TW211037B - - Google Patents
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- Publication number
- TW211037B TW211037B TW081103444A TW81103444A TW211037B TW 211037 B TW211037 B TW 211037B TW 081103444 A TW081103444 A TW 081103444A TW 81103444 A TW81103444 A TW 81103444A TW 211037 B TW211037 B TW 211037B
- Authority
- TW
- Taiwan
- Prior art keywords
- composition
- weight
- patent application
- methanol
- pentafluorobutane
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/028—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons
- C23G5/02803—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5036—Azeotropic mixtures containing halogenated solvents
- C11D7/5068—Mixtures of halogenated and non-halogenated solvents
- C11D7/5077—Mixtures of only oxygen-containing solvents
- C11D7/5081—Mixtures of only oxygen-containing solvents the oxygen-containing solvents being alcohols only
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/26—Cleaning or polishing of the conductive pattern
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
- Extraction Or Liquid Replacement (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Luminescent Compositions (AREA)
- Vending Machines For Individual Products (AREA)
- Bus Control (AREA)
Description
- Λ -? Λ
AB 經濟部中央標準局貝工消費合作社印製 五、發明説明4 ). 本發明係關於一種新顆組成物,其可用於乾燥淸潔、 脱脂及乾洗固醱表面,特定言之,其可用來除去來自於印 刷電路上之焊劑,以及乾洗印刷電路。 1,1, 2 —三氣_1, 2, 2 —三覦乙烷(已知的 商品名為F113)乃廣用於工業上以淸潔固«表面及使 固體表面脫脂。F 1 1 3除了可應用在電子工學上淸潔焊 錫焊劑以除去黏附在印刷電路上的蝕刻焊劑,邇可應用在 重金屬零件之脱脂以及清潔高品質與高精密度之機械零件 ,舉例說明,例如迴轉儀和蓮用設備或太空設備。在F 1 1 3的各種用途上,其最希與其他有機溶剤(如甲醇) 相連結,較佳地是以共沸混合物或不會分開的假一共沸混 合物(其像在回流下使用的,並具有和液相組成份近似相 同的蒸氣相組成份)形式。 然而,F113是那些目前正被懷疑會攻擊或降解同 溫層中臭氣之完全鹵化氯氟烴類中的一個。 根據本發明,以F113為底之組成物可被一以甲醇 及1,1, 1, 3, 3 —五氟基丁烷為底之新穎組成物取 代。此後項化合物(已知之商品名為F365 m f c ) 對臭氣並沒有破壤性的影響。 根據本發明之組成份包含了 9 3到9 9重童% F 3 6 5 mf c及7到1%甲醇。在此範圍内,其會有 一共沸物存在,並且在常壓下(1. 013巴)之沸點為 36. 5¾;同時根據本發明之組成份會有假共沸行為, 也就是説蒸氣相組成物和液相組成份近似相同,此舉對於 (請先閱讀背面之注意事項再填寫本頁) 本紙»•尺度遑用中家樣毕(CNS)甲4規格(210x297公*) 一 3 一 81. 5. 20.000(H) 0110^7 A6 B6 經濟部中央標準局员工消費合作社印製 五、發明説明) 所要之應用特別有利。較佳地,該F365 mf c含量 傜選為96到97重量%,而甲醇含量則在3到4重量% 0 F 3 6 5 m f c /甲酵共沸物像一正共沸物,因為 彼之沸點(36. 5*C)低於該二組份(F365 mfc:40t:;甲醇:65¾)。 如以F113為底之已知組成物,根據本發明之組成 物可藉添加一慣用的安定劑,如硝基烷而有利地被安定化 以對抗易於在清潔過程中發生的水解和/或自由基之攻擊 ,安定劑比率較合適地為0. 01到5%相對於 F 3 6 5 mfc+甲醇之總量。 根據本發明之組成份可用在相同的應用上,並且和先 前技藝之以F113為底組成物有相同的技巧。 下列實施例可進一步解說本發明。 實施例1:共沸物之証明 將100克甲醇及100克F365 mfc放入一 蒸餾塔(3 0 Μ板)的鍋爐内。然後使該混合物完全回流 1小時,以便譲該条統平衡。在達到溫度曲線平頂( 36. 51C)時,取下一脯份並藉用氣相色層分析來分析 〇 其記錄如下表,審現結果顯示了F365 mfc/ 甲醇共沸物的存在。 (請先閲讀背面之注意事項再填窝本頁) 本紙張尺度遑用中醺家櫺準(CNS)甲4規格(210X297公») 81. 5 . 20.000(H) -4 - 2110^ J A6 — B6 五、發明説明幺) 組成物(重馕%) F365 mfc 甲酵 最初混合物 50 50 除下之皤份 96.2 3.8 宣施例2 :共沸組成份之証實 將200克含96. 2重董%F365 mfc及 3. 8重量%甲醇之混合物放入一絶熱蒸皤塔(3〇片板 )的鍋嫌内。然後令該混合物加熱至回流1小時,以便使 該条統平衡,接著將約5 0克之脯份抽取出來並分析之, 同時也抽出蒸餾底部之躕份以進行氣相色層分析。該等記 錄於下表之結果顯示出正共沸物的存在,因為彼之沸點低 於該二個純組份:F365 mf c及甲酵的沸點。 (請先閱讀背面之注意事項再填寫本頁) 裝- 訂· 經濟部中央標準局員工消贽合作杜印製 本紙张尺度遑用中《國家樣竿(CNS)甲4規格(210X297公*) 81. 5. 20,000(H) -5 - ο VX 1 2
AB 五、發明説明釭) 組成物重量%) F365 mfc 甲醇 最初混合物 96.2 3.8 收集之餾份 96.2 3.8 蒸餾底部 96.2 3.8 在1.013巴下所收集的沸點:36.510 (請先閲讀背面之注意事項再填窝本頁) 裝· 經濟部中央標準局負工消费合作社印製 此共沸物,使用來淸潔焊錫焊劑及使機械零件脱脂會 有好的結果。 奮掄例3 :經硝基甲烷安定化之組成物 將1 5 0克含有9 6 . 1重量%F 3 6 5 mfc 3. 8重量%甲醇及0.1%硝基甲烷的混合物放入一超 音波清洗容器内。在讓該条統回流1小時之後,取下能整 除之蒸氣相。藉用氣相色層分析來分析,顯示有硝基甲院 存在,此乃表示該混合物在蒸氣相中也被安定化。 本紙張尺度逍用中《國家«準(CNS)甲4規格(210x297公*) 81. 5 . 20,000(H) -6 - 訂- 線· 五、發明説明会) A 6 B6 組成物(重量%) F365 mfc 甲醇 CH3N〇2 最初混合物 96.1 3.8 0.1 蒸氣相 96.2 3.78 0.02 (請先閲讀背面之注意事項再填寫本頁) 裝· 訂- 經濟部中央標準局員工消費合作社印製 本紙張尺度逍用中國困家樣準(CNS)甲4規格(210X297公釐) 81. 5. 20.000(H) -7 -
Claims (1)
- 公告本 卜年飞Λ Ά 修正 補充j At B7 C7 D7 姪濟部中央標準局R工消费合作社印¾ 六、申請專利範圍 附件一(A ): 第8Π 034 44號專利申請案 中文申請專利範圍修正本 民國82年7月修正 1 ·—種似共沸組成物,其特徵爲彼包含有9 3到 99重量i,} ,3 , 3 一五氟基丁烷及了到!重 量%甲醇,且彼在常壓下共沸點爲3 6. 5°C。 2. 如申請專利範圍第丨項之組成物,其特徵爲彼包 含有96到97重量%1 ,1 ,1 ,3,3 -五氟基丁烷 及4到3重量%甲醇。 3. 如申請專利範圍第1項之組成物,其特徵爲彼亦 可包含硝基焼作爲安定劑。 4 .如申請專利範圍第3項之組成物,其特徵爲該安 定劑之比率是0 . 0 1到5 %相對於1 ,1 ,1,3,3 一五氟基丁烷及甲醇的總重量。 5. 如申請專利範圍第1至4項中任一項之組成物, 其可用於清潔和/或乾燥固體表面。 6. 如申請專利範圍第1至4項中任一項之組成物, 其可用於將焊劑自印刷電路上除去或使機械零件脫除油污 0 7 . —種供清潔和/或乾燥固體表面之方法,其特徵 爲以如申請專利範圍.第1至4項中任一項之組成物與固體 表面接觸。 ------------------------裝!----ir------線 (請先Missis面之注f項再Ϊ本頁) 太《祺R燎碘明申WW家揀迆(rNS、V 4 «达V叫7公瞀、 -1 -
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9105397A FR2676067B1 (fr) | 1991-05-02 | 1991-05-02 | Composition a base de 1,1,1,3,3-pentafluorobutane et de methanol, pour le nettoyage et/ou le sechage de surfaces solides. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW211037B true TW211037B (zh) | 1993-08-11 |
Family
ID=9412452
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW081103444A TW211037B (zh) | 1991-05-02 | 1992-04-30 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5268121A (zh) |
| EP (1) | EP0512885B1 (zh) |
| JP (1) | JPH0794679B2 (zh) |
| KR (1) | KR950006293B1 (zh) |
| CN (1) | CN1033819C (zh) |
| AT (1) | ATE104336T1 (zh) |
| AU (1) | AU647919B2 (zh) |
| BR (1) | BR9201603A (zh) |
| CA (1) | CA2067267C (zh) |
| DE (1) | DE69200104T2 (zh) |
| ES (1) | ES2063568T3 (zh) |
| FI (1) | FI921983L (zh) |
| FR (1) | FR2676067B1 (zh) |
| IE (1) | IE65874B1 (zh) |
| NO (1) | NO921661L (zh) |
| TW (1) | TW211037B (zh) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2676066B1 (fr) * | 1991-05-02 | 1993-07-23 | Atochem | Composition a base de 1,1-dichloro-1-fluoroethane, de 1,1,1,3,3-pentafluorobutane et de methanol, pour le nettoyage et/ou le sechage de surfaces solides. |
| FR2694943B1 (fr) * | 1992-08-21 | 1994-10-14 | Atochem Elf Sa | Composition à base de 1,1,1,3,3-pentafluorobutane, de chlorure de méthylène et de méthanol, pour le nettoyage et/ou le séchage de surfaces solides. |
| FR2694942B1 (fr) * | 1992-08-21 | 1994-10-14 | Atochem Elf Sa | Composition à base de 1,1,1,3,3-pentafluorobutane et de chlorure de méthylène, pour le nettoyage et/ou le séchage de surfaces solides. |
| DE69432702T2 (de) * | 1993-03-12 | 2004-04-08 | Daikin Industries, Ltd. | Verfahren zur herstellung von sauberen gegenstaenden |
| BE1006894A3 (fr) * | 1993-03-31 | 1995-01-17 | Solvay | Compositions comprenant du pentafluorobutane et utilisation de ces compositions. |
| BE1007543A3 (fr) * | 1993-09-29 | 1995-08-01 | Solvay | Compositions comprenant du 1,1,1,3,3-pentafluorobutane et utilisation de ces compositions. |
| BE1007522A5 (fr) | 1993-09-29 | 1995-07-25 | Solvay | Compositions comprenant du 1,1,1,3,3-pentafluorobutane et procede d'elimination d'eau d'une surface solide. |
| BE1007699A3 (fr) * | 1993-11-04 | 1995-10-03 | Solvay | Compositions comprenant du pentafluorobutane et utilisation de ces compositions. |
| US5696307A (en) * | 1994-01-21 | 1997-12-09 | Alliedsignal Inc. | Hydrofluoroalkanes as cleaning and degreasing solvents |
| BE1009630A3 (fr) * | 1995-09-26 | 1997-06-03 | Solvay | Premelanges pour la preparation de mousses de polyurethane ou de polyisocyanurate. |
| FR2740469B1 (fr) * | 1995-10-31 | 1997-12-05 | Atochem Elf Sa | Compositions de nettoyage a base de 1,1,1,2,2,4,4,- heptafluorobutane et d'alcools |
| US5683974A (en) * | 1996-06-20 | 1997-11-04 | Alliedsignal Inc. | Azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and C1 -C3 alcohols for cleaning |
| FR2766836B1 (fr) | 1997-07-31 | 1999-09-24 | Atochem Elf Sa | Melange quasi azeotropique a base de 1,1,1,3,3- pentafluorobutane, de chlorure de methylene et de methanol pour le traitement de surfaces solides |
| FR2781499B1 (fr) * | 1998-07-24 | 2000-09-08 | Atochem Elf Sa | Compositions de nettoyage ou de sechage a base de 1,1,1,2,3,4,4,5,5, 5 - decafluoropentane |
| US6951835B1 (en) * | 1999-03-22 | 2005-10-04 | E.I. Du Pont De Nemours And Company | Azeotrope-like compositions of 1,1,1,3,3-pentafluorobutane |
| FR2792647B1 (fr) * | 1999-04-22 | 2001-06-08 | Atochem Elf Sa | COMPOSITIONS DE NETTOYAGE OU DE SECHAGE A BASE DE F365 mfc, CH2CL2, CH3OH ET 43-10mee |
| US6403550B1 (en) | 2000-03-10 | 2002-06-11 | Atofina Chemicals, Inc. | Compositions based on 142 |
| US7091170B2 (en) * | 2001-02-14 | 2006-08-15 | Kaneko Chemical Co., Ltd. | Solvent composition for washing |
| JP3263065B1 (ja) * | 2001-02-14 | 2002-03-04 | 株式会社カネコ化学 | 洗浄用溶剤組成物 |
| US6365566B1 (en) * | 2001-03-21 | 2002-04-02 | Honeywell International Inc. | Azeotrope-like compositions of pentafluorobutane and water |
| KR100898520B1 (ko) | 2001-06-01 | 2009-05-20 | 허니웰 인터내셔널 인코포레이티드 | 펜타플루오로부탄의 공비성 조성물 |
| WO2002099007A1 (en) * | 2001-06-01 | 2002-12-12 | Honeywell International, Inc. | Compositions of hydrofluorocarbons and methanol |
| JP3640661B1 (ja) * | 2004-03-09 | 2005-04-20 | 株式会社カネコ化学 | ペンタフルオロブタン組成物 |
| MX336377B (es) | 2007-02-06 | 2016-01-15 | Solvay Fluor Gmbh | Composiciones no inflamables que comprenden compuestos fluorados y uso de dichas composiciones. |
| AT522091B1 (de) | 2019-03-21 | 2020-08-15 | Steger Heinrich | Verfahren zum Herstellen eines Zahnersatzes |
| CN112553014B (zh) * | 2020-12-07 | 2022-12-09 | 北京飞狐鱼智能科技有限公司 | 电子产品带电抑菌清洁剂 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4748223A (en) * | 1986-04-01 | 1988-05-31 | Nippon Mektron Limited | Process for producing peroxide-vulcanizable, fluorine-containing elastomer |
| JPS63304009A (ja) * | 1987-06-04 | 1988-12-12 | Nippon Mektron Ltd | パ−オキサイド加硫可能な含フッ素エラストマ−の製造方法 |
| US5246617A (en) * | 1988-01-20 | 1993-09-21 | E. I. Du Pont De Nemours And Company | Azeotropic compositions of 1,1-dichloro-1-fluoroethane and methanol/ethanol |
| US4842764A (en) * | 1988-05-03 | 1989-06-27 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane and methanol |
| EP0414804B1 (en) * | 1988-05-03 | 1994-01-12 | AlliedSignal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, methanol and nitromethane |
| DE3903336A1 (de) * | 1989-02-04 | 1990-08-09 | Bayer Ag | Verwendung von c(pfeil abwaerts)3(pfeil abwaerts)- bis c(pfeil abwaerts)5(pfeil abwaerts)-polyfluoralkanen als treibgase |
| AU635362B2 (en) * | 1989-12-07 | 1993-03-18 | Daikin Industries, Ltd. | Cleaning composition |
| EP0432672B1 (de) * | 1989-12-12 | 1997-03-19 | SOLVAY (Société Anonyme) | Verfahren zur Herstellung von Schaumstoffen mit Hilfe von Fluoralkanen |
| DE4002120A1 (de) * | 1990-01-25 | 1991-08-01 | Hoechst Ag | Neues azeotropartiges loesemittelgemisch und verfahren zur reinigung von elektronischen bauteilen mit hilfe desselben |
| JPH05504590A (ja) * | 1990-03-02 | 1993-07-15 | アライド―シグナル・インコーポレーテッド | 1,1―ジクロロ―1―フルオロエタン、メタノールおよびニトロメタンの共沸混合物様組成物を用いる洗浄法 |
| US5059728A (en) * | 1990-06-29 | 1991-10-22 | Allied-Signal Inc. | Partially fluorinated alkanes having a tertiary structure |
| FR2676066B1 (fr) * | 1991-05-02 | 1993-07-23 | Atochem | Composition a base de 1,1-dichloro-1-fluoroethane, de 1,1,1,3,3-pentafluorobutane et de methanol, pour le nettoyage et/ou le sechage de surfaces solides. |
| US5099081A (en) * | 1991-08-28 | 1992-03-24 | Atochem North America, Inc. | Solvent extraction of I-365 from I-141b |
| US5099082A (en) * | 1991-08-28 | 1992-03-24 | Atochem North America, Inc. | Solvent extraction of I-141B from I-365 |
-
1991
- 1991-05-02 FR FR9105397A patent/FR2676067B1/fr not_active Expired - Fee Related
-
1992
- 1992-04-23 AT AT92401166T patent/ATE104336T1/de not_active IP Right Cessation
- 1992-04-23 DE DE69200104T patent/DE69200104T2/de not_active Expired - Fee Related
- 1992-04-23 EP EP92401166A patent/EP0512885B1/fr not_active Expired - Lifetime
- 1992-04-23 ES ES92401166T patent/ES2063568T3/es not_active Expired - Lifetime
- 1992-04-27 CA CA002067267A patent/CA2067267C/fr not_active Expired - Fee Related
- 1992-04-28 NO NO92921661A patent/NO921661L/no unknown
- 1992-04-29 BR BR929201603A patent/BR9201603A/pt not_active IP Right Cessation
- 1992-04-30 US US07/876,160 patent/US5268121A/en not_active Expired - Lifetime
- 1992-04-30 FI FI921983A patent/FI921983L/fi not_active Application Discontinuation
- 1992-04-30 TW TW081103444A patent/TW211037B/zh active
- 1992-05-01 JP JP4112916A patent/JPH0794679B2/ja not_active Expired - Fee Related
- 1992-05-01 AU AU15968/92A patent/AU647919B2/en not_active Ceased
- 1992-05-02 KR KR1019920007542A patent/KR950006293B1/ko not_active Expired - Fee Related
- 1992-05-02 CN CN92103154A patent/CN1033819C/zh not_active Expired - Fee Related
- 1992-07-01 IE IE921382A patent/IE65874B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR950006293B1 (ko) | 1995-06-13 |
| ATE104336T1 (de) | 1994-04-15 |
| FI921983A7 (fi) | 1992-11-03 |
| AU1596892A (en) | 1992-11-05 |
| NO921661L (no) | 1992-11-03 |
| KR920021696A (ko) | 1992-12-18 |
| NO921661D0 (no) | 1992-04-28 |
| FI921983A0 (fi) | 1992-04-30 |
| EP0512885A1 (fr) | 1992-11-11 |
| CA2067267A1 (fr) | 1992-11-03 |
| IE921382A1 (en) | 1992-11-04 |
| DE69200104T2 (de) | 1994-11-03 |
| FR2676067B1 (fr) | 1993-07-23 |
| EP0512885B1 (fr) | 1994-04-13 |
| AU647919B2 (en) | 1994-03-31 |
| IE65874B1 (en) | 1995-11-29 |
| FR2676067A1 (fr) | 1992-11-06 |
| DE69200104D1 (de) | 1994-05-19 |
| BR9201603A (pt) | 1992-12-15 |
| ES2063568T3 (es) | 1995-01-01 |
| CN1066288A (zh) | 1992-11-18 |
| CN1033819C (zh) | 1997-01-15 |
| JPH0794679B2 (ja) | 1995-10-11 |
| CA2067267C (fr) | 1998-02-03 |
| FI921983L (fi) | 1992-11-03 |
| US5268121A (en) | 1993-12-07 |
| JPH05140592A (ja) | 1993-06-08 |
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