201036792 六、發明說明: 【發明所屬之技術領域】 [0001] 本發明涉及一種模内裝飾成型方法及以該方法製成的模 製品。 【先前技術】 [〇〇〇2] —般物品、汽車、家電、消費型電子產早等的外觀表面 塗裝方式分有液體塗裝、粉體塗裝、靜電塗裝以及電泳 塗裝幾種,以塗裝方式進行表面加工完全無法處理圖樣 ’並且在塗覆具有平面與側邊的大片基板時,由於基板 〇 的側邊尺寸與平面尺寸袓較之下甚為懸殊,故當喷漆進 行到塗覆基板的侧邊時,相當多的噴漆將會累積於側邊 J 。經由時間演變,一種改良式旋塗機應用於基材的塗覆 ’此種旋塗機利用離心力將液態塗劑滴落於欲塗覆的水 平基板表面中部,再將基板水平面經由高速旋轉進行塗 覆層的塗布。但其問題在於基板轉折邊緣的端部容易產 生塗覆層厚度不均勻的現象。 〇 [0003]隨著外觀設計的進步與消費者對於外觀的要求標準提高 ,用於各種產品的殼體亦講求具有高光澤的表面以及多 變的彩色圖案’習知用以形成高光澤表面殼體的作法為 對其做習稱鋼琴烤漆的表面喷漆,但其過程必須將成品 放於無塵室巾進行數道喷漆料,再靜置數天以乾燥, 如此-來不僅拉長製造時間,且由於進❹道喷漆之後 ’會造成產品上烤漆的膜料平均或麵厚造成龜裂, 另外經過多道喷漆工序,其最終成品的總體良率降低, 造成成本的;Mi提高。另-種達到高辆度表面的製造 098111790 表單編號A0101 第3頁/共32頁 0982019464-0 201036792 方法為將成型的模具内表面進行鏡面拋光,使其模具内 表面高度光亮,再將原料射出成塑。由此法所製成的產 品表面硬度無法達到一般業界的耐磨耗標準,很容易造 成刮痕及表面亮度降低。 [0004] 為達到表面的高光澤度、多變的彩色圖案以及表面的耐 磨損要求,現有技術以模内裝飾成型轉印具有高光澤衫 色圖案來達成上述要求,其中係採用裝飾薄膜,該裝飾 薄膜主要包括載體層、離型層、硬質保護層(硬化層)、 油墨層以及粘著層。其中該載體層用於承載油墨以及轉 〇 印高光澤彩色圖案的作用,用來將上述其他各層轉印到 位在成型模具内的成型塑件上,待成型完成後,載體層 藉由離型層的作用從成型塑件上剝雜°在載艟層剝離後 ,硬質保護層以及具有彩色圖案的油墨層被粘著層粘著 在塑件表面。硬質保護層通常還需經過熱烘烤或紫外線 照射硬化成為透明材料後,造成高光澤效果並起到保護 塑件及油墨層不被磨損及到損的作用。關於此種技術的 前案可參見日本專利第3546034號,第3895896號,台灣 ◎ 專利第350820號,美國專利第5993588號。該技術揭露 的裝飾薄膜具有離型層與硬化層,且在成型開模時,載 體層與離型層從粘著在塑件表面的硬質保護層上剝離, 在成型後的塑件與轉印後裝飾薄膜上的硬化層與油墨層 無法切齊’且硬化層的厚度在5微米(5em)以内,通常經 不起比較嚴重的外力刮傷。經長時間的使用後,硬化層 會被磨耗,造成光澤度降低,甚至彩色圖案亦會受到磨 損。且離型層與載體層經剝離後無法再利用,製作成本 098111790 表單煸號A0101 第4頁/共32頁 0982019464-0 201036792 偏7¾ ◊ [0005] ❹ Ο [0006] [0007] 另外一種習知技術,參照美國專利第58〇〇759號專利案以 及日本專利號第4-1 〇923號,美國專利第58〇〇759號揭示 了利用-傳送裝置3G將-薄媒7置於—裁切模1〇中該裁 切模10用以將該薄W裁料適當的形狀或大小。接著, 該傳送裝置3G將該裁切後的薄膜7由裁切模1〇中取出,並 將其置於射出模1内。由於該位於射出模i内的薄膜7並未 被定位,故當進行射膠時,射膠的流動及其所產生的射 壓易使該薄膜7產生移位或皴折,該薄膜7因而無法完整 包覆於塑件,且由於薄臈7需先裁切為適當的形狀或大小 ,其必須有一定的厚度才能保持裁切後的形狀,這樣一 來會導致成本的增加。參照圖丨丨所示,其顯示該美國前 案第5800759號所製成的產品斷面示意圖,其中,塑件 700的邊緣710未受裝飾薄膜800完全包覆而露出,此一 成型方法的加工步驟複雜、成品的品質不穩定且不美觀 ' _ . .:! 〇 【發明内容】 鑒於以上内容,有必要提供一種加工步驟簡單、成品的 品質穩定的模内裝飾成型方法及以該方法製成的模製品 〇 一種模内裝飾成型方法,包括以下步驟:提供一貼附薄 膜;將貼附薄膜送入模内裝飾成型模具,使貼附薄膜的 一選定區域貼靠於模穴内;進行第一次合模,公模的分 模面與母模的分模面之間未接觸;對模穴進行射膠;進 行第二次合模,使公模的分模面與母模的分模面接觸, 09811Π90 表單編號A0101 第5頁/共32頁 0982019464-0 201036792 並使該貼附薄膜的選定區域自貼附薄膜上切下;充填完 成,停止射膠;開模取出成型的模製品。 [0008] —種模製品,係運用上述的模内裝飾成型方法所製成, 該模製品包括基材及貼附薄膜,該基材具有一第一周緣 端面,該貼附薄膜具有一第二周緣端面,其中該貼附薄 膜的第二周緣端面與該基材的第一周緣端面大致齊平。 【實施方式】 [0009] 請參閱圖1,本發明是使用一種模内裝飾成型模具進行模 内裝飾成型,該模内裝飾成型模具包括一送膜裝置15、 一母模25及一公模30。 [0010] 該送膜裝置15包括一對薄膜傳送輪及一對導向輪。該對 薄膜傳送輪分設於模具上下游,用於牽引薄膜。所述導 向輪用於對薄膜的傳送方向進行引導。 [0011] 母模25於一面開設模穴22。母模25自具模穴22的一面至 相對另一面貫穿開設若干排氣槽,用於與抽真空裝置相 連以將由送膜裝置15送入的薄膜吸附於模穴22的内壁。 [0012] 公模30的分模面上開設一凹槽24,在該公模30的分模面 上設有一切割部26。該公模30包括與母模25的模穴22相 對應的配合部。配合部大致在其中央位置開設有貫穿公 模30的射膠口用於將熔融狀態的塑膠注入母模25的模穴 22内。請參閱圖2,可以理解的是,亦可在該母模25的分 模面上沿該模穴22周圍開設一凹槽24’ ,進而在該模穴 22的周圍形成一切割部26’ 。 [0013] 請參閱圖5,本發明模内裝飾成型方法的第一實施方式包 098111790 表單編號A0101 第6頁/共32頁 0982019464-0 201036792 括以下步驟: [0014]步驟S102,提供一貼附薄膜1〇(); 剛步驟SHM,使用送膜裝置15牽引貼附薄膜ι〇〇並使貼附 薄膜l〇m母模25的分模面送料模25與公模3〇之間 並將其壓制定位於母模25的分模面上。使貼附薄膜1()〇的 一選定區域貼靠在母模25的模穴22的内壁,如圖3所示。 較佳實施方式是通過騎模25的模穴22進行抽真空的方 法將貼附薄膜100吸附於母模25的模穴22。 陶㈣則6,進行第—次合模,但此時公獅的分模面與 母模25的分模面之間尚未接觸。 _步驟S108 ’進行射膠,由公模3〇側進行射移至成型樹脂 充填總量的90%-99. 5%,優選方案為99. 5%,形成模製品 基材;貼附在模穴22内的貼附薄膜100枯著在模製品基材 的表面,如圖4所示。 _ «SlU),進行第二次合模,使公獅的分模面與母模 25的分模面之間接觸,在第减合模的同時將剩餘的充 填量進行射膠充填,同時,在公獅的分模面的掩壓下 ’公模30的切割部26將枯著在模製品基材表面的貼附薄 膜100的選定區域自貼附薄膜1〇〇上切下,使其與送膜裝 置15上的貼附薄膜1〇〇脫離。 、 [0019] 步驟S112,充填完成,停止射膠。 [0020] 步驟S114,冷卻。 [0021] 步骤S116 H模,將模製品頂出,即可得到表面附著有 098111790 表單編號A0101 第7頁/共32頁 0982019464-0 201036792 貼附薄膜100的模製品;同時,送膜裝置15將貼附薄膜 100位於該成型週期内的部分自公、母模30、20之間移出 ,並開始下一成型週期。 [0022] 請參閱圖6,本發明模内裝飾成型方法的第二實施方式包 括以下步驟: [0023] 步驟S202,提供一連續的貼附薄膜100 ; [0024] 步驟S204,使用送膜裝置15牽引連續的貼附薄膜100並 使貼附薄膜100沿著母模25的分模面送到母模25與公模 30之間並將其壓制定位於母模25的分模面上。並使貼附 薄膜100的一選定區域貼靠在母模25的模穴22的内,如圖 3所示。模具設有一切割部26或26’ 。 [0025] 步驟S206,進行合模。 [0026] 步驟S208,進行射膠,將模製品基材成形於模穴22内的 貼附薄膜100之上,如圖4所示。 [0027] 步驟S210,利用該模具的切割部26或26’將粘著在模製 品基材表面的貼附薄膜1 00的選定區域自連續的貼附薄膜 100上切下,使其與連續的貼附薄膜100脫離。 [0028] 步驟S212,充填完成,停止射膠。 [0029] 步驟S214,冷卻。 [0030] 步驟S216,開模,將模製品基材頂出,即可得到表面附 著有貼附薄膜100的模製品。 [0031] 上述模内裝飾成型方法將貼附薄膜利用送膜裝置進行自 098111790 表單編號A0101 第8頁/共32頁 0982019464-0 201036792 動送膜,進而實現貼附薄膜的連續送膜,並直接在模内 進行裁切,不僅可以得到著色牢固,不易磨損的塑膠件 ,而且可以實現連續自動化生產,生產效率提高,使成 品的品質提高,並增加美觀的效果。 [0032] Ο [0033] 請參照圖7Α、7Β,利用上述模内裝飾成型方法製成一模 製品10,該模製品10包括一基材200及一貼附薄膜100, 該基材200具有一頂面201與一側緣202圍繞該頂面201, 該貼附薄膜100貼附於該基材200上,並完全包覆該頂面 201。 請參照圖8Α、8Β,利用上述模内裝飾成型方法製成另一 模製品20,該模製品20包括一基材300及一貼附薄膜500 ,該基材300具有一頂面301與一侧緣302圍繞該頂面301 ,該貼附薄膜500貼附於該基材300上,並完全包覆該頂 面301及該侧緣302。 [0034] Ο 在本實施例中,該貼附薄膜500具有一第二周緣端面501 ,該基材300具有一第一周緣端面303,該貼附薄膜500 的第二周緣端面501與該第一周緣端面303相銜接,且該 貼附薄膜500的第二周緣端面501與該基材300的第一周 緣端面303為大致齊平。 [0035] 請參照圖9Α為沿圖7Β的9-9剖面線所取的剖視圖,該貼附 薄膜100包括一基體層102、一裝飾層104及一黏著層106 〇 基體層102卷附在送膜裝置上並在成型後貼附於該基材 200的表面,對其内的裝飾層104起保護作用,使裝飾層 098111790 表單編號Α0101 第9頁/共32頁 0982019464-0 [0036] 201036792 104及基材200免於磨損及刮花。基體層1〇2一般由聚碳 酸醋(pc)、聚對苯二甲酸乙二醇酯(PET)、聚甲基丙 烯酸甲酯(PMMA)、定向聚丙烯(opp)、聚氣乙烯”代 )等一種或兩種以上的高分子材料製成的單層膜,或者 由選自於則述材料中兩種或兩種以上製成的積層膜或共 聚合物膜。由於本發明的模内裝飾成型方法不需先對貼 附薄膜100、500裁切為適當的形狀或大小,而是利用送 膜裝置15進行自動送膜,而使貼附薄膜1〇〇、5〇〇受到送 膜裝置15的支撐,所以貼附薄膜100、5〇〇的基體層厚度 可以較薄’優選的厚度介於〇· 01毫米至Q 125毫米之間 ,以節省成本。 [0037] 在該基體層1〇2内表面,形成有可顯示圖案及色彩等的裝 飾層104。請參閱圖9B,裝飾層1〇4是由若干油墨層1〇41 、1 042及1043用網版印刷於基體層1〇2上所形成,每一 油墨層的厚度介於0. 005毫米至〇. 〇2毫米之間。此外, 亦可利用真空蒸鍍法、真空濺鍍法等提供一由鋁、鉻、 銅、鎳、銦、錫中一種或一種以上製成的金屬膜層作為 該裝飾層104,這種裝飾層1〇4可使模製品表面呈現金屬 色澤。 [0038] 該黏著層106具有將該貼附薄膜100與模製品基材2〇〇結 合的效果’且最好使用丙烯酸樹_、硝化纖維素樹醋、 聚胺基甲義樹脂、氣化橡膠㈣、氣乙烯_醋酸乙歸 共聚合物樹酯、聚醯胺樹酯、聚酯樹酯、環氧樹脂、聚 碳酸樹醋、雜樹S旨、丙烯腈-丁烯—笨乙婦樹醋等作 為該黏著層106的材料。_著層1〇6以便在黏著性及印 098111790 表單煸號A0101201036792 VI. Description of the Invention: [Technical Field of the Invention] [0001] The present invention relates to an in-mold decorative molding method and a molded article produced by the method. [Prior Art] [〇〇〇2] Appearance surface coating methods for general items, automobiles, home appliances, and consumer electronics are divided into liquid coating, powder coating, electrostatic coating, and electrophoretic coating. When the surface is processed by the coating method, the pattern cannot be processed completely, and when the large substrate having the flat surface and the side is coated, since the side dimension of the substrate 与 is very different from the plane size ,, when the painting is carried out When the sides of the substrate are coated, a considerable amount of paint will accumulate on the side J. Through time evolution, an improved spin coater is applied to the coating of a substrate. This spin coater uses centrifugal force to drip the liquid paint on the middle of the surface of the horizontal substrate to be coated, and then coats the substrate level through high-speed rotation. Coating of the coating. However, the problem is that the end portion of the substrate turning edge is liable to cause uneven thickness of the coating layer. 〇[0003] With the advancement of design and the increasing standard of consumer requirements for appearance, the housing for various products also emphasizes a high-gloss surface and a variety of color patterns, which are conventionally used to form high-gloss surface shells. The practice of the body is to paint the surface of the piano paint, but the process must put the finished product in a clean room towel to carry out several painting materials, and then let it sit for several days to dry, so - not only lengthen the manufacturing time, Moreover, due to the average or thickness of the film on the product after the paint is applied to the raft, the overall yield of the finished product is reduced, resulting in cost reduction; Another type of manufacturing to achieve high degree of surface 098111790 Form No. A0101 Page 3 / Total 32 pages 0992019464-0 201036792 The method is to mirror the inner surface of the formed mold, so that the inner surface of the mold is highly bright, and then the raw material is injected into Plastic. The surface hardness of the product produced by this method cannot meet the abrasion resistance standards of the general industry, and it is easy to cause scratches and surface brightness reduction. [0004] In order to achieve the high gloss of the surface, the variable color pattern, and the wear resistance of the surface, the prior art achieves the above requirements by in-mold decorative transfer printing with a high-gloss shirt color pattern, wherein a decorative film is used. The decorative film mainly comprises a carrier layer, a release layer, a hard protective layer (hardened layer), an ink layer, and an adhesive layer. Wherein the carrier layer is used for carrying ink and transferring a high-gloss color pattern for transferring the other layers to the formed plastic part in the forming mold. After the forming is completed, the carrier layer is separated by a release layer. The action is stripped from the molded part. After the carrier layer is peeled off, the hard protective layer and the ink layer having the color pattern are adhered to the surface of the plastic part by the adhesive layer. The hard protective layer usually needs to be hardened by thermal baking or ultraviolet irradiation to become a transparent material, which causes a high gloss effect and protects the plastic parts and the ink layer from being worn and damaged. For a prior art of such a technique, see Japanese Patent No. 3546034, No. 3895896, Taiwan ◎ Patent No. 350820, and U.S. Patent No. 5,993,588. The decorative film disclosed by the technology has a release layer and a hardened layer, and when the mold is opened, the carrier layer and the release layer are peeled off from the hard protective layer adhered on the surface of the plastic part, and the molded part and the transfer after molding The hardened layer on the back decorative film cannot be aligned with the ink layer' and the thickness of the hardened layer is within 5 micrometers (5 cm), and generally cannot withstand severe external force scratches. After prolonged use, the hardened layer will be worn away, causing a decrease in gloss and even the color pattern will be worn. Moreover, the release layer and the carrier layer can not be reused after being peeled off, and the manufacturing cost is 098111790. Form No. A0101 Page 4/32 pages 0992019464-0 201036792 Partiality 73⁄4 ◊ [0005] ❹ Ο [0006] [0007] Another conventional knowledge For the technique, reference is made to U.S. Patent No. 5,759,759, and Japanese Patent No. 4-1, 923, and U.S. Patent No. 5,759,759, the disclosure of which is incorporated herein by reference. The cutting die 10 in the die 1 is used to cut the thin W into an appropriate shape or size. Next, the conveying device 3G takes out the cut film 7 from the cutting die 1 and places it in the shooting die 1. Since the film 7 located in the injection mold i is not positioned, when the glue is applied, the flow of the glue and the resulting pressure tend to cause the film 7 to be displaced or collapsed, and the film 7 cannot be It is completely covered in the plastic part, and since the thin raft 7 needs to be cut into an appropriate shape or size, it must have a certain thickness to maintain the shape after cutting, which leads to an increase in cost. Referring to FIG. 3, it shows a schematic cross-sectional view of the product made by the U.S. Patent No. 5800759, wherein the edge 710 of the plastic member 700 is not completely covered by the decorative film 800, and the molding process is processed. The steps are complicated, the quality of the finished product is unstable and unsightly ' _ . . :! 〇 [Invention content] In view of the above, it is necessary to provide an in-mold decorative molding method with simple processing steps and stable quality of the finished product and made by the method Molded article 〇 an in-mold decorative molding method comprising the steps of: providing an attached film; feeding the attached film into the in-mold decorative molding mold, and a selected area of the attached film is placed in the cavity; Once the mold is closed, there is no contact between the parting surface of the male mold and the parting surface of the master mold; the glue is applied to the cavity; the second clamping is performed to make the split surface of the male mold and the partial mold of the female mold Face contact, 09811Π90 Form No. A0101 Page 5 / Total 32 pages 0992019464-0 201036792 and cut the selected area of the attached film from the attached film; filling is completed, the injection of glue is stopped; mold is taken out by molding[0008] A molded article is produced by using the above-described in-mold decorative molding method, the molded article comprising a substrate and an attached film, the substrate having a first peripheral end surface, the attached film having a first And a second peripheral end surface, wherein the second peripheral end surface of the attached film is substantially flush with the first peripheral end surface of the substrate. [Embodiment] Referring to FIG. 1, the present invention uses an in-mold decorative molding die for in-mold decoration molding, and the in-mold decorative molding die includes a film feeding device 15, a master mold 25, and a male mold 30. . [0010] The film feeding device 15 includes a pair of film conveying wheels and a pair of guiding wheels. The pair of film transfer wheels are disposed upstream and downstream of the mold for pulling the film. The guide wheel is used to guide the conveying direction of the film. [0011] The master mold 25 opens the cavity 22 on one side. The master mold 25 has a plurality of exhaust grooves extending from one side of the cavity 22 to the other side for connection with the vacuuming device to adsorb the film fed from the film feeding device 15 to the inner wall of the cavity 22. [0012] A groove 24 is formed on the parting surface of the male mold 30, and a cutting portion 26 is provided on the parting surface of the male mold 30. The male mold 30 includes a mating portion corresponding to the cavity 22 of the master mold 25. The fitting portion is provided with a rubber injection port penetrating the male mold 30 at a central portion thereof for injecting molten plastic into the cavity 22 of the female mold 25. Referring to Fig. 2, it can be understood that a groove 24' may be formed around the cavity 22 on the parting surface of the die 25 to form a cutting portion 26' around the cavity 22. [0013] Referring to FIG. 5, a first embodiment of the in-mold decoration molding method of the present invention includes a package 098111790, a form number A0101, a sixth page, a total of 32 pages, a number of 0982019464-0, 201036792, including the following steps: [0014] Step S102, providing an attachment Film 1 〇 (); just step SHM, using the film feeding device 15 to pull the film 〇〇 贴 and attach the film splitting die 25 of the film 〇m master 25 to the male die 3 并将 and The pressure is set on the parting surface of the master mold 25. A selected area of the attached film 1 () is placed against the inner wall of the cavity 22 of the master mold 25 as shown in FIG. In a preferred embodiment, the attached film 100 is adsorbed to the cavity 22 of the master mold 25 by vacuuming the cavity 22 of the rider 25. Tao (4) is 6, the first time the mold is clamped, but at this time, the parting surface of the male lion is not in contact with the parting surface of the master mold 25. _Step S108 'Adhesive injection, from the side of the male mold 3 to the side of the molding resin to 90% -99. 5%, the preferred solution is 99. 5%, forming a molded article substrate; attached to the mold The attached film 100 in the cavity 22 is dried on the surface of the molded article substrate as shown in FIG. _ «SlU), the second clamping is performed to make the contact between the parting surface of the male lion and the parting surface of the female mold 25, and the remaining filling amount is filled at the same time as the lowering of the mold, and at the same time, Under the masking of the split surface of the male lion, the cutting portion 26 of the male mold 30 cuts the selected portion of the attached film 100 that has been dried on the surface of the molded substrate from the attached film 1〇〇 to make it The attached film 1 on the film feeding device 15 is detached. [0019] Step S112, the filling is completed, and the glue is stopped. [0020] Step S114, cooling. [0021] Step S116 H mold, the molding product is ejected, and the surface is attached with 098111790 Form No. A0101 Page 7 / Total 32 pages 0992019464-0 201036792 The molded product of the attached film 100; at the same time, the film feeding device 15 will The portion of the attached film 100 located in the molding cycle is removed from between the male and female molds 30, 20, and the next molding cycle is started. [0022] Referring to FIG. 6, a second embodiment of the in-mold decoration molding method of the present invention includes the following steps: [0023] Step S202, providing a continuous attachment film 100; [0024] Step S204, using a film feeding device 15 The continuous attaching film 100 is pulled and the attached film 100 is fed between the master mold 25 and the male mold 30 along the parting surface of the master mold 25 and pressed into the parting surface of the master mold 25. A selected area of the attached film 100 is placed against the cavity 22 of the master mold 25, as shown in FIG. The mold is provided with a cutting portion 26 or 26'. [0025] Step S206, performing clamping. [0026] Step S208, performing a shot molding to form a molded article substrate on the attaching film 100 in the cavity 22, as shown in FIG. [0027] Step S210, using the cutting portion 26 or 26' of the mold, the selected region of the attached film 100 adhered to the surface of the molded substrate is cut from the continuous attached film 100 to be continuous with The attached film 100 is detached. [0028] Step S212, the filling is completed, and the glue is stopped. [0029] Step S214, cooling. [0030] Step S216, the mold is opened, and the molded article substrate is ejected to obtain a molded article having the attached film 100 attached to the surface. [0031] The above-mentioned in-mold decoration molding method uses a film feeding device to perform film feeding from 098111790 Form No. A0101, page 8 / 32 pages 0982019464-0 201036792, thereby realizing continuous film feeding of the attached film, and directly Cutting in the mold can not only obtain plastic parts that are firmly colored and not easily worn, but also can realize continuous automatic production, improve production efficiency, improve the quality of the finished product, and increase the aesthetic effect. [0033] Referring to FIGS. 7A and 7B, a molded article 10 is formed by the above-described in-mold decoration molding method, and the molded article 10 includes a substrate 200 and an attached film 100, and the substrate 200 has a The top surface 201 and the one side edge 202 surround the top surface 201. The attaching film 100 is attached to the substrate 200 and completely covers the top surface 201. Referring to FIGS. 8A and 8B, another molded article 20 is formed by the above-described in-mold decoration molding method. The molded article 20 includes a substrate 300 and an attached film 500 having a top surface 301 and one side. The edge 302 surrounds the top surface 301, and the attachment film 500 is attached to the substrate 300 and completely covers the top surface 301 and the side edge 302. [0034] In the present embodiment, the attachment film 500 has a second peripheral end surface 501 having a first peripheral end surface 303, a second peripheral end surface 501 of the attachment film 500, and the first The peripheral end surface 303 is engaged, and the second peripheral end surface 501 of the attached film 500 is substantially flush with the first peripheral end surface 303 of the substrate 300. [0035] Referring to FIG. 9A, a cross-sectional view taken along line 9-9 of FIG. 7A, the attached film 100 includes a base layer 102, a decorative layer 104, and an adhesive layer 106. The base layer 102 is attached to the package. The film device is attached to the surface of the substrate 200 after molding, and protects the decorative layer 104 therein, so that the decorative layer 098111790 is numbered Α0101, page 9 / total 32 pages 0992019464-0 [0036] 201036792 104 And the substrate 200 is free from abrasion and scratching. The base layer 1〇2 is generally composed of polycarbonate (PC), polyethylene terephthalate (PET), polymethyl methacrylate (PMMA), oriented polypropylene (opp), and polyethylene. a single layer film made of one or two or more kinds of polymer materials, or a laminated film or a copolymer film made of two or more kinds selected from the above materials. Since the in-mold decoration of the present invention The molding method does not need to first cut the attached film 100, 500 into an appropriate shape or size, but automatically feeds the film by the film feeding device 15, and the attached film 1 and 5 are subjected to the film feeding device 15 Support, so the thickness of the base layer to which the film 100, 5 贴 is attached may be thinner 'the preferred thickness is between 〇·01 mm and Q 125 mm to save cost. [0037] In the base layer 1〇2 The inner surface is formed with a decorative layer 104 which can display patterns, colors, etc. Referring to FIG. 9B, the decorative layer 1〇4 is screen-printed on the base layer 1〇2 by a plurality of ink layers 1〇41, 1042 and 1043. The thickness of each ink layer is between 0.005 mm and 〇. 〇 2 mm. A vacuum coating method, a vacuum sputtering method, or the like provides a metal film layer made of one or more of aluminum, chromium, copper, nickel, indium, and tin as the decorative layer 104, and the decorative layer 1〇4 can be used. The surface of the molded article exhibits a metallic color. [0038] The adhesive layer 106 has the effect of bonding the attached film 100 to the molded substrate 2' and preferably uses acrylic tree, nitrocellulose vinegar, polyamine Resin, gasified rubber (4), gas ethylene _ acetic acid ethyl co-polymeric resin, polyamine resin, polyester resin, epoxy resin, polycarbonate vinegar, miscellaneous tree S, acrylonitrile-butene - Stupid woman vinegar, etc. as the material of the adhesive layer 106. _ layer 1 〇 6 so as to be in the adhesive and printed 098111790 form nickname A0101
第1〇頁/共32 I 0982019464-0 201036792 [0039] [0040] Ο [0041] Ο 刷後乾燥方面取得較好的综合效果。形成該黏著層i 〇6的 方法可使用例如凹版印刷、網版印刷及膠版印刷等任一 種一般性印刷方法,或者例如喷塗、刷塗等方法。 在本實施方式中,該貼附薄膜10〇的基體層1〇2是透明或 者半透明的’用於顯現裝飾層1〇4的圖案及色澤。 本發明中的貼附薄膜1〇〇也可以僅包括基體層1〇2及黏著 層106。該黏著層106黏著於該基材200,該基體層1〇2位 於黏著層106相對於基材2〇〇的另一側,進而利用透明的 基體層102顯現基材200的本色。顯而易見的是,該基體 層102也可以由具有色彩的材料製成,其貼附於基材2〇〇 表面後使成型品顯現出該基體層102的色彩。 請參閲圖10 ’利用上述模内裝飾成型方法製成模製品1〇 可包括另一態樣的貼附薄膜120貼附在該基材200上。該 貼附薄膜120包括一基體層122、一第一裝飾層124、一 第二裝飾層128及一黏著層126,該黏著層126黏著於該 基材200,該第一裝飾層124位於基體層122與黏著層126 之間,該基體層122位於第一裝飾層124相對於黏著層 126的另一側’該第二裝飾層128位於基體層122的上表 面。第一裝飾層124與第二裝飾層128是若干油墨層用網 版印刷於基體層122上所形成,每一油墨層的厚度介於 0. 005毫米至0. 02毫米之間。 綜上所述,本發明符合發明專利要件,爰依法提出專利 申請。惟,以上所述者僅為本發明之較佳實施例,舉凡 熟悉本案技藝之人士,在爰依本發明精神所作之等效修 098111790 表單編號Α0101 第11頁/共32頁 0982019464-0 [0042] 201036792 [0043] [0044] [0045] [0046] [0047] [0048] [0049] [0050] [0051] [0052] [0053] [0054] 098111790 飾或變化白應涵蓋於以下之申請專利範圍内。 【圖式簡單說明】 圖1為本發明板内裝錦成型方法所使用的模具的剖面示夸 圖0 圖2為本發月模内裝飾成型方法所使用的另一模具的剖 不意圖。 圖3為圖1的模具第一次合模 ’準備進行射膠。 圖4為圖3的模具第二次合模 部將貼附薄膜切下。 圖 公模與母模之間沒有接鸿 完成射膠,且公模的切割 5為本發明模内裝飾成型方法的第-實施方式的流程 圖 圖6為本發明模内”成型方法的第二實施方式的流程圖 ㈣為本發明模内裝飾成型方法製成模製品的立體圖。 隨為沿圖7A0m_则面線所取的剖視圖。 Z為本發明模内裝飾成型方法製成另—模製品的立趙 麵為沿隨物__面線所取的剖視圖。 圖9A為沿圖7_、㈣面線所取的剖視圖表本發明 裝飾成型用貼附薄膜的結構。 圖9B為沿圖7B_ —9剖面線所取的剖視圖,表本發明模内 表單編號A0101 第12頁/共32頁 0982019464-0 201036792 裝飾成型用貼附薄膜的裝飾層由若干個油墨層所形成結 構。 [0055] [0056] 圖1 0為本發明貼附薄膜另一實施方式的結構圖剖面示意 圖。 圖11為依據美國專利前案第508059760號所製成的產品 斷面示意圖。 Ο 098111790 【主要元件符號說明】 [0057] ο 送膜裝置 15 母模 25 公模 30 模穴 22 凹槽 24、24’ 切割部 26、26’ 貼附薄膜 100 ' 500 ' 120 基材 200 、 300 頂面 201 > 301 侧緣 202 、 302 模製品 10、20 基體層 102 、 122 裝飾層 104 黏著層 106 、 126 第二周緣端面 501 第一周緣端面 303 第一裝飾層 124 第二裝飾層 128 油墨層 1041 、 1042 、1043 表單編號Α0101 第13頁/共32頁 0982019464-0Page 1 / 32 I 0982019464-0 201036792 [0040] 004 [0041] 取得 A better overall effect is achieved in terms of drying after brushing. The method of forming the adhesive layer i 〇 6 may be any conventional printing method such as gravure printing, screen printing or offset printing, or a method such as spraying, brushing or the like. In the present embodiment, the base layer 1〇2 of the attached film 10〇 is transparent or translucent' for visualizing the pattern and color of the decorative layer 1〇4. The attached film 1〇〇 in the present invention may include only the base layer 1〇2 and the adhesive layer 106. The adhesive layer 106 is adhered to the substrate 200. The base layer 1 is positioned on the other side of the adhesive layer 106 with respect to the substrate 2, and the original color of the substrate 200 is visualized by the transparent substrate layer 102. It will be apparent that the base layer 102 can also be made of a material having a color which, after being attached to the surface of the substrate 2, causes the molded article to exhibit the color of the base layer 102. Referring to Fig. 10', a molded article 1 is formed by the above-described in-mold decoration molding method. The attached film 120 which may include another aspect is attached to the substrate 200. The adhesive film 120 includes a base layer 122, a first decorative layer 124, a second decorative layer 128, and an adhesive layer 126. The adhesive layer 126 is adhered to the substrate 200. The first decorative layer 124 is located on the base layer. Between 122 and the adhesive layer 126, the base layer 122 is located on the other side of the first decorative layer 124 with respect to the adhesive layer 126. The second decorative layer 128 is located on the upper surface of the base layer 122. 005毫米至0. 02毫米之间。 The first decorative layer 124 and the second decorative layer 128 is a plurality of ink layers are formed by screen printing on the base layer 122, each ink layer having a thickness of between 0.005 mm to 0.02 mm. In summary, the present invention complies with the requirements of the invention patent and submits a patent application according to law. However, the above description is only a preferred embodiment of the present invention, and those skilled in the art of the present invention are equivalent to 098111790 in the spirit of the present invention. Form number Α 0101 Page 11 / Total 32 pages 0992019464-0 [0042 [0048] [0048] [0054] [0054] 098111790 Decoration or variation white shall be covered by the following patent application Within the scope. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a cross-sectional view showing a mold used in a method for forming a sheet in the present invention. Fig. 2 is a cross-sectional view showing another mold used in the method for molding the in-mold mold. Figure 3 is a first shot of the mold of Figure 1 ready to be shot. Fig. 4 is a view showing the second mold clamping portion of the mold of Fig. 3 cutting the attached film. There is no connection between the male mold and the female mold, and the cutting of the male mold is the flow chart of the first embodiment of the in-mold decorative molding method of the present invention. FIG. 6 is the second in the in-mold "forming method of the present invention. Flowchart (4) of the embodiment is a perspective view of a molded article produced by the in-mold decorative molding method of the present invention. A cross-sectional view taken along the line of Fig. 7A0m_ is taken. Z is the in-mold decorative molding method of the present invention. Fig. 9A is a cross-sectional view taken along the upper line of Fig. 7 and (4), showing the structure of the decorative film for decorative molding of the present invention. Fig. 9B is a view along Fig. 7B_ 9 is a cross-sectional view taken from the section line, and is shown in the in-mold form number A0101 of the present invention. Page 12/32 pages 0992019464-0 201036792 The decorative layer for attaching a film for decorative molding is formed by a plurality of ink layers. [0055] [0056] Figure 10 is a cross-sectional view showing the structure of another embodiment of the attached film of the present invention. Figure 11 is a schematic cross-sectional view of the product made in accordance with U.S. Patent No. 508,059,760. Ο 098111790 [Description of Main Components] [0057] ] ο Film feeding device 15 female mold 25 male mold 30 mold cavity 22 groove 24, 24' cutting portion 26, 26' attached film 100 '500 '120 substrate 200, 300 top surface 201 > 301 side edge 202, 302 molded article 10, 20 base layer 102, 122 decorative layer 104 adhesive layer 106, 126 second peripheral end surface 501 first peripheral end surface 303 first decorative layer 124 second decorative layer 128 ink layer 1041, 1042, 1043 form number Α 0101 page 13 / total 32 pages 0992019464-0