TW201701759A - Synergistic insecticidal composition - Google Patents

Abstract

The present invention relates to three components comprising (A) spinosad, (B) abatatin or bifenin, and (C) at least one selected from the group consisting of abatatin, arsenic, thiocarb, and triflumuron. A synergistic insecticidal composition and a method of preparing the insecticidal composition. The invention also relates to a method of preventing, controlling and/or treating insect infections of plants, plant parts and/or their surroundings by applying a synergistic insecticidal composition comprising three components (A), (B) and (C) .

Description

Synergistic insecticidal composition

The present invention relates to a synergistic insecticidal composition comprising three components (A), (B) and (C) and a process for preparing the synergistic insecticidal composition. The invention also relates to the use of the aforementioned three components, including the prevention, control and/or treatment of plants, plants by application of a synergistic pesticidal composition comprising the three components (A), (B) and (C) A method of infection of a part and/or surrounding insects.

Insect infections are a major threat to important economic crops. The yield of plants such as fruits, sugar cane, citrus plants, coffee plants and vegetables is adversely affected by insect attack.

Chemical control is an important way to prevent and control pests in agriculture. However, existing agents are not satisfactory for certain types of pests. In addition, many pests have developed resistance to commonly used pesticides due to long-term use of commonly used pesticides. Therefore, there is an urgent need to develop new methods and pesticides to control these pests. In addition, the current environmental and economic requirements for pesticides (for example, in terms of spectrum of action, toxicity, selectivity, application rate, formation of residues, and good preparation ability) are increasing. Because of the problems, for example, the problem of resistance to known active compounds, there is a continuing need to develop new insecticides which, in some respects, are at least advantageous over their known counterparts.

The term Spinosad denotes an insecticide consisting of two components called spinosad A and D. It is produced by the soil bacteria Saccharopolyspora spinosa , which belongs to actinomycetes, which is a large class of Gram-positive filamentous or mycobacteria, which has been evaluated by the European Commission as new since 2000. Active substances, and are temporarily approved in the Netherlands, Spain and the United Kingdom.

Spinosaurus is an insecticide used to control caterpillars, thrips, beetles and fly pests in a variety of fruit and vegetable crops, ornamental plants, turf and stored grains. Nixon has contact activity throughout the life stages of insects, including eggs, larvae and adults. Eggs must be sprayed directly, but larvae and adults can be effectively administered via contact with the treated surface. The promise is the most effective when it is ingested. Although the permeation activity is evident in certain plant and ornamental plants, the application of the leaves is not highly systematic. Spinosad works by altering the function of the nicotine and GABA-gated ion channels of the insect nervous system, but it does not interact with known binding sites for other nicotine or GABA-agonist insecticides. However, the promise of killing has limited effect on some types of pests. In addition, due to its extremely high price, the promise is not easy to promote and large-scale application. Furthermore, experience with direct formulations of single active insecticides worldwide has shown a high risk of developing resistant subpopulations of insects. The world has reported that more and more insects, fruits, vegetables and other insects are resistant. As suggested, the combination of spinosad and other pesticide classes can reduce the selection pressures that lead to drug resistance.

Enhancements to insecticides and compositions have been obtained to improve control of insect pests and their application as target crops, either alone or in combination. Proper use Only in the high incidence of insects, strip application and spot application and soil application to avoid direct contact with natural enemies and the use of selective and non-persistent agents increase environmental safety and reduce the occurrence of insect resistance. In addition, the use of insect control agents in different modes of action has contributed to good pest management. There is a need for insecticidal compositions that have high synergistic effects and are not cross-resistant to existing insecticides and have low environmental impact. Therefore, it is beneficial to provide a composition having the following properties: insect invasion It is effective, has a stable physical compatibility formulation during storage, can be safely packaged and is ready-to-use.

The present invention relates to a synergistic insecticidal composition comprising at least components (A), (B) and (C). The active ingredient of component (A) is spinosad and the active ingredient of component (B) is selected from abamectin or bifenthrin. The active ingredient of component (C) is at least one selected from the group consisting of ababatine, acetamiprid, thiodicarb and triflumuron, provided that the components are The active ingredient of B) is different from the active ingredient of component (C).

The invention also relates to a plant, plant part and/or its control by applying a synergistic insecticidal composition comprising the above components (A), (B) and (C) to plants, plant parts and/or its surroundings The method of infection around the insects.

The invention also relates to a method for preparing a group comprising (A) spinosad, (B) abatatin or bifenin and (C) selected from the group consisting of abatatin, arsenic, thiocarb, and triflumuron. At least one method of synergistic insecticidal composition.

The invention also relates to the use of a synergistic pesticidal combination comprising the above components (A), (B) and (C) for the prevention, control and/or treatment of insect infections of plants, plant parts and/or their surroundings.

The invention also relates to plants treated with the compositions or components (A), (B) and (C) as defined above, which are treated prior to infection by insects or treated to combat existing insect infections.

As used herein, "plant" refers to all plants and plant populations, such as wild plants or crop plants that are needed or not desired.

As used herein, "plant part" refers to all parts and organs of a plant, such as shoots, leaves, needles, stems, stems, fruit bodies, fruits, seeds, roots, tubers, and rhizomes. Also package Materials that are harvested, as well as vegetative and sexually propagated materials, such as cuttings, tubers, meristems, rhizomes, side branches, seeds, single plant cells, and multi-plant cells, as well as any other plant tissue.

The term "around" or "position" refers to the location at which the plant is grown, the location at which the plant propagation material of the plant is sown, or the location at which the plant propagation material of the plant will be sown.

"At least one" means 1, 2, 3, 4, 5, 6, 7, 8, 9 or more various compounds, preferably 1, 2 or 3 compounds.

It has now surprisingly been found that when components (A), (B) and (C) are applied, on plants, plant parts and/or their surroundings (especially on legumes, fruits, vegetables and coffee) When combined, for example, an insecticidal composition comprising the above three components, superior performance in preventing and treating insect infections can be observed. The synergistic insecticidal combination is very effective in protecting the above crops from insect damage.

The synergistic insecticidal combination was found to be highly active against a wide range of pests, namely aphids, armyworms, beetles, cotton aphids, budworms, pickleworms, and burrowing worms. Burrowing bugs, locusts, caterpillars, citrus orthezia, Great Southern White, leafhoppers, leafminers, loopers, millipedes, tea (broad mites), moths, spiders, stink bugs, thrips, weevils, whiteflies, worms, hibiscus. The invention also illustrates reduced application costs, increased crop yields, and reduced environmental risks. The present invention also delays the advantages of pest resistant strains, has a broader broad spectrum of activity and reduces the risk of developing resistance.

Another advantage of the present invention is to provide a preparation for containing (A) spinosad, (B) abatatin or bifenin and (C) selected from the group consisting of abatatin, arsenic, sulfur enemy and killing A method of synergistic pesticidal composition of at least one of the groups consisting of a bellulidine. The advantage of this method relates to at least one of (A) spinosad, (B) abatatin or bifenin and (C) selected from the group consisting of abatatin, arsenic, thiocarb, and triflumuron. The synergistic composition of the person coats and/or plant propagation parts, in particular seeds, containing the synergistic composition.

In the methods and uses of the invention, components (A), (B) and (C) can be administered continuously or simultaneously in any desired order, in any combination.

Component (A) can be present in the compositions of the present invention in any suitable amount, and is usually present in an amount of from about 1% to about 80% by weight of the composition, preferably about 5% to about 70% (based on the weight of the composition), more preferably from about 10% to about 60% (by weight of the composition), most preferably from about 20% to about 55% (by the composition) Weight meter).

Component (B) Abatatin or Phenfanning may be present in the compositions of the present invention in any suitable amount, usually present in an amount from about 0.05% to about 70% by weight of the composition, preferably the weight of the composition. From about 0.1% to about 60%, more preferably from about 0.2% to about 50% by weight of the composition, still more preferably from about 0.2% to about 40% by weight of the composition, more preferably the weight of the composition. From about 0.2% to about 30%, and more preferably from about 0.2% to about 20% by weight of the composition, most preferably from about 0.2% to about 10% by weight of the composition.

Component (C) is at least one selected from the group consisting of abatatin, arsenic, thiocarb, and triflumuron, which may be present in the composition of the present invention in any suitable amount, which is usually present The amount is from about 0.5% to about 80% by weight of the composition, preferably from about 0.5% to about 70% by weight of the composition, more preferably from about 0.5% to about 60% by weight of the composition, more preferably The composition is from about 0.5% to about 50% by weight, further preferably from about 0.5% to about 40% by weight of the composition, more preferably from about 0.5% to about 30% by weight of the composition, most preferably From about 1% to about 20% by weight of the composition.

Components (A) and (B) may be present in the group in any amount relative to each other The product or application is provided to provide a synergistic effect of the mixture. Specifically, the weight ratio of components (A) and (B) in the composition is independently in the range of from about 150:1 to about 1:150, from 100:1 to about 1:100, from about 80:1 to about 1:80, more preferably from about 60:1 to about 1:60 or from about 40:1 to about 1:40, up to about 100:1, 80:1, 60:1, 40:1, 20:1, 10: 1, 5: 1, 1:1.

Components (A) and (C) may be present in the composition or applied in any amount relative to each other to provide a synergistic effect of the mixture. Specifically, the weight ratio of components (A) and (C) in the composition is independently preferably in the range of from 100:1 to about 1:100, from about 80:1 to about 1:80, more preferably. 60:1 to about 1:60 or about 50:1 to about 1:50 or about 40:1 to about 1:40 or about 30:1 to about 1:30 or about 20:1 to about 1:20 or about 10:1 to about 1:10, up to about 50:1, 40:1, 30:1, 20:1, 10:1, 5:1, 2.5:1, 2:1, 1:1.

The components (A), (B) and (C) may be present together in the composition of the invention in any suitable amount, and are usually present in an amount of from about 5% to about 90% by weight of the composition. Preferably, preferably from about 10% to about 85% (based on the weight of the composition), more preferably from about 15% to about 75% (by weight of the composition), more preferably from about 20% to about 70% (based on the weight of the composition), preferably from about 25% to about 65% by weight of the composition.

In a preferred embodiment of the invention, each combination is a composition comprising components (A), (B) and (C), and optionally one or more auxiliaries. The adjuvant employed in the composition will depend on the type of formulation and/or the manner in which the end user will administer the formulation. Formulations incorporating the compositions of the invention are described hereinafter. Suitable auxiliaries which may be included in the compositions according to the invention are all adjuvants or components, such as extenders, carriers, solvents, surfactants, stabilizers, antifoaming agents, antifreeze agents, Preservatives, antioxidants, colorants, thickeners, solid binders, and inert fillers. Such adjuvants are known in the art and are commercially available. Its use in the formulation of the compositions of the present invention will be apparent to those skilled in the art.

The composition also includes one or more inert fillers. The inert filler is The art is known and commercially available. Suitable fillers are in solid form and include, for example, natural ground minerals such as kaolin, alumina, talc, chalk, quartz, attapulgite, montmorillonite, and diatomaceous earth, or synthetic ground minerals, Such as highly dispersed tannic acid, alumina, citrate and calcium phosphate and calcium hydrogen phosphate. Suitable inert fillers for granules include, for example, ground and graded natural minerals such as calcite, marble, pumice, sepiolite and dolomite, or synthetic inorganic and organic ground material particles, and organic materials such as sawdust Granules of coconut shells, corn cobs and tobacco stems.

The composition optionally comprises one or more surfactants, preferably non-ionic, cationic and/or anionic in nature, and a surfactant mixture having good emulsifying, dispersing and wetting properties. It depends on the nature of the active compound to be formulated. Suitable surfactants are known in the art and are commercially available. Suitable anionic surfactants may be the so-called water soluble soaps and water soluble synthetic surface active compounds. Usable soaps are alkali metal salts, alkaline earth metal salts or substituted or unsubstituted ammonium salts of higher fatty acids (C ₁₀ -C ₂₂ ), such as oleic or stearic acid or sodium or potassium salts of natural fatty acid mixtures. The surfactant may be an ionic or nonionic emulsifier, dispersant or wetting agent. Usable examples are salts of polyacrylic acid, salts of lignosulfonic acid, salts of benzenesulfonic acid or naphthalenesulfonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, substituted phenols ( In particular alkylphenols), sulfosuccinates, taurine derivatives (especially alkyltaurates), or polyethoxylated phenols or alcohol phosphates. When the active compound and/or inert carrier and/or adjuvant/adjuvant are insoluble in water and the vehicle for the final application of the composition is water, it is generally desirable to have at least one surfactant present.

The composition optionally further comprises one or more polymeric stabilizers. Suitable polymeric stabilizers useful in the present invention include, but are not limited to, polypropylene, polyisobutylene, polyisoprene, copolymers of monoolefins and diolefins, polyacrylates, polystyrene, polyvinyl acetate, polyamines Ester or polyamine. Suitable stabilizers are known in the art and are commercially available.

In general, the above surfactants and polymeric stabilizers are believed to impart stability to the composition, thereby permitting formulation, storage, transportation, and application of the composition.

Suitable antifoaming agents include all materials which are conventionally used in agrochemical compositions for this purpose. Suitable antifoaming agents are known in the art and are commercially available. A particularly preferred antifoaming agent is a mixture of polydimethylsiloxane and perfluoroalkylphosphonic acid, such as an anthrone defoamer available from GE Corporation or Compton.

Suitable organic solvents are selected from all common organic solvents which completely dissolve the active compound employed. Likewise, suitable organic solvents for the active ingredients (A), (B) and (C) are known in the art. The following may be regarded as preferred substances: N- methylpyrrolidone, N- octyl pyrrolidone, cyclohexyl-1-pyrrolidone; or paraffins, isoparaffins, cyclic paraffins and aromatics mixture of chains (e.g., SOLVESSO ^TM 200). Suitable solvents are commercially available.

Suitable preservatives include all materials conventionally used for this purpose in this type of agrochemical composition, and are also well known in the art. Suitable examples that can be exemplified include PREVENTOL ^® (from Bayer AG) and PROXEL ^® (from Bayer).

Suitable antioxidants are all materials conventionally used for this purpose in agrochemical compositions as is known in the art. Preferred is butylated hydroxytoluene.

Suitable thickeners include all materials which are conventionally used for this purpose in agrochemical compositions. For example, xanthan gum, PVOH, cellulose and its derivatives, clay hydrated silicate, magnesium aluminum silicate or mixtures thereof. Likewise, such thickeners are known in the art and are commercially available.

The composition may also comprise one or more solid adhesives. The adhesion agents are known in the art and are commercially available. It includes organic binders, including tackifiers, for example Cellulose of substituted cellulose, natural and synthetic polymers in the form of powders, granules or webs, and inorganic binders such as gypsum, vermiculite or cement.

Furthermore, the composition according to the invention may also comprise water, depending on the formulation.

Preferably, the combination employed in the present invention or the composition according to the present invention may comprise a combination of the following components: (A) Ciproxil + (B) Bifenin + (C) triflumuron; (A) Kill + (B) Bifenin + (C) sub-killing; (A) Cioxol + (B) Bifenin + (C) Abatin; (A) Cino kill + (B) Bifenin + (C) Abba Ting + sulfur enemy grams; (A) give promise + (B) Abatin + (C) sulfur enemy grams.

The compositions or combinations of the present invention can be used in the agricultural field and in related fields to prevent and control insects such as, but not limited to, helminths, mites, moths, noctuids, and Helicoverpa spp. Helicoverpax (Heliots spp.), aphids, thrips, leaf miners, whiteflies, worms: Agrotis ipsilon, Spodoptera frugiperda, Pod army worm (Pod army worm) Spodoptera latifascia), Spodoptera eridania, Agrotis ipsilon, Helicoverpa zea, Heliothis virescens, Helicoverpa armigera; 蝽: 稻 (rice green) Nezara viridula), Euschistus heroes, Piezodorus guildinii, Diechelos melancanthus, moths (including larvae): Epinotiaaporema, Cowpea Caterpillar (Anticarsia gemmatalis); whitefly: whitefly (Mosca branca); aphid: Toxoptera citricida; Hummer: Thrips palmi, Frankliniella brevicaulis, Frankliniella fusca, Frankliniella insularis, Frankliniella occidentalis, pasture Frankliniella rodeos, Frankliniella schultzei, Frankliniella williamsi; leaf miner: Lyriomyza (Liriomyza huidobrensis), Liriomyza sativae , Lyriomyza trifolii, Liriomyza trifolii, Lyriomyza sativae, Lyriomyza trifolii, Leucoptera coffeella, Lepidoptera (Lepidoptera) Lyriomyza trifolii), Phyllocnistis citrella.

The compositions of the present invention have surprisingly high potency for controlling infections caused by insects such as soybeans, dried beans, worms on peas (Agrotis ipsilon, corn autumn insects (Spodoptera frugiperda) ), Pod army worm (Spodoptera latifascia), Spodoptera eridania, Agrotis ipsilon, Helicoverpa zea, Heliothis virescens, cotton boll Worm (Helicoverpa armigera); thrips on fruits and vegetables (Thrips palmi, Frankliniella brevicaulis, Frankliniella fusca, Frankliniella insularis) , Frankliniella occidentalis, Frankliniella rodeos, Frankliniella schultzei, Frankliniella williamsi; leaf miners on vegetables, fruits and coffee ( Liriomyza (Liriomyza huidobrensis), Liriomyza sativae, Lyriomyza trifolii, Liriomyza trifolii, Liriomyza sativ Ae), Liriomyza trifida (Lyriomyza Trifolii), Leucoptera coffeella, Lyriomyza trifolii, Phyllocnistis citrella.

The methods, uses, and compositions of the present invention are suitable for use in crop plants: cereals (wheat, barley, rye, oats, corn, rice, sorghum, triticale, and related crops); fruits such as pear, stone, and non-nuclear Fruits such as apples, grapes, pears, plums, peaches, apricots, pistachio, cherries, and berries such as strawberries, raspberries and blackberries; bell peppers, red peppers; legumes ( Soybeans, lentils, peas, soybeans; oil-producing plants (canola, mustard, sunflower); cucurbitaceae (cucurbit, cucumber, watermelon); fiber plants (cotton, flax, hemp, jute); citrus plants, such as the four seasons Orange, citron, citrus hybrid (including grapefruit orange, orange pomelo, and orange), grapefruit, kumquat, lemon, lime, citrus (orange), bitter orange, orange, Wendan and Wenzhou mandarin; vegetables (spinach) , lettuce, asparagus, cabbage, carrots, onions, tomatoes, potatoes, red peppers; coffee; and ornamental plants (flowers such as roses, shrubs, broad-leaved trees and evergreens, such as conifers).

The method, use and composition of the present invention are preferably applied to legumes, vegetables, fruits, and coffee. More preferably, the composition of the invention is applied to soybeans, dried beans, vegetables, fruits, citrus or coffee.

Various combinations or compositions of the invention can be applied to or around the leaves or fruits of the plants.

The invention also provides the use of a pesticidal composition according to the invention for the prevention, control and/or treatment of insect infections in plants, plant parts and/or their surroundings.

The compositions of the present invention may comprise or be mixed with other pesticides such as other herbicides, fungicides, insecticides and nematicides, growth factors and fertilizers.

The application (application) rate of the composition of the present invention may vary depending on factors such as the type of application, the type of crop, the specific active compound in the composition, and the type of plant. However, it is desirable to administer the active compound in the composition in an amount effective to provide the desired effect, such as insect or pest control. The application rate of the composition for a given set of conditions can be readily determined by experimentation.

The components (A), (B) and (C) and any other pesticide may be applied and used as a solid active compound in pure form, for example at a specific particle size, or preferably with at least one such as in a formulation technique Conventional adjuvants or adjuvant components are used together, such as extenders, such as solvents or solid carriers or surface-active compounds (surfactants), as described in more detail above. In general, components (A), (B) and (C) are used in the form of a formulation composition formed with one or more of the aforementioned conventional formulation auxiliaries.

Examples of types of formulations for the composition are: water-soluble liquid (SL), emulsion (EC), water-based emulsion (EW), microemulsion (ME), water-dispersible oil suspension (OD), seed treatment A flowable suspension (FS), water-dispersible granules (WG), water-soluble granules (SG), wettable powders (WP), water-soluble powders (SP), granules (GR), capsules Granules (CG), fine granules (FG), large granules (GG), concentrated suspoemulsions (SE), capsule suspensions (CS), microgranules (MG), or preferably aqueous suspensions (SC) and emulsions (EC), wettable powder (WP), water dispersible granule (WG).

Using such formulations, directly (i.e., undiluted) or diluted with a suitable solvent (particularly water), the plants, plant parts and/or surroundings can be treated and protected against insects by spraying, pouring or immersing. The formulation may be diluted with water in a ratio of from about 1 to 1000 grams of total active ingredient per hectare, preferably from about 10 to about 700 grams of total active ingredient per hectare (ha).

Preferably, the application rate of the preferred combination of active ingredients is as follows: about 10 to 1000 g/ha of spinosad; about 1-500 g/ha of diphenfenine; about 1-700 g/ha of ababatene; about 1-500 g /ha of chlorfenapyr; about 1-500 g / ha of sub-cracking; about 10-1000 g / ha of sulfur enemy; More preferably, about 100-800 g/ha of spinosad; about 1-100 g/ha of bifenin; about 1-100 g/ha of ababatine; about 1-300 g/ha of triflumuron; about 1-200 g /ha sub-killing; about 10-500g / ha sulfur enemy grams.

Combinations or compositions comprising the active ingredients (A), (B) and (C) can be applied by any method known in the art. The method includes coating, spraying, dipping, wetting, injecting, irrigating, and the like.

The active ingredients (A), (B) and (C) can be applied to the plants, plant parts and/or surroundings, continuously for simultaneous or short intervals, for example on the same day, for the position to be controlled. The components (A), (B) and (C) can be applied to the plant, one or more parts of the plant (such as leaves or seeds), or in any order. Each component can be administered one or more times. Preferably, each of components (A), (B) and (C) is administered in multiples, in particular 2-5 times.

As stated above, the active ingredients (A), (B) and (C) can be administered in any suitable form. In general, the active ingredient is administered in the form of a formulation, i.e., a composition comprising one or more active ingredients together with other carriers, surfactants or other administration-promoting adjuvants conventionally employed in formulating techniques.

In the case of simultaneous application of components (A), (B) and (C), it may be applied as a composition comprising components (A), (B) and (C), in which case the components (A), (B), and (C) may be obtained from separate formulation sources and mixed together (referred to as tank-mix, ready-to-use, spray soup or slurry), optionally accompanied Other pesticides, or components (A), (B) and (C), may be obtained as a source of a single formulation mixture (referred to as premixed, concentrated, formulated compound (or product)) and optionally mixed with other pesticides. Together.

The composition of the invention has the following outstanding features: it has particularly good plant tolerance and is environmentally friendly.

Each of the compositions according to the invention is particularly advantageous for plant treatment.

The following examples of the invention are provided by way of illustration and not limitation.

In the examples, percentages are by weight unless otherwise indicated.

Formulation example Example 1

Preparation of water-dispersible granules (WG) by the following method: finely ground active ingredient with auxiliaries (0.5% SUPRALATE ^® (Witco Inc., Greenwich), 5% REAX ^® 88B (sodium lignosulfonate, Westvaco Corp., potassium carbonate (to 100%)) was mixed, then extruded and dried in an air flow dryer.

Example 2

An aqueous suspension (SC) was prepared by the following method: finely ground active ingredient with adjuvant (10% propylene glycol, 5% tristyrylphenol ethoxylate, 1% sodium lignosulfonate, 1% carboxyl) Methylcellulose, 1% eucalyptus oil (in the form of a 75% emulsion in water), 0.1% xanthan gum, Mix 0.1% NIPACIDE BIT 20 and water (to make up to 1L).

Example 3

An emulsion (EC) was prepared by mixing the active ingredient with an adjuvant (50 g of tristyrylphenol ethoxylate, 1 g of eucalyptus oil, 300 g of N-methylpyrrolidone, SOLVESSO 200 (to 1 L)).

Example 4

A wettable powder (WP) was prepared by mixing the finely ground active ingredient with an adjuvant (50 g Dispersogen 1494, kaolin (to 1000 g)), then extruding and drying in an air flow dryer.

Other formulations were prepared according to the methods shown in the above examples. The following table summarizes the details of the formulation:

Biological embodiment Biological Example 1 - Soybean - Worm

Agrotis ipsilon, Helicoverpa zea, Heliothis virescens, and Helicoverpa armigera were cultured in the laboratory. Count the number of insects, collect them, and then apply them to healthy juveniles Bean plants. The diluted formulation is then sprayed onto the plant. The remaining insect population was tested after 10 days in the greenhouse at 21-25 ° C and 80% relative atmospheric humidity. (Table A)

Biological Example 2 - Soybean - Worm

Spodoptera frugiperda, Pod army worm (Spodoptera latifascia), and Spodoptera eridania were cultured in the laboratory. The number of insects is counted, collected, and then applied separately to healthy juvenile soybean plants. The diluted formulation is then sprayed onto the plant. The remaining insect population was tested after 10 days in the greenhouse at 21-25 ° C and 80% relative atmospheric humidity. (Table B)

Biological Example 3 - Soybean - 蝽

Nezara viridula and Piezodorus guildinii were cultured in the laboratory. The number of insects is counted, collected, and then applied separately to healthy juvenile soybean plants. The diluted formulation is then sprayed onto the plant. The remaining insect population was tested after 10 days in the greenhouse at 21-25 ° C and 80% relative atmospheric humidity. (Table C)

Biological Example 4 - Soybean - Moth

The larvae of Epinotia aporema and Anticarsia gemmatalis were separately cultured in the laboratory. The number of insects is counted, collected, and then applied separately to healthy juvenile soybean plants. The diluted formulation is then sprayed onto the plant. The remaining insect population was tested after 10 days in the greenhouse at 21-25 ° C and 80% relative atmospheric humidity. (Table D)

Biological Example 5 - Coffee-Leaf Leaf (Coffee Leafminer)

Coffee leaf miner (Leucoptera coffeella) is cultivated in the laboratory. The number of insects is counted, collected, and then applied separately to healthy juvenile coffee plants. The diluted formulation is then sprayed onto the plant. The remaining insect population was tested after 10 days in the greenhouse at 21-25 ° C and 80% relative atmospheric humidity. (Table E)

Biological Example 6 - Toxoptera citricida, Thrawn (Frankliniella insularis) and Leafy (Phyllocnistis citrella)

Toxoptera citricida, scorpion horse (Frankliniella insularis) and leaf miner (Phyllocnistis citrella) were separately cultured in the laboratory. The number of insects is counted, collected, and then applied separately to healthy juvenile citrus plants. The diluted formulation is then sprayed onto the plant. The remaining insect population was tested after 10 days in the greenhouse at 21-25 ° C and 80% relative atmospheric humidity. (Table F)

Biological Example 7 - Grape - Thrips (Frankliniella occidentalis and Frankliniella rodeos)

Thrips (Frankliniella occidentalis and Frankliniella rodeos) were cultured in the laboratory. The number of insects is counted, collected, and then applied separately to healthy juvenile grape plants. The diluted formulation is then sprayed onto the plant. The remaining insect population was tested after 10 days in the greenhouse at 21-25 ° C and 80% relative atmospheric humidity. (Table G)

Biological Example 8 - Dry Bean - Agrotis ipsilon, Helicoverpa armigera

Agrotis ipsilon, Helicoverpa armigera, was cultured in the laboratory. The number of insects is counted, collected, and then applied separately to healthy juvenile dry bean plants. The diluted formulation is then sprayed onto the plant. The remaining insect population was tested after 10 days in the greenhouse at 21-25 ° C and 80% relative atmospheric humidity. (Table H)

Biological Example 9 - Potato-Lepidoptera (Lyriomyza huidobrensis, Lyriomyza sativae, Lyriomyza trifolii)

The leaf miner (Lyriomyza huidobrensis, Lyriomyza sativae, Lyriomyza trifolii) was cultured in the laboratory. The number of insects is counted, collected, and then applied separately to healthy juvenile potato plants. The diluted formulation is then sprayed onto the plant. The remaining insect population was tested after 10 days in the greenhouse at 21-25 ° C and 80% relative atmospheric humidity. (Table I)

All publications, patents and patent applications cited in this specification are hereby incorporated by reference in their entirety in their entirety in the the the the the the the the Although the present invention has been described in detail by way of illustration and example embodiments of the embodiments of the invention Some changes and modifications.

Claims (20)

An insecticidal composition comprising at least three different components selected from the group consisting of (A) to (C), wherein the group consists of: (A) spinosad; (B) abatatin (abamectin) or bifenin; and (C) at least one compound selected from the group consisting of abatatin, acetamiprid, thiodicarb, and triflumuron. The composition according to claim 1, which comprises the following combination: (A) chlorhexidine + (B) bifenin + (C) triflumuron; or (A) chlorpyrifos + (B) bifenin + (C) Sub-killing; or (A) giving promise + (B) Bifenin + (C) abatatin; or (A) giving promise + (B) Bifenin + (C) Abatin + sulfur enemy; or A) Give the kill + (B) Abatin + (C) sulfur enemy. The insecticidal composition according to claim 1 or 2, wherein the amount of the components (A), (B) and (C) in the composition is the component (A), 1% by weight to 80% by weight, the group Parts (B), 0.05% by weight to 70% by weight, component (C), 0.5% by weight to 80% by weight, each based on the weight of the composition. The insecticidal composition according to claim 3, wherein the amount of the components (A), (B) and (C) in the composition is the component (A), 20% by weight to 55% by weight, the component ( B), from 0.2% by weight to 10% by weight, component (C), from 1% by weight to 20% by weight, Each is based on the weight of the composition. The insecticidal composition according to any one of the preceding claims, wherein the ratio of the component (A) to the component (B) is from 150:1 to 1:150. The insecticidal composition according to claim 5, wherein the ratio of the component (A) to the component (B) is from 1:5 to 1:5. The insecticidal composition according to any one of claims 5 to 6, wherein the ratio of the component (A) to the component (B) is from 100:1 to 1:100. The insecticidal composition according to claim 7, wherein the ratio of the component (A) to the component (C) is from 2.5:1 to 1:2.5. The pesticidal composition according to any of the preceding claims, which further comprises a herbicide, a fungicide, other insecticide, nematicide, growth factor and fertilizer. The pesticidal composition according to any of the preceding claims, further comprising an adjuvant, an adjuvant or a component, such as a bulking agent, a carrier, a solvent, a surfactant, a stabilizer, an antifoaming agent, and an antibiotic Freezing agents, preservatives, antioxidants, colorants, thickeners, solid binders and inert fillers. A method for controlling an infection of an insect at a plant, a plant part or a location thereof, comprising administering to the plant, a plant part or a locus thereof: (A) a promise, (B) abatatin or bifenin; C) at least one compound selected from the group consisting of abatatin, arsenic, thiocarb, and triflumuron. The method according to claim 11, wherein the pest to be controlled comprises aphids, armyworms, beetles, cotton aphids, moth larvae, kimchi, burrowing locusts, aphids, caterpillars, citrus mites, southern white, and spider mites. , leaf miner, ruler, millipede, tea mites, moths, spider mites, crickets, hummers, elephant beetles, whiteflies, worms, hibiscus. The method of claim 11 or 12, wherein the plant, plant part or location thereof comprises cereals, fruits, legumes, cucurbitaceae, fiber plants, citrus, vegetables, coffee and ornamental plants, preferably legumes , fruit, vegetables and coffee. The method of any one of claims 1 to 10, wherein the composition of any one of claims 1 to 10 is employed. Use of one of the following: (A) spinosad, (B) abatatin or bifenin; and (C) at least one selected from the group consisting of abatatin, arbutin, thiocarb, and triflumuron A compound that is used to control insect infection at a plant, plant part or its location. The use of claim 15, wherein the composition of any one of claims 1-10 is employed. A method for the preparation of the composition of any one of claims 1 to 10, which comprises the combination of abalone and abatatin or diphennin, and a selected from the group consisting of abatatin, arsenic, thiophene and killing At least one compound of the bellulose is mixed. A synergistic insecticidal composition substantially as described above. A method of controlling insect infection at a plant, plant part and/or its location substantially as described above. Use of one of the following: (A) spinosad, (B) abatatin or bifenin; and (C) at least one compound selected from the group consisting of abatatin, arsenic, thiocarb, and triflumuron. As mentioned above, it is used to control insect infections at plants, plant parts and/or their locations.