201212993 六、發明說明： 【發明所屬之技術領域】 本發明係有關於消泡劑，特別是有關於一種固態消泡劑 及其製造方法。 【先前技術】 消泡劑主要運用於化學工業（樹脂合成）、廢水工業、石 油工業、製紙工業、塗料印刷工業、纖維工業、醫藥品工業、 發酵工業、食品工廠及其他相關產業中。目前消泡劑可分為以 下幾麵型：水性消泡劑、油性消_、溶_聽劑、及自 身乳化型消泡劑（水油二用）。消泡劑係利用降低液體表面張 力達到4除泡沫之作用，並同時抑制泡珠的產生。 從以上消泡劑類型可看出，傳統消泡劑均以液體形態存 在，且大多為乳白色黏稠狀液體，因此當用於廢水處理時，容 ^發生下列缺點。第—肖泡劑本身之_性質，容易導致加 藥泵或相關設備之管線阻塞，使得廢汙水處理廠之操作人員需 要經常地清理，不理想之至。第二，由於一般廢汙水處理設施 距離放流口通常還有一段距離或高程上之落差，為避免消泡劑 樂，失效，常需提高用藥量或使用較昂貴之長效型消泡劑，致 使消泡效果不易控制，加之廢汙水處理廠營運成本提高。 【發明内容】 蓉於以上所述習知消泡劑之缺失，本發明之一目的為提 4 201212993 供一種固態消泡劑。 藥日本發明之另—目的為於相同使訂降低消泡劑所需之加 發月之又目的為提供一種固態消泡劑，減少營運点 本、人力與時間。 ，發明提供一種固態消泡劑製造方法，其包含下列步 驟.提供-難溶液；加人—油祕上述雜溶液，以產生一 息化反應’形成-肥4與-甘油；加人-液誠賴；以及靜 置包含上述用於皂化反應的雖溶液、油脂及液㈣泡劑之混 合液以形成本發明之_消酬。其帽述提供雜溶液步驟 包含製作25〜60%濃度之氫氧化納，並冷卻該1氧化納至聊 以下。 刖述加入液態消泡劑步驟包含加入矽油消泡劑，加入油 脂步驟包含加熱5〜40重量百分比之植物油至大約5〇〇c，加入 上述氫氧化鈉以產生一第一混合液，進行攪拌並冷卻第一混合 液至50C以下。前述第一混合液產生步驟，進一步包含進行 授掉至無泡珠產生。 前述植物油包含10〜20重量百分比之椰子油與5〜1〇重量 百分比之棕欖油。前述加入液態消泡劑步驟包含加入3〇〜6〇 重量百分比之液態消泡劑於第一混合液，並攪拌均勻成一第二 混合液。本發明之一較佳實施例包含30重量百分比之氫氧化 鈉、20重量百分比之植物油及45重量百分比之液態消泡劑。 本發明之固態消泡劑形成方法’進一步包含加入5〜2〇重 201212993 量百分比之錢2〜5重量聰b之洋m洋菜溶液加 熱溶解此洋菜絲絲她，緩慢取縣溶_卜3重量百 分比之粉狀活性碳於上述第二混合液並攪拌均句，其中上 菜包含鹿角藻。 本發明亦提供-_M_，其成份包含胁息化反 應的5〜40重f百分比之鶴油、2(M()重奸分比之氮氧化 鈉’以及30〜60 f量百分比之液態消泡劑。上述植物油包含 K)〜20重量百分比之椰子油與5〜1〇重量百分比之織油液 態消泡劑包含矽油消泡劑。 本發明之固誠泡劑進—步包含2〜5重量百分比之洋菜 及1〜3重量百分比之粉狀活性碳，其中洋菜包含鹿㈣。在一 較佳實施财’本發明包含2G重量百分比之植 物油、30重量百姐之氫氧钱與45重量百分比之液態消泡 劑。 【實施方式】 消泡劑是-種用途十分廣泛的複配形精細化工產品，可 在紡織、印染、造紙、食品、化工、石油、制革、清洗、污水 處理及相關領域使用，不但具有快速消泡和持久抑泡的性能， 並具有使用範圍廣、成本低、生產容易、設備投資少、生產週 期短、無環境污染和經濟效益可觀等諸多優勢。 本發明提供一種固態消泡劑及其製造方法。如圖丨所示， 本發明固態消泡劑之製造方法，大體上至少包含下列4個主要 步驟：步驟110為提供鹼性溶液；步驟130為加入油脂於鹼性 6 201212993 溶液以產生皂化反應，形成肥皂與甘油；步驟15〇為加入液態 消泡劑；以及於步驟170靜置包含用於皂化反應的鹼性溶液、 油脂及液態消泡劑之混合液以形成固態消泡劑。本發明固態消 泡劑之製造方法’其獨特之處在於利用皂化反應將液態消泡劑 轉變成固態消泡劑’使原本液態消泡劑所帶來之種種缺點，得 以消失於無形。 圖2所示為本發明固態消泡劑製造方法另一實施例之流 程圖。如圖所示，前述提供鹼性溶液步驟11()進一步包含步驟 111.製作25〜60%遭度之氮氧化納’並冷卻此氮氧化納至5〇。〇 以下。然而在不同實施例中，驗性溶液之成份亦可包含氫氧化 _。此外，前述加入油脂步驟130進一步包含步驟ι31 :加熱 5〜40重量百分比之植物油至大約5〇艺，再加入上述已冷卻之 氫氧化鈉以產生第一混合液，並發生皂化反應，形成肥皂與甘 油。然而在不同實施例中，油脂之成份亦可包含動物油，如豬 油、牛油、羊油以及其他合適之動物油。植物油則可使用椰子 油、棕欖油、撖欖油、葵花油、芥花油以及其他合適之植物油。 之後進行轉133 ’將第-混合液進行獅至無躲產生，並 冷卻此第一混合液至501：以下。 如圖2所示，加入液態消泡劑步驟15〇進一步包含步驟 :當第-混合液溫度降至耽以下域_狀時，即可加 入30〜60重量百分比之矽油消泡劑於第一混合液，並攪拌均句 成第二混合液。在此-步驟中，箱消泡劑亦可以其他類型之 消泡劑取代’例如水性消細、溶刪消軸或自身乳化型消 201212993 泡劑等。接著即為圖2之最後一個步驟171 :靜置冷卻此第二 混合液成固態消泡劑。 關於矽油消泡劑，一般市售消泡劑以矽油系統應用範圍 最為廣泛’且效果最好。碎油系統消泡劑可分為聚梦氧流體 (Silicone fluid )、聚梦氧流體界面活性劑（Silicone fluid surfactant)、聚梦氧化合物（Silicone compound)與自行乳化 型矽油。用於廢污水處理系統之矽油消泡劑較佳為Silicone fluid surfactant ’其特點為泡破速率慢但抑泡效果好，適用於中 低溫（室溫〜50°C )且耐酸驗溶液環境p 再者，為加速反應將大約需要2〇天之反應時間縮減至少 於一星期，以提高生產效率及符合經濟效益，較佳可於製造固 態消泡劑之過程中添加洋菜（即瓊脂）及粉狀活性碳。然而在 不同實施例洋菜及粉狀活性碳亦可自其他具類似功效之成 份加以替代。洋菜須加水並加熱溶解後才可倒入前述之第二混 合液’亦即於圖2之步驟151之後。 如圖3所示’其作法較佳包含步驟160 :加入5〜20重量 百分比之水於2〜5重量百分比之洋菜產生一洋菜溶液，將其加 熱溶解成黏铜狀。接著於步驟161中，緩慢加入已溶解之洋菜 及1〜3重量百分比之粉狀活性碳於前述第二混合液並授摔均 句。必需強調的是’在不同實施例中，洋菜溶液及滩碳亦可 獨立擇一使用’並非必需同時使用。接著進行步驟172 ’靜置 冷卻此包含㈣、缝雜碳料二混合狀溶缝天後即形 成固態消泡劑。 8 201212993 如别所述，為縮短反應時間，本發明之固態消泡劑酌量 加入洋菜與雜雜碳。在較佳實_巾，如圖4所示，洋菜 之成份主要包含鹿角藻。而在此一步驟中各材料之最佳重量百 分比為3重量百分比之鹿角藻，15重量百分比之水，與i重 量百分比之雜活性碳。—般而言，加人鹿肖_粉狀活性碳 之第二混合液，在靜置冷卻六天後即可形成一固態消泡劑。然 而在不同實補中，洋菜亦可使用鹿角藻之外之成份，例如明 膠、黃原膠、魔¥膠、阿拉伯膠、海藻酸納及其他類似膠質。 粉狀活性碳則可以蜜蠟加以替代。 在本發明之較佳實施例中，如圖4所示，固態消泡劑之 各必要成份具有下列之重量百分比：用於皂化反應的3〇重量 百分比之氫氧化鈉，20重量百分比之植物油，以及45重量百 分比之液態消泡劑。再者，用於皂化反應的2〇重量百分比之 植物油又以15重量百分比椰子油與5重量百分比棕欖油之組 合為較佳。此些特定之重量百分比將可達成較理想之固態消泡 劑狀況，如體積大小、硬度適中等。另外，由於大於5〇%濃度 氫氧化鈉之製備較為困難而較少見，因此在較佳實施例中，將 選擇製作45%濃度之氫氧化鈉。然而大於50%濃度氫氧化鈉 仍可使用於本發明固態消泡劑之製備程序中。 簡而言之，在本發明之較佳實施例中，如圖4所示，本 發明固態消泡劑之製造方法包含步驟112:製作45%濃度之氫 氧化鈉’靜置冷卻此氮氧化鈉至50°c以下。接著進行步驟 132 ·•加熱15重量百分比之椰子油及5重量百分比之棕欖油， 201212993 再加入上述已冷卻30重量百分比之氫氧化鈉以產生第一混合 液。之後進行轉133 :將第—混合液進行麟至無泡泳產生， 並冷卻此第-混合液至町。接著進行步驟152 ··加入 45重量百分比之石夕油消泡劑於第一混合液，並擾拌均勻成第 二混合液。之後進行步驟162 :加人15重量百分比之水於3 重量百分比之鹿肖藻’將其加熱轉絲概。接著於步驟 163中：緩慢加入已溶解之鹿角蕩及i重量百分比之粉狀活性 碳於前述第二混合液並攪拌均^再接著即為圖4之最後一個 步驟173 :靜置冷卻此包含縣、粉狀活性雜第二混合液之 溶液數天後即形成固態消泡劑。 本發明較佳實施射產生之_消泡输佳具有下列特 徵：顏色為近似乳白色，比重介於！机i，pH值介於7 5_9 〇， 適合使用之水溫範圍為5t_45t，其溶解速率介於 10m!/hr-40ml/hr。 本發明以齡實_綱如上，雜並_嫌定本發 明所主張之專利權利範圍。其專利保護範圍當視後附之申請專 利範圍及其等闕域喊。凡縣此賴之贿者，在不麟 本專利精神或範圍内，所作之更動或潤飾，均屬於本發明所揭 讀神下所完成之等效改變或設計，且應包含在下述之申請專 【圖式簡單說明】 圖1係本發蝴__製造方法之實施例流程圖。 圖2係本發麵態_赚造方料—實施例之流程圖。 201212993 圖3係本發明固態消泡劑製造方法另一實施例之流程圖。 圖4係本發明固態消泡劑製造方法另一實施例之流程圖。 【主要元件符號說明】 110提供驗性溶液 111製作25〜60%濃度之氫氧化納，冷卻此氫氧化納至50。〇以 下。 112製作45%濃度之氫氧化鈉，靜置冷卻此氫氧化鈉至5〇〇匸 以下。 130加入油脂於驗性溶液以產生皂化反應 131加熱5〜40重量百分比之植物油至大約5(rc，加入已冷卻 之氫氧化鈉以產生第一混合液。 132加熱15重量百分比之椰子油及5重量百分比之棕欖油， 再加入已冷卻30重量百分比之氫氧化鈉以產生第一混合 液。 133將第一混合液進行授拌至無泡沐產生，並冷卻至兄。。以 下。 150加入液態消泡劑 151加入30〜60重量百分比之梦油消泡劑於第一混合液，並攪 拌均勻成第二混合液。 152加入45重量百分比之带油消泡劑於第一混合液，並攪拌 均勻成第二混合液。 201212993 160加入5〜20重量百分比之水於2〜5重量百分比之洋菜，將 其加熱溶解成黏稍狀。 161緩慢加入已溶解之洋菜及1〜3重量百分比之粉狀活性碳 於第二混合液，並攪拌均勻。 162加入15重量百分比之水於3重量百分比之鹿角藻，將其 加熱溶解成黏稠狀。 163緩慢加入已溶解之鹿角藻及丨重量百分比之粉狀活性碳 於第二混合液，並攪拌均勻。 170靜置包含用於皂化反應的鹼性溶液、油脂及液態消泡劑之 混合液以形成固態消泡劑。 Γ71靜置冷卻第二混合液成固態消泡劑 172靜置冷卻即形成固態消泡劑 173靜置冷卻即形成固態消泡劑 12201212993 6. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to antifoaming agents, and more particularly to a solid defoaming agent and a method of manufacturing the same. [Prior Art] Defoamers are mainly used in the chemical industry (resin synthesis), wastewater industry, petroleum industry, paper industry, paint printing industry, fiber industry, pharmaceutical industry, fermentation industry, food factory and other related industries. At present, defoamers can be divided into the following types: aqueous defoamers, oily eliminators, dissolved _ listeners, and self-emulsified defoamers (water and oil). The defoaming agent utilizes a reduction in the surface tension of the liquid to achieve the effect of removing the foam while suppressing the generation of the beads. As can be seen from the above types of defoamers, the conventional antifoaming agents exist in the form of liquids, and most of them are milky white viscous liquids, so when used for wastewater treatment, the following disadvantages occur. The nature of the first-bubble foaming agent itself tends to cause blockage of the pipeline of the dosing pump or related equipment, so that the operators of the waste water treatment plant need to be cleaned frequently, which is not ideal. Second, since the general waste water treatment facility usually has a distance or elevation from the discharge port, in order to avoid the defoaming agent, it is often necessary to increase the dosage or use a relatively expensive long-acting defoamer. The defoaming effect is not easy to control, and the operating cost of the waste water treatment plant is increased. SUMMARY OF THE INVENTION One of the objects of the present invention is to provide a solid antifoaming agent for the use of the above-mentioned defoaming agent. Another purpose of the invention in Japan is to provide a solid defoamer to reduce the operating point, manpower and time. The invention provides a method for manufacturing a solid antifoaming agent, which comprises the following steps: providing a difficult solution; adding a human-oil secreting solution to produce a mono-chemical reaction 'formation-fertilizer 4 and -glycerol; adding human-liquid And a mixture of the solution, the oil, and the liquid (4) foaming agent for the saponification reaction described above to be allowed to stand to form the present invention. The capping step of providing a heterogeneous solution comprises preparing sodium hydroxide at a concentration of 25 to 60% and cooling the sodium oxide to below. The step of adding a liquid antifoaming agent comprises adding an eucalyptus defoaming agent, and the step of adding the oil and fat comprises heating 5 to 40% by weight of the vegetable oil to about 5 〇〇c, adding the above sodium hydroxide to produce a first mixed liquid, stirring and Cool the first mixture to below 50C. The first first liquid producing step further includes performing the imparting to the bubble-free bead generation. The aforementioned vegetable oil comprises 10 to 20% by weight of coconut oil and 5 to 1% by weight of palm oil. The aforementioned step of adding a liquid antifoaming agent comprises adding 3 〇 to 6 重量% by weight of a liquid antifoaming agent to the first mixed liquid, and stirring to form a second mixed liquid. A preferred embodiment of the invention comprises 30 weight percent sodium hydroxide, 20 weight percent vegetable oil and 45 weight percent liquid antifoam. The method for forming a solid antifoaming agent of the present invention further comprises adding 5~2 〇weight 201212993 amount of money 2~5 weight Cong byangyang m seaweed solution to dissolve and dissolve this amaranth silk, slowly taking the county dissolution _ 3 parts by weight of powdered activated carbon is added to the above second mixture and stirred, wherein the dish contains the staghorn algae. The invention also provides -_M_, the composition of which comprises 5 to 40 weight percent of the noose oil, 2 (M () heavy rape ratio sodium oxynitride" and a liquid defoaming percentage of 30 to 60 f The above vegetable oil comprises K) to 20% by weight of coconut oil and 5 to 1% by weight of the woven oil liquid antifoaming agent comprising an eucalyptus oil defoaming agent. The solid foaming agent of the present invention comprises 2 to 5 weight percent of seaweed and 1 to 3 weight percent of powdered activated carbon, wherein the amaranth contains deer (four). In a preferred embodiment, the invention comprises 2 G weight percent vegetable oil, 30 weight percent hydroxyl alcohol and 45 weight percent liquid defoamer. [Embodiment] Defoamer is a compound chemical product with a wide range of uses. It can be used in textile, printing and dyeing, paper making, food, chemical, petroleum, leather, cleaning, sewage treatment and related fields. Defoaming and long-lasting foam suppression, and has many advantages such as wide use range, low cost, easy production, low equipment investment, short production cycle, no environmental pollution and considerable economic benefits. The present invention provides a solid antifoaming agent and a method of producing the same. As shown in FIG. ,, the method for producing a solid antifoaming agent of the present invention generally comprises at least the following four main steps: step 110 is to provide an alkaline solution; and step 130 is to add a fat to a basic 6 201212993 solution to produce a saponification reaction, Soap and glycerin are formed; step 15 is to add a liquid antifoaming agent; and in step 170, a mixture containing an alkaline solution for saponification, a grease and a liquid antifoaming agent is allowed to stand to form a solid defoaming agent. The method for producing a solid antifoaming agent of the present invention is unique in that the liquid antifoaming agent is converted into a solid defoaming agent by a saponification reaction, and the disadvantages caused by the original liquid defoaming agent are lost to invisible. Fig. 2 is a flow chart showing another embodiment of the method for producing a solid antifoaming agent of the present invention. As shown, the foregoing provision of the alkaline solution step 11 () further comprises the step 111. Making 25 to 60% of the nitrogen oxides of degree ' and cooling the nitrogen oxides to 5 Torr. 〇 The following. However, in various embodiments, the components of the assay solution may also comprise hydroxide. In addition, the foregoing adding grease step 130 further comprises the step of: heating the 5 to 40 weight percent of the vegetable oil to about 5 liters, adding the cooled sodium hydroxide to produce the first mixture, and saponifying to form a soap and glycerin. However, in various embodiments, the oil component may also comprise animal oils such as lard, butter, sheep oil and other suitable animal oils. For vegetable oils, coconut oil, palm oil, eucalyptus oil, sunflower oil, canola oil and other suitable vegetable oils can be used. Thereafter, the mixture was subjected to 133' to carry out the lion to no hiding, and the first mixture was cooled to 501: or less. As shown in FIG. 2, the step of adding a liquid antifoaming agent 15 further comprises the step of: adding 30 to 60% by weight of the eucalyptus oil defoaming agent to the first mixture when the temperature of the first mixed liquid falls to the lower 耽 state. The liquid was stirred and mixed into a second mixture. In this step, the defoamer can also be replaced by other types of defoamers, such as aqueous thinning, dissolution or self-emulsification, etc. 201212993 foaming agent. This is followed by the last step 171 of Figure 2: the second mixture is allowed to cool to form a solid defoamer. Regarding the eucalyptus defoamer, the commercially available defoamer is the most widely used in the eucalyptus system and has the best effect. Crude oil system defoamers can be classified into Silicone fluid, Silicone fluid surfactant, Silicone compound and self-emulsified eucalyptus. The eucalyptus oil defoaming agent used in the waste sewage treatment system is preferably Silicone fluid surfactant, which is characterized by slow foaming rate but good foam suppression effect, and is suitable for medium and low temperature (room temperature ~ 50 ° C) and acid resistance test solution environment p In order to speed up the reaction, it takes about 2 days to reduce the reaction time by at least one week to improve production efficiency and economic efficiency. It is better to add acacia (ie agar) and powder during the manufacture of solid defoamer. Activated carbon. However, in different embodiments, acacia and powdered activated carbon may be replaced by other components having similar efficacy. The amaranth must be added with water and heated to dissolve before being poured into the second mixture as described above, i.e., after step 151 of FIG. As shown in Fig. 3, the method preferably comprises the step 160: adding 5 to 20% by weight of water to 2 to 5 weight percent of the amaranth to produce an amica solution, which is heated and dissolved into a sticky copper shape. Next, in step 161, dissolved amica and 1 to 3 weight percent of powdered activated carbon are slowly added to the second mixture to impart a sentence. It must be emphasized that 'in different embodiments, the acacia solution and the beach carbon can be used independently. It is not necessary to use them at the same time. Then, the step 172 ′ is allowed to stand for cooling to form a solid defoaming agent after the (4) and the mixed carbonaceous material are mixed. 8 201212993 As described elsewhere, in order to shorten the reaction time, the solid antifoaming agent of the present invention is added to acacia and heteropolycarbons as appropriate. In the preferred embodiment, as shown in Fig. 4, the ingredients of the amaranth mainly include the staghorn algae. In this step, the optimum weight percentage of each material is 3% by weight of sphaerocephala, 15% by weight of water, and i by weight of hetero-activated carbon. In general, a second mixture of deer _ powdered activated carbon is added to form a solid defoamer after standing cooling for six days. However, in different supplements, the vegetables can also use ingredients other than staghorn algae, such as gelatin, xanthan gum, magic gel, gum arabic, sodium alginate and other similar gums. Powdered activated carbon can be replaced by beeswax. In a preferred embodiment of the present invention, as shown in FIG. 4, each of the essential components of the solid antifoaming agent has the following weight percentages: 3 parts by weight of sodium hydroxide for saponification, 20% by weight of vegetable oil, And 45 weight percent of a liquid defoamer. Further, the vegetable oil of 2% by weight for the saponification reaction is preferably a combination of 15% by weight coconut oil and 5% by weight palm oil. These specific weight percentages will result in a better solid state defoamer condition, such as moderate size and moderate hardness. In addition, since the preparation of sodium hydroxide is more difficult and less common than the concentration of 5% by weight, in the preferred embodiment, a 45% strength sodium hydroxide will be selected. However, greater than 50% strength sodium hydroxide can still be used in the preparation of the solid defoamer of the present invention. Briefly, in a preferred embodiment of the present invention, as shown in FIG. 4, the method for producing a solid antifoaming agent of the present invention comprises the step 112 of: preparing a 45% sodium hydroxide to "cool down" the sodium oxynitride. Up to 50 ° C. Next, step 132 is performed. • Heating 15% by weight of coconut oil and 5% by weight of palm oil, 201212993, and adding 30% by weight of the above-mentioned cooled sodium hydroxide to produce a first mixture. Thereafter, the transfer is carried out 133: the first mixed solution is subjected to a sump-free swimming, and the first mixed liquid is cooled to the town. Next, step 152 is carried out. - 45 wt% of Shixia oil defoamer is added to the first mixture, and the mixture is disturbed to form a second mixture. Then, step 162 is carried out: 15 weight percent of water is added to 3 weight percent of the deer sylvestris' to heat it. Next, in step 163, slowly add the dissolved staghorn and i weight percentage of the powdered activated carbon to the second mixture and stir them, and then continue to be the last step 173 of FIG. 4: standing and cooling the county After a few days, the solution of the powdery active hetero-second mixture forms a solid antifoaming agent. The preferred embodiment of the present invention has the following characteristics: the color is approximately milky white, and the specific gravity is between! Machine i, the pH value is 7 5_9 〇, the suitable water temperature range is 5t_45t, and the dissolution rate is between 10m!/hr-40ml/hr. The present invention is based on the scope of patent rights claimed by the present invention. The scope of patent protection is to be attached to the scope of the patent application and its equivalent. Any change or refinement made by the county's bribes in the spirit or scope of this patent belongs to the equivalent change or design done by God under the invention and should be included in the following application. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flow chart of an embodiment of a manufacturing method. 2 is a flow chart of an embodiment of the present invention. 201212993 Figure 3 is a flow chart showing another embodiment of the method for producing a solid antifoaming agent of the present invention. Figure 4 is a flow chart showing another embodiment of the method for producing a solid antifoaming agent of the present invention. [Description of main component symbols] 110 provides an inert solution 111. A sodium hydroxide having a concentration of 25 to 60% is prepared, and the sodium hydroxide is cooled to 50. Below you. 112 A 45% sodium hydroxide was prepared, and the sodium hydroxide was allowed to stand to cool below 5 Torr. 130 adding the oil to the test solution to produce a saponification reaction 131 heating 5 to 40 weight percent of the vegetable oil to about 5 (rc, adding the cooled sodium hydroxide to produce the first mixture. 132 heating 15 weight percent of coconut oil and 5 The weight percentage of palm oil, and then added 30% by weight of sodium hydroxide to produce the first mixture. 133 The first mixture is stirred until no foaming occurs, and cooled to the brother. Below. The liquid antifoaming agent 151 is added with 30~60% by weight of the dream oil defoaming agent in the first mixed liquid, and stirred uniformly to form the second mixed liquid. 152 adding 45 weight percent of the oil defoaming agent to the first mixed liquid, and Stir well to form a second mixture. 201212993 160 Add 5~20% by weight of water to 2~5 wt% of seaweed, heat it to dissolve into a sticky shape. 161 Slowly add dissolved amaranth and 1~3 weight A percentage of powdered activated carbon is added to the second mixture and stirred evenly. 162 15 weight percent water is added to 3 weight percent of the genus Ceratophyta, which is heated to dissolve into a viscous form. The powdered activated carbon of the staghorn and the weight percentage of sorghum is in the second mixture and stirred uniformly. 170 The mixture containing the alkaline solution, the oil and the liquid antifoaming agent for the saponification reaction is allowed to stand to form a solid defoaming agent. Γ71 is allowed to cool and cool the second mixed liquid to form a solid defoaming agent 172, which is cooled to form a solid defoaming agent 173, which is cooled to form a solid defoaming agent 12