201127601 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種於成型樹脂上積層有設計層而成之 加飾成型材及其製造方法、以及使用於該製造方法之積層 體。更詳細而言，本發明係關於一種藉由模内成型轉印進 仃之加飾成型材之製造方法、及利用該製造方法而製造之 加飾成型材、.以及使用於該製 x表&方法之積層體，該加飾成 i材之製造方法係可將藉由轉印紡織物、編織物、不織布、 曰本紙等賦型材表面之凹凸而獲得之凹凸花紋與金屬光 澤、著色、印刷圖案等同時賦予至成型樹脂。 【先前技術】 自先前以來’已知藉由使用模内成型機之模内成型轉 印而將具有金屬光澤、著色、印刷圖案等之設計層積層於 成型樹脂上而成之加飾成型材。 上述加飾成型材係用作音響製品、其他家電製品之殻 體荨各種成型品者。 於專利文獻1中，記都右·上 己載有如下附有圖樣之射出成形品 、方法·其特徵在於’藉由於將使附有圖樣之轉印膜 與纖維材料重疊而成者以使該轉印膜面向射出孔之方式而 配設於射出成形用模具内後，自射出孔將合成樹脂射出成 形，而獲得表面附著有上述轉印臈與纖維材料之成形品， 其後藉由將上述轉印膜與纖維材料自該成形品剝離，而將 圖樣與纖維花紋同時轉印至成形品表面。 201127601 為了對作為被轉印物之成型品賦予、 印刷圖案等’ m常使用將金屬薄膜層、著色屏’： 加以適當組合而形成於塑膠膜之 s (轉印材）。 有作為上述轉印膜 雖然轉印膜或纖維材料之任一者 之情形，但通常使用長條且親狀者㈣在使用版紙狀者 =使用長條且輥狀之轉印膜及纖維材料之情形時，通 吊木用如下方法：分別將轉印膜及纖維材料設置於不同 =繞裝置中並送出而插入模具内’或者藉由預先將轉印 膜與纖維材料重#並捲繞而製造長條且輥狀之生 :，將該雙層構造體設置於退繞裝置中並送出而： 1^ 〇 '八 上述專利文獻1之附有圖樣之射出成 又π 口（加飾成型 材）係具有轉印作為賦型材之纖維材料表面之凹凸 凹凸花紋與金屬光澤、¥色、印刷圖案等相 = 的設計性者。 蜀特 [先前技術文獻] [專利文獻] [專利文獻1]日本專利特開平4-261819號公報 【發明内容】 [發明所欲解決之問題] 然而，上述專利文獻1中記載之附有圖樣之 U itj成开> 品及其製造方法、以及使用於該製造方法之雙層 v 傅造體具 201127601 有如下所示之缺點。 由於僅使轉印膜及纖維材料接觸並重疊，而並非將轉 印膜及纖維材料以整個面或部分地加以貼合，因此， (1)於將轉印膜與纖維材料配設於模具（將轉印膜與 纖維材料插入凸模具（陽模）與凹模具（陰模）之間，且 正確地定位於成型之位置並固定）後，存在於鎖模（將陽 模與陰模閉合）時轉印膜及纖維材料產生皺褶之情形或費 力定位之轉印膜或纖維材料發生偏移之情形。 p其結果，存在如下情形：製成之附有圖樣之射出成形 品會產生存在未形成所需之凹凸花紋之部分等問題，並且 金屬光澤、著&、印刷圖案等亦未被確實地賦予等，無法 成為具有所需之設計性者。 ⑺於藉由如下方法而製造附有圖樣之射出成形品之 月幵/時#在上述雙層構造體之轉印膜與纖維材料易於發 生偏移之問題，該方法係預先將轉印模與纖 :繞而製造長條且輕狀之雙層構造體，將該雙層構造體設 :於退繞裝置中並送出而插入模具内。 = 時間點時轉印膜與纖維材料發生偏移之問題广“體之 本發明之課題在於’為了消除上述所有缺點 種可將藉由轉印賦型材纟面之㈤凸而獲 、·. “ ，、 屬光澤、著色、印刷圖案等同時且清晰^凹凸花紋與金 並且生產性優異之“ π晰地馱予至成型樹脂， 法而製造之力飾::材之製造方法及利用該製造方 而“之加飾成型材，以及使用於該製造方法之積層體。 201127601 [解決問題之技術手段] 本發明係-種加飾成型材之製造方法，其係製造於成 型樹脂上積層有設計層而成之加飾成型材之方法， 且包括如下步驟： ‘ (A)將於塑膠膜之—面形成有設計層而成之轉印材與 至少一面具冑凹&之片狀賦型材以使上述塑膠膜之另一面 與上述賦型材之上述凹凸面相接觸之方式而部分貼合，從 而獲得積層有轉印材及賦型材之積層體； ⑻將上述積層體以使設計層側面向射出孔之方式而 配設於射出成型用模具内； (C)於鎖模後，將熔融狀態之成型用樹脂自射出孔射 出至模穴内，並將上述賦型材之凹凸轉印至轉印材及至少 成型樹脂之設計層側表面，從而獲得 ⑼於將上述轉印積層體冷卻後，將賦;體材及:；材 之塑膠膜自該轉印積層體剝離，從而獲得於設計層及至,1 成型樹脂之設計層側表面形成有凹凸花紋之加傳成型材; 於上述步驟（A)中，較佳為藉由線狀之貼合部將上妇 轉印材與上述賦型材加以貼合。 尤其’較佳為藉由利用雙面膠帶而形成之線狀之貼合 部將上述轉印材與上述賦型材加以貼合。 又’本發明係-種加飾成型材，其係利用上述製造方 法而製造之於成型樹脂上積層有設計層而成者，其特徵在 於:於設計層及至少成型樹脂之設計層側表面形成有轉印 上述賦型材之凹凸而成之凹凸花紋。 6 201127601 又，本發明係一種積層體，其係使用於上述製造方法 者，其特徵在於··其係將於塑膠膜之—面形成有設計層而 成之轉印材與至少一面具有凹凸之片狀賦型材以使上述塑 膠膜之另-面與上述賦型材之上述凹凸面相接觸之方式而 部分貼合而成。 ·[ 作為上述積層體，較佳為藉由線狀之貼合部將上述轉 印材與上述賦型材加以貼合而成之積層體。 尤其，較佳為藉由利用雙面膠帶而形成之線狀之貼合 部將上述轉印材與上述賦型材加以貼合而成之積層體。 [發明之效果] 由於本發明之加飾成型材及其製造方法、以及使用於 該製造方法之積層體具有上述特徵，因此成為具有下述優 異之效果者。 於本發明中，由於不僅使轉印膜及賦型材接觸並重 疊，亦將轉印膜及賦型材部分貼合，因此， 1.於將轉印材與賦型材配設於模具内&，不t導致於鎖 模時轉印材及賦型材產生皺褶、或導致費力定位之轉印材 或賦型材發生偏移。其結果，利用本發明之製造方法而製 造之加飾成㈣不存纟產生未形成所需之凹凸^文之部分 等問題。 因此，於利用本發明之製造方法而製造之本發明之加 飾成型材中確實地形成清晰之凹凸花紋，並且亦同時且確 實地賦予金屬光澤、著&、印刷圖案等。因此，可獲得具 有所需之設計性之加飾成型材。 201127601 2.於使用預先將轉印材與賦型材貼合並捲繞而成之長 條且輥狀之積層體來製造本發明之加飾成型材之情形時， 不會產生積層體之轉印材與賦型材發生偏移之問題。如 此，由於本發明之積層體於操作時轉印材與賦型材不會發 生偏移，因此不存在無法於模具内進行正確之定位之問 題，或於最初製造積層體時轉印材與賦型材發生偏移之問 題。 【實施方式】 利用本發明之加饰成型材之製造方法所製造之本發明 之加飾成型材係於成型樹脂上積層設計層而成者。 並且，本發明之加飾成型材之特徵在於：於上述μ叶 層及至少成型樹脂之設計層側表面（與設計層密接之二 樹脂之面）形成有凹凸花紋。上述凹凸花紋係轉印本發明 之製造方法中所使用之賦型材之表面之凹凸而形成者。 本發明之製造方法中所使用之賦型材為片狀，例如由 纺織物、編織物、不織布、曰本紙等所構成。該賦型材於 至少-面之表面具有凹凸花紋。此處，所謂賦型材表面之 凹凸’係指作為賦型材之纺織物、編織物、不織布、 =之表面形狀。即係指藉由構成作為賦型材之紡織物、 碑’;物、不織布、曰本紙等之纖維露出於上述紡織物、編 織物、不織布、日本紙等之表面而形成之表面形狀。、 並且’使用上述賦型材所製造之本發明之加飾 係於其設計層及至少成型㈣之設計㈣表面具有上述賦 8 201127601 型材之表面形狀反轉而轉印之凹凸花紋。 因此’本發明中所謂的凹凸花紋係指上述贼型 之凹凸正好反轉而轉印之狀表面 卩#由轉印賦型材表面之凸部而形 成型材之凹花纹，茲士妯t 分a之加飾 明之加倚成型材之凸花紋。 $成本發 首先，對本發明之加錦成型材之製造方 積層體進行說明。 π使用之 上述積層體係將於糊_& 印材與至少—面ΙΓ膜之一面形成設計層而成之轉 凹凸之片狀賦型材以上述塑膠膜之χ -面（與形成有設計層之面相反之面）與上述賦型材之： 述凹凸面相接觸之方式部分性地貼合而獲得。 牌膜造本發明之加飾成型材而使用之轉印材係於塑 膠膜之早面形成有設計層者。 此處所I胃設計層，係指制本發明之製造方法而積尽 樹脂上之層，且係為了獲得所需加飾成型材而需： 之所有層之總稱所謂設計層，不僅係指 ： 明之加飾成型材賦予金屬古、罢^ τ本發 予金屬先澤、者色、印刷圖案等之加飾 : 用以賦予金屬光澤之金屬薄膜層、用以著色 者色層及用以賦予印刷圖案之印刷層），亦指用以 倚層t與成型樹脂密接之接著層，以及將設計層轉印至2 树月曰後保濩加飾層表面不受損傷或腐蝕等之保護層 獲得所需加飾成型材而需要之所有層之總稱。 了 構成加飾層之上述金屬薄膜層、著色層'印刷層可為 9 201127601 單層’或者為了獲得所需之設計，亦可將該等層加以適當 組合而成為複數層。 一例如，可藉由使用具有將金屬薄臈層與著色層加以組 合=成之設計層之轉印#，而對本發明之加飾成型材賦予 經耆色之金屬光澤。又，可藉由使用具有將金屬薄膜層與 印刷層加以組合而成之設計層之轉印材，而對本發明之加 飾成型材賦予印刷圖案及金屬光澤。 又。又计層可形成於轉印材之整個面，亦可部分地來 成。 7 進而’構成設計層之各層 著色層、印刷層等）、保護層 之整個面，亦可部分地形成。 ，即加飾層（金屬薄膜層' 、接著層等可形成於轉印材 使哪一層形成於整個面，或使哪一層部分地形成，只 要根據所需之加飾成型材之設計性而適當組合決定即可。 =此’藉由使設計層本身或構成設計層之各層形成於 轉印材之整個面或使其部分地形成，而利用本發明… p而製造之㈣成型材，亦為設計層本身或構成設計^ :各層積層於該加飾成型材之整個面或部分地 曰 因此，可製造具有富於變化之設計性之加飾成型材。 對構成上述設計層之各層（加飾層[金屬 層.印刷層卜接著層、保護層）進行更詳細之說明。 作為上述金屬薄膜層， 材賦予金屬光澤者則無特別 骐層 '銅薄膜層、鉻薄膜層 成型 銀薄 只要為可對本發明之加飾 限制，可使用鋁薄犋層、 、鎳薄.膜層及錫薄膜層等 10 201127601 金屬簿膜層之厚度只要根據所需之金屬光澤而適當決 定即可。 田〆、 又，作為金屬薄膜層之形成方法’可使用真空蒸鑛法 等公知之方法。 作為上述著色層，可使用將染料或顏料等著色劑混入 丙烯酸系樹脂、聚酯樹脂等樹脂中而成之薄膜。上述著色 層可利用凹板印刷式塗佈法、反向塗佈法等八去 A知之方法而 形成。 著色劑之量或著色層之厚度只要根據所需之著色程度 而適當決定即可。 作為上述印刷層，可使用由印刷油墨所構成之薄膜。 該印刷層可利用網版印刷法、凹板印刷法等公知之方法而 將印刷油墨印刷成圖案狀而形成。 印刷層之圖案只要根據所需之印刷圖案而適當決定即 ~5J" 〇 上述接著層係由樹脂所構成之薄膜，且係用以使加飾 層與成型樹脂密接之層。 使用於接著層之樹脂只要為可密接於成型樹脂之樹脂 則無特別限制，可使用丙烯酸系樹脂、聚酯樹脂、氣乙烯 樹脂及氣乙烯-醋酸乙烯共聚物樹脂等樹脂。使用於接著層 之樹脂之種類只要根據作為被轉印物之成型樹脂之種類而 適當決定即可。 这保《蔓層係由樹脂所構成之薄膜，係保護加飾層表 面不受損傷或腐触等。 11 201127601 亦可使保護層為具有尤其難以造成損傷之硬塗性之 層。 又’亦可使保護層為易於與塑膠膜剝離之層。於如此 之情形時，無需使用下述脫模性塑膠膜（具有脫模層之塑 膠膜）作為塑膠膜。 使用於保護層之樹脂只要為可保護加飾層表面不受損 傷或腐蝕等之樹脂則無特別限制，可使用丙烯酸系樹脂、 聚s曰树脂、氣乙烯樹脂、氣乙烯_醋酸乙烯共聚物樹脂等樹 脂。 其次，對一起構成轉印材之上述設計層及塑膠膜進行 說明》 3亥塑膠膜係於轉印後自成型樹脂剝離者。#，於轉印 後僅形成於塑膠膜之單面之設計層殘留於成型樹脂上，成 為加飾成型材之一部分。 作為上述塑膠膜，可使用聚對苯二甲酸乙二酯膜、聚 丙烯膜'聚乙烯膜及聚醯胺膜等先前公知之塑膠膜。a 塑膠膜之厚度較佳為3〜5〇 “爪。 —度薄於3 A m，則於製造本發明之加飾成型材時 塑膠膜會產生心m而欠佳。另—方面，若厚度厚於 π ”，則存在如下情形：無法將賦型材表面之凹凸 地轉印至成型樹脂或設計層，結果可能無法於本發明之加 飾成型材形成所需之凹凸花紋，故而欠佳。 為了將上述設計層容易地自塑膠膜剝離，較佳 膠膜上（塑膠膜盥抓斗思々" 膜與5又3十層之間）形成由樹脂所構成之脫名 12 201127601 層。 如此形成有脫模層之脫模性塑膠膜亦包含於 塑膠膜巾。 支 於脫模層形成於塑膠膜之轉印材之情形時，脫模層係 於轉印後與塑膠膜-同自成型樹脂剝㉟，僅設計層殘留於 成型樹脂上。 ' 作為上述轉印材（塑膠膜及設計層）之具體之構成， 例々可列舉塑膠膜/脫模層/保護層/加飾層/接著層、塑膠 膜/脫模層/加飾層/接著層等之構成。 / 又，轉印材之形狀亦可為版紙狀（短尺寸之片） 者亦可為長條物（長尺寸之片）。於使用長條之轉印材1 情形時’可連續生產本:’發明之加飾成型材。進而，於使用 長條之轉印材之情形時，就操作方面而言，較佳為輥狀。 ❹轉印ΐ之厚度、寬度、長度只要根據本發明之加部成 孓材之所需的大小而適當決定即可。 為了製造本發明之加飾成型材而使用之賦型材 於本發明之加飾成型材之設計層及至少成型樹脂之設計居 用。 賦1材表面之凹凸而成之凹凸花紋而使 上述賦型材為紡織物、編織物、不織布、 狀之構件，且為至少-個表面具有凹凸者。 4片 因此，當然亦可於賦型材表面之雙面具有凹凸。 作為上述紡織物或編織物之素材，可為棉 絹等天然纖維，或由平萨似, 干七、麻、 由聚3曰祕脂、聚丙浠樹脂、聚乙稀樹脂、 13 201127601 聚酿胺樹脂及丙烯酸樹脂等所構成之化學纖維之任一種。 组織ΐ，，：：紡織組織’存在平紋組織、斜紋組織、锻紋 雙反面組織等。.在緯編、千針線圈、羅紋組織、 作為上述不織布之素Μ π , , ^ 材可使用與紡織物或編織物相 同之天然纖維或化學纖維。 於賦型材為紡織物或編織物之時，可藉由將纺織 組織或編織組織、所使用 '' 取、产<_租細度荨加以各種组 S ’又，於賦型材為不織布之情形時，可藉由變更基重量 :，=地使賦型材之表面形狀（凹凸）成為多種多樣 者。其…果，可容易地將使用該賦型材而製造之本發明之 加飾成型材之凹凸花紋成為多種多樣者。 於使訪織物或編織物之纺織組織或編織組織為單純之 平紋組織或平針線圈等，且使纺織物或編織物表面之凹凸 成為反覆完全相同之花紋之無變化的單調之凹凸之情形 時，於使用該紡織物或編織物而製造之本發明之加飾成型 材會形成反覆完全相同之花紋之無變化的單調之凹凸花 纹。 又’亦τ使用⑨纺織⑼或編織物之表面之一部分形成 有例如花樣、水珠花纹等各種紡織圖案或編織圖案:或者 利用刺瑜等之立體圖案（較纺織圖案或編織圖案更立體之 圖案）之賦型材。由於在使用上述賦型材而製造之本發明 之加飾成型材轉印有構成纺織物或編織物之纖維之表面形 狀與上述纺織圖案、編織圖案及立體圖案，因此可獲得具 14 201127601 有單調之凹凸花纹伽 、· /、圖案花紋相輔相成之富於情趣之設計 性的加飾成型材》 進而’亦可蘇ώ 胃田使用具有構成紡織物或編織物之纖維 之表面形狀與平坦 圖案的賦型材’而獲得具有單調之凹 λ化紋與平坦之圖牵从^ i 丄& 朱化紋相輔相成之富於情趣之設計性的 加飾成型材。 為了轉印平坦之圖 下方法.將樹脂等塗佈 等，使紡織物或蝙織物 平坦部所構成之圖案， 分切成圖案狀。 案而形成上述圖案花紋，可舉出如 於纺織物或編織物之表面之一部分 之表面之一部分平坦，而形成由該 或者將紡織物或編織物本身之一部 賦型材表面之凹凡夕仙外γ 凹部或凸部之形狀等 (凹部之深度、凸部之高度、 需的凹凸花蚊，藉由客只要根據本發明之加飾成型材之所 維之粗細度等加以曰各種^組織或編織組織、所使用之纖 種，，且σ而適當決定即可。 如上所述，由於賦型材之 維，因此存在如下情开/: 一 、材為天然纖維或化學纖 鋅成型材之製造方.二.右一旦賦型材於下述本發明之加 力，則賦型材表面之凹凸會發生變^(D)中受到熱或壓 因此’假如再次使絲面之凹凸 利用本發明之製造方法来製造本發 形之賦型材，並 在難以獲得具有所需之凹凸花紋之，成型材，則存 因此，為了確實地獲得具有所f $材之情形。 型材，較佳為於本發明之加飾成型材之製= :::: 15 201127601 (A )〜（d )中，不具泠你田p估田__. . .[Technical Field] The present invention relates to a decorative molding material in which a design layer is laminated on a molding resin, a method for producing the same, and a laminate used in the production method. More specifically, the present invention relates to a method for producing a decorative molding material which is transferred by in-mold molding, and a decorative molding material produced by the manufacturing method, and for use in the production of the x-table & The method for manufacturing the laminated body, the method for manufacturing the decorative material, which is obtained by transferring the unevenness on the surface of the surface of the woven fabric, the woven fabric, the non-woven fabric, the stencil paper, etc., the metallic embossing, the coloring, and the printing A pattern or the like is simultaneously imparted to the molding resin. [Prior Art] A decorative molding material obtained by laminating a design layer having a metallic luster, a coloring, a printing pattern, or the like on a molding resin by in-mold forming transfer using an in-mold molding machine has been known. The above-mentioned decorative molding material is used as a shell of an acoustic product or other home electric appliance, and various molded articles. In Patent Document 1, it is noted that the injection molded article and the method with the following pattern are attached to the right side, and the method is characterized in that "the transfer film with the pattern attached is overlapped with the fiber material to make the After the transfer film is disposed in the injection molding die so as to face the injection hole, the synthetic resin is injection-molded from the injection hole, and a molded article having the transfer enthalpy and the fiber material adhered to the surface is obtained, and then The transfer film and the fiber material are peeled off from the molded article, and the pattern and the fiber pattern are simultaneously transferred to the surface of the molded article. 201127601 In order to impart a molded article or a printed pattern or the like as a material to be transferred, a metal film layer and a colored screen ‘ are often used in combination with each other to form a plastic film s (transfer material). There is a case where the transfer film is a transfer film or a fiber material, but a long strip and a shape is generally used. (4) When a plate type is used = a long and roll-shaped transfer film and a fiber material are used. In the case of the hanging wood, the transfer film and the fiber material are respectively disposed in different = winding devices and sent out into the mold or by winding the transfer film and the fiber material in advance. Producing a long strip and a roll-like shape: the double-layer structure is placed in the unwinding device and sent out: 1^ 〇 '8 The above-mentioned Patent Document 1 is accompanied by a pattern and is injected into a π mouth (addition molding material) It is a design that has a concave-convex embossing pattern on the surface of the fiber material as a forming material, and a metal gloss, a color, a printed pattern, and the like. [Patent Document 1] [Patent Document 1] Japanese Patent Laid-Open No. Hei 4-261819 (Draft of the Invention) [Problems to be Solved by the Invention] However, the above-described Patent Document 1 is accompanied by a pattern. The Uitj product and its manufacturing method, and the double-layered v-making tool 201127601 used in the manufacturing method have the following disadvantages. Since the transfer film and the fiber material are only brought into contact and overlapped, and the transfer film and the fiber material are not bonded to the entire surface or a part thereof, (1) the transfer film and the fiber material are disposed in the mold ( After the transfer film and the fiber material are inserted between the convex mold (male mold) and the concave mold (female mold), and correctly positioned at the molding position and fixed), the mold is present in the mold clamping (the male mold and the female mold are closed) The case where the transfer film and the fiber material are wrinkled or the transfer film or the fiber material which is laboriously positioned is displaced. As a result, there is a problem in that the injection molded article with the pattern formed thereon has a problem that a portion where the desired uneven pattern is not formed, and the metallic luster, the image, the printed pattern, and the like are not reliably imparted. Etc., can not be the design with the required design. (7) The problem that the transfer film and the fiber material in the double-layer structure are easily displaced by the method of producing the injection molded article with the pattern by the following method, the transfer mold is previously Fiber: A long and light double-layer structure is produced by winding, and the double-layer structure is placed in an unwinding device and sent out into the mold. = The problem that the transfer film and the fiber material are offset at the time point is wide. "The object of the present invention is that in order to eliminate all the above-mentioned disadvantages, it is possible to obtain the (five) convexity by transferring the profiled surface." , which is a gloss, a coloring, a printed pattern, and the like, and is clear and embossed with gold and has excellent productivity. π 驮 驮 至 成型 成型 成型 成型 成型 , , , , , , : : : : : : : : : : : : : : : : : : : : And "the decorative molding material, and the laminate used in the manufacturing method. [Technical means for solving the problem] The present invention relates to a method for producing a decorative molding material, which is a method for manufacturing a decorative molding material obtained by laminating a design layer on a molding resin, and comprising the following steps: ' (A a method of forming a transfer layer of a design layer and a sheet-like profile of at least one of the masks on the surface of the plastic film such that the other side of the plastic film is in contact with the uneven surface of the shaped material (8) The laminated body is disposed in the injection molding die so that the side surface of the design layer is directed to the injection hole; (C) after the mold clamping, the laminated body is laminated; The molding resin in a molten state is ejected from the ejection hole into the cavity, and the unevenness of the molding material is transferred to the transfer material and at least the side surface of the design layer of the molding resin, thereby obtaining (9) after cooling the transfer laminate The plastic film of the material and the material is peeled off from the transfer laminate to obtain a transfer molding material having a concave-convex pattern formed on the design layer and the side surface of the design layer of the molding resin; In the step (A), it is preferable that the upper transfer material and the above-mentioned molding material are bonded together by a linear bonding portion. In particular, it is preferable that the transfer material and the above-mentioned molding material are bonded together by a linear bonding portion formed by a double-sided tape. Further, the present invention relates to a decorative molding material obtained by laminating a design layer formed on a molding resin by the above-described manufacturing method, characterized in that a design layer and at least a side surface of a design layer of a molding resin are formed. There is a concave-convex pattern obtained by transferring the unevenness of the above-mentioned shaped material. 6 201127601 Further, the present invention is a laminate which is used in the above-described manufacturing method, and is characterized in that it is a transfer material in which a design layer is formed on a surface of a plastic film and a sheet having at least one surface having irregularities. The shaped profile is partially bonded such that the other surface of the plastic film is in contact with the uneven surface of the shaped material. [The laminated body is preferably a laminated body obtained by laminating the above-mentioned transfer material and the above-mentioned shaped material by a linear bonding portion. In particular, a laminate in which the transfer material and the molding material are bonded together by a linear bonding portion formed by a double-sided tape is preferable. [Effects of the Invention] The decorative material of the present invention, the method for producing the same, and the laminate used in the production method have the above-described characteristics, and therefore have the following advantageous effects. In the present invention, since the transfer film and the molding material are not only brought into contact with each other but also overlapped, the transfer film and the molding material portion are bonded to each other. Therefore, 1. The transfer material and the molding material are disposed in the mold & t causes wrinkles in the transfer material and the profile at the time of mold clamping, or shifting of the transfer material or the profile which causes laborious positioning. As a result, the decoration manufactured by the production method of the present invention has a problem that (4) does not exist, and the portion where the desired irregularities are not formed is produced. Therefore, in the decorative molding material of the present invention produced by the production method of the present invention, a clear embossing pattern is surely formed, and at the same time, metal luster, & print, pattern, and the like are simultaneously and surely imparted. Therefore, it is possible to obtain a decorative molding material having a desired design. 201127601 2. When the decorative molding material of the present invention is produced by using a long strip-shaped laminated body obtained by laminating a transfer material and a molding material in advance, a transfer material and a laminate of a laminate are not produced. The problem of profile offset. Thus, since the transfer material of the present invention does not shift during the operation of the transfer material and the molding material, there is no problem that the correct positioning cannot be performed in the mold, or the transfer material and the molding material are biased when the laminated body is initially manufactured. The problem of moving. [Embodiment] The decorative molding material of the present invention produced by the method for producing a decorative molding material of the present invention is obtained by laminating a design layer on a molding resin. Further, the decorative molding material of the present invention is characterized in that an uneven pattern is formed on the surface layer side surface of the μ leaf layer and at least the molding resin (the surface of the resin which is in close contact with the design layer). The embossing pattern is formed by transferring irregularities on the surface of the molding material used in the production method of the present invention. The molding material used in the production method of the present invention is in the form of a sheet, and is composed of, for example, a woven fabric, a woven fabric, a non-woven fabric, a crepe paper, or the like. The profile has an embossed pattern on at least the surface of the face. Here, the "concave and convex surface" of the surface of the shaped material refers to the surface shape of the woven fabric, the woven fabric, the non-woven fabric, and the constituting material. In other words, it is a surface shape formed by exposing fibers such as a woven fabric, a tablet, a non-woven fabric, a crepe paper, etc., which are embossed materials, to the surface of the woven fabric, woven fabric, non-woven fabric, Japanese paper, or the like. Further, the decoration of the present invention produced by using the above-mentioned molding material is applied to the design layer thereof and at least the design (4) of the molding (4) surface has the concave-convex pattern in which the surface shape of the above-mentioned profile is reversed and transferred. Therefore, the term "embossing pattern" as used in the present invention means that the ridge shape of the thief type is reversed and the surface of the transfer surface 卩# is formed by the convex portion of the surface of the transfer profile to form a concave pattern of the profile, and the zirconium is divided into a The embossed pattern of the molding material is added. Cost-of-cost First, the manufacturing layer body of the embossed molding material of the present invention will be described. The above-mentioned laminated system using π will form a design layer of a paste layer and a surface of at least one of the enamel films to form a slab-shaped profile of the above-mentioned plastic film (with the surface on which the design layer is formed) The opposite side is obtained by partially adhering to the above-mentioned shaped material in such a manner that the uneven surface is in contact with each other. The transfer film used for forming the decorative molding material of the present invention is formed on the early surface of the plastic film to form a design layer. The stomach design layer herein refers to the manufacturing method of the present invention to accumulate the layer on the resin, and is required to obtain the desired decorative molding material: the collective design of all the layers, not only refers to: The decorative molding material is given to the metal, the metal, the metal color, the printing pattern, and the like: a metal film layer for imparting metallic luster, a color layer for coloring, and a printing pattern for imparting The printed layer) is also used to obtain the adhesive layer which is used to adhere the layer to the molding resin, and to transfer the design layer to the protective layer of the surface of the decorative layer without damage or corrosion. A general term for all the layers needed to decorate a molding. The metal thin film layer and the colored layer 'printed layer constituting the decorative layer may be 9 201127601 single layer' or in order to obtain a desired design, the layers may be appropriately combined to form a plurality of layers. For example, the decorative molding material of the present invention can be imparted with a metallic luster by using a transfer # having a design layer in which a metal thin layer and a coloring layer are combined. Further, by using a transfer material having a design layer in which a metal thin film layer and a printing layer are combined, a decorative pattern and metallic luster can be imparted to the decorative molding material of the present invention. also. Further, the layer may be formed on the entire surface of the transfer material, or may be partially formed. 7 Further, the entire surface of the protective layer, which is the respective layers of the design layer, the printed layer, and the like, may be partially formed. That is, the decorative layer (metal thin film layer ', the adhesive layer, etc. can be formed on the transfer material to form which layer is formed on the entire surface, or which layer is partially formed, as long as it is appropriately combined according to the design of the desired decorative molding material. The decision can be made. = [This] by forming the design layer itself or the layers constituting the design layer on the entire surface of the transfer material or partially forming it, the (four) molding material manufactured by the present invention p is also a design layer. By itself or in the design of the design ^: each layer is laminated on the entire surface or part of the decorative molding material. Therefore, it is possible to manufacture a decorative molding material having a change in design. The layers constituting the above design layer (the decorative layer [ The metal layer, the printed layer, and the protective layer are described in more detail. As the metal thin film layer, the material is imparted with a metallic luster, and the copper thin film layer and the chromium thin film layer are formed into a silver thin film as long as it can be used in the present invention. For the decoration restrictions, aluminum thin enamel layer, nickel thin film layer and tin film layer can be used. 10 201127601 The thickness of the metal film layer can be appropriately determined according to the desired metallic luster. In addition, as a method of forming a metal thin film layer, a known method such as a vacuum distillation method can be used. As the colored layer, a film obtained by mixing a coloring agent such as a dye or a pigment into a resin such as an acrylic resin or a polyester resin can be used. The colored layer can be formed by a method such as a gravure printing method or a reverse coating method, etc. The amount of the coloring agent or the thickness of the colored layer can be appropriately determined depending on the degree of coloration desired. As the printing layer, a film made of printing ink can be used. The printing layer can be formed by printing a printing ink into a pattern by a known method such as a screen printing method or a gravure printing method. The desired printing pattern is appropriately determined, that is, the above-mentioned adhesive layer is a film made of a resin, and is a layer for adhering the decorative layer to the molding resin. The resin used for the adhesive layer is as close as possible to the resin. The resin for molding the resin is not particularly limited, and an acrylic resin, a polyester resin, a gas-vinyl resin, and an ethylene-vinyl acetate copolymer resin can be used. The type of the resin to be used in the adhesive layer may be appropriately determined depending on the type of the molding resin to be transferred. This is a film made of a resin which protects the surface of the decorative layer from damage. Or corrosion, etc. 11 201127601 It is also possible to make the protective layer a hard coating layer which is particularly difficult to cause damage. Also, the protective layer can be a layer which is easy to peel off from the plastic film. In such a case, it is not necessary to use The release plastic film (the plastic film having the release layer) is used as the plastic film. The resin used for the protective layer is not particularly limited as long as it is a resin which can protect the surface of the decorative layer from damage or corrosion, and an acrylic system can be used. A resin such as a resin, a polystyrene resin, a gas-ethylene resin, or a vinyl-vinyl acetate copolymer resin. Next, the above-mentioned design layer and plastic film constituting the transfer material are described. Resin stripper. #, After the transfer, only the design layer formed on one side of the plastic film remains on the molding resin and becomes a part of the decorative molding material. As the plastic film, a previously known plastic film such as a polyethylene terephthalate film, a polypropylene film 'polyethylene film, and a polyamide film can be used. a The thickness of the plastic film is preferably 3 to 5 〇 "claw. The degree is thinner than 3 A m, the plastic film may produce a heart m and is not preferable in the manufacture of the decorative molding material of the present invention. On the other hand, if the thickness is When it is thicker than π", there is a case where the unevenness of the surface of the molding material cannot be transferred to the molding resin or the design layer, and as a result, the desired uneven pattern may not be formed in the decorative molding material of the present invention, which is not preferable. In order to easily peel off the above-mentioned design layer from the plastic film, it is preferable to form a layer of 12 201127601 which is composed of a resin on the film (between the film and the film of 5 and 30 layers). The release plastic film thus formed with the release layer is also included in the plastic film. When the release layer is formed on the transfer material of the plastic film, the release layer is peeled off from the plastic film by the transfer film after the transfer, and only the design layer remains on the molding resin. As a specific constitution of the above-mentioned transfer material (plastic film and design layer), examples thereof include a plastic film/release layer/protective layer/decorative layer/adhesive layer, plastic film/release layer/decorative layer/thickness The composition of layers. / Further, the shape of the transfer material may be a plate-shaped (short-sized piece) or a long piece (long-sized piece). In the case of using the long transfer material 1 , the product can be continuously produced: the invention of the decorative molding material. Further, in the case of using a long transfer material, it is preferably in the form of a roll in terms of handling. The thickness, width, and length of the transfer crucible may be appropriately determined according to the size required for the addition of the crucible according to the present invention. The molding material used for producing the decorative molding material of the present invention is used in the design layer of the decorative molding material of the present invention and at least the design of the molding resin. The embossing pattern is formed by the unevenness of the surface of the material, and the forming material is a woven fabric, a woven fabric, a non-woven fabric, or a member having at least one surface having irregularities. 4 pieces Therefore, it is of course possible to have irregularities on both sides of the surface of the profiled material. As the material of the above-mentioned textile or woven fabric, it may be a natural fiber such as cotton aphid, or by Ping Sa, dry seven, hemp, from poly 3 曰 secret fat, polypropylene resin, polyethylene resin, 13 201127601 polyamide Any of chemical fibers composed of a resin, an acrylic resin, or the like. Organization ΐ,,:: Textile organization ‘the existence of plain weave, twill weave, forged double back tissue. In the weft knitting, the thousand-needle coil, the rib structure, and the above-mentioned non-woven fabric Μ π , , the material can use the same natural fiber or chemical fiber as the woven fabric or the woven fabric. When the shaped material is a woven fabric or a woven fabric, the woven fabric or the woven structure, the used ‘take, the production< _ rental fineness 荨 can be added to the various groups S', and the shaped material is not woven. In this case, the surface shape (concavity and convexity) of the shaped material can be varied by changing the basis weight: As a result, the embossing pattern of the decorative molding material of the present invention produced by using the molding material can be easily made into various types. When the textile structure or the weave structure of the fabric or the woven fabric is a simple plain weave or a flat stitch, and the unevenness of the surface of the woven fabric or the woven fabric is a monotonous unevenness of the pattern of the same pattern. The decorative molding material of the present invention produced by using the woven fabric or the woven fabric forms a monotonous embossing pattern which is repeated without changing the same pattern. Also, one of the surfaces of the woven fabric (9) or the woven fabric is formed with various textile patterns or woven patterns such as patterns and waterdrop patterns: or a three-dimensional pattern such as a woven or woven pattern is used. ) The profile. Since the decorative shape of the fiber of the present invention produced by using the above-mentioned shaped material is transferred with the surface shape of the fiber constituting the woven fabric or the woven fabric and the above-mentioned textile pattern, woven pattern, and three-dimensional pattern, it is possible to obtain a monotonous shape of 201127601 A embossed pattern, a embossed embossed pattern, a embossed embossed pattern, and a pattern of a decorative pattern that is pleasing to the temperament of the woven fabric or the woven fabric. 'There is a design with a monotonous concave λ pattern and a flat pattern that is complementary to the design of the decorative texture of the ^ i 丄 & Zhuhua pattern. In order to transfer the flat pattern, a resin or the like is applied, and the pattern formed by the flat portion of the woven fabric or the bat fabric is cut into a pattern. The pattern pattern is formed by, for example, partially flattening one of the surfaces of the surface of the woven fabric or the woven fabric, and forming a concave surface of the surface of the woven fabric or the woven fabric itself. The shape of the outer γ concave portion or the convex portion, etc. (the depth of the concave portion, the height of the convex portion, and the desired embossed mosquito, can be made by the customer according to the thickness of the decorative molding material according to the present invention, etc.) The weaving structure, the type of fiber used, and the σ can be appropriately determined. As described above, due to the dimension of the profile, there is the following situation: 1. The material is a manufacturer of natural fiber or chemical fiber zinc molding material. 2. Right Once the profiled material is subjected to the force of the present invention described below, the unevenness of the surface of the profiled material may be subjected to heat or pressure in the process of (D), so that if the unevenness of the surface of the wire is again used, the manufacturing method of the present invention is used. The shape of the present invention is made, and it is difficult to obtain a molded material having a desired uneven pattern. Therefore, in order to obtain the material having the desired material, the profile is preferably decorated with the present invention. forming The system = :::: 15 201127601 (A) ~ (d), the non-Ling your field estimation field p __...
形之凹凸恢復成原本之凹凸，恢復後之賦型材當然亦可於 上述步驟（A)〜（D)中再次使用。 狀態使用已使用過一 ，攸而再次使用。即’並非依照原本之 一次之賦型材，而是使因熱或壓力而變 若使用長條之賦型材， 又，賦型材之形狀亦可為版紙狀或長條物之任一種。 則可連續生產本發明之加飾成型 材。進而，於使用長條之賦型材之情形時，就操作方面而 言，較佳為輥狀。 賦^•材之厚度、寬度、長度只要根據本發明之加飾成 型材之所需的大小而適當決定即可。 本發明之積層體可藉由將上述轉印材與賦型材部分貼 合而獲得。此時，以使塑膠膜之非設計層面（與形成有設 計層之面相反之面）與賦型材之凹凸面相接觸之方式而將 轉印材與賦型材加以貼合。 於將轉印材與賦型材部分貼合時，進行貼合之部分（貼 合部）之形狀可採用點狀 '線狀等適當之形狀。又，在選 擇點狀之情形之點的大小（點的面積）或點的間隔與在選 擇線狀之情形之線的粗細度或長度等只要根據本發明之加 飾成型材之所需的大小、形狀等而適當決定即可。 作為將轉印材與賦型材部分貼合之方法，可例示如下 16 201127601 方法：將接著劑或黏著劑等塗佈 至邯於轉印材之塑膠膜或賦型 材從而進行貼合之方法；如市售 炙雙面膠帶使用預先於基 材（紙或塑膠膜等）之雙面塗佈右垃益如^ 至师有接者劑或黏著劑等之膠 帶等進行貼合之方法；以及藉由 稭由利用熱或超音波等之融著 進行貼合之方法等。 其中，於利用雙面膠帶而形成之線狀之貼合部將轉印 材與賦型材加以貼合之方法較簡便，故而較佳。 積層體中之貼合部之位置只要根據所製造之本發明之 加飾成型材而適當決定即可。 關於本發明之加飾成型材之製造中所使用之成型樹 脂，可使用 ABS (acryl0nitrile_butadiene styrene，丙烯猜_ 丁二稀-苯乙稀共聚物）樹脂、ps(p〇lystyrene，聚苯乙稀） 樹脂、pp( P〇iypropylene，聚丙烯）樹脂、pc( p〇iycarb〇nate， 聚碳酸醋）樹脂、PVC ( polyvinyl chi〇ride，聚氯乙稀）樹 月曰' AS ( acrylonitrile-styrene ,丙烯腈_笨乙烯共聚物）樹 脂及PMMA ( P〇lymethyl methacrylate，聚甲基丙烯酸甲醋） 樹脂等丙烯酸系樹脂等樹脂，其中較佳為熱塑性樹脂。 成型樹脂之形狀係根據本發明之加飾成型材之所需的 形狀而適當決定。 再者，成型樹脂係以將與上述相同之樹脂製成顆粒 狀、粉狀等之成型用樹脂作為原料，利用本發明之製造方 法’使成為炼融狀態，自射出孔射出至模穴内，並進行冷 卻’藉此與設計層積層。 其次’對本發明之加飾成型材之製造方法進行說明。 17 201127601 如上所述，本發明之加飾成材之製造方法係製造於成 型樹脂上積層有設計層而成之加飾成型材之方法，其特徵 在於包括如下步驟： (A)將於塑膝膜之一面形成有言史計層巾成之轉印材與 至少一面具有凹凸之賦型材以使上邊塑膠膜之另—面與上 述賦型材之上述凹凸面相接觸之方式而部分貼合，從而獲 得積層有轉印材及賦型材之積層體； ()將上述積層體以使設計層側面向射出孔之方式而 配設於射出成型用模具内； ()於將上述模具閉合後，將熔融狀態之成型用樹脂 出孔射出至模穴内，並將上述賦型材之凹凸轉印至轉 卩# & ^成型樹脂之設計層側表面’從而獲得轉印積層 體；以及 (D)於將上述轉印積層體冷卻後，將賦型材及轉印材 之塑膠膜自該轉印積層體剝離，從而獲得於設計層及至少 成型樹脂之設計層側表面形成有凹凸.花紋之加飾成型材。 上述步驟（A)〜（D)之順序為步驟（a)、步驟（B)、 步驟（C )及步驟（D )之順序。 首先對各步驟進行說明。 <步驟（A ) > 為如下㈣：首&，將於塑膠膜之一面形成有設計層 轉P材與至少一面具有凹凸之片肖大賦型材以使上述塑膠 、另面（與形成有設計層之面相反之面）與上述賦型 述凹凸面相接觸之方式而部分貼合，從而獲得積層 18 201127601 有轉印材及職型材之積層體。 轉P材及賦型材之形狀可為版紙狀或長條物之任_ 種。於長條物之愔报吐 1、 夺丨.，就操作方面而言’較佳為輥狀。 如上所述，眩# c ‘， 將轉印材與賦型材加以貼合之部分Γ 部）之形狀可採用此 丨刀（貼合 休用點狀、線狀等適當之形狀。 在選擇點狀之情形之點的大小（點的面 的間隔與在選揠蠄灿+ & 價^ a點 、，之情形之線的粗細度或長度等只要根 踩本發明之加傲占荆^^ 即可。 冑成&材之所需的大小、形狀等而適當決定 將轉印材與賦型材部分貼合之方法如上所述。 、又’上述貼合部之1位置只要根據所製造之本發明之加 飾成型材而適當決定即可。 然而，由於上述貼合部附著有接著劑或黏著劑等或貼 附有膠帶等，或者貼合部本身被融著，因此與未貼合 分相比’貼合部之厚度變得略厚等使厚度產生差異。並且。 =上之差異而於由轉印#與賦型材所構 體中，在貼合部與其以外之部分之間產生微小之段差 因此，於將積層體配設於射出成型用模具内（步驟 時，若上述貼合部進入上述模穴内，則於將上述 八) 後，將熔融狀態之成型用樹脂自射 、σ 得轉印積層體（步驟（c))時，存在/出至模穴内而獲 ^ ^吁，存在如下情形：於 及至少成型樹脂之設計層側表@ # 衣面不僅轉印賦型材表面之凹The concave shape of the shape is restored to the original unevenness, and the restored shaped material can of course be used again in the above steps (A) to (D). The status usage has been used one time and is used again. That is, the profile is not changed in accordance with the original one, but is changed by heat or pressure. If the profile is used, the shape of the profile may be either a paper or a long article. Then, the decorative molding material of the present invention can be continuously produced. Further, in the case of using a long profile, it is preferably a roll in terms of handling. The thickness, width, and length of the material to be used may be appropriately determined according to the size required for the decorative molding of the present invention. The laminate of the present invention can be obtained by laminating the above-mentioned transfer material and the profile portion. At this time, the transfer material and the molding material are bonded so that the non-design layer of the plastic film (the surface opposite to the surface on which the design layer is formed) is brought into contact with the uneven surface of the molding material. When the transfer material and the molding material portion are bonded to each other, the shape of the bonded portion (bonding portion) may be a shape such as a dot-like shape. Further, the size (area of the dot) or the interval between the dots at the point of selecting the dot shape and the thickness or length of the wire in the case of selecting the linear shape are as long as the size required for the decorative molding material according to the present invention. The shape, shape, etc. can be appropriately determined. As a method of bonding the transfer material and the molding material portion, the following method can be exemplified as follows: 16 201127601 Method: a method of applying an adhesive or an adhesive to a plastic film or a molding material applied to a transfer material to perform lamination;炙Double-sided tape is applied by double-sided coating of the substrate (paper or plastic film, etc.) on the double-sided tape, such as a tape to the master or adhesive, etc.; A method of bonding by heat or ultrasonic or the like. Among them, the method of bonding the transfer material and the molding material to the linear bonding portion formed by the double-sided tape is preferable, and therefore it is preferable. The position of the bonding portion in the laminate may be appropriately determined depending on the decorative molding material of the present invention to be produced. For the molding resin used in the production of the decorative molding material of the present invention, ABS (acryl0nitrile_butadiene styrene) resin, ps (p〇lystyrene, polystyrene) can be used. Resin, pp (P〇iypropylene, polypropylene) resin, pc (p〇iycarb〇nate, polycarbonate) resin, PVC (polyvinyl chiride), acrylonitrile-styrene A resin such as an acrylic resin such as a nitrile-based ethylene copolymer resin or a PMMA (P〇lymethyl methacrylate) resin, and a thermoplastic resin is preferable. The shape of the molding resin is appropriately determined according to the desired shape of the decorative molding material of the present invention. In addition, the molding resin is formed into a molding state by using a resin which is formed into a pellet or a powder in the same manner as the above-mentioned resin, and is formed into a molten state by the manufacturing method of the present invention, and is ejected from the injection hole into the cavity. Perform cooling 'by this to layer with the design layer. Next, a method of producing the decorative molding material of the present invention will be described. 17 201127601 As described above, the manufacturing method of the decorative material of the present invention is a method of manufacturing a decorative molding material obtained by laminating a design layer on a molding resin, which comprises the following steps: (A) a knee-length film will be formed One side of the surface is formed with a transfer material having a history of a tissue layer and a profile having at least one surface having irregularities so as to partially contact the other surface of the upper plastic film in contact with the uneven surface of the shaped material, thereby obtaining a laminate a laminated body of a transfer material and a shaped material; () the laminated body is disposed in the injection molding die so that the side surface of the design layer faces the injection hole; () after the mold is closed, the molten state is used for molding The resin outlet hole is ejected into the cavity, and the unevenness of the above-mentioned profile is transferred to the side surface of the design layer of the molding resin to obtain a transfer laminate; and (D) the transfer laminate is formed After cooling, the plastic film of the molding material and the transfer material is peeled off from the transfer laminated body, thereby obtaining irregularities formed on the design layer and at least the side surface of the design layer of the molding resin.The order of the above steps (A) to (D) is the order of the steps (a), (B), (C) and (D). First, each step will be described. <Step (A) > is as follows (4): First &, a plastic layer on one side of the plastic film is formed with a design layer to turn the P material and at least one side of the sheet having the relief surface to make the above plastic, the other surface (with the design The surface opposite to the surface of the layer is partially bonded to the surface of the above-mentioned shaped concave-convex surface to obtain a laminate 18 201127601 A laminate having a transfer material and a profile. The shape of the transfer P material and the profile material may be any type of paper or long strip. In the case of long strips, it is reported as a shot. In terms of operation, it is preferably a roll. As described above, the shape of the part Γ of the glare #c', which is to be bonded to the transfer material and the shape-receiving material, can be used as a squeegee (a suitable shape such as a point shape or a line shape). The size of the point of the situation (the interval between the faces of the dots and the thickness or length of the line in the case of the selection of the + and the price of the point, as long as the root of the invention is proud of the ^^ The method of appropriately bonding the transfer material and the profile portion to the size, shape, and the like required for the material is as described above. Further, the position of the above-mentioned bonding portion is as long as the present invention is manufactured. The decorative part may be appropriately determined by the addition of the molding material. However, since the bonding portion or the adhesive or the like adheres to the bonding portion, or the bonding portion itself is fused, it is compared with the unattached portion. The thickness of the bonding portion becomes slightly thicker or the like to cause a difference in thickness. And the difference in the upper portion causes a slight difference between the bonding portion and the portion other than the bonding member and the member. , when the laminated body is placed in the mold for injection molding (in the case of When the bonding portion is placed in the cavity, after the above-mentioned eight), the molding resin in a molten state is self-emissive and σ is transferred to the laminated body (step (c)), and is present in/out of the cavity. ^,, there are the following situations: at least the design side of the molding resin side table @ #衣面 not only transfer the concave surface of the profile
凸，亦由於上述段差之影響而—併轉印貼合部之 Z 段差而形成之形狀）。 （由 19 201127601 其結果，利用士 丨 中亦形成如下花紋.、月之製造方法而製造之加倚成型材 表面除轉印所需之四㈣計層及至少成型樹脂之設計層側 狀而成之花紋。凸化紋以外，亦形成轉印貼合部之形 H ^ ^上所述，為了不於本發明之加飾成型材形成 印有貼合部之形妝 φ取生材形成轉 之製造方法中，於將j &佳為於本發明之加飾成型材 雜時，預先《使m/與^㈣㈣合而獲得積層 不進入模穴中之二*鎖模後之模穴之外部之方式（以 將兮接Μ Μ 式）而將轉印材與賦型材部分貼合，而 亥積層體配設於射出成型用模具内。 而 因此’較佳為本發明夕接a 4 後的模穴之外部之方Γ 合部位於鎖模 可藉由進入模穴中之方式)而形成。 製造方法而製造之加飾t操作’而防止於利用本發明之 合部之花紋）。 t材形成無需之花紋（轉印有貼 又，關於將轉印材與賦型材加以貼合 於即將插入模且内之义斗，土 于門點，可為 材加以貼合，别’或者’亦可預先將轉印材與賦型 成為觀狀）之任=狀亦可為版紙狀或長條物（亦可捲繞 <步驟（B ) > 2如下步驟：將上述積層體以使設計層側面向射 ，而配設於射出成型用模具内〇. 此處，所謂將積層體配設於射出成型用模具内， 201127601 將由轉印材與賦型材所構成之積層體插入凸模具（陽模） 與凹模具（陰模）之間’正確地定位於成型之位置並固定。 又，、將積層體以使設計層側面向射出孔之方式而=設 於射出成型用模具内’其原因在於，於下述步驟（c)中在 自射出孔所射出之成型用樹脂之所需之位置正確地形成設 計層。 οχ <步驟（C ) > 為如下步驟：於鎖模後，將熔融狀態之成型用樹脂自 射出孔射出至上述模具之模穴内，並使成型用樹脂融著於 t述積層體，藉此將上述賦型材之凹凸轉印至轉印材及至 V成型樹脂之設計層側表面，從而獲得轉印積層體。 ,、此處’所謂將上述賦型材表面之凹凸轉印至轉印材及 至J成型樹脂之設計層側表自，係指於轉印材（於單面形 成有設計層之塑膠膜）及至少成型樹脂之設計層側表面（與 ❸十層密接之成型樹脂之面）形成賦型材表面之凹凸正好 反轉而成之凹凸，換言之係p a t…，志 以“將轉印材及至少成型樹脂之 。又计層側表面成型為賦型材表 凸狀。 止好反轉而成之凹 因此，步驟（C )中之轉印積層體 成型樹脂按照賦型材[凹 材、轉印材及 順序進行積層）成為如下社構.认絲“層成型祕月日之 , 、、。構.於轉印材（塑膠膜與設計 層）及至少成型樹脂之設計 a ^ ^ ^ 側表面形成賦型材表面之凹 凸正好反轉而成之凹凸花紋。 為了將賦型材表面之凹凸 p至轉印材及至少成型樹 21 201127601 脂之設計層你丨矣& „ ^ _ !表面，必須於鎖模後，將熔融狀態之成型用 樹月曰自射出孔射出至模穴内。 即:可藉由將熔融狀態之成型用樹脂之溫度與將熔融 冬、i用樹脂自射出孔射出至模穴内時之壓力設為適 ^溫度與恩力’而將賦型材表面之凹凸轉印至轉印材及 至 > 成型樹脂之設計層側表面。 <步驟（D ) > ，如下步驟：於將上述轉印積層體冷卻後，將賦型材 P材之塑膠膜自轉印積層體剝離，從而獲得在設計層 =少成型樹脂之設計層側表面形成有凹凸花紋之加飾成 $材〇 為如下步驟：將賦型材與塑膠膜自轉印積層體（賦 凸面〕/塑膠膜/設計層/成型樹脂）除去，而獲得由 -汁層與成型樹脂所構成之加飾成型材。於上述步驟（c) I面：！：材（塑膠膜與設計層）及成型樹脂之設計層側 成有賦型材表面之凹凸正好反轉而成之凹凸花紋。 :此二藉由將賦型材及轉印材之塑膠膜自轉印積層體剝 Γ凹凸?Γ設計層及至少成型樹脂之設計層側表面形成 有凹凸化紋之本發明之加飾成型材。 ^者，於將賦型材及轉印材之塑膠膜自轉印積層體剝 情形時，當然亦可將賦型材與塑膠膜一次剝離，作亦 :離型材剝離而剩下塑膠臈’其後將剩餘之塑膠膜 到離專，將剝離賦型材與塑膠膜之時間點錯開。 如上所述，可藉由先僅將職型材剝離而剩了塑膠臈， 22 201127601 可使塑膠膜實現保護本發明之加飾成型材之設計層側表面 不文相傷或灰塵等之保護膜之作用。 以上所述之利用本發明之加飾成型材之製造方法而製 造之本發明之加飾成型材成為於成型樹.脂積層有設計層， 並且於該設計層及與該設計層之背面相接觸之成型樹脂面 (成型樹脂之設計層側表面）形成有轉印有賦型材表 凹凸之凹凸花紋者。 由於本發明之加飾成型材具有具備上述特徵之構成， 因此成為具有凹凸花紋與金眉氺、、罢 興*屬先澤、者色、印刷圖案等相 輔相成之獨特之設計性者，並且為發揮上錢異之效果者。 本發明之加飾成型材之製造方法中所使用之本發明之 積層體係將於塑膠膜之一面形成有設計層而成之轉印材與 至>、一面具有凹凸之片狀賦型材以使而 (未形成有設計層之面)與上述賦型材之上:::::： =以㈣分貼合而成。即’本發明之積層體係轉印材 ::尘材以設計層/塑膠膜/(凹凸面）賦型材之順序 成者。 將轉印材與賦型材加以貼合之部分（ 將轉印材與賦型材部分貼合之方法或時間點如上所述 又，貼合部之位置亦如上所述，只要根據所製造之本 發明之加飾成型材而適當決定即可。 進而，於本發明之加飾成型材之製造方法中 於本發明之加飾成型材形成轉印有貼合部之形狀而成 紋，較佳為本發明之積層 化 槓禮體係以使貼合部位於鎖模後之模 23 201127601 穴的外部之方式（以不進入模穴中之方式）而形成。 本發明之積層體之形狀亦可為政紙狀或長條物（亦可 捲繞成為輥狀）之任一種。 再者，若製造預先將轉印材與賦型材加以貼合並捲繞 而成之長條且輥狀之積層體，則可不使用特別之機械，而 使用通常之模内成型機及通常之單軸猪輸送裝置（具備各 一台退繞裝置及捲繞裝置之㈣送裝置），來製造本發明 之加飾成型材，故而較佳。 又，當獲得積層體時，於採用使用雙面膠帶等使用接 者劑或黏著劑等之貼合方法之情形時，存在如下情形：於 獲得轉印積層體之步驟（c)中，由於所射出之熔融狀態之 成型用樹脂之壓力或溫度而使貼合部之接著劑或黏著劑穿 過賦型材並密接於模具’其結果，產生轉印積層體貼附於 模具之現象。 邗马用以防止該現象之方法，例如，可採用如下方法： 對應於積層體之貼合部之位置，於賦型材之外側表面：與 核具相接觸之側之表面）部分貼合另一塑膠膜等。藉由進 =如此操作，即使假設貼合部之接著劑或黏著劑穿過賦型 材，亦可藉由上述塑膠膜而防止該接著劑或黏著劑直接接 觸於模具。 ’較佳為上述另外 之大小（寬度等） 再者’為了更確實地防止上述現象 貼合之塑膠膜等以大於（寬於）貼合部 而形成。 於賦型材之外側表面 如此’對應於積層體之貼合部 24 201127601 部分貼合有塑膠臈等而成之積層體亦包含於本發明之積層 體中。 曰 【實施例] [實施例1 ] 採用如下方法：預先利用層壓裝置製造將轉印材與賦 型材部分性地貼合而成之積層體，其後，使用通常之模内 成型機及通常之單軸箔輸送裝置（具備退繞裝置及捲繞裝 置各一台之箱輸送裝置），將上述積層體設置於退繞裝置 而製造本發明之加飾成型材。 <步驟（A) > 使用層壓裝置將長條且輥狀之轉印材[厚度38 “爪之 聚對本一甲酸乙二s旨膜/脫模層/設計層a m / 接著層以聚對苯二甲酸乙二㈣面（未形成有設計層之The convex shape is also formed by the influence of the above-described step difference and the transfer of the Z section of the bonding portion. (As a result of 19 201127601, the surface of the addition molding material which is manufactured by the method of manufacturing the moon, which is manufactured by the method of the moon, is formed by the four (four) layer required for the transfer and at least the design layer of the molding resin. In addition to the convexized pattern, the shape of the transfer bonding portion is also formed as described above, in order to form the shaped material which is printed with the bonding portion without forming the decorative part of the decorative material of the present invention. In the manufacturing method, when j & is preferred in the decorative molding material of the present invention, the m/ and ^ (4) (4) are combined in advance to obtain a laminate which is not inserted into the cavity after the two * mold clamping holes The method of bonding the transfer material to the molding portion is carried out in a manner of splicing the splicing material, and the inner layer body is disposed in the mold for injection molding. Therefore, it is preferable to use the mold after the a4 The outer portion of the hole is formed by the way the mold can be inserted into the cavity. The decorative t-operation manufactured by the manufacturing method is prevented from using the pattern of the joint of the present invention). The t-material forms a pattern that is unnecessary (transfer and paste, and the transfer material and the profile material are attached to the inner bucket that is about to be inserted into the mold, and the soil is attached to the door point, and the material can be attached, not 'or' The shape of the transfer material and the shape of the transfer material may be in the form of a paper or a long strip (may also be coiled <Step (B) > 2 The following steps: the above-mentioned laminated body is designed In the injection molding die, the laminated body is disposed in the injection molding die, and the laminate formed by the transfer material and the molding material is inserted into the convex mold (the male mold). And the concave mold (female mold) is 'correctly positioned at the position of the molding and fixed. Moreover, the laminated body is placed in the injection molding mold so that the design layer side faces the injection hole'. In the following step (c), the design layer is correctly formed at a desired position from the molding resin which is ejected from the ejection hole. οχ <Step (C) > is a step of: melting after the mold clamping The molding resin of the state is ejected from the injection hole to the above mold In the mold cavity, the molding resin is melted in the laminated body, whereby the unevenness of the shaped material is transferred to the transfer material and the design layer side surface of the V molding resin to obtain a transfer laminated body. Here, the so-called transfer of the unevenness of the surface of the above-mentioned shaped material to the transfer material and the design layer side of the J-shaped resin refers to the design of the transfer material (the plastic film having the design layer formed on one side) and at least the molding resin. The layer side surface (the surface of the molding resin which is in close contact with the ten layers of the enamel) forms the unevenness of the surface of the profiled surface, which is reversed, in other words, the pat..., the "transfer material and at least the molding resin. The surface is formed into a convex shape of the profiled sheet. The concave portion is formed by reversal. Therefore, the transfer laminated body molding resin in the step (C) is formed as follows according to the molding material [concave material, transfer material, and order). Knowing the silk "layer molding secret moon day, ,,. The design of the transfer material (plastic film and design layer) and at least the molding resin a ^ ^ ^ The side surface forms a concave-convex pattern in which the concave surface of the profiled surface is reversed. In order to transfer the unevenness of the surface of the profile to the transfer material and at least the design layer of the molding tree 21 201127601 grease, you must use the tree-shaped raft to form the molten state after the mold is clamped. The injection is carried out into the cavity. That is, the profile can be formed by setting the temperature of the molding resin in a molten state to the pressure at which the molten winter and the resin are ejected from the injection hole into the cavity. The surface unevenness is transferred to the transfer material and to the design layer side surface of the molding resin. <Step (D) >, as follows: After cooling the transfer laminate, the plastic film of the profile P material is rotated The printed laminate is peeled off, thereby obtaining a decorative material having a concave-convex pattern formed on the side surface of the design layer of the design layer = less molding resin as follows: the self-transferring laminated body (plastic surface) / plastic of the molding material and the plastic film The film/design layer/molding resin is removed to obtain a decorative molding material composed of a juice layer and a molding resin. In the above step (c) I: :: material (plastic film and design layer) and molding resin Design layer side The unevenness of the surface of the profile is reversed. The second is formed by peeling the plastic film of the profile and the transfer material from the transfer laminate. The design layer and at least the side surface of the design layer of the molding resin are formed with irregularities. The decorative molding material of the invention according to the invention. ^When the plastic film of the shaping material and the transfer material is peeled from the transfer layer body, of course, the shaping material and the plastic film may be peeled off once, and the peeling of the profile material is also performed. The remaining plastic 臈' will then leave the remaining plastic film to the special point, staggering the time between the stripping of the profile and the plastic film. As mentioned above, the plastic enamel can be left by peeling off only the job profile, 22 201127601 The plastic film can be used to protect the side surface of the design layer of the decorative molding material of the present invention from the surface protective film or the protective film of dust, etc. The above-described manufacturing method using the manufacturing method of the decorative molding material of the present invention The decorative molding material of the invention is formed in the molding tree. The fat layer has a design layer, and the molding layer and the molding resin surface (the side surface of the design layer of the molding resin) which are in contact with the back surface of the design layer are formed with a transfer. Since the decorative molding material of the present invention has the above-described characteristics, the decorative molding material of the present invention has a embossed pattern and a golden eyebrow, and a singularity, a singularity, a color, a printing pattern, and the like. The unique design is used to exert the effect of the money. The laminated system of the present invention used in the method for producing a decorative molding material of the present invention is formed by forming a design layer on one side of the plastic film. And a sheet-like shaped material having irregularities on one side so that (the surface on which the design layer is not formed) and the above-mentioned shaped material are:::::: = (4) is bonded together. The laminated system transfer material: the dust material is formed in the order of the design layer/plastic film/(concave surface). The part where the transfer material and the profiled material are attached (the method of bonding the transfer material and the profile part) Alternatively, as described above, the position of the bonding portion may be as described above, and may be appropriately determined depending on the decorative molding material of the present invention to be produced. Further, in the method for producing a decorative molding material according to the present invention, the decorative molding material of the present invention is formed into a shape in which the bonding portion is transferred, and it is preferable to laminate the layered bar system of the present invention. The part is located outside the mode of the mold 23 201127601 (formed in a manner that does not enter the cavity). The shape of the laminate of the present invention may be any of a paper-like shape or a long article (which may be wound into a roll shape). Further, if a long and roll-like laminated body obtained by laminating and transferring a transfer material and a molding material in advance is manufactured, a normal in-mold molding machine and a usual single-axis pig can be used without using a special machine. It is preferable that the conveying device (the (four) feeding device of each of the unwinding device and the winding device) is used to manufacture the decorative molding material of the present invention. Further, when a laminated body is obtained, in the case of using a bonding method using a contactor or an adhesive such as a double-sided tape, there is a case where, in the step (c) of obtaining a transfer laminated body, When the pressure or temperature of the molding resin in the molten state is emitted, the adhesive or the adhesive of the bonding portion is passed through the molding material and adhered to the mold. As a result, the transfer laminated body is attached to the mold. The method for preventing the phenomenon by the hummer, for example, the following method may be employed: corresponding to the position of the bonding portion of the laminated body, the surface on the outer side surface of the forming material: the surface contacting the side of the nucleus) partially fitting the other Plastic film, etc. By doing so, even if the adhesive or adhesive of the bonding portion is passed through the molding material, the adhesive or the adhesive can be prevented from directly contacting the mold by the above-mentioned plastic film. It is preferable that the size (width, etc.) of the above-mentioned another is formed to be larger than (wider than) the bonding portion in order to prevent the above phenomenon from being more reliably prevented. The outer surface of the shaped material is such that the laminated portion corresponding to the laminated body is also included in the laminated body of the present invention. [Examples] [Example 1] A laminate in which a transfer material and a molding material were partially bonded together was previously produced by a laminating apparatus, and thereafter, a usual in-mold molding machine and a usual one were used. A uniaxial foil conveying device (a tank conveying device each having an unwinding device and a winding device) is provided, and the laminated body is placed in an unwinding device to manufacture the decorative molding material of the present invention. <Step (A) > Using a laminating apparatus, a strip-shaped and roll-shaped transfer material [thickness 38" of the claws is gathered to the original formic acid ethylene s film/release layer/design layer am / subsequent layer to a pair Ethylene (tetra) phthalate (not formed with a design layer
1尼、=由^縱/橫=32根/3〇根之線密度對粗細度為25Q 由平紋二：m線進行平紋織而形成之表裏兩面具有 型材;凹凸的長條且輥狀之平紋組織物(賦 材與賦型材之二二：:長條且輥狀之積層體。轉印 东藉由線狀之貼合部而谁并， 係藉由於轉印材或職型材之兩端部（於長度方向：。部 :邊緣部)貼合寬度5mm之雙面膠帶：：伸之 邊緣所形成者。 長度方向之兩 位於 )而 使積層體（轉印材與賦型材）之 鎖模後之模穴的外Λ )之貼 卜之方式（以不進入模穴中之 帶與雙面穋帶之間隔，從而形成積層 25 201127601 <步驟（B ) > 於將上述積層體設置於單軸络輸送裝置之退繞裝置 中，並向模内成型機側送出後，將上述積層體以使設計層 側面向射出孔之方式而配設於模内成型機之射出成型用模 具内。 <步驟（C ) > 於將上述模具鎖模後，將熔融狀態之AB s樹脂（成型 用樹脂）自射出孔射出至模穴内，從而獲得使成型樹脂融 著於上述積層體而成之轉印積層體。上述轉印積層體係由 賦型材（平紋組織物）/轉印材（聚對笨二曱酸乙二酯膜/ 脫模層/設計層）/ABS樹脂所構成，且於轉印材及至少ABS 樹脂之設計層側表面轉印有上述凹凸。 <步驟（D ) > 於將上述轉印積層體冷卻後，將平紋組織物及轉印材 之聚對苯二甲酸乙二酯膜與脫模層自轉印積層體剝離，從 而獲得由設計層及ABS樹脂所構成之本發明之加飾成型 材。於上述設計層及ABS樹脂之設計層側表面形成有轉印 有平紋組織物之上述凹凸而成之凹凸花紋。 再者，轉印後之積層體係利用捲繞裝置進行捲繞。 所製造之實施例1之本發明之加飾成型材於鎖模時不 會導致轉印材及賦型材產生皺褶、或費力定位之轉印材或 賦型材發生偏移’具有平紋組織物之凹凸依照原樣轉印而 成之凹凸花紋與鋁之金屬光澤相輔相成之獨特的設計性。 又，實施例1之本發明之加飾成型材不會產生上述凹 26 201127601 凸化紋於加舞成型材之長度方向（長邊方向）或寬度方向 (紐邊方向）上部分變得不清晰等不良，而於加飾成型材 之整體形成有清晰之凹凸花紋。 再者，於製造積層體時轉印材與賦型材均不會發生偏 移進而於將積層體設置於退繞裝置中等對積層體進行操 作時轉印材與賦型材亦不會發生偏移。 [實施例2] 才木用如下方法：使用通常之模内成型機及通常之雙軸 V自輸送裝置（具備纟2台退繞裝置及捲繞裝置之箔輸送裝 置），製造本發明之加飾成型材，且於退繞裝置與模内成 型機之間設置層壓裝置，於即將進行模内成型之前獲得將 轉印材與賦型材部分貼合而成之積層冑，從而製造本發明 之加飾成型材。 <步驟（A ) > 分別將長條且輥狀之轉印材[厚度38 之聚對苯二 曱酸乙二酯膜/脫模層/設計層（保護層/鋁薄膜層/接著層） 設置於退繞裝置…將藉由以縱/橫巧議根之線密 度對粗細纟250丹尼之聚0旨線進行平紋織而形成之表裏兩 面具有平紋組織之凹凸的長條且幸昆狀之平紋組織物 材）設置於退繞裝置2中。 其次，將轉印材及平紋組織物分別自退繞裝置i 繞裝置2向層磨裝置側送出，並使用層壓裝置，以與實施 例1相同之方式，以利用兩面膠帶所構成之線狀之貼 將轉印材與賦型材（平紋組織物）之兩邊緣加以貼合，^ 27 201127601 而獲得積層體。 <步驟（B ) > 將上述積層體向模内成型機側送出，並且將上述積層 體以使設計層側面向射出孔之方式而配設於模内成型機之 射出成型用模具内。 <步驟（C)〉 以與實施例1相同之方式獲得轉印積層體。 <步驟（D ) > v 以與實施例1相同之方式，製造於設計層及abs樹脂 之設計層側表面形成有轉印平紋組織物之上述凹凸而成之 凹凸花紋的本發明之加飾成型材。 再者，轉印後之積層體係利用捲繞裝置1或捲繞裝置2 進行捲繞。 所製造之實施例2之本發明之加飾成型材於鎖模時不 會導致轉印材及賦型材產生皺褶、或費力定位之轉印材或 賦型材發生偏移’具有平紋組織物之凹凸依照原樣轉印而 成之凹凸花紋與鋁之金屬光澤相辅相成之獨特的設計性。 “又，實射"《本發明之加飾成型材不會產生上述凹 2花紋於加飾成型材之長度方向或寬度方向上部分變得不 清晰等不良，而於加飾成型材之整體形成有清晰之凹凸“ [實施例3、4] 除了使用基重 布作為賦型材以外 量為25g/m2且由聚 ’以與實施例1、2 酯樹脂所構成之不織 (使用平紋組織物作 28 201127601 為賦型材）相同之方式，分別製造實施例3、4之本發明之 加飾成型材。 所製造之實施例3、4之本發明之加飾成型材的任—者 於鎖模時不會導致轉印材及賦型材產生皺褶、或費力定位 之轉印材或賦型材發生偏移，具有不織布之凹凸依照原樣 轉印而成之凹凸花紋與鋁之金屬光澤相輔相成之獨特的設 計性。 又，實施例3、4之本發明之加飾成型材之任一者均不 會產生上述凹凸花紋於加飾成型材之長度方向或寬度方向 上部分變得不清晰等不良，而於加飾成型材之整體形成有 不織布特有之無規則且清晰之凹凸花紋。 再者，實施例3之本發明之加飾成型材於製造積層體 時轉印材與賦型材均不會發生偏移，進而於將積層體設置 於退繞裝置中等對積層體進行操作時轉印材與賦型材亦不 會發生偏移。 [實施例5、6] 除了使用長條且輥狀之轉印材[厚度38 # m之聚對苯 一甲酸乙二酯膜/脫模層/設計層（保護層/藉由將黑色顏料混 树月曰中而著色成黑色之著色層/接著層）]作為轉印材以 外以與實施例1、2 (作為設計層，包含由鋁所構成之金 屬薄膜層’不含著色層）相同之方式，分別製造實施例5、 6之本發明之加飾成型材。 所製造之實施例5、6之本發明之加飾成型材的任一者 均於鎖模時不會導致轉印材及賦型材產生㈣、或費力定 29 201127601 位之轉印材或賦型材發生偏移’具有平紋組織物之凹凸依 照原樣轉印而成之凹凸花紋與黑色相輔相成之獨特的設計又 性0 又，實施例5、6之本發明之加飾成型材之任一者均不 會產生上述凹凸花紋於加飾成型材之長度方向或寬度方向 上部分變得不清晰等不良，而於加飾成型材之整體形成有 清晰之凹凸花紋。 再者，實施例5之本發明之加拂成型材於製造積層體 時轉印材與賦型材均不會發生偏移，進而於將積層體設置 於退繞裝置中等對積層體進行操作時轉印材與賦型材亦不 會發生偏移。 ' [比較例1] 以不使用雙面膠帶將轉印材及平紋組織物（賦型材） 加以貼合而僅將轉印材及平紋組織物重疊獲得雙層構造體 之步驟代替實施例1之獲得積層體乏步驟，以及使用該雙 層構造體代替實施例1之積層體，除此以外以與實施例i 相同之方式製造加飾成型材。 所製造之比較例1之加飾成型材係形成有轉印平紋組 織物之凹凸而成之凹凸花紋者。 然而’比較例1之加飾成型材於鎖模時轉印材及賦型 材產生皺褶、或費力定位之轉印材或賦型材發生偏移，其 結果’產生凹凸花紋於加飾成型材冬長度方向或寬度方向 上部分變得不清晰等不良。 再者’有時於製造雙層構造體時轉印材與賦型材發生 30 201127601 偏移，進而有時於將雙層構造體設置於退繞裝置中等對雙 層構造體進行操作時轉印材與賦型材發生偏移。 [比較例2] 以不利用層壓裝置將轉印材及平紋組織物（賦型材） 用雙面膠帶加以貼合而僅將轉印材及平紋組織物重疊獲得 雙層構造體之步驟代替實施例2之獲得積層體之步驟，以 及使用該雙層構造體而代替實施例2之積層體，除此以外 以與實施例2相同之方式製造加飾成型材。 所製造之比較例2之加飾成型材係形成有轉印平紋組 織物之凹凸而成之凹凸花紋者。 然而，比較例2之加飾成型材於鎖模時轉印材及賦型 材產生皺褶、或費力定位之轉印材或賦型材發生偏移，其 結果，產生凹凸花紋於加飾成型材之長度方向或寬度方向 上部分變得不清晰等不良。 1 【圖式簡單說明】 無 【主要元件符號說明】 無 311 Ni, = from vertical / horizontal = 32 / 3 〇 root line density to thickness 25Q from plain weave: m line for plain weave formed on both sides of the surface with profiles; concave and long strips and roll-like plain Organisms (two-two of the material and the profile): a long strip and a roll-like laminate. The transfer east is made up of a linear fitting and the other is due to the transfer material or the ends of the profile ( In the length direction: part: edge part) fit the double-sided tape of width 5mm: the edge formed by the extension. The two of the length direction are located) and the cavity of the laminated body (transfer material and the profile material) after the mold clamping The outer layer of the Λ 之 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 After the unwinding device of the apparatus is fed to the in-mold forming machine side, the laminated body is placed in the injection molding die of the in-mold forming machine so that the side surface of the design layer faces the injection hole. C) > After the mold is clamped, the AB s resin in the molten state (molding resin) The transfer layer is ejected into the cavity to obtain a transfer layered body in which the molding resin is fused to the laminate. The transfer layer system is composed of a profiled material (plain structure)/transfer material (poly-p-benzoic acid) The ethylene glycol film/release layer/design layer)/ABS resin is formed, and the unevenness is transferred to the design layer side surface of the transfer material and at least the ABS resin. [Step (D) > After the laminate is cooled, the polyethylene terephthalate film of the plain weave and the transfer material and the release layer are peeled off from the transfer laminate to obtain the decorative molding material of the present invention composed of the design layer and the ABS resin. A concave-convex pattern in which the unevenness of the plain weave is transferred is formed on the design layer side surface of the design layer and the ABS resin. Further, the laminated system after the transfer is wound by a winding device. The decorative molding material of the present invention of the first embodiment does not cause wrinkles of the transfer material and the profiled material during the mold clamping, or the transfer material or the profiled material which is laboriously positioned is displaced. The unevenness of the plain weave structure is transferred according to the original sample. Made The decorative pattern of the embossed pattern and the metallic luster of aluminum complement each other. Moreover, the decorative molding material of the present invention of the first embodiment does not produce the concave portion 26 201127601 convex pattern in the longitudinal direction of the dance molding material (long side direction) Or the part in the width direction (the direction of the rim) becomes unclear, and the entire surface of the decorative molding material is formed with a clear embossing pattern. Furthermore, the transfer material and the molding material are not offset when the laminated body is manufactured. Further, when the laminated body is placed in the unwinding device or the like, the transfer material and the shaped material are not displaced when the laminated body is operated. [Example 2] The following method is used for the wood: using a conventional in-mold molding machine and usually A biaxial V self-conveying device (a foil conveying device having two unwinding devices and a winding device), manufacturing the decorative molding material of the present invention, and providing a laminating device between the unwinding device and the in-mold forming machine A laminate of the transfer material and the profile portion is obtained immediately before the in-mold molding, thereby producing the decorative molding material of the present invention. <Step (A) > A long and roll-shaped transfer material [polyethylene terephthalate film/release layer/design layer (protective layer/aluminum film layer/adhesion layer) of thickness 38) It is set in the unwinding device... It will be formed by plain weaving of the thickness of the 纟250 丹 之 以 以 以 纟 纟 纟 纟 纟 纟 丹 丹 丹 丹 丹 丹 丹 丹 丹 丹 丹 丹 丹 丹 丹 丹 丹 丹 丹The plain weave material) is disposed in the unwinding device 2. Next, the transfer material and the plain weave are separately fed from the unwinding device i to the layer grinding device side by the unwinding device i, and using a laminating device, in the same manner as in the first embodiment, a linear line composed of double-sided tape is used. The laminate is bonded to both edges of the transfer material (plain texture), and 27 27201127601 to obtain a laminate. <Step (B) > The laminated body is fed to the in-mold forming machine side, and the laminated body is placed in the injection molding die of the in-mold forming machine so that the side surface of the design layer faces the injection hole. <Step (C)> A transfer layered body was obtained in the same manner as in Example 1. <Step (D) > v In the same manner as in the first embodiment, the present invention is formed on the design layer and the side surface of the design layer of the abs resin, and the embossed pattern obtained by transferring the unevenness of the plain weave is formed. Decorative moldings. Further, the laminated system after the transfer is wound by the winding device 1 or the winding device 2. The decorative molding material of the present invention produced in the second embodiment does not cause wrinkles in the transfer material and the molding material during the mold clamping, or the transfer material or the molding material which is laboriously positioned to be displaced, and the unevenness of the plain weave structure is The unique design of the embossed pattern of the original transfer and the metallic luster of aluminum complement each other. "Further, real shot" "The decorative molding material of the present invention does not cause the above-mentioned concave 2 pattern to be unclear in the longitudinal direction or the width direction of the decorative molding material, and the entire decorative molding material is not good. Clear concavities and convexities were formed "Examples 3, 4] In addition to the use of a base fabric as a profile, the amount of 25 g/m 2 and the polyester to be woven with the ester resins of Examples 1 and 2 (using plain weave In the same manner as in the case of the profiled material, the decorative molding materials of the present invention of Examples 3 and 4 were produced. Any of the decorative molding materials of the present invention of Examples 3 and 4 produced in the present invention does not cause wrinkles in the transfer material and the molding material during the mold clamping, or the transfer material or the molding material which is laboriously positioned is displaced. The non-woven fabric is uniquely designed in accordance with the original embossed pattern and aluminum metallic luster. Further, in any of the decorative molding materials of the present invention of the third and fourth embodiments, the uneven pattern is not caused to be unclear in the longitudinal direction or the width direction of the decorative molding material, and the decorative portion is not decorated. The entire molding material is formed with a random and clear embossing pattern unique to the nonwoven fabric. Further, in the decorative molding material of the present invention of the third embodiment, the transfer material and the molding material are not displaced when the laminated body is produced, and the transfer material is disposed when the laminated body is placed on the unwinding device or the laminated body. There is also no offset from the profile. [Examples 5 and 6] In addition to the use of a long and roll-shaped transfer material [polyethylene terephthalate film / release layer / design layer of thickness 38 # m (protective layer / by mixing black pigment) In the same manner as in the first and second embodiments (the design layer includes a metal thin film layer made of aluminum, which does not contain a colored layer), the coloring layer/adhesive layer which is colored in black in the moonlight is used as the transfer material. The decorative molding materials of the present invention of Examples 5 and 6 were separately produced. Any of the decorative molding materials of the present invention manufactured in Examples 5 and 6 does not cause the transfer material and the molding material to be produced during the mold clamping (4), or the transfer material or the molding material of the 201120110601 position is biased. The unique design of the embossed pattern which has the unevenness of the embossed structure and the black embossed by the original pattern is 0. The decorative molding materials of the present invention of Examples 5 and 6 are not produced. The uneven pattern is partially unclear in the longitudinal direction or the width direction of the decorative molding material, and a clear uneven pattern is formed on the entire decorative molding material. Further, in the twisted molding material of the present invention of the fifth embodiment, the transfer material and the molding material are not displaced when the laminated body is produced, and the transfer material is disposed when the laminated body is placed on the unwinding device or the laminated body. There is also no offset from the profile. [Comparative Example 1] A step of laminating a transfer material and a plain weave without using a double-sided tape, and superposing only the transfer material and the plain weave to obtain a two-layer structure, instead of obtaining the laminate in the first embodiment A decorative molding material was produced in the same manner as in Example i except that the steps were omitted and the two-layer structure was used instead of the layered body of Example 1. The decorative molding material of Comparative Example 1 produced was formed into a embossed pattern in which the unevenness of the plain weave fabric was transferred. However, in the case of the decorative molding material of Comparative Example 1, the transfer material and the molding material are wrinkled during the mold clamping, or the transfer material or the molding material which is laboriously positioned is displaced, and the result is that the embossed pattern is formed in the winter direction of the decorative molding material. Or the part in the width direction becomes unclear and the like. In addition, when the double-layer structure is manufactured, the transfer material and the molding material are offset by 30 201127601, and sometimes the double-layer structure is disposed in the unwinding device, and the transfer material and the transfer are performed when the double-layer structure is operated. The profile is offset. [Comparative Example 2] A step of laminating a transfer material and a plain weave material (a molding material) with a double-sided tape without using a laminating apparatus, and superposing only the transfer material and the plain weave structure to obtain a two-layer structure is used instead of the second embodiment. A decorative molding material was produced in the same manner as in Example 2 except that the laminate was obtained in the same manner as in Example 2 except that the two-layer structure was used instead of the laminate of Example 2. The decorative molding material of Comparative Example 2 produced was formed into a embossed pattern in which the unevenness of the plain weave fabric was transferred. However, in the decorative molding material of Comparative Example 2, the transfer material and the molding material are wrinkled during the mold clamping, or the transfer material or the molding material which is laboriously positioned is displaced, and as a result, the concave and convex pattern is generated in the longitudinal direction of the decorative molding material. Or the part in the width direction becomes unclear and the like. 1 [Simple diagram description] None [Main component symbol description] None 31