TW201127911A - Coloring composition and color filter - Google Patents

Abstract

The present invention provides a color filter of sound color characteristic, heat-resistance, light resistance and solvent resistance, and a coloring composition used for manufacturing thereof. The coloring composition for color filter includes a transparent resin and a colorant. The colorant contains a halide composed of an alkaline dye and a counter compound of an anion component. The molecular weight of the counter compound is in the range from 200 to 3,500.

Description

201127911 VI. Description of the Invention: [Technical Field] [0001] The present invention relates to a coloring composition for use in manufacturing color filters, such as a crystal display device, a color image pickup device, and the like. The invention relates to a color light-passing sheet which has a calender sheet section formed by using the coloring site. [Patent [0002] 〇 [Prior Art] The liquid crystal display device has a structure in which, for example, a liquid crystal layer is sandwiched between W polarizing plates. The liquid crystal display device utilizes the alignment of liquid crystal molecules to change the polarization state of a polarizing plate, thereby controlling the amount of light penetrating the other light.

And let the polarizing plate liquid crystal display device: display mode package g to I) wedge type, IPS (plane switching} mode and mode. gas φ |

In particular, the TN model is the mainstream. Color filter for use in TV for color filter reproduction area

The liquid crystal display devices can display color images by setting colors between polarizing plates. Color liquid car taste and benefit, such as camera and personal computer monitor, etc., machine: device. / Therefore, the requirements for high contrast and high brightness and high reliability of the film are also increasing. Further, the color filter is provided on a transparent substrate such as glass, and two types of filter segments having different color phases are disposed. Each filter segment has a very small table with a width ranging from a few micrometers to hundreds of micrometers. Various shapes and configurations such as stripe arrangement and dihedral arrangement can be realized in the filter section. In any event, the filter segments are arranged neatly in a particular arrangement for each hue. In addition, a color camera device using C-MOS (Complementary Metal Oxide Semiconductor) or CCD (Charge Coupled Device) is generally used on the light-receiving surface of the image sensor 099132160 Form No. Α0101 Page 3 / 154 Page 10 201127911 , Filters with three primary colors of additive color mixing, namely blue (B), green (B) and red (R) colors, or their complementary yellow (Y), magenta (Μ) and cyan (C) colors Segmented color filter. In recent years, for color filters used in color image pickup apparatuses, demands for high transmittance, that is, color characteristics such as high brightness and wide color reproduction area have increased. The method for producing a color filter includes, for example, a method of using a dye as a colorant by a dyeing method using i coloration and a dye dispersion method, a pigment dispersion method using a colorant as a pigment, a printing method, and an electroplating method. In the pigment dispersion method, a color resist is used, which is obtained by dispersing pigment particles of a colorant in a transparent resin, mixing a sensitizer, an additive, and the like. Then, the color anti-caries agent is applied onto the substrate by a coating device such as a spin coater, and the interposer selectively exposes the coating film. The exposed coating film is sequentially subjected to inspection development and heat hardening treatment, thereby obtaining a filter segment. The color crossings are completed by repeating the above operations for each color. In many cases, the blue filter segment and the cyan calender segment have utilized a phthalocyanine pigment having good tolerance and color tone. The phthalocyanine pigment has different crystal forms such as a-type, b-type, d-type, and e-type. Since either type has good color and coloring power, it is suitable as a coloring agent coloring agent. Phthalocyanine pigments are known to have various central metals such as copper, zinc, nickel, cobalt and aluminum. Among them, copper-cyanine pigments have the highest chroma, and are therefore widely used. In addition, dissimilar metal phthalocyanine pigments such as metal-free copper phthalocyanine pigments, phthalocyanine pigments, alumina phthalocyanine pigments, and cobalt phthalocyanine pigments have also been put into practical use in the magenta filter segment and the magenta filter segment. In many cases, the benefits are 099132160. Form No. A0101 Page 4 / 154 pages 1003010545-0 201127911 Diketopyrrolopyrrole pigments, quinophthalone pigments and anthraquinone pigments with good tolerance and color tone. Any of these has good properties of high chroma and coloring power, and is therefore suitable as a coloring agent for color filters. When a green filter segment is formed, a halogenated phthalocyanine pigment having good tolerance and color tone is used in many cases. Any of these has good properties of high chroma and coloring power, and is therefore suitable as a color filter coloring agent. Further, similarly to the blue pigment, it is known that there are various central metals such as copper, zinc, nickel, cobalt, and aluminum. Among them, especially the phthalocyanine pigment and the phthalocyanine pigment have the highest chroma, so they are widely used.

In the conventional liquid crystal display device using a cold cathode tube type backlight, for example, a blue filter segment or a cyan filter region is a combination of a copper phthalocyanine pigment and a diketopyrrolopyrrole pigment. The blue filter segment or the ... - ή , magenta filter segment is a combination of an anthraquinone pigment and a diketone ratio and a pyrrole pigment, and the green filter segment is a halogenated phthalocyanine pigment. This achieves a high brightness and width color display area. However, as described above, in the case of the color filter, which is required to further increase the brightness and the width, the color display area 0 -, - : - 〆 | | | 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 A technique in which a dye is dissolved in a resin or the like as a coloring agent. Further, Japanese Laid-Open Patent Publication No. 2001-81348 discloses that a triaryl decane dye, a rosin dye, and an azo dye are subjected to lake formation, and these precipitated toners are used as colorants for color filters. However, the dye has a problem of poor heat, light, and poor solubility compared with the pigment. In JP-A-2008-304766, it is described that in order to improve heat resistance, light resistance, and solvent resistance, Triarylmethane dye and aromatic 099132160 Form No. A0101 Page 5 of 154 1003010545-0 201127911 A monosulfonic acid halogenated product or a triarylsulfane-based basic dye is used as a coloring agent coloring agent. However, since the triaryl decane-based basic dye and the halogenated product of the aromatic monosulfonic acid have a small molecular weight, they have a disadvantage of poor durability. Moreover, even if a basic dye is used directly, of course, its durability is still poor. SUMMARY OF THE INVENTION [0003] The present invention provides a color filter excellent in color characteristics, heat resistance, light resistance, and solvent resistance, and a colored composition used in the production thereof. In order to solve the above problems, the inventors of the present invention have intensively accumulated research, and as a result, it has been found that a coloring agent as a coloring composition can achieve high brightness by using a basic dye and a product obtained by halogenating a relative compound having a molecular weight within a specific range. A wide range of color reproduction areas has also found good performance in terms of heat resistance, light resistance and solvent resistance. Then, the invention according to the first and second aspects below is completed in accordance with the discretion. That is, the first aspect of the present invention relates to a coloring composition for a color filter comprising a transparent resin and a coloring agent; and the coloring agent comprises a halogenated product composed of a relative compound of a basic dye and an anionic component. The molecular weight of the aforementioned relative compound is in the range of 200 to 3,500. The molecular weight of the aforementioned relative compound may also be in the range of 250 to 3,500. The above relative compound may also be selected from at least one selected from the group consisting of heteropolyacids, organic sulfonic acids, organic carboxylic acids, and acid dyes. The colorant may further contain a resin having an acid group. The weight average molecular weight of the above acid group-containing resin may also be in the range of 400 to 12,000. The aforementioned resin having an acid group may also be a rosin-modified maleic acid resin. The acid value of the above acid-containing resin may also be in the range of 100 to 300 mgKOH/g. 099132160 Form No. A0101 Page 6 of 154 Page 1003010545-0 201127911 The above basic dyes can also be selected from the group consisting of triarylmethane dyes, rose red dyes, indigo dyes and flavin dyes. At least one of them. The coloring composition for a color filter may further contain a photopolymerizable composition and/or a photopolymerization initiator. Further, a second aspect of the invention relates to a color filter comprising a filter segment formed of the coloring composition for a color filter.

In order to solve the above problems, the inventors of the present invention have intensively accumulated research, and as a result, it has been found that a halogenated product composed of a triarylsulfane dye and a xanthene dye can realize a high brightness and a wide color reproduction region, and Good performance was also found with regard to tolerance. Then, according to this discretion, the inventions of the following third and fourth aspects are completed. That is, the third aspect of the present invention relates to a blue coloring composition for a color and a light-emitting sheet, which comprises a transparent resin and a coloring agent; the coloring agent contains a triarylmethane dye and a xanthene A halogenated product composed of a dye. The triarylmethane-based dye is a triarylmethane-based basic dye, and the xanthene-based dye may be a xanthene-based acid dye. Alternatively, the triarylmethane-based dye is a triarylmethane-based acid dye, and the xanthene-based dye may be an exemplary dye. The aforementioned xanthene dye may also be a rose red dye. The colorant may further contain a phthalocyanine-based pigment. Further, the coloring agent may further contain a dioxazine-based pigment. The blue coloring composition for the color filter may further contain a photopolymerizable monomer and/or a photopolymerization initiator. Further, a fourth aspect of the present invention relates to a color filter comprising a grass color number A0101, a seventh page, a total of 154 pages, 1003010545-0, 201127911, wherein the color filter is formed of a blue coloring composition. Blue filter section. Further, in order to solve the above problems, the inventors of the present invention have intensively accumulated research, and as a result, it has been found that a halogenated product composed of a xanthene-based basic dye and a xanthene-based acid dye can realize a high-brightness and a wide color reproduction region. It has also been found that good performance can also be achieved with regard to tolerance. Then, according to this discretion, the inventions of the following fifth and sixth aspects are completed. That is, the fifth aspect of the present invention relates to a coloring composition for a color filter comprising a transparent resin and a coloring agent; the coloring agent comprising a xanthene-based basic dye and a xanthene-based acid A halogenated product composed of dyes. The aforementioned xanthene-based basic dye may also be a rose-red, red dye. The colorant may further contain a phthalocyanine-based pigment. Further, the aforementioned colorant further contains a dioxin pigment. The coloring composition for the color filter may further contain a photopolymerizable monomer and/or a photopolymerization initiator. Further, a sixth aspect of the invention relates to a color filter comprising a filter segment formed of the coloring composition for a color filter. [Embodiment] [0004] 099132160 Hereinafter, the aspect of the invention will be described in detail. In addition, unless otherwise specified, "(meth)acrylic", "(meth)acrylyl", "(meth)acrylic acid", "(mercapto) acrylate" and "(meth)) "Acrylamide" means "acrylonitrile and/or mercaptopropene", "acrylic and/or mercaptopropene", "acrylic acid and/or form number A0101 lactone", "acrylate" and methyl Acrylate and "acrylic amine and methyl". Also, "c.i." means that the color index is exhausted. Page 8 of 154 1 Coffee 1〇54 201127911 (c.ι·). 〇First Aspect First, a first aspect of the present invention will be described. &lt;<Coloring composition for color filter>

The coloring composition for a color filter according to the first aspect of the present invention contains a transparent resin and a coloring agent. The colorant comprises a halogenated product of a relative dye of a basic dye and an anion source. Then, the molecular weight of the relative compound is within a specific range. That is, the colorant contains a salt which is an ion having a specific molecular weight and a relative ion of a dye in which the dye ion is an anion. Therefore, by using the colored composition, a color filter having a high luminance and a wide color reproduction region and having good heat resistance, light resistance, and good solvent property can be produced. <Colorant> The i-formation product which can be suitably used in the coloring composition is blue, purple, green, red, red, magenta, cyan or yellow. That is, the functionalized product which can be suitably used in the colored composition is a basic dye classified by CI basic blue, CI basic violet, CI basic green, CI basic red, and CI basic yellow, and the molecular weight is A dentured product obtained by a halogenation reaction of a relative compound within a specific range. The basic dye and the relative compound can be produced by, for example, dissolving both in an aqueous solution or an alcohol solution to form a halogenated product. Alternatively, the mixture may be melted and mixed while being heated, whereby a halogenated product may be obtained. Although the basic dye has good spectral characteristics, it is extremely lacking in light resistance and heat resistance as in general dyes. That is, when the basic dye is used in a color filter which requires a high reliability color display device or a color image pickup device, its characteristics are not sufficient. 099132160 Form No. A0101 Page 9 / 154 pages 1003010545-0 201127911 Therefore, in order to remove the disadvantages of basic dyes, anion replacement alkaline lifting knife ® larger material and molecular weight in a specific range of relative compounds 'It is preferable to use the resin with an acid group to compare the molecular weight of the compound relative to the molecular weight of the compound to the range of 25 to 5%, and the molecular weight of the compound is within the range of 25 to 3,500. Within the scope. The latter, i seems to be human and within the molecular range of 300 to 3500 (four) shirts relative to the compound. It is difficult to use heat resistance and light resistance when using a knife θ between 2 〇〇 and 75 吏 with a knife to reduce the relative compound. When it is sufficiently "sub-relative compound, it is not easy to shoot early, so that the tooth is not fully colored.... The number of ears exists, it is difficult [intestinal dye] 2. =3 can contain triaryl Μ The test dyes and the scent of the red scent are the "fourth" dyes, the flavin-based basic dyes, the rhododendron-based dyes, the fragrant dyes, the oleander red dyes and the methylene blue bases. Sex dyes, etc. ^ Specific triarylmethyst (tetra) dyes include, for example, CI basic purple U methyl violet), · (: I. Basic purple 3' (. leeches basic purple "^" / "" ^ .Basic blue with basic essence "^丨Basic Blue 5 (Basic Jing EX), C.丄Basic Blue 7 (Victoria Pure Blue BO) and CI Basic Blue 26 (Victoria Blue B c〇nc.); and 〇τ. Basic Green 丨 (bright green GX) and C · I. basic green 4 (malachite green). Among them, c. 丨. basic blue 7, C_I. basic green 4, c. I. basic purple 1 or C.丨.Basic Violet 3. In addition, rosin-based dyes can be exemplified by: c. 丨 Basic Red 〗 (Ms. Red 6G, 6GCP) and CI Basic Red 8 (Rose Red G); and C. 1_Basic Purple 10 (Rose Red B). Especially suitable for use c. Basic red number or ^丨.Basic form number A0101 099132160 Page 1 of 154 pages 201127911 Purple ίο. Also, the lycopene-based basic dye can be, for example, CI basic yellow 1. The rhododendron-based dye can be used. For example, CI basic yellow 2 and C..I. basic yellow 3. The safranin basic dye may have, for example, CI basic red 2. The oleander red basic dye may, for example, be CI basic red 12. Methylene blue The basic dye may, for example, be CI Basic Blue 9 (methylene blue FZ, methylene blue B), CI Basic Blue 25 (Basic Blue GO), and CI Basic Blue 24 (New Methylene Blue NX).

Among them, it is preferable to use CI basic yellow 1, CI basic blue 9, CI basic blue 24 or CI basic blue 25 〇 in terms of good color rendering, among which triaryl decane basic dye and rose red basic dye are particularly suitable. Or methylene blue basic dye. Further, on the formation of red pixels, a flavin-based basic dye as a complementary color is an effective material. The methylene blue basic dye exhibits a vivid blue color, and when it is made into the above halogenated product, it is a suitable material in terms of good heat. Further, the flavin-based dyes exhibit a vivid yellow color, and when the halogenated product is produced, it is a suitable material for good heat resistance. The triarylmethane-based basic dye and the rose-red basic dye are described in detail below. (Triarylmethane-based basic dye) The triarylsulfane-based basic dye is a color-developing material obtained by oxidizing the ruthenium 2 or 01! base to the center carbon. The triarylmethane-based basic dye is classified into the following three types depending on the number of 2 or 011 groups. Among them, a triamine triphenylmethane-based basic dye is particularly preferable from the viewpoint of exhibiting blue, red, and green in a good manner. a) Diamine triphenylmethane basic dye 099132160 Form No. A0101 Page 11 / 154 pages 1003010545-0 201127911 b ) - Amines bismuth calcination test dye c) Rose oxalate acid with 0H base Dyes = amine triphenylmethane-based basic dyes and diamine triphenyl decane-based basic dyes, good shades of sunlight, more suitable for good dyes and/or triphenylamine-based fuels Also suitable. One of the blue-based enamel-based laboratory dyes is in the range of wavelengths from 働 to (10), which has a high penetration rate. (Rose Red Basic Dyes) Next, the red color basic dyes of the rose block will be described. : Hai coloring composition Yang Zhong can be used to make the rosy red dye-based dyes appear red or purple. „ „ The red or purple test dyes belong to the test dyes such as C.!. Basic red and C·I.·Basic purple. Rose red dyes are in the range of ~ to 43_ Spectral characteristics with penetrating height. • s - fi &gt; ' 'S , Λ .; Rose red dyes are suitable for the transmittance of light above 0 nm above 9 〇 / °, for wavelength 600 rim; the light transmittance is above 75%, the transmittance is 5% or less in the range of wavelength 500 to 55 〇 nm, and the transmittance of light at a wavelength of 4 〇〇 coffee is 7 % or more. It is better to have a transmittance of more than 95% for a wavelength of 65 ,, a transmittance of 80% or more for a wavelength of 6 〇〇 nm, and a transmittance of (10) for a wavelength of _ to 55 (). Hereinafter, the transmittance of light for a wavelength of 4〇〇nffl2 is 75% or more. For each color total, the above basic dye can be used for a blue pixel such as a triaryl-based dye or methylene blue. For the test (4), (4), for example, CI basic blue U basic crystal 6G), cj basic 099132360 form number A0101 page 12 / 154 pages 1003010545- 201127 911 Blue 5 (Basic Crystal EX), c. I. Basic Blue 7 (Victoria Pure Blue B), CI Basic Blue 9 (Methylene Blue Fz, Methylene Blue B), c·丨·Basic Blue 24 (New Asia Blue NX), c. I. Basic Blue 25 (Basic Blue G〇) and CI Basic Blue 26 (Victoria Blue β c〇nc.). Also, as a complementary color to blue pixels, Rose Red is an artificial dye, and It is also effective to present red fragrant basic dyes and oleander red dyes, which are described later. For example, by using copper phthalocyanine pigment (CI pigment 15 : 6)

A blue pixel with high brightness can be obtained with a dentured product derived from a basic dye in red. In particular, a combination of a copper phthalocyanine pigment (C.I. Pigment Blue 15: 6) and a tooth-forming product of a rose-red basic dye is more preferable. 'a ., h, f, I * Γ V ' The basic dyes that can be used for red pixels are 'examples of mei # red ^ dyes, — M v - f

Safranin: test: sex dye or bamboo clip pink red test dye-material; can be cited as CI basic red 1 (Rose red 66 and 6 (; (^), c. J • basic red 2 (saffron) Analytical dyes), c. I. Basic red 8 (Meng Shouhong G), c. I. Basic red 12 (Oleander red alkaline dye) and CJ basic purple 1〇, (Rose Red B). As a complementary color of the red humiliation pixel, it is preferable to present a sucrose-based basic dye of the chapter 'color. It can be used for the green dye-based aryl aryl ketone-based test dye, and specifically, for example, CI basic green 1 ( Bright green GX) and CI basic green 4 (malachite green). [Comparative compound] The relative compound used in the colored composition is an anionic compound having a molecular weight in the range of 200 to 3500. The molecular weight of the relative compound is preferably In the range of 2 5 0 to 3 0 0 0, it is more preferably in the range of 3 〇〇 to 3 5 〇. Alternatively, the molecular weight of the relative compound is preferably in the range of 2 Torr to 750. Further, the relative compound The molecular weight of the anion should be in the range of 199 to 3499 099132160 Form No. A0101 Page 13 / 154 pages 1003010545-0 201127911, preferably in 249 In the range of 3499 or in the range of 199 to 749. The specific compound is, for example, an organic sulfonic acid such as a heteropoly acid or an aromatic sulfonic acid, an organic carboxylic acid such as an aromatic carboxylic acid or a fatty acid, or an acid dye. The relative compound is preferably organic. A sulfonic acid or an acid dye. In this case, the molecular weight of the relative compound is preferably in the range of 200 to 750.

Further, the molecular weight and the average molecular weight specified herein are obtained by rounding off the first decimal place of the theoretical value calculated from the molecular structure and the atomic weight. Further, when the relative compound is a sodium salt, the molecular weight and the average molecular weight defined herein mean the value of the molecule obtained by substituting hydrogen. (heteropoly acid) The heteropoly acid may, for example, be a phosphonic acid H3 (PW12〇4D) · nH2〇 (n and 30; and the expression is almost equal) (molecular weight 34.21), and the ashes tungstic acid 114 (5丨¥12〇) 4{)) • nH2〇(n and 30) (molecular weight 3418), manganese acid H3 (PM〇12〇4〇) · nH2〇(n and 30) (molecular weight 2205), shixi acid 113 (31 cubits) 〇12〇4()) · nH2〇(n and 30) (molecular weight 2202), phosphotungstic acid HQ (PW1Q vMovO, n) · nHqO (6&lt;X&lt;12) and phosphovanadomanganic acid

H15-X(PVl2-XMoxV.nH20(r^30). Phospho-tungstic acid, phosphorus vanadium manganese and strontium tungstate are formed by changing phosphotungstic acid, manganic acid, lanthanum tungstic acid and lanthanum manganic acid. The content of the component can be adjusted within the range of 2202 to 3421. When the heteropoly acid is used as the relative compound, the average molecular weight is preferably in the range of 2820 to 3421. This is because when the relative compound contains manganese and tungsten, The ratio of tungsten is preferably more than 50°/◦. In the case of phosphotungstic acid, a large amount of W is obtained by reducing the Mo content. (Organic acid: organic sulfonic acid and organic carboxylic acid) Acid) Organic acid can be used, for example, as an aromatic acid. As an aromatic acid, suitable for 099132160 Form No. A0101 Page 14 of 154 Page 1003010545-0 201127911

Suitable compounds are, for example, 1-naphthylamine-4,8-dicarboxylic acid (molecular weight 303), 1-naphthylamine-3,8-disulfonic acid (molecular weight 303), 1-naphthylamine-5, 7 -disulfonic acid (molecular weight 303), 1-naphthylamine-3,6-disulfonic acid (molecular weight 303), 1-naphthylamine-3,6,8-disulfonic acid (molecular weight 383), 2-naphthylamine- 6, 8-disulfonic acid (molecular weight 303), 2-naphthylamine-1,6-disulfonic acid (molecular weight 303), 2-naphthylamine-4, 8-disulfonic acid (molecular weight 303), 2-naphthylamine -3,6-disulfonic acid (amino-R acid) (molecular weight 303), 2-naphthylamine-5,7-disulfonic acid (amino J acid) (molecular weight 303), naphthol-4, 8 -disulfonic acid (molecular weight 304), 1-naphthol-3, 8-disulfonic acid (e acid) (molecular weight 304), 1-propanol-3,6-disulfonic acid (molecular weight 304), naphthol -3, 6, 8-trisulphonic acid (molecular weight 384), 2-naphthene-6,8-dicarboxylic acid (molecular weight · 304), 2_naphthene-3,6, 8, tricalcetrien (molecular weight 384 , Ν-phenyl-1-naphthylamine-8-sulfonic acid (molecular weight 299), Ν-p-tolyl-1-naphthylamine-8-sulfonic acid (molecular weight 313), fluorenyl-phenyl-naphthylamine- 5-sulfonic acid (molecular weight 299), Ν-styl-2-naphthylamine-6-sulfonic acid (molecular weight 299), Ν-acetamido-7-amino-1-naphthol-3- Acid (molecular weight 281), fluorenyl-phenyl-7-amino-1-naphthol-3-sulfonic acid (molecular weight 315), Ν-acetam-6-amino-1-naphthol-3-sulfonic acid ( Molecular weight 281), fluorenyl-phenyl-6-amino-1-naphthol-3-sulfonic acid (molecular weight 315), 1,8-dihydro-3,6-dicarboxylic acid (chromogenic acid) (molecular weight 320 ), 8-amino-1-caracene-5,7-disulfonic acid (molecular weight 319), 1,6-diamino-2-naphthol-4-disulfonic acid (molecular weight 254), 1-amine 2-naphthol-6,8-disulfonic acid (molecular weight 319), amidino-2-naphthol-3,6-disulfonic acid (molecular weight 319), 2, 8-diamino-1- Cai _5,7 - bis acid (molecular weight 334), 2,7-diamino-1-caxine · - 3 - continued acid (molecular weight 2 5 4), 2,6-diamino-1 Naphthalene-3 - acid (molecular weight 254), 2, 8-diamino-1-naphthol-3,6-disulfonic acid (molecular weight 334) and 2-amino-7-aniline-1-naphthol 3-sulfonic acid (molecular weight 330). 099132160 Form No. 1010101 Page 15 of 154 Page 1003010545-0 201127911 Also, it is also suitable to use fluorite (molecular weight 2 5 8 ), 蒽i Kun-2 - continuous acid or 蒽酉 -1- 1-1-6 acid (molecular weight 2.88). When a naphthylaminesulfonic acid having one amine group and one sulfonic acid group is used, good heat resistance and light resistance can be achieved. Examples of the naphthylaminesulfonic acid include 2-amino-1-naphthalenesulfonic acid (Tour acid, molecular weight 223), 4-amino-1-naphthalenesulfonic acid (naphthalenesulfonic acid, molecular weight 223), and 8-amino group. -1-naphthalenesulfonic acid (peripheric acid, molecular weight 223), 2-amino-6-naphthoic acid (Broenner acid, molecular weight 223), 1-amino-5-naphthalenesulfonic acid (Lorentz acid, molecular weight 223), 5-amino-2-naphthalenesulfonic acid (molecular weight 223), 1-amino-6-naphthalenesulfonic acid (molecular weight 223), 6-amino-1-naphthalenesulfonic acid (molecular weight 223) and 3- Amino-1-naphthalenesulfonic acid (molecular weight 223). Among them, 2-amino-1-naphthalenesulfonic acid (toluic acid) is particularly suitable. .' ' . It is also preferred to use hydroxynaphthalenesulfonic acid having one hydroxyl group and one sulfonic acid group. The hydroxynaphthalenesulfonic acid may, for example, be 2-hydroxy-6-naphthalenesulfonic acid (sialon, molecular weight 224), hydroxy-4-naphthalenesulfonic acid (niven acid: NW acid, molecular weight 224), 1-hydroxy-5 Naphthalenesulfonic acid (L acid 'molecular weight 224) and 2-hydroxy-8. Naphthalenesulfonic acid (hidden acid, molecular weight 224). From the viewpoint of good color rendering and high brightness, an organic sulfonic acid having 2 to 3 sulfonic acid groups is particularly preferable. If there are four or more sulfonic acids, the environmental stability is not good, and it is easy to cause a change with time. If it is one sulfonic acid, since the test dye and the relative compound will react by 1:1, when it is a primary color, Color development may be worse. However, in the case of an organic sulfonic acid having a molecular weight of from 200 to 250, since the molecular weight of the relative compound is small, even if the sulfonic acid group per molecule is one, the color rendering property is not impaired. The organic sulfonic acid can use, for example, an aromatic sulfonic acid or a fatty acid Specific Organic 099132160 Table_Single No. A0101 Page 16 of 154 Page 1003010545-0 201127911 The sulfonic acid may, for example, be tetrachlorophthalic acid (molecular weight 304), palmitic acid (molecular weight 257), stearic acid (molecular weight 285) ), arachidic acid (molecular weight 313), oxalic acid (molecular weight 341), twenty-four succinic acid (molecular weight 369), oleic acid (molecular weight 282), oleic acid (molecular weight 282), fentanic acid (molecular weight 339), nervonic acid (molecular weight 367), linoleic acid (molecular weight 280), gamolenic acid (molecular weight 278), arachidonic acid (molecular weight 305), a-linolenic acid (molecular weight 278), linoleic acid (molecular weight 276), twenty Carbaenoic acid (molecular weight 302) and docosahexaenoic acid (molecular weight 328).

In the case of an organic acid, the molecular weight is preferably from 200 to 400, more preferably from 250 to 400. By setting the molecular weight within this range, a coloring agent having a good balance between tolerance and coloring ability can be obtained. Further, in the case of an organic acid, the molecular weight may range from 300 to 400. (Acid Dye) The hue can also be controlled by using an acid dye as a relative compound. As described above, for the red pixel, for example, an i-formation product derived from a fragrant red dye, a fragrant basic dye, or a bamboo-pink-based basic dye can be used. In this case, an acid dye suitable as a relative compound is, for example, CI Acid Yellow 11 (molecular weight 380), C. 'I. Acid Yellow 23 (molecular weight 534), CI oxime red 52 (acid rose B) (molecular weight 580) , CI Acid Red 52 (Acid Rose B) (molecular weight 580), CI Acid Red 87 (Eosin G) (molecular weight 691.6) and CI Acid Red 289 (molecular weight 676.7). As the blue pixel, for example, a halogenated product derived from a triarylsulfane-based basic dye or a methylene blue-based basic dye can be used. In this case, an acid dye suitable as a relative compound is, for example, CI Acid Red 52 (Acid Rose B) (molecular weight 580), CI Acid Red 87 (Eosin G) (molecular weight 691.6), and CI Acid Red 289 (molecular weight) 676. 7). 099132160 Form No. A0101 Page 17 of 154 Page 1003010545-0 201127911 Green pixels can be used, for example, c. I. Basic Green 1 (Bright Green GX) and CI Basic Green 4 (Manet Green) from triaryl decane bases Halogenated product of a dye. In this case, an acid dye suitable as a relative compound is, for example, CI Acid Green 3 (Edible Green No. 1) (molecular weight 690), CI Acid Green 5 (Edible Green No. 2) (molecular weight 671), CI Acid Green 9 (molecular weight 724). ) CI Acid Green 16 (molecular weight 560), CI Acid Green 19 (molecular weight 625), and CI Acid Green 25 (molecular weight 622). In the case of an acid dye, the molecular weight is preferably in the range of from 300 to 750, more preferably from 350 to 700. When the molecular weight is set in this range, a coloring agent having a good balance between the tolerance and the coloring power can be obtained. In particular, rose red basic dyes and yellow acid dyes are suitable materials for obtaining red pigments. The halogenated product of the basic dye and the relative compound can be synthesized by a conventional method. Specific methods are disclosed, for example, in Japanese Patent Laid-Open No. 2003-21 5850. For example, using an example of a triarylmethane-based basic dye, after dissolving a triarylmethane-based basic dye in water, an organic sulfonic acid solution is added to the solution and stirred to thereby cause a halogenation reaction. Thereby, a halogenated product in which an amine group (-NHC9Hq) of a triaryl-based calcining dye is combined with an organic acid-based acid group L 〇 (-SOqH) can be obtained. 0 The organic sulfonic acid may be dissolved in an alkali solution such as sodium hydroxide before the halogenation reaction. For example, the organic sulfonic acid can also be used in the form of sodium sulfonate (-S〇3Na). That is, the sulfonic acid solution contains a solution of a compound in which a hydrogen atom of a sulfonic acid group (-s〇3h) is not substituted, and a sodium sulfonate solution such as a compound in which a hydrogen atom of a acid group is substituted. [Resin with acid group] 099132160 Form No. A0101 Page 18 of 154 Page 1003010545-0 201127911 Adding a resin with an acid group, such as adding rosin modified maleic acid resin and rosin modified anti-butyl Dioric acid (4) resin with acid group, rosin, (4) resin or erythritol copolymer with _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ . As a result, more excellent color rendering, heat and light resistance can be achieved. Here, the acid group is preferably a group (-c_) or an acid group (for example, -S〇3H4~S〇3Na). Further, the weight average molecular weight of the resin having an acid group is preferably from 4 Å to 12 Å.

Within the range of 400 to 60 Torr, it is more preferably in the range of 4 〇〇 to 2,000. Since such a resin is excellent in compatibility with a halogenated product, if it is made into a %, the dispersion of the tooth to form a miscellaneous viscosity becomes good. 2; -*· &gt; -r% Further, the weight of the acid-based eucalyptus wax is determined by the following method. Tetrahydrofuran (THF) was added to the sample and allowed to stand for 12 hours. Thereafter, the THF solution of the sample was taken care of, and the molecular weight of the sample dissolved in the filtrate was measured. The measurement was carried out by a gel column chromatography (GPC) method, and the molecular weight was calculated from a calibration curve prepared using a standard polystyrene. Take one of the conditions of «cutting conditions. :::·:; ; - ,:v: : -·ίν;:···;':'';:: ;:::' -ι5 &quot;i;i ^ * GPC installation: TORAY shares limited company fiStc-8120GPC Pipe column: TSK Guardcolumn Su-perH-HT/SK-GEL/SuperHM-M made by T0RAY Co., Ltd. 3 flow rate: 1. Oml/min (THF) Resin with acid group should be modified with rosin Butylene resin. Rosin The modified maleic acid resin has a polar group having an acid and a non-polar rosin skeleton. The acidic polar group is derived from the carboxyl group of the unreacted rosin acid and the carboxyl group of the maleic acid reacting and being compatible with the polar group of the binder resin. In addition, the non-polar rosin skeleton and the non-polarity of the bonding resin 099132160 Form No. A0101 Page 19 of 154 1003010545-0 201127911 Compatibility. Further, the polar group of the rosin-modified maleic acid resin having an acid reacts with the amine group of the test dye (unreacted dye in the halogenated product). The acid value of the acid group-containing resin is preferably in the range of 100 to 300 mgKOH/g. If the acid value is small, the compatibility between the resin and the halogenated product is insufficient. In addition, when the coloring composition is used as an alkali-developing type coloring resist to be described later, development failure is likely to occur. Here, the acid value is a value measured by the method specified in JIS K-0070. The mixing of the halogenated product and the resin having an acid group is carried out, for example, by the following method. (1) A method of mixing a resin dissolved in a solvent with a toothed product (2) A method of mixing a dissolved resin and a halogenated product. Further, mixing of a halogenated product and a resin having an acid group may be carried out by other methods. . Specific examples of the above mixing methods (1) and (2) are described below. Here, an example of the use of rose-red basic dye and rosin-modified maleic acid resin is shown. (1) Method of mixing a resin dissolved in a solvent with a halogenated product (1-1) ‘ A red rose-based dye is dissolved in water, and the solution is disturbed while adding a relative compound such as organic acid. In this way, the amine group of the sage red basic dye is combined with the acid group of the opposite compound to obtain a halogenated product. Further, the relative compound may be dissolved in a sodium hydroxide or the like before the halogenation reaction, and used, for example, in the form of sodium sulphate (-S〇3Na). (1-2) Next, add rosin to the previous liquid containing the halogenated product. 099132160 Form No. A0101 Page 20 of 154 1003010545-0 201127911 Alkene-acid resin. Specifically, 'firstly, in the body containing the product, the aqueous solution of the hydroquinone sodium aqueous solution is added, and the liquid liquid 4 is neutral. Then, in the solution, the added solvent is dissolved in the water, ~ right The maleic acid resin is modified and stirred. Thereafter, a mineral acid such as hydrochloric acid or sulfuric acid is added to the liquid to adjust the liquid to avoid hiding. The weight of the maleic acid resin is insoluble, and then filtered. 4 and drying to obtain a colored composition. Further, if necessary, the colored composition may be pulverized to a desired particle size.

099132160 (2) Method of mixing dissolved resin and toothed product in heating, "Banbrui closed mixer, 3-roll mill, city grinder, vibrating mill, ball research, fine Mixer, such as grinder and extruder, to reduce the burden of umbrellas: _ based resin, here is rosin modified cis-butyl 2 ore, with the softening point of _· acid-based resin The temperature is dissolved and mixed. Thereby, the functionalized product is uniformly dispersed in the resin having an acid group, and the coloring group obtained here is in the tree surface self-generating product package of the acid group. The shape of the coating, and then the coloring (4) is called crushing and pulverization, and adjusted to the desired particle size. 5* The mass ratio of the toothed product to the resin having an acid group (self-forming product: resin having a mercapto group) In the range of 70:30 to 95:5, the greater the ratio of the resin having an acid group to the coloring composition, the lower the color rendering property. Specifically, the color derived from the resin having an acid group is due to the coloring composition. The hue has a great influence. X, the ratio of the acid-based resin in the coloring composition The smaller the nano-chemical product, the smaller the effect of improving the dispersibility in the binder resin. The mass ratio of the halogenated product to the resin having an acid group (halogenated product·resin having an acid group) is preferably at 75:25 to 9〇: 1〇之范1003010545-0 表翠编号Α0101 Page 21 of 154 pages 201127911 围内. [Other colorants] In the coloring composition, for example, for the purpose of further improving heat resistance, it may contain more For the red coloring composition, for example, red pigments such as c. I. Pigment Red 168, 177, 179, 242, and 254 can be used. Further, the red coloring composition can be used in combination with CI. Pigment Yellow 13,138 Yellow pigment or yellow dye halogenated product such as 139, 150, 185 and 214, or orange pigment or orange dye functionalized product such as CI Pigment 38, 43, 71 and 73. For red coloring composition 'Weakness system: such as cd 4 Η gment Green 7, 36 and 58 and other green colors. Also, in the green coloring composition' can be combined with the above-mentioned coloring pigments or ·&quot; yellow edges to produce various things. For blue coloring compositions, For example c. Shu .pigment

Blue 15, 15 : 1, 15 : 2 ' 15 : 3, 15 : 4, 15 : 6 and 80 blue pigments. Further, in the blue color f group subtraction, C.I. Pigment Violet 19犮0 or the like: a violet pigment or a violet dye halogenated product can be used in combination. - In the yellow colored composition, the above yellow pigment or yellow halogenated product can be used. For the magenta coloring composition, for example, c. L pigment can be used.

Reddish pigments such as Red 122, 144, 146, 169, 192, 202, 207 and 209. Further, in the magenta colored composition, the yellow pigment or the yellow chemical product may be used in combination. For the cyan coloring composition, for example, c. j. pigment can be used.

Blue 15 ·· 1,15 : 2,15 : 4,15 : 3,15 : 6 and 80 etc. Blue 099132160 1003030545-0 Form No. A010 Page 22 / Total 54 pages 201127911 Color pigments. Further, in the cyan coloring composition, a purple pigment or a purple dye such as dPigment Vi〇iet 19 and 23 may be used in combination to form a product. In order to maintain sufficient brightness, the pigment component is preferably 5 parts by mass or less based on 100 parts by mass of the halogenated product. In this case, even if the coloring agent contains a large amount of pigment with respect to the above-mentioned _ chemical product, high brightness can be achieved. (Pigment Refining) The above pigment can be made fine by, for example, a salt milling treatment. From the viewpoint of good dispersion in the colorant carrier, the primary particle diameter of the pigment is preferably 20 nm or more. Further, from the viewpoint of forming a filter segment having a high contrast ratio, the one-human particle diameter is not more than 10 nm. The range of _ 輙 輙 is especially suitable for Μ to 85nm. .

:]ti f: ^ V Further, the primary particle size of the pigment was determined from an electron micrograph of the pigment obtained by T E Μ (through-type electron microscope). Specifically, the pigment particles of the entire _th particle can be viewed first by selecting '丨' from the image. Next, the line segment having the largest length is selected from the line segments connecting the two points of the pigment granules. The gray section intercepts the first line segment. Next, from the sharp line segment connecting the pigment particles like the rim 1, a line segment intersecting the i-th line segment between the towels JL is selected. This line segment is set to the second line segment. Then, the average length L of the first line segment and the length L2 of the second line segment are obtained, and the average length Lav is obtained, and the volume v of the cube whose length is equal to the average length L av is obtained. Perform the above measurement and calculation for more than 100 pigment particles, and find the average of the volume v, and set it as the average volume v.

3 V. The length of the cube having the average _Vav is set as the average primary particle diameter of the pigment particles. 2 roll mill, 3 roll mill, ball salt mill process means kneading machine 099132160 Form No. A0101 Page 23 / 154 pages 1003010545-0 201127911 Mixing mixer such as grinding crucible, grinder and sand mill, The mixture of the pigment, the water-soluble inorganic salt and the water-soluble organic solvent is heated while being mechanically mixed and stirred, and the water-soluble inorganic salt and the water-soluble organic solvent are removed by washing with water. The water-soluble inorganic salt functions as a pulverization aid. In salt milling, the high hardness of the inorganic salt is used to pulverize the pigment. By optimizing the conditions for the salt-milling treatment of the pigment, it is possible to obtain a pigment having a very small particle diameter, or a narrow distribution width, and a clear particle size distribution. As the water-soluble inorganic salt, for example, sodium gasification, barium chloride, potassium chloride or sodium sulfate can be used. From the price point of view, it is advisable to use sodium vapor (salt). From the viewpoints of processing efficiency and production efficiency, when the total mass of the pigment is set to 100 parts by mass, the water-soluble inorganic salt is preferably used in an amount of 50 to 2000 parts by mass, preferably 300 to Τ00 Ό. The amount within the range is used. The water-soluble organic solvent functions as a wet pigment and a water-soluble inorganic salt, and is not particularly limited as long as it is dissolved (mixed) in water and substantially not dissolved in the ice-soluble inorganic salt. However, in the salt milling treatment, the temperature rises and the solvent is in a state of easy evaporation. Therefore, from the viewpoint of safety, it is preferably a high boiling point solvent having a boiling point of 120 ° C or higher. For example, 2-(methoxymethoxy)ethane, 2-butoxyethane, 2-(isopropoxy)ethane, 2-(hexyloxy)ethane, 2-(hexyloxy) can be used. Ethylene, diethylene glycol, diethylene glycol monodecyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, triethylene glycol, triethylene glycol monomethyl ether, Liquid polyethylene glycol, 1-decyloxy-2-propanil, 1-ethoxypropane, dipropylene glycol, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether or liquid polypropylene glycol. The water-soluble organic solvent is used when the total mass of the pigment is set to 1 〇〇 mass part, preferably 099132160 Form No. A0101 Page 24 / 154 pages 1003010545-0 201127911 It is used in the range of 5 to mt). It is preferably used in an amount within the range of 5 〇 to 5 〇〇 mass. When the pigment is subjected to salt milling treatment, a resin may also be added. The kind of the resin is not particularly limited, and for example, a natural resin, a modified natural resin, a synthetic resin or a synthetic resin modified from a natural resin can be used. The resin is preferably solid at room temperature and insoluble in water is more soluble in the above organic solvent. The amount of the resin used is preferably in the range of 5 to 20 Q by weight when the total mass of the pigment is 100 parts by weight.

099132160 When the pigment is subjected to salt milling treatment (fine refinement), it is preferred to add the above-mentioned chemical conversion product at the same time as described above. Since the chemically formed product is insoluble in water and alcohol, a better coloring agent can be obtained. Γ ^ ' 丄' ., <Transparent Resin. _ $ &amp; Transparent resin is a coloring agent, especially for chemical generation A substance that is dispersed and/or dissolved. The transparent resin may, for example, be a thermoplastic resin or a thermosetting resin. Further, the coloring agent herein is, for example, a functional product or a mixture of a halogenated product and a pigment.透明;· The transparent resin is preferably visible in the first zone, that is, in the full wavelength region of 400- to 70 Onm, the spectral transmittance is 8〇% or more. When a coloring composition is used in the form of an alkali-developing coloring resist, an alkali-soluble vinyl resin obtained by copolymerizing a monomer containing an acidic group and ethylene is preferably used. Further, in order to further enhance the light sensitivity, an energy ray-curable resin having ethylene bonding may also be used. Examples of the thermoplastic resin include acrylic resin, butyral resin, styrene-maleic acid copolymer, vaporized polyethylene, vaporized polypropylene, polyvinyl chloride, ethylene-vinyl acetate copolymer, and polyacetic acid. Ethylene, urethane resin, polyester resin, vinyl resin, alkyd resin, poly form number A0101, page 25 / 154 s 1003010545-0 201127911 Styrene resin, polyamide resin, rubber resin, cyclized rubber Resin, cellulose, polyethylene (HDPE, LDPE), butadiene resin and polyimide resin. The alkali-soluble vinyl-based resin obtained by copolymerizing a monomer having an acidic group and an ethylene-bonded monomer may, for example, be a resin having an acidic group such as a carboxyl group or a sulfonic acid group. Specific examples of the alkali-soluble resin include an acrylic resin having an acidic group, an a-olefin-(anhydride) maleic acid copolymer, a styrene-styrenesulfonic acid copolymer, and a styrene-(fluorenyl)acrylic acid copolymer. And isobutylene-(anhydride) maleic acid copolymer. Among them, at least one resin selected from the group consisting of an acrylic resin having an acidic group and a styrene-styrenesulfonic acid copolymer having an acidic group is preferable, and an acrylic resin having an acidic group is particularly preferably used because it has high heat resistance and transparency.

As the active energy ray-curable resin having ethylene bonding, for example, a polymer having a reactive substituent such as a hydroxyl group, a carboxyl group or an amine group, and a reactive substituent having an isocyanate group, an aldehyde group or an epoxy group are used. A resin which reacts with an acrylic acid compound or cinnamic acid to introduce a photo-branching group such as a (meth) acrylonitrile group or a styryl group. Further, a copolymer of a copolymer of stupid ethylene-maleic anhydride or a-olefin-maleic anhydride is also used by using a (meth)acrylic compound having a hydroxyl group such as a hydroxyalkyl (meth) acrylate. A polymer such as an acid anhydride is semi-esterified. The active energy ray-curable resin having an ethylene bond may, for example, be a resin obtained by introducing ethylene in combination by the following method (a) or (b). In the method (a), a copolymer having an epoxy group in a side chain is obtained, for example, by copolymerizing a monomer having an epoxy group and ethylene in combination with one or more other monomers. Next, in the side chain, the ethylene bond and the carboxyl group are not sufficient, and the carboxyl group of the monovalent acid is additionally reacted with the carboxyl group of the monovalent acid to further react the acid anhydride. . Thus, a resin into which an ethylene bond and a carboxyl group were introduced was obtained. Examples of the monomer having an epoxy group and an ethylene bond include a glycidyl (meth) acrylate, a decyl propyl propyl (meth) acrylate, and a 2-glycidoxy group (methyl). ) acrylate, 3, 4 epoxybutyl (meth) acrylate and 3, 4 epoxy cyclohexyl (meth) acrylate. These may be used alone or in combination of two or more. The viewpoint of the reactivity with the unsaturated monovalent acid in the next step is preferably epoxypropyl (decyl) acrylate.

Examples of the unsaturated monovalent acid include (mercapto)acrylic acid, crotonic acid, hydrazine-, m- or p-vinylbenzoic acid, and a-halogenane, alkoxy, dentate, and (meth)acrylic acid. A monocarboxylic acid such as a nitrate or a cyanide substitute. These may be used alone or in combination of two or more. ;- As the sour liver, for example, tetrahydrophthalic anhydride, stupid acid liver, hexahydrophthalic anhydride, succinic anhydride, maleic anhydride or the like can be given. These may be used alone or in combination of two or more. For the substitution of an acid anhydride having two carboxyl groups, or an acid anhydride having two carboxyl groups, an acid anhydride having three or more carboxyl groups, for example, a tricarboxylic acid such as trimellitic anhydride or a tetracarboxylic acid such as pyromellitic dianhydride may be used. Diacid anhydride. In this case, the anhydride group remaining after the reaction of the hydroxyl group with the acid anhydride can also be hydrolyzed. As the acid anhydride, an acid anhydride having ethylene bonding such as tetrahydrophthalic anhydride or maleic anhydride can also be used. This can further increase the ethylene bond. Further, as a method similar to the method (a), for example, the following method. First, a monomer having a carboxyl group and an ethylene bond is copolymerized with one or more other monomers to obtain a copolymer having a carboxyl group in a side chain. Next, a monomer having an ethylene bond and an epoxy group is added to a portion of the carboxyl group of the side chain. 099132160 Form No. A0101 Page 27 of 154 Page 1003010545-0 201127911 Reaction. Thus, a resin into which an ethylene bond and a carboxyl group were introduced was obtained. In the method (b), a monomer having a hydroxyl group and an ethylene bond is copolymerized with an unsaturated monovalent acid or other monomer having a carboxyl group and an ethylene group to obtain a copolymer having a warp group in a side chain. Next, an isocyanate group having a monomer having an isocyanate group and an ethylene bond is reacted at the base of the side chain. Thus, a resin into which an ethylene bond and a carboxyl group were introduced was obtained. Examples of the monomer having a hydroxyl group and an ethylene bond include 2-hydroxyethyl (decyl) acrylate, 2- or 3-hydroxypropyl (decyl) acrylate, 2- or 3- or 4-hydroxy butyl Hydroxyalkyl (fluorenyl) acrylates such as methacrylic acid esters, glycerol (meth) acrylates, and cyclohexanedimethanol mono(meth) acrylates. These may be used alone or in combination of two or more. Further, it can also be used in a hydroxyalkyl (meth) acrylate, a compound obtained by additionally polymerizing an ethylene peroxide, a propylene peroxide, and/or a butyl peroxide, for example, a polyether mono (methyl). An acrylate, or a hydroxyalkyl (mercapto) acrylate, with at least one of (poly)g-valerolactone, (poly)e-caprolactone, and (poly)12-hydroxystearic acid A (poly) ester mono(indenyl) acrylate. From the viewpoint of suppressing the incorporation of foreign matter into the coating film, it is preferably 2-hydroxyethyl (meth) acrylate or glycerol (mercapto) acrylic acid. The monomer having an isocyanate group and an ethylene bond may, for example, be 2-(indenyl)acryloyloxyethyl isocyanate or 1,1-bis[(meth)acryloxime]ethyl isocyanate. These may be used alone or in combination of two or more. Further, as the thermoplastic resin, it is also preferable to use an alkali-soluble energy and an energy ray-curing property in the coloring composition for a color filter. Examples of the thermosetting resin include epoxy resin, benzoamine resin, 099132160, Form No. A0101, page 28, and 154 pages, 1003010545-0, 201127911. Rosin modified cis-butyl hydrazine, t-cyanide resin, urea tree Lavanji h modified the fumaric acid tree, the Sanjuling 掏 'month &amp; room to disperse or wait for the colorant. Sub-quantity (five)) should be in the embarrassment. ,. . . , consideration, the average weight of Lin

10j 000^〇〇〇^J should be at 5, 00. To 5. , _ again 'the average molecular weight (Μη) (10) and the average number of points within the circumference. The ratio Mw/Mn of the weight average molecular weight of the resin 4 XCMn) is preferably 10 or less. From the film-forming properties and the various tolerant agents, the transparent tree is tied to the coloring

099132160 When the mass is 100 mass parts, it should be 3. Quality and quantity are used. In addition, since the color concentration of the colorant is high, good color characteristics can be exhibited. Therefore, the quality of the coloring agent is based on the mass of the coloring agent, and it is preferable to use the amount below the coffee quality part. <Dispersion: The coloring composition It can be dispersed by a coloring agent comprising a coloring agent of an organic dye and an opposite compound, a transparent resin and a solvent used as needed, and preferably dispersed with a color: ii1 Auxiliary equipment is manufactured together with various dispersing mechanisms such as a 3-roll mill, a mill, a sand mill, a kneader, and a grinder. Further, the colored composition may be produced by dispersing a plurality of coloring agents individually on a colorant carrier, and then mixing them. (Dispersing aid) When the coloring agent is dispersed in the coloring agent carrier, a dispersing aid such as a pigment derivative, a resin type pigment dispersing agent, and a surfactant can be suitably used. The dispersing aid has a good ability to disperse the colorant, and the effect of preventing the re-coagulation of the dispersing coloring agent is great. Therefore, when a coloring composition using a dispersing aid to disperse the coloring agent in the coloring agent carrier is used, 1003010545-0 can be obtained. Form No. Α0101 Page 29 of 154 pages 201127911 Color with high light transmittance Filter. The pigment derivative may be an organic dye such as an organic pigment or an organic dye, an anthracene, an acridone or a triazine, and a basic substituent, an acidic substituent or an adjacent substituent may be introduced. Amine-based compound. Among these, pigment derivatives are particularly suitable. The structure is represented by the following formula (1). Ρ-L Formula (1) η wherein lanthanide represents an organic pigment residue, an anthracene skeleton, an acridone skeleton or a triazine skeleton, and the L system represents a basic substituent, an acidic substituent or may have a substituent. Orthoxylene imine f group, η is an integer of 1 to 4. Examples of the organic pigment constituting the residue of the organic pigment include, for example, a π-pyrolopyrrole-based pigment; an azo-based pigment such as azo, disazo, or polyazide; copper phthalocyanine and copper phthalocyanine; , non-metal phthalocyanine and other phthalocyanine pigments; amine onion, diamine, scallions, pyridazine, xanthone, indolinone, standard reduction blue, furanone, anthrone purple dye and other onion pigments; Quinone pigment; dithiazine pigment; anthraquinone pigment; anthraquinone pigment; thiazinium blue pigment; isoindane pigment; isoindolinone pigment; quinophthalone pigment; Pigments; and metal-missing pigments. The pigment derivative can be, for example, those described in JP-A-63-30051, JP-A-57-15620, JP-A-59-40172, and JP-A-5-9469. These may be used alone or in combination of two or more. From the viewpoint of the improvement of the dispersibility, the amount of the pigment derivative is preferably 1 part by mass or more, more preferably 3 parts by mass or more, and most preferably 5 parts by mass or more for 100 parts by mass of the colorant. In addition, from the viewpoint of financial efficiency and financial property, the blending amount of the pigment derivative is 10 parts by mass for the coloring agent, preferably 099132160, the form number Α 0101, the 30th page, the total 154 pages, the 1003010545-0, the 201127911 is 50 mass parts or less. It is more preferably 30 mass parts or less, and most preferably 25 mass parts or less.

The resin type dispersant has a pigment affinity site having a property of adsorbing on a pigment and a site compatible with the pigment carrier, and has a function of adsorbing the colorant to stabilize the dispersion of the colorant with respect to the pigment carrier. As the specific resin type dispersant, for example, a polycarboxylate such as polyurethane or polyacrylate, an unsaturated polyamine, a polycarboxylic acid, a polycarboxylic acid (partial) amine salt, a polycarboxylate ammonium salt, a polycarboxylic acid alkylamine can be used. a salt, a polyoxyalkylene, a long-chain polyamine phthalamide phosphate, a hydrocarbon-containing polycarboxylate or a modification thereof, by reacting with a polyester having a polymerization (lower alkylenimine) and a free carboxyl group An oily dispersant such as a guanamine or a salt thereof, a (mercapto)acrylic acid-(mercapto) acrylate copolymer, a styrene-maleic acid copolymer, a polyvinyl alcohol, a polyvinylpyrrolidone, or the like A water-soluble resin, a water-soluble polymer compound, a polyester-based dispersant, a modified polyacrylic acid vinegar-based dispersant, an ethylene oxide/propylene oxide-addition compound, and a phthalate-based dispersant. These may be used alone or in combination of two or more. The resin type dispersant is not necessarily limited to these. The surfactant may, for example, be sodium lauryl sulfate, polyepoxysulfate sulfate, sodium dodecylbenzenesulfonate, an acrylate of a styrene-acrylic acid copolymer, sodium alkylnaphthalenesulfonate or an alkyl group. Sodium phenyl ether disulfonate, ethanolamine lauryl sulfate, triethanolamine lauryl sulfate, ammonium lauryl sulfate, ethanolamine stearate, ammonium stearate, sodium lauryl sulfate, ethanolamine of styrene-acrylic acid copolymer, polyepoxy Anionic surfactants such as ethane ether phosphate; polyethylene oxide oleyl ether, polyethylene oxide lauryl ether, polyethylene oxide decyl phenyl ether, polyethylene oxide ether phosphate, polyethylene oxide sorbose Cationic surfactants such as glycerol stearic acid; alkyl 4-grade ammonium 099132160 Form No. A0101 Page 31 / 154 pages 1003010545-0 201127911 Salt or its epoxy Ethylene add-on and other raw gel dryness Surfactant; alkyl quaternary ammonium carboxylate internal salt such as alkyl dimethylamine acetic acid quaternary ammonium carboxylate; or an amphoteric surfactant such as alkyl imidazoline. These may be used singly or in combination of two or more. The surfactant is not necessarily limited to these. The solvent is formed in the coloring composition so that the coloring agent can be sufficiently dispersed in the coloring agent carrier, and it is easy to apply to a substrate such as a glass substrate, and after being applied as a dry film, it is, for example, 0.2 to 5 mm, forming a light-receiving sheet section. . Examples of the solvent include 1,2,3-tris-propane, 1, 3-butanediol, 1,3-butene glycol, and benzyl alcohol. 1,3,3-butanediol diacetate, 1,4-dioxane, 2-heptanone, 2-mercapto-1,3-propanediol, 3,3,5-trimethyl-2-cyclohexane En-1-one, 3,5,5-trimethylcyclohexanone, 3-ethoxypropionic acid ethyl, 3-methoxy-3-methylacetate butyl ester, 3-methoxybutanol, 3-methoxyacetic acid butyl ester, 4-heptanone, m-xylene, m-diethylbenzene, m-dichlorobenzene, N,N-dimercaptoacetamide, n-butylbenzene, n-propyl acetate, N- Pyrrolidone, o-diphenylbenzene, o-toluene, o-diethylbenzene, o-diphenyl, p-chlorotoluene, p-diethylbenzene, dibutylbenzene, tert-butylbenzene, isophorone, ethylene glycol diethyl ether , ethylene glycol dibutyl ether, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether, ethylene glycol monobutyl ether acetate, ethylene glycol monopropyl ether, diisobutyl ketone, cyclohexanol acetic acid Salt, dipropylene glycol dimethyl ether, dipropylene glycol methyl ether acetate, dipropylene glycol monobutyl ether, diacetone alcohol, propylene glycol diacetate, propylene glycol phenyl Ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monoterpene ether, propylene glycol monomethyl ether acetate, propylene glycol monomethyl ether propionate, phenyl alcohol, methyl isobutyl ketone, nonyl cyclohexanol, n-amine acetate Base, n-butyl acetate, isoamyl acetate 'isobutyl acetate, 099132160 Form No. A0101 Page 32 / 154 pages 1003010545-0 201127911 Acetate propyl and dibasic acid ester. Among them, propylene glycol monodecyl ether acetate, propylene glycol monoethyl ether acetate, ethylene glycol monodecyl ether acetate, and ethylene glycol monoethyl group are preferably used from the viewpoint of good dispersibility or solubility of the colorant. An alcohol such as an alcohol acetate such as an ether acetate or a ketone such as cyclohexanone or an aromatic alcohol such as a benzyl alcohol. The solvent may be used alone or in combination of two or more. In addition, since the solvent can adjust the coloring composition to an appropriate viscosity to form a coloring layer having a uniform film thickness, it is preferable to use it in an amount of 800 to 4,000 parts by mass when the total mass of the coloring agent is 100 parts by mass. .

099132160 <Photopolymerizable composition> Examples of the monomer or oligomer used in the photopolymerizable composition include methyl (meth) acrylate, ethyl (meth) acrylate, and 2 &amp; hydroxy group. Monofunctional (meth) propylene such as ethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, cyclohexyl (meth) acrylate, b-carboxy (meth) acrylate, and tricyclodecenylmethacrylate Acid esters; polyethylene glycol mono(indenyl)acrylate, 1,6-hexanediyl(decyl)acrylate, triethylene glycol di(meth)acrylate, and tripropylene glycol di(methyl) Acrylate, etc. di-functional (meth) acrylates; trimethylolpropane (meth) acrylate, neopentyl alcohol (meth) acrylate, neopentyl alcohol tetra (meth) acrylate a trifunctional or higher polyfunctional (meth) acrylate such as dipentaerythritol penta (meth) acrylate or dipentaerythritol hexa (meth) acrylate; 1,6-butanediol diglycidyl Ether, bisphenol A diglycidyl ether, neopentyl glycol glyceryl ether And a reaction product of an epoxy compound such as a phenol resin and (meth)acrylic acid, that is, an epoxy (meth) acrylate; a modified polyester (meth) acrylate such as polyester, polyurethane, isocyanate or methylolated melamine Ester; and (meth)acrylic acid Form No. A0101. Page 33 / 154 pages 1003010545-0 201127911, styrene, vinyl acetate, hydroxyethyl vinyl ether, ethylene glycol divinyl ether, neopentyl alcohol triethylene A monomer other than a (meth) acrylate such as an ether, (mercapto) acrylamide, N-hydroxymethyl (decyl) acrylamide, N-vinyl decylamine or acrylonitrile. These may be used alone or in combination of two or more. The monomer or the condensed polymer is not necessarily limited to the <photopolymerization initiator>. When the filter segment is formed from the color filter using the color ray lithography by the ultraviolet ray, the coloring composition is formed. A photopolymerization initiator or the like is added. The photopolymerization initiator may, for example, be 4-phenoxydioxoacetophenone, 4-t-butyldichloroacetophenone, diethoxyacetophenone or 1-(4-isopropylene). Phenyl)-2-hydroxy-2-mercaptopropan-1-one, 1-hydroxycyclohexyl benzophenone, 2-benzyldimethylamine-1 - (4-morpholinylphenyl)-butane- a benzoyl compound such as a ketone; a benzo compound such as benzo, benzoxyl ether, benzoethyl ether, benzoisopropyl ether or benzyl didecyl ketal; benzophenone, benzoquinone benzoic acid , benzoquinone benzoic acid sulfhydryl, 4-phenyldibenzofluorenone, hydroxydibenzophenone, propylene dibenzophenone, 4-benzoquinone-4 '-methyldiphenyl sulfide, 3,3 a benzophenone compound such as ',4,4'-tetra(t-butylperoxycarboxy)benzophenone; thioxanthone, 2-chlorothioxanthone, 2-methylthioxanthone, isopropyl Thiophenone compounds such as thioxanthone, 2,4-diisopropylthioxanthone, 2,4-diethylthioxanthone; 2,4,6-tris-o-triazine, 2-benzene 4-,6-bis(trichloroindenyl)-o-triazine, 2-(p-methoxyphenyl)-4,6-bis(triseodecyl)-o-triazine, 2-(p-quinone Phenyl)-4,6- (tri-gasmethyl)-o-triazine, 2-piperidin-4,6-bis(trichloroindenyl)-o-triazine, 2,4-bis(trishydrazinyl)-6-styrylyl- O-triazine, 2-(naphthalene 099132160 Form No. A0101 Page 34 / 154 pages 1003010545-0 201127911 and-1-yl)-4,6-bis(trichloroindenyl)-o-triazine, 2_(4_ A Oxynaphtho-1-yl)-4,6-bis(trichloromethyl)-o-triazine, 2'4-dichloromethyl-(piperidinyl)-6-tri. Triazine compounds such as Qin, 2,4-tris-methyl (4,-methoxystyryl)-6 • triazine; 1,2-dienedione, 1-[4-(phenylthio) -, 2 (0_benzopyrene-(b.) _N_(1_phenyl_2_bis-2-(4'-methoxy-naphthyl)ethylidene) hydroxylamine and other oxime ester compounds ; bis(2,4,6-trimethylbenzo)epoxyphenylphosphine, 2,4,. 6-trimethylbenzoepoxyphosphonium, etc.

A phosphine-based compound; a quinone-based compound such as 9,10-phenanthrenequinone, camphorquinone, or ethyl hydrazine; a borate ester-based compound; a salivary compound; and a salivary compound. If ^ ^ f These photopolymerization initiators can be used alone in a mixture of 2: kinds! The photopolymerization initiator is used in an amount of from 5 to 200 parts by weight of the coloring agent in the composition of the color calender sheet, from the viewpoint of photocurability and developability. It is preferably used in an amount of from 1 to 15 parts by weight. ;.. 4 <sensitizer> :. «I / In the coloring composition for color filters, y. may further contain a sensitizer. Examples of the sensitizer include unsaturated ketones represented by flavonoid derivatives or dibenzylidene fluorene, oximes represented by benzyl or camphorquinone, 2-dione derivatives, benzo derivatives, Anthracene derivatives, naphthoquinone derivatives, anthracene derivatives, xanthene derivatives, thioxanthene derivatives, xanthone derivatives, thioxanthone derivatives, coumarin derivatives, coumarinone Polymethine pigments such as derivatives, phthalocyanine derivatives, merocyanine derivatives, cyanine derivatives, acridine derivatives, azabenzene derivatives, diene terpene derivatives, oxazine 099132160 derivatives, hydrazine Porphyrin derivative '萁 derivative, 镔 镔 salt derivative, square form number A0101 Page 35 / 154 pages 1003010545-0 201127911 Acid ylide derivative, 卟 Lin derivative, tetraphenyl quinone derivative, Sanfangjia A burned derivative, a tetrabenzopyrene derivative, a tetrapyrazine derivative, an esterine derivative, a tetrazolium derivative, a tetralin derivative, a naphthalocyanine derivative, a secondary Phthalocyanine derivatives, pyridine rust salt derivatives, thio-π-bite salt derivatives, Tetraphyrin derivatives, Dilute derivatives, spiro. Pyran derivatives, snail derivatives, snail derivatives, metal aromatic complexes, organic ruthenium complexes, Michler's derivatives, a-methoxy ethers, sulfhydryl phosphating Hydroxide, phenylphenylglyoxylic acid, benzyl-9,10-phenanthrene, camphorquinone, ethylhydrazine, 4,4'-diethylnonanol, 3,3',4 , 4'-tetrakis (tertiary butylperoxycarboxy)dibenzophenone, 4,4'-didecylamine benzophenone, and the like. More specifically, "Special Functional Materials" (1 986, CMC) and Chisen-san Sanlang, etc., edited by the "Pigment Handbook" (1 986, Kodansha), and Okawa Keisuke, etc. The sensitizer described in "Special Functional Materials" (1 986, CMC). The sensitizer is not limited to these. Further, the coloring composition may further contain a sensitizer which exhibits absorption of light from the ultraviolet to the near-infrared region. The sensitizer may be combined in two or more kinds at any ratio. When the sensitizer is used in an amount of 100 parts by mass in the photopolymerization initiator contained in the coloring composition, it is preferably in the range of 3 to 60 parts by mass, from the viewpoint of photocurability and developability. In view of it, it is better to be within the range of 5 to 50 mass parts. Alternatively, the sensitizer may be used in an amount of, for example, 0.1 to 60 parts by mass of the photopolymerization initiator in the coloring composition. <Amine compound> The coloring composition for a color filter may further contain an amine compound having a function of reducing dissolved oxygen. 099132160 Form No. A0101 Page 36 / 154 pages 1003010545-0 201127911 Examples of such amine-based compounds include triethanolamine, mercapto diethanolamine, triisopropanolamine, 4-dimethylamine benzoic acid sulfhydryl group, 4 - dimethylamine benzoic acid ethyl, 4-dimethylamine benzoic acid 2-ethylhexyl and N,N-dimercapto-p-toluidine. <leveling agent>

In the colored composition, in order to improve the dyeing property of the composition on the transparent substrate, it is preferable to further add a leveling agent. The leveling agent is preferably a dimethyl siloxane having a polyether structure or a polyester structure in the main chain. Specific examples of the dimethyloxane having a polyfluorene structure in the main chain include FZ-2122 manufactured by T0RAY D〇w Corning Co., Ltd. and BYK_ 3 33 manufactured by βYK Corporation. Specific examples of the Qiaojiaji sand-bird service in which the main chain has a polyester structure can be exemplified by BY K Co., Ltd., which can be used for {(-'31(^&amp;spot_37;0&gt; The dimethyl ketone oxime chain having a polyether structure in the main chain has a polyester structure of dimethyl oxime. The content of the leveling agent is usually set to 100% by mass based on the total mass of the coloring composition. It is preferably in the range of 〇.^〇3 to 〇5 wt%.: 2:) The leveling agent is a compound having a hydrophobic group & a pro- ing group in the molecule, which is a so-called surfactant, which is true: It has a low solubility in water and a low solubility in water; when it is added to a coloring composition, it is particularly useful for exhibiting a low ability to lower the surface tension, and further has a good squeezing property to a glass plate. It is preferable to use a substance which can sufficiently suppress the chargeability in the amount of addition of the coating film which is not caused by the start of the film. The leveling agent having such a suitable property should preferably use a dimethyl sulphur oxide having a polyepoxy burning unit. Burning. Polyepoxy material includes hemp polyethylene oxide unit and polycyclopropylene unit. It can have both polyethylene oxide unit and polypropylene oxide unit. 099132160 Form No. A0101 Page 37 / 154 Page 1003010545-0 201127911 ♦ The combination of epoxy burning unit and diterpene base oxygen burning is the following type Sentence *T . XK epoxy-fired unit is combined with a pendant type in a repeating unit of methyl oxime; the polyalkylene oxide unit is bonded to the terminal end of the dimethyl methoxy olefin; and the poly ring The linear block copolymer in which the oxyalkylene unit and the dimethyl methoxy oxane are repeatedly and repeatedly bonded. The dimethyl methoxy siloxane having a polyalkylene oxide unit may, for example, be Fz_ 2U0 commercially available from T0RAY·Doff Corning Co., Ltd. , FZ-2122, FZ-2130 'FZ-2166, FZ-2191, FZ-2203 and FZ-2207. The dimethyl decane having a polycyclodecane unit is not limited to these. Auxiliary, cationic, nonionic or amphoteric surfactants are added in an auxiliary manner. "The noodles can be used alone (for seed, or a mixture of two or more. LV·,, i: ^ f if " A side-active surfactant which is added to the leveling agent in an auxiliary manner, for example, a polyethylene oxide Ether sulfate, sodium dodecylbenzenesulfonate, stupid ethylene acrylate copolymer, sodium alkylnaphthalene sulfonate, sodium alkyl diphenyl ether disulfonate, ammonium lauryl sulfate, lauryl acid Ethanolamine, lauryl sulfate saddle, stearic acid ethyl slk, "ammonium stearate, lauryl sulfate......., Yan \1^ ^ — nano, styrene-acrylic acid copolymer Poly Ethylene Ethylene Ether Phosphate Ether. The cationic surfactant of the auxiliary leveling agent may, for example, be a hospital-based grade 4 salt and the like, and may be added to the homogenizer. Examples of the ionic surfactant include polyethylene oxide oleyl ether, polyethylene oxide lauryl ether, polyethylene oxide decyl ether, polycycloethylene oxide phosphate, and polyethylene oxide sorbitan. An alkyl quaternary ammonium carboxylate inner salt such as glyceryl stearic acid, polyethylene glycol monolauryl ester, alkyl dimethylamine acetic acid quaternary ammonium carboxylate inner salt, or an amphoteric surfactant such as alkyl imidazoline, and a fluorine-based or矽基099132160 Form No. A0101 Page 38 of 154 1〇〇201127911 Department interface active agent. <Curing Agent and Hardening Accelerator> In order to assist in the hardening of the thermosetting resin, a curing agent and a curing accelerator may be contained in the composition of the color and the color of the color.

Useful hardeners are, for example, phenol resins, amine compounds, acid anhydrides, activated brews, carboxylic acid compounds, and sulfonic acid compounds. The hardener is not particularly limited thereto. Any hardener may be used if it can react with the thermosetting resin. Among these, a compound having two or more benzene groups and an amine-based curing agent in the fluorene molecule is preferable. The hardening accelerator may, for example, be dicyandiamide, benzyldimethylamine, 4-(dimethylamine)-N, I dimethylbenzyl span, '4-methoxylatene 7 N, N-di Methylbenzylamine and 4-methyl "N,N-dimethylbenzyl 4 magnesium compound; material; triethylbenzyl ammonium sulfate and other four-stage chlorine compound; dimethylamine amine $4 · segment isocyanate Compound; mercapto, 2-methylimidazolyl, 2-ethylimidazolyl, 2-ethyl-4-methylimidazolyl, 2-phenylimidazolyl, 4-phenylimidazolyl, cyanopropyl A 2-cyclic adenylation derivative of the imidazolyl derivative such as 2-ethyl-4-methylimidonyl, and a salt thereof; Triphenylphosphine: a phosphorus compound such as V ' Λ·.. , S i ; a guanamine compound such as melamine, i-amine, guanamine or benzoguanamine; and 2,4-diamine-6-methylpropene oxime s-S-triazine, 2-vinyl-2,4-diamine-6-triazine, 2-vinyl-4,6-diamine _S-triazine·isocyanate acid addenda and 2, 4- An S-triazine derivative such as a diamine-6-methacryloyloxyethyl triazine-isocyanuric acid addition product. The effect accelerator may be used singly or in combination of two or more. The content of the initiator is based on the total amount of the thermosetting resin, and is preferably in the range of 0.01 to 15% by mass. <Other additive components> 099132160 Form No. A0101 Page 39 of 154 Page 1003010545-0 201127911 In the colored composition, a storage stabilizer may be contained in order to stabilize the viscosity of the composition over time. Further, in the colored composition, a decane coupling agent may be contained in order to improve the adhesion to the transparent substrate. Examples of the storage stabilizer include 4-grade ammonium chlorides such as T-based trimethyl chloride and dimercaptohydroxylamine; organic acids such as lactic acid and oxalic acid, and ethyl ether; tertiary butyl pyrocatechol; An organic phosphine such as a phosphine or a tetraphenylphosphine; and a phosphite. The storage stabilizer is used in an amount of, for example, 0.1 to 10 parts by weight of the coloring agent in a coloring composition of 100 parts by mass. Examples of the lifting agent include the following decane coupling agents: ethylene decane such as ethylene tris(b-decyloxy group) oxirane, ethylene ethoxy decane, and ethylene trimethoxy decane; g-methacryloxy propylene Trimethoxydecane, etc. (methyl) Alkanoic acid; b - (3,4-epoxycycloalkyl)ethyltrimethoxydecane, b-(3,4-epoxycycloalkyl)methyltrimethoxynonane, b-(3, 4-epoxycycloalkyl)ethyltriethoxydecane, b-(3,4-epoxycycloalkyl)methyltriethoxydecane, g-glycidoxypropyltrimethoxydecane , an epoxy decane such as g-glycidoxypropyltriethoxy oxalate; Nb (amine ethyl) g-aminopropyltrimethoxy fever, Nb (amine ethyl) g-aminopropyl Triethoxy decane, Nb (amine ethyl) g - amine propyl methyl diethoxy pulverization, g_aminopropyl triethoxy sulphur, g-aminopropyl trimethoxy decane, N - Alkaloids such as phenyl-g-aminopropyltrimethoxy decane, N-phenyl-g-aminopropyltriethoxylate; and g_whenylpropyltrimethoxydecane, g- A thiononane such as mercaptopropyltrimethylethyl decane. The amount of the coloring agent is preferably used in an amount of from 0.01 to 10 parts by mass, and is preferably used in an amount of from 0.05 to 5 parts by mass. <Removal of coarse particles> 099132160 Form No. A0101 Page 40 of 154 1003010545-0 201127911 Using a mechanism such as a centrifugal separation, a sintered filter, or a membrane filter, coarse particles of 5 mm or more are preferably formed from the colored composition. The coarse particles above the imin are particularly preferably 0. 5 mm or more of the coarse particles and the removal of the fine dust. Thus, the coloring composition is preferably free of particles of 5 mni or more. Further, the coloring composition is preferably substantially free of particles of 3 mm or more. &lt;<Color Filter> Next, a color filter according to a second aspect of the present invention will be described. The color filter of the second aspect contains different absorption spectra, typically regular.

099132160 A plurality of filter segments arranged. A color filter of one form has at least one red filter segment, at least one green filter segment, and at least one blue pupil segment. Another aspect of the color filter or sheet includes at least one magenta filter segment, at least one cyan layer, and at least one HS1 yellow filter segment. In the color filter of the second aspect, at least one of the filter segments is formed of the coloring composition for color filter sheets. <Method for Producing Color Filter> The color filter can be manufactured by, for example, a printing method or a light shadow. The patterned filter segments can be formed by repeating the printing and drying of the colored composition prepared by Qin Huihui by the printing method. Therefore, the printing method is low in cost and good in mass production. Further, by the development of printing technology, it is possible to form a fine pattern having high dimensional accuracy and smoothness by printing. When the ink is used in printing, it is preferably a composition in which the ink does not dry and solidify on the printing plate or on the felt cloth. Moreover, the control of ink flow on the press is also important. The ink fluidity can be controlled by adjusting the ink viscosity by using a dispersant or an extender pigment. Form No. A0101 Page 41 of 154 '1003010545-0 201127911 By the method of light microscopic method, it is possible to manufacture a shirt color with higher precision than the printing method. When the filter segment is formed by the photolithography method, the solvent development type or the alkali development type color resistance is applied to the transparent substrate by a coating method such as spray coating or spin coating, slit coating, or roll coating. The colored composition prepared by the etchant material is applied so that the dry film thickness is in the range of, for example, 〇2 to 5]11111. The coating film is dried as needed, and the coating film is exposed to ultraviolet rays through a mask ??? of a specific pattern which is provided in contact or non-contact with the coating film. Thereafter, the coating film is immersed in a solvent or a developer, or a solvent or a mating agent is sprayed on the coating film, and the unhardened portion is removed from the coated apricot. Thereby, a thin, medium pattern corresponding to the filter segment of a certain color is obtained. The film operation corresponding to the remaining filter segments is formed by repeating the same operation as described above except that the color filter segments for the other color filter segments are used. Thereafter, a color filter is obtained by firing the film patterns. Further, firing may be performed each time a film pattern is formed. At the time of development, as an axial solution, an aqueous solution such as carbon and sodium hydroxide is used. Organic tests such as dimercaptospermine and triethanolamine can also be used. Also, a ship or a surfactant may be added to the developing core. Furthermore, in order to improve the ultraviolet exposure sensitivity, a water-soluble or solvent-soluble resin such as a polyethylene glycol or a water-soluble acrylic resin may be applied to the colored anti-film formed by coating and drying the above-mentioned coloring resistance (4). Film drying is followed by UV exposure. A coating made of a water-soluble or soluble resin _ preventing oxygen from inhibiting the polymerization of the coloring film (tetra) film 0 099132160 The color filter can also be produced by a method other than printing or photolithography. For example, it can be produced by an electrodeposition method or a transfer method. The above coloring composition can be used on page 42 of 154 Form No. A0101 - - 1003010545-0 201127911 Used in any method. Further, in the manufacture of a color filter using an electrodeposition method, a substrate having a transparent conductive film on one main surface is prepared, and the transparent conductive film is used as an electrode to cause colloidal particles to be electrophoresed on the transparent conductive film. Thereby a filter segment is formed. Further, in the manufacture of a color filter using a transfer method, a filter segment is formed in advance on a previous main surface of a transfer substrate having a release surface on a main surface, and the filter region is formed. The segment is transferred from the transfer substrate to the substrate.

On the transparent substrate, a black matrix of a light-shielding pattern may be formed before the filter segments are formed. The black matrix is made of, for example, a metal film such as a chromium film, a multilayer film such as a chromium/chromium oxide film, an inorganic compound film such as titanium nitride, or a resin film in which a light-shielding material is dispersed in a resin. , : On the transparent substrate, a circuit is formed before the color filter is formed, for example, an active matrix circuit including a thin film transistor (TFT) is formed. Further, on the color filter, other layers such as a film and a transparent conductive film may be further formed as needed. The substrate on which the color filter is formed is not transparent. For example, a color filter can also be formed on the reflective substrate. 〇Second aspect Next, a second aspect of the present invention will be described. In the case of the blue color of the color filter, it is proposed to use a triphenyl decane dye and a xanthene dye in combination with the blue color of the color filter. Here, a triphenylmethane-based acid dye and a xanthene-based acid dye are mixed, and a metal complex is used in order to improve resistance. However, in the current situation, only the acid dye is simply mixed, and the color rendering property is still insufficient, and high luminance cannot be obtained. In addition, the technology must use the heavy metal mismatch that is not suitable for use in the environmental burden. Form 099132160 Form No. A0101 Page 43 / 154 Page 1003010545-0 201127911 There is still room for improvement. The inventors of the present invention have intensively accumulated research, and as a result, it has been found that as a coloring agent for a coloring composition for a color filter, high-brightness and broadness can be realized by using an i-forming product derived from a triarylmethane-based dye and a xanthene-based dye. The color reproduction area has been found to achieve good tolerance, and according to this discretion, the invention of this aspect is achieved. That is, the second aspect of the present invention relates to a blue coloring composition for a color filter comprising a transparent resin and a coloring agent; and the coloring agent comprises a triaryl decane-based dye and a xanthene-based dye. A halogenated product composed of. Further, the xanthene dye is known as, for example, magenta dye as described in JP-A-2005-292305. The pigment system used for the magenta filter section can be selected to be extremely narrow, but the xanthene pigment has good spectral characteristics. Specifically, the xanthene-based pigment system has a higher transmittance on the short-wavelength side (400 to 50 nm) than the magenta quinacridone-based pigment. Therefore, xanthene pigments are used in many magenta filter segments. The blue coloring composition for the color filter of the second aspect contains a halogenated product composed of a triarylmethane dye and a rosin dye as a colorant. Therefore, by forming the filter segments of the color filter from the blue coloring composition, in addition to achieving high luminance and a wide color reproduction region, good resistance can be achieved. Further, in the past, a transmittance spectrum of a blue coloring composition for a color filter such as a copper phthalocyanine blue pigment or a dioxin-based pigment is used, and the peak position thereof is in the vicinity of 450 nm, and is worn on the short wavelength side of 450 nm or less. The penetration rate has dropped sharply. In contrast, the color filter of the present aspect is colored with a blue coloring composition as 099132160. Form No. A0101 Page 44 / 154 pages 1003010545-0 201127911 For at least a part of the coloring agent, using a triarylmethane dye and a xanthene It is a halogenated product of a pigment. Therefore, the high-intensity can be achieved from the filter section obtained by the coloring composition of the color filter of the present aspect. &lt;&lt;Coloring composition for color filters&gt;

As described above, the coloring composition for a color filter according to the second aspect of the present invention contains a blue coloring composition for a color filter of a transparent resin and a coloring agent. The colorant is a halogenated product of a triarylmethane dye and a xanthene dye. The xanthene dye is, for example, a mixture of a basic dye, a relative compound or the like of the first aspect. Further, the triarylmethane dye is also, for example, a basic dye of the first aspect, a relative compound or a mixture thereof. Further, in the second aspect, the relative compound has the first aspect, and the relative compound has a molecular weight within the range of the above description, but may have a molecular weight outside the range. &gt; One · ~ <Colorant> The coloring agent used in the second aspect includes a triarylmethane dye and a xanthene dye.

By halogenation of a triarylmethane dye and a xanthene dye, as described above, a high transmittance can be achieved by reducing the vicinity thereof in the wavelength range of 420 to 440 nm. Therefore, high brightness and wide color reproducibility can be achieved as compared with the conventional filter segments in which a copper phthalocyanine blue pigment and a dioxin-based pigment are combined. In other words, it can also achieve heat, light and solvent. [Triarylsulfanyl dye] First, a triarylmethane dye is described. The triarylmethane dye which can be suitably used herein has a blue, violet or green color and has an acid dye and/or a basic dye. The dyes exhibiting blue, purple or green are, for example, CI Basic Blue 099132160 Form No. A0101 Page 45/154 pages 1003010545-0 201127911, (:.I. Basic violet and CI basic green and other basic dyes; C. : [. Acidic blue, CI acid violet and CI acid green acid dyes; and direct dyes such as CI Direct Blue, CI Direct Violet and CI Direct Green. Here, the direct dye is a dye having a sulfonic acid group in the structure. In this aspect, the direct dye is regarded as an acid dye. The triarylmethane-based basic dye is oxidized by the N Η 2 or 0 fluorenyl group in the para position of the central carbon, thereby obtaining a quinone structure and a coloring matter. The quinone-based dye is mainly a basic dye, and is converted into an acid dye by introducing a sulfonic acid group. The triarylmethane-based basic dye is classified into the following three types depending on the number of fluorenyl groups. From the viewpoint, triamine triaryl decane-based dyes are particularly suitable. a) diamine triarylmethane dye b) triamine triaryl decane dye c) rose acid dye triamine triaryl decane having 0H group Dye system Good tune, sunlight is more appropriate than the terms of the robustness of the good aspects of otherness. Among them, a diphenylnaphthyl dye which is a basic dye is preferable. • The triarylmethane dye is in the wavelength range of 400 to 430 nm and has a high transmittance. However, triarylmethane dyes are the same as general dyes and are extremely resistant to light and heat. That is, when the triarylmethane dye is used in a color filter which requires a high reliability color display device or a color image pickup device, its characteristics are still insufficient. Here, in order to improve this disadvantage, a triarylmethane dye is used as a salt with a xanthene dye. The triarylmethane-based basic dye may, for example, be CI basic blue 1 (basic cyanine 6G), CI basic blue 5 (basic cyanine BX), CI basic blue 7 (Vidoli 099132160, Form No. A0101, page 46, 154, pp. 1003010545 -0 201127911 Pure blue), CI basic blue 26 'C. I. Basic purple 1 (methyl violet) and CI basic violet 3 (crystal violet). Among them, from the viewpoint of good color rendering, it is preferable to use C.I. Basic Blue 7. The diaryl-based acid dye is suitably used, for example, C. j. Acid Blue 1 (Food Blue No. 101), CI Acid Blue 3 (Acid Pure Blue), cj Acid Blue Bahu Blue II), CI Acid Blue 9 ( Eat blue nickname), c. 丨. Acid blue. , CI Acid Blue 83, CI Acid Blue 9〇, c. I. Acid Blue 93, c. I. Acid Blue 1〇〇, c. I. Acid Blue 103, c. 丨 Acid Blue 1〇4 or CI Acid Blue 1〇9.

099132160 Among them, it is preferable to use C·I. Acid blue 1, c. I. Acid blue 3 or c· j acid blue 93 ° [咕 系 dye] Next ‘ Describes about the xanthene dye. The xanthene dyes which can be suitably used in this aspect are red or purple in the form of an acid dye and/or an artificial dye. The dyes exhibiting red or purple are - such as g:: d, basic red and c.]. Basic purple and other dyes; c' I. zinc and C i ". acid dyes such as acid purple; or C · I. Direct Red and C. Dyestuffs Here, the direct dye is a dye having a repeating acid group in the structure. In this aspect, the direct dye is considered to be an acid dye. The xanthene dye is in the wavelength range of 400 to 430 nm and has a spectral characteristic between transmittances. However, the xanthene dyes are the same as general dyes and are extremely resistant to light and heat. That is, when the xanthene dye is used in a color filter which requires N reliability or a color filter of a color image pickup device, its characteristics are still insufficient. Here, in order to improve this disadvantage, a xanthene-based dye is used as a salt with a triaryldecane-based dye. 1003010545-0 Form No. A0101 Page 47 of 154 201127911 The dye of the xanthene system should have a transmittance of more than 9〇% for wavelengths above 650ηπι and a transmittance of 75 for wavelengths of 6〇〇nm2. The transmittance of % or more is 5% or less in the range of wavelength 500 to 550 nm, and the transmittance of light having a wavelength of 4 〇〇 nm is 70% or more. More preferably, the transmittance of light at a wavelength of 65 〇 nmw is above 95%, and the transmittance of light having a wavelength of 6 〇〇 nm is above 80%. 'The transmittance is at a wavelength of 5 〇〇 to 55 〇 1 ^ The range is 丨(10) or less, and the transmittance for light having a wavelength of 400 nm is 75% or more. The smear of acid dyes can be, for example, mouth. Acid red 51 (erythro red: edible red No. 3), CI acid red 52 (acid rose red), c. [acid red 87 (blush G: edible red 104) No.), c. 〖. Acid red offense (acidic bamboo f! Pink PB: food shouting color 104), tiger red B (food: red No. 5) 'Acid rose red G, acid red 289 or C. 1 / Acidic purple g Among them, c. L acid blush 51, c. Acid red 87 or CI acid red 289 is particularly suitable.咕 tons of basic dyes can be given, for example, c.〗. Basic red 1 (Rose red 6Gcp), c. I. Basic red 8 (Rose red G) and c: h Basic purple 1 〇 (Rose red. Use c·I. Basic red 丨 or c: ΓBasic tightly 10. Among the 咕 ton dyes, rosy red ageing materials are particularly suitable because of their good coloring and good resistance. [Diaryl decane dyes and A halogenated product composed of a xanthene dye] The toothed product composed of the triarylmethane dye and the xanthene dye is preferably one of the following two forms: (A) a diarylmethane-based basic dye Halogenated product composed of a halogenated product composed of a xanthene-based acid dye (B) a triarylmethane-based acid dye and a xanthene-based basic dye 099132160 Form No. A0101 Page 48 of 154 Page 1003010545-0 201127911 The combination of the acid dye and the basic dye can be obtained. In the case of the form (A), specifically, the combination of the reaction stability and the color rendering property is particularly good as follows: a combination of CI basic blue 7 and CI acid red 289, Combination of CI Basic Blue 7 and CI Acid Red 52, CI Basic Blue 7 and CI Acidity a combination of 87, a combination of CI basic blue 7 and CI acid red 92, a combination of CI basic violet 3 and CI acid red 87, and a combination of CI basic violet 3 and CI acid red 52. Of course, halogenation obtained from other combinations can also be used. In the case of the form (B), specifically, the combination of the reaction stability and the color rendering property is particularly good as follows: a combination of CI basic 釭1 and CI acid blue 1, and a combination of CI basic red 1 and CI acid blue 93 Λ CI combination of basic purple 10 and CI acid blue 1 and combination of CI basic violet 1 and CI acid blue 3. It is of course also possible to use other functionalized products obtained, for example, from the combination of the aforementioned dyes, wherein triarylmethane is acidic. The halogenated product composed of the dye and the rose red basic dye is particularly suitable, and is particularly suitable. The triarylmethane dye and the xanthene dye can be synthesized by a conventional method. For example, when a triarylmethane-based acid dye and a xanthene-based basic dye are used, after dissolving a triarylsulfane-based acid dye in water, a xanthene-based basic dye or an aqueous solution thereof is added thereto and stirred. Therefore, a drawing reaction can be performed. Thereby, a halogenated product in which a sulfonic acid group of a triarylf-based acid dye (for example, -S〇3H4-S〇3Na) is combined with an amine group of a xanthene-based basic dye can be obtained. Further, when a xanthene-based acid dye and a triarylsulfane-based basic dye are used, after the xanthene-based acid dye is dissolved in water, a triarylmethane-based 099132160 is added thereto. Form No. A0101 Page 49/154 pages 1003010545- 0 201127911 Alkaline dye or its aqueous solution is stirred and stirred to cause a toothing reaction. Thereby, a halogenated product in which a sulfonic acid group of a xanthene-based acid dye (e.g., -so/ or -S〇3Na) is combined with an amine group of a triarylmethane-based basic dye can be obtained. [Resin having acid group] As described in the first aspect, the above-mentioned i-formed product can be made into a relatively stable color material by modifying it with a resin having an acid group. When the halogenated product is added with a resin having an acid group, for example, a resin having an acid group such as a carboxyl group, or a rosin ester, a rosin-modified maleic acid resin, and a rosin-modified anti-succinic acid resin, The compatibility and dispersibility in the binder resin and the dispersibility to the solvent are greatly enhanced. As a result, more excellent color rendering, heat resistance and light resistance can be achieved. Here, the acid group is preferably a carboxyl group (-C00H) or a sulfonic acid group (e.g., -SOqli.-SC^Na). 〇 0 It is especially preferable to use rosin to modify maleic acid resin. The rosin-modified cis-enedenediic acid resin has a polar group having an acid and a non-polar rosin skeleton. The acidic polar group is derived from the carboxyl group of the unreacted rosin acid and the carboxyl group of the maleic acid, and reacts and is compatible with the polar group of the binder resin. In addition, the non-polar rosin skeleton is compatible with the non-polar portion of the binder resin. Further, the acid-based polar group of the rosin-modified maleic acid resin reacts with the amine group of the test dye (unreacted dye in the deuterated product). Further, the weight average molecular weight of the resin having an acid group is typically within the range described in the first aspect. Here, however, the weight average molecular weight of the resin having an acid group may be outside the range described in the first aspect. The mixing of the halogenated product and the resin having an acid group is carried out, for example, by the following method. Here, as an example, the resin having an acid group is modified by rosin. 099132160 Form No. 1010101 Page 50 of 154 Page 1003010545-0 201127911 Butadiene resin. (1) a method of dissolving a rosin-modified maleic acid resin in a solvent, adding a halogenated product to the solution, and (2) using a mixing scrambler to mix the dissolved rosin-modified cis-butylene _-resin and halogenated The method of producing the product is further carried out by mixing the toothed product with the resin having an acid group.

The mass ratio of the deuterated product to the resin having an acid group (deuterated product: resin having an acid group in the ear) is preferably in the range of 70:30 to 95:5. The larger the ratio of the resin having an acid group to the colored composition, the lower the color rendering property. In the case of the ear body, the color of the resin from the acid group 1: color shifting von coloring composition has a great influence. Further, the acid-based chelating resin has a smaller ratio of the color composition, and the effect of the halogenated product on the lack of dispersibility in the 4-bonded resin is smaller. The mass ratio of the halogenated product to the resin having an acid group (halogenated product: resin having an acid group) is preferably in the range of from 75:25 to 90:1 Torr. :,:! ?&gt; ' . . The resin having an acid group, such as rosin ester or 'scented maleic acid resin, preferably has an acid value of from 20 to 200 mgKOH/g·. The coloring composition is used as a development type. When the coloring agent material is used, the carboxyl group of the resin functions as a colorant adsorbent and an alkali soluble group during development, and the aliphatic group and the aromatic group function as a colorant carrier and an affinity group for the solvent. Therefore, the acid value of the resin acts on the dispersibility or solubility, developability, and longevity of Yankee and the functional product. Specifically, if the acid is small, the compatibility between the resin and the dentured product is insufficient. Further, when the acid value is small, when the coloring composition is used as, for example, an alkali-developing type coloring resist, the solubility of the uncured coloring composition to the developing solution is insufficient. 099132160 Form No. Α 0101 Page 51 / 154 pages 1003010545-0 201127911 Further, when the acid value is large, when the coloring composition is used as, for example, an alkali-developing type coloring resist, the exposed portions may be removed by development. . Here, the acid value is a value measured by the method specified in JIS K_0070. [Other Coloring Agents] In the coloring composition, other coloring agents may be further added to the extent that the effect is not hindered. Among them, in particular, when the A product and the organic pigment are used in combination, a better tolerance can be achieved. As the organic pigment, a phthalocyanine pigment, a dioxazine pigment, an anthraquinone pigment, an azo pigment or a quinophthalone pigment is preferably used. Among them, a phthalocyanine or a dioxazine pigment is particularly preferably used. The ugly blue pigment may, for example, be C. IBlufe 15, CI Pigment Blue 15 · 1 'C: Γ; Pigment Blue 15 : 2 ' CI Pigment Blue 15 · ' 3 ' CI Pigment Blue 15 : 4 and CI Pigment Blue 15 : 6. Among them, copper phthalocyanine blue with e-type, b-type or a-type is preferred. Such suitable pigments are, for example, C. I. Pigment Bl: ue 15:6, C.I. Pig-roent Bluel 5:3 &amp; C.I. HPigii Ten1; Bluel 5:1. Further, C. I. Pigment Violet 23 is preferably used as the dioxazine-based pigment. These pigments are preferably used in an amount of 50 parts by mass or less when the amount of the above-mentioned functional product is 100 parts by mass. In particular, when the above-mentioned image forming product, copper phthalocyanine-based pigment, and/or dioxazine-based pigment are used in combination, in addition to obtaining good weather resistance, it is possible to obtain brightness beyond the use of the pigment alone. (Refinement of Pigment) The above pigment can be refined by, for example, salt milling treatment. One of the pigments 099132160 Form No. A0101 Page 52 of 154 1003010545-0 201127911 The secondary particle size should be within the range indicated by the first aspect. The salt milling treatment can be carried out by the same method as the method of the first aspect, for example. Further, as the salt milling treatment, the same water-soluble organic inorganic salt, water-soluble organic solvent and resin as those described in the first aspect can be used. The amount of each material used should be within the range described in the first aspect. <Transparent Resin> A transparent resin is a coloring agent, particularly a substance which disperses and/or dissolves a halogenated product. As the transparent resin, the same as the description of the first aspect, for example, can be used. Further, the amount of the transparent resin to be used is preferably within the range described in the first aspect.

099132160 <Solvent> The solvent composition may be contained in the coloring composition in the same manner as the coloring composition of the first aspect, so that the coloring agent is sufficiently dispersed in the colorant carrier, and is easily applied to a substrate such as a glass substrate to be applied as a dried film. It becomes, for example, 0.2 to 5 mm, forming a filter segment. The solvent can be used in the same manner as the description of the first aspect, for example. Further, the amount of the solvent to be used is preferably within the range described in the first aspect. <Dispersion> The colored composition can be produced by the same method as the description of the first aspect, for example. (Dispersing aid) When the coloring agent is dispersed in the coloring agent carrier, a dispersing aid such as a dye derivative, a resin type pigment dispersing agent, or a surfactant can be suitably used in the same manner as in the first embodiment. As the dye derivative, the same as the description of the first aspect, for example, can be used. From the viewpoint of the improvement of the dispersibility, the amount of the pigment derivative is preferably 0.5 parts by mass or more, more preferably 1 part by mass or more, and the form number A0101, page 53 of 154 pages 1003010545- 0 201127911, the most suitable for more than 3 quality. In addition, the amount of the pigment derivative to be used is preferably 40 parts by mass or less, and most preferably 35 parts by mass or less, from the viewpoint of heat resistance and light resistance. As the resin type dispersant, the same as the description of the first aspect, for example, can be used. As a commercially available resin type pigment dispersant, for example, Disperbyk-101, 103, 1〇7, 1〇8, 11〇, 111, 116, 130, 140, 154, 161, 162, 163 manufactured by Βγκ-Chemie Co., Ltd. can be used. , 164, 165, 166, 170, 171, 174, 180, 181, 182, 183, 184, 185, 190, 2000, 2001, 2020, 2090, 2091, 2164 or 2163, Anti-Terra-U, 203 &amp; 204 , BYK-P104, P104S, 220S: and 6919, Lac'tiffldrv'-Lactimoni-WS and Bykumen, Japanese Lubrizolf word system, S0LSPERSE-3OOO, 9000, 13240, 13650, 13940, 17000, 18000, 20000, 21 000 , 2400 0, 26000, 27004, 2800 0, 31845, 32000, 32500, 32600, 34750, 36600, 38500, 41 000, 41090, 53095Ί5000 and 76500 ' EFKA-46, 47, 48乂 452, manufactured by Chiba Corporation LP40 08, 4009, LP4010, LP4050, LP4055' i〇0, 401, 402, 403, 450, 451, 453, 4540, 4550, 4560, 4800, 5010, 5065, 5066, 5070, 7500, 7554, 1101, 120 , 150, 1501, 1502, and 1503, AJISPER by Aj inomoto Fine-Techno -PA111, ΡΒΉ1, PB821, PB822 and PB824. As the surfactant, the same as the description of the first aspect can be used. When a resin-type dispersant and/or a surfactant is added, the total amount of the dispersant and the surfactant is preferably in the range of from 0.1 to 55, more preferably from 0.1 to the total mass of the coloring agent. Within 45 mass parts. Resin type dispersion 099132160 Form No. A0101 Page 54 of 154 1003010545-0 201127911 When the total amount of the agent and the surfactant is small, it is difficult to obtain the effect of adding it. Further, when the total amount of the mixture is large, excessive dispersion may affect the dispersion. Further, a photopolymerizable composition and/or a photopolymerization initiator may be added to the coloring composition to be used as a photosensitive coloring composition (resist) for a color filter. <Photopolymerizable composition>

The monomer or oligomer used in the photopolymerizable composition may, for example, be mercapto (meth) acrylate, ethyl (meth) acrylate or 2-hydroxyethyl (meth) acrylate. Monofunctional (meth) acrylates such as 2-hydroxypropyl (meth) acrylate, cyclohexyl (meth) acrylate, b-carboxy (meth) acrylate, and tricyclodecenylmethacrylate; polyethylene glycol (meth) acrylate, hexamethylene bis(indenyl) acrylate, triethylene glycol bis(indenyl) acrylate, tripropylene glycol di(meth) acrylate, etc. Acrylates; trimethylolpropane (mercapto) acrylate, neopentyl alcohol (mercapto) acrylate, neopentyl alcohol tetra (meth) acrylate, dipentaerythritol penta (methyl) a trifunctional or higher polyfunctional (meth) acrylate such as acrylate or dipentaerythritol hexa(meth)acrylate; 1,6-butanediol diglycidyl ether, bisphenol A diglycidyl group Epoxide compounds such as ether, neopentyl glycol glyceryl ether and phenolic resin Acrylic reactants, namely epoxy (meth) acrylate; various modified (meth) acrylates such as polyester, polyurethane, isocyanate and hydroxylated melamine; and (meth)acrylic acid, styrene Vinyl ether such as vinyl acetate, hydroxyethyl vinyl ether, ethylene glycol divinyl ether and neopentyl alcohol trivinyl ether; (meth) acrylamide; N-hydroxymethyl (meth) acrylamide; N -vinylamine; and propylene oxime 099132160 Form No. A0101 Page 55 of 154 Page 1003010545-0 201127911 Nitrile. These may be used alone or in combination of two or more. The monomer or oligomer is not necessarily limited to these. When the total mass of the coloring agent is 100 parts by mass, it is preferably in the range of 5 to 400 parts by mass, and it is preferable from the viewpoint of photocurability and developability. <Photopolymerization initiator> in the range of 10 to 300 parts by mass

When a filter segment is formed from a color filter using a blue colored composition by photolithography of ultraviolet light, a photopolymerization initiator or the like is added to the coloring composition. As the photopolymerization initiator, the same as the description of the first aspect, for example, can be used. When a photopolymerization initiator is used, the amount thereof is preferably the same as that described in the first aspect. <Sensitizer> The coloring composition for a color filter may further contain a sensitizer. As the sensitizer, the same as the description of the first aspect, for example, can be used. When a sensitizer is used, the amount of the sensitizer is preferably the same as that described in the first aspect.

<Amine compound> The coloring composition for a color filter may further contain an amine compound having a function of reducing dissolved oxygen. As the amine compound, for example, the same as the description of the first aspect can be used. <Leveling Agent> In the blue coloring composition, in order to improve the leveling property of the composition on the transparent substrate, it is preferred to further add a leveling agent. As the leveling agent, the same as the description of the first aspect, for example, can be used. When a leveling agent is used, the amount thereof is preferably the same as that described in the first aspect. The leveling agent may also be auxiliaryly added to the anionic, cationic, non-offset 099132160 Form No. A0101 Page 56 / 154 pages 1003010545-0 201127911 Sub- or bi-sex surfactant. The surfactant may be used singly or in combination of two or more. As the surfactant, the same as the description of the first aspect can be used.

099132160 <Hardener and hardening accelerator> In order to assist the hardening of the thermosetting resin, a curing agent and a curing accelerator may be contained in the colored composition as needed. As the curing agent and the hardening accelerator, the same as the description of the first aspect, for example, can be used. When a hardening accelerator is used, the amount thereof is preferably the same as that described in the first aspect. &lt;Other additive components&gt; In the blue coloring composition, a storage stabilizer may be contained in order to stabilize the viscosity of the composition over time. Further, in the blue dance color composition, in order to provide a close contact with the transparent substrate, the twisted W may contain an anthracycline coupling agent. The storage stabilizer can be used in the same manner as the description of the first embodiment. When using a stabilizing stabilizer and/or a sticking enhancer, the blending amount should be the same as that described in the first aspect. <Preparation method of coloring composition> The blue coloring composition can be produced by the following method when it is used in the form of a dissolution type or an alkali-developing type coloring resist material. . First, the colorant is mixed with a transparent resin and a colorant carrier optionally containing an organic solvent. Then, this is treated with various dispersing mechanisms such as a three-roll mill, a two-roll mill, a sand mill, a kneader, and an attritor to uniformly disperse the colorant in the colorant carrier. Further, in the thus obtained colorant blade, a photopolymerizable monomer and/or oligomer, a photopolymerization initiator, and other resins, solvents, dispersants, and additives which are used as needed are used. A blue coloring composition was obtained as above. &lt;Removal of coarse particles&gt; Table 鹄 A A0101 Page 57 of 154 1003010545-0 201127911 It is preferable to remove the coarse particles and mix the fine dust from the colored composition in the same manner as the mth sample. Also, the coloring composition is preferably substantially free of G. 5 or more particles and substantially does not contain particles of 0.3 mm or more. &lt;<Color Filter> Next, a color filter according to a second aspect of the present invention will be described. The color filter sheet of the twenty-first embodiment comprises a plurality of filter segments which are different in absorption spectrum and are typically regularly arranged. A modal color filter has at least one red filter segment, at least i green filter segments, and at least one blue filter segment. In the color filter of the second aspect, at least one of the blue filter segments is formed of the blue coloring composition of the color filter. } i · The red coloring composition can be formed using, for example, a package, a red coloring composition containing a red color + bucket, and a 'pigment carrier. Red pigments can be used, for example, CI Pigment Red 7, 14, 41, 48: 1, 48: 2, 48: 3, 48: 4, 81: 1, 81: 2, 81: 3, 81: 4, 122, 146, 168, 177 '178, 184, J85, 187, 200, 202, 208, 210, 242 '246, 254 "255, 264, 270, 272, 273, 2 74, 2 76, 277, 278, 279, 280, 281, 282, 283 '284, 285, 286 or 287. Instead of the red pigment or in addition to the red pigment, a halogenated product of a basic dye and an acid dye may be used. For example, the first aspect may be used. Halogenated product. In the red coloring composition, CI Pigment Orange 43, 71, 73 and other orange pigments, CI Pigment Yellow 1, 2, 3, 4, 5, 6, 10, 12, 13, 14 may also be used in combination. 15, 16, 17, 18, 24, 31, 32, 34, 35, 35: 1, 36, 36: 1, 37, 37: 1, 40, 42, 43 '53, 55, 60, 61, 62, 63, 65, 73, 099132160 Form No. A0101 Page 58 of 154 Page 1003010545-0 201127911 74, 77, 81, 83, 93, 95, 97, 98, 100, 101, 104, 106, 108, 109, 110 , 113, 114 '115, 116, 117, 118, 119 120,123,126,127,128,129,138,147,150,151,152,153,154,155,156,161,162,164,166,167,168,169,170,171,172, 173, 174, 175, 176, 177, 179, 180, 181, 182 '185, 187, 188, 193, 194, 198, 199, 213, 214

Yellow pigments such as 218, 219, 220 and 221 or mixtures thereof. A halogenated orange or yellow halogenated product of a basic dye and an acid dye can also be used. For example, the functionalized product described in the first aspect can also be used. The green filter section can be formed using, for example, a blister color and a pigment carrier Ά * a general green coloring composition. For example, CI Pigment Yellow I, 2, 3 can be used, for example, CI Pigment Green 7 ΊΟ '&quot;36 ' 37^, 58 green coloring composition and yellow pigment can be used together. '4,5,6,10,12,13 '14,15,:16ϋ7,Γ8 '24,31,32,34,35,35: 1, 36, 36: V, 37...37: 1, 40, 42, 43, 53, 55, 60, 61, 62, 6^?, _ 73, 74, 77, 81, 83, 93, 95, 97, 98, 100, 1〇1, 〇4, 106, 108, 109, -110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 126, 127, 128' 129, 138, 147, 150, 151, 152, 153, 154, 155, 156 , 161, 162, 164, 166, 167, 168, 169, 170, 171, 172, 173, 174, 175, 176, 177, 179, 180, 181, 182, 185, 187, 188 '193, 194, 198 , 199, 213, 214, 218, 219, 220 and 221 » instead of yellow pigment or in addition to yellow pigment, can also make 099132160 Form No. 1010101 Page 59 / 154 pages 1003010545-0 201127911 With dyes and acid dyes A yellow halogenated product is present. For example, the halogenated product described in the first aspect can also be used. <Method of Manufacturing Color Filter> The color filter can be produced by the same method as the method of the first aspect, for example. 〇 Third Aspect Next, a third aspect of the present invention will be described. The inventors of the present invention have intensively conducted research, and as a result, it has been found that a coloring agent for a coloring composition for a color filter can be realized by using a halogenated product derived from a sputum-based dye and a xanthene-based acid dye. Brightness and a wide range of color reproduction areas have been found to achieve good financial gains, and according to this discretion, the invention of this aspect is achieved. That is, the third aspect of the present invention relates to a coloring composition for a color filter, which comprises a transparent resin and a coloring agent; and the coloring agent comprises an acid dye of 咕° 镇 and an acidity of 咕β A halogenated product composed of a dye, a color filter of the third aspect, and a coloring composition as a coloring agent, including

.. V is a chemical composition consisting of a xanthene-based basic dye and a xanthene-based acid dye. Therefore, by forming the filter segments of the color filter from the colored composition, in addition to achieving high brightness and a wide color reproduction region, good resistance can be achieved. The coloring composition for the color filter is particularly suitably used in a blue or magenta filter section. Further, in the conventional blue filter section, for example, a combination of a copper phthalocyanine blue pigment and a dioxazine-based pigment is used. A color filter combined with a copper phthalocyanine blue pigment and a dioxin-based pigment&gt;1 a transmittance spectrum of a blue colored composition, the peak position of which exists near 450 nm, and a short wavelength below 450 nm 099132160 A0101 Page 60 of 154 pages 1003010545-0 201127911 Side, the penetration rate dropped sharply. On the other hand, the color filter composition of the present aspect is a halogenated product composed of a xanthene-based basic dye and a xanthene-based acid dye, and is preferably a phthalocyanine-based pigment. Use together. Therefore, when the composition for a color filter of the present aspect is used, high luminance is achieved on the short wavelength side below 450 nm and when combined with a copper phthalocyanine blue pigment and a dioxazine pigment. Then, the luminescence spectrum of many backlights such as a cold cathode tube is in the wavelength range of 425 to 440 nm or has a peak wavelength in the vicinity thereof. Therefore, high brightness can be achieved from the filter section obtained by the color filter of the present aspect with the ochre composition. Moreover, the color filter of the color filter used for the complementary color is extremely narrow in selection, and it is difficult to obtain a complementary color pigment having good first-order characteristics in the current situation. This point is one of the reasons why it is difficult to obtain good color reproducibility in an image pickup element using a complementary color filter. Especially with respect to the magenta filter section, it is difficult to obtain sufficient spectral characteristics. For example, the C.I. Pigment Red 122 of the quinacone-based magenta pigment has a low transmittance on the short-wavelength side (400 to 500 nm), so it is difficult to balance the color of the color filter.

r Q is optimized. A xanthene dye is known as, for example, a dye exhibiting magenta. The xanthene dye has good spectroscopic properties. Specifically, the xanthene-based colorant has a high transmittance in the wavelength range of 400 to 450 nm or in the vicinity thereof in comparison with the quinophthalone-based dye. Therefore, the xanthene-based coloring matter is used in many magenta filter segments as described in Japanese Patent Laid-Open Publication No. Hei. However, as described above, the dye is less tolerant than the pigment. The coloring composition of this aspect has a higher transmittance on the short wavelength side (400 to 500 nm) than the quinophthalone type pigment. Then, if the colored composition of this aspect 099132160 Form No. A0101 Page 61 / 154 page 1003010545-0 201127911 is used, a well-tolerant filter segment can be obtained. Therefore, if the coloring composition of the present aspect is used in the magenta filter section, a color filter such as a color balance and a good complementary color filter can be obtained. &lt;Coloring composition for color filter As described above, the coloring composition for a color filter according to the third aspect of the present invention contains a blue coloring composition for a color filter of a transparent resin and a coloring agent. The coloring agent contains a halogenated product composed of a xanthene-based basic dye and a xanthene-based acid dye. For example, the smear dyes and the acid dyes of the 咕° town are the basic dyes and relative compounds of the first aspect. Further, in the third aspect, the relative compound is typically in the first aspect, and the relative amount of the relative compound is in the range described above, but may have a molecular weight outside the range. <Colorant> The coloring agent used in the third aspect contains a halogenated product composed of a xanthene-based dye and a xanthene-based dye. The colorant is capable of achieving high transmittance in or near the wavelength range of 420 to 440 nm when used in combination with, for example, a copper phthalocyanine pigment. Therefore, high brightness and wide color reproducibility can be achieved as compared with the conventional blue filter section in which a combination of a copper phthalocyanine blue pigment and a dioxin-based pigment is combined. Further, since the transmittance in the wavelength range of 4000 to 450 mn is high, a color filter having a good color balance complementary color can be obtained. [Xenon-based acid dye and xanthene-based basic dye] Hereinafter, a xanthene-based acid dye and a xanthene-based basic dye will be described. 〇 嘲 系 )) The xanthene dyes that can be used here are red or purple, 099132160 Form No. A0101 Page 62 / 154 pages 1003010545-0 201127911 Forms with acid dyes and/or basic dyes . The dyes exhibiting red or purple belong to, for example, c. 〗 Basic red and c. 匕 basic purple and other basic dyes; c. I. Acid red and c. 丨. Acid violet and other acid dyes ' or CI direct red and c. I. Direct dyes such as direct purple. Here, the 'direct dye' is a material having a sulfonic acid group (_so J^_so Na) in the structure. In this aspect, the direct dye is considered an acid dye. Further, in the oil-cooling property, a substance having a sulfonic acid group and functioning substantially as an acid dye is also regarded as an acid dye in this aspect.

CU 099132160 The xanthene acid dye and the xanthene alkali dye are in the wavelength range from 4 〇 to 4 5 〇 n m and have a high transmittance. However, xanthene-based acid dyes and bismuth-based basic dyes are generally poorly resistant to light and heat. That is, the xenon system and the xanthene alkaline materials are used in color filters requiring high reliability. The characteristics of the plant are still insufficient. Here, in order to improve this disadvantage, a salt of a xanthene-based acid dye and a xanthene-based dye is used. The salt has a tooth-forming product of a color-based substance: a coloring property is good, and . '5 , * · , α·-^ Ί r !? ν TM · a mouth-and-mouth acid dye and xanthene The basic dye system is 'yield at a wavelength of 65〇11111. The transmittance of light is above 90%'. The transmittance for light with a wavelength of 60〇nm is above 75%. The transmittance is at a wavelength of 5〇〇55. 〇111 is less than 5% in the range of {{1'. The transmittance for light having a wavelength of 400ηπι is 7〇% or more. It is more preferable that the transmittance of light having a wavelength of 650 nm or more is 95% or more, the transmittance of light of a wavelength of 6 〇〇ηπι is 80% or more, and the transmittance is 10% in the range of 50 〇 to 550 nm. The following 'for wavelength 4〇〇1111' light penetration rate is above 75%. (咕 系 酸性 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸 酸Red 52 (acid rose red), c. i • Acid red 87 (blush G: edible red 1〇4), c. I. Acid red 92 (acid oleander red PB. Edible red 1〇4), tiger Red B (food red No. 5), acid rose red G, acid red 289 or C. I·acid purple g. Among them, it is particularly preferable to use C. I. Acid Red 52, C. I. Acid Red 87, C. I. Acid Red 92, C. I. Acid Red 289 or C. I. Acid Red 388. (Xenon-based basic dye) Examples of the xanthene-based basic dye include c. I. Basic red 1 (Rose red 6GCp), c' I. Basic red 8 (Rose red (eight) and .h basic purple 1〇 ( Rose red. It is especially suitable to use CI basic. Red 1 or c. I. Basic purple 1 〇. s. Among the basic dyes of ton, rose red, condensed dye due to color rendering and good tolerance' Therefore, it is particularly suitable. 〆> [a halogenated product obtained from a ton-tonic acid dye and a xanthene-based basic dye] The tooth-forming product of a xanthene-based acid dye and a xanthene-based basic dye has high heat resistance. And light resistance and solvent resistance. The halogenated product is preferably at least one of the following combinations: ,,,, specifically, a combination of CI basic red 1 and c·· i. acid red 52, c. J 乂 basic red 1 combination with CI acid red 87, CI basic red 1 and (: combination of acid red 92, CI basic red 丨 and 匕丨. acid red 289 combination, (: · I. basic red 1 and c. I. acid Combination of red 388, combination of c丨 basic purple 10 and CI acid red 52, c. I. basic purple 10 and c. · combination of acid red 87, c. I. basic purple 1〇 and c. I. acid red Combination of 92, CI basic violet 1〇 and c. I. Acid red 289 combination, c. I. Basic purple 1〇 and C. I·acid red 388 combination, CI basic red 8 and C. 丨 acid red 52 , CI Basic Red 8 and CI Acid Red 87, c. I. Basic Red 8 and 1003010545-0 099132160 Form No. A0101 Page 64 / 154 pages 201127911 CI Acid Red 92, CI Basic Red 8 and CI Acid Red 289 and CI The combination of basic red 8 and CI acid red 388 is particularly good in reaction stability and color rendering. Of course, halogenated products obtained from other combinations can also be used. - 咕 系 系 验 验 咕 镇The dentured product can be synthesized by a conventional method. For example, after dissolving a xanthene-based acid dye in water, a xanthene-based basic dye or an aqueous solution thereof is added thereto and stirred to thereby cause a halogenation reaction. Thus, a halogenated product of a sulfonic acid group of a xanthene-based acid dye (for example, -30 &lt;^ or '-SOqNa) in combination with an amine group of a mouth-finish dye can be obtained. Ο [Resin having acid group] ..., The above halogenated product can be modified by a resin having an acid group. It is a stable color material. The resin having an acid group is the same as the description of the second aspect. [Other coloring agents] In the coloring composition, it is possible to further prevent the effect from being affected. Other colorants are added, especially when the halogenated product is combined with the ti - - L w organic pigment to achieve better tolerance. As the organic pigment, a phthalocyanine pigment, a dioxazine pigment, an anthraquinone pigment, an azo pigment or a quinophthalone pigment is preferably used. Among them, a phthalocyanine-based pigment or a dioxazine-based pigment is particularly preferably used. The ugly blue pigment may, for example, be CI· Pigment Blue 15, CI Pigment Blue 15 : 1, C·I. Pigment Blue 15 : 2, CI Pigment Blue 15 : 3 ' CI Pigment Blue 15 : 4 and CI Pigment Blue 15 : 6. Among them, a copper phthalocyanine blue pigment having an e-type, a b-type or an a-type is preferable. Such suitable pigments are specific 099132160 Form No. A0101 Page 65 of 154 1003010545-0 201127911 For example, C. I. Pigment Blue 15:6, C. I. Pigment Blue 15 : 3 and C. I. Pigment Blue 15 : 1 . Also, two. It is preferred to use C. I. P i gme n t V i ο 1 e t.. 2 3 for the cockroach pigment. When the amount of the halogenated product is 100 parts by mass, the pigment is preferably used in the range of 2 to 100 parts by mass. In particular, when the above-mentioned tooth-forming product, copper phthalocyanine-based pigment, and/or dioxazine-based pigment are used in combination, in addition to obtaining good weather resistance, it is possible to obtain brightness beyond when the pigment is used alone. When the magenta filter segment is formed from the above colored composition, the above-mentioned i-formed product and other red or magenta pigments may be used in combination for the purpose of color adjustment. Other pigments which can be used in combination are, for example, C. I. Pigmentl 22 'C. I. Pigment 192 'C. I. Pigment 202 ' C. I. Pigment 207 and C. I. Pigment 209. It is preferable to use an anthrone pigment from the viewpoint of good heat resistance, light resistance, and solvent resistance. In view of the fact that the quality of the halogenated product is 100 parts by mass, it is preferable to use it in an amount of 40 parts by mass or less, from the viewpoint of obtaining a good color separation property. (Refinement of Pigment) The above pigment can be refined by, for example, salt milling treatment. The primary particle diameter of the pigment should preferably be within the range described in the first aspect. The salt milling treatment can be carried out by the same method as the method of the first aspect, for example. Further, as the salt milling treatment, the same water-soluble organic inorganic salt, water-soluble organic solvent and resin as those described in the first aspect can be used. The amount of each material used should be within the range described in the first aspect. <Transparent Resin> The transparent resin is a coloring agent, especially the halogenated product is dispersed and/or dissolved. 099132160 Form No. A0101 Page 66 of 154 Page 1003010545-0 201127911. As the transparent resin, the same as the description of the first aspect, for example, can be used. Further, the amount of the transparent resin used can be the same as that of the first aspect. <Dispersion> The colored composition can be produced by the same method as the description of the first aspect, for example. (Dispersing aid) When the coloring agent is dispersed in the coloring agent carrier, a dispersing aid such as a dye derivative, a resin type pigment dispersing agent, or a surfactant can be suitably used in the same manner as in the first embodiment.

As the dye derivative, the same as the description of the first aspect, for example, can be used. From the viewpoint of the improvement of the dispersibility, the blending amount of the pigment derivative is considered from the viewpoint of improving the dispersibility, and should be the same as the description of the second aspect. As the resin type dispersant, for example, the same as the first aspect of the invention can be used. As the commercially available resin type pigment dispersant, for example, those exemplified in the second aspect can be used. As the surfactant, the same as the description of the first aspect can be used. When a resin type dispersant and/or a surfactant is added, the total amount thereof is preferably within the range described in the second aspect. Further, a photopolymerizable composition and/or a photopolymerization initiator may be added to the coloring composition to be used as a photosensitive coloring composition (resist) for a color filter. <Photopolymerizable Composition> For the photopolymerizable composition, for example, a monomer or an oligomer exemplified in the second aspect can be used. The total amount of the monomers and oligomers is preferably within the range described in the second aspect. <Photopolymerization initiator> 099132160 Form No. A0101 Page 67 of 154 Page 1003010545-0 201127911 By using ultraviolet rays to illuminate the water, the first micro-shirt, from the color filter with blue In the segment, (4) the composition is added to the photopolymer. The initiator and the like are combined with H (4) and can be produced as described in the first aspect. When using a light dreamer such as a rabbit, when the starter is used, the instructions are the same. &amp; <Sensitizer> In the color passage film, "the sensitizer can be further used." The agent can be used in the same manner as the first aspect. For example, Sensation Lin is used. Na is the same as the description of the first aspect. <Amine compounds> ....... .:...::..................;: : The same thing is indicated in the color step m step containing the first aspect. <Leveling agent> In the coloring composition, the rabbit should further add a leveling agent in order to improve the dyeability of the complex on the transparent substrate. *.:, the leveling agent can be used in the same way as the description of the sample. For example, when the leveling agent is used, the formula is the same as the day and month. A surfactant, a cationic, a nonionic or a surfactant of a double 14. The surfactant may be used singly or in combination of two or more. The surfactants may be used in the same manner as the ith aspect, for example. <Reinforcing agent and hardening accelerator> In order to assist the hardening of the thermosetting resin, the coloring composition may contain a curing agent and hardening promotion as needed. The curing agent and the hardening accelerator may be the same as those described in the first aspect, for example, when using the hardening 1003010545 Form No. A0101 099132160, page 68 / 154 pages 201127911, the amount of the agent is preferably the same as the first aspect. <Other additive components> In the colored composition, a storage stabilizer may be contained in order to stabilize the viscosity of the composition over time. Further, in order to improve the adhesion to the transparent substrate, the colored composition is used. It may also contain a decane coupling agent. The storage stabilizer may be the same as that described in the first aspect, for example, when the storage stabilizer and/or the adhesion promoter are used, the amount of the preparation is preferably the same as that of the first aspect. In the same manner as in the first aspect, it is preferable to remove the coarse particles and mix the fine dust from the colored composition. That is, the colored composition should preferably contain no particles of 0.5 mm or more, more preferably substantially The particles of 0.3 mm or more are not included. <Color filter> Next, a color filter according to a third aspect of the present invention will be described. The color filter of the second aspect includes different absorption spectra. a plurality of filter segments regularly arranged in a pattern. The color plate of one form has at least one red filter segment, at least one green filter segment, and at least one blue filter In the color filter of the second aspect, at least one blue filter segment is formed by the color filter 甩 coloring composition. The red coloring composition may use, for example, a red pigment and a pigment. A general red coloring composition of the carrier is formed. For example, CI Pigment Red 7'CI Pigment Red 14' CI Pigment Red 48 ' CI Pigment Red 48 · 1 ' CI Pigment Red 48 : 2, CI Pigment Red 48: 3, CI Pigment Red 48 : 4, (λ I. Pigment Red 099132160 Form No. A0101 Page 69 / 154 pages 1003010545-0 201127911 81 · 1 ' CI Pigment Red 81 : 2, CI Pigment Red 81 · 3 ' CI Pigment Red 81 · 4 ' CI Pigment Red 122 ' CI Pigment Red 146 ' CI Pigment Red 168 ' CI Pigment Red 177 ' CI

Pigment Red 178, C. I. Pigment Red 184, C. I.

Pigment Red 185, C. I. Pigment Red 187, C. I.

Pigment Red 200, C. I. Pigment Red 202, C. I.

Pigment Red 208 ' C. I. Pigment Red 210 ' C. I.

Pigment Red 242 ' C. I. Pigment Red 246 ' C. I.

Pigment Red 254, C. I. Pigment Red 255, C. I.

Pigment Red 264 ' C. I. Pigmfeiit R^d-^TO ' C. I.

Pigment Red 272 ' C. I. Pigment =Red r273 ' C. I.

Pigment Red 274 ' C. I. Pigment Red 276 ' C. I.

Pigment Red 277 ' C. I. Pigment Red 278 ' C. I.

Pigment Red 27.}, G.I.Pigment: Red280, G.I·ffl _ , I: -

Pigment Red 281 'C. I. Pigment Red 282 'C. I.

Pigment Red 283 ' C. I. Pigment Red 284 ' C. I.

Pigment Red 285, C. I.'^Pi poor raeifft Red 286 and C. I. Pigment Red 287 and other red pigments. It is also possible to use a reddish functional product of an anionic dye and an acid dye. For the red coloring composition, it is also possible to use CI Pigment Orange 43, 71, 73 and other orange pigments, CI Pigment Yellow 1, CI Pigment Yellow 2, CI Pigment Yellow 3 'CI Pigment Yellow 4 ' CI Pigment Yellow 5'CI Pigment Yellow 6'CI Pigment Yellow 10 'CI Pigment Yellow 12 'CI Pigment 099132160 Form No. A0101 Page 70 of 154 Page 1003010545-0 201127911

Yellow 13 ' CI Pigment Yellow 14 ' CI Pigment Yellow 15 ' CI Pigment Yellow 16, CI Pigment Yellow 17, CI Pigment Yellow 18, CI Pigment Yellow 24 'CI Pigment Yellow 31, C.+I. Pigment Yellow 32, C. 1 .. Pigment Yellow 34 ' CI Pigment Yellow 35 'CI Pigment Yellow 35 · 1 ' CI Pigment Yellow 36 '

CI Pigment Yellow 36 · 1 ' CI Pigment Yellow 37 ' CI Pigment Yellow 37 · 1 ' CI Pigment Yellow 40 ' GI Pigment Yellow 42 ' CI Pigment Yellow 43 ' 0.3⁄4^Pigment lei low 53 ' CI Pigment Yellow 55f&gt;CXJ; ^Pigment Yellow 60 'CI Pigment Ye 1 low 61 ' CI Pigment Yellow 62 ' C. I, Pigment Yellow 63 ' CI Pigment Yellow 65 ' CI Pigment Yellow 73 ' CI Pigment Ye 11 ow 74 CI Pigment Yellow 77' C. i. Pigment Yellow 81 'CI Pigment Yellow 83 'CI Pigment Yellow 93 'CI Pigment Yellow 95 ' CI Pigment Yellow 98 ' CI Pigment Yellow 98 ' CI Pigment Yellow 100 ' CI Pigment Yellow 101, CI Pigment Yellow 104'CI Pigment Yellow 106 'CI Pigment Yellow 108, CI Pigment Yellow 109, CI Pigment Yellow 110, CI Pigment Yellow 113 'CI Pigment Yellow 114 'CI Pigment Yellow 115 'CI Pigment Yellow 116 'CI Pig- 099132160 Form No. A0101 Page 71 of 154 Page 1003010545- 0 201127911 ment Yellow 117, CI Pigment Yellow 118, CI Pig Ment Yellow 119, CI Pigment Yellow 120 'CI Pigment Yellow 123 ' CI Pigment Yellow 126, CI Pigment Yellow 127, CI Pigment Yellow 128 'CI Pigment Yellow 129 'CI Pigment Yellow 138 'CI Pigment Yellow 147 ' CI Pigment Yellow 150 ' CI Pigment Yellow 151 ' CI Pigment Yellow 152,

CI Pigment Yellow 153, CI Pigment Yellow 154 'CI Pigment Yellow 155 ' CI Pigment Yellow 156, CI Pigment Yellow 1.61, CI Pigment Yellow 162 'CI Pigment Yellow 164 ' CI Pigment Yellow 166 ' CI Pigment Yellow 167'CI Pigment Yellow 168' CI Pigment Yellow 169'CI Pigment Yellow 170'

C. I. Pigment Yellow 171 &gt;C. I. Pigment Yellow 172 'C.I. Pigment YeMow 173 ' G. I. Pigment :!K 3. Vi... - ^ _

Yellow 174 ' CI Pigment Yellow 175 ' CI Pigment Yellow 176'CI Pigment Yellow 177 'CI Pigment Yellow 179 'CI Pigment Yellow 180 ' CI Pigment Yellow 181 'CI Pigment Yellow 182 'CI Pigment Yellow 185' CI Pigment Yellow 187 'CI Pigment Yellow 188 'CI Pigment Yellow 193 'CI Pigment Yellow 194, CI Pigment Yellow 198, C. I. Pigment Yellow 199 'CI Pigment Yellow 213 099132160 Form No. A0101 Page 72 of 154 Page 1003010545-0 201127911 ' CI Pigment Yellow 214 ' CI Pigment Yellow 218 ' CI Pigment Yellow 219 ' CI Pig-ment Yellow 220 and CI Pigment Yellow 221 etc.

A combination of two or more kinds of color pigments or the like. Further, it is also possible to use a basic dye which exhibits an orange color and/or a yellow color and an acid dye. The green filter segment can be formed using, for example, a green coloring composition comprising a green pigment and a pigment carrier. For the green pigment, for example, C. I. Pigment Green 7 ' C. I. Pigment Green 10 ' C. I. Pigment Green 36, C. I ' Pigment Green 37 or G. I. Pigment Green .: 58 can be used. The green coloring composition may further comprise a yellow pigment. The yellow pigment which can be used in combination is, for example, C. I. Pignrefit, Ye'n〇w il'C. I. Γ

Pigment Yellow 2,.'CI Pigment Yellow 3' CI Pigment Yellow 4 ' CI Pigment Yellow 5 ' CI Pigment Yellow 6 ' CI Pigment Yellow 10 ' CI Pigment Yellow i2 rC. Ii: Pigment Yellow 13. CI Pigmeiit fellow 14 ' CI Pig-ment Yellow 15 'C, I. Pigmen^t Yellow 16 'CI Pigment Yellow 17, CI Pigment Yellow 18, CI Pigment Yellow 24, C. I· Pigment Yellow 31, CI Pigment Yellow 32, CI Pigment Yellow 34 ' CI Pigment Yellow 35 ' CI Pigment Yellow 35 : 1 ' CI Pigment Yellow 36 ' CI Pigment Yellow 36 : 1 ' CI Pigment Yellow 37., CI Pigment Yel low 37 : 1, CI Pigment Yellow 40 ' CI Pigment Yellow 42 'CI 099132160 Form No. A0101 Page 73 / 154 pages 10030105.45-0 201127911

Pigment Yellow 43 ' CI Pigment Yellow 53 ' CI Pigment Yellow 55, CI Pigment Yellow 60, C. I· Pigment Yellow 61, CI Pigment Yellow 62 'CI Pigment Yellow 63 'CI Pigment Yellow 65, CI Pigment Yellow 73, CI Pigment Yellow 74 'CI Pigment Yellow 77' CI Pigment Yellow 81 'CI Pigment Yellow 83, CI Pigment Yellow 93, CI Pigment Yellow 95 'CI Pigment Yellow 97 'CI Pigment Yellow 98 ' CI Pigment Yellow 100 ' GI Pigment Yellow 1-01 ' CI r.Pigment Yellow 104 ' CI Pigment Ye 1 law 10&amp;^&gt;^CI ! Pigment Yellow 108 'CI Pigment Ye 1 low 109 ' CI Pigment Yellow 110 'CI Pigment Ye 1 low 113 ' CI Pigment Yellow 114 'CI Pigment Yellow 115 'CI Pigment Yel Low 116 'CI Pigment Yellow 117 ' CI P i gment Yellow 118' CI Pigment Yellow 119'C:I. Pigment Yellow 120 'CI Pigment Yellow 123 ' CI Pigment Yellow 126 'CI Pigment Yellow 127 ' CI Pigment Yellow 128 'CI Pigment Yellow 129 'CI Pigment Yellow 138 'C .I. Pigment Yellow 147 ' CI Pigment Yellow 150 ' CI Pigment Yellow 151 ' CI Pigment Yellow 152 ' CI Pigment Yellow 153, CI· Pigment Yellow 154, CI Pigment Yellow 155, CI Pigment 099132160 Form No. A0101 Page 74 of 154 Page 1003010545-0 201127911

Yellow 156, C. I. Pigment Yellow 161, C. I.

Pigment Yellow 162 'CI Pigment Yellow 164 'CI Pigment Yellow 166 'CI Pigment Yellow 167 ' CI Pigment Yellow 168 ' CI Pigment Yellow 169 'CI Pigment Yellow 170' CI· Pigment Yellow 171, CI Pigment Yellow 172, CI Pigment Yellow 173, CI Pigment Yellow 174, CI Pigment Yellow 175, CI

099132160

Pigment Yellow 176, C. I· Pigment Yellow 177 'CI Pigment Yellow 179 'CI Pigment Yellow 180 ' Cf I. Pigment Yellow I. Pigment ment Yel low 182 ' CI Pigmenl/Kifel low 185 ' , ^ ^ ν~ΐ&gt; CI Pigment Yellow 187'CI Prgment Yellow 188 ' CI Pigment Yellow 193 'CI Pigment Yellow 194 'CI Pigment Yellow 198'CI

Pigment Yellow 199 'C.I. Pigment Yellow 213, C.I. Pigment Yellow 214, G.·I. Pigmeni: Ye 1-low 218'C. I. Pigment Yellow 219 'C. I. Pig-ment Yellow 220 and C.I. Pigment Yellow 221 . Further, a halogenated product of each of the yellow-colored basic dye and the acid dye may be used in combination. The cyan filter section may be formed using, for example, a cyan coloring composition containing a blue pigment or a cyan pigment and a pigment carrier. Cyan pigments can be used, for example, CI Pigment Blue 15, CI Pigment Blue 15 : 1 ' CI Pigment Blue 15 : 2 ' CI Pigment Blue 15 : 3 ' CI Pigment Blue 15 : 4 ' CI Form No. A0101 Page 75 / 154 pages 1003010545 -0 201127911

Pigment Blue 15 : 5, C. I· Pigment Blue 15 : 6, C.I. Pigment Blue 16 'C.I. Pigment Blue 22 &gt; C.I. Pigment Blue 60 or C.I. Pigment Blue 64 . Among them, CI Pigment Blue 15 and CI Pigment Blue 15 : CI Pigment Blue 15 · 2 ' CI PigiDGnt Blue 15 · 3 ' CI Pigment Blue 15 : 4, C· I. Pigment Blue 15 : 5 and CI

Pigment Blue 15:6 is appropriate. Further, it is also possible to use a halogenated product of each of the blue-based test dye and the acid dye. The yellow filter segment can be formed, for example, by using a yellow pigmented composition containing a yellow pigment and a pigment carrier. The material can be used, for example, as a yellow pigment which can be used in combination with a green pigment. Further, a halogenated product of each of a yellow basic dye and an acid dye may be used in combination. <Method of Manufacturing Color Filter> The color filter and the light sheet can be produced by the same method as the method of the first aspect, for example. - The embodiments of the present invention are described below, but the invention is not limited to the embodiments. In addition, unless otherwise specified, "part" means "weight part" 〇 First, various measurement methods and the like performed in the examples and comparative examples will be described. The polymerization average molecular weight (Mw) of the acrylic resin is converted into a weight average molecular weight of polystyrene. The weight average molecular weight (jjw) was measured by using a TSKgel column (manufactured by TOSOH Co., Ltd.), equipped with a detector (manufactured by GPCCTOS CO., Ltd., HLC-8120GPC), using THF as a developing solvent. 099132160 Form No. A0101 Page 76 of 154 Page 1003010545-0 201127911 The average particle size of the halogenated product and the rose-red compound after pulverization is the volume average obtained by using Beckmancoulter Multisizer 3' under the aperture diameter of 100 mm. Particle size. Further, the degree of refinement of the pigment is evaluated by the relative surface area of the pigment particles. The measurement of the relative surface area was carried out by using a BET (Brunauer-Emmett-Teller) method using an automatic vapor adsorption amount measuring device ("BELS0RP18" manufactured by Bel Japan Co., Ltd.).

Next, the acrylic resin solution, the commercial product, and the method for producing the rose-red chemical used in the examples and the comparative examples, and a method for refining the pigment will be described.

Test 1 is about the first aspect. In the case of the test ash '.1', the example of the hk sample is described as "Example", and the other examples are described as "Comparative Example". <Method for Producing Acrylic Resin Solution> (Modulation of Acrylic Resin Solution 1)

099132160 In the separate 4 flasks, install, 泠, grind, nitrogen inlet tube and agitator ‘in the reaction vessel ‘put the seven-ring 鲷7〇. The temperature is increased to 80 Χ:, the reaction capacity is replaced by nitrogen, and the η-butyl methacrylate is added dropwise through the dropping tube for 2 hours. . 3 parts, p-cumyl epoxide ethylene oxide modified acrylate ("AR0NIX Μΐΐ〇" manufactured by Toagosei Co., Ltd.) 7.4 and 2, 2'-azobisisobutyronitrile. 4 parts mixture. After the completion of the dropwise addition, the reaction was further continued for 3 hours to obtain an acrylic resin solution having a weight average molecular weight (Mw) of 26,000. After cooling to room temperature, about 2 g of the Shuyue solution was sampled, and it was dried by i8 (pc heating for 2 minutes to measure the non-volatile content. The non-volatile content contained in this way was 1003010545-0. A0101, page 77, pp. 154, 201127911, propylene glycol monoethyl ether ethyl vinegar (PGMAC) was added to the previously synthesized resin solution to prepare an acrylic resin solution 1. <Method for Producing Halogenated Products> (Rose Red Halogenated Product) 1. Formation of 1-1, 1-2 and 1-3) Add 2, 8-diamino-1-naphthol-5,7-disulfonate in 7 to 15 mol% sodium hydroxide solution Acid (molecular weight 334) 'The liquid is thoroughly stirred to obtain its sodium salt. The aqueous solution of 2, 8-diamino-1-naphthol-5,7-disulfonic acid sodium salt is heated to 70 to 90 ° C. After the 'red rose red 6GCP dye (CI basic red 1). The rose red 6GCP dye can also be used as a water f.' solution. After the drop of rose red 6GCP dye, in order to make it v. , with 70 shy 90t 'travel to &amp; 〇 minutes to mix the solution. The end of the reaction is based on the filter paper drop reaction _$ and * bar no __ liquid Domain point, that is, when there is no liquid leakage, it is judged that the obtained sputum is formed, and after being stirred and allowed to cool to room temperature, it is subjected to suction filtration and further washed with water. After washing, the teeth remaining on the filter paper are washed. Chemical product, using a dryer to remove water 'obtained the political red 66 € dye and 2, ': 8 - di-based-,. 1_naphthalene _5,7-disulfonic acid halogenated product, namely 汝瑰 糸 糸 糸 糸 糸 糸 糸 糸 玫瑰 玫瑰 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于32) 20 mass parts, which were mixed by a pressure kneader. The mixing system set the material temperature to g12 (rc, which was carried out after 3 knives. After cooling, the mechanical pulverizer (KRYPTRON KTM1 type manufactured by Earthtechnica Co., Ltd.) was used. Fine pulverization was carried out to obtain particles having an average particle diameter of 10 mm as a rose-red halogenated product. 1. Further, a rosin-modified cis-butyl diacid resin (acid) was added to a mass-mass product 1 of 100 mass parts. Price 35, weight average molecular weight 3500, Arakawa 099132160 Form No. A0101 Page 78 of 154 pages 1003010545-0 201127911 MALKYD No. 8 of Chemical Co., Ltd. 20 mass parts were mixed by a pressure kneader. The mixing system set the material temperature to 120 ° C for 3 minutes. After that, it was finely pulverized by a mechanical pulverizer (Kart PTRON KTM type manufactured by Earthtech Co., Ltd.) to obtain particles having an average particle diameter of 1 mm as the rose-red halogenated product 1-2.

Further, 20 parts by mass of the rose-red halogenated product 1 was added to a mass of the thermoplastic resin, and the mixture was mixed by a pressure kneader. The thermoplastic polyester resin is a mosquito polyester resin composed of terephthalic acid, isophthalic acid, stearic tricarboxylic acid, propylene epoxy plus bisphenol A and ethylene glycol (acid value: 10 mgKOH/g, 0H price: 43 mgKOH/ g, weight average molecular weight 35 〇〇) 1 . Furthermore, the amount of the money was determined under the same conditions as the rosin-regular resin. Further, the mixing was carried out by discharging the material to 120 t, and it was carried out for 30 minutes. After cooling, a Lime mechanical pulverizer (KRYPTRON KTM type 1 manufactured by Earthtechnica Co., Ltd.) was finely pulverized to obtain particles having an average particle diameter of 10 mm as a rose-red halogenation generation &amp; 1 -V' , . . . . ::: (formation of rose erythropurine products 2 and 2 -1) ' ' : it- 8 in 7 to 15 mol% of sodium hydroxide solution, 1-Cineamine~3 6 disulfonic acid (molecular weight 383) was added, and the liquid was sufficiently stirred, thereby obtaining a sodium salt thereof. The aqueous solution of the naphthylamine-3,6,2-disulfonic acid sodium salt was heated to 7 Torr to 9 Torr, after which a rose red 6GCP dye (c. I. basic red 1) was successively dropped. Meishen Red 6GCP dye can also be used as an aqueous solution. After the completion of the dropwise drop of the rose red 6GCP dye, the solution was stirred at 70 to 90 ° C for 40 to 60 minutes in order to allow sufficient reaction. The end point of the reaction is at the point when the filter paper drops the reaction solution without bleeding. That is, when there is no liquid leakage, it is judged that the obtained deuterated product β-face is mixed and allowed to cool to room temperature, and then sucked. 099132160 Form No. 1010101 Page 79/154 pages 1003010545-0 201127911 - Steps to wash. After washing with water, the halogenated product remaining on the filter paper was removed by a dryer to obtain a halogenated product of Rose Bengal 6GCP dye and 1-naphthylamine ~3,6,8-disulfonic acid, ie, rose-red teething. Product 2. Then, 20 parts by mass of rosin-modified halogenated product 2 was added to rosin-modified butyl bromide resin (acid value: 100, weight average molecular weight: 1,600, MALKYD No. 3002, manufactured by Arakawa Chemical Co., Ltd.). The pressure kneader was mixed. This mixing system set the material temperature to 12 (TC, which was carried out for 30 minutes. After cooling, it was finely pulverized by a mechanical pulverizer (KRYPTRON KTM type 1 manufactured by Earthtechnica Co., Ltd.) to obtain particles having an average particle diameter of ΙΟππη as a rose soul red. Tooth-forming product 2-1 〇气玄2~ &lt; i (formation of rose-red halogenated products 3 and 3) 1) Adding sulfonic acid to 7 to 15 mol% of sodium hydroxide solution Molecular weight 258), the liquid is sufficiently stirred to obtain the sodium salt thereof. After heating the aqueous solution of sodium sulfonate sodium salt to 70 to 9 Torr, the rose red B dye (CI basic purple 10) is successively dropped thereon. The pain dyeing code can also be used as an aqueous solution. After the rose red B dye is dropped into the east, in order to make it fully react, the solution is stirred at 70 to 9 (TC, 40 to 60 minutes. The end point of the reaction is the filter paper dropping reaction. When the liquid has no liquid leakage, it is judged that the halogenated product is obtained. After stirring, the mixture is allowed to cool to room temperature, and then suction-filtered and further washed with water. After washing, it remains on the filter paper. Halogenated product The water is removed by a dryer to obtain a chemical product of rose bengal B dye and sulfonic acid, i.e., rose red proteinization product 3. Next, '100 parts by mass of rose red halogenated product 2, adding rosin 099132160 form Editing · A0101 Page 80 of 154, 2011, 27911 Modified maleic acid resin (acid value 1〇〇, weight average molecular weight 16 (10), MALKYD Νο·3〇〇2 by Arakawa Chemical Co., Ltd.) The mixture was mixed by a pressure kneader, and the temperature was set to 12 Torr, and the sound was carried out for 30 minutes. After cooling, it was finely pulverized by a mechanical pulverizer (KRYPTRON® type 1 manufactured by Earthtechnica Co., Ltd.) to obtain an average particle diameter l. The particles of 〇mm are used as the rose-red halogenated product 3 -! 〇 (The production of rose and red halogens 4 and 4-1)

In the dissolution of sodium hydroxide of 7 to 15 mol%, phosphotungstic acid (molecular weight 2880) was added, and the liquid was sufficiently stirred, thereby obtaining a sodium salt thereof. The aqueous solution of the sodium phosphotungstate solution is heated to 70 to 90 ° C, and then it is immersed in the red color of the 6 GCP dye (c. I. basic red 1).卞红红^cp dyeing can also be used as an aqueous solution &gt; Rose red qi CP dye i after the end of the drop _, in order to make it fully reacted '70 to 90 ° C, the mixture was mixed for 40 to 60 minutes. The end point of the reaction is at the point when the filter paper drops the reaction solution without bleeding. That is, when there is no liquid leakage, it is judged that the _halogen is also allowed to be stirred while being cooled to _ room temperature. After washing with water, the halogen roasting product of the rose erythro 6GCP dye and the phosphotungstic acid, i.e., the rose red halogenated product 4, was obtained by drawing 4 of the bristles remaining on the filter paper and removing the water by a drier. Then, rosin-modified maleic acid resin (acid value of 100, weight average molecular weight of 16 〇〇, MALKYD No. 3002 by Arakawa Chemical Co., Ltd.) was added to 20 parts by mass. , mixed by a pressure kneader. This mixing set the material temperature to 12 Torr. (:, after 30 minutes. After cooling, it was finely pulverized by a mechanical pulverizer (KRYPTRON KTM1 type manufactured by Earthtechnica Co., Ltd.) Form No. A0101 Page 81 / 154 pages 1003010545-0 201127911, and an average particle diameter of l〇mm was obtained. The particles are rosin-based halogenated product 4-1 〇 (formation of rose red halogenated products 5 and 5 -1). In 7 to 15 mol% of sodium hydroxide solution, lemon yellow is added (edible yellow No. 4) : CI Acid Yellow 23) (molecular weight 534), the liquid is sufficiently stirred to obtain the sodium salt thereof. After heating the aqueous solution of the sodium citrate salt to 7 〇 to 9 〇 ° C, the rose red 6Gcp dye is successively dropped thereon. (c. Basic red 1). Rose red 6GCP dye can also be used as an aqueous solution. After the drop of the rose red 6GCp dye, in order to make it fully react, the solution is stirred at 70 to 9 (TC, 40 to 60 minutes. The end point is when the filter paper drops the reaction solution and there is no liquid leakage. 'Also, when the liquid has not been exuded, it is judged that the halogenated product is obtained. While stirring the surface, let it cool until it is at room temperature, and then suction and filter, further Washed with water. Washing, removing the water from the halogenated product that has been left on the filter paper, and removing the water by a dryer to obtain a tooth-forming product of rose red &amp; GCp dye and tartrazine, that is, rose-red tooth-forming product 5. Next, at 100 The rose red of the quality department is a halogenated product 5, and a rosin-modified maleic acid resin is added (acid value 1 〇〇, weight average molecular weight 16 〇〇, Arakawa Chemical Co., Ltd. MALKYD Ner. lOOSko mass part, pressurized The kneading machine was mixed. The mixing was carried out by setting the material temperature to 12 CTC for 30 minutes. After cooling, the material was finely pulverized by a mechanical pulverizer (KRYPTRON KTM type 1 manufactured by Earthtechnica Co., Ltd.) to obtain particles having an average particle diameter of 10 mm. Rose-red halogenated product 5-1 (mass of reddish-browning product of "rose" and "formation of ^") in a 9 mol% sodium hydroxide solution, adding 2_amino group_ι-naphthalene acid (spit Acid (molecular weight 223), the liquid is thoroughly stirred, thereby obtaining its sodium salt 099132160 Form No. A0101 Page 82 / 154 pages 1003010545-0 201127911. The aqueous solution of 2-amino-1-naphthalenesulfonate sodium salt After heating to 85 ° C, 'after its succession A few drops of rose red 6GCP dye (CI basic red 1). Rose red 6GCP dye can also be used as an aqueous solution. After the drop of rose red 6GCP dye, in order to make it fully react, the solution was stirred at 85 ° C for 55 minutes. The end point of the reaction is the point at which the reaction liquid is dropped from the filter paper and the liquid is not oozing. That is, when the liquid has not been oozing, it is judged that the halogenated product is obtained. After cooling to room temperature while stirring, the mixture was suction filtered and further washed with water. After washing with water, the toothed product remaining on the filter paper is dried.

(Q 099132160 The machine removes moisture and obtains a reddish 6 (iCP dye and 2-amino-1-naphthalenesulfonic acid (Touric acid) functionalized product, ie, the political pain red toothed product 2. Then' In the 100-mass part of the rose red system. Chemical 'sheng: into _〗 〇, add rosin modified maleic acid resin (acid price 梂 0, weight # average molecular weight 16 〇〇, MALKYD manufactured by Arakawa Chemical Co., Ltd. 3002) 20 mass parts, mixed by a pressure kneader. The mixing system sets the material temperature to l2〇〇c for 30 minutes. After cooling/using a mechanical pulverizer (£&1&quot;1;1^ 6(^111&lt;^ company 〇 suppression (^0*4'1 type) was finely pulverized, and particles having an average particle diameter of l〇min were obtained as: rose red halogenated product 10-1. Ά 乂 (Sanfang Formation of methyl halide-derived products 1 and 1-1) Addition of 2, diamino 4-naphthol-5,7-disulfonic acid (molecular weight 334) in 7 to 15 mol% sodium hydroxide solution The liquid is sufficiently stirred to obtain a sodium salt thereof. The aqueous solution of 2,8-diamino-1-naphthol-5,7-disulfonic acid sodium salt is heated to 70 to 9 (TC, after successively A little drop down Victoria# Blue Dye (CI Basic Blue 7) ^ Victoria Pure Blue Dye can also be used as an aqueous solution. After the end of the Victoria Pure Blue Dye, the solution is stirred at 70 to 9 (TC, 40 to 60 minutes) in order to allow it to react adequately. Form No. A0101 Page 83 of 154 '1003010545-0 201127911 The end point of the reaction is at the point when the filter paper drops the reaction solution and there is no liquid leakage. That is, when there is no liquid leakage, it is judged that the halogenated product is obtained. — After the surface is allowed to cool to room temperature, it is suction-filtered and further washed with water. After the nine-washing, the virgin product remaining on the filter paper is dehydrated by a dryer to obtain Victoria Pure Blue Dyes and 2, 8- 2 A halogenated product of an amine-1, a Tsai, and a 5,7-disulfonic acid, that is, a triaryl decane-based halogenated product 1 followed by a triarylmethane-based halogenated product 1 at a mass of 100, a method of adding rosin A mass of maleic acid resin (acid value 丨3〇, weight average molecular weight 1000, Arakawa Chemical Co., MALKYD No. 32) 20 mass parts, D|, mixed with a pressure kneader. : Material temperature is set to 12 (Γ (:, After 30 minutes, it was finely pulverized by a bee-type pulverizer (KRYPTRON® type 1 manufactured by Earthtechnica Co., Ltd.) to obtain particles having an average particle diameter of 1 Gmm as a halogenated product of triaryl-based firing system. Formation of the methane-based halogenated products 2 and 2-1) in the 7 to 15 mol% sodium hydroxide solution, such as ι_naphthylamine 8_trisulphonic acid (kohic acid) (molecular weight 383,), The liquid is thoroughly stirred to thereby obtain its sodium salt. After heating the 1-naphthylamine-3,6,8-trinucleic acid (kohic acid) sodium salt solution to 70 to 90 ° C, the malachite green dye (C.I. Basic Green 4) was successively dropped. Malachite green dye can also be used as an aqueous solution. peacock

After the end of the green dye, the mixture is stirred for 70 to 9 (TC, 40 to 60 minutes. The end point of the reaction is at the point when the filter paper drops the reaction solution and there is no liquid leakage. When there is no liquid leakage, it is judged that the chemical product is obtained. After being disturbed and allowed to cool to room temperature, it is suction-filtered and further washed with water. After washing, it remains on the filter paper. 099132160 Form No. A0101 Page 84 of 154 1003 201127911 The halogenated product is removed by a dryer to obtain a halogenated product of malachite green dye and 1-naphthylamine-3,6,8-trisulphonic acid (kohic acid), ie, triarylmethane system. Object 2.

Then, 20 parts by mass of a rosin-modified maleic acid resin (acid value 200, weight average molecular weight 750, MALKYD No. 31 manufactured by Arakawa Chemical Co., Ltd.) was added to 100 parts by mass of the triaryl decane halogenated product 2, It was mixed by a pressure kneader. The mixing was carried out by setting the material temperature to 120 ° C for 30 minutes. After cooling, it was finely pulverized by a mechanical pulverizer (KRYPTRON KTM type 1 manufactured by Earthtechnica Co., Ltd.) to obtain particles having an average particle diameter of 10 mm as a triarylmethane-based halogenated product 2-1 〇ύ * . (Triarylmethane-based halogenation Preparation of product 10 and 10-1) 2-amino-1-naphthalenesulfonic acid (Tour acid) (molecular weight 334) was added to a 9 mol% sodium hydroxide solution, and the liquid was sufficiently stirred. Obtain its sodium salt. After heating the aqueous solution of 2-amino-1-naphthalenesulfonic acid (Thronic acid) sodium salt to 85 ° (:, after successively dropping Victoria blue dye (CI basic blue 7), Victoria pure blue dye can also be used. It is used as an aqueous solution. After the completion of the dropwise addition of the Victoria Pure Blue Dyestuff, in order to make it fully react, the solution is stirred at 85X: for 55 minutes. The end point of the reaction is at the point when the filter paper drops the reaction solution and there is no liquid leakage. When there is no liquid leakage, it is judged that the halogenated product is obtained, and after cooling to room temperature, the mixture is suctioned and filtered, and further washed with water. After washing with water, the halogenated product remaining on the filter paper is removed by a dryer to obtain water. a halogenated product of a pure blue dye of Victoria and 2-amino-1-naphthalenesulfonic acid (Touric acid), that is, a triarylsulfane halogenated product 10. Next, a triarylmethane halogenated product at 100 parts by mass 10, add 099132160 Form No. A0101 Page 85 / 154 pages 1003010545-0 201127911 Rosin modified maleic acid resin (acid price 200, weight average molecular weight 750, MALK manufactured by Arakawa Chemical Co., Ltd. YD No. 31) 20 mass parts were mixed by a pressure kneader. The mixing system was set to a temperature of 120 ° C for 30 minutes. After cooling, a mechanical pulverizer (KRYP.TRON KTM1 manufactured by Earthtechnica Co., Ltd.) was used. The pulverization was carried out to obtain particles having an average particle diameter of 10 mm as a triaryl decane-based halogenated product 10-1. (Production of triarylmethane-based halogenated products 11 and 11-1) at 9 mol% To the sodium hydroxide solution, 1-amino-5-naphthalenesulfonic acid (Lorentz acid, molecular weight 223) (molecular weight 223) was added, and the liquid was sufficiently stirred to obtain a sodium salt thereof. -5-naphthalenesulfonic acid (Lorentz acid, molecular weight 223) aqueous sodium salt solution heated to 85 ° C, after which a small amount of Victoria pure blue dye (CI basic blue 7). Victoria pure blue dye can also be used as an aqueous solution After the end of the Victoria pure blue dye, in order to make it fully react, the solution was stirred at 85 ° C for 55 minutes. The end point of the reaction was at the point when the filter paper dripped the reaction solution and there was no liquid leakage. When exuding, it is judged that a halogenated product is obtained. After cooling to room temperature with stirring, the mixture was suction-filtered and further washed with water. After washing with water, the halogenated product remaining on the filter paper was removed by a dryer to obtain Victoria Pure Blue dye and amidino-5-naphthalene. A halogenated product of a sulfonic acid (Lorentz acid, molecular weight 223), that is, a triarylmethane-based halogenated product 11. Next, a rosin-modified butylene is added to a monovalent decane-based halogenated product 11 of 100 parts by mass. A 20-mass portion of a diacid resin (acid value of 200, weight average molecular weight of 750, and MALKYD No. 31 manufactured by Arakawa Chemical Co., Ltd.) was mixed by a pressure kneader. The mixing system sets the material temperature to 120 ° C and proceeds through 099132160 Form No. A0101 Page 86 / 154 pages 1003010545-0 201127911 30 minutes. After cooling, it was finely pulverized by a mechanical pulverizer (KRYPTRON KTM type 1 manufactured by Earthtechnica Co., Ltd.) to obtain particles having an average particle diameter of 10 mm as a triaryl decane-based halogenated product 11-1 〇 (triarylmethane-based halogenated product 12 And the formation of 12-1) In a 9 mol% sodium hydroxide solution, 1-ion-based 4-naphthalene acid (NW acid) (molecular weight 224) was added, and the liquid was sufficiently stirred to obtain a sodium salt thereof. . The aqueous solution of the hydroxy-4-naphthalenesulfonic acid (NW acid) sodium salt was heated to 85. (after 3

'Voice Pure Blue Dye (C. I. Basic Blue 7) ° Victoria Blue Pure Dye can also be used as an aqueous solution. After the end of the Victoria Pure Blue dye drop, the solution was stirred at 85 ° C for 55 minutes in order to flood the reaction. At the end of the reaction, Meng Meng filtered the sweat reaction solution and no time was observed. That is, when it is no liquid, V judges that the chemical product is obtained. The mixture was allowed to cool to room temperature while stirring, and subjected to suction filtration', and further washed with water. After washing with water, the toothed product remaining on the filter paper is removed by a dryer to obtain 雉: Dolly; the mesogenic blue dye and the tooth of 1-hydroxy-4-nathene acid (NW acid) And the product, that is, the triarylmethylidene 1 system is formed by the chemical product 12. '-, ν Next, a rosin-modified maleic acid resin was added to the triarylmethane-based halogenated product I2' of the mass portion (acid value 200, weight average molecular weight 750, MALKYD No. 31 manufactured by Arakawa Chemical Co., Ltd.) ) 20 mass parts, mixed by twisting the barrier machine. This mixing was carried out by setting the material temperature to 120 ° C for 30 minutes. After cooling, it was finely pulverized by a mechanical pulverizer (KRYPTRON KTM type 1 manufactured by Earthtechnica Co., Ltd.) to obtain particles having an average particle diameter of 10 mm as halogenated by triarylmethane to form 099132160. 12-1 〇Form No. A0101 Page 87 of 154 003010545Ό 201127911 (Formation of flavin halogenated products 1 and 1-1) 7 to 15 mol% of sodium hydroxide solution, 'addition of acid (molecular weight 258), and fully stir the liquid, thereby G The latter is the sodium salt. After heating the aqueous solution of sodium sulfonate sodium salt to 7 Torr to 90 ° C, it was recognized that there was no flavin dye (C. I. Basic Yellow 1). Huang Xinju Group ★ Χ can be used as an aqueous solution. After the end of the Victoria Pure Blue Dye, the horse has fully reacted to 70 to 90 ° C, and after 40 to 60 minutes, the solution is treated with the solution. The end point of the reaction is the drop of the reaction solution on the filter paper. When the effluent is sputum, it is time. That is, when the liquid has not been oozing, it is judged that the halogenated product is obtained. — After mixing and cooling to room temperature, perform suction filtration and further wash with water. After the observation, from the i-formed product remaining on the crepe paper, the moisture of the flavin dye and the sulphuric acid was obtained, and the yttrium-like dentate product i was obtained. Next, the flavin-based dentured product 1 was added to 100 parts by mass; rosin-modified maleic acid resin was added (acid value 3 〇〇, weight _ sub-amount 45 (), MALKYD No. 33 manufactured by Arakawa Chemical Co., Ltd. ) 20 mass parts, mixed by a pressure kneader. In the mixing system, the material temperature is set to i2 (rc, which is carried out over 3 minutes. After cooling, the mechanical pulverization mechanism om_ ΚΤΜΓ type) is used to finely pulverize, and the average particle of the cockroach is obtained as a flavin halogenated product.丨_ i. (Methylene blue halogenated product 1 and formed thereof) In a 7 to 15 mol% sodium hydroxide solution, adding 2 8 -diamino-p-naphthalene-5,7-diwei (molecular weight 334), The liquid is thoroughly stirred to thereby obtain a copper salt thereof. The 2,8-diamino+naphthene_5 7-dibasic acid sodium salt aqueous solution was heated to -9 Torr. (: After that, it drops the methylene blue FZ dye (C.I_Basic Blue 9) in a row. The methylene blue Fz_ material can also be used as an aqueous solution. After the drop of the indigo blue FZ dye, in order to make it full Reaction, 099132160 Form No. Toilet 1 Page 88 / 154 pages 201127911, the solution is stirred at 70 to 9 (TC ' over 40 to 60 minutes. The end point of the reaction is at the point when the filter paper drops the reaction solution and there is no liquid leakage. When it is no liquid, it is judged that the halogenated product is obtained. After stirring, the surface is allowed to cool to room temperature, and then the mixture is sucked and further washed with water. After washing with water, the toothed product remaining on the filter paper is dried. The machine removes moisture' to obtain a halogenated product of methylene blue FZ dye and 2, 8-diamino-1-naphthol-5,7-disulfonic acid, that is, a methylene blue halogenated product 1.

Methylene blue halogenated product 1 in a mass portion of 1 '20% of a rosin-modified cis-butane adipic acid resin (acid value 130, weight average molecular weight 1 〇〇〇, MALKYD No. 32 manufactured by Arakawa Chemical Co., Ltd.) It was mixed by a pressure kneader. The mixing enthalpy set the material temperature to 420 ° C for 30 minutes. After cooling, the material was subjected to micro-dressing by a mechanical powder mill, KRYPTRON KTM1 type manufactured by ga hth t e chn i c a company, and a particle # of an average particle diameter of 10 mm was obtained as a methylene blue halogenated product 1-1. (Formation of the dynasty red halogenated products 5 and 5-1) 7 to 15 mol% of the sodium hydroxide onion, add lemon yellow (edible yellow No. 4: C · I. acid yellow 23) The molecular weight is 34)" to fully mix the liquid, ........;;;:; '^· - ·? &gt; thereby obtaining the bismuth salt thereof. The solution of the scented sodium sulphate solution is heated to 70 To 90 ° (: after 'after a drop of rose red 6GCP dye (CI basic red 1). Rose red 6GCP dye can also be used as an aqueous solution. Rose red 6GCP dye after the end of the drop 'to make it fully react, to 7 〇 to 90. (:, the solution is stirred for 40 to 60 minutes. The end point of the reaction is at the point when the filter paper drops the reaction liquid and there is no liquid leakage. That is, when the liquid has not been permeated, it is judged that the deuterated product is obtained. After the surface is mixed and allowed to cool to room temperature, it is suction-filtered and further washed with water. After washing, the halogenated product remaining on the filter paper is removed by a dryer to obtain rose red 6GCP dye 099132160 Form No. Α0101 Page 89 / Total 154 pages 1003010545-0 201127911 The material and the halogenated product of tartrazine, namely rose red Next, a rosin-modified maleic acid resin (acid value of 100, weight average molecular weight of 1,600, MALKYD No. manufactured by Arakawa Chemical Co., Ltd.) was added to the rosin-based halogenated product 5 of the mass portion of 100%. 3002) 20 mass parts, which were mixed by a pressure kneader. The mixing system was set to a temperature of 120 ° C for 30 minutes, and after cooling, it was micro-machined using a mechanical pulverizer (KRYPTRON KTM type 1 manufactured by Earthtechnica Co., Ltd.). After pulverization, particles having an average particle diameter of 10 mm are obtained as a rose-red halogenated product 5 -1 〇 (formation of rose red halogenated products 6 and 6-1). 7 to 15 mol% of sodium hydroxide To the solution, 3, hydroxy-2-naphthoic acid (molecular weight 177) was added, and the liquid was thoroughly stirred to thereby obtain a sodium salt thereof. The aqueous solution of sodium 3-hydroxy-2-naphthate was heated to 70 to 90 ° C. After that, the rose red 6GCP dye (CI basic red 1) is dripped a little later. Rose red 6GCP dye can also be used as an aqueous solution. After the drop of the rose red 6GCP dye, in order to make it fully react, 70 to 90 ° C, Stir the solution for 40 to 60 minutes. When the reaction paper is dripped, the liquid is not oozing. That is, when the liquid has not been oozing, it is judged that the halogenated product is obtained. After stirring, the mixture is allowed to cool to room temperature, and then suction-filtered and further washed with water. The halogenated product on the filter paper is dehydrated by a dryer to obtain a halogenated product of Rose Bengal 6GCP dye and 3-hydroxy-2-naphthoic acid, that is, rose-red halogenated product 6. Then, 20 parts by mass of rosin-modified maleic acid resin (acid value 130, weight average molecular weight 1,000, MALKYD No. 32 manufactured by Arakawa Chemical Co., Ltd.) was added to 100 parts by mass of the rose-red halogenated product 6 to The pressure kneader was mixed. The mixing system sets the material temperature to 120 ° C and proceeds through 30 099132160 Form No. A0101 Page 90 / 154 pages 1003010545-0 201127911 minutes. After cooling, it was finely pulverized by a mechanical pulverizer (KRYPTRON KTM type 1 manufactured by Earthtechnica Co., Ltd.) to obtain particles having an average particle diameter of 1 mm as a rose-red halogenated product 6-1. <Manufacture of ruthenium red compound> (Production of rose red compound 1-1)

Adding 50 parts of rosin-modified maleic acid resin (acid price 35, weight average molecular weight 3600, MALKYD No. 8 manufactured by Arakawa Chemical Co., Ltd.) to 100 parts of rose red 6GCP dye (CI basic red 1) The kneading machine is mixed. The mixing was carried out by setting the material temperature to 120 ° C for 45 minutes. After cooling, a micro-teaching machine was used to obtain a particle having an average particle diameter of 1 〇mm as a rosin-based compound by using a mechanical pulverizer (KRYPTRON KTM type 1 manufactured by Earthtechnica Co., Ltd.). Preparation of red fine pigment 1) CI Pigment Red 254 (2030, manufactured by Chiba Corporation, Japan, relative surface area: 65 m2/g) of diketopyrrolopyrrole red pigment 2 〇〇, sodium chloride: 14 知部 and The ethylene glycol 360 part was placed in a stainless steel 1# gallon kneading mechanism, and mixed and stirred at 80 t for 6 hours. Next, the kneaded material was placed in 8 liters of warm water and heated to 80 ° C, and mixed for 2 hours to prepare a slurry. After repeated filtration and water washing to remove the vaporized sodium and diethylene glycol, the film was dried at 85 ° C for one night to obtain 190 red fine pigments 1 ^ Red Fine pigment 1 having a relative surface area of 8 μm 2 /g. (Formation of green fine pigment 1) C.1. Pigment Green 36 of phthalocyanine-based green pigment (Li〇nol Green 6YK, manufactured by Toyo Ink Co., Ltd.), relative table 099132160 Form No. A0101 Page 91 of 154 Page 1003010545-0 201127911 200 parts of area 60 m2/g), 1400 parts of sodium chloride and 360 parts of diethylene glycol were placed in a stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.), and mixed and stirred at 80 ° C for 6 hours. Next, the kneaded material was placed in 8 liters of warm water and heated to 80 ° C to be stirred for 2 hours to prepare a slurry. After repeating filtration and washing with water to remove sodium chloride and diethylene glycol, it was dried at 85 ° C for one day and night to obtain 190 green fine pigments 1. The green fine pigment 1 has a relative surface area of 75 m 2 /g. (Formation of yellow fine pigment 1) CI Pigment Ye 1 low 150CLANXESS "E-4GN", relative surface area 100 m2 / g), sodium chloride 1400, and diethylene glycol 360 were recorded as yellow pigments. The parts were placed in a stainless steel 1 gallon kneader (manufactured by Inoue Co., Ltd.), and mixed and stirred at 80 ° C for 6 hours. Next, the kneaded material was placed in 8 liters of warm water, and heated to 80 ° C on one side, and stirred for 2 hours to form a slurry. After repeated filtration and washing with water to remove sodium chloride and diethylene glycol, it was dried at 85 ° C for one day and night to obtain 190 yellow fine pigments 1. The yellow fine pigment 1 had a relative surface area of 130 m 2 /g.

(Formation of Blue Fine Pigment 1) CI Pigment Blue 15:6 ("Lionol Blue ESj, relative surface area 60 m2 / g" manufactured by Toyo Ink Co., Ltd.) 200 parts, sodium chloride 1400 and two The 360 parts of ethylene glycol was placed in a stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.), and mixed and stirred at 80 ° C for 6 hours. Then, the mixed mixture was placed in 8 liters of warm water and heated to 80 °. C, a slurry was formed by stirring for 2 hours. After repeated filtration and washing with water to remove sodium chloride and diethylene glycol, it was dried at 85 ° C for one day and night to obtain 190 blue fine pigments 1. Blue 099132160 of fine pigment 1 Form No. A0101 Page 92 / 154 pages 1003010545-0 201127911 Relative surface area is 80 m2 / g. (Formation of purple fine pigment 1) CI Pigment Violet 23 of dioxin-based purple pigment (Toyo) "LI0N0GEN VIOLET RL" manufactured by Ink Manufacturing Co., Ltd., 200 parts of relative surface area: 75 m2/g), 1400 parts of sodium chloride, and 360 parts of diethylene glycol were placed in a stainless steel one-gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.) at 80 ° C. Mix for 6 hours . Next, the kneaded material was placed in 8 liters of warm water and heated to 80 ° C to be stirred for 2 hours to prepare a slurry. After repeated filtration and washing to remove sodium chloride and diethylene glycol,

After drying at 85 ° C for one day and night, 190 purple fine pigments 1 were obtained. The purple fine pigment 1 has a relative surface area of 95 m 2 /g. [Examples 1 to 16 and Comparative Examples 1 to 71. (Example 1: Coloring composition for color filter (D-1)) After the following mixture was stirred uniformly, zirconia beads having a diameter of 0.5 ππη were used. By IGER grinding machine ("Mini Model M-!:;-:; 250 ΜΚΙI" made by IGER Japan), it was processed for 5 hours, and the dispersion was filtered with a 5.0 mm filter to obtain color.着色f-light film coloring composition (D-1) Rose red halogenated product 1:11. 0 part acrylic resin solution 1: 40. 0 propylene glycol monoethyl ether ethyl ester (PGMAC) ·· 48. 0 Resin type dispersant (EFKA4300): 1. 0 part 099132160 Form No. A0101 Page 93 / 154 pages 1003010545-0 201127911 (Examples 2 to 16 and Comparative Examples I to 7 · Coloring composition for color filters ( D-2) to (D-23)) Coloring was carried out in the same manner as in the coloring composition (I)-) of Example 1, except that the rose-red halogenated product was replaced with the coloring agent shown in Table 1. Compositions (D-2) to (D-23). Table 1 Coloring composition coloring agent breeding example 1 D-1 Rose red: coloring composition 1 breeding example 2 D-2 rose red halogenated product example 3 1&gt;1 3 rose soul red toothing Product 4; Example 4 D-4 Rose-red halogenated product j _3 - 贲 Example 5 D-5 Rosemary-based chemical product 2-Ί Example 6 D-6 Rose-red halogenated product 3 — :! Example 7 D-7 Rose-red halogenated product 4_ T - Lean SD - 8 Rose red-based chemical product 5_·! Example 9 D-9 Bi-based methylate-based product Example 10 D-10. Diarylcarbazide-based product 2~1 Leaning Example 11 1&gt;-11 Flavin-based halogenated product li Lean Example 4 2 D-12 Methylene blue halogenated product Comparative Example 1 D-13. Rose-washing coloring composition 6-1 Comparative Example 2 D-14 Rose red compound 1 - 1 Comparative Example 3 D-15 Red fine pigment 1 Comparative Example 4 D-16 Green fine pigment 1 ... Comparative Example 5 D-17 Yellow Fine Yankee 1 Comparative Example $8 Basket Color Mark_fine Pigment 1 Comparative Example 7 D-19 Purple Fine Pigment 1 Example 13 D-20 Rose Red System Deuterated Product 10-1 Example 14 Example 15 D-21 "D- 22 Diarylmethane system. Chemical product 〇 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; [Evaluation of Colored Composition] The color characteristics evaluation and heat resistance test of the coloring compositions (D4) to (D_23) were carried out by the following methods (Evaluation method of color characteristics and heat resistance) On the glass substrate, under the c-light source, each of the colored compositions (D1) to (D23) was coated to exhibit the hue shown in Table 2, at 23 Torr. The substrate was heated for another minute. Spectrophotometer (〇1卿3光099132160 Form No. A0101 Page 94/154 pages 1003010545-0 201127911 "OSP-SP200") The thickness Y of the substrate on which the colored layer is formed is measured. Table 2 [0008]

Coloring composition color X _ Greedy Example 1 D-1 0.640 Example 2 D-2 0.640 __.1T Example 3 D-3 0.640 食施你 ί 4 D-4 0.640 Τ Example 5 D-5 Red 0.640 1ΓExample 7 D-7 Magenta 0.640 Appreciation Example 8 D-8 0.640 ttComparative Example 1 Wide D-13 0.640 fct Comparative Example 2 D-14 0.640 School Example 3 D-15 0.640 Appreciation Example 1 1 D-11 Yellow 0.440 Ratio School Example 5 D-I7 0.440 Coloring composition color y 1 Example 1 0 D-10 Green 0.600 Comparative Example 4 D-16 0.600 T Example 9 D-9 0.060 Example 12 D-12 Basket 0.060 Comparison Example 6 D-18 0.060 Set 1 Example D-6 Violet 0.100 Comparative Example 7 0-19 0.100 Colored composition color X Example 1 3 D-20 Red 0.640 Magenta coloring composition color y ir Bait 14 D-21 Blue 0.060 Example 15 D-22 Blue 0.060 Example 16 D-23 Blue 0.060 [0009]

8 i : ϊ ί J Further, the color difference l (L*(i) measured under the C light source is measured by a microscopic spectrophotometer ("OSP-SP200" manufactured by Olympus Optics Co., Ltd.) for the colored layer; , a*(i), then, the above-mentioned substrate which has formed the colored layer is supplied to the oven, and the heat resistance test is performed by heating for 250 hours, and the color difference 2 under the C light source is further measured (L*( 2), a*(2), b*(2)). Using the color difference values, the color difference change rate Δ Eab* is calculated by the following calculation formula, and then 'according to the color difference change rate AEab*' The heat resistance of the coating film is evaluated in stages 4. 099132160 Form No. A0101 Page 95 / 154 pages 1003010545-0 201127911 ◎ : Less than 5 〇: 1 &lt; 5 or more, less than 3 〇 △: Wab* is 3. 〇 or more Less than 5 〇X : AEab* is 5. 〇 The evaluation results of color characteristics and heat resistance are shown in Table 3. Table 3 Example 1 匕 成 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 实施 实施 实施 实施 实施 D D Magenta 15.2 __ 〇15.1 &quot; Example 3 ΙΙ3ΞΓΖΖ ◎ Example 4 Ί 15.5 〇-D-4 Γ?Τ4 &quot; Example 5 'Q_D-5 15.6] Implementation Example 7 D-7 ◎ Example 8 D-8 15.3 ◎ Comparative Example 1 D-13 15.1 ◎ Comparative Example 2 D-14 15.4 X Comparative Example 3 D-15 9.3 13.1 ΔX Present Example 1 1 Comparative Example 5 D-ll D-17 ------ D·-10 Yellow ' -1 . · 1 — Green 88.1 L ◎ Poor Example 10 84.1 491 &quot; One ◎ Comparative Example 4 D-16 AC 实施 Example 9 D-9 Blue 7.1 ◎ Example 12 D-12 7.2 ◎ Comparative Example 6 D -18 6.5 β) Example 6 D-6 Purpura 5 ◎ Comparative Example 7 D-19 8·9 1 A ◎ Example 13 D-20 Red magenta 15.4 ◎ Example Μ D-21 Blue 7.1 L ◎ Example 15 D-22 7.1 ◎ Example 16 D-23 7.1 ◎ (Evaluation result of color characteristics and heat resistance) Coloring using a halogenated product as a coloring agent When the composition is to (D-12) and the coloring compositions (D-20) to (D-23), compared with the case of using the coloring compositions (D-15) to (D_19) containing only a pigment as a coloring agent, A higher brightness Y can be obtained. The coloring composition (D_14) of Comparative Example 2 was obtained by using a coloring agent which was not toothed with a relative compound (anionic component), because 099132160 Form No. A0101 Page 96 of 154 pages 1003010545-0 201127911 This color was weak and had no tinting strength. Therefore, the brightness is low. Further, when the coloring compositions (D-1) to (D-12) and the coloring compositions (D-20) to 23) containing the dentured product as the coloring agent are used for heat resistance, good results are obtained. . When compared with the results obtained when using the colored composition (D-丨) to (D_4) containing the rose-red halogenated product 1, the rosin modified in the range of 100 to 300 mgKOH/mg is used. In the case of the enedionic acid resin, it is possible to achieve a brightness which is substantially equal to that of other cases, and it is possible to achieve better heat resistance. (In view of the above results, it is understood that the coloring composition containing the A-chemical residue exhibits good performance in both color characteristics and heat resistance. [Example 17 to Comparative Example 8 to find]: (Example 13 : Resist material ^: color) ' -· After the following mixture is mixed uniformly, the alkali-developed resist material (R-1) is obtained by filtering the dispersion liquid with a 〇&quot; m. Composition (D-8): 50. Minmetals No. 3 Factory i: , coloring composition (DU) (: ❹·: 1〇.. Partial acrylic resin solution 1: 11.0 trimethylolpropane triacrylate .. : (2) (Nippon Nakamura Chemical Co., Ltd. "NK ester ATMPT") Photopolymerization initiator: 1. 2 (IRGACURE 907, manufactured by Chiba Corporation, Japan) 099132160 Form No. A0101 Page 97 of 154 Page 1003010545 -0 201127911 Sensitizer ("EAB ~ F" manufactured by Hodogaya Chemical Co., Ltd.): 0.4 propylene glycol monoethyl ether ethyl ester (PGMAC): 23.2 (Examples 17 to 46 and Comparative Examples 8 to 12) : Resist materials (R-2) to (R-35)) Except that the coloring composition shown in Table 4 was substituted for the coloring composition, as shown in Table 4, the amount of the composition was changed. In the same manner, the alkali-developing resist materials (R-2) to (R-35) were obtained as the resist material (R-1). Further, a plurality of coloring compositions were used in combination, and the entire resist material was set to 100 parts. At the time, the total amount of the coloring composition is .60. Table 4, Resist material resist material, t3, L color composition #配配量, color tone, color tone, color tone, color ratio, color ratio, R-1 Red D-8 50 D-11 10-' - - - Real 18 R-2 D-8 50 D-17 10 - - One by one R-3 D-8 30 D -11 10 D-1 20 parts - - Sina R-4 D-8 30 D-11 10 D-2 20 parts - One real _ R-5 D-8 30 D-11 10 D- 3 20 Part One - Shina R-6 D-8 30 Department D-11 10 Department D-4 20 Department One - Implementation "23 R-7 D-8 30 Parts D-11 10 Parts D-5 20 Parts - - SINA 4 R—8 D-8 30 D-11 '10 D-7 20-- Real _ R-9 D-8 50 D-11 5 D-17 5 _ - Real _6 R -10 D-8 40 D-15 10 D-11 10 - I Shi Na R-11 D-8 40 D-15 10 D-17 10 - 099132160 Form No. A0101 Page 98 of 154 Page 1003010545-0 201127911

099132160 Implementation Qing R-12 D-8 8 D-15 10 D-11 5 D-17 5 Parts R-13 Green D-10 45 D-11 15 _ 一实娜R-14 D -10 45 D-17 15 parts one by one cargo foot 1 R-15 D-10 45 parts 0-11 15 parts D-17 5 parts real coffee R-16 D-10 35 parts D-16 10 parts D- 11 15 parts willow 3 R-17 D-10 35 parts D-16 10 parts D-17 15 parts R-18 D-10 35 parts D.-16 10 parts D-11 5 parts D-17 10 parts R-19 Blue D-9 55 Σ)—6 5 — One implementation “36 R-20 D-9 45 D-6 5 D-2 10 f n 7 R-21 D-9 45 D -6 5 parts 30-5 10 parts willow S R-22 D-9 45 parts D-6 5 parts D-7 10 parts _ 娜娜 9 R-23 D-9 55 parts D-19 5 parts _ _ Real *Qing R-24 D-9 45 D-18 10 D-19 5 _ &quot; SINA 1 R-25 D-9 45 D-18 10 D-6 3 D-17 2 R -26 D-12 55 D-6 5 _ A ratio «8 R-27 Red D-13 50 D-17 10 — _ — . · · Compare 9 R-28 D-14 50 D .-17 10部一_ Comparative Qing R-29 D-15 50 D-17 10 _ _ «1娜R-30 Green D-16 45 D-17 15 _ _ __ Gang 12 R-31 Blue D-lg 55 D-I9 5 parts one real Na R-32 red D-8 30 D-11 10 parts D-20 20 parts __ real example "R-33 blue D-21 55 parts D-6 5 parts one - Shina R-34 D-22 55 parts D-6 5 parts one - one阙46 R-35 D-23 5 5 parts D-6 5 parts - one - - Γ 3 ^ , v 芦二 - • -&lt;v5.-5.-S5: s·,' [resist material Evaluation] The following methods were used to carry out the color characteristics of the resist material -1 to (R_^5) - » =_=-_! _ % &quot;&quot; Evaluation and tolerance (for heat and light resistance) Sex and solvent resistance test (color property evaluation) if ϊδ On the glass substrate, the anti-money material 彳 is applied. Specifically, the red anti-yf f/ruthenium material (R-i) (R-12), '(R-27) to (R-29) and (R-32)' are coated as C Under the light source, the chromaticity will be 640, y = 0. 330: .Vri':^' % § i| » ί. ί 矣·^~ one way 4 g %!s«, r, another · film thick. The green resist materials (R-13) to (R-18) and (R-30) are coated so that the chromaticity under the C light source becomes 膜 = 〇 300, y = 〇 600. The blue resist materials (R-19) to (R-26), (R-31) to (R-33) and (R-35) are coated so that the chromaticity under the C light source becomes χ= 0. 150, y=0. 060 film thickness. Next, the substrate was heated at 230 ° C for 20 minutes to form a colored layer on the substrate. Then, the luminance Y of the substrate on which the colored layer was formed was measured by a microscopic spectrophotometer ("OSP-SP200" manufactured by Olympus Optics Co., Ltd.). Table 5 shows the evaluation results. Form No. A0101 Page 99/154 Page 1003010545-0 201127911 Table 5 [0012] Resist Material Color X y Y Example 17 R-1 Red 0.640 0, 330 15.8 Example 18 R-2 0.640 0.330 15.7 Example 19 R -3 0.640 0.330 16.1 Example 20 R-4 0.640 0.330 16.0 Example 21 R-5 0.640 0.330 16.2 Example 22 R-6 0.640 0.330 15.8 Example 23 R-7 0.640 0.330 15.7 Example 24 R-8 0.640 0.330 15.6 Example 25 R-9 0.640 0.330 15.6 Example 26 R-10 0.640 0.330 15.9 Example 27 R-11 0.640 0.330 15.7 Example 28 R-12 0.640 0.330 15.8 Comparative Example 8 R-27 0.640 0.330 15.8 Comparative Example 9 R- 28 0.640 0.330 9.6 Comparative Example 10 R-29 0,640 0.330 13.1 Example 29 R-13 Green 0,300 0.600 51,1 Example 30 R-14 0.300 0.600 50.9 Example 31 R-15 0.300 0.600 50.6 Example 32 R-16 0.300 0.600 50.6 Example 33 R-17 0300 0.600 50.5 Example 34 R-18 0300 0.600 50.7 Comparative Example 11 R-30 0.300 0.600 46.1 Example 35 R-19 Blue 0.150 0.060 7.1 Example 36 R-20 0.150 0.060 Ί3 Example 37 R-21 0.150 0.060 7.3 Example 38 R-22 0.150 0 .060 7.2 Example 39 R-23 0.150 0.060 7.1 Example 40 R-24 0.150 0.060 7.0 Example 41 R-25 0.150 0.060 6.9 Example 42 R-26 0.150 0.060 7.0 Comparative Example 12 R-31 0.150 0.060 5.9 Example 43 R-32 Red 0.640 0.330 15.6 Example 44 R-33 Blue 0.150 0.060 7.0 Example 45 R-34 0.150 0.060 7.1 Example 46 R-35 0.150 0,060 7.2 For red resist materials (R-1) to (R -12), (R-27) to (R-29) and (R-32), the following procedures were carried out to test for resistance (heat resistance, light resistance and solvent resistance). (Method of Coating Film Heat Resistance Test) On a transparent substrate, a resist material was applied as a dry coating film to 2. 5 # m, and a mask having a specific pattern was interposed, and the coating film was exposed by ultraviolet rays. The alkali film is sprayed on the coating film to remove the uncured portion, thereby forming the desired pattern by the form 099132160 Form No. A0101 Page 100 / 154 pages 1003010545-0 201127911. Thereafter, it was heated in the oven at 23 {rc for a few hours. After cooling, the color difference ΐα*(1), a*(1), b* of the obtained coating film under c light source was measured by a microscopic spectrophotometer ("OSP-SP200" manufactured by 01y叩us Optics Co., Ltd.). (1)). Thereafter, it was subjected to a heat resistance test in an oven at 250 ° C for 1 hour to further measure the color difference 2 under the xenon light source (L*(2), a*(2), b*(2). ). Using the color difference values, the color difference change rate Δ Eab* is calculated by the following calculation formula. Then, according to the chromatic aberration change rate AEab*, the following four stages are adopted.

The heat resistance of the coating film was evaluated. ◎ : △EabM, at 1. 5 〇: AEab* is 1. 5 or more, + ling ^0 ... v. ' : Λ": △ : AEab* is 3. 0 or more, less than 5. 0 ' ' w Ίυ ' Mei-X: AEab* is 5.0 or more&quot; (Method of coating film light resistance test) The test substrate is prepared by the same procedure as the film heat resistance test, and the micro-spectrophotometer (OlympW) is used. First 皋: 司. ". 〇 sP - SP200 》) Determine the color difference l (L * 〇: &gt;, 'a gas 1), b * (l) under the C light source. Then, the substrate was placed in a " SUNTEST CPS+" manufactured by the light-resistant ^*® Y〇SEIKI company, and left for 500 hours. After the substrate was taken out, the color difference 2 (L*(2), a*(2), b*(2)) under the c-light source was measured. Using the color difference values, the color difference change rate Δ Eab*' was calculated in the same manner as the heat resistance of the coating film, and the light resistance of the coating film was evaluated in four stages in accordance with the same criteria as the heat resistance. Table 6 shows the results of the tests for resistance (heat resistance, light resistance, and solvent resistance). Table 6 099132160 Form No. A0101 Page 101 of 154 1003010545-0 201127911 [0013]

A female case 17: TFifeijiF agent material stomach R-3

If Example _ Example 23 &quot;&quot;It Example 2Γ&quot;If Shi _Example 27&quot; -12 A Comparative Example. Factory-ib Comparative Example 10Γ -32 — — (Evaluation of Color Characteristics and Tolerance RESULTS) Right-to-red comparison of red anti-residual materials (H) to (b (2), &amp; (R-29) and (R_32) J. Fruit, using anti-stringent materials (R-n, (R-27) ) and (R-32), use: color:: anti-material (four) &gt; time comparison: brightness ^,, variegated anti-residual material (R-13) to (r_18M (r_i8), Shishi = When the pigment is composed of the anti-rice material, it is compared with the anti-surname material using the coloring agent containing the product, and the lower pair of blue resist material (R_19) is also applied to the pumping material). K~31) and ((4)) J 'When a colorant is used only as a resist material composed of a pigment, the degree of intention is lower than that of the user's colorant containing a tooth-forming product. When the anti-material (R_28) is used, the relative coloring agent (anionic component) is neutralized, so that the color is weak and has no coloring power, so that the brightness is low. Further, the anti-money material (R_imR_12) is used. (R_ 27) to (when (R,) is set to 'resistance to good results. If comparing the results obtained for anti-surname materials (R_3) to (R_6), use 099132160

R-1 R-2 - Implementation - Example Sink - -4 R-5 R-6 R-7 R-8 ~ R^9~ R-10 R-11 Example 2 _ Example 2 $ R-27 ^ .-28 -29

&quot;^ifeWT =:: to ~ within the range of rosin modified succinic acid A0101 Page 102 / 154 pages 201127911 Resin coloring composition (D-2) resist material (R_4), Better brightness and heat resistance can be achieved than when resist materials (R-3), (R_5), and (R_6) are used. When a resist material (R_27) is used, good color characteristics can be achieved, but since the molecular weight of the relative compound used in the chemical conversion is less than 250, the resistance is poor. When the resist material (R_28) is used, although it is slightly better than the resistance when the resist material (R_27) is used, as described above, the luminance is a low value. Further, when a resist material (R-29) is used, good resistance can be achieved, but the brightness is low and the color is particularly poor.

099132160 (Making color filters) On the color substrate, a shading pattern is formed: the case: black, the moment falls, and each of the red anti-surname materials is coated with a rotary coater: Qiandou (W). The red anti-material is coated to have a chromaticity of c light source: χ = {) 64 〇, y = 0.330 film thickness. In the coating film, an ultraviolet ray of 300 mJ/cm 2 is irradiated with an ultra-high pressure mercury lamp by interposing a photomask, and thereafter, an ion exchange is performed by using 〇 2% by weight of sodium carbonate in water to remove the unexposed portion. Washed with water. Further, the substrate is heated for 20 minutes to form a red filter zone* segment. Next, a green anti-material (anti-material (R_13)) was applied on the substrate by the same method as described above. The green anti-paste material is coated so that the chromaticity under the C light source becomes the film thickness of x = q.3qq and y = G · (9) q. The coating film was applied as a red anti-material for the same exposure, development, washing and firing as described above to form a green calender sheet section. Further, a blue resist material (anti-drug material (R_19)) was applied onto the substrate by the same method as described above. The blue anti-residue material is coated so that the chromaticity under the c-light source becomes the film thickness of X = G. 15Q, y = (). The 1003010545-0 form is compiled as A0101 page 103 / 154 pages 201127911 The coating film is used for the red resist material. The same exposure, development, cleaning and firing are described above to form a blue filter region. segment. A color filter was obtained as above. As described above, by using a specific halogenated product, a color filter excellent in color characteristics, heat resistance, light resistance, and solvent resistance can be obtained. &lt; <Test 2>&gt; Test 2 relates to the second aspect. In the test 2, the example corresponding to the second aspect is described as "example" and the other example is described as "comparative example". <Method for Producing Acrylic Resin Solution> (Preparation of Acrylic Resin Solution 1A) In a separate four-flask flask, 'the installation of a smart meter, a cooling tube, a nitrogen gas introduction tube, and a drop device' are used in the reaction valley. Cyclohexane, steel 〇. The temperature is increased to 80 ° C. After replacing the reaction with a nitrogen gas, the substrate is immersed in the mixture; and the η-butyl methacrylate is added dropwise over a period of 2 hours. Department, 3.4 parts of methacrylic acid, p-cumylphenol ethylene oxide modified acrylate (Aronix Μ110) 7·4 and 2, 2'-even double Isobutyronitrile 〇. A mixture of 4. After the completion of the dropwise addition, the reaction was further continued for 3 hours to obtain an acrylic resin solution having a weight average molecular weight (Mw) of 26,000. After cooling to room temperature, the resin solution was sampled to about 2 g. The mixture was heated at 180 ° C for 2 minutes to dry it, and the non-volatile component was determined. According to the non-volatile component thus obtained, propylene glycol monoethyl propylene (PGMAC) was added to the previously synthesized tree wax solution to prepare an acrylic resin solution. Ια. <Method for producing halogenated product> (halogenated product 1A) Basic blue 7) and. Zhanji 1003010545-0 099132160 The following procedure was synthesized by Victoria Blue Dye (C Form No. A0101 Page 104 / 154 pages 201127911 Acid dye (CI basic red 289 ) The composition of the composition 1A.

To a sodium hydroxide solution of 7 to 15 mol%, a xanthene-based acid dye (C.I. Basic Red 28 9) was added, and the liquid was sufficiently stirred to obtain a sodium salt thereof. After heating the xanthene acid dye sodium salt aqueous solution to 70 to 90 ° C, the Victoria blue dye (C.I. Basic Blue 7) was successively dropped thereto. Victoria blue dye can also be used as an aqueous solution. After the end of the Victoria blue dye, the solution was stirred at 70 to 90 ° C for 40 to 60 minutes in order to allow it to react sufficiently. The end point of the reaction is at the point where the filter paper drops the reaction solution without bleeding. Namely, when no liquid leakage has occurred, it is judged that a halogenated product is obtained. After cooling to room temperature while stirring, the mixture was suction filtered and further washed with water. After washing with water, a halogenated product is formed from the halogenation remaining on the filter paper, and the moisture is removed by a dryer to obtain a halogenated product of the male dolomite blue dye (CI basic blue 7) and the xanthene acid dye (CI basic red 289). The product, that is, the halogenated product 1A. (Tooth formation product 2A) A halogenated product 2A' composed of Victoria blue dye (C.I. Basic Blue 7) and rose erythric acid dye (C.I. Acid Red 5 2 : Acid Rose Bengal B) was synthesized by the following procedure. To a sodium hydroxide solution of 7 to 15 mol%, a rose-red acid dye (C.I. Acid Red 52) was added, and the liquid was sufficiently stirred to obtain a sodium salt thereof. After heating the aqueous solution of the rose red acid dye sodium salt to 70 to 90 ° C, the Victoria blue dye (C.I. Basic Blue 7) was successively dropped. Victorian blue dye can also be used as an aqueous solution. After the end of the Victoria blue dye, the solution was stirred at 70 to 90 ° C for 40 to 60 minutes in order to allow it to react sufficiently. The end point of the reaction is at the point when the filter paper drops the reaction solution and there is no liquid leakage. That is, when there is no liquid leakage, it is judged that halogen is obtained. 099132160 Form No. A0101 Page 105/154 pages 1003010545-0 201127911 Chemical product. After cooling to room temperature while stirring, the mixture was suction filtered and further washed with water. After washing with water, the toothed product remaining on the filter paper is removed by a dryer to obtain a halogenated product of Victoria Blue dye (c. I. Basic Blue 7) and Rose Red Acid Dye (CI Acid Red 52). The halogenated product 2 A. (halogenated product 3A) The halogenated product 3A consisting of Victoria blue dye (CI basic blue 7) and xanthene acid dye (CI acid red: blush) was synthesized by the following procedure at 7 to 15 mol%. To the sodium hydroxide solution, a xanthene-based acid dye (CI Acid Red 87) was added, and the liquid was sufficiently stirred to obtain a sodium salt thereof. After heating the aqueous solution of the xanthene acid dye sodium salt to 70 to 90 ° C, the Victoria blue dye (C.I. Basic Blue 7) was successively dropped therefrom. Victorian blue dye can also be used as an aqueous solution. After the end of the Victoria blue dye, the solution was stirred at 70 to 90 ° C for 40 to 60 minutes in order to allow it to react sufficiently. The end point of the reaction is at the point when the filter paper drops the reaction solution and there is no liquid leakage. That is, when the liquid has not been oozing, it is judged that the halogenated product is obtained. After cooling to room temperature while stirring, suction filtration was carried out, and further washed with water. After washing with water, the halogenated product remaining on the filter paper is removed by a dryer to obtain a halogenated product of Victoria Blue Dye (CI Basic Blue 7) and an acid dye (CI Acid Red 8 7 ), that is, halogenated product. 3A. (Halogenated product 4A) A halogenated product 4A composed of Victoria blue dye (C.I. Basic Blue 7) and xanthene acid dye (C.I. Acid Red 92: Oleander Red B) was synthesized by the following procedure. 099132160 Form No. A0101 Page 106 of 154 Page 1003010545-0 201127911

To a sodium hydroxide solution of 7 to 15 mol%, a xanthene-based acid dye (C.I. Acid Red 92) was added, and the liquid was sufficiently stirred to obtain a sodium salt thereof. That will be. After heating the aqueous solution of the acid dye sodium salt to 70 to 90 ° C, the Victoria blue dye (C. I. Basic Blue 7) was successively dropped. Victorian blue dye can also be used as an aqueous solution. After the end of the Victoria blue dye, the solution was stirred at 70 to 90 ° C for 40 to 60 minutes in order to allow it to react sufficiently. The end point of the reaction is at the point when the filter paper drops the reaction solution and there is no liquid leakage. That is, when there is no liquid leakage, it is judged that the A chemical product is obtained. After cooling to room temperature while stirring, suction filtration was carried out, and further washed with water. After washing with water, the halogenated product remaining on the filter paper is removed by a dryer to obtain a halogenated product of the Victorian blue dye (CI basic blue 7) and the xanthene acid dye (CI acid red '92). Halogenated product 4A. (Halogenated product 5A) A halogenated product 5A composed of Rose Bengal 6G dye (C.I. Basic Red 1) and a triphenylmethane-based acid dye (C.I. Acid Blue 1) was synthesized by the following procedure. To a sodium hydroxide solution of 7 to 15 mol%, a triphenylmethane-based acid dye (C.I. Acid Blue 1) was added, and the liquid was sufficiently stirred to obtain a sodium salt thereof. After heating the xanthene acid dye sodium salt aqueous solution to 70 to 90 ° C, the rose red 6G dye (C.I. Basic Red 1) was successively dropped. Rose 6G dye can also be used as an aqueous solution. After the dropwise addition of the rose red 6G dye, the solution was stirred at 70 to 90 ° C for 40 to 60 minutes in order to allow it to react sufficiently. The end point of the reaction is at the point when the filter paper drops the reaction solution and there is no liquid leakage. That is, when the liquid has not been oozing, it is judged that the halogenated product is obtained. After stirring to cool to room temperature, perform suction filtration and enter 099132160 Form No. A0101 Page 107 of 154 Page 1003010545-0 201127911 - Step by water. After washing with water, the halogenated product remaining on the filter paper is removed by a dryer to obtain rose red 6G dye (c. I. basic red 1) and triphenylmethane acid dye (C·I.. acid blue 丨The halogenated product, that is, the halogenated product 5A. (halogenated product 6A) The halogenated product 6A ° composed of rose red 6G dye (CI basic red fluorene) and triphenylmethane based acid dye (C·acid blue 93) was synthesized by the following procedure at 7 to 15 To the sodium hydroxide solution of the ear, a triphenylmethane-based acid dye (C·I. Acid Blue 93) was added, and the liquid was sufficiently stirred to obtain a salt thereof. The triphenyl ketone acid is added to the Kona salt solution to 70 to 9 (after TC 'after a few drops of 〒 〒 魏 wei wei red dye s (c.). Basic red 1). Mei 6G_ can also Use as water material: drop of rose red sputum "after the α-beam", in order to make it fully react, euphoria to g generation, mix the solution after 40 to 60 minutes. The reaction L is based on the anti-liquid and no osmosis At the time of the liquid, that is, when the liquid has not been exuded, it is judged that the product of the southernization is obtained. - The surface is mixed and placed, and after being cooled to room temperature, it is sucked; the water is washed in the step-by-step. The halogen=products remaining on the filter paper are removed by a dryer to obtain a red (4) material, a basic red color, and a tribasic acid-based acid dye (a chemical product of CI acid blue, that is, a chemical product) 6A. (Halogenated product 7A). = The program synthesis consists of Rose B red dye (CI basic violet (8) and tri-burning acid dye (U. Acid Blue 93) (4) to generate 099132160 in 7 to 15 Mo form No. 1010101 耳% of sodium hydroxide solution, page 108/total 154 page added three stupid methane acid 100301 201127911 Sex dye CI Acid Blue 1), the liquid is thoroughly stirred, thereby obtaining the sodium salt thereof. After heating the aqueous solution of the sodium succinyl sulfonate acid dye to 70 to 90 ° C, the rose red b dye is successively dropped. c. 丨. Basic purple 10). Rose red B dye can also be used as an aqueous solution. Rose red b dye • After the end of the drop, in order to make it fully react, 70 to 9 (TC, after 40 to 60 minutes The solution is carried out at the point where the reaction liquid is dropped from the paper and the liquid is not oozing. That is, when the liquid has not been oozing, it is judged that the halogenated product is obtained, and the mixture is allowed to cool to room temperature, and then suction-filtered.

' Further washing. After washing with water, the halogenated product remaining on the filter paper is removed by a dryer to obtain a halogenated red 6G dye (CI basic red 1) and a triphenyl decane acid dye d. Weidulan j). i ' Λ ν'&quot; '%-Production, ie the tooth formation product 7Α'3* % (halogenated product 8Α and 9Α)', synthesized by Rose Bengal 6G dye (C. I·Basic) Red 1) Halogenated product composed of triphenylsulfonate acid dye (CI. Acid Blue 3) | ρ; * 吾8Α. ...: 7 to 15 moles of sodium hydroxide solution. Ning, 'addition of triphenylsulfonate acid dye (C.I. Acid Blue 3), and thoroughly mix the liquid to obtain the sodium salt. After heating the aqueous solution of the triphenylmethane-based acid dye sodium salt to 70 to 90 ° C, the rose red 6G dye (c. 丨. Basic Red 1) was successively dropped. Rose red 6G dye can also be used as an aqueous solution. After the end of the drop of the dye red 6 (} dye, in order to make it fully react, the solution is stirred for 7 to 9 minutes, and the reaction is carried out for 40 to 60 minutes. The end point of the reaction is at the time when the filter paper drops the reaction liquid and there is no liquid leakage. That is, when there is no liquid leakage, it is judged that the halogenated product is obtained. After the surface is mixed and cooled to room temperature, it is filtered through 099132160 and further washed with water. After washing, it remains in the filter form No. 1010101, 109 Page / a total of 154 pages of halogenated 1003010545-0 201127911 product, using a dryer to remove water, to obtain the halogenation of rose red 6G dye (CI basic red 1) and triphenyl decane acid dye (CI acid blue 3) The halogenated product 8A is added to the halogenated product 8A of 100 parts by mass, and 30 parts by mass of rosin-modified maleic acid resin (acid price 130, MALKYD No. 32 manufactured by Arakawa Chemical Co., Ltd.) is added to add This was mixed by a kneading machine, and the mixture was set to a temperature of 120 ° C for 30 minutes, and after cooling, it was finely pulverized by a jet flow type pulverizer (IDS-2 type manufactured by Nippon Pneumatic Industries Co., Ltd.). A particle having an average particle diameter of 10 mm was obtained as the halogenated product 9A. (Halogenated product 10A) A halogenated product 10A composed of Victoria blue dye (CI Basic Blue 7) and 1-naphthoic acid was synthesized by the following procedure. To a 15 mol% sodium hydroxide solution, 1-naphthalenesulfonic acid was added, and the liquid was sufficiently stirred to obtain a sodium salt thereof. After heating the aqueous solution of sodium 1-naphthalenesulfonate to 70 to 90 ° C, The Victoria Blue dye (CI Basic Blue 7) is dripped a little bit later. The Dodrian blue dye can also be used as an aqueous solution. After the end of the Victoria blue dye, in order to make it fully react, at 70 to 90 ° C, after 40 to The solution was stirred for 60 minutes. The end point of the reaction was at the point when the filter paper was dropped and the liquid was not oozing. That is, when the liquid was not oozing, it was judged that the halogenated product was obtained, and the mixture was allowed to cool to room temperature while stirring. After filtration, it was further washed with water. After washing with water, the halogenated product remaining on the filter paper was removed by a dryer to obtain a halogenated product of Victoria blue dye and 1-naphthalenesulfonic acid, that is, a halogenated product of 10 A. (halogenated product 11A) 099132160 Form No. A0101 Page 110 of 154 Page 1003010545-0 201127911 The following procedure was used to synthesize a halogenated product 11A composed of Rose Bengal 6G dye (CI Basic Red 1) and 1-naphthoic acid. .

To the sodium hydroxide solution of 7 to 15 mol%, 1-naphthalenesulfonic acid was added, and the liquid was sufficiently stirred, thereby obtaining a sodium salt thereof. The sodium 1-naphthalenesulfonate salt solution was heated to 70 to 90 ° C, and then rose red 6G dye (C.I. Basic Red 1) was successively dropped. Rose red 6G dye can also be used as an aqueous solution. After the dropwise addition of the rose red 6G dye, the solution was stirred at 70 to 90 ° C for 40 to 60 minutes in order to allow sufficient reaction. The end point of the reaction is at the point where the filter paper drops the reaction solution without bleeding. That is, when the liquid has not been oozing, it is judged that the halogenated product is obtained. After cooling to room temperature while stirring, the mixture was suction filtered and further washed with water. After washing with water, the functional product remaining on the filter paper was removed by a dryer to obtain a halogenated product of rose-red 6G dye and 1-naphthalenesulfonic acid, i.e., halogenated product 11A. <Method for Producing Micronized Pigment> (Production of Blue Fine Pigment 1A) CIPigment Blue 15:6 ("Lionol Blue ES" manufactured by Toyo Ink Co., Ltd., relative surface area: 60 m2 / g) 200 The 1400 parts of sodium chloride and 360 parts of diethylene glycol were placed in a stainless steel 1-gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.), and mixed and stirred at 80 ° C for 6 hours. Next, the kneaded material was placed in 8 liters of warm water, and heated to 80 ° C on one side, and stirred for 2 hours to form a slurry. After repeated filtration and washing with water to remove sodium vaporized and diethylene glycol, it was dried at 85 ° C for one day and night to obtain 190 blue fine pigment 1A. The relative surface area of the blue fine pigment 1A was 80 m 2 /g. (Production of purple fine pigment 1A) CIPigment Violet 23 of the 嗔 秦 秦 系 紫色 紫色 紫色 ( ( 东 东 东 东 东 东 东 东 东 东 东 东 东 东 东 东 东 东 东 东 东 东 东 LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI LI 200 parts of a relative surface area of 75 m2/g), 1400 parts of sodium chloride, and 360 parts of diethylene glycol were placed in a stainless steel one-gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.), and mixed and stirred at 80 ° C for 6 hours. Next, the kneaded material was placed in 8 liters of warm water and heated to 80 ° C to be stirred for 2 hours to prepare a slurry. After repeating filtration and washing with water to remove sodium chloride and diethylene glycol, it was dried at 85 ° C for one day and night to obtain 190 purple fine pigment 1A. The fine surface area of the purple fine pigment 1A was 95 m 2 /g. (Formation of Red Fine Pigment 1A) 200 pieces of CI Pigment Red 254 ("IRGAZIN RED 2030" manufactured by Chiba Corporation of Japan), 1400 parts of sodium chloride and diethylene glycol of diketone 360 parts were placed in a stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.), and mixed and stirred at 80 ° C for 6 hours. Then, the kneaded material was placed in 8 liters of warm water and heated to 80 ° C to be stirred for 2 hours to form a slurry. After repeating filtration and washing to remove sodium chloride and diethylene glycol, the mixture was dried at 85 ° C for one day and night to obtain 190 red fine pigments 1A. (Formation of green fine pigment 1A) 200 pieces of CI Pigment Green 36 ("Lionol Green 6YK" manufactured by Toyo Ink Co., Ltd.), 1400 parts of sodium vaporization and 360 parts of diethylene glycol were placed in the green pigment. A 1 gallon kneader made of stainless steel (manufactured by Inoue Seisakusho Co., Ltd.) was mixed and stirred at 80 ° C for 6 hours. Then, the kneaded material was placed in 8 liters of warm water and heated to 80 ° C to be stirred for 2 hours to form a slurry. After repeating filtration and washing to remove sodium vaporized and diethylene glycol, it was dried at 85 ° C for one day and night to obtain 190 green fine pigment 1A. 099132160 Form No. A0101 Page 112 of 154 Page 1003010545-0 201127911 (Generation of color-only fine pigments) CI Pigment Yellow 150 (LAN_ESS "e_4GNj") Sodium chloride 14 〇〇 and 360 parts of diethylene glycol were placed in a stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.), and mixed and stirred at 80 ° C for 6 hours. Then, the mixed mixture was placed in 8 In liter of warm water, heat it to 8 一面 on one side. 〇, it is made into a slurry after stirring for 2 hours. Repeat filtration and water washing to remove gasification.

After sodium and diethylene glycol, it was dried at 85 ° C for one day and night to obtain 190 yellow fine pigment 1A. . :/'&quot;. (Formation of yellow fine pigment 2A) The turmeric compound is yellow pigment 丨〇w 150 (1^1^55 company "£-401〇') 20{), gasification : 1400 parts and - 360 parts of ethylene glycol were placed in stainless steel. The first 1 plus kneading machine (manufactured by Inoue Seisakusho Co., Ltd.) was mixed and mixed at 80 C for 6 hours. Then, the mixed mixture was placed in 8 liters. a. water....., one side is heated to 8_〇 °c, and it is stirred for 2 hours to form a slurry, and the Kuibu filter is filtered to remove the gasification... ^. -Sodium and After the diethylene glycol, it is 85 oz.; after drying for a day and night, a yellow fine pigment 2A of 19 〇 is obtained. <Method for Producing Pigment Dispersion> (Preparation of Pigment Dispersion (P-1A)) The following mixture is stirred. After the uniformity, the oxidized wrong beads having a diameter of 〇·5 mm were used for dispersion treatment by an IGER mill ("Elbow 1111^1〇(161]«- 25〇MKII" manufactured by IGER Japan Co., Ltd.) for 5 hours. Thereafter, The dispersion was filtered with a 5.0 mm filter to obtain a pigment dispersion (p-iA). Blue fine pigment 1A: 11. 0 part 099132160 Form No. A0101 No. 113 Buy/Total 154 Page 1003010545- 0 201127911 (CIPigment Blue 15 : 6) Acrylic resin solution 1A : 40.0 parts of propylene glycol monoethyl ether ethyl ester (PGMAC) : 4 8. 0 Resin type dispersant: 1. 0 ("KAKA4300" manufactured by Chiba Corporation, Japan" (Preparation of the pigment dispersions (P-2A) to (P-6A)) The same as the pigment dispersion (P-1A) except that the blue fine pigment 1A was changed to the pigment shown in Table 7 Pigment dispersions (P-2A) to (P-6A) were obtained. Table 7 Pigment Dispersion 韹 Colorant (Pigment &gt; P-1A Blue Fine Pigment 1A C. LPigment Blue 15:6 P-2A Purple Fine Pigment 1A C .LPigment &quot;Wolet 23 P-3A Red Fine Pigment 1A ClJPigment Red 254 P-4A Yellow Fine Pigment 1A C Work Pigment Yellow 139 P-5A Green Fine Pigment 1A C.LPigment Greea36 P-6A Yellow Fine Pigment 2A C Worker Pigment Yellow 150 <Method for Producing Red and Green Resist Material> (Preparation of Red Resist Material) After the following mixture was stirred uniformly, the dispersion was filtered through a 1. Ο/zm filter to obtain a red resist material. Pigment Dispersion (P-3A): 5 0. 0 Partial Pigment Dispersion (P-4A): 10. 0 099 132 160 114 Form Page number A0101 / 1003010545-0 Total 154 201 127 911 acrylic resin solution ΙΑ:. 11 0 Department Three hydrocarbon meth propane triacrylate: 4 2

099132160 ("Nippon Chemical Co., Ltd.") "Photopolymerization starter: 1. 2 parts (IRGACURE 907" sensitizer manufactured by Chiba Corporation, Japan (EAB-F, manufactured by Hodogaya Chemical Co., Ltd.): 0· 4 propylene glycol monoethyl ether ethyl ester (PGMAC): 2 3. 2 (modulation of green resist material) After the following mixture was stirred uniformly, the dispersion was filtered through a 1.0/zm filter to obtain green Resist material. Pigment dispersion (P-5A) : ' :45. 0 parts ~ . .v: f:i» • .1 * · ' ·: f: -%^· 5 . # Λ Pigment dispersion (Ρ-6Α) : 15. 0. Acrylic resin solution 1Α :1. 0 Partial trihydrocarbylmethylpropane triacrylate: 4. 2 ("Nippon Chemical Co., Ltd." "Nippon ΑΤΜΡΤ") Photopolymerization initiator: 1. 2 part number Α 0101 Page 115 / 154 pages 1003010545-0 201127911 (IRGACURE 907, manufactured by Chiba Corporation, Japan) Sensitizer (EAB-F, manufactured by Hodogaya Chemical Co., Ltd.) 0. 4 propylene glycol monoethyl Ethyl Ethyl Ester (PGMAC): 23.2 [Examples 4 to 5 5 and Comparative Examples 1 to 3] (Example 47: Blue coloring composition for color filters (7) - 丨8)) After the following mixture was stirred uniformly, zirconia beads having a diameter of 0 mm were used, and M- was dispersed by _, and then by an IGER mill ("Mini Model 250 MKII" manufactured by Iger Japan Co., Ltd.). Thereafter, : ....... 5. 0mm filter filtration dispersion to protect the pigment dispersion (d-!A) halogenated product '10: 11.0 acrylic resin solution ΙΑ: 40. 0 propylene glycol monoethyl Ether ethyl ester (PGMAC)

: 48.0 Resin-type dispersing agent: 1.0 part ("EFKA4300" manufactured by Sakamoto Chiba Co., Ltd.) (Examples 48 to 55 and Comparative Examples 13 to 16: Blue coloring composition for color filters (D-2A) (D-13A)) The color filter was obtained in the same manner as the blue coloring composition (D-1A) of the color filter except that the halogenated product 1A was changed to the coloring agent shown in Table 8. The sheets were colored with blue (D-2A) to (D-13A). Table 8 099132160 Form No. A0101 Page 116 of 154 1003010545-0 201127911 [0015]

M color composition D-.1A colorant

D-2A D-3A D-4A. Tooth formation product 彳 彳 彳 b product 2 卤 halogenated product 3A halogenated product 4A

099132160 Evaluation of blue coloring composition for ochre filter] The y-resistance test of the blue coloring composition (D-1A) to (D-13A) of the color filter was carried out as follows. (Method of heat resistance test) Each of the coloring compositions CD-1A) to (D-13A) was applied to a drying plate to dry (4) to 2, and the substrate was heated by 23 generations for another minute. For the formation of the colored layer $ above #板, Lee (four) differential spectrophotometer COlympus Optical Co., Ltd. "〇苏: _-all 2〇〇"), measured in C light, difference (1), 丨, into a colored layer The upper plate is 'inside, and 25q〇c has passed through the heat test for hourly heating, and the color difference 2 (L*(2), a*(2), b*(2)) under the xenon light source is further measured. Using the color difference values, the color difference change rate Δ is calculated by the following calculation formula

Eab*. Then, based on the change rate of the chromatic aberration, the heat resistance of the coating film was evaluated by the following four stages s. ◎ : AEab* is less than 1. 5 〇: AEab* is 1. 5 or more, less than 3. 〇 Form Dock No. A0101 Page 117 / Total 154 pages 201127911 △ : AEab* is 3. 0 or more, less than 5. 0 X : AEab* is 5.0 or more. Table 9 shows the evaluation results of color characteristics and heat resistance. Table 9

Coloring Composition vs. Thermal Example 47 D-1A 〇 Example 48 D-2A ◎ Example 49 D-3A 〇 Example 50 D-4A 〇 Example 51 D-5A ◎ Example 52 D-6A ◎ Example 53 D-7A ◎ Example 54 D-8A ◎ Example 55 D-9A ◎ Comparative Example 13 D-10A X

Comparative Example 14 D-11A X Comparative Example 15 D-12A X Comparative Example 16 D-1SA X

[Evaluation Result of Heat Resistance] When the coloring compositions (D-1A) to (D-9A) containing a specific halogenated product as a coloring agent were used, good results were obtained for heat resistance. Then, particularly good results were obtained when the dentured product obtained from the rosin dye was used. On the other hand, when a dye-containing and colorless component of the same composition or a dye-containing coloring composition (D-10A) to (D-13A) is used, the color difference changes by more than 5, and the heat resistance is relatively Lower. From the above results, it is understood that the coloring composition containing a specific halogenated product is in a property of achieving good heat recovery. [Examples 56 to 67 and Comparative Examples 17 to 21] (Example 56: Resist material (R-1A)) 099132160 Form No. A0101 Page 118 of 154 Page 1003010545-0 201127911 After mixing the following mixture The dispersion was filtered with a filter of i.0/zm to obtain an alkali-developable resist material (R-1A). Coloring composition (D-l A): 60.0 parts Acrylic resin solution 1A.11. 0 Department of three-smoke methyl propylene entertainment • triacrylate: 4. 2

(: 〇 ("Nippon Nakamura Chemical Co., Ltd." "NK ester ATMPT") Photopolymerization initiator: 1.2: ("IRGACUM 907" manufactured by Chiba Corporation, Japan] Sensitizer ("έΑΒ"" by Hodogaya Chemical Co., Ltd.) : 0.4 propylene glycol monoethyl ether ethyl ester (PGMAC): 23.2 (Example 5 7 to 6 7 clothing Comparative Example 17 to g '1 .: ·! 疋 _ material (r _ 2 a ) to ( R-17A)) In addition to the one shown in Table 1U, there are &amp;,, and defying pigment dispersions, and the coloring composition is replaced, as shown in Table 10, and the other materials are combined with the resist material (R). - 1A) The development-type anti-retaining agent material (K-17A) was obtained in the same manner. Further, the 'in-partial anti-material> used a pigment as a coloring agent, and when the entire resist material was 100 parts, the coloring composition was used. And / or the total amount of the pigment dispersion is 60. Table 10 099132160 Form No. A0101 Page 119 / 154 pages 1003010545-0 201127911 Anti-blocking material heat-resistant material #色色组成物或戗料分散« The amount of the coloring composition or the pigment dispersion of the ship is adjusted to the coloring composition or the pigment dispersion. The amount of the coloring composition or the pigment dispersion tt Example 56 R-1A D-1A Part 60 - - Example 57 R-2A D-2A 60 parts _ a - - Example 58 R-3A D-3A 60 parts _ one one - ★ Example 59 R- 4A D-4A 60 parts _ _ - - Example 60 R-5A D-5A 60 parts _ one-one - Example 61 R-6A Dh5A 60 parts one - - Example. 62 R-7A D-7A 60 _一一 - Example 63 R-8A D-8A 60 parts _ _ — - Example 64 R-9A D-9A 60 parts _ - - Example 65 R-10A D-1A 50 parts P-1A ίο 1 - Example 66 R-11A IMA 57-i P-2A 3-part 1 - - Example 67 R-12A D-1A 45-part P-1A 12-part P-2A 3-part comparative example 17 R-13A D -10A 50 parts D-11A 10 parts - - - Comparative example 18 R-14A D-10A 50 parts D-13A 10 parts - _ _ Comparative example 19 R-15A, D-12A 50 parts D-11A 10 parts - - ΛComparative example 20 R-16A D-11A 50 parts D-13A 10 parts _ - Comparative example 21 R-17A P-1A 50 parts P-1A 10 parts - - [0018] [Evaluation of anti-# agent materials] The following method was carried out to evaluate the color s (lightness) of the resist material, and to evaluate the resistance (heat resistance, light resistance, and solvent resistance) of "- 丨^. (Color characteristic evaluation) On the glass substrate, the resist material is applied s>, in which the anti-surname material (R-1A) to (R-17 winter) is coated as [the chromaticity under the light source becomes • * t 5^ 1 x = 0. 150, y = 〇. 060 film thickness. The substrate such as Jiang Sai is heated at 230 t for 20 i &quot; minutes to form a colored layer on the substrate. Thereafter, the luminance γ of the substrate on which the colored layer was formed was measured by a microscopic spectrophotometer (r〇SP-SP200 manufactured by Olympus Optics Co., Ltd.). (Method of coating film heat test) On the transparent substrate, the anti-side material was applied as a dry film to a film having a specific pattern of 25 Å, and the film was exposed by an f-line. The developing solution is applied to the coated mist, and the hardened portion is removed to thereby form a desired pattern. Thereafter, in the baking (four), (four) generation of the hour of heating 099132160 form number A0101 page 120 / a total of 154 pages 201127911. After cooling, 'Using a microscopic spectrophotometer (MSP-SP200 manufactured by 01ympus Optics Co., Ltd.)' to measure the color difference 1 of the obtained coating film under c light source (L*(U, a*(l), b*(l )). Thereafter, it is used as a heat resistance test in an oven at 250 ° C for 1 hour, and further measured in the light, the color difference 2 (L*(2), . The difference 'the chromatic aberration change AEab* is calculated by the following calculation formula. Then, based on the chromatic aberration change rate, the following four stages are used to evaluate the heat quality of the coating film.

◎ : AEab* is less than 1.5. 〇: △ Eab* is 1. 5 or more, less than 3. 〇 △ : ΔΕ &amp; 13* is 3. 0 or more, + is 5: 〇X: AEab★ is 5_0 or more &gt; (Method of coating film resistance and light resistance test) ' • · .. : . : . The test substrate was prepared by the same procedure as the film heat resistance test, and a microscopic spectrophotometer (Ospus Optics Co., Ltd. "0SP - SP200" was used. 》Measure the color difference 1 (1^(1:), b*(l)) under the C light source. Then, the substrate was placed in a light-resistant test ("SunTEST CPS+" manufactured by T0YQSEIKI Co., Ltd.) and left for 500 hours. After the substrate was taken out, the color difference 2 (L*(2), a*(2), b*(2)) under the c-light source was measured. Using the color difference values, the color difference change rate Δ Eab* was calculated in the same manner as the heat resistance of the coating film, and the light resistance of the coating film was evaluated in four stages in accordance with the same criteria as the heat resistance. (Method of Coating Solvent Resistance Test) A test substrate was prepared by the same procedure as the coating film heat resistance test, and the color difference under the C light source was measured by a microscopic spectrophotometer ("〇sp - SP200" manufactured by Olympus Optical Co., Ltd.). (L*(1), a*(l), b*(l)). Thereafter, the substrate was impregnated with N-mercaptopurinone over 30 minutes. Take out the base 099132160 Form No. A0101 Page 121 / 154 page 1003010545-0 201127911 After the board, measure the color difference 2 under the c light source (L*(2), a*(2), b*(2)). Using the color difference values, the color difference change rate Δ Eab* was calculated in the same manner as the heat resistance of the coating film, and the solvent property of the coating was evaluated in four stages based on the same criteria as the heat resistance. Table 11 shows the results of the tests for resistance (heat resistance, light resistance and solvent resistance). Table 11

Example 67 fcb Comparative Example Comparative Example 18 Comparative Example 19 Comparative Example 20 Comparative Example 21 _ R-12A R-13A R-14A .R-15A R- 16A R-17A 0.150 0.150 0.150 0.150 0.150 η 1 Present π 0.060 0.060 0.060 0.060 &amp;.060 6.8 7.3 7.1 • 7.3 7.2 ◎ XXXX ◎ XXXX ◎ XXXX v.UOU 5.9 ◎ ◎ ◎ [0019] [0020] (Evaluation results of color characteristics and tolerance) Using tooth products and dyes The resist material (R_U) to (r_15a) is compared with the case where the anti-surname material composed of the coloring agent is only used as a pigment, and the redundancy is a higher value. Then, a resist material (R-9A) is used. At the time of 'the brightness is particularly high. It is presumed that this is because the dispersibility and solubility of the surface of the colorant are resin-treated and the solubility is improved, and high brightness can be obtained. Also, when using the resist material (R_1A) to (R-12A) Good results were also obtained for the heat resistance. In the case of the halogenated product of 099132160 Form No. A0101, page 122, pp. 154, 1003010545-0, 201127911, the weaving product was obtained, and good results were particularly obtained for heat resistance. Furthermore, the use of colorants is only resistant to pigments. The agent material (Ry is a 'good result for heat resistance. In contrast, a halogenated product containing a dye and a colorless relative component, or a colored composition containing a dye as a colorant (R-13A) to (R) is obtained. -J6A), the chromatic aberration changes over $ • The heat resistance is relatively low. From the above results, it is understood that the resist material containing the specific i-formation product exhibits excellent performance in both color characteristics (brightness) and weather resistance.

[Examples 68 to 79 and Comparative Examples 22 to 26] A color filter was produced by the following method. (Example 68: color filter (CF-1')), ,, ^ :t , , - - forming a blackout on a color substrate fortunately, then using a spin coater to coat red Resist material. The 'red' color resist material is applied such that the chromaticity under the C light source becomes the film thickness of x = 〇. 640, y = 〇 · 330. The coating film was used as an intermediate mask to irradiate 3 〇〇mJ/em2t of ultraviolet rays with an ultrahigh pressure mercury lamp. Thereafter, an alkali developing solution consisting of 0. by weight of an aqueous solution of sodium sulphate was used for the spray, and the exposed portion was removed and washed with ion-exchanged water. Further, the substrate was heated at 230 t for 20:, and a red filter segment was formed. Next, a green resist material was applied on the substrate by the same method as described above. The green resist material is applied such that the chromaticity under the C light source becomes a film thickness of x = 0.300 and y = 0.60. The coating film was applied to the red resist material as described above for exposure, development, washing and firing to form a green filter segment. Further, a blue resist material was applied onto the substrate by the same method as described above. The blue resist material is applied such that the chromaticity under the C light source becomes x = 〇 150, y = 〇. 〇 6 film 099132160 Form No. A0101 Page 123 / 154 pages 1003010545-0 201127911 Thick. The coating film was applied as the red resist material as described above for the same exposure, development, washing and firing to form a blue filter segment. A color filter (CF-1A) was obtained as above. (Production of Liquid Crystal Display Device) On the color filter (CF-1A), an electrode formed of indium tin oxide (1T0) was formed thereon to form an alignment layer composed of polyimide. Further, a TFT array and a pixel electrode were formed on one surface of a separately prepared glass substrate, and an alignment layer composed of polyimide was formed thereon. Next, a frame-like pattern having a path connecting the inside and the outside of the frame is formed by a sealant on one surface of the glass substrate on which the electrode is provided. Next, the electrodes are bonded to each other with the spacers interposed therebetween in such a manner that the electrodes face each other. -# '*一·': Ten: 'Next' in the cell thus obtained (the inner space of ce ,, the liquid crystal composition is injected from the previous passage. After sealing the passage, the polarizing plate is adhered to the double side of the cell to obtain the liquid crystal display) Panel. Thereafter, the liquid crystal display device is completed by combining the liquid crystal display panel and the backlight unit. : ^ ^ (Examples 69 to 79 and Comparative Example 22 to: Color Filter (CF-2A) to (CF-17A) )) A color filter (CF-2A) is produced separately from the color filter (CF-1A) and the above liquid crystal display device except that the resist material is changed to the resist material shown in Table 6. ) to (CF-17A). Further, the light emission spectrum of the backlight used is shown in Fig. 1. [Evaluation of color filters (CF-1A) to (CF-17A)] Color display on the above liquid crystal display device The image was measured by a microscopic spectrophotometer ("sp-SP200" manufactured by Olympus Optics Co., Ltd.) corresponding to red 099132160 Form No. A0101 Page 124 / 154 pages 1003010545-0 201127911 Color, Green, and Blue Color Filters The brightness of the area. Then, the brightness of the white display is obtained from its brightness. The brightness of the white display is shown in Table 12. Table 12 Color Filtered Moon Blue Resist Material Filter Section, Electric White Display Brightness Red Green Blue Example 68 CF-1A R-1A 20.3 56.9 7.2 28.1 Example 69 CF-2A R-2A 20.3 56.9 7.1 28,1 Example 70 CF-3A R-3A 20.3 56.9 7.3 28.2. Example 71 -CF-4A R-4A 20.3 56.9 7.2 28.1 Example 72 CF-5A R-5A 20.3 56.9 7.2 28.1 Example 73 CF-6A R-6A 20.3 56.9 7.1 28.1 Example 74 CF-7A R-7A 20.3 56.9 7.3 28.2 Example 75 CF-8A R-8A 203 56.9 7.2 28.1 Example 76 CF -9A R-9A 20.3 56.9 7.5 28.2 Example 77 CF-10A R-10A 203 56.9 6.9 28.0 Example 78 CF-11A R-11A 20.3 56.9 6.7 28.0 Example 79 CF-12A -R-12A 20.3 56.9 6.8 28.0 Comparison Example 22 CF-13A R-13A 20.S 56.9 7.3 28.2 Comparative Example 23 CF-14A R-14A 20.3 56.9 7.1 28.1 Comparative Example 24 CF-15A R-15A 20.3 56.9 7.3 28'2 Comparative Example 25 CF-16A R- 16A 203 56.9 7.2 28.1 Comparative Example 26 CP-17A R-17A 20.3 56.9 5'9 27.7

In the blue filter section of the color filter (CF-17A), a combination of a phthalocyanine pigment and a dioxin-based pigment which have been conventionally used in such a filter section are used. Further, in the blue color filter section of the color filters (CF-1A) to (CF-12A), a specific halogenated product is used. Compare color filters (CF-1A) to (CF-12A) and color filters (CF-17A) to color filters (CF-1A) to (CF-12A) for blue and white Each of them obtained a higher brightness than the color filter (CF-17A). Further, in the blue filter sections of the color filters (CF-13A) to (CF-16A), a combination of a toothed product of a dye and a colorless component and a dye is used. Therefore, although the brightness is high, the resistance is relatively low. ^9999132160 Form No. A0101 Page 125 of 154 Page 1003010545-0 201127911 As above, color characteristics (straightness) and heat resistance can be obtained by using a specific halogenated product. Blue calender segment with good properties, light resistance and solvent resistance. &lt; <Test 3>&gt; Test 33 relates to the third aspect. The example in which the test 3' corresponds to the third aspect is described as "example", and the other example is described as "comparative example". <Method for Producing Acrylic Resin Solution> (Preparation of Acrylic Resin Solution 1B) In a separate four-piece flask, a thermometer, a cooling tube, a nitrogen gas guide, and a stirring device were placed in the reaction vessel to place cyclohexanone 7 〇. . Warm up to 80 ° C, change the reaction container with nitrogen shyness: front, turn down the tube to slow down 2] when dropping η-butyl methyl acrylate: 13⁄4. 3 parts *, '2 - by ethyl 6 parts, thioglycol 4. 3#, p-cumyl epoxide Ethylene epoxide modified acrylate ("AR〇NU Μΐι〇'" manufactured by Toagosei Co., Ltd.) 7. 4 and 2, 2 '-Azobisisobutyronitrile 〇. 4 parts of the mixture. After the end of the drop, 'further continue the reaction for 3 hours': Obtain an acrylic resin solution with a weight average molecular weight (Mw) of 26000. The sputum solution was sampled after room temperature. About 2g. It is 〇 苈 苈 苈 苈 〇 〇 〇 〇 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' 测定 测定 测定 测定 测定 测定 测定 测定 测定 测定 测定 测定 测定 测定Non-volatile to 8% to 20% by weight 'Prepared into acrylic resin solution 1B. (Preparation of acrylic resin solution 2B) In a separate flask equipped with a thermometer, a cooling tube, a nitrogen gas guiding tube and a device, the injection ring was injected. _7, this temperature is raised to ^. After replacing the gas in the flask with nitrogen, after dripping the tube through the 20 parts of methacrylic acid were added in 2 hours, and the modification of cumyl epoxide was carried out. 099132160 Page 126 of 154

Form No. A0101 3 V 201127911 c ο 099132160 1003010545-0 Sub 2 = "__〇" ~ (4) Small fluorenylmethyl (10) bismuth 5 Mixture of U3 parts. After the completion of the dropwise τ, the copolymer was dissolved in an even = hour, and the reaction was carried out. Γ: Nitrogen gas was supplied into the flask, and the total of the copolymer solution was placed in a dry air for 1 hour. Thereafter, cool to the room

' 7〇C was added dropwise 2-methyl-endo-oxyethyl isophthalate (a mixture of Karenz M〇I and hexa-6) made by Showa Denko Co., Ltd. for 3 hours. 5° diced dibutyl laurate The == solution was sampled by about 2 g. It was heated in 18 passages for 20 minutes to make the determination of the non-volatile components honest, such as the non-volatile component contained in the _! The previously synthesized tree $ (four) (10) secret ingredient became 20% by weight, Modulated into a propylene tree, the lion is dissolved. In addition, the average molecular weight (4) of the __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The temperature of the mixing device is increased to ah. After replacing the gas with the gas, the methyl propylene is added to the tube by dropping the tube for 2 hours, and the acetaminophen is modified with acetophenone. Company's "ARONIX Μ110") 2 〇, methyl propyl methacrylate 45, 2 _ ethyl methyl acrylate vinegar 8. 5 and 2, 2 ' azobisisobutyronitrile 1. 3 After the completion of the dropwise addition, the reaction was further continued for 3 hours to obtain a copolymer solution. The soil was supplied with nitrogen gas to the flask. The total amount of the copolymer solution was poured into the dry air for 1 hour while stirring. Thereafter, it was cooled to room temperature, and the form number Α0101, page 127 of 154 pages 1 (201127911 scratching (four) was dropped 2 基 base (four) saki, laurel Dibutyltin hydride, 〇8 and cyclohexanone _ part of the resin is melted (10) g. It will be fine 8 hearts. It will be reduced by '敎 forwarding component. «This is a non-tr component containing the resin The solution is added; the hair component is made up to 20% by weight, and is prepared into an acrylic resin. The resin is dissolved in the resin and is included in the tree. The number of trees is 19000. Ding knives * * Uw) C aggravated acid · Shu Li 曰 > Valley 4 B modulation) In a separate type of burning with a thermometer, a cooling tube, and a nitrogen gas guide, the ring is injected into the ring, and the temperature is raised to the state. After replacing the gas in the flask with nitrogen,牡 管 细 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基a mixture of acetic acid lysate 2, methyl propyl hydrazide 25 and 2, 2' azobisisobutyronitrile bismuth (tetra). The tre was further reacted to a small amount of 3, and then a solution obtained by dissolving L0 portion of azobisisobutyronitrile in 5 parts of cyclohexyl steel was added to the solution, and the reaction was further carried out at 100 ° C for a few hours. Thereafter, the inside of the reaction vessel was replaced with air, and 93 parts of acrylic acid (100% of glycerol groups), 0.5 parts of trimethylaminophenol, and 1 part of hydroquinone oxime were placed in the container. C continued the reaction for 6 hours, and the reaction was completed when the acid value of the solid component became 〇. 5. Next, in the solution thus obtained, 19.5 parts of the tetrahydrobenzene acid needle (1% by weight of the generated hydroxyl group) and 0.5 parts of triethylamine was reacted at 120 ° C for 3.5 hours to obtain an acrylic resin. 099132160 The resin solution was sampled at about 2 g. This was dried by using 1801: heating for 20 minutes to form a sample No. A0101, page 128 / page 154 ιηη 201127911, and the non-volatile content was measured. Based on the non-volatile component content thus obtained, cyclohexanone was added to the previously synthesized resin solution to have a non-volatile component of 20% by weight to prepare an acrylic resin solution 4B. Further, the weight average molecular weight ' of the acrylic resin contained in the resin solution 4B' is 19,000 〇 <Method for producing a halogenated product> (halogenated product 1 B ) The following procedure is used to synthesize a rose red 6GCP dye (CI basic red 1) ) and 咕

099132160 ton acid dye (CI acid red 289) composed of halogenated product 1B 0 at 7 to 15 mol% of sodium hydroxide solution t widely added but 嗲 ton acid dye (CI acid red 289) 'full interference will After the liquid is heated to 70 to 90 ° C, 'after a little bit ^ drop of the soul red> pillow p dye (c,]. Basic red 1.). Rose red 6G_CP dye can also be used as an aqueous solution. After the drop of the Essence Red 6GCP dye, in order to make it fully react, stir the 1|Τ solution at 70 to 90 ° C for 40 to 60 minutes: the end point of the heart reaction is the dropping of the reaction solution on the filter paper. When the liquid is infiltrated with Zhitai. That is, when there is no liquid leakage, it is judged that a halogenated product is obtained. After allowing to cool to room temperature on one side, it was suction filtered and further washed with water. After washing with water, the product was removed from the filter paper, and the water was removed by a dryer to obtain a halogenated product of Rose Bengal 6GCP dye (CI basic red 1) and sputum spray acid dye (c. I. Acid Red 289). 'Immediately halogenated product (halogenated product 2Β) The following procedure was used to synthesize a halogenated product 2β consisting of a rose scented red 6GCP dye (c.〗. basic red 丨) and an acid rose red (C·I · acid k52) . Add acid rose red to 7 to 15 mol% sodium hydroxide solution Form No. Α0101 Page 129 of 154 201127911 (C. I. Acid Red 52) 'Agitate the liquid well. After heating the solution to 7 Torr to 90 ° C, it was dripped a few times with Rose Bengal 6GCp dye (c. [Basic Red 1]. Rose 6GCP dye can also be used as an aqueous solution. After the end of the drop of the rose red 6GCP dye, the solution was stirred for 7 to 9 〇 C for 40 to 60 minutes in order to allow it to react sufficiently. The end point of the reaction is at the point where the filter paper drops the reaction solution without bleeding. That is, when there is no liquid leakage, it is judged that a halogenated product is obtained. The mixture was allowed to cool to room temperature while stirring, and then suction-filtered and further washed with water. After washing with water, the water was removed from the filter paper by a dryer to obtain rose red 6GCP dye (C·I. Basic red). 1) 舆acid rose red (c. 丄 acid red 52) . :'... .............................. Draw the product 2] &amp; Human (halogenated product 3B) A halogenated product 3B composed of rose red 6Gcp dye (c. table red 丨) and ruthenium (C. I. acid red 87) was synthesized by the following procedure. Eosin (C.I. Acid Red 87) was added to 7 to 15 mol% of the sodium oxyhydroxide solution to sufficiently mix the liquid. After heating the solution to 7 〇 to 9 ,, it was dripped a little bit of Rose Ghost Red 6Gcp^^ (c. 丨. Basic Red 丨). Rose 6GCP dyeing can also be used as an aqueous solution after the end of the drop of 1 rose red 6GCp dye. In order to make it fully react, it is disturbed by 7〇 to 9〇, and the solution is scrambled for 4〇 to 60 minutes. The end point of the reaction is at the point when the filter paper drops the reaction solution and there is no liquid leakage. That is, when no liquid leakage has occurred, it is judged that a halogenated product is obtained. After cooling to room temperature while stirring, the mixture was suction filtered and further washed with water. After washing with water, the toothed product remaining on the filter paper was removed by a dryer to obtain a halogenated product of Rose Bengal 6GCp dye (C.I. Basic Red 1) and Eosin (CI Acid Red 87), that is, halogenated product. Product 3B. 099132160 Form nickname A〇l〇l Page 130 of 154 201127911 (Suihua product 4B) = The following procedure was synthesized by Rose Red 6Gcp dye (c. I Basic Red 1) and C. Ik'l· The halogenated product 4B composed of raw red 388. =15 (four) of the oxyhydrogen solution t, add mosquitoes to red, h to mix the ". (4) Inspection plus _? Q butterfly. q, in its own - some people drop the rose red 6GCP dye (c. 丨, 6GCP dye can also be used as an aqueous solution =) rose red, in order to make it fully react, (four) ^ dyed drops

C [Ο 099132160 minutes to mix the solution. The end point of the reaction; calendar: 4 off the coffee without liquid. That is, (4) the reaction liquid is formed. - Face mixing - face to cool, _ when entering into the break to get the water from the metamorphosis - step. After washing with water, take the transition from Zheng Zheng ', take the dryer to remove the water, and obtain the colloidal product.

This red Chen is difficult to... I hate I. The product 'that is, the halogenated product 4B (halogenated product 5B) ::; , i adopts the following light-sequence synthesis by rose red B mulberry

Acid dye (C. I: acid red 28 to 仏, basic purple 1G) and 咕 mock (1) "% of the oxyhydrogen solution solution handle to the product I acid red 289", fully mix the liquid to survive After the dye 70 is applied to the crucible, it may be used as an aqueous solution after a slight drop of it. After the end of the drop of the dye ^ dye, in order to make it fully react, (4) after 4 to 6 minutes, the solution. The end point of the reaction is the point at which the reaction liquid is dropped by the woven fabric and the liquid is not oozing. When the liquid has not been oozing, the chemical product is obtained. - Face _ - Face chilly to room temperature, enter Form No. A0101 Page 131 / 154 pages &amp; 1〇〇3〇1〇545~〇 201127911 Take the filter and wash it in step. After washing with water, the halogenated product remaining on the filter paper is dehydrated by a dryer to obtain a halogenated product of rose bengal dye (CI basic violet 1) and xanthene acid dye (c. acid red 289). Halogenated product 5B. (Halogenated product 6B) The following procedure was used to synthesize a halogenated product consisting of a rose scented red B dye (c.) and a basic dye (acid oleander red: c·j•acid red 92). Product 6B.

An acidic oleander red ρβ dye (C·I. Acid Red 92) was added to a 7 to 15 mol% sodium hydroxide solution to sufficiently stir the solution. The solution is heated to a temperature of 70 to 9 (after Tc, in which it is successively simmered in a red Β Β dye (c丨. basic purple 10). Rose red B dye dye can be used as an aqueous solution. After the end of the drop of the red B dye, 'for: to make it fully react, take 7 () to (4). 'The solution is 40 (four) minutes. The reaction turns _ when the reaction solution is dripped and the liquid has no liquid leakage. When the liquid has not been oozing, the i-formation product is obtained. The surface of the surface is 'cooled to room temperature, and then suctioned and filtered at room temperature'. The step is washed with water. After the forest: after the residue is formed on the crepe paper The product 'Lei Boots' secret, obtained the halogenated product of Meishe B_t (C. I·Basic Violet 10) and Acidic Oleander Red (d. Acid Red 92), ie, the chemical product 6B. Product 7B) A functional product 7B composed of Rose Bengal G dye (cj basic (4)) and a pout-type acid dye (CI Acid Red 289) was synthesized by the following procedure: 099132160

The xanthene-based acid dye (C.I. Acid Red 289) was sufficiently stirred in a 7 to 15 mol% sodium hydroxide solution. The solution was heated to 7 to 9 Torr. (: After that, in a few drops of Rose Red G dye (c I Form No. A0101, I32 page / Total IS4 page 1〇〇3〇1〇545_〇201127911 Red 8) ° Rose Red G dye can also be used as The aqueous solution is used. After the drop of the rose red G dye is not finished, the solution is stirred at 70 to 90 rpm for 40 to 60 minutes in order to allow it to react sufficiently. The end point of the reaction is at the point when the filter paper drops the reaction solution without bleeding. In other words, when the liquid has not been permeated, it is judged that the toothed product is obtained, and the mixture is allowed to cool to room temperature while stirring, and then suction-filtered and further washed with water. After washing with water, the halogenated product remaining on the filter paper is dried. The machine removes moisture and obtains rose red G dye (CI basic red 8) and xanthene acid dye (c. L acid red 289).

Halogenated product 'is a halogenated product (halogenated product 8B)

099132160 In 1 〇 0 massification product 13⁄4, Mengjia # will be grass maleic acid resin (acid price 13 〇 mgK 〇 H / g, waste ^ ^ number | ^ greasy 〇 1) n〇.32 ) 3 〇 quality department, pressurizing and pinching - machine to ten. This mixing set the material temperature to 12 Torr. (:, after 3 minutes. After cooling, it was finely pulverized by a mouth jet flow pulverizer (IDS_2 type manufactured by Nippon Pneumatic Co., Ltd.) to obtain a flat product as a southern product 8B: 'v ～ 4 ... 2 / : \ <Production method of micronized pigments> (Production of red fine pigment 1B) 200 parts of di-pyrrolopyrrole-based red pigment c. ι .Pigment Red 254 ("IRGAZIN RED 2030" manufactured by Chiba Corporation, Japan) 1400 parts of sodium and 36 parts of diethylene glycol were placed in a stainless steel kneading kneader (manufactured by Inoue Seisakusho Co., Ltd.) to mix and stir at 8 (TC) for 6 hours. The mixed mixture was placed in a temperature of 8 liters. In the water, one side is heated to go, and the mixture is stirred for 2 hours to form a slurry. After repeated filtration and washing with water to remove sodium and diethylene glycol, it is dried at 85 ° C for one day and night, and is obtained 133 pages / total Page 154 Form nickname A0101 1003010545-0 201127911 Known 190 red fine pigments. The relative surface area of red fine pigments is 65m2/g 〇' (formation of red fine pigments) c. L pigment Red 254 200 pieces of "IRGAZIN RED 2030" manufactured by Chiba Corporation of Japan, 1400 parts of sodium chloride and 360 parts of diethylene glycol were placed in a stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.) to mix and stir at 80 ° C for 6 hours. Then, the mixture was placed in 8 liters of warm water and heated to 80 C' while stirring for 2 hours to form a slurry. After repeated filtration and water washing to remove sodium chloride and diethylene glycol, Drying at 85 昼 for a day and night, obtaining 19 red fine pigments. ^Red lifting fine: material, the relative surface area is 65m2 / g. ', _ 4 浔 ( (magenta fine pigment 1 β generation will be quin c. I pigment: 122 (History of HOSTAPERM Pink E by Clariant), 200 parts of sodium chloride, and 1-2 parts of Teflon. Prepared by the manufacturer, and mixed with 8 (rc for 6 hours). Next, the mixture was weighed and the surface was heated to 80 C. The mixture was stirred for 2 hours to form a slurry. Repeated filtration and washing. After removing sodium chloride and diethylene glycol, drying at 85 ° C Day and night, 190 parts of magenta fine pigments were obtained. The relative surface area of magenta fine pigments was 90 m2/g. (Production of green fine pigment 1B) CIPigment Green 36 of green pigments (made by Toyo Ink Manufacturing Co., Ltd.) "Lionol Green 6YK") 200 parts, 1400 parts of gasification and 360 parts of diethylene glycol are placed in the unrecorded steel 1 plus kneading 099132160 Form No. A0101 Page 134 / 154 pages 100 201127911 Machine (manufactured by Inoue Manufacturing Co., Ltd.) ' Mix and mix at 8 0 C for 6 hours. Next, the mixed batch was placed in 8 liters of warm water, and the surface was heated to ° C, and stirred for 2 hours to form a slurry. After repeating filtration and washing to remove sodium vaporized and diethylene glycol, drying at 85 ° t - day and night to obtain 190 green fine pigment 1B. The relative surface of the green fine pigment 1B has a product of 75 m 2 /g. (production of blue fine pigment 1B)

In the Pig 系 蓝色 蓝色 Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig Pig (manufactured by Inoue Seisakusho Co., Ltd.), stirring at 8:00 for 6:00 hours. Then, the mixture was placed in 8 liters of warm rice and heated to 8 (rc, while stirring for 2 hours) The system was indiscriminately recovered, filtered and washed with water to remove sodium and diethylene glycol, and dried at 85 ° C for one day and night to obtain a 19-inch blue fine pigment 1B. The relative surface area of the blue fine pigment 16 was 80 m 2 / g. "One U (the formation of cyan fine pigment 1B) -... The CI of the succulent blue pigment is ME1:; BiUe 15 : 3 ("Li_i Blue FG-7351" by Toyo Ink Co., Ltd.), The gasification hydrazine and the ethylene glycol 360 part were placed in a 1 gallon kneading machine (manufactured by Inoue Seisakusho Co., Ltd.), which was not made of steel, and mixed and stirred at 8 ° C for 6 hours. Then the σ compound was put into 8 liters. In warm water, it is heated to the surface and stirred for 2 hours to form a slurry. Repeat filtration and washing After degassing sodium and monoethylene glycol, it was dried at 85 ° C for one day and night to obtain the cyan fine pigment 1B of Cang Shao. The relative surface area of cyan fine pigment 1B was 85 m 2 /g. 099132160 Table No. A0101 Page 135 / 154 pages ^03010545-0 201127911 (Formation of yellow fine pigment 1B) CI Pigment Yellow 139 ("IRGA For Yellow 2R-CF", manufactured by Chiba Corporation, Japan) 50 parts, chlorine 500 parts of sodium and 250 parts of diethylene glycol were placed in a stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.), and mixed and stirred at 120 ° C for 8 hours. Then, the mixture was placed in 5 liters of warm water. The mixture was heated to 70 t and stirred for 1 hour to form a slurry. After repeated filtration and washing with water to remove sodium chloride and diethylene glycol, it was dried at 80 ° C for a day and night to obtain 490 parts of yellow. Fine pigment 1B. The relative surface area of the yellow fine pigment 1B is 80 m 2 /g. (Formation of yellow fine pigment 2B) 200 parts of CI Pigment Yel low 150CLANXESS "E-4GN", which is a yellow pigment of the recording compound, is gasified. Sodium 1400 and diethylene glycol 360 A stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.) was placed, and the mixture was stirred and mixed at 80 ° C for 6 hours. Next, the mixed agitated material was placed in 8 liters of warm water, and heated to 80 ° C, and stirred for 2 hours to form a slurry. After repeating filtration and washing with water to remove sodium chloride and diethylene glycol, it was dried at 85 ° C for one day and night to obtain 190 yellow fine pigment 2B. The yellow fine pigment 2B has a relative surface area of 70 m 2 /g. (Formation of the purple fine pigment 1B) 200 pieces of CI Pigment Violet 23 ("LIONOGEN VIOLET RL" manufactured by Toyo Ink Co., Ltd.), 1400 parts of sodium chloride, and 360 parts of diethylene glycol were placed. The stainless steel one-gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.) was mixed and stirred at 80 ° C for 6 hours. Then, the kneaded material was placed in 8 liters of warm water and heated to 80 ° C to be stirred for 2 hours to form a slurry. Repeated filtration and water 099132160 Form No. A0101 Page 136 of 154 1003010545-0 201127911 After washing to remove sodium chloride and diethylene glycol, it was dried at 85 ° C for one day and night to obtain 190 purple fine pigments 1B. The relative surface area of the purple fine pigment 1B was 95 m 2 /g. <Method for Producing Pigment Dispersion> (Preparation of Pigment Dispersion (P-1B)) After mixing the following mixture uniformly, a cerium oxide bead having a diameter of 0.5 mm was used, and an IGER grinding machine (IGER Japan &amp; 3f "MiniModel M" was used. -250 MKII"), dispersed for 5 hours. Thereafter, the dispersion was transferred with a filter of 5.0 mm to obtain a pigment dispersion (P-1B). Red fine pigment 1 _B : 11.0 (C.I.Pigment Red 254) Acrylic resin solution IB : 40. 0

Propylene glycol monoethyl ether ethyl ester (PGMAC): 48. 0 resin type dispersant - 3⁄4^ : 1. 0 # ("EFKA4300" manufactured by Sakamoto Chiba Co., Ltd.) (Pigment dispersion (P-2B) to (P- Preparation of 8B)) In addition to changing the red fine pigment 1B to the pigment shown in Table 13, the pigment dispersions (P-2B) to (P-8B) were obtained in the same manner as the above pigment dispersion (P-1B). . Table 13 099132160 Form No. A0101 Page 137 of 154 1003010545-0 201127911 Pigment Dispersion Colorant (Pigment) P-1B Red Micro 1® Pigment 1B CXPigment Red 254 P-2B Magenta Fine Pigment 1B C.LPigmentRed 122 P -3B Green Fine Pigment 1B C.LPigcnent Green 36 P-4B Blue Fine Pigment 1B C.LPigment Blue 15:6 P-5B Cyan Fine Pigment 1B C.LPigment Blue 15:3 P-6B Yellow Fine Pigment 1B CIPigment Yellow 139 P-7B Yellow Fine Pigment 1B C.LPigment Yellow 150 P-8B Purple Fine Pigment 1B C .LPigment Violet 23 , Filtered and dispersed by a filter of 1. Ομm

<Method for Producing Resist Material> (Preparation of Red Resist Material) The following mixture was stirred and homogenized to obtain a red resist material pigment dispersion (P-1B): 50. 0 pigment dispersion ( P-6B): 10. 0 parts of acrylic resin solution 1B: 11.0 part of trimethylolpropane triacrylate: 4. 2 parts ("NK ester ATMPT" manufactured by Shin-Nakamura Chemical Co., Ltd.) Photopolymerization initiator: 1·2 Department (IRGACURE 907) sensitizer ("EAB-F" manufactured by Hodogaya Chemical Co., Ltd.) 0. 4 ethylene glycol monodecyl ether ethyl ester: 23. 2 parts 099132160 Form No. A0101 Page / Total 154 pages 1003010545-0 201127911 (Preparation of green anti-button material) After the following mixture is stirred uniformly, the dispersion is filtered with a filter of 1. 〇μm to obtain a green anti-residue material. P-crime &gt; :45. 〇部. Pigment dispersion

:15 · 〇 Part Acrylic Resin Solution 1B

Trimethylolpropane triacrylate vinegar • 4. 2: jilt (Naka Nakamura Chemical Co., Ltd. “Νκ ester j Μ: photopolymerization initiator-1 &quot; ^ :1. 2 (IRGACURE, manufactured by Chiba Corporation, Japan) 907" sensitizer (made by Baotu Valley Chemical Co., Ltd.) - r - F j ) 0.4 parts, * ethylene glycol monoterpene kisaki: _ 匕 ' '__'丨 '丨人.; : 23. 2 parts (cyan resistance Preparation of the etchant material) After the following mixture is stirred uniformly, the dispersion is filtered through a filter of 1. 〇&quot; m to obtain a cyan anti-surname material. Pigment dispersion (P-5B)

:60.0 Acrylic resin solution 1B : 11·0 part 099132160 Form No. A0101 Page 139 / 154 pages 1003010545-0 201127911 Trihydrocarbylmethylpropane triacrylate: 4. 2 (Mecester ATMPT, manufactured by Shin-Nakamura Chemical Co., Ltd.) ") Photopolymerization initiator ·· 1. 2 (IRGACURE 907, a sensitizer manufactured by Chiba Corporation, Japan) (EAB-F. 0. 4 ethylene glycol monomethyl ether ethyl ester manufactured by Hodogaya Chemical Co., Ltd.: 23. Part 2 (Preparation of yellow resist material) 3 After the following mixture was stirred uniformly, the dispersion was filtered at 1.0/ζ 111 to obtain a yellow anti-reagent material pigment dispersion (P-&amp;B). ): 0. 0 parts of pigment dispersion (P-7B): 15. 0 parts of acrylic resin solution 1B: 11. 0 parts of trihydrocarbyl propane triacrylate: 4. 2 ("Nippon Nakamura Chemical Co., Ltd." ATMPT") Photopolymerization initiator: 1.2 parts (IRGACURE 907" sensitizer ("EAB-F" manufactured by Hodogaya Chemical Co., Ltd.) 099132160 Form No. A0101 Page 140 of 154 Page 1003010545- 0 201127911 0. 4 parts ethylene glycol monomethyl ether ethyl ester: 23.2 [Examples 8 to 8 7 and comparative examples 2 to 2 8] (Example 80: The color filter is colored with a blue coloring composition (D-1B). After the following mixture is stirred uniformly, an oxidized hammer having a diameter of 〇 5 mm is used.

The dispersion treatment was carried out for 5 hours by an IGER mill ("Mini Model M-250 MKII" manufactured by IGER Japan Co., Ltd.). Thereafter, the dispersion was filtered through a filter of 5.0 mm to obtain a pigment dispersion (D-1B). Halogenated product 1B: 11, part 0. Acrylic resin solution IB: 40. 0 part cyclohexanone: 48.0 parts

Resin type dispersant: 1. 0 Department ("Esaka Chiba Co., Ltd." "EFKA4"

(Examples 81 to 87 and Comparative Examples 27 and 28: Coloring Compositions for Color Filters (D-2B) to (D-10B)) In addition to changing the halogenated product 1B to the coloring agent shown in Table 14, The blue coloring composition for color filters (D-2B) to (D-10B) was obtained in the same manner as the blue coloring composition (D-1B) of the color filter. Table 14 099132160 Form No. A0101 Page 141 / 154 pages 1003010545-0 201127911 Coloring composition colorant Example 80 D-1B Halogenated product 1B Example 81 D-2B Halogenated product 2B Example 82 D-3B Halogenated product 3B Example 83 D -4B Halogenated product Example 84 D-5B Halogenated product 5B Example S5 D-6B Halogenated product 6B Example 86 D-7B Halogenated product 7B Example 87 D-8B Deuterated product 8B Comparative Example 27 D -10B CI Acid Blue 1 Comparative Example 28 D-11B CI Acid Red 289 [Evaluation of Coloring Composition for Color Filter] The coloring composition (D-1B) for color filter was subjected to the same method as Test 2 (D-10B) for the thermal test. Table 15 shows the results of the thermal test. Table 15 .

Coloring Composition Heat Resistance Example 80 D-1B Example 81 D-2B Example 82 D-3B Example 83 D-4B Example 84 D-5B Example S5 D-6B Example 86 D-7B 〇 Example 87 D-8B ◎ Comparative Example 27 D-10B X Comparative Example 28 D-11B X When a colored composition (D-1B) to (D-8B) containing a specific halogenated product is used, achievable Good heat resistance. Then, when a colored composition (D-8B) containing a coloring agent which has been treated with rosin-modified maleic acid resin is used, particularly good performance can be attained. On the other hand, when the coloring composition (D-9B) to (D-10B) containing a dye as a coloring agent is used, the chromaticity change exceeds 5, and the heat resistance is low. From the above results, it is understood that the coloring composition containing a specific halogenated product is excellent in heat resistance. 099132160 Form No. A0101 Page 142 of 154 Page 1003010545-0 201127911 [Examples 88 to 108 and Comparative Examples 29 to 32] (Example 88: Resist Material (R-1B)) The following mixture was stirred. After homogenization, the dispersion was filtered through a filter of 1.00 m to obtain a resist material (R-1B). Coloring composition (D-1B): 10. 0 parts Pigment dispersion (P-4B)

••50.0 parts of acrylic resin solution 1B: 11.0 parts of trihydrocarbyl propane triacrylate: 4. 2 parts (“NK ester ATMPT” manufactured by Shin-Nakamura Chemical Co., Ltd.) Photopolymerization initiator: 1. 2 (Japan Chiba Corporation) "IRGACURE 907" sensitizer (preservative, "EAB-Fj" manufactured by Tanibe Chemical Co., Ltd.: 0.4 ethylene glycol monomethyl ether ethyl ester: 23.2 (Examples 89 to 108 and Comparative Examples 29 to 32) : Resist materials (R-2B) to (R-25B)) The coloring composition (D-1B) and the pigment dispersion (P-4B) were replaced by the coloring composition or the pigment dispersion shown in Table 16, The alkali-developing resist materials (R-2B) to (R-12B) and (R-24B) were obtained in the same manner as the resist material (R-1B) except that the blending amount was changed in Table 16. R-26B), 099132160 Form No. A0101 Page 143 of 154 pages 1003010545-0 201127911 and (R-23B) to (R-25B). Furthermore, a part of the resist material is dispersed with the coloring composition and pigment. When the total amount of the resist material is 10 〇, the total amount of the coloring composition and/or the pigment dispersion is 6 。. In addition, the acrylic resin solution 2B to 4B is substituted for propylene. The developed resist materials (R-13B) to (R-15B) were obtained in the same manner as the resist material (R_1B) except for the resin solution 1B. Further, the acrylic resin solution 2B to 4B was replaced with acrylic acid. Other than the resin solution iB, alkali-developing resist materials (R-19B) to (R-21B) were obtained in the same manner as the anti-agent material (R-16B). Table 16 Resist material color resistance &amp; Preparation of coloring composition or pigment dispersion in puncturing material 孴Acrylic resin solution coloring composition or pigment dispersion 艎 compounding amount coloring composition or pigment dispersion 艟 compounding amount coloring composition or pigment dispersion compounding amount Example 88 R- 1B Blue D-1B 10 Ρ-4Β 50 _ _ 1 ★Example 89 R-2B ]&gt;2Β10 Ρ-4Β 50^ _ _ 1 Real cover 卯R-3B D-3B 10 Ρ 4Β 50 parts _ _ 1 Example 91 R-4B1 D-4B 1 NaΡ-4Β 5 Na_ 1 Example 92 R-5B D-5B QingΡ-4Β 5:1 - 1 Example 93 R-6B D- 6B Ρ-4Β 50 parts X Example 94 R-7B Ρ-7Β Ρ-4Β 5&lt;m 1 Appreciation Example 95 R-8B D-8B 10# Ρ-4Β 50 part 1 Example 96 R-9B D-1B 20 Ρ-4Β 40 parts _ 1 Example 97 R-10B D-1B 7 parts Ρ-4Β 50 parts P-8B 3 parts 1 Example -11R-11B D-1B 57 parts D-9B 3 gur 1 Appreciation Example 99 R-12B ΕΜΒ 45 parts D-9B 15 parts _ _ 1 Example 100 R-13B Ι&gt;-ΧΒ 10 parts Ρ-4Β 50 parts _ _ 2 Real R-14B D-1B 10 parts Ρ-4Β 50 parts _ ~1 3 Embodiment 102 R-15B 3D-1B 10 Ρ-4Β 50 parts _ _ 4 Example 103 R-16B O-IB 60 parts _ __ _ — 1 Example Ϊ 04 R.-17B D-1B 45 Department Ρ-2Β15部_ 1 Example 105 R-18B Artichoke-ΙΒ 45 D-10B 15 parts _ 1 Example 106 R-19B Red D-1B 60 parts _ Suspended 2 Real vibration example 107 R-20B D -1B έο却— _ 3 Example 108 R-21B D-1B 60 but the net lion _ _ 4 Comparative Example 29 R-22B Basket D-9B 60 village. One _ _ a 1 Comparison tree 3 〇 R-23B Ρ - 4Β 57ΡΡ-8Β 3 parts _1 1 Comparative Example 31 R-24B Artichoke-10Β 60 parts _ _ _ 1 Comparative Example 32 R-25B Red Ρ-2Β 60 parts - - 1 [Resist material (R -1B) to (R-25B) Evaluation] The following methods were used to evaluate the color characteristics (brightness) and resistance (heat resistance, light resistance, and solvent resistance) of the resist material. 099132160 Form No. A0101 No. 144 Buy / Total 154 pages 1003010545-0 201127911 Test. (color characterization)

A resist material is applied on the glass substrate. Specifically, the blue resist material is applied such that the chromaticity under the C light source becomes a film thickness of y = 0.060. The magenta resist material is applied such that the chromaticity under the C light source becomes a film thickness of x=0.348. The substrates were heated at 230 ° C for 20 minutes to form a colored layer on the substrate. Thereafter, the luminance Y of the substrate on which the colored layer was formed was measured by a microscopic spectrophotometer ("OSP-SP200" manufactured by Olympus Optics Co., Ltd.). (Tolerance test) The heat resistance of the coating film was the same as that of the tester of Test 2. The test, the film light resistance test, and the film solvent resistance test (result of evaluation of the resist material) are shown in Table 17 as a resist. Evaluation results of materials (R-1B) to (R-25B) Table 17 Anti-blocking materials Color brightness Y Heat resistance Light resistance vs. Solventability Example 88 R-1B 7*2 〇〇〇 Example 89 R-2B 7.1 〇〇〇Example 90 R-3B 73 〇〇〇Example 91 R-4B 12. 〇〇〇贲Example 92 R-5B 7J2 〇〇〇Example 9Ϊ R-6B 7.1 〇〇〇. Implementation inverted 94 R -7B 73 〇〇〇Example 妁R-8B Blue 7.6 ◎ ◎ ◎ Example 96 R-9B 6.9 ◎ ◎ ◎ Example 97 R-10B 6.8 ◎ ◎ ◎ 贲 Example 98 R-11B 7.4 〇〇〇Example 99 R-12B 13 A △ △ Example 100 R-13B 7*2 ◎ ◎ ◎ Example 101 R-14B 7*2 ◎ ◎ ◎ Example 102 R-15B 7*2 ◎ ◎ ◎ Example 103 R- I6B 27.6 〇〇〇 Example 104 R-17B 26-6 ◎ ◎ ◎ Example 105 R-18B Ocean 27, 9 △ △ △ Example 106 R-19B Red 27.6 ◎ ◎ ◎ Example 107 R-20B 27.6 ◎ ◎ ◎ Example 108 R-21B 27.6 ◎ ◎ ◎ Comparative Example 29 R-22B Blue 7.1 XXX Comparative Example 30 R-23B 5.9 ◎ ◎ ◎ Comparative Example 31 R-24B Ocean 27.7 XXX Comparative Example 32 R-25B Red 24.3 ◎ ◎ ◎ Resist material (R-1B) containing halogenated product and dye to 099132160 Form No. A0101 Page 145 of 154 1003010545-0 201127911 (R-22B) and (R When -24B), a higher luminance γ can be achieved as compared with the use of the pigmented anti-materials (R-23B) and (R~25B). Then, when the resist material (R_8B) is used, it is presumed that this is because the surface of the colorant is subjected to resin treatment, and the coloring property is improved in dispersibility and solubility, and high luminance can be obtained. Good results were also obtained in the resistance test using the resist materials (r-1B) to (R-21B) of the § special halogenated product. Then, when a resist material containing a chemical product and a pigment is used, particularly good results are obtained. Further, when the anti-money agent materials (R 12B) and (R-18B) containing the chemical product and the dye are used, the results of the 'scratch resistance test are slightly inferior, but the degree of practicality does not pose a problem: - When using only pigments as coloring anti-dispersion materials, materials (r_23b) and (R-25B), the tolerance test results were good, but the brightness was low. On the other hand, when the anti-caries material (R-22B) and (R-24B) containing only a dye as a coloring agent are used, the chromatic aberration changes by more than 5, and the resistance is low. Further, when the resist material dUg) was used: to (ρ15Β) and (R_i9B) to (R-21B), the resistance test was performed: the crucible was also good. It is judged that the hardening property of the coating film is enhanced by the use of the living shaft-twist curing resin having ethylene bonding. From the above, it is known that the anti-surname material containing the to-be-fixed product exhibits good performance in terms of color characteristics (brightness) and financial acceptability. [Examples 109 to 129 and Comparative Examples 36 to 39] A hearing and complementary color change filter (Example 100: primary color filter (CF_1B)) 099132160 was produced on a color substrate by the following. , forming a black matrix of the light-shielding pattern, and then using the rotation 100301 (Form No. A0101, page 146 / 154 pages ΖΌηζ / ^ιι coater to coat the red anti-material 1 color under the c light source will become (4) (10) ^ _ system Coating: Photomask and irradiation with ultra-high pressure mercury lamp _:&quot;^=: Spraying::, 1=% carbon_aqueous solution is used to test the developer solution, and (4) sub-exchange water is washed. () c depends on the minute plus __, the shape of the county section of the film, on the substrate, by with the rape ^ #

The method of etching the etched material is coated with a green anti-C film thickness. The coating film was used as an exposure to the color legs of the red-agent material, % ring, forming green = '. Furthermore, the substrate & humiliation same hand = coated blue anti-material ((4)). Blue stealing material is painted = the color under the handle will become (4) 』6 · The film is coated with color resistance _ material has been described above for the same exposure, development cleaning and firing, _ blue (10) first I^ segment light film (CF-1B). , .' ^ ^*ϋ·- ^ ^ -;i^ (production of liquid crystal display device) i'n, = use color filter (CF-1B) instead of color filter (CF_U) to eve, other A liquid crystal display device was produced by the same method as that described in Example 68. Examples 110 to 123 and Comparative Examples 36 and 37: primary color-based color calendering sheets (C^2B) to (CF_17B)) 099132160, except that the resist material was changed to the resist material shown in Table 18, The primary color system color filters (CF-2B) to (CF-17B) were produced in the same manner as the color filter (CF-1B) and the liquid crystal display device described above. &gt; Form Compilation A0101 Page 147 / 154 pages 1003010545-0 201127911 (I know * Example 124: complementary color color filter (CF-1 8B)) On the shirt substrate, a black matrix of shading pattern is formed. The magenta anti-narr material (R_16B) was then applied using a spin coater. The magenta anti-buckling agent material (^, 16B) is applied as a ray having a chromaticity under c light source, which is χ=〇 _, thicker than the coating film, and an ultraviolet ray irradiated by an ultrahigh pressure mercury lamp. Thereafter, an alkali developing solution composed of Q·2% by weight of acid-saturated water &amp; liquid was used for spray development, and the unexposed portion was removed and washed from ion-exchanged water. Further, the substrate was heated at 23 rc for 2 minutes to form a magenta filter segment. Next, a yellow resist material was applied on the substrate by the same method as above. The yellow resist material was worn. Shuangheng is the color of the light under the .C light and source will become the film thickness of x=〇. 440. The same exposure is described above for the magenta resist material, V display, Qin, wash溱 and firing to form a yellow filter segment. Further, a cyan resist material is applied on the substrate by the same method as described above. The cyan resist material is coated as a chromaticity under C light source. It becomes the film thickness of y=„〇·〇,6. The coating film is used for the magenta resist material. The same is the above, the same exposure, development, washing and firing, forming a cyan filter 443⁄4 history: Color filter (CF-18B) is obtained as above. (Production of liquid crystal display device) Except that color filter (CF-18B) is used instead of color filter (CF-1A) 099132160 A liquid crystal display device was produced in the same manner as the method described in Example 68. (Examples 125 to 129) And Comparative Examples 38 and 39: Supplementary Color Filters (CF~19B) to (CF-25B)) In addition to changing the resist material to the resist material shown in Table 19, I No. A0101 No. 148 Pages / Total 154 pages 1003010545-0 201127911 Others are the same as the color filter (CF-18B) and the above liquid crystal display device, respectively, to produce complementary color system color filters (CF-1B) to (CF-25B). Evaluation of Filters (CF-1B) to (CF-25B)]

A color image is displayed on the liquid crystal display device described above. Then, for the liquid crystal display containing the primary color filter, the brightness of the region corresponding to the red, green, and blue color filters was measured by microscopic spectrophotometry ("OSP-SP200" manufactured by Olympus Optics Co., Ltd.). Further, for the liquid crystal display containing the complementary color filter, the luminance of the region corresponding to the red, green, and blue color filters was measured by a microspectrophotometer ("OSP-SP200" manufactured by Olympus Optical Co., Ltd.). Then, the brightness of the white display is obtained from the brightness. _ Table 18 shows the results obtained for the liquid crystal display device containing the primary color filter. Further, Table 19 shows the results obtained by the needle 'for a liquid crystal display device containing a complementary color system color filter. Table 18 Color Filter Blue Resist Material Filter Brightness Brightness White Display Brightness Red Color Green Color Example 1G9 CF-1B R-1B 20.3 56.9 7.5 28.2 Example 110 CF-2B R- 2B 20.3 56.9 7.4 2SJ2 Example 111 CF-3B R-3B 20.3 56.9 7.6 283 Example 112 CF-4B R-4B 20.3 56S 7.5 2SJ2 Example 113 CF-5B R-5B 20.3 56.9 7.5 Example 114 CF-6B R -6B 20.3 56.9 7.4 28.2 Example 115 CF-7B R-7B 20.3 56.9 7.6 28.3 Example 116 CF-8B R-8B 20.3 56.9 7-9 28.4 Example 117 CF-9B R-9B 2Ό3 56.9 7.2 28.1 Example 118 CJP-10B R-10B 203 56.9 7.1 2S.1 Example 119 CF-11B R-11B 203 56.9 7.7 28.3 Example 120 CF-12B R-12B 20.3 56.9 7.6 28.3 Example 121 CF-13B R-13B 20.3 56.9 7 , 5 28.2 Lean application 122 CF-14B R-14B 20.3 56.9 7.5 28.2 Example 123 CF-15B R-15B 203 56.9 7.5 28.2 Comparative Example 36 CF-16B R-16B 20.3 56.9 7.4 28^ Comparative Example 37 CF-17B R-17B 20.3 56.9 6.1 27.8 Table 19 Color filter magenta filter month section brightness white display resist material plain color magenta yellow show brightness 09 9132160 Form Number Α0101 Page 149 of 154 1003010545-0 201127911 Example 124 CF-18B R-16B 7.8 28.7 80.1 38.9 Example 125 CF-19B R-17B 7.8 28.7 80.1 38.5 Example 126 CF-20B R-18B 7.8 28.7 S0.1 39.0 Example 127 CF-21B R-19B 7.8 28.7 80.1 38.9 Example 128 CF-22B R-20B 7.8 28.7 S0.1 38.9 Example 129 CF-23B R-21B 7.8 28.7 S0.1 38.9 Comparative Example 38 CF-24B R-22B 7.8 28.7 S0.1 38.9 Comparative Example 39 CF-25B R-23B 7.8 28.7 80.1 37.7 For the blue filter section of the primary color filter (CF-17B), use A combination of a copper phthalocyanine pigment and a dioxazine-based pigment which have been conventionally used in such a filter section. Further, in the color filters (CF-1B) to (CF-15B), a specific halogenated product is used in the blue filter section. Compare color filters (CF-1B) to (CF-15B) and color filters (CF-17B) to color filters (CF-1B) to (CF-15B) for blue and white Each of them obtained a higher brightness than the color filter (CF-17B). Further, a dye was used as a colorant in the blue filter section of the color filter (CF-17B). Therefore, although the brightness is high, the tolerance is relatively low. Regarding the magenta filter section of the complementary color filter, the same results as those described for the filter &gt; 1 section of the primary color filter are obtained, for example, by using specificization. The color filter (brightness) and the blue filter segment excellent in heat resistance, light resistance, and solvent resistance can be obtained. BRIEF DESCRIPTION OF THE DRAWINGS [0024] Fig. 1 is a view showing an emission spectrum of a backlight used in Examples and Comparative Examples. [Description of main component symbols] [0025] None 099132160 Form No. A0101 Page 150 of 154 1003010545-0

Claims (1)

201127911 VII. Patent application scope: 1. A coloring composition for a color filter, which comprises a transparent resin and a coloring agent; the coloring agent comprises a halogenated product composed of a relative compound of a basic dye and an anionic component, and the relative The molecular weight of the compound is in the range of from 200 to 3,500. 2. The coloring composition for a color filter according to claim 1, wherein the molecular weight of the aforementioned relative compound is in the range of 250 to 3,500. 3. The coloring composition for a color filter according to claim 1 or 2, wherein the relative compound is selected from the group consisting of heteropoly acid, organic sulfonic acid, organic carboxylic acid, and acid dye. At least one. The coloring composition for a color filter according to any one of the items of the present invention, wherein the coloring agent further comprises a resin having an acid group. 5. The coloring composition for a color filter according to the fourth aspect of the invention, wherein the weight average molecular weight of the resin having an acid group is in the range of 400 to 12,000. 6. The coloring composition for a color filter according to the fourth or fifth aspect of the invention, wherein the acid-based resin-based rosin-modified maleic acid resin is used. The coloring composition for a color filter according to any one of claims 4 to 6, wherein the acid value of the acid group-containing resin is in the range of 100 to 300 mgKOH/g. The coloring composition for a color filter according to any one of claims 1 to 7, wherein the basic dye is derived from a triarylmethane dye, a rose red dye, and a methylene blue dye. And at least one of the group selections of the flavin dyes. 9. Coloring group for color filter according to any one of claims 1 to 8 099132160 Form No. A0101 Page 151 / 154 pages 1003010545-0 201127911 The product further contains a photopolymerizable composition and At least one of the photopolymerization initiators. </ br> </ br> </ br> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; The coloring composition color filter is a blue colored composition, and the chemical product contains a triaryl decane dye and a 13 ton dye. The coloring composition for a color filter according to the first aspect of the invention, wherein the triarylmethane-based dye is a triarylmethane-based basic dye; and the oxime-based dye is a xanthene-based acid dye. The coloring composition for a color filter according to the first aspect of the invention, wherein: - the triaryl-based graft dye is a triarylmethane-based acid dye; and the aforementioned ridiculous dye-based xanthene-based basic dye * &gt; „ &gt;; 4 - Coloring composition for color filters as described in the first and second column of the patent application 'The above-mentioned xanthene dyes are rose red dyes. The coloring composition for a color filter according to any one of the above-mentioned items, wherein the coloring agent comprises the phthalocyanine pigment in two steps, and the color filter according to any one of the items of the patent application No. 10 to 14 A coloring composition for a light sheet, wherein the coloring agent further comprises a dioxazine-based pigment. The coloring composition for a color filter as described in any one of claims 1 to 9 wherein the halogenated product contains a halogenated product composed of an oxime-based dye and an oxime-based acid dye. The coloring filter for a color filter according to any one of claims, wherein the xanthene-based basic dye is a rose red dye. A coloring composition for a color filter according to claim 16 or 17, wherein the coloring agent further contains a cocaine-based pigment. The color illuminating sheet of any one of claims 16 to 18 is for use in a color composition, wherein the coloring agent further comprises a dioxazine-based pigment. A blue coloring composition for a color filter, which comprises a transparent resin and a colorant, and the coloring agent contains a halogenated product composed of a triarylsulfane dye and a xanthene dye. A coloring composition for a color filter comprising a transparent resin and a coloring agent; and the coloring agent comprises a toothed product comprising a xanthene-based basic dye and a xanthene-based acid dye. twenty two A color filter comprising a filter segment formed by a coloring composition for a color filter according to any one of claims 1 to '% 099132160 Form No. A0101 Page 153 of 154 1003010545-0