1261578 九、發明說明: 【發明所屬之技術領域】 依據奈米物舰論得知,凡奈 從而糊在水泥粉體使㈣,加效及震特性’ 礦物粉體或奈米化水細泥,㈣^以下的奈米級 波阻抗的奈米顆粒和較:固f中,布著由較高震 即是制震源之所在,因此生成奈之界面’ 【先前技術】 萌水m織三妈和鐵銘酸 混凝土,惟由这Γ材料,也可和骨料製成砂 W樣成材料之凝固體尚缺乏強力制震功效。 【發明内容】 發現 夺米於本案發日狀鑽研奈*物理理論時, 的超強吸震能力,兹說明如下: 而無法_卜,;,目前尚缺乏理論依據 發明人已成猶構出夺^物^理前進的情況’所幸本案 ,,包括:_之前知其細科學諸 研磨的技術ί所遭遇之技術瓶頸。如果乾式 力制震水泥凝固體,,之可行3二,仔解決。本案奈米強 粉體之技術革_基礎上讀健立在上述乾式研絲製造奈米 5 1261578 • 材料大小縮小至夺半尺斗# ± .案發明人認為,奈米體寸卞,表面原子的面積比率甚高。本 係,會出現缺少成,其初生表面原子㈣露於外界關 時虽需向外界捕捉電二S面而處於極不安定狀態,此 原力,所以以下稱奈米二米體具有極強烈的化學還 地球,因受日照而使^ 教j面自由基。環顧人類居住的 奈米表面自由基ί有電並遺大留地面大氣帶負電。由於 遭帶負電的大氣奪取電子而成,就立即向其周 奈f表面吸著電子的存在。由於表==證實 ίίίΐί1子並非在自由狀態,而是處 ^、d,則奈米表面吸著電子的基態能位 ^ # 取_位0稍高的能隙(3)中,如第一圖所示。a在比w(2) 雖然:奈米體的表面吸著電子可視同 體),但兩者有著明顯的區別,其一是夺電子(施 型半導體彻,其次是奈 半導體的電子(施體)卻存在於材料内部。由 ,料表面的關係,很容易從外界吸收能量並位 第一圖中,當表面吸著電子所獲得能量大於 電子的能位就進入傳導帶⑴;第二圖表示,如表電 子並釋放能量。根據本案發明人侧示,奈米 下列多種方式吸收能並發生能位變化: (1) 光子撞擊引起導電或游離作用; (2) 低頻光反射及高頻光透射作用; (3) 粒子撞擊引起導電或游離作用; 6 1261578 (4) 吸收電磁波生熱作用; (5) 傳導熱和幅射熱引起導電或游離作用; (6) 電場牽引引起導電或游離作用; (7) 吸收震波(超音速壓力波)引起導電或游離作用; (8>f彳f稀釋波(超音速拉力波)引起導電或游離作用; (9) 文父變磁場感應引起導電或游離作用; (10) 受互為垂直的靜態電場和磁場之感應引起導電增強作用; (11) 吸收彈性波(音波和超音波)引起導電或游離作用; (12) 摩擦引起導電或游離作用。 ^奈f材料之所以具有諸多奇異特性,均因帶負電的表面吸著 電子^容易吸收上述各種不同型態能並起能位變遷或游離化所引 起。這些奇異特性包括:(1)光觸媒作用;(2)化學觸媒作用;(3)雙 親表,現象^4)雙疏表面現象;(5)分散作用;(6)高折光率;(7)高 誘,率;(8)遠紅外線反射性;反射遮光作用隨材料粒徑變小而 &藍移現1(10)高電導率;⑴)高鮮率;(12)高比熱;(13)防火 ,=14)乾式研磨起黏聚現象;(15)低熔點;〇6)韌性增加;(17)蒸 氣壓上升;(18)對電磁波吸收性;(19)吸音性;(20)毛細管現 $,(21)奈米粉體和塑膠等混合固化後強度增加、阻氣性變佳、電 =性上升;(22)非磁性材料出現強磁性;(23)奈米磁性體的迥異磁 子=性;(24)巨磁電阻現象;(25)生物晶片的工作原理;(26)活性炭 3菌作用;(27)性質奇異的奈米碳管;⑽)奈米金屬粉體呈里 端(奈幻放電現象;(32)強力的摩擦去污作用;⑶)撕 其。(7、)吸震作用;(35)奈米線具強力、網捕功能;(36)奈米導波 二,ί 溫超導電現象。此外,尚有許多借助奈米現象的應用 」^诸如··微電子元件、微機電、能源、環保、生物、醫學、保^、 艮u口、化妝品、古傳療法以及自然界現象等不勝枚舉。,、 本案係利用上述奈米材料37項特性中編號第(34)吸 里,將較高震雜抗的奈錄體2她低震波险的水泥凝固^ 7 1261578 3相結合之混合體作為制震材料體丨,如第二圖所示。一旦震波進 入吸震材料體’則震波(壓力波)就在兩種物質界面行反射作用。設震 波在原物質1的震波速度US1、質點速度Un、質點密度^^、壓力Pl, 其抵達承接物質(2)時,壓力即由Pl變成P2,質點速度由Upi變成 Ik,並行反射和穿入作用,此時反射震波速度為u:穿入震波速 度為Ik,如第三圖所示。根據質量和動量守恒關係分別得: 0) (2) ⑶ (4) P \ U si + /9 οι Usi = 〇 P2 P1 Usi (Up2 - Upi),1261578 IX. Description of invention: [Technical field to which the invention belongs] According to the theory of nano-ships, it is known that Fannai pastes in cement powder to make (four), additive effect and seismic characteristics 'mineral powder or nano-fine water, (4) The following nano-wave impedance nano-particles and comparison: solid f, clothed by the higher earthquake that is the source of the source, so the interface of the Nai's [previous technology] Mengshui m-woven three mothers and Tie Ming acid concrete, but the solidified body made of sand and W-like material from this material can also lack strong shock-damping effect. [Summary of the Invention] It is found that the super shock absorbing ability of the rice in the case of the Japanese physics theory of the case is as follows: However, there is still no theoretical basis for the inventor. ^The situation of the advancement of the matter's case, fortunately, the case, including: _ before knowing the technical bottleneck of its fine-grained technology. If the dry force is used to make the cement solidified body, it is feasible to solve it. In this case, the technical leather of nano-strong powder _ based on Jianli in the above-mentioned dry-type grinding wire to manufacture nano 5 1261578 • The material size is reduced to half the size of the bucket # ± . The inventor believes that the nano-body volume, surface atom The area ratio is very high. This system, there will be a lack of formation, its primary surface atom (4) exposed to the outside world, although it is necessary to capture the electric two S surface to the outside world is in a state of extreme instability, this force, so the following called nanometer body is extremely strong Chemistry is also on the earth, because of the exposure to sunlight, it teaches free radicals. Looking around the human body, the surface of the nano-free radicals has electricity and left the ground to be negatively charged. Since the negatively charged atmosphere captures electrons, it immediately absorbs the presence of electrons on its surface. Since the table == confirms that the ίίίίί1 is not in a free state, but at ^, d, the surface energy of the electrons on the surface of the nanometer is ^ # _ _ bit 0 is slightly higher in the energy gap (3), as shown in the first figure Shown. a is in the ratio w(2). Although the surface of the nano-body is absorbing electrons, the two have obvious differences. The first one is the electron-trapping (the semiconductor is applied, followed by the electron of the semiconductor). ) exists in the interior of the material. From the relationship between the surface of the material, it is easy to absorb energy from the outside and position it in the first picture. When the surface absorbs electrons and the energy obtained is greater than the energy of the electron, it enters the conduction band (1); the second figure shows According to the inventor's side, the nanometer absorbs energy and changes the energy level in the following ways: (1) photon impact causes conduction or free action; (2) low-frequency light reflection and high-frequency light transmission; (3) Conductive or free action caused by particle impact; 6 1261578 (4) Electromagnetic heat absorption; (5) Conductive or radiative heat causes conduction or free action; (6) Electric field traction causes conduction or free action; Absorbing seismic waves (supersonic pressure waves) cause conduction or free action; (8>f彳f dilution waves (supersonic tension waves) cause conduction or free action; (9) Wenchang's variable magnetic field induction causes conduction or free action; 10) Induction of vertical static electric and magnetic fields causes conduction enhancement; (11) absorption of elastic waves (sonic and ultrasonic) causes conduction or free action; (12) friction causes conduction or free action. The singular characteristics are caused by the negatively charged surface absorbing electrons, which easily absorb the above various types of energy and change or disengage the energy levels. These singular characteristics include: (1) photocatalytic action; (2) chemical catalyst action (3) Parental table, phenomenon ^4) double sparse surface phenomenon; (5) dispersion; (6) high refractive index; (7) high tempering rate; (8) far infrared ray reflectivity; The particle size becomes smaller and & blue shift 1 (10) high conductivity; (1) high high rate; (12) high specific heat; (13) fireproof, = 14) dry grinding to cohesive phenomenon; (15) low melting point 〇6) increase in toughness; (17) increase in vapor pressure; (18) absorption of electromagnetic waves; (19) sound absorption; (20) capillary present, (21) nano-powder and plastic, etc. Good gas barrier properties, electrical = rise; (22) non-magnetic materials appear strong magnetic; 23) different magnetic properties of nano magnetics = (24) giant magnetoresistance; (25) working principle of biochip; (26) activated carbon 3 bacteria; (27) singular carbon nanotubes; (10) The nano metal powder is in the inner end (nano-discharge phenomenon; (32) strong friction decontamination; (3)) tear it. (7) shock absorption; (35) nanowire with strong, net catching function; (36) nano guided wave two, ί warm superconducting phenomenon. In addition, there are many applications that rely on the phenomenon of nanotechnology. ^Microelectronic components, micro-electromechanical, energy, environmental protection, biology, medicine, insurance, 艮u mouth, cosmetics, ancient transmission therapy, and natural phenomena are numerous. . The case is based on the above-mentioned 37 characteristics of the nano-materials, No. (34), and the high-shatter-resistant anti-Nei 2, her low-shock-proof cement solidification ^ 7 1261578 3 combination The material of the shock material is as shown in the second figure. Once the shock wave enters the body of the shock absorbing material, the shock wave (pressure wave) acts as a reflection at the interface between the two substances. Set the seismic wave velocity US1, mass velocity Un, mass density ^^, pressure Pl of the original material 1 to the receiving material (2), the pressure changes from P1 to P2, the particle velocity changes from Upi to Ik, parallel reflection and penetration At this time, the reflected seismic velocity is u: the penetration velocity is Ik, as shown in the third figure. According to the conservation relationship of mass and momentum, respectively: 0) (2) (3) (4) P \ U si + /9 οι Usi = 〇 P2 P1 Usi (Up2 - Upi),
Pi =/9 01 Usi Upi , P2 =p〇2 Us2 Up2 , 式中、P〇2為震波未到達時的質量密度,運用(丨)至(4)式,即 求得: UP2 2 p OlUsl Upi p 〇lUsl+ p 〇2Us2 (5) P. 2 P 02Us2 ⑹ Pi P 〇lUsl+ p 〇2Us2 列兩種情形: I) 和⑹式可分析震波吸收體的震波吸收能力。考慮下 ,0p〇2Us2>p〇iUsil^ , nm:h f没二\P2 < Upl。此結果表示反射波為如第三圖所示之震波 月。就能量觀點而言,奈米材料顆粒具有將壓力K Z還水泥凝固料,使之壓力增大,因此 所以壓縮耗能效果不彰u顆粒均為相,_量甚小, 8 1261578 :Η)當震波從較高震波阻抗(…Usi)的奈米顆粒 猱、rt,丄’山Κ Π。此結果表示反射波為如第四圓所-夕接 21拉主力波)。由於奈米顆粒表面發生拉力:圖;: 傳統吸震體體”之吸震原理不同於 用來有效吸收肋#,日^表面吸者電子之紐提升或游離作 狀保持不變,所以‘用於4;=t其,才料體的體積形 .層板和屋頂等結構體。”、憤力建杀物基地、牆、樓層板、地 【實施方式】 物粉體或時力:,適量粒徑1000nm以下的奈米級礦 凝土,待水、、尼起水彳卜以後再與水和骨料混合製成砂漿或混 值抗的奈米顆粒2和較低固f中便滿佈著由較高震波 面,即生絲二騎示之麟成之界 ^【圖式簡單說明】 ^為:奈録面吸著電子的能位圖。 能隙 乂 1)-:傳導帶’⑵一價帶,⑶— 價帶最高能位為零,Pi =/9 01 Usi Upi , P2 =p〇2 Us2 Up2 , where P 〇 2 is the mass density when the seismic wave is not reached, using (丨) to (4), that is: UP2 2 p OlUsl Upi p 〇lUsl+ p 〇2Us2 (5) P. 2 P 02Us2 (6) Pi P 〇lUsl+ p 〇2Us2 Two cases: I) and (6) can analyze the shock absorption capacity of the shock absorber. Consider 0p〇2Us2>p〇iUsil^ , nm:h f no two\P2 < Upl. This result indicates that the reflected wave is the shock wave as shown in the third figure. From the energy point of view, the nano material particles have the pressure KZ and the cement solidification material, so that the pressure is increased, so the compression energy consumption effect is not clear, the particles are all phase, _ very small amount, 8 1261578 : Η) The shock wave is from the high seismic impedance (...Usi) of the nanoparticle 猱, rt, 丄 'Hawthorn Π. This result indicates that the reflected wave is as the fourth circle - the eleventh pulls the main wave. Due to the tensile force on the surface of the nanoparticle: Fig.;: The shock absorption principle of the traditional shock absorber body is different from that used to effectively absorb the rib #, the surface of the surface attractor electrons to enhance or free the shape remains unchanged, so 'for 4 ;=t, it is the volumetric shape of the body. The structure such as the laminate and the roof.”, the construction of the smuggling base, the wall, the floor board, the ground [implementation] Powder or time force: Nano-scale minerals below 1000nm, after water, Nishui water, and then mixed with water and aggregate to make mortar or mixed-resistance nanoparticle 2 and lower solid f will be covered by The higher seismic wave surface, that is, the raw silk two-ride display of the lining into the boundary ^ [simple description of the figure] ^ is: Nai recorded surface absorbing electron energy map. Energy gap 乂 1)-: conduction band '(2) one price band, (3) - the highest energy level of the valence band is zero,
Eg E〜 表面吸著電子的基態能位, ~傳導帶的最低能位, 傳導帶的最高能位,Ed=Eg-Ea, 9 1261578 第二圖為:奈米強力制震水泥凝固體(圖中省略實際混合之骨料)。 圖號: 1 ---奈米強力制震水泥凝固體(圖中省略實際混合之骨料) 2- --較高震波阻抗的粒徑i〇〇〇nm以下礦物或水庫淤泥作奈米化之 奈米級粉粒。 ^ 3- 一較低震波阻抗之水泥凝固料。 差ϋ為:震波從較低震波阻抗的水泥凝固料進入較高震波阻抗 奈米顆粒時所發生的反射狀態。 圖號: (1)一-水泥凝固料,(2)—一奈米顆粒,(3) 一—一界面, p〇1 一―水泥凝固料原有密度, P()2奈米顆粒原有密度, pi-一文震壓後之水泥凝固料密度,p!—一反射前之震波壓力, 一-反射後之震波壓力, usi—-原有震波速度, usl —-反射之震波速度, Uh-—反射前質點速度,Eg E~ The ground state energy of the surface absorbing electrons, the lowest energy level of the conduction band, the highest energy level of the conduction band, Ed=Eg-Ea, 9 1261578 The second picture is: Nano strong earthquake-damping cement solidified body (Figure The actual mixed aggregate is omitted. Drawing No.: 1 --- Nano strong earthquake-damping cement solidified body (the actual mixed aggregate is omitted in the figure) 2- --The particle size of the higher seismic impedance is below the mineralization of the mineral or reservoir sludge for nanometerization Nano-grade powder. ^ 3- A cementitious material with a lower seismic impedance. The difference is: the reflection state of the seismic wave from the cement material of the lower seismic impedance entering the higher seismic impedance of the nanoparticle. Drawing No.: (1) one-cement solidified material, (2)-one nanometer particle, (3) one-to-one interface, p〇1--the original density of cement solidified material, P()2 nanometer original Density, density of cement solidification after pi-text pressure, p!—shock wave pressure before reflection, shock wave pressure after one-reflection, usi—original shock wave velocity, usl—reflection shock wave velocity, Uh- - the velocity of the particle before reflection,
Ik---反射後質點速度, US2--_奈米顆粒震波速度。 1四圖為•震波從較較高震波阻抗的奈米顆粒進入低震波阻抗的 水泥凝固料時所發生的反射狀態。 圖號: (1)奈米顆粒, (2)---水泥凝固料, (3)一一界面, p〇1 ---奈米顆粒原有密度, pQ2一-水泥凝固料原有密度,Ik---the particle velocity after reflection, US2--_ nanoparticle seismic velocity. Figure 1 is the reflection state of the seismic wave when the seismic wave enters the low-shock impedance cement solidification material from the nanoparticle particles with higher seismic impedance. Drawing No.: (1) nano granules, (2)---cement solidified material, (3) one-to-one interface, p〇1 --- original density of nano-particles, pQ2--the original density of cement solidified material,
Pi-一受震壓後之奈米顆粒密度,h反射前之震波壓力, P2一-反射後之震波壓力 Usi---反射震波速度, Ufi---反射前質點速度,The density of the nanoparticle after Pi-shock, the shock wave pressure before h reflection, the shock wave pressure after P2-reflection Usi---reflection shock velocity, Ufi--the velocity before reflection,
Usi〜-原有震波速度,Usi~-the original shock wave speed,
Usr—-水泥凝固料内震波速度 Up2—-反射後質點速度。 【主要元件符號說明】Usr—the internal seismic velocity of cement solidified material Up2—the velocity of the particle after reflection. [Main component symbol description]