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TW200919527A - Fluorescent discharge lamp tube of novel structure and LCD display device - Google Patents

Fluorescent discharge lamp tube of novel structure and LCD display device Download PDF

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Publication number
TW200919527A
TW200919527A TW097109779A TW97109779A TW200919527A TW 200919527 A TW200919527 A TW 200919527A TW 097109779 A TW097109779 A TW 097109779A TW 97109779 A TW97109779 A TW 97109779A TW 200919527 A TW200919527 A TW 200919527A
Authority
TW
Taiwan
Prior art keywords
fluorescent
phosphor
discharge lamp
light
discharge
Prior art date
Application number
TW097109779A
Other languages
Chinese (zh)
Inventor
Lyuji Ozawa
Original Assignee
Daiken Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daiken Chemical Co Ltd filed Critical Daiken Chemical Co Ltd
Publication of TW200919527A publication Critical patent/TW200919527A/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J65/00Lamps without any electrode inside the vessel; Lamps with at least one main electrode outside the vessel
    • H01J65/04Lamps in which a gas filling is excited to luminesce by an external electromagnetic field or by external corpuscular radiation, e.g. for indicating plasma display panels
    • H01J65/042Lamps in which a gas filling is excited to luminesce by an external electromagnetic field or by external corpuscular radiation, e.g. for indicating plasma display panels by an external electromagnetic field
    • H01J65/046Lamps in which a gas filling is excited to luminesce by an external electromagnetic field or by external corpuscular radiation, e.g. for indicating plasma display panels by an external electromagnetic field the field being produced by using capacitive means around the vessel
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/30Vessels; Containers
    • H01J61/305Flat vessels or containers

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  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Vessels And Coating Films For Discharge Lamps (AREA)
  • Discharge Lamp (AREA)

Abstract

The invention provides a fluorescent discharge lamp tube, which comprises independent inner and outer circuits of electron flow and has the character of high light-up. Around electric insulated particles covered with metal electrodes, the inner circuit is employed to form electron cloud and ion cloud produced from electricity discharge gas ionization for use as the power source. The gas discharges while the electron of the electron cloud migrates to the ion cloud. The electron and the ion are combined into gas and the inner circuit is then closed. Gas discharging is performed without inputting electron into the outer circuit, without the exposure of metal and without metal evaporation so that the lifetime can be longer. As the electron of initial speed close to zero is used, the cathode voltage drop (40 percent of the entirety) inevitably encountered in the conventional skill can be avoided to greatly reduce light-up electricity. Fluorescent film is made from the mixed powder of electron beam phosphor and photo-phosphor. The electron flow of conduction on the surface of the fluorescent film is applied to leading the start of the discharge, thereby achieving the instantaneous light-up and the entire surface light-up in about 10 milliseconds. If several fluorescent discharge lamp tubes of the invention are applied to backlight of LCD for proceeding linearly sequential scan, the picture quality of LCD screen can be greatly enhanced.

Description

200919527 九、發明說明: 【發明所屬之技術領域】 本發明係關於一種螢光放電燈管,其藉由電子之非彈 性碰撞而使氬氣(Ar )與汞(Hg )蒸氣之混合氣體發光, 並藉由於螢光放電燈管内壁面上塗佈之螢光膜而將其中之 Hg發出之較強之254 nm不可見紫外線轉換為可見光,更 洋細而言,本發明係關於一種新穎螢光放電燈管及使用其 之LCD ( Liquid-crystal display,液晶顯示器)顯示裝置, 藉由改變螢光放電燈管之基本構造,儘管放電燈管之點亮 所需之耗電低於習知之螢光放電燈管的點亮,但能以習知 之#光放電燈管亮度兩倍以上之高亮度發光。 【先前技術】 [習知之放電燈與本發明之概要] 習知之螢光放電燈管之放電係自冷陰極電極(c〇id Ca—de Flu〇rescent Lamps,咖)、或熱陰極電極㈤ ⑽ode Fluoresceni Lamps,HCFL )取出放電所需之電子。 J等电桎共通之事項在於’自電極取出之電子具有高能200919527 IX. Description of the Invention: [Technical Field] The present invention relates to a fluorescent discharge lamp which emits a mixed gas of argon (Ar) and mercury (Hg) vapor by inelastic collision of electrons. And by using the fluorescent film coated on the inner wall surface of the fluorescent discharge lamp to convert the strong 254 nm invisible ultraviolet light emitted by Hg into visible light, and more specifically, the present invention relates to a novel fluorescent light. A discharge lamp tube and an LCD (Liquid Crystal Display) display device using the same, by changing the basic structure of the fluorescent discharge lamp, although the power consumption of the discharge lamp is lower than that of the conventional fluorescent lamp The discharge lamp is lit, but can be illuminated with a high brightness of more than twice the brightness of the conventional light discharge lamp. [Prior Art] [Preferred discharge lamp and outline of the present invention] The discharge of a conventional fluorescent discharge lamp is a cold cathode electrode (c〇id Ca-de Flu〇rescent Lamps, coffee) or a hot cathode electrode (5) (10) ode Fluoresceni Lamps, HCFL) removes the electrons required for discharge. The common thing about J et al. is that the electrons taken out from the electrode have high energy.

置:且採用強行進人氣體空間之方式,因此直至電 為氣體放電所需之台L … b值為止之期間有複雜之現象介入, ::引起陰極電麼大幅降低。該陰極電屢降低完全盘發光 值為劻古其針舰 上述氧體放電所需之能量 ,“,整體所需之能量之大約40%。而本 非自金屬電極取出氣體放亚 管之兩端分別形成電子”離:;電 疋於氣體放電 在與離子雲’於自電子雲取出之電 200919527 子於放電管中遷移 ^ ^ §| , 。程中引起氣體放電,而到達離1 + 之电子則與離子再妹八 逆離子雲 ^ ^ 、0 5並开》成氣體。藉由該氣體开:士 電管内以電子雲盥 g田成矾髖形成,敌 ^ ψ /、 妥作為驅動源之電路封閉。自雷 公取出之電子之能景 目電子 往果Α 、零,上述陰極電壓不會降低。 、’口果為’與相同管輕夕姓+ , 其 .tet ^ 笔燈相比時,本發明之螢光放兩 W可以40%以下之電力點亮。 愛先放4 本發明藉由改變雷搞据 ^ ra ^ ^ 罨桎構&,而消除於螢光放電燈 知因陰極電壓降低而導致 电燈之营 本發明之螢光放電燈管 九,、…果為, „ . ^ 自放電燈之管端遍及整個表& 以均勻強度發光。習知之罄 定幻表面 ^ r p, . m . 螢先放電燈管中,於陰極電壓降 低之乾圍内因發光而產生 电垩降 W 士、, 用之熱’但本發明之螢光放雷 文豆官中亚不產生埶,瞢 疋欲宅 露於氣體中之金屬電極,因此太& 升又亚無暴 命非常長。 因此本發明之螢錢電燈管之壽 習知之螢光放電燈管之氣體放電 ^ _ JL pa θ§ ρ , 存在長J未解決 ^ ^ ^ 點冗之相關機制不明確, 因此各種改良只不過是僅根據經 尿丄驗而應用於螢光放電燈管 之點党。本發明者首次闡明了氣 ^ 制。5 + ' 電之點受之相關機 主二* U素係於螢光膜上遷移之 表面導電電子之控制。氣體放電 他从狄 點壳之問題,可藉由塗 佈於螢光放電燈管内之螢光體之選 βΛ %释、以及所選擇之螢光 體粒子之排列而得以解決。其紝果 收& 、…為’本發明之螢光放電 燈官具有於1毫秒左右瞬時點亮之特徵 螢光放電燈管存在即便增加耠λ Μ入電力’螢光膜之亮度 200919527 亦會飽和之現象,該飽和現象之問題在5〇餘年間—直未 獲得解決。該飽和現象限制螢光放電燈管之亮度,導致、 了獲得必要之房間照明⑨,而必須於房間内二多:螢: 放電燈。本發明亦解決此問題。因排列於勞光膜最上層之 螢光體粒子具有之負電荷的庫余斥力,使陽極區之電子無 法接近螢光膜,陽極區收容於螢光膜之負電荷(sbe SUrface-b〇und-electrons,表面結合電子)之鞘内。若自螢 光膜除去SBE鞘,則陽極區擴展至螢光膜,螢光膜之光輸 出與輸入電力成正比。可藉由亮度之增加而減少房屋照日^ :使用之螢光放電燈數,省電效果明冑,且因減少二氧化 兔氣體而對環境保護作出重大貢獻。 【發明内容】 人類之生活因照亮黑暗之光源之開發而快速進步。光 :之歷史始於營火,後發展為燃燒火炬、植物油、石油、 、以及煤氣等,逐漸實現了照明度之提高。作為近代 學基礎t電子之發現使光源之照明度變革之歷史得以較 :改變。發現電子後,開發出利用電子運動之鶴絲燈以及 子光放电k ’亚廣泛應用於世界中。最近,有同樣利用電 行為之發光二極體(light_emiuing di〇de,led 電場於朵r , m 光(^ 灿〇 1UmineSCenCe,EL )、以及有機電場發 。了ic light_emiuing di〇de,〇led)之提案,並進行 之實用評價。利用電子行為之各種光源可以如下方 進行科學評價。 工 鎢絲燈係利用藉由電子運動時之電阻所產生之焦耳熱 200919527 而將鎮金屬加熱至高溫(3,⑼代左右)所得之光。輸入電 力轉換為可見光之能量轉換效率較低,為〇 8%,但直至金 屬軟化點之高溫為止皆可保持轉換效率,因此可藉由增減 輸入電力而獲得更廣範圍之光度。因此,當前鎢絲燈仍廣 泛用作房屋内外之照明光源。最多之使用者係普通家庭。 鎢絲f係可最廉價地製造之光源,且在世界上大多家庭中 做為簡便之照明光源使用。缺點係壽命短(5〇〇小時)。 加熱後之金屬會蒸發,因此隨著點亮時間經過,鶴絲線會 變細,電阻增加而導致斷線。 螢光放電燈係藉由玻璃管内帛面所塗佈t營光膜,將 W氣體之不可見紫外線發光轉換為可見光的光源,能量轉 換效率約4 2G%。問題與鶴絲燈不同,是在於螢光膜之發 光強度相對於輸入會飽和,自單一榮光放電燈取出之光量 存在極限。飽和⑨度之水準較低,因此於需高亮度照明之 方門中排列多個螢光放電燈。相比於鎢絲燈,螢光放電 燈雖價格高,㉟能量轉換效率較高,產生之熱較少,因此 用狖工業化社會之較大高樓内之事務室之主照明。工業化 達之國豕中,作為省電照明光源而普及至普通家庭之房 至=衫響螢光放電燈壽命之原因主要係發射電子之電極 陽離子所導致產生的㈣。其他原因㈣光膜表面吸附 :光放電官内之有機殘留氣體,而於紫外線到達登光膜之 ♦吸附氣體層便已吸收紫外線。有機殘留氣體根據勞光放 :燈管之製造步驟中之除氣步驟之程度,及因⑥Hg汞齊 與Ba集氣器之活化初期產生大量有機氣體故於活化時進 200919527 行排氣之條件而產生甚大變化,可減少至能忽略之水準。 當前之螢光放電燈之壽命長於鎢絲燈之壽命,約為2,000 小時左右。 LED係作為近代電子產業技術之一個應用例而開發 者。LED由使無機元素之薄膜多層重疊之元件而製作成。 為了使LED發光,向LED之薄膜層注入電子,並於發光 中〜(雜質)注入電子與電洞再結合時發光。LEd之問題 在於:雖有約一半之注入電子有助於發光,但剩餘之一半 電子無法於發光中心發光,而是轉換為熱。發光強度雖與 注入之電子數成正比,但LED之溫度亦成比例地變成高 溫。即便將LED加熱至70〇c左右,亦可忽略發光強度之 經時變化。若將LED加熱為1〇〇〇c以上,則薄膜中之發光 (雜貝)因熱而自薄膜内向薄膜外擴散,因此隨著時 間推移光中心數不斷減少。發光強度隨著溫度及時間 之推移而急遽減弱。實用LED亮度之操作條件下,咖為 :〇C左右。雖利用眼睛目測到亮度時出現之殘像效應,萨 發光而防止溫度上升,但並未本質上解決問題。Γ /攸艮本上解決發熱問題。明亮之咖存在壽命之問題·。、、、 亦藉由無機材料元件之薄膜之積層 原理與LPD知fi u J ^ 行發光二Γ 子與電洞於發^心再結合而進Set: and the method of strong traveling gas space is adopted, so there is a complicated phenomenon during the period until the electric power is required to discharge the gas L ... b, and :: causing the cathode electric power to be greatly reduced. The cathode electricity repeatedly reduces the total disk illuminating value to the energy required for the above-mentioned oxygen discharge of the ancient ship, "the overall required energy is about 40%. And the non-self-metal electrode takes out the gas discharge tube at both ends of the tube. The electrons are separated from each other; the electricity is discharged in the discharge tube with the gas discharge in the ion cloud 'removed from the electron cloud ^ ^ §| , . The gas is caused to discharge in the process, and the electrons reaching 1 + are separated from the ions by the counter ion cloud ^ ^ and 0 5 . With the gas on the inside of the electrician, the electronic cloud is used to form the hip, and the enemy is used as the driving source. The electrons taken out from Leigong can be reduced to the above-mentioned cathode voltage. When the 'mouth is ' and the same tube lighter + surname, compared with the .tet ^ pen lamp, the fluorescent light of the present invention can be illuminated by 40% or less. The invention is based on the invention, and the fluorescent discharge lamp of the present invention is eliminated by the change of the cathode discharge voltage caused by the decrease of the cathode voltage of the fluorescent discharge lamp. ...... The result is that the tube end of the self-discharge lamp spreads over the entire surface & with uniform intensity. The conventional illusion surface ^ rp, . m . The internal cause emits electricity and the electric power is lowered, and the heat is used. However, the fluorescent light of the present invention, the Leizhong bean official, does not produce sputum, and the sputum is exposed to the metal electrode in the gas, so too & The sub-destroy is very long. Therefore, the gas discharge of the fluorescent lamp of the present invention is known as the gas discharge of the fluorescent discharge lamp ^ _ JL pa θ§ ρ , the existence of the long J is not solved ^ ^ ^ The mechanism of the point redundancy is not Clearly, therefore, the various improvements are only the point of application to the fluorescent discharge lamp tube based on the urinary test. The inventors have for the first time clarified the gas control system. 5 + 'Electrical points are affected by the main machine 2* U The control of the surface conduction electrons that migrate on the fluorescent film. The gas discharges him from the Dian point shell. The problem can be solved by the βΛ% release of the phosphor coated in the fluorescent discharge tube and the arrangement of the selected phosphor particles. The result is & The fluorescent discharge lamp has a characteristic that the fluorescent discharge lamp is instantaneously lit in about 1 millisecond. Even if the brightness of the fluorescent film is increased, the brightness of the fluorescent film 200919527 is saturated. The saturation phenomenon is 5〇. For the rest of the year—there is no solution. This saturation restricts the brightness of the fluorescent discharge lamp, resulting in the necessary room illumination 9 and must be more than two in the room: Firefly: Discharge lamp. The present invention also solves this problem. Because of the negative repulsive repulsion of the phosphor particles arranged in the uppermost layer of the working film, the electrons in the anode region cannot be close to the fluorescent film, and the anode region is contained in the negative charge of the fluorescent film (sbe SUrface-b〇und -electrons, the surface of the electrons in the sheath. If the SBE sheath is removed from the phosphor film, the anode region extends to the phosphor film, and the light output of the phosphor film is proportional to the input power. The house can be reduced by the increase in brightness. Photo day ^ : The number of fluorescent discharge lamps used has a clear power saving effect, and contributes greatly to environmental protection by reducing the oxidation of rabbit gas. [Summary of the Invention] Human life is rapidly progressing due to the development of a light source that illuminates the darkness. The history began with campfires, and later developed into burning torches, vegetable oils, oil, and gas, and gradually improved the illumination. As the basis of modern science, the discovery of the t-electronics made the history of the illumination of the light source change: change. After the discovery of electrons, the development of the use of electronic movement of the crane lamp and the sub-photovoltaic discharge k'A is widely used in the world. Recently, there are light-emitting diodes (light_emiuing di〇de, led electric field) that also utilize electrical behavior. m light (^ mine 〇 1UmineSCenCe, EL), and organic electric field. The proposal of ic light_emiuing di〇de, 〇led), and a practical evaluation. Various sources of light using electronic behavior can be scientifically evaluated as follows. The tungsten filament lamp heats the town metal to a high temperature (3, (9) generation) by using Joule heat 200919527 generated by the resistance of the electron movement. The energy conversion efficiency of input power to visible light is low, 〇 8%, but the conversion efficiency can be maintained until the high temperature of the metal softening point, so that a wider range of luminosity can be obtained by increasing or decreasing the input power. Therefore, the current tungsten filament lamp is still widely used as an illumination source inside and outside the house. The most users are ordinary families. Tungsten wire f is the light source that can be manufactured at the cheapest price, and is used as a simple illumination source in most households around the world. The shortcomings are short life (5 hours). The heated metal will evaporate, so as the lighting time passes, the crane wire will become thinner and the resistance will increase and the wire will be broken. The fluorescent discharge lamp converts the invisible ultraviolet ray of W gas into a visible light source by coating the t-light film on the inner surface of the glass tube, and the energy conversion efficiency is about 42 G%. The problem is different from the crane light. The light intensity of the fluorescent film is saturated with respect to the input, and the amount of light taken out from a single glare discharge lamp has a limit. The saturation level is lower than 9 degrees, so multiple fluorescent discharge lamps are arranged in the door requiring high brightness illumination. Compared with tungsten lamps, fluorescent discharge lamps are expensive, 35 energy conversion efficiency is high, and generate less heat, so they are used for the main lighting in the office of a large building in an industrialized society. Industrialization In the country, it is widely used as a power-saving lighting source to the ordinary family. The reason for the life of the singer-sounding fluorescent lamp is mainly caused by the cation of the electron-emitting electrode (4). Other reasons (4) Adsorption on the surface of the light film: The organic residual gas in the light discharge official, and the ultraviolet light reaches the light film. The adsorbed gas layer absorbs the ultraviolet light. The organic residual gas is discharged according to the degree of the degassing step in the manufacturing process of the lamp tube and the large amount of organic gas generated in the initial stage of activation of the 6Hg amalgam and the Ba collector. Great changes can be made to a level that can be ignored. The current life of fluorescent discharge lamps is longer than the life of tungsten lamps, which is about 2,000 hours. LED is a developer of an application example of modern electronics industry technology. The LED is fabricated by an element in which a thin film of an inorganic element is stacked in multiple layers. In order to cause the LED to emit light, electrons are injected into the thin film layer of the LED, and light is emitted when the injected electrons and the holes are recombined in the light emission. The problem with LEd is that although about half of the injected electrons help to illuminate, one of the remaining electrons cannot be illuminated at the center of the luminescence, but instead is converted to heat. Although the luminous intensity is proportional to the number of electrons injected, the temperature of the LED also becomes proportionally high. Even if the LED is heated to about 70 〇c, the change in luminous intensity over time can be ignored. When the LED is heated to 1 〇〇〇c or more, the luminescence (misc) in the film spreads out from the inside of the film due to heat, so the number of light centers decreases with time. Luminous intensity is rapidly diminished with temperature and time. Under the operating conditions of practical LED brightness, the coffee is: 〇C or so. Although the afterimage effect of brightness is visually observed by the eye, Sa emits light to prevent temperature rise, but does not substantially solve the problem. Γ / 攸艮 解决 solve the fever problem. The problem of the life of a bright coffee. And, by the principle of lamination of thin films of inorganic material elements, LPD knows that the light-emitting diodes and the holes are combined in the heart.

丁“。各薄膜層之厚度遠大於L 扯發光,必須施加高電壓μ 之厚度®此為了使 減。EL之拿^ 〖。發光強度與輸入電壓成正比增 生放電擊穿。放電擊穿限制了溥媒層會產 J J 之蚨大壳度。壽命之問 200919527 題係發光中心之擴散導致亮度劣化。EL之研究開發持續了 5〇餘年’其間亦多次報道了實用化產品,但均未本質上改 善上述問題,產品並未出現在市場便已消失。該重複現象 產自亞洲諸國之大企業,但歐美之大企業並未產生。〇led 具有與EL相同之問題,明亮之〇LED若連續點亮會有壽 命問題。以低照明度使用0LED _可減輕問題,因此限定 了 OLED之使用範圍。 如上所述開發提出之照明光源均未解決實用化時之主 要問題。當前剩下之照明光源係營光放電燈。營光放電燈 之開發研究長達50餘年,作為榮光放電燈基礎之放電: 科學研究更長達⑽年以上。根據該情形普通投資者及企 業經營者認為螢光放電燈之技術已開發完畢。本發明者自 當前為止確立之放電理論之最某 , 取丞礎。卩分開始進行重新檢 δ才’並^试進行驗證。其纟士黑 八、°果仵知,認為螢光放電燈之技 術已開發完畢之評論並不正確, 了以對螢光放電燈之基本 構造進订改良。 闡述放電現象之前,先老 亏慮人颏必要之光源照明度。 即便照亮黑暗,非夜行性之人 月厪 顆之主要活動於500萬年之 間為白天活動,當前我們的 呀邪過應白天之亮膚。鈇而, 眼睛並不適應晴朗白天之旦 …、 —, 斤、已’而是適應白天微_之真 度。光係具有波動之光子,本2 又试丨农之冗 吐t a 士 尤子之能量因波長而異。平泊 值為具有2.3 eV能量之綠多 , 一。白天之景色係取決於措降 之白天之照明度,其照明於微陰 中照射⑽個左右之光子。田於早位時間内每單位面積 之能量為3.7χ〗〇,19 10 200919527 故上述照明度達到80 w/cm2 曰 <犯Ϊ。照明光源中發射 述光子數之光源對人眼最舒適。 w/ 2 ^ Bt _ 右此1轉換效率累計為80 W/cm和則可計算出所開發 3 ^ 匆之先源之必需輸入。作為如此 之光源,已有開發出各種光源。 丹甲鱟光放電燈被選作备 合適之光源’在過去6〇餘车門泛丄 年間為大眾所接受。然而,每 根螢光放電燈管之昭明声侗 ^ 列多根螢光放電管來獲得最佳昭貫才係排 照明度之照明。若可提高每 根螢光放電燈管之照明声,目丨丨叮、上、 ^ …、又則可減少照明所使用之螢光放 電燈管數,隨之亦可減少Μ 藏少耗電。又,為減少耗電,不使用 時使螢光放電燈管镅I Μ、他 电-"員繁閃爍’因此對電極之損傷加快。為 解決該等問題人們Ρ #山1 , 們已付出了大量努力,但滿足度遠遠不 足,螢:放電燈管之劃時代之改良仍受到期待。 田:使用之螢光放電燈管之構造非常簡單。真空密封 之玻,g内包3適篁之Ar氣體與Hg氣體,金屬電極内藏 <玻& g之兩端’且於玻璃管之内壁塗饰有將紫外線轉換 2見光之營光膜。金屬電極經由金屬棒之傳導體而與外 邓电源連接。放電係對金屬電極施加正弦波之交流高電 位,於真空中自金屬電極取出電子,將取出之電子加速, 使其與介於放電管兩端之電極間之空間令的&與取氣體 石亚才里。,從而引起放電。放電時受到激發之Hg氣體所發射 不可見之254 nm紫外線(uitravi〇iet,uv )之產生具有 重大作用。所發射之不可見UV光照射至塗佈於放電燈管 内土面之勞光膜上。螢光膜將不可見uv光轉換為可見光, 以此來製作螢光放電燈管。因構造簡單,故螢光放電燈管 200919527 之技術者已進行久兩μ 令件之最佳化。榮 今已經過60餘年,每年之產=放«官自市售至 與螢光放電燈管相關之技術已二::二因此通常認為 而,上述最佳化係 4亦非不可理解。然 他从匕確立之槿谇i么 佳化,而並未檢討構&為則提之範圍内之最 才螢先放電燈管之基本構造。 根據固體元件及液體 燈管之驅動本質上必須向榮光=類推出’上述營光放電 空中發射電子之材:燈管内注入電子。於真 1射電子之材抖係於近代科學 對工作函數較小之金屬進行了 ⑽年代發現’ 發現若對金屬進行加敎, 直^A.Edlson於1884年 ,$ 則可向真空中發射埶電子。冷盖 熱電子發射之重大發現,係若用過氧化物改善 :::)覆蓋加熱至8。。。。之鎢絲,則容易發射出 子/其係Ba-氧化物發射熱電子之效果最佳。螢光放、電 燈官之陰極採用覆蓋有Ba•氧化物之鶴絲。 而開發出管徑為25 _以上 p之幻、 ^ ( ΗΓΡΤ ^ . 耷尤放電燈® ’並作為熱陰 極放U (HCFL)而普及。㈣年,發現金^直^ 間之FI — N〇rdheim穿隨效應,檢討了金屬板金二 釣鐘型 '表面凹凸等金屬電極形狀。其結果為,採用了釣 鐘型之金屬電極。金屬電極可加工成較小者’因此金屬電 極之管徑可小至15_以下’尤其作為液晶顯示 _ crystal display,LCD)之昔忠、、s 工_ ¥、ώ 丄 月先源而普遍使用内徑為2 mm 以下的冷陰極螢光放電燈管(CCFL)。 使用上述金屬陰極之螢光放電燈管之電極中,·l 與CCFL均存在金屬陰極素材會蒸發之問題1下對陰極 12 200919527 電極之蒸發加以說明。氣體中質量較大之陽離子與陰極碰 撞。陽離子之碰撞會使金屬電極之極小部分瞬時被加熱至 金屬蒸發之高溫。所蒸發之金屬元素沈積於溫度較低之電 極周邊之玻璃管内壁上塗佈的螢光膜上。該現象被稱作藏 鍍。經金屬元素濺鍍而成之薄膜内,吸附有放電管内之射 氣體與Hg》氣,t光放電燈管内之氣體^減少程度隨著 點冗時間經過而加重,從而使螢光放電燈管之壽命縮短。 因濺鍍現象而導致螢光放電燈管之平均壽命為2,〇〇〇小 時。作為減少金屬陰極電極之濺鍍現象之方法,根據經驗 對電極金屬材料以及密封氣體壓力進行了檢討,但仍無法 從根本上解決問題。 … HCFL與CCFL存在多個共同之未解決問題。其中一 個較大問題係如下現象:使用金屬電極之螢光放電燈管之 陰極與陽極前方近處之狹小距離上’施加電壓會大幅變 化。於施加電壓急遽變化之範圍内,可觀測到8個發光與 不發光之條紋。發光條紋以最初之觀測者之姓名命名。該 寻規測者為 Aston dark、Cathode gl〇w、Cr〇〇ke,s 如吐'Ding. The thickness of each film layer is much larger than that of L. The thickness of the high voltage μ must be applied. This is to reduce the EL. The luminous intensity is proportional to the input voltage. The discharge breakdown is limited. The discharge breakdown is limited. The media layer will produce JJ's large shell. Lifetime 200919527 The diffusion of the illuminating center causes the brightness to deteriorate. The research and development of EL has lasted for more than 5 years, and the practical products have been reported many times, but they are not essential. The above problems have been improved, and the products have disappeared without appearing in the market. This duplication has been produced by large companies in Asian countries, but large companies in Europe and the United States have not been produced. 〇led has the same problems as EL, bright LED Continuous lighting will have life problems. Using 0LED _ with low illumination can alleviate the problem, thus limiting the scope of use of OLEDs. The illumination sources developed as described above have not solved the main problems in practical use. The light source is a camping light discharge lamp. The development of camp light discharge lamp has been researched for more than 50 years, as the discharge of glory discharge lamp: scientific research is longer than (10) years. According to this situation Ordinary investors and business operators believe that the technology of fluorescent discharge lamps has been developed. The inventors have established the most important theory of discharge theory so far, and the basis for the re-examination of δ is started. The gentleman black eight, ° fruit know, think that the technology of fluorescent discharge lamp has been developed is not correct, in order to improve the basic structure of the fluorescent discharge lamp. Before the discharge phenomenon, the old loss Considering the necessary illumination of the light source. Even if it illuminates the darkness, the main activity of the non-night person is the daytime activity between 5 million years. At present, our evil spirits should be brighter during the day. It does not adapt to the sunny daytime..., —, jin, has 'but adapted to the true degree of daytime micro _. The light system has fluctuating photons, and this 2 tries to smash the peasant’s energy. The flat berth is more green with 2.3 eV energy, and the daytime scenery depends on the illumination of the day during the sag, and the illumination illuminates (10) photons in the slight yin. Unit area The amount is 3.7χ〗, 19 10 200919527 Therefore, the above illumination reaches 80 w/cm2 曰< Ϊ. The light source emitting the number of photons in the illumination source is most comfortable for the human eye. w/ 2 ^ Bt _ Right 1 conversion The cumulative efficiency is 80 W/cm and the necessary input for the development of the 3 ^ rush source can be calculated. As such a light source, various light sources have been developed. Dan Aluminium Xenon discharge lamp was selected as a suitable light source 'in the past 6 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 车 然而 然而 然而 然而 然而 然而 然而 然而Improve the lighting sound of each fluorescent discharge tube, witness, upper, ^ ..., and reduce the number of fluorescent discharge lamps used in lighting, and thus reduce the consumption of electricity. In addition, in order to reduce the power consumption, the fluorescent discharge lamp is 镅I Μ, and the electric-" In order to solve these problems, people #Ρ1, we have put a lot of effort, but the satisfaction is far from enough. Firefly: The epoch-making improvement of discharge lamps is still expected. Tian: The construction of the fluorescent discharge lamp used is very simple. Vacuum sealed glass, g contains 3 suitable Ar gas and Hg gas, metal electrode contains <glass & g both ends' and the inner wall of the glass tube is coated with a light film that converts ultraviolet light to 2 . The metal electrode is connected to the external power source via the conductor of the metal bar. The discharge system applies a sinusoidal alternating current high potential to the metal electrode, extracts electrons from the metal electrode in a vacuum, accelerates the extracted electrons, and makes a space between the electrodes at both ends of the discharge tube and the gas stone. in. , causing a discharge. The invisible 254 nm ultraviolet light (uitravi〇iet, uv) emitted by the excited Hg gas during discharge has a significant effect. The invisible UV light emitted is irradiated onto the working film applied to the soil surface of the discharge lamp. A fluorescent film converts invisible uv light into visible light to produce a fluorescent discharge lamp. Due to the simple structure, the technician of the fluorescent discharge lamp 200919527 has been optimized for a long time. Rong has been in business for more than 60 years, and the annual production = release of the company's technology from the market to the fluorescent discharge lamp has been two:: Second, it is generally believed that the above optimization system 4 is not incomprehensible. However, he has not established a review of the basic structure of the first discharge lamp in the scope of the structure. According to the driving of the solid element and the liquid lamp, it is essential to introduce the above-mentioned camp light discharge air-emitting electron material: electrons are injected into the lamp tube. Yu Zhen 1 shoots electrons in the modern science of the metal with a small work function (10) found that 'if the metal is twisted, straight ^A.Edlson in 1884, $ can be launched into the vacuum埶electronic. Cold cover The major discovery of thermal electron emission is the use of peroxide to improve the :::) coverage heating to 8. . . . The tungsten wire is easy to emit the best effect of the emitter/the Ba-oxide emitting hot electrons. The cathode of the fluorescent lamp and the lamp officer is covered with a Ba• oxide. The development of a tube diameter of 25 _ or more p, ^ ( ΗΓΡΤ ^ . Chiyou discharge lamp ® ' and popular as a hot cathode discharge U (HCFL). (D) years, found the gold ^ straight ^ between FI - N〇 With the effect of rdheim, the shape of the metal electrode such as the surface irregularity of the metal plate and the second fishing bell type was reviewed. As a result, the metal electrode of the bell-shaped type was used. The metal electrode can be processed into a smaller one, so the diameter of the metal electrode can be as small as possible. 15_Following, especially as a liquid crystal display (LCD display), it is commonly used as a cold cathode fluorescent discharge lamp (CCFL) with an inner diameter of 2 mm or less. In the electrode of the fluorescent discharge lamp using the above metal cathode, the evaporation of the electrode of the cathode 12 200919527 is explained by the problem that both the metal and the CCFL are evaporated. The cation with a higher mass in the gas collides with the cathode. The collision of the cation causes a very small portion of the metal electrode to be instantaneously heated to a high temperature at which the metal evaporates. The evaporated metal element is deposited on the fluorescent film coated on the inner wall of the glass tube around the lower temperature electrode. This phenomenon is called Tibetan plating. In the film formed by sputtering of metal elements, the gas and Hg gas in the discharge tube are adsorbed, and the degree of gas reduction in the t-light discharge lamp is increased with the passage of time, thereby making the fluorescent discharge tube The life is shortened. The average life of the fluorescent discharge lamp due to sputtering is 2, 〇〇〇 small. As a method of reducing the sputtering phenomenon of the metal cathode electrode, the electrode metal material and the sealing gas pressure have been reviewed based on experience, but the problem has not been fundamentally solved. ... There are several unresolved issues in common between HCFL and CCFL. One of the major problems is the fact that the applied voltage at the narrow distance between the cathode of the fluorescent discharge lamp using a metal electrode and the front of the anode greatly changes. In the range where the applied voltage is rapidly changing, eight illuminating and non-illuminating streaks are observed. The luminescent stripes are named after the original observer. The finder is Aston dark, Cathode gl〇w, Cr〇〇ke, s such as spit'

Negative Glow > Faraday dark ^ Positive Column ^ Anode Glow、以及Anode Dark。雖大致說明了該等條紋但此說 明係限於對觀測現象進行說明之範圍,而並未闡明產生發 光條紋之科學根據。於陰極較顯著地產生該等不規則發 光。將該陰極周邊之施加電壓之急遽變化統稱為陰極電壓 降低1陰極電壓降低而損失之能量,達到螢統電燈管 之整體點亮能量之·左右’消除陰極電壓降低雖係開發 13 200919527 省電榮光放電燈管中之一重要課題,但因原因不明,故仍 2法解決。上述濺鑛現象與陰極電M降低之消除係 光放電燈管之重要研究課題,但即便閱讀已出版之專門: 刊,该等現象產生之科學根據仍不明確,始終停留於對^ 測現象之說明。因無法理解產 ' 签“ 鮮座生原因’故為未解決課題。 放電燈官之技術在基礎方面之開發未完成。本發明者 石^體放電時出現之陰極電料低與濺叙課題進行科學 [本發明者之闡述與思想] 面之=中!::習知放電燈管中SBE形成於金屬陰極表 7 ’、、、止之與氣體放電相關之出版物書籍中未 況月的疋,從金屬陰極發射 於金屬中之電洞(電子之孔、,广!發射電子後殘留 作用。,發揮考產生氣體放電之 “之固祕理所示之事實是,若將電子e自 曾取出至真空中’則金屬中必定殘留有電洞h。由於 蜀二¥電體’因此假定電洞由自電源供給之電子立刻填 ㈡此習知之思考存在錯誤。自電源供給至金屬電極30 之电子,受到金屬電阻之阻礙 到達金屬電極之電、、η ό t 疋律),而不會瞬時 …中㈣: 自電源供給電子與自金屬陰極% 發射γΓ 間存在時間差。加以統計處理時,於 料之電阻:::極金屬表面’電洞存在量雖因陰極金屬材 電洞Γ::;:變化,但會穩定存在有數量不容忽視之 *中果為,位於金屬表面層之電洞h與發射至真 工中之電子e藉由靜電力而強烈地相互吸引,真空中之電 14 200919527 子再度結合。 位於金屬表面層之電洞h之正電場涵蓋真空中。發射 至真空中之電+ e雖受到金屬表面層之電洞h之正電場的 吸引仁不具有再次進入金屬中之能量,從而於略微離開 金屬表面之位置(約5 μιη )之真空中與金屬電極中之電洞 h結合。此即為表面結合電子(sbe,surface_b〇und_ electrons)。螢光放電燈管中之金屬陰極表面被sbe覆蓋。 於”工¥研九之初期(1 900s )已檢測出,自真空侧觀察SBE 時,SBE表現為存在於陰極表面之空間電子雲。 根 最近出版之 Cathodoluminescence and Photoluminescence; Theories and Practical Applications, CRC Press,Taylor and Francis G,,Β_ Μ. L〇nd〇n,Negative Glow > Faraday dark ^ Positive Column ^ Anode Glow, and Anode Dark. Although the stripes are generally illustrated, the description is limited to the scope of the observations and does not clarify the scientific basis for the generation of luminescent stripes. These irregular luminescence are more pronounced at the cathode. The sudden change of the applied voltage around the cathode is collectively referred to as the reduction of the cathode voltage and the loss of the cathode voltage, and the energy of the overall lighting energy of the fluorescing electric tube is reduced. The elimination of the cathode voltage is developed. 13 200919527 Power saving An important issue in the glory discharge lamp, but the cause is unknown, so it is still solved by two methods. The above-mentioned phenomenon of splashing and reduction of cathode electric M is an important research topic of light-discharge lamps, but even if the published special editions are published, the scientific basis for such phenomena is still unclear, and it is always stuck in the phenomenon of measurement. Description. Due to the inability to understand the production of 'significant' reasons for fresh births, it is an unresolved issue. The development of the basic technology of the discharge lamp official has not been completed. The inventors of the present invention have a low cathode magnetism and a splashing problem. Science [The inventor's elaboration and thoughts] No. =::: SBE is formed in the discharge tube of the metal cathode 7', and the publications related to gas discharge are not in the state. From the metal cathode emitted into the hole in the metal (hole of electron, wide! Residual effect after emitting electrons. The fact that the function of generating gas discharge is shown is that if the electron e is taken out In the vacuum, there is a hole h in the metal. Because of the electric body, it is assumed that the hole is immediately filled by the electron supplied from the power supply. (2) There is an error in the conventional thinking. The electron supplied from the power source to the metal electrode 30 , the resistance to the metal electrode is hindered by the metal resistance, η ό t law), and not instantaneous... (4): There is a time difference between the power supply electron and the metal cathode % emission γ 。. When statistical processing is carried out, the resistance of the material::: the surface of the polar metal 'the existence of the hole is due to the change of the cathode metal hole Γ::;:, but there will be a steady number of *the fruit can not be ignored. The hole h of the surface layer and the electron e emitted to the real work are strongly attracted to each other by the electrostatic force, and the electricity in the vacuum 14 200919527 is again combined. The positive electric field of the hole h located in the metal surface layer covers the vacuum. The electric + e emitted into the vacuum is attracted by the positive electric field of the hole h of the metal surface layer, and does not have the energy to re-enter the metal, so that it is in a vacuum slightly away from the metal surface (about 5 μmη) and the metal The hole h in the electrode is combined. This is the surface bound electron (sbe, surface_b〇und_ electrons). The surface of the metal cathode in the fluorescent discharge tube is covered by sbe. At the beginning of the work (1 900s), SBE was observed as a space electron cloud present on the surface of the cathode when the SBE was observed from the vacuum side. The recently published Cathodoluminescence and Photoluminescence; Theories and Practical Applications, CRC Press , Taylor and Francis G,,Β_ Μ. L〇nd〇n,

NeWY〇rk,Pp30_37 與 69_76,2〇〇7(非專利文獻 〇 ,可由 陰極射線發光之螢光膜上照射至螢光膜之電子束能量與發 光強度之關係之測定’而推測形成於陰極表面《觀之負 電位。㈣之大小為1〇6eV/cm。為了自陰極表面取出電 ^必須向電子施加大於懸之負電位之正電位。以高能 置被取出之電子被加速至高速。教科書中所寫之放電現象 Μ 具有高能#之電子進入氣體空間時之現象,觀 測結果全部被超過必需之高速電子之行為遮蔽。 於氣體空間中,以不相互作用之距離(可忽略原子之 ^㈣之重^填充有中性原子之氣體。各氣體 ’、子中’填充有包圍原子核之多個電子殻之電子之她負電 荷、與原子核之陽電荷達到均衡,各氣體原子之電性為中 15 200919527 性。然而,氣體空間中原子之最外殼電子之負電場(5xl〇5 eV)持續擴展,故氣體空間充滿較強之負電場。具有氣體 空間之負電場(5X105 eV)以上之高能量(106 eV)並進 入氣體空間之電子,無法進入由填滿電子殻之電子所遮蔽 之氣體原子中,故重複與氣體原子進行多次非彈性碰撞, 亚將位於最外殻之電子發射至真空中。氣體原子之離子化 伴隨產生有熱’因此多個氣體原子隨著散熱而離子化。此 係螢光放電燈陰極周邊之温度上升之原因。離子化而成之 電子與離子之電荷量庫侖)相同,但質量上存 在較大差異。電子之質量為9_lxl〇-u克,而離子之質量雖 隨原子種類而略有變化,但均為1.7X 1 〇-24克左右,約為電 子貝里之1,〇〇〇倍。電子容易因施加至氣體之電場而遷移, 但離子之遷移稍慢且較少。在此雖未說明詳細理由,但電 子與離子之遷移距離之差便造成上述陰極近前之發光條 紋。 ’、 此處必須預先指出的錯誤是,於研究氣體放電之初期, 將氣體放電定義為來自不可見之氣體發射(discharge)光。 根據該理由,對氣體放電之研究係測定來自放電管之光之 強弱,亚根據其結果來闡述放電。僅測定光則難以科學地 闡明放電。如上所述,氣體之放電必須根據進入氣體介質 中之電子與氣體原子之相乘作用而決定之電子行為來分 析。若根據該新觀點來分析螢光放電燈管之特性,可知至 今為止無法解決之問題得以解決。當前之螢光放電燈管之 製造技術仍未完成。 16 200919527 螢光放電燈管之特性由裔 ”由虱體中之電子行為決定。決定 另—重要因於螢光放電燈管之習知之特性 檢討中被遺漏。即罃朵访φ其+ & 尸愛光放電官中塗佈於内壁面上之螢光膜 中之各螢光體粒子的物性。Μ僅考慮㈣錢將氣體發 出之不可見之υν光轉換為可見光之作用。根據本發明者 之研究’纟螢光體粒子之物性並非僅與發光現象相關。各 螢光體粒子係結晶化粒子’亦係具有非對稱結晶構造之結 晶,當置於放電管内時’表現出結晶之物i生,並對氣體放 電中之電子行為產生顯著影響。實用上之螢光體粒子具有 非對稱結晶構造之理由如下:佔據非對稱晶格點之發光中 心,允許於對稱晶格點之發光中心所不允許之電子遷移, 且允許之電子遷移概率異常高。此係市售之螢光體之發光 特性異常南之理由。然而,研究固態物理之大多數研究者 認為,螢光體粒子並非單晶,而是含有多個晶軸之多晶體, 且為含有多個結晶缺陷之結晶粒子。即,判斷為固態物理 之知識並不適用於含有多個結晶缺陷之結晶。該判斷並不 正確根據 Chemical Review’Volume 103,No. 1 〇,ρρ3835· 3855,2003上發表之論文(非專利文獻2),決定發光中心 之電子遷移之晶場之大小,係非常狹小之範圍(半徑為5〇〇 入)之晶場的完成度’與粒子整體之結晶性無關。此係即 便市售之螢光體粒子形狀不規則,螢光體粒子亦以相同效 率發光之理由。螢光體粒子為多晶體,多晶體之粒徑之優 化由塗佈條件而決定。 使用外部紫外線光源,於實驗室中調查實際存在之螢 17 200919527 光體時,市售螢光體中發光效率最高之勞光體 電子束發光叫榮光體。然而,即便於勞光放二:: 管壁上塗佈市售CL·螢光體,甘 電燈^之 耸九體’亦無法獲得明亮 燈管D因此’發亮光之營光放電燈管之勞光 : 根據經驗而找出之螢光體。根# A螢先體係 體才艮據經驗而得出之結果缺乏理 ^刀1因此’所選擇之A多數勞光體係藉由光直接 激發發光中心之螢光體(PL榮NeWY〇rk, Pp30_37 and 69_76, 2〇〇7 (non-patent document 〇, the measurement of the relationship between the electron beam energy and the luminescence intensity of the fluorescent film irradiated onto the fluorescent film by the cathode ray illuminating) is presumed to be formed on the surface of the cathode The negative potential of the view. (4) The size is 1〇6eV/cm. In order to take out the electricity from the surface of the cathode, a positive potential greater than the negative potential of the suspension must be applied to the electrons. The electrons taken out at high energy are accelerated to high speed. The discharge phenomenon written Μ has the phenomenon that the electrons of high energy # enter the gas space, and the observation results are all obscured by the behavior of the high-speed electrons exceeding the necessary. In the gas space, the distance of non-interaction (the negligible atom ^ (4) Refilling a gas with a neutral atom. Each gas ', sub-filled with electrons surrounding a plurality of electron shells of the nucleus, her negative charge, and the cation charge of the nucleus are balanced, and the electrical properties of each gas atom are medium 15 200919527 Sex. However, the negative electric field (5xl〇5 eV) of the outermost shell electron of the atom in the gas space continues to expand, so the gas space is filled with a strong negative electric field. The high energy (106 eV) above the negative electric field (5X105 eV) and the electrons entering the gas space cannot enter the gas atoms blocked by the electrons filled in the electron shell, so repeating multiple inelastic collisions with the gas atoms The electrons of the sub-shell are emitted into the vacuum. The ionization of the gas atoms is accompanied by the generation of heat. Therefore, a plurality of gas atoms are ionized with heat dissipation. This is the cause of the temperature rise around the cathode of the fluorescent discharge lamp. The ionized electrons are the same as the ion charge Coulomb, but there is a big difference in mass. The mass of the electron is 9_lxl〇-u gram, and the mass of the ion varies slightly with the atom type, but both are 1.7. X 1 〇-24 grams or so, about 1 times the electrons of Berry. Electrons are easily migrated by the electric field applied to the gas, but the migration of ions is slightly slower and less. Although detailed reasons are not explained here. However, the difference between the migration distance of electrons and ions causes the light-emitting streaks of the cathode nearby. ', The error that must be pointed out here is that, in the initial stage of studying the gas discharge, the gas discharge is defined as From the invisible gas, the light is discharged. For this reason, the study of gas discharge measures the intensity of light from the discharge tube, and the discharge is explained based on the result. It is difficult to scientifically clarify the discharge only by measuring the light. The discharge of the gas must be analyzed according to the electronic behavior determined by the multiplication of the electrons entering the gas medium and the gas atoms. If the characteristics of the fluorescent discharge lamp are analyzed according to this new viewpoint, it is known that the problem that has not been solved so far can be solved. The current manufacturing technology of fluorescent discharge lamps has not been completed. 16 200919527 The characteristics of fluorescent discharge lamps are determined by the electronic behavior of the body. The decision is made another important to the practice of fluorescent discharge lamps. The review of the characteristics of the knowledge was omitted. That is, the physical properties of each of the phosphor particles in the fluorescent film coated on the inner wall surface of the φ++amp; Μ Only consider (4) money to convert the invisible υν light emitted by the gas into visible light. According to the study of the present inventors, the physical properties of the phosphor particles are not only related to the phenomenon of luminescence. Each of the phosphor particle-based crystallized particles 'is also a crystal having an asymmetric crystal structure, and when placed in a discharge tube, exhibits a crystallized substance and has a significant influence on the electron behavior in gas discharge. Practically, the reason why the phosphor particles have an asymmetric crystal structure is as follows: occupying the luminescent center of the asymmetric lattice point, allowing electron migration which is not allowed in the luminescent center of the symmetrical lattice point, and allowing the electron migration probability to be abnormally high . This is the reason why the luminescent properties of commercially available phosphors are abnormally south. However, most researchers who study solid-state physics believe that phosphor particles are not single crystals, but polycrystals containing a plurality of crystal axes, and are crystal particles containing a plurality of crystal defects. Namely, the knowledge that solid state physics is judged is not applicable to crystals containing a plurality of crystal defects. This judgment is not correct according to the paper published in Chemical Review 'Volume 103, No. 1 〇, ρρ3835·3855, 2003 (Non-Patent Document 2), which determines the size of the crystal field of electron transfer in the luminescent center, which is a very narrow range. The completion degree of the crystal field (with a radius of 5 〇〇) is independent of the crystallinity of the particles as a whole. This is because the commercially available phosphor particles are irregular in shape and the phosphor particles are illuminated at the same efficiency. The phosphor particles are polycrystalline, and the optimization of the particle size of the polycrystal is determined by the coating conditions. Using an external ultraviolet light source to investigate the actual presence of fluorescent light in the laboratory. In the case of light bodies, the luminous efficiency of the commercially available phosphors is the highest. However, even if the light is placed on the wall:: the commercially available CL·fluorescent body is coated on the wall of the pipe, the light of the lamp is not able to obtain the bright lamp D, so the light discharge lamp of the camp Lao Guang: A fluorescent body that is found based on experience. Root #A Firefly System The result of the experience is lack of rationality. Therefore, the majority of the Aluminium light system selected by the light directly stimulates the phosphor of the illuminating center by light (PL Rong

公司笋行之”炉“帛先體)<列如即便查閱〇HM 體手冊亦未發現為何使用p 論解釋。 赏尤體之理 將市售PL榮光體塗佈於螢光放電燈管之内壁上 光放電燈中,以下問題仍夫醢、叔 屮夕1 θ 未解決。即便使用自金屬陰極取 之问月匕罝之電子,螢光放電燈管内之氣體亦不會容易地 放電。雖對螢光放電燈管之 吕 < 點冗益具進行改善以使1 地進行氣體放電,作仍去 /、 ^ % 1'仍未開發出瞬時放電之螢光放電燈。 出之以體中單向前進之電子之速度非常快,為2χ1〇5 ec。為何向陰極與陽極之-方向高速前進之電子未r 使榮光放電燈瞬時放電之科學分析完全欠缺,從而未= 寻The company's "boiler" 帛 precursor) < column, even if you look at the 〇 HM body manual, did not find out why the use of p theory. The beauty of the body is applied to the inner wall of the fluorescent discharge lamp. The following problems remain unresolved. Even if the electrons from the metal cathode are used, the gas in the fluorescent discharge tube will not be easily discharged. Although the fluorescent discharge lamp is improved to make the gas discharge in one place, the fluorescent discharge lamp that has not yet developed the instantaneous discharge has not been developed. The speed of electrons that come out in one direction is very fast, which is 2χ1〇5 ec. Why is the electron analysis of the high-speed advancement of the cathode and the anode in the direction of the cathode? The scientific analysis of the instantaneous discharge of the glare discharge lamp is completely lacking, so that ==

理論_。習知技術者與技師僅停留於經驗階段。X 产总=其他未解決之問題存在。增加放電後之螢光放電 ϋΐ人時’光輸出容易飽和。射人螢光膜粒子層之uv 尤因螢光體粒子之較高之# j 於辏丄 先折射率(n? 2),首先在排列 先膜最上部之勞光體粒子表面反射,…uv光亦 排列於螢光膜下部之螢光體粒子。螢光膜上參與發光 有效螢光體粒子數可根據實驗而求出。可以計算出有效 18 200919527 螢光體粒子數中包含之發光中心數。計算出之發光中心數 約為照射於螢光膜上之uv光之光子數的10倍。營光放電 燈管内螢光膜之發光中心之激發數並未飽和。亮度飽和係 指到達螢光膜上之UV之光強度。儘管如此,螢光放電燈 管之技術者們仍期待以提高螢光體之發光效率(2〜3% ) 來提高螢光膜之亮度。該思考並不正確。必須有應對照射 至螢光膜之uv光不飽和之對策,但仍未見定量論述uv 光飽和現象之論文。 根據本發明者之研究發現,發現放電管中之電子行為 大受排列於螢光膜之最上層之螢光體粒子之電特性影響‘。 控制放電管中之電子行為之另一重要因素,係選擇適當之 螢光體及適當排列螢光體粒子之螢光膜。為解決該等問題 必須用到習知述參考文獻i中揭示之榮光體之物性知識。 如上所述,螢光放電燈管可自基本構造進行改良。本 2明=螢光放電燈管係科學地解決習知無法解決之螢光放theory_. The skilled technicians and technicians only stay in the experience stage. X Total Production = Other unresolved issues exist. Increasing the fluorescence discharge after discharge. When the person is on, the light output is easily saturated. The higher the uv Ewing phosphor particles of the fluorescent film layer, the refractive index (n? 2), first reflected on the surface of the uppermost layer of the first film, ...uv The light is also arranged in the phosphor particles in the lower part of the fluorescent film. Participation in luminescence on the fluorescent film The number of effective phosphor particles can be determined experimentally. It can be calculated that the number of illuminating centers included in the number of phosphor particles is 18 200919527. The calculated number of illuminating centers is about 10 times the number of photons of uv light irradiated on the fluorescent film. Camp Light Discharge The number of excitations in the luminescent center of the fluorescent film inside the lamp is not saturated. Brightness saturation refers to the intensity of the UV light that reaches the fluorescent film. Despite this, the technicians of fluorescent discharge lamps are still looking to increase the brightness of the fluorescent film by increasing the luminous efficiency of the phosphor (2 to 3%). This thinking is not correct. There must be countermeasures against the uv light unsaturation that is irradiated to the fluorescent film, but there is still no paper that quantitatively discusses the UV light saturation phenomenon. According to the findings of the present inventors, it has been found that the electronic behavior in the discharge tube is greatly affected by the electrical characteristics of the phosphor particles arranged in the uppermost layer of the phosphor film. Another important factor in controlling the electronic behavior of the discharge tube is the selection of a suitable phosphor and a phosphor film that suitably aligns the phosphor particles. In order to solve these problems, the knowledge of the physical properties of the glory body disclosed in the reference i can be used. As described above, the fluorescent discharge lamp can be modified from the basic configuration. Ben 2 Ming = Fluorescent Discharge Lamp System Scientifically solves the problem that the fluorescent light can not be solved

$燈管之所有問題者。其結果為,可顯著提高螢光放電燈 官之亮度’並減少房間之適當照明所必需之螢光放電燈管 T。而且螢光放電燈管之點亮時間能夠以可增加其位數之 水準延長,因此f光放電燈管之生產單價低於其他任―听 =源。因可簡化瑩光放電燈管之構造,故製造步驟縮短了 改良’本發明之螢光放電燈可大大有助於省電, ^少社會所強烈要求之%氣體之排放’對環境保護 ^獻料亦大1於料利讀3〜料散獻6 人進行敍述。 、; 19 200919527 非專利文獻 1: Cathodoluminescence and Photoluminescence; Theories and Practical Applications, CRC Press, Taylor and Francis Group, Boca Raton, London, New York, pp 30-37 and 69-76, 2007 非專利文獻 2: Chemical Review Volume 103, No. 10, pp 3835-3855, 2003 非專利文獻 3 : Cathodoluminescence, Kodansha, 1990,p 104-120 非專利文獻 4 : Applied Physics Letters, 43,pp 1073-4, 1983 非專利文獻 5 : Physical Review Letters, Vol. 27,1 9715 P1345 非專利文獻 6 : Journal Physics D Applied Physics, 32 (1999 ) , pp 5 13-517 【實施方式】 [發明所欲解決之問題] 々如上所述,習知之螢光放電燈管累積有如下眾多問題。 第1問題係陰極周邊之急遽之陰極電壓降低,其能量損失 達到螢光放電燈管之所有點亮能量之4〇%左右。第2問題 係述陰極電壓降低,於電極附近產生發光與不發光之 條紋狀圖案而—giL,& &道 存放“#, 導整體照明度降低。第3問題 :、孔豆之陽離子與陰極碰撞而使金屬陰極蒸發,於螢 光膜上形成蒸發膜並 、 .光放雷柊其一 孔體,成為導致放電壽命及 Μ放電燈f之壽命縮短 電燈管之昭^ + ¥ 4 ^係母根螢光放 …、月度大大低於要求之照明度,實用時必須排列 20 200919527 多個螢光放電管,難以節能,且$ All problems with the lamp. As a result, the fluorescent discharge lamp T necessary for the brightness of the fluorescent discharge lamp can be remarkably improved and the proper illumination of the room can be reduced. Moreover, the lighting time of the fluorescent discharge lamp can be extended by the level at which the number of bits can be increased, so that the production unit price of the f-discharge lamp tube is lower than that of other sources. Since the structure of the fluorescent discharge lamp can be simplified, the manufacturing steps are shortened. The 'fluorescent discharge lamp of the present invention can greatly contribute to power saving, and less than the gas emissions strongly demanded by the society' It is also reported that the material is large and is read by 3 people. 19 200919527 Non-Patent Document 1: Cathodoluminescence and Photoluminescence; Theories and Practical Applications, CRC Press, Taylor and Francis Group, Boca Raton, London, New York, pp 30-37 and 69-76, 2007 Non-Patent Document 2: Chemical Review Volume 103, No. 10, pp 3835-3855, 2003 Non-Patent Document 3: Cathodoluminescence, Kodansha, 1990, p 104-120 Non-Patent Document 4: Applied Physics Letters, 43, pp 1073-4, 1983 Non-Patent Document 5 : Physical Review Letters, Vol. 27,1 9715 P1345 Non-Patent Document 6: Journal Physics D Applied Physics, 32 (1999), pp 5 13-517 [Embodiment] [Problems to be Solved by the Invention] As described above, The conventional fluorescent discharge lamp has accumulated many problems as follows. The first problem is that the cathode voltage around the cathode is lowered, and the energy loss is about 4% of the total lighting energy of the fluorescent discharge lamp. The second problem is that the cathode voltage is lowered, and a stripe pattern of light emission and non-light emission is generated in the vicinity of the electrode - giL, &&&&&&&&&&&&&&&&&&&&&&& The cathode collides to evaporate the metal cathode, form an evaporation film on the fluorescent film, and the light discharges a hole in the body, which causes the discharge life and the life of the xenon discharge lamp f to shorten the electric lamp tube. The mother is fluorescent, and the monthly illumination is much lower than the required illumination. In practice, it is necessary to arrange 20 200919527 multiple fluorescent discharge tubes, which is difficult to save energy, and

pa eg ,Λ _ ^ R俘在限制。笛S 問通係接通電源後,開始放電直至點亮為」弟5 成為快速點亮之阻礙。 而很長%間, 匕本奂明之目的在於,從基礎上重 電燈管之動作ffi理 仏讨登光放 料原理,4除陰極電壓降低並 時消除電極附近之日H5郎月b ’同 电枉附近之明暗條紋狀圖案,從 本發明之進一步目的卢认sg q',、、明度。又, - 的在於,提供一種金屬陰極盔j。知 著提高單根螢光於φ欣Μ …、貝耗、顯 放電燈管,又蔣也 、速點冗之螢光 … “、—種具有利用著該螢光放電燈管之背井 源叙置之LCD顯示裝置(液晶顯示裳置)。 月先 [解決問題之手段] 本發明係為解μ、+,π 形態係-種螢= 製而成者’本發明之第】 螢先放電燈管,於螢光放電 塗佈有螢光膜,兮技, 电/且芝玻璃官内壁面 , 、 °χ螢光放電燈管之特徵在於,上述玻璃其Pa eg , Λ _ ^ R captured in the limit. After the flute S is connected to the power supply, it starts to discharge until it is lit. "Different 5 becomes a hindrance to rapid lighting. And for a long time, the purpose of 匕本奂明 is that, based on the action of the heavy-duty lamp on the basis of ffi, the principle of light-receiving is discussed. 4After the cathode voltage is lowered, the day near the electrode is eliminated. The light-dark stripe pattern near the electric enamel recognizes sg q', and brightness from the further object of the present invention. Also, - a metal cathode helmet j is provided. Knowing to improve the single fluorescent light in φ Xin Μ ..., shell consumption, discharge discharge lamp, and Jiang also, speed point redundant fluorescence ... ", - the species with the use of the fluorescent discharge tube back source The LCD display device (liquid crystal display device). The first step [the means to solve the problem] The present invention is to solve the μ, +, π form system - the type of firefly = the maker of the 'the invention' The tube is coated with a fluorescent film on a fluorescent discharge, a 兮 technology, an electric/and a glass inner wall surface, and a fluorescent discharge lamp is characterized in that the glass is

内之放電氣體之點亮係藉 玻璃S 盥遠接φ、β , 雅坩电于之抓動獨立之内部電路、 〃連接電源之外部電路而產生。 邻電之第2形態係一種螢光放電燈管,其中上述内 Ζ路係由分別個別地形成於上述 之電子源與離子源椹士、, 电版g円邛兩編 係於自上ii·〜 勞光放電燈管内之氣體放電 =:述電子源取出之電子於氣體空間中朝 你遷移之過程中吝 -^m-r 時,上述電子_ ’ h遷移之上述電子到達離子源 九、離子再結合並封閉上述内部電路。 本發明之第3 Μ 榮光放電燈管内之:;係二勞光放電燈管’其中於上述 、 知配置層狀覆蓋有電絕緣體粒子 21 200919527 金屬電極’並將該金屬電極 極;於上述螢光放電燈管内之另一…:::形成用電 緣體粒子之全屬雷η 層狀覆蓋有電絕 成用電極。 胃电独作為上逑離子源形 本·月之第4形態係一種螢光放電燈 源形成用電極之上述金屬Π上逑電子 金屬電極…極性之電位,使上述 、 。電、、、邑緣體粒子介電極化,_由+ > 離子化而產生之自由電子受到介電極:f邊之氣體 粒子之正電荷的吸5丨化叙上述電絕緣體 折今+々μ 電子於上述電絕緣體粒子 二間中與上述電絕緣體粒子内之正電荷結合而 开^成工間電子雲,將此空間電子雲作為上述電子源;向上 述離子源形成用電極之上述 ’、° n屬電極施加負極性之電位, 使亡述金屬電極之電絕緣體粒子介電極化’藉由電極周邊 =體離子化而產生之離子受到介電極化後之上述電絕緣 肢粒子之負電荷之吸引,上述離子與上述電絕緣體粒子之 壶化負電荷結合而形成離子群,將此離子群作為 源。 < 雕丁 本發明之第5形態係一種螢光放電燈管,將電子自上 述電子源取出至螢光膜表面上,#由螢光膜之表面傳導而 :電子加速’加速電子係作為氣體放電之始動誘因,藉由 f負電荷之螢光體粒子而使上述加速電子之執道彎向氣體 空間,從而使螢光放電燈管之氣體瞬時點亮放電,藉此產 生無陰極電壓降低之氣體放電。 曰 於上述螢光 本电明之第6形態係一種螢光放電燈管 22 200919527 膜之表面交替配置不帶負電荷之螢光體粒子與帶負電荷之 f光體=子’且於上述螢光膜表面之多個部位,藉由上述 咿負電何之螢光體粒子而使上述加速電子彎向氣體空間 側。 本發明之第7形態係一種螢光放電燈管,其中塗佈於 上述勞光放電燈官之玻璃管内壁面之上述營光膜,係由電 子束發光螢光體粉與光致發光榮光體粉之混合粉體構成。 本么明之第8形態係一種螢光放電燈管,其中上述光 致發光螢光體粉係由單獨地發出三色光之三種稀土類光致 《光螢光體私所構成,且上述電子束發光螢光體粉係由低 電壓電子束發光螢光體粉所構成。 本卷明之第9形態係一種螢光放電燈管,其中上述稀 土類光致發光螢光體粉内’發出綠色光之螢光體粉由π 發光碎酸辞螢光體粉所取代。 :本發明之第1 〇形態係一種螢光放電燈管,其中上述稀 土類光致發光螢光體粉内,發出綠色光之發光體粉由cl 电光石夕酸鋅螢光體粉肖pL纟光石夕酸鋅登光體粉之混合粉 體所取代。 本电明之第1 1形態係一種螢光放電燈管,其中於上述 螢光膜,將上述低電壓電子束發光螢光體之粒子配置為於 上述螢光膜之表面上不連續分布。 本發明之第12形態係一種螢光放電燈管,其中上述螢 光膜係由單獨發出白色光之光致發光螢光體粉與低電壓電 子束發光螢光體粉之混合粉體所構成。 23 200919527 本發明之第13形態係一種螢光放 光膜中,發出白色丼之卜冲丄 八甲上述螢 勞光體所構成。 迷光致發光勞光體係由鹵磷_ ⑪光:之第14形態係—種螢光放電燈管,其中於上述 勞光體。 有曰強發紅色先之電子束發光氧化紀 本發明之第15形態係一種LCD顯示裝置,其特徵在 於平面上排列單個或多個第1形態〜f 14形態中之 任一螢光放電燈管來作為LCD顯示裝置之背光。 本發明之第16形態係一種LCD顯示裝置於垂直方 :或者水平方向上配置多個上述發光放電燈管,各榮光放 =管單獨地、或者以多個榮光放電燈管作為群,以線序 掃4田之方式依序點免,並將線序之影像映出於 置之整個屏幕上。 产 [發明之效果] J艮據本發明之第1形態可提供-種螢光放電燈管,玻 离s内之放電氣體之點亮係藉由電子之流動獨立之内部電 路、與連接於電源之外部電路而產生,產生放電之電子之 供給源係放電氣體自身之離子化,從而不自外部電路供給 放電用之電子。因此,整個放電過程中,放電燈管内部之 ,電氣體與外部電路隔斷,放電氣體自身連續反覆地進行 離子化與再結合,因此不會消耗放電氣體,而實現放電燈 官之長壽命化。而且,因不自外部電源供給電子,故並不 存在陰極電壓降低,從而可減小外部電源之耗電,商用電 24 200919527 源無須多言,即便係蓄 妨叮〜, 畜電池電源’蓄電池之消耗亦較小, 故可貫現放電燈管及其 瓊電路之長哥命化。換言之,本 ^明可提供一種劃時代 η之放電燈官,即便於因無商 而必須使用蓄電池電’π用電源 ,'、 稀夕、地區、山區等,亦可葬 由畜電池驅動而使用放雷$ # 曰 -齡… 官。而且,因不存在上述陰極 .寸近之明暗條紋狀圖案消失,電極附近 亦整體明亮地發光,從而可提高照明度。 ^ 根據本發明之第 述内部電路係由藉由放電 礼收之離子化而生忐夕+ 2、e & ~ 路於電子上與上述Hr 源所構成,該内部電 ^ " °卩電路π全隔斷,並於電子自上述電 千源向上述離子调夕„ 象係相同遷移電子、重= 生放電現象。該放電現 重複共氣體原子進行非彈性碰撞,藉由 紫外線而使f光膜持續發光,且上述電子 閉上述:部電路。本發明提供-種藉由上述放電 钹而使更光膜穩定地持續發光之螢光放電燈管。 述’電子與氣體原子持續之非彈性碰撞以及再結合 …電軋體内產生,外部電路被完全隔斷,因此幾乎不 =物之能量損耗。而且,本發明提供一種營光放 並不自外部電路向内部電路供給電子,因此並無 去包壓降低,從而可大幅減少外部電源之 可低電流驅動。 電源之驅動電流,且 根據本發 之金屬電極而 成用電極,因 月之第3形態,藉由層狀覆蓋電絕緣體粒子 構成上述電子源形成用電極及上述離子源形 此可糟由電絕緣體粒子層而隔斷自金屬電極 25 200919527 射及金屬蒸發,且上述内部電路與上述外部電路 元全分離。由於自上述金屬電極之電子發射及金屬基= :因此不存在金屬電極之消耗’從而導 ⑽現象消失,故可實現榮光放電燈管之長壽命化=之 極發射電子,但流過外部電路之外部電流僅 電極上之絕緣體粒子之介電極化之誘發電 ° 、現螢光放電燈管之低電流驅動,j:处果為, 可實現節能效果。 ㉟一果為, 根據本發明之第4形態’藉由外部電源而向上述電子 ’’、形成用電極之上述金屬電極施加正電位,並 位而使電絕緣體層介雷朽外# χ主电 “啄體層,丨電極化,精由極化電荷之極化電場, 來吸引猎由放電氣體$雜三 隹於… 離子化而生成之電子,從而形成聚 rt 屬電極周邊之空間電子雲來作為電子源。構成 二亥"子源之電子全部為放電氣體之離子化所產生之電子, 完全不自外部電路供給電子’因此並無内部電路之電壓降 低,從而可顯著降低外部電路之耗電。同樣,向位於放電 燈管内部之另-端之上述離子源形成用電極之金屬電極施 加負電位’藉由該負電位而使電絕緣體層介電極化,並藉 由極化,荷之極化電場,來吸引藉由放電氣體之離子化而 、陽離子 <而形成聚集於上述金屬電極周邊之陽離 子群=作為離子源。該離子源藉由電絕緣體層而與負金屬 电極凡全絕緣。上述電子源之電子一面進行氣體放電一面 向該離子源遷移’並藉由電子與離子之再結合而變回中性 乳體。镥由該微過程之連續動作,榮光體會藉由因放電產 26 200919527 生之紫外線而發出可見光,故可 放雷@^ ^ 實見低電流驅動之節能型 放…。由於不自外部電路向 並無陰極電廢降低,故供、-電子’因此 可實現放電燈管之使用成二;知耗之放電燈管’且 ^ 吏用成本之超低化以及超長壽命化。 圭·上述絕緣體粒子層$丨 m m '形成於與電極間形成之放電 工間連接之對向面(表面)上, 6J J此止金屬蒸發’隔斷 自外#電路之電子供給。為增 強°亥隔畊性,上述絕緣體粒 子層可形成於金屬電極之整個表 、耵同面、背面以及側 ’亦可形成於對向面與側面、或對向面與背面上。 此處,所謂背面係指與外部電路之接合面。 根據本發明之第5形態可實現一種螢光放電燈管,藉 由螢光膜表面之表面傳導將自上述電子源取出之電子加速 而將氣體放電始動,並藉由螢光膜上帶負電荷之螢光體粒 子而使上述加速電子之軌道彎向氣體空間,從而將螢光放 =燈管之氣體瞬時點亮放電。藉此,可提供—種並無陰極 電壓降低’可提高發光強度(照明度),且可低電流驅動 之節能型螢光放電燈管。通常,帶負電荷之螢光體粒子中 包含光致發光螢光體(PL榮光體)。光致發光螢光體之粒 子内部存在之雜質會捕獲電子,因該被捕獲之電子而形成 永久内部極化(PIP,persistent internal p〇laHzati〇W ,永 久内部極化之電子出現於螢光膜表面而構成上述負電荷, 發揮使上述加速電子彎向放電空間之作用。因此,若於期 望加速電子彎曲之位置預先配置光致發光螢光體,該位置 上之光致發光螢光體之負電荷會發揮對上述加速電子之彎 27 200919527 曲作用。可藉由選擇螢光體而調整上述負電荷之大小’藉 此使螢光膜上之表面傳導電子與放電氣體之碰撞加速,而 實現放電空間内之快速點亮,消除螢光放電燈管中習知即 存在之延遲點亮。 據本1明之第6形態’可提供—種高效率之 電燈管,於上述勞光膜之表面交替配置不帶負電荷 ΓΓ子與帶負電荷之鸯光體粒子,且於上述螢光膜表面之 =位,藉由上述帶負電荷之榮光體粒子而使上述加速 2 ^向虱體空間側,從而實現快速點亮及整個表面發 不帶負電荷之勞光體粒子中通常包含電子束發光 體(CL螢光體)。尤其係低電麼電子束發光螢光體且 有表面污染較少、不帶6 、 俨极# 页負電何之性質,因而具有不充電之 九.. 子束發先螢光體則會出現表面污 木’亦存在向負電荷充雷少,降 之缺本驷r i 之清形。本形態中,不帶負電荷 之赏光體區域中不產峰庙入心丄 傳莫夕Φ 產生庫网斥力,因此可使螢光膜上表面 得導之電子加速。 嫌 ^ w ._ 面,市*負電荷之螢光體區域中, 加速電子藉由庫侖斥力而彎 強制放電,放電燈管會快速點!電广…吏放電氣體 負〇〜 既迷點冗。而且’本形態中,多個 之=區域分布於電子之表面傳導方向,因此於放電燈管 換令…… 故放電燈皆之整體可明亮地發光。 之前:夕個上述負電荷性螢光體粒子沿著加速電子 之剛進方向分布於螢光膜上逯電子 之庫侖斥力,而可於多個負_2由加速電子與負電荷 放電空間中,並藉由力ή 置強制使加速電子彎向 藉由加速電子與放電氣體在多區域之整個 28 200919527 f間碰撞’而於放電空間之整個區域中產生放電,從而可 實現能夠同時達成快速點亮盘整 一 i髖工間點亮之放電燈管。The discharge of the discharge gas is generated by the glass S 盥 being connected to φ, β, and the external circuit of the 电源 坩 抓 独立 独立 独立 独立 独立 独立 独立 独立 独立 独立 独立 独立 独立 。 。 。 。 。 。 The second aspect of the adjacent electric power is a fluorescent discharge lamp, wherein the inner crucible is separately formed on the electron source and the ion source gentleman, and the electrotype g円邛 is compiled from the above. ~ Gas discharge in the lamp discharge lamp =: When the electrons taken out by the electron source move toward you in the gas space 吝-^mr, the electrons of the above electron _ 'h migrate to the ion source IX, the ion again Combine and close the above internal circuits. In the third aspect of the present invention, in the glory discharge lamp tube, the system is covered with an electrical insulator particle 21 200919527 metal electrode and the metal electrode electrode; The other ...::: in the light discharge lamp tube is formed by the electric horn particles, which are covered with a layer of electric ray. Gastric electricity alone as the upper sputum ion source form The fourth form of this month is a kind of electric potential of the above-mentioned metal Π upper 逑 electronic metal electrode of the fluorescent discharge lamp source forming electrode, and the above-mentioned. Electrode, and 邑 体 体 粒子 粒子 , , _ _ _ _ 由 由 _ 由 + + 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由Electrons are combined with positive charges in the electrical insulator particles in the two electrical insulator particles to form an inter-work electron cloud, and the space electron cloud is used as the electron source; and the above-mentioned ion source forming electrode The n-electrode applies a potential of a negative polarity, and the electrical insulator particles of the metal electrode are memorized. The attraction of the negative electric charge of the electrically insulating limb particles after the ionization of the ions generated by the ionization of the electrode periphery is subjected to the dielectric polarization. The ions are combined with the potting negative charges of the electrical insulator particles to form an ion group, and the ion group is used as a source. < Engraving The fifth aspect of the present invention is a fluorescent discharge lamp in which electrons are taken out from the electron source to the surface of the fluorescent film, # is conducted by the surface of the fluorescent film: electron acceleration 'accelerates the electron system as a gas Initiating the cause of the discharge, the accelerating electrons are bent into the gas space by the negatively charged phosphor particles, so that the gas of the fluorescent discharge lamp is instantaneously lit and discharged, thereby generating no cathode voltage reduction. Gas discharge. The sixth form of the above-mentioned fluorescent light-emitting device is a fluorescent discharge lamp 22 200919527. The surface of the film is alternately arranged with negatively charged phosphor particles and negatively charged phosphors = sub' and the above-mentioned fluorescent light At a plurality of locations on the surface of the film, the accelerated electrons are bent toward the gas space side by the negatively charged phosphor particles. According to a seventh aspect of the invention, there is provided a fluorescent discharge lamp, wherein the camping film coated on an inner wall surface of the glass tube of the glare discharge lamp is an electron beam luminescent phosphor powder and a photo luminescent phosphor powder. The mixed powder is composed. The eighth aspect of the present invention is a fluorescent discharge lamp, wherein the photoluminescence phosphor powder is composed of three kinds of rare earth light-emitting "light phosphors" which emit three-color light separately, and the electron beam illumination The phosphor powder is composed of a low voltage electron beam luminescent phosphor powder. The ninth aspect of the present invention is a fluorescent discharge lamp in which the phosphor powder which emits green light in the rare earth-based photoluminescent phosphor powder is replaced by π-light-emitting acid phosphor powder. The first aspect of the present invention is a fluorescent discharge lamp, wherein the above-mentioned rare earth photoluminescence phosphor powder emits green light illuminant powder by cl electro-optic zinc silicate phosphor powder Xiao pL纟Replaced with the mixed powder of glacial acid zinc powder. The first aspect of the invention is a fluorescent discharge lamp, wherein the particles of the low-voltage electron beam illuminating phosphor are arranged to be discontinuously distributed on a surface of the fluorescent film in the fluorescent film. A twelfth aspect of the invention is directed to a fluorescent discharge lamp, wherein the fluorescent film is composed of a mixed powder of a photoluminescent phosphor powder and a low-voltage electron beam emitting phosphor powder which emit white light alone. 23 200919527 A thirteenth aspect of the present invention is a fluorescent light-emitting film which is formed by emitting a white enamel. The photoluminescence system consists of a phosphorous _ 11 light: the 14th form of a fluorescent discharge lamp, which is in the above-mentioned working body. The fifteenth aspect of the present invention is an LCD display device characterized in that one or a plurality of fluorescent discharge lamps of the first form to the f14 form are arranged in a plane. Comes back to the backlight of the LCD display device. According to a sixteenth aspect of the present invention, in a liquid crystal display device, a plurality of the light-emitting discharge lamps are disposed in a vertical direction or in a horizontal direction, and each of the glare discharge tubes is individually or a plurality of glare discharge lamps are used as a group in a line sequence. The method of sweeping the 4 fields is sequentially ordered, and the image of the line sequence is reflected on the entire screen. [Effect of the Invention] According to the first aspect of the present invention, a fluorescent discharge lamp can be provided, and the discharge of the discharge gas in the glass s is an internal circuit independent of the flow of electrons, and is connected to the power source. The external circuit generates, and the source of the generated electrons is ionized by the discharge gas itself, so that the electrons for discharge are not supplied from the external circuit. Therefore, during the entire discharge process, the electric gas is separated from the external circuit by the electric discharge gas, and the discharge gas itself is continuously ionized and recombined, so that the discharge gas is not consumed, and the life of the discharge lamp is long. Moreover, since the electrons are not supplied from the external power source, there is no cathode voltage drop, so that the power consumption of the external power source can be reduced, and the commercial power supply 24 200919527 source need not be said, even if it is detrimental ~, the battery power supply 'battery battery The consumption is also small, so the discharge lamp and its long circuit can be realized. In other words, the present invention can provide a discharge lamp official of the epoch η, even if it is necessary to use the battery electric 'π power supply, ', the rare night, the region, the mountain area, etc. due to no business, can also be buried by the animal battery and used Ray $ # 曰-age... Official. Further, since the above-mentioned cathode does not exist, the pattern of the light and dark stripes disappears, and the vicinity of the electrode is also brightly illuminated as a whole, thereby improving the illumination. ^ The internal circuit according to the present invention is formed by ionization of a discharge eclipse, and the electronic circuit is formed by the above-mentioned Hr source, and the internal electric circuit is formed by the above-mentioned Hr source. π is completely blocked, and the electrons are transferred from the above-mentioned electric source to the above-mentioned ions, and the same electrons are transferred, and the heavy discharge phenomenon occurs. The discharge repeats the incoherent collision of the common gas atoms, and the optical film is made by ultraviolet rays. Continuously emitting light, and the above-mentioned electrons are closed to the above-mentioned circuit. The present invention provides a fluorescent discharge lamp in which a smoother film continuously emits light by the above-mentioned discharge enthalpy. In combination with the electric rolling body, the external circuit is completely blocked, so that there is almost no energy loss of the object. Moreover, the present invention provides a camping light that does not supply electrons from an external circuit to an internal circuit, and thus is not decompressed. Lowering, which can greatly reduce the low current drive of the external power supply. The driving current of the power supply, and the electrode for forming the metal electrode according to the present invention, by the third form of the month, by layer covering The insulator particles constitute the electrode for forming an electron source and the ion source may be separated from the metal electrode 25 by the electrical insulator particle layer and the metal evaporation, and the internal circuit is completely separated from the external circuit element. The electron emission of the electrode and the metal base = : Therefore, there is no consumption of the metal electrode, and the conduction (10) phenomenon disappears, so that the long life of the glory discharge lamp can be realized = the electron emission of the electrode, but the external current flowing through the external circuit is only the electrode The induction current of the dielectric particles on the insulator particles and the low current drive of the current fluorescent discharge lamp, j: the result is that energy saving effect can be achieved. 35. According to the fourth aspect of the present invention, The external power source applies a positive potential to the metal electrode of the electron '', the electrode for formation, and the bit is placed to make the electrical insulator layer dissipate the external χ main 啄 "啄 layer, 丨 electrode, fine by the polarization charge The electric field is used to attract the electrons generated by the ionization of the discharge gas, thereby forming a space electron cloud around the poly rt electrode. As the electron source. The electrons constituting the Erhai "subsource are all electrons generated by the ionization of the discharge gas, and the electrons are not supplied from the external circuit at all. Therefore, there is no voltage drop of the internal circuit, so that the power consumption of the external circuit can be remarkably reduced. Similarly, a negative potential is applied to the metal electrode of the ion source forming electrode at the other end inside the discharge lamp tube. The electric insulator layer is dielectrically polarized by the negative potential, and the polarization is polarized by polarization. The electric field attracts the cations by ionization of the discharge gas to form a group of cations clustered around the periphery of the metal electrode as an ion source. The ion source is completely insulated from the negative metal electrode by an electrical insulator layer. The electrons of the electron source migrate toward the ion source while performing gas discharge, and return to the neutral emulsion by recombination of electrons and ions.镥 From the continuous action of the micro-process, the glory experience emits visible light by the ultraviolet rays generated by the discharge, so it can be used to release the low-current drive energy-saving type. Since there is no reduction from the external circuit to the cathode, the supply and the 'electron' can realize the use of the discharge lamp; the discharge lamp of the know-how is ultra-low cost and long life. Chemical. The above-mentioned insulator particle layer $丨 m m ' is formed on the opposite surface (surface) of the discharge junction formed between the electrodes, and the metal is evaporated to block the electron supply from the external circuit. In order to enhance the intertwining property, the insulator particle layer may be formed on the entire surface, the same surface, the back surface, and the side of the metal electrode, and may be formed on the opposite surface and the side surface, or on the opposite surface and the back surface. Here, the back surface refers to a joint surface with an external circuit. According to the fifth aspect of the present invention, a fluorescent discharge lamp tube can be realized, which accelerates a gas by accelerating electrons taken out from the electron source by surface conduction of a surface of the phosphor film, and is negatively charged by the fluorescent film. The phosphor particles bend the orbit of the accelerating electrons into the gas space, thereby instantaneously lighting and discharging the gas of the fluorescent lamp=lamp. Thereby, it is possible to provide an energy-saving fluorescent discharge lamp which does not have a cathode voltage drop, which can increase the luminous intensity (illuminance) and can be driven at a low current. Usually, a photoluminescence phosphor (PL glaze) is contained in the negatively charged phosphor particles. Impurities present in the particles of the photoluminescence phosphor capture electrons, resulting in permanent internal polarization due to the trapped electrons (PIP, persistent internal p〇laHzati〇W, permanent internal polarization electrons appearing in the fluorescent film The negative charge is formed on the surface, and the accelerated electron is bent into the discharge space. Therefore, if the photoluminescence phosphor is disposed in advance at a position where acceleration of the electron is desired, the photoluminescence phosphor at the position is negative. The charge acts on the above-mentioned accelerated electron bend 27 200919527. The size of the negative charge can be adjusted by selecting the phosphor, thereby accelerating the collision between the surface conduction electrons on the phosphor film and the discharge gas, thereby achieving discharge. The rapid illumination in the space eliminates the delay in the conventional occurrence of the fluorescent discharge lamp. According to the sixth form of the present invention, a high-efficiency electric lamp can be provided, which alternates on the surface of the above-mentioned working film. Configuring a negatively charged scorpion and a negatively charged illuminant particle, and at the position of the surface of the fluorescent film, the above-mentioned negatively charged honor particles Acceleration 2 ^ to the side of the corpus callosum, so that the light-emitting body particles that are quickly lit and the entire surface is not negatively charged usually contain an electron beam illuminator (CL phosphor). Especially low-power electron beam illuminating Light body with less surface contamination, no 6 , 俨 pole # page negative electricity what nature, and therefore has no charge nine.. The sub-beam first fluorescent body will appear surface stained wood 'also exists to charge negative charge Lei Shao, the lack of the shape of the 驷 ri. In this form, the area of the light-extracting body without negative charge is not produced in the peak temple, and the Moxi Φ produces a repulsion of the net, so the upper surface of the fluorescent film can be made. The electronic acceleration of the guide. In the phosphor area of the negative charge of the city, the accelerating electrons are forced to discharge by the Coulomb repulsion, and the discharge lamp will be fast! The electric discharge is wide... The discharge gas is negative. ~ It is both fascinating and cumbersome. In this case, a plurality of areas are distributed in the surface conduction direction of the electrons, so the discharge lamp is replaced by a discharge lamp. Therefore, the entire discharge lamp can be brightly illuminated. Negatively charged phosphor particles along accelerated electrons The Coulomb repulsion of the electrons distributed on the fluorescent film, and the negative electrons in the negative electrons and the negative charge discharge space, and forced to bend the accelerated electrons by accelerating electrons and discharges The gas collides in the entire region of the multi-region, and the discharge is generated in the entire region of the discharge space, so that the discharge lamp capable of simultaneously illuminating the plate and the i-hip is illuminated at the same time.

:據本發明之第7形態可提供—種螢光放電燈I 中塗佈於上述營光放電燈管之玻璃管内壁面: 膜,係由電子束發光勞光體粉與光致發光勞光體粉之混人 粉體所構成。如上所述,電子束發光螢光體粉不帶負電荷: 且光致發光營光體粉帶負電荷,因此若預先混合兩種營光 :粉並塗佈於放電燈管内,則負電荷區域與中性區域以粉 體之直控大小交替配置,且無數個表面傳導電子之加速區 域與彎曲區域交替配置。因此’可提供—種在放電燈管之 :體區域產生放電發光,瞬時實現快速點亮與整個表面點 儿且以低電力實現高照明度之放電燈管。 根據本發明之第8形態可提供一種榮光放電燈管,其 中上述光致發光螢光體粉係由單獨地發出三色光之三種稀 土類光致發光螢光體粉所構成,且上述電子束發光螢光體 粉係由低電壓電子束發光螢光體粉所構成。若選擇紅光、 彔光及藍光作為二色,則合成色為白色,故可提供白色 螢光放電燈管。且,三種稀土類光致發光螢光體粉係負電 荷螢光體,低電壓電子束發光螢光體粉係不帶負電荷之螢 光體’故可實現快速點亮與整個表面點亮。 根據本發明之第9形態可提供一種螢光放電燈管,其 中上述稀土類光致發光螢光體粉内,發出綠色光之光致發 光榮光體粉由CL發光矽酸鋅螢光體粉取代。當第8形態 中之綠光之光致發光螢光體粉由電子束發光(CL發光)之 29 200919527 矽SiL鋅螢光體粉取代時,因不含有作為稀有元素之稀土 類’因此材料變得廉價’且發光明亮美麗。 根據本發明之第1〇形態可提供一種螢光放電燈管,其 中^述稀土類光致發光榮光體粉内,發出綠色光之光致發 光螢光體粉由CL發切酸鋅#光體粉與pL發切酸辞營 先體粉之混合粉體取代。因不含有作為稀有元素之稀土類 故:物寻廉價,且藉由調整^發光妙酸辞勞光體粉與 PU切酸鋅螢光體粉之混合比,而可將發光亮度及NTsc 口TelevisiGn System CGmmittee,美國電視系統委 貝έ規定之綠色之清晰度與亮度調整為最佳。 根據本發明之第U形態可提供—種勞光放電燈管,並 ::述螢光膜,將上述低電壓電子束發光螢光體之粒子配 ^於上述螢光膜之表面不連續地分布。如上所述,低電 子束發光螢光體係不帶負電荷之螢光體, =連續地分布配置,係指不帶負電荷之區域(亦稱: …電荷區域)不連續存在, 亡 盔+ # 換5之,係形成負電荷區域與 …、电何區域交替配詈之姆— m w 之杈式。因此,於負電荷區域彎曲產 地每> 傳導電子加速’藉此可確實 只見决速點焭與整個表面點亮。 根據本發明之第12形態可提供_種螢光放電燈管,其 上述螢光膜係由單獨發 低泰限士 出白色光之光致發光螢光體粉與 低电壓電子束發光螢 白色#於丄 叔之混合粉體所構成。單獨發出 ν , 尤體私係負電荷螢光體,而低電壓φ 子束發光螢光體粉係盔m丄μ 坠電 …窀何螢光體,藉由混合兩種粉體, 30 200919527 而可實現快速點亮及整個表面點亮。若不使用對應於光之 二原色之三種光致發光螢光體,而是使用單獨發出白色光 之光致發光發光體粉,彳降低榮光體成I。本發明之勞光 放電燈管無亮度飽和現象,螢光膜之亮度不隨管徑改變。 可使家庭照明所使狀管徑為25匪以上之螢光放電燈管 之亮度提昇約观,而LCD之背光所使用之管徑為5 mm 以下之螢光放電燈管,可獲得與使用稀土類螢光體之榮光 放電燈管同等或其以上之發光。亦可將營光放電燈用於彎 折多次而成之電燈狀省電型螢光燈中,可大大降低省電型 2光燈之製造成本,且可獲得1萬小時以上之長壽命,對 需求者之利益作出較大貢獻。 根據本發明之第13形態可提供-種螢光放電燈管,盆 中上述螢光膜中’單獨發出白色光之上述光致發光榮光體 係由南磷酸㈣光體所構成。歯鱗_勞光體不使用克拉 2數較低之稀有的稀土類元素,因此具有可降低螢光體成 丰之效果。 根據本發明之第14形態可提供—種螢光放電燈管,其 + ;第1 3开八 悲、之螢光膜追加性地添加有增強發紅色光之 :子束發光氧化紀螢光體。齒磷酸简螢光體單獨雖發出白 ^但於加以分色時不包含紅色光,因此藉由添加電子 2先氧化紀勞光體’而實現分色後由三原色光構成。尤 ;用作下述LCD顯示襄置之背光光源之情形時,必須為 由,加本第14形態之紅色電子束發光氧化 智先體,而可貫現三原色光。 31 200919527According to a seventh aspect of the present invention, there is provided a fluorescent discharge lamp I for coating an inner wall surface of a glass tube of the above-mentioned camping discharge lamp tube: an electron beam illuminating body powder and a photoluminescence body It is composed of powder mixed with human powder. As described above, the electron beam luminescent phosphor powder does not have a negative charge: and the photoluminescence campsite powder has a negative charge, so if two camp lights are mixed in advance: the powder is applied to the discharge lamp, the negative charge The region and the neutral region are alternately arranged in the direct control of the powder, and the acceleration regions of the infinite number of surface conduction electrons are alternately arranged with the curved regions. Therefore, it is possible to provide a discharge lamp which emits light in the body region in the discharge lamp tube, and instantaneously realizes a discharge lamp which is quickly lit and the entire surface is spotted and which achieves high illumination with low power. According to an eighth aspect of the present invention, a luminescence discharge lamp can be provided, wherein the photoluminescence phosphor powder is composed of three rare-earth photoluminescence phosphor powders that emit three-color light alone, and the electron beam illumination is performed. The phosphor powder is composed of a low voltage electron beam luminescent phosphor powder. If red, neon, and blue are selected as the two colors, the composite color is white, so a white fluorescent discharge tube can be provided. Further, the three kinds of rare earth photoluminescent phosphor powders are negatively charged phosphors, and the low voltage electron beam emitting phosphor powders are non-negatively charged phosphors, so that rapid lighting and illumination of the entire surface can be achieved. According to a ninth aspect of the present invention, there is provided a fluorescent discharge lamp, wherein the photoluminescent luminescent phosphor powder emitting green light in the rare earth photoluminescent phosphor powder is replaced by a CL luminescent zinc silicate phosphor powder. . When the green light photoluminescence phosphor powder in the eighth embodiment is replaced by electron beam light emission (CL light) 29 200919527 矽SiL zinc phosphor powder, since it does not contain rare earth as a rare element, the material becomes It’s cheap, and it’s bright and beautiful. According to a first aspect of the present invention, a fluorescent discharge lamp can be provided, wherein a photoluminescence phosphor powder emitting green light in a rare earth photoluminescence glomerium powder is produced by a CL-cut zinc oxide The powder is replaced with a mixed powder of pL hair-cutting acid-dealing precursor powder. Because it does not contain rare earths as rare elements: the material is cheap, and by adjusting the mixing ratio of the luminescent acid powder and the PU zinc silicate phosphor powder, the illuminating brightness and the NTsc port TelevisiGn can be obtained. System CGmmittee, the clarity and brightness adjustment of the green color specified by the American Television Systems Committee. According to a U-shaped aspect of the present invention, a fluorescent discharge lamp can be provided, and a fluorescent film is disposed, and the particles of the low-voltage electron beam emitting phosphor are distributed on the surface of the fluorescent film discontinuously. . As described above, a low electron beam luminescent fluorescent system does not have a negatively charged phosphor, = a continuously distributed configuration, meaning that a region without a negative charge (also referred to as: ... a charge region) is discontinuous, a dead helmet + # For the change of 5, the negative charge region is formed with ..., the electric region and the region are alternately matched with the m-mw. Therefore, in the negatively charged region, the yield of the electrons is accelerated by the conduction electrons, so that it is possible to surely illuminate the entire surface and the entire surface. According to a twelfth aspect of the present invention, there is provided a fluorescent discharge lamp, wherein the fluorescent film is made of a photoluminescence phosphor powder and a low voltage electron beam illumination white color which are white light alone. It is composed of Yu Shu's mixed powder. ν, singularly private negative-charged phosphors, and low-voltage φ sub-beam luminescent phosphors are helmets, m丄μ, and other fluorescent materials, which can be realized by mixing two kinds of powders, 30 200919527 Fast lighting and the entire surface is lit. If three kinds of photoluminescence phosphors corresponding to the two primary colors of light are not used, but a photoluminescence phosphor powder that emits white light alone is used, the glory body is reduced to I. The light-emitting discharge lamp of the present invention has no brightness saturation phenomenon, and the brightness of the fluorescent film does not change with the pipe diameter. The brightness of the fluorescent discharge lamp with a diameter of 25 匪 or more can be improved by the home illumination, and the fluorescent discharge lamp with a diameter of 5 mm or less used for the backlight of the LCD can obtain and use rare earth. The luminescence of a phosphor-like luminescence lamp is equivalent or above. The camping discharge lamp can also be used in a lamp-like power-saving fluorescent lamp which is bent many times, which can greatly reduce the manufacturing cost of the power-saving type 2 light lamp, and can obtain a long life of more than 10,000 hours. Make a greater contribution to the interests of the needs. According to a thirteenth aspect of the present invention, there is provided a fluorescent discharge lamp, wherein the photoluminescence glory body which emits white light alone in the fluorescent film of the basin is composed of a phosphoric acid (tetra) phosphor.歯 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ According to a fourteenth aspect of the present invention, there is provided a fluorescent discharge lamp, wherein: the first and second fluorescent films are additionally provided with a sub-beam oxidized oxidized phosphor. Although the tooth phosphoric acid phosphor alone emits white light, it does not contain red light when it is color-separated. Therefore, it is composed of three primary colors of light by adding electrons 2 to oxidize the seed polish. In particular, when used as a backlight source for the LCD display device described below, it is necessary to add the red electron beam oxidizing oxidant precursor of the fourteenth aspect, and to realize the three primary colors. 31 200919527

根據本發明之第M 弟5形態可提供一種LCD顯示裝置, 其特徵在於,於单而μ 4jl_ 〇 、 上排列皁個或多個第1形態〜第14 二二之任-螢光放電燈管,並用作[CD顯示裝置之背 古$⑶顯不裝置之背光光源使用冷陰極管(CCFL), 但免度較低,且毒合右Κρ 古 ^ ΐ π有限。本發明之螢光放電燈管之亮度 问、且哥命長,最適合 用作月先先源。即,本發明之螢光 敌^且管可用作液晶顯 源,其低耗電、t M心置)之背光光 …、又、廉價、長壽命,因此成為優質 且%疋之背光光源。 根據本發明之第J 6 — 於番吉古乂心可貫現一種LCD顯示裝置, 光放雷概- 上配置夕個上述第丨5形態之螢 先放電燈官,將各螢光放 電燈管為群,以線序播y 或者以多個螢光放 像映出至Γ 田之方式依序點亮,並將線序之影 H置之整個屏幕。本發明之螢光放電燈 官可實現快速點亮及整個矣“上 笼线罨燈 電燈管m广 個表面點党,即便排列多根螢光放 电燈s亚進仃線序掃描, 地瞬時點* L 『了以阿於知描速度之速度快速 電二’因此可提供—種適於掃描點亮方式之榮光放 L⑶…二: 掃描型L C D顯示裝置。習知之 …、貝不裝置中使用之crp 無法進行線序掃描。 之取快點亮速度為秒單位, [本發明之更詳細之說明] 本發明者為了掇舍罄土 & & 電現象之最基礎部分研討用2取佳動作條件,自放 向放電管内供給使氣體放電=止於電之基本係 电之電子。於使用當前使用之金 32 200919527 ki. 情形時,由於會受到於陰極表面不可避免地形成 之SBE ( 1〇6 eV/cm)之影響,故電子具有1〇6 ev/cm以上 1¾ *§" -rf' JL· λ 並自陰極表面被取出。可觀察到之放電現象中, 存在及阿能量電子之影響’而又無法以分析來除去該影 "為調查氣體放電之基本,便需要未形成SBE之電極。 本發月者利用形成於絕緣體粒子表面t SBE 1發出一種 (放電Μ )供給初速接近零之電子之新賴電 :5 '原§使用來自該電子供給源之電子時,可調查出 至今為止無法闡明之螢光放電管中之氣體放電之詳情,從 :可闡明未解決之全部事項。在將新闡明之事項最佳化 〗可開發出放電特性得到顯著改良之螢光放電燈管。 新穎电子供給源以如下方式獲得。於金 電絕緣體粒子層。在向金屬電 '么 ° °又 +人 金屬電極施加电位後絕緣體粒子產 盘全…、邑緣體拉子"電極化後之電荷之極性,雖 /、金屬電極之極性相反,但電 V ^ x L 7里Q與施加於電極之電位 g成正比,比例常數使用絕緣 =εν本- 1 丁 < "芄吊數ε而以q %表…絕緣體粒子之電容(介電電 二 由絕緣體粒子誘發之極化電位ν ''' 、 + 丄 e Vc~ Q/c= εν /C 央矣 不,由於c為常數,因此為εν/倍 g來表 ε值為3〜50,因此極化電 、’邑緣體粒子之 高…利用該較高之極化電行:位/。比金屬電極電位' 电何中出現之電位。 若於氣體空間中設置由絕緣 並向金屬電極施加峰值為!〜5kV、頻率;,金屬電極’ 高頻電場,電極周邊之氣^ 〜7〇他之 會在阿頻電場中離子化, 33 200919527 從而於電極周邊形成自由電子與自由離子。相比於金屬電 極電tVg之電場的吸引,該自由電子與自由離子更受到電 位較南之絕緣體验子之高雷你v Λ ^ 股杻于之问電位、之電場的吸引。自由電子 與自由離子雖受到極性不同之介電極化之吸引,但由於不 具有進入絕緣體έ士晶內邱3^ & | _ 、,,口日日内4之此篁,因此分別積聚於極化後 之絕緣體粒子表面上之真空中。使用單獨地積聚於極化後 之絕緣體粒子表面上之電子與離子,使營光放電管内之氣 體放電1 1係表示該放電方式之原理之示意圖。當向電 和/、電極3施加電源電壓後,置於電極2與電極3上之 絕緣體粒+ 4會如圖所示產生介電極化。氣體空間側之介 電極化之極性與電極之極性一致。電極2與鋒3之極性 會隨高頻電壓而變化,_ i中顯示其一瞬間之狀態。藉由 離子化而生成之自由電子受到絕緣體粒子中誘發之極化之 正極性吸引,並停留於絕緣體粒子4之近前之真空中,與 =緣體粒子4之正極性結合。將與該絕緣體粒子4表面結 口之電子作為氣體放電之新電子源7。離子化之Ar+受到絕 緣體粒子之介電極化中誘發之極化之負極性的吸引,並停 留於絕緣體粒子4之近前之真空中,與絕緣體粒子4之負 極陡結合,而形成離子源(積聚離子)8。放電5係藉由 自電子源7取出之電子遷移至積聚離子8而產生。參與放 2之電子係由放電管中之氣體供給,而不自絕緣體粒子供 、。電子。參與放電之電子於放電管中與離子結合而回復成 氣體原子參與放電之電子與離子不自放電管之外部 給。 ,、 34 200919527 &此處之疑問在於’積聚於絕緣體粒子表面之電子,可 月b由於與粒子内成對介 而不容易取出。電㈣Γ! 地結合形…’從 〇朴電極周邊之電場以高頻變化,絕緣體粒子 之誘發電荷之極性快速地變化。 ^ ^ ^ ^ _ 再結果為,電子供給源7 之電子在短時間内懸浮於真空 Τ 絕緣體粒子中介電極化 之電荷對懸浮於真空中之雷早夕由诚 ^ * 甲之電子之束縛力較弱,電子容易於 較弱之尚頻電場中遷移。由 ^ . 、係取出取出懸浮於絕緣體粒 子表面附近之真空中之電子,因此電子之初速度接近零。 ^發明之電子源僅於存在高頻電場時獲得,高頻波數較小 時、以及施加直流電壓時不產生上述電子源。 絕緣體粒子誘發之極化電荷量Q隨絕緣體之介電常數 ε之值而變化。本發明者發現:雖可使用普通之絕緣體粒 子,但當使用大小相同之絕緣體粒子時,於絕緣體粒子誘 發更大之誘發電壓有利於氣體放電。為獲得較大之誘發電 壓’具有較大之介電常數ε之絕緣體較佳。作為如此之絕 緣體粒子’最佳為已實用化之電子束發光螢光體(a螢光 體)粒子。高效率發光之CL勞光體之結晶係晶格點非對 ,之結晶’發光中心佔據非對稱之晶格點。佔據非對稱之 晶格點之發光中心可進行佔據對稱性結晶之晶袼點之發光 中心所不允許的電子遷移,該電子遷移概率異常大。: 實用螢光體粒子全部為具有非對稱性之結晶之理由。且有 非對稱性之結晶具有㈣特性,且具有較大之介電常數、p 根據該理由’營光體粒子適用於覆蓋金屬電極之絕緣體粒 子0 35 200919527 於絕緣體誘發之電荷量Q與絕緣體之表面積成正比變 化。較絕緣體為薄膜之情形,絕緣體為粒子時表面積更大。 平面緻密排列成一層之粒子之表面積以_表示。此“ 係粒子直徑。根據 Cath〇d〇luminescence, K〇dansha,_, P104— 120 (非專利文獻3)之記述,於規定面上排列之粒 子〜表面積與粒徑無關,而是由排列之粒子層數決定。 附著之最佳粒子總數為3層左右。根據該理由,實際 著於金屬電極表面之絕緣體粒子並非為-個,而是使3層 左右之粒子均勾地附著於金屬電極之表面。附著於全屬; 極表面之絕緣體粒子之士 i , 备屬電 隹子之大小,受到粒子對金屬表面之附著 力之限制。使用多個粒子。多個粒子之粒徑並非為均—直 :是以對數正常分布分散。分布之粒子以平均值或分 之位數為代表看待之。絕緣體粒子藉由凡得瓦耳力附 著於金屬電極表面。粒盥 ^ 寸 〃、金屬表面之附著雖可採用接著 齊1 ’旦不使用接著劑可獲得較佳結果 測定,附著力㈣之粒子t 子』微鏡之 子之千均值處於1 μη〜7 μηι之間。 為μηΐ〜5 μιη之間。粒徑大 較弱,易因機械性振動而自今屬^主 著力 i㈣之粒子奸^自金屬電極表面脫落。粒徑小於 水八而、” 時自空氣中藉由毛細凝結而吸附 於螢光放電燈管中=::粒+子’因此無法使用。 放電燈之氣體放電且有:::上述條件之新電子源時, 並不自金屬電極第一特徵係電流 L Θ、屬緣體粒子。氣體对f 由氣體之離子化而白A I體放电所需之電子藉 離子化而自氣體空間内取得,並與積聚離子再結 36 200919527 合而消失。即,放電管 即為封閉之内部電路。,內爪動係於放電管内產生、 部電路沒有電子自放電路形成於放電管内。於内 光放電燈管之驅^ 卜之電路(外部電路)流入。勞 流,但並不直接向内雖形成外部電路,且具有感應電 則内邙電路盥休°彳電路供給電子。若限定電子之流動, 子^^ 電源電路獨立存在。形成内部電路之電 二:::圖 ^ 至今為止之勞:::上述内部電路15與外部電路12。 驅動電路之電㈣ 管之放電現象之調查,係測定 電燈管之外=時T將探針連接於本發明之營光放 因并… 蚪’則可檢測電信號。此處產生誤解。 =釋該誤解。流過圖2之外部電路。之電流, 之=屬電極之絕緣體粒子之介電極化與去極化時流動 流’與㈣電路15中流動之電流錢。目前, I無檢測内部電路之電流之方法。 推:’’、、來自外部電路之電子流便可進行氣體放電,則可 =體放電所需之内部電流之大小。假設一個電子激發 算出激癸:子’亚產生一個光子之發光。於該假設下可計 放電严二:體原子之最大電子流。可根據通常之填滿螢光 η内之氣體原子數量求出所要求之最大電流。其數 :螢光放電燈之内容積已知時,可根據B〇yie_c—波 數,:查:斯:定律來計算出氣體之莫耳數。使用Α— 氣 ^所算出之莫耳數内包含之原子數。將所計算出之 孔體原子之數量換算為電流,則大多數螢光放電燈中電流 37 200919527 約為ο·ι毫安。實際上, 用構成本發明之内部電路之電子電子可重複使用,因此若使 放電燈管放電,別螢源,於理想條件下使螢光 … 貝!營光放電燈管之耗電更小,可開發出声 之省電型螢光放電燈管,但盔 流。雖由外部電路中浐雷:ή纟測疋放電燈内之電 力,但即便如此,相比於通常U之電 耗電。氣體放雷^ "之鸯先放電燈’可大幅減少 相Γ:之内部電路之電子行為複雜,即便電 二;相二結果亦存在較大差異。為實現省電型勞光放電 月複雜之電子仃為’從而最佳化電子行為。 、自極化絕緣體粒子表面上之積聚電子中取出之電子之 不刀速度接近零,因田丨、/ 士·私 匕右使用以市售放電燈用榮 —^„„0,„Applied Physics LeJ;"; ;ρ1073-4,1983 (非專利文獻4)之論文’市售營光體粒子 必須存在電子與電洞之捕獲’螢光體粒子具有永久内部 :化(PIP ) 。PIP電荷之電場向螢光體粒子外擴展。大多 :形時’肖螢光體粒子外擴展之電場為負電場。向蝥光膜 '日It時’捕獲電子自捕獲向傳導帶上升’其結果為pip 之电场消失。螢光體材料廣泛應用於電子照片或乾式影印 機之感光材料。市售放電燈用螢光體< ριρ作為光致感光 材料之特性雖較弱’因此並未實用作感光材料,但市售放 =用蟹光體之PIP’對於具有較低之能量往榮光膜:近 、电子具有充分之作用。該情形於使用放電燈之實驗中難 以硯測到。根據參考文獻3, PP141— 149之記載,於雷 康昭iU· 、电丁 π 士下之螢光膜之特性調查中,明確定量得知ριρ之存 38 200919527 在。市售放電燈用螢光體之PIP之負電場之大小,可根據 向螢光體膜照射使加速電壓變化之電子束之實驗來決定。 根據測定所決定之螢光膜上之負電位約在ii〇 v〜i5〇 v之 間。自塗佈有螢光膜之玻璃基板之背側,向螢光膜施加· v以上之正電場時,PIP之負電荷從螢光膜消失而出現 正電荷。照射電子到達螢光膜並發光。藉由施加外部電場 而使ΡΙΡ ώ現與消失之現象’與電子照片或乾式影印機之 感光材料相同,可重複多次。 未理解市售螢光體粒子所具有之ΡΙΡ之存在之螢光放 電燈管之開發者們,為除去螢光膜之HP貞電荷而辛勞。 已有開發—種瞬時點亮之螢光放電燈,於螢光膜之下側或 表面設置導電膜’或者於放電管之外壁面設置導電膜、或 於靠近放電管外壁之部位配置金屬板,採用僅於放電初期 向該等導體施加正電位之外部電路,.點亮時間以秒單位至 分單位進行變化。作為以更快時間點亮之方法,雖於電極 周邊之螢光膜上附著雜 大 Cs原子之薄膜、或向螢光膜照射 光等處理之累積,放電開始時間之縮短仍停留於秒單位程According to the aspect of the fifth aspect of the present invention, there is provided an LCD display device characterized in that the soap or the plurality of the first form to the 14th two-those-fluorescent discharge lamp are arranged on the single and the μ1jl_〇. And used as the backlight of the CD display device (3), the backlight source of the device uses a cold cathode tube (CCFL), but the degree of immunity is low, and the poisonous right Κ ρ ancient ^ ΐ π is limited. The brightness of the fluorescent discharge lamp of the present invention is long and is suitable for use as a source of the first month. That is, the fluorescent host of the present invention can be used as a liquid crystal display source, which has low power consumption and low-power backlighting, and is inexpensive, long-lived, and thus becomes a high-quality and low-resolution backlight source. According to the sixth aspect of the present invention, an LCD display device can be realized in the heart of the phoenix, and the fluorescent discharge lamp is disposed on the luminescent light discharge lamp of the above-mentioned 丨5 form. For the group, the y is broadcasted in line or in a way that multiple fluorescent images are reflected to the Γ field, and the shadow H of the line sequence is placed on the entire screen. The fluorescent discharge lamp of the invention can realize rapid lighting and the entire 矣 "cage line xenon lamp tube m wide surface point party, even if a plurality of fluorescent discharge lamps are arranged, the sub-injection line scan, the ground instantaneously Point * L "The speed of the speed of the speed of the speed of the speed of the two" is therefore available - a variety of suitable for scanning lighting glory L (3) ... 2: Scanning LCD display device. Known ..., used in the device The crp cannot scan the line sequence. The fast lighting speed is in seconds, [More Detailed Description of the Invention] The present inventors have studied the most basic part of the electric field and the electric phenomenon. The operating condition is to supply the electrons in the discharge tube to discharge the gas = the basic electricity that stops at the electricity. In the case of using the currently used gold 32 200919527 ki., it is subject to the inevitable formation of SBE on the cathode surface ( 1 〇6 eV/cm), so the electron has 1〇6 ev/cm or more 13⁄4 *§" -rf' JL· λ and is taken out from the cathode surface. Observable discharge phenomenon, presence and energy Influence" and cannot be removed by analysis In order to investigate the basics of gas discharge, it is necessary to use an electrode that does not form an SBE. This month, a person who uses the surface formed on the surface of the insulator particle t SBE 1 to emit a new type of electron (the discharge Μ) to supply electrons with an initial velocity close to zero: 5 'The original § uses the electrons from the electronic supply source to adjust the details of the gas discharge in the fluorescent discharge tube that has not been clarified so far. From: It can clarify all the unresolved issues. A fluorescent discharge lamp with significantly improved discharge characteristics can be developed. A novel electron supply source is obtained in the following manner. In the layer of gold insulator particles, after applying a potential to the metal electrode and the human metal electrode, the insulator The particle production plate is full, and the polarity of the charge after the electrode is polarized. Although the polarity of the metal electrode is opposite, the electric potential in the electric V ^ x L 7 is proportional to the potential g applied to the electrode. The constant uses insulation = εν本 - 1 &<" 芄 数 ε and q % table... Capacitance of insulator particles (dielectric potential 2 is induced by insulator particles Δ ''', + 丄e Vc~ Q /c= εν /C 矣 矣, because c is a constant, so ε ν / times g to the table ε value of 3 to 50, so polarized electricity, 'the height of the 邑 体 体 ... 利用 利用 利用 利用 利用 利用 利用 利用 利用 利用 利用 利用/. The potential of the electric potential of the metal electrode. If the gas is placed in the gas space, the peak is applied to the metal electrode! ~5kV, the frequency; the metal electrode 'high-frequency electric field, the gas around the electrode ^~7 He will ionize in the A-frequency electric field, 33 200919527 thus forming free electrons and free ions around the electrode. Compared with the attraction of the electric field of the metal electrode electric tVg, the free electron and the free ion are more affected by the insulation experience of the souther than the south, and the electric field is attracted by the electric potential. Although the free electrons and the free ions are attracted by the dielectric polarization of different polarities, they do not have the intrusion into the insulator, and they accumulate in the polarization, respectively. The vacuum is then applied to the surface of the insulator particles. The use of electrons and ions accumulated on the surface of the polarized insulator particles separately to cause the gas discharge in the camping discharge tube to be a schematic diagram showing the principle of the discharge mode. When a power supply voltage is applied to the electric and/or electrode 3, the insulator particles + 4 placed on the electrodes 2 and 3 will be dielectrically polarized as shown. The polarity of the dielectric polarization on the gas space side coincides with the polarity of the electrode. The polarity of the electrode 2 and the front 3 will vary with the high frequency voltage, and the state of the moment is displayed in the _i. The free electrons generated by ionization are attracted by the positive polarity induced by the polarization of the insulator particles, and stay in the vacuum in the vicinity of the insulator particles 4, and are bonded to the positive polarity of the edge particles 4. The electrons that are in contact with the surface of the insulator particles 4 serve as a new electron source 7 for gas discharge. The ionized Ar+ is attracted by the negative polarity of the polarization induced in the dielectric polarization of the insulator particles, and stays in the vacuum near the insulator particles 4, and is sharply bonded to the negative electrode of the insulator particles 4 to form an ion source (accumulated ions). )8. The discharge 5 is generated by migration of electrons taken out from the electron source 7 to the accumulated ions 8. The electrons participating in the discharge are supplied by the gas in the discharge tube, and are not supplied from the insulator particles. electronic. The electrons participating in the discharge are combined with ions in the discharge tube to return to the outside of the discharge tube. , 34 200919527 & The question here is that the electrons accumulated on the surface of the insulator particles are not easily removed due to the pairing with the particles. Electric (four) Γ! The combination of the ground shape...' changes the frequency of the induced electric charge from the electric field around the electrode to the high frequency, and the polarity of the induced charge of the insulator particles changes rapidly. ^ ^ ^ ^ _ The result is that the electrons of the electron supply source 7 are suspended in the vacuum Τ in a short time. The charge of the insulator particles is superimposed on the charge of the suspension. In the vacuum, the binding force of the electrons is better. Weak, electrons are prone to migration in weaker frequency electric fields. The electrons in the vacuum suspended near the surface of the insulator particles are taken out by ^. , and the initial velocity of the electrons is close to zero. The electron source of the invention is obtained only when a high-frequency electric field is present, and when the high-frequency wave number is small, and when a direct-current voltage is applied, the electron source is not generated. The amount of polarization charge Q induced by the insulator particles varies with the value of the dielectric constant ε of the insulator. The inventors have found that although ordinary insulator particles can be used, when insulator particles of the same size are used, a larger induced voltage is induced in the insulator particles to facilitate gas discharge. An insulator having a large dielectric constant ε is preferable in order to obtain a large induced voltage. As such an insulator particle, it is preferably an electron beam luminescent phosphor (a phosphor) particle which has been put to practical use. The high-efficiency luminescent CL light body has a lattice point that is not right, and the crystallization center occupies an asymmetric lattice point. The luminescence center occupying the asymmetric lattice point can perform electron migration which is not allowed by the luminescence center occupying the crystallization point of the symmetry crystal, and the electron migration probability is extremely large. : Practical phosphor particles are all reasons for crystals with asymmetry. And the amorphous crystal has (4) characteristics and has a large dielectric constant, p. For this reason, the camping particles are suitable for covering the metal electrode. The insulator amount is 0 35 200919527. The insulator induced charge amount Q and the insulator The surface area varies in proportion. In the case where the insulator is a thin film, the surface area of the insulator is larger when the particles are particles. The surface area of the particles densely arranged in a plane is indicated by _. This is the particle diameter. According to the description of Cath〇d〇luminescence, K〇dansha, _, P104-120 (Non-Patent Document 3), the particles to be surfaced on the predetermined surface are not related to the particle diameter, but are arranged. The number of particles is determined. The total number of particles to be attached is about three. For this reason, the insulator particles actually on the surface of the metal electrode are not one, but the particles of about three layers are attached to the metal electrode. The surface is attached to the whole genus; the insulator particle of the extreme surface i, which is the size of the electric raft, is limited by the adhesion of the particle to the metal surface. A plurality of particles are used. The particle size of the plurality of particles is not uniform - Straight: It is distributed by the normal distribution of the logarithm. The particles of the distribution are represented by the average value or the number of bits. The insulator particles are attached to the surface of the metal electrode by van der Waals force. The best results can be obtained by using the adhesive without the use of an adhesive. The adhesion (4) of the particles of the micro-mirror is between 1 μη and 7 μηι. μηΐ~5 μ Between ιη. The particle size is relatively weak, and it is easy to be due to mechanical vibration. Since then, the particle of the main force i (4) has fallen off from the surface of the metal electrode. The particle size is smaller than the water, and the air is condensed by air. Adsorption in the fluorescent discharge tube =::granule + child' is therefore not available. When the gas of the discharge lamp is discharged and there is a new electron source of the above condition, the current is not from the first characteristic of the metal electrode, L Θ , and the rim particle. The gas f is ionized by the gas and the electrons required for the white A I body discharge are taken from the gas space by ionization and disappear with the accumulated ions. That is, the discharge tube is a closed internal circuit. The inner claw is generated in the discharge tube, and the electric circuit is formed in the discharge tube without an electronic self-discharge circuit. The circuit (external circuit) of the internal discharge lamp is flooded. The current flows, but does not directly form an external circuit, and has an inductive power, and the internal circuit supplies the electrons. If the flow of electrons is limited, the sub-power circuit is independent. The electric circuit forming the internal circuit 2:::Fig. ^ Until now::: The internal circuit 15 and the external circuit 12 described above. The electric circuit of the drive circuit (4) The investigation of the discharge phenomenon of the tube is determined by measuring the electric light outside the electric tube. When the probe is connected to the camp light of the present invention and ...', the electric signal can be detected. There is a misunderstanding here. = Release the misunderstanding. Flow through the external circuit of Figure 2. The current, which is the dielectric polarization of the insulator particles of the electrode and the current flowing in the depolarization and the current flowing in the circuit (15). Currently, there is no way to detect the current of the internal circuit. Push: '', the electron flow from the external circuit can be gas discharge, then the internal current required for body discharge. Suppose an electron excitation calculates the radical: the sub-sub-generation produces a photon of light. Under this assumption, the discharge can be counted as the maximum electron flow of the body atom. The maximum current required can be determined by the amount of gas atoms normally filled in the fluorescent η. The number: When the internal volume of the fluorescent discharge lamp is known, the number of moles of the gas can be calculated according to the B〇yie_c-wavenumber, check:: law. The number of atoms contained in the mole number calculated using Α-gas ^. By converting the calculated number of pore atoms into a current, the current 37 200919527 in most fluorescent discharge lamps is about ο·ι mA. In fact, the electronic electrons constituting the internal circuit of the present invention can be reused. Therefore, if the discharge lamp is discharged, the fluorescent source is used to make the fluorescent light under ideal conditions. The consumption of the fluorescent lamp is smaller. A sound-saving fluorescent discharge lamp can be developed, but the helmet flow. Despite the lightning in the external circuit: the power in the discharge lamp is measured, but even so, compared to the power consumption of the usual U. Gas discharge thunder ^ " 鸯 first discharge lamp ' can greatly reduce the phase: the internal circuit of the electronic behavior is complex, even the electricity two; phase two results are also quite different. In order to realize the power-saving type of labor-saving discharge, the complicated electronic 月 is thus optimized for electronic behavior. The speed of the electrons taken out from the accumulated electrons on the surface of the self-polarizing insulator particles is close to zero. Because of the use of the commercially available discharge lamp, the field is used by the 丨 丨, / 士 匕 — ^ ^ „ „ „ „ „ „ „ „ „ „ „ „ „ „ „ „ „ „ „ ; ";; ρ1073-4, 1983 (Non-Patent Document 4) paper 'The sale of commercial light-emitting particles must have the capture of electrons and holes. 'The phosphor particles have a permanent internal: PIP. PIP charge The electric field expands outside the phosphor particles. Most of the time: the electric field outside the 'Xu phosphor particle expands to a negative electric field. The electron capture from the trap to the conduction band when the photo film 'day It' catches', the result is that the electric field of pip disappears. Fluorescent materials are widely used in electrophotographic photos or photosensitive materials for dry photocopiers. Commercially available discharge lamps use phosphors < ριρ as a photo-sensitive material, although the characteristics are weak, so it is not used as a photosensitive material, but the city Sold out = PIP' with crab light has a sufficient effect on the lower energy to the glory film: near, electron. This situation is difficult to detect in the experiment using the discharge lamp. According to Reference 3, PP141-149 Record, Yu Lei Kangzhao In the investigation of the characteristics of the fluorescent film under the iU· and the electric π 士, the quantitative analysis of the ριρ存38 200919527 is used. The size of the negative electric field of the PIP of the commercially available discharge lamp phosphor can be based on the phosphor. The film irradiation is determined by an experiment of an electron beam that accelerates the voltage change. The negative potential on the fluorescent film determined by the measurement is between ii 〇 v and i5 〇 v. From the back of the glass substrate coated with the fluorescent film. On the side, when a positive electric field of v or more is applied to the fluorescent film, the negative charge of PIP disappears from the fluorescent film and a positive charge occurs. The irradiated electrons reach the fluorescent film and emit light, and the external electric field is applied to cause the ΡΙΡ to disappear and disappear. The phenomenon is the same as that of the electrophotographic photo or the dry photocopying machine. It can be repeated many times. The developer of the fluorescent discharge lamp that does not understand the existence of the commercially available phosphor particles is to remove the fluorescent film. HP has a charge and hard work. It has been developed - a kind of instantaneously lit fluorescent discharge lamp, with a conductive film on the underside or surface of the fluorescent film 'or a conductive film on the outer wall of the discharge tube, or near the discharge tube Metal part of the outer wall An external circuit that applies a positive potential to the conductors only at the initial stage of discharge, and the lighting time is changed in units of seconds to minutes. As a method of lighting at a faster time, the film is attached to the fluorescent film around the electrodes. The accumulation of the film of the heterogeneous Cs atom or the irradiation of the fluorescent film, etc., the shortening of the discharge start time remains in the second unit

度、。,如上所述放電開始時間之難以縮短,與構成螢光膜之 發光體粒子具有之P 了 P 的作用有關。只要可除去螢光膜之 ΡΙΡ ’則螢光放電燈管可於10毫秒以下瞬時真正發光。螢 光放電燈之瞬時點;g; m π ’’儿’、困難課題,因此進行更詳細之敍 述。 將初速度接近t 2 ^子導入螢光放電管中後,因螢光 體粒子之PIP產生之备 4 <貝电何,電子無法靠近螢光膜。甚至 39 200919527 亦無法進入填充有氣體原子之氣體办pq , u遐二間。在氣體空間中填 充氣體之最外殼電子軌道之電子的备++曰/ 丁幻員電場(5xl〇5 eV)向 氣體空間擴展,受其負電場阻擋,雷;i 电子無法入氣體空間中, 故螢光放電燈管不放電。為使氣體访+ 體放電,必須變更螢光膜 之PIP,使各螢光體粒子之表面上 不存在負電位。最佳方 法係用CL螢光體製作螢光膜,此 u 萤先體以150 eV以 下之低電壓電子束進行發光。該種整 愛光體於螢光體粒子中 並不捕獲電子’因此不具有PIP。若用低電壓CL螢光體製 作螢光膜,則自積聚電子源取出之 电卞谷易進入螢光膜面 上,並於螢光膜上單向前進,而進 吧仃衣面傳導。電子碰撞 螢光膜上略微凹凸之凸起部分而產生螢光體粒子進行CL 發光,因此可確認於螢光膜上單向進行表面傳導之電子之 存在,但該發光之發光強度極低。螢光體技術者與勞光放 之技術者因其發光強度較低而忽視了該低電塵η 2光體。相比於關注發光強度,本發明者更關注為何電子 f下明亮發光之CL螢光體於螢光放電燈管之榮光膜 度較低。低電I CL螢光體膜之實驗,提供了與 榮光放電燈管之於雷她在丨 甘 電機制之基礎相關之非常重要的資訊。 :上冑用本發明之電子供給源、以及低電里發光CL 螢光膜時,於1〇古名丨 一 “ 1G讀以下瞬時產生螢光放電燈管之氣體 ^ 3對於螢光放電燈管之瞬時放電作出了各種努 力’但此事實借兮楚奴丄 鸯光膜Γ 失去意義,僅選擇電子供給源及 實无膜,即可以羽4 點亮。義於^ °想像之速度使發光放電燈管瞬時 亥發現’科學地推進了螢光放電燈管中明亮發 40 200919527 光之放電機制之闡明。 給'極與陽極雷極問;$ 电極間存在之電場為單向。若如此思考則 電子運動亦為單向。可 相遇之概案。带 /异出早向運動之電子與氣體原子 相、馬 、子直控為5·6χ10-13 cm。若將電子與原子 6χΓ〇:面積作為原子直徑,則單向運動之電子之體積為 cm /cm。常溫下1莫耳 々 為 莫耳之乳體於1大氣壓下之體積 〇2/ 1G⑽。計算時以咖之背光用CCFL(内徑為 气m,管長為Μ為例,管之體積為一封入 力為(M大氣壓(7。Το—。τ。…因此可計 々中之Ar氣之莫耳數為1χ1〇.3莫耳(= 23/22 4χΐ〇·3)。 6χ]02〇孔體之AV〇gadr〇數為6x 1 023個,因此CCFL管中 ::::r體原子隨機分布著(玻耳兹曼分…單向 :路徑:所包含…體原子數極少,為…,可認為ΐ 不與氣體原子碰撞。電子速度 ‘、、、 算明確地表示以下事實。放電現:之分二斤;上述計 在氣體空間中單向前進。該处不可°'"為電子 結論。 ^口哪係刀析氧體放電時之重要 於螢光膜上單向進行表面傳導 之概率極低(10,7…傅…子與氧體原子相遇 · ( m),無法觀測放電管之氣體放雷 ^吏氣體放電’可強制擾敗單向傳導之表面導電軌 ::使具㈣當運動能量之電子之軌道彎向氣體空間之= :道X到彎曲之加速電子與氣體原子非彈 羊較大。市售螢光放電燈用營光體粒子之—之概 电何,適用 41 200919527 於使電子軌道彎曲。若以適當比例混合低電I。 燈用勞光體粒子而製作營光膜,則可製作兼有 +。 、之表面傳導與使軌道彎曲之兩個功能的螢光 0 :證明表面傳導電子之執道隨構成螢光膜之螢光體粒 八、面狀‘4改變之事實之方法存在。可使用發出綠色光 之3 Μη之矽酸鋅螢光體(Zn2Si〇4:Mn)來證明上述事實。 Zn2S1〇4 :Mn螢光體可藉由兩種方法製造。第— :料=較超過化學反應計量一〇2,而製造勞光 肢、、I成之Zn2Sl〇4:Mn螢光體粒子表面上,附著有因過 剩添加而未反應之Si〇2之微粒子。不論化學方面抑或物理 方面均無法除去所附著之Si〇2之微粒子。於螢光放電管之 :壁面上塗佈該螢光體,並向電極施加5kv之高電壓後, 螢光放電燈會發出明壳之綠色光。s丨〇2之微粒子不吸收紫 外線,帶電之Si02微粒子之負電荷發揮向氣體空間排斥電 子之作用。然@ ’因放電之電子無法靠近螢光膜’因此陽 極區收納於Si〇2微粒子上形成之SBE鞘中,可取出之螢 光膜之發光出現飽和現象。即使以相㈣光體形成CRT(陰 極射線管cathode-ray tube)之螢光膜’並向營光膜照射15〇 eV之電子束’螢光膜亦不發光。其原因在於,附著於螢光 體粒子表面之Si〇2微粒子帶負電,而排斥靠近螢光膜之電 子^。此次於混合原料時添加過量2〇%之氧化辞Zn〇,並使 用5亥〉昆合原牙斗@製造螢光冑。於所製造之螢光體粒子之表 面附著有大量未反應之Zn〇微粒子。為了以化學方面除去 42 200919527degree,. As described above, it is difficult to shorten the discharge start time, and it is related to the effect of P which is composed of the illuminant particles constituting the fluorescent film. As long as the fluorescent film can be removed, the fluorescent discharge lamp can be truly illuminated at a moment below 10 milliseconds. The instantaneous point of the fluorescent discharge lamp; g; m π ’', is a difficult problem, and therefore will be described in more detail. After the initial velocity is close to t 2 ^ into the fluorescent discharge tube, the electrons cannot be brought close to the fluorescent film due to the PIP generated by the phosphor particles. Even 39 200919527 can not enter the gas filled with gas atoms to do pq, u遐 two. The ++曰/丁幻员 electric field (5xl〇5 eV) of the electrons filling the outermost electron orbit of the gas in the gas space expands into the gas space, is blocked by its negative electric field, and the electrons cannot enter the gas space. Therefore, the fluorescent discharge lamp does not discharge. In order to discharge the gas to the body, the PIP of the phosphor film must be changed so that there is no negative potential on the surface of each phosphor particle. The best method is to use a CL phosphor to make a fluorescent film that emits light at a low voltage electron beam of 150 eV or less. This kind of love light body does not capture electrons in the phosphor particles, so it does not have PIP. If a low-voltage CL fluorescent system is used as the fluorescent film, the electric sputum that is taken out from the accumulated electron source easily enters the surface of the fluorescent film, and advances in one direction on the fluorescent film, and the surface is conductive. The electron collides with the convex portion of the fluorescent film with a slight unevenness to generate the phosphor particles to perform CL light emission. Therefore, it is confirmed that the surface conduction electrons are unidirectionally observed on the fluorescent film, but the light emission intensity is extremely low. The phosphor technician and the technician of the laboratorium have neglected the low dust η 2 light body because of its low luminous intensity. The present inventors are more concerned with the fact that the CL phosphor of the brightly-emitting light under the electron f has a lower glory film in the fluorescent discharge lamp than the light-emitting intensity. The experiment of low-electricity I CL phosphor film provides very important information related to the glory discharge lamp to the basis of her power mechanism. When using the electron supply source of the present invention and the low-energy illuminating CL fluorescent film, the gas of the fluorescent discharge lamp is instantaneously generated by the first reading of "1G" for the fluorescent discharge lamp. The instantaneous discharge has made various efforts', but this fact has lost its meaning by using the 丄鸯 丄鸯 丄鸯 , , , , , , , , , , , , , , 选择 选择 选择 选择 选择 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子 电子The tube instantaneously found 'scientificly promoted the bright hair in the fluorescent discharge tube 40 200919527 The explanation of the discharge mechanism of light. The 'electrode and anode lightning poles are asked; the electric field existing between the electrodes is one-way. If so thinking Then the electronic movement is also one-way. The case of encountering can be met. The electrons and gas atomic phases of the belt/outward movement are directly controlled by the horse and the son are 5·6χ10-13 cm. If the electron and the atom are 6χΓ〇: area As the atomic diameter, the volume of the electrons moving in one direction is cm / cm. At room temperature, 1 mole is the volume of the milk of the molar at 1 atm. / 2 / 1G (10). The diameter is m, the length of the tube is Μ, and the volume of the tube is one. The force is (M atmospheric pressure (7. Το-.τ.... Therefore, the number of moles of Ar gas in the 々 can be 1χ1〇.3mol (= 23/22 4χΐ〇·3). 6χ]02〇孔体The number of AV〇gadr turns is 6x 1 023, so the CCFL tube::::r body atoms are randomly distributed (Boltzmann points... one-way: path: contained... the number of atoms is very small, for... It is believed that ΐ does not collide with gas atoms. The electron velocity ',,, and the calculation clearly indicates the following facts. The discharge is now divided into two kilograms; the above calculation is one-way advancement in the gas space. This is not an electronic conclusion. ^The mouth is the most important factor for the one-way surface conduction on the fluorescent film when the oxygen is discharged. (10,7...fu...the gas meets with the oxygen atom. (m), the gas of the discharge tube cannot be observed. Thundering ^ 吏 gas discharge 'can force the unidirectional conduction surface conduction rail:: make the (4) trajectory of the electrons of the kinetic energy bend toward the gas space =: the road X to the curved acceleration electron and the gas atom non-elastic sheep Larger. Commercially available fluorescent discharge lamps with the use of the light-emitting particles - the application of 41 200919527 to bend the electronic track. Mixing low-voltage I in an appropriate ratio. When a lamp is used to produce a camping film with a light-emitting particle, it is possible to produce a fluorescent light that has both the surface conduction and the function of bending the track. There is a method of changing the fact that the phosphor particles granules and the planar shape of the fluorescent film are changed. The above fact can be confirmed by using a zinc silicate phosphor (Zn2Si〇4: Mn) which emits green light. The Zn2S1〇4:Mn phosphor can be produced by two methods. The first material is more than the chemical reaction meter, and the surface of the Zn2S1〇4:Mn phosphor particles is made. On the top, fine particles of Si〇2 which are unreacted due to excessive addition are attached. The attached particles of Si〇2 cannot be removed chemically or physically. After the phosphor is applied to the wall of the fluorescent discharge tube and a high voltage of 5 kV is applied to the electrode, the fluorescent discharge lamp emits green light of the bright shell. The s丨〇2 microparticles do not absorb the ultraviolet rays, and the negative charge of the charged SiO2 microparticles acts to repel the electrons into the gas space. However, @'s electrons cannot be placed close to the fluorescent film, so the anode region is housed in the SBE sheath formed on the Si 2 particles, and the fluorescence of the extractable fluorescent film is saturated. Even if the phosphor film of the CRT (cathode-ray tube) is formed by the phase (four) light body and the electron beam of the 15 〇 eV is irradiated to the camping film, the fluorescent film does not emit light. The reason for this is that the Si 〇 2 fine particles attached to the surface of the phosphor particles are negatively charged, and the electrons close to the fluorescent film are repelled. In this case, add 2% by weight of oxidized Zn〇 to the mixed raw materials, and use 5H>Kunming original tooth hopper@ to make fluorescent enamel. A large amount of unreacted Zn 〇 fine particles are attached to the surface of the produced phosphor particles. In order to remove chemically 42 200919527

ZnO微粒子而以氨水溶& (NH4〇h液)#戶斤製造之螢光體 粉進行蝕刻後,可獲得除去Zn〇微粒子之ZnSi〇:Mn勞光 月丑右用6亥螢光體製作CRT螢光膜,並向螢光膜照射! eV 之電子束’螢光臈會以明亮之綠色之CL#光。於螢光放 電燈管之内壁面塗佈相同勞光體,並向電極施加高電壓。 螢光放電燈發出非常暗之綠色光。之後,以重量比7: 3 之比例’機械混合過剩添加si〇2而製作之螢光體粉、以及 過剩添加ZnO而製作之由NH4〇H液蝕刻過之勞光體粉。 於螢光放電管之内劈面γ士 ## 主佈該’此合螢光體粉,則可獲得 -種螢光放電燈管,其發出之光較單獨過量添加吨而製 =之螢光膜更明亮(增力σ 3()%)。上述實驗雖於cl發光 時發出亮光,㈣可以於螢光放電燈管之螢光膜中發光較 暗之螢光體再進行驗證。例如,存在表面於化學上、物理 上均清潔之Y202S:Tb綠多淼止+ μ ,此 ’、色叙光之螢光體的情形。該實驗 事實明料示於製造發出亮光之螢光放電燈管時必須考慮 之重要項目。 内徑為25 mm以上之螢光放電燈管,長期以來使用資 :豐富、廉價且以丨種螢光體發出白色光之經録及猛雙重 活化之㈣㈣螢光體[3Ca3(p〇4)2CaFci:sbMn]。於内 ^ 1G_以下之#光放電燈中,叫㈣从㈣价Μη ^體之亮度非常低而無法使用,而是使用存在資源枯竭 =鹵磷㈣螢光體< 1G倍以上價格之混合三色稀土 二榮光體的白色發光榮光膜。即便查閱出版書[亦無法 一 3Ca3(P〇4)2CaFci:Sb:Mn無法使用於内徑較小之勞 43 200919527 光放電燈管中的原因。本發明者對其原因進行了調杳。 (PO4) 2CaFC1:Sb:Mn勞光體之發光係藉由w直接刺Z +發光中心,Sb3 +發出之藍色光被同—粒子内之Μ〆*吸 收’從而使黃色之W+發光。藉*⑽+與Mn2+此兩者之 發光’而於-個螢光體粒子中發出白色光。發光過程中並 無基體結晶之吸收’目此該螢光體於電子之照射下具有絕 緣體結晶之特性。當將絕緣體結晶粒子放置於電管内時, 易於粒子表面形成較強< SBE。其結果為,氣體放電 極區收納於SBE鞘内.當縮小放電管徑後,螢光膜上之SBE 之強度不冑,因此,僅陽極區之直徑變小,氣體放電量便 飽和。以與所述之螢光體相同之方式於冗〜 (P04) 2CaFCl:Sb:Mn螢光體粉中,機械混合 3 鳩之以低電壓發出白色光之CLZn〇螢光體粉。將= 皆先體粉塗佈於内徑為1G mm之CCFL螢光放電燈管之内 壁面上。言亥CCFL瞬時放電,發出亮度高於内徑為Μ _ 以上之習知螢光放電燈管之螢光膜的白色光。上述實驗表 明螢光放電燈管内之螢光膜明亮發光之具備條件。 對於氣體空間中遷移之電子行為進行更詳細調查。一 :、又而。加速電子之非彈性碰撞,會產生氣體原子之激發 ==離子化。於加速電子具有激發氣體原子之適當大小二 此I時’僅產生氣體原子之激發,從而放射光(放電)。 與氣體原子進行非彈性碰撞後之電子失去能量,改變軌道 停留於氣體空間中,藉由下一高頻波而再次加速,並與其 他氣體原子進行非彈性碰撞。藉由該重複,電子於放電管 44 200919527 中之陽極區中朝向相對電極前進。i個電子於非彈性碰撞 期間前進之距離(平均自由行程)可根據pasehen (帕申) 曲線之測定之決定(pd)而求出。所求出之平均自由行程, 於HCFL中為1〇 _,而於CCFL中為〇2 _左右。根據 對陰極與:極間施加之電位,計算出單位長度之電場強 度,並計算出平均自由行程内之電場強度。具有代表性之 CCFL之管長為73⑽,施加於電極間之峰值電位為匕謂 V,因此峰值電麗下可算出$ 〇.2x1〇-3v/〇2_。該值遠 未達到藉由電子之非彈性碰撞而激發Hg㈣所需之能量 (10_4eV)。通常認為藉由陽極區之電位梯度而加速電子, 而於此想法中’無法加速因非彈性碰撞而失去能量之電 子。從而習知之想法並不正確。 ? 上所述,電子之質量為9X1G.28克,離子之質量為 2 X 1 〇 4克。電荷量均沒右 里U差別為I㈤Ο.丨9庫侖。假設較輕 =子易藉由高頻電場之波而運動,則根據經驗求出之最 ϋ頻波之i個波長與根據實驗求出之平均自由行程岸一 致。計算根據經驗求出之施 〜 彻、士 Ε Ε Λ 之取佳南頻波之1 變 度A1)時Η個波長之長度隨施加頻率而改 (1 )、ai = 〇-2 μια = 〇·2X 1 〇-4 (2 ) Xcal = 0.3 μιη = 〇·3 χ 1 〇-4 ^ ) ^cal = 1.0 μιη ~ ι 〇χ j q-4 (4 ) 丨=1 0 μιη :=; ι ·〇χ ι 〇·4 根據實驗求出之平均自 cm ( = 1 cm/5〇xl〇3 Hz) 50 kHz cm ( = 1 cm/3〇xl〇3 Hz) 30 kHz cm ( = 1 cm/l〇xi〇3 Hz) i〇 kHz cm ( = 1 cm/lxi〇3 Hz) j kHz 由行程於測定之誤差範圍内與 45 200919527 1個波長之長度-致。該一致表示:非彈性碰撞後之最初 之電子並未自氣體空間消失,而是再次藉由高頻電場之波 (峰值電壓為1,500 V)自高頻電場中獲取能量。即,存 在於氣體空間中之電子並未於放電管内中途消失,而是與 =波共振’於放電管中㈣方向前進,並重複與氣體原 2進行非彈性碰撞。榮光放電管中產生之陽極區,係相當 ;乳體原子之激發能量之電子與高頻波共振,才目同電子重 ^發氣體原子而產生者4採用電子與高頻共振而於放 =二沿軸方向前進之模式時,陽極區中之電位梯度便為 、 ‘驗證過去大量之測定杳· 大置之測疋貝抖時,於1900年代之報告 =若干個如此資料。就認為陽極區中存在電位梯度, I,於由電位梯度而加速之最近之測定資料的可靠性而 ^ ]定技術方面存在問題,有待對敎方法加以確認。 因加:於陰極與陽極所檢測出之電子數㈣,故難以接受 對^成^與氣體原子之碰撞而使電子數激增之說明。於 高頻之各蟹光體粒子之帶電狀況進行最佳化時, 巨觀觀:電子:峰值電位大幅減少。電子與高頻波共振係 為時,、電子運動時所觀察到之現象,而微觀觀察電子行 體粒子之2長内之電子行為大幅受到構成營光膜之勞光 衣面荷電狀態的影響。 _。當另t之方高頻波條件(50 k叫下平均自由行程為0.2 ^ 万面’螢光體粒子之平均粒徑為 i π出與高頻波共振之電子於一個螢此了 間,到達同-螢光體表面多達2"。— 46 200919527 加速而進入螢光膜之CL螢光體粒子中,但根據參考文獻1 之3己載,無法於CL螢光體表面形成SBE,而是轉變為 面傳導電子。電子藉由重複上述運動而於放電管中沿管軸 方向刖進,亚到達位於放電燈管另一端之積聚離子,與離 再而回復成氣體原子。高效之螢光放電燈管 膜必須允許雷+夕矣而淺道 光 .首 電子之表面傳導,同時亦須具有使進行表面傳 …子軌道-向氣體空間的功能。上述螢光膜之 被係螢光膜即便在暗處亦瞬時點亮。進而,由於並* 電子進入勞光體粒子時產生之咖,因此亦無咖勒,從 螢光膜之亮度。本發明消除了習知之螢光膜使用中 热法解決之較大障礙。可解決以上之揭示中與電子供= 及螢光臈、氣體放電相關之所有問題。 :發明提供一種高亮度且省電型螢光放電燈 螢光放電燈管之齑駚;^工ΐ3ζ-e之*1體原子最大限度地放電’同時使FL之 驅動電力降為最小值。本發 之 4¾ /3乏螢先放電燈之另一 於,極度延長螢光燈之使用壽命, ° 人一輩子購買一個榮光 此每個螢光放電燈管製造之終身使用電 境伴*1課題作Γ發明亦提供一種對於近年來成為問題之環 保護课越作出較大貢獻之螢光放電燈。 【實施方式】 使用圖式詳細說明本發明 — 電产f FT内谷。說明中所謂螢光放 电燈(FL)之點亮係指如下步驟: 屬泰托你^十 向連接於驅動電路之金 屬兒極施加電壓,使放電燈 於放電燈管玻璃内壁面之登光膜之^放電,並藉由塗佈 、 將藉由氣體之激發而發 47 200919527 光之不可見紫外線轉換為可見 # ^, M ^ 兄尤本發明之螢光放電燈營 金屬電極施加電壓而點亮 步 ._ 黑7^攻电燈管,伸放雷 之電子並非如習知之螢 “所項 全屬雷& ^ 般自連接於電源電路之 孟屬電極直接注入放電管内。 之 部藉由離子化u 將π頻,點免之放電燈管内 生之電子源中取出電子至氣體,門緣體粒子表面而新產 電後,盘,隼電子參與氣體放 聚集於放電管另一端之離 閉。即,罄止4 + P卞冉釔合,内部電路封 鸯先放電燈管之.點亮並不 入放雷糌技咖 八电也外4將電子注 B ,而是於放電燈管内部供給電子, 管内供給之Φ工入*、… 丨1、…冤子’且放電燈 失,同一兩:心、’肖耗。進入氣體空間之電子並不消 D电子重複多次與氣體原子進行 放電燈管内沿轴方向前進。氣::彈叫,亚於 電燈管所含之氣 電斤而之電子數小於放 之乳體原子數。計算出之每 電流量為t 风罨燈吕之内部 mA,但並無直接測定内部電流 因此無法確認。螢光 方法, 中流過之電法盘Ϊ 官之耗電係藉由測定外部電路 電雖亦-" 而決定。本發明之螢光放電燈管之耗 電雖亦错由測定外部電 广耗 放電燈内部之耗、冤‘而决疋’ 1 至並非與 蓋金屬電極之絕緣丨電流係覆 <、έ緣體粒子之極化及極化解離所恭 流,與覆蓋金Μ恭虹 之"电電 入Ρ 屬%極之絕緣體粒子數成正比例捭诸 金屬電極之面穑f & 匕1幻增减。若將 之感應電流亦最小化,表而… 丨咸〆外部電路 發明之鸯光放電光放電燈之耗電減少。本 放電燈之耗電的數分之_、隹…耗電心為習知螢光 。進而,由於本發明之電子供給 48 200919527 =在使用中完全無暴露於放電氣體中之金屬,因此並無因 陽離子引起之金屬錢渡,從而完全不存在因機渡導致之雙 :供給源減少。於#光放電燈管内不存在有機殘留氣賤 時,放電管内亮度減少之原因亦隨之消失。其結果為’螯 光放電燈管之點亮壽命延長至習知之螢光放電燈管所無 心像到之馬人長度。點亮壽命可初始亮度保_⑽ZnO microparticles are etched with phosphor powder prepared by ammonia solubilization & (NH4〇h liquid), and ZnSi 除去 which removes Zn 〇 microparticles can be obtained: Mn Laoguang ugly right is made with 6 ray phosphor CRT fluorescent film and irradiate the fluorescent film! The eV's electron beam 'fluorescent 臈 will be bright green CL# light. Apply the same mortar to the inner wall of the fluorescent discharge tube and apply a high voltage to the electrode. The fluorescent discharge lamp emits very dark green light. Thereafter, the phosphor powder prepared by excessively adding si〇2 at a weight ratio of 7:3 was mechanically mixed, and the glaze powder etched from the NH4 〇H liquid prepared by excessive addition of ZnO was prepared. In the fluorescent discharge tube, the surface of the γ γ # # # # # # 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此Brighter (enhanced force σ 3 ()%). Although the above experiment emits bright light when cl emits light, (4) it can be verified by emitting a darker phosphor in the fluorescent film of the fluorescent discharge lamp. For example, there is a case where the surface is chemically and physically cleaned by Y202S: Tb green poly-stop + μ, which is a fluorescent body of a color. The facts of this experiment are clearly shown to be important items that must be considered when manufacturing a fluorescent discharge lamp that emits light. Fluorescent discharge lamps with an inner diameter of 25 mm or more have long been used: rich, inexpensive, and recorded by white light of the phosphors. (4) (4) Phosphors [3Ca3(p〇4) 2CaFci: sbMn]. In the #1g_ below #光光灯, it is called (4) from the (four) price Μη ^ body brightness is very low and can not be used, but the use of the existence of resources exhaustion = halogen phosphorus (four) phosphors < 1G times the price of the mix White luminescent glory film of trichrome rare earth glory. Even if you consult the published book [cannot be a 3Ca3 (P〇4) 2CaFci: Sb: Mn can not be used in the lower diameter of the labor 43 200919527 light discharge lamp. The inventors have ridiculed the cause. (PO4) The luminescence of the 2CaFC1:Sb:Mn laborer is directly punctured by the Z + luminescence center, and the blue light emitted by Sb3 + is absorbed by the —* in the same particle to cause the yellow W+ to emit light. By the light emission of *(10)+ and Mn2+, white light is emitted from the phosphor particles. There is no absorption of the matrix crystal during the luminescence process. Thus, the phosphor has the characteristics of the insulator crystal under the irradiation of electrons. When the insulator crystal particles are placed in the electric tube, it is easy to form a strong < SBE on the surface of the particles. As a result, the gas discharge pole region is housed in the SBE sheath. When the discharge vessel diameter is reduced, the intensity of the SBE on the phosphor film is not high. Therefore, only the diameter of the anode region becomes small, and the gas discharge amount is saturated. In the same manner as the above-mentioned phosphor, a white light-emitting CLZn 〇 phosphor powder was mechanically mixed at a low voltage in a redundant (P04) 2CaFCl:Sb:Mn phosphor powder. Apply the = precursor powder to the inner wall of a CCFL fluorescent discharge tube with an inner diameter of 1G mm. The CCFL instantaneous discharge discharges white light with a brightness higher than that of the fluorescent film of the conventional fluorescent discharge lamp having an inner diameter of Μ _ or more. The above experiment shows that the fluorescent film in the fluorescent discharge lamp is brightly illuminated. A more detailed investigation of the electronic behavior of migration in gas spaces. One: Again. Acceleration of inelastic collisions of electrons produces excitation of gas atoms == ionization. When the accelerating electron has an appropriate size for exciting the gas atom, the I only produces an excitation of the gas atom, thereby emitting light (discharge). The electrons after inelastic collision with the gas atoms lose energy, change the orbit and stay in the gas space, accelerate again by the next high-frequency wave, and inelastically collide with other gas atoms. With this repetition, electrons are advanced toward the opposite electrode in the anode region in the discharge tube 44 200919527. The distance (mean free path) at which the electrons advance during the inelastic collision can be obtained from the determination (pd) of the measurement of the pasehen curve. The average free path found is 1 〇 _ in the HCFL and 〇 2 _ in the CCFL. Based on the potential applied between the cathode and the pole, the electric field strength per unit length is calculated, and the electric field strength in the mean free path is calculated. The representative CCFL has a tube length of 73 (10), and the peak potential applied between the electrodes is 匕V, so the peak value can be calculated as $〇.2x1〇-3v/〇2_. This value is far from the energy (10_4 eV) required to excite Hg (4) by inelastic collision of electrons. It is generally believed that electrons are accelerated by the potential gradient of the anode region, and in this idea, it is impossible to accelerate electrons that lose energy due to inelastic collisions. Thus the conventional idea is not correct. As mentioned above, the mass of the electron is 9X1G.28g, and the mass of the ion is 2 X 1 〇 4g. The amount of charge is not right. The difference between U and U is I (five) Ο.丨9 coulomb. Assuming that it is lighter = the sub-easily moves by the wave of the high-frequency electric field, the i-wavelength of the most frequent frequency wave obtained empirically is consistent with the average free-travel shore obtained from experiments. Calculate according to the experience, the length of one wavelength is changed with the applied frequency (1), ai = 〇-2 μια = 〇······································ 2X 1 〇-4 (2 ) Xcal = 0.3 μιη = 〇·3 χ 1 〇-4 ^ ) ^cal = 1.0 μιη ~ ι 〇χ j q-4 (4 ) 丨=1 0 μιη :=; ι ·〇 ι ι 〇·4 Average from the experiment from cm ( = 1 cm/5〇xl〇3 Hz) 50 kHz cm (= 1 cm/3〇xl〇3 Hz) 30 kHz cm (= 1 cm/l〇 Xi〇3 Hz) i〇kHz cm (= 1 cm/lxi〇3 Hz) j kHz is caused by the stroke within the error range of the measurement and the length of 45 200919527 1 wavelength. This agreement indicates that the first electron after the inelastic collision does not disappear from the gas space, but the energy from the high frequency electric field is again obtained by the wave of the high frequency electric field (peak voltage is 1,500 V). That is, the electrons present in the gas space do not disappear in the middle of the discharge tube, but proceed in the direction of (four) in the discharge tube with the resonance of the = wave, and the inelastic collision with the gas source 2 is repeated repeatedly. The anode region generated in the glory discharge tube is equivalent; the electrons of the excitation energy of the milk atom resonate with the high-frequency wave, and the electrons are generated by the electrons and the high-frequency resonance is generated by the electrons and the high-frequency resonance. In the direction of the forward mode, the potential gradient in the anode region is, 'Verify the past a large number of measurements 杳 · Large test 疋 抖 , , , , , , , = = = = = = = = = = = = = = = = = = It is considered that there is a potential gradient in the anode region, I, the reliability of the most recent measurement data accelerated by the potential gradient, and there is a problem in the technical aspect, and the method needs to be confirmed. In addition: the number of electrons detected in the cathode and the anode (4), so it is difficult to accept the collision of the gas and the gas atom to increase the number of electrons. When the charging state of each of the high-frequency crab light particles is optimized, the giant view: electron: the peak potential is greatly reduced. The resonance between the electron and the high-frequency wave is a phenomenon observed during the movement of the electron, and the electronic behavior of the microscopic observation of the electron beam of the electron beam is greatly affected by the state of charge of the coat surface of the camping film. _. When the other t high-frequency wave condition (50 k is called the average free path is 0.2 ^ 10,000 faces), the average particle size of the phosphor particles is i π and the electrons of the high-frequency wave resonate with each other, reaching the same-fluorescence The surface of the body is up to 2"-- 46 200919527 Accelerated into the CL phosphor particles of the fluorescent film, but according to the reference 1 3, it is impossible to form SBE on the surface of the CL phosphor, but to convert into surface conduction. By repeating the above-mentioned motion, the electrons are pushed in the discharge tube along the tube axis direction, and the accumulated ions accumulated at the other end of the discharge lamp tube are returned to the gas atoms. The high-efficiency fluorescent discharge lamp film must be Allowing lightning + 矣 矣 and shallow light. The surface conduction of the first electron must also have the function of making the surface pass the sub-orbit to the gas space. The fluorescent film of the above fluorescent film is instantaneous even in the dark. Further, since the electrons generated when the electrons enter the mortar particles, there is no coffee, and the brightness of the fluorescent film is eliminated. The present invention eliminates the major obstacles to the thermal solution in the conventional use of the fluorescent film. Can solve the above All problems related to electron supply = and fluorescent krypton, gas discharge: The invention provides a high-brightness and power-saving fluorescent discharge lamp fluorescent discharge lamp; ^ ΐ 3ζ-e * 1 atom Maximize the discharge' while minimizing the driving power of the FL. This is the other 43⁄4 / 3 lack of the first discharge lamp, which greatly prolongs the life of the fluorescent lamp. ° People buy a glory for a lifetime. The life-saving use of the fluorescent discharge lamp is related to the subject of the invention. The invention also provides a fluorescent discharge lamp that contributes greatly to the environmental protection course that has become a problem in recent years. [Embodiment] Detailed description using the drawings The invention - the electric product f FT inner valley. The lighting of the so-called fluorescent discharge lamp (FL) in the description refers to the following steps: The tycoon is connected to the metal electrode of the driving circuit, so that the discharge lamp is The discharge film of the inner wall of the discharge lamp glass is discharged, and by coating, will be excited by the gas. 47 200919527 Invisible ultraviolet light is converted into visible # ^, M ^ Brother Discharge lamp camp metal electrode Adding voltage and lighting the step._ Black 7^Tension light tube, the electronic device that stretches and thunder is not like the well-known firefly. "All the items are lightning & ^. The Meng electrode connected to the power circuit is directly injected into the discharge tube. The part is extracted by ionization u, and the electrons are taken out from the electron source inside the discharge lamp tube, and the surface of the door body particle is newly produced. After the electricity is generated, the disk and the electron are concentrated in the discharge tube. The other end of the separation. That is, the 4 + P junction, the internal circuit is sealed first discharge lamp. The lighting does not enter the Thunder technology, the electric 8 is also the external 4 will be the electronic injection B, but the discharge The inside of the lamp is supplied with electrons, and the Φ in the pipe is supplied into the *, ... 丨 1, ... 冤 ' ' and the discharge lamp is lost, the same two: heart, 'xiao consumption. The electrons entering the gas space do not disappear. The electrons are repeatedly repeated with the gas atoms to advance in the direction of the axis inside the discharge lamp. Gas:: Bounce, the gas contained in the electric tube is less than the number of atoms in the milk. The calculated current per flow rate is the internal mA of the wind-powered lamp, but the internal current is not directly measured and therefore cannot be confirmed. Fluorescent method, the electric current flowing through the system is determined by measuring the external circuit electricity. The power consumption of the fluorescent discharge lamp of the present invention is also wrongly determined by measuring the internal consumption of the external electric discharge lamp, and is not the same as the insulation current of the metal electrode of the cover metal. The polarization and polarization dissociation of the bulk particles are in agreement with the number of insulator particles covering the % pole of the gold Μ 虹 虹 捭 捭 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 幻 幻 幻 幻 幻 幻. If the induced current is also minimized, the watch is... The external circuit of the invention The reduction of the power consumption of the inventive Xenon discharge discharge lamp is reduced. The power consumption of this discharge lamp is _, 隹... The power consumption is conventional fluorescent. Further, since the electron supply of the present invention 48 200919527 = there is no metal exposed to the discharge gas at all in use, there is no metal money caused by the cation, so that there is no double due to the machine: the supply source is reduced. When there is no organic residual gas in the #light discharge lamp, the cause of the decrease in brightness in the discharge tube also disappears. As a result, the lighting life of the 'slip-discharge lamp tube is extended to the length of the horseman of the conventional fluorescent discharge lamp. Lighting life can be initial brightness protection _ (10)

時以上。 J 本發明之螢光放電燈管内之電子運動與固體及液體中 之電子運動不同。原子有規律地排列之固體中之導電受到 阻)之限制。原子無秩序地排列之液… =二子或電子濃度成比例。榮光放電燈内之放電雖由 ^ — 電子行為與㈣及液體之情形不同,受到 查光膜之荷電分布極大影響,並於 此歐姆定揸廿丁 ^ 曰卜决疋仃為,因 疋律並不通用於放電燈管内之電子行 燈管内之登·氺趙^•士 / 、 榮光放电 早、“、 (a)激發氣體原子發出之紫外線井 與氣體非彈性碰撞而散射之電子、及' 射電子與高頻電場共振而自高頻電場 及曰政 砦孙妗止v、, ^g又阿 < 阿月& s電子。 糸外線先子並無電荷因此 習知之放電中未、、主……先膜上之電荷之作用。 受到螢光膜φ /思、 面$,帶貞電荷並遷移之電子 子軌道之方 響而改變電 光體粒子之内邙……一 τ之負電何令’存在因螢 子表面上形成之表面結合電子(SBE) 光體粒 粒子表面附著微量絕緣體時便不可避免地sf/於榮光體 避免地會出現於微量絕 49 200919527 緣體^因SBE之負電場,營光體粒子被遮蔽。因登光膜 上之该等負電場之庫侖斥力而使電子遠離螢光臈,並社果 為氣體放電路曰徑收納於霞負電荷之勒内,與螢光膜隔開 由SBE電何I決定之距離而存在氣體放電路徑(陽極區)。 陽極區與螢光膜之間隙中存在非激發⑽氣體,有效吸收 自/氣體放電路徑發射之254 nm f外線之結果,到達勞光 艇之254㈣紫外線量飽和。即,SBE鞘之存在導致習知 螢光放電燈管之亮度飽和現象,限制了亮度之最大值。本 發明發現以適當之比例混合除去赃之螢光體粒子與保持 咖之螢光體粒子,且用該混合體製作成螢光膜,則可自 螢光膜獲得高亮度’從而提供一種高亮度、長壽命、且耗 電顯著降低之新穎構造的螢光放電燈。 圖1係圖解本發明之FLi放電機構之原理的說明圖。 將與放電燈之驅動電路直接連接之金屬電極2以及金屬電 極3置入氣體放電燈管i内,並自位於放電燈外部之電源 6向金屬電極施加交流高頻電場。為便於說明,圖丨中各 金屬電極2與金屬電極3上分別放置—個絕緣體粒子4。 向金屬電極2與金屬電極3施加電壓後’絕緣體粒子4於 圖1所示之極化方向上瞬時極化。通常絕緣體粒子之介電 褕數ε較大,因此於絕緣體粒子4誘發之極化電荷之電位 比金屬電極2與金屬電極3之電位高ε倍。於絕緣體粒子 4誘發之極化電荷内,氣體空間側之電荷將電場擴展至氣 體空間中。當絕緣體粒子4與金屬電極2以及金屬電極3 置於ac高頻電場中時,金屬電極周邊之氣體藉由扣高頻 50 200919527 電場而瞬時離子化,電子4 作用之距離。即,成A白Μ 刀開至不產生相互 ώ ^ 成為自由電子與自由離子。自由雷子金 自由離子於氣體空 /、 靠近。貪、…’刀別向作為相對電極之介電體極化 罪近。罪近之自由電子(盥自 粒子内之能量,自… 具有進入絕緣體 電子經由界面而與絕緣體内之正f* / 結合。Μ由令舌.s # 小胆Π <止罨何 錯由5亥重複,隨著時間推移結合電子 表面積聚,於絕緣體粒+ 4 子於、、邑緣體粒子 ^ 之表面形成電子供給源7。同More than above. J The electron motion in the fluorescent discharge lamp of the present invention is different from the electron motion in solid and liquid. The conduction of the atoms in the regularly arranged solids is limited. The liquid in which the atoms are arranged in an orderly manner... = the concentration of the two sub- or electrons is proportional. Although the discharge in the glory discharge lamp is different from that of (4) and the liquid, it is greatly affected by the charge distribution of the light-detecting film, and it is determined by the ohms. It is not used in the electronic light-emitting tube in the discharge lamp tube. 氺 氺 ^ ^ ^ 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 'The electrons and the high-frequency electric field resonate from the high-frequency electric field and the 曰政寨孙妗止v,, ^g又阿<阿月&s electron. The outer line has no charge, so the conventional discharge is not , the main ... the role of the charge on the film. The fluorescent film φ / think, face $, with the charge of the electrons and the migration of the electron sub-orbital ring to change the internal light of the electro-optical body particles ... It is inevitable that sf/ glory will be avoided in the presence of trace insulators on the surface of the surface-bound electrons (SBE) formed on the surface of the fluorescing. The electric field, the camping body particles are obscured. The Coulomb repulsion of these negative electric fields on the light film keeps the electrons away from the fluorescent 臈, and the fruit is placed in the negative charge of the gas discharge circuit, and is separated from the fluorescent film by SBE. There is a gas discharge path (anode region) at the distance. There is a non-excited (10) gas in the gap between the anode region and the fluorescent film, which effectively absorbs the result of the 254 nm f outer line emitted from the gas discharge path, and reaches the 254 (four) ultraviolet light of the Laoguang boat. The amount is saturated. That is, the presence of the SBE sheath causes the brightness saturation of the conventional fluorescent discharge lamp to limit the maximum brightness. The present inventors have found that mixing the phosphor particles in the appropriate proportions and maintaining the fluorescence of the coffee The bulk particles, and the use of the mixture to form a fluorescent film, can obtain high brightness from the fluorescent film', thereby providing a novel structure of fluorescent discharge lamp with high brightness, long life, and significantly reduced power consumption. Description of the principle of the FLi discharge mechanism of the present invention. The metal electrode 2 and the metal electrode 3 directly connected to the drive circuit of the discharge lamp are placed in the gas discharge lamp tube i, and are located outside the discharge lamp. The power source 6 applies an alternating-current high-frequency electric field to the metal electrode. For convenience of explanation, each of the metal electrode 2 and the metal electrode 3 is placed with an insulator particle 4. After the voltage is applied to the metal electrode 2 and the metal electrode 3, the insulator particle 4 is applied. It is instantaneously polarized in the polarization direction shown in Fig. 1. Generally, the dielectric enthalpy ε of the insulator particles is large, so the potential of the polarization charge induced by the insulator particles 4 is higher than the potential of the metal electrode 2 and the metal electrode 3. In the polarization charge induced by the insulator particles 4, the charge on the gas space side expands the electric field into the gas space. When the insulator particles 4 and the metal electrode 2 and the metal electrode 3 are placed in the ac high-frequency electric field, the periphery of the metal electrode The gas is instantaneously ionized by deducting the high frequency 50 200919527 electric field, and the distance of the electron 4 is. That is, the A white knives are opened until they do not produce mutual ώ ^ become free electrons and free ions. Free Thunder Gold Free ion in the gas air /, close. Greed, ... 'knife is not close to the polarization of the dielectric as the opposite electrode. The sin is near to the free electrons (the energy from the particles, from ... has entered the insulator electrons through the interface and the positive f* / in the insulator. Μ by the tongue. s #小胆Π < 罨 罨 错 错 5 The repetition is repeated, and the electron surface area is combined with the passage of time to form an electron supply source 7 on the surface of the insulator particles + 4 and the edge particles.

才水’於絕緣體粒子4之#》丄 ,J 井妨+ 表面形成由Ar+形成之離子源8。螢 先放电燈管内之氣體發光 螢 至Ar+之正離子s 係於自电子源7取出之電子遷移 部雷Γ 期間產生。如上所述,放電所需之全 燈管内供給,並於燈管内消耗,氣體放電5 源自放電燈管外供給。此係本發明之電子 之开/成與放電5之特徵。 圖2表示本發明之螢 電路,時存在之兩個等效 圖不貝貝上驅動放電燈之外部 燈管12以及於放電 電路V虽 之内部電路15。圖2 (A)所示之外部 〜12係由兩個電容13與電源6所構成。電容器 if覆蓋金屬電極2與金屬電極3之絕緣體粒子4”; °丨電路12中,葬cb 又卜 曰由ac南頻而進行驅動時 體…之極化以及極化離解(與電容=邑緣 流⑷進而在電子於放電燈内部運動後4上)之感應電 會有由該放電管内部之電… ’於外電路12 12中不電路12%加&電壓時,夕卜部電路 中电k並不机動,放電燈管不放電。圖2 ( b )所示之 51 200919527 内部電路15由電子供給源i6取 於放電管内放電之陽極區 積來之正離子源17、以及 源16與積聚正離子源丨 斤構成。放電係以電子供給 可確知,於螢光放電之電子移動產生。根據圖式 並無直接之電子流動。 電路15與外部電路12之間 圖3係表示使用本發明 之簡略圖。螢光放電产之〜操作榮光放電燈9 你占 且谷益'係由真空密封之玻璃管9 f 作成。於玻璃管9内 ^ " 9 ^ 夕入& ^ 臧有由多個以絕緣體粒子4覆芸 之金屬電極2與金屬電極 卞4覆| 榮光體粒子(大小為4 玻璃管9之内壁面’以 眩1 〇 - ^ ’ μΠ1左右)之適當厚度塗佈有螢光 二放電之陽極區u無法接近勞光们。 先啸開些距離而配置於破璃管9 :陽: 區11發光之UV光不帶雷4 ^ 由於在%極 何,因此不受螢光膜内之螢光體 粒子之電荷的影響而到達蛍九體 ^ a , 茧尤膜10,在螢光膜10被轉換 為可見光。於陽極區u與榮 、 蒸氣。該非激發之汞基氣於陽A 0子在非激發之汞 ……w極區u中發光之㈣ 赏先Μ之前吸收(自行吸收) 目争』、, 及收)UV先,因此發光出現飽和 現象。4細情形於下述螢光膜處敍述。 本發明由補充之兩個部分構成。第一係勞光放電燈内 成為電子之供給源之金屬電極上之絕緣體粒子表面形成的 電子源^6與積聚正離子17。第二係於放電燈管内遷移並 使氣體產生發光之電子之行為,受到構成榮光膜之各螢光 體粒子之電荷的作用’因此進行找出施加 子之電荷之最佳條件的作業。 愛尤體粒 52 200919527 發明之螢光放電燈不使用熱陰極作為電子供給源。 本I明之新穎電子源用絕緣體粒子遮蔽冷陰極()之 金屬電極,並使用絕緣體粒子上積聚之電子作為供給源。 基材為CCFL之金屬電極。圖4表示根據CCFL考慮之冷 陰極電極中,藉由絕緣體粒子4覆蓋通常使用之金屬電^ 表面之電極構造。最常用之金屬電極係圖4 (A )所示之釣 鐘型電極19。雖可使用該釣鐘型電極19,但釣鐘型電極μ 之表面積較大,覆蓋表面之絕緣體粒子數較多,絕緣體粒 子之充j電會導致外部電路中流過較大之感應電流,因此 不利於實用。為使絕緣體粒子之充放電而流動於外部電路 之感應電流最小化,可使金屬電極的形狀為平板狀。圖* ⑻中係使时板狀金屬電極21,已使絕緣體粒4附著 於平板狀金屬電極21《放電氣體面上。該電極構造中存 在於絕緣體表面之電子之取出表現出顯著之異向性。上述 ,鐘型電極19及平板狀金屬電極21上連接有用於施加外 口15电壓之引導電極18。根據1111}^(^1]^_1^^3¥。127 P1345之論文(非專利文獻5),電子於沿著絕緣體 界面之平行方向上遷移時移動性較高,若於與表面垂直 Q出電子貝j移動14較差。習知之勞光放電燈中係於與 陰極面成直角之方向取出電子,因此就取 電而δ存在問題。為使螢光放電燈瞬時放電, 順序可以Η)㈣以下之速度使螢光放電燈f 使電子直接進入氣體空間,…子供給源取出; 先膜上取出,使該電子加速後使其朝向氣體空間散射。金 53 200919527 屬電極21非常適於按照該顺序取出電子。而且,自平板 狀金屬電極21取出之電子, 其山 囬<€于係取出距離螢光放電燈管之 管令而1 mm〜3 mm之間的雷工 π 1 之間的電子,因此若使螢光膜塗佈至距 離e蜢1 mm左右,螢光放 ^ 宅燈官之全長便會均勻發光。 驾知之CCFL中,因金屬電極 大小,存在距離管端丨〇 mm 以上便會變暗之缺陷,而於 .m ^ ^ ttLFL中因熱陰極之大小,於 更長之2〜3 cm之間存在變典从μ 子在變暗缺陷。該問題在採用本發明 之圖4 (B)之平板狀金屬電極u時解決。 人眼無法感知房屋照明所使用之螢光放電管之i秒左 右之點亮速度的差異,因此即便房屋照明中使用發明之螢 光放電燈管,人眼亦無法感知 4 π點冗迷度之差。但將本發明 之勞光放電燈管使用於LCD等顯示裝置之光源(背光)時, 可貫現10毫秒以下之速度之耽古 — 度之點冗,可實現背光之線掃描 月滅。…结果為’減少屏幕上呈現之晝質對lcd之特性的 依賴’人眼可明確辨認晝質提高。其結果為,並血主像之 顫動或畸變,以碳之黑為基準時’藉由與作為微陰:天之 光照明度之350 Cd/m2之照明度之間的對比度而形成4 近自然之清晰影像。長時間觀看當前之lcd屏幕上之麥像 時丄於黑水準有亮度,從該水準採用高對比值故上限亮\ 較高,成為與白天太陽直射之日光之影像等效的影像。$ 而’根據LCD之特性,長時間觀看無法明確辨認之不清晰 影像’會造成人眼永久性損傷。其結果為,每年必須更換 眼鏡。該問題於使用本發明之CCFL之lcd可得以解決。 不僅個人眼睛之永久損傷。LCD之耗電亦大幅度減少。咖 54 200919527 之透光率為8%亡 ^ « 無法進行線^敕,之點亮速度為1秒左右,因此 光發光,耗齋命户右以線掃描使背 若掃描二Γ 量成反比,以—次函數減少。 、數為條,則背光之耗電減少為十分之 若 •描線數為20條,則電力消耗成為二十分之:二 耗電減少直接導致LCD顯示I置之省電。 。月先 徑電極21有利於縮…之放電管玻璃 右放電*玻璃内徑小於1<51麵,則如 僅於單面塗佈絕緣體粒子無法取出足量之電 不 塗佈二=不,於平板狀金屬電…兩個表面 二”即可。若使用圖4(〇之電極,便可製造The water source 8 forms an ion source 8 formed of Ar+ on the surface of the insulator particle 4. The gas in the first discharge lamp is illuminated. The positive ion s from Ar+ is generated during the thunder of the electron transfer section taken out from the electron source 7. As described above, the entire lamp tube required for discharge is supplied and consumed in the lamp tube, and the gas discharge 5 is supplied from outside the discharge lamp tube. This is a feature of the on/off and discharge 5 of the electron of the present invention. Fig. 2 shows the flash circuit of the present invention. The two equivalent diagrams of the external lamp 12 for driving the discharge lamp and the internal circuit 15 for the discharge circuit V are shown. The external ~12 shown in Fig. 2(A) is composed of two capacitors 13 and a power source 6. The capacitor if the insulator electrode 4 of the metal electrode 2 and the metal electrode 3 is covered; in the circuit 12, the cb is buried and the polarization and polarization dissociation of the body are driven by the ac south frequency (with capacitance = rim The inductive electricity of the current (4) and then after the electrons move inside the discharge lamp will have electricity from the inside of the discharge tube... 'In the external circuit 12 12, when the circuit is not 12% plus & voltage, the electric circuit in the circuit is It is not maneuverable, and the discharge lamp is not discharged. Figure 51 (b) shows 51 200919527 The internal circuit 15 is taken from the electron supply source i6 to the positive ion source 17 of the discharge in the discharge tube, and the source 16 and the accumulation are positive. The ion source is composed of an ion source. The discharge is determined by electron supply, and the electron movement in the fluorescent discharge is generated. There is no direct electron flow according to the drawing. Between the circuit 15 and the external circuit 12, FIG. 3 shows a brief use of the present invention. Fig. Fluorescence discharge produced ~ operation glory discharge lamp 9 You accounted for and the valley is made of vacuum sealed glass tube 9 f. In the glass tube 9 ^ " 9 ^ 夕入 & ^ 臧 has multiple Metal electrode 2 and metal covered with insulator particles 4 Extremely 卞4 Covering | The radiant body particles (the inner wall surface of the size of the glass tube 9 is glare 1 〇- ^ 'μΠ1 or so) is coated with the fluorescent second discharge anode area u can not approach the light. Open some distance and arrange it on the broken glass tube 9: Yang: The UV light emitted by the area 11 does not have a thunder. 4 ^ Because it is in %, it is not affected by the charge of the phosphor particles in the fluorescent film. The body ^ a , 茧 膜 film 10 , is converted into visible light in the fluorescent film 10 . In the anode region u with rong, vapor. The non-excited mercury-based gas in the yang A 0 in the non-excited mercury ... w polar region u In the middle of the illuminating (4) absorbing the Μ before absorbing (self-absorption) 目,, and receiving) UV first, so the luminescence appears saturated. 4 fine case is described in the following fluorescent film. The invention consists of two parts The electron source 6 formed on the surface of the insulator particles on the metal electrode serving as the supply source of electrons in the first-system discharge lamp and the accumulation of the positive ions 17. The second system migrates in the discharge lamp and causes the gas to emit light. The behavior of electrons is affected by the charge of each of the phosphor particles that make up the glory film. The role of 'therefore is the job of finding the optimum conditions for applying the charge of the sub-body. Aiyou Body Particles 52 200919527 The fluorescent discharge lamp of the invention does not use a hot cathode as an electron supply source. The novel electron source of the present invention shields the cold with insulator particles. The metal electrode of the cathode () uses electrons accumulated on the insulator particles as a supply source. The substrate is a metal electrode of CCFL. Fig. 4 shows that the cold cathode electrode considered according to CCFL is covered with insulator particles 4 to cover the commonly used metal ^ Electrode structure of the surface. The most commonly used metal electrode is the bell-type electrode 19 shown in Fig. 4 (A). Although the bell-shaped electrode 19 can be used, the surface area of the bell-shaped electrode μ is large, and the number of insulator particles covering the surface is large, and the charging of the insulator particles causes a large induced current to flow in the external circuit, which is disadvantageous for practical use. . In order to minimize the induced current flowing to the external circuit by charging and discharging the insulator particles, the shape of the metal electrode can be flat. In Fig. 8 (8), the plate-shaped metal electrode 21 is placed, and the insulator particles 4 are adhered to the discharge metal surface of the flat metal electrode 21. The removal of electrons present in the electrode structure on the surface of the insulator exhibits significant anisotropy. As described above, the bell electrode 19 and the flat metal electrode 21 are connected to the lead electrode 18 for applying the voltage of the outer port 15. According to the paper of 1111}^(^1]^_1^^3¥.127 P1345 (Non-Patent Document 5), electrons have higher mobility when moving in parallel directions along the interface of the insulator, and if they are perpendicular to the surface Q In the conventional light discharge lamp, electrons are taken out at a right angle to the cathode surface, so there is a problem in taking power and δ. In order to instantaneously discharge the fluorescent discharge lamp, the order can be Η) (4) The speed causes the fluorescent discharge lamp f to directly enter the gas space, and the sub-supply source is taken out; first, the film is taken out, and the electrons are accelerated to be scattered toward the gas space. Gold 53 200919527 The genus electrode 21 is very suitable for taking out electrons in this order. Moreover, the electrons taken out from the flat metal electrode 21 are returned to the electrons between the laser π 1 of 1 mm to 3 mm from the tube of the fluorescent discharge lamp, so Apply the fluorescent film to a distance of about e蜢1 mm, and the full length of the fluorescent light will be evenly illuminated. In the CCFL of the driver, due to the size of the metal electrode, there is a defect that it will become darker than the end of the tube 丨〇mm, and in the .m ^ ^ ttLFL, due to the size of the hot cathode, it exists between the longer 2~3 cm. The variation from the muon is darkening the defect. This problem is solved when the flat metal electrode u of Fig. 4(B) of the present invention is employed. The human eye cannot perceive the difference in lighting speed of about 1 second of the fluorescent discharge tube used for house lighting. Therefore, even if the inventive fluorescent discharge lamp is used in house lighting, the human eye cannot perceive the 4 π point redundancy. difference. However, when the light-emitting discharge lamp of the present invention is used for a light source (backlight) of a display device such as an LCD, the speed of the speed of 10 milliseconds or less can be realized, and the line scan of the backlight can be realized. ...the result is 'reducing the dependence of the enamel presented on the screen on the characteristics of the lcd'. The human eye can clearly identify the improvement in enamel. As a result, the main image of the blood is trembled or distorted, and when it is based on carbon black, it is formed by the contrast between the illumination of 350 Cd/m2 as the illuminance of the light of the sky. Clear image. When viewing the current image on the current lcd screen for a long time, there is brightness at the black level. From this level, the high contrast value is used, so the upper limit is brighter and higher, which is equivalent to the image of the daylight that is directly exposed to the sun. $ And depending on the characteristics of the LCD, long-term viewing of unclear images that cannot be clearly identified can cause permanent damage to the human eye. As a result, glasses must be replaced every year. This problem can be solved by using the lcd of the CCFL of the present invention. Not only permanent damage to the individual's eyes. The power consumption of the LCD is also greatly reduced. Coffee 54 200919527 The light transmission rate is 8%. ^« Unable to carry out the line ^敕, the lighting speed is about 1 second, so the light is shining, and the right-handed line scan is used to make the back scan ratio inversely proportional. Reduced by the - time function. When the number is strip, the power consumption of the backlight is reduced to a very small number. If the number of lines is 20, the power consumption is 20%: 2 The power consumption decreases directly, causing the LCD display to save power. . The first diameter electrode 21 is favorable for the discharge tube glass right discharge * the glass inner diameter is less than 1 < 51 surface, if only one side of the insulator particles can not be taken out, a sufficient amount of electricity is not coated, two is not, in the flat plate Metal-like electricity... two surfaces are two". If you use Figure 4 (the electrode of the crucible, you can manufacture

Sc 71以上且亮度高之咖。再者,圖4(幻〜 圖4 ( C)中,小玻璃管2〇係 其 後注入Ar氣體及Hg氣體之微小破:管,=Coffee with a brightness of above 71 and high brightness. Furthermore, in Fig. 4 (phantom ~ Fig. 4 (C), the small glass tube 2 is followed by a small break of the Ar gas and the Hg gas: tube, =

Si:接而密封破璃管9。心=: 4體粒子之極化無關,因此平板狀金 無特別要求’但使用硬度高之材料時作業性較佳?= 金屬電極21之電極厚度隨所使用之金屬材料而改變。以 保持絕緣體粒子、以及製造時容 摆I- 隹予令易進仃電極設定作業為選 丄’、用各種金屬材料。必須考慮之方面在於,因 =表面之射虫而導致吸附有機氣體及無機氣體。若存在 ^吸附’則螢光放電燈之壽命、尤其係榮光膜之發光將 冒因該“體吸附而變弱’因此必須加以注意。於使用 心合金之情形時’最佳之厚度處於〇.2 — _之間。 55 200919527 平板狀金屬電極21之直徑隨所使用之#光放電 而改變,但於内管徑為15 _以上之螢光放電管中,可使 用直徑為1〇咖之平板狀金屬電極21,因此上述平板狀 金屬電極21之最大直徑為1 Λ 位馮10 mm。於螢光放電管之内管 徑處於5 mm〜15 mm之間之情形時,金屬電極之直和較 内徑小2mm即可。於螢光放電管之内管徑處於2_〜5mm 之情形時,金屬電極之大 八』权内徑小1 mm即可。於 放電管之内管徑為2 mm以 一 Γ您匱形時,金屬電極之大小 較内徑小〇_5 mm即可。 於螢光放電管之内營為9 T , , S马2 mm以下之情形時,考岸到 平板狀金屬電極2〗之作業拙女 可應幻 同之作業性’亦可採用棒狀金屬電極。 圖5(A)表示於棒狀金屬 子之示例。棒狀金屬電極表面塗佈有絕緣體粒 n t & 極22僅猎由熔接器於玻璃密封之 emet線之前端熔融接 著絕緣體粒子即可,因此較細之之=奉,t金屬棒上附 使用之金屬棒之粗度為〇 呢之作業性優良。所 長度處於o5mm 5 職〜1随,粗度並無限定。 處所示之數字之入:_之間即可。當然,大於或小於此 ^ 文予之盃屬棒亦可作為電極。 金屬電極之表:表面為粗链面’以使絕緣體粒子易附著於 經化學蝕刻德’但較佳為不藉由化學蝕刻製作粗糙面。 X 4之面對於絕緣體粒 + 粒子難以附基^ 于而3係千滑面,絕緣體 末粒徑略小於叙祕^ 戚為粗铋面,較佳為使用粉 ; 緣體粒徑 '且粒徑平 末研磨劑。 卞3值為1〜3 μπι之粉 56 200919527 為使絕緣體粒子更牢固地附著於金屬表面,首先㈣ 屬表面附著非晶質粉玻璃23, Λ热主馬1嘁點以上之溫度後 = '絕=體粒子’並再次進行加熱,將粉玻璃Μ炼融後 :部至室溫’絕緣體粒子藉由溶融粉玻璃Μ❿牢固地接 著。然而,若不使用粉玻璃製作則性能較佳。 金屬電極上塗佈之絕緣體材料4若為介電常數ε處於 3〜50之絕緣體,則均可㈣絕緣體粒子。若使用介電常 ^ 8為50卩上之絕緣Μ,則外部電路之ac電壓之上升與 此::It放電燈之點亮速度變慢。同時電力亦增加,因 此欠佳。-般而言’無機絕緣材料之蒸發溫度非常高時亦 穩=因此對螢光放電燈管之壽命並無影響。$而,登光 ^兒官巾之正離子並不直接碰撞絕緣體粒子,如圖1所明 不’亦不與負電位之金屬陰極碰撞。因此,本發明之螢光 電燈s中亚無存在因陰極影響螢光放電燈管壽命之因 :'、此處’針對螢光放電燈管之壽命進而略做敍述整理。 I、“放電燈g中決定哥命之另一因素係螢光膜亮度之經時 :化。出版書籍中明確說明發光膜之亮度之經時劣化,係 螢光體之發光中心之破壞而引起之劣化,但該說 士异 λ ^ 、占據結晶之晶格點之發光中心非常穩定。然而,螢光 體粒子> s ^ 、 1面附近不穩定,製造時會產生大量之晶格缺 ^尤其係離子半徑較大之陰離子於結晶界面處其存在不 y 晶格脫離而於原子層自表面至往下5層左右之間 、θ成陰離子缺陷。若製造螢光體時於還原性氣體環境中高 …’則氧缺陷數強制性地增加。具有該等陰離子缺陷 57 200919527 之螢光體粒子吸附製造之螢 策元放电官中之殘留氣體。 於螢光體粒子表面之有機廣砂 ' 機矾體會吸收照射至螢光膜之254 nm务外線’因此到達登先㉟2 ¥ + Μ 拉子之紫外線強度相應地減 、 、儿度隨者吸附氣體量之增加而減 小。並無自化合物結晶之表面完全除去陰離子缺陷之方 法。螢光膜劣化之主要原因係有機殘留氣體。殘留氣體可 於製造螢光放電燈時之除氣步驟中除去至可忽視之程度。 即’若改良螢光放電燈管之製程則可忽視殘留氣體之影 :。:有機殘留氣體除去至可忽視程度之本發明之螢光放 包燈官由於可忽視與壽命有關之全部因素,因此可保持初 始亮度ιοο,οοο小時以上。 返回絕緣材料之話題。所使用之絕緣體粒子中必須使 各粒子為獨立之粒子。重要的是不含有凝聚粒子。若粉體 材料中含有0 · 5 μιη以下之粒子,則保存粉體時較小粒子之 接觸面因毛細凝結而吸附空氣中之水’吸附之水與絕緣體 粒子表面之間產生電化學反應,導致粒子產生凝聚。因此, 較理想的是所使用之絕緣體粉中不含〇·5 μηι以下之粒子。 絕緣體粒子之平均粒徑只要於顯微鏡下決定大小之方法為 1 μηι〜10 μιη之間即可。尤其,若使用平均粒徑處於1 μιη 〜7 μιη之間之絕緣體粒子可獲得良好結果。 絕緣體粒子材料若為化學手冊中揭示之無機氧化物則 均可使用。作為該等中較理想之氧化物,有Mg〇、Si02、 A1203、CaO、SrO、BaO、Y203、La203、CaA103、銘酸鹽 與石夕酸鹽、及其錯合物等。除了該等氧化物之外,還有螢 58 200919527Si: The glass tube 9 is sealed and sealed. Heart =: The polarization of the 4 body particles is irrelevant, so there is no special requirement for flat gold. 'But is the workability better when using a material with a high hardness? = The electrode thickness of the metal electrode 21 varies depending on the metal material used. In order to maintain the insulator particles and the manufacturing process, I- 隹 令 易 易 易 易 设定 设定 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 The aspect that must be considered is the adsorption of organic and inorganic gases due to the surface of the worm. If there is a 'adsorption', the lifetime of the fluorescent discharge lamp, especially the luminescence of the glory film, will be weakened by the "body adsorption". Therefore, attention must be paid to the case where the alloy is used. 2 — _. 55 200919527 The diameter of the flat metal electrode 21 varies with the light discharge used, but in a fluorescent discharge tube with an inner diameter of 15 _ or more, a flat plate having a diameter of 1 〇 can be used. The metal electrode 21 is such that the maximum diameter of the flat metal electrode 21 is 1 Λ von 10 mm. When the diameter of the fluorescent discharge tube is between 5 mm and 15 mm, the straight and the metal electrodes are compared. The inner diameter is as small as 2 mm. When the diameter of the tube in the fluorescent discharge tube is 2_~5mm, the inner diameter of the large electrode of the metal electrode is 1 mm. The diameter of the tube inside the discharge tube is 2 mm. When you are in shape, the size of the metal electrode is smaller than the inner diameter by 〇5 mm. When the inside of the fluorescent discharge tube is 9 T, and the S horse is less than 2 mm, the test is done to the flat metal. Electrode 2〗 The work of prostitutes can be used in the same way as the work of the same kind of rod metal electrode. Figure 5 ( A) is an example of a rod-shaped metal. The surface of the rod-shaped metal electrode is coated with an insulator nt & the pole 22 is only squirted by a fusion splicer at the front end of the emet line sealed by the glass, and then the insulator particles are melted, so that it is finer The thickness of the metal rod attached to the metal bar is excellent in workability. The length is at o5mm 5 jobs ~1, the thickness is not limited. Of course, larger or smaller than this cup can also be used as an electrode. The surface of the metal electrode: the surface is a thick chain surface 'so that the insulator particles are easy to adhere to the chemically etched 'but preferably not The rough surface is formed by chemical etching. The surface of X 4 is difficult to adhere to the insulator particles + particles, and the 3 series is smooth, and the particle size of the insulator is slightly smaller than that of the crumb, and the powder is preferably used. The particle size 'and the particle size of the polishing agent. 卞3 value is 1~3 μπι powder 56 200919527 In order to make the insulator particles adhere more firmly to the metal surface, first (4) the surface of the genus is attached to the amorphous powder glass 23, Λ After the hot main horse has a temperature above 1嘁 = '绝 = body particle' And heating again, after the powder glass crucible is smelted: the portion to the room temperature 'insulator particles are firmly followed by the molten powder glass crucible. However, the performance is better if the powder glass is not used. The insulator coated on the metal electrode If the material 4 is an insulator having a dielectric constant ε of 3 to 50, (4) insulator particles can be used. If a dielectric 常 8 is used as an insulating 卩 on the 50 Μ, the ac voltage of the external circuit rises with this:: It The lighting speed of the discharge lamp is slowed down, and the power is also increased, so it is not good. Generally speaking, the evaporation temperature of the inorganic insulating material is also very stable. Therefore, there is no influence on the life of the fluorescent discharge lamp. $,, Deng Guang ^ The positive ions of the official towel do not directly collide with the insulator particles, as shown in Figure 1, and do not collide with the metal cathode of the negative potential. Therefore, there is no sub-existence in the fluorescent lamp s of the present invention due to the influence of the cathode on the life of the fluorescent discharge lamp: 'here', the life of the fluorescent discharge lamp is further described. I. "The other factor determining the fate of the discharge lamp g is the time-lapse of the brightness of the fluorescent film. The published book clearly states that the brightness of the luminescent film deteriorates with time, and is caused by the destruction of the luminescent center of the phosphor. Deterioration, but it is said that the illuminating center of the crystal lattice point is very stable. However, the phosphor particles > s ^, the vicinity of the 1 surface is unstable, and a large number of crystal lattices are generated during manufacturing. In particular, an anion having a large ionic radius has a y lattice detachment at the crystal interface and an anion defect between the atomic layer and the bottom 5 layers, and θ becomes an anion defect. When a phosphor is produced in a reducing gas atmosphere In the middle and high...', the number of oxygen defects is forcibly increased. The residual gas in the fire-emitting element discharger produced by the phosphor particle adsorption of the anion defect 57 200919527. The organic shale on the surface of the phosphor particle The experience absorbs the 254 nm extraneous line that is irradiated to the fluorescent film', so it reaches the first 352 ¥ + Μ 之 之 之 之 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线 紫外线A method of completely removing an anion defect. The main cause of deterioration of a fluorescent film is an organic residual gas. The residual gas can be removed to a negligible degree in a degassing step in the manufacture of a fluorescent discharge lamp. That is, if the fluorescent discharge lamp is improved The process of the tube can ignore the shadow of the residual gas: the organic residual gas is removed to a negligible degree. The fluorescent light-receiving lamp of the present invention can maintain the initial brightness due to neglecting all the factors related to the life, ιοο, οοο Above. Return to the topic of insulating materials. In the insulator particles used, each particle must be an independent particle. It is important that the particles are not contained. If the powder contains 0. 5 μηη or less particles, the powder is preserved. The contact surface of the smaller particles adsorbs the water in the air due to capillary condensation. The electrochemical reaction between the adsorbed water and the surface of the insulator particles causes the particles to agglomerate. Therefore, it is desirable that the insulator powder used does not contain antimony. · Particles below 5 μηι. The average particle size of the insulator particles is determined by the microscope to be 1 μηι~ It can be used between 10 μm, especially if an insulator particle having an average particle diameter of between 1 μm and 7 μm is used. The insulator particle material can be used as the inorganic oxide disclosed in the chemical handbook. The preferred oxides include Mg〇, SiO 2 , A 120 3 , CaO, SrO, BaO, Y203, La203, CaA103, citrate and lysine, and complexes thereof, etc. In addition, there is firefly 58 200919527

光體之基體結晶。螢光體之某& B ®尤粒 < 丞體結晶具有非對稱晶格點, 且具有較高之介電常數,故而有利。可作為絕緣體素材使 用之螢光體粒子’為 Y2〇3、Y2〇2S、YV〇4、Yp〇4、ZnS、The base of the light body crystallizes. Some of the phosphors & B ® granules < steroidal crystals have asymmetric lattice points and have a high dielectric constant, which is advantageous. The phosphor particles 'which can be used as an insulator material' are Y2〇3, Y2〇2S, YV〇4, Yp〇4, ZnS,

ZnO、(Y,Gd)2〇3、(Y,Gd)B〇3、γ(ρ ν)〇4、Lap〇4、以及ZnO, (Y, Gd) 2 〇 3, (Y, Gd) B 〇 3, γ (ρ ν) 〇 4, Lap 〇 4, and

BaMgAl10O17 #。亦可使用於上述螢光體之基體結晶中, 導入作為螢光體之發来中心夕、^ ^九T、之活化劑的螢光體粒子。缺 而’含化學性為活性之S之化合物與Hg蒸氣產生化學反 應而生成HgS (黑色物質),因此無法使用。若粒子表面 層不含S則可使用。所利用之粒子表面要求係化學上與物 :上清潔之表面。㊉了上述化合物以外,眾所周知有介電 常數較大之鈣鈦礦粒子。作為盆 作马其代表者,存有PbZr03、 pbTi〇3、CaTi03、SrTiO、BaMgAl10O17 #. It is also possible to use, in the base crystal of the above-mentioned phosphor, a phosphor particle which is an activator which is a center of the phosphor and which is a center of the phosphor. The compound containing S which is chemically active reacts with Hg vapor to form HgS (black substance), so it cannot be used. It can be used if the particle surface layer does not contain S. The surface of the particles used is chemically compatible with the surface: the surface that is cleaned. In addition to the above compounds, perovskite particles having a large dielectric constant are known. As a representative of pottery, there are PbZr03, pbTi〇3, CaTi03, SrTiO,

BaTl〇3、pbTi〇3 與 pbZr〇3 之 固溶體(PZT)、以及PhT;n ^ 1〇3與CaTi〇3之固溶體等。鈣 鈦礦粒子之介電常數非常大。 ^ 上所述,粒控過大之介電 $數材料之粒子即便穑聚士县4 A , I仗檟來大$之自由電子及離子,亦因鈣 、太石廣粒子之充放電導致外部雷软_夕處& 電路之感應電流的速度變慢而 無法使用。 本發明之新電子源係作A恶 作马螢先放電燈管製造之零件而 處理。藉由實施例,詳έ田勺Λ 方法 、’ D兄月作為零件之新電子源之製作 [實施例1 ] 本發明之電子源之零件伤 淹故ύ ν件係於金屬電極上以適當之厚度 佈、、、邑緣體粒子。由於絕緣 髀私ν 緣體粒子為粉末,因此混合絕緣 體极子與被稱作媒液之社人 w 、’0 口 Wh谷液而製作塗佈液(漿液)。 59 200919527 通常使用之媒液有I i所示之兩種媒液。不論使用哪 液均可獲得相同結果。 μ 媒液A ____ L〜、丄」 乙酸丁酯100 e -------- 硝化纖維素1 0 媒液B ------- & 二甲苯100 g ---- 乙基纖維素2.0 [表2]BaTl〇3, a solid solution of pbTi〇3 and pbZr〇3 (PZT), and a solid solution of PhT; n ^ 1〇3 and CaTi〇3. The dielectric constant of the perovskite particles is very large. ^ As mentioned above, even the particles of the material with a large amount of dielectric control are even free of electrons and ions of the 4 A, I仗槚, and the external electrons, and the external lightning is caused by the charge and discharge of calcium and taishiguang particles. The current induced current of the circuit is slow and cannot be used. The new electron source of the present invention is processed as a part of the manufacture of the A. By way of example, the method of έ田ΛΛ, 'D brothers and months as a new electron source for parts” [Example 1] The parts of the electron source of the present invention are wounded on the metal electrode to be appropriate Thickness cloth, and 邑 体 body particles. Since the insulating ν ν 体 粒子 缘 缘 缘 缘 缘 缘 缘 缘 缘 缘 缘 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 59 200919527 The commonly used media contains two media solutions as shown by I i. The same result can be obtained regardless of which solution is used. μ Media A ____ L~,丄” Butyl Acetate 100 e -------- Nitrocellulose 1 0 Media B ------- & Xylene 100 g ---- Ethyl Cellulose 2.0 [Table 2]

材料 重量混合比(2 ) ----- Y(V,P)〇1:Eu 100 媒液A 150 --—-J 於Ni金屬棒電極選擇Y(v,p)〇4:Eu紅色螢光體粉末作 為絕緣體粒子,並用媒液A製作漿液。纟2表示其混合比 例。用秤準確地秤量表2之材料,充分混合兩者而製作漿 液。將Ni金屬棒電極浸潰於漿液中,並立即拉出,則^ =屬棒電極表面上附著有漿液。所附著之絕緣體粒子層數 藉由改變表2所示之混合比例而進行調節。拉出之妬金 屬棒電極上之絕緣體粒子層被漿液浸濕,因此吹5〇t左右 之熱風而進行乾燥。乾燥後,將電極置於無蓋爐中以它 加熱10〜30分鐘。加熱使有機物氧化並形成水蒸氣與二 氧化碳氣體擴散至空氣中。當Ni金屬棒電極之溫度降= 室溫時,獲得塗佈有y(v,p)〇4:Eu紅色螢光體之白色粉末 之Ni金屬棒電極。塗佈有該白色粉末之犯金屬棒電極可 60 200919527 作為CCFL電極而使用。 [實施例2] 於Nl-Cr圓盤狀金屬電極選擇Y2〇3:Eu紅色螢光體粉 末作為絕緣體粒子,並選擇媒液B而混合成襞液。表3 ^ 不製作漿液時之混合比例。用秤準確地秤量表3之材料, 充分混合兩者而製作毁液。將Ni_Cr盤狀金屬電極浸潰於 該漿液後拉出’則聚液附著於犯心盤狀金屬電極之兩表 面。所附著之絕緣體粒子層數可藉由改變纟3戶斤示之混合 比例而進行調節。拉出之Ni_Cr圓盤狀金屬電極上之絕緣 體粒子層破製液浸濕’因此吹微熱風而使其乾燥。乾焊德 將電極置入盔蓋燐中以, λ 乾躲後, m 5〇C加熱10〜30分鐘,則有機物 :由:化而分解並形成水蒸氣與二氧化碳氣體擴散至空氣 佑右I Mr圓盤狀金屬電極之溫度降為室溫時,獲得塗 +極0:EU紅色發光體之白色粉末之Ni_Cr圓盤狀金屬 二之:有該白色粉末盤狀金屬電極可作為 nr L·疋電極而使用。Material weight mixing ratio (2) ----- Y(V,P)〇1:Eu 100 medium A 150 ----J at Ni metal rod electrode selection Y(v,p)〇4:Eu red The light body powder was used as an insulator particle, and a slurry was prepared using the vehicle A.纟2 indicates the mixing ratio. Use the scale to accurately weigh the material of Table 2 and mix the two to make a slurry. The Ni metal rod electrode is immersed in the slurry and immediately pulled out, and then the slurry is attached to the surface of the rod electrode. The number of layers of the insulator particles to be attached was adjusted by changing the mixing ratio shown in Table 2. The layer of the insulator particles on the metal rod electrode that has been pulled out is wetted by the slurry, so that hot air of about 5 Torr is blown and dried. After drying, the electrode was placed in a capless oven and heated for 10 to 30 minutes. Heating causes the organic matter to oxidize and form water vapor and carbon dioxide gas to diffuse into the air. When the temperature of the Ni metal bar electrode was lowered to room temperature, a Ni metal bar electrode coated with a white powder of y(v,p)〇4:Eu red phosphor was obtained. The metal rod electrode coated with the white powder can be used as a CCFL electrode. [Example 2] Y2〇3:Eu red phosphor powder was selected as an insulator particle on a Nl-Cr disc-shaped metal electrode, and the vehicle B was selected to be mixed into a mash. Table 3 ^ Mixing ratio when no slurry is prepared. Use the scale to accurately weigh the material of Table 3 and mix the two to make a destructive solution. The Ni_Cr disc-shaped metal electrode was immersed in the slurry and pulled out, and the poly-liquid was attached to both surfaces of the disc-shaped metal electrode. The number of layers of insulator particles attached can be adjusted by changing the mixing ratio of 纟3. The insulating particle layer on the pulled-out Ni_Cr disc-shaped metal electrode is wetted by the breaking liquid, so that it is dried by blowing a slight hot air. Dry welding puts the electrode into the helmet cover, λ, after hiding, m 5〇C heating for 10~30 minutes, then the organic matter: decomposes by: and forms water vapor and carbon dioxide gas to diffuse to the air. When the temperature of the disc-shaped metal electrode is lowered to room temperature, the Ni_Cr disc-shaped metal of the white powder coated with the +0:EU red illuminant is obtained: the white powder disc metal electrode can be used as the nr L·疋 electrode And use.

[實施例3J 於抝金屬棒電極選擇Ba〇絕緣體粒子與媒液B,而 61 200919527 製作成漿液。表4表示其混合比例。製造步驟與實施例丄 及實施例2中所述之步驟相同,因此省略說明。塗佈有該 白色粉末之Ni金屬棒電極可作為CCFLi電極而使用。[Example 3J Ba 〇 insulator particles and vehicle B were selected from the ruthenium metal rod electrode, and 61 200919527 was prepared into a slurry. Table 4 shows the mixing ratio thereof. The manufacturing steps are the same as those in the embodiment 丄 and the second embodiment, and thus the description thereof will be omitted. A Ni metal rod electrode coated with the white powder can be used as a CCFLi electrode.

---Li_4] 材料 重量混合比(g) 100 ---— BaO ---— 媒液B 150 ---—J---Li_4] Material Weight mixing ratio (g) 100 --- — BaO ---— Medium liquid B 150 ---—J

[實施例4 ] 於Ni杯狀電極選擇BaMgAliG〇i7絕緣體粒子與媒液 A ’而製作成漿液。表5表示其混合比例。製造步驟與實 施例1及實施2所述之步驟相同,因此省略說明。塗佈 有該白色粉末之Ni杯狀電極可作為C(:FL之電極而使用。 -_ϋ 5] 材料 ------- 重量混合比 BaMgAlin〇_ 100 媒液A 150 化物之粉末, 因此雖省略該 即便使用實施例中未示之氧化物、多氧 亦可獲得與實施例2〜4所示之同樣結果, 等實施例之上述敍述’但亦屬於本發明。 [實施例5] 實施例 將敍述藉由本發明 之電子源取代HCFL中廣 62 200919527 泛使用之熱陰極時,可解決哪此 ^ 1二問碭。世界上使用最廣泛 之電極係熱陰極。熱陰極係用氧 ,〇00〇Γ,^此 用虱化鋇(BaO)等覆蓋加熱 至 〇左右之鎢絲而成之陰極。白 ^ 自配置於加熱BaO層之 表上層:Ba向真空中發射電子。當操作咖時,電極 附近之官壁溫度高於其他部分之 ^ s 土 /皿度。官内控小於1 〇 mm之省電型HCFL加埶至人丰釭、“ 。 ,、 手無法觸摸之高溫(5 0 °C〜 6〇㈡。電極周邊之放電管之管壁溫度上升之原因不明, 因此無法採取對策。根據本發明者之研究,陰極表面受到 不可避免地形成之表面結合電子SBE(iQ5v/em)之覆蓋, 為超越SBE之負電場而自陰極取出電子,必須向陰極施加 1〇5 WCm以上之陽極電塵。自陰極取出之電子當然係具有 V/cm α上之能量的高速電+。進入充滿氣體原子之氣 體空間之高速電子藉由陰極與陽極間之較強之一方向的電 场,電子向一方6义、隹 . 方向則進。向一方向前進之高速電子,不激 毛’花體原子而於氣體空間中通過一定距離後,與氣體原子 非彈性碰撞,佶@ μ s ^ 使乳體原子離子化而分離為電子與離子。每 人離子化時皆因氣體原子之熵之變化而產生熱。該熱陰極 周邊之較廣範圍内放電燈之管壁溫度升高。高速電子一面 :複’、氣體原子進行非彈性碰撞-面-點點地損失能量, =陰極遷移一定距離之處’遷移電子之能量減少至激發 乱版原子之能量。電子激發氣體原子時並不伴隨熱之產 =。:此,以後之管軸長度上管壁溫度固定。陰極附近之 s 土 /皿度上升係hcfl之第一問題。該問題表示如下 即不參與螢夯播+ μ十 Λ 先放-¾燈管之主放電之氣體原子產生離 63 200919527 此係對勞光放電管之點亮無用之能量消耗。當電子 採用本發明之電子调丰 《电子糾,HCFL成為CCFL,自電子源 之電子之能量接近零速度,並不引起氣體原子之離子化。 因此,螢光放電燈管之點亮中螢光放電管端周邊之溫度並 =上升因此,使用本發明之電子源之CCFL之點亮電力, 較之習知HCFL盘CCFI签本妓不败奸 少。 螢先放笔燈官之點亮電力顯著減 第問題係陰極财面產生之較大之陰極電壓降低。榮 光放電燈之全部能量之·〜娜之能量因陰極電壓降低 而損失掉。於CCFL中亦產生陰極電壓降低,因此通常認 為亚非熱電子陰極所固有。如上所述,將電子直接取出至 真空中之,極被不可避免地形成之較強負電荷之觀(1〇5 V/cm )覆蓋。為自陰極取出電子,必須向陰極施加i〇5 以上之陽極電壓。所敌ψ φ 4 所取出之電子猎由陰極與陽極間之較強 之一方向之電場,而向一古— a 4 丄 门方向則進。向一方向前進之高速 電子’不激發乳體原子而是通過氣體空間之過程中,與氣 體原子進行非彈性碰撞’使氣體原子產生離子化而分離為 電子與離子。高速電子一面重複與氣體原子進行非彈性碰 撞-面-點點地損失能量’於自陰極遷移_定距離之處, 遷移電子之能量減少為激發氣體原子之能量之水準。如上 所述’藉由電子激發氣體原子時並不伴隨熱之產生。參與 以後之放電之電子由呈古私& a _ /、有激鲞乳體原子之水準之能量的電 子行為決定,成為不喹险搞μ犯Λ、 又U極上形成之SBE之影響的放電。 該放電為陽極區放雷。差 產生陰極電壓降低之範圍,與陰極 200919527 表面至開始有陽極區之間一致。 於該範圍内’混有自陰極取 一 ?取出之根據場所而能量值不 同之咼速電子、藉由氣體原子 〈離子化而產生之自由離子 與自由電子,但各荷電粒子 <刀帝並不均勻,根據距陰極 面之距離而不規則變化。該變彳卜& + > 语工々At旦 荔又化中亦存在具有可激發氣體 原子之月匕里之電子’雖激获畜挪7 敦發孔體原子而使之發光,但該電 子之數量較少。其他具有能| ^ ^ 里之電子與離子不使氣體原子 、, 里疋個因素係電子與離子之質量 差。離子化而產生之離子盥雷早 卞/、罨子错由陰極與陽極之電場, 而於電場中遷移,但遷移 秒迷度遷移方向、遷移距離差異 較大’因此於氣體空間中不均勺 、 τ小岣勺地分布。偏積分布之離子 之電場(與陽極電場反方向) 乃同)作用於輕量且運動之電子。 月b里值不同之尚速電子、偏積之雜工 . 丁彳杨檟之離子、根據電場強度而易 運動之電子之複雜分布,傕今笙 ^ 便及專何電粒子無法均勻分布, 觀察到據此而產生之線狀發光條紋。陰極電壓降低之產生 範圍相當於線狀發光條紋之產生_。若使用習知之陰極 則於陰極面上不可避免油连吐 產生SBE,因此陰極電壓降低亦 不可避免地產生。藉由本發明之電子源替換習知之陰極電 才°卩可自勞光放電燈中完全消除陰極電壓降低。其結果 為,使用本發明之電子源之ΓΓΡΤ 电于原之CCFL之點亮耗電,相比於習 知產品減少約40%,因此斟搭+立一 。 U此對%楗π染問題作出較大貢獻。 第三㈣係螢光放電燈之點亮壽命。使用之登 光放電燈之壽命縮短之原因在於,電極金屬周邊產生之陽 離子被陰極電位吸弓卜與陰極進行彈性碰撞,將陰極金屬 65 200919527 之局部加熱至高溫,於此蒸發出金屬蒸氣。若採用本發明 之電子源,放電氣體内並無曝露於陽離子之金屬。因此, 可極大延長壽命。 以上為止說明之發明之詳細内容,係螢光放電燈管之 電子供給源之改良。若使用本發明之電子源,gll ώ 电于/原則可取出初 &接、$之電子至放電路中。 τ 具結果為,可闡明習知之餐 光放電燈管之研究中難u Μ 雷之現象。該等現㈣螢光放 點Γ 亮開始時間之延遲、以及陽極區收納入咖 荷電狀=等問題之原因在於構成螢光膜之各螢光體粒子之 ‘:至今為止無人可理解螢光體粒子之物性,因此 热法闡明該尊鬥 能關於放雷/下詳細說明各螢光體粒子之荷電狀 心關方、放電電子之狀態。 圖6中圖解制· Τ?Τ这& 之4錄# Ε内之氣體放電產生影響之螢光膜 之4種何電狀態鱼 # ^ ^ 電子軌道之變化。圖ό (A)係於螢光放 冤燈官玻螭9 、 』面塗佈市售放電燈用(PL)螢光體粉 叩风I堂光膜24沾 白制、& B 、 的局部圖。市售PL用螢光體之全體粒子 自衣&日f開始便 r ,, τ 示待求久内部極化(PIP) ,PIP之負電荷 k、、勺丄5 〇 v )之+ PL螢光體而製作'場到達粒子外。理所當然地’使用市售 荷。當來自電子〉之螢光膜24之上表面覆蓋有PIP之負電 受到ριρ 振之初速接近零之電子e接近時,電子e 僅如此。場之靜電斥力,無法進人榮光膜上。不僅 充滿負電場間因填充氣體原子之最外殼之外殼電子而 電。即氣體放/ 6 #無法進入氣體空間。氣體原子不放 从电不點亮。 66 200919527 可進入螢光放電營办 子。習知之访^ 巾之風體工間之電子僅係高能量電 “之放電燈管係自陰極取出高能量電子, 可進入氣體空間,但高能量:子 傳導,從而盔法倭#上進仃表面 體電始動。欲使螢光放電燈管之氣 必須於氣體放電前先向榮光膜上 : :使用之高能量電子單向前進,散射電子而無法克=光 膜之附貞電場。若於榮光膜周邊設置傳導體,並向其施 加300 V左右之正電壓,則根據經驗會發現放電燈之 始動之現象。特殊CRT開發者亦根據經驗而知悉向 =施::以上之正電場,則發光膜…榮光: 4。螢切之PIP之存在及其消除方法可實用於乾式影 印機及電子照片之感光板。螢光體材料亦可用作感光板伸 性能較低’因此無法實用化。榮光膜《ριρ亦利用於特殊 CRT(儲存管)。作為螢光放電燈管之放電之始動方法, 螢光放電燈管之技術者根據經驗發現了螢光膜之ριρ之消 除法’但因無法理解PIP自身之存在,因此不明盆動作原 理。受到因消除HP而隨之產生之諸問題之除去的困擾’,、 根據經驗發現之方法成為公司内部之機密。本發明者藉由 選擇榮光體而完全解決PIP之問題。若控制螢光體之^類 及製作方法,則可製作螢光膜中無PIP之螢光體。 圖6(B)表示對使用螢光體粒子不具有pip之螢光體 衣作成之螢光膜25上導入初速接近零之電子時,螢光膜 表面傳導電子之狀態。作為無ριρ之螢光體,係於Μ V以 下之低電子束之照射下發光之CL螢光體。代表之榮光體 67 200919527 m白綠色光或者於39。一有峰值且發出尖 狀先的氧化鋅(zn〇)勞光體、不使用鋼作為炼劑而 之發出藍色光之硫化辞(zns:Ag:cl) f光體、發出綠色光 之硫化鋅(zns:cu:A1)螢光體、以及特殊條件下製作之 Mg〇。當照射至螢光膜之電子能量上升4 i2〇 v時另外 有藉由氧化辞過量而製造之石夕酸辞(Zn2Si〇4:Mn)榮光體、 :表面進行化學蝕刻而製作之硫酸釔或丁” 螢光體、以及不使用㈣而製作之氧化紀(¥2〇過或 勞光體等。圖6⑻之示例表示以Zn◦螢光體製作榮光 膜之情形。因不存在pip g雪,, 口个仔在負電场,故進入至螢光膜表面之 低速電子容易進入螢光膜上,i受位於放電管之另一端之 積聚離子8之電場加速,於螢光膜表面上往單向前進,到 達積聚離子8並藉由與累計離子8再結合而形成氣體原 子。在通常之FL管(管長50 cm)往單向前進之電子軌道 上=在氣體原子之機率為可計算。其值為1〇_6,可認為單 向前進之加速電子肖氣體原子碰撞之概率為零。並無表面 傳導之電子引起之氣體原子發光。進而,並無直接測定於 螢光臈上進行表面傳導之電子的方法。由於可間接地於設 置於放電管外壁之導體中檢測出較大之感應電流,因此可 理解有流過較大之表面傳導電流。可觀測到以下事實。ho 螢光膜亚非為凡全之平滑面,因此於螢光膜表面上往單向 前進之加速電子碰撞螢光膜之突起部分後,該部分之螢光 版^進行CL發光。CL發光雖微弱,但可確認往單向前進 之加速電子之存在。若螢光膜為完全之平滑面,則無法檢 68 200919527 測出電子運動。若加速電子之檢測使用HjU螢光體(於 V之電子照射下發光)之螢光膜,則可觀測到以下事 實。Y2〇3:Eu螢光體中少數螢光體粒子存在缺陷,藉由該 粒子之負電荷,使往單向前進之電子執道被彎曲,因表面 傳導而加速之電子進入充滿氣體原子之氣體空間中。軌道 被彎向氣體空間之加速電子與氣體空間之氣體原子進行非 弹性碰撞。因非彈性碰撞而獲得能量之氣體原子(Hg)受 到激發出紫外光。發出之紫外線照射至螢光膜,螢光 *、進行PL發光。因非彈性碰撞而使軌道彎曲之電子停留 於,體空間中,並受施加於氣體空間之高頻電場加速,激 2乳體空間之其他氣體原子。於氣體空間中產生該重複, ::原子開始放電。榮光膜中所含之、單向前進之電子軌 曲之粒子數較少,因此PL發光強度較低,但相比於ZnO 螢光膜之情形已有較多#光體粒子進# pL發光。如此, #觀$ PIj發光可明確檢測出單向前進之加速電子、及 加=電子之軌道彎向氣體空間而激發氣體原子之方法。使 亦:t彔色光之螢光體Zn2Si〇4:Mn或紅色螢光體Y2〇2S:Eu =Μ出相同之結果。然⑥’單獨以該等螢光體製作之 =膜之發光,相比於實用水準之發光強度相#低。上述 :驗對於重視實務之放電燈技術者而纟,因低亮度而被忽 〇 会p -y» ’、,如上所述錯過了提供非常重要之科學資訊之來 子傳導FTP之螢光膜容易允許低速電子於螢光膜上進行電 導,從而加速電子(誘因之作用),但對於螢光放電 69 200919527 燈官中之氣體激發並無直接貢獻。若螢光膜中存在帶負電 之螢光體粒子,則加速電子之軌道於帶負電之螢光體粒子 處被彎曲而進入氣體空間,並激發氣體原子。經激發之氣 體原子發出紫外光。非彈性碰撞之電子停留於氣體空間 内,受高頻電場加速,並激發其他氣體原子。藉由該重複 而使氣體放電始動。此係使實用螢光放電燈管之氣體放電 瞬時點亮之機制。該觀察對於科學解析螢光放電燈管而言 係一非常重要之發現。 圖6(C)中為確認上述發現,於螢光放電燈管之螢光 膜末端之小面積上塗佈Zn〇螢光體粒子25 (無ριρ),剩 餘之大面積上由排列有市售PL螢光體粒子之螢光膜24(有 IP)覆蓋螢光放電管内壁面。實驗性地首先於玻璃内壁面 f佈市售PL螢光體粒子,乾燥後焚化結合劑。用柔軟之 布拭去玻璃端之螢光膜後,於擦拭後之玻璃面上塗佈Zn〇 螢光體粒子25。進行乾燥後焚化結合劑。藉由該方法而可 製作圖6(C)之螢光膜。 ;X螢光膜上3又置本發明之電子源,並導入初速接近 “電子電子於ZnO螢光體粒子25之排列處加速,且 /、有可政發氣體原子之能量。加速電子無法進入市售螢光 膜24上,而是彎曲電子執道進入氣體空間中。進入氣體 空間之電子與氣體原子進行非彈性碰撞,激發氣體原子而 使虱體空間之放電點亮。該現象係螢光放電燈管之氣體放 毛之瞬時點亮。非彈性碰撞之電子藉由氣體空間之高頻 波自153頻電場獲取適當之能量,並藉由非彈性碰撞而激 200919527 毛下氣體原子。與傳播過放電路之高頻波共振之電子一 面藉由該重複而激發氣體原+,—面於放電管中遷移至管 端:最後與離子結合而消失。當人們用眼睛觀察於勞光放 電S中與阿頻波共振而遷移之電子時,會認為螢光放電燈 g係以均勻強度發光之螢光膜。然而,遺漏了重要之事實。 於放電路中遷移之電子藉由加速而具有能量,並與氣 7原子進行非彈性碰撞。非彈性碰撞之電子之軌道方向為 隨機。向隨機方向散射之電子中存有具有接近營光膜之機 會之電子,但螢光膜中存在PIP26之負電荷,因此該電子 …、法接近螢光膜,而是返回陽極區内。與高頻波共振之使 氣體原子發光之電子之活動範圍並非為氣體放電管之整個 二間,而疋限定於與螢光膜保持固定距離之放電管之中央 之氣體空間内。該空間係收納於PIP鞘26之陽極區。氣體 原子之電性為中性,不受電場及電荷之影響,於放電管内 以均勻濃度分布。於PIP鞘26中收納之陽極區與螢光膜之 ^間,氣體原子(未激發之氣體原子)以均勻濃度分布。若 2陽極區發出之光係藉由自氣體原子之激發能階向基態能 P白之电子過渡而產生’則允許發出之光被氣體原子吸收。 該情形時陽極區内發出之光被介於陽極區與螢光膜之間之 氣體原子吸收,到達螢光膜之光係吸收後之殘留光。於螢 光放電燈之情形時,利用低壓Hg蒸氣之發光。發光係自 Hg之激發能階6p向基態能階、之電子遷移,因此受到陽 極區與螢光膜之間存在之Hg蒸氣吸收。光係不帶電荷之 粒子,因此不文PIP之影響,僅有被陽極區與螢光膜之間 71 200919527 存在之Hg蒸氣吸收後殘留之光到達螢光媒。螢光體粒子 係具有較大之光折射率夕私2 ^ 钾耵羊之粒子,因此紫外線之一部分進入 排列於榮光膜表層之榮光體粒子,直接被發光中心吸收而 發出可見光。由表層粒子反射之紫外線成為散射光,並進 入營光膜之深部之螢光體粒^發光。為增加f光放電燈 ^中料螢光膜之紫外線量,較佳為螢光膜不被ριρ負電 何覆蓋。即,較佳為不形成PIP鞘。 若向靠近螢光膜配置之導體施加正電 PIP電荷消失。若期望立社 】堂尤膜之 八果為,PIP鞘20消失,陽極區 擴展至螢光膜,增加亮度,但並非如此。不存纟PIP之蝥 :膜等同於圖6⑻所示之螢光膜25,電子不進入負電 场之氣體空間5而是於^签本睹主工,^ 疋於螢先膜表面上進行單向前進之表面 傳導,螢光放電燈管之亮度顯著降低。高亮度發光之勞光 膜必須具有藉由於螢光膜上表面傳導而加速電子之功能、 與使上述電子軌道向氣體空間偏折之ριρ榮光體粒子此兩 者之螢光體粒子之組合。實務上力ριρ電荷無法作用之處 設置陽極區即可,允許抑原子之自行吸收,實用管徑為25 mm以上之較大之螢光放電燈,並根據經驗求出最佳條件。 此係習知之螢光放電燈,即允許於陽極區内Hg發出之254 麵紫外線之自行吸收,將存在發光飽和現象之榮光放電燈 實用化。 根據圖5之結果’如圖6 (D)所示,於玻璃管内面交 替排列具有PIP之市售PL營光體24以及無PIP之低電壓 CL螢光體25。可知ριρ26之作用大幅度降低,氣體放電 72 200919527 之始動較快,且陽極區擴展導致亮度上升。此處必須選擇 低電壓CL螢光體25。低電壓CL發光體25之替代物已於 上述。並非該等螢光體中之任一者皆可使用。市售之該等 螢光體中’謂表面處理而於表面附著有絕緣體之微細粒 子。於其他情形時,螢光體製造時之處理不充分,殘留物 殘留於粒子表面。藉由散射而自陽極區照射至螢光體粒子 之電子,進入螢光體粒子内,並自榮光體粒子向真空中發 射二次電子。此時螢光體粒子中殘留電洞。該電洞盥二·欠 電子於真空中結合,藉由與金屬陰極之情形相同之機制, 於粒子表面形成SBE。若有附著雜質,則於該雜質之表面 上亦形成咖心螢光體粒子之發光係藉由電子之射入 而於螢光體粒子内產生大量電洞與電子,該等電洞與電子 於發光甲心再結合而發光。若CL螢光體粒子之表面潔淨, 貝J CL·螢光體粒子之表面之^ ^ ^ ^ 電洞。失去對象之真空中之電子成為自由電 子,破加速並使電子軌道彎向陽極區’有助於放電。問題 在:附著於粒子表面之雜質上所產生之觀。其具有與^ 作用。困難在於無法消除雜質上之SBE。因該理由, 低%*屢CL螢井·_夕样、秤# ·τ ㈣甚重要。最可靠之低錢CL螢光 勞光體。此處對CL營光體之亮度大於PL勞光 加以說明。進入#光體粒子内之ι個射入電子所 /成之笔子與電洞對數 性散射之數量(約_個)。另::,:格進订非彈 中-個光子僅可激發一個發光/一方面,PL發光體粒子 "们發先中心。此係CL螢光體明亮 73 200919527 之理由。 使PL螢光體24與低電壓cl螢光體25於螢光放電燈 管之内壁面鄰接而製造螢光膜,係最難之工作。根據出版 論文、Journal Physics D Applied Physics, 32, ( 1999 ), pp5 13-5 17 (非專利文獻6) ,fl之最佳螢光膜厚為3層 之螢光體粒子。照射至該螢光膜之電子可進入之粒子,僅 係排列於最上層之粒子’紫外線不受粒子之荷電之影響, 而進入螢光膜中。以粒子層數來表示進入深度時為3層。 根據該理由’於玻璃管内壁面塗佈3層之市售螢光體粒子 24 ’乾燥後以散布於市售螢光體層24上之方式塗佈低電 壓CL螢光體25,則可製造本發明之螢光膜。圖7(A)表 示如此製作之螢光膜之示意圖。 分兩次塗佈螢光膜,導致作業步驟複雜。設計一種對 螢光體漿液進行一次塗佈便製作出螢光膜之方法。市售pL 赏光體之平均粒徑為4 μιη。低電壓CL螢光體之粒徑為2 μ以重i比PL螢光體:CL螢光體=7:3之比例,秤量粒 /不同之兩種螢光體粉,將秤量粉體置入混合瓶中,並混 合均勻,製作螢光體塗佈液並將其塗佈於放電管玻璃内壁 田塗佈液未乾燥時,於接近玻璃管壁之處選擇性地聚 二車乂大之PL螢光體粒子24,並於螢光膜之表面聚集大量 車:小之CL螢光體粒子25,因此獲得圖7 ( b )所示之榮光 ,使用圖7 ( B )之螢光膜製作螢光放電燈管,則位於表 =之CL螢光體粒子並不形成SM,因此陽極區内具有 南能量之電子到達CL帛光體粒子。其結果為,陽極區靠 74 200919527 近螢光膜並發出紫外線。該紫外線因陽極區與螢光膜之間 並未有未激發之Hg原子,而使得大多數紫外線射入pL螢 光體層中。其結果為,螢光膜之PL強度增加。此處當PL 螢光體之平均粒徑為4 μηι時,使用之CL螢光體粒子之大 小的平均值為1 μηι〜3 μηι,則可獲得良好之結果。該粒徑 Ik PL螢光體之粒徑而改變。要注意之事項係當螢光體 粒子較小、為丨μιη以下時,粒子不於螢光膜之表面排列, 而是於螢光膜之乾燥時聚集於螢光膜之底部,〇1^螢光體粒 子之效果變小。以下使用實施例對螢光膜進行更詳細之說 明。 [實施例6] 對混合有本發明之低電壓發光CL螢光體之勞光膜之 例進行s兒明。螢光膜係混合表6所示之螢光體粉而製作。 作為性能良好之低電壓CL螢光體,存有ZnS系螢光體, 但基體結晶之硫S於放電中與Hg蒸氣產生化學反應而形 成HgS,因此避免使用zns系螢光體。 秤量表6之各螢光體粉之重量,並將其置入混合瓶, 充刀/昆合所秤量之螢光體粉。於該混合粉體中添加丨5 〇克 之媒液A ’進行攪拌使得螢光體粒子充分分散於漿液中。 將逢光體漿液導入外徑5 mm之玻璃管内,放置短暫時間 後’自玻璃管内除去漿液,則玻璃内壁面上附著螢光體粒 子’武光膜被塗佈於玻璃管内壁面。對勞光膜進行熱風乾 燦後’以600°C於無蓋爐中加熱30分鐘,藉由熱分解而使 營光膜内之有機結合劑成為水蒸氣與二氧化碳氣體並自管 75 200919527 内除去,則玻璃管壁上殘留僅由螢光體粒子構成之榮光 膜。藉由柔軟之布擦拭位於玻璃管壁端之螢光膜。於擦拭 之玻璃^之。卩位,插入貫施例4與貫施例5中之任一電極。 其中一管端藉由熔融玻璃管而密封電極。對另一管端之玻 璃管略微加以熔融而使管徑變細。於變細之管徑頂端設置 Hg汞齊與Ba集氣器後,將開口之小玻璃管2〇連接於排 氣裝置,使用真空泵除去玻璃管内之空氣。除設置有 水>=i M Ba集氣器之玻璃管之部位以外,將玻璃管全體置 入爐内,加熱至500。〇左右使玻璃管内之材料除氣。若除 氣步驟結束,則使溫度降低至接近室溫。其後略微加熱Hg 汞齊與Ba集氣器,進行自該等之氣體排出。用泵進行排[Example 4] A BaMgAliG〇i7 insulator particle and a vehicle A' were selected from a Ni cup electrode to prepare a slurry. Table 5 shows the mixing ratio thereof. The manufacturing steps are the same as those described in the first embodiment and the second embodiment, and thus the description thereof will be omitted. The Ni cup electrode coated with the white powder can be used as the electrode of C (:FL. -_ϋ 5) Material ------- a weight mixing ratio of BaMgAlin〇_100 A liquid of A medium, therefore Although the same results as those shown in Examples 2 to 4 can be obtained by using oxides and polyoxygens which are not shown in the examples, the above description of the examples is also included in the present invention. [Example 5] For example, when the hot cathode of the HCFL Zhongguang 62 200919527 is replaced by the electron source of the present invention, it can be solved which is the most widely used electrode type hot cathode in the world. The hot cathode system uses oxygen, 〇 00〇Γ,^This is a cathode formed by heating a tungsten wire to the left and right sides of the crucible with BaO. The white is self-disposed on the upper surface of the heated BaO layer: Ba emits electrons into the vacuum. The temperature of the official wall near the electrode is higher than that of the other parts. The power-saving HCFL with an internal control of less than 1 〇mm is added to the high temperature (5 ° °, the hand can not touch) C~6〇(2). The reason why the temperature of the tube wall around the electrode rises is not Therefore, no countermeasure can be taken. According to the study of the present inventors, the surface of the cathode is covered by the inevitably formed surface-bound electron SBE (iQ5v/em), and electrons are taken out from the cathode to exceed the negative electric field of the SBE, and it is necessary to apply 1 to the cathode.阳极5 WCm or more of anode electric dust. The electrons taken out from the cathode are of course high-speed electricity with energy of V/cm α. The high-speed electrons entering the gas space filled with gas atoms are one of the stronger between the cathode and the anode. In the direction of the electric field, the electrons move toward one side, and the direction is advanced. The high-speed electrons that advance in one direction do not provoke the 'flower body atoms and pass through a certain distance in the gas space, and collide with the gas atoms inelastically. @ μ s ^ ionizes the atom of the milk and separates it into electrons and ions. Each person ionizes heat due to the change of the entropy of the gas atom. The temperature of the wall of the discharge lamp in the wider range around the hot cathode rises. High. High-speed electronic side: complex ', gas atoms undergo inelastic collision - face-to-point loss of energy, = cathode moves a certain distance, 'the energy of migration electrons is reduced to stimulate the disorder The energy of the electrons. The electrons excite the gas atoms without accompanying the heat production. This: The temperature of the tube wall is fixed at the length of the tube axis in the future. The first problem of the s soil/span rise hcfl near the cathode is the first problem. The following is the gas atom generated by the main discharge of the 夯 夯 μ μ μ μ μ 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 Feng "Electronic correction, HCFL becomes CCFL, the energy of electrons from the electron source is close to zero speed, and does not cause ionization of gas atoms. Therefore, the temperature around the end of the fluorescent discharge tube in the lighting of the fluorescent discharge lamp = Therefore, the lighting power of the CCFL using the electron source of the present invention is less than that of the conventional HCFL disk CCFI. The lighting power of the first light bulb is significantly reduced. The first problem is that the cathode voltage generated by the cathode is reduced. The energy of all the energy of the singer discharge lamp is lost due to the decrease in the cathode voltage. Cathode voltage drops also occur in CCFLs and are therefore generally considered to be inherent in sub-thermal electronic cathodes. As described above, electrons are directly taken out into a vacuum, and are extremely covered by a view of a strong negative charge (1〇5 V/cm) which is inevitably formed. In order to take out electrons from the cathode, it is necessary to apply an anode voltage of i 〇 5 or more to the cathode. The electrons taken by the enemy φ 4 are strobed by an electric field in one of the stronger directions between the cathode and the anode, and proceed toward the direction of an ancient-a 4 gate. The high-speed electrons advancing in one direction 'inelastic collision with gas atoms during the process of passing through the gas space without exciting the emulsion atoms' cause the gas atoms to be ionized and separated into electrons and ions. The high-speed electrons repeat the inelastic collision with the gas atoms - the energy loss from the surface-points. At the distance from the cathode to the fixed distance, the energy of the transferred electrons is reduced to the level of the energy of the excited gas atoms. As described above, the generation of heat is not accompanied by the excitation of gas atoms by electrons. The electrons participating in the subsequent discharge are determined by the electronic behavior of the energy of the ancient milk & a _ /, which has the level of the atomic state of the milk, and becomes the discharge of the effect of the SBE which is not smashed and smashed on the U pole. . This discharge is the release of the anode region. The difference in the range of cathode voltage drop is consistent with the surface of the cathode 200919527 to the beginning of the anode region. Within this range, 'mixed with one from the cathode? Idle electrons with different energy values according to the location, free ions and free electrons generated by ionization of gas atoms, but the charged particles are not uniform, and are irregular according to the distance from the cathode surface. Variety. The 彳 && + > 语 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 々 The number of electrons is small. Other electrons and ions with energy | ^ ^ do not make gas atoms, and the factors in the electrons are poor. Ionization produces ion 盥 卞 卞 罨 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 τ is distributed in small spoons. The electric field of the ion distributed in the opposite direction (in the opposite direction to the anode electric field) acts on the light and moving electrons. In the month b, the values of the fast-moving electrons and the partial product are different. The complex distribution of the electrons that are easy to move according to the electric field strength, the ions of the 彳 彳 彳 傕 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及And the resulting linear illuminating stripes. The range in which the cathode voltage is lowered is equivalent to the generation of linear luminescent stripes. If a conventional cathode is used, SBE is unavoidably generated on the cathode surface, so that a decrease in the cathode voltage is inevitable. The cathode voltage reduction can be completely eliminated from the conventional discharge lamp by replacing the conventional cathode electric power with the electron source of the present invention. As a result, the power consumption of the original CCFL using the electron source of the present invention is reduced by about 40% compared with the conventional product, so that it is erected. U makes a big contribution to the problem of %楗π dyeing. The third (four) is the lighting life of the fluorescent discharge lamp. The reason why the life of the discharge lamp used is shortened is that the positive ions generated around the electrode metal are elastically collided with the cathode by the cathode potential, and the portion of the cathode metal 65 200919527 is heated to a high temperature, thereby evaporating the metal vapor. If the electron source of the present invention is used, there is no metal exposed to the cation in the discharge gas. Therefore, life can be greatly extended. The details of the invention described above are improvements in the electron supply source of the fluorescent discharge lamp. If the electron source of the present invention is used, gll ώ can be used to extract the initial & The result of τ is that it can clarify the phenomenon that it is difficult to find the light in the study of light discharge lamps. The reason for the delay in the start time of the current (4) fluorescent spot, the storage time of the anode area, and the like is that the phosphor particles constituting the fluorescent film are: The physical properties of the particles, so the thermal method clarifies that the respect can explain the state of the charged center of the phosphor particles and the state of the discharge electrons. In Fig. 6, the four types of the fluorescent film of the fluorescent film which affects the gas discharge in the Ε Τ Τ & &## ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ Figure ό (A) is attached to the fluorescent lamp 官 官 、 、 、 、 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市 市Figure. The whole particle of the commercially available PL phosphor is self-dressing & day f, then r, τ shows the long-term internal polarization (PIP), the negative charge of PIP, the scoop 丄5 〇v) + PL The light body produces a 'field that reaches the outside of the particle. It is a matter of course to use a commercial sale. When the negative surface of the fluorescent film 24 from the electrons is covered with the negative charge of the PIP, the electron e is close to the electron e whose initial velocity close to zero is ριρ. The electrostatic repulsion of the field cannot enter the glory film. Not only is it filled with a negative electric field due to the electrons of the outer shell of the outermost shell of the filled gas atoms. That is, the gas discharge / 6 # cannot enter the gas space. The gas atoms are not lit. 66 200919527 You can enter the fluorescent discharge camp. The interview with the knowledge of the wind is only the high-energy electricity. The discharge lamp tube takes high-energy electrons from the cathode and can enter the gas space, but the high energy: the child conduction, so the helmet method 上#上进仃The surface body is electrically activated. The gas of the fluorescent discharge lamp must be directed to the glory film before the gas discharge: : The high-energy electrons used advance in one direction, and the electrons are scattered and cannot be the same as the electric field of the light film. When a conductor is placed around the glory film and a positive voltage of about 300 V is applied to it, the phenomenon of the start of the discharge lamp will be discovered based on experience. Special CRT developers also know from experience that the positive electric field above = Luminous film...Glory: 4. The presence of PIP and its elimination method can be applied to dry photocopiers and electrophotographic photoplates. Phosphor materials can also be used as low-strength of photoreceptor plates, so they cannot be put into practical use. The glory film "ριρ is also used in special CRT (storage tube). As the starting method of the discharge of the fluorescent discharge lamp, the technician of the fluorescent discharge lamp has discovered the elimination method of the fluorescent film by experience." The law understands the existence of PIP itself, so it does not understand the principle of pot action. It is troubled by the elimination of problems caused by the elimination of HP, and the method discovered by experience becomes a secret inside the company. The inventor selects the glory body by selecting The PIP problem can be completely solved. If the phosphor type and the manufacturing method are controlled, a phosphor without a PIP in the fluorescent film can be produced. Fig. 6(B) shows that the phosphor particles are not used with the pip. When an electron with an initial velocity close to zero is introduced into the fluorescent film 25 made of a light body coat, the state of the electrons is transmitted on the surface of the fluorescent film. As a phosphor without ριρ, it is a CL that emits light under the irradiation of a low electron beam below ΜV. Fluorescent body. Representing the glory 67 200919527 m white-green light or at 39. A zinc oxide (zn〇) mortar with a peak and a pointed shape, and a blue light vulcanization without using steel as a refining agent (zns:Ag:cl) f light body, zinc sulfide (zns:cu:A1) phosphor emitting green light, and Mg〇 produced under special conditions. When the electron energy irradiated to the fluorescent film rises 4 i2 〇v is additionally produced by oxidizing excess The sulphate (Zn2Si〇4: Mn) glory, a strontium sulfate or butyl sulphate produced by chemical etching on the surface, and an oxidized period (¥2〇 or 劳光体) produced without using (4). The example of Fig. 6(8) shows the case where the honing film is made of Zn◦ phosphor. Since there is no pip g snow, the mouth is in the negative electric field, so the low-speed electrons entering the surface of the fluorescent film easily enter the fluorescent film, i The electric field accelerated by the accumulated ions 8 at the other end of the discharge tube advances in one direction on the surface of the phosphor film, reaches the accumulated ions 8 and recombines with the accumulated ions 8 to form gas atoms. In the usual FL tube ( Tube length 50 cm) on the electron orbit in one direction = the probability of a gas atom is calculable. The value is 1 〇 _6, and it can be considered that the probability of a unidirectional forward acceleration electron gas gas atom collision is zero. There is no gas emitted by the surface conduction electrons. Further, there is no method of directly measuring electrons that conduct surface conduction on a fluorescent iridium. Since a large induced current can be detected indirectly in the conductor disposed on the outer wall of the discharge tube, it is understood that a large surface conduction current flows. The following facts can be observed. The ho fluorescent film is a smooth surface. Therefore, after the accelerated electrons collide with the protruding portion of the fluorescent film on the surface of the fluorescent film, the fluorescent plate of the portion emits CL. Although the CL light is weak, it is confirmed that the accelerated electrons are moving in one direction. If the fluorescent film is completely smooth, it is impossible to detect the electronic motion. If the accelerated electron detection uses a fluorescent film of HjU phosphor (which emits light under the electron irradiation of V), the following facts can be observed. Y2〇3: A small number of phosphor particles in the Eu phosphor have defects. By the negative charge of the particles, the electrons that advance in one direction are bent, and the electrons accelerated by the surface conduction enter the gas filled with gas atoms. In space. The orbital acceleration electrons bent into the gas space inelastically collide with the gas atoms in the gas space. Gas atoms (Hg) that acquire energy due to inelastic collisions are excited to emit ultraviolet light. The emitted ultraviolet light is irradiated onto the fluorescent film, and the fluorescent light is emitted. The electrons that bend the orbit due to inelastic collisions stay in the body space and are accelerated by the high-frequency electric field applied to the gas space to excite other gas atoms in the milk space. This repetition occurs in the gas space, and the :: atom begins to discharge. The number of particles in the unidirectionally advanced electronic track contained in the glory film is small, so the PL luminescence intensity is low, but more than the ZnO phosphor film, there are many light particles in the #pL luminescence. In this way, the # PIj illuminating can clearly detect the acceleration electrons in one-way advancement, and the method in which the orbit of the electron is bent toward the gas space to excite the gas atoms. The same is true for the phosphor of Zn2Si〇4:Mn or red phosphor Y2〇2S:Eu=Μ. However, the light emission of the film made by these phosphors alone is lower than that of the practical level. The above: the inspection of the discharge lamp technology that pays attention to the practice, and because of the low brightness, it will be p-y» ', and as mentioned above, it is easy to provide the fluorescent film that is very important to provide the scientific information. Allowing low-speed electrons to conduct conductance on the fluorescent film, thereby accelerating electrons (the role of incentives), but does not directly contribute to the gas excitation in the fluorescent discharge 69 200919527. If a negatively charged phosphor particle is present in the phosphor film, the accelerated electron orbit is bent at the negatively charged phosphor particle to enter the gas space, and the gas atom is excited. The excited gas atoms emit ultraviolet light. The electrons of the inelastic collision stay in the gas space, are accelerated by the high frequency electric field, and excite other gas atoms. The gas discharge starts by this repetition. This is a mechanism for instantaneously lighting the gas discharge of a practical fluorescent discharge lamp. This observation is a very important finding for the scientific analysis of fluorescent discharge lamps. In Fig. 6(C), in order to confirm the above findings, Zn〇 phosphor particles 25 (no ριρ) are coated on a small area of the end of the fluorescent film of the fluorescent discharge lamp, and the remaining large area is arranged by a commercially available one. The fluorescent film 24 (with IP) of the PL phosphor particles covers the inner wall surface of the fluorescent discharge tube. Experimentally, PL phosphor particles were commercially available first on the inner wall surface of the glass, and after drying, the binder was incinerated. After the glass-side fluorescent film was wiped off with a soft cloth, Zn 萤 phosphor particles 25 were applied to the surface of the glass after wiping. The binder is incinerated after drying. The fluorescent film of Fig. 6(C) can be produced by this method. The X-ray film is further provided with the electron source of the present invention, and the initial velocity is close to that "electron electrons are accelerated at the arrangement of the ZnO phosphor particles 25, and /, there is energy of a politic gas atom. Acceleration electrons cannot enter. Commercially available on the fluorescent film 24, the curved electrons enter the gas space. The electrons entering the gas space collide with the gas atoms in an inelastic collision to excite the gas atoms to illuminate the discharge of the body space. The gas of the discharge lamp is instantaneously lit. The electrons of the inelastic collision acquire the appropriate energy from the 153-frequency electric field by the high-frequency wave in the gas space, and stimulate the gas atoms under the hair by the inelastic collision. The electron side of the high-frequency wave resonance of the road excites the gas source + by the repetition, and the surface migrates to the tube end in the discharge tube: finally, it disappears by combining with the ions. When people observe the Luguang discharge S and the A-wave with the eyes When resonating and migrating electrons, it is considered that the fluorescent discharge lamp g is a fluorescent film that emits light with uniform intensity. However, an important fact is omitted. The electrons migrated in the discharge circuit are added by It has energy and inelastic collision with the gas of 7 atoms. The orbital direction of the electrons in the inelastic collision is random. The electrons scattered in the random direction have electrons with the opportunity to be close to the camping film, but exist in the fluorescent film. The negative charge of PIP26, so the electrons...the method is close to the fluorescent film, but returns to the anode region. The range of electrons that illuminate the gas atoms by resonance with the high-frequency wave is not the entire two of the gas discharge tubes, and 疋 is limited to The gas space in the center of the discharge tube is kept at a fixed distance from the fluorescent film. The space is accommodated in the anode region of the PIP sheath 26. The electrical properties of the gas atoms are neutral and are not affected by the electric field and electric charge. Uniform concentration distribution. Between the anode region and the fluorescent film contained in the PIP sheath 26, gas atoms (unexcited gas atoms) are distributed at a uniform concentration. If the light emitted from the 2 anode region is excited by gas atoms The energy can be shifted to the ground state energy P white electrons to generate 'the light that is allowed to be emitted by the gas atoms. In this case, the light emitted from the anode region is between the anode region and the fluorescent film. The gas atom is absorbed and reaches the residual light after absorption by the light of the fluorescent film. In the case of the fluorescent discharge lamp, the light is emitted by the low-pressure Hg vapor. The light-emitting system is from the excitation energy level 6p of Hg to the ground state energy level. Migration, so it is absorbed by the Hg vapor existing between the anode region and the fluorescent film. The light system has no charged particles, so it is only affected by the PIP, only the Hg vapor exists between the anode region and the fluorescent film 71 200919527 The light remaining after absorption reaches the fluorescent medium. The phosphor particles have a large refractive index of the 2 ^ potassium 耵 sheep particles, so that one part of the ultraviolet light enters the glory particles arranged on the surface of the glory film and is directly illuminated. The center absorbs and emits visible light. The ultraviolet light reflected by the surface layer particles becomes scattered light, and enters the phosphor particles of the deep portion of the camping film to emit light. To increase the amount of ultraviolet light in the fluorescent film of the f-light discharge lamp, it is preferably The fluorescent film is not covered by ριρ negative. That is, it is preferred that the PIP sheath is not formed. If a positively charged PIP charge is applied to a conductor disposed close to the phosphor film. If you want to set up the company, the PIP sheath 20 disappears and the anode area expands to the fluorescent film to increase the brightness, but this is not the case. The 纟 不 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥 蝥The surface conduction of the advancement, the brightness of the fluorescent discharge lamp is significantly reduced. The high-intensity light-emitting film must have a combination of the phosphor particles that accelerate the electrons due to the conduction of the upper surface of the phosphor film and the phosphor particles that deflect the electron orbit toward the gas space. In practice, the force ριρ can not work. The anode area can be set, allowing the self-absorption of the atom, and the larger fluorescent discharge lamp with a diameter of 25 mm or more is used, and the best conditions are obtained empirically. This is a conventional fluorescent discharge lamp that allows self-absorption of 254 ultraviolet rays emitted from Hg in the anode region, and practically uses a glare discharge lamp having a phenomenon of luminescence saturation. According to the result of Fig. 5, as shown in Fig. 6(D), a commercially available PL camping body 24 having PIP and a low voltage CL phosphor 25 having no PIP are alternately arranged on the inner surface of the glass tube. It can be seen that the effect of ριρ26 is greatly reduced, the gas discharge 72 200919527 starts faster, and the anode region expands to cause the brightness to rise. The low voltage CL phosphor 25 must be selected here. An alternative to the low voltage CL illuminator 25 has been described above. Not all of these phosphors can be used. In the above-mentioned phosphors which are commercially available, fine particles having an insulator attached to the surface are treated as a surface treatment. In other cases, the processing of the phosphor is insufficient, and the residue remains on the surface of the particles. The electrons that have been irradiated from the anode region to the phosphor particles by scattering enter the phosphor particles, and the secondary electrons are emitted from the phosphor particles into the vacuum. At this time, holes are left in the phosphor particles. The hole 盥 · 欠 electrons are combined in a vacuum, and SBE is formed on the surface of the particle by the same mechanism as in the case of the metal cathode. If there are adhesion impurities, the luminescence of the gamma-based phosphor particles is also formed on the surface of the impurity, and a large number of holes and electrons are generated in the phosphor particles by the injection of electrons, and the holes and electrons are generated. The glowing nails are combined to illuminate. If the surface of the CL phosphor particles is clean, the ^ ^ ^ ^ hole on the surface of the shell J CL phosphor particles. The electrons in the vacuum that lost the object become free electrons, breaking the acceleration and bending the electron orbit toward the anode region' to facilitate discharge. Problem: The view produced by the impurities attached to the surface of the particles. It has a function with ^. The difficulty is that the SBE on the impurities cannot be eliminated. For this reason, it is very important that the low %* repeated CL swells, _ eve, and scale # · τ (four). The most reliable low-cost CL fluorescent work light body. Here, the brightness of the CL camper is greater than that of the PL lamp. Enter the number of singular injection electrons in the photon particle / the logarithmic scattering of the pen and the hole (about _). Another::,:Gate to order non-elastic - a photon can only excite a luminescence / on the one hand, PL illuminator particles " This is the reason why the CL phosphor is bright 73 200919527. It is most difficult to manufacture the PL phosphor 28 and the low voltage cl phosphor 25 adjacent to the inner wall surface of the fluorescent discharge lamp to produce a fluorescent film. According to the published paper, Journal Physics D Applied Physics, 32, (1999), pp5 13-5 17 (Non-Patent Document 6), the best fluorescent film thickness of fl is three layers of phosphor particles. The particles which are incident on the electrons of the fluorescent film are only arranged in the uppermost layer. The ultraviolet rays are not affected by the charge of the particles and enter the fluorescent film. When the depth of entry is expressed as the number of layers of particles, it is 3 layers. For this reason, the present invention can be manufactured by applying three layers of commercially available phosphor particles 24' after drying on the inner wall surface of the glass tube and then coating the low-voltage CL phosphor 25 so as to be spread on the commercially available phosphor layer 24. Fluorescent film. Fig. 7(A) shows a schematic view of the thus produced fluorescent film. Coating the phosphor film twice, resulting in a complicated work procedure. A method of fabricating a fluorescent film by coating a phosphor slurry once is designed. The average particle size of the commercially available pL light-appearing body is 4 μιη. The particle size of the low-voltage CL phosphor is 2 μ to the weight of the PL phosphor: CL phosphor = 7:3, and the two kinds of phosphor powders are weighed and placed, and the powder is placed in the weighing powder. In a mixing bottle, and mixing uniformly, a phosphor coating liquid is prepared and applied to the inner wall of the discharge tube glass. When the coating liquid is not dried, the PL is selectively collected near the glass tube wall. The phosphor particles 24 are collected on the surface of the fluorescent film: a small number of CL phosphor particles 25 are obtained, so that the glory shown in Fig. 7 (b) is obtained, and the fluorescent film of Fig. 7 (B) is used to produce the fluorite. In the light discharge lamp, the CL phosphor particles in the table=the SM do not form the SM, so the electrons having the south energy in the anode region reach the CL phosphor particles. As a result, the anode region is close to the fluorescent film by 74 200919527 and emits ultraviolet rays. The ultraviolet rays do not have unexcited Hg atoms between the anode region and the phosphor film, so that most of the ultraviolet rays are incident on the pL phosphor layer. As a result, the PL intensity of the fluorescent film increases. Here, when the average particle diameter of the PL phosphor is 4 μηι, the average value of the size of the CL phosphor particles used is 1 μηι to 3 μηι, and good results are obtained. The particle size of the Ik PL phosphor changes. It should be noted that when the phosphor particles are small and below 丨μηη, the particles are not arranged on the surface of the fluorescent film, but are concentrated at the bottom of the fluorescent film when the fluorescent film is dried. The effect of the light body particles becomes small. The fluorescent film will be described in more detail below using examples. [Example 6] An example of a mortar film in which the low-voltage light-emitting CL phosphor of the present invention was mixed was described. The fluorescent film was produced by mixing the phosphor powder shown in Table 6. As a low-voltage CL phosphor having good performance, a ZnS-based phosphor is present, but the sulfur S of the matrix crystal is chemically reacted with Hg vapor during discharge to form HgS, so that the zns-based phosphor is avoided. Weigh the weight of each phosphor powder of the meter 6 and place it in a mixing bottle, and fill it with the phosphor powder weighed. To the mixed powder, 媒5 克 of the vehicle A' was added and stirred to sufficiently disperse the phosphor particles in the slurry. The smoothing slurry was introduced into a glass tube having an outer diameter of 5 mm, and after a short period of time, the slurry was removed from the glass tube, and the phosphor particles were attached to the inner wall surface of the glass. The wuguang film was applied to the inner wall surface of the glass tube. After the hot film is dried by hot air, it is heated in a capless furnace at 600 ° C for 30 minutes, and the organic binder in the camping film is made into water vapor and carbon dioxide gas by thermal decomposition and removed from the tube 75 200919527. A glory film composed only of phosphor particles remains on the wall of the glass tube. The fluorescent film located at the end of the glass tube wall was wiped with a soft cloth. For wiping the glass ^. In the clamp position, any of the electrodes of Example 4 and Example 5 was inserted. One of the ends of the tube seals the electrode by melting a glass tube. The glass tube of the other tube end is slightly melted to make the tube diameter thin. After the Hg amalgam and the Ba collector are placed at the tip of the tapered pipe diameter, the small glass tube 2〇 of the opening is connected to the exhaust device, and the air in the glass tube is removed by a vacuum pump. The entire glass tube was placed in a furnace and heated to 500, except for the portion of the glass tube provided with the water >= i M Ba collector. The material inside the glass tube is degassed by the left and right sides. If the degassing step is over, the temperature is lowered to near room temperature. Thereafter, the Hg amalgam and the Ba collector are slightly heated, and the gas is discharged from the gases. Pumping

氣。其後,導入70 Torr左右之Ar氣體,熔融收納有Hg 汞齊與Ba集氣器之習知之玻璃並自排氣裝置斷開玻璃管。 斷開後’加熱Hg汞齊與Ba集氣器而使其活化。之後,熔 解並密封電極部分之排氣細管,則可獲得外徑為5 mm之 CCFL登光放電燈管。言亥CCFL以1〇冑秒左右之速度點亮 放電。當然點亮速度即便於暗處亦不改變。該放電燈中 並無陰極電壓降低,外部電路測定之點亮電力較習知之 CCFL相比’減少3G%。進而,並無限制陽極區大小之sbe 勒’因此可自螢光放電燈管之螢光膜獲得13%以上之光。 76 200919527 [表6] 螢光體 4匕學式 重量混合比(g ) PL藍色螢光體 BaMgAl10O17:Eu2+ 15 PL綠色螢光體 LaP04:Ce3+:Tb3+ 60 PL紅色螢光體 (Y,Gd)B〇vEu3+ 25 低電壓CL螢光體 ZnO 10 媒液A 150 [實施例7] 表7係混合本發明之低電壓發光CL螢光體粉之螢光 膜的其他示例。市售PL螢光體係以混合發出藍色光之化 學式(Ca,Sr,Ba,Mg)(P04)6Cl:Eu2+ 、發出綠色光之 BaMgAl10O17:Eu2 + :Mn2+、以及發出紅色光之 Y(V,P)04:Eu3 + 之螢光體而發出白色光之方式進行製備,進而於低電壓CL 螢光體中添加ZnO螢光體粉。螢光膜之製造步驟以及螢光 放電燈管之製造步驟與實施例6相同,因此省略其等之說 明。 [表7] 螢光體 化學式 重量混合比(g ) PL藍色螢光體 (Ca,Sr,Ba,Mg)(P04)6Cl:Eu2+ 20 PL綠色螢光體 BaMgAlin0lv:Eu2+:Mn2+ 58 PL紅色螢光體 Y(V,P)04:Eu3+ 22 低電壓CL螢光體 ZnO 15 媒液A 120 77 200919527 [實施例8] 表《衣不本發明之低電壓發光CL螢光體粉之螢 光膜的另一其他示例。實施例6與7中使用之螢光體中使 用貴重之稀土類元素,因此價格非常高。尤其大量使用了 資源曰漸枯竭之铽Tb元素。急需開發一種不使用該等貴 重元素之明亮的螢光放電燈。於NTSC之x_y色度座標= 中,發出明亮綠色光之螢光體係Zn2Si〇4:Mn2+螢光體。 螢光體粉根據PL用與CL用而存有兩種不同 之製造法。習知之螢光放電燈管中所使用者係pL用 Zr^SiO^Mn2—螢光體粉,即於粒子表面附著有大量絕 緣體微粒子之螢光體粒子粉。該螢光體粉末可用於管徑較 大之螢光放電燈中,陽極區收納於螢光膜上形成之較強之gas. Thereafter, an Ar gas of about 70 Torr was introduced, and a conventional glass containing Hg amalgam and a Ba collector was melted and the glass tube was disconnected from the exhaust device. After the disconnection, the Hg amalgam is heated and activated by the Ba collector. After that, the exhaust pipe of the electrode portion is melted and sealed, and a CCFL discharge discharge lamp having an outer diameter of 5 mm can be obtained. The Haihai CCFL lights up at a speed of about 1 second. Of course, the lighting speed does not change even in the dark. In the discharge lamp, there was no decrease in the cathode voltage, and the lighting power measured by the external circuit was reduced by 3 G% compared with the conventional CCFL. Further, there is no limitation on the size of the anode region, so that 13% or more of the light can be obtained from the fluorescent film of the fluorescent discharge lamp. 76 200919527 [Table 6] Phosphor 4 Drop Weight Mix Ratio (g) PL Blue Phosphor BaMgAl10O17: Eu2+ 15 PL Green Phosphor LaP04: Ce3+: Tb3+ 60 PL Red Phosphor (Y, Gd) B〇vEu3+ 25 Low Voltage CL Phosphor ZnO 10 Vehicle A 150 [Example 7] Table 7 is another example of a fluorescent film of the low voltage light-emitting CL phosphor powder of the present invention. A commercially available PL fluorescent system is a mixture of a chemical formula (Ca, Sr, Ba, Mg) (P04) 6Cl:Eu2+ emitting blue light, BaMgAl10O17:Eu2 + :Mn2+ emitting green light, and Y (V,P) emitting red light. 04: Eu3 + phosphor is prepared by emitting white light, and ZnO phosphor powder is added to the low voltage CL phosphor. The manufacturing steps of the fluorescent film and the manufacturing steps of the fluorescent discharge lamp are the same as those in the sixth embodiment, and thus the description thereof will be omitted. [Table 7] Fluorescent chemical formula Weight mixing ratio (g) PL blue phosphor (Ca, Sr, Ba, Mg) (P04) 6Cl: Eu2+ 20 PL green phosphor BaMgAlin0lv: Eu2+: Mn2+ 58 PL red Light body Y(V,P)04:Eu3+22 Low voltage CL phosphor ZnO 15 Medium A 120 77 200919527 [Example 8] Table "Foam film of low voltage light-emitting CL phosphor powder of the present invention Another other example. The rare earth elements used in the phosphors used in Examples 6 and 7 were very expensive. In particular, a large number of Tb elements that are gradually depleted of resources are used. There is an urgent need to develop a bright fluorescent discharge lamp that does not use these precious elements. In the x_y chromaticity coordinate = of NTSC, a bright green light Zn2Si〇4:Mn2+ phosphor is emitted. The phosphor powder has two different manufacturing methods depending on the PL and the CL. In the fluorescent lamp tube of the prior art, Zr^SiO^Mn2-phosphor powder is used for the user's pL, that is, the phosphor particle powder having a large amount of insulating fine particles attached to the surface of the particle. The phosphor powder can be used in a fluorescent discharge lamp having a large diameter, and the anode region is formed on the fluorescent film to form a stronger one.

SBE鞘中,因此無法用於細管徑之螢光放電燈管之螢光膜。 螢光放電燈管之内壁面上不形成SBEi ZnjiOrMn2—螢光 體粉,係於120 eV之電子束照射下進行明亮之CL發光的 Zn2Si04:Mn2+螢光體粉。將該CL發光之Zn2Si〇4:Mn2+螢光 月a卷與稀土類活化之藍色螢光體粉以及紅色螢光體粉混 合,則可獲得發出白色光之螢光體粉。當採用於管徑為15 mm以下之CCFL管之内壁上塗佈該螢光體粉之螢光膜時, 發光Zn2Si(V_Mn2+螢光體粉之粒子上不形成sbe ,陽極 區靠近螢光膜而進行明亮發光。因此,可將CL發光之 Zn2Sl〇4:Mn2+螢光體粉使用於與多色之Pl螢光體粉之混合 ;刀而I出白色光之螢光膜。可獲得管徑為15 mm以下之細 e之CCFL。無須大量使用貴重之Tb,亦可獲得發出白色 78 200919527 光之CCFL。表8表示獲得具有綠色NTSC色度座標點之 白色螢光膜之螢光體粉的混合比例。混合粉並不限定於表 8所示之PL螢光體粉,使用CCFL中使用之其他種類之PL 藍色發光螢光體粉與其他種類之PL紅色螢光體粉的混合 粉,亦可獲得相同之結果。螢光膜之製造步驟以及螢光放 電燈管之製造步驟與實施例6相同,因此省略其等之說明。 [表8] 螢光體 化*學式 重量混合比(g ) PL藍色螢光體 BaMgAl10O17:Eu2+ 20 CL綠色螢光體(120 eV) Zn,Si04:Mn2+ 58 PL紅色螢光體 YBO,:Eu3+ 22 低電壓CL螢光體 ZnO 10 媒液A 130 [實施例9] 根據經驗獲得之結果,實施例8之細管CCFL之螢光 膜之構成包含約35重量%之CL綠色螢光體粉以及23重 量%之PL綠色螢光體粉時,可獲得最高之亮度。表9表示 混合比例。表9之混合係作為實施例一例,混合之PL螢 光體並不限定於表9所示之PL螢光體,使用CCFL中使 用之其他種類之PL藍色發光螢光體粉以及其他種類之PL 紅色螢光體粉之混合粉,亦可獲得相同之結果。螢光膜之 製造步驟以及螢光放電燈管之製造步驟與實施例6相同, 79 200919527 因此省略其等之說明。 [表9] 螢光體 化*學式 (g) --20__ PL藍色螢光體 BaMgAlin017:Eu2+ CL綠色螢光體(120 eV) Zn?Si04:Mn2+ ~~-_ 綠色螢光體 Zn7Si04:Mn2+ —色螢光體 YBO,:Eu3+ --—一 螢光體 ZnO —一___乂 z —---- -- 1 ςη 媒液B ---—_ [貫施例10] 實施例6〜9中使用之螢光體中,使用克拉刻數較小且 :在資源枯竭之擔憂之貴重稀土類元素,因此價格非常 四。尤其係大量使用資源日漸枯竭之轼Tb盥&元 各In the SBE sheath, it cannot be used for the fluorescent film of a fluorescent tube with a small diameter. SBEi ZnjiOrMn2-fluorescent powder is not formed on the inner wall surface of the fluorescent discharge lamp, and is a bright CL-emitting Zn2Si04:Mn2+ phosphor powder irradiated by an electron beam of 120 eV. When the CL-emitting Zn2Si〇4:Mn2+ fluorescent moon a roll is mixed with the rare earth-activated blue phosphor powder and the red phosphor powder, a white light-emitting phosphor powder can be obtained. When the phosphor film of the phosphor powder is coated on the inner wall of a CCFL tube having a diameter of 15 mm or less, the luminescent Zn2Si (the sbe is not formed on the particles of the V_Mn2+ phosphor powder, and the anode region is close to the fluorescent film) Bright luminescence is performed. Therefore, the CL-emitting Zn2Sl〇4:Mn2+ phosphor powder can be used for mixing with multi-color Pl phosphor powder; the knife can be used to produce a white-light fluorescent film. CCFL with a fine e of 15 mm or less. It is possible to obtain a CCFL emitting white 78 200919527 without using a large amount of valuable Tb. Table 8 shows a mixture of phosphor powders obtained with a white fluorescent film with green NTSC chromaticity coordinates. The mixed powder is not limited to the PL phosphor powder shown in Table 8, and the other type of PL blue luminescent phosphor powder used in CCFL and other types of PL red phosphor powder are also used. The same results were obtained. The manufacturing steps of the fluorescent film and the manufacturing steps of the fluorescent discharge lamp were the same as those in Example 6, and therefore the description thereof will be omitted. [Table 8] Fluorescence * Theoretical weight mixing ratio (g ) PL Blue Phosphor BaMgAl10O17: Eu2+ 20 CL Green Phosphor (120 eV) Z n, Si04: Mn2+ 58 PL red phosphor YBO,: Eu3 + 22 low voltage CL phosphor ZnO 10 medium A 130 [Example 9] According to the results obtained empirically, the fluorescent film of the thin tube CCFL of Example 8 When the composition comprises about 35 wt% of the CL green phosphor powder and 23 wt% of the PL green phosphor powder, the highest brightness is obtained. Table 9 shows the mixing ratio. The mixing of Table 9 is an example of the example, and the mixture is mixed. The PL phosphor is not limited to the PL phosphor shown in Table 9, and other types of PL blue-emitting phosphor powder used in CCFL and other types of PL red phosphor powder may be used. The same results were obtained. The manufacturing steps of the fluorescent film and the manufacturing steps of the fluorescent discharge lamp were the same as those in Example 6, 79 200919527, and the description thereof will be omitted. [Table 9] Phosphorescence * Formula (g) - -20__ PL Blue Phosphor BaMgAlin017: Eu2+ CL Green Phosphor (120 eV) Zn? Si04: Mn2+ ~~-_ Green Phosphor Zn7Si04: Mn2+ - Color Phosphor YBO, :Eu3+ --- One Firefly Light body ZnO — ___ 乂 z —--- -- 1 ςη Media B --- — _ [Example 10] Used in Examples 6 to 9 Phosphor, a small moment and Carat: precious rare earth element in the concern of resource depletion, and therefore the price is very large system, especially four gradual depletion of resources used Shi Tb wash & each element.

:開=種不使用該等貴重元素而明亮發光之勞光放; 無明者著眼於習知登光放電燈管中使用之·磷酸鈣 2發光螢光體Ca5(P〇4)3(F,C1):Sb3 + :Mn2+。根據本發明者 :由函她螢光體而製作之螢光膜存在於榮光 古?中目PIP而導致放電發光之點亮的問題。進而,點 截向 彡成較強之SBE,陽極區㈣於㈣之SBE 線,士介於陽極區與螢光膜間之&蒸氣吸收254 nm紫外 主要 〖制了螢光放電燈管之光輪出。產生如此現象之 要原因在於,南細榮光體之發光中,發光中心利用 80 200919527:Open=Do not use these precious elements and brightly illuminate the light; the unidentified person looks at the calcium phosphate 2 luminescent phosphor Ca5(P〇4)3 (F, used in the conventional Dengguang discharge lamp) C1): Sb3 + : Mn2+. According to the present inventors: a fluorescent film produced by a letter of her fluorescent body exists in glory ancient? The problem of the lighting of the discharge is caused by the PIP of the middle mesh. Furthermore, the point is cut into a stronger SBE, the anode region (4) is in the (S) SBE line, and the voltage between the anode region and the fluorescent film is & vapor absorption 254 nm ultraviolet mainly by the light wheel of the fluorescent discharge lamp Out. The reason for this phenomenon is that the illuminating center is utilized in the illuminating light of the South glory body. 80 200919527

Sb”與Μβ之敏化作用,在一個螢光體粒子中μ直接吸 收254·紫外線,Sb3 +發出之藍色光之—部分由隐2+吸 收,並於汽色之寬廣頻帶中發光,葬由兩袖政1 疋错甶兩個發光頻帶而發 出白色光。根據活化劍夕也路拖庄,丨^、 d之激發機制之分類,為直接激發螢 光體,基體結晶之電子盥雷、,同兀灸你议, 卞興電洞不參與發光。該種螢光體於 電子束照射下僅發出較暗之ΓΤ本 lL w 平乂啃之CL先。此係眾所周知之事實。 遺漏之處在於’基體結晶之電子與電洞不參與發光,因此 直接激發螢光體粒子之物性於電子束照射下具有絕緣體之 特性。如上所述,螢光放電燈管内之螢光膜上,陽極區内 剛進行非彈性碰撞之後之電子的前進方向為隨機,亦有具 有向能量之電子到達螢光膜。若向絕緣體照射電子,則於 絕緣體粒子表面形纟SBE。SBE量隨時間積聚,其結果為 產生較強t SBE。此即造成使用_酸㈣光體時陽極區 進入SBE勒中’螢光膜出現亮度飽和現象。若解決觀 鞘之問題,則鹵磷酸鈣螢光體可適用於内徑為2mm之ccfl 之螢光膜。若CCFL中可使用_磷酸鈣螢光體,即可獲得 不使用有資源枯竭之擔憂之稀土類元素之廉價之白色發光 CCFL。_磷酸鈣螢光體具有之放電發光之點亮延遲問題, 係與螢光放電燈中使用之PL螢光體共通之問題,可解決 該問題。以下根據實施例說明解決方法。 [表 1 0] 螢光體 化學式 重量混合比(2 ) 鹵磷酸鈣螢光體 Ca5(P04),(F,Cl):Sb3+:MnH 70 低電壓CL螢光體 ZnO 30 媒液A ------ 150 81 200919527 如表10所示,秤量70克之發出白色光之㈣酸與勞 光體粉以及30克之發出藍白色光之低電壓CL zn〇螢光體 粉,並混合該等粉體。將該混合粉體與15〇克之媒液A混 合而製作衆液。以後之營光膜之製造步驟與實施例6相同, 因此省略其說明。可獲得—# CCFL,所得之内徑為2麵 之CCFL以毫秒單位瞬時點亮,榮光膜上基乎無法檢測出 SBE’其發光亮度遠读莴於翌左 又m遂问於%知之25 mm管之螢光放電燈。 本發明之画磷酸鈣螢光體粉之材料成本相比於當前市售之 〇爾常低,約為十分之一。開發之内徑為5mm以上之 CCFL螢先放電燈最適合用於室内照明。尤其外徑為B〜別 一咖適於房屋之照明。開發之榮光燈廉價,且壽 印長達1〇〇,_小時以上,因此對使用者有利。 [實施例1 1] 將實施例1 〇 — ……之CCFL用於LCD之背光時,紅色 之榮光體。發表螢先3體係以Eu、子為發光中心 w勞光體之任"U作為活化劑之榮光體,實用 體。其中於"0 ev之糸於電子束照射下明亮發光之登光 榮光體。實施传 束下3發光之勞光體為Y2〇3:EU3 + 但並不限定㈣螢:二WE11帛先體增強紅色之示例, 色。 β切’其他紅色螢光體亦可用於增強紅 82 200919527 [表 11] ----- 螢光體 化學式 重量混合比(g ) 鹵磷酸鈣勞光體 Cas(P04)3(F,Cl):Sb3+:Mn2+ 100 PL 體 Y70,:Eu3+ 30 低電壓CL營光體 ZnO 25 媒液A —— 130Sensitization of Sb" and Μβ, in a phosphor particle, μ directly absorbs 254·UV, and the blue light emitted by Sb3+ is partially absorbed by the hidden 2+, and emits light in a wide frequency band of the vapor color. The two sleeves are erroneously illuminating the two light-emitting bands and emitting white light. According to the activation of the sword, the road is dragged, the classification mechanism of the 丨^, d is the direct excitation of the phosphor, the electrons of the matrix crystal, With the moxibustion, you can't participate in the luminescence. This kind of phosphor emits only the darker ΓΤ l l l 。 。 。 。 。 。 。 。 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该 该'The electrons and holes of the crystal of the matrix do not participate in the luminescence, so the physical properties of the directly excited phosphor particles have the characteristics of an insulator under electron beam irradiation. As described above, on the fluorescent film in the fluorescent discharge lamp, the anode region The direction of advancement of the electrons immediately after the inelastic collision is random, and electrons having energy toward the energy reach the fluorescent film. If the electrons are irradiated to the insulator, the surface of the insulator particles is shaped like SBE. The amount of SBE accumulates over time, and the result is Production Strong t SBE. This causes the brightness of the fluorescent film to appear in the anode region when the anodic (four) light body is used. If the problem of the sheath is solved, the calcium halophosphate phosphor can be applied to the inner diameter. 2mm ccfl fluorescent film. If _phosphate calcium phosphor can be used in CCFL, you can get cheap white luminescent CCFL without using rare earth elements with resource depletion. _ Calcium phosphate phosphor has discharge The problem of the lighting delay of the illuminating light is a problem common to the PL phosphor used in the fluorescent discharge lamp, and the problem can be solved. The following describes the solution according to the embodiment. [Table 1 0] Fluorescent chemical weight mixing ratio ( 2) Calcium halophosphate phosphor Ca5 (P04), (F, Cl): Sb3+: MnH 70 Low voltage CL phosphor ZnO 30 Medium A ------ 150 81 200919527 As shown in Table 10, weigh 70 grams of white light (4) acid and mortar powder and 30 grams of blue-white light low voltage CL zn 〇 phosphor powder, and mixed with the powder. The mixed powder and 15 grams of media A Mixing and making a public liquid. The manufacturing steps of the camp light film are the same as in the sixth embodiment, so Slightly explained. Obtained - # CCFL, the obtained CCFL with inner diameter of 2 faces is instantaneously illuminated in milliseconds, and the glory film can not detect SBE'. The brightness of the light is far from the 翌 left and m遂% know the 25 mm tube fluorescent discharge lamp. The material cost of the calcium phosphate phosphor powder of the present invention is about one tenth lower than that of the currently marketed one. The developed inner diameter is more than 5 mm. The CCFL fluorescent discharge lamp is most suitable for indoor lighting. Especially the outer diameter is B~ another coffee is suitable for the illumination of the house. The development of the glory light is cheap, and the longevity is as long as 1 〇〇, _ hour or more, so the user advantageous. [Embodiment 1 1] When a CCFL of Example 1 is used for backlighting of an LCD, a red glory body. Publish the first 3 systems with Eu, the child as the illuminating center, and the glory body and utility of the actuator. Among them, "0 ev is the bright light that shines under the electron beam. The 3 illuminating light body under the transmission is Y2〇3:EU3 + but not limited to (4) Firefly: an example of the second WE11 帛 precursor enhanced red color.切切' other red phosphors can also be used to enhance red 82 200919527 [Table 11] ----- Phosphorescent chemical weight mixing ratio (g) Calcium halophosphate Cas(P04)3 (F, Cl) :Sb3+:Mn2+ 100 PL Body Y70,:Eu3+ 30 Low Voltage CL Camp ZnO 25 Media A —— 130

表u係為增強發出白色光之caJPOddF/lhSb^Mn2·1 之紅色波長範圍内之光,而於表10之混合螢光體粉中添 加♦出紅色光之Y2〇3:Eu3+螢光體粉(具有於611 nm線發 光波長)的情形。混合螢光體粉使用媒液A而混合漿液。 以後之螢光膜之製造步驟與實施例6相同,因此省略其說 明。所得之外徑為2 mm之CCFL以1毫秒左右之速度瞬 日守放電’藉由Y2〇3:Eu3+螢光體(於611 nm線發光)之發 光而進行色校正,可於LCD之背光中使用。且表現出無法 觀祭到陰極電壓降低,於點亮中之CCFL管中之螢光膜上 基乎無法檢測到SBE之特徵。 [產業上之可利用性] 根據本發明可實現一種榮光放電燈管,無陰極電壓降 低因此有利於節約能源’可減小外部電源之電流,同時電 極附近之明暗條紋狀圖案消I,可顯著提高照明度。又毛 根據本發明可實現一種螢光 蛍尤放包燈官,金屬陰極無損耗因 此可延長螢光放電燈管之壽命,— 味 、、者&面母根榮光放電燈 官之照明度’同時快速點亮盥整 王個表面點売。該螢光放電 83 200919527 蛻官包含直線管、曲線管、環技、 放電燈。又,本#明 〇、勞光燈泡及其他螢光 日日蝻示裝置),里呈右 .、肩不滅置(液 /、八有利用了該螢光放電燈管之 【圖式簡單說明】 月光4置。 圖1係本發明之螢光放 理的說明圖。 Μ放電燈官内形成之内部電路之原 圖2係關於本發明之營光放電燈管 流動獨立之内部兩 且屯流之 电路外。[5驅動電路的說明圖。 電路圖之關 内部電:=與形成關於榮光放電燈管之放電之 路之電子流的說明圖。 舜蓋^係本發明之榮光放電燈管内設置之由絕緣體粒子 二板=電極中,金屬電極之形狀使用杯狀金屬電極與 十板狀金屬板之例示圖。 ρ圖5係本發明之螢光放電燈管内設置之由絕緣體粒子 盍之孟屬電極中,金屬電極之形狀為金屬棒之例示圖。 圖6係說明本發明中導入至勞光膜表面之電子行為隨 蛍“之荷電狀態而改變之情形的示意圖。 盘一圖?係表示本發明中藉由低電壓電子束發光螢光體粉 。光致發光螢光體粉之混合粉而製作之最光膜之狀態 的不意圖。 圖8係習知之螢光放電燈管内部設置之金屬陰極之表 、之;形成表面結合電子(SBE )之現象的說明圖。 【主要元件符號說明】 84 200919527 1、9 螢光放電燈管(或者玻璃管) 2、3 金屬電極 4 絕緣體粒子 5 氣體放電 6 外部電源(高頻電源) 7、16 電子源(電子供給源) 8 離子源(正離子源) 10 螢光膜(或者螢光體膜) 11 陽極區 12 外部電路 13 電容器 14 感應電流 15 内部電路 17 離子源(正離子源或者積聚正離子) 18 引導電極 19 釣鐘型電極 20 小玻璃管 21 平板狀金屬電極 22 棒狀金屬電極 23 玻璃介質 24 具有PIP之螢光膜(市售PL螢光體膜) 25 無PIP之螢光膜(CL螢光體膜) 26 PIP ( PIP負電荷或者PIP鞘) 30 金屬陰極 85 200919527 CCFL 冷陰極螢光放電燈管 CL 電子束發光(Cathode Luminescence ) e 電子(發射電子) EL 無機電場發光 FL 螢光放電燈 h 電洞 HCFL 熱陰極電極 LED 發光二極體 LCD 液晶顯不 OLED 有機電場發光顯示器 PIP 永久内部極化 PL 光致發光(Photo Luminescence) SBE 表面結合電子(surface-bound-electrons) uv 紫外線Table u is for enhancing the red wavelength range of caJPOddF/lhSb^Mn2·1 emitting white light, and adding Y2〇3:Eu3+ phosphor powder of red light to the mixed phosphor powder of Table 10 (There is a ray wavelength at 611 nm line). The mixed phosphor powder was mixed with the medium A using the medium A. The manufacturing steps of the subsequent fluorescent film are the same as those of the sixth embodiment, and thus the description thereof will be omitted. The obtained CCFL with an outer diameter of 2 mm is color-corrected by the illuminating of the Y2〇3:Eu3+luminescence (lighting at 611 nm line) at a speed of about 1 millisecond, which can be corrected in the backlight of the LCD. use. It also shows that the cathode voltage is not observed, and the characteristics of the SBE cannot be detected on the fluorescent film in the CCFL tube that is lit. [Industrial Applicability] According to the present invention, a glory discharge lamp can be realized, and the cathode voltage is not reduced, thereby saving energy. The current of the external power source can be reduced, and the light and dark stripe pattern near the electrode can be eliminated. Improve the illumination. According to the present invention, a fluorescent luminaire can be realized, and the metal cathode has no loss, so that the life of the fluorescent discharge lamp can be prolonged, and the illuminance of the scented light discharge lamp At the same time, it quickly lights up the surface of the king. The fluorescent discharge 83 200919527 The eunuch includes a straight tube, a curved tube, a ring technique, and a discharge lamp. In addition, this #明〇, Laoguang bulb and other fluorescent day and day display devices), in the right, the shoulder is not extinguished (liquid /, eight have used the fluorescent discharge tube [simplified description] Fig. 1 is an explanatory view of the fluorescent lithography of the present invention. The original drawing of the internal circuit formed in the discharge lamp of the present invention is related to the internal flow of the luminescence discharge lamp of the present invention. Outside the circuit. [5. Description of the drive circuit. Internal diagram of the circuit diagram: = and an illustration of the flow of electrons forming a discharge path for the luminescence discharge lamp. The cover is provided in the glory discharge lamp of the present invention. In the insulator particle two-plate=electrode, an example of a cup-shaped metal electrode and a ten-plate metal plate is used for the shape of the metal electrode. ρ FIG. 5 is an insulator particle disposed in the fluorescent discharge lamp of the present invention. In the electrode, the shape of the metal electrode is an illustration of a metal rod. Fig. 6 is a schematic view showing the state in which the electronic behavior introduced into the surface of the light-retardant film changes with the state of charge of the ruthenium film in the present invention. Invented by low voltage The state of the most light film produced by the sub-beam luminescent phosphor powder and the mixed powder of the photoluminescent phosphor powder. Fig. 8 is a table showing the metal cathode provided inside the conventional fluorescent discharge lamp tube; Explanation of the phenomenon of surface-bound electrons (SBE). [Main component symbol description] 84 200919527 1,9 Fluorescent discharge lamp (or glass tube) 2, 3 Metal electrode 4 Insulator particles 5 Gas discharge 6 External power supply (high Frequency power supply) 7, 16 electron source (electron supply source) 8 ion source (positive ion source) 10 fluorescent film (or phosphor film) 11 anode region 12 external circuit 13 capacitor 14 induced current 15 internal circuit 17 ion source ( Positive ion source or accumulation of positive ions) 18 Guide electrode 19 Bell-shaped electrode 20 Small glass tube 21 Flat metal electrode 22 Rod-shaped metal electrode 23 Glass medium 24 PIP fluorescent film (commercial PL phosphor film) 25 None PIP fluorescent film (CL phosphor film) 26 PIP (PIP negative charge or PIP sheath) 30 Metal cathode 85 200919527 CCFL Cold cathode fluorescent discharge lamp CL Electron beam illumination (Cathode Luminescence) e Electron (emission electron) EL Inorganic electric field emission FL Fluorescent discharge lamp h Hole HCFL Hot cathode electrode LED Light-emitting diode LCD Liquid crystal display OLED Organic electric field display PIP Permanent internal polarization PL photoluminescence ( Photo Luminescence) SBE surface-bound-electrons uv UV

8686

Claims (1)

200919527 十、申請專利範固: L —種螢光放電燈管,豆俜 壁面塗佈有螢光膜^ 螢先放電燈之玻璃管内 之點亮,係4玻璃官内之放電氣體 源之外部電路而產生。 之内^電路、與連接於電 2.如申請專利項之營光放電燈管,其 = 子源所構成,該瑩光放電燈管内之氣體2 移之過程中產:取子於氣體空間内朝向該離子源遷 .且*遷移之該電子到達離子源時,該電 子與離子再結合,該㈣電路封閉。 為電 3+如申請專利範圍第2項之螢光放電燈管,其中 為该笔子源形成用電極,於該螢光放電燈管内之1中 配置層狀覆蓋有電 a ^ 源报士、田+ T卞之金屬電極,而作為該離子 '、少成用电極,於該螢光放電燈管内 盍有電絕緣體粒子之金屬電極。 而己θ狀覆 ㈣:如申請專利範圍第3項之勞光放電燈管,其中,向 属源形成用電極之該金屬電極施加正極性之電位,使 ^金屬電極之電絕緣體粒子介電極化,電極周邊之氣體之 子化所產生之自由電子受到介 子 # 又丨電桎化後之该電絕緣體粒 之’將該自由電子於該電絕緣體粒子近前 之軋體空間盥續雷紹 間電子f作二” 内之正電荷結合而形成的空 屬^ 源;且向該離子源形成用電極之該金 遂施加負極性之電位,使該金屬電極之電絕緣體粒子 87 200919527 介電極化,電極周邊之氣 ^ jrrr η ^ 離子化所產生之離子受到介 电極化後之該電絕緣體粒子之 — ϋ % ^ 、电何吸引,將該離子與該 电.,'色緣體粒子之極化負雷 子源。 °、、° σ而形成之離子群作為該離 5. 如申請專利範圍第4 員之螢光放電燈管,豆將電子 自该電子源取出至螢光膜表面, 八 #雷;错由發光膜之表面傳導而 使電子加速,加速電子志盔# ……丄:放電之始動之誘因,藉由 帶負電何之螢光體粒子而侦 n 而使忒加速電子之軌道彎向氣體空 間,使螢先放電燈管之齑體# 1 ^ +夺2凴放電,藉此產生I陰 極電壓降低之氣體放電。 6. 如申請專利範圍第 項之螢光放電燈管,其中,於 該螢光膜之表面交替配置不帶 个V貝電何之螢光體粒子與帶負 電荷之螢光體粒子,且於哕罄本 且於该螢光膜表面之多個部位,藉由 該帶負電荷之螢光體粒子使該加竦+ 文〆加迷电子彎向氣體空間側。 7·如申請專利範圍第1 — 主6項中任一項之螢光放電燈 g ’、中虡螢光放電燈官之玻璃管内壁面塗佈之該螢光 膜,係由電子束發光勞光體粉與光致發光勞光體粉之混合 粉體所構成。 8·如申請專利範圍帛7項之螢光放電燈管,其t,該 光致發光螢光體粉係由單獨發出三色光之三種稀土類光致 發光螢光體粉所構成,且該電子束發光勞光體粉係由低電 壓電子束發光螢光體粉構成。 9.如申請專利範圍帛8項之螢光放電燈管,苴中,該 稀土類光致發光螢光體才分内]吏肖CL#光之石夕酸鋅營光 88 200919527 體粉取代發出綠色光之光致發光螢光體粉。 10·如申請專利範圍第8項之螢光放電燈管,其中,該 稀土類光致發光螢光體粉内,使用CL發光之矽酸辞螢光 體粉與PL發光之矽酸鋅螢光體粉之混合粉體,取代發出 綠色光之光致發光螢光體粉。 11.如申請專利範圍第8項之螢光放電燈管,其中,於 該螢光膜,將該低電壓電子束發光螢光體之粒+配置為於 該螢光膜之表面不連續散布。 、 12.如申請專利範圍第9項之螢光放電燈管,其中,於 '亥瓦光膜,將该低電壓電子束發光螢光體之粒子配置為於 該螢光膜之表面不連續散布。 、 如申明專利範圍第1 〇項之螢光放電燈管,其中, 於該螢光膜,將該低電壓電子束發光螢光體之粒子 於該螢光膜之表面不連續散布。 為 ,該 電壓 螢 電 14.如申凊專利範圍第7項之螢光放電燈管,其中 光膜係由早獨發出白色光之光致發光螢光體粉與低 子束發光螢光體粉之混合粉體所構成。 如申請專利範圍第 只、災〜从电笕官,其中 。,光中,自色光致發光之該光致發光 ―螢光體所構成。 16.如申請專利範圍帛15 ;頁之榮 於該螢光膜抬 B * t . 冑、加性地添加有增強紅色發光之電子束 化釔螢光體。 丁不七先氧 17· 一種LCD顯示裴置 其特徵在於 將單個或多個 89 200919527 如申請專利範圍第!至16帛中任—項之鸯光放電燈管排 列於平面上’作為LCD顯示裝置之背光而使用。 、 明辱利耗圍第1 7項之L C D顯示裳置,於垂直 方向上配置多個該勞光放電燈管,、將各榮光放 方式依序多個螢光放為群1線序掃描之 個屏幕。冗,並將線序之影像映出至,示裝置之整 十一、《式: 如次頁 90200919527 X. Application for patents: L-type fluorescent discharge lamp, the surface of the soybean meal is coated with a fluorescent film ^ The lighting inside the glass tube of the first discharge lamp is the external circuit of the discharge gas source in the glass And produced. The circuit is connected to the electricity 2. The luminaire discharge lamp of the patent application is composed of a sub-source, and the gas in the fluorescent discharge lamp is moved during the process: the gas is taken in the gas space. When the electrons are moved toward the ion source and the *migrated electrons reach the ion source, the electrons recombine with the ions, and the (4) circuit is closed. For the electric fluorescent lamp tube of the second aspect of the invention, the electrode for forming the pen source is arranged in the layer 1 of the fluorescent discharge lamp tube. The metal electrode of the field + T卞 is used as the electrode for the ion and the electrode for the electrode, and the metal electrode of the electric insulator particle is contained in the fluorescent discharge lamp. And the θ-shaped coating (4): the working light discharge tube according to claim 3, wherein a positive polarity is applied to the metal electrode of the source forming electrode, and the electrical insulator particles of the metal electrode are mesogenic The free electrons generated by the gasization of the gas around the electrode are subjected to the meson # 丨 丨 该 该 该 该 该 该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该 将该a space source formed by combining positive charges in the second"; and applying a negative potential to the gold electrode of the ion source forming electrode, and electrically insulating the electrical insulator particles 87 200919527 of the metal electrode, and the periphery of the electrode The gas generated by the gas ^ jrrr η ^ ionization is subjected to the dielectric polarization of the electrical insulator particles - ϋ % ^, which is attracted by the electron, and the polarization of the ion-particle particles The ion group formed by the °, °, ° σ as the fluorescent discharge lamp of the fourth member of the patent application, the bean is taken out from the electron source to the surface of the fluorescent film, eight #雷; The error is caused by the conduction of the surface of the luminescent film to accelerate the electrons, accelerating the electronic Helmet # 丄 丄: the cause of the start of the discharge, by the negatively charged phosphor particles, and detecting the n, the 忒 accelerates the orbit of the electron to the gas Space, so that the first discharge of the fluorescent tube of the fluorescent tube #1 ^ + 2 凴 discharge, thereby generating a gas discharge with a reduced cathode voltage. 6. The fluorescent discharge lamp of the scope of the patent application, wherein The surface of the fluorescent film is alternately arranged without a V-Bei electric phosphor particle and a negatively charged phosphor particle, and is applied to a plurality of portions of the surface of the fluorescent film by the tape. The negatively charged phosphor particles bend the twisted + text and the electrons toward the gas space side. 7 · The fluorescent discharge lamp g ', Zhong Yiying, as in any one of the main items The fluorescent film coated on the inner wall surface of the glass tube of the light discharge lamp is composed of a mixed powder of an electron beam luminous powder and a photoluminescent working powder. 8·If the patent application scope is 7 Fluorescent discharge lamp, t, the photoluminescent phosphor powder is It is composed of three kinds of rare earth photoluminescent phosphor powders which are three-color light, and the electron beam luminous powder is composed of low-voltage electron beam fluorescent powder. 9. As claimed in the patent item 8 Fluorescent discharge lamp tube, 苴中, the rare earth photoluminescence phosphor is only included] 吏肖CL#光石石酸锌营光88 200919527 Body powder replaces the green light photoluminescence phosphor powder 10. The fluorescent discharge lamp of the eighth aspect of the patent application, wherein the rare earth photoluminescence phosphor powder uses CL light-emitting strontium phosphorate powder and PL-emitting zinc citrate The mixed powder of the light body powder replaces the photoluminescent phosphor powder that emits green light. 11. The fluorescent discharge lamp of claim 8, wherein the phosphor film is arranged such that the particles of the low voltage electron beam emitting phosphor are discontinuously dispersed on the surface of the fluorescent film. 12. The fluorescent discharge lamp of claim 9, wherein the particles of the low voltage electron beam illuminating phosphor are arranged to be discontinuously spread on the surface of the fluorescent film in the 'Hawa film. . The fluorescent discharge lamp of the first aspect of the invention, wherein the particles of the low-voltage electron beam illuminating phosphor are discontinuously spread on the surface of the fluorescent film. For the voltage, the fluorescent discharge lamp of the seventh aspect of the invention, wherein the light film is a photoluminescence phosphor powder and a low beam emission phosphor powder which emit white light in the morning. It is composed of a mixed powder. For example, the scope of the patent application is the only one, the disaster ~ from the eunuch, among them. In the light, the photoluminescence of the self-chromic photoluminescence is composed of a phosphor. 16. If the patent application scope is 帛15; the page is proud of the fluorescent film B*t. 胄, additively added with enhanced red luminescence of the electron beam 钇 phosphor. Ding not seven oxygen first 17 · An LCD display device is characterized by a single or multiple 89 200919527 as claimed in the scope of patents! The light-emitting discharge lamps of the above-mentioned items are arranged on a flat surface as the backlight of the LCD display device. The LCD display of the 17th item of the humiliation and consumption is arranged in the vertical direction, and a plurality of the discharge lamps are arranged in the vertical direction, and the plurality of fluorescent lamps are sequentially placed in the group 1 line sequence scanning. Screens. Redundant, and the image of the line sequence is reflected to the whole of the device. 十一:《式:如次页 90
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JP2001303042A (en) * 2000-04-20 2001-10-31 Toshiba Corp Phosphor for rapid start type fluorescent lamp and rapid start type fluorescent lamp using the same
DE10057881A1 (en) * 2000-11-21 2002-05-23 Philips Corp Intellectual Pty Gas discharge lamp, used in e.g. color copiers and color scanners, comprises a discharge vessel, filled with a gas, having a wall made from a dielectric material and a wall with a surface partially transparent for visible radiation
KR100857990B1 (en) * 2002-08-05 2008-09-10 비오이 하이디스 테크놀로지 주식회사 Backlight Unit Structure of LCD
JP2004207183A (en) * 2002-12-26 2004-07-22 Nippon Electric Glass Co Ltd Fluorescent lamp

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CN101868845B (en) 2014-04-09
CN101868845A (en) 2010-10-20
WO2009050818A1 (en) 2009-04-23
WO2009050930A1 (en) 2009-04-23

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