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TW201311454A - Apparatus and process for producing laminated sheet - Google Patents

Apparatus and process for producing laminated sheet Download PDF

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Publication number
TW201311454A
TW201311454A TW101126219A TW101126219A TW201311454A TW 201311454 A TW201311454 A TW 201311454A TW 101126219 A TW101126219 A TW 101126219A TW 101126219 A TW101126219 A TW 101126219A TW 201311454 A TW201311454 A TW 201311454A
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TW
Taiwan
Prior art keywords
laminated sheet
roller
chamber
resin
sheet
Prior art date
Application number
TW101126219A
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Chinese (zh)
Other versions
TWI554406B (en
Inventor
Takeshi Hosomi
Kenta Ue
Akinori Yoshihara
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Sumitomo Bakelite Co
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Publication of TW201311454A publication Critical patent/TW201311454A/en
Application granted granted Critical
Publication of TWI554406B publication Critical patent/TWI554406B/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/16Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
    • B32B37/20Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of continuous webs only
    • B32B37/203One or more of the layers being plastic
    • B32B37/206Laminating a continuous layer between two continuous plastic layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10Coating or impregnating independently of the moulding or shaping step
    • B29B15/12Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/122Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/504Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands
    • B29C70/506Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands and impregnating by melting a solid material, e.g. sheet, powder, fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/26Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer which influences the bonding during the lamination process, e.g. release layers or pressure equalising layers
    • B32B2037/264Pressure equalizing layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/26Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer which influences the bonding during the lamination process, e.g. release layers or pressure equalising layers
    • B32B2037/268Release layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/07Parts immersed or impregnated in a matrix
    • B32B2305/076Prepregs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/0046Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by constructional aspects of the apparatus
    • B32B37/0053Constructional details of laminating machines comprising rollers; Constructional features of the rollers

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Laminated Bodies (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

The invention relates to an apparatus for producing a laminated sheet, which produces a heated laminated sheet (40 (40A)) by a heating device (30B) heating a laminated sheet comprising a fiber substrate and a resin layer provided on one or two sides of the fiber substrate (the laminated sheet (40 (40A)) that has not been heated by the heating device (30B)). The heating device (30B) comprises: a chamber (91) through which the laminated sheet (40 (40A)) passes; a heating means (92) for heating the chamber (91) and thus heating the laminated sheet (40 (40A)); and a path length varying means for making it variable the length of the path that the laminated sheet (40 (40A)) passes through the chamber (91).

Description

積層片製造裝置及積層片之製造方法 Multilayer sheet manufacturing apparatus and method for manufacturing laminated sheet

本發明係關於積層片之製造裝置及積層片之製造方法。 The present invention relates to a manufacturing apparatus of a laminated sheet and a method of manufacturing the laminated sheet.

近年來,為了電子零件‧電子機器之小型化、薄膜化,而要求其中所使用之電路基板等的小型化‧薄膜化。為了對應此要求,而使用多層構造之電路基板,並進行其各層的減薄。 In recent years, in order to reduce the size and thickness of electronic components and electronic devices, it is required to reduce the size and thickness of circuit boards used therein. In order to cope with this requirement, a circuit board having a multilayer structure is used, and thinning of each layer is performed.

於多層構造之電路基板,係使用例如於纖維基材之兩面上配置樹脂組成物片(樹脂層)並予以層合接黏的片材(例如參照專利文獻1)。 In the circuit board of the multilayer structure, for example, a sheet in which a resin composition sheet (resin layer) is placed on both surfaces of a fiber base material and laminated and bonded is used (for example, see Patent Document 1).

此片材係藉由於纖維基材之兩面上,重疊B階段樹脂組成物片,對此積層體進行加壓而製造。 This sheet is produced by superposing a B-stage resin composition sheet on both surfaces of a fibrous base material and pressurizing the laminated body.

專利文獻1:日本專利特開2003-340952號公報 Patent Document 1: Japanese Patent Laid-Open Publication No. 2003-340952

在製造此種片材時,有時對B階段樹脂組成物片進行加熱。例如,有時對B階段樹脂組成物片進行加熱,調整B階段樹脂組成物片的硬化程度。此時,有視B階段樹脂組成物片的樹脂組成物之組成、或B階段樹脂組成物片之樹脂層厚度,而使樹脂層成為所需硬化程度的加熱時間相異的情形。已知僅藉由使B階段樹脂組成物片通過加熱爐內,將難以獲得所需之B階段樹脂組成物片。 In the production of such a sheet, the B-stage resin composition sheet is sometimes heated. For example, the B-stage resin composition sheet is sometimes heated to adjust the degree of hardening of the B-stage resin composition sheet. In this case, depending on the composition of the resin composition of the B-stage resin composition sheet or the thickness of the resin layer of the B-stage resin composition sheet, the heating time of the resin layer to the desired degree of hardening may be different. It is known that it is difficult to obtain a desired B-stage resin composition sheet only by passing the B-stage resin composition sheet through a heating furnace.

根據本發明,提供一種積層片之製造裝置,係將具備具有 可撓性之帶狀基材、與供給至該基材之單面或兩面之樹脂組成物的積層片進行加熱,而製造積層片者,其特徵為,具備:上述積層片所通過的腔室;將上述腔室內加熱,以對上述積層片加熱的加熱手段;與使上述積層片通過上述腔室內時之通過路徑之長度為可變的路徑長可變手段。 According to the present invention, there is provided a manufacturing apparatus for a laminated sheet which is provided with The flexible tape-shaped base material and the laminated sheet of the resin composition supplied to the one surface or both surfaces of the base material are heated to produce a laminated sheet, and the chamber is provided with a chamber through which the laminated sheet passes. And a heating means for heating the chamber to heat the laminated sheet; and a path length variable means for changing a length of a passage path when the laminated sheet passes through the chamber.

本發明之積層片之製造裝置係具備使積層片於腔室內之通過路徑之長度為可變的路徑長可變手段。藉由路徑長可變手段變更積層片於腔室內之通過路徑之長度,則可調製積層片通過腔室內的時間,而可調整積層片的加熱時間,故可得到所需的積層片。 The apparatus for manufacturing a laminated sheet according to the present invention includes a path length variable means for making the length of the passage of the laminated sheet in the chamber variable. By changing the length of the passage path of the laminated sheet in the chamber by the variable path length means, the time during which the laminated sheet passes through the chamber can be modulated, and the heating time of the laminated sheet can be adjusted, so that the desired laminated sheet can be obtained.

另外,根據本發明,提供一種積層片之製造方法,係包括:第1加熱步驟,係使具備屬於具有可撓性之帶狀之無機織布或有機纖維基材的基材、與供給至該基材之單面或兩面之樹脂組成物的第1積層片,依第1通過路徑長度,一邊通過腔室內、一邊進行加熱;與第2加熱步驟,係使具備屬於具有可撓性之帶狀之無機織布或有機纖維基材的基材、與供給至該基材之單面或兩面之樹脂組成物的第2積層片,依與上述第1通過路徑長度相異之第2通過路徑長度,一邊通過上述腔室內、一邊進行加熱。 Further, according to the present invention, there is provided a method for producing a laminated sheet, comprising: a first heating step of supplying a substrate having a flexible ribbon-like inorganic woven fabric or an organic fiber substrate, and supplying the substrate The first layered sheet of the resin composition having one side or both sides of the substrate is heated while passing through the chamber according to the length of the first passage path; and the second heating step is provided with a strip having flexibility The substrate of the inorganic woven fabric or the organic fiber base material and the second laminated sheet of the resin composition supplied to one side or both surfaces of the base material have a second passage path length different from the length of the first passage path The heating is performed while passing through the chamber.

如上述,根據本發明,可提供能得到所需積層片的積層片製造裝置及積層片之製造方法。 As described above, according to the present invention, it is possible to provide a laminated sheet manufacturing apparatus and a method for producing a laminated sheet which can obtain a desired laminated sheet.

上述目的及其他目的、特徵及優點,將藉由以下所述之較佳實施形態、及隨附之以下圖式進一步闡明。 The above and other objects, features and advantages of the invention will be apparent from

以下,根據圖式說明本發明之實施形態。又,所有圖式中,對相同之構成要素加註同一符號,且其詳細說明不重複而適當省略。 Hereinafter, embodiments of the present invention will be described based on the drawings. In the drawings, the same components are denoted by the same reference numerals, and the detailed description thereof is omitted as appropriate.

以下,根據添附圖式所示之較佳實施形態詳細說明本發明之積層片製造裝置及積層片。 Hereinafter, the laminated sheet manufacturing apparatus and the laminated sheet of the present invention will be described in detail based on preferred embodiments shown in the accompanying drawings.

參照圖1~12,說明本實施形態。 This embodiment will be described with reference to Figs.

圖1~圖3係分別表示本發明之積層片之製造裝置之實施形態的概略剖面側面圖(依序表示製造本發明之積層片時之製造過程的圖),圖4為圖1中之A-A線剖面圖,圖5為圖1中之B-B線剖面圖,圖6為圖1中由單點虛線所包圍之區域[C]的放大圖,圖7為圖2及圖3所示之積層片製造裝置中之硬化爐的分解立體圖,圖8為表示本發明之積層片的剖面圖,圖9為表示使用圖8所示之積層片所製造之基板的剖面圖,圖10為表示使用圖9所示之基板所製造之半導體裝置的剖面圖。又,以下說明中,將圖1~圖10中之上側作為「上」或「上方」,將下側作為「下」或「下方」進行說明。又,圖8~圖10係將厚度方向(圖中之上下方向)誇大表示。又,有時將圖2、圖3、圖7中之左右方向稱為x軸方向,將相對於x軸方向呈垂直之方向稱為y軸方向。 1 to 3 are schematic cross-sectional side views showing an embodiment of a manufacturing apparatus for a laminated sheet of the present invention (a diagram showing a manufacturing process when the laminated sheet of the present invention is produced), and FIG. 4 is an AA of FIG. FIG. 5 is a cross-sectional view taken along line BB of FIG. 1, FIG. 6 is an enlarged view of a region [C] surrounded by a single dotted line in FIG. 1, and FIG. 7 is a laminated sheet shown in FIGS. 2 and 3. FIG. 8 is a cross-sectional view showing a laminated sheet of the present invention, FIG. 9 is a cross-sectional view showing a substrate produced by using the laminated sheet shown in FIG. 8, and FIG. 10 is a view showing the use of the laminated sheet of the present invention. A cross-sectional view of a semiconductor device fabricated on the substrate shown. In the following description, the upper side in FIGS. 1 to 10 will be referred to as "upper" or "upper", and the lower side will be referred to as "lower" or "lower". 8 to 10 are exaggerated in the thickness direction (upward and downward directions in the drawing). Further, the left-right direction in FIGS. 2, 3, and 7 may be referred to as an x-axis direction, and the direction perpendicular to the x-axis direction may be referred to as a y-axis direction.

圖11係表示腔室內之輥之移動狀態的平面圖。圖12係由腔室側面側所觀看的圖,表示隨著輥移動而遮蔽構件進行移動之樣子的圖。 Figure 11 is a plan view showing the state of movement of the rolls in the chamber. Fig. 12 is a view as seen from the side surface side of the chamber, showing a state in which the shield member moves as the roller moves.

圖1~圖3所示之積層片製造裝置30,係製造圖8所示構成之積層片40(40A)的裝置。 The laminated sheet manufacturing apparatus 30 shown in Figs. 1 to 3 is an apparatus for manufacturing the laminated sheet 40 (40A) having the configuration shown in Fig. 8.

<積層片> <Laminated film>

首先,參照圖8說明積層片40(40A)。又,若將積層片40(40A)於其長度方向之途中切斷為既定尺寸,則得到預浸體1。 First, the laminated sheet 40 (40A) will be described with reference to Fig. 8 . Moreover, when the laminated sheet 40 (40A) is cut into a predetermined size in the longitudinal direction, the prepreg 1 is obtained.

圖8所示之積層片(第1積層片)40,係由具有:可撓性之薄板狀(帶狀)的纖維基材(基材)2;位於纖維基材2之一面(上面)側,由固形或半固形之第1樹脂組成物所構成的第1樹脂層(樹脂層)3;與位於纖維基材2之另一面(下面)側,由固形或半固形之第2樹脂組成物所構成的第2樹脂層(樹脂層)4。該積層片40係切斷為既定尺寸而使用。各樹脂層3、4為B階段狀態。 The laminated sheet (first laminated sheet) 40 shown in Fig. 8 is a fibrous base material (base material) 2 having a flexible sheet shape (belt shape); and is located on one side (upper surface) side of the fibrous base material 2 a first resin layer (resin layer) 3 composed of a solid or semi-solid first resin composition; and a second resin composition which is solid or semi-solid on the other side (lower side) side of the fiber substrate 2 The second resin layer (resin layer) 4 is formed. The laminated sheet 40 is cut into a predetermined size and used. Each of the resin layers 3 and 4 is in a B-stage state.

圖8所示之積層片(第2積層片)40A,係由與積層片40同樣之纖維基材(基板)2所構成,但除了樹脂層3A、4A之組成與樹脂層3、4相異之外,其餘點與樹脂層3、4相同。 The laminated sheet (second laminated sheet) 40A shown in Fig. 8 is composed of the same fibrous base material (substrate) 2 as the laminated sheet 40, except that the composition of the resin layers 3A and 4A is different from that of the resin layers 3 and 4. The remaining points are the same as those of the resin layers 3, 4.

尚且,圖8中雖未圖示,但亦可於樹脂層3、4(3A、4A)之表面上設有支撐基板52(參照圖1)。其中,在支撐基材52為由樹脂薄膜等所構成的情況,係在製造後述之基板10 時,將支撐基材52樹脂層剝離。 Further, although not shown in FIG. 8, a support substrate 52 (see FIG. 1) may be provided on the surfaces of the resin layers 3, 4 (3A, 4A). In the case where the support base material 52 is made of a resin film or the like, the substrate 10 to be described later is manufactured. At this time, the resin layer of the support substrate 52 is peeled off.

纖維基材2具有提升積層片40(40A)之機械強度的機能。 The fibrous base material 2 has a function of enhancing the mechanical strength of the laminated sheet 40 (40A).

作為該纖維基材2,可舉例如:玻璃織布、玻璃不織布等之玻璃纖維基材;以聚醯胺樹脂纖維、包括芳香族聚醯胺樹脂纖維或全芳香族聚醯胺樹脂纖維等之芳醯胺纖維等的聚醯胺系樹脂纖維,聚酯樹脂纖維、芳香族聚酯樹脂纖維、全芳香族聚酯樹脂纖維等之聚酯系樹脂纖維,聚醯亞胺樹脂纖維、聚對伸苯基苯并雙唑、氟樹脂纖維等之任一者作為主成分的織布或不織布所構成的合成纖維基材;以牛皮紙、棉短絨紙、短絨與牛皮紙漿的混抄紙等之任一種為主成分的紙纖維基材等的任一種纖維基材等。 Examples of the fiber base material 2 include a glass fiber base material such as a glass woven fabric or a glass nonwoven fabric; and a polyamide resin fiber, an aromatic polyamide resin fiber, or a wholly aromatic polyamide resin fiber. Polyamide type resin fiber such as linaloamide fiber, polyester resin fiber such as polyester resin fiber, aromatic polyester resin fiber or wholly aromatic polyester resin fiber, polyimine resin fiber, poly-stretch Phenyl benzobis a synthetic fiber base material comprising a woven fabric or a non-woven fabric as a main component of any one of an azole or a fluororesin fiber; and a kraft paper, a cotton linter paper, a mixed paper of a velvet and a kraft pulp, and the like Any one of a fibrous base material such as a paper fiber base material.

又,纖維基材可使用上述纖維之任一種,亦可使用2種以上。其中,作為纖維基材2,較佳係無機織布基材或有機纖維基材的任一種。 Further, any of the above fibers may be used as the fiber base material, and two or more types may be used. Among them, the fiber base material 2 is preferably any of an inorganic woven fabric base material or an organic fiber base material.

此等之中,纖維基材2較佳係屬於無機織布基材的玻璃織布基材。藉由使用此種玻璃織布基材,可更加提升切斷積層片40(40A)所得之預浸體1的機械強度。又,亦有可減小預浸體1的熱膨脹係數的效果。 Among these, the fibrous base material 2 is preferably a glass woven fabric substrate belonging to an inorganic woven fabric substrate. By using such a glass woven base material, the mechanical strength of the prepreg 1 obtained by cutting the laminated sheet 40 (40A) can be further enhanced. Further, there is also an effect of reducing the thermal expansion coefficient of the prepreg 1.

作為構成玻璃纖維之玻璃可舉例如E玻璃、C玻璃、A玻璃、S玻璃、D玻璃、NE玻璃、T玻璃、H玻璃、石英玻璃等任一種。此等之中,較佳為石英玻璃、S玻璃或T玻璃。 藉此,可使玻璃纖維基材之熱膨脹係數較小,因此可使積層片40的熱膨脹係數儘可能地減小。 Examples of the glass constituting the glass fiber include E glass, C glass, A glass, S glass, D glass, NE glass, T glass, H glass, and quartz glass. Among these, quartz glass, S glass or T glass is preferred. Thereby, the coefficient of thermal expansion of the glass fiber base material can be made small, so that the thermal expansion coefficient of the laminated sheet 40 can be made as small as possible.

纖維基材2的平均厚度並無特別限定,較佳為150μm以下、更佳100μm以下、再更佳10~20μm左右。藉由使用此種厚度的纖維基材2,則可確保預浸體1(積層片40(40A))的機械強度,並達到其薄型化。進而亦可提升預浸體1的加工性。 The average thickness of the fibrous base material 2 is not particularly limited, but is preferably 150 μm or less, more preferably 100 μm or less, still more preferably about 10 to 20 μm. By using the fiber base material 2 having such a thickness, the mechanical strength of the prepreg 1 (the laminated sheet 40 (40A)) can be ensured and the thickness thereof can be reduced. Further, the workability of the prepreg 1 can be improved.

於該纖維基材2之一面側上,設有第1樹脂層3(3A),並於另一面側上,設有第2樹脂層4(4A)。又,第1樹脂層3(3A)與第2樹脂層4(4A)可由相同之樹脂組成物所構成,亦可由不同之樹脂組成物所構成。本實施形態中係設為相同之組成物。 The first resin layer 3 (3A) is provided on one surface side of the fiber base material 2, and the second resin layer 4 (4A) is provided on the other surface side. Further, the first resin layer 3 (3A) and the second resin layer 4 (4A) may be composed of the same resin composition, or may be composed of different resin compositions. In the present embodiment, the same composition is used.

如圖8所示,本實施形態中,係於纖維基材2之厚度方向之一部分中含浸第1樹脂組成物(第1樹脂層3(3A))(以下將此部分稱為「第1含浸部31」),在纖維基材2之未含浸第1樹脂組成物的剩餘部分,含浸第2樹脂組成物(第2樹脂層4(4A))(以下將此部分稱為「第2含浸部41」)。藉此,屬於第1樹脂層3(3A)一部分之第1含浸部31與屬於第2樹脂層4(4A)一部分之第2含浸部41位於纖維基材2內。而且,於纖維基材2內,第1含浸部31(第1樹脂層3之下面)與第2含浸部41(第2樹脂層4之上面)接觸。 As shown in Fig. 8, in the present embodiment, the first resin composition (the first resin layer 3 (3A)) is impregnated in one of the thickness directions of the fiber base material 2 (hereinafter, this portion is referred to as "the first impregnation". In the remaining portion of the fibrous base material 2, which is not impregnated with the first resin composition, the second resin composition (second resin layer 4 (4A)) is impregnated (hereinafter referred to as "the second impregnation portion" 41"). Thereby, the first impregnation portion 31 belonging to a part of the first resin layer 3 (3A) and the second impregnation portion 41 belonging to a part of the second resin layer 4 (4A) are located in the fiber base material 2. In the fiber base material 2, the first impregnation portion 31 (the lower surface of the first resin layer 3) is in contact with the second impregnation portion 41 (the upper surface of the second resin layer 4).

本實施形態中,第1含浸部31的厚度與第2含浸部41 的厚度相等。 In the present embodiment, the thickness of the first impregnation portion 31 and the second impregnation portion 41 The thickness is equal.

再者,第1樹脂層3(3A)之除了第1含浸部31以外的部分(第1非含浸部32)的厚度、與第2樹脂層4(4A)之除了第2含浸部41以外的部分(第2非含浸部42)的厚度相等。第1非含浸部32之厚度、第2非含浸部42之厚度為例如2~20μm。又,第1含浸部31之厚度、與第2含浸部41之厚度可相異,且第1非含浸部32之厚度與第2非含浸部42之厚度可相異。又,符號20係示意性地表示含浸部31、41間的境界。 In addition, the thickness of the portion other than the first impregnation portion 31 (the first non-impregnated portion 32) of the first resin layer 3 (3A) and the second resin layer 4 (4A) other than the second impregnation portion 41 The portions (the second non-impregnated portion 42) have the same thickness. The thickness of the first non-impregnated portion 32 and the thickness of the second non-impregnated portion 42 are, for example, 2 to 20 μm. Further, the thickness of the first impregnation portion 31 and the thickness of the second impregnation portion 41 may be different, and the thickness of the first non-impregnation portion 32 may be different from the thickness of the second non-impregnation portion 42. Further, reference numeral 20 schematically shows the boundary between the impregnation portions 31 and 41.

如圖1所示,第1樹脂層3(3A)係作成薄板狀之第1積層片5a而供給至積層片製造裝置30。該片材5a具備第1樹脂層3(3A)、支撐該樹脂層3(3A)的支撐基材52、保護第1樹脂層3的保護片51。支撐基材52係挾持第1樹脂層3(3A)而設於保護片51的相反側。因此,圖1中,第1樹脂層3(3A)係經由支撐基材52而與第2輥72a接觸。 As shown in FIG. 1, the first resin layer 3 (3A) is supplied to the laminated sheet manufacturing apparatus 30 as a first laminated sheet 5a having a thin plate shape. The sheet 5a includes a first resin layer 3 (3A), a support base 52 that supports the resin layer 3 (3A), and a protective sheet 51 that protects the first resin layer 3. The support base material 52 is provided on the opposite side of the protective sheet 51 while holding the first resin layer 3 (3A). Therefore, in FIG. 1, the first resin layer 3 (3A) is in contact with the second roller 72a via the support base material 52.

同樣地,第2樹脂層4(4A)係作成薄板狀之第2積層片5b而供給至積層片製造裝置30。該片材5b具備第2樹脂層4(4A)、支撐該樹脂層4(4A)的支撐基材52、保護第2樹脂層4的保護片51。支撐基材係挾持第2樹脂層4(4A)而設於保護片51的相反側。因此,圖1中,第2樹脂層4(4A)係經由支撐基材52而與第2輥72b接觸。 In the same manner, the second resin layer 4 (4A) is supplied to the laminated sheet manufacturing apparatus 30 as the second laminated sheet 5b in the form of a thin plate. The sheet 5b includes a second resin layer 4 (4A), a support base 52 that supports the resin layer 4 (4A), and a protective sheet 51 that protects the second resin layer 4. The support substrate is placed on the opposite side of the protective sheet 51 while holding the second resin layer 4 (4A). Therefore, in FIG. 1, the 2nd resin layer 4 (4A) contacts the 2nd roller 72b via the support base material 52.

作為保護片51,較佳為例如樹脂薄膜。作為構成樹脂薄 膜的樹脂材料,可舉例如氟系樹脂、聚醯亞胺、聚對苯二甲酸丁二酯、聚對苯二甲酸乙二酯等之聚酯、聚乙烯等的任一種。而且,作為構成樹脂薄膜的樹脂材料,此等之中,由耐熱性優越、廉價而言,較佳為聚對苯二甲酸乙二酯、聚乙烯。又,樹脂薄膜較佳係於其樹脂薄膜之樹脂層側之面實施了可剝離之處理者。藉此,可如後述般使保護片51與樹脂層容易分離。 As the protective sheet 51, for example, a resin film is preferable. As a constituent resin thin The resin material of the film may, for example, be any of a polyester such as a fluorine resin, a polyimide, a polybutylene terephthalate or a polyethylene terephthalate, or a polyethylene. Further, among the resin materials constituting the resin film, among these, from the viewpoint of excellent heat resistance and low cost, polyethylene terephthalate or polyethylene is preferable. Moreover, it is preferable that the resin film is subjected to a peelable treatment on the side of the resin layer side of the resin film. Thereby, the protective sheet 51 and the resin layer can be easily separated as will be described later.

作為支撐基材52,可使用與保護片51相同物。又,支撐基板52亦可為銅箔等之金屬層。 As the support substrate 52, the same material as the protective sheet 51 can be used. Further, the support substrate 52 may be a metal layer such as copper foil.

保護片51或支撐基材52的平均厚度並無特別限定,較佳為8~70μm左右、更佳12~40μm左右。 The average thickness of the protective sheet 51 or the support base material 52 is not particularly limited, but is preferably about 8 to 70 μm, more preferably about 12 to 40 μm.

樹脂層3、3A、4、4A係由下述之樹脂組成物所構成。 The resin layers 3, 3A, 4, and 4A are composed of the following resin compositions.

各樹脂層3、3A、4、4A係例如含有硬化性樹脂,視需要含有硬化助劑(例如硬化劑、硬化促進劑)及無機填充材中之至少1種而構成。 Each of the resin layers 3, 3A, 4, and 4A contains, for example, a curable resin, and optionally contains at least one of a curing aid (for example, a curing agent and a curing accelerator) and an inorganic filler.

作為硬化性樹脂,可舉例如脲(尿素)樹脂、三聚氰胺樹脂、順丁烯二醯亞胺化合物、聚腔基甲酸酯樹脂、不飽和聚酯樹脂、具有苯并環的樹脂、雙烯丙基降伯烯二甲酸化合物、乙烯基苄基樹脂、乙烯基苄基醚樹脂、苯并環丁烯樹脂、氰酸酯樹脂、環氧樹脂等之熱硬化性樹脂、紫外線硬化性樹脂、嫌氣硬化性樹脂等之任一種。此等之中,硬化性樹脂較佳係由玻璃轉移溫度成為200℃以上的組合。例如較佳 係使用含螺環、雜環式、三羥甲基型、聯苯型、萘型、蒽型、酚醛清漆型之2或3官能以上的環氧樹脂、氰酸酯樹脂(包括氰酸樹脂之預聚物)、順丁烯二醯亞胺化合物、苯并環丁烯樹脂、具有苯并環之樹脂的任一種。 Examples of the curable resin include urea (urea) resin, melamine resin, maleimide compound, polycavity resin, unsaturated polyester resin, and benzoic acid. a thermosetting resin such as a cyclic resin, a bisallyl-lowering primary dicarboxylic acid compound, a vinyl benzyl resin, a vinyl benzyl ether resin, a benzocyclobutene resin, a cyanate resin, or an epoxy resin; Any one of an ultraviolet curable resin and an anaerobic resin. Among these, the curable resin is preferably a combination in which the glass transition temperature is 200 ° C or higher. For example, it is preferred to use an epoxy resin having a spiro ring, a heterocyclic formula, a trimethylol type, a biphenyl type, a naphthalene type, a fluorene type, a novolac type, or a cyanate resin (including cyanide). Prepolymer of acid resin), maleimide compound, benzocyclobutene resin, with benzoic acid Any of the resins of the ring.

上述硬化性樹脂中,藉由使用熱硬化性樹脂,進而在製作了後述基板10(參照圖9)後,由於在硬化後之樹脂層3、3A、4、4A中交聯密度增加,故可達到硬化後之樹脂層3、3A、4、4A(所得基板)的耐熱性提升。 In the above-mentioned curable resin, after the substrate 10 (see FIG. 9) to be described later is produced by using a thermosetting resin, the crosslinking density is increased in the resin layers 3, 3A, 4, and 4A after curing. The heat resistance of the resin layers 3, 3A, 4, and 4A (the obtained substrate) after hardening is improved.

藉由併用上述熱硬化性樹脂與填充材,可使預浸體1之熱膨脹係數減小(以下亦稱為「低熱膨脹化」)。再者,亦可達到預浸體1之電氣特性(低介電係數、低耗損因子)等的提升。作為上述環氧樹脂,可舉例如苯酚酚醛清漆型環氧樹脂、雙酚型環氧樹脂、萘型環氧樹脂、蒽型環氧樹脂、芳基伸烷基型環氧樹脂等之任一種。 By using the thermosetting resin and the filler in combination, the thermal expansion coefficient of the prepreg 1 can be reduced (hereinafter also referred to as "low thermal expansion"). Furthermore, the electrical characteristics (low dielectric constant, low loss factor) of the prepreg 1 can be improved. Examples of the epoxy resin include a phenol novolak type epoxy resin, a bisphenol type epoxy resin, a naphthalene type epoxy resin, a fluorene type epoxy resin, and an aryl alkylene type epoxy resin.

此等之中,環氧樹脂較佳係萘型、芳基伸烷基型環氧樹脂的任一種。藉由使用萘型、芳基伸烷基型環氧樹脂,則於硬化後之樹脂3、4(所得基板)中,可提升吸濕焊錫耐熱性(吸濕後之焊錫耐熱性)及難燃性。作為萘型環氧樹脂,可舉例如DIC(股)製之HP-4700、HP-4770、HP-4032D、HP-5000、HP-6000、日本化藥(股)製之NC-7300L、新日鐵化學(股)製之ESN-375等;作為芳基伸烷基型環氧樹脂,可舉例如日本化藥(股)製之NC-3000、NC-3000L、NC-3000-FH、日本 化學(股)製之NC-7300L、新日鐵化學(股)製之ESN-375等。所謂芳基伸烷基型環氧樹脂,係指於重複單位中含有一個以上之芳香族基與亞甲基胺之伸烷基之組合的環氧樹脂,其耐熱性、難燃性及機械強度優越。又,為了對應無鹵素之佈線板,較佳係使用實質上不含鹵素的環氧樹脂。 Among these, the epoxy resin is preferably any of a naphthalene type or an arylalkylene type epoxy resin. By using a naphthalene type or arylalkylene type epoxy resin, the heat resistance of the moisture absorption solder (solder heat resistance after moisture absorption) and flame retardancy can be improved in the cured resin 3 and 4 (the obtained substrate). . Examples of the naphthalene type epoxy resin include HP-4700, HP-4770, HP-4032D, HP-5000, HP-6000, and Nippon Chemical Co., Ltd., NC-7300L, manufactured by DIC Co., Ltd. ESN-375, etc., which is made of ferrous chemical (manufactured by the company); as an arylalkylene type epoxy resin, for example, NC-3000, NC-3000L, NC-3000-FH, manufactured by Nippon Kayaku Co., Ltd., Japan NC-7300L manufactured by Chemical Co., Ltd., ESN-375 manufactured by Nippon Steel Chemical Co., Ltd., etc. The term "aryl extended alkyl type epoxy resin" refers to an epoxy resin which contains a combination of more than one aromatic group and an alkylene group of a methylene amine in a repeating unit, and has excellent heat resistance, flame retardancy and mechanical strength. . Moreover, in order to correspond to a halogen-free wiring board, it is preferable to use an epoxy resin which does not contain a halogen substantially.

上述氰酸酯樹脂可例如使鹵化氰化合物與酚類或萘酚類反應,視需要藉加熱等方法進行預聚化而獲得。又,亦可使用如此調製的市售物。 The cyanate resin can be obtained, for example, by reacting a halogenated cyanide compound with a phenol or a naphthol, and prepolymerizing it by heating or the like as needed. Further, a commercially available product thus prepared can also be used.

上述氰酸酯樹脂可舉例如酚醛清漆型氰酸酯樹脂、雙酚A型氰酸酯樹脂、、雙酚E型氰酸酯樹脂、四甲基雙酚F型氰酸酯樹脂等之雙酚型氰酸酯樹脂,及萘酚伸烷基型氰酸酯樹脂等之任一種。 The cyanate resin may, for example, be a phenolic resin such as a novolac type cyanate resin, a bisphenol A type cyanate resin, a bisphenol E type cyanate resin or a tetramethylbisphenol F type cyanate resin. Any of a type cyanate resin and a naphthol alkylene type cyanate resin.

另外,上述氰酸酯樹脂較佳係於分子內具有2個以上氰酸酯基(-O-CN)。可舉例如2,2’-雙(4-氰酸基苯基)亞異丙基、1,1’-雙(4-氰酸基苯基)乙烷、雙(4-氰酸基-3,5-二甲基苯基)甲烷、1,3-雙(4-氰酸基苯基-1-(1-甲基亞乙基))苯、雙(4-氰酸基苯基)硫醚、二環戊二烯型氰酸酯、苯酚酚醛清漆型氰酸酯、雙(4-氰酸基苯基)醚、1,1,1-參(4-氰酸基苯基)乙烷、參(4-氰酸基苯基)亞磷酸酯、雙(4-氰酸基苯基)碸、2,2-雙(4-氰酸基苯基)丙烷、1,3-、1,4-、1,6-、1,8-、2,6-或2,7-二氰酸基萘、1,3,6-三氰酸基萘、4,4-二氰酸基聯苯及苯酚酚醛清漆型、甲酚酚醛清漆型、二環戊二烯型等之任一種的多元酚 類與鹵化氰的反應所得的氰酸酯樹脂、萘酚伸烷基型之多元萘酚類與鹵化氰之反應所得的氰酸酯樹脂的任一種以上。此等之中,苯酚酚醛清漆型氰酸酯樹脂係難燃性及低熱膨脹性優越,2,2-雙(4-氰酸基苯基)亞異丙基及二環戊二烯型氰酸酯樹脂係交聯密度之控制及耐濕可靠性優越。由低熱膨脹性的觀點而言,特佳為苯酚酚醛清漆型氰酸酯樹脂。又,亦可進一步併用1種或2種以上之其他氰酸酯樹脂,並無特別限定。 Further, the cyanate resin preferably has two or more cyanate groups (-O-CN) in the molecule. For example, 2,2'-bis(4-cyanylphenyl) isopropylidene, 1,1'-bis(4-cyanylphenyl)ethane, bis(4-cyanyl-3) ,5-dimethylphenyl)methane, 1,3-bis(4-cyanylphenyl-1-(1-methylethylidene))benzene, bis(4-c-cyanophenyl)sulfide Ether, dicyclopentadiene type cyanate, phenol novolac type cyanate, bis(4-cyanylphenyl) ether, 1,1,1-cis (4-c-cyanophenyl)ethane , ginseng (4-cyanylphenyl) phosphite, bis(4-c-cyanophenyl)anthracene, 2,2-bis(4-cyanylphenyl)propane, 1,3-, 1, 4-, 1,6-, 1,8-, 2,6- or 2,7-dicyanatophthalene, 1,3,6-tricyanatophthalene, 4,4-dicyanate biphenyl And polyphenols such as phenol novolak type, cresol novolac type, and dicyclopentadiene type Any one or more of the cyanate resins obtained by the reaction of a cyanate resin obtained by a reaction with a cyanogen halide, a naphthol alkylene type polyheptaphenol, and a cyanogen halide. Among these, the phenol novolak type cyanate resin is excellent in flame retardancy and low thermal expansion property, and 2,2-bis(4-cyanylphenyl) isopropylidene and dicyclopentadiene type cyanic acid. The ester resin is excellent in control of crosslinking density and moisture resistance reliability. From the viewpoint of low thermal expansion properties, a phenol novolac type cyanate resin is particularly preferred. Further, one or two or more kinds of other cyanate resins may be further used in combination, and are not particularly limited.

上述氰酸酯樹脂可單獨使用,亦可併用重量平均分子量相異的氰酸酯樹脂,或亦可併用上述氰酸酯樹脂與其預聚物。 The cyanate resin may be used singly or as a cyanate resin having a different weight average molecular weight, or a combination of the above cyanate resin and its prepolymer.

藉由使用此種氰酸酯樹脂,則可有效地發揮耐熱性及難燃性。 By using such a cyanate resin, heat resistance and flame retardancy can be effectively exhibited.

另外,上述硬化性樹脂亦可併用2種以上。例如在使用上述環氧樹脂作為硬化性樹脂時,為了更加提升難燃性,可併用上述氰酸酯樹脂,又,為了提升耐熱性,可併用上述順丁烯二醯亞胺化合物。再者,在使用上述氰酸酯樹脂作為硬化性樹脂時,為了更加提升耐熱性或難燃性等,可併用上述環氧樹脂。 Further, the curable resin may be used in combination of two or more kinds. For example, when the epoxy resin is used as the curable resin, the cyanate resin may be used in combination in order to further improve the flame retardancy, and the maleimide compound may be used in combination in order to improve heat resistance. In addition, when the cyanate resin is used as the curable resin, the above epoxy resin may be used in combination in order to further improve heat resistance, flame retardancy, and the like.

硬化性樹脂的含量並無特別限定,較佳為樹脂組成物整體的5~70質量%,更佳10~50質量%。若硬化性樹脂的含量未滿上述下限值,則視硬化性樹脂的種類等,有樹脂組成物之清漆黏度過低、難以形成預浸體1的情形。另一方面,若 硬化性樹脂之含量超過上述上限值,則因其他成分的量過少,故視硬化性樹脂的種類等而有預浸體1之機械強度降低的情形。 The content of the curable resin is not particularly limited, but is preferably 5 to 70% by mass, and more preferably 10 to 50% by mass based on the entire resin composition. When the content of the curable resin is less than the above-described lower limit, the varnish viscosity of the resin composition is too low, and it is difficult to form the prepreg 1 depending on the type of the curable resin. On the other hand, if When the content of the curable resin is more than the above-mentioned upper limit, the amount of the other components is too small, and the mechanical strength of the prepreg 1 may be lowered depending on the type of the curable resin or the like.

另外,樹脂組成物較佳係含有無機填充材。藉此,即使將預浸體1薄型化(例如厚度35μm以下),仍可得到機械強度優越的基板10。再者,亦可提升基板10的低熱膨脹化。 Further, the resin composition preferably contains an inorganic filler. Thereby, even if the prepreg 1 is made thin (for example, the thickness is 35 μm or less), the substrate 10 excellent in mechanical strength can be obtained. Furthermore, the low thermal expansion of the substrate 10 can also be improved.

作為無機填充材,可舉例如滑石、氧化鋁、玻璃、熔融二氧化矽般之二氧化矽、雲母、氫氧化氫、氫氧化鎂等。又,視無機填充材的使用目的,適當選擇破碎狀、球狀者。此等之中,由低熱膨脹性優越的觀點而言,無機填充材較佳為二氧化矽,更佳為熔融二氧化矽(尤其是球狀熔融二氧化矽)。 Examples of the inorganic filler include talc, alumina, glass, cerium oxide such as molten cerium oxide, mica, hydrogen hydroxide, and magnesium hydroxide. Moreover, depending on the purpose of use of the inorganic filler, a broken shape or a spherical shape is appropriately selected. Among these, the inorganic filler is preferably cerium oxide, and more preferably molten cerium oxide (especially spherical molten cerium oxide) from the viewpoint of superior low thermal expansion property.

另外,樹脂層3、3A、4、4A係除了上述說明的成分之外,在不妨礙本發明效果的範圍內,視需要亦可調配其他成分。作為其他成分,可舉例如Orben、Benton等之增黏劑,聚矽氧系、氟系、高分子系之消泡劑或均平劑、偶合劑等之密黏性賦予劑、難燃劑、酞菁‧藍、酞菁‧綠、碘‧綠、雙偶氮黃、碳黑、蒽醌類等之著色劑等。 Further, the resin layers 3, 3A, 4, and 4A may be blended with other components as needed, in addition to the components described above, without departing from the effects of the present invention. Examples of other components include a tackifier such as Orben and Benton, a polyoxymethylene-based, a fluorine-based, a polymer-based antifoaming agent, a leveling agent, a coupling agent, and the like, and a flame retardant and a flame retardant. Coloring agents such as phthalocyanine, blue, phthalocyanine, green, iodine, green, bisazo yellow, carbon black, and hydrazine.

<積層片製造裝置(積層片之製造方法)> <Laminar sheet manufacturing apparatus (manufacturing method of laminated sheets)>

接著,針對積層片40、40A之製造中所使用的積層片製造裝置30,參照圖1~圖7、圖11、12進行說明。 Next, the laminated sheet manufacturing apparatus 30 used in the manufacture of the laminated sheets 40 and 40A will be described with reference to FIGS. 1 to 7, 11 and 12.

如圖1~圖3所示,積層片製造裝置30係具備:圖1所示之壓黏裝置30A;與配置於積層片搬送方向之較該壓黏裝置 30A更下游側的加熱裝置30B(參照圖2)。 As shown in FIGS. 1 to 3, the laminated sheet manufacturing apparatus 30 includes the pressure bonding apparatus 30A shown in FIG. 1 and the pressure bonding apparatus disposed in the conveying direction of the laminated sheet. 30A is a further downstream heating device 30B (see Fig. 2).

壓黏裝置30A係具備:殼體6;收納於殼體6內之第1輥71a、71b、第2輥(供給用輥)72a、72b及第3輥73a、73b;對殼體6內進行減壓的減壓手段8。 The pressure-adhesive device 30A includes a casing 6 , first rollers 71 a and 71 b housed in the casing 6 , second rollers (supply rollers) 72 a and 72 b and third rollers 73 a and 73 b , and the inside of the casing 6 . Decompression means 8 under reduced pressure.

加熱裝置30B係具備將樹脂層3、4(3A、4A)加熱,使各樹脂層3、4(3A、4A)之硬化進展的硬化爐9。以下說明各部構成。 The heating device 30B includes a curing furnace 9 that heats the resin layers 3 and 4 (3A, 4A) to progress the hardening of the respective resin layers 3 and 4 (3A, 4A). The configuration of each unit will be described below.

首先,說明壓黏裝置30A。該壓黏裝置30A係使樹脂層3(3A)壓黏於纖維基材2之一面側、並使樹脂層4(4A)壓黏於纖維基材2之另一面側的裝置。更具體而言,壓黏裝置30A係於纖維基材2之表背面壓黏構樹脂層3(3A)、樹脂層4(4A),且使樹脂層3(3A)、樹脂層4(4A)含浸於纖維基材2中。 First, the pressure bonding device 30A will be described. In the pressure-bonding device 30A, the resin layer 3 (3A) is pressure-bonded to one surface side of the fiber base material 2, and the resin layer 4 (4A) is press-bonded to the other surface side of the fiber base material 2. More specifically, the pressure-bonding device 30A is bonded to the front and back pressure-bonding resin layer 3 (3A) of the fiber base material 2, the resin layer 4 (4A), and the resin layer 3 (3A) and the resin layer 4 (4A). Immersed in the fibrous substrate 2.

如圖4所示,殼體6係具有隔著間隔而彼此相對向配置之一對壁部61的例如呈箱狀者。作為壁部61之構成材料並無特別限定,可舉例如鐵、不銹鋼、鋁等之各種金屬或含有此等的合金。 As shown in FIG. 4, the casing 6 has, for example, a box shape in which one pair of wall portions 61 are disposed to face each other with a space therebetween. The constituent material of the wall portion 61 is not particularly limited, and examples thereof include various metals such as iron, stainless steel, and aluminum, or alloys containing the same.

於殼體6之2個壁部61間,分別架設著第1輥71a及71b、第2輥72a與72b、第3輥73a與73b。此等輥係彼此平行配置。此等輥係例如經由配置了多數齒輪之齒輪機構(未圖示)而與馬達(未圖示)連結。而且,若該馬達作動,則其動力經由齒輪機構而傳達,使各輥分別旋轉。又,此等輥除了粗 度相異之外,其餘為相同構成,依同樣構造被支撐於壁部61。以下以第1輥71a之構成為代表進行說明。 The first rolls 71a and 71b, the second rolls 72a and 72b, and the third rolls 73a and 73b are placed between the two wall portions 61 of the casing 6. These rolls are arranged parallel to each other. These rollers are coupled to a motor (not shown) via, for example, a gear mechanism (not shown) in which a large number of gears are disposed. Further, when the motor is actuated, the power is transmitted via the gear mechanism, and the respective rollers are rotated. Again, these rolls are not only thick The other components have the same configuration and are supported by the wall portion 61 in the same configuration. Hereinafter, the configuration of the first roller 71a will be described as a representative.

如圖4所示,第1輥71a之外形形狀為圓柱狀,由位於其長度方向之中間部的本體部74、與分別位於本體部74之兩端側的軸75所構成。各軸75之外徑係分別較本體部74之外徑更縮小。 As shown in FIG. 4, the first roller 71a has a cylindrical outer shape, and is composed of a main body portion 74 located at an intermediate portion in the longitudinal direction thereof and a shaft 75 located at both end sides of the main body portion 74. The outer diameter of each of the shafts 75 is smaller than the outer diameter of the body portion 74, respectively.

該第1輥71a係使各軸75分別插入至設置在壁部61的軸承(承環)76,藉該軸承76可旋轉地被支撐著。 In the first roller 71a, each of the shafts 75 is inserted into a bearing (ring) 76 provided in the wall portion 61, and the bearing 76 is rotatably supported.

尚且,第1輥71a雖於圖1、圖4所示構成中為實心體,但並不限定於此,例如亦可為中空體。 Further, the first roller 71a is a solid body in the configuration shown in Figs. 1 and 4, but is not limited thereto, and may be, for example, a hollow body.

另外,作為第1輥71a之構成材料並無特別限定,可使用例如壁部61之構成材料所列舉的材料。此時,於第1輥71a之本體部74之外周面741,亦可實施防止外周面741磨損的處理。作為此處理,可舉例如於外周面741形成DLC(類鑽碳)被膜的方法。 In addition, the constituent material of the first roller 71a is not particularly limited, and for example, a material exemplified as the constituent material of the wall portion 61 can be used. At this time, the outer peripheral surface 741 of the main portion 74 of the first roller 71a may be subjected to a process of preventing the outer peripheral surface 741 from being worn. As such a treatment, for example, a method of forming a DLC (Drilling Carbon) film on the outer circumferential surface 741 can be mentioned.

第1輥71a與第1輥71b係於水平方向上彼此平行配置,使本體部74之外周面741彼此相抵接(壓接)(參照圖4)。然後,當第1輥71a與第1輥71b旋轉時,於此等之間可將纖維基材2由圖1中之左側搬送至右側。 The first roller 71a and the first roller 71b are arranged in parallel with each other in the horizontal direction, and the outer peripheral surface 741 of the main body portion 74 is in contact with each other (pressure-bonded) (see FIG. 4). Then, when the first roller 71a and the first roller 71b are rotated, the fiber base material 2 can be conveyed to the right side from the left side in FIG.

第2輥72a與第2輥72b係配置於與第1輥71a、71b相異的位置,亦即相對於第1輥71a、71b朝纖維基材2之搬送方向前方(下游側)。又,第2輥72a與第2輥72b係於水 平方向上彼此平行配置,使本體部74之外周面741彼此相抵接(壓接)。然後,當第2輥72a與第2輥72b旋轉時,於此等之間可將纖維基材2、由未硬化或半硬化(任一狀態下,均為半固形狀態或液狀狀態)之樹脂組成物所構成的第1樹脂層3(3A)、由未硬化或半硬化(任一狀態下,均為半固形狀態或液狀狀態)之樹脂組成物所構成的第2樹脂層4(4A)依被挾持狀態一概地通過。此時,於纖維基材2使第1樹脂層3(3A)與第2樹脂層4(4A)分別壓黏(接合)(參照圖1)。然後,將該接合體、亦即未硬化或半硬化之積層片40朝向硬化爐9(腔室91)送出。 The second roller 72a and the second roller 72b are disposed at positions different from the first rollers 71a and 71b, that is, forward (downstream) with respect to the first roller 71a and 71b in the conveyance direction of the fiber base material 2. Further, the second roller 72a and the second roller 72b are attached to water. The square faces are arranged in parallel with each other such that the outer peripheral faces 741 of the body portions 74 abut each other (crimped). Then, when the second roller 72a and the second roller 72b are rotated, the fiber base material 2 can be uncured or semi-hardened (in either state, a semi-solid state or a liquid state). The first resin layer 3 (3A) composed of the resin composition, and the second resin layer 4 composed of a resin composition which is not cured or semi-cured (all in a semi-solid state or a liquid state in any state) 4A) Passed through the state of being held. At this time, the first resin layer 3 (3A) and the second resin layer 4 (4A) are respectively adhered (joined) to the fiber base material 2 (see FIG. 1). Then, the joined body, that is, the unhardened or semi-hardened laminated sheet 40 is sent toward the hardening furnace 9 (chamber 91).

第3輥73a係配置於第1輥71a、第2輥72a之間,第3輥73b係配置於第1輥71b與第2輥72b之間。又,第3輥73a與第3輥73b係彼此於上下方向(鉛垂方向)上離間,於水平方向上平行相對向配置。然後,當第3輥73a旋轉時,可由第1片材5a之第1樹脂層3剝離(捲取)保護片51(參照圖1)。與此同樣地,若第3輥73b旋轉,則可由第2片材5b之第2樹脂層4剝離保護片51(參照圖1)。 The third roller 73a is disposed between the first roller 71a and the second roller 72a, and the third roller 73b is disposed between the first roller 71b and the second roller 72b. Further, the third roller 73a and the third roller 73b are spaced apart from each other in the vertical direction (vertical direction), and are disposed to face each other in the horizontal direction. Then, when the third roller 73a is rotated, the protective sheet 51 can be peeled off (rolled up) from the first resin layer 3 of the first sheet 5a (see FIG. 1). In the same manner, when the third roller 73b is rotated, the protective sheet 51 can be peeled off from the second resin layer 4 of the second sheet 5b (see FIG. 1).

再者,第3輥73a係使其本體部74之外周面741分別與第1輥71a之本體部74之外周面741、及第2輥72a之本體部74之外周面741抵接。另一方面,第3輥73b係使其本體部74之外周面741分別與第1輥71b之本體部74之外周面741、及第2輥72b之本體部74之外周面741抵接。 藉由此種配置,於積層片製造裝置30中形成由殼體6之各壁部61、第1輥71a及71b、第2輥72a及72b、第3輥73a及73b所包圍的空間70。空間70係藉減壓手段8的作動而被減壓(參照圖5)。 In the third roller 73a, the outer peripheral surface 741 of the main body portion 74 is in contact with the outer peripheral surface 741 of the main portion 74 of the first roller 71a and the outer peripheral surface 741 of the main portion 74 of the second roller 72a. On the other hand, in the third roller 73b, the outer peripheral surface 741 of the main body portion 74 is in contact with the outer peripheral surface 741 of the main portion 74 of the first roller 71b and the outer peripheral surface 741 of the main portion 74 of the second roller 72b. With this arrangement, the space 70 surrounded by the wall portions 61 of the casing 6, the first rollers 71a and 71b, the second rollers 72a and 72b, and the third rollers 73a and 73b is formed in the laminated sheet manufacturing apparatus 30. The space 70 is decompressed by the action of the decompression means 8 (see Fig. 5).

如圖4所示,第1輥71a及71b(關於第2輥72a及72b、第3輥73a及73b亦相同)之各別的本體部74之兩端、與各壁部61之間,介存著密封材62。各密封材62分別由環狀之彈性體所構成,依壓縮狀態插入至形成於壁部61的環狀凹部612中。藉此,可確實維持空間70的氣密性,而在藉減壓手段8對空間70進行減壓時,使該減壓迅速且確實地進行。 As shown in Fig. 4, the ends of the respective main body portions 74 of the first rolls 71a and 71b (the second rolls 72a and 72b and the third rolls 73a and 73b are also the same) and the respective wall portions 61 are interposed. A sealing material 62 is stored. Each of the seal members 62 is composed of an annular elastic body and is inserted into the annular recessed portion 612 formed in the wall portion 61 in a compressed state. Thereby, the airtightness of the space 70 can be surely maintained, and when the space 70 is depressurized by the decompression means 8, the decompression is quickly and surely performed.

作為密封材62之構成材料並無特別限定,可舉例如天然橡膠、異戊二烯、丁二烯橡膠、苯乙烯-丁二烯橡膠、腈橡膠、氯平橡膠、丁基橡膠、丙烯酸橡膠、乙烯-丙烯橡膠、表氯醇橡膠、胺基甲酸乙酯橡膠、聚矽氧橡膠、氟橡膠般之各種橡膠材料(尤其是經加硫處理者),或苯乙烯系、聚烯烴系、聚氯乙烯系、聚胺基甲酸酯系、聚酯系、聚醯胺系、聚丁二烯系、反式聚異戊二烯系、氟橡膠系、氯化聚乙烯系等之各種熱可塑性彈性體,可使用此等之中之一種或混合使用2種以上。 The constituent material of the sealing material 62 is not particularly limited, and examples thereof include natural rubber, isoprene, butadiene rubber, styrene-butadiene rubber, nitrile rubber, chloroprene rubber, butyl rubber, and acrylic rubber. Ethylene-propylene rubber, epichlorohydrin rubber, urethane rubber, polyoxyethylene rubber, fluororubber-like rubber materials (especially those subjected to sulfurization), or styrene, polyolefin, polychlorinated Various thermoplastic elastomers such as vinyl, polyurethane, polyester, polyamine, polybutadiene, trans-polyisoprene, fluororubber, and chlorinated polyethylene One type of these may be used or two or more types may be used in combination.

如圖1所示,第1輥71a及71b、第2輥72a及72b、第3輥73a及73b係彼此本體部74之外徑(大小)相異。本實施 形態中,其大小關係為(第3輥)<(第1輥)<第2輥)。又,第1輥71a及71b、第2輥72a及72b、第3輥73a及73b之各輥尺寸雖為任意,但較佳係依例如在使具有可撓性之片材被沿輥時於該片材上不發生皺摺之程度,儘可能地小。具體而言,直徑較佳為75~300mm、更佳100~200mm。 As shown in FIG. 1, the first rolls 71a and 71b, the second rolls 72a and 72b, and the third rolls 73a and 73b are different in outer diameter (size) of the main body portion 74. This implementation In the form, the size relationship is (third roll) < (first roll) < second roll). Further, the size of each of the first rolls 71a and 71b, the second rolls 72a and 72b, and the third rolls 73a and 73b is arbitrary, but it is preferable, for example, when the flexible sheet is placed along the roll. The extent to which wrinkles do not occur on the sheet is as small as possible. Specifically, the diameter is preferably 75 to 300 mm, more preferably 100 to 200 mm.

如圖5所示般,減壓手段8係具有泵81,及使泵81與分別形成於各壁部61的開口部611連接的連接管82。 As shown in FIG. 5, the decompression means 8 has a pump 81 and a connection pipe 82 that connects the pump 81 to the opening 611 formed in each wall portion 61.

泵81係設置於殼體6外側,可應用例如真空泵。 The pump 81 is disposed outside the casing 6, and for example, a vacuum pump can be applied.

各連接管82分別為例如由不銹鋼等之金屬材料所構成的硬質管。 Each of the connecting pipes 82 is a rigid pipe made of, for example, a metal material such as stainless steel.

各開口部611分別朝空間70開口。又,圖5所示之構成中,於雙方之壁部61分別形成有開口部611,但並不限定於此,例如亦可僅於一方壁部61上形成開口部611。 Each of the openings 611 is open to the space 70. Further, in the configuration shown in FIG. 5, the opening portion 611 is formed in each of the wall portions 61. However, the opening portion 611 is not limited thereto. For example, the opening portion 611 may be formed only on one of the wall portions 61.

而且,藉由使泵81作動,可由各開口部611吸引空間70內之空氣G,藉此可使空間70減壓。又,藉此,產生使輥彼此接近的力而進一步予以壓接,因此可更確實地維持空間70的氣密性。 Further, by actuating the pump 81, the air G in the space 70 can be sucked by the respective opening portions 611, whereby the space 70 can be decompressed. Further, by this, the force that brings the rollers closer to each other is further pressed, so that the airtightness of the space 70 can be more reliably maintained.

在相對於第2輥72a及72b朝積層片40之搬送方向前方(搬送方向下游側),如圖2所示,配置有加熱裝置30B的硬化爐9。硬化爐9係使樹脂層3、4、(3A、4A)硬化進展的裝置。 The curing furnace 9 of the heating device 30B is disposed as shown in FIG. 2 in front of the second roller 72a and 72b in the conveying direction of the laminated sheet 40 (downstream side in the conveying direction). The hardening furnace 9 is a device which hardens the resin layers 3, 4 and (3A, 4A).

於此,說明加熱裝置30B。 Here, the heating device 30B will be described.

首先針對加熱裝置30B之概要進行說明。 First, the outline of the heating device 30B will be described.

加熱裝置30B係將具備屬於具有可撓性之帶狀之無機織布或有機纖維基材的基材(纖維基材2)、與供給至該基材(纖維基材2)之單面或兩面之樹脂組成物(樹脂層3、4(3A、4A)的積層片(藉加熱裝置30B進行加熱前的積層片40(40A)進行加熱,以製造經加熱之積層片40(40A)的積層片製造裝置。 The heating device 30B is provided with a base material (fiber base material 2) belonging to a flexible belt-shaped inorganic woven fabric or an organic fiber base material, and one or both sides supplied to the base material (fiber base material 2). The resin composition (the laminated sheets of the resin layers 3 and 4 (3A, 4A) (the laminated sheet 40 (40A) before heating by the heating device 30B is heated to produce a laminated sheet of the heated laminated sheet 40 (40A)). Manufacturing equipment.

該加熱裝置30B係具備:上述積層片所通過之腔室91;將腔室91內加熱,以對上述積層片進行加熱的加熱手段92;與使上述積層片於上述腔室91內之通過路徑長度為可變的路徑長可變手段。 The heating device 30B includes a chamber 91 through which the laminated sheet passes, a heating means 92 for heating the inside of the chamber 91 to heat the laminated sheet, and a passage path for the laminated sheet in the chamber 91. A variable path length variable means.

加熱裝置30B係將長形之積層片40(40A)進行加熱者,於30B連續地搬送積層片40(40A)。 The heating device 30B heats the elongated laminated sheet 40 (40A), and continuously transports the laminated sheet 40 (40A) at 30B.

如圖2、圖3所示,硬化爐9具有:腔室(爐本體)91;作為將腔室91內進行加熱之加熱手段的加熱器92;位於腔室91內之第1輥93a、93b、第2輥94a、94b、第3輥95。輥93a、94a、94b、95係用於將積層片40(40A)於腔室91內進行搬送的搬送手段。 As shown in Figs. 2 and 3, the hardening furnace 9 has a chamber (furnace body) 91, a heater 92 as a heating means for heating the chamber 91, and a first roller 93a, 93b located in the chamber 91. The second rolls 94a and 94b and the third roll 95. The rollers 93a, 94a, 94b, and 95 are conveying means for conveying the laminated sheet 40 (40A) in the chamber 91.

腔室91係呈長方形或正方形之箱狀,可使經供給了樹脂層3、4、(3A、4A)的纖維基材2、亦即積層片40(40A)通過其內部空間96。 The chamber 91 has a rectangular or square box shape, and allows the fiber substrate 2, that is, the laminated sheet 40 (40A) to which the resin layers 3, 4, (3A, 4A) are supplied, to pass through the internal space 96.

於腔室91之彼此相對向的一對壁部911、912,分別形成有各一個的積層片40(纖維基材2)所進入的入口913、與積 層片40(40A)出去的出口914。藉由使入口913與出口914經由內部空間96而位於彼此相反側,則在例如由積層片40(40A)得到預浸體1時而設置將積層片40(40A)切斷的切斷裝置(未圖示)的情唬,可將切斷裝置設置於積層片40(40A)之搬送方向前方、亦即積層片40(40A)之流路的下游側,而可容易進行裝置的配置。 In the pair of wall portions 911 and 912 opposed to each other in the chamber 91, an inlet 913 into which the laminated sheet 40 (fiber substrate 2) of each of the layers is formed is formed. The exit 40 of the layer 40 (40A) exits. By placing the inlet 913 and the outlet 914 on the opposite sides of each other via the internal space 96, a cutting device for cutting the laminated sheet 40 (40A) is provided when the prepreg 1 is obtained, for example, by the laminated sheet 40 (40A) ( In the case of not shown, the cutting device can be disposed in front of the conveying direction of the laminated sheet 40 (40A), that is, on the downstream side of the flow path of the laminated sheet 40 (40A), and the arrangement of the apparatus can be easily performed.

腔室91之入口913的高度位置(y軸方向之位置),係與出口914之高度位置(y軸方向之位置)相異,於本實施形態中,入口913係位於出口914之更靠y軸正方向處。 The height position (position in the y-axis direction) of the inlet 913 of the chamber 91 is different from the height position (position in the y-axis direction) of the outlet 914. In the present embodiment, the inlet 913 is located at the outlet 914. The positive direction of the axis.

腔室91之構成材料並無特別限定,可舉例如鐵、不銹鋼、鋁等之各種金屬、或含有此等的合金。 The constituent material of the chamber 91 is not particularly limited, and examples thereof include various metals such as iron, stainless steel, and aluminum, or alloys containing the same.

腔室91的內部配置有複數之加熱器92。加熱器92係對樹脂層3、4(3A、4A)進行加熱的加熱手段(熱板),本實施形態中,係藉由此加熱,使樹脂層3、4(3A、4A)分別硬化。 A plurality of heaters 92 are disposed inside the chamber 91. The heater 92 is a heating means (hot plate) for heating the resin layers 3, 4 (3A, 4A). In the present embodiment, the resin layers 3, 4 (3A, 4A) are respectively cured by heating.

圖2中,各加熱器92係沿著積層片40之搬送方向延伸存在。 In FIG. 2, each heater 92 extends along the conveying direction of the laminated sheet 40.

尚且圖2中雖表示了加熱器92,但在圖3中考慮到容易瞭解度,而省略了加熱器92。 Although the heater 92 is shown in FIG. 2, the ease of understanding is considered in FIG. 3, and the heater 92 is omitted.

尚且,加熱器92係由例如鎳鉻線等之電熱線所構成者。 Further, the heater 92 is composed of a heating wire such as a nickel-chromium wire.

另外,由加熱器92所進行之腔室91內的加熱溫度,較佳為例如100~350℃,更佳150~300℃。 Further, the heating temperature in the chamber 91 by the heater 92 is preferably, for example, 100 to 350 ° C, more preferably 150 to 300 ° C.

如圖2、圖3所示,加熱裝置30B係具備配置於腔室91 內的第1輥93a、93b、第2輥94a、94b、第3輥95。此等輥係設置成可旋轉,藉由此等輥進行旋轉,可於腔室91內搬送積層片40(40A)。此等輥係抵接積層片40(40A)的搬送輥。各輥分別配置成其長度方向相對於積層片40(40A)之搬送方向呈正交。 As shown in FIGS. 2 and 3, the heating device 30B is disposed in the chamber 91. The first rollers 93a and 93b, the second rollers 94a and 94b, and the third roller 95. These rolls are provided so as to be rotatable, and by rotating the rolls, the laminated sheets 40 (40A) can be conveyed in the chamber 91. These rollers are in contact with the conveying rollers of the laminated sheet 40 (40A). Each of the rolls is disposed such that its longitudinal direction is orthogonal to the conveying direction of the laminated sheet 40 (40A).

第1輥93a、93b、第2輥94a、94b、第3輥95係彼此於y軸方向上的位置相異。硬化爐9中,第1輥93a、93b係配置於最y軸正側(最高位置),第3輥95係配置於最y軸負側(最低位置),第2輥94a、94b係配置於第1輥93a、93b與第3輥95之間。又,第1輥93a與第1輥93b亦配置成彼此於y軸方向上的位置相異,第1輥93a係位於第1輥93b之更靠y軸正側。與此相同地,第2輥94a與第2輥94b亦配置成彼此於y軸方向上位置相異,第2輥94a係位於第2輥94b之更靠y軸正側。 The positions of the first rollers 93a and 93b, the second rollers 94a and 94b, and the third roller 95 are different from each other in the y-axis direction. In the hardening furnace 9, the first rolls 93a and 93b are disposed on the most y-axis positive side (the highest position), the third roll 95 is disposed on the most y-axis negative side (the lowest position), and the second rolls 94a and 94b are disposed on the first roll 93a and 93b. The first roller 93a, 93b is between the third roller 95. Further, the first roller 93a and the first roller 93b are also arranged to be different from each other in the y-axis direction, and the first roller 93a is located on the positive side of the first roller 93b on the y-axis. Similarly, the second roller 94a and the second roller 94b are also disposed to be different in position in the y-axis direction, and the second roller 94a is located on the positive side of the second roller 94b on the y-axis.

而且,積層片40(40A)係依序架掛於第1輥93a、93b、第2輥94a、94b、第3輥95,藉由各輥旋轉的被搬送。 Further, the laminated sheet 40 (40A) is sequentially attached to the first rolls 93a and 93b, the second rolls 94a and 94b, and the third roll 95, and is conveyed by the rotation of the respective rolls.

輥93a、94a、95係抵接積層片40(40A)之一面側,輥93b、94b係抵接於積層片40(40A)的另一面側。 The rollers 93a, 94a, and 95 are in contact with one surface side of the laminated sheet 40 (40A), and the rollers 93b and 94b are in contact with the other surface side of the laminated sheet 40 (40A).

尚且,此等輥93a、93b、94a、94b、95由於為同一構成,故以下以第1輥93a之構成為代表進行說明。 In addition, since these rolls 93a, 93b, 94a, 94b, and 95 have the same structure, the structure of the 1st roll 93a is demonstrated below.

如圖7所示,第1輥93a之外形形狀呈圓柱狀,由位於其長度方向之中間部的本體部97、與分別位於本體部97兩端 側之軸部98所構成,各軸98係分別較本體部97之外徑更縮小。 As shown in Fig. 7, the outer shape of the first roller 93a is cylindrical, and the main body portion 97 located at the intermediate portion in the longitudinal direction thereof is located at both ends of the main body portion 97. The side shaft portion 98 is formed, and each of the shafts 98 is smaller than the outer diameter of the main body portion 97.

尚且,第1輥93a之本體部97,係於圖2、圖3所示之構成中為實心體,但並不限定於此,例如亦可為中空體。 Further, the main body portion 97 of the first roller 93a is a solid body in the configuration shown in Figs. 2 and 3, but is not limited thereto, and may be, for example, a hollow body.

另外,本體部97係抵接於積層片40(40A)的部分。作為本體部97的構成材料並無特別限定,可使用例如腔室91之構成材料所列舉的材料。此時,於第1輥93a之本體部97之外周面971,亦可實施減低與積層片40(40A)間之摩擦的摩擦減低處理。藉此,可防止外周面971的磨損。作為此摩擦減低處理,可舉例如於外周面971形成氟、DLC(類鑽碳)等之被膜的方法。 Further, the main body portion 97 abuts against a portion of the laminated sheet 40 (40A). The constituent material of the main body portion 97 is not particularly limited, and for example, a material exemplified as the constituent material of the chamber 91 can be used. At this time, the outer peripheral surface 971 of the main portion 97 of the first roller 93a may be subjected to a friction reducing treatment for reducing the friction with the laminated sheet 40 (40A). Thereby, the abrasion of the outer peripheral surface 971 can be prevented. As the friction reducing treatment, for example, a method of forming a film such as fluorine or DLC (Drilling Carbon) on the outer circumferential surface 971 can be mentioned.

各輥93b、94a、94b、95亦具備與輥93a相同的本體部97與軸部98。 Each of the rollers 93b, 94a, 94b, 95 also has a main body portion 97 and a shaft portion 98 which are the same as the roller 93a.

於此,上述之輥93a、93b、94a、94b、95中,輥93a、94a係於腔室91內可移動。另一方面,輥93b、94b、95係於腔室內不移動,而相對於腔室91的位置固定。 Here, among the rollers 93a, 93b, 94a, 94b, and 95 described above, the rollers 93a and 94a are movable in the chamber 91. On the other hand, the rollers 93b, 94b, 95 are not moved in the chamber, but are fixed relative to the position of the chamber 91.

輥93a係朝輥93b將積層片40(40A)於鉛垂方向(y軸方向)上進行搬送。而且,如圖2、圖3、圖11所示,第1輥93a係藉由形成於腔室91之壁部917、918的一字狀的凸輪溝(引導溝)915而對該腔室91於x軸方向(水平方向)上可移動地支撐著。第1輥93b係其相對於腔室91的位置固定。然後,藉由第1輥93a進行移動,則可使第1輥93a與第1輥93b 沿著x軸彼此接近‧離間,而可變更軸間距離。 The roller 93a conveys the laminated sheet 40 (40A) in the vertical direction (y-axis direction) toward the roller 93b. Further, as shown in FIGS. 2, 3, and 11, the first roller 93a is the chamber 91 formed by the in-line cam groove (guide groove) 915 formed in the wall portions 917 and 918 of the chamber 91. It is movably supported in the x-axis direction (horizontal direction). The first roller 93b is fixed to the position of the chamber 91. Then, by moving the first roller 93a, the first roller 93a and the first roller 93b can be used. The distance between the axes can be changed by approaching each other along the x-axis.

本實施形態中,係對在積層片40之搬送方向下游側之端部連接了積層片40A之搬送方向上游側之端部的一連串的長形之積層片進行加熱處理,但藉由使輥93a在屬於與輥93a上之長形之上述積層片之搬送方向(於此係指由輥93a進行之積層片之搬送方向、亦即y軸方向)呈交叉(正交)、且與長形之上述積層片之寬度方向呈正交之方向的x軸方向上移動,則可使輥93a及輥93b間之長型之上述積層片之x軸方向(輥93a之移動方向)的搬送距離變更。 In the present embodiment, a series of elongated laminated sheets in which the end portion of the layered sheet 40A on the upstream side in the conveying direction is connected to the end portion on the downstream side in the conveying direction of the laminated sheet 40 is heat-treated, but the roller 93a is formed by the roller 93a. In the transport direction of the above-mentioned laminated sheet belonging to the elongated shape on the roller 93a (herein, the transport direction of the laminated sheet by the roller 93a, that is, the y-axis direction) is crossed (orthogonal) and elongated When the width direction of the laminated sheet moves in the x-axis direction orthogonal to the width direction, the transport distance of the elongated laminated sheet between the roller 93a and the roller 93b in the x-axis direction (the moving direction of the roller 93a) can be changed.

尚且,第1輥93a之各軸部98係分別插入至形成於腔室91之壁部917、918的各凸輪溝915中,各凸輪溝915係貫通腔室91之各壁部917、918的貫通孔。 Further, each of the shaft portions 98 of the first roller 93a is inserted into each of the cam grooves 915 formed in the wall portions 917 and 918 of the chamber 91, and each of the cam grooves 915 penetrates the wall portions 917 and 918 of the chamber 91. Through hole.

另外,第2輥94a係朝輥94b將積層片40(40A)於鉛垂方向上進行搬送。而且,輥94a係藉由形成於腔室91之壁部917、918的一字狀的凸輪溝916而對該腔室91於x軸方向上可移動地支撐著。第2輥94b係其相對於腔室91的位置固定。然後,藉由第2輥94a進行移動,則可使第2輥94a與第2輥94b彼此接近‧離間,而可變更軸間距離。換言之,藉由使輥94a在屬於與輥94a上之長形之上述積層片之搬送方向(由輥94a進行之積層片之搬送方向,於此為y軸方向)呈交叉(正交)、且與長形之上述積層片之寬度方向呈正交之方向的x軸方向上移動,則可使輥94a及輥94b間之長型之 上述積層片之x軸方向(輥94a之移動方向)的搬送距離變更。 Further, the second roller 94a conveys the laminated sheet 40 (40A) in the vertical direction toward the roller 94b. Further, the roller 94a is movably supported in the x-axis direction by the in-line cam groove 916 formed in the wall portions 917 and 918 of the chamber 91. The second roller 94b is fixed to the position of the chamber 91. Then, by moving the second roller 94a, the second roller 94a and the second roller 94b can be moved closer to each other, and the distance between the axes can be changed. In other words, the roller 94a is crossed (orthogonal) in the conveyance direction of the above-mentioned laminated sheet belonging to the elongated shape of the roller 94a (the conveyance direction of the laminated sheet by the roller 94a, in this case, the y-axis direction), and When moving in the x-axis direction orthogonal to the width direction of the elongated laminated sheet, the length between the roller 94a and the roller 94b can be made long. The conveyance distance of the laminated sheet in the x-axis direction (the moving direction of the roller 94a) is changed.

尚且,第2輥94a之各軸部98係分別插入至形成於腔室91之壁部917、918的各凸輪溝916中,各凸輪溝916係貫通腔室91之各壁部917、918的貫通孔。 Further, each of the shaft portions 98 of the second roller 94a is inserted into each of the cam grooves 917 formed in the wall portions 917 and 918 of the chamber 91, and each of the cam grooves 916 penetrates through the wall portions 917 and 918 of the chamber 91. Through hole.

第3輥95係與第1輥93b或第2輥94b同樣地,相對於腔室91之位置固定。其中,輥93b、94b、95係於其軸部98連接著未圖示的馬達,構成為可藉由馬達進行旋轉驅動。該馬達係如後述馬達90同樣地,可配置於腔室91外部,亦可配置於腔室91內部。在配置於腔室91外部時,輥93b、94b、95之軸部98係貫通腔室91之壁部917、918。 Similarly to the first roller 93b or the second roller 94b, the third roller 95 is fixed to the position of the chamber 91. Among them, the rollers 93b, 94b, and 95 are connected to a motor (not shown) to the shaft portion 98, and are configured to be rotationally driven by a motor. Similarly to the motor 90 to be described later, the motor may be disposed outside the chamber 91 or may be disposed inside the chamber 91. When disposed outside the chamber 91, the shaft portions 98 of the rollers 93b, 94b, 95 penetrate the wall portions 917, 918 of the chamber 91.

另外,如圖7、圖11所示般,第1輥93a可藉由屬於用於使輥93a移動之移動手段的線性滑軌道99沿著凸輪溝915滑順地進行移動。此構成於第2輥94a亦相同。 Further, as shown in FIGS. 7 and 11, the first roller 93a is slidably moved along the cam groove 915 by the linear slide rail 99 belonging to the moving means for moving the roller 93a. This configuration is also the same for the second roller 94a.

線性滑軌道99分別配置於軌道93a的各端部側。具體而言,分別配置於輥93a之一軸部98側、另一軸部98側,並分別配置於腔室91之相對向的一對壁部917、918之外側。 The linear slide rails 99 are respectively disposed on the respective end sides of the rail 93a. Specifically, they are disposed on the shaft portion 98 side and the other shaft portion 98 side of the roller 93a, respectively, and are disposed on the outer sides of the opposing pair of wall portions 917 and 918 of the chamber 91, respectively.

線性滑軌道99係由長形之一對導軌道991、與在導軌道991上移動的滑件(移動體)992所構成。導軌道991係對腔室91呈固定。於一對之導軌道991間,配置有螺旋軸993。於該螺旋軸993之端部,連接著用於使螺旋軸993旋轉驅動的馬達994。又,於螺旋軸993,螺合著設於滑件992的螺 帽995。藉螺旋軸993與螺帽995構成滾珠螺桿構造,藉由旋轉螺旋軸993,則螺帽995及滑件992於螺旋軸993上進行直線移動。 The linear slide rail 99 is composed of one of the elongated guide rails 991 and a slider (moving body) 992 that moves on the guide rails 991. The guide rail 991 is fixed to the chamber 91. A screw shaft 993 is disposed between the pair of guide rails 991. A motor 994 for rotationally driving the screw shaft 993 is connected to the end of the screw shaft 993. Further, in the screw shaft 993, the screw provided on the slider 992 is screwed Cap 995. The screw shaft 993 and the nut 995 constitute a ball screw structure, and by rotating the screw shaft 993, the nut 995 and the slider 992 linearly move on the screw shaft 993.

另外,用於使輥93a移動的1對之線性滑軌道99中,於一線性滑軌道99之滑件992上,固定著作為第1輥93a旋轉時之驅動源的馬達90。馬達90係藉由滑件992移動,而與第1輥93a一起移動。該馬達90係與第1輥93a之一軸部98連結著。而且,藉由馬達90作動,使第1輥93a確實旋轉。 Further, in the pair of linear slide rails 99 for moving the roller 93a, the motor 90 of the drive source when the first roller 93a is rotated is fixed to the slider 992 of the linear slide rail 99. The motor 90 is moved by the slider 992 to move together with the first roller 93a. The motor 90 is coupled to one of the shaft portions 98 of the first roller 93a. Further, the first roller 93a is surely rotated by the operation of the motor 90.

尚且,於另一線性滑軌道99之滑件992上,配置有可旋轉地支撐第1輥93a之軸部的軸承(省略圖示)。軸承亦藉由滑件992之移動,而與第1輥93a一起移動。 Further, a bearing (not shown) that rotatably supports the shaft portion of the first roller 93a is disposed on the slider 992 of the other linear slide rail 99. The bearing is also moved together with the first roller 93a by the movement of the slider 992.

導軌道991及螺旋軸993係與凸輪溝915平行而延伸存在。藉由驅動馬達994,則螺旋軸993旋轉,使螺帽995及滑件992於螺旋軸993上移動。隨此,輥93a之軸部98於凸輪溝915內移動,而輥93a於腔室91內移動。 The guide rail 991 and the screw shaft 993 are extended in parallel with the cam groove 915. By driving the motor 994, the screw shaft 993 is rotated to move the nut 995 and the slider 992 on the screw shaft 993. Accordingly, the shaft portion 98 of the roller 93a moves in the cam groove 915, and the roller 93a moves in the chamber 91.

第2輥94a亦可藉由屬於移動手段之線性滑軌道99而沿著凸輪溝916滑順地移動。 The second roller 94a can also smoothly move along the cam groove 916 by the linear slide rail 99 belonging to the moving means.

第2輥94a之一軸部98,係連接於線性滑軌道99上之馬達90。又,第2輥94a之另一軸部98,係插入至另一線性滑軌道99上的軸承(省略圖示)。而且,線性滑軌道99之導軌道991及螺旋軸993,係與凸輪溝916平行而延伸存在。 藉由驅動馬達994,則螺旋軸993旋轉,螺帽995及滑件992於螺旋軸993上移動。隨此,輥94a之軸部98於凸輪溝916內移動,而輥94a於腔室內移動。 One of the shaft portions 98 of the second roller 94a is connected to the motor 90 on the linear slide rail 99. Further, the other shaft portion 98 of the second roller 94a is inserted into a bearing (not shown) of the other linear slide rail 99. Further, the guide rail 991 and the screw shaft 993 of the linear slide rail 99 extend in parallel with the cam groove 916. By driving the motor 994, the screw shaft 993 is rotated, and the nut 995 and the slider 992 are moved on the screw shaft 993. Accordingly, the shaft portion 98 of the roller 94a moves within the cam groove 916, and the roller 94a moves within the chamber.

於此,本實施形態中,凸輪溝915、916係形成於腔室91的壁部917、918,並貫通壁部917、918。為了防止腔室91內部的溫度變化,如圖11、12所示,於腔室91之壁部917、918外側,係配置著分別將凸輪溝915、916封鎖的被覆構件900。圖11係由上面側觀看腔室91內部的圖,圖12係由側面側觀看腔室91的圖。 Here, in the present embodiment, the cam grooves 915 and 916 are formed in the wall portions 917 and 918 of the chamber 91 and penetrate the wall portions 917 and 918. In order to prevent a temperature change inside the chamber 91, as shown in Figs. 11 and 12, a covering member 900 that blocks the cam grooves 915 and 916 is disposed outside the wall portions 917 and 918 of the chamber 91. Fig. 11 is a view of the inside of the chamber 91 viewed from the upper side, and Fig. 12 is a view of the chamber 91 viewed from the side.

該被覆構件900係沿著凸輪溝915(916)之長度方向延伸存在,完全地被覆凸輪溝915(916)。於被覆構件900,形成有通過輥93a(94a)之軸部98的貫通孔,輥93b(94b)之軸部98,係經由凸輪溝915(916)、被覆構件900之貫通孔,連接至馬達90或軸承。被覆構件900之軸部98通過的貫通孔,係在腔室91之由壁部917(918)側觀看的側面視時,形成為與凸輪溝915(916)重疊(參照圖12)。 The covering member 900 extends in the longitudinal direction of the cam groove 915 (916) and completely covers the cam groove 915 (916). A through hole that passes through the shaft portion 98 of the roller 93a (94a) is formed in the covering member 900, and the shaft portion 98 of the roller 93b (94b) is connected to the motor via the cam groove 915 (916) and the through hole of the covering member 900. 90 or bearing. The through hole through which the shaft portion 98 of the covering member 900 passes is formed to overlap the cam groove 915 (916) when viewed from the side of the chamber 91 viewed from the side of the wall portion 917 (918) (see FIG. 12).

被覆構件900中,沿著其長度方向的端部係嵌入至設於腔室之壁部917(918)外側的軌道R中。該軌道R係沿著凸輪溝915(916)之長度方向延伸存在,被覆構件900係於軌道R上滑動。 In the covering member 900, the end portion along the longitudinal direction thereof is fitted into the rail R provided outside the wall portion 917 (918) of the chamber. The rail R extends along the longitudinal direction of the cam groove 915 (916), and the covering member 900 slides on the rail R.

藉由設置此種被覆構件900,則遮蔽凸輪溝915(916),可防止經由凸輪溝915(916)使腔室91之空氣流出至外部、或 外部空氣流入至腔室91內部的情形。藉此,可穩定地維持腔室91內部的溫度。 By providing such a covering member 900, the cam groove 915 (916) is shielded, and the air of the chamber 91 can be prevented from flowing out to the outside via the cam groove 915 (916), or The outside air flows into the inside of the chamber 91. Thereby, the temperature inside the chamber 91 can be stably maintained.

首先,如圖11(a)、圖12(a)所示,輥93a(94a)之軸部98係位於凸輪溝915(915)之一端部側。 First, as shown in Figs. 11(a) and 12(a), the shaft portion 98 of the roller 93a (94a) is located on one end side of the cam groove 915 (915).

接著,驅動馬達994時,如上述般,輥93a(94a)之軸部98於凸輪溝915(916)內移動。隨此,如圖12(b)所示,被覆構件900於軌道R上滑動。被覆構件900之長度方向的長度(x軸方向之長度)由於較凸輪溝915(916)之長度方向之長度(x軸之長度方向)長,故即使在輥93a(94a)經移動時,仍可被覆凸輪溝915(916)。 Next, when the motor 994 is driven, as described above, the shaft portion 98 of the roller 93a (94a) moves in the cam groove 915 (916). Accordingly, as shown in FIG. 12(b), the covering member 900 slides on the rail R. The length in the longitudinal direction of the covering member 900 (the length in the x-axis direction) is longer than the length in the longitudinal direction of the cam groove 915 (916) (the length direction of the x-axis), so even when the roller 93a (94a) is moved, The cam groove 915 (916) can be covered.

而且,如圖11(b)、圖12(c)所示,輥93a(94a)之軸部98係移動至凸輪溝915(916)的另一端部為止。於此狀態下,仍可藉被覆構件900被覆凸輪溝915(916)的整體。 Further, as shown in FIGS. 11(b) and 12(c), the shaft portion 98 of the roller 93a (94a) is moved to the other end portion of the cam groove 915 (916). In this state, the entire cam groove 915 (916) can be covered by the covering member 900.

於此,作為被覆構件900的材料並無特別限定,被覆構件900可由與腔室91相同的金屬等之材料構成。 Here, the material of the covering member 900 is not particularly limited, and the covering member 900 may be made of a material such as metal similar to the chamber 91.

尚且,本實施形態中,被覆構件900係設於腔室91之壁部917、918外側,由外側被覆凸輪溝915(916),但並不限定於此,亦可於腔室91之壁部917、918內側設置被覆構件,由腔室91之內側被覆凸輪溝915(916)。 Further, in the present embodiment, the covering member 900 is provided outside the wall portions 917 and 918 of the chamber 91, and the cam groove 915 (916) is covered by the outside. However, the covering member 900 is not limited thereto, and may be formed on the wall portion of the chamber 91. A covering member is provided inside the 917 and 918, and a cam groove 915 (916) is covered by the inside of the chamber 91.

其中,如本實施形態般,在於腔室91外側設置被覆構件900時,被覆構件900對壁部的安裝變得容易。 However, as in the present embodiment, when the covering member 900 is provided outside the chamber 91, the covering member 900 can be easily attached to the wall portion.

如上述構成的硬化爐9,係構成為藉由上述移動手段,使 輥93a、94a之至少一者於積層片40(40A)之厚度方向上移動,而使積層片之通過路徑長度為可變。 The hardening furnace 9 configured as described above is configured by the above-described moving means. At least one of the rollers 93a, 94a moves in the thickness direction of the laminated sheet 40 (40A), and the passage length of the laminated sheet is made variable.

更詳細說明之,本實施形態中,藉由變更第1輥93a與第1輥93b間的軸間距離、及第2輥94a與第2輥94b間之軸間距離的雙方或單方,則使積層片40通過腔室91內時之通過路徑長度(以下稱為「路徑長」)、亦即積層片於腔室91內之由入口913至出口914的全長成為可變。 More specifically, in the present embodiment, by changing both the distance between the shaft between the first roller 93a and the first roller 93b and the distance between the shaft between the second roller 94a and the second roller 94b, The passage length (hereinafter referred to as "path length") when the laminated sheet 40 passes through the chamber 91, that is, the entire length of the laminated sheet in the chamber 91 from the inlet 913 to the outlet 914 is variable.

如圖2所示,在第1輥93a及第2輥94a分別位於圖中之最右側的狀態(將此位置稱為「第1位置」)下,係第1輥93a與第1輥93b間之軸間距離、及第2輥94a與第2輥94b間之軸間距離分別成為最大,路徑長成為最長。如圖3所示,在第1輥93a及第2輥94a分別位於圖中最左側的狀態(將此位置稱為「第2位置」)下,係第1輥93a與第1輥93b、及第2輥94a與第2輥94b間之軸間距離分別成為最小,距徑長成為最短。又,第1輥93a、第2輥94a亦可分別位於第1位置與第2位置之間,此時,路徑長成為最長與最短的中間長度。 As shown in FIG. 2, in the state in which the first roller 93a and the second roller 94a are located on the rightmost side in the drawing (this position is referred to as "first position"), between the first roller 93a and the first roller 93b. The distance between the shafts and the distance between the shafts between the second roller 94a and the second roller 94b are the largest, and the path length is the longest. As shown in FIG. 3, in the state in which the first roller 93a and the second roller 94a are located on the leftmost side in the drawing (this position is referred to as "second position"), the first roller 93a and the first roller 93b, and The distance between the axes between the second roller 94a and the second roller 94b is the smallest, and the distance from the diameter is the shortest. Further, the first roller 93a and the second roller 94a may be located between the first position and the second position, respectively, and in this case, the path length becomes the longest and shortest intermediate length.

如此,本實施形態中,藉由無法移動的輥93a、94b、可移動之第1輥93a及第2輥94a、與引導此等輥之凸輪溝915、916、與線性滑軌道99,可構成使路徑長為可變的路徑長可變手段。本實施形態中,路徑長可變手段係變更路徑長的變更手段。 As described above, in the present embodiment, the rollers 93a and 94b which are not movable, the movable first roller 93a and the second roller 94a, the cam grooves 915 and 916 for guiding the rollers, and the linear slide rail 99 can be configured. A path length variable means that makes the path length variable. In the present embodiment, the path length variable means is a means for changing the path length.

然而,藉由樹脂層的組成,有硬化為止的加熱時間相異的情形。此時,若積層片之搬送速度為一定、路徑長亦限制為一定,則於腔室91內對各樹脂層的加熱時間不變,結果有硬化不足、硬化過剩的情形。例如,如本實施形態,將樹脂層之組成相異的積層片40、40A連續形成、進行加熱處理時,將發生樹脂層之硬化過剩或不足。 However, the composition of the resin layer may have a different heating time until hardening. At this time, if the conveyance speed of the laminated sheet is constant and the path length is also kept constant, the heating time of each resin layer in the chamber 91 does not change, and as a result, there is a case where the hardening is insufficient and the hardening is excessive. For example, in the present embodiment, when the laminated sheets 40 and 40A having different compositions of the resin layers are continuously formed and subjected to heat treatment, the curing of the resin layer is excessive or insufficient.

若改變腔室91內之積層片的搬送速度,例如使其變慢,則在較腔室91更上流側的積層片將滯留,則必須有用於該滯留積層片的待機處。此時,位於待機處的積層片40非本意地開始各樹脂組成物的硬化,而使被搬送至腔室91時之硬化度產生偏差,所得之積層片40的品質不一定。 When the conveyance speed of the laminated sheet in the chamber 91 is changed, for example, it is made slow, the laminated sheet on the upstream side of the chamber 91 is retained, and the standby portion for the retained laminated sheet is required. At this time, the laminated sheet 40 located at the standby position unintentionally starts the hardening of each of the resin compositions, and the degree of hardening when being conveyed to the chamber 91 varies, and the quality of the laminated sheet 40 obtained is not necessarily obtained.

因此,藉由使路徑長成為可變,則在使積層片之搬送速度維持為一定之下,可容易且確實地變更於腔室91內之對各樹脂組成物的加熱時間。藉此,可視各樹脂層之組成而適度地進行加熱,因此可無過剩或不足地使各樹脂層硬化。 Therefore, by making the path length variable, the heating time for each resin composition in the chamber 91 can be easily and surely changed while maintaining the conveyance speed of the laminated sheet constant. Thereby, heating can be appropriately performed depending on the composition of each resin layer, so that each resin layer can be cured without excess or deficiency.

例如,在欲連續地製造硬化條件(加熱時間)相異之樹脂組成物所積層的積層片40、40A時,依將一連串之長形之積層片之搬送速度維持為一定的方式,一邊控制腔室91內之各輥的旋轉,一邊使路徑長為可變,則可容易地製造積層片40、40A。 For example, when it is desired to continuously manufacture the laminated sheets 40 and 40A in which the resin composition having different curing conditions (heating time) is laminated, the conveying speed is maintained while maintaining the conveying speed of the plurality of elongated laminated sheets. When the rotation of each of the rolls in the chamber 91 is made variable, the laminated sheets 40 and 40A can be easily produced.

此時,加熱裝置30B係具有用於使輥93a、94a旋轉的馬達90、及控制用於使輥93a、94a移動之馬達994之驅動的 控制部(省略圖示)。若作業者將用於使輥93a、94a移動的信號輸入至加熱裝置30B時,則控制部不使馬達90之驅動停止,而使用用於移動輥93a、94a之馬達994被驅動。然後,藉未圖示之檢測手段檢測輥93a、94a的位置,由控制部判斷檢測手段所檢測出之位置是否位於既定位置。在判斷其為既定位置時,控制部停止馬達994的驅動,停止輥93a、94a的移動。在判斷其非既定位置時,控制部係維持馬達994的驅動。其中,在均一情況下,控制部均不停止使輥93a、94a旋轉的馬達90的驅動。 At this time, the heating device 30B has a motor 90 for rotating the rollers 93a, 94a, and a motor 994 for controlling the movement of the rollers 93a, 94a. Control unit (not shown). When the operator inputs a signal for moving the rollers 93a and 94a to the heating device 30B, the control unit is driven by the motor 994 for moving the rollers 93a and 94a without stopping the driving of the motor 90. Then, the position of the rollers 93a and 94a is detected by a detecting means (not shown), and the control unit determines whether or not the position detected by the detecting means is at a predetermined position. When it is judged that it is a predetermined position, the control unit stops the driving of the motor 994 and stops the movement of the rollers 93a and 94a. When it is judged that it is not a predetermined position, the control unit maintains the driving of the motor 994. However, in the case of uniformity, the control unit does not stop the driving of the motor 90 that rotates the rollers 93a and 94a.

如圖2、圖3所示,凸輪溝915係於x軸方向上,相對於第1輥93b,由x軸負側朝正側延伸存在。亦即,凸輪軸915係由圖2、圖3中之右側越過第1輥93b,延伸存在至左側為止。藉此,第1輥93a可依跨越第1輥93b的方式進行移動,而可將第1輥93a之可動範圍儘可能地確保為較大。 As shown in FIGS. 2 and 3, the cam groove 915 is formed in the x-axis direction and extends from the negative side of the x-axis toward the positive side with respect to the first roller 93b. That is, the cam shaft 915 extends over the first roller 93b from the right side in FIGS. 2 and 3 and extends to the left side. Thereby, the first roller 93a can be moved so as to straddle the first roller 93b, and the movable range of the first roller 93a can be made as large as possible.

其中,輥93a可較輥93b僅依積層片40A之厚度份朝x軸負側移動,供給至腔室91內的積層片40(40A)係均與輥93a、93b的任一者接觸。 Among them, the roller 93a can move toward the negative side of the x-axis only by the thickness portion of the laminated sheet 40A, and the laminated sheet 40 (40A) supplied into the chamber 91 can be brought into contact with any of the rollers 93a and 93b.

另外,凸輪溝916亦於x軸方向上,相對於第2輥94b,由x軸負側朝正側延伸存在。亦即,凸輪軸916係由圖中之右側越過第2輥94b,延伸存在至左側為止。藉此,第2輥94a可依跨越第2輥94b的方式進行移動,而可將第2輥94a之可動範圍儘可能地確保為較大。 Further, the cam groove 916 also extends from the negative side of the x-axis toward the positive side with respect to the second roller 94b in the x-axis direction. That is, the cam shaft 916 extends beyond the second roller 94b from the right side in the drawing to the left side. Thereby, the second roller 94a can be moved so as to straddle the second roller 94b, and the movable range of the second roller 94a can be made as large as possible.

其中,輥94a可較輥94b僅依積層片40A之厚度份朝x軸負側移動,供給至腔室91內的積層片係均與輥94a、94b的任一者接觸。 Among them, the roller 94a can move toward the negative side of the x-axis only by the thickness portion of the laminated sheet 40A, and the laminated sheets supplied into the chamber 91 are in contact with any of the rollers 94a and 94b.

因此,路徑長之可變量亦變大,可配可多種的樹脂組成物,將其加熱時間調整為最適合的時間。又,亦有可將腔室91小型化、低成本化的優點。 Therefore, the variable length of the path length is also large, and a plurality of resin compositions can be provided, and the heating time is adjusted to the most suitable time. Further, there is an advantage that the chamber 91 can be reduced in size and cost.

另外,如上述般,使用線性滑軌道99使第1輥93a或第2輥94a移動。例如,首先先複數設定馬達994的驅動量(亦即,先複數設定輥93a、94a的配置位置),並適當選擇馬達994的驅動量,則可設定輥93a、94a的移動距離。 Further, as described above, the first roller 93a or the second roller 94a is moved by the linear slide rail 99. For example, first, the driving amount of the motor 994 (that is, the arrangement position of the plurality of setting rollers 93a and 94a) is set in plural, and the driving amount of the motor 994 is appropriately selected, whereby the moving distance of the rollers 93a and 94a can be set.

另外,亦可不事先設定馬達994之驅動量,由作業者驅動馬達994而使第1輥93a或第294a移動至所需位置。 Further, the driving amount of the motor 994 may not be set in advance, and the operator drives the motor 994 to move the first roller 93a or the 294a to the desired position.

另外,第1輥93a與第1輥93b,係彼此大小相同者,第2輥94a與第2輥94b亦彼此大小相同者。本實施形態中,第1輥93a、93b、第2輥94a、94b、第3輥95係彼此大小相同者。藉此,可容易把握路徑長之長度為何種程度。 Further, the first roller 93a and the first roller 93b are the same size, and the second roller 94a and the second roller 94b are also the same size. In the present embodiment, the first rolls 93a and 93b, the second rolls 94a and 94b, and the third roll 95 are the same size. Thereby, it is easy to grasp the extent of the length of the path length.

接著,針對藉積層片製造裝置30製造積層片40、40A的狀態(製造過程),參照圖1~圖3、圖6進行說明。 Next, a state (manufacturing process) in which the laminated sheets 40 and 40A are produced by the multilayer sheet manufacturing apparatus 30 will be described with reference to FIGS. 1 to 3 and 6.

於積層片製造裝置30之壓黏裝置30A中,係在使第1輥71a、71b、第2輥72a、72b與第3輥73a、73b旋轉前,作成減壓手段8,先將空間70內減壓。又,於加熱裝置30B中,係使加熱器92作動而將腔室91內先加熱至既定溫度、 亦即積層片40、40A之樹脂層3、3A、4、4A進行硬化的溫度。又,先將腔室91內之路徑長調整為既定量,亦即適合使積層片40之樹脂層3、4硬化的量。例如,使硬化爐9成為圖2所示狀態、圖3所示裝置或圖2與圖3所示狀態的中間狀態的任一種狀態。 In the pressure-bonding device 30A of the laminated sheet manufacturing apparatus 30, before the first rolls 71a and 71b, the second rolls 72a and 72b, and the third rolls 73a and 73b are rotated, the pressure reducing means 8 is formed, and the space 70 is first placed. stress reliever. Further, in the heating device 30B, the heater 92 is actuated to heat the chamber 91 to a predetermined temperature. That is, the temperature at which the resin layers 3, 3A, 4, and 4A of the laminated sheets 40 and 40A are hardened. Further, the path length in the chamber 91 is first adjusted to a predetermined amount, that is, an amount suitable for curing the resin layers 3, 4 of the laminated sheet 40. For example, the hardening furnace 9 is in any state of the state shown in FIG. 2, the apparatus shown in FIG. 3, or the intermediate state of the state shown in FIG. 2 and FIG.

本實施形態中,係驅動馬達994,使螺旋軸993旋轉,使滑件992於導軌道991上滑動。由於在滑件992上設置的馬達90或於軸承上連接著第1輥93a的軸部98,故隨著滑件992的滑動,使輥93a之軸部98於溝915內移動。而且,本實施形態係如圖2所示,將輥93a配置於溝915的一端部側。 In the present embodiment, the motor 994 is driven to rotate the screw shaft 993 to slide the slider 992 on the guide rail 991. Since the motor 90 provided in the slider 992 or the shaft portion 98 of the first roller 93a is connected to the bearing, the shaft portion 98 of the roller 93a moves in the groove 915 as the slider 992 slides. Further, in the present embodiment, as shown in FIG. 2, the roller 93a is disposed on one end side of the groove 915.

同樣地,驅動馬達994,使螺旋軸993旋轉,使滑件992於導軌道991上滑動。由於在滑件992上設置的馬達90或於軸承上連接著第2輥94a的軸部98,故隨著滑件992的滑動,使輥94a之軸部於溝916內移動。而且,本實施形態係如圖2所示,將輥94a配置於溝916的一端部側。 Similarly, the motor 994 is driven to rotate the screw shaft 993 to slide the slider 992 over the guide rail 991. Since the motor 90 provided in the slider 992 or the shaft portion 98 of the second roller 94a is connected to the bearing, the shaft portion of the roller 94a moves in the groove 916 as the slider 992 slides. Further, in the present embodiment, as shown in FIG. 2, the roller 94a is disposed on one end side of the groove 916.

如圖1所示,當第1輥71a與第1輥71b旋轉時,由此等輥間將纖維基材2送至出空間70內(連續地供給)。纖維基材2被供給輥所捲繞,而由此供給輥連續地供給至輥71a、71b。 As shown in FIG. 1, when the first roller 71a and the first roller 71b are rotated, the fiber base material 2 is sent to the discharge space 70 (continuously supplied) between the rollers. The fiber base material 2 is wound by a supply roller, and thus the supply roller is continuously supplied to the rollers 71a, 71b.

另外,當第2輥72a與第3輥73a旋轉時,由此等輥之間將第1片材5a送出至空間70內(連續地供給)。此第1片材 5a係保護片51被第3輥73a所捲取(拉取),藉此,由第1樹脂層3剝離保護片51。剝離了保護片51之第1樹脂層3,係沿著第2輥72a慢慢地接近纖維基材2。又,經剝離之保護片51係由第1輥71a與第3輥73a之間朝外側(空間70外)被送出。 Further, when the second roller 72a and the third roller 73a are rotated, the first sheet 5a is fed into the space 70 (continuously supplied) between the rollers. This first sheet The 5a-type protective sheet 51 is taken up (pulled) by the third roller 73a, whereby the protective sheet 51 is peeled off from the first resin layer 3. The first resin layer 3 of the protective sheet 51 is peeled off, and the fibrous base material 2 is gradually approached along the second roller 72a. Moreover, the peeled protective sheet 51 is sent out between the first roller 71a and the third roller 73a (outside the space 70).

另外,當第2輥72b與第3輥73b旋轉時,由此等輥之間將第2片材5b送出至空間70內。此第2片材5b係保護片51被第3輥73b所捲取,藉此,由第2樹脂層4剝離保護片51。剝離了保護片51之第2樹脂層4,係沿著第2輥72b慢慢地接近纖維基材2。又,經剝離之保護片51係由第1輥71b與第3輥73b之間朝外側被送出。 Further, when the second roller 72b and the third roller 73b are rotated, the second sheet 5b is fed into the space 70 between the rollers. The second sheet 5b-based protective sheet 51 is taken up by the third roller 73b, whereby the protective sheet 51 is peeled off by the second resin layer 4. The second resin layer 4 from which the protective sheet 51 is peeled off is gradually approached to the fiber base material 2 along the second roll 72b. Moreover, the peeled protective sheet 51 is sent out between the first roller 71b and the third roller 73b.

藉由在如此即將使第1樹脂層3及第2樹脂層4分別壓黏至纖維基材2之前,於空間70內剝離保護片51,則可防止該保護片51成為各樹脂之壓黏阻礙,並在即將壓黏前為止藉由保護片51保護各樹脂層。 By peeling the protective sheet 51 in the space 70 immediately before the first resin layer 3 and the second resin layer 4 are pressure-bonded to the fiber base material 2, the protective sheet 51 can be prevented from being pressed against each resin. And the respective resin layers are protected by the protective sheet 51 just before the pressure bonding.

而且,纖維基材2與第1樹脂層3與第2樹脂層4,係一次地通過第2輥72a與第2輥72b之間。此時,如圖6所示,藉由第2輥72a與第2輥72b之間的壓接力(抵接力)F1,使第1樹脂層3由上側壓黏至纖維基材2,並使第2樹脂層4由下側壓黏至纖維基材2。 Further, the fiber base material 2, the first resin layer 3, and the second resin layer 4 pass between the second roller 72a and the second roller 72b at a time. At this time, as shown in FIG. 6, the first resin layer 3 is pressure-bonded to the fiber base material 2 from the upper side by the pressure contact force (contact force) F1 between the second roller 72a and the second roller 72b, and 2 The resin layer 4 is pressure-bonded to the fibrous base material 2 from the lower side.

另外,如上述般,空間70係藉減壓手段8之作動而被減壓。藉此,如圖6所示,於空間70內所產生之減壓力F2 可輔助纖維基材2與第1樹脂層3間之壓黏、及纖維基材2與第2樹脂層4間的壓黏。 Further, as described above, the space 70 is decompressed by the action of the decompression means 8. Thereby, as shown in FIG. 6, the pressure reduction F2 generated in the space 70 The pressure-bonding between the fiber base material 2 and the first resin layer 3 and the pressure-bonding between the fiber base material 2 and the second resin layer 4 can be assisted.

由此種壓接力F1進行之壓黏與由減壓力F2所進行之壓黏相配合,使纖維基材2與第1樹脂層3間的接合、及纖維基材2與第2樹脂層4間的接合強化。藉此,可使樹脂層3、4含浸於纖維基材2內部。而且,例如不論第1樹脂層3或第第2樹脂層4的厚度或組成,可製造使該各樹脂層確實且牢固地接合至纖維基材2的積層片40。 The pressure-bonding by the pressure contact force F1 is combined with the pressure-bonding by the pressure reduction F2 to bond the fiber base material 2 and the first resin layer 3, and between the fiber base material 2 and the second resin layer 4. Bonding reinforcement. Thereby, the resin layers 3 and 4 can be impregnated inside the fiber base material 2. Further, for example, regardless of the thickness or composition of the first resin layer 3 or the second resin layer 4, the laminated sheet 40 in which the respective resin layers are reliably and firmly bonded to the fiber base material 2 can be produced.

再者,藉由將第2輥72a與第2輥72b設為加熱輥,則可使樹脂層3、4確實地含浸於纖維基材2內部。 In addition, by using the second roller 72a and the second roller 72b as the heating roller, the resin layers 3 and 4 can be surely impregnated into the inside of the fiber base material 2.

另外,於積層片製造裝置30中,係將應減壓的空間設為由第1輥71a及71b、第2輥72a及72b、第3輥73a及73b所包圍的空間70,可使其儘可能地減小。藉此,在使減壓手段8作動時,可迅速地進行其減壓。又,亦可進行高真空化。 Further, in the laminated sheet manufacturing apparatus 30, the space to be decompressed is a space 70 surrounded by the first rolls 71a and 71b, the second rolls 72a and 72b, and the third rolls 73a and 73b, so that the space can be made It is possible to reduce. Thereby, when the decompression means 8 is actuated, the decompression can be performed rapidly. Moreover, it is also possible to carry out high vacuum.

另外,在將纖維基材2與第1樹脂層3接合時,即使於此等之間殘留有空氣,仍可藉由壓接力F1擠出空氣,因此,可確實防止於空氣殘留之下直接予以接合的情形(在纖維基材2與第2樹脂層4之接合時亦相同)。 Further, when the fiber base material 2 and the first resin layer 3 are joined, even if air remains between the fibers, the air can be extruded by the pressure contact force F1, so that it can be reliably prevented from being directly left under the air remaining. In the case of bonding (the same applies to the joining of the fiber base material 2 and the second resin layer 4).

由一對之輥72a、72b所送出之積層片40,係如圖2所示,由腔室91之入口913連續地送入至腔室91內部。使腔室內部之輥93a、93b、94a、94b、95藉馬達進行旋轉,則使積 層片40於腔室91內部移動。然後,由腔室91之出口914連續地被送出至腔室91外部。 The laminated sheet 40 fed by the pair of rolls 72a, 72b is continuously fed into the inside of the chamber 91 from the inlet 913 of the chamber 91 as shown in Fig. 2 . By rotating the rollers 93a, 93b, 94a, 94b, 95 inside the chamber by the motor, the product is made The ply 40 moves inside the chamber 91. Then, the outlet 914 of the chamber 91 is continuously sent out to the outside of the chamber 91.

更具體而言,由入口913被送入之積層片40,係藉由輥93a使於腔室91內之搬送方向折返,到達輥93b。然後,藉由輥93b,於腔室91內之搬送方向折返,到達輥94a。接著,藉輥94a,於腔室91內之搬送方向折返,到達輥94b。進而藉由輥94b,於腔室91內之搬送方向折返,到達輥95,而由出口914被排出至腔室91外部。 More specifically, the laminated sheet 40 fed by the inlet 913 is folded back by the roller 93a in the conveying direction in the chamber 91, and reaches the roller 93b. Then, the roller 93b is folded back in the conveying direction in the chamber 91 to reach the roller 94a. Then, the roller 94a is folded back in the conveying direction in the chamber 91 to reach the roller 94b. Further, the roller 94b is folded back in the conveying direction in the chamber 91 to reach the roller 95, and is discharged to the outside of the chamber 91 by the outlet 914.

積層片40係於腔室91內不停止,一邊通過91內、一邊被加熱,而促進樹脂層3、4的硬化。由於腔室91內之積層片40之路徑長係適合各樹脂層3、4硬化的長短,故可無過剩或不足地進行該硬化。而後,由腔室91出來的積層片40,係各樹脂層3、4經適度硬化者。 The laminated sheet 40 is heated in the inside of the chamber 91 without being stopped, and is accelerated by the inside of 91 to accelerate the resin layers 3 and 4. Since the path length of the laminated sheet 40 in the chamber 91 is suitable for the length of hardening of the respective resin layers 3, 4, the hardening can be performed without excess or deficiency. Then, the laminated sheet 40 from the chamber 91 is moderately hardened by the respective resin layers 3, 4.

接著,在朝腔室91搬送積層片40的期間,將供給至壓黏裝置30A之樹脂層的種類由樹脂層3、4變更為樹脂層3A、4A。藉此,由壓黏裝置30A之輥72a、72b之間搬送積層片40A。又,積層片40A係與積層片40之樹脂層的組成物相異,但於其他方面則與積層片40相同。該積層片40A係與積層片40連續設置。例如,在積層片40之端部與積層片40A之端部之間,有露出纖維基材2的區域,經由此區域,可將積層片40與積層片40A連接。又,亦可使積層片40之端部與積層片40A之端部連接。 Then, while the laminated sheet 40 is being conveyed toward the chamber 91, the types of the resin layers supplied to the pressure-bonding device 30A are changed from the resin layers 3 and 4 to the resin layers 3A and 4A. Thereby, the laminated sheet 40A is conveyed between the rollers 72a and 72b of the pressure-bonding device 30A. Further, the laminated sheet 40A is different from the composition of the resin layer of the laminated sheet 40, but is otherwise the same as the laminated sheet 40. The laminated sheet 40A is continuously provided with the laminated sheet 40. For example, between the end portion of the laminated sheet 40 and the end portion of the laminated sheet 40A, there is a region where the fibrous base material 2 is exposed, and the laminated sheet 40 can be connected to the laminated sheet 40A via this region. Further, the end portion of the laminated sheet 40 may be connected to the end portion of the laminated sheet 40A.

積層片40與積層片40A係構成一連串之連續的長形之積層片。 The laminated sheet 40 and the laminated sheet 40A constitute a series of continuous elongated laminated sheets.

另一方面,驅動上述移動手段,變更腔室91內之輥93a、94a的配置。依將含有積層片40及40A而構成的上述一連串之長形之積層片抵接於輥93b、94b的狀態,變更抵接於長形之上述積層片的輥93a、94a的配置。 On the other hand, the above-described moving means is driven to change the arrangement of the rollers 93a, 94a in the chamber 91. The above-described series of elongated laminated sheets including the laminated sheets 40 and 40A are brought into contact with the rolls 93b and 94b, and the arrangement of the rolls 93a and 94a abutting on the elongated laminated sheets is changed.

例如,在積層片40之搬送方向後端側之端部與積層片40A之端部的境界部分到達了腔室91之入口913的階段,亦即積層片40位於腔室91內部的狀態,一邊搬送積層片40、40A,一邊變更腔室91內之輥93a、94a的配置。具體而言,係依積層片40與輥93b、94b相抵接的狀態,變更抵接於積層片40之輥93a、94a的配置。 For example, the boundary portion between the end portion on the rear end side in the conveying direction of the laminated sheet 40 and the end portion of the laminated sheet 40A reaches the inlet 913 of the chamber 91, that is, the state in which the laminated sheet 40 is located inside the chamber 91, one side. The arrangement of the rolls 93a and 94a in the chamber 91 is changed while the laminated sheets 40 and 40A are conveyed. Specifically, the arrangement of the rollers 93a and 94a abutting on the laminated sheet 40 is changed in a state in which the laminated sheet 40 is in contact with the rollers 93b and 94b.

尚且,輥93a、94a之配置變更的時機並不限定於此,亦可在積層片40A進入腔室91內部、積層片40A與輥93b、94b相抵接的狀態,變更抵接積層片40A之輥93a、94a的配置。 In addition, the timing of changing the arrangement of the rolls 93a and 94a is not limited thereto, and the roll of the laminated sheet 40A may be changed while the laminated sheet 40A enters the inside of the chamber 91 and the laminated sheet 40A abuts against the rolls 93b and 94b. Configuration of 93a, 94a.

進而,亦可於積層片40、40A間,僅形成一定長度的纖維基材2的區域,將此僅有纖維基材2之區域送入腔室91內,依於腔室91內部存在僅有纖維基材2之區域的狀態,一邊搬送積層片40、40A,一邊進行輥93a、94a的配置變更。 Further, it is also possible to form only a region of the fiber base material 2 having a predetermined length between the laminated sheets 40 and 40A, and to feed only the region of the fibrous base material 2 into the chamber 91, depending on the inside of the chamber 91. In the state of the region of the fiber base material 2, the arrangement of the rolls 93a and 94a is changed while the laminated sheets 40 and 40A are conveyed.

尚且,亦可使包括積層片40、40A之一連串之長形的積 層片的搬送停止,依長形之上述積層片之一部分位於腔室內的狀態,變更輥93a、94a的配置。 Furthermore, it is also possible to make a long product including a series of laminated sheets 40, 40A The conveyance of the layer is stopped, and the arrangement of the rolls 93a and 94a is changed in a state in which one of the above-mentioned laminated sheets in the elongated shape is located in the chamber.

本實施形態中,係設為圖3所示之輥93a、94a的配置。驅動馬達994,使螺旋軸993旋轉,而使滑件992於導軌道991上滑動。由於在設置於滑件992上之馬達90或軸承上分別連接著第1輥93a之軸部98,故隨著滑件992的滑動,使輥93a之軸部98於溝915內移動。藉此,輥93a位於腔室91內,沿著抵接於93a之積層片40的厚度方向(本實施形態中為x軸方向)移動。然後,如圖3所示,將輥93a配置於溝915的另一端部側。 In the present embodiment, the arrangement of the rolls 93a and 94a shown in Fig. 3 is adopted. The motor 994 is driven to rotate the screw shaft 993 to slide the slider 992 over the guide rail 991. Since the shaft portion 98 of the first roller 93a is connected to the motor 90 or the bearing provided on the slider 992, the shaft portion 98 of the roller 93a moves in the groove 915 as the slider 992 slides. Thereby, the roller 93a is located in the chamber 91, and moves along the thickness direction (in the present embodiment, the x-axis direction) of the laminated sheet 40 abutting on 93a. Then, as shown in FIG. 3, the roller 93a is disposed on the other end side of the groove 915.

尚且,輥93a雖移動至溝915的另一端部側,但依輥93a所搬送之積層片40A接觸輥93b的方式使輥93a移動。藉此,可確實地搬送積層片40A。 In addition, the roller 93a moves to the other end side of the groove 915, but the roller 93a is moved so that the laminated sheet 40A conveyed by the roller 93a contacts the roller 93b. Thereby, the laminated sheet 40A can be reliably conveyed.

同樣地,驅動馬達994,使螺旋軸993旋轉,使滑件992於導軌道991上滑動。由於在設置於滑件992上之馬達90或軸承分別連接著第2輥94a之軸部98,故隨著滑件992的滑動,使輥94a之軸部於溝916內移動。藉此,輥94a係位於腔室91內,沿著接觸至輥94a之積層片40之厚度方向(本實施形態中為x軸方向)移動。而且,本實施形態中,係如圖3所示,將輥94a配置於溝916的另一端部側。 Similarly, the motor 994 is driven to rotate the screw shaft 993 to slide the slider 992 over the guide rail 991. Since the shaft portion 98 of the second roller 94a is connected to the motor 90 or the bearing provided on the slider 992, the shaft portion of the roller 94a moves in the groove 916 as the slider 992 slides. Thereby, the roller 94a is located in the chamber 91, and moves along the thickness direction (in the present embodiment, the x-axis direction) of the laminated sheet 40 that is in contact with the roller 94a. Further, in the present embodiment, as shown in FIG. 3, the roller 94a is disposed on the other end side of the groove 916.

尚且,輥94a雖移動至溝916之另一端部側,但依輥94a所搬送之積層片40A可接觸至輥94b的方式移動輥94a。藉 此,可確實地搬送積層片。 Further, the roller 94a moves to the other end side of the groove 916, but the laminated sheet 40A conveyed by the roller 94a can move the roller 94a so as to be in contact with the roller 94b. borrow Thereby, the laminated sheet can be reliably conveyed.

於上述之進行輥93a、94a之配置調整的步驟中,可不需打開腔室91,依關閉腔室91的狀態,變更輥93a、94a的位置。 In the above-described step of adjusting the arrangement of the rollers 93a and 94a, the position of the rollers 93a and 94a can be changed without opening the chamber 91 in accordance with the state in which the chamber 91 is closed.

藉由旋轉各輥,由入口913使積層片40A連續地被送入至腔室91內。積層片40A係藉由輥93a使搬送方向由x軸方向變更為y軸方向,依輥93b、輥94a的順序抵接。而且,藉輥94b使搬送方向由y軸方向變更為x軸方向,藉輥95由出口914連續地排出。 The laminated sheet 40A is continuously fed into the chamber 91 by the inlet 913 by rotating the rolls. In the laminated sheet 40A, the conveyance direction is changed from the x-axis direction to the y-axis direction by the roller 93a, and the roller 93b and the roller 94a are in contact with each other. Further, the transfer roller 94b changes the conveyance direction from the y-axis direction to the x-axis direction, and the roller 95 is continuously discharged from the outlet 914.

積層片40A係於腔室91內不停止,一邊通過91內、一邊被加熱,而促進樹脂層3A、4A的硬化。由於腔室91內之積層片40A之路徑長係適合各樹脂層3A、4A硬化的長短,故可無過剩或不足地進行該硬化。而後,由腔室91出來的積層片40A,係各樹脂層3A、4A經適度硬化者。 The laminated sheet 40A is heated in the inside of the chamber 91 without being stopped, and is accelerated by the inside of 91, thereby promoting the hardening of the resin layers 3A and 4A. Since the path length of the laminated sheet 40A in the chamber 91 is suitable for the length of hardening of each of the resin layers 3A, 4A, the hardening can be performed without excess or deficiency. Then, the laminated sheet 40A from the chamber 91 is moderately hardened by the respective resin layers 3A and 4A.

本實施形態中,由於將馬達994設於外部,故例如即使需要以手動驅動馬達994,而驅動馬達994以變更輥93a、94a的位置時,仍不需打開腔室91。 In the present embodiment, since the motor 994 is provided outside, for example, even if it is necessary to manually drive the motor 994 and drive the motor 994 to change the positions of the rollers 93a and 94a, it is not necessary to open the chamber 91.

因此,可防止腔室91內路的溫度變化,可連接積層片40迅速地對積層片40A進行加熱處理。 Therefore, the temperature change of the inner path of the chamber 91 can be prevented, and the laminated sheet 40 can be connected to heat the laminated sheet 40A quickly.

本實施形態中,由於將由線性滑軌道99所構成的移動手段配置於腔室91外部,故可減小腔室91。藉此,容易穩定地保持腔室91內的溫度。 In the present embodiment, since the moving means constituted by the linear slide rails 99 is disposed outside the chamber 91, the chamber 91 can be made small. Thereby, it is easy to stably maintain the temperature in the chamber 91.

另外,本實施形態中,在複數之輥93a、93b、94a、94b、95中,將配置於積層片之搬送方向下游側的2個輥94b、95,設為相對於腔室91之位置呈固定的固定輥。如此,可將積層片40(40A)之由腔室91的排出位置固定,並可將形成於腔室91的積層片40(40A)的出口成為一個。藉此,可提高腔室91內的溫度穩定性。 In the present embodiment, the plurality of rollers 94a, 93b, 94a, 94b, and 95 are disposed on the downstream side of the stacking sheet in the transport direction, and are disposed at positions relative to the chamber 91. Fixed fixed roller. Thus, the discharge position of the laminated sheet 40 (40A) from the chamber 91 can be fixed, and the outlet of the laminated sheet 40 (40A) formed in the chamber 91 can be made one. Thereby, the temperature stability in the chamber 91 can be improved.

再者,本實施形態中,加熱裝置30B係具備複數之可於腔室91內移動的輥。具體而言,於腔室91內,配置有輥93a、94a。如此,藉由設置複數個可於腔室91內移動的輥,則可將腔室91內之積層片之路徑長設定為各種距離。 Further, in the present embodiment, the heating device 30B includes a plurality of rollers that are movable in the chamber 91. Specifically, rollers 93a and 94a are disposed in the chamber 91. Thus, by providing a plurality of rollers movable in the chamber 91, the path length of the laminated sheets in the chamber 91 can be set to various distances.

尚且,於加熱裝置30B中,亦可藉由加熱積層片40、40A,進行樹脂層3、4(3A、4A)對纖維基材的含浸。 Further, in the heating device 30B, the resin substrates 3, 4 (3A, 4A) may be impregnated into the fiber substrate by heating the laminated sheets 40, 40A.

<基板> <Substrate>

接著,針對使用了切斷40而構成之預浸體1的基材10,參照圖9進行說明。圖9所示之基板10,係具有積層體11、與設於該積層體11兩面的金屬層12。 Next, the base material 10 of the prepreg 1 which used the cutting 40 is demonstrated with reference to FIG. The substrate 10 shown in FIG. 9 has a laminate 11 and a metal layer 12 provided on both surfaces of the laminate 11.

尚且,於此,雖針對使用了切斷積層片40而構成之預浸體1的基板10進行說明,但亦可將積層體40A切斷而構成同樣的基板10。 In the above description, the substrate 10 using the prepreg 1 configured by cutting the laminated sheet 40 will be described. However, the laminated body 40A may be cut to constitute the same substrate 10.

積層體11係具備:以第2樹脂層4彼此為內側而配置的2個預浸體1;與由第2樹脂層4彼此挾持的內層電路基板13。 The laminated body 11 includes two prepregs 1 that are disposed inside the second resin layer 4 and an inner layer circuit board 13 that is held by the second resin layer 4 .

內層電路基板13係具備電路(未圖示)的基板。又,本實施形態中,第2樹脂層4由於具有上述特性(可撓性),故使內層電路基板13之至少一部分確實地埋入(埋設)於第2樹脂層4中。 The inner layer circuit board 13 is a board including a circuit (not shown). Further, in the present embodiment, since the second resin layer 4 has the above-described characteristics (flexibility), at least a part of the inner layer circuit board 13 is surely embedded (embedded) in the second resin layer 4.

金屬層12係加工為佈線部的部分,可藉由例如將銅箔、鋁箔等之金屬箔接合至積層體11,將銅、鋁鍍覆於積層體11表面等而形成。 The metal layer 12 is formed as a portion of the wiring portion, and is formed by, for example, bonding a metal foil such as a copper foil or an aluminum foil to the laminated body 11 and plating copper or aluminum on the surface of the laminated body 11.

金屬層12與第1樹脂層3的剝離強度,較佳為0.5kN/m以上、更佳0.6kN/m以上。藉此,可使將金屬層12加工為佈線部而得到之半導體裝置100(參照圖10)的連接可靠性提升。 The peeling strength of the metal layer 12 and the first resin layer 3 is preferably 0.5 kN/m or more, more preferably 0.6 kN/m or more. As a result, the connection reliability of the semiconductor device 100 (see FIG. 10) obtained by processing the metal layer 12 into a wiring portion can be improved.

此種基板10可舉例如準備於第1樹脂層3上形成了金屬層12的2個預浸體1,依藉此等預浸體1挾持內層電路基板13的狀態,使用例如真空壓製、常壓層合器及於真空下進行加熱加壓之層合器進行積層的方法。真空壓製可挾持於平板而藉通常之熱壓機等實施。作為此種裝置,可舉例如名機製作所公司製的真空壓製機、北川精機公司製之真空壓製機、MIKADO TECHNOS公司製之真空壓製機等。又,作為層合裝置,可舉例如Nichigo-Morton公司製之真空施加器、名機製作所公司製之真空加壓式層合器、日立Techno Engineering公司製之真空輥式乾式塗佈機等之市售的真空積層機或帶式壓製機等,而可使用此等進行製造。 In the substrate 10, for example, two prepregs 1 in which the metal layer 12 is formed on the first resin layer 3 are used, and in the state in which the prepreg 1 holds the inner layer circuit board 13, for example, vacuum pressing, A method of laminating a normal pressure laminator and a laminator which is heated and pressurized under vacuum. The vacuum pressing can be carried out on a flat plate by a usual hot press or the like. As such a device, for example, a vacuum press manufactured by Nihon Seiki Co., Ltd., a vacuum press manufactured by Beichuan Seiki Co., Ltd., a vacuum press manufactured by MIKADO TECHNOS Co., Ltd., and the like can be given. In addition, as a laminating apparatus, for example, a vacuum applicator manufactured by Nichigo-Morton Co., Ltd., a vacuum pressurizing laminator manufactured by a famous machine company, and a vacuum roll type dry coater manufactured by Hitachi Techno Engineering Co., Ltd., etc. A vacuum laminator or a belt press which is sold can be manufactured using these.

另外,基板10可為省略內層電路基板13而含有二個預浸體1直接接合第2樹脂層4彼此所成之積層體者,亦可為省略金屬層12者。 In addition, the substrate 10 may be a laminate in which the two prepregs 1 are directly bonded to the second resin layer 4, and the metal layer 12 may be omitted.

<半導體裝置> <semiconductor device>

接著,針對使用了基板10之半導體裝置100,參照圖10進行說明。又,圖10中,係省略表示纖維基材2、內層電路基板13,而將第1樹脂層3及第2樹脂層4一體表示。 Next, the semiconductor device 100 using the substrate 10 will be described with reference to FIG. In FIG. 10, the fiber base material 2 and the inner layer circuit board 13 are omitted, and the first resin layer 3 and the second resin layer 4 are integrally shown.

圖10所示之半導體裝置100,係具有:多層基板200;設於多層基板200上面的墊部300;設於多層基板200下面之佈線部400;與藉由將凸塊501連接至墊部300,而搭載於多層基板200上的半導體元件500。 The semiconductor device 100 shown in FIG. 10 has a multilayer substrate 200, a pad portion 300 provided on the upper surface of the multilayer substrate 200, a wiring portion 400 provided under the multilayer substrate 200, and a bump portion 501 connected to the pad portion 300. The semiconductor element 500 mounted on the multilayer substrate 200 is provided.

多層基板200係具備:設置作為核基板的基板10;設於該基板10上側的3個預浸體1a、1b、1c;與設於基板10下側之3個預浸體1d、1e、1f。分別構成預浸體1a~1c之纖維基材2、第1樹脂層3、第2樹脂層4於基板10起的配置順序,與分別構成預浸體1d~1f之纖維基材2、第1樹脂層3、第2樹脂層4於基板10起的配置順序係相同。亦即,預浸體1a~1c與預浸體1d~1f係彼此上下相反者。 The multilayer substrate 200 includes a substrate 10 as a core substrate, three prepregs 1a, 1b, and 1c provided on the upper side of the substrate 10, and three prepregs 1d, 1e, and 1f provided on the lower side of the substrate 10. . The fiber base material 2, the first resin layer 3, and the second resin layer 4 constituting the prepregs 1a to 1c are arranged on the substrate 10, and the fiber base materials 2 and 1 which constitute the prepregs 1d to 1f, respectively. The arrangement order of the resin layer 3 and the second resin layer 4 on the substrate 10 is the same. That is, the prepregs 1a to 1c and the prepregs 1d to 1f are opposite to each other.

另外,多層基板200係具有:設於預浸體1a與預浸體1b之間的電路部201a;設於預浸體1b與預浸體1c之間的電路部201b;設於預浸體1d與預浸體1e之間的電路部201d;設於預浸體1e與預浸體1f之間的電路部201e。 Further, the multilayer substrate 200 includes a circuit portion 201a provided between the prepreg 1a and the prepreg 1b, a circuit portion 201b provided between the prepreg 1b and the prepreg 1c, and a prepreg 1d. A circuit portion 201d between the prepreg 1e and the prepreg 1e; and a circuit portion 201e provided between the prepreg 1e and the prepreg 1f.

再者,多層基板200係具備分別貫通各預浸體1a~1f而設置,將相鄰接之電路部彼此、或電路部與墊部予以電氣連接的導體部202。 Further, the multilayer substrate 200 includes a conductor portion 202 that is provided to penetrate the respective prepregs 1a to 1f, and electrically connect adjacent circuit portions or circuit portions and pad portions.

基板10之各金屬層12,係分別被加工為既定圖案,該經加工之金屬層12彼此係藉由貫通基板10而設置的導體部203被電氣連接。 Each of the metal layers 12 of the substrate 10 is processed into a predetermined pattern, and the processed metal layers 12 are electrically connected to each other by a conductor portion 203 provided through the substrate 10.

尚且,半導體基板100(多層基板200)亦可於基板10之單面側上設置4個以上的預浸體1。再者,半導體裝置100亦可包有本發明之預浸體1以外的預浸體。 Further, in the semiconductor substrate 100 (multilayer substrate 200), four or more prepregs 1 may be provided on one side of the substrate 10. Further, the semiconductor device 100 may also include a prepreg other than the prepreg 1 of the present invention.

以上,雖針對圖示之實施形態說明了本發明之積層片製造裝置及積層片,但本發明並不限定於此,構成積層片製造裝置及積層片的各部,可置換為能發揮相同機能的任意構成。又,亦可附加任意的構成物。 In the above, the laminated sheet manufacturing apparatus and the laminated sheet of the present invention have been described with reference to the embodiments shown in the drawings. However, the present invention is not limited thereto, and the respective portions constituting the laminated sheet manufacturing apparatus and the laminated sheet can be replaced with the same function. Arbitrary composition. Further, any constituent may be added.

另外,積層片製造裝置雖於圖1所示之構成中設置了1組之1對之第3輥,但並不限定於此,亦可設置例如2組以上。 In the configuration shown in FIG. 1 , the laminated sheet manufacturing apparatus is provided with a pair of third rollers. However, the laminated sheet manufacturing apparatus is not limited thereto, and may be provided, for example, in two or more groups.

另外,各第1輥與各第2輥與各第3輥雖然於圖1所示構成中本體部外徑彼此相異,但並不限定於此,亦可例如本體部之外徑彼此相同。 Further, although the outer diameters of the main body portions of the first roller, the respective second rollers, and the respective third rollers are different from each other in the configuration shown in Fig. 1, the present invention is not limited thereto, and for example, the outer diameters of the main body portions may be the same.

另外,圖2、圖3中,雖圖示了移動之輥、與限制了移動之輥的2組,但組數並不限定於此,例如亦可為1組或3組以上。 In addition, in FIG. 2 and FIG. 3, although the moving roller and the two rollers which restrict the movement are shown, the number of the groups is not limited to this, and may be one set or three or more sets, for example.

另外,積層片雖於圖8所示構成中在纖維基材之兩面分別接合了樹脂層者,但並不限定於此,亦可僅於纖維基材之單面接合了樹脂層者。此種構成之積層片亦可藉由積層片製造裝置進行製造。 Further, in the configuration shown in Fig. 8, the resin layer is bonded to both surfaces of the fiber base material, but the laminated layer is not limited thereto, and the resin layer may be bonded only to one side of the fiber base material. The laminated sheet of such a configuration can also be manufactured by a laminated sheet manufacturing apparatus.

另外,上述實施形態中,雖將被覆構件900設為隨著輥移動而於軌道R上進行移動,但並不限定於此。例如亦可準備與凸輪溝略相同長度的被覆構件。此時,係在確定了輥之位置後,將被覆構件安裝於腔室之壁部。使輥移動時,係將被覆構件由腔室之壁部去除。 Further, in the above-described embodiment, the covering member 900 is moved on the rail R as the roller moves, but the invention is not limited thereto. For example, a covering member having the same length as the cam groove may be prepared. At this time, after the position of the roller is determined, the covering member is attached to the wall portion of the chamber. When the roller is moved, the covering member is removed from the wall portion of the chamber.

再者,於上述實施形態中,雖將輥93a、94a設於可於腔室91內移動,但並不限定於此。亦可如圖13所示般,藉由於腔室91設置複數之出口,而作成可變更積層片之路徑長的加熱裝置。如圖13(a)所示,將積層片依序架掛於輥93a、93b、94a、94b、95。其後,一邊搬送積層片、一邊進行加熱。此時,由出口914排出積層片40。 Further, in the above embodiment, the rollers 93a and 94a are provided to be movable in the chamber 91, but the invention is not limited thereto. As shown in Fig. 13, by providing a plurality of outlets in the chamber 91, a heating means for changing the path length of the laminated sheets can be formed. As shown in Fig. 13 (a), the laminated sheets are sequentially attached to the rollers 93a, 93b, 94a, 94b, 95. Thereafter, the laminate is conveyed while being heated. At this time, the laminated sheet 40 is discharged from the outlet 914.

接著,打開腔室91,將積層片40A架掛於輥93a、93b、94a,以變更積層片之路徑長。其後,如圖13(b)所示,一邊搬送積層片40A、一邊進行加熱。此時,係由出口914A排出積層片40A。 Next, the chamber 91 is opened, and the laminated sheet 40A is hung on the rollers 93a, 93b, and 94a to change the path length of the laminated sheet. Thereafter, as shown in FIG. 13(b), the laminated sheet 40A is conveyed while being heated. At this time, the laminated sheet 40A is discharged from the outlet 914A.

於此變化例中,係藉由輥93a、93b、94a、94b、95與複數之出口914、914A構成路徑長可變手段。 In this variation, the path length variable means is formed by the rollers 93a, 93b, 94a, 94b, 95 and the plurality of outlets 914, 914A.

另外,於此變化例中,積層片40、40A亦可不為一連串 的連續片材。 In addition, in this variation, the laminated sheets 40, 40A may not be a series Continuous sheet.

再者,於上述實施形態中,亦可不將積層片40、40A作成一連串之連續片材。 Further, in the above embodiment, the laminated sheets 40 and 40A may not be formed as a series of continuous sheets.

再者,上述實施形態中,雖未於加熱裝置30B中進行樹脂層的硬化,但並不限定於此,加熱裝置亦可進行樹脂層之乾燥。 Further, in the above embodiment, the resin layer is not cured in the heating device 30B, but the present invention is not limited thereto, and the heating device may perform drying of the resin layer.

另外,上述實施形態中,雖藉由加熱處理30B處理積層片40、及與此積層片40為相異樹脂層組成的積層片40A,但並不限定於此,亦可僅對積層片40藉加熱處理進行處理。例如,亦可在依圖2所示之輥配置於積層片40中對搬送方向上游側部分(第1積層片)進行加熱處理後,依圖3所示之輥配置於積層片40中對搬送方向下游側部分(第2積層片)進行加熱處理。如此,可連續地製造具有樹脂層之硬化反相異之複數區域的積層片。 Further, in the above-described embodiment, the laminated sheet 40 is processed by the heat treatment 30B, and the laminated sheet 40A composed of the different resin layers is not limited thereto, and only the laminated sheet 40 may be borrowed. Heat treatment for processing. For example, the upstream side portion (the first laminated sheet) in the transport direction may be heat-treated in the laminated sheet 40 by the roller shown in FIG. 2, and then placed in the laminated sheet 40 by the roller shown in FIG. The downstream side portion (the second laminated sheet) is subjected to heat treatment. In this manner, the laminated sheet having the plurality of hardened reverse phase regions of the resin layer can be continuously produced.

另外,上述實施形態中,雖於腔室91內使積層片水平地搬送,但並不限定於此,亦可於腔室91內沿著垂直方向(鉛垂方向)搬送積層片。例如,亦可將圖2之壁部911作為腔室之底面側,將壁部912作為腔室91之上面側。此時,輥93a、94a係於鉛垂方向上移動。 Further, in the above-described embodiment, the laminated sheet is conveyed horizontally in the chamber 91. However, the laminated sheet is not limited thereto, and the laminated sheet may be conveyed in the vertical direction (vertical direction) in the chamber 91. For example, the wall portion 911 of FIG. 2 may be the bottom side of the chamber, and the wall portion 912 may be the upper side of the chamber 91. At this time, the rollers 93a and 94a move in the vertical direction.

再者,上述實施形態中,輥93a、94a係藉馬達90進行旋轉驅動的搬送輥,但並不限定於此,亦可設為追隨積層片之搬送而進行旋轉的輔助輥(隨動輥)。 In the above-described embodiment, the rollers 93a and 94a are transport rollers that are rotationally driven by the motor 90. However, the present invention is not limited thereto, and may be an auxiliary roller (slave roller) that rotates following the conveyance of the laminated sheet. .

本發明係包括以下形態。 The present invention includes the following aspects.

(1)一種積層片製造裝置,係將具有可撓性之帶狀基材、與供給至該基材之單面或兩面之液狀或半固形狀之樹脂組成物進行加熱,而製造積層片者,其特徵為,具備:經供給了上述樹脂組成物之狀態的上述基材所通過的腔室;將上述腔室內加熱,使上述樹脂組成物之硬化進行的加熱手段;與在使上述基材通過上述腔室內時,使其通過路徑之長度為可變的路徑長可變手段。 (1) A laminated sheet manufacturing apparatus which heats a strip-shaped base material having a flexibility and a liquid or semi-solid resin composition supplied to one or both sides of the base material to produce a laminated sheet. The present invention includes a chamber through which the substrate is supplied in a state in which the resin composition is supplied, a heating means for heating the chamber to cure the resin composition, and a heating means When the material passes through the chamber, the length of the path is variable and the path length variable means.

(2)如(1)之積層片製造裝置,其中,上述路徑長可變手段係具有:設於上述腔室內,架掛並搬送上述基板的至少一對輥;上述一對輥可彼此接近‧離間,構成為藉由變更其軸間距離,可使上述通過路徑長度為可變。 (2) The apparatus for manufacturing a laminated sheet according to (1), wherein the path length changing means includes at least one pair of rollers provided in the chamber to hang and transport the substrate; the pair of rollers may approach each other. The separation is configured such that the length of the passage path is variable by changing the distance between the shafts.

(3)如(2)之積層片製造裝置,其中,上述一對輥中之一輥,係相對於上述腔室的位置呈固定,另一輥則相對於上述腔室可移動地被支撐,上述路徑長可變手段係具有在移動上述另一輥時,引導該另一輥的凸輪溝。 (3) The apparatus for manufacturing a laminated sheet according to (2), wherein one of the pair of rolls is fixed relative to the position of the chamber, and the other roll is movably supported relative to the chamber. The path length changing means has a cam groove for guiding the other roller when the other roller is moved.

(4)如(2)或(3)之積層片製造裝置,其中,上述軸間距離係可多階段或無階段地進行變更。 (4) The apparatus for manufacturing a laminated sheet according to (2) or (3), wherein the distance between the axes is changeable in a plurality of stages or in a stepless manner.

(5)如(2)至(4)中任一項之積層片製造裝置,其中,上述一對輥係彼此大小相同者。 (5) The laminated sheet manufacturing apparatus according to any one of (2) to (4) wherein the pair of rolls are the same size.

(6)如(2)至(5)中任一項之積層片製造裝置,其中,上述加熱手段係具有內藏於上述腔室之壁部中的加熱器。 (6) The laminated sheet manufacturing apparatus according to any one of (2) to (5) wherein the heating means has a heater housed in a wall portion of the chamber.

(7)如(1)至(6)中任一項之積層片製造裝置,其中,上述樹脂組成物係依液狀或半固形狀態供給至上述基材者;進一步具有一邊挾持上述基材與上述樹脂組成物而予以壓黏,一邊朝上述腔室送出的一對之供給用輥。 (7) The laminated sheet manufacturing apparatus according to any one of (1) to (6), wherein the resin composition is supplied to the substrate in a liquid or semi-solid state; further comprising: holding the substrate and The resin composition is pressed and adhered to a pair of supply rollers that are fed to the chamber.

本申請案係主張以2011年7月22日所申請之日本專利申請案2011-161020為基礎的優先權,將其揭示內容全部引用於此。 The present application claims priority based on Japanese Patent Application No. 2011-161020, filed on Jul. 22, 2011.

1、1a、1b、1c、1d、1e、1f‧‧‧預浸體 1, 1a, 1b, 1c, 1d, 1e, 1f‧‧‧ prepreg

2‧‧‧纖維基材(基材) 2‧‧‧Fiber substrate (substrate)

3、3A‧‧‧第1樹脂層(樹脂層) 3, 3A‧‧‧1st resin layer (resin layer)

4、4A‧‧‧第2樹脂層(樹脂層) 4, 4A‧‧‧2nd resin layer (resin layer)

5b‧‧‧第2片材 5b‧‧‧2nd sheet

6‧‧‧殼體 6‧‧‧Shell

8‧‧‧減壓手段 8‧‧‧Decompression

9‧‧‧硬化爐 9‧‧‧ Hardening furnace

10‧‧‧基板 10‧‧‧Substrate

11‧‧‧積層體 11‧‧‧Layer

12‧‧‧金屬層 12‧‧‧metal layer

13‧‧‧內層電路基板 13‧‧‧ Inner layer circuit board

20‧‧‧境界 20‧‧‧ Realm

30‧‧‧積層片製造裝置 30‧‧‧Laminated sheet manufacturing equipment

30A‧‧‧壓黏裝置 30A‧‧‧pressure bonding device

30B‧‧‧加熱裝置 30B‧‧‧heating device

31‧‧‧第1含浸部 31‧‧‧1st impregnation

32‧‧‧第1非含浸部 32‧‧‧1st Non-Immersion Department

40、40A‧‧‧積層片 40, 40A‧‧‧ layered film

41、42‧‧‧第2含浸部 41, 42‧‧‧2nd impregnation

42‧‧‧第2非含浸部 42‧‧‧2nd Non-Immersion Department

51‧‧‧保護片 51‧‧‧Protection film

52‧‧‧支撐基材 52‧‧‧Support substrate

61‧‧‧壁部 61‧‧‧ wall

62‧‧‧密封材 62‧‧‧ Sealing material

70‧‧‧空間 70‧‧‧ space

71a、71b‧‧‧第1輥 71a, 71b‧‧‧1st roll

72a、72b‧‧‧第2輥(供給用輥) 72a, 72b‧‧‧ second roller (supply roller)

73a、73b‧‧‧第3輥 73a, 73b‧‧‧3rd roller

74‧‧‧本體部 74‧‧‧ Body Department

75‧‧‧軸 75‧‧‧Axis

76‧‧‧軸承 76‧‧‧ bearing

81‧‧‧泵 81‧‧‧ pump

82‧‧‧連接管 82‧‧‧Connecting tube

90‧‧‧馬達 90‧‧‧Motor

91‧‧‧腔室 91‧‧‧ chamber

92‧‧‧加熱手段(加熱器) 92‧‧‧heating means (heater)

93a、93b‧‧‧第1輥 93a, 93b‧‧‧1st roll

94a、94b‧‧‧第2輥 94a, 94b‧‧‧2nd roller

95‧‧‧第3輥 95‧‧‧3rd roller

96‧‧‧內部空間 96‧‧‧Internal space

97‧‧‧本體部 97‧‧‧ Body Department

98‧‧‧軸部 98‧‧‧Axis

99‧‧‧線性滑軌道 99‧‧‧Linear slide track

100‧‧‧半導體裝置 100‧‧‧Semiconductor device

200‧‧‧多層基板 200‧‧‧Multilayer substrate

201a、201b、201d、201e‧‧‧電路部 201a, 201b, 201d, 201e‧‧‧ Circuit Department

202、203‧‧‧導體部 202, 203‧‧‧ conductor

300‧‧‧墊部 300‧‧‧Mats

400‧‧‧佈線部 400‧‧‧Wiring Department

500‧‧‧半導體元件 500‧‧‧Semiconductor components

501‧‧‧凸塊 501‧‧‧Bumps

611‧‧‧開口部 611‧‧‧ openings

612‧‧‧環狀凹部 612‧‧‧ annular recess

741‧‧‧外周面 741‧‧‧ outer perimeter

900‧‧‧被覆構件 900‧‧‧covered components

911、912‧‧‧壁部 911, 912‧‧‧ wall

913‧‧‧入口 913‧‧‧ entrance

914、914A‧‧‧出口 914, 914A‧‧ exports

915、916‧‧‧凸輪溝 915, 916‧‧‧ cam groove

917、918‧‧‧壁部 917, 918‧‧‧ wall

971‧‧‧外周面 971‧‧‧ outer perimeter

991‧‧‧引導軌道 991‧‧‧ Guided track

992‧‧‧滑件 992‧‧‧Sliding parts

993‧‧‧螺旋軸 993‧‧‧Spiral axis

994‧‧‧馬達 994‧‧‧Motor

995‧‧‧螺帽 995‧‧‧ nuts

F1‧‧‧抵接力 F1‧‧‧Resistance

F2‧‧‧減壓力 F2‧‧‧Reducing pressure

G‧‧‧空氣 G‧‧‧Air

R‧‧‧軌道 R‧‧ track

圖1為表示本發明之積層片之製造裝置之實施形態的概略剖面側面圖(依序表示製造本發明之積層片時之製造過程的圖)。 Fig. 1 is a schematic cross-sectional side view showing an embodiment of a manufacturing apparatus for a laminated sheet according to the present invention (a view showing a manufacturing process in the case of producing a laminated sheet of the present invention).

圖2為表示本發明之積層片之製造裝置之實施形態的概略剖面側面圖(依序表示製造本發明之積層片時之製造過程的圖)。 Fig. 2 is a schematic cross-sectional side view showing an embodiment of a manufacturing apparatus for a laminated sheet according to the present invention (a view showing a manufacturing process in the case of producing a laminated sheet of the present invention).

圖3為表示本發明之積層片之製造裝置之實施形態的概略剖面側面圖(依序表示製造本發明之積層片時之製造過程的圖)。 Fig. 3 is a schematic cross-sectional side view showing an embodiment of a manufacturing apparatus for a laminated sheet according to the present invention (a view showing a manufacturing process in the case of producing a laminated sheet of the present invention).

圖4為圖1中之A-A線剖面圖。 Figure 4 is a cross-sectional view taken along line A-A of Figure 1.

圖5為圖1中之B-B線剖面圖。 Figure 5 is a cross-sectional view taken along line B-B of Figure 1.

圖6為圖1中由單點虛線所包圍之區域[C]的放大圖。 Fig. 6 is an enlarged view of a region [C] surrounded by a single dotted line in Fig. 1.

圖7為圖2及圖3所示之積層片製造裝置中之硬化爐的分解立體圖。 Fig. 7 is an exploded perspective view showing the hardening furnace in the laminated sheet manufacturing apparatus shown in Figs. 2 and 3;

圖8為表示本發明之積層片的剖面圖。 Figure 8 is a cross-sectional view showing a laminated sheet of the present invention.

圖9為表示使用圖8所示之積層片所製造之基板的剖面圖。 Fig. 9 is a cross-sectional view showing a substrate produced by using the laminated sheet shown in Fig. 8.

圖10為表示使用圖9所示之基板所製造之半導體裝置的剖面圖。 Fig. 10 is a cross-sectional view showing a semiconductor device manufactured using the substrate shown in Fig. 9.

圖11(a)及(b)係表示腔室內之輥之移動狀態的平面圖。 Figures 11 (a) and (b) are plan views showing the movement state of the rolls in the chamber.

圖12(a)至(c)係由腔室側面側所觀看的圖,表示隨著輥移動而遮蔽構件進行移動之樣子的圖。 Fig. 12 (a) to (c) are views as seen from the side surface side of the chamber, showing a state in which the shield member is moved as the roller moves.

圖13(a)及(b)係表示本案發明之變化例的圖。 Fig. 13 (a) and (b) are views showing a modification of the invention of the present invention.

9‧‧‧硬化爐 9‧‧‧ Hardening furnace

30B‧‧‧加熱裝置 30B‧‧‧heating device

40‧‧‧積層片 40‧‧‧Layered film

40A‧‧‧積層片 40A‧‧‧Layered film

91‧‧‧腔室 91‧‧‧ chamber

92‧‧‧加熱手段(加熱器) 92‧‧‧heating means (heater)

93a‧‧‧第1輥 93a‧‧‧1st roll

93b‧‧‧第1輥 93b‧‧‧1st roll

94a‧‧‧第2輥 94a‧‧‧2nd roller

94b‧‧‧第2輥 94b‧‧‧2nd roller

95‧‧‧第3輥 95‧‧‧3rd roller

96‧‧‧內部空間 96‧‧‧Internal space

97‧‧‧本體部 97‧‧‧ Body Department

911‧‧‧壁部 911‧‧‧ wall

912‧‧‧壁部 912‧‧‧ wall

913‧‧‧入口 913‧‧‧ entrance

914‧‧‧出口 914‧‧‧Export

915‧‧‧凸輪溝 915‧‧‧ cam groove

916‧‧‧凸輪溝 916‧‧‧ cam groove

917‧‧‧壁部 917‧‧‧ wall

971‧‧‧外周面 971‧‧‧ outer perimeter

Claims (15)

一種積層片製造裝置,係將具備具有可撓性之帶狀基材、與供給至該基材之單面或兩面之樹脂組成物的積層片進行加熱而製造積層片者,其具備:上述積層片所通過的腔室;將上述腔室內加熱,以對上述積層片加熱的加熱手段;與使上述積層片通過上述腔室內時之通過路徑之長度為可變的路徑長可變手段。 A laminated sheet manufacturing apparatus which is provided with a flexible tape-shaped base material and a laminated sheet of a resin composition supplied to one side or both surfaces of the base material to produce a laminated sheet, comprising: the above-mentioned laminated layer a chamber through which the sheet passes; a heating means for heating the chamber to heat the laminated sheet; and a path length variable means for changing a length of a passage path when the laminated sheet passes through the chamber. 如申請專利範圍第1項之積層片製造裝置,其中,上述樹脂組成物為熱硬化性;上述加熱手段係對上述積層片之上述樹脂組成物進行加熱而使硬化進行。 The laminated sheet manufacturing apparatus according to the first aspect of the invention, wherein the resin composition is thermosetting, and the heating means heats the resin composition of the laminated sheet to be cured. 如申請專利範圍第1項之積層片製造裝置,其中,上述基材為無機織布或有機纖維基材。 The laminated sheet manufacturing apparatus according to the first aspect of the invention, wherein the substrate is an inorganic woven fabric or an organic fibrous base material. 如申請專利範圍第1項之積層片製造裝置,其中,上述路徑長可變手段係具備:配置於上述腔室內的第1輥;與使上述第1輥於上述腔室內移動的移動手段;該積層片製造裝置係構成為使上述積層片朝上述第1輥搬送;上述路徑長可變手段係於上述第1輥上之上述積層片之與上述搬送方向呈交叉的方向,藉上述移動手段使上述第1 輥移動,而使上述積層片之通過路徑長度成為可變。 The apparatus for manufacturing a laminated sheet according to the first aspect of the invention, wherein the path length variable means includes: a first roller disposed in the chamber; and a moving means for moving the first roller in the chamber; The laminated sheet manufacturing apparatus is configured to convey the laminated sheet to the first roller, and the path length changing means is configured such that the laminated sheet on the first roller intersects with the conveying direction by the moving means Above 1st The roller moves to make the passage length of the laminated sheet variable. 如申請專利範圍第1項之積層片製造裝置,其中,上述路徑長可變手段係具備:配置於上述腔室內並抵接上述積層片之第1輥;與使上述第1輥於上述腔室內移動的移動手段;上述移動手段係沿著在上述腔室內所搬送之上述積層片之抵接於上述第1輥之部分的厚度方向,使上述第1輥移動;上述路徑長可變手段係藉由上述移動手段,使上述第1輥於上述積層片之厚度方向移動,而使上述積層片之通過路徑長度成為可變。 The apparatus for manufacturing a laminated sheet according to the first aspect of the invention, wherein the path length changing means includes: a first roller disposed in the chamber to abut against the laminated sheet; and the first roller being disposed in the chamber The moving means for moving the first roller along a thickness direction of a portion of the laminated sheet that is conveyed in the chamber to contact the first roller; and the path length variable means The moving means moves the first roller in the thickness direction of the laminated sheet to change the passage length of the laminated sheet. 如申請專利範圍第4項之積層片製造裝置,其中,上述路徑長可變手段係具備:抵接於上述積層片之一面的上述第1輥;與抵接於上述積層片之另一面的第2輥;其構成為藉由上述移動手段使上述第1輥移動,俾使抵接上述積層片之一面的上述第1輥及抵接上述積層片之另一面的上述第2輥間的軸間距離變更,而使上述通過路徑之長度成為可變。 The apparatus for manufacturing a laminated sheet according to the fourth aspect of the invention, wherein the path length changing means includes: the first roller that abuts against one surface of the laminated sheet; and the first surface that abuts against the other surface of the laminated sheet a two-roller configured to move the first roller by the moving means to knead between the first roller that abuts one surface of the laminated sheet and the second roller that abuts the other surface of the laminated sheet The distance is changed, and the length of the passage path described above is made variable. 如申請專利範圍第6項之積層片製造裝置,其中,上述第2輥係配置於較上述第1輥更靠上述積層片之搬送方向下游側;上述第2輥係相對於上述腔室的位置呈固定。 The apparatus for manufacturing a laminated sheet according to the sixth aspect of the invention, wherein the second roller is disposed on a downstream side of the first roller in a conveying direction of the laminated sheet, and a position of the second roller relative to the chamber Fixed. 如申請專利範圍第4項之積層片製造裝置,其中,於上 述腔室的壁部,形成有引導上述第1輥之移動、並貫通上述壁部的引導溝;上述路徑長可變手段之上述移動手段,係配置於上述腔室之外部。 The apparatus for manufacturing a laminated sheet according to item 4 of the patent application, wherein The wall portion of the chamber is formed with a guide groove for guiding the movement of the first roller and penetrating the wall portion, and the moving means for the path length variable means is disposed outside the chamber. 如申請專利範圍第8項之積層片製造裝置,其中,上述移動手段係具備:軌道;配置於上述軌道上,連接於上述第1輥的滑件;與用於使該滑件於上述軌道上移動的馬達;其構成為藉由上述馬達,使上述滑件於上述軌道上移動,俾移動上述第1輥。 The apparatus for manufacturing a laminated sheet according to the eighth aspect of the invention, wherein the moving means comprises: a rail; a slider disposed on the rail and connected to the first roller; and a slider for the slider a moving motor configured to move the slider on the rail by the motor to move the first roller. 如申請專利範圍第8項之積層片製造裝置,其中,上述第1輥係具有:和積層片相接的本體部、與設於該本體部的軸部;上述軸部係經由上述引導溝連接至上述移動手段;並具備有被覆構件,其係由上述軸部所貫通,並從上述壁部之外側或內側被覆上述引導溝。 The laminated sheet manufacturing apparatus according to the eighth aspect of the invention, wherein the first roller system includes: a main body portion that is in contact with the laminated sheet; and a shaft portion that is provided in the main body portion; and the shaft portion is connected via the guide groove The moving means is provided, and the covering member is penetrated by the shaft portion, and the guiding groove is covered from the outer side or the inner side of the wall portion. 如申請專利範圍第4項之積層片製造裝置,其中,上述積層片製造裝置係構成為一邊於上述腔室內搬送上述積層片,一邊將抵接於上述積層片之上述第1輥藉上述移動手段進行移動。 The laminated sheet manufacturing apparatus according to the fourth aspect of the invention, wherein the laminated sheet manufacturing apparatus is configured to transfer the first roll that abuts the laminated sheet while the laminated sheet is conveyed in the chamber Move. 如申請專利範圍第1項之積層片製造裝置,其中,上 述加熱手段係對上述積層片進行加熱並使上述樹脂組成物含浸於上述基材中。 For example, the laminated sheet manufacturing apparatus of the first application of the patent scope, wherein In the heating means, the laminated sheet is heated and the resin composition is impregnated into the substrate. 如申請專利範圍第1項之積層片製造裝置,其中,上述樹脂組成物係依液狀或半固形狀態供給至上述基材;進一步具備有:一邊將上述基材與上述樹脂組成物挾持並壓黏,一邊朝上述腔室送出的一對之供給用輥。 The laminated sheet manufacturing apparatus according to the first aspect of the invention, wherein the resin composition is supplied to the substrate in a liquid or semi-solid state, and further comprising: pressing and pressing the substrate and the resin composition A pair of supply rollers that are fed toward the chamber. 一種積層片之製造方法,該積層片具備第1積層片與第2積層片,該製造方法係包括:第1加熱步驟,係使第1積層片依第1通過路徑長度,一邊通過腔室內、一邊進行加熱,該第1積層片具備屬於具有可撓性之帶狀之無機織布或有機纖維基材的基材、與供給至該基材之單面或兩面之樹脂組成物;與第2加熱步驟,係使第2積層片依與上述第1通過路徑長度相異之第2通過路徑長度,一邊通過上述腔室內、一邊進行加熱,該第2積層片具備屬於具有可撓性之帶狀之無機織布或有機纖維基材的基材、與供給至該基材之單面或兩面之樹脂組成物。 A method for producing a laminated sheet comprising a first laminated sheet and a second laminated sheet, the manufacturing method comprising: a first heating step of passing the first laminated sheet through the chamber according to the length of the first passage path; The first laminate sheet is provided with a base material belonging to a flexible ribbon-shaped inorganic woven fabric or an organic fiber base material, and a resin composition supplied to one or both sides of the base material, and the second laminate sheet; In the heating step, the second laminate sheet is heated while passing through the chamber in accordance with the length of the second passage path different from the length of the first passage path, and the second laminate sheet is provided with a flexible strip shape. A substrate of an inorganic woven fabric or an organic fiber substrate, and a resin composition supplied to one or both sides of the substrate. 如申請專利範圍第14項之積層片之製造方法,其中,上述第2積層片係與上述第1積層片連續設置;在上述第1加熱步驟與第2加熱步驟之間,實施下述步驟:不打開上述腔室,使配置於上述腔室內、抵接上述第1積層片或上述第2積層片的第1輥於上述第1積層片或上述 第2積層片的厚度方向移動,而將通過路徑之長度由上述第1通過路徑之長度變更為第2通過路徑之長度。 The method for producing a laminated sheet according to claim 14, wherein the second laminated sheet is continuously provided with the first laminated sheet; and between the first heating step and the second heating step, the following steps are performed: Opening the chamber, and placing the first roller disposed in the chamber to contact the first laminated sheet or the second laminated sheet on the first laminated sheet or the above The second laminated sheet is moved in the thickness direction, and the length of the passing path is changed from the length of the first passing path to the length of the second passing path.
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