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TW201009885A - External electrode fluorescent lamp and apparatus utilizing the same - Google Patents

External electrode fluorescent lamp and apparatus utilizing the same Download PDF

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Publication number
TW201009885A
TW201009885A TW098122051A TW98122051A TW201009885A TW 201009885 A TW201009885 A TW 201009885A TW 098122051 A TW098122051 A TW 098122051A TW 98122051 A TW98122051 A TW 98122051A TW 201009885 A TW201009885 A TW 201009885A
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TW
Taiwan
Prior art keywords
light
tube
external electrode
layer
light transmission
Prior art date
Application number
TW098122051A
Other languages
Chinese (zh)
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TWI389164B (en
Inventor
Satoshi Tamura
tetsuro Fuyuki
Yasuhiro Mano
Kouji Imada
Eri Matsuda
Original Assignee
Nec Lighting Ltd
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Publication of TW201009885A publication Critical patent/TW201009885A/en
Application granted granted Critical
Publication of TWI389164B publication Critical patent/TWI389164B/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J65/00Lamps without any electrode inside the vessel; Lamps with at least one main electrode outside the vessel
    • H01J65/04Lamps in which a gas filling is excited to luminesce by an external electromagnetic field or by external corpuscular radiation, e.g. for indicating plasma display panels
    • H01J65/042Lamps in which a gas filling is excited to luminesce by an external electromagnetic field or by external corpuscular radiation, e.g. for indicating plasma display panels by an external electromagnetic field
    • H01J65/044Lamps in which a gas filling is excited to luminesce by an external electromagnetic field or by external corpuscular radiation, e.g. for indicating plasma display panels by an external electromagnetic field the field being produced by a separate microwave unit
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/04Electrodes; Screens; Shields
    • H01J61/06Main electrodes
    • H01J61/067Main electrodes for low-pressure discharge lamps
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/04Electrodes; Screens; Shields
    • H01J61/06Main electrodes
    • H01J61/067Main electrodes for low-pressure discharge lamps
    • H01J61/0675Main electrodes for low-pressure discharge lamps characterised by the material of the electrode
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/04Electrodes; Screens; Shields
    • H01J61/06Main electrodes
    • H01J61/09Hollow cathodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/38Devices for influencing the colour or wavelength of the light
    • H01J61/42Devices for influencing the colour or wavelength of the light by transforming the wavelength of the light by luminescence
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J65/00Lamps without any electrode inside the vessel; Lamps with at least one main electrode outside the vessel
    • H01J65/04Lamps in which a gas filling is excited to luminesce by an external electromagnetic field or by external corpuscular radiation, e.g. for indicating plasma display panels
    • H01J65/042Lamps in which a gas filling is excited to luminesce by an external electromagnetic field or by external corpuscular radiation, e.g. for indicating plasma display panels by an external electromagnetic field
    • H01J65/046Lamps in which a gas filling is excited to luminesce by an external electromagnetic field or by external corpuscular radiation, e.g. for indicating plasma display panels by an external electromagnetic field the field being produced by using capacitive means around the vessel
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B41/00Circuit arrangements or apparatus for igniting or operating discharge lamps
    • H05B41/14Circuit arrangements
    • H05B41/26Circuit arrangements in which the lamp is fed by power derived from DC by means of a converter, e.g. by high-voltage DC
    • H05B41/28Circuit arrangements in which the lamp is fed by power derived from DC by means of a converter, e.g. by high-voltage DC using static converters
    • H05B41/2806Circuit arrangements in which the lamp is fed by power derived from DC by means of a converter, e.g. by high-voltage DC using static converters with semiconductor devices and specially adapted for lamps without electrodes in the vessel, e.g. surface discharge lamps, electrodeless discharge lamps

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  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Vessels And Coating Films For Discharge Lamps (AREA)

Abstract

To provide an external electrode fluorescent lamp and apparatuses utilizing the same, which utilize zinc oxide having a superior primary-electron emission property to that of alumina fine particles, and thereby can achieve a stable in-dark startup characteristic, inhibit the formation of an amalgam, maintain light emission for a long period of time, and prevent a decline of luminous intensity, and in addition which are highly reliable and easy to produce. An external electrode fluorescent lamp comprises a light transmissive tube which retains a noble gas and mercury thereinside, a fluorescent material layer which is provided on the inner wall surface of the light transmissive tube, and an external electrode which is provided in the outer peripheral surface of each end of the light transmissive tube, wherein the external electrode fluorescent lamp includes a startup acceleration layer containing zinc oxide in a region opposed to at least one external electrode on the inner surface of the light transmissive tube, with a tube-center-side edge of the startup acceleration layer being located at a position of 10 mm toward the tube-center side from the tube-center-side edge of the external electrode, or at the tube-end side to the foregoing position.

Description

201009885 六、發明說明: 【交又參考之相關申請案】 本案係基於下述案件,並主張其優先權:八 ,2008-191276號,申請曰為2〇〇時7月 ;二 此併入以供參照。 王砟内今在 【發明所屬之技術領域】 尤關裝置, 光強度的外部電極式螢光備抑制水合金的生成、達成高發 【先前技術】 μΪΪΪ螢優異屬性’如高發光強度、高演色性、 曰顯-功率雜等,已廣泛應用於如電視、電腦等之液 種顯-二ί傳ΐ機等的讀閱光源、影印機的除像光源及 二各種顯7F顧4。在該種冷陰極螢光燈巾,冑紐施加至設 ◎ 玻ϊί製成之光透射管之魏附近的電極,該光透射管在 雜。方式保存稀魏體及汞,俾使稀有氣體被光電子游 S,而在光透射管中僅出現非常少量的光電子作為—次電子, =化的稀有氣體離子受力而撞擊電極,進而發射出二次電 W :此產生輝級電’而汞軒藉此受激發後髓紫外光。接 t受到紫外光侧時,㈣在光透射管内壁上的螢光材料會發 jli光。在此種冷陰極縣燈巾,因為電極會受到稀有氣體 =專的鱗,便使料部電極式螢光燈,其中電極設置於光透 射&之外圍表面上,以減少濺擊所造成的損害。 /冷陰極螢光燈長時間置放於阻擋外部光線進入的空間(暗區) 之後、’會變的很難或無法啟動(點亮),因此便有了對暗區啟動失效 =改進%知技藝中有一種利用氧化銘(alumha)之一次電子發射 f性的节,式燈(discharge lamp),氧化銘微粒散佈、混合在螢光層 中,或是氧化鋁微粒層形成在玻璃燈管的内面上,俾使氧化鋁曝 201009885 露 一^放電空。中(參照日本公開專利公報第雇4_95378號〗,以及 棟ίί由氧化鋅與氧化釔之混合物所形成之氧化層的放電式 層係設置在發光管内圍表面與螢光材料層之間,或毁 發光&各端(參照日本公開專利公報第2007_73481號)。 ,在日本公開專利公報第2004-95378號所揭露的外部電 碎巾’將氧化15微粒混合人螢光材料層巾會導致發光強 氏。亦即’氧化銘的電子發射屬性非常弱,而當為了達 暗驗動特性時,便_增加氧她的混合量。氧化叙 if 子所發射之紫外光激發而發㈣光的螢光材料,而 二口=螢光材,層中氧化铭的量會導致燈發光強度的降低。再 禮3量不會影響而降低發光強度,該含量將不會達成 性。又’玻璃燈管中的汞,被混合在螢光材料層ϊ 收後’會形成的汞合金,導致發光強度維持因素 邗心人二再者’雖然在一已揭露的方法中,氧化鋁微粒 螢料中,且氧她微粒層觀置於玻璃燈管之外 上’且該處並未設置螢光材料層,因為氧化紹 分上ΐ能不二 氧化織粒層設置於該部 么ίΐίϊίΓ後反射’導致燈發光強度的減弱。此外, i,ίΐΐϊΐ整個内圍表面上的氧化層會將兩端的外部電t 成之氧區製 設備本=:氧==== 201009885 屬性更優異的-次電子發射屬性,藉此能達到穩定的暗區 性,抑制汞合金的生成,長時間維持光發射,以及防止發 先強度的降低,且其具有高可靠度並容易生產之特色。 【發明内容】 本案發明人經努力實驗後最終發現,在光透射管中之相對外 之喊面上的特定11域上’設置含氧化制啟動加速層, f制螢光材料岐的吸收及反射,抑制汞的魏,以及防止燈 發光強度的減弱。基於此等魏’該等發明人完成本發明。 味亦即本發明係關於外部電極式榮光燈,其包含:一光透射 螢光材料層及—外部雜’該光透射管在其崎保存有稀 有乳體及汞,該螢光材料層設置於該光透射管之一内壁表面上, 該外部電極設置於該光透射管之各端的一外圍表面上,其中該外 式螢光燈包括—含氧鱗之啟動加速層,該啟動加速層位 光透射管之内表面上之相對於至少一外部電極的一區域中, 且Ϊ啟動加速層之靠光透射管中心侧之邊緣位於距離該外部電極 之罪光透射管中心侧之邊緣靠光透射管中心侧1Gmm的位置 位於前述位置之靠光透射管末端側。 a 再者,本發明係關於具備上述外部電極式螢光燈的設備。 本發明之外部電極式螢光燈利用氧化鋅,氧化鋅之一次電子 X射屬性較佳於氧化鋁微粒的一次電子發射屬性,藉此達成穩 t暗區啟動特性’此外’能抑制汞合金的生成,長時間維持光發 射,防止發光強度的減弱,並具有高可靠度,且容易生產。Λ 【實施方式】 本發明之外部電極式螢光燈包含:光透射管,在其内部 有稀有氣體及汞;螢光材料層,設置在光透射管之内壁表面上; 及外部電極,設置在光透射管之各端的外圍表面上,並令,誃 部電極式縣燈包括含有氧鱗的啟動加速層,該啟^ ^ 於光透射管之喊面上之相對於至少—外部電極的區域中,&啟 201009885 =速層之靠光透射管中心侧之邊緣位於光透射管中心侧距 °』電靠光透射管中心侧之邊緣丨。咖之位置,或位於前述位 置之罪光透射管末端侧。 丄用於本發明之外部雜錢絲的光透鮮,可歧具有從 螢光材料發射出之高螢絲射率的任何材料,該㈣可為玻蹲, t酸〒玻璃、卿酸鹽玻璃、鋅财酸鹽玻璃、錯玻璃、鈉破 ,等。詳細而言,適當的材料包括鈉玻璃、硼矽酸鹽玻璃等, ❹ ❹ 其組成中,如鈉、鉀等之鹼性成分不超過1〇%質量比。A形狀 =是直管_、f醜型或其他_之其中—者。光透射管 如外直徑可以是2至5mm。雖然依據使用目的不同而可適杏 選擇光透射管的厚度,若按上述光透射管的直徑,其厚度較佳 0.2至0.7mm。光透射管的兩端皆為氣密式密封,且盆管長可以J 如 500 mm 至 1500 mm。 〃 螢光材料層係設置在光透射管之幾乎整個内壁表面上。 =料層所含之狄材料’係錄原子輻射之料光所激發而發射 出可見光。此螢光機的選擇,係使其依據仙目的而發射出所 欲的色光;例如,可使用鹵磷酸鹽螢光材料、稀土族螢光材料 亦可使用上述材料的適當組合錢射自光。詳細而言,用 白光之螢光材_可能組合包括下狀組合:紅色t光材料& ,、=色螢光材料LaP04: Ce,Tb ;及藍色螢光材料BaMgAli〇〇 Eu。螢光材料的厚度較佳為不低於15叫且不超過25哗。雖然 可將螢光材㈣設置咖對於外部電極的輯巾,但相對區域較 佳為在光透射管之軸向方向1〇 mm之内。 將汞及稀有氣體通人光透射管之中,其巾,汞經由放電效應 而產生紫外光,而稀有氣體係適當選自於氬、氣 ^ 光透射管中鼓之放钱子會郷㈣子, 光,該紫外光係包括具有激發$光材料之2537nm的波長的^ 光。通入光透射管之I的量較佳為陳時汞的氣態壓力為如^至 10Pa的量。取光透射管之财纽的量較 的廢力為如誦Pa至6_ pa的4。 m㈣乳體 201009885 如光透射管1:外圍表面兩端的外㈣極係由如鐵或 y 鐵3金所形成。猎由將鐵或鐵合金纏繞在光透射管上一, 的黏 著性 ^形成外部電極,且能使用焊料來加強電極與光透射管之間 含辞之啟動加速層係設置在前述光透射管的内表面上,且 於相對於至少-外部電極醜域巾。啟動加速層201009885 VI. Description of invention: [Related application for reference] The case is based on the following cases and claims its priority: eight, 2008-191276, the application is 2 7 July; the second is incorporated For reference. Wang Hao is in the field of technology of the invention. The special-purpose device, the external electrode type fluorescent device for light intensity suppresses the formation of the water-alloy and achieves high incidence [Prior Art] Excellent properties of μ ΪΪΪ ' such as high luminous intensity, high color rendering , 曰 display - power miscellaneous, etc., has been widely used in such as reading light source such as TV, computer, etc., the image source of the photocopier, and the image light source of the photocopying machine. In the cold cathode fluorescent lamp, the neon is applied to an electrode near the Wei of the light transmission tube made of ◎ glass ϊ, and the light transmission tube is mixed. The method saves the dilute body and mercury, so that the rare gas is swept by the photoelectron S, and only a very small amount of photoelectrons appear as a sub-electron in the light transmission tube, and the rare gas ions of the chemical force hit the electrode and emit two Sub-electricity W: This produces a grading electric power' and the mercury swell is excited by the post-myelin ultraviolet light. When the t-light is on the ultraviolet side, (4) the fluorescent material on the inner wall of the light-transmitting tube emits light. In such a cold cathode lamp, since the electrode is subjected to a rare gas=special scale, the electrode-type fluorescent lamp is placed, and the electrode is disposed on the peripheral surface of the light transmission to reduce the splashing. damage. /Cold cathode fluorescent lamp is placed in a space (dark area) that blocks external light from entering for a long time. 'It will become difficult or impossible to start (light up), so there is a failure to start the dark area. In the art, there is a section that utilizes a single electron emission of alumha, a discharge lamp, a diffusion of the oxidized particles, a mixture in the phosphor layer, or a layer of alumina particles formed in the glass tube. On the inner surface, the aluminum oxide is exposed to 201009885. (refer to Japanese Laid-Open Patent Publication No. 4_95378), and the discharge layer of the oxide layer formed by the mixture of zinc oxide and cerium oxide is disposed between the inner surface of the light-emitting tube and the layer of fluorescent material, or destroyed The external electric shredder disclosed in Japanese Laid-Open Patent Publication No. 2004-95378, which oxidizes 15 particles mixed with a human fluorescent material layer towel, causes light to be emitted. That is to say, 'Oxidation's electron emission property is very weak, and when it is used to darken the characteristics of the test, it increases the amount of oxygen. The ultraviolet light emitted by the oxidation of the ion is excited and emits (four) the fluorescence of the light. Material, and two = fluorescent material, the amount of oxidation in the layer will lead to a decrease in the luminous intensity of the lamp. The amount of 3 will not affect the luminous intensity, and the content will not be achieved. In the 'glass tube Mercury, which is mixed in the layer of phosphorescent material, will form amalgam, which will lead to the maintenance of luminescence intensity. Although in an exposed method, alumina particles are in the phosphor, and oxygen Her micro The layer is placed on the outside of the glass tube and there is no layer of phosphor material at that place, because the oxidation layer can be placed on the part of the layer without oxidizing the woven layer. In addition, i, 氧化 氧化 氧化 ΐΐϊΐ ΐΐϊΐ 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化Stable dark zone, inhibit the formation of amalgam, maintain light emission for a long time, and prevent the decrease of initial strength, and it has the characteristics of high reliability and easy production. [Invention] The inventor of this case tried hard after the experiment. It was found that in the specific 11 domains on the opposite outer surface of the light transmission tube, 'the ignition acceleration layer containing the oxidation, the absorption and reflection of the fluorescent material f, the suppression of mercury, and the prevention of the luminous intensity of the lamp are set. The present invention relates to an external electrode type glory lamp comprising: a layer of light transmissive phosphor material and an external impurity 'the light transmissive tube The surface of the light transmissive tube is disposed on a surface of an inner wall of the light transmitting tube, and the outer electrode is disposed on a peripheral surface of each end of the light transmitting tube, wherein the external fluorescent light is disposed on the inner wall surface of the light transmitting tube The lamp includes an activation buffer layer containing an oxygen scale, the activation is accelerated in a region of the inner surface of the layered light transmission tube relative to the at least one external electrode, and the edge of the center of the light transmission tube of the activation layer is located The edge of the center side of the light transmitting tube of the external electrode is located 1 Gmm from the center side of the light transmitting tube at the end of the light transmitting tube at the position described above. a Further, the present invention relates to the above-described external electrode type fluorescent lamp. The external electrode type fluorescent lamp of the present invention utilizes zinc oxide, and the primary electron emission property of zinc oxide is better than the primary electron emission property of the alumina fine particles, thereby achieving a stable dark region start-up characteristic 'in addition' capable of suppressing mercury The formation of the alloy maintains light emission for a long period of time, prevents the luminescence intensity from being weakened, has high reliability, and is easy to produce. Λ [Embodiment] The external electrode type fluorescent lamp of the present invention comprises: a light transmitting tube having a rare gas and mercury therein; a phosphor layer disposed on an inner wall surface of the light transmitting tube; and an external electrode disposed at a peripheral surface of each end of the light transmissive tube, and the crucible electrode type county lamp includes a start acceleration layer containing an oxygen scale, the opening of the light transmissive tube on the surface of the light transmissive tube relative to at least the outer electrode , &启201009885 = The edge of the velocity layer on the center side of the light transmission tube is located at the edge of the center of the light transmission tube. The position of the coffee, or the end of the sin light transmission tube at the aforementioned position.光 The light-transparent used in the external fuse yarn of the present invention can distinguish any material having a high fluorescene rate emitted from the fluorescent material, and the (4) can be glass crucible, t-sodium silicate glass, and sulphate glass. , zinc acid salt glass, wrong glass, sodium broken, and so on. In detail, suitable materials include soda glass, borosilicate glass, etc., and the composition thereof, such as sodium, potassium, etc., has an alkaline component of not more than 1% by mass. A shape = is straight pipe _, f ugly or other _ among them. The light transmission tube may have an outer diameter of 2 to 5 mm. Although the thickness of the light transmitting tube can be selected according to the purpose of use, the thickness of the light transmitting tube is preferably 0.2 to 0.7 mm according to the diameter of the light transmitting tube. Both ends of the light transmission tube are hermetically sealed, and the length of the tube can be, for example, 500 mm to 1500 mm. 〃 The layer of phosphor material is disposed on almost the entire inner wall surface of the light transmitting tube. = The material contained in the layer is excited by the light of the atomic radiation and emits visible light. The choice of the illuminator is such that it emits the desired chromatic light in accordance with the singularity; for example, a halophosphate fluorescent material, a rare earth fluorescent material, or a suitable combination of the above materials can be used to illuminate the light. In detail, a fluorescent material using white light may include a combination of the following: a red t-light material &, a = fluorescent material LaP04: Ce, Tb; and a blue fluorescent material BaMgAli〇〇 Eu. The thickness of the fluorescent material is preferably not less than 15 and not more than 25 Å. Although the phosphor material (4) can be provided with the outer electrode, the relative area is preferably within 1 mm of the axial direction of the light transmitting tube. Mercury and rare gases pass through the light transmission tube, and the towel, mercury emits ultraviolet light through the discharge effect, and the rare gas system is appropriately selected from the argon gas, the gas transmission tube, and the drum of the money (four) , the light, the ultraviolet light comprising a light having a wavelength of 2537 nm that excites the $ light material. The amount of I introduced into the light transmitting tube is preferably such that the gaseous pressure of the mercury is from 0 to 10 Pa. The amount of waste of the light-transmitting tube is more than 4, such as 诵Pa to 6_ pa. m (four) milk body 201009885 Such as light transmission tube 1: the outer (four) poles at both ends of the outer surface are formed by iron or y iron 3 gold. Hunting by winding iron or iron alloy on the light transmission tube, the adhesion is formed to form an external electrode, and solder can be used to strengthen the electrode between the electrode and the light transmission tube. The acceleration layer is disposed in the light transmission tube. On the surface, and in relation to at least the outer electrode ugly towel. Start acceleration layer

tfbS ίίΐίί電子發射能力’其持續地發射電子,因此能將絕佳的 曰區啟動躲舒外部電極式螢絲,藉此即使外部電極式 $位於暗處而長時間未施加電壓時,在將t壓施加至電極後,短 時間内便能開聽電。含魏鱗之啟動加速層較佳 =不ϊΐ i00nm的一次粒子,而因藉由氧化辞粒子的表面^ 增加’可加速電子的發射。 買 射式====峨咖式細卿EM)或透 雖然上述之啟動加速層可僅由氧化鋅所構成,其更可含呈 ^電子發射能力的-或更多個材料,如氧做(、氧魅、氧化敛: 氧化鎮及氧化錫。此等㈣能增料部電極式螢紐的啟動特 性^此等材料的組成較佳為氧化鋅具有在10%至100%之範圍中的 ,罝比。此外’啟絲速層亦可含有在不會減損氧化鋅與上述具 有電子發雜力之材料的魏之麵_發光㈣。詳細而言, 螢光材料可關上述螢光材料層中所用之榮紐料作為範例。 上述啟動加速層係設置於光透射管之内表面上之相對至少一 外部電極的區域巾。雖可以在光透射管之内表面上之相對外 部電極處設置成非雜形式,其較佳為在光透射之内表面上之 相對外部電極處設置成環獅式。如圖i之立體_示,啟動加 速1 6巧佳地在光透射管2之内表面上之相對外部電極3處設置 成環狀形式。啟動加速狀靠光赫管巾^姻絲雜於距離 外部電極之靠光透射管中心侧之邊緣靠光透射管中心側1〇mm的 位置,或位於則述位置之靠光透射管末端側。因為啟動加速層之 201009885 靠光透射管中心側的邊緣位於距離外部電極之靠光透射管中心側 之邊緣靠光透射管中心側10mm的位置,或位於前述位置之靠光 透射管末端侧,便有可能防止阻礙紫外光對螢光材料的激發,藉 =止燈發光強度降低。雜啟動加速層之靠光透射管末端側的 可以位於外部電極之靠光透射管末端侧之邊緣的靠光透射管 土巧側,,較佳位於距離外部電極之靠光透射管中心侧之邊緣之 罪光透射管末端侧10 mm的位置,或位於前述位置之靠光透射管 t二侧,因為有可能抑制汞被啟動加速層吸收後形成汞合金。不 論光透射管的形狀及尺寸為何,啟動加速層較佳具有在光透射管 j向方向上2Gmm之内的寬度。若設置在上述區域中,啟動加 ^層可包括與螢光材料層形成疊層的部分。依據所使用氧化辞粒 ^平均粒徑,以及光透射f的材料等,可適當選擇啟動加 的展磨。 ,啟動加速層能藉由製備塗佈液體而形成,在該塗佈液體 中,氧化鋅具有上述平均粒徑一次粒子,且其係散佈於如水、異 賴中,且藉由制此液體,在光透射管之喊面的期 ,藉由浸潰或塗佈等方法,形倾,並在此之後適 虽烘乾及加熱塗佈膜。 參 总本發明之外部電極式螢光燈可依需求在螢光材料層與光透射 I之間設有髓層及其類她,財卩制縣原子所輻射出之紫外 其他朗達光透射管外部m或抑糊汞或其他化學物 所造成光透射管的降解。 “ίΐ上料部電極式螢絲的方法包括㈣光獅層形成在 十^射&的内壁上。形成螢光材料層包括製備流體散佈液,其 光獅歸在溶财,並包括浸佈,以及隨後在以玻 璃或其他触物所製紅具有預定雜的光透鮮巾的内壁表面 縣具有駭厚度,⑽成具有上述厚度的螢光 ϊίίιϊ狀後,藉由浸潰手段或其她手段,將上述啟動加 射管的内表面上。在此之後,將預定量的汞及稀 有乳體通入光透射管,並將光透射管的兩端密封。將鐵合金等的 201009885 薄片纏繞在光透射管各端的外圍表面上,並將烊料填入 與纏繞的薄片之間,使其二者緊密接觸而形成外部電極。 吕 本發明之外部電極式螢光燈的範例係繪示於圖2至圖6。圖2 所示之外部電極式螢光燈丨配置為:油玻璃、卿酸鹽及 其他類似玻璃製成的光透射管2,其兩端以氣密方式密封;稀有氣 體及汞保存在光透射管_部;以及,_壓力減為約佔大氣壓 力數成的壓力。在幾乎整個長度的光透射管2的内壁表面上'設 置螢光材料層5。外部電極3設置在光透射管2之軸向方向的^ 端。啟動加速層6係設置在光透射管之相對外部電極的内圍表面tfbS ίίΐίί electron emission capability 'it continuously emits electrons, so it can start the excellent electrode zone to avoid the external electrode type filament, so that even if the external electrode type $ is in the dark and no voltage is applied for a long time, After the pressure is applied to the electrode, the power can be turned on in a short time. The initiation acceleration layer containing the Wei scale is preferably = primary particles of i00 nm, and the emission of electrons can be accelerated by increasing the surface of the particles by oxidation. Buying shot ====峨咖式细卿 EM) or through, although the above-mentioned starting acceleration layer can be composed only of zinc oxide, it can also contain - or more materials, such as oxygen (, Oxygen, Oxidation: Oxidation Town and Tin Oxide. These (4) Start-up characteristics of the electrode type of the energy-increasing part of the material. The composition of these materials is preferably such that the zinc oxide has a range of 10% to 100%. In addition, the 'speeding layer can also contain the surface of Wei, which does not detract from the zinc oxide and the above-mentioned materials with electrons, _ illuminating (4). In detail, the fluorescent material can close the layer of fluorescent material. The illuminating material used in the above is taken as an example. The starting acceleration layer is disposed on the inner surface of the light transmitting tube with respect to at least one outer electrode, although it may be disposed at the opposite outer electrode on the inner surface of the light transmitting tube. Preferably, the non-heteromorphic form is disposed on the inner surface of the light transmissive surface at a position opposite to the outer electrode as a ring lion. As shown in the stereoscopic view of FIG. i, the start acceleration 16 is preferably on the inner surface of the light transmissive tube 2. The outer electrode 3 is disposed in an annular form at the opposite end. The inner tube is mixed with the edge of the outer side of the light transmitting tube from the center of the light transmitting tube by a position of 1 mm on the center side of the light transmitting tube, or at the end of the light transmitting tube at the position described above. 201009885 The edge of the center side of the light transmitting tube is located 10 mm away from the center side of the light transmitting tube on the center side of the light transmitting tube, or at the end of the light transmitting tube at the aforementioned position, it is possible to prevent the ultraviolet rays from being blocked. The excitation of the light on the fluorescent material is reduced by the light intensity of the light-emitting tube. The end of the light-transmitting tube of the hybrid start-up layer may be located on the edge of the light-transmitting tube at the edge of the end of the light-transmitting tube of the external electrode. Preferably, it is located at a position 10 mm from the end side of the outer side of the light transmitting tube on the center side of the light transmitting tube, or at the opposite position of the light transmitting tube t at the aforementioned position, because it is possible to suppress the mercury from being activated. Forming an amalgam after absorption. Regardless of the shape and size of the light transmitting tube, the starting acceleration layer preferably has a width within 2 Gmm of the direction of the light transmitting tube j. In the domain, the startup layer may include a portion formed by lamination with the layer of the phosphor material. Depending on the oxidized granules used, the average particle diameter, and the material of the light transmission f, the start-up grinding may be appropriately selected. The acceleration layer can be formed by preparing a coating liquid in which zinc oxide has the above-mentioned average particle diameter primary particles, and is dispersed in, for example, water, and is formed by the liquid in the light transmission. The period of the shouting of the tube is tilted by dipping or coating, and after that, the coating film is dried and heated. The external electrode type fluorescent lamp of the present invention can be fired on demand. Between the layer of light material and the light transmission I, there is a myelin layer and the like, and the ultraviolet light of other Ronda light transmission tubes radiated by the atom of the Caixian County is m or the light transmission tube caused by paste mercury or other chemicals. Degradation. "The method of feeding the electrode type filaments includes (4) the layer of the light lion is formed on the inner wall of the lens. Forming the layer of phosphor material includes preparing a fluid dispersion liquid, the light lion is disposed of in a wealth, and includes a dip cloth, and then the surface of the inner wall of the predetermined surface of the light-transparent towel having a red color made of glass or other touch material has a flaw. After the thickness (10) is in the form of a fluorescent ray having the above thickness, the inner surface of the firing tube is activated by dipping means or the like. Thereafter, a predetermined amount of mercury and a rare emulsion are introduced into the light transmitting tube, and both ends of the light transmitting tube are sealed. A 201009885 sheet of a ferroalloy or the like is wound around the peripheral surface of each end of the light transmitting tube, and the crucible is filled between the wound sheet and the two sheets are brought into close contact with each other to form an external electrode. An example of an external electrode type fluorescent lamp of the present invention is shown in FIGS. 2 to 6. The external electrode type fluorescent lamp shown in Fig. 2 is configured as: oil glass, sulphate and other light-transmitting tubes 2 made of glass, which are sealed at both ends in a gastight manner; rare gases and mercury are stored in light transmission. Tube _ part; and, _ pressure is reduced to a pressure of about the atmospheric pressure. The phosphor material layer 5 is disposed on the inner wall surface of the light transmission tube 2 of almost the entire length. The external electrode 3 is disposed at the end of the light transmitting tube 2 in the axial direction. The starting acceleration layer 6 is disposed on the inner peripheral surface of the opposite external electrode of the light transmitting tube

上丄啟動加速層6係設置在螢光材料層的末端,且啟動加速層6 之靠光透射管中心側的邊緣6a係位於距離外部電極3之靠光透射 管中心侧之邊緣3a 10 mm之靠光透射管中心侧的位置如,,或位 於前述位置之靠光透射管末端側。啟動加速層6之靠光透射管末 端側的邊緣6b係位於距離外部電極之靠光透射管中心側之邊緣如 10mm之靠光透射管末端側的位置3b,,或位於前述位置之靠光 射管中心側。The upper priming acceleration layer 6 is disposed at the end of the phosphor layer, and the edge 6a of the activation layer 6 on the center side of the light transmission tube is located 10 mm away from the edge 3a of the outer electrode 3 on the center side of the light transmission tube. The position on the center side of the light transmitting tube is, for example, or on the end side of the light transmitting tube at the aforementioned position. The edge 6b of the start-up acceleration layer 6 on the end side of the light-transmitting tube is located at a position 3b from the edge of the outer side of the light-transmitting tube on the center side of the light-transmitting tube, such as 10 mm on the end side of the light-transmitting tube, or at the aforementioned position. Tube center side.

圖3中欲設置在外部電極式螢光燈n中的啟動加速層61係 =置在螢光材料層及光透射管的内壁表面上,且啟動加速層61之 ,光透射管中心侧的邊緣61a係位於距離外部電極3之靠光透射 管中心侧之邊緣3a 10mm之靠光透射管中心侧的位置3a,(示於圖 2),或位於前述位置的靠光透射管末端侧;而啟動加速層&之 光透射管末端侧的邊緣61b係位於距離外部電極3之靠光透射管 中心侧之邊緣3a 10 mm之靠光透射管末端側的位置北,(示於 2),或位於前述位置的靠光透射管中心侧。在圖3中,與圖2相似 的元件符號’代表與圖2所示之外部電極式螢光燈i相似的元件。 圖4中欲設置在外部電極式螢光燈12中的啟動加速層泣 位於光透射管的内壁表面上,且啟動加速層62之靠光透射管中心 側的邊緣62a係位於距離外部電極3之靠光透射管中心側之邊緣 3a 10 _之靠光透射管中心側的位置知,(示於圖2),或位於前 位置的靠光透射管末端側,而啟動加速層62之靠光透射管末端 201009885 • · =邊緣係位於距離外部電極3之靠光透射管中心側之邊緣知 光透射官末端側的位置3b,(示於圖,或位於前述位 =罪光透射管中心側。在圖4中,與圖2相似的元件符號,代 表與圖2所示之外部電極式螢光燈〗相似的元件。 設置在外部電極式勞光燈13,的啟動加速層纪係 官的内壁表面上,且螢光材料層係在—部分的啟動加 ^層上與其形成疊層。啟動加速層&之#光透射管巾心侧的邊緣 夕外部電極3之靠光透射管中心侧之邊緣%10咖 側的位置3a,(示於圖2),或位於前述位置的靠 啟動树層63之絲義管核侧的邊緣 之外部電極3之靠光透射管中心侧之邊緣3a 1〇咖 来的位置3b’(示於圖2),或位於前述位置的靠 ί透ΐΐΓ:在圖5中,與圖2相似的元件符號,代表與圖2 所不之外部電極式螢光燈1相似的元件。 办认又置在外部電極式螢光燈14 +的啟動加速層64係 ❹ 内壁表面上,且螢光材料含在上述的層中。2 ‘靠:二罪Φ光if管中心側的邊緣64a係位於距離外部電極3 3a,(示於圖^心之邊緣3a 10 mm之靠光透射管中心側的位置 層t之靠井诱述位置的靠光透射管末端侧’而啟動加速 i透射管中心側:3^緣_,於距離外部電極3之靠 3bY千於m ^ 邊緣3 1〇 ^之靠光透射管末端侧的位置 血圖、2 或,於前述位置的靠光透射管中心侧。在圖6中,, =的^ 號’代表與圖2穌之外㈣極式螢光燈1 用於ΐΐϊ之外部電極式勞光燈’其特定範例為使 裝置 電月尚仃動電話、傳真機、影印機等中的液晶顯示 範例 兹在士以數個範雕贿本剌。 將螢光材料’連同卿酸鹽玻璃結合劑及魏_素,散佈 11 201009885 在醋酸丁酯中,俾使其具有濃度為60%重量比,而製備螢光材料 塗佈液體。將鈉玻璃管的内壁表面浸潰在合成的塗佈液體中;鈉 玻璃管的外直從為4.0 mm ’厚度為0.5 mm,長度為1〇〇〇 mm,且 具有重量比不超過10%的鹼類成分濃度。之後,將乾空氣運送穿 過該處,以乾燥而產生厚度為20 μιη的螢光材料層。 將具有-次粒子平均粒徑約為3〇腿的氧化鋅散佈在異 (IPA)^,以製備具有氧化鋅濃度重量比為5%的塗佈液體。 藉使用合成的塗佈液體,便將如圖3所示具有寬度為15咖、 在鈉玻齡—表面上, 共甲蛩光材料層已先被製造在鈉玻璃管中。 在將触猜輯㈣㈣錢_贿之後,_ 入触璃管中,並將鋼玻離管的兩端密 =納玻璃管各端的外圍表面上,並用焊料將其固定 的量測。極錢光舰行暗區啟動特性 小時,之i il fn Λ式勞光燈,將其置放於黑暗環境中72 勞光燈皆ί 管中電流,則發現3G個外部電極式 ❿ ,備的外性因?發現其中 本發明之外部電極式螢光燈的暗區特性較佳。Q此,顯然地, 【圖式簡單說明】 意圖圖1雜林發明之外㈣極絲絲之範_部分結構示 4係緣示本發明之外部電極^榮光剖面示意. 5係緣示本發明之外部電極式螢光燈之範二 圖 圖 示,。 12 201009885 ,雜示本發明之外部電極式螢紐之範例㈣面示意圖。 【主要元件符號說明】 1、1卜12、13、14〜外部電極式螢光燈 2〜光透射管 3〜外部電極 3a〜外部電極之靠光透射管中心側之邊緣 〜距離外部電極之靠光透射管中心側之邊緣靠光透射管中心側 10 mm的位置 3b’〜距離外部電極之靠光透射管中心側之邊緣之靠光透射管末端 側10 mm的位置 5〜螢光材料層 6、61、62、63、6、4〜啟動加速層 6a、61a、62a、63a、64a〜啟動加速層之靠光透射管中心侧之邊緣 6b、61b、62b、63b、64b〜啟動加速層之靠光透射管末端側之邊 緣The start acceleration layer 61 to be disposed in the external electrode type fluorescent lamp n in Fig. 3 is placed on the inner wall surface of the phosphor layer and the light transmission tube, and the edge of the center side of the light transmission tube is activated. 61a is located at a position 3a from the edge 3a of the outer side of the light transmitting tube on the center side of the light transmitting tube, 10 mm from the center of the light transmitting tube, (shown in FIG. 2), or at the end of the light transmitting tube at the aforementioned position; The edge 61b on the end side of the light transmitting tube of the accelerating layer & is located north of the edge 3a of the light transmitting tube from the edge 3a of the outer side of the light transmitting tube on the center side of the light transmitting tube, (shown at 2), or located at The aforementioned position is on the center side of the light transmission tube. In Fig. 3, the same reference numerals as in Fig. 2 denote elements similar to those of the external electrode type fluorescent lamp i shown in Fig. 2. The startup acceleration layer to be disposed in the external electrode type fluorescent lamp 12 in FIG. 4 is located on the inner wall surface of the light transmission tube, and the edge 62a of the activation acceleration layer 62 on the center side of the light transmission tube is located at a distance from the external electrode 3. By the position of the edge 3a 10 _ on the center side of the light transmission tube, the position on the center side of the light transmission tube, (shown in FIG. 2), or on the end side of the light transmission tube at the front position, and the light transmission of the acceleration layer 62 is activated. Tube end 201009885 • The edge is located at a position 3b from the edge of the outer side of the light transmitting tube on the center side of the light transmitting tube, as shown in the figure, or at the center of the position = sin light transmission tube. In Fig. 4, a component symbol similar to that of Fig. 2 represents an element similar to that of the external electrode type fluorescent lamp shown in Fig. 2. It is disposed on the inner wall surface of the external accelerator type lamp 13 which is activated by the accelerator lamp And the layer of the phosphor material is laminated on the starting layer of the portion of the phosphor layer. The edge of the center of the light transmitting tube of the accelerating layer & 10 coffee side position 3a, (shown in Figure 2) Or the position 3b' (shown in FIG. 2) of the outer electrode 3 of the edge of the light-transmissive tube on the side of the light-transmissing tube on the edge of the core of the wire-like tube 63 of the starting tree layer 63, or at the aforementioned position相对的位置: In Fig. 5, the same reference numerals as in Fig. 2 denote elements similar to those of the external electrode type fluorescent lamp 1 of Fig. 2. The identification is placed on the external electrode type fluorescent lamp 14 The start-up acceleration layer 64 is on the inner wall surface, and the fluorescent material is contained in the above layer. 2 'Resist: the edge 64a of the center side of the sin Φ light if tube is located at a distance from the external electrode 3 3a (shown in ^The edge of the heart 3a 10 mm by the position of the center side of the light transmission tube t is at the end of the light transmission tube at the end of the well-inducing position and accelerates the center side of the transmission tube: 3^ edge_, at the distance from the external electrode 3 by 3bY thousand m ^ edge 3 1〇^ by the position of the light transmission tube on the end side of the blood, 2 or at the position of the light transmission tube on the center side. In Figure 6, the = ^ ' Representative and Figure 2 (4) Pole Fluorescent Lamp 1 for external electrode type headlamps for sputum' The examples of liquid crystal display in the telephone, fax machine, photocopying machine, etc. are in the form of a number of Fans. The fluorescent material is combined with the clearing glass binder and Wei-Yu, spread 11 201009885 in diced acetate In the ester, the cerium is made to have a concentration of 60% by weight to prepare a fluorescent material coating liquid. The inner wall surface of the soda glass tube is immersed in the synthetic coating liquid; the outer straight line of the soda glass tube is 4.0 mm. 'The thickness is 0.5 mm, the length is 1 〇〇〇mm, and the concentration of the alkali component is not more than 10% by weight. After that, dry air is transported therethrough to dry to produce a phosphor with a thickness of 20 μm. Material layer. Zinc oxide having a primary particle diameter of about 3 angstroms was spread at a specific (IPA) to prepare a coating liquid having a zinc oxide concentration of 5% by weight. By using a synthetic coating liquid, a layer having a width of 15 coffee, as shown in Fig. 3, on the surface of the sodium silicate, has been first fabricated in a soda glass tube. After you touch the guess (4) (4) money _ bribe, _ into the glass tube, and the steel glass is separated from the ends of the tube = the outer surface of each end of the glass tube, and fixed with solder to measure. When the dark-light start-up characteristic of the ultra-light ship is small, the i il fn 劳-type worklight is placed in a dark environment. 72 The light is in the tube, and 3G external electrodes are found. External factors? It has been found that the dark spot characteristics of the external electrode type fluorescent lamp of the present invention are preferred. Q, obviously, [schematic description of the drawing] is intended to be in addition to the invention of the hybrid forest. (4) The outline of the filament wire is partially shown as the outline of the external electrode of the present invention. The second electrode diagram of the external electrode type fluorescent lamp is shown. 12 201009885, an example (4) of a schematic diagram of an external electrode type fluorescent button of the present invention. [Description of main component symbols] 1. 1, 12, 13, 14 to external electrode type fluorescent lamp 2 to light transmitting tube 3 to external electrode 3a to the edge of the external electrode by the center of the light transmitting tube - by the distance from the external electrode The edge of the center side of the light transmission tube is located 10 mm from the center side of the light transmission tube 3b' to the position 5 mm from the edge of the center side of the light transmission tube of the external electrode to the end side of the light transmission tube, 5 to the phosphor layer 6 , 61, 62, 63, 6, 4 to start the acceleration layer 6a, 61a, 62a, 63a, 64a to the edge 6b, 61b, 62b, 63b, 64b of the light-transmitting tube on the center side of the light-increasing layer By the edge of the end side of the light transmission tube

1313

Claims (1)

201009885 七、申請專利範圍: 1. -種外部電極式§光燈,其包含—絲射管、—螢光材料層及 -外部電極’該光透射管在其内部保树射氣體及采,該營 光材料層没置於該光透射管之一内壁表面上,該外部電極設置 於該光透射管之各端的一外圍表面上,其中: ,外部電極式螢絲包括—含氧鱗之啟動加速層,該啟動加 ^層位於該絲射管之内表面上之相麟至少—外部電極的一區 ^ 且ί啟動加速層之靠光透射管中心、側之邊緣位於距離該外 口 Ρ電,之靠光透射管中心側之邊緣#光透射管中心侧1G麵的位 置,或位於刖述位置之靠光透射管末端側。 2. 請i利範圍?1項之外部電極式螢光燈,其中,該啟動加 $二光透f管末ΐ侧之邊緣位於距離該外部電極之靠光透 ^中心侧之邊緣之靠光透射管末端供uo聰 刖述位置之靠光透射管中心側。 置次位於 3. 如申請專利範圍第1項之外部電極式 速層冬右gj於/, κ_ ^ 愛光燈’其中’該啟動加 ^ 4氧減、祕銘、氧化鈦、輸錢氧倾之一或更 ◎ 4. 如申請專利範圍第i項之外部電極 速艾具有一部分’該部分係以該螢光材料“;層該$加 動加速層之材料所纽成。 九材枓層之材料及構成該啟 5. 如申請專利範圍第!項之外部電極式 _ 具有一次粒子,該一次粒子之平/、中,該氧化鋅 十攝後不超過100酿。 6· 一種裝設有申請專利範圍第丨至6 光燈的設備。 4 項之外部電極式螢201009885 VII. Patent application scope: 1. An external electrode type § light lamp, comprising: a wire tube, a fluorescent material layer and an external electrode, wherein the light transmission tube protects the gas and the inside of the light transmission tube, The camping light material layer is not disposed on an inner wall surface of the light transmitting tube, and the outer electrode is disposed on a peripheral surface of each end of the light transmitting tube, wherein: the external electrode type filament comprises: an oxygen-containing scale starting acceleration a layer, the start-up layer is located on the inner surface of the wire tube, at least one region of the outer electrode, and the illuminating layer is located at the center of the light-transmitting tube, and the edge of the side is located at a distance from the outer port. The edge of the center side of the light transmission tube #1 is the position of the 1G surface on the center side of the light transmission tube, or the end of the light transmission tube at the position of the light transmission. 2. Please refer to the external electrode type fluorescent lamp of the first item, wherein the edge of the end of the opening and the end of the light is located at the edge of the outer side of the outer electrode. The end of the transmission tube is provided by the center of the light transmission tube. Set the time to 3. In the scope of the patent application, the external electrode type fast layer winter right gj in /, κ_ ^ love light 'where 'the start plus ^ 4 oxygen reduction, secret Ming, titanium oxide, lose money oxygen dump One or more 4. The external electrode of the item i of the scope of the patent application has a part of 'the part is made of the fluorescent material'; the layer is made of the material of the acceleration layer. And constitute the Kai 5. If the external electrode type _ of the patent application scope item _ has primary particles, the primary particles are flat/medium, and the zinc oxide does not exceed 100 after ten shots. Equipment with a range of 6th to 6th light. 4th external electrode type
TW098122051A 2008-07-24 2009-06-30 External electrode fluorescent lamp and apparatus utilizing the same TWI389164B (en)

Applications Claiming Priority (1)

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JP2008191276A JP2010027576A (en) 2008-07-24 2008-07-24 Outer surface electrode fluorescent lamp

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TWI389164B TWI389164B (en) 2013-03-11

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080252193A1 (en) * 2005-05-31 2008-10-16 Kenji Yamada Fluorescent Lamp, Backlight Unit and Liquid Crystal Television
JP2007073481A (en) * 2005-09-09 2007-03-22 Nec Lighting Ltd Discharge lamp
KR20070076197A (en) * 2006-01-18 2007-07-24 삼성전자주식회사 External electrode lamp, manufacturing method thereof and liquid crystal display using the same

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