47、48、53及58； C.I.媒介綠1、3、4、5、10、15、19、26、29、33、34、35、41、43及53等染料。 以該著色劑中的固體成分計，該染料之含量可為0.5至80重量份，較佳為0.5至60重量份，更佳為1至50重量份。染料之含量以上述基準在上述範圍內時，能夠防止在形成圖案後有機溶劑使染料溶出之問題，而且由於其敏感度優異而較佳。 包含在該著色劑中的成分可以預先分散/溶解於後述的組合物溶劑中的一部分，以添加於該著色感光性樹脂組合物中，但不限於此。黏合劑樹脂
該黏合劑樹脂通常具有在光或熱的作用下的反應性及鹼性溶解性，可以作用為著色劑之分散劑。具體地，該黏合劑樹脂可以對著色劑起黏合劑樹脂之作用。例如，該黏合劑樹脂可為能夠溶解於用於製造彩色濾光片之顯影步驟中使用的鹼性顯影液中的黏合劑樹脂。 例如，該黏合劑樹脂可為含羧基單體、與該單體能夠共聚之其他單體的共聚物等。例如，含羧基單體可為不飽和單羧酸或不飽和多元羧酸等不飽和羧酸，其中，多元羧酸在分子中具有一個以上之羧基，且諸如為不飽和二羧酸、不飽和三羧酸等。 例如，該不飽和單羧酸可為丙烯酸、甲基丙烯酸、丁烯酸、α-氯丙烯酸、肉桂酸等。 例如，該不飽和二羧酸可為馬來酸、富馬酸、衣康酸、檸康酸、中康酸等。 該不飽和多元羧酸可為酸酐，具體可為馬來酸酐、衣康酸酐、檸康酸酐等。此外，不飽和多元羧酸可為多元羧酸之單(2-甲基丙烯醯氧基烷基)酯，例如可為單(2-丙烯醯氧基乙基)琥珀酸酯、單(2-甲基丙烯醯氧基乙基)琥珀酸酯、單(2-丙烯醯氧基乙基)鄰苯二甲酸酯、單(2-甲基丙烯醯氧基乙基)鄰苯二甲酸酯等。不飽和多元羧酸可為其兩個末端為二羧基之聚合物的單(甲基)丙烯酸，例如，可為ω-羧基聚己內酯單丙烯酸酯、ω-羧基聚己內酯單甲基丙烯酸酯等。此等含羧基單體可以單獨使用或以兩種以上混合使用。該與含羧基單體能夠共聚之其他單體例如可為苯乙烯、α-甲基苯乙烯、o-乙烯基甲苯、m-乙烯基甲苯、p-乙烯基甲苯、p-氯苯乙烯、o-甲氧基苯乙烯、m-甲氧基苯乙烯、p-甲氧基苯乙烯、o-乙烯基苄基甲醚、m-乙烯基苄基甲醚、p-乙烯基苄基甲醚、o-乙烯基苄基縮水甘油醚、m-乙烯基苄基縮水甘油醚、p-乙烯基苄基縮水甘油醚、茚等芳族乙烯基化合物；丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸乙酯、甲基丙烯酸乙酯、n-丙烯酸丙酯、n-甲基丙烯酸丙酯、i-丙烯酸丙酯、i-甲基丙烯酸丙酯、n-丙烯酸丁酯、n-甲基丙烯酸丁酯、i-丙烯酸丁酯、i-甲基丙烯酸丁酯、sec-丙烯酸丁酯、sec-甲基丙烯酸丁酯、t-丙烯酸丁酯、t-甲基丙烯酸丁酯、丙烯酸-2-羥乙酯、甲基丙烯酸-2-羥乙酯、丙烯酸-2-羥丙酯、甲基丙烯酸-2-羥丙酯、丙烯酸-3-羥丙酯、甲基丙烯酸-3-羥丙酯、丙烯酸-2-羥丁酯、甲基丙烯酸-2-羥丁酯、丙烯酸-3-羥丁酯、甲基丙烯酸-3-羥丁酯、丙烯酸-4-羥丁酯、甲基丙烯酸-4-羥丁酯、丙烯酸烯丙酯、甲基丙烯酸烯丙酯、丙烯酸苄酯、甲基丙烯酸苄酯、丙烯酸環己酯、甲基丙烯酸環己酯、丙烯酸苯酯、甲基丙烯酸苯酯、丙烯酸-2-甲氧基乙酯、甲基丙烯酸-2-甲氧基乙酯、丙烯酸-2-苯氧基乙酯、甲基丙烯酸-2-苯氧基乙酯、甲氧基二甘醇丙烯酸酯、甲氧基二甘醇甲基丙烯酸酯、甲氧基三甘醇丙烯酸酯、甲氧基三甘醇甲基丙烯酸酯、甲氧基丙二醇丙烯酸酯、甲氧基丙二醇甲基丙烯酸酯、甲氧基二丙二醇丙烯酸酯、甲氧基二丙二醇甲基丙烯酸酯、丙烯酸異冰片酯、甲基丙烯酸異冰片酯、雙環戊二烯丙烯酸酯、雙環戊二烯甲基丙烯酸酯、甲基丙烯酸金剛烷酯、甲基丙烯酸降冰片酯、2-羥基-3-苯氧基丙烯酸丙酯、2-羥基-3-苯氧基甲基丙烯酸丙酯、甘油單丙烯酸酯、甘油單甲基丙烯酸酯等不飽和羧酸酯類；2-胺基丙烯酸乙酯、2-胺基甲基丙烯酸乙酯、2-二甲基胺基丙烯酸乙酯、2-二甲基胺基甲基丙烯酸乙酯、2-胺基丙烯酸丙酯、2-胺基甲基丙烯酸丙酯、2-二甲基胺基丙烯酸丙酯、2-二甲基胺基甲基丙烯酸丙酯、3-胺基丙烯酸丙酯、3-胺基甲基丙烯酸丙酯、3-二甲基胺基丙烯酸丙酯、3-二甲基胺基甲基丙烯酸丙酯等不飽和羧酸胺基烷基酯類；丙烯酸環氧丙酯、甲基丙烯酸環氧丙酯等不飽和羧酸縮水甘油酯類；乙酸乙烯酯、丙酸乙烯酯、丁酸乙烯酯、苯甲酸乙烯酯等羧酸乙烯酯類；乙烯基甲醚、乙烯基乙醚、烯丙基縮水甘油醚等不飽和醚類；丙烯腈、甲基丙烯腈、α-氯丙烯腈、亞乙烯基二氰等丙烯腈化合物；丙烯醯胺、甲基丙烯醯胺、α-氯丙烯醯胺、N-2-羥基乙基丙烯醯胺、N-2-羥基乙基甲基丙烯醯胺等不飽和胺類；馬來醯亞胺、苄基馬來醯亞胺、N-苯基馬來醯亞胺、N-環己基馬來醯亞胺等不飽和亞胺類；1、3-丁二烯、異戊二烯、氯丁二烯等脂肪族共軛二烯類；及聚苯乙烯、聚丙烯酸甲酯、聚甲基丙烯酸甲酯、聚-n-丙烯酸丁酯、聚-n-甲基丙烯酸丁酯、聚矽氧烷的聚合物分子鏈末端具有單丙烯醯基或單甲基丙烯醯基的巨大單體類等。 該單體可分別單獨使用或以兩種以上混合使用。尤其是，作為能夠與該含羧酸單體共聚之其他單體，較佳具有降冰片基骨架之單體、具有金剛烷骨架之單體、具有松香骨架之單體等，因為此等膨脹(bulky)單體具有降低介電常數之傾向。 該黏合劑樹脂之酸值可為20至200(KOHmg/g)。該黏合劑樹脂的酸值滿足上述範圍時，提高在顯影液中的溶解性以使非裸露部容易溶解，從而具有敏感度增加之優點。由此，最終裸露部之圖案在顯影時遺留下來，從而具有改善留膜率(film remainig ratio)之優點。 本發明中酸值係指測定用於中和1g聚合物所需之氫氧化鉀的量(g)的值，通常可藉由使用氫氧化鉀水溶液進行滴定而求得。 此外，該黏合劑樹脂之重量平均分子量具體可為3000至200000，具體可為5000至100000，但不限於此。該重量平均分子量可為藉由凝膠滲透色譜(GPC：四氫呋喃作為溶出溶劑)測定之聚苯乙烯換算重量平均分子量。該黏合劑樹脂之分子量滿足上述範圍時，提高塗覆膜之硬度以使留膜率提高，且具有使顯影液中之非裸露部的溶解性變得優異且提高清晰度的優點。 該黏合劑樹脂的分子量分佈(重量平均分子量(Mv)/數目平均分子量(Mn))為1.5至6.0，具體可為1.8至4.0，但不限於此。但該黏合劑樹脂的分子量分佈滿足上述範圍的時候，顯影性優異，因此上述範圍較佳。 相對於該著色感光性樹脂組合物總固體成分，該黏合劑樹脂之含量可為5至85重量份，具體可為10至70重量份。該黏合劑樹脂相對於該著色感光性樹脂組合物總固體成分的含量在上述範圍內時，由於對顯影液之溶解性充分而能夠防止在非像素部分的基板上產生顯影殘渣的現象，且防止在顯影時漏光部之像素部分的膜減少的現象，從而具有趨於使得非像素部分的遺漏性良好的優點。光聚合化合物
該光聚合化合物只要能夠基於光或後述光聚合引發劑的作用而聚合的化合物即不受限制，例如，可為單官能單體、雙官能單體、其他多官能單體。 單官能單體具體可為壬基苯基丙烯酸卡必酯(nonylphenyl carbitol acrylate)、2-羥基-3-苯氧基丙基丙烯酸酯(2-hydroxy-3-phenoxypropyl acrylate)、2-乙基己基丙烯酸卡必酯、丙烯酸-2-羥乙酯、N-乙烯基吡咯啶酮等。 雙官能單體具體例可為二甲基丙烯酸1,6-己二醇酯(1,6-hexanediol dimethacrylate)、二甲基丙烯酸乙二醇酯、二甲基丙烯酸新戊二醇酯、三乙二醇二甲基丙烯酸酯、雙酚A的雙丙烯醯氧基乙基醚(bis[2-(acryloyloxy)ethyl]ether)、二甲基丙烯酸3-甲基戊二醇酯(3-methylpentandiol dimethacrylate)等。 其他多官能團單體的具體例可為三羥甲基丙烷三甲基丙烯酸酯、季戊四醇三甲基丙烯酸酯(pentaerythritol trimethacrylate)、季戊四醇四甲基丙烯酸酯(pentaerythritol tetramethacrylate)、聚二季戊四醇五甲基丙烯酸酯(dipentaerythritol pentamethacrylate)、聚二季戊四醇六甲基丙烯酸酯(dipentaerythritol hexamethacrylate)等。較佳使用其中雙官能以上之多官能單體。 相對於自發光感光樹脂中的固體成分，該光聚合化合物之含量通常可在5至50重量份的範圍內，較佳在7至45重量份的範圍內，但不限於此。當光聚合化合物之含量在上述範圍內時，能夠使得像素部之強度或平滑性趨於良好。光聚合引發劑
該光聚合引發劑只要是此項技術常用之光聚合引發劑即不受限制，具體地可含有苯乙酮類化合物。 苯乙酮類化合物例如可為二乙氧基苯乙酮、2-羥基-2-甲基-1-苯基丙烷-1-酮、苯偶醯二甲基縮酮(Benzil Dimethyl Ketal)、2-羥基-1-[4-(2-羥基乙氧基)苯基]-2-甲基丙烷-1-酮、1-羥基環己烷苯酮、2-甲基-1-(4-甲基硫代苯基)-2-嗎啉基丙烷-1-酮、2-苄基-2-二甲基胺基-1-(4-嗎啉基苯基)丁烷-1-酮、2-羥基-2-甲基 [4-(1-甲基乙烯基)苯基]丙烷-1-酮的低聚體等。較佳2-苄基-2-二甲基胺基-1-(4-嗎啉基苯基)丁烷-1-酮。 此外，亦可組合使用上述苯乙酮類之外的光聚合引發劑。該除了苯乙酮類之外的光聚合引發劑可為藉由照射光而產生活性自由基之活性自由基發生劑、增敏劑、酸發生劑等。該活性自由基發生劑例如可為安息香類化合物、二苯甲酮類化合物、噻噸酮類化合物、三嗪類化合物等。該安息香類化合物例如可為安息香、安息香甲醚、安息香乙醚、安息香異丙醚、安息香異丁醚等。該二苯甲酮化合物例如可為二苯甲酮、鄰苯甲醯苯甲酸甲酯、4-苯偶氮基苯酮(4-phenylazo phenone)、4-苯甲醯-4'-甲基二苯硫醚、3,3',4,4'-四(第三丁基過氧羰基)二苯甲酮、2,4,6-三甲基二苯甲酮等。該噻噸酮類化合物例如可為2-異丙基噻噸酮、4-異丙基噻噸酮、2,4-二乙基噻噸酮、2,4-二氯噻噸酮、1-氯-4-丙氧基噻噸酮等。 該三嗪類化合物例如可為2,4-雙(三氯甲基)-6-(4-甲氧基苯基)-1,3,5-三嗪、2,4-雙(三氯甲基)-6-(4-甲氧基萘基)-1,3,5-三嗪、2,4-雙(三氯甲基)-6-(4-甲氧基苯乙烯基)-1,3,5-三嗪、2,4-雙(三氯甲基)-6-[2-(5-甲基呋喃-2-基)乙烯基]-1,3,5-三嗪、2,4-雙(三氯甲基)-6-[2-(呋喃-2-基)乙烯基]-1,3,5-三嗪、2,4-雙(三氯甲基)-6-[2-(4-二乙胺基-2-甲基苯基)乙烯基]-1,3,5-三嗪、2,4-雙(三氯甲基)-6-[2-(3,4-二甲氧基苯基)乙烯基]-1,3,5-三嗪等。該活性自由基發生劑例如可為2,4,6-三甲基苯甲醯基二苯基氧化膦、2,2-雙(o-氯苯)-4,4',5,5'-四苯基-1,2'-聯咪唑、10-丁基-2-氯吖啶酮、2-乙基蒽醌、苄基、9,10-菲醌、樟腦醌、苯甲醯甲酸甲酯(Methyl phenylglyoxylate)、二茂鈦化合物等。該酸發生劑例如可為4-羥苯基二甲基鋶對甲苯磺酸鹽、4-羥苯基二甲基鋶六氟銻酸鹽、4-乙醯氧基苯基二甲基鋶對甲苯磺酸鹽、4-乙醯氧基苯基甲基苄基鋶六氟銻酸鹽、三苯基鋶對甲苯磺酸鹽、三苯基鋶六氟銻酸鹽、二苯基碘鎓對甲苯磺酸鹽、二苯基碘鎓六氟銻酸等鎓鹽類或硝基苄基甲苯磺酸鹽類、安息香甲苯磺酸鹽類等。此外，作為活性自由基發生劑的上述化合物中亦同時產生活性自由基及酸之化合物，例如，三嗪類光聚合化合物亦用作酸發生劑。 進而，本發明中亦可使用光聚合引發輔助劑。該光聚合引發輔助劑可與上述光聚合引發劑組合使用，其為用於促進由上述光聚合引發劑引發的該光聚合化合物的聚合的化合物。該光聚合引發輔助劑可為胺類化合物、烷氧基蒽類化合物、噻噸酮類化合物等。 該胺類化合物例如可為三乙醇胺、甲基二乙醇胺、三異丙醇胺、4-二甲基胺基苯甲酸甲酯、4-二甲基胺基苯甲酸乙酯、4-二甲基胺基苯甲酸異戊酯、苯甲酸2-二甲基胺基乙酯、4-二甲基胺基苯甲酸2-乙基己酯、N,N-二甲基對甲苯胺、4,4'-雙(二甲基胺基)二苯甲酮(統稱：米希勒酮)、4,4'-雙(二乙胺基)二苯甲酮、4,4'-雙(乙基甲基胺基)二苯甲酮等。其中較佳使用4,4'-雙(二乙胺基)二苯甲酮，但不限於此。 該烷氧基蒽類化合物例如可為9,10-二甲氧基蒽、2-乙基-9,10-二甲氧基蒽、9,10-二乙氧基蒽、2-乙基-9,10-二乙氧基蒽等。該噻噸酮類化合物例如可為2-異丙基噻噸酮、4-異丙基噻噸酮、2,4-二乙基噻噸酮、2,4-二氯噻噸酮、1-氯-4-丙氧基噻噸酮等。 該光聚合引發劑或該光聚合引發輔助劑可以單獨使用或以多個組合使用亦無妨。此外，該光聚合引發輔助劑可以使用市售的，市售光聚合引發輔助劑例如可為商品名為EAB-F(製造商：保土谷化學工業株式會社(Hodogaya Chemical Co,. LTD))等。 以總固體成分計，相對於該黏合劑樹脂及該光聚合化合物總量，本發明之自發光感光樹脂組合物中光聚合引發劑之含量為0.1至40重量份，較佳為1至30重量份。當該光聚合引發劑滿足上述範圍時，該著色感光性樹脂組合物具有高敏感度，以使得使用該組合物形成之像素部具有良好強度，且使得該像素部之表面具有良好的平滑性，因此較佳。 當使用該光聚合引發輔助劑時，相對於光聚合引發劑1莫耳，其使用量通常低於10莫耳，較佳為0.01~5莫耳。當該光聚合引發輔助劑滿足上述範圍時，該著色感光性樹脂組合物的敏感度變得更高，以使得使用該組合物形成之彩色濾光片的生產性趨於提高，因此較佳。溶劑
本發明之著色感光性樹脂中含有的溶劑不受特別限制，可為著色感光性樹脂組合物領域中通常使用之有機溶劑。 具體可為乙二醇單甲醚、乙二醇單乙醚、乙二醇單丙醚、乙二醇單丁醚等乙二醇單烷基醚類；二乙二醇二甲醚、二乙二醇二乙醚、二乙二醇二丙醚、二乙二醇二丁醚等二乙二醇二烷基醚類；醋酸甲氧乙酯、醋酸乙氧乙酯等乙二醇烷基醚醋酸酯類；丙二醇單甲醚乙酸酯、丙二醇單乙醚乙酸酯、丙二醇單丙醚乙酸酯、乙酸甲氧基丁酯、乙酸甲氧基戊酯等亞烷基乙二醇烷基醚乙酸酯類；苯、甲苯、二甲苯、均三甲苯等芳香烴類；甲基乙基酮、丙酮、甲基戊酮、甲基異丁酮、環己酮等酮類；乙醇、丙醇、丁醇、己醇、環己醇、乙二醇、甘油等醇類；乙烷基3-乙氧丙酸酯、甲烷基3-甲氧丙酸酯等酯類；γ-丁內酯等環狀酯類等。鑒於塗覆性、乾燥性方面，在上述溶劑中較佳沸點為100℃至200℃的有機溶劑，更佳為亞烷基乙二醇烷基醚乙酸酯類、酮類、乙烷基3-乙氧丙酸酯或甲烷基3-甲氧丙酸酯等酯類，最佳丙二醇單甲醚乙酸酯、丙二醇單乙醚乙酸酯、環己醇、乙烷基3-乙氧丙酸酯、甲烷基3-甲氧丙酸酯等。此等溶劑可以分別單獨使用或以兩種以上混合使用。 相對於該著色感光性樹脂組合物總體，該溶劑之含量可為60至90重量份，具體可為70至85重量份。相對於該著色感光性樹脂組合物總體，當該溶劑之含量在上述範圍內時，若使用輥塗機、旋塗機、狹縫式及旋轉式塗佈機、夾縫式塗佈機或模具式塗佈機、噴墨機等塗覆裝置進行塗覆，塗覆性趨於良好，因此較佳。添加劑
本發明之著色感光性樹脂組合物根據需要亦可包含填充劑、其他高分子化合物、顏料分散劑、密著促進劑、防氧化劑、紫外線吸收劑、抗凝劑等添加劑，但不限於此。 該填充劑之具體例有玻璃、二氧化矽、氧化鋁等。 該其他高分子化合物具體可為環氧樹脂、馬來醯亞胺樹脂等固化樹脂；聚乙烯醇、聚丙烯酸、聚乙二醇單烷基醚、丙烯酸多氟烷基酯、聚酯、聚亞胺酯等熱固性樹脂等。 該顏料分散劑可以利用市售界面活性劑，例如矽樹脂類、氟類、酯類、陽離子類、陰離子類、非離子類、陽性等界面活性劑等。其可分別單獨使用或以兩種以上之組合使用。 該界面活性劑例如可為聚氧乙烯烷基醚類、聚氧乙烯烷基苯基醚類、聚乙二醇二酯類、失水山梨醇脂肪酸酯類、脂肪酸改質聚酯類、三元胺改質聚亞胺酯類、聚乙烯亞胺類等，除此之外可以舉例商品名為KP(由信越化學工業株式會社(SHIN-ETSU CHEMICAL CO., LTD)製造)、POLYFLOW(由共榮社化學株式會社(KYOEISHA CHEMICAL CO., LTD)製造)、EFTOP(由TOHKEM PRODUCTS CORPORATION製造)、MEGAFAC(由大日本墨水化學工業株式會社(DIC CORPORATION)製造)、Flourad(由住友3M株式會社(SUMITOMO 3M LTD)製造)、Asahi guard、Surflon(以上由旭硝子株式會社(ASAHI GLASS CO., LTD)製造)、SOLSPERSE(由ZENECA CO., LTD製造)、EFKA(由伊夫卡化學品公司(EFKA CHEMICALS B.V.)製造)、PB 821(由味之素株式會社(AJNOMOTO CO., INC)製造)等。 該密著促進劑例如可為乙烯基三甲氧基矽烷、乙烯基三乙氧基矽烷、乙烯基三(2-甲氧基乙氧基)矽烷、N-(2-胺基乙基)-3-胺基丙基甲基二甲氧基矽烷、N-(2-胺基乙基)-3-胺基丙基三甲氧基矽烷、3-胺基丙基三乙氧基矽烷、3-縮水甘油醚氧丙基三甲氧基矽烷、3-縮水甘油醚氧丙基甲基二甲氧基矽烷、2-(3,4-環氧基環己基)乙基三甲氧基矽烷、3-氯丙基甲基二甲氧基矽烷、3-氯丙基三甲氧基矽烷、3-甲基丙烯醯氧基丙基三甲氧基矽烷、3-巰基丙基三甲氧基矽烷等。 該防氧化劑具體可為2,2'-硫代雙(4-甲基-6-第三丁基苯酚)、2,6-二-第三丁基-4-甲基苯酚等。 該紫外線吸收劑具體可為2-(3-第三丁基-2-羥基-5-甲基苯基)-5-氯苯并噻唑、烷氧基苯甲酮等。 該抗凝劑具體可為聚丙烯酸鈉等。 相對於該著色感光組合物總體而言，該添加劑之含量可為0.1至10重量份，具體地可為0.1至5重量份，更具體地可為0.1至1重量份，但不限於此。當上述添加劑的含量在上述範圍內時，能夠在不降低由該著色感光性樹脂組合物製造的彩色濾光片的性能的同時，賦予各個添加劑所預期達到的性能。 本發明之著色劑感光樹脂組合物例如可以藉由以下方法製造。預先將著色劑與溶劑混合，使用砂磨機等使著色劑分散至平均粒徑低於0.2μm的程度。此時，根據需要可以使用顏料分散劑，有時亦可配伍黏合劑樹脂的一部分或全部。獲得之分散液(以下亦可稱為粉碎物料)中進一步添加黏合劑樹脂之剩餘部分、光聚合化合物及光聚合引發劑、根據需要而使用之其他成分、根據需要而使用之額外溶劑，使其濃度達到預定濃度，從而獲得所需著色感光性樹脂組合物。濾光片及圖像顯示裝置
本發明提供由該著色感光性樹脂組合物製造之彩色濾光片及包含該彩色濾光片的圖像顯示裝置。 本發明中，該著色感光性樹脂組合物可用於綠色像素，但不限於此。 可以配置此彩色濾光片之圖像顯示裝置有液晶顯示裝置、OLED、柔性顯示器等，但不限於此，此項技術已知可使用之所有圖像顯示裝置均可。 可以藉由將前述本發明之著色感光性樹脂組合物塗覆於基材之上且進行光固化及顯影而形成圖案，從而製造彩色濾光片。 首先，將著色感光性樹脂組合物塗覆於基材上後，藉由加熱乾燥而移除溶劑等揮發成分，從而獲得平滑塗覆膜。 塗覆方法例如可以藉由使用旋塗、柔韌塗覆法、輥塗、狹縫式及旋轉式塗覆或狹縫式塗覆等來實施。藉由在塗覆後進行加熱乾燥(預烘)，或在減壓乾燥後進行加熱而將溶劑等揮發成分揮發。此時，加熱溫度通常為70至200℃，較佳80至130℃。加熱乾燥後之塗覆膜的厚度通常為1至8μm程度。藉由用於形成所需圖案之掩膜，向由此獲得之塗覆膜照射紫外線。此時，可向漏光部整體均勻照射平行光線，且較佳使用掩膜對準器或步進機等裝置以使掩膜及基板精確對準位置。照射紫外線時，紫外線照射到的部位發生固化。 該紫外線可以使用g線(波長：436nm)、h線、i線(波長：365nm)等。紫外線照射量可以根據需要適當選擇，本發明中對此並不限定。若使完成固化之塗覆膜接觸顯影液以使非曝光部位溶解顯影，則可以形成所需的圖案形狀。 上述顯影方法使用添液法、浸漬法、噴霧法等中的任一者亦無妨。此外，顯影時可以將基板以任意角度傾斜。該顯影液為含有通常鹼性化合物及界面活性劑之水溶液。該鹼性化合物可為無機鹼性化合物及有機鹼性化合物中的任一者。無機鹼性化合物之具體例子可為氫氧化鈉、氫氧化鉀、磷酸氫二鈉、磷酸二氫鈉、磷酸氫二銨、磷酸二氫銨、磷酸二氫鉀、矽酸鈉、矽酸鉀、碳酸鈉、碳酸鉀、碳酸氫鈉、碳酸氫鉀、硼酸鈉、硼酸鉀、氨等。此外，有機鹼性化合物的具體例可為羥化四甲銨、2-羥基乙基三甲基氫氧化銨、一甲胺、二甲胺、三甲胺、一乙胺、二乙胺、三乙胺、單異丙胺、二異丙胺、乙醇胺等。 此等無機鹼性化合物及有機鹼性化合物可單獨使用或以兩種以上之組合使用。鹼性顯影液中之鹼性化合物的濃度較佳為0.01至10重量份，更佳為0.03至5重量份。 該鹼性顯影液中的界面活性劑可以使用選自由非離子型界面活性劑、陰離子型界面活性劑或陽離子型界面活性劑組成的組中的至少一者。 該非離子型界面活性劑的具體例有聚氧乙烯烷基醚、聚氧乙烯芳基醚、聚氧乙烯烷基芳基醚及其他聚氧乙烯衍生物；氧乙烯/氧丙烯嵌段共聚物；山梨醇酐脂肪酸酯、聚氧乙烯山梨醇酐脂肪酸酯、聚氧乙烯脂肪酸山梨醇酯；脂肪酸甘油酯；聚氧乙烯脂肪酸酯；聚氧乙烯烷基胺等。 該陰離子型界面活性劑的具體例可為月桂醇硫酸酯鈉或油醇硫酸酯鈉等高級醇硫酸酯鹽類；十二烷基硫酸鈉或十二烷基硫酸銨等烷基硫酸鹽類；十二烷基苯磺酸鈉或十二烷基萘磺酸銨等烷基芳基磺酸鹽類等。 該陽離子型界面活性劑的具體例可為硬脂醯胺鹽酸鹽或十二烷基三甲基氯化銨等銨鹽或4元銨鹽等。此等界面活性劑可以單獨使用或以兩種以上之組合使用。 該顯影液中的界面活性劑的濃度通常可為0.01至10重量份，較佳為0.05至8重量份，更佳為0.1至5重量份。在顯影後，進行水洗，且根據需要可在150至230℃實施10至60分鐘的後烘焙。 以下結合實施例進一步詳細說明本發明。下面揭示之本發明的實施形態僅為示例性的，本發明之範圍並不由此等實施形態限定。本發明的範圍由隨附申請專利範圍限定，尤其包括與申請專利範圍中記載均等之含義及範圍內的所有的變更。此外，以下實施例、比較例中表示含量的“%”及“份”在沒有特別說明的情況下均表示質量基準。黏合劑樹脂的合成例 黏合劑樹脂 (B)
在具有攪拌器、溫度計、回流冷凝管、滴定物料及氮氣導入管的燒瓶中加入丙二醇單甲醚醋酸酯182g，使燒瓶的氛圍從空氣置換為氮氣後，升溫至100℃，隨後將含有甲基丙烯酸苄酯70.5g(0.40莫耳)、甲基丙烯酸45.0g(0.50莫耳)、碳環骨架的單甲基丙烯酸44.5g(0.10莫耳)及丙二醇單甲醚醋酸酯136g的混合物中添加偶氮二異丁腈3.6g的溶液，藉由滴定物料導入口向燒瓶中滴落2小時，繼續在100℃攪拌5小時。接著，將燒瓶中的氛圍從氮氣替換為空氣後，將甲基丙烯酸縮水甘油酯30g(0.2莫耳，相對於本發明中使用的甲基丙烯酸的羧基而言為40莫耳%)、三二甲基胺基甲基苯酚0.9g及對苯二酚0.145g投入到燒瓶中，在110℃繼續反應6小時，獲得了固體成分的酸值為99mgKOH/g的樹脂B。藉由GPC測定之聚苯乙烯換算的重量平均分子量為28000，分子量分佈(Mw/Mn)為2.2。 對於該黏合劑樹脂的重量平均分子量(Mw)及數目平均分子量(Mn)，利用GPC法按照下列條件進行測定。 裝置：HLC-8120GPC(由東曹株式會社(TOSOH CORPORATION)製造) 色譜柱：TSK-GELG4000HXL + TSK-GELG2000HXL(串聯連接) 柱溫：40℃ 流動相溶劑：四氫呋喃 流速：1.0㎖/分鐘 注入量：50㎕ 偵測器：RI 測定試樣濃度：0.6質量%(溶劑=四氫呋喃) 校正用標準物質：TSK STANDARD POLYSTYRENE F-40、F-4、F-1、A-2500、A-500(由東曹株式會社製造) 將上述獲得之重量平均分子量及數目平均分子量的比作為分子量分佈(Mw/Mn)。實施例
按照下列表1之成分及含量製備著色感光性樹脂組合物。 [表1]
1)光聚合化合物(C)：雙季戊四醇六丙烯酸酯(KAYARAD DPHA；由日本化藥株式會社(NIPPON KAYAKU CO., LTD)製造) 2)引發劑(D1)：2-苄基-2-二甲基胺基-1-(4-嗎啉基苯基)丁-1-醇(Irgacure 369；由汽巴精化(Ciba Specialty Chemical)公司製造) 引發劑(D2)：4,4'-二(N,N'-二甲基胺基)-苯甲酮(EAB-F；由保土谷化學工業株式會社製造) 3)溶劑(E)：丙二醇甲醚醋酸酯 4)添加劑(F)：丙烯酸類顏料分散劑(Disper byk-2001，畢克化學(BYK)公司製造)亮度、色座標及對比度測定 測定試片製備
利用上述實施例1至4及比較例1至4製備之著色感光性樹脂組合物製造著色層。即，將上述著色感光性樹脂組合物利用旋塗法塗覆於玻璃基板上，隨後放置於加熱板上且在100℃溫度下維持3分鐘形成薄膜。接著，使用同時含有g、h、i線的1kW高壓水銀燈以100mJ/cm2
的照射量照射。此時，未使用特殊的光學過濾片。將上述照射紫外線之薄膜在pH 10.5的KOH水溶液顯影液中浸漬2分鐘進行顯影。將上述塗覆薄膜的玻璃基板用蒸餾水洗滌後，吹氮氣進行乾燥，在200℃加熱箱中加熱30分鐘。由此獲得之著色層的厚度為1~5μm，更佳2~4μm左右。亮度測定方法
利用顯微光譜儀OSP-SP2000測定。亮度在下表2中示出。 亮度(Y)的評價標準如下。 ○：Y≥40，△：38≤Y＜40，X：Y＜38對比度測定方法
利用拓普康(TOPCON)公司的對比度測定儀BM-5A進行了測定，且測定標準為玻璃基板(著色層形成前)的對比度的1/30000。其結果在下表2中示出。 對比度的評級標準如下。 ◎：CR≥15000，○：12000≤CR＜15000，△：10000≤CR＜12000，X：CR＜10000著色力區分及彩色濾光片的圖案形成 著色力
著色力以製造成目標塗覆膜厚度所需的著色感光性樹脂組合物內的顏料含量比為基準。其結果在下表2中示出。 ○：著色力＜0.45，△：0.45≤著色力＜0.5，X：著色力＞0.5彩色濾光片的圖案形成
將製造的著色感光性樹脂組合物用旋塗法塗覆於玻璃基板(#1737，康寧(CORNING)公司製造)後，放置於加熱板上且在100℃溫度下維持3分鐘形成薄膜。接著，在上述薄膜上放置具有在透過率1至100%的範圍內以階梯狀變化之圖案的試驗光掩膜，與試驗光掩膜的距離設置為1000μm，利用超高壓水銀燈(USH-250D，由牛尾電機株式會社(USHIO INC.)製造)，在大氣氛圍下，以40mJ/cm2
的曝光量(365nm)進行光照射。利用pH為12.5的KOH水溶液顯影液的噴霧顯影儀，對上述照射紫外線的薄膜進行80秒顯影。使用蒸餾水將該包覆有薄膜的玻璃板洗滌後，吹入氮氣進行乾燥，在220℃的加熱箱中加熱20分鐘，由此製造彩色濾光片圖案。上述製造之彩色濾光片的圖案形狀(薄膜)厚度為2.5至2.9μm。 [表2]
如上表2所示，該實施例1至4及比較例1及4的比較結果為，與比較例1至4相比，使用C.I.顏料綠59及C.I.顏料藍16或者同時使用C.I.顏料綠58、C.I.顏料藍16及C.I.顏料綠59的實施例1至4的亮度、對比度及/或著色力特性更優異。 自上表2中可以確認，對於同一色座標的觀點而言時，與比較例相比，實施例之亮度、對比度更優異，且高色彩再現中的著色力優異，從而有利於液晶顯示裝置中的圖案形成，因此顯示不良發生之可能性低。The present invention will be described in further detail below. In the present invention, when a component is described as being "on" other components, this includes not only the case where a certain component is in contact with other components, but also the case where another component is provided between two components. In the present invention, when it is stated that a certain part "includes" a certain component, unless there is a clear description to the contrary, it means that other components are not excluded, and other components may be further included. The present invention provides a colored photosensitive resin composition and a color filter manufactured therefrom. Colored photosensitive resin composition The colored photosensitive resin composition of the present invention contains a colorant, and the colorant contains CI Pigment Green 59 and CI Pigment Blue 16. The colored photosensitive resin composition of the present invention includes a binder resin, a photopolymerization compound, a photopolymerization initiator, and a solvent. In addition, it may further include auxiliary components commonly used in the art, such as additives. Colorant The colorant of the present invention includes CI Pigment Green 59 and CI Pigment Blue 16 in order to provide a coloring layer with high color reproducibility. In addition, the coloring agent of the present invention includes CI Pigment Green 59 and CI Pigment Blue 16, and may also include CI Pigment Green 58. The colorant uses binary mixed pigments including green pigments and blue pigments, not only can realize a wide color range of green and blue, but also can present high brightness and high contrast or excellent coloring power. In addition, it can also present the advantages of excellent pattern formation. In the present invention, the CI Pigment Green 59 or CI Pigment Green 58 mainly functions to make the composition appear green, and the CI Pigment Blue 16 functions to make the composition appear blue. At this time, the weight ratio of CI Pigment Green 59 to CI Pigment Blue 16 may be configured to be 3:97 to 50:50, specifically 5:95 to 15:75. Relative to the total solid content of the colored photosensitive resin composition, the content of the colorant composition may be 10 to 60 parts by weight, specifically 20 to 60 parts by weight; more specifically, 30 to 60 parts by weight. When the content of the colorant satisfies the above range, it has the following advantages: even if a thin film is formed, the color density of the pixel is sufficient, and the omission of the non-pixel portion during the development process can be prevented from decreasing, so there are advantages such as less likely to generate residue. In the present invention, the total solid content of the colored photosensitive resin composition or the solid content in the colored photosensitive resin composition may represent the total amount of components removed from the solvent. When the colorant includes a pigment, the colorant may contain a pigment dispersant for dispersion treatment, thereby obtaining a pigment dispersion in which the pigment is uniformly dispersed in the solution. The pigment dispersant can be, for example, cationic, anionic, nonionic, positive, polyester, polyamine, and polyacrylic surfactants, etc., and can be used alone or in combination of two or more. When the pigment dispersant is used, the amount used is preferably less than 1 part by weight, more preferably 0.05 to 0.5 part by weight, relative to 1 part by weight of the coloring material. When the amount of the pigment dispersant used is in the above range, since the pigment in a uniformly dispersed state can be obtained, it is preferable. In addition to the above-mentioned pigments, the coloring agent according to the present invention may also include the pigments and dyes used in this technology without exceeding the scope of the purpose of the present invention. For example, the colorant may also include CI pigment yellow series. When the colorant further contains CI pigment yellow series, it has the advantage of being able to achieve a wider color range. The pigments that can be further included in the present invention include organic pigments and inorganic pigments. The organic pigment can use various pigments for printing inks, inkjet inks, etc., specifically, iron phthalocyanine (Phthalocyan) (water-soluble azo pigment, insoluble azo pigment), phthalocyanine pigment, quinacridone Pigments, isoindolinone pigments, isoindoline pigments, perylene pigments, perynone pigments, dioxazine pigments, anthraquinone pigments, dianthraquinone pigments, anthrapyrimidine pigments, Anthanthrone (anthanthrone) pigment, indanthrone (indanthrone) pigment, flavanthrone (flavanthrone) pigment, pyranthrone (pyranthrone) pigment or pyrrolopyrrole diketo pigment, etc. The inorganic pigments can be metal compounds such as metal oxides or metal complexes, and can be specifically exemplified as metal oxides or composite metals such as iron, cobalt, aluminum, cadmium, tin, copper, titanium, magnesium, chromium, zinc, and antimony. Oxide etc. Specifically, the organic pigments and inorganic pigments may specifically be compounds classified as pigments in the Dye Index (published by the British Dye Workers Association), and more specifically, may be pigments with the following dye index (CI) numbers, but not Limited to this. The pigment used in the pigment dispersion composition according to the present invention may be an organic pigment or an inorganic pigment commonly used in this technology, and it may be used alone or in combination of two or more. The pigment undergoes the following treatments as needed: resin treatment; surface treatment by introducing acidic or basic group derivatives, etc.; pigment surface grafting treatment by polymer compounds, etc.; micronization by sulfuric acid micronization method, etc. Treatment or washing treatment using organic solvents or water for removing impurities; removal treatment of ionic impurities by ion exchange methods, etc. Specific examples of this pigment are: CI Pigment Yellow 20, 24, 31, 53, 83, 86, 93, 94, 109, 110, 117, 125, 129, 137, 138, 147, 148, 153, 154, 166, 173, 180 and 185; CI Pigment Orange 13, 31, 36, 38, 40, 42, 43, 51, 55, 59, 61, 64, 65 and 71; CI Pigment Red 9, 97, 105, 122, 123, 144, 149, 166, 168, 176, 177, 180, 192, 215, 216, 224, 242, 254, 255 and 264; CI Pigment Violet 14, 19, 23, 32, 33, 36 and 38; CI Pigment Blue 15 (15:3, 15:4, 15:6, etc.), 21, 28, 64 and 76; CI Pigment Green 10, 15, 25, 36, 47, 62 and 63; CI Pigment Brown 28. As the pigment, it is preferable to use a pigment dispersion in which the particle size is uniformly dispersed. As a method of uniformly dispersing the particle diameter of the pigment, for example, a method of performing a dispersion treatment by including a pigment dispersant, etc., can obtain a pigment dispersion in a state where the pigment is uniformly dispersed in a solution by this method. The pigmented photosensitive resin composition of the present invention can include the pigment in the form of a pigment dispersion composition. The pigment dispersion composition includes a pigment, a dispersant, and a dispersion auxiliary agent, and may further include a dispersion resin for storage stability and easy dispersion. In addition, relative to the total weight of the solid content in the pigment dispersion composition, the content of the pigment may be in the range of 20 to 90 parts by weight, preferably in the range of 30 to 70 parts by weight. When the content of the pigment is not within the above range, the viscosity is high, the storage stability is poor, and the dispersion efficiency is low, which also has a bad influence on the contrast. The dye can be used without restriction as long as it has solubility in organic solvents. It is preferable to use organic solvents while ensuring solubility in alkaline developing solutions, heat resistance, and solvent resistance. The dye. The dye can be selected from acid dyes having acidic groups such as sulfonic acid or carboxylic acid, acid dyes and salts of nitrogen-containing compounds, acid dyes sulfonamides, etc. and their derivatives, in addition to Choose azo, xanthene, titanic acid dyes and their derivatives. Preferably, the dye is a compound classified as a pigment in the Dye Index (published by the British Dye Workers Association), or a conventional dye described in the Dyeing Manual (Dyeing Company). Specific examples of the dye include: CI solvent dyes include: CI solvent yellow 4, 14, 15, 21, 23, 24, 38, 62, 63, 68, 82, 94, 98, 99, and 162; CI solvent red 8 , 45, 49, 122, 125 and 130; CI solvent orange 2, 7, 11, 15, 26 and 56; CI solvent blue 35, 37, 59 and 67; CI solvent green 1, 3, 4, 5, 7, 28, 29, 32, 33, 34, 35 and other green dyes. In addition, as CI acid dyes: CI acid yellow 1, 3, 7, 9, 11, 17, 23, 25, 29, 34, 36, 38, 40, 42, 54, 65, 72, 73, 76, 79 , 98, 99, 111, 112, 113, 114, 116, 119, 123, 128, 134, 135, 138, 139, 140, 144, 150, 155, 157, 160, 161, 163, 168, 169, 172 , 177, 178, 179, 184, 190, 193, 196, 197, 199, 202, 203, 204, 205, 207, 212, 214, 220, 221, 228, 230, 232, 235, 238, 240, 242 , 243 and 251; CI Acid Red 1, 4, 8, 14, 17, 18, 26, 27, 29, 31, 34, 35, 37, 42, 44, 50, 51, 52, 57, 66, 73, 80, 87, 88, 91, 92, 94, 97, 103, 111, 114, 129, 133, 134, 138, 143, 145, 150, 151, 158, 176, 182, 183, 198, 206, 211, 215,216,217,227,228,249,252,257,258,260,261,266,268,270,274,277,280,281,195,308,312,315,316,339,341, 345, 346, 349, 382, 383, 394, 401, 412, 417, 418, 422 and 426; CI Acid Orange 6, 7, 8, 10, 12, 26, 50, 51, 52, 56, 62, 63 , 64, 74, 75, 94, 95, 107, 108, 169 and 173; CI Acid Blue 1, 7, 9, 15, 18, 23, 25, 27, 29, 40, 42, 45, 51, 62, 70, 74, 80, 83, 86, 87, 90, 92, 96, 103, 112, 113, 120, 129, 138, 147, 150, 158, 171, 182, 192, 210, 242, 243, 256, 259, 267, 278, 280, 285, 290, 296, 315, 324:1, 335 and 340; CI Acid Violet 6B, 7, 9, 17 and 19; CI Acid Green 1, 3, 5, 9, 16, 25, 27, 50, 58, 63, 65, 80, 104, 105, 106 and 109 dyes. In addition, as CI direct pigments: CI direct yellow 2, 33, 34, 35, 38, 39, 43, 47, 50, 54, 58, 68, 69, 70, 71, 86, 93, 94, 95, 98 , 102, 108, 109, 129, 136, 138 and 141; CI direct red 79, 82, 83, 84, 91, 92, 96, 97, 98, 99, 105, 106, 107, 172, 173, 176, 177, 179, 181, 182, 184, 204, 207, 211, 213, 218, 220, 221, 222, 232, 233, 234, 241, 243, 246 and 250; CI direct orange 34, 39, 41, 46 , 50, 52, 56, 57, 61, 64, 65, 68, 70, 96, 97, 106 and 107; CI direct blue 38, 44, 57, 70, 77, 80, 81, 84, 85, 86, 90, 93, 94, 95, 97, 98, 99, 100, 101, 106, 107, 108, 109, 113, 114, 115, 117, 119, 137, 149, 150, 153, 155, 156, 158, 159, 160, 161, 162, 163, 164, 166, 167, 170, 171, 172, 173, 188, 189, 190, 192, 193, 194, 196, 198, 199, 200, 207, 209, 210, 212, 213, 214, 222, 228, 229, 237, 238, 242, 243, 244, 245, 247, 248, 250, 251, 252, 256, 257, 259, 260, 268, 274, 275 and 293; CI direct purple 47, 52, 54, 59, 60, 65, 66, 79, 80, 81, 82, 84, 89, 90, 93, 95, 96, 103 and 104; CI direct green 25, 27, 31, 32, 34, 37, 63, 65, 66, 67, 68, 69, 72, 77, 79 and 82 dyes. In addition, as CI mediator dyes: CI media yellow 5, 8, 10, 16, 20, 26, 30, 31, 33, 42, 43, 45, 56, 61, 62 and 65; CI media red 1, 2, 3, 4, 9, 11, 12, 14, 17, 18, 19, 22, 23, 24, 25, 26, 30, 32, 33, 36, 37, 38, 39, 41, 43, 45, 46, 48, 53, 56, 63, 71, 74, 85, 86, 88, 90, 94 and 95; CI media orange 3, 4, 5, 8, 12, 13, 14, 20, 21, 23, 24, 28 , 29, 32, 34, 35, 36, 37, 42, 43, 47 and 48; CI media blue 1, 2, 3, 7, 8, 9, 12, 13, 15, 16, 19, 20, 21, 22, 23, 24, 26, 30, 31, 32, 39, 40, 41, 43, 44, 48, 49, 53, 61, 74, 77, 83 and 84; CI medium violet 1, 2, 4, 5 , 7, 14, 22, 24, 30, 31, 32, 37, 40, 41, 44, 45, 47, 48, 53, and 58; CI medium green 1, 3, 4, 5, 10, 15, 19, 26, 29, 33, 34, 35, 41, 43 and 53 dyes. Based on the solid content in the colorant, the content of the dye may be 0.5 to 80 parts by weight, preferably 0.5 to 60 parts by weight, and more preferably 1 to 50 parts by weight. When the content of the dye is within the above-mentioned range based on the above-mentioned reference, the problem of elution of the dye by the organic solvent after pattern formation can be prevented, and it is preferable because of its excellent sensitivity. The components contained in the coloring agent may be dispersed/dissolved in a part of the composition solvent described later to be added to the colored photosensitive resin composition, but it is not limited thereto. Binder resin The binder resin usually has reactivity and alkaline solubility under the action of light or heat, and can be used as a dispersant for colorants. Specifically, the binder resin can act as a binder resin for the colorant. For example, the binder resin may be a binder resin that can be dissolved in an alkaline developer used in a development step for manufacturing a color filter. For example, the binder resin may be a carboxyl group-containing monomer, a copolymer of other monomers that can be copolymerized with the monomer, or the like. For example, the carboxyl group-containing monomer may be an unsaturated carboxylic acid such as an unsaturated monocarboxylic acid or an unsaturated polycarboxylic acid, wherein the polycarboxylic acid has more than one carboxyl group in the molecule, such as an unsaturated dicarboxylic acid, an unsaturated Tricarboxylic acid and so on. For example, the unsaturated monocarboxylic acid may be acrylic acid, methacrylic acid, crotonic acid, α-chloroacrylic acid, cinnamic acid and the like. For example, the unsaturated dicarboxylic acid may be maleic acid, fumaric acid, itaconic acid, citraconic acid, mesaconic acid and the like. The unsaturated polycarboxylic acid may be an acid anhydride, specifically maleic anhydride, itaconic anhydride, citraconic anhydride, and the like. In addition, the unsaturated polycarboxylic acid may be a mono(2-methacryloxyalkyl) ester of a polycarboxylic acid, for example, mono(2-acryloxyethyl) succinate, mono(2- Methacryloxyethyl) succinate, mono(2-acryloxyethyl) phthalate, mono(2-methacryloxyethyl) phthalate Wait. The unsaturated polycarboxylic acid may be a mono(meth)acrylic acid whose two ends are dicarboxyl polymers, for example, it may be ω-carboxy polycaprolactone monoacrylate, ω-carboxy polycaprolactone monomethyl Acrylic etc. These carboxyl group-containing monomers can be used alone or in combination of two or more. The other monomers that can be copolymerized with carboxyl group-containing monomers can be, for example, styrene, α-methylstyrene, o-vinyl toluene, m-vinyl toluene, p-vinyl toluene, p-chlorostyrene, o -Methoxystyrene, m-methoxystyrene, p-methoxystyrene, o-vinylbenzyl methyl ether, m-vinylbenzyl methyl ether, p-vinylbenzyl methyl ether, o-Vinyl benzyl glycidyl ether, m-vinyl benzyl glycidyl ether, p-vinyl benzyl glycidyl ether, indene and other aromatic vinyl compounds; methyl acrylate, methyl methacrylate, ethyl acrylate Ester, ethyl methacrylate, n-propyl acrylate, n-propyl methacrylate, i-propyl acrylate, i-propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, i-butyl acrylate, i-butyl methacrylate, sec-butyl acrylate, sec-butyl methacrylate, t-butyl acrylate, t-butyl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, 2-hydroxypropyl methacrylate Hydroxybutyl ester, 2-hydroxybutyl methacrylate, 3-hydroxybutyl acrylate, 3-hydroxybutyl methacrylate, 4-hydroxybutyl acrylate, 4-hydroxybutyl methacrylate, Allyl acrylate, allyl methacrylate, benzyl acrylate, benzyl methacrylate, cyclohexyl acrylate, cyclohexyl methacrylate, phenyl acrylate, phenyl methacrylate, 2-methoxy acrylate Ethyl ethyl, 2-methoxyethyl methacrylate, 2-phenoxyethyl acrylate, 2-phenoxyethyl methacrylate, methoxydiglycol acrylate, methoxy Diethylene Glycol Methacrylate, Methoxy Triethylene Glycol Acrylate, Methoxy Triethylene Glycol Methacrylate, Methoxy Propylene Glycol Acrylate, Methoxy Propylene Glycol Methacrylate, Methoxy Dipropylene Glycol Acrylic Acid Ester, methoxydipropylene glycol methacrylate, isobornyl acrylate, isobornyl methacrylate, dicyclopentadiene acrylate, dicyclopentadiene methacrylate, adamantyl methacrylate, methacrylic acid Unsaturated carboxylic acid esters such as norbornyl ester, 2-hydroxy-3-phenoxy propyl acrylate, 2-hydroxy-3-phenoxy propyl methacrylate, glycerol monoacrylate, glycerol monomethacrylate, etc. ; Ethyl 2-amino acrylate, ethyl 2-amino methacrylate, ethyl 2-dimethylamino acrylate, ethyl 2-dimethylamino methacrylate, 2-amino propyl acrylate , 2-Amino propyl methacrylate, 2-dimethylamino propyl acrylate, 2-dimethylamino propyl methacrylate, 3-amino propyl acrylate, 3-amino methacrylate Propyl ester, 3-dimethylamino propyl acrylate, 3-dimethylamino propyl methacrylate and other unsaturated carboxylic acid amino alkyl esters; glycidyl acrylate, glycidyl methacrylate Glycidyl esters of unsaturated carboxylic acids such as esters; vinyl carboxylates such as vinyl acetate, vinyl propionate, vinyl butyrate, and vinyl benzoate; vinyl methyl Unsaturated ethers such as ether, vinyl ethyl ether, and allyl glycidyl ether; acrylonitrile compounds such as acrylonitrile, methacrylonitrile, α-chloroacrylonitrile, and vinylidene dicyanide; acrylamide, methacrylonitrile Unsaturated amines such as amines, α-chloroacrylamide, N-2-hydroxyethylacrylamide, N-2-hydroxyethylmethacrylamide, etc.; maleimines, benzylmaleimines Unsaturated imines such as amine, N-phenylmaleimide, N-cyclohexylmaleimide; 1,3-butadiene, isoprene, chloroprene and other aliphatic conjugates Dienes; and polystyrene, polymethyl acrylate, polymethyl methacrylate, poly-n-butyl acrylate, poly-n-butyl methacrylate, polysiloxane polymer molecular chain ends have Monoacrylic or monomethacrylic macromonomers, etc. This monomer can be used individually or in mixture of 2 or more types, respectively. In particular, as other monomers that can be copolymerized with the carboxylic acid-containing monomer, a monomer having a norbornyl skeleton, a monomer having an adamantane skeleton, a monomer having a rosin skeleton, etc. are preferred because of these swelling ( bulky) The monomer has a tendency to lower the dielectric constant. The acid value of the binder resin can be 20 to 200 (KOHmg/g). When the acid value of the binder resin satisfies the above-mentioned range, the solubility in the developer is improved so that the non-naked part is easily dissolved, which has the advantage of increased sensitivity. As a result, the pattern of the final exposed part is left during development, which has the advantage of improving the film remainig ratio. The acid value in the present invention refers to the value measured for the amount (g) of potassium hydroxide required to neutralize 1 g of polymer, and it can usually be obtained by titration with an aqueous potassium hydroxide solution. In addition, the weight average molecular weight of the adhesive resin may specifically be 3000 to 200,000, specifically 5,000 to 100,000, but is not limited thereto. The weight average molecular weight can be a polystyrene conversion weight average molecular weight measured by gel permeation chromatography (GPC: tetrahydrofuran as an elution solvent). When the molecular weight of the binder resin satisfies the above range, the hardness of the coating film is increased to increase the film retention rate, and it has the advantages of improving the solubility of the non-naked part in the developer and improving the clarity. The molecular weight distribution (weight average molecular weight (Mv)/number average molecular weight (Mn)) of the binder resin is 1.5 to 6.0, specifically 1.8 to 4.0, but is not limited thereto. However, when the molecular weight distribution of the binder resin satisfies the above range, the developability is excellent, so the above range is preferred. The content of the binder resin may be 5 to 85 parts by weight, specifically 10 to 70 parts by weight, relative to the total solid content of the colored photosensitive resin composition. When the content of the binder resin with respect to the total solid content of the colored photosensitive resin composition is within the above range, the solubility of the developer solution is sufficient to prevent the occurrence of development residues on the non-pixel portion of the substrate and prevent The phenomenon that the film of the pixel portion of the light leakage portion is reduced during development, which has an advantage that the non-pixel portion tends to have good omission. Photopolymerizable compound The photopolymerizable compound is not limited as long as it can be polymerized by the action of light or a photopolymerization initiator described below, and may be, for example, a monofunctional monomer, a bifunctional monomer, or other polyfunctional monomers. The monofunctional monomer can specifically be nonylphenyl carbitol acrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-ethylhexyl Carbityl acrylate, 2-hydroxyethyl acrylate, N-vinylpyrrolidone, etc. Specific examples of bifunctional monomers can be 1,6-hexanediol dimethacrylate, ethylene glycol dimethacrylate, neopentyl glycol dimethacrylate, triethyl Glycol dimethacrylate, bis[2-(acryloyloxy)ethyl]ether of bisphenol A, 3-methylpentandiol dimethacrylate (3-methylpentandiol dimethacrylate) )Wait. Specific examples of other multifunctional monomers can be trimethylolpropane trimethacrylate, pentaerythritol trimethacrylate (pentaerythritol trimethacrylate), pentaerythritol tetramethacrylate (pentaerythritol tetramethacrylate), polydipentaerythritol pentamethacrylate Ester (dipentaerythritol pentamethacrylate), dipentaerythritol hexamethacrylate (dipentaerythritol hexamethacrylate), etc. It is preferable to use polyfunctional monomers with difunctional or higher functions. Relative to the solid content of the self-luminous photosensitive resin, the content of the photopolymerizable compound may generally be in the range of 5 to 50 parts by weight, preferably in the range of 7 to 45 parts by weight, but is not limited thereto. When the content of the photopolymerizable compound is within the above range, the intensity or smoothness of the pixel portion can be made good. Photopolymerization initiator The photopolymerization initiator is not limited as long as it is a photopolymerization initiator commonly used in this technology, and specifically may contain an acetophenone compound. The acetophenone compound may be, for example, diethoxyacetophenone, 2-hydroxy-2-methyl-1-phenylpropane-1-one, benzil dimethyl ketal (Benzil Dimethyl Ketal), 2 -Hydroxy-1-[4-(2-hydroxyethoxy)phenyl]-2-methylpropane-1-one, 1-hydroxycyclohexanephenone, 2-methyl-1-(4-methyl Thiophenyl)-2-morpholinopropane-1-one, 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)butan-1-one, 2 -Hydroxy-2-methyl[4-(1-methylvinyl)phenyl]propan-1-one oligomer, etc. Preferred is 2-benzyl-2-dimethylamino-1-(4-morpholinylphenyl)butan-1-one. In addition, photopolymerization initiators other than the aforementioned acetophenones may also be used in combination. The photopolymerization initiators other than acetophenones may be active radical generators, sensitizers, acid generators, etc. that generate active radicals by light irradiation. The active radical generator may be, for example, benzoin compounds, benzophenone compounds, thioxanthone compounds, triazine compounds, and the like. The benzoin compound may be, for example, benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether, and the like. The benzophenone compound may be, for example, benzophenone, methyl phthalate, 4-phenylazo phenone (4-phenylazo phenone), 4-benzyl-4'-methyl two Phenyl sulfide, 3,3',4,4'-tetra(tert-butylperoxycarbonyl)benzophenone, 2,4,6-trimethylbenzophenone, etc. The thioxanthone compound can be, for example, 2-isopropylthioxanthone, 4-isopropylthioxanthone, 2,4-diethylthioxanthone, 2,4-dichlorothioxanthone, 1- Chloro-4-propoxythioxanthone and so on. The triazine compound can be, for example, 2,4-bis(trichloromethyl)-6-(4-methoxyphenyl)-1,3,5-triazine, 2,4-bis(trichloromethyl) Yl)-6-(4-methoxynaphthyl)-1,3,5-triazine, 2,4-bis(trichloromethyl)-6-(4-methoxystyryl)-1 ,3,5-triazine, 2,4-bis(trichloromethyl)-6-[2-(5-methylfuran-2-yl)vinyl]-1,3,5-triazine, 2 ,4-Bis(trichloromethyl)-6-[2-(furan-2-yl)vinyl]-1,3,5-triazine, 2,4-bis(trichloromethyl)-6- [2-(4-Diethylamino-2-methylphenyl)vinyl]-1,3,5-triazine, 2,4-bis(trichloromethyl)-6-[2-(3 ,4-Dimethoxyphenyl)vinyl]-1,3,5-triazine and the like. The active radical generator can be, for example, 2,4,6-trimethylbenzyl diphenyl phosphine oxide, 2,2-bis(o-chlorobenzene)-4,4',5,5'- Tetraphenyl-1,2'-biimidazole, 10-butyl-2-chloroacridone, 2-ethylanthraquinone, benzyl, 9,10-phenanthrenequinone, camphorquinone, methyl benzoate (Methyl phenylglyoxylate), titanocene compounds, etc. The acid generator may be, for example, 4-hydroxyphenyl dimethyl sulfonium p-toluenesulfonate, 4-hydroxyphenyl dimethyl sulfonium hexafluoroantimonate, 4-acetoxyphenyl dimethyl sulfonate Toluenesulfonate, 4-acetoxyphenylmethylbenzyl alumium hexafluoroantimonate, triphenyl alumium p-toluenesulfonate, triphenyl alumium hexafluoroantimonate, diphenyliodonium p Onium salts such as tosylate, diphenyliodonium hexafluoroantimonate, nitrobenzyl tosylate, benzoin tosylate, etc. In addition, the above-mentioned compounds as active radical generators also generate active radicals and acid compounds at the same time. For example, triazine-based photopolymerizable compounds are also used as acid generators. Furthermore, a photopolymerization initiation auxiliary agent can also be used in this invention. The photopolymerization initiation auxiliary agent may be used in combination with the above-mentioned photopolymerization initiator, and is a compound for promoting the polymerization of the photopolymerization compound initiated by the above-mentioned photopolymerization initiator. The photopolymerization initiation auxiliary agent may be an amine compound, an alkoxyanthracene compound, a thioxanthone compound, and the like. The amine compound can be, for example, triethanolamine, methyldiethanolamine, triisopropanolamine, methyl 4-dimethylaminobenzoate, ethyl 4-dimethylaminobenzoate, 4-dimethyl Isoamyl aminobenzoate, 2-dimethylaminoethyl benzoate, 2-ethylhexyl 4-dimethylaminobenzoate, N,N-dimethyl-p-toluidine, 4,4 '-Bis(dimethylamino)benzophenone (collectively: Michler's ketone), 4,4'-bis(diethylamino)benzophenone, 4,4'-bis(ethylmethyl) Amino) benzophenone and the like. Among them, 4,4'-bis(diethylamino)benzophenone is preferably used, but it is not limited thereto. The alkoxyanthracene compound may be, for example, 9,10-dimethoxyanthracene, 2-ethyl-9,10-dimethoxyanthracene, 9,10-diethoxyanthracene, 2-ethyl- 9,10-diethoxyanthracene and so on. The thioxanthone compound can be, for example, 2-isopropylthioxanthone, 4-isopropylthioxanthone, 2,4-diethylthioxanthone, 2,4-dichlorothioxanthone, 1- Chloro-4-propoxythioxanthone and so on. The photopolymerization initiator or the photopolymerization initiation auxiliary agent may be used alone or in combination of plural kinds. In addition, the photopolymerization initiation auxiliary agent may be commercially available, and the commercially available photopolymerization initiation auxiliary agent may be, for example, the trade name EAB-F (manufacturer: Hodogaya Chemical Co,. LTD), etc. . Based on the total solid content, the content of the photopolymerization initiator in the self-luminous photosensitive resin composition of the present invention is 0.1 to 40 parts by weight, preferably 1 to 30 parts by weight, relative to the total amount of the binder resin and the photopolymerization compound. Copies. When the photopolymerization initiator satisfies the above range, the colored photosensitive resin composition has high sensitivity, so that the pixel portion formed using the composition has good strength and the surface of the pixel portion has good smoothness, So better. When the photopolymerization initiation auxiliary agent is used, the amount used is usually less than 10 mol, preferably 0.01 to 5 mol, relative to 1 mol of the photopolymerization initiator. When the photopolymerization initiation adjuvant satisfies the above range, the sensitivity of the colored photosensitive resin composition becomes higher, so that the productivity of the color filter formed using the composition tends to be improved, which is therefore preferable. Solvent The solvent contained in the colored photosensitive resin of the present invention is not particularly limited, and may be an organic solvent generally used in the field of colored photosensitive resin compositions. Specifically, it can be ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether and other glycol monoalkyl ethers; diethylene glycol dimethyl ether, diethylene two Diethylene glycol dialkyl ethers such as alcohol diethyl ether, diethylene glycol dipropyl ether, and diethylene glycol dibutyl ether; glycol alkyl ether acetates such as methoxyethyl acetate and ethoxyethyl acetate Class; propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, methoxybutyl acetate, methoxypentyl acetate and other alkylene glycol alkyl ether acetates Benzene, toluene, xylene, mesitylene and other aromatic hydrocarbons; methyl ethyl ketone, acetone, methyl pentanone, methyl isobutyl ketone, cyclohexanone and other ketones; ethanol, propanol, butanol , Hexanol, cyclohexanol, ethylene glycol, glycerol and other alcohols; esters such as ethyl 3-ethoxypropionate and methyl 3-methoxypropionate; cyclic esters such as γ-butyrolactone Class etc. In view of coating properties and drying properties, among the above-mentioned solvents, organic solvents with a boiling point of 100°C to 200°C are preferable, and alkylene glycol alkyl ether acetates, ketones, and ethyl 3- Ethoxypropionate or methyl 3-methoxypropionate and other esters, the best propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, cyclohexanol, ethylene 3-ethoxypropionate , Methyl 3-methoxypropionate, etc. These solvents can be used individually or in combination of two or more. With respect to the entire colored photosensitive resin composition, the content of the solvent may be 60 to 90 parts by weight, specifically 70 to 85 parts by weight. With respect to the entire colored photosensitive resin composition, when the content of the solvent is within the above range, if a roll coater, spin coater, slit and spin coater, slot coater or die type is used Coating devices such as a coater and an ink-jet machine are preferable because the coatability tends to be good. Additives The colored photosensitive resin composition of the present invention may also contain additives such as fillers, other polymer compounds, pigment dispersants, adhesion promoters, antioxidants, ultraviolet absorbers, and anticoagulants as needed, but is not limited thereto. Specific examples of the filler include glass, silica, alumina, and the like. The other polymer compounds can specifically be epoxy resins, maleimide resins and other cured resins; polyvinyl alcohol, polyacrylic acid, polyethylene glycol monoalkyl ether, polyfluoroalkyl acrylate, polyester, polyimide resin, etc. Thermosetting resins such as urethane. The pigment dispersant can utilize commercially available surfactants, such as silicone resins, fluorines, esters, cationic, anionic, nonionic, and positive surfactants. They can be used individually or in combination of two or more. The surfactant can be, for example, polyoxyethylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyethylene glycol diesters, sorbitan fatty acid esters, fatty acid modified polyesters, ternary Amine modified polyurethanes, polyethyleneimines, etc., in addition to the trade name KP (manufactured by Shin-Etsu Chemical Co., Ltd.), POLYFLOW (manufactured by Seisha Chemical Co., Ltd. (manufactured by KYOEISHA CHEMICAL CO., LTD), EFTOP (manufactured by TOHKEM PRODUCTS CORPORATION), MEGAFAC (manufactured by Dainippon Ink Chemical Industry Co., Ltd. (DIC CORPORATION)), Flourad (manufactured by Sumitomo 3M Co., Ltd.) SUMITOMO 3M LTD), Asahi guard, Surflon (manufactured by Asahi Glass Co., Ltd.), SOLSPERSE (manufactured by ZENECA CO., LTD), EFKA (manufactured by EFKA Chemical Company (EFKA) CHEMICALS BV), PB 821 (manufactured by AJNOMOTO CO., INC), etc. The adhesion promoter can be, for example, vinyl trimethoxysilane, vinyl triethoxy silane, vinyl tris (2-methoxyethoxy) silane, N-(2-aminoethyl)-3 -Aminopropylmethyldimethoxysilane, N-(2-aminoethyl)-3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, 3-condensation Glycidoxypropyl trimethoxysilane, 3-glycidoxypropyl methyldimethoxysilane, 2-(3,4-epoxycyclohexyl) ethyl trimethoxysilane, 3-chloropropane Methyldimethoxysilane, 3-chloropropyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-mercaptopropyltrimethoxysilane, etc. The antioxidant may specifically be 2,2'-thiobis(4-methyl-6-tert-butylphenol), 2,6-di-tert-butyl-4-methylphenol, and the like. Specifically, the ultraviolet absorber may be 2-(3-tertiarybutyl-2-hydroxy-5-methylphenyl)-5-chlorobenzothiazole, alkoxybenzophenone, and the like. The anticoagulant may specifically be sodium polyacrylate and the like. With respect to the coloring photosensitive composition as a whole, the content of the additive may be 0.1 to 10 parts by weight, specifically 0.1 to 5 parts by weight, more specifically 0.1 to 1 part by weight, but is not limited thereto. When the content of the above-mentioned additive is within the above-mentioned range, it is possible to impart the expected performance of each additive without reducing the performance of the color filter manufactured from the colored photosensitive resin composition. The colorant photosensitive resin composition of the present invention can be produced, for example, by the following method. The colorant is mixed with the solvent in advance, and the colorant is dispersed using a sand mill or the like until the average particle diameter is less than 0.2 μm. At this time, a pigment dispersant may be used as needed, and a part or all of the binder resin may be compatible in some cases. The obtained dispersion liquid (hereinafter also referred to as pulverized material) is further added with the remaining part of the binder resin, photopolymerization compound and photopolymerization initiator, other components used as needed, and additional solvents used as needed to make it The concentration reaches a predetermined concentration to obtain the desired colored photosensitive resin composition. Filter and image display device The present invention provides a color filter manufactured from the colored photosensitive resin composition and an image display device including the color filter. In the present invention, the colored photosensitive resin composition can be used for green pixels, but it is not limited thereto. Image display devices that can be equipped with this color filter include liquid crystal display devices, OLEDs, flexible displays, etc., but are not limited to this, and all image display devices known to be usable in this technology can be used. A color filter can be manufactured by coating the colored photosensitive resin composition of the present invention on a substrate, photocuring and developing to form a pattern. First, after coating the colored photosensitive resin composition on a substrate, it is heated and dried to remove volatile components such as a solvent, thereby obtaining a smooth coating film. The coating method can be implemented by, for example, spin coating, flexible coating, roll coating, slit-type and spin-type coating, or slit-type coating. The volatile components such as the solvent are volatilized by heating and drying (pre-baking) after coating, or heating after drying under reduced pressure. At this time, the heating temperature is usually 70 to 200°C, preferably 80 to 130°C. The thickness of the coating film after heating and drying is usually about 1 to 8 μm. The coating film thus obtained is irradiated with ultraviolet rays through a mask for forming a desired pattern. At this time, parallel light rays can be uniformly irradiated to the entire light leakage part, and it is preferable to use a device such as a mask aligner or a stepper to accurately align the mask and the substrate. When the ultraviolet rays are irradiated, the parts irradiated by the ultraviolet rays are cured. As the ultraviolet rays, g-line (wavelength: 436 nm), h-line, i-line (wavelength: 365 nm), etc. can be used. The amount of ultraviolet irradiation can be appropriately selected according to needs, and this is not limited in the present invention. If the cured coating film is brought into contact with a developer to dissolve and develop the non-exposed areas, the desired pattern shape can be formed. The above-mentioned development method may use any one of a liquid addition method, a dipping method, and a spray method. In addition, the substrate can be tilted at any angle during development. The developer is an aqueous solution containing a general alkaline compound and a surfactant. The basic compound may be any one of an inorganic basic compound and an organic basic compound. Specific examples of inorganic alkaline compounds can be sodium hydroxide, potassium hydroxide, disodium hydrogen phosphate, sodium dihydrogen phosphate, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, potassium dihydrogen phosphate, sodium silicate, potassium silicate, Sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate, sodium borate, potassium borate, ammonia, etc. In addition, specific examples of the organic basic compound may be tetramethylammonium hydroxide, 2-hydroxyethyltrimethylammonium hydroxide, monomethylamine, dimethylamine, trimethylamine, monoethylamine, diethylamine, and triethylamine. Amine, monoisopropylamine, diisopropylamine, ethanolamine, etc. These inorganic basic compounds and organic basic compounds can be used alone or in combination of two or more. The concentration of the alkaline compound in the alkaline developer is preferably 0.01 to 10 parts by weight, more preferably 0.03 to 5 parts by weight. As the surfactant in the alkaline developer, at least one selected from the group consisting of nonionic surfactants, anionic surfactants, and cationic surfactants can be used. Specific examples of the nonionic surfactant include polyoxyethylene alkyl ether, polyoxyethylene aryl ether, polyoxyethylene alkyl aryl ether and other polyoxyethylene derivatives; oxyethylene/oxypropylene block copolymer; Sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene fatty acid sorbitol esters; fatty acid glycerides; polyoxyethylene fatty acid esters; polyoxyethylene alkylamines, etc. Specific examples of the anionic surfactant can be higher alcohol sulfates such as sodium lauryl sulfate or sodium oleyl sulfate; alkyl sulfates such as sodium lauryl sulfate or ammonium lauryl sulfate; Alkyl aryl sulfonates such as sodium dodecyl benzene sulfonate or ammonium dodecyl naphthalene sulfonate. Specific examples of this cationic surfactant may be ammonium salts such as stearylamine hydrochloride or dodecyltrimethylammonium chloride, or quaternary ammonium salts. These surfactants can be used alone or in combination of two or more. The concentration of the surfactant in the developer solution is usually 0.01 to 10 parts by weight, preferably 0.05 to 8 parts by weight, and more preferably 0.1 to 5 parts by weight. After development, water washing is performed, and post-baking may be performed at 150 to 230°C for 10 to 60 minutes as needed. Hereinafter, the present invention will be described in further detail with reference to the embodiments. The embodiments of the present invention disclosed below are only exemplary, and the scope of the present invention is not limited by these embodiments. The scope of the present invention is defined by the scope of the attached patent application, and in particular includes all changes within the equivalent meaning and scope described in the scope of the patent application. In addition, the "%" and "parts" indicating the content in the following examples and comparative examples all indicate a quality standard unless otherwise specified. Synthesis Example of Binder Resin Binder Resin (B) Put 182 g of propylene glycol monomethyl ether acetate in a flask equipped with a stirrer, thermometer, reflux condenser, titration material, and nitrogen introduction tube, and replace the atmosphere in the flask with nitrogen from air After that, the temperature was raised to 100°C, and then 70.5 g (0.40 mol) of benzyl methacrylate, 45.0 g (0.50 mol) of methacrylic acid, 44.5 g (0.10 mol) of monomethacrylic acid with carbocyclic skeleton and A solution of 3.6 g of azobisisobutyronitrile was added to a mixture of 136 g of propylene glycol monomethyl ether acetate, dropped into the flask through the titration material inlet for 2 hours, and stirring was continued at 100°C for 5 hours. Next, after replacing the atmosphere in the flask from nitrogen to air, 30 g of glycidyl methacrylate (0.2 mol, 40 mol% with respect to the carboxyl group of methacrylic acid used in the present invention), three two 0.9 g of methylaminomethylphenol and 0.145 g of hydroquinone were put into the flask, and the reaction was continued at 110° C. for 6 hours to obtain resin B having a solid acid value of 99 mgKOH/g. The weight average molecular weight in terms of polystyrene measured by GPC was 28,000, and the molecular weight distribution (Mw/Mn) was 2.2. The weight average molecular weight (Mw) and number average molecular weight (Mn) of the binder resin were measured by the GPC method under the following conditions. Device: HLC-8120GPC (manufactured by TOSOH CORPORATION) Column: TSK-GELG4000HXL + TSK-GELG2000HXL (connected in series) Column temperature: 40°C Mobile phase solvent: Tetrahydrofuran Flow rate: 1.0㎖/min Injection volume: 50㎕ Detector: RI test sample concentration: 0.6% by mass (solvent = tetrahydrofuran) Calibration standard material: TSK STANDARD POLYSTYRENE F-40, F-4, F-1, A-2500, A-500 (by East The ratio of the weight average molecular weight and the number average molecular weight obtained above was defined as the molecular weight distribution (Mw/Mn). Examples A colored photosensitive resin composition was prepared according to the components and contents in Table 1 below. [Table 1] 1) Photopolymerizable compound (C): Dipentaerythritol hexaacrylate (KAYARAD DPHA; manufactured by NIPPON KAYAKU CO., LTD) 2) Initiator (D1): 2-benzyl-2-di Methylamino-1-(4-morpholinophenyl)butan-1-ol (Irgacure 369; manufactured by Ciba Specialty Chemical) Initiator (D2): 4,4'-di (N,N'-dimethylamino)-benzophenone (EAB-F; manufactured by Hodogaya Chemical Industry Co., Ltd.) 3) Solvent (E): propylene glycol methyl ether acetate 4) Additive (F): acrylic acid Pigment-like dispersant (Disper byk-2001, manufactured by BYK) Brightness, color coordinate and contrast measurement test piece preparation The coloring photosensitive resin combination prepared by the above Examples 1 to 4 and Comparative Examples 1 to 4物 Manufacturing colored layer. That is, the above-mentioned colored photosensitive resin composition is coated on a glass substrate by a spin coating method, and then placed on a hot plate and maintained at a temperature of 100° C. for 3 minutes to form a thin film. Next, a 1 kW high-pressure mercury lamp containing g, h, and i lines was used to irradiate at an irradiation amount of 100 mJ/cm 2 . At this time, no special optical filter is used. The film irradiated with ultraviolet rays was immersed in a pH 10.5 KOH aqueous solution developer for 2 minutes for development. After the above-mentioned film-coated glass substrate was washed with distilled water, it was dried by blowing nitrogen gas, and heated in a heating box at 200°C for 30 minutes. The thickness of the colored layer thus obtained is 1 to 5 μm, more preferably about 2 to 4 μm. The brightness measurement method is measured by the OSP-SP2000 microscope. The brightness is shown in Table 2 below. The evaluation criteria of brightness (Y) are as follows. ○: Y ≥ 40, △: 38 ≤ Y <40, X: Y <38. The contrast measurement method was measured with the contrast meter BM-5A of TOPCON Company, and the measurement standard was the glass substrate (coloring layer 1/30000 of the contrast before forming). The results are shown in Table 2 below. The contrast rating standards are as follows. ◎: CR≥15000, ○: 12000≤CR＜15000, △: 10000≤CR＜12000, X: CR＜10000 tinting strength distinction and color filter pattern forming tinting strength tinting strength to produce the target coating film thickness The pigment content ratio in the required coloring photosensitive resin composition is a reference. The results are shown in Table 2 below. ○: Coloring power <0.45, △: 0.45 ≤ Coloring power <0.5, X: Coloring power> 0.5 Pattern formation of color filter The manufactured colored photosensitive resin composition is applied to a glass substrate by spin coating (#1737 , Corning (CORNING) company), placed on a hot plate and maintained at a temperature of 100 ℃ for 3 minutes to form a film. Next, a test photomask with a pattern that changes stepwise in the range of transmittance from 1 to 100% is placed on the above film, and the distance between the test photomask and the test photomask is set to 1000 μm, and an ultra-high pressure mercury lamp (USH-250D, It is manufactured by Ushio Electric Co., Ltd. (USHIO INC.), and light is irradiated at an exposure amount (365 nm) of 40 mJ/cm 2 in an atmosphere. The above-mentioned ultraviolet ray irradiated film was developed for 80 seconds using a spray developer using a KOH aqueous solution developer with a pH of 12.5. After washing the film-coated glass plate with distilled water, it was dried by blowing in nitrogen gas, and heated in a heating box at 220° C. for 20 minutes, thereby manufacturing a color filter pattern. The thickness of the pattern shape (film) of the color filter manufactured above is 2.5 to 2.9 μm. [Table 2] As shown in Table 2 above, the comparison results of Examples 1 to 4 and Comparative Examples 1 and 4 are that, compared with Comparative Examples 1 to 4, CI Pigment Green 59 and CI Pigment Blue 16 are used or both CI Pigment Green 58, Examples 1 to 4 of CI Pigment Blue 16 and CI Pigment Green 59 are more excellent in brightness, contrast, and/or tinting power characteristics. From Table 2 above, it can be confirmed that from the viewpoint of the same color coordinates, compared with the comparative example, the example has better brightness and contrast, and excellent coloring power in high color reproduction, which is beneficial to the liquid crystal display device. The pattern is formed, so the possibility of display failure is low.