TW201249338A

TW201249338A - Particulate pesticide composition

Info

Publication number: TW201249338A
Application number: TW101114655A
Authority: TW
Inventors: Hideo Kawanaka; Motofumi Mizutani
Original assignee: Sumitomo Chemical Co
Priority date: 2011-04-27
Filing date: 2012-04-25
Publication date: 2012-12-16
Also published as: WO2012147979A1; KR101944560B1; TWI524845B; KR20140027287A; CN103501600A; CN103501600B; JP2012229182A; JP5842374B2

Abstract

This invention relates a particulate pesticide composition containing a pesticide active compound having a chemical structure containing an anilinocarbonyl moiety, and at least one magnesium compound selected from the group consisting of magnesium oxide, magnesium phosphate and magnesium hydroxide. The particulate pesticide composition of this invention is an excellent composition that exhibits desired pesticide activity rapidly because the pesticide active compound dissolves rapidly after applying.

Description

201249338 六、發明說明：【發明所屬之技術領域】本發明係有關含有特定農藥活性化合物及特定鎂化入物之粒狀農藥組成物。【先前技術】於例如日本特開2006-249020中已知含有具有笨胺烏羰基部分之化學構造之農藥活性化合物之農藥粒劑。又，於例如日本特開昭64-4、特開平5-271021及特開平 1-207205中已知含有氧化鎂化合物之組成物。【發明内容】本發明以提供含有具有苯胺基羰基部分之化學構造之農藥活性化合物，在施用時，該農藥活性化合物迅迷溶之粒狀組成物為課題。出具有笨胺基本案發明人等研究上述課題之結果發現，羰基部分作為部分構造之農藥活性化合物若與特定之錢& 成因合物組合，作成粒狀製劑使用，則在施用後’作為活性分之該農藥活性化合物迅速溶出，可發揮卓越之欵果，而完成本發明。以下為本發明。 [1]含有：具備含有苯胺基羰基部分之化學構造之農藥活性化合物及一種以上選自由氧化鎂、磷酸鎂及氫氧化鎂所成群組之錢化合物 324206 3 201249338 之粒狀農藥組成物（以下，稱為本發明組成物）。 [2]上述項[1]記載之粒狀農藥組成物，其中，係為粒劑者。上述項[1]或項⑵記載之粒狀農藥組成物，其中，該農藥活性化合物為醯替苯胺殺菌劑。 [4] 上述項[3]記載之粒狀農藥組成物，其中，該醯替苯胺殺菌劑為異嘴菌胺（isotianil)或魏滅（Thifiu細制。 [5] 上述項[1]至項⑷中任何—項記載之粒狀農藥組成物，其中，該鎂化合物為氧化鎂。 [6] 上述項[1]至項[5]中任何一項記載之粒狀農藥組成物，其中，該農藥活性化合物及鎂化合物被包覆在核粒中。 [7] 有害生物防治方法，為將上述項[丨]至項[6]中任何一項 5己載之粒狀農藥組成物在水田或育苗箱施用。【實施方式】本發明組成物中含有之具備含有苯胺基羰基部分之化學構造之農藥活性化合物（以下，稱為本農藥化合物）為具有式 -CO— Π 表示之苯胺基羰基部分（又，苯環可具有取代基）之化學構造之農藥活性化合物，可列舉例如酿替苯胺殺菌劑’具體而言’可列舉式（1)表示之異噻菌胺、201249338 6. DISCLOSURE OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a granular pesticide composition containing a specific pesticidal active compound and a specific magnesiumated product. [Prior Art] A pesticide granule containing a pesticidal active compound having a chemical structure of a sulfazone moiety is known, for example, from JP-A-2006-249020. Further, a composition containing a magnesium oxide compound is known, for example, from JP-A-64-4, JP-A-5-271021, and JP-A-1-207205. SUMMARY OF THE INVENTION The present invention has been made in an effort to provide a pesticidal active compound having a chemical structure having an anilinocarbonyl moiety, and a particulate composition in which the pesticidal active compound is rapidly dissolved at the time of application. As a result of research on the above-mentioned problems, the inventors of the basic case of the stupid amine have found that the carbonyl moiety is used as a partially active pesticidal active compound in combination with a specific money & a caustic compound, and is used as a granular preparation. The present invention can be completed by rapidly dissolving the agrochemical active compound and exerting excellent results. The following is the invention. [1] Containing: a pesticidal active compound having a chemical structure containing an anilinocarbonyl moiety and one or more granular pesticide compositions selected from the group consisting of magnesium oxide, magnesium phosphate, and magnesium hydroxide 324206 3 201249338 (hereinafter , referred to as the composition of the present invention). [2] The granular pesticide composition according to the above [1], which is a granule. The granular pesticide composition according to the above item [1], wherein the agrochemical active compound is a guanidine bactericide. [4] The granular pesticide composition according to the above [3], wherein the anilide bactericide is isotianil or weichen (Thifiu fine. [5] the above item [1] to the item The granular pesticide composition according to any one of the above-mentioned items, wherein the particulate pesticide composition according to any one of the above-mentioned items, wherein The pesticidal active compound and the magnesium compound are coated in the nucleus. [7] The pest control method is the particulate pesticide composition contained in any one of the above items [丨] to [6] in the paddy field or The seedling box is applied. The pesticidal active compound having a chemical structure containing an anilinocarbonyl moiety (hereinafter referred to as the present pesticide compound) contained in the composition of the present invention is an anilinocarbonyl moiety represented by the formula -CO-? The agrochemical active compound having a chemical structure of (the benzene ring may have a substituent) may, for example, be a specific amount of the anilide, and the specific form of the fungicide may be exemplified by the formula (1).

324206 201249338324206 201249338

ClCl

式（2)表示之赛氟滅 B「Formula (2) represents the cyanofluorin B"

本農藥化合物在本發明組成物中通常含有0.1至 75%，較好含有0. 5至60重量％。本發明組成物中含有之鎂化合物（以下，稱為本鎂化合物）為1種以上選自由氧化鎂、磷酸鎂及氫氧化鎂所成之群組。本鎂化合物中較好為氧化鎂。本鎂化合物亦包含水合物之形態，可列舉例如填酸鎮八水合物。本鎂化合物在本發明組成物中通常含有0. 05至50重量％，較好含有0. 2至40重量％。於本發明組成物中，本鎂化合物相對於本農藥化合物1重量份，通常含有0. 1至30 重量份之比率。本發明組成物另可含有本農藥化合物以外之農藥活性化合物。相關之農藥活性化合物可列舉殺蟲活性化合物、5至60重量百分比。 The present invention, the present invention, the composition of the present invention is usually from 0.1 to 75%, preferably from 0.5 to 60% by weight. The magnesium compound (hereinafter referred to as the present magnesium compound) contained in the composition of the present invention is one or more selected from the group consisting of magnesium oxide, magnesium phosphate, and magnesium hydroxide. Magnesium oxide is preferred among the present magnesium compounds. The magnesium compound also contains a form of a hydrate, and examples thereof include acid-filled octahydrate. 2至40重量百分比。 The present invention, the composition of the present invention is usually from 0. 05 to 50% by weight, preferably from 0.2 to 40% by weight. 1至30重量份的百分比之间。 The present invention, the present invention, the present invention, the present invention, the present invention, the present invention The composition of the present invention may further contain a pesticidally active compound other than the present pesticidal compound. Related pesticidal active compounds can be listed as insecticidal active compounds,

324206 5 S 201249338 殺菌活性化合物、除草活性化合物、植物成長調節活性化合物、驅蟲活性化合物。以下，呈示其具體之化合物。殺蟲活性化合物：賽扶寧（Cyfluthrin)、賽滅寧（Cypermethrin)、第滅寧 (Deltamethrin)、芬普寧（Fenpropathrin)、益化利 (Esfenvalerate)、泰滅寧（Tralomethrin)、阿納寧 (Acrinathrin)、畢芬寧（Bifenthrin)、列滅寧（Resmethrin)、治滅寧（Tetramethrin)等除蟲菊精化合物；殘殺威 (Propoxur)、異丙威（Isoprocarb)、滅殺威（Xylylcarb)、滅多威（Metolcarb)、XMC、加保利（Carbaryl)、比加普 (Pirimicarb)、卡巴σ夫0南（Carbofuran)、納乃得（Methomy 1)、殿殺滅（Oxamyl)、苯氧威（Fenoxycarb)、棉鈴威 (Alanycarb)、惡盘酮（Metoxadiazone)、免扶克 (Benfuracarb)、丁基加保扶（Carbosulfan)、°夫線威 (Furathiocarb)、PHC、惡蟲威（Bendiocarb)等胺基曱酸酯化合物；跋殺松（Acephate)、赛達松（Phenthoate)、繁米松（Vamidothion)、三氣松（Trichlorfon)、亞素靈 (Monocrotophos)、殺蟲威（Tetrachlorvi叩hos)、曱基毒蟲畏（Dimethylvinphos)、松必爽粉（Phosalone)、毒死碑 (Chlorpyrifos)、曱基毒死蜱（Chlorpyrifos methyl)、必芬松（Pyridaphenthion)、拜裕松（Quinalphos)、滅大松 (Methidathion)、達馬松（Methamidophos)、大滅松 (Dimethoate)、乙基硫滅松（Ethyl thiometon)、加護松 324206 ⑧ 201249338 (Propaphos)、費莫松、乙基谷速松（Azi叩hos ethyl)、甲基谷速松（Azinphos methyl)、殺力松（Salithion)等有機鱗化合物；二福隆（Diflubenzuron)、克福隆 (Chlorfluazuron)、祿芬隆（Lufenuron)、六伏隆 (Hexaflumuron)、篆芬隆（Flufenoxuron)、氟瞒脲 (Flucycloxuron)、赛滅淨（Cyromazine)、汰芬隆 (Diafenthiuron)、合赛多（Hexythiazox)、諾伐隆 (Novaluron)、得福隆（Teflubenzuron)、殺鈴腺 (Triflumuron)、4-氯-2-(2-氯-2-甲基丙基）-5-(6-碘-3-°比啶基曱氧基）噠嗪-3(2H)-酮、1-(2, 6-二氟苯醯基）-3-[2-氟-5-(二乱曱基）本基]脈、1_(2, 6-二氟苯酿基）-3-[2-氟-4-(1，1，2, 3, 3, 3-六氟丙氧基）苯基]脲、2-第三丁基亞胺基-3-異丙基-5-笨基-3, 4, 5, 6-四氫-2H-1，3, 5-噻二嗓 -4-闕、1-(2, 6-· — 氟本酿基）-3-[2-iL-4-(l，1，2，2-四氟乙軋基）苯基]脲等具有殼質合成抑制活性之脲化合物；5-胺基-4-二氯氟甲基硫醯基-1-(2, 6-二氯-4-二氟曱基苯基） °比唑、5-胺基-1-(2, 6-二氣-4-三氟甲基苯基）-4-三氟曱基硫醯基α比峻等°比°坐化合物；益達胺（Imidacloprid)、亞滅培（Acetamiprid)、烯啶蟲胺（Nitenpyram)、大可定 (Diacloden)、可尼丁（ciothianidin)、賽速安 (Thiamethoxam)、達特南（Dinotefuran)、赛果培 (Thiacloprid)等氯尼古丁（Chloronicotinyl)化合物；賜諾殺（Spinosad)等巨内酯化合物；培丹（Cartap)鹽酸鹽、布芬淨（Buprofezin)、硫賜安（Thiocyclam)、芬諾克 324206 7 201249338 (Fenoxycarb)、芬殺蜗（Fenazaquin)、芬普瞒 (Fenpyroximate)、畢達本（Pyridaben)、百利普芬 (Pyriproxyfen)、芬普尼（Fipronil)、乙蟲晴（Ethipro 1 e)、乙醯蟲晴（Acetoprole)、二嗓農（Diazinon)、愛美松 (Hydramethylnon)、硫敵克（Thiodicarb)、克凡派 (Chlorfenapyr)、芬普瞒（Fenpyroximate)、派滅淨 (Pymetrozine)、畢汰芬（Pyrimidifen)、得芬諾 (Tebufenozide)、得芬瑞（Tebufenpyrad) 、 °坐财威 (Triazamate)、因得克（Indoxacarb)、氰蟲胺（Sulfluramid)、密滅汀（Milbemectin)、阿佛菌素（Avermectin)、克芬瞒 (Clofentezine)、硼酸、對二氣苯。殺菌活性化合物：苯菌靈（Benomyl)、貝芬替（Carbendazim)、°塞菌靈 (Thiabendazole)、曱基多保淨（Thiophanate methyl)等笨并咪°坐化合物；乙霉威（Diethofencarb)等苯基胺基曱酸酯化合物；秋蘭姆（Thiuram)等二硫代胺基甲酸酯化合物；撲滅寧（Procymidone)、依普同（Iprodione)、免克寧 (Vinclozolin)等二甲醯亞胺化合物；達克利（Diniconazole)、依普座（Epoxiconazole)、得克利（Tebuconazole)、待克利 (Difenoconazole)、環克座（Cyproconazole)、護矽得 (Flusilazole)、三泰芬（Triadimefon)、菲克利 (Hexaconazole)等唑化合物；滅達樂（Metalaxy 1)等醯基丙胺酸化合物，福拉比（Furametpyr)、滅普寧（Mepronil)、噻醢菌胺（Tiadinil)、福多寧（Flutolanil)、賽氟滅 324206 ⑧ 201249338 (Thifluzamide)等敌基醯胺化合物；脫克松（Tolclofos-methyl)、福賽得（Fosetyl-aluminum)、白粉松（Pyrazophos) 等有機磷化合物；護汰寧（Fludioxonil)、拌種咯 (Fenpiclonil)等氰基β比洛化合物；稻瘟素S(Blasticidin-S)、春日黴素（Kasugamycin)、保粒黴素（Polyoxin)、有效黴素（Validamycin)、米多霉素（Mildiomycin)等抗生物質；克收欣（Kresoxim-methyl)、苯氧菌胺（Metominostrobin) 等曱氧基丙烯酸酯化合物；歐殺斯（Oxadixyl)、PCNB、土菌消（Hydroxyisoxazole)、邁隆（Dazomet)、達滅淨 (Diclomezine)、三0秦、亞賜圃（Isoprothiolane)、雙氯氰菌胺（Diclocymet)、肪鍵菌胺（Orysastrobin)、加普胺 (Carpropamid)、四氯異苯腈（Chlorothalonil)、鋅锰乃浦 (Manzeb)、蓋普丹（Captan)、滅菌丹（Folpet)、快得寧 (Oxine-copper)、驗性氯化銅、三赛°坐（Tricyclazole)、百快隆（Pyroquilon)、撲殺熱（Probenazole)、熱必斯 (Fthalide)、曱嘆活素（Acibenzolar S methyl)、克絕 (Cymoxanil)、達滅芬（Dimethomorph)、S-曱基苯并[1· 2. 3] 嗟二唾-7-硫幾酸酯、凡殺同（Famoxadone)、歐索林酸 (Oxolinic acid)、扶吉胺（Fluazinam)、克氯綜 (Chlobenthiazone)、依索巴雷酮（Isovaledione)、石夕氟〇坐 (Simeconazole)、四氯異苯腈 (Tetrachloroisophthalonitrile)、硫代鄰苯二甲亞胺氧代雙吩°惡胂（Thiophthalimide oxybisphenoxarsine)、3- 碘-2-丙基丁基胺基曱酸酯、銀沸石、矽膠銀、磷酸錘銀鹽、 324206 9 201249338 對羥基苯甲酸酯、去氫乙酸鈉、山梨酸鉀。除草活性化合物：阿特拉津（Atrazine)、滅必淨（Metribuzin)等三嗪化合物、伏草隆（Fluometuron)、異丙隆（Isoproturon)、殺草隆 (Daimuron)等腺化合物；漠塞尼爾（Bromoxyni 1)、峨塞尼爾 (Ioxyni 1)等經基苯腈化合物；施得圃（Pendimethalin)、三福林（Trif luralin)等2, 6-二硝基苯胺化合物；2, 4-D、麥草畏（Dicamba)、氟氣比（Fluroxypyr)、二曱四氣丙酸 (Mecoprop)等烯丙氧基烷酸化合物；苄嘧黃隆 (Bensulfuron-methyl)、甲黃隆（Metsulfuron-methyl)、煙响石黃隆（Nicosulfuron)、氟0密石黃隆-曱酯 (Primisulfuron-methyl)、環磺隆（Cyclosulfamuron)、依速隆（Imazosulfuron)、1-(2-氣-6-丙基0米吐[1,2-b]0 比0秦 -3_基續酿基）-3_(4，6-二甲氧基-。密咬·^-基）脈等續酿基脲化合物；依滅草（Imazapyr)、滅草啥（Imazaquin)、咪草煙（Imazethapyr)等味。坐琳酮化合物；雙草醚鈉鹽 (Bispyribac-sodium)、雙硫醚鈉鹽（Bisthiobac sodium)、亞喜芬納鹽（Acifluorfen sodium)、曱石黃草胺 (Sulfentrazone)、百草枯（Paraquat)、唾 σ密續草胺 (Flumetsulam)、氟胺續隆（Triflusulfuron-methyl)、精惡嗤禾草靈（Fenoxaprop-p-ethyl)、丁基赛伏草 (Cyhalofop-butyl)、°比氟草胺（Diflufenican)、氟草敏 (Norflurazon)、異噁氣草酮（Isoxachlortole)、本達隆 (Bentazone)、禾草丹（Benthiocarb)、滅芬草（Mefenacet)、 324206 10324206 5 S 201249338 Bactericidal active compounds, herbicidal active compounds, plant growth regulating active compounds, insect repellent active compounds. Hereinafter, specific compounds thereof are presented. Insecticidal active compounds: Cyfluthrin, Cypermethrin, Deltamethrin, Fenpropathrin, Esfenvalerate, Tralomethrin, Arrinathrin ), bifenthrin, Resmethrin, Tetramethrin and other pyrethroid compounds; Propoxur, Isoprocarb, Xylylcarb, and methomyl ( Metolcarb), XMC, Carbaryl, Pirimicarb, Carbofuran, Methomy 1, Oxamyl, Fenoxycarb, Cotton Boll Amino phthalate such as Alanycarb, Metoxadiazone, Benfuracarb, Carbosulfan, Furathiocarb, PHC, Bendiocarb Compounds; Acephate, Phenthoate, Vamidothion, Trichlorfon, Monocrotophos, Tetrachlorvi叩hos, Thioglyx (Dimethylvinphos), Song Bishuang (Phosalone), Chlorpyrifos, Chlorpyrifos methyl, Pyridaphenthion, Quinalphos, Methidathion, Methamidophos, Dasong ( Dimethoate), Ethyl thiometon, Panasonic 324206 8 201249338 (Propaphos), Fermson, Azi叩hos ethyl, Azinphos methyl, killing power Organic scaly compounds such as Salithion; Diflubenzuron, Chlorfluazuron, Lufenuron, Hexaflumuron, Flufenoxuron, Flucycloxuron Cyromazine, Diafenthiuron, Hexythiazox, Novaluron, Teflubenzuron, Triflumuron, 4-chloro-2-( 2-chloro-2-methylpropyl)-5-(6-iodo-3-°pyridinyloxy)pyridazine-3(2H)-one, 1-(2,6-difluorophenylhydrazine Benzyl-3-(2-fluoro-5-(2)-[2-fluoro-4-(1,1,1,6-difluorophenyl) 2, 3, 3, 3-hexafluoropropoxy)benzene Urea, 2-telebutylimido-3-isopropyl-5-phenyl-3,4,5,6-tetrahydro-2H-1,3,5-thiadiindole-4-indole , 1-(2, 6-·-fluorobenzyl)-3-[2-iL-4-(l,1,2,2-tetrafluoroethane)phenyl]urea, etc. have chitin synthesis inhibition Active urea compound; 5-amino-4-dichlorofluoromethylthiomethyl-1-(2,6-dichloro-4-difluorodecylphenyl) ° azole, 5-amino-1 -(2,6-dioxa-4-trifluoromethylphenyl)-4-trifluoromethylsulfonyl α is a compound of the same ratio; Imidacloprid, Acetamiprid ), Nitenpyram, Diacloden, ciothianidin, Thiamethoxam, Dinotefuran, Thiaclocrid, and other Chloronicotinyl Compounds; macrolide compounds such as Spinosad; Cartap hydrochloride, Buprofezin, Thiocyclam, Fenoke 324206 7 201249338 (Fenoxycarb), fennel worm (Fenazaquin), Fenpyroximate, Pyridaben, Pyriproxyfen, Fipronil, B Ethipro 1 e, Acetoprole, Diaznon, Hydramethylnon, Thiodicarb, Chlorfenapyr, Fenpyroximate, Pai Pyrmetrozine, Pyrimidifen, Tebufenozide, Tebufenpyrad, Triazamate, Indoxacarb, Sulfluramid, dense Milbemectin, Avermectin, Clofentezine, boric acid, p-benzene. Bactericidal active compounds: Benomyl, Carbendazim, Thiabendazole, Thiophanate methyl and other stupid compounds; Diethofencarb, etc. Phenylamino phthalate compounds; dithiocarbamate compounds such as Thiuram; dimethyl sulfonate such as Procymidone, Iprodione, Vinclozolin Amine compounds; Diniconazole, Epoxiconazole, Tebuconazole, Difenoconazole, Cyproconazole, Flusilazole, Triadimefon, Philippine An azole compound such as Hexaconazole; a mercaptoalanine compound such as Metalaxy 1 , Furametpyr, Mepronil, Tiadinil, Flutolanil,赛灭 324206 8 201249338 (Thifluzamide) and other carbamide compounds; Tolclofos-methyl, Fosetyl-aluminum, Pyrazophos and other organic phosphorus compounds; Onil), cyanobeta-pyrolo compound such as Fenpiclonil; Blasticidin-S, Kasugamycin, Polyoxin, Validamycin, Rice Antibiotics such as Mildiomycin; oxime acrylate compounds such as Kresoxim-methyl and Metominostrobin; Oxadixyl, PCNB, Hydroxyisoxazole, Dazomet, Diclomezine, Trioxon, Isoprothiolane, Diclocymet, Orysastrobin, Carpropamid, Tetrachloride Chlorothalonil, Manzeb, Captan, Folpet, Oxine-copper, Chlorinated Copper, Tricyclazole , Pyroquilon, Probenazole, Fthalide, Acibenzolar S methyl, Cymoxanil, Dimethomorph, S-mercaptobenzoene [1· 2. 3] 嗟二唾-7-thioester, Famoxadone, Oxolin (Oxo) Linic acid), Fluazinam, Chlobenthiazone, Isovaledione, Simeconazole, Tetrachloroisophthalonitrile, Thiophthalic acid Thiophthalimide oxybisphenoxarsine, 3-iodo-2-propylbutylamino phthalate, silver zeolite, silicone silver, phosphate rock salt, 324206 9 201249338 p-hydroxybenzoic acid Ester, sodium dehydroacetate, potassium sorbate. Herbicidal active compounds: Atrazine, Metribuzin and other triazine compounds, Fluometuron, Isoproturon, Daimuron and other glandular compounds; Bromoxyni 1 , Ioxyni 1 and other benzoic nitrile compounds; 2,6-dinitroaniline compounds such as Pendimethalin and Trif luralin; 2, 4-D, Allyloxyalkanoic acid compounds such as Dicamba, Fluroxypyr, and Mecoprop; Bensulfuron-methyl, Metsulfuron-methyl, Nicosulfuron, Primisulfuron-methyl, Cyclosulfamuron, Imazosulfuron, 1-(2-Ga-6-propyl0) Rice sulphate [1,2-b]0 is less than 0-methyl-3-yl aryl)-3_(4,6-dimethoxy-. Imazapyr, Imazaquin, Imazethapyr and other flavors. Sesinium ketone compound; Bispyribac-sodium, Bisthiobac sodium, Acifluorfen sodium, Sulfentrazone, Paraquat , sulphate, sulphate, sulphate, sulphate, sulphate, sulphate, sulphate, sulphate, sulphate, sulphate, sulphate Diflufenican, Norflurazon, Isoxachlortole, Bentazone, Benthiocarb, Mefenacet, 324206 10

201249338 除草靈（Propani 1)、氟吐草胺（Fluthiamide)、西草淨 (Simetryn)、四唑醯草胺（Fentrazamide)、乙氧苯草胺 (Etobenzanid)、減草靈（Swep)、°惡嗪草酮（Oxaziclomefone)、樂滅草（Oxadiazon)、η比唑特（pyraz〇iate)、氨基丙樂靈 (Prodiamine)、苯酮唑（Cafenstrole)、環戊惡草酮 (Pentoxazone)、克普草（Clomeprop)、環酯草醚 (Pyriftal id)、苯並雙環酮（Benzobicyclon)、漠丁醢草胺 (Bromobutide)、雙唑草腈（Pyraclonil) 植物成長調節活性化合物：抑芽素（Maleic hydrazide)、矮壯素（Chlormequat)、益收生長素（Ethephon)、赤黴素（Gibberellin)、曱派咬 (Mepiquat chloride)、噻苯隆（Thidiazuron)、依納素 (Inabenfide)、巴克素（Paclobutrazol)、烯效唾 (Uniconazole) 驅活性化合物： IS, 3R，4R，6R-蒈-3, 4-二醇、二丙基2, 5-*»比唆二敌酸醋等。本發明組成物中含有本農藥化合物以外之農藥活性化合物時，本發明組成物中本農藥化合物及本農藥化合物以外之農藥活性化合物合計通常含有0. 5至80重量％，較好含有1至75重量％。本發明組成物中通常含有增量成分。又，本發明組成物視需要亦可含有黏合劑、界面活性劑、溶劑、安定化劑、著色劑、香料等製劑用助劑。該增量成分、該製劑用助劑各個可單獨使用，亦可2種以上併用。本發明組成物中含 324206 11 201249338 有該增量成分、該製劑用助劑時，本發明組成物中，增量成刀可3有1至97重量％，黏合劑可含有Q 5至別重量％，㈣3有〇. 5至10重量％，界面活性劑可含有至重量％，較好含有0.5至1〇重量％，溶劑可含有3〇重量％ :二二好含有°，1至20重量%’安定化劑可含有〇·01 旦置％’著色劑及/或香料可含有0.01至5重量％。增！成分可列舉祕㈣體、植物性龍水溶性載體等。礦物性載體可列舉例如高嶺石、地開石、珍珠陶土、埃洛石等陶土礦物；纖蛇紋石、利蛇紋石、葉蛇紋石、錯綠泥石等蛇紋石；蒙脫石納、蒙脫石妈、蒙脫石鎂等蒙脫石礦物；皂石、鐘蒙脫石、鋅蒙脫石、貝得石等蒙脫石. 葉蠘石、滑石粉、蠛石、白雲母、多石夕白雲石、絹雲母、’ 伊利石等雲母；方英石、石英等二氧化石夕，綠坡縷石、海泡，等含切魏；白雲石等碳賴、石f (gypsum)、石貧等硫酸鹽礦物’·沸石（zeolite)、沸泡石、凝灰石、蛭石、輕石、矽砂、矽藻土、酸性白土、活性白土等。植物性載體可列舉例如纖維素、稻榖、小澱粉、糠、麥糠、大豆粉等。 n 71 ' 合成載體可列舉例如濕式法二氧化矽、乾式法二氧化石夕、濕式法二氧化石夕之燒製品' 表面改質之二氧化石夕乳加工澱粉（松谷化學公司製造之巴因福樂等）等。水溶性載體可列舉例如乳糖、嚴糖、糊精等糖類；食鹽、芒确、三聚碟酸納、焦填酸钟、尿素、碳酸氫納、碳 324206 12 201249338 酸納、碳酸鉀、碳酸氫卸、果酸等。馬來酸、檸檬酸、虽馬酸、韻素、==τ纖維素鈉，基甲基纖維乙賴其衍生物維酵素素經基丙基纖維素、聚、α化澱叔、酵素改性糊精、焙燒糊精、聚丙烯酸納、_酸鈉、㈣膠、阿拉伯膠等。 f面活性劑可列舉例如聚氧伸乙基院絲、聚氧伸乙基院基芳鱗、聚氧伸乙基笨乙烯基苯賴、聚氧伸乙基 έ水羊毛丨a §1 ♦氧伸乙基烧基笨*曱酿縮合物、聚氧伸乙基山梨_酐脂肪酸g旨、聚氧伸乙基甘油基單脂肪酸醋，聚氧伸丙基-醇單脂肪酸s旨、聚氧伸乙基山梨糖醇脂肪酸酯、聚氧伸乙基蓖麻油衍生物、聚氧伸乙基脂肪酸酯、高級脂肪酸甘油酯、山梨糖醇酐脂肪酸酯、蔗糖脂肪酸酯、聚氧伸乙基♦氧伸丙基嵌段聚合物、聚氧伸乙基脂肪酸醯胺、烷醇醯胺、聚氧伸乙基烷基胺等非離子性界面活性劑；十二烷基胺鹽酸鹽等烷基胺鹽酸鹽；十二烷基三甲基銨鹽、烷基二甲基苯甲基銨鹽、烷基吡啶鑌鹽、烧基異喹啉麵鹽、一烧基嗎琳錯鹽等烧基四級敍鹽；节索氯按（benze thonium chloride)、聚烷基乙烯基吡啶鏘鹽等陽離子性界面活性劑；棕櫚酸鈉等脂肪酸鈉；聚氧伸乙基月桂基醚羧酸鈉等醚羧酸鈉；月桂醯基肌胺酸鈉、N-月桂醯基麩胺酸鈉等高級脂肪酸之胺基酸縮合物；烷基磺酸鹽、烷基硫酸酯鹽、烯基硫酸酯鹽、月桂酸酯磺酸鹽等高級脂肪酸酯磺酸鹽；二辛基磺基琥珀酸酯等二烷基磺基琥珀酸鹽、油酸 324206 13 201249338 醯胺磺酸鹽等高級脂肪酸醯胺磺酸鹽；十二烷基苯磺酸鈉、二異丙基萘磺酸鹽等烷基芳基磺酸鹽；烷基芳基磺酸鹽之甲酿縮合物；十五碳-2-硫酸鹽等高級醇硫酸酯鹽；二聚氧伸乙基十二烷基醚磷酸酯等聚氧伸乙基烷基磷酸酯；苯乙烯-馬來酸共聚物等陰離子性界面活性劑；N _月桂基丙胺酸、N，N，N-三曱基胺基丙酸、n，N，N-三羥基乙基胺基丙酉欠、N-己基-N，N-二曱基胺基乙酸、ι_(2_羧基乙基）吡啶錄甜菜鹼、卵磷脂等兩性界面活性劑等， · 溶劑可列舉例如癸烷、十三碳烷、十四碳烷、十六碳烷、十八碳烷等飽和脂肪族烴類；丨_十一碳烯、丨_二十一碳烯等不飽和脂肪族烴；協烈庫爾（Cerecl〇r)S45(ICI製溶)等鹵素烴類，甲基乙基曱酮、環己酮等酮類；乙醇、丁醇、辛醇等醇類；乙酸乙酯、苯二甲酸二曱酯、月桂酸曱酯、棕櫚酸乙醋、乙酸辛酿、琥拍酸二辛醋、己二酸二癸醋等S旨類；二曱苯、乙基苯、十八炫基苯、索貝索 (S〇lvessQ)1()()(依克松化學公司製㈣）、海索（Hi—s〇i) S&AS-296(曰石化學製溶劑）等烷基苯類；十二碳基萘、十三兔基，、索时_(依克松化學製溶劑）等烧基萘類；丙 —醇單m乙二醇單乙基㈣等二醇嶋；油酸、癸酸、庚酸等脂肪酸類；N，N-二甲基甲酿胺、N，N-二乙基甲醯胺等酸醯胺類；撖欖油、大豆油、菜種油、E麻油、亞麻仁油、棉籽油、棕櫚油、輯梨油、f魚肝油等動植物油；機油專礦物油；甘油、甘油脂㈣料甘油魅物等。女疋化劑可列舉例如笨紛（phen〇1)系抗氧化劑、胺系 324206 14 201249338 抗氧化劑、雄系抗氧化劑、硫系抗氧化劑、pH調整劑、苯并三唑系紫外線吸收劑、二苯曱酮系紫外線吸收劑、苯甲酸酯系紫外線吸收劑、氰基丙烯酸酯系紫外線吸收劑、水揚酸系紫外線吸收劑受阻胺系紫外線吸收劑等紫外線吸收劑；環氧化大豆油、環氧化亞麻仁油、環氧化菜種油等環氧化植物油；酸式磷酸異丙酯、液體石蠟等。著色料可列舉例如若丹明（Rhodamine)B、索拉若.丹明等若丹明類；黃色4號、藍色1號、紅色2號等。香料可列舉例如乙醯乙酸乙酯、胺茴酸曱酯、異纈草酸異戊酯、庚酸乙酯、桂皮酸乙酯、丁酸異戊酯等酯類；己酸、桂皮酸等有機酸類；桂皮醇、香葉醇、檸檬醛、癸醇等醇類；香草醛、胡椒醛、紫蘇醛等醛類；麥芽醇、曱基yS-萘基酮等酮類；薄荷醇類等。本發明組成物之劑型可列舉粒劑、顆粒水合劑。本發明組成物可使用本農藥化合物、本鎂化合物、視需要之本農藥化合物以外之農藥活性化合物、增量成分、黏合劑、界面活性劑、溶劑、安定化劑、著色劑、香料等之製劑用助劑製造。本發明組成物可使用擠壓造粒法、轉動造粒法、壓縮造粒法、喷霧造粒法、流動層造粒法、攪拌造粒法、塗佈造粒法等製造。以擠壓造粒法製造本發明粒劑時，該造粒法含有以下之步驟。 A1)將本農藥化合物、本鎂化合物、視需要之本農藥化合物 324206 15 201249338 以外之農藥活性化合物或增量成分、黏合劑、界面活性劑、溶劑、安定化劑、著色劑、香料等之製劑用助劑混合。 A2)在獲得之混合物中，視需要可添加水進行練合。可將黏合劑、界面活性劑、安定化劑等溶解或分散於該水中使用。 A3)將獲得之練合物以具有規定直徑之洞之篩子擠出。 A4)將獲得之壓出物破碎成規定之長度，進行整粒·乾燥。獲得之本發明組成物，其粒長通常為0. 5至6. Omm，較好為0. 7至4. 0mm。又，於本發明中之粒長係指可取得粒子之最大長度。在步驟A1)中可使用混合機，該混合機可列舉螺旋葉片式混合機、亨舍爾混合機（Henschel mixer)、諾塔混合機（Nauta mixer)、羅迪治混合機（Lodige mixer)等。在步驟A2)中可使用練合機，該練合機可列舉捏和機、諾塔混合機、羅迪治混合機等。在步驟A3)中通常使用擠壓造粒機，該擠壓造粒機可列舉螺旋型擠壓造粒機、滾筒型擠壓造粒機、盤式造粒型擠壓造粒機、顆粒混練型擠壓造粒機、籃框型擠壓造粒機、鋼板型擠壓造粒機、振動型擠壓造粒機、齒輪式擠壓造粒機、環狀凹模式擠壓造粒機等，具體而言可使用道爾頓公司製造之雙圓頂造粒機、圓頂造粒機、籃框型造粒機、雙軸造粒機、畑鐵工之畑式造粒機。該篩子之擠壓徑（穿孔洞徑）通常為0. 5至2. 0mmφ，較好為0. 7至1. 5mm屮。在步驟Α4)之破碎或整粒之方法可列舉經由道爾頓公司製造之球形整粒機擠壓造粒之顆粒進行濕式整粒之方法 324206 16 ⑧ 201249338 或將經乾燥之顆粒經由針型研磨機等破碎機進行乾式整粒之方法。在步驟A4)之乾燥，通常使用乾燥機，該乾燥機可列舉流動層乾燥機、振動流動層乾燥機、回轉型乾燥機、箱型通氣乾燥機等。乾燥溫度通常為30至90°C，較好為 50 至 8(TC。以塗佈造粒法製造本發明組成物時，該造粒法含有以下之步驟。 B1)在核粒添加黏合劑。 B2)在附著黏合劑之核粒中添加本農藥化合物及本鎂化合物使附著。 B3)將獲得之顆粒乾燥·整粒。核粒通常可使用礦物性載體、植物性載體、水溶性載體製造。核粒之粒徑通常為0. 5至10mm，更好為0. 8至 5· 0_ 〇在步驟Bl)、B2)中，將核粒在裝置内部邊轉動•流動邊添加黏合劑，於此添加本農藥化合物及本鎂化合物（以下，合併稱為附著物質），反覆進行使附著在核粒之步驟，將規定量之附著物質附著在核粒。又，在步驟B1)之後視需要，可將本農藥化合物以外之農藥活性化合物或增量成分、界面活性劑、溶劑、安定化劑、著色劑、香料等之製劑用助劑分別單獨或將2種以上預先混合之物質附著在核粒後更進行步驟Bl)、B2)之操作。通常，黏合劑作成溶解液，加注、喷霧在核粒上。黏合劑溶解液亦可與附著物質或製劑用助劑混合使用，於該情況，可反覆進行在核粒用 324206 17 201249338 水喷霧’將核粒表面濕潤後添加該黏合劑溶解製造方法可列舉轉動造粒法、流動層造粗法、離ΐ作。造粒法、_造粒法、塗覆造粒法，使用之=動層舉鼓型造粒機、盤型造粒機、橫型授拌造教機、；：可列粒機、高逮混合機、垂直造粒機、混凝土混^動層造步驟3)之乾燥通常使用乾燥機，該乾燥集層乾燥機、振動流動層乾燥機、回轉㈣燥機、」舉〜動乾_等。乾燥溫度通常為3〇至啊，相型通氣 t：。马 50 至 8〇本發明組成物可經由粒狀農藥之通常施 ::明組成物之施用方法可列舉例如將:：用。直接散布之方法或使關單之餘機散布 /物用手，負式散粒機、管子散粒機、空中散粒機、動^另可使月苗箱用散粒機、搭載於拖拉機型之气粒力政粒機、 :、附設於插秧機等之散粒機等之散:機散粒之多：管散粒 f成物之·為難狀水，時，將本2法。又，，水中稀釋，將獲得之_液使用簡單月組成物散布機、動力散布機、搭載於:機、背負式布機、夕口管散布機等散布機進行散布。式之散的，=月組成物根據含有之農藥活性成分或其使用目 ::可，田、乾田、育苗箱、旱田、果樹園、旱:目等農耕地’森林、草坪、高爾夫球場、街路樹：道路、路肩、濕地等非農耕地，池、m /于、下水道等水系等使用。貯水池、川、水路、 324206 201249338 . 以下以說明。，對於在水稻栽培中使使用本發心成物之情況加本發明組成物可在播種時、育苗其發明組成物可在未作任何稀釋下二=功2插秧時施用。本田或育苗箱中施用。其施用方法可使用或用水稀釋後在水布機、噴壺、洒水機、併設於上述之散粒機、散機等施用之方法。相用之播種機等之處理本發明組成物以原狀施用時，其施用日時，每10畝通常為0.2至4kg，較'好為〇戛在水田中施用播種時或在育苗期間中等之育苗箱中”施用，至_3. 〇kg，在 (30crax60cm)通常為1〇至2〇〇g，較好為25每個育苗箱本發明組成物用水稀釋後施用時，將二=。水稀釋使成為所含本農藥化合物量之5至:成物用 10至5000倍。獲得之水稀釋液在水田中施用時彳二’較好通常施用使本農藥化合物量為〇.丨至1〇g，較好為每丨〇玖 5 g ’在育苗箱中施用時，每個育苗箱施用使本農藥0 · 2至為0.2至5g。 '&物 [實施例] 以下，呈示實施例對本專利發明作更詳細的本專利發明不只限於該等實施例。 ’惟，之在製劑例、為了比較試驗之比較製劑例中，製卞成刀、機器右未特別說明，使用以下者。. 中氧化鎮：關東化學（股）公司製造試藥磷酸鎂八水合物：關東化學（股）公司製造試藥 324206 19 201249338 氫氧化鎂：關東化學（股）公司製造試藥勝光山黏土 s:(股）勝光山鑛業公司製造黏土阿米洛克斯No. 1A :日本玉米澱粉（股）公司製造α化澱粉索普（Sorpol)5080:東邦化學工業（股）公司製造非離子性界面活性劑 85%磷酸：日本化學工業（股）公司製造糊精NDS:日澱化學（股）公司製造糊精卡卡萊1號：新石興產（股）公司製造輕石迪莫魯SN-B:花王（股）公司製造特殊芳族磺酸曱醛水縮合物之納鹽耶馬魯10PT:花王（股）公司製造月桂基硫酸鈉富巴薩黏土 A-300 :富巴薩黏土（股）公司製造喷射研磨機：（股）協新企業公司製造諾塔混合機：細川密庫隆（股）公司製造圓頂造粒機：不二拋達魯（股）公司製造流動層乾燥機：Powerex(股）公司製造針型研磨機：自由粉碎機稹野產業（股）公司製造首先，呈示製劑例。製劑例1 將異噻菌胺（純度99.0%)70.0重量份及勝光山黏土 S 30. 0重量份放入袋中，振盪混合後將混合物用喷射研磨機粉碎，獲得異噻菌胺粉碎物（以下，以異噻菌胺微粉末表示。有效成分含量為69.3%，雷射衍射式粒子徑測定器（濕式法）平均粒徑為4. 2 // πι)。 324206 20 ⑧ 201249338 將異噻菌胺微粉末28.9重量份、阿米洛克斯No. ΙΑ 30.0重量份、氧化鎂5.0重量份、索普5080 10. 0重量份、勝光山黏土 S 926. 1重量份用諾塔混合機混合，獲得混合粉末1000重量份。將該混合粉末1000重量份與水250重量份混合，用諾塔混合機混練，獲得混練物。將獲得之混練物用圓頂造粒機擠壓，以徑φ 1.0mm造粒，將獲得之造粒物用流動層乾燥機乾燥後用針型研磨機破碎、整粒，獲得農藥粒劑1。製劑例2 除了將氧化鎂之量變更為20· 0重量份，勝光山黏土 S 之量變更為911· 1重量份以外，進行與製劑例1相同之操作，獲得農藥粒劑2。製劑例3 除了將氧化鎂之量變更為50.0重量份’勝光山黏土 $ 之量變更為881.1重量份，水之量變更為240重量份以外，進行與製劑例1相同之操作，獲得農藥粒劑3。製劑例4 除了將氧化鎂之量變更為10.0重量份’勝光山黏土 s 之里變更為921. 1重量份以外，進行與製劑例1相同之操作，獲得農藥粒劑4。 ” 製劑例5 除了將氧化鎂之量變更為2.0重量份，勝光山黏土 § 之量變更為929. 1重量份以外，進行與製劑例丨相同之操作，獲得農藥粒劑5。 324206 21 201249338 製劑例6 將異噻菌胺微粉末28.9重量份、阿米洛克斯No. ΙΑ 30. 0重量份、氫氧化鎂50. 0重量份、索普5080 10. 0重量份、勝光山黏土 S 881. 1重量份用諾塔混合機混合，獲得混合粉末1000重量份。將該混合粉末1000重量份與水 240重量份混合，用諾塔混合機混練，獲得混練物。將獲得之混練物用圓頂造粒機擠壓，以徑φ 1. 0mm造粒，將獲得之造粒物用流動層乾燥機乾燥後用針型研磨機破碎。將粗破碎獲得之造粒物過歸，獲得圓柱狀造粒物之農藥粒劑 6 〇製劑例7 除了將氫氧化鎂之量變更為100. 0重量份，勝光山黏土 S之量變更為831. 1重量份，水之量變更為220重量份以外，進行與製劑例6相同之操作，獲得農藥粒劑7。製劑例8 將異噻菌胺微粉末28.9重量份、阿米洛克斯No. 1A 30. 0重量份、磷酸鎂八水合物50. 0重量份、索普5080 10. 0 重量份、勝光山黏土 S 881. 1重量份用諾塔混合機混合，獲得混合粉末1000重量份。將該混合粉末1000重量份與水19 0重量份混合，用諾塔混合機混練，獲得混練物。將獲得之混練物用圓頂造粒機擠壓，以徑W 1. 0mm造粒，將獲得之造粒物用流動層乾燥機乾燥後用針型研磨機破碎、整粒，獲得農藥粒劑8。製劑例9 324206 22 ⑧ 201249338 . 除了將磷酸鎂八水合物之量變更為100. 0重量份，勝光山黏土 S之量變更為831. 1重量份，水之量變更為270 重量份以外，進行與製劑例8相同之操作，獲得農藥粒劑 9 ° 製劑例10 將異噻菌胺微粉末57. 7重量份、阿米洛克斯No. 1Α 30. 0重量份、氧化鎂（商品名UC95H宇部馬提阿魯斯公司製造）20. 0重量份、索普5080 10. 0重量份、勝光山黏土 S 882.3重量份用諾塔混合機混合，獲得混合粉末1000重量份。將該混合粉末1000重量份與水310重量份混合，用諾塔混合機混練，獲得混練物。將獲得之混練物用圓頂造粒機擠壓，以徑φ 1.0mm造粒，將獲得之造粒物用流動層乾燥機乾燥後用針型研磨機破碎。將破粉碎獲得之造粒物過篩，獲得圓柱狀造粒物之農藥粒劑10。製劑例11 除了將氧化鎂（商品名UC95H宇部馬提阿魯斯公司製造）之量變更為50.0重量份，勝光山黏土 S之量變更為 852.3重量份，水之量變更為330重量份以外，進行與製劑例10相同之操作，獲得農藥粒劑11。製劑例12 除了將氧化鎂（商品名UC95H宇部馬提阿魯斯公司製造）之量變更為100. 0重量份，勝光山黏土 S之量變更為 802.3重量份，水之量變更為330重量份以外，進行與製劑例10相同之操作，獲得農藥粒劑12。 324206 23 201249338 製劑例13 將異°塞菌胺微粉末57.7重量份、阿米洛克斯No. ΙΑ 30.0重量份、氧化鎂（商品名uC95H宇部馬提阿魯斯公司製造）20.0重量份、索普5080 10.0重量份、85%磷酸11.8 重量份、勝光山黏土 S 872. 3重量份用諾塔混合機混合，獲得混合粉末1〇(Π.8重量份。將該混合粉末丨001.8重量份與水310重量份混合，用諾塔混合機混練，獲得混練物。將獲得之混練物用圓頂造粒機擠壓，以徑φ1〇ιηιη造粒，將獲得之造粒物用流動層乾燥機乾燥後用針型研磨機破碎’整粒，獲得農藥粒劑13。製劑例14 除了將氧化鎂（商品名UC95H宇部馬提阿魯斯公司製造）之量變更為50. 〇重量份，勝光山黏土 s之量變更為 842.3重量份以外，進行與製劑例13相同之操作，獲得農藥粒劑14。製劑例15 除了將氧化鎮（商品名UC95H宇部馬提阿魯斯公司製造)之量變更為100.0重量份，勝光山黏土 s之量變更為 792.3重量份’水之量變更為330重量份以外，進行與製劑例13相同之操作，獲得農藥粒劑15。〃製劑例16 將異噻菌胺微粉末28.9重量份、执具邮 m 培丹鹽酸鹽（純产 Θ6. 9%)68· 1重量份、阿米洛克斯Ν〇. ία η & 又 .υ重量份、氧化鎂50· 0重量份、85%磷酸23. 5重量份、各* 里I切、索普5080 1〇.〇 324206 24 201249338 重量份、勝光山黏土S微〇重量份用諾塔混合機混合’ 獲得混合粉末1003.5重量份。將該混合粉末丨〇〇3. 5重量份與水250重量份混舍’用諾塔混合機混練’獲得混練物。將獲得之混練物用圓谓造粒機擠壓，以徑φ1·ΟΠΙΐη造^戚將獲得之造粒物用流動詹乾燥機乾燥後用針型斫磨么農碎。將粗破碎獲得之遠粒物過筛’獲得圓柱狀造粗物藥粒劑16。製劑例17 ^ 將異噻菌胺微粉28. 9重量份及氧化鎂100. 〇重重贫果汁混合機混合，獲得混合物（以下，稱為異噻菌胺滿 Α)128. 9重量份。在不銹鋼製之300mL燒瓶中放入離子^ 換水136. 3重量份、糊精NDS 20. 0重量份及85%磷酸3· 重量份，用斯利旺發動機攪拌’獲得將糊精溶解之滲浪（以下’稱為糊精水溶液A)160.0重量份。將卡卡萊1號847. 9重量份填充在混凝土混合機中邊攪拌（回轉數40rpm)邊每次少量交互加入糊精水滲浪j 160. 〇重量份、異噻菌胺混合物A 128 9重量份，椽附著在卡卡萊1號。之後，用流動層乾燥機錢，獲得農藥雜劑17。製劑例18 將異嗟菌胺微粉末28.9重量份及氧化鎂10.〇爹責份用果汁此0機混合，獲得混合物（以下，稱為異漆菌胺p技物Β)38· 9重量份。除了將卡卡萊1號之量變更為937 9重量份、異屬銷 324206 25 201249338 胺混合物A 128.9重量份變更為異嗔菌胺混合物B 38 9 重量份以外，進行與製劑例17相同之操作，獲得農藥粒劑 18。製造例19 將異噻菌胺（純度98.2%)611.〇重量份、迪莫魯sn_b 120.0重量份、耶馬魯1〇ρτ 3〇〇重量份、氧化鎮ι〇〇〇重量份、富巴薩黏土 Α-300 139.0重量份混合。獲得之混合物用喷射研磨機粉碎。獲得之粉碎物平均粒徑為6. (雷射衍射式粒控測定器（濕式））。將該粉碎物1 〇〇〇. 〇重量份與水8.0重量份用諾塔混合機混練。獲得之混練物用圓頂造粒機擠壓，以徑pO Mm造粒，將獲得之造粒物用流動層乾燥機乾燥、過筛，獲得圓柱狀造粒物之農藥粒劑19。製造例20 將異噻菌胺（純度98. 2%)407. 3重量份、迪莫魯SN_b 120.0重量份、耶馬魯1〇ρτ 3〇〇重量份、氧化鎂1〇〇 () 重量份、富巴薩黏土 Α-300 342. 7重量份混合。獲得之混合物用喷射研磨機粉碎’獲得之粉碎物平均粒徑為5. 9# m (雷射衍射式粒徑測定器（濕式將該粉碎物1〇〇〇.〇重量份與水100. 〇重量份用諾塔混合機混練。獲得之混練物用圓頂造粒機擠壓’以徑p0 7min造粒。將獲得之造粒物用流動層乾燥機乾燥、過篩，獲得圓柱狀造粒物之農藥粒劑2〇。接著’呈示用於比較試驗之比較製劑例。比較製劑例1201249338 Herbicide (Propani 1), Fluthiamide, Simetryn, Fentrazamide, Etobenzanid, Swep, ° Evil Oxaziclomefone, Oxadiazon, pyraz〇iate, Prodiamine, Cafenstrole, Pentoxazone, Kepu Clomeprop, Pyriferal id, Benzobicyclon, Bromobutide, Pyraclonil Plant Growth Regulating Active Compound: Maleic hydrazide ), Chlormequat, Ethephon, Gibberellin, Mepiquat chloride, Thidiazuron, Inabenfide, Paclobutrazol ), Uniconazole active compound: IS, 3R, 4R, 6R-蒈-3, 4-diol, dipropyl 2, 5-*» than dihydro acid vinegar. 5至80重量百分比, preferably containing 1 to 75, in the composition of the present invention, the pesticidal compound, and the pesticide active compound other than the present pesticide compound in the composition of the present invention, usually 0.5 to 80% by weight, preferably 1 to 75 weight%. The composition of the present invention usually contains an extender component. Further, the composition of the present invention may contain an auxiliary agent for preparation such as a binder, a surfactant, a solvent, a stabilizer, a coloring agent, or a fragrance, as needed. The extender component and the auxiliary agent for the preparation may be used singly or in combination of two or more. The composition of the present invention contains 324206 11 201249338. When the additive component and the auxiliary agent for the preparation are used, the composition of the present invention may have an increment of 3 to 97% by weight, and the adhesive may contain Q 5 to other weights. %, (4) 3 has 〇. 5 to 10% by weight, the surfactant may be added to the weight%, preferably 0.5 to 1% by weight, the solvent may contain 3% by weight: 22%, 1 to 20% by weight The 'stabilizing agent may contain 〇·01 旦%%' colorant and/or perfume may contain 0.01 to 5% by weight. increase! The component may, for example, be a secret (tetra) or a plant-derived water-soluble carrier. Examples of the mineral carrier include kaolinite, dickite, pearlite, and halloysite; mineral serpentine, serpentine, serpentine, and chlorite; serpentine; Smectite minerals such as Shima and montmorillonite; smectites such as saponite, montmorillonite, zinc montmorillonite, beidetite, etc.. ochre, talcum powder, vermiculite, muscovite, and more Dolomite, sericite, 'Ilistone and other mica; Fangyingshi, quartz and other dioxides, sloping stones, sea saponins, etc. containing cut Wei; dolomite and other carbon ray, stone f (gypsum), stone poor and other sulfuric acid Salt mineral 'zeolite, zeolite, tuff, vermiculite, pumice, strontium, diatomaceous earth, acid white clay, activated clay and the like. The vegetable carrier may, for example, be cellulose, rice bran, small starch, alfalfa, wheat bran, soybean powder or the like. n 71 ' The synthetic carrier may, for example, be a wet-process cerium oxide, a dry-process sulphur dioxide, or a wet-type sulphur dioxide sinter-fired product' surface-modified sulphur dioxide cermet milk processing starch (manufactured by Matsutani Chemical Co., Ltd.) Bain Fule, etc.). The water-soluble carrier may, for example, be a sugar such as lactose, sucrose or dextrin; salt, mango, trisodium silicate, coke acid, urea, sodium bicarbonate, carbon 324206 12 201249338 sodium, potassium carbonate, hydrogen carbonate Unloading, fruit acid, etc. Maleic acid, citric acid, horse acid, rhyme, ==τ cellulose sodium, methyl group fiber, its derivative, enzyme, modified by propyl cellulose, poly, α-deuterate, enzyme Dextrin, calcined dextrin, sodium polyacrylate, sodium sulphate, (iv) gum, gum arabic, and the like. The f-side active agent may, for example, be a polyoxy-extended ethyl silk, a polyoxy-extended ethyl-based aromatic scaly, a polyoxy-extended ethyl strepto-vinyl benzene, a polyoxy-extended ethyl hydrazine wool 丨 a § 1 ♦ oxygen Stretching ethyl ketone stupid * condensed condensate, polyoxyethylene ethyl sorbitol _ anhydride fatty acid g, polyoxyethyl glyceryl mono fatty acid vinegar, polyoxypropylene propyl alcohol monoglyceride s, polyoxygen extension Ethyl sorbitol fatty acid ester, polyoxyethylene ethyl castor oil derivative, polyoxyethylidene ester, higher fatty acid glyceride, sorbitan fatty acid ester, sucrose fatty acid ester, polyoxygen Non-ionic surfactants such as oxo-propyl block polymer, polyoxy-ethylidene fatty acid decylamine, alkanolamine, polyoxyethylamine, etc.; dodecylamine hydrochloride, etc. Alkylamine hydrochloride; dodecyltrimethylammonium salt, alkyldimethylbenzylammonium salt, alkylpyridinium salt, alkyl isoquinoline salt, monomolecular salt, etc. a four-stage salt of the base; a cationic surfactant such as a benzothonium chloride or a polyalkylvinylpyridinium salt; a sodium fatty acid such as sodium palmitate ; sodium polyetherate such as sodium polyethyl laurate ether carboxylate; amino acid condensate of higher fatty acid such as sodium lauryl sarcosinate, sodium N-lauric acid glutamate; alkyl sulfonate a higher fatty acid ester sulfonate such as an alkyl sulfate, an alkenyl sulfate or a laurate sulfonate; a dialkyl sulfosuccinate such as dioctyl sulfosuccinate; oleic acid 324206 13 201249338 Higher fatty acid decyl sulfonate such as decyl sulfonate; alkyl aryl sulfonate such as sodium dodecyl benzene sulfonate or diisopropyl naphthalene sulfonate; Brewed condensate; higher alcohol sulfate salt such as fifteen carbon-2-sulfate; polyoxyethylene ethyl phosphate such as dimerized oxygen ethyl dodecyl ether phosphate; styrene-maleic acid copolymerization Anionic surfactant; N _ lauryl alanine, N, N, N-tridecylaminopropionic acid, n, N, N-trihydroxyethyl amide oxime, N-hexyl-N , N-dimercaptoaminoacetic acid, i-(2-carboxyethyl)pyridine, betaine, lecithin and other amphoteric surfactants, etc., and the solvent may, for example, be decane, tridecane or tetradecene. Saturated aliphatic hydrocarbons such as alkane, hexadecane or octadecane; unsaturated aliphatic hydrocarbons such as 丨_undecene and 丨-20 hexene; Cerecl〇r S45 ( Halogen hydrocarbons such as ICI), ketones such as methyl ethyl fluorenone and cyclohexanone; alcohols such as ethanol, butanol and octanol; ethyl acetate, dinonyl phthalate, decyl laurate, Ethyl palmitate, acetic acid, succinic acid, dioctyl vinegar, adipic acid, diterpenic vinegar, etc.; diterpene benzene, ethyl benzene, stearyl benzene, Sobess Q (S〇lvessQ) 1 () () (Ikesson Chemical Co., Ltd. (4)), Hess (Hi-s〇i) S& AS-296 (solvent from vermiculite), alkylbenzenes; dodecaphthalene, thirteen rabbits a base such as a base, a solute _ (a solvent based on yakesong chemical), a propylene glycol such as a mono-methylene glycol monoethyl (tetra), a fatty acid such as oleic acid, capric acid or heptanoic acid; , N-dimethyl ketoamine, N, N-diethylformamide and other acid amides; eucalyptus oil, soybean oil, vegetable oil, E sesame oil, linseed oil, cottonseed oil, palm oil, pear Oil, f cod liver oil and other animal and vegetable oils; oil special mineral oil; glycerin, (Iv) glycerol feed oil charm and the like. The female remedy agent may, for example, be an odorant (phen 〇 1) antioxidant, an amine 324206 14 201249338 antioxidant, a male antioxidant, a sulfur antioxidant, a pH adjuster, a benzotriazole ultraviolet absorber, or the like. A benzophenone-based ultraviolet absorber, a benzoate-based ultraviolet absorber, a cyanoacrylate-based ultraviolet absorber, a salicylic acid-based ultraviolet absorber, a hindered amine-based ultraviolet absorber, and the like, an ultraviolet absorber; an epoxidized soybean oil, a ring Epoxidized vegetable oil such as oxidized linseed oil or epoxidized vegetable oil; isopropyl acid phosphate, liquid paraffin, and the like. Examples of the coloring material include Rhodamine B, Solaramine, and the like, and Rhodamine, Yellow No. 4, Blue No. 1, Red No. 2, and the like. Examples of the perfume include ethyl acetate, anthranilic acid anthranilic acid, isoamyl isocyanate, ethyl heptanoate, ethyl cinnamate, and isoamyl butyrate; and organic acids such as caproic acid and cinnamic acid. Alcohols such as cinnamyl alcohol, geraniol, citral, sterol; aldehydes such as vanillin, piperonal, and perillaldehyde; ketones such as maltitol and sulfonyl yS-naphthyl ketone; menthol and the like. The dosage form of the composition of the present invention may be granules or granule hydrating agents. The composition of the present invention can be used as a preparation of the present pesticide compound, the present magnesium compound, an agrochemical active compound other than the present pesticide compound, an extender component, a binder, a surfactant, a solvent, a stabilizer, a colorant, a fragrance, and the like. Made with additives. The composition of the present invention can be produced by an extrusion granulation method, a rotary granulation method, a compression granulation method, a spray granulation method, a fluidized bed granulation method, a stirring granulation method, a coating granulation method or the like. When the granule of the present invention is produced by extrusion granulation, the granulation method comprises the following steps. A1) Preparation of the present pesticide compound, the present magnesium compound, the pesticide active compound other than the pesticide compound 324206 15 201249338, or an additive component, a binder, a surfactant, a solvent, a stabilizer, a coloring agent, a fragrance, etc. Mix with auxiliaries. A2) In the obtained mixture, water may be added for the purpose of mixing as needed. A binder, a surfactant, a stabilizer, or the like may be dissolved or dispersed in the water. A3) The obtained compound is extruded through a sieve having a hole having a prescribed diameter. A4) The obtained extrudate is crushed to a predetermined length, and is granulated and dried. 0至。 0. The thickness of the present invention is 0. 7 to 4. 0mm. Further, the grain length in the present invention means the maximum length at which the particles can be obtained. A mixer may be used in the step A1), and the mixer may be a spiral blade mixer, a Henschel mixer, a Nauta mixer, a Lodige mixer, or the like. . A kneading machine can be used in the step A2), and the kneading machine can be exemplified by a kneader, a Nauta mixer, a Rodizhi mixer, and the like. In the step A3), an extrusion granulator is generally used, and the extrusion granulator may be a spiral extrusion granulator, a drum type extrusion granulator, a tray granulation extrusion granulator, and a granule kneading machine. Type extrusion granulator, basket type extrusion granulator, steel plate extrusion granulator, vibration type extrusion granulator, gear type extrusion granulator, annular concave mode extrusion granulator, etc. Specifically, a double dome granulator, a dome granulator, a basket type granulator, a biaxial granulator, and a shovel granulator made by Dalton Company can be used. 5至屮。 5mm屮, preferably from 0. 7至1. 5mm屮. The method of crushing or granulating in the step )4) may be a method of wet granulation by granulating and granulating granules of a spherical granulator manufactured by Dalton Co., Ltd. 324206 16 8 201249338 or by passing the dried granules through a needle type A method of dry granulation by a crusher such as a grinder. In the drying in the step A4), a dryer is usually used, and examples of the dryer include a fluidized bed dryer, a vibrating fluidized bed dryer, a rotary dryer, a box type air dryer, and the like. The drying temperature is usually from 30 to 90 ° C, preferably from 50 to 8 (TC. When the composition of the present invention is produced by a coating granulation method, the granulation method comprises the following steps. B1) A binder is added to the nucleus particles. B2) The pesticide compound and the magnesium compound are added to the core particles to which the binder is attached to adhere. B3) Drying and granulating the obtained granules. The core particles can usually be produced using a mineral carrier, a vegetable carrier, or a water-soluble carrier. The particle size of the core particles is usually 0.5 to 10 mm, more preferably 0.8 to 5·0_ 〇 In steps B1) and B2), the core particles are rotated inside the device, and a binder is added to the flow side. The present pesticide compound and the present magnesium compound (hereinafter, collectively referred to as an adhering substance) are added, and the step of adhering to the core particles is repeated, and a predetermined amount of the adhering substance is adhered to the core particles. Further, after the step B1), the agrochemical active compound other than the pesticide compound or the additive for the formulation, the surfactant, the solvent, the stabilizer, the colorant, the fragrance, etc., may be separately or separately prepared. The above-mentioned pre-mixed substances are attached to the core particles and further subjected to the operations of steps B1) and B2). Usually, the binder is made into a solution, which is filled and sprayed on the nucleus. The binder solution may also be used in combination with an adhering substance or a auxiliaries for preparation. In this case, the method of dissolving the nucleus particle 324206 17 201249338 water spray after the surface of the nucleus particle is wetted and then the binder is dissolved may be mentioned. Rotating granulation method, flowing layer roughing method, and smashing. Granulation method, granulation method, coating granulation method, use = moving layer lifting drum type granulator, disc type granulator, horizontal type mixing and teaching machine;;: granulator, high catch The drying of the mixer, the vertical granulator, and the concrete mixing layer 3) is usually carried out by using a dryer, a dry layer dryer, a vibrating fluid layer dryer, a rotary (four) dryer, a lifter, and the like. The drying temperature is usually 3 〇 to ah, phase venting t:. Horses 50 to 8 〇 The composition of the present invention can be exemplified by the application method of the usual composition of the granular pesticide. Directly spread the method or distribute the remaining machine to the hand, the negative granulator, the pipe granulator, the air granulator, the movable granule, the granule box, the tractor, and the tractor type. The gas-grain force granulator, :, the granules attached to the rice transplanter, etc.: the bulk of the machine: the tube granules are the hard-to-water, when the method is the second. In addition, the water is diluted, and the obtained liquid is distributed using a simple monthly composition spreader, a power spreader, and a spreader such as a machine, a knapsack cloth machine, and an eve-mouth pipe spreader. The formula of the formula is based on the active ingredients contained in the pesticide or its use::, fields, dry fields, nursery boxes, dry fields, orchards, droughts, and other agricultural land 'forests, lawns, golf courses, street roads Tree: Non-agricultural land such as roads, shoulders, and wetlands, such as pools, m/yu, sewers, etc. Storage tank, Sichuan, waterway, 324206 201249338 . The following is a description. For the case where the present invention is used in rice cultivation, the composition of the present invention can be applied at the time of sowing, and the inventive composition can be applied without any dilution. Apply in a Honda or nursery box. The method of application may be carried out by using a method of diluting with water or using a water dispenser, a watering can, a sprinkler, and the above-mentioned pelletizer, machine or the like. When the composition of the present invention is applied as it is, when it is applied as it is, it is usually 0.2 to 4 kg per 10 mu on the day of application, which is better than the seedling box which is used in the paddy field or during the seedling period. Medium" application, to _3. 〇kg, usually at 1 〇 to 2 〇〇g, preferably 25 per seedling box. When the composition of the present invention is diluted with water, it is applied as two times. 5 to 5000 times the amount of the pesticide compound contained in the product: the obtained water dilution solution is preferably applied in the paddy field, and the amount of the pesticide compound is usually 〇.丨 to 1〇g. It is preferred that when each 5 g of 丨〇玖 is applied in a nursery box, each seedling box is applied so that the pesticide is 0.2 to 0.2 g to 5 g. '& [Embodiment] Hereinafter, the present invention is presented to the present invention. The present invention, which is more detailed, is not limited to the examples. However, in the preparation examples and the comparative preparation examples for the comparative test, the boring tool and the machine right are not specifically described, and the following is used. : Kanto Chemical Co., Ltd. manufactures test drug magnesium phosphate octahydrate Kanto Chemical Co., Ltd. manufactures reagents 324206 19 201249338 Magnesium hydroxide: Kanto Chemical Co., Ltd. manufactures test drugs Shengguangshan clay s: (shares) Shengguangshan Mining Company manufactures clay Amilos No. 1A: Japanese corn starch (Stock) company to manufacture alpha-starch Sorp (Sorpol) 5080: Toho Chemical Industry Co., Ltd. manufactures non-ionic surfactants 85% phosphoric acid: Japan Chemical Industry Co., Ltd. manufactures dextrin NDS: Nitto Chemical Co., Ltd. ) The company manufactures dextrin Kakal No. 1: Xinshi Xingye Co., Ltd. manufactures Shishi Dimoru SN-B: Kao (stock) company manufactures special aromatic sulfonic acid furfural water condensate 10PT: Kao (stock) company manufactures sodium lauryl sulfate Fubasa clay A-300: Fubasa clay (stock) company manufactures jet mill: (share) Xiexin Enterprise Co., Ltd. manufactures Nauta mixer: Hosokawa Mikulong The company manufactures a dome granulator: Fujita Daru Co., Ltd. manufactures a laminar flow dryer: Powerex Co., Ltd. manufactures a needle-type grinder: Free shredder Takino Industry Co., Ltd. manufactures first, presentation system Example 1 Formulation Example 1 Isotianil (purity 99.0%) 70.0 parts by weight and Shengguangshan clay S 30. 0 parts by weight were placed in a bag, shaken and mixed, and the mixture was pulverized by a jet mill to obtain imipenem pulverization. The content of the active ingredient is 69.3%, and the average particle size of the laser diffraction particle diameter measuring device (wet method) is 4. 2 // πι). 324206 20 8 201249338 28.9 parts by weight of isothiazide micropowder, 30.0 parts by weight of Amilos No. 5.0, 5.0 parts by weight of magnesium oxide, 5080 10.0 parts by weight of Sopo, and S926. 1 part by weight of Nota mixer The mixture was mixed to obtain 1000 parts by weight of the mixed powder. 1000 parts by weight of the mixed powder was mixed with 250 parts by weight of water, and kneaded by a Nauta mixer to obtain a kneaded product. The obtained kneaded material was extruded by a dome granulator, granulated by a diameter of 1.0 mm, and the obtained granulated product was dried by a fluidized bed dryer, and then crushed and granulated by a needle type grinder to obtain a pesticide granule 1 . [Formulation Example 2] The same procedure as in Preparation Example 1 was carried out, except that the amount of the magnesium oxide was changed to 20.0 parts by weight, and the amount of the Shouguangshan clay S was changed to 911·1 part by weight, and the agrochemical granule 2 was obtained. Formulation Example 3 The same procedure as in Preparation Example 1 was carried out to obtain a pesticide granule, except that the amount of magnesium oxide was changed to 50.0 parts by weight, the amount of 'Shengguangshan clay $ was changed to 881.1 parts by weight, and the amount of water was changed to 240 parts by weight. 3. Formulation Example 4 A pesticide granule 4 was obtained in the same manner as in Preparation Example 1, except that the amount of the magnesium oxide was changed to 10.0 parts by weight, and the amount of the smear was changed to 921.1 parts by weight. Formulation Example 5 A pesticide granule 5 was obtained in the same manner as in the preparation example except that the amount of magnesium oxide was changed to 2.0 parts by weight, and the amount of shengguangshan clay § was changed to 929. 1 part by weight to obtain a pesticide granule 5. 324206 21 201249338 Preparation Example 6 Isotianil micropowder 28.9 parts by weight, Amilos No. ΙΑ 30. 0 parts by weight, magnesium hydroxide 50. 0 parts by weight, Thorpe 5080 10. 0 parts by weight, Shengguangshan clay S 881. 1 part by weight was mixed with a Nauta mixer to obtain 1000 parts by weight of a mixed powder, and 1000 parts by weight of the mixed powder was mixed with 240 parts by weight of water, and kneaded by a Nauta mixer to obtain a kneaded product. The granulator is extruded, granulated by a diameter of φ 1. 0 mm, and the obtained granules are dried by a fluidized bed dryer and then crushed by a needle mill. The granulated material obtained by coarse crushing is over-reduced to obtain a cylindrical shape. In addition to changing the amount of magnesium hydroxide to 100. 0 parts by weight, the amount of S. s. The same operation as in Preparation Example 6 was carried out to obtain a pesticide granule 7. Formulation Example 8 28.9 parts by weight of isothiazide micropowder, Amilos No. 1A 30.0 parts by weight, magnesium phosphate octahydrate 50. 0 parts by weight, Thorpe 5080 10. 0 parts by weight, wins 1 part by weight of the light mountain clay S was mixed with a Nauta mixer to obtain 1000 parts by weight of the mixed powder. 1000 parts by weight of the mixed powder was mixed with 19 parts by weight of water, and kneaded by a Nauta mixer to obtain a kneaded product. The kneaded material was extruded by a dome granulator, granulated by a diameter of W 1.0 mm, and the obtained granules were dried by a fluidized bed dryer, and then crushed and sized by a pin mill to obtain a granule 8 of agrochemicals. Formulation Example 9 324206 22 8 201249338. In addition to changing the amount of the magnesium phosphate octahydrate to 100. 0 parts by weight, the amount of the Shouguangshan clay S was changed to 831.1 parts by weight, and the amount of water was changed to 270 parts by weight. The same procedure as in Preparation Example 8 was carried out to obtain a pesticide granules at 9 °. Example 10: Isotianzil micropowder 57. 7 parts by weight, Amilos No. 1 Α 30. 0 parts by weight, magnesium oxide (trade name UC95H Ube) 0. 0 parts by weight, Thorpe 5080 10. 0 parts by weight 88 parts by weight of Shengguangshan clay S was mixed with a Nauta mixer to obtain 1000 parts by weight of the mixed powder. 1000 parts by weight of the mixed powder was mixed with 310 parts by weight of water, and kneaded by a Nauta mixer to obtain a kneaded product. The product was extruded by a dome granulator, granulated by a diameter of 1.0 mm, and the obtained granules were dried by a fluidized bed dryer and then crushed with a needle mill. The granulated product obtained by crushing and pulverizing was sieved to obtain Pesticide granule 10 of cylindrical granules. Formulation Example 11 The amount of the Shouguangshan clay S was changed to 852.3 parts by weight, and the amount of water was changed to 330 parts by weight, except that the amount of the magnesium oxide (trade name: UC95H, manufactured by Utopia) was changed to 50.0 parts by weight. The same operation as in Formulation Example 10 was carried out to obtain a pesticide granule 11. Formulation Example 12 The amount of the Shouguangshan clay S was changed to 802.3 parts by weight, and the amount of water was changed to 330 parts by weight, except that the amount of the magnesium oxide (trade name: UC95H, manufactured by Utopia) was changed to 100. 0 parts by weight. The same procedure as in Preparation Example 10 was carried out to obtain a pesticide granule 12. 324206 23 201249338 Formulation Example 13 57.7 parts by weight of dexamethasone micropowder, 30.0 parts by weight of Amilos No., and 20.0 parts by weight of magnesium oxide (trade name: uC95H Ube Martius), Thorpe 5080 10.0 parts by weight, 85% phosphoric acid 11.8 parts by weight, Shengguangshan clay S 872. 3 parts by weight mixed with a Nauta mixer to obtain a mixed powder of 1 〇 (Π. 8 parts by weight. The mixed powder 丨 001.8 parts by weight with water 310 parts by weight of the mixture was kneaded by a Nauta mixer to obtain a kneaded material. The obtained kneaded product was extruded by a dome granulator, granulated by a diameter of φ1 〇ιηιη, and the obtained granulated product was dried by a fluidized bed dryer. After that, the granules were crushed by a needle-type grinder to obtain a granule of the pesticide 13. Formulation Example 14 In addition to changing the amount of magnesium oxide (trade name: UC95H, manufactured by Utopia Martius) to 50. 〇 by weight, Shengguangshan clay The amount of s was changed to 842.3 parts by weight, and the same procedure as in the preparation example 13 was carried out to obtain a pesticide granule 14. Formulation Example 15 The amount of the oxidized town (trade name UC95H Ube Mart Aruth Co., Ltd.) was changed to 100.0. Weight, win The amount of the mountain clay s was changed to 792.3 parts by weight, and the amount of water was changed to 330 parts by weight, and the same procedure as in the preparation example 13 was carried out to obtain a pesticide granule 15. 制剂 Formulation Example 16 Isotianzamide fine powder 28.9 parts by weight执 m m 培盐盐 ( ( 纯纯纯纯纯纯纯 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 % phosphoric acid 23. 5 parts by weight, each * I cut, Thorpe 5080 1 〇. 〇 324206 24 201249338 parts by weight, Shengguangshan clay S micro 〇 parts by weight mixed with a Nauta mixer' to obtain 1003.5 parts by weight of the mixed powder. The mixed powder 丨〇〇3.5 parts by weight and 250 parts by weight of water were mixed and mixed with 'Norta mixer' to obtain a kneaded material. The obtained kneaded material was extruded by a round granulator, and the diameter was φ1·ΟΠΙΐη. ^戚 The granulated material obtained by the granules is dried by a flow dryer and then pulverized with a needle type. The granules obtained by coarsely pulverizing the granules are sieved to obtain a cylindrical granule for granules 16. Preparation Example 17 ^ 9 parts by weight of isothiazide micropowder and magnesium oxide 100. 〇 heavy and heavy juice mixer mixed to obtain a mixture 12重量份。 In the 300mL flask made of stainless steel, Ion I change water 136.3 parts by weight, dextrin NDS 20. 0 parts by weight and 85% phosphoric acid 3 · Parts by weight, stirred with a Slimwang engine to obtain 160.0 parts by weight of the solubilized dextrin (hereinafter referred to as the aqueous solution of dextrin A). Fill the Kakalai No. 1 847. 9 parts by weight in a concrete mixer While stirring (40 rpm), add a small amount of dextrin water percolation j 160. 〇 by weight, isothiazide mixture A 128 9 parts by weight, 椽 attached to Kakalai No. 1. Thereafter, the pesticide layer was obtained by using a fluid layer dryer. Formulation Example 18 28.9 parts by weight of isomacurone fine powder and magnesium oxide 10. The mixture is mixed with fruit juice to obtain a mixture (hereinafter, referred to as quercetin p-technical compound) 38·9 parts by weight . The same operation as in Formulation Example 17 was carried out, except that the amount of Kakalai No. 1 was changed to 937 9 parts by weight, the different pin 324206 25 201249338 amine mixture A 128.9 parts by weight was changed to the isoproteril mixture B 38 9 parts by weight. , obtaining pesticide granules 18 . Production Example 19 Isotianil (purity: 98.2%) 611. 〇 by weight, Dimoru sn_b 120.0 parts by weight, Yemaru 1 〇 ρτ 3 〇〇 by weight, oxidized 〇〇〇〇〇〇重量, Fusaba Clay Α-300 139.0 parts by weight mixed. The obtained mixture was pulverized by a jet mill. The obtained pulverized material had an average particle diameter of 6. (Laser diffraction type particle size measuring instrument (wet type)). The pulverized product of 1 〇〇〇. 〇 and 8.0 parts by weight of water were kneaded by a Nauta mixer. The obtained kneaded product was extruded by a dome granulator, granulated by a diameter of pO Mm, and the obtained granules were dried with a fluid layer dryer and sieved to obtain a granulated agrochemical granule 19 of a cylindrical granule. Production Example 20 Isotianil (purity 98.2%) 407.3 parts by weight, Dimoru SN_b 120.0 parts by weight, Yemaru 1 〇ρτ 3 〇〇 parts by weight, magnesium oxide 1 〇〇 () parts by weight, Fubasa clay Α - 300 342. 7 parts by weight of the mixture. The obtained mixture was pulverized by a jet mill to obtain an average particle size of the pulverized material of 5. 9 # m (laser diffraction type particle size analyzer (wet type pulverized material 1 〇〇〇. 〇 by weight and water 100. The weight fraction was kneaded by a Nauta mixer. The obtained kneaded material was pulverized by a dome granulator to granulate at a diameter of p0 7 min. The obtained granules were dried with a fluidized bed dryer and sieved to obtain a cylindrical shape. The pesticide granules of the granules were 2 〇. Next, the comparative preparation examples for comparison experiments were presented. Comparative Preparation Example 1

將異噻菌胺微粉末28.9重量份、阿米洛克斯No. 1A 324206 201249338 30. 0重量份、索普5080 10. 〇重量份、勝光山黏土 S 931. 1 重量份用諾塔混合機混合’獲得混合粉末1 〇〇〇重量份。將該混合粉末1000重量份與水220重量份混合，用諾塔混合機混練。獲得之混練物用圓頂造粒機擠壓，以徑1. Omm 造粒。將獲得之造粒物用流動層乾燥機乾燥後用針槊研磨機破碎。將粗破碎獲得之造粒物過韩，獲得圓柱狀造粒物之比較農藥粒劑1。接著，呈示試驗例。試驗例1 在附有蓋子之玻璃製容器9. 6cm X高18cm)中放入 900mL之3度硬水，將水溫調整為25±1. (TC。將上述製劑例獲付之各粒劑之規定量放入該容器中，邊將該容器内之溶液溫度調整為25± 1 · 〇 °c進行溫度管理邊將該容器放置。從放入粒劑3日後及7日後，使用多注射器（p〇lyspuit) 取樣各容器中央部之溶液約2mL。將取樣之溶液以規定之條件用高速液體層析儀進行分析，將取樣之溶液中之異喧菌胺濃度定量，使用以下之公式算出異噻菌胺之溶出率。又’本試驗中使用之農藥粒劑之量為粒劑中含有之異噻菌胺全部溶解於水時之濃度（最大溶出濃度[卯m])為 0. 63±0. 05ppm 之量。異噻菌胺之溶出率（％) =(取樣之水溶液中異噻菌胺濃度[p P m ] /供給水中溶出試驗之農藥粒劑之最大溶出濃度[Ppm])Xl〇〇 324206 27 201249338 [表1] 供試粒劑 3曰後之溶出率（％) 7曰後之溶出率（％) 農藥粒劑1 29.1 73.4 農藥粒劑2 47.6 73.3 農藥粒劑3 78.5 81.3 農藥粒劑4 39.7 55.4 農藥粒劑5 19.4 21.8 農藥粒劑6 15. 0 27.7 農藥粒劑7 40.4 67.6 農藥粒劑8 27.8 34.4 農藥粒劑9 25.9 38.4 農藥粒劑10 45.6 63.2 農藥粒劑11 70.0 93.5 農藥粒劑12 87.3 91.3 農藥粒劑13 39.4 42.6 農藥粒劑14 75.2 89.4 農藥粒劑15 90.5 91.4 農藥粒劑16 78.9 84.7 農藥粒劑17 76.0 74.9 農藥粒劑18 40.5 50.7 比較農藥粒劑1 3.9 7.5 (產業上利用之可能性）本發明組成物為在組成物中含有之具有苯胺基羰基部分之化學構造之農藥活性化合物可迅速溶出，可早期、充分的發揮該農藥活性化合物具有之有害生物防治等之效力之組成物。【圖式簡單說明】益 #»»> 【主要元件符號說明】益 <»*> 324206 2828.9 parts by weight of isothiazide micropowder, Amilos No. 1A 324206 201249338 30. 0 parts by weight, Thorpe 5080 10. 〇 by weight, Shengguangshan clay S 931. 1 parts by weight mixed with Nouta mixer 'Approximately 1 part by weight of the mixed powder was obtained. 1000 parts by weight of the mixed powder was mixed with 220 parts by weight of water, and kneaded by a Nauta mixer. The obtained kneaded material was pulverized by a dome granulator and granulated with a diameter of 1.0 mm. The obtained granules were dried in a fluidized bed dryer and then crushed by a needle mill. The granulated product obtained by coarse crushing was passed through Han to obtain a comparative granule 1 of a cylindrical granulated product. Next, a test example is presented. Test Example 1 900 mL of 3 degree hard water was placed in a glass container with a lid of 9. 6 cm X height and 18 cm), and the water temperature was adjusted to 25 ± 1. (TC. The granules obtained by the above preparation examples were The predetermined amount is placed in the container, and the temperature of the solution in the container is adjusted to 25 ± 1 · 〇 ° c. The container is placed under temperature management. Three days after the granule is placed and after 7 days, the multi-injector is used (p 〇lyspuit) Sampling about 2 mL of the solution in the center of each container. The sampled solution was analyzed by a high-speed liquid chromatograph under the specified conditions, and the concentration of isopridamide in the sampled solution was quantified, and the isothiophene was calculated using the following formula. The concentration of the agrochemicals in the present invention is the concentration (maximum dissolution concentration [卯m]) of the isopropionamide contained in the granules when the granules are dissolved in water (0. 63 ± 0). The amount of 05 ppm. The dissolution rate of isothiazide (%) = (the concentration of isothiazide in the sampled aqueous solution [p P m ] / the maximum dissolution concentration of the pesticide granules in the dissolution test in the supply water [Ppm]) Xl〇〇 324206 27 201249338 [Table 1] Dissolution rate after the test granules are 3 ( (%) Dissolution after 7 曰Rate (%) Pesticide granules 1 29.1 73.4 Pesticide granules 2 47.6 73.3 Pesticide granules 3 78.5 81.3 Pesticide granules 4 39.7 55.4 Pesticide granules 5 19.4 21.8 Pesticide granules 6 15. 0 27.7 Pesticide granules 7 40.4 67.6 Pesticide granules Agent 8 27.8 34.4 Pesticide granules 9 25.9 38.4 Pesticide granules 10 45.6 63.2 Pesticide granules 11 70.0 93.5 Pesticide granules 12 87.3 91.3 Pesticide granules 13 39.4 42.6 Pesticide granules 14 75.2 89.4 Pesticide granules 15 90.5 91.4 Pesticide granules 16 78.9 84.7 Pesticide granules 17 76.0 74.9 Pesticide granules 18 40.5 50.7 Comparative Pesticide granules 1 3.9 7.5 (Probability of industrial use) The composition of the present invention is a chemical structure pesticide having an anilinocarbonyl moiety contained in the composition. The active compound can be rapidly dissolved, and the composition of the pesticidal active compound can be used for early and sufficient effects. [Simplified illustration] Yi#»»> [Main component symbol description] Benefit <» *> 324206 28

Claims

201249338 . VII. Patent application scope: 1. A granular pesticide composition comprising: a pesticidal active compound having a chemical structure containing an anilinocarbonyl moiety, and one or more selected from the group consisting of magnesium oxide, magnesium phosphate and argon magnesium oxide. Group of town compounds. 2. The granular pesticide composition according to claim 1, wherein the granule is a granule. 3. The granular pesticide composition according to claim 1 or 2, wherein the agrochemical active compound is a guanidine bactericide. 4. The granular pesticide composition according to claim 3, wherein the anilide bactericide is Isotiani 1 or Thiflugamide. 5. The granular agricultural composition according to any one of claims 1 to 4, wherein the magnesium compound is magnesium oxide. 6. The granular pharmaceutical composition according to any one of the preceding claims, wherein the pesticidal active compound and the magnesium compound are coated on a nucleus. 7. A pest control method according to any one of claims 1 to 6, wherein the granular pesticide composition according to any one of claims 1 to 6 is applied to a paddy field or a nursery box. 324206 1 201249338 IV. Designated representative map: (1) The representative representative of the case is: (). (There is no picture in this case) (2) A brief description of the symbol of the representative figure: (none) 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: This case does not represent the chemical formula 324206